Laminate
The laminate structure, featuring resin layers with glass fiber or carbon fiber, addresses the lack of a high-class touch feel in thermal transfer image receiving sheets by enhancing stiffness and preventing curl, thus improving the overall performance and feel of the laminate.
Patent Information
- Application Number
- JP2019058543
- Authority / Receiving Office
- JP · JP
- Patent Type
- Patents
- Current Assignee / Owner
- Filing Date
- 2019-03-26
- Publication Date
- 2025-06-30
- Estimated Expiration
- 2039-03-26
AI Technical Summary
Existing thermal transfer image receiving sheets lack a high-class feel in terms of touch, which is desired for premium applications.
A laminate structure comprising a first resin layer, a base material, and a second resin layer, where both resin layers contain a resin composition with glass fiber, talc, or carbon fiber, and the ratio of the flexural modulus products of the two resin layers is 1.5 or less, thereby preventing curl and enhancing stiffness.
The laminate imparts a high-class feel to the touch of the thermal transfer image receiving sheet while effectively preventing curl, thereby improving the strength and conveyance suitability of the laminate.
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Abstract
Description
Technical Field
[0001] The present invention relates to a laminate.
Background Art
[0002] Conventionally, various printing methods have been known. Among them, the sublimation thermal transfer method can freely adjust density gradation, is excellent in the reproducibility of intermediate colors and gradations, and enables high-quality image formation comparable to silver halide photography.
[0003] This sublimation thermal transfer method involves laminating a thermal transfer sheet having a dye layer containing a sublimable dye and a thermal transfer image receiving sheet having a base material and a receiving layer, and then heating the thermal transfer sheet with a thermal head provided in a thermal transfer printer to transfer the sublimable dye in the dye layer to the receiving layer provided in the thermal transfer image receiving sheet, thereby forming an image and obtaining a printed matter.
[0004] In recent years, printed matters obtained in this way are required to have various performances according to their uses and the like. For example, they are made to have a high-class feeling in terms of touch.
Summary of the Invention
Problems to be Solved by the Invention
[0005] Therefore, the problem to be solved by the present invention is to provide a laminate that can impart a high-class feeling to the touch of a thermal transfer image receiving sheet.
Means for Solving the Problems
[0006] The laminate of the present invention includes a first resin layer, a base material, and a second resin layer, the first resin layer and the second resin layer include a resin composition containing at least a resin material, and at least one of the resin compositions contained in the first resin layer and the second resin layer further includes at least one of glass fiber, talc, and carbon fiber.
[0007] In one embodiment, the ratio (B / A) of the product (A) of the flexural modulus of the resin composition contained in the first resin layer and the weight of the first resin layer to the product (B) of the flexural modulus of the resin composition contained in the second resin layer and the weight of the second resin layer is 1.5 or less.
[0008] In one embodiment, the resin compositions contained in the first resin layer and the second resin layer contain at least one of glass fiber, talc, and carbon fiber.
[0009] In one embodiment, the resin compositions contained in the first resin layer and the second resin layer contain glass fiber.
[0010] In one embodiment, the stiffness of the laminate of the present invention is 500 mg or more and 2000 mg or less.
[0011] In one embodiment, the flexural modulus of the resin composition contained in the first resin layer is 1800 MPa or more and 9000 MPa or less.
[0012] In one embodiment, the flexural modulus of the resin composition contained in the second resin layer is 1800 MPa or more and 9000 MPa or less.
Advantages of the Invention
[0013] According to the laminate of the present invention, a high-class feeling can be imparted to the touch feeling of the thermal transfer image receiving sheet.
Brief Description of the Drawings
[0014]
Figure 1
Figure 2
Embodiments for Carrying Out the Invention
[0015] (Laminate) As shown in FIG. 1, the laminate 10 of the present invention includes a first resin layer 11, a base material 12, and a second resin layer 13 in this order. In one embodiment, as shown in FIG. 2, the laminate 10 includes a receiving layer 14 on the first resin layer 11. Also, in one embodiment, as shown in FIG. 2, the laminate 10 includes a porous layer 15 between the first resin layer 11 and the receiving layer 14. In the present invention, "comprising in this order" includes the case where a primer layer is provided between any layers, for example, between the first resin layer and the receiving layer.
[0016] In the laminate of the present invention, the ratio (B / A) of the product (A) of the flexural modulus of the resin composition contained in the first resin layer and the weight of the first resin layer to the product (B) of the flexural modulus of the resin composition contained in the second resin layer and the weight of the second resin layer is preferably 1.5 or less. Thereby, generation of curl generated in the laminate can be prevented during storage. In particular, a laminate having a paper substrate as a substrate is easily affected by the surrounding environment, and particularly, curl is significantly generated when it is left standing in a high-humidity environment. By setting B / A within the above numerical range, generation of this curl can be effectively prevented. B / A is preferably 0.8 or more and 1.4 or less, and more preferably 1.0 or more and 1.3 or less. The measurement of the flexural modulus is performed in accordance with JIS K 7171 (ISO 178).
[0017] In the present invention, the weights of the first resin layer and the second resin layer can be measured, for example, after impregnating the laminate in a sodium hydroxide solution and peeling each layer.
[0018] The stiffness of the laminate of the present invention is preferably 500 mg or more and 2000 mg or less, and more preferably 700 mg or more and 2000 mg or less. Thereby, the strength of the laminate and the conveyance suitability in the printer can be improved. Also, the feel of the thermal transfer image receiving sheet can be further improved. In the present invention, the stiffness of the laminate is measured using a Gurley stiffness tester manufactured by Toyo Seiki Co., Ltd. in an environment of a temperature of 25°C and a humidity of 50% in accordance with the method described in JIS L 1085.
[0019] Hereinafter, each layer included in the laminate according to the present invention will be described.
[0020] (First resin layer and second resin layer) The first resin layer and the second resin layer contain a resin composition containing a resin material, and at least one of the resin compositions contained in the first resin layer and the second resin layer further contains at least one of glass fiber, talc, and carbon fiber. Moreover, it is preferable that both of the resin compositions contained in the first resin layer and the second resin layer contain at least one of glass fiber, talc, and carbon fiber. Thereby, a high-class feeling can be imparted by the feel of the laminate. Also, the generation of curl in the above laminate can be more effectively prevented.
[0021] Moreover, the resin composition contained in the first resin layer and the second resin layer preferably has a flexural modulus conforming to JIS K 7171 (ISO 178) of 1800 MPa or more and 9000 MPa or less, and more preferably 2000 MPa or more and 8500 MPa or less. Thereby, a high-class feeling can be imparted by the feel of the laminate. Also, the generation of curl in the above laminate can be more effectively prevented. Furthermore, the conveyance suitability within the printer can be improved.
[0022] The content of the resin composition in the first resin layer and the second resin layer is preferably 60% by mass or more, more preferably 70% by mass or more, and still more preferably 80% by mass or more. Thereby, a high-class feeling can be imparted by the feel of the laminate. Also, the generation of curl in the above laminate can be more effectively prevented. Furthermore, the conveyance suitability within the printer can be improved.
[0023] Examples of the resin material include polyesters such as polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyethylene naphthalate (PEN), 1,4-polycyclohexylene dimethylene terephthalate, and terephthalic acid-cyclohexanedimethanol-ethylene glycol copolymer; polyamides such as nylon 6 and nylon 6,6; polyolefins such as polypropylene (PP), polyethylene (PE), and polymethylpentene; polyvinyl chloride; polyvinyl alcohol (PVA); polyvinyl acetate; vinyl chloride-vinyl acetate copolymer; vinyl resins such as polyvinyl butyral and polyvinyl pyrrolidone (PVP); (meth)acrylic resins such as polyacrylate, polymethacrylate, and polymethyl methacrylate; imide resins such as polyimide and polyetherimide; cellulose resins such as cellophane, cellulose acetate, nitrocellulose, cellulose acetate propionate (CAP), and cellulose acetate butyrate (CAB); styrene resins such as polystyrene (PS); polycarbonate; and ionomer resins. The resin composition may contain two or more resin materials. Among the above, polyolefin is preferable, and PP is particularly preferable from the viewpoints of feel and curl prevention. As described above, a laminate having a paper substrate as a substrate is susceptible to the influence of the surrounding environment. By incorporating polyolefin into the first resin layer and the second resin layer, the occurrence of this curl can be effectively prevented. In the present invention, “(meth)acrylate” means including both “acrylate” and “methacrylate”.
[0024] The content of the resin material in the resin composition is preferably 50% by mass or more and 95% by mass or less, and more preferably 55% by mass or more and 90% by mass or less. Thereby, a high-class feeling can be imparted by the feel of the laminate.
[0025] The resin composition contains, as inorganic particles, at least one of glass fiber, talc, and carbon fiber. Among these, carbon fiber is preferable from the viewpoint of the rigidity and softness of the laminate.
[0026] The content of glass fiber, talc, and carbon fiber in the resin composition is preferably 5% by mass or more and 50% by mass or less, and more preferably 10% by mass or more and 45% by mass or less. Thereby, a high-class feeling can be imparted by the feel of the laminate, and the rigidity and softness of the laminate can be improved.
[0027] The first resin layer and the second resin layer can contain inorganic particles other than glass fiber, talc, and carbon fiber within a range not impairing the characteristics of the present invention. Examples of the inorganic particles include titanium oxide, zinc oxide, magnesium carbonate, calcium carbonate, stilbene-based compounds, benzimidazole-based compounds, benzoxazole-based compounds, hindered amine-based compounds, hindered phenol-based compounds, benzotriazole-based compounds, benzophenone-based compounds, and resin particles such as (meth)acrylic resin particles and polyaniline resin particles.
[0028] The first resin layer and the second resin layer can contain additives such as release agents, plasticizers, ultraviolet stabilizers, anti-coloring agents, surfactant materials, fluorescent brightening agents, matting agents, deodorizing agents, flame retardants, weather-resistant materials, antistatic agents, yarn friction reducing materials, slip materials, antioxidants, ion exchange materials, dispersants, ultraviolet absorbers, and coloring materials such as pigments and dyes within a range not impairing the characteristics of the present invention.
[0029] Also, the weight of the first resin layer is preferably 5 g / m 2 or more and 100 g / m 2 or less, and more preferably 10 g / m 2 or more and 40 g / m 2 or less. Thereby, a high-class feeling can be imparted by the feel of the laminate. Also, the generation of curl in the laminate can be more effectively prevented. Also, the weight of the second resin layer is 5 g / m 2Preferably, it is 100 g / m or less, more preferably 20 g / m or more and 50 g / m or less. This can impart a more luxurious feel to the touch of the laminate. Also, the generation of curl in the laminate can be more effectively prevented. 2 Preferably, it is 100 g / m or less, more preferably 20 g / m or more and 50 g / m or less. This can impart a more luxurious feel to the touch of the laminate. Also, the generation of curl in the laminate can be more effectively prevented. 2 Preferably, it is 100 g / m or less, more preferably 20 g / m or more and 50 g / m or less. This can impart a more luxurious feel to the touch of the laminate. Also, the generation of curl in the laminate can be more effectively prevented. 2 Preferably, it is 100 g / m or less, more preferably 20 g / m or more and 50 g / m or less. This can impart a more luxurious feel to the touch of the laminate. Also, the generation of curl in the laminate can be more effectively prevented.
[0030] In one embodiment, the first resin layer and the second resin layer are extrusion resin layers, and can be formed by melt-extruding a mixture containing the above material onto a substrate or the like. Also, in another embodiment, the first resin layer and the second resin layer are formed by dispersing or dissolving the above material in water or a suitable solvent to obtain a coating solution, and applying this coating solution onto a paper substrate by known means such as a roll coating method, a reverse roll coating method, a gravure coating method, a reverse gravure coating method, a bar coating method, and a rod coating method to form a coating film, and then drying the coating film.
[0031] (Substrate) The substrate is required to have heat resistance capable of withstanding the thermal energy applied during thermal transfer (for example, heat from a thermal head) and mechanical strength capable of supporting a receiving layer or the like provided on the substrate. As such a substrate, for example, paper substrates such as high-quality paper, art paper, coated paper, resin-coated paper, cast-coated paper, cardboard, synthetic paper, and impregnated paper, and films made of resin materials such as polyester, polyamide, polyolefin, vinyl resin, and (meth)acrylic resin (hereinafter simply referred to as "resin film") can be used. Among the above, coated paper is preferred from the viewpoints of stiffness and prevention of uneven printing. In the present invention, coated paper refers to paper for information such as medium-quality paper with a coating material of 10 μm or more and 30 μm or less applied to at least one surface. Also, in the present invention, "(meth)acrylic" includes both "acrylic" and "methacrylic".
[0032] In addition, a laminate composed of only the above-mentioned paper base material, a laminate composed of only a resin film, or a laminate of a paper base material and a resin film can be used as a base material. These laminates can be produced by utilizing methods such as the dry lamination method, the wet lamination method, and the extrusion method.
[0033] The thickness of the base material is preferably 80 μm or more and 200 μm or less, and more preferably 95 μm or more and 150 μm or less. Thereby, the generation of curl in the above laminate can be more effectively prevented.
[0034] (Receiving layer) The receiving layer is a layer that receives sublimable dyes transferred from the dye layer provided on the thermal transfer sheet and maintains the formed image, and contains at least one resin material. Examples of the resin material include polyester, polyamide, polyolefin, vinyl resin, (meth)acrylic resin, imide resin, cellulose resin, styrene resin, polycarbonate, and ionomer resin. Among these, vinyl resin is preferred for reasons such as improving image density and print durability.
[0035] The content of the above resin material in the receiving layer is not particularly limited, and can be, for example, 80% by mass or more and 98% by mass or less.
[0036] In one embodiment, the receiving layer contains one or more release agents. Thereby, the releasability from the thermal transfer sheet after image formation can be improved. Examples of the release agent include solid waxes such as polyethylene wax and amide wax, fluorine-based surfactants, phosphate ester-based surfactants, silicone oil, reactive silicone oil, curable silicone oil, and silicone resin.
[0037] The content of the release agent in the receiving layer is preferably 0.5% by mass or more and 20% by mass or less, and more preferably 0.5% by mass or more and 10% by mass or less. Thereby, the releasability from the thermal transfer sheet after image formation can be further improved.
[0038] Further, the receiving layer can contain the above additives as long as the characteristics of the present invention are not impaired.
[0039] The thickness of the receiving layer is preferably 0.5 μm or more and 20 μm or less, more preferably 1 μm or more and 10 μm or less. Thereby, the generation of curl in the above laminate can be more effectively prevented. Further, the density of the image formed on the receiving layer can be further improved.
[0040] The receiving layer is formed by dispersing or dissolving the above material in water or an appropriate solvent to obtain a coating solution, and applying this coating solution onto the first resin layer or the like by known means such as roll coating method, reverse roll coating method, gravure coating method, reverse gravure coating method, bar coating method, and rod coating method to form a coating film, and then drying the coating film.
[0041] (porous layer) In one embodiment, the laminate of the present invention includes a porous layer between the base material and the receiving layer, whereby the image density formed on the receiving layer can be improved. As the porous layer, for example, a porous resin film having fine voids inside can be used.
[0042] The porous layer contains at least one resin material, and examples thereof include polyester, polyamide, polyolefin, vinyl resin, (meth)acrylic resin, imide resin, cellulose resin, styrene resin, polycarbonate, and ionomer resin.
[0043] The porous layer can contain the above additives as long as the characteristics of the present invention are not impaired.
[0044] The thickness of the porous layer is preferably 20 μm or more and 100 μm or less, more preferably 30 μm or more and 80 μm or less. Thereby, the image density formed on the receiving layer can be further improved. Further, the generation of the above curl in the laminate can be more effectively prevented.
[0045] The porous resin film using the above-described resin material or the like can be produced by a known method. For example, it can be produced by forming a film from a mixture in which incompatible organic particles or inorganic particles are kneaded with the above-described resin material. Further, in one embodiment, the porous resin film can be produced by forming a film from a mixture containing a first resin material and a second resin material having a melting point higher than that of the first resin material. In this case, the second resin material functions as a nucleating agent for forming fine voids. The mixing amount of the second resin material is preferably 2 parts by mass or more and 10 parts by mass or less with respect to 100 parts by mass of the first resin material. For example, a porous resin film can be produced by forming a film from a mixture containing polypropylene as the first resin material and an acrylic resin as the second resin material. Further, the film may be a uniaxially stretched film or a biaxially stretched film. Also, a commercially available porous film may be used.
[0046] (Primer layer) In one embodiment, the laminate of the present invention includes a primer layer between any layers. Thereby, the adhesion between layers can be improved.
[0047] The primer layer contains at least one resin material, and examples thereof include polyester, polyamide, polyolefin, vinyl resin, (meth)acrylic resin, imide resin, cellulose resin, styrene resin, polycarbonate, and ionomer resin.
[0048] In one embodiment, the primer layer contains a layered silicate. Thereby, conductivity can be imparted to the primer layer, and the spreading property of the printed matter can be improved.
[0049] Also, within a range that does not impair the characteristics of the present invention, the primer layer can contain the above-described additives.
[0050] The thickness of the primer layer is not particularly limited and can be, for example, 0.05 μm or more and 5 μm or less.
[0051] The primer layer can be formed by dispersing or dissolving the above material in water or an appropriate solvent to obtain a coating solution, and applying this coating solution onto a substrate or the like by known means such as a roll coating method, a reverse roll coating method, a gravure coating method, a reverse gravure coating method, a bar coating method, and a rod coating method to form a coating film, and then drying the coating film.
Examples
[0052] Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. Hereinafter, descriptions of contents, ratios, etc. are based on mass unless otherwise specified.
[0053] Example 1 As a substrate, coated paper A with a thickness of 130 μm (manufactured by Daio Paper Corporation, S Yutori Coat 157) was prepared.
[0054] On one surface of the substrate, as a resin composition, polypropylene composite resin A (manufactured by Daicel Polymer Ltd., containing 10% by mass of glass fiber (GF), flexural modulus 2700 MPa) was melt-extruded to form a first resin layer with a weight of 20 g / m 2 At the same time, a porous polypropylene film with a thickness of 35 μm was laminated to form a porous layer.
[0055] On the other surface of the substrate, polypropylene composite resin A was melt-extruded to form a second resin layer with a weight of 25 g / m 2 of the second resin layer. The ratio (B / A) of the product (A) of the flexural modulus of the resin composition contained in the first resin layer and the weight of the first resin layer to the product (B) of the flexural modulus of the resin composition contained in the second resin layer and the weight of the second resin layer was 1.3.
[0056] On the porous layer formed as described above, a coating liquid for forming a primer layer having the following composition was applied and dried to form a primer layer with a thickness of 1 μm. <Coating Liquid for Forming Primer Layer> · 5 parts by mass of polyurethane (Manufactured by Nippon Polyurethane Industry Co., Ltd., N-5199) · 10 parts by mass of anatase titanium oxide (Manufactured by Sakai Chemical Industry Co., Ltd., TCA-888) · 2 parts by mass of isocyanate compound (Manufactured by Mitsui Chemicals, Inc., Takenate (registered trademark) A-14) · 8 parts by mass of toluene · 8 parts by mass of methyl ethyl ketone (MEK) · 4 parts by mass of isopropanol (IPA)
[0057] On the primer layer formed as described above, a coating liquid for forming a receiving layer having the following composition was applied and dried to form a receiving layer with a thickness of 2.5 μm. <Composition of Coating Liquid for Forming Receiving Layer> · 60 parts by mass of vinyl chloride-vinyl acetate copolymer (Manufactured by Nisshin Chemical Industry Co., Ltd., Solbine (registered trademark) C) · 1.2 parts by mass of epoxy-modified silicone (Manufactured by Shin-Etsu Chemical Co., Ltd., X-22-3000T) · 0.6 parts by mass of methylstyrene-modified silicone (Manufactured by Shin-Etsu Chemical Co., Ltd., X-24-510) · 2.5 parts by mass of MEK · 2.5 parts by mass of toluene
[0058] Examples 2 to 7, 9 to 13, Reference Example 8 and Comparative Examples 1 to 2 A laminate was produced in the same manner as in Example 1, except that the thickness of the base material, the composition and weight of the first resin layer, the composition and weight of the second resin layer, and the presence or absence of the porous layer were changed as shown in Table 1. The details of each component in Table 1 are as follows. · Coated paper B: Manufactured by Daio Paper Corporation, S Yutoriro Coat 127, thickness: 105 μm · Low-density polyethylene (LDPE): manufactured by Japan Polyethylene Corporation, NOVATECH (registered trademark) LD LC600A, density 0.918 g / cm 3 · High-density polyethylene (HDPE): manufactured by Japan Polyethylene Corporation, NOVATECH (registered trademark) HD HS471, density 0.956 g / cm 3 · Polypropylene composite resin B (manufactured by Daicel Polymer Ltd., containing 20 mass% of Daicel PP PG4N1 GF, flexural modulus 4200 MPa) · Polypropylene composite resin C (manufactured by Daicel Polymer Ltd., containing 30 mass% of Daicel PP PG6N1 GF, flexural modulus 6000 MPa) · Polypropylene composite resin D (manufactured by Daicel Polymer Ltd., containing 40 mass% of Daicel PP PG8N1 GF, flexural modulus 8500 MPa) · Polypropylene composite resin E (manufactured by Daicel Polymer Ltd., containing 40 mass% of talc in Daicel PP PT8N1, flexural modulus 4000 MPa) · Polypropylene composite resin F (manufactured by Daicel Polymer Ltd., containing 40 mass% of carbon fiber (CF) in Plastron (registered trademark) PP-CF40-11, flexural modulus 20000 MPa)
[0059] <<Evaluation of touch feeling>> Regarding the touch feeling of the laminates produced in the examples and comparative examples, a sensory evaluation was conducted by 10 monitor tests. (Evaluation criteria) A: Nine or more monitors answered that they "felt a sense of luxury". B: Five or more but less than nine monitors answered that they "felt a sense of luxury". C: Three or more but less than five monitors answered that they "felt a sense of luxury". NG: Less than three monitors answered that they "felt a sense of luxury".
[0060] <<Evaluation of curl difference>> The laminates produced in the examples and comparative examples were cut into test pieces with a width of 152 mm, The test piece was wound up so that the receiving layer provided on the test piece was on the outside, and a roll-shaped test piece with an outer diameter of 60 mm with the leading end of the unwinding taped was used. The roll-shaped test piece was left standing in an environment of 40°C and a relative humidity of 90% (high humidity environment) for 2 weeks. The tape portion was provided over the entire width direction of the test piece. After standing, the roll-shaped test piece was unwound, 30 mm was cut from the leading end of the unwinding, and the test piece was cut so that the length from the cut end was 203 mm. The test piece having a width of 152 mm and a length of 203 mm obtained in this way was placed on a flat table, and the lifting height at the four corner points was measured. Specifically, in the case of curl where the receiving layer side was concave, it was placed on a flat table with the receiving layer side facing up, and in the case of curl where the receiving layer side was convex, it was placed on a flat table with the receiving layer side facing down for measurement. The maximum lifting height at the four corner points was defined as the curl amount (curl amount in the low humidity environment). The measurement results were summarized in Table 1. Also, the standing environment was changed to 50°C and a relative humidity of 13% (low humidity environment), and the curl amount (curl amount in the high humidity environment) was measured in the same manner as above, and the measurement results were summarized in Table 1. The difference between the curl amount in the low humidity environment and the curl amount in the high humidity environment obtained as described above (curl amount in the high humidity environment - curl amount in the low humidity environment) was determined, evaluated based on the following evaluation criteria, and summarized in Table 1. (Evaluation Criteria) A: The absolute value of the curl difference was less than 15 mm. B: The absolute value of the curl difference was 15 mm or more.
[0061] <<Measurement of Rigidity and Softness>> The rigidity and softness of the laminated bodies produced in the examples and comparative examples were measured using a Gurley stiffness tester manufactured by Toyo Seiki Co., Ltd. in an environment of a temperature of 25°C and a humidity of 50% in accordance with the method described in JIS L 1085. The measurement results were summarized in Table 1.
[0062]
Table 1
Explanation of Symbols
[0063] 10: Laminate, 11: First resin layer, 12: Substrate, 13: Second resin layer, 14: Receiving layer, 15: Porous layer
Claims
1. A laminate for a thermal transfer image receiving sheet, comprising a first resin layer, a substrate, and a second resin layer, wherein the first resin layer and the second resin layer contain a resin composition containing at least a resin material, and at least one of the resin compositions contained in the first resin layer and the second resin layer further contains at least one of glass fiber and carbon fiber, and the stiffness and flexibility measured using a Gurley stiffness tester in an environment of a temperature of 25°C and a humidity of 50% in accordance with the method described in JIS L 1085 is 500 mg or more and 2000 mg or less.
2. The laminate for a thermal transfer image receiving sheet according to claim 1, further comprising a receiving layer on the first resin layer.
3. The laminate for a thermal transfer image receiving sheet according to claim 2, wherein a ratio (B / A) of a product (A) of a flexural modulus of the resin composition contained in the first resin layer and the weight of the first resin layer and a product (B) of a flexural modulus of the resin composition contained in the second resin layer and the weight of the second resin layer is 1.5 or less.
4. The laminate for a thermal transfer image receiving sheet according to any one of claims 1 to 3, wherein the resin composition contained in the first resin layer and the second resin layer contains at least one of glass fiber and carbon fiber.
5. The laminate for a thermal transfer image receiving sheet according to any one of claims 1 to 4, wherein the resin composition contained in the first resin layer and the second resin layer contains glass fiber.
6. The laminate for a thermal transfer image receiving sheet according to any one of claims 1 to 5, wherein the flexural modulus of the resin composition contained in the first resin layer is 1800 MPa or more and 9000 MPa or less.
7. The laminate for a thermal transfer image receiving sheet according to any one of claims 1 to 6, wherein the flexural modulus of the resin composition contained in the second resin layer is 1800 MPa or more and 9000 MPa.
8. A thermal transfer image receiving sheet comprising the laminate for a thermal transfer image receiving sheet according to any one of claims 1 to 7.
Citation Information
Patent Citations
Thermally dye transferred image receiving sheet
JP1991183591A
High strength composite paper
JP1996034095A