Gelling agent, method for producing gelling agent, and cosmetic

Abstract

To provide a gelled product that specifically thickens a silicone oil and maintains long-term stability.SOLUTION: The present invention provides a gelling agent that is composed of a water-swellable clay mineral in which an ammonium group-modified organopolysiloxane having the average composition formula (1) described below is incorporated between its layers.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to a gelling agent, a method for producing the gelling agent, and a cosmetic composition. [Background technology]

[0002] Silicone oil has light spreadability, excellent smoothness, and water repellency, and cosmetics containing silicone oil can have a light feel. However, there is a limit to the compatibility with oils other than silicone oil, and in order to stabilize cosmetics containing them, it is necessary to solidify or thicken the silicone oil.

[0003] Methods reported for thickening silicone oil include using a crosslinked organopolysiloxane (Patent Document 1) and using a gelling agent in which an aromatic group and a siloxane chain are bonded by an amide bond (Patent Document 2). However, when the amount of these gelling agents used is large, the product may feel sticky or heavy to the touch.

[0004] Another method for thickening silicone oil has been reported, which involves blending clay minerals with silicone compounds trapped between layers. However, the ammonium salt organopolysiloxanes used are limited to those modified at both ends or those modified at the side chains, and the thickening effect and stability over time are insufficient (Patent Document 3). [Prior art documents] [Patent documents]

[0005] [Patent Document 1] JP 2016-169324 A [Patent Document 2] International Publication No. 2018 / 163989 [Patent Document 3] Japanese Patent Application Publication No. 63-72779 Summary of the Invention [Problem to be solved by the invention]

[0006] The present invention has been made in view of the above circumstances, and particularly aims to provide a gelling agent that is excellent in thickening silicone oil and giving a gelified product that is stable over time, a method for producing the same, and a cosmetic containing the gelling agent. [Means for Solving the Problems]

[0007] As a result of intensive studies to achieve the above object, the present inventors have found that a water-swellable clay mineral incorporating an ammonium salt-modified organopolysiloxane with one terminal end in its interlayer exhibits excellent thickening properties as a gelling agent for silicone oil. Further, it has been found that a cosmetic containing the gelling agent is excellent in feel of use and usability, and also excellent in stability over time, leading to the completion of the present invention.

[0008] In order to solve the above problems, in the present invention, a gelling agent is provided, which is composed of a water-swellable clay mineral incorporating an ammonium group-modified organopolysiloxane represented by the following average composition formula (1) in its interlayer. [Chemical formula] (In formula (1), R 1 is independently a group selected from an alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms, R 2 is an ammonium group represented by the following formula (2), a1 is 0 < a1 ≤ 20, a2 is 0 < a2 ≤ 12, b is 0 ≤ b ≤ 150, c is 0 ≤ c ≤ 10, and d is 0 ≤ d ≤ 5. However, a1 + a2 + b + c + d is 2 to 170. n is an integer of 1 to 3.) [Chemical formula] (In formula (2), R 3 is independently a hydrogen atom, or a group selected from an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms, Y is any one of groups represented by the following formula (3): A - is the anion that serves as the counterion for the ammonium ion.) [ka] (p is an integer in the range of 1≦p≦10, p1 is an integer in the range of 1≦p1≦10, and p2 is an integer in the range of 1≦p2≦10, with the proviso that 1≦p1+p2≦15. p3 is an integer in the range of 1≦p3≦10. p4 is an integer in the range of 1≦p4≦12. p5 is an integer in the range of 1≦p5≦10. R 4 is a hydrogen atom or a group selected from an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms.

[0009] Such a gelling agent can provide a gelling agent that is particularly excellent in thickening silicone oil and giving a gel that is stable over time.

[0010] In addition, A in the formula (2) - is preferably an anion selected from the group consisting of hydroxide ion, chloride ion, bromide ion, nitrate ion, hydrogen sulfate ion, hydrogen carbonate ion and acetate ion.

[0011] Such a gelling agent can provide a gelling agent that is more excellent in viscosity increasing property and stability over time.

[0012] The ammonium-modified organopolysiloxane is preferably represented by the following formula (4). [ka] (In formula (4), R 1 , R 2 and n is the same as above, and x is 0≦x≦100.

[0013] Such a gelling agent can provide a gelling agent that is particularly excellent in viscosity increasing property and stability over time.

[0014] The water-swellable clay mineral is preferably one or more water-swellable clay minerals selected from montmorillonite, saponite, smectite, hectorite, sodium silicic mica, sodium taeniolite, and lithium taeniolite.

[0015] As the water-swellable clay mineral, those mentioned above are preferable.

[0016] The present invention also provides a cosmetic preparation comprising a gelling agent.

[0017] Such a cosmetic can provide a cosmetic that has excellent adhesion, good fit, and excellent stability over time.

[0018] Moreover, it is preferable that the cosmetic further contains an oil that is liquid at 25°C.

[0019] Such a cosmetic can provide a cosmetic that has excellent adhesion, good fit, and excellent stability over time.

[0020] The oil preferably contains silicone oil.

[0021] As the oil agent, silicone oil is particularly suitable.

[0022] The present invention also provides a method for producing a gelling agent, comprising the steps of: The present invention provides a method for producing a gelling agent, which comprises a step of treating a water-swellable clay mineral with an ammonium group-modified organopolysiloxane represented by the following average composition formula (1): [ka] (In formula (1), R 1 are independently a group selected from an alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms, R 2is an ammonium group represented by the following formula (2), a1 satisfies 0 < a1 ≤ 20, a2 satisfies 0 < a2 ≤ 12, b satisfies 0 ≤ b ≤ 150, c satisfies 0 ≤ c ≤ 10, and d satisfies 0 ≤ d ≤ 5. However, a1 + a2 + b + c + d is from 2 to 170. n is an integer from 1 to 3.) [Chemical formula] (In formula (2), R 3 is independently a group selected from a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms, Y is any of the groups represented by the following formula (3), A - is an anion that serves as a counter ion to the ammonium ion.) [Chemical formula] (p is an integer from 1 ≤ p ≤ 10, p1 is from 1 ≤ p1 ≤ 10, p2 is an integer from 1 ≤ p2 ≤ 10, provided that 1 ≤ p1 + p2 ≤ 15. p3 is an integer from 1 ≤ p3 ≤ 10. p4 is an integer from 1 ≤ p4 ≤ 12. p5 is an integer from 1 ≤ p5 ≤ 10. R 4 is a group selected from a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms.)

[0023] For such a method for producing a gelling agent, a gelling agent excellent in thickening property and stability over time can be obtained.

[0024] Also, it is preferable that the anion represented by A - in the formula (2) is an anion selected from hydroxide ion, chloride ion, bromide ion, nitrate ion, hydrogen sulfate ion, hydrogen carbonate ion, and acetate ion.

[0025] For such a method for producing a gelling agent, a gelling agent more excellent in thickening property and stability over time can be obtained.

[0026] It is also preferable to use, as the ammonium group-modified organopolysiloxane, one represented by the following formula (4). [ka] (In formula (4), R 1 , R 2 and n is the same as above, and x is 0≦x≦100.

[0027] According to such a method for producing a gelling agent, it is possible to obtain a gelling agent that is particularly excellent in viscosity increasing properties and stability over time.

[0028] In addition, it is preferable to use, as the water-swellable clay mineral, one or more water-swellable clay minerals selected from montmorillonite, saponite, smectite, hectorite, sodium silicic mica, sodium taeniolite, and lithium taeniolite.

[0029] As the water-swellable clay mineral, those mentioned above are preferable. Effect of the Invention

[0030] The gelling agent of the present invention can thicken oils that are liquid at 25° C., particularly silicone oils, to give gels that are stable over time. Furthermore, cosmetics containing the gelling agent are not sticky or heavy when applied, and can be light, spread easily, and give a smooth feel. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0031] As described above, there has been a need for the development of a gelling agent that is particularly effective in thickening silicone oils and providing a gel that is stable over time.

[0032] As a result of intensive studies on the above problems, the inventor of the present invention has found that the gelling agent of the present invention can thicken an oil agent that is liquid at 25°C, particularly silicone oil, and provide a gelified product that is stable over time. The cosmetic containing the gelified product has no stickiness or heaviness during application, has a smooth and spreading texture, and can give a smooth feel, thus completing the present invention.

[0033] That is, the present invention relates to a gelling agent, wherein the gelling agent is composed of a water-swellable clay mineral in which an ammonium group-modified organopolysiloxane represented by the following average composition formula (1) is incorporated between layers. [Chemical formula] (In formula (1), R 1 is independently a group selected from an alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms, R 2 is an ammonium group represented by the following formula (2), a1 satisfies 0 < a1 ≤ 20, a2 satisfies 0 < a2 ≤ 12, b satisfies 0 ≤ b ≤ 150, c satisfies 0 ≤ c ≤ 10, and d satisfies 0 ≤ d ≤ 5. However, a1 + a2 + b + c + d is 2 to 170. n is an integer of 1 to 3.) [Chemical formula] (In formula (2), R 3 is independently a hydrogen atom or a group selected from an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms, Y is any one of the groups represented by the following formula (3), A - is an anion that serves as a counter ion to the ammonium ion.) [Chemical formula] (p is an integer where 1 ≤ p ≤ 10, p1 is 1 ≤ p1 ≤ 10, p2 is an integer where 1 ≤ p2 ≤ 10, provided that 1 ≤ p1 + p2 ≤ 15. p3 is an integer where 1 ≤ p3 ≤ 10. p4 is an integer where 1 ≤ p4 ≤ 12. p5 is an integer where 1 ≤ p5 ≤ 10.) R 4 is a group selected from a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms.)

[0034] Hereinafter, the present invention will be described in detail, but the present invention is not limited thereto.)

[0035] [(A) Gelator] The (A) gelator of the present invention is a gelator composed of a water-swellable clay mineral in which an ammonium group-modified organopolysiloxane represented by the following average composition formula (1) is incorporated between layers, and can be used alone or in combination of two or more.) [Chemical formula] (In formula (1), R 1 is independently a group selected from an alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms, R 2 is an ammonium group represented by the following formula (2), a1 is 0 < a1 ≤ 20, a2 is 0 < a2 ≤ 12, b is 0 ≤ b ≤ 150, c is 0 ≤ c ≤ 10, d is 0 ≤ d ≤ 5. Provided that a1 + a2 + b + c + d is 2 to 170. n is an integer from 1 to 3.) [Chemical formula] (In formula (2), R 3 is independently a group selected from a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms, Y is any of the groups represented by the following formula (3), A -is the anion that serves as the counterion for the ammonium ion.) [ka] (p is an integer in the range of 1≦p≦10, p1 is an integer in the range of 1≦p1≦10, and p2 is an integer in the range of 1≦p2≦10, with the proviso that 1≦p1+p2≦15. p3 is an integer in the range of 1≦p3≦10. p4 is an integer in the range of 1≦p4≦12. p5 is an integer in the range of 1≦p5≦10. R 4 is a hydrogen atom or a group selected from an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms.

[0036] [Ammonium-modified organopolysiloxane] The ammonium group-modified organopolysiloxane of the present invention is an organopolysiloxane having, in each molecule, one or more quaternary ammonium cations that are exchangeable with exchangeable cations present between the layers of the clay mineral.

[0037] The ammonium-modified organopolysiloxane in the present invention is represented by the following average composition formula (1), and can use either a single type alone or a combination of two or more types. [ka]

[0038] R 1 are each independently a group selected from an alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms. Specific examples include alkyl groups such as a methyl group, an ethyl group, a propyl group, a butyl group, and a pentyl group; cycloalkyl groups such as a cyclopentyl group; and aryl groups such as a phenyl group and a tolyl group. 1 As the alkyl group, a methyl group or a phenyl group is preferable, and a methyl group is more preferable.

[0039] R 2 is an ammonium group represented by the following general formula (2). [Chemical formula]

[0040] a1 is 0 < a1 ≤ 20, preferably 0 < a1 ≤ 5. a2 is 0 < a2 ≤ 12, preferably 1 ≤ a2 ≤ 3. b is 0 ≤ b ≤ 150, preferably 0 ≤ b ≤ 100. c is 0 ≤ c ≤ 10, preferably 0 ≤ c ≤ 1. d is 0 ≤ d ≤ 5, preferably 0 ≤ d ≤ 1. However, a1 + a2 + b + c + d is 2 to 170, preferably 2 to 110. n is an integer from 1 to 3, preferably 1.

[0041] R 3 is independently a group selected from a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms. Specifically, examples include alkyl groups such as methyl group, ethyl group, propyl group, butyl group, pentyl group, lauryl group, stearyl group, and myceryl group, cycloalkyl groups such as cyclopentyl group, and aryl groups such as phenyl group and tolyl group. R 3 is preferably a hydrogen atom, methyl group, ethyl group, propyl group, butyl group, pentyl group, lauryl group, stearyl group, or myceryl group, more preferably a hydrogen atom, methyl group, lauryl group, or stearyl group, and even more preferably a hydrogen atom or methyl group.

[0042] Y is any of the groups represented by the following formula (3). [Chemical formula] (p is an integer from 1 ≤ p ≤ 10, p1 is 1 ≤ p1 ≤ 10, p2 is an integer from 1 ≤ p2 ≤ 10, provided that 1 ≤ p1 + p2 ≤ 15. p3 is an integer from 1 ≤ p3 ≤ 10. p4 is an integer from 1 ≤ p4 ≤ 12. p5 is an integer from 1 ≤ p5 ≤ 10.)

[0043] R 4represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, preferably 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, or an arylene group having 7 to 10 carbon atoms, preferably a hydrogen atom or a methyl group, more preferably a hydrogen atom.

[0044] Specific examples of Y include the following structures. [ka]

[0045] A - A is an anion that serves as a counter ion for ammonium ion, and specific examples thereof include hydroxide ion, chloride ion, bromide ion, nitrate ion, hydrogen sulfate ion, hydrogen carbonate ion, acetate ion, citrate ion, lactate ion, glutamate ion, and aspartate ion. - As the cation, a chloride ion or an acetate ion is preferable, and a chloride ion is more preferable.

[0046] The ammonium group-modified organopolysiloxane may be one represented by the following formula (4): Ammonium group-modified organopolysiloxanes having such a structure are particularly capable of thickening silicone oils, and can provide gels that are stable over time. [ka] (In formula (4), R 1 , R 2 and n is the same as above, and x is 0≦x≦100.

[0047] [Water-swellable clay minerals] Examples of the water-swellable clay minerals used in the present invention include montmorillonite, saponite, smectite, hectorite, sodium silicic mica, sodium taeniolite, lithium taeniolite, etc. Among these, montmorillonite, saponite, smectite, and hectorite are preferred.

[0048] [Method of manufacturing gelling agent] The gelling agent of the present invention is characterized in that it is one which has been treated so that the ammonium-modified organopolysiloxane is incorporated between the layers of the water-swellable clay mineral.

[0049] The above-mentioned treatment method includes a method of adding a solvent such as isopropyl alcohol, ethanol, or cyclopentasiloxane in which the ammonium-modified organopolysiloxane is dissolved to a low-boiling solvent such as water, acetone, isopropyl alcohol, or ethanol in which the water-swellable clay mineral is dissolved or dispersed, stirring at room temperature or under heating, and then distilling off the solvent, and a method of adding the water-swellable clay mineral and the ammonium-modified organopolysiloxane to a low-boiling solvent such as water, acetone, isopropyl alcohol, or ethanol, stirring at room temperature or under heating, and then distilling off the solvent. When heating and stirring, the temperature is preferably 40 to 100°C, more preferably 40 to 60°C.

[0050] The amount of the ammonium-modified organopolysiloxane used as the treatment agent is preferably 10 to 200 parts by mass, and more preferably 50 to 150 parts by mass, per 100 parts by mass of the water-swellable clay mineral.

[0051] In this case, A in the formula (2) - can be an anion selected from the group consisting of hydroxide ion, chloride ion, bromide ion, nitrate ion, hydrogen sulfate ion, hydrogen carbonate ion, and acetate ion.

[0052] The ammonium group-modified organopolysiloxane may be represented by the formula (4):

[0053] The water-swellable clay mineral may be one or more water-swellable clay minerals selected from montmorillonite, saponite, smectite, hectorite, sodium silicic mica, sodium taeniolite, and lithium taeniolite.

[0054] [Cosmetics] The present invention relates to a cosmetic preparation comprising the above gelling agent. The cosmetic preparation may further comprise an oil agent that is liquid at 25° C. In addition, the oil agent preferably comprises silicone oil.

[0055] [(B) Oil that is liquid at 25°C] The cosmetic preparation of the present invention may contain (B) an oily agent that is liquid at 25° C. The oily agent preferably has a kinetic viscosity at 25° C. of 0.5 to 100 mm 2 / s, 0.5 to 20 mm 2 More preferred is one having a viscosity of 1 / s. The oil agent may be used without any particular limitation as long as it is one that is generally blended in cosmetics, and may be used alone or in combination of two or more. In this specification, the kinetic viscosity is the kinetic viscosity at 25°C measured by a Cannon-Fenske viscometer according to the method described in JIS Z 8803:2011.

[0056] (B) Examples of oils that are liquid at 25°C include hydrocarbon oils, higher fatty acids, natural animal and vegetable oils and semi-synthetic oils and fats, esters, silicone oils, and fluorine-based oils, and specific examples are as follows.

[0057] Hydrocarbon oil The hydrocarbon oil may be a linear or branched hydrocarbon oil, and may be either a volatile or non-volatile hydrocarbon oil.Specific examples of the hydrocarbon oil include olefin oligomer, isododecane (INCI:Isododecane), dodecane (INCI:Dodecane), isohexadecane (INCI:Isohexadecane), undecane (INCI:Undecane), squalane (INCI:Squalane), squalene (INCI:Squalene), mineral oil (INCI:Mineral Oil), liquid isoparaffin, polyisobutylene (INCI:Hydrogenated Polyisobutene), (C13-15) alkane (INCI:C13-15 Alkane), and the like.

[0058] ·Higher fatty acids Examples of higher fatty acids include oleic acid (INCI: Oleic Acid), linoleic acid (INCI: Linoleic Acid), linolenic acid (INCI: Linolenic Acid), arachidonic acid (INCI: Arachidonic Acid), eicosapentaenoic acid (EPA) (INCI: Eicosapentaenoic Acid), docosahexaenoic acid (DHA) (INCI: Docosahexaenoic Acid), isostearic acid (INCI: Isostearic Acid), and hydroxystearic acid (INCI: Hydroxystearic Acid).

[0059] Natural animal and vegetable oils and semi-synthetic oils Natural animal and vegetable oils and semi-synthetic oils and fats, アボガド oil (: Indicates the name (INCI: Persea Gratissima (Avocado) Oil)), アマニ Oil (: Indicates the name (INCI: Linum Usitatissimum (Linseed) Seed Oil)), アーモンドoil (: Indicates the name (INCI: Prunus Amygdalus Dulcis (Sweet Almond) Oil)), オリーブoil (: Indicates the name (INCI: Olea Europaea (Olive) Fruit Oil)), アメリカガヤ Oil (: Indicates the name (INCI: Torreya Californica) (California Nutmeg) Oil)), コウスイガヤ Oil (: Indicates the name (INCI: Cymbopogon Nardus (Citronella) Oil), Shark Liver Oil (INCI: Shark Liver Oil), Cod Liver Oil (INCI: Cod Liver Oil), Fish Liver Oil (INCI: Fish Liver Oil), Kyounin Oil (INCI: Kyounin Yu), Goma Oil (INCI: Sesamum Indicum (Sesame) Seed Oil), Comae Germ Oil (INCI: Oryza Sativa (Rice) Germ Oil), Comena Oil (INCI: Oryza Sativa (Rice) Bran Oil), Saffron Oil (INCI: Camellia Kissi Seed Oil), Saffron Oil (INCI: Carthamus Tinctorius (Safflower) Seed Oil), Turtle Oil (INCI: Turtle Oil), Tsubaki Oil (INCI: Camellia Japonica Seed Oil), Evening Primrose Oil (INCI: Oenothera Biennis (Evening Primrose) Oil), Tomologosus Germ Oil (INCI: Zea Mays (Corn) Germ Oil), Natanes Oil (INCI: Rape Shushi Yu), Corn Germ Oil (INCI: Triticum Vulgare(Wheat) Germ Oil), palm oil (INCI: Elaeis Guineensis (Palm) Oil), palm kernel oil (INCI: Elaeis Guineensis (Palm) Kernel Oil), hematuria oil (INCI: Ricinus Communis (Castor) Seed Oil), hardened hematuria oil (INCI: Hydrogenated Castor Oil), hematuria oil (INCI: Helianthus Annuus (Sunflower) Seed Oil), bulb seed oil (INCI: Vitis Vinifera (Grape) Seed Oil), hohoba oil (INCI: Simmondsia Chinensis (Jojoba) Seed Oil), Macadamia Ternifolia Seed Oil, Mink Oil, Medowfoam Oil, Gossypium Herbaceum (Cotton) Seed Oil, Coconut Oil, Hydrogenated Coconut Oil, Egg Oil, etc.

[0060] ·エステル The ester is a liquid oil having a structure in which a fatty acid having 1 to 20 carbon atoms is condensed with an alcohol having 1 to 20 carbon atoms, and examples of the ester include monoesters, or polyesters such as diesters and triesters. Specifically, n-alkyl glycol monoisostearates such as diisobutyl adipate (display name (INCI: Diisobutyl Adipate)), dihexyldecyl adipate (display name), diheptylundecyl adipate (display name (INCI: Diheptylundecyl Adipate)), and isostearyl isostearate (display name (INCI: Isostearyl Isostearate)), isocetyl isostearate (display name (INCI: Isocetyl Isostearate)), trimethylolpropane triisostearate (display name (INCI: Trimethylolpropane Triisostearate)), glycol diethylhexanoate (display name (INCI: Glycol Diethylhexanoate)), and cetyl ethylhexanoate (display name (INCI: Cetyl Ethylhexanoate), triethylhexanoin (:Display Name (INCI:Triethylhexanoin)), trimethylolpropane triethylhexanoate (:Display Name (INCI:Trimethylolpropane Triethylhexanoate)), pentaerythrityl tetraethylhexanoate (:Display Name (INCI:Pentaerythrityl Tetraethylhexanoate)), cetyl octanoate (:Display Name (INCI:Cetyl Ethylhexanoate)), octyldodecyl stearoyloxystearate (:Display Name (INCI:Octyldodecyl Stearoyl Stearate)), and other octyldodecyl esters, oleyl oleate (:Display Name (INCI:Oleyl Oleate)), octyldodecyl oleate (:Display Name (INCI:Octyldodecyl Oleate)), decyl oleate (:Display Name (INCI:Decyl Oleate), Neopentyl Glycol Dioctanoate (Indicated Name (INCI: Neopentyl GlycolDiethylhexanoate), Neopentyl glycol dicaprate (:Display name (INCI:Neopentyl Glycol Dicaprate)), Triethyl citrate (:Display name (INCI:Triethyl Citrate)), Diethylhexyl succinate (:Display name (INCI:Diethylhexyl Succinate)), Amyl acetate (:Display name (INCI:Amyl Acetate)), Ethyl acetate (:Display name (INCI:Etyl Acetate)), Butyl acetate (:Display name (INCI:Butyl Aceetate)), Isocetyl stearate (:Display name (INCI:Isocetyl Stearate)), Butyl stearate (:Display name (INCI:Butyl Stearate)), Diisopropyl sebacate (:Display name (INCI:Diisopropyl Sebacate)), Diethylhexyl sebacate (:Display name (INCI:Diethylhexyl Sebacate), cetyl lactate (INCI: Cetyl Lactate), myristyl lactate (INCI: Myristyl Lactate), isononyl isononanoate (INCI: Isononyl Isononanoate), isotridecyl isononanoate (INCI: Isotridecyl Isononanoate), isopropyl palmitate (INCI: Isopropyl Palmitate), ethylhexyl palmitate (INCI: Ethylhexyl Isopalmitate), hexyldecyl palmitate (INCI: Isocetyl Palmitate, Hexyldecyl Palmitate), and other palmitic acid esters; cholesteryl hydroxystearate (INCI: Cholesteryl Hydroxystearate), isopropyl myristate (INCI: Isopropyl Myristate), Octyldodecyl myristate (Indication name (INCI: Octyldodecyl Myristate)), Myristyl myristate (Indication name (INCI: MyristylExamples of glyceride oils include myristic acid esters such as myristate, ethylhexyl laurate (INCI: Ethylhexyl Laurate), hexyl laurate (INCI: Hexyl Laurate), dioctyldodecyl lauroyl glutamate (INCI: Dioctyldodecyl Lauroyl Glutamate), isopropyl lauroyl sarcosine ester (INCI: Isopropyl Lauroyl Sarcosinate), diisostearyl malate (INCI: Diisostearyl Malate), glyceryl acetate (INCI: Glyceryl Acetate), and glyceryl stearate (INCI: Glyceryl Stearate).

[0061] Silicone oil Examples of silicone oils include trisiloxane (:display name (INCI:Trisiloxane)), volatile dimethicone (:display name (INCI:Dimethicone)), low viscosity dimethicone (:display name (INCI:Dimethicone)), cyclotetrasiloxane (:display name (INCI:Cyclotetrasiloxane)), cyclopentasiloxane (:display name (INCI:Cyclopentasiloxane)), cyclohexasiloxane (:display name (INCI:Cyclohexasiloxane)), methyl trimethicone (:display name (INCI:Methyl Trimethicone)), caprylyl methicone (:display name (INCI:Caprylyl Methicone)), phenyl trimethicone (:display name (INCI:Phenyl Trimethicone)), methylphenylpolysiloxane (:display name (INCI:Diphenyl Dimethicone), diphenylsiloxy phenyl trimethicone (:display name (INCI:Diphenylsiloxy Phenyl Trimethicone)), ethyl methicone (:display name (INCI:Ethyl Methicone)), ethyl trisiloxane (:display name (INCI:Ethyl Trisiloxane)), hydrogen dimethicone (:display name (INCI:Hydrogen Dimethicone)), and other linear or branched dimethicones with low to high viscosity, amodimethicone (:display name (INCI:Amodimethicone)), aminopropyl dimethicone (:display name (INCI:Aminopropyl Examples include silicone rubbers such as highly polymerized gum-like dimethicone (display name (INCI:Dimethicone)), gum-like amodimethicone (display name (INCI:Amodimethicone)), gum-like dimethylsiloxane-methylphenylsiloxane copolymer, as well as cyclic organopolysiloxane solutions of silicone gums and rubbers, amino acid-modified silicones, fluorine-modified silicones, silicone resins, and silicone resin solutions.

[0062] Fluorine-based oils Examples of fluorine-based oil agents include perfluoropolyethers such as polyperfluoromethylisopropyl ether (INCI: Polyperfluoromethylisopropyl Ether), and perfluorocarbons such as perfluorodecalin (INCI: Perfluorodecalin) and perfluorohexane (INCI: Perfluorohexane).

[0063] (B) As the oil agent that is liquid at 25°C, silicone oil is preferable, and among them, particularly methyl trimethicone (: display name (INCI: Methyl Trimethicone)), trisiloxane (: display name (INCI: Trisiloxane)), volatile dimethicone (: display name (INCI: Dimethicone)), kinematic viscosity at 25°C of 0.5 to 20 mm 2 / s Dimethicone (: display name (INCI: Dimethicone)) and diphenylsiloxy phenyl trimethicone (: display name (INCI: Diphenylsiloxy Phenyl Trimethicone)) are more preferred.

[0064] [Other ingredients] The cosmetic of the present invention may contain any suitable amount of ingredients other than those mentioned above. Examples of such optional ingredients include (1) an oily ingredient that is solid or semi-solid at 25°C, (2) a compound having an alcoholic hydroxyl group, (3) a surfactant, (4) a composition consisting of a crosslinked organopolysiloxane and an oil agent that is liquid at 25°C, (5) a film-forming agent, (6) an antiperspirant, (7) an antibacterial agent, and (8) other additives. These may be used alone or in combination of two or more.

[0065] (1) Oily components that are solid or semi-solid at 25°C The oil component that is solid or semi-solid at 25°C may be either solid or semi-solid, and for example, higher fatty acids, higher alcohols, esters, silicone oils, and fluorine-based oils can be used.

[0066] Solid oily ingredients In the present invention, when it is desired to solidify the cosmetic, it is preferable to blend wax, hydrocarbon, ester, higher alcohol, and higher fatty acid that are solid at 25°C. The oily component that is solid at 25°C is preferably one having a melting point of 40°C or higher, more preferably 60 to 110°C, and examples thereof include wax, hydrocarbon, ester, higher alcohol, and higher fatty acid, and is not particularly limited as long as it is a raw material that can be blended in a normal cosmetic. Specific examples thereof include vegetable waxes such as carnauba wax, candelilla wax, rice wax, Japan wax, and shea butter, animal waxes such as beeswax and whale wax, solid paraffin, polyethylene, ceresin, ozokerite, and microcrystalline wax, hydrocarbon waxes such as stearyl alcohol, behenyl alcohol, and cetanol, fatty acids such as stearic acid and behenic acid, and silicone waxes such as acrylic silicone resins of acrylic-silicone graft or block copolymers (acrylic-silicone graft copolymers: KP-561P, 562P, etc., manufactured by Shin-Etsu Chemical Co., Ltd.) or derivatives thereof.

[0067] Semi-solid oily ingredients In the present invention, when it is desired to give a cosmetic a film-like texture or thickness, it is preferable to blend a hydrocarbon or ester that is semi-solid (paste-like) at 25° C., and there is no particular limitation as long as it is a raw material that can be normally blended in a cosmetic. Specific examples include lanolin, petrolatum, dipentaerythritol fatty acid esters, hardened oils, etc.

[0068] (2) Compounds containing an alcoholic hydroxyl group Examples of the compound having an alcoholic hydroxyl group include lower alcohols, such as ethanol and isopropanol, preferably having 2 to 5 carbon atoms, sugar alcohols, such as sorbitol and maltose, and sterols, such as cholesterol, sitosterol, phytosterol, and lanosterol. 1 The higher alcohols exemplified as the component (a) are not included in the compounds having an alcoholic hydroxyl group.

[0069] (3) Surfactants The surfactant may be nonionic, anionic, cationic or amphoteric, but is not particularly limited, and any surfactant used in ordinary cosmetics may be used. Among these surfactants, partially crosslinked polyether modified silicone, partially crosslinked polyglycerin modified silicone, linear or branched polyoxyethylene modified organopolysiloxane, linear or branched polyoxyethylene polyoxypropylene modified organopolysiloxane, linear or branched polyoxyethylene / alkyl co-modified organopolysiloxane, linear or branched polyoxyethylene polyoxypropylene / alkyl co-modified organopolysiloxane, linear or branched polyglycerin modified organopolysiloxane, linear or branched polyglycerin modified organopolysiloxane, linear or branched polyglycerin / alkyl co-modified organopolysiloxane pyrrolidone modified organopolysiloxane are preferred. In these surfactants, the content of hydrophilic polyoxyethylene groups, polyoxyethylene polyoxypropylene groups or polyglycerin residues preferably accounts for 10 to 70% by mass in the molecule. When using a partially crosslinked polyether-modified silicone or a partially crosslinked polyglycerin-modified silicone, in a composition consisting of the crosslinked organopolysiloxane and an oil that is liquid at 25°C, it is preferred that the crosslinked organopolysiloxane swells with the liquid oil in an amount equal to or greater than its own weight. As the liquid oil, liquid silicones, hydrocarbon oils, ester oils, natural animal and vegetable oils, semi-synthetic oils and other fluorine-based oils in the optional oils can be used. For example, the kinetic viscosity at 25°C of the crosslinked organopolysiloxane is 0.65 to 100 mm. 2Examples of the oils include low viscosity silicones of 100 / s, liquid paraffin, squalane, isododecane, isohexadecane, and other hydrocarbon oils, glyceride oils such as trioctanoin, isotridecyl isononanoate, N-acyl glutamic acid esters, lauroyl sarcosinate, and other ester oils, and natural animal and vegetable oils such as macadamia nut oil.Specific examples include KSG-210, KSG-240, KSG-310, KSG-320, KSG-330, KSG-340, KSG-320Z, KSG-350Z, KSG-710, KSG-810, KSG-820, KSG-830, KSG-840, KSG-820Z, KSG-850Z, and the like, manufactured by Shin-Etsu Chemical Co., Ltd. Specific examples of surfactants that are not crosslinked organopolysiloxanes include KF-6011, KF-6013, KF-6043, KF-6017, KF-6028, KF-6038, KF-6048, KF-6100, KF-6104, KF-6105, and KF-6106 manufactured by Shin-Etsu Chemical Co., Ltd. In any case, the content of the surfactant in the cosmetic is preferably 0.1 to 20% by mass. If it is 0.1% by mass or more, the function of dispersion and emulsification can be sufficiently performed, and if it is 20% by mass or less, it is preferable because there is no risk of the cosmetic having a sticky feel when used. The HLB of the surfactant is not limited, but is preferably 2 to 14.5 for the purpose of maintaining the water resistance of the cosmetic.

[0070] (4) A composition comprising a crosslinked organopolysiloxane and an oil agent that is liquid at 25°C. In a composition comprising a crosslinked organopolysiloxane and an oil that is liquid at 25° C., it is preferred that the crosslinked organopolysiloxane swells with the liquid oil in an amount equal to or greater than its own weight. In the optional oil, liquid silicones, hydrocarbon oils, ester oils, natural animal and vegetable oils, semi-synthetic oils, and fluorine-based oils can be used. 2Examples of the oils include low-viscosity silicones of 100 / s, liquid paraffin, squalane, isododecane, isohexadecane, and other hydrocarbon oils, glyceride oils such as trioctanoin, isotridecyl isononanoate, N-acyl glutamic acid esters, lauroyl sarcosinic acid esters, and natural animal and vegetable oils such as macadamia nut oil. The component (4) is different from the component (3) according to the present invention, and is a compound that does not have a polyether or polyglycerin structure in its molecular structure. Specific examples include the KSG series (trade name) manufactured by Shin-Etsu Chemical Co., Ltd., in particular KSG-15, KSG-16, KSG-016F, KSG-19, KSG-41, KSG-42, KSG-43, KSG-44, KSG-042Z, and KSG-045Z.

[0071] (5) Film-forming agents The film-forming agent is mainly blended for the purpose of further maintaining the effect durability of the cosmetic. Although there is no particular limitation, it is preferable that the composition is a silicone-based composition from the viewpoint of imparting water repellency. Specifically, trimethylsiloxysilicate, acrylic-silicone film-forming agent, silicone-modified norbornene, silicone-modified pullulan, etc. can be used. The film-forming agent may be dissolved in a liquid oil at room temperature beforehand and then blended into the cosmetic. As the liquid oil, liquid silicone, hydrocarbon oil, ester oil, natural animal and vegetable oil, semi-synthetic oil, etc., in the optional oil, and fluorine-based oil can be used. For example, a kinetic viscosity at 25°C of 0.65 to 100 mm 2Examples of such oils include low viscosity silicones of 100 / s, liquid paraffin, squalane, isododecane, isohexadecane, and other hydrocarbon oils, glyceride oils such as trioctanoin, isotridecyl isononanoate, N-acyl glutamic acid esters, lauroyl sarcosinate, and other ester oils, and natural animal and vegetable oils such as macadamia nut oil. Specific examples of such oils include KF-7312J, a silicone solution of trimethylsiloxysilicate, KP-545 and KP-549, silicone solutions of acrylic-silicone coating agents, NBN-30-ID, a silicone-modified norbornene solution in isododecane, TSPL-30-ID, a silicone-modified pullulan solution in isododecane, and TSPL-30-D5, a silicone solution, all manufactured by Shin-Etsu Chemical Co., Ltd.

[0072] (6) Antiperspirants When the cosmetic composition according to the present invention is a deodorant, an antiperspirant can be optionally blended. The antiperspirant is not particularly limited as long as it is a component that suppresses sweat generation by astringing the skin, and a wide variety of general-purpose components can be used. Examples include chlorohydroxyaluminum, aluminum chloride, allantoin chlorohydroxyaluminum, allantoin aluminum salt, tannic acid, aluminum potassium sulfate, zinc oxide, zinc paraphenolsulfonate, burnt alum, tetrachloro(Al / zirconium) hydrate, trichlorohydrex glycine(Al / zirconium), and the like. In particular, as a component that exhibits a high effect, an antiperspirant active ingredient selected from the group consisting of aluminum halide, hydroxyaluminum halide, and complexes or mixtures of these with oxyhalogenated zirconyl and hydroxyhalogenated zirconyl. These antiperspirants can be dissolved in water and blended, or the powder can be blended directly into the formulation. The antiperspirant can be a commercially available product. The commercially available product used may be in the form of a mixed raw material with other components. The content of the antiperspirant is not particularly limited and can be appropriately changed depending on the content of other components. For the purpose of obtaining a deodorant agent having excellent antiperspirant effect and for the purpose of obtaining a deodorant agent with reduced irritation to the skin, the content is preferably 0.001 to 30% by mass, more preferably 0.01 to 20% by mass in the cosmetic.

[0073] (7) Antibacterial agents The antibacterial agent is not particularly limited as long as it is a component that can obtain a deodorizing effect by suppressing the proliferation of the bacteria normally present on the skin that produce the substances that cause body odor.For example, antibacterial agents such as triclosan, benzylkonium chloride, benzothonium chloride, chlorhexidine hydrochloride, chlorhexidine gluconate, halocarban, and isomethylphenol are commonly used.In addition, essential oils and extracts derived from herbal medicines, such as dry distillation extract of green tea, that have antibacterial properties may be added. Examples of antibacterial agents having a deodorizing effect, such as essential oils and extracts derived from herbal medicines, include green tea extract, lavender extract, Scutellaria baicalensis extract, Coptis japonica extract, Plantain extract, Artemisia capillaris extract, Aloe arborescens extract, Sophora arborescens root extract, Sasa kumamoto leaf extract, garlic extract, Hamamelis extract, black tea extract, sage leaf extract, Zanthoxylum pepper extract, ginger root extract, Calamus calamus root extract, Hedera helix extract, Houttuynia cordata extract, peach fruit extract, peach leaf extract, peppermint leaf extract, Cnidium officinalis extract, eucalyptus leaf extract, peanut seed coat extract, lychee extract, and Sanguisorba officinalis extract.

[0074] (8) Other additives Other additives include oil-soluble gelling agents, moisturizing agents, preservatives, fragrances, salts, antioxidants, pH adjusters, chelating agents, cooling agents, anti-inflammatory agents, skin-beautifying ingredients (skin whitening agents, cell activators, skin roughness improving agents, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, etc.

[0075] Oil-soluble gelling agent Examples of the oil-soluble gelling agent include organically modified bentonite, metal soaps such as aluminum stearate, magnesium stearate, and zinc myristate, amino acid derivatives such as N-lauroyl-L-glutamic acid and α,γ-di-n-butylamine, dextrin fatty acid esters such as dextrin palmitate, dextrin stearate, and dextrin 2-ethylhexanoate palmitate, sucrose fatty acid esters such as sucrose palmitate and sucrose stearate, fructooligosaccharide fatty acid esters such as fructooligosaccharide stearate and fructooligosaccharide 2-ethylhexanoate, and benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol.

[0076] Moisturizer Examples of moisturizing agents include glycerin, sorbitol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, pentylene glycol, glucose, xylitol, maltitol, polyethylene glycol, hyaluronic acid, chondroitin sulfate, pyrrolidone carboxylate, polyoxyethylene methylglucoside, polyoxypropylene methylglucoside, egg yolk lecithin, soybean lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, and sphingophospholipids.

[0077] Preservatives Examples of preservatives include alkyl paraoxybenzoates, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, and phenoxyethanol, while examples of antibacterial agents include benzoic acid, salicylic acid, carbolic acid, sorbic acid, alkyl paraoxybenzoates, parachlorometacresol, hexachlorophene, trichlorocarbanilide, and photosensitizers.

[0078] ·Fragrance Fragrances include natural fragrances and synthetic fragrances. Natural fragrances include plant-based fragrances separated from flowers, leaves, wood, peels, etc., and animal-based fragrances such as musk and civet. Synthetic fragrances include hydrocarbons such as monoterpenes, alcohols such as aliphatic alcohols and aromatic alcohols, aldehydes such as terpene aldehydes and aromatic aldehydes, ketones such as alicyclic ketones, esters such as terpene esters, lactones, phenols, oxides, nitrogen-containing compounds, and acetals.

[0079] ·salts Examples of salts include inorganic salts, organic acid salts, amine salts, and amino acid salts. Examples of inorganic salts include sodium salts, potassium salts, magnesium salts, calcium salts, aluminum salts, zirconium salts, zinc salts, etc. of inorganic acids such as hydrochloric acid, sulfuric acid, carbonic acid, and nitric acid; examples of organic acid salts include salts of organic acids such as acetic acid, dehydroacetic acid, citric acid, malic acid, succinic acid, ascorbic acid, and stearic acid; examples of amine salts and amino acid salts include salts of amines such as triethanolamine, and salts of amino acids such as glutamic acid. In addition, salts of hyaluronic acid, chondroitin sulfate, etc., aluminum zirconium glycine complexes, etc., and even neutral salts of acids and alkalies used in cosmetic formulations can also be used.

[0080] Antioxidants Examples of antioxidants include, but are not limited to, carotenoids, ascorbic acid and its salts, ascorbyl stearate, tocopherol acetate, tocopherol, pt-butylphenol, butylhydroxyanisole, dibutylhydroxytoluene, phytic acid, ferulic acid, thiotaurine, hypotaurine, sulfites, erythorbic acid and its salts, chlorogenic acid, epicatechin, epigallocatechin, epigallocatechin gallate, apigenin, campherol, myricetin, and quercetin.

[0081] pH adjuster Examples of pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium hydrogen carbonate, and ammonium hydrogen carbonate.

[0082] Chelating agents Examples of the chelating agent include alanine, edetic acid sodium salt, sodium polyphosphate, sodium metaphosphate, phosphoric acid, aspartic acid diacetate, and ethylenediamine disuccinic acid.

[0083] · Cooling agent Examples of cooling agents include L-menthol and camphor.

[0084] Anti-inflammatory Anti-inflammatory agents include allantoin, glycyrrhizinic acid and its salts, glycyrrhetinic acid and stearyl glycyrrhetinate, tranexamic acid, azulene, and the like.

[0085] ·Skin-beautifying ingredients Examples of skin-beautifying ingredients include whitening agents such as vitamin C derivatives, hydroquinone, tranexamic acid, arbutin, phenylethyl resorcinol, kojic acid, and plant extracts; cell activators such as royal jelly, photosensitizers, cholesterol derivatives, and calf blood extract; rough skin improving agents; blood circulation promoters such as nonylic acid valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingerone, cantharides tincture, ichthammol, caffeine, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, and γ-oryzanol; skin astringents such as zinc oxide and tannic acid; and antiseborrheic agents such as sulfur and thianthrol.

[0086] Vitamins Vitamins include vitamin A oil, retinol, retinol acetate, retinol palmitate, and other vitamin A derivatives, riboflavin, riboflavin butyrate, flavin adenine nucleotide, and other vitamin B2 derivatives, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine tripalmitate, and other vitamin B6 derivatives, vitamin B12 and its derivatives, vitamin B15 and its derivatives, and other vitamin B derivatives, L-ascorbic acid, L-ascorbic acid dipalmitate, sodium L-ascorbic acid 2-sulfate, and dipotassium L-ascorbic acid phosphate diester. vitamin C such as ergocalciferol and cholecalciferol; vitamin E such as α-tocopherol, β-tocopherol, γ-tocopherol, dl-α-tocopherol acetate, dl-α-tocopherol nicotinate, and dl-α-tocopherol succinate; nicotinic acids such as nicotinic acid, benzyl nicotinate, and nicotinamide; vitamin H, vitamin P, pantothenic acids such as calcium pantothenate, D-pantothenyl alcohol, pantothenyl ethyl ether, and acetyl pantothenyl ethyl ether; and biotin.

[0087] Amino acids Examples of amino acids include glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, and tryptophan.

[0088] ·Nucleic acid The nucleic acid includes deoxyribonucleic acid and the like.

[0089] ·hormone Hormones include estradiol, ethenyl estradiol, and the like.

[0090] ·Inclusion compounds An example of the inclusion compound is cyclodextrin. EXAMPLES

[0091] The present invention will be specifically described below using examples and comparative examples, but the present invention is not limited to these.

[0092] In the following examples, unless otherwise specified, "%" in the composition means "% by mass." The viscosity is a value measured at 25°C using a rotational viscometer as described in JIS K 7117-1:1999.

[0093] [Production Examples 1-4, Silicone Modified Clay Minerals 1-2] Manufacturing Example 1 200 g of an aqueous solution in which 2 g of purified bentonite (trade name: Kunipia F, manufactured by Kunimine), a water-swelling clay mineral, was dispersed was heated and stirred at 60° C., while 200 g of isopropyl alcohol in which 2 g of an ammonium group-modified organopolysiloxane represented by the following formula (A-1) was dissolved was dropped. After stirring for 2 hours, the solution was removed by filtration, and the mixture was dried under reduced pressure to obtain a clay mineral treated with an ammonium group-modified organopolysiloxane.

[0094] [ka]

[0095] Manufacturing Example 2 A clay mineral treated with an ammonium-modified organopolysiloxane was obtained in the same manner as in Production Example 1, except that an ammonium-modified organopolysiloxane represented by the following formula (A-2) was used instead of the ammonium-modified organopolysiloxane (A-1) used in Production Example 1.

[0096] [ka]

[0097] Production Example 3 A clay mineral treated with an ammonium-modified organopolysiloxane was obtained in the same manner as in Production Example 1, except that an ammonium-modified organopolysiloxane represented by the following formula (A-3) was used instead of the ammonium-modified organopolysiloxane (A-1) used in Production Example 1.

[0098] [ka]

[0099] Production Example 4 A clay mineral treated with an ammonium-modified organopolysiloxane was obtained in the same manner as in Production Example 1, except that an ammonium-modified organopolysiloxane represented by the following formula (A-4) was used instead of the ammonium-modified organopolysiloxane (A-1) used in Production Example 1.

[0100] [ka]

[0101] Silicone modified clay mineral 1 Silicone-modified clay mineral 1 was obtained in the same manner as in Production Example 1, except that the ammonium-modified organopolysiloxane (A-1) used in Production Example 1 was replaced with an ammonium-modified organopolysiloxane represented by the following formula (A-1)'.

[0102] [ka]

[0103] Silicone modified clay mineral 2 Silicone-modified clay mineral 2 was obtained in the same manner as in Production Example 1, except that the ammonium-modified organopolysiloxane (A-1) used in Production Example 1 was replaced with an ammonium-modified organopolysiloxane represented by the following formula (A-2)'.

[0104] [ka]

[0105] [Examples 1 to 4, Comparative Examples 1 to 5] A gel composition was obtained by mixing the components in the amounts shown in Table 1 according to the manufacturing method described below.

[0106] [Table 1] component (※) Bentonite: Kunipia F (manufactured by Kunimine Industries) (※) Quaternium-18 Bentonite: Moistite WO (manufactured by Kunimine Industries) (※) Cyclopentasiloxane: KF-995 (Kinematic viscosity: 4mm 2 / s, manufactured by Shin-Etsu Chemical Co., Ltd.) (※) Dimethylpolysiloxane: KF-96A-6cs (Kinematic viscosity: 6mm 2 / s, manufactured by Shin-Etsu Chemical Co., Ltd.) (※) PEG-10 Dimethicone: KF-6017 (Shin-Etsu Chemical Co., Ltd.)

[0107] (Manufacturing method) Component (B) in Table 1 was stirred with a disperser while being heated at 60°C, and component (A) was added little by little. Subsequently, PEG-10 dimethicone or propyl carbonate was added as necessary, and the mixture was stirred for 10 minutes to obtain a gel composition.

[0108] The gel compositions of Examples 1 to 4 and Comparative Examples 1 to 5 were evaluated for appearance (uniformity), appearance (stability over time at 50° C.), and composition viscosity according to the following evaluation methods. The results are shown in Table 1.

[0109] Appearance (Uniformity) 25 g of the gel composition was placed in a glass bottle, and the occurrence of liquid phase separation, aggregation of clay minerals, and sedimentation was visually observed and evaluated according to the following criteria. (Evaluation Criteria) 〇: No powder clumping or oil floating △: Some powder clumping and oil floating. ×: Powder and oil are completely separated

[0110] [Stability over time at 50℃] The gel composition was placed in a 50 g glass bottle and stored at 50° C. for one week, after which the occurrence of liquid phase separation or aggregation of the gel composition was visually observed and evaluated according to the following criteria. (Evaluation Criteria) ◎: No change from immediately after preparation of the composition ○: Oil floating in some areas ×: Powder and oil are separated

[0111] [viscosity] 50 g of the gel composition was placed in a glass bottle, and the viscosity at 25° C. was measured by the method using a rotational viscometer described in JIS K 7117-1: 1999. For samples whose viscosity could not be measured because they had lost fluidity and solidified, the results were indicated with ⊚.

[0112] As is clear from the above results, in the cases of Examples 1 to 4, a silicone oil gel composition was obtained, which was excellent in both uniformity of appearance and stability over time.

[0113] On the other hand, gelation was not observed in Comparative Example 1 in which no clay mineral was blended.

[0114] In Comparative Examples 2 and 3, which contained a clay mineral treated with an organopolysiloxane modified at both ends with ammonium groups or an organopolysiloxane with ammonium groups in the side chains, it was found that the composition had a low viscosity and was also poor in appearance uniformity and stability over time.

[0115] Furthermore, in Comparative Examples 4 and 5, in which an untreated clay mineral or an organically modified clay mineral was used, it was found that the clay mineral significantly aggregated in the composition, resulting in poor uniformity in appearance.

[0116] Thus, it was found that the organopolysiloxane of the present invention is capable of satisfactorily gelling silicone oil and providing a gel composition that is excellent in uniformity and stability over time.

[0117] [Examples 5 to 7] Example 5: Water-in-oil cream (Component) (%) 1. Dimethylpolysiloxane(※) 10.0 2. Cyclopentasiloxane 7.0 3. Glyceryl trioctanoate 4.5 4. Polyether modified branched silicone (※) 2.0 5. Manufacturing Example 1 1.5 6. Dipropylene glycol 7.0 7. Preservatives (appropriate amount) 8.Fragrance (appropriate amount) 9. Remaining purified water Total 100.0 (※) Dimethylpolysiloxane: KF-96A-6cs (manufactured by Shin-Etsu Chemical Co., Ltd.) (※) Polyether modified branched silicone: KF-6028 (Shin-Etsu Chemical Co., Ltd.) A) Components 1 to 5 were mixed. B) Components 6 to 9 were mixed, added to the above A) and emulsified with stirring.

[0118] The water-in-oil cream thus obtained was not oily or sticky, spread lightly and refreshingly, had excellent adhesion and fit, and was also confirmed to be a water-in-oil cream with excellent stability.

[0119] Example 6: Water-in-oil cream (Component) (%) 1. Manufacturing Example 2 2.0 2. Dimethylpolysiloxane(※) 10.0 3. Cross-linked polyether modified silicone (※) 5.0 4. Dipropylene glycol 10.0 5. Sodium citrate 0.2 6. Ethanol 5.0 7. Preservatives (appropriate amount) 8.Fragrance (appropriate amount) 9. Remaining purified water Total 100.0 (※) Dimethylpolysiloxane: KF-96A-6cs (manufactured by Shin-Etsu Chemical Co., Ltd.) (※) Cross-linked polyether modified silicone: KSG-21 (Shin-Etsu Chemical Co., Ltd.) A) Components 1 to 3 were mixed. B) Components 4 to 9 were mixed, added to the above A) and emulsified with stirring.

[0120] The water-in-oil cream thus obtained was not oily or sticky, spread lightly and refreshingly, had excellent adhesion and fit, and was also confirmed to be a water-in-oil cream with excellent stability.

[0121] Example 7: Foundation (Component) (%) 1. Ceresin 5.5 2. Microcrystalline wax 1.0 3. Liquid Paraffin 4.0 4. Propylene glycol dicaprylate 3.0 5. Alkyl-polyether co-modified silicone (※) 1.0 6. Alkyl-modified cross-linked polyether-modified silicone (※) 7.0 7. Dimethylpolysiloxane(※) 15.0 8. Manufacturing Example 1 1.5 9. Pigment (appropriate amount) 10. Oil-treated titanium dioxide 10.0 11. Lecithin 0.3 12. Polyoxyethylene sorbitan monooleate 0.5 13. 1,3-Butylene glycol 8.0 14. Preservatives (appropriate amount) 15.Fragrance (appropriate amount) 16. Remaining purified water Total 100.0 (※) Alkyl-polyether co-modified silicone: KF-6026 (Shin-Etsu Chemical Co., Ltd.) (※) Alkyl-modified cross-linked polyether-modified silicone: KSG-33 (Shin-Etsu Chemical Co., Ltd.) (※) Dimethylpolysiloxane: KF-96-6cs (manufactured by Shin-Etsu Chemical Co., Ltd.) A) Components 1 to 8 were heated and dissolved. B) Components 9 to 12 and 14 were added to Component 13 and uniformly mixed. C) Component 16 was added to the above B) and uniformly dispersed. D) The above C) and Component 15 were added to the above A), stirred, emulsified, and filled to obtain a product.

[0122] The foundation thus obtained was confirmed to be a foundation that, despite containing a large amount of oil, has no greasiness or stickiness, has a light spreading property, excellent adhesion, good hold, and excellent makeup retention.

[0123] From the above results, it was shown that the gelling agent of the present invention gives a gel composition excellent in both appearance uniformity and stability over time. Further, it was shown that a cosmetic containing the gelling agent of the present invention has excellent adhesion and good hold.

[0124] This specification includes the following aspects. [1]: A gelling agent, wherein the gelling agent is composed of a water-swellable clay mineral in which an ammonium group-modified organopolysiloxane represented by the following average composition formula (1) is incorporated between layers.

Chem.

Chem.

[10] : A method for producing a gelling agent according to the above [8] or [9], wherein the ammonium group-modified organopolysiloxane is represented by the following formula (4): [ka] (In formula (4), R 1 , R 2 and n is the same as above, and x is 0≦x≦100.

[11] : A method for producing a gelling agent according to [8], [9] or

[10] above, in which the water-swellable clay mineral is one or more water-swellable clay minerals selected from montmorillonite, saponite, smectite, hectorite, sodium silicic mica, sodium taeniolite or lithium taeniolite.

[0125] The present invention is not limited to the above-described embodiment. The above-described embodiment is merely an example, and anything that has substantially the same configuration as the technical idea described in the claims of the present invention and exhibits similar effects is included in the technical scope of the present invention.

Claims

1. A gelling agent, comprising a water-swellable clay mineral having an ammonium group-modified organopolysiloxane represented by the following average composition formula (1) incorporated between layers: 【Chemistry 1】 (In formula (1), R １ are independently a group selected from an alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms, R ２ is an ammonium group represented by the following formula (2): a1 is 0<a1≦20, a2 is 0<a2≦12, b is 0≦b≦150, c is 0≦c≦10, and d is 0≦d≦5. However, a1+a2+b+c+d is 2 to 170. n is an integer from 1 to 3. 【Chemistry 2】 (In formula (2), R ３ are independently a hydrogen atom or a group selected from an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms; Y is any one of groups represented by the following formula (3): A － is the anion that serves as the counterion for the ammonium ion.) 【Chemistry 3】 (p is an integer in the range of 1≦p≦10, p1 is an integer in the range of 1≦p1≦10, and p2 is an integer in the range of 1≦p2≦10, provided that 1≦p1+p2≦15. p3 is an integer in the range of 1≦p3≦10. p4 is an integer in the range of 1≦p4≦12. p5 is an integer in the range of 1≦p5≦10. R ４ is a hydrogen atom or a group selected from an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms.

2. A in the formula (2) － 2. The gelling agent according to claim 1, wherein the anion represented by the formula (I) is selected from the group consisting of hydroxide ion, chloride ion, bromide ion, nitrate ion, hydrogen sulfate ion, hydrogen carbonate ion and acetate ion.

3. 2. The gelling agent according to claim 1, wherein the ammonium group-modified organopolysiloxane is represented by the following formula (4): 【Chemistry 4】 (In formula (4), R １ , R ２ , and n are the same as above, and x is 0≦x≦100.

4. The gelling agent according to claim 1, characterized in that the water-swellable clay mineral is one or more water-swellable clay minerals selected from montmorillonite, saponite, smectite, hectorite, sodium silicic mica, sodium taeniolite and lithium taeniolite.

5. A cosmetic preparation, comprising the gelling agent according to any one of claims 1 to 4.

6. 6. The cosmetic according to claim 5, further comprising an oil that is liquid at 25°C.

7. The cosmetic preparation according to claim 6 , wherein the oil contains silicone oil.

8. A method for producing a gelling agent, comprising the steps of: A method for producing a gelling agent, comprising the step of treating a water-swellable clay mineral with an ammonium group-modified organopolysiloxane represented by the following average composition formula (1): 【Chemistry 5】 (In formula (1), R １ are independently a group selected from an alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms, R ２ is an ammonium group represented by the following formula (2): a1 is 0<a1≦20, a2 is 0<a2≦12, b is 0≦b≦150, c is 0≦c≦10, and d is 0≦d≦5. However, a1+a2+b+c+d is 2 to 170. n is an integer from 1 to 3. 【Chemistry 6】 (In formula (2), R ３ are independently a hydrogen atom or a group selected from an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms; Y is any one of groups represented by the following formula (3): A － is the anion that serves as the counterion for the ammonium ion.) 【Chemistry 7】 (p is an integer in the range of 1≦p≦10, p1 is an integer in the range of 1≦p1≦10, and p2 is an integer in the range of 1≦p2≦10, provided that 1≦p1+p2≦15. p3 is an integer in the range of 1≦p3≦10. p4 is an integer in the range of 1≦p4≦12. p5 is an integer in the range of 1≦p5≦10. R ４ is a hydrogen atom or a group selected from an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an arylene group having 7 to 10 carbon atoms.

9. A in the formula (2) － is an anion selected from the group consisting of hydroxide ion, chloride ion, bromide ion, nitrate ion, hydrogen sulfate ion, hydrogen carbonate ion and acetate ion.

10. 9. The method for producing a gelling agent according to claim 8, wherein the ammonium group-modified organopolysiloxane is represented by the following formula (4): 【Chemistry 8】 (In formula (4), R １ , R ２ , and n are the same as above, and x is 0≦x≦100.

11. A method for producing a gelling agent described in any one of claims 8 to 10, characterized in that the water-swellable clay mineral is one or more water-swellable clay minerals selected from montmorillonite, saponite, smectite, hectorite, sodium silicic mica, sodium taeniolite and lithium taeniolite.

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