Sesame oil mixture

Abstract

It allows identifying active agents that can change the keynote of a perfume composition in very small amounts. [Solution] (a) Carbomentone, (b) at least one fragrance different from compound (a), and (c) proposes a perfume oil mixture consisting of, or consisting only of, optionally at least one cosmetically acceptable carrier.

Description

Technical Field

[0001] The present invention relates to the field of perfumes with improved olfactory profiles, compositions containing the same, and methods for modifying the olfactory notes of fragrances.

Background Art

[0002] Fragrances not only are used directly as fragrances but also have very important economic value for the cosmetics industry or the detergent industry. Despite the trend towards fragrance-free products, many consumers want to transfer a pleasant scent to their skin or fabric products such as shampoos and fabric softeners. For example, the citrus scent contained in detergents usually evokes a sense of freshness and cleanliness.

[0003] Today, the types of fragrance scents handled by perfumers are almost infinite. Nevertheless, fragrances are constantly being newly created and usually composed of 20, 50, or more than 100 ingredients. Still, there is a high interest in new fragrances, and even those without particularly remarkable olfactory effects may have expected effects. In the market, chemical compounds that can enhance or change the scent of other fragrances or fragrance mixtures even in small amounts have attracted particular attention. Such substances are of particular interest because they can potentially change the characteristics of existing perfumes simply and efficiently without changing their composition as much as possible.

[0004] Patent Document 1 relates to a fragrance-enhancing composition that can significantly suppress body odor and thereby reduce the total amount of fragrance necessary to achieve a satisfactory cosmetic, particularly a product for underarms. This fragrance-enhancing composition is made by combining at least three components from a selected group of non-nitromusk materials. Among many other fragrances, isopropyl methylcyclohexanone is cited.

[0005] Patent Document 2 discloses a process for producing carvone by thermally isomerizing limonene-1,2-epoxide in the presence of synthetic zeolite under reduced pressure.

Prior Art Documents

Patent Document

[0006]

Patent Document 1

Patent Document 2

Summary of the Invention

Problems to be Solved by the Invention

[0007] Therefore, an object of the present invention is to provide an essential oil, which is a specific enhanced or boosted note, particularly a musk note, a marine note, a geranium note, a green note, with an overall freshness, with a dry orris effect, and in particular, an essential oil which is an essential oil concentrate having an essential oil content of at least 80% by weight. More specifically, it has been a problem to identify an activator that can vary the key notes of the fragrance composition as described above in a very small amount.

Means for Solving the Problems

[0008] A first object of the present invention relates to an essential oil mixture consisting of, or consisting only of, the following: (a) Carvone (b) At least one fragrance different from compound (a), and optionally (c) At least one cosmetically acceptable carrier.

[0009] Surprisingly, carvone matches the above complex profile, and it has been observed that adding even a very small amount of this compound can change the olfactory impression of many fragrances, fragrance mixtures, and essential oils.

[0010] In particular, carvone · Enhances the overall musk scent. · Introduces a unique marine scent, especially to woody and amber materials. · It imparts a very natural geranium effect to rose-based materials in particular. · It imparts a dry orris effect to violet scents in particular. · In the case of aldehydes, it enhances freshness in particular. · It enhances the impact of green notes.

[0011] Carvomenthone refers to the stereoisomers (structures I - XIII) of 2 - methyl - 5 - (1 - methylethyl) - cyclohexanone and its derivatives, and can be exemplified as follows.

Table 1

Table 2

Table 3

[0012] In the context of the present invention, it is emphasized that the term "carvomenthone" covers each of its various stereoisomers including its racemic mixture.

[0013] Carvomenthone is contained in, for example, cornmint and can be separated from the oil of, for example, Tanacetum vulgare

[0014] Secondary fragrance The fragrance different from carvomenthone that forms component (b) (the "secondary fragrance") is preferably selected from fragrances that provide musk, woody, amber, rose, violet and / or green notes.

[0015] More specifically, the fragrance that forms component (b) is selected from the group consisting of the following.

Table 4

Table 5

Table 6

Table 7

Table 8

Table 9

Table 10

Table 11

Table 12

Table 13

Table 14

[0016] For the sake of clarity, it is necessary to emphasize that carvomentone exhibits at least one of the favorable effects as described above with each of the flavor molecules summarized in the above table. In other words, each binary combination of carvomentone with one of the scents cited above is disclosed, represents a preferred embodiment, and can form a basis for selection.

[0017] Preferred secondary fragrance The following secondary fragrance that forms component (b) is particularly preferred because adding a small amount of carvone imparts a remarkable boosting effect on its overall musk note. Globanone-cyclohexadecenone-8 Globaride-Habanolide Macrolide-cyclopentadecanolide-Exaltolide-Pentalide Galaxolide- Tonalid- Helvetolide- Ethylene Brassylate-Musk T Romandolide- Ambratolide- Dihydroambratolide- Aureolione- Exaltenone- Isomuscone- Muscone- Muscenone- Vervione- Civetone- Ambrette Seed Oil- Musk Ketone

[0018] In particular, the following auxiliary fragrances that form component (b) are preferred because adding a small amount of carvone can introduce a unique marine note to the woody note and amber note. · Amber Ketal-Ambral-Ketamber · Amber Core · Ambroxan · Ambrocenide · Ambroxide-Ambroxane · Cetalox · Ambrox DL · Hydroxyambran · Isamber K · Dihydroionone β · Dynamone · Aldolone · Amber Wood F-Boisambrene Fort · Andran-Cedrene Epoxide · Cashmeran · Cedramber · α-Cedrene · β-Cedrene · Cedrol · Cedroxide · Cedryl acetate · Iso E Super · Kephalis · Madranol · Madrox · Oxooctalinic acid salt · Parisandal · Parisandin · Timberol · Trimofix O · Amyris oil - West Indian sandalwood oil · Bornefix · Boronal · Caryophyllene · Caryophyllene acetate · Sandalwood oil - Virginia · Sandalwood oil - Chinese · Sandalwood oil - Atlas · Copaiba balsam · Cypriol oil · Ebanol · Guaiacwood oil · Guaiyl acetate · Gurjun balsam · Gurjun balsam oil · Alpha ionone · Beta ionone · Isobornyl cyclohexanol · Isocamphyl cyclohexanol · Isopentyl cyclohexanol · Isolongifolanone · Isolongifolene · Corebon · Okoumal · Orinox · Oshiol · Patchouli oil · Patchouli terpene · Polysaccharide · Sandalwood · Sandal Mysore core · Sandranol - Bacdanol · Sandalwood oil Australia · Sandalwood oil East India · Teranol - Isolongifolanol · Vertofix - Acetyl cedrene - Methyl cedryl ketone · Veticol acetate · Vetivertal · Veticon · Vetiver oil Bourbon · Vetiver oil Haiti · Vetiver oil Java · Vetiverol · Vetiveryl acetate

[0019] In particular, the following auxiliary fragrances that form component (b) are preferred because adding a trace amount of carvone can obtain a very natural geranium effect, especially in the rose note. · Anser · Phenylate · Phenoxyethyl isobutyrate · Phenylethyl acetate · Phenylethyl butyrate · Phenylethyl isobutyrate · Phenylethyl isovalerate · Phenylethyl methyl ether · Phenylethyl phenylacetate · Phenylethyl propionate · Aldehyde C9 - Nonyl aldehyde · Benzophenone · Citronellol 95 · Laevocitronellol · Citronellyl acetate · Citronellyl butyrate · Citronellyl formate · Citronellyl isobutyrate · Citronellyl propionate · Citronellyl tiglate · Copaesgrandine · Cyclomethylene citronellol · Cyclohexyl magnolol · Damascenone · Damascone α · Damascone β · Damascone δ · Diphenyl oxide · Dupical · Farnesol · Florhydral · Fluoro-sa-fluoro-pyranol · Isodamascone · Ethyl safuranate · Geraniol 60 · Geraniol · Geranyl acetate 60 · Geranyl acetate · Geranyl formate · Geranyl methyl ether · Geranyl propionate · Geranyl tiglate · Dibson · Helional · Hybanal · Hydroxycitronellal · Linalool · Lily flower · Lily bell · Maysul · Majantol · Mayol · Mugetanol · Muget alcohol · Nerol · Neryl acetate · Palmarosa oil · Rhodinol · Loral · Romascone · Rosacetate · Rosaphene · Phenoxanol · Rose oil Bulgaria · Rose oil Turkey · Rose oxide high Cis · Rose oxide L · Rose oxide D · Simrose · Tetrahydrogeraniol · Vernal aldehyde · Vertomgal · Ylang-ylang oil

[0020] In particular, when a trace amount of carvone is added, a remarkable dry iris effect can be obtained, especially in the violet note. Therefore, the following auxiliary fragrances forming component (b) are preferred. · Ceton α · Iraldehyde α · Iraldehyde β · Iraldehyde γ · Isoradine 70 · Isoradine 95 · Orris concrete · Iris nitrile · Iron α · Ionaral · Carrot seed oil · Olibone · Methyl octyninc carbonate · Methyl heptyninc carbonate · Neofolione · Nonadienal trans, cis-2,6 · Nonadienol-2,6 · Parmanyl · Undecabathol · Violet leaves absolute · Violet tine · Bioref · Allyl amyl glycolate · Cortex aldehyde · Dibutyl sulfide · Dynasco · Galbanum resinoid · Galbanum oil · Galbacon · Galdamide · Heptanal diethyl acetal · Herbavel · Hexenal trans-2 · Hexenol β γ cis trans-3 · Hexenol cis-3 · Hexenyl cis trans-3 acetate · Hexenyl cis-3 acetate · Hexenyl cis-3 butyrate · Hexenyl cis-3 caproate · Hexenyl cis trans-3 formate · Hexenyl cis-3 isovalerate · Methylhexenyl cis-3,2 butyrate · Hexenyl cis-3 propionate · Hexenyl cis-3 salicylate · Hexenyl tiglate · Hydratropic aldehyde · Hydratropic aldehyde dimethyl acetal · Isobutyl-3-methoxypyrazine,2 · Isovaleraldehyde · Leaf acetal · Leaf over - leaf aroma · Lentonique absolute · Ligustral · Melozone · Methylphenylhexenal trans-5,2,2 · Neocyclocitral · Nonenol cis-6 · Pharaon · Phenylacetaldehyde · Phenylacetaldehyde dimethyl acetal · Phenylacetaldehyde glycerin acetal · Spirogalbanone · Undecabattle · Vertrinate · Beltprene · Cyclogalvanate · Tiramizone · Herbaflorat - Cyclaset · Herbil - Cycloprop of propionate · Allyl caproate · Allyl heptanoate · Cyclohexyl allyl propionate

[0021] In particular, the following auxiliary fragrances that form component (b) are preferably used because adding a trace amount of carvone can enhance the freshness of the aldehyde complex and the impact of the green note. · Aldehyde C6 · Aldehyde C7 · Aldehyde C8 · Aldehyde C9 · Aldehyde C10 · Undecylic aldehyde · Undecylene aldehyde · Aldehyde C11 iso · Aldehyde C11 MOA · Aldehyde C12 lauric · Aldehyde C12 MNA - methyl nonyl acetaldehyde · Citroxal · Clone · Decenal cis - 4 · Decenal trans - 2 · Decenal trans - 4 · Decenal - 9,1 · Dodecadienal - 2,6 · Dodecanal trans - 2 · Farenal - adoxal · Ger aldehyde · Heptanal diethyl acetal · Heptanal cis - 4 · Intrevenal aldehyde · Isononyl aldehyde · Linalool · Mandarin aldehyde · Nonenal cis-6 · Nonenal trans-2 · Orangier · Profarnesal · Tridecenal trans-2 · Undecenal trans-2 · γ-Nonalactone · Gamma-decalactone · γ-Undecalactone · Alcohol C7 · Alcohol C8 · Alcohol C9 · Alcohol C10 · Alcohol C12 · Alcohol C13 oxo · Burtcin · Hexyl acetate · Agrumecks-Verdox · Orichloron-Vertec · Ethyl acetoacetate · Butyl acetate · Benzyl butyrate · Ethyl acetate · Ethyl methyl butyrate-2 · Isoamyl acetate · Jasmaplneate-Fructone · Manzanate · Prenyl acetate

[0022] Essential oil mixture The sesame oil mixture according to the present invention can contain carvomentone (component a) in an amount of 0.00001 - about 5% by weight. Preferred contents of carvomentone are 0.00005% by weight, 0.0001% by weight, 0.0005% by weight, 0.001% by weight, 0.005% by weight, 0.01% by weight, 0.05% by weight, 0.1% by weight, 0.5% by weight, 1% by weight and 2% by weight. Also, these amounts can be arranged to function as upper or lower limits of a range.

[0023] The sesame oil mixture can be solvent - free or can contain a cosmetically acceptable carrier such as water, ethanol, triethyl citrate or a mixture thereof.

[0024] In another preferred embodiment, the mixture according to the present invention comprises the following. (a) about 0.00001 - about 5% by weight, preferably 0.0001 - about 1% by weight, more preferably 0.001 - 0.01% by weight of carvomentone, (b) about 99.9999 - about 95% by weight of at least one fragrance different from component (a), and (c) 0 - about 4.99999% by weight of at least one Carrier on the condition that all amounts are added so that the total is 100% by weight.

[0025] It is emphasized that mixtures according to the conditions provided above showing less than 100% by weight or more than 100% by weight are not the subject of the present invention and would not be considered by any person skilled in the art for a good fragrance.

[0026] Capsule In another preferred embodiment, the mixture can be encapsulated. Thus, another object of the present invention relates to a capsule comprising the sesame oil mixture.

[0027] For example, the mixture can be encapsulated by a solid coating material. This coating material is preferably selected from starch, starch that has been degraded or chemically or physically modified (in particular dextrin and maltodextrin), gelatin, gum arabic, agar, ghatti gum, gellan gum, modified and unmodified cellulose, pullulan, curdlan, carrageenan, alginic acid, alginates, pectin, inulin, xanthan gum, and mixtures of two or more of the foregoing substances.

[0028] The solid coating material is preferably selected from gelatin (preferably porcine, bovine, chicken and / or fish gelatin and mixtures thereof, preferably at least one gelatin having a Bloom value of 200 or more, preferably at least one gelatin having a Bloom value of 240 or more), maltodextrin (preferably obtained from corn, wheat, tapioca or potato, and a preferred maltodextrin has a DE value of 10-20), modified cellulose (such as cellulose ether), alginates (such as sodium alginate), carrageenan (β-, ι-, λ- and / or κ-carrageenan), gum arabic, curdlan and / or agar. Gelatin is preferably used, especially since it is readily available with different Bloom values. Particularly preferred are seamless gelatin or alginate capsules, especially for oral use, the coating of which dissolves very rapidly in the mouth or ruptures when chewed. Manufacture can be carried out as described, for example, in EP0389700 A1, US4,251,195, US6,214,376, WO2003055587 or WO2004050069A1.

[0029] However, the capsule may represent a microcapsule. A "microcapsule" is understood to be a spherical aggregate having a diameter of about 0.1 - about 5 mm, containing at least one solid or liquid core surrounded by at least one continuous membrane. More precisely, it is a finely dispersed liquid or solid phase coated with a film-forming polymer, and in its manufacture, the polymer is deposited on the material to be encapsulated after emulsification and coacervation or interfacial polymerization. In another process, a liquid active ingredient may be absorbed into a matrix ("microsponge") and further coated with a film-forming polymer as fine particles. Tiny capsules called nanocapsules can be dried in the same way as powders. In addition to mononuclear microcapsules, there are also multinuclear aggregates (also called microspheres) in which two or more cores are distributed in the continuous membrane material. Furthermore, mononuclear or multinuclear microcapsules may be surrounded by additional second, third, etc. membranes. The membrane may be composed of natural materials, semi-synthetic materials or synthetic materials. Examples of natural membrane materials include polysaccharides such as gum arabic, agar, agarose, maltodextrin, alginic acid and its salts such as sodium alginate or calcium alginate, fats and fatty acids, cetyl alcohol, collagen, chitosan, lecithin, gelatin, albumin, shellac, starch or dextran, polypeptides, proteolysates, sucrose and waxes. Semi-synthetic membrane materials are, in particular, chemically modified celluloses, more specifically cellulose esters and ethers such as cellulose acetate, ethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose and carboxymethyl cellulose, and starch derivatives, more specifically starch ethers and esters. Examples of synthetic membrane materials include polymers such as polyacrylate, polyamide, polyvinyl alcohol, polyvinyl pyrrolidone, etc.

[0030] Examples of well-known microcapsules include the following commercially available products (the materials in parentheses are film materials). Hallcrest microcapsules (gelatin, gum arabic), Colletica Catalasphere (marine collagen), Lipotec Millicapsulen (alginate, agar), Indukem Unispheres (lactose, microcrystalline cellulose, hydroxypropylmethylcellulose), Unicetin C30 (lactose, microcrystalline cellulose, hydroxypropylmethylcellulose), Kobo Carbosphere (modified starch, fatty acid ester, phospholipid), Softsphere (modified agar), Kuhs Probiol Nanospheres (phospholipid).

[0031] The active ingredient is usually released from the microcapsules by mechanical, thermal, chemical, or enzymatic destruction of the membrane during the use of the preparation containing the microcapsules. Despite the fact that the potential for encapsulation of state-of-the-art active ingredients is very wide, the method by which the shell is obtained by coazeotropism, precipitation, or polycondensation of anionic and cationic polymers is very suitable for the formation of stable capsules. In particular, the preferred process for encapsulating the active ingredient according to the present invention includes the following steps. (a) Preparing a matrix from a gelling agent, a cationic polymer, and an active ingredient; (b) Optionally, dispersing the matrix in an oil phase; and, (c) Treating the dispersed matrix with an aqueous solution of an anionic polymer and optionally removing the oil phase in the process. Of course, the anionic polymer and the cationic polymer in steps (a) and (c) can be exchanged.

[0032] Gelling agent. In the context of the present invention, preferred gelling agents are substances that can form a gel in an aqueous solution at a temperature above 40°C. Typical examples of such gelling agents are heteropolysaccharides and proteins. A preferred thermogelating heteropolysaccharide is agarose, which may exist in the form of agar obtained from red algae and can also be present together with up to 30% by weight of non-gelling agaropectin. The main component of agar is a linear polysaccharide of galactose and 3,6-anhydro-L-galactose, in which 1,3- and 1,4-glycosidic bonds alternate. This heteropolysaccharide preferably has a molecular weight of 110,000 - 160,000 and is odorless and tasteless. Suitable alternatives are pectin, xanthan (including xanthan gum), and mixtures thereof. Another preferred type forms a gel that does not melt at a temperature below 80°C and solidifies again at a temperature above 40°C in a 1% by weight aqueous solution. Examples from the group of thermogelating proteins include various gelatins.

[0033] Anionic polymer. For this purpose, salts of alginic acid are preferred. Alginic acid is a mixture of carboxyl group-containing polysaccharides having the following ideal monomer units.

Chemical formula

[0034] The average molecular weight of alginic acid or its salts is in the range of 150,000 - 250,000. The salts of alginic acid, and their fully and partially neutralized products, are understood to be, in particular, alkali metal salts, preferably sodium alginate ("algin"), ammonium, and alkaline earth metal salts. Mixed alginates, such as sodium alginate / magnesium or sodium alginate / calcium, are particularly preferred. However, in alternative embodiments of the present invention, carboxymethyl cellulose and anionic chitosan derivatives, such as carboxylated and the above-mentioned succinylated products, are also suitable for this purpose.

[0035] Cationic polymer. Chitosan is a biopolymer belonging to the group of hydrocolloids. Chemically, chitosan is deacetylated chitin with different molecular weights and contains the following ideal monomer units.

Chem.

[0036] In contrast to many hydrocolloids that are negatively charged at in vivo pH values, chitosan is a cationic biopolymer under these conditions. Positively charged chitosan can interact with oppositely charged surfaces and is thus used in cosmetic hair care products, body care products, and pharmaceutical preparations.

[0037] In a preferred embodiment of the present invention, an aqueous solution of 1-10% by weight, preferably 2-5% by weight, of a gelling agent, preferably agar, is usually prepared and heated under reflux. A second aqueous solution containing 0.1-2% by weight, preferably 0.25-0.5% by weight, of a cationic polymer, preferably chitosan, and 0.1-25% by weight, preferably 0.25-10% by weight, of an active ingredient is added at the heat of boiling, preferably at 80-100°C; this mixture is called a matrix. Thus, the loading of microcapsules with the active ingredient can also consist of 0.1-25% by weight, based on the weight of the capsules. If desired, water-insoluble components, such as inorganic pigments, can also be added at this stage to adjust the viscosity, and can generally be added in the form of an aqueous or aqueous / alcoholic dispersion. Furthermore, it may be useful to add an emulsifier and / or solubilizer to the matrix to emulsify or disperse the active ingredient. The matrix prepared from the gelling agent, cationic polymer and active ingredient can also be very finely dispersed in the oil phase by intensive shearing to produce small particles in a subsequent encapsulation process. In this regard, it has been proven particularly advantageous to heat the matrix in the range of 40-60°C while cooling the oil phase to 10-20°C. The actual encapsulation, i.e., the formation of a film by the contact of the cationic polymer and the anionic polymer in the matrix, is carried out in a third step. For this purpose, the matrix dispersed in the oil phase is washed with an aqueous solution of about 0.1-3% by weight, preferably 0.25-0.5% by weight, of an anionic polymer, preferably alginic acid, at a temperature in the range of 40-100°C, preferably 50-60°C, and at the same time, if present, it is desirable to remove the oil phase. The resulting aqueous preparation generally has a microcapsule content of 1-10% by weight. In some cases, it may be advantageous for the polymer solution to contain other components, such as an emulsifier or a preservative. After filtration, microcapsules having an average diameter of preferably 1-3 mm are obtained. It is desirable to sieve the microcapsules so that the size distribution of the capsules is uniform. The microcapsules thus obtained can have any shape within the range related to the manufacture, but are preferably substantially spherical.

[0038] Cosmetic composition Another object of the present invention relates to a cosmetic composition containing either a sesame oil mixture or a capsule as described above. The cosmetic composition can represent a skin care, personal care, hair care or sun care composition, and contains the mixture in an amount calculated on the composition(s) of, for example, about 0.1 - about 10% by weight, preferably about 0.5 - about 8% by weight, particularly about 1 - about 5% by weight.

[0039] The preparations according to the present invention may contain, for example, anti-dandruff agents, anti-irritation agents, irritation suppressants, antioxidants, astringents, antiperspirants, preservatives, antistatic agents, binders, buffers, carrier substances, chelating agents, cell activators, detergents, care agents, deodorants, antiperspirants, softeners and the like. Emulsifiers, enzymes, essential oils, fibers, film formers, fixatives, foam formers, foam stabilizers, antifoaming substances, foam boosters, gelling agents, gel formers, hair care agents, hair setting agents, hair straightening agents, moisturizers, moisturizing substances, bleaching agents, strengthening agents, stain removers, fluorescent brighteners, impregnating agents, antifouling agents, friction reducers, lubricants, moisturizing creams, ointments, opacifiers, plasticizers, coating agents, polishing agents, polymers, powders, proteins, re-oiling agents, abrasives, silicones, hair growth promoters, cooling agents, skin cooling agents, warming agents, skin warming agents, stabilizers. UV absorbers, UV filters, detergents, thickeners, vitamins, fats and oils, waxes, phospholipids, saturated fatty acids, mono- or polyunsaturated fatty acids, α-hydroxy acids, polyhydroxy fatty acids, liquefiers, dyes, color protectants, pigments, odoriferous substances, polyols, surfactants, electrolytes, organic solvents or silicone derivatives and the like can be included as additional auxiliaries and additives.

[0040] Surfactant Preferred auxiliaries and additives are anionic and / or amphoteric or zwitterionic surfactants. Nonionic and cationic surfactants may also be present in the composition. Suitable examples are described together with the paragraph dealing with emulsifiers.

[0041] Representative examples of anionic and zwitterionic surfactants include the following. Almond amidopropylamine oxide, almond amidopropyl betaine, aminopropyl lauryl glutamate, C 12-15 Alkyl ammonium sulfate, C 12-16 Alkyl ammonium sulfate, capryl ammonium sulfate, coco monoglyceride ammonium sulfate, coco ammonium sulfate, cocooyl isethionate ammonium, cocooyl sarcosinate ammonium, C 12-15 Pales ammonium sulfate, C 9-10 Perfluoroalkyl sulfonic acid ammonium, dinonyl sulfosuccinate ammonium, dodecyl benzene sulfonic acid ammonium, isostearic acid ammonium laures-6 carboxylate ammonium, laures-8 carboxylate ammonium, laures ammonium sulfate, laures-5 ammonium sulfate, laures-7 ammonium sulfate, laures-9 ammonium sulfate, laures-12 ammonium sulfate, lauroyl sarcosinate ammonium, lauryl ammonium sulfate, lauryl sulfosuccinate ammonium, myres ammonium sulfate, myristyl ammonium sulfate, nonoxynol 4 ammonium sulfate, nonoxynol 30 ammonium sulfate, oleic acid ammonium, palm kernel ammonium sulfate, stearic acid ammonium, tallate ammonium, AMPD-isostearoyl hydrolyzed collagen, AMP-Rosin hydrolyzed collagen, AMP-isostearoyl hydrolyzed collagen, AMP-isostearoyl hydrolyzed keratin, AMP-isostearoyl hydrolyzed soy protein, AMP-isostearoyl hydrolyzed wheat, apricot amidopropyl betaine, arachidic acid, arginine hexyl phosphate, avocado amidopropyl betaine, avocado oil glyceryl 8 ester, babassu acid, babassu amidopropylamine oxide, babassu amidopropyl betaine, beeswax acid, behenamide propyl betaine, behenamine oxide, behenes-25, behenes-30, behenic acid, behenyl betaine, bisbutyldimethicone polyglyceryl-3, butoxynol-5 carboxylic acid, butoxynol-19 carboxylic acid butyldimonium hydroxypropyl butyl glucoside chloride, butyldimonium hydroxypropyl lauryl glucoside chloride, butyl glucoside, butyl glucoside caprate, butyl glucoside hydroxypropyl trimonium chloride, butyl octanoic acid, C 18-36 acid, C 20-40 acid, C 30-50 acid, C 16-22 acid amide MEA, calcium dodecylbenzene sulfonate, calcium lauroyl taurate, C 9-16 alkane / cycloalkane, C 10-14 alkylbenzene sulfonic acid, C 12-14 alkyldiaminoethyl glycine HCL, C 9-15Alkyl phosphate, Candida bombicola / glucose / rapeseed methyl ferment, canolamidopropyl betaine, capric acid, caproic acid, caproyl ethyl glucoside, capryl / capramidopropyl betaine, caprylic 4-carboxylic acid, caprylic 6-carboxylic acid, caprylic st-9-carboxylic acid, caprylic acid, caproyl collagen amino acids, caproyl glycine, caproyl hydrolyzed collagen, caproyl hydrolyzed keratin, caproyl keratin amino acids, caproyl silk amino acids, caprylyl / capryl glucoside, caprylyl / capryl wheat bran / stro glucoside, caprylyl glucoside, caprylyl glyceryl ether, caprylyl pyrrolidone, carnitine, cetearyl eth-20, cetearyl eth-23, cetearyl eth-24, cetearyl eth-25, cetearyl eth-27, cetearyl eth-28, cetearyl eth-29, cetearyl eth-30, cetearyl eth-33, cetearyl eth-34, cetearyl eth-40, cetearyl eth-50, cetearyl eth-55, cetearyl eth-60, cetearyl eth-80, cetearyl eth-100, cetearyl eth-25 carboxylic acid, cetearyl eth-2 phosphate, cetearyl eth-4 phosphate, cetearyl eth-5 phosphate, cetearyl eth-10 phosphate, cetes-20, cetes-23, cetes-24, cetes-25, cetes-30, cetes-40, cetes-45, cetes-150, cetes-8 phosphate, cetes-10 phosphate, cetes-20 phosphate, cetores-22, cetores-24, cetores-25, cetores-30, cetyl betaine, chrysanthemum fresh flower extract, C 12 - 14 Hydroxyalkyl hydroxyethyl β-alanine, C 12 - 14Hydroxyalkyl hydroxyethyl sarcosine, cocoamidopropyl betaine, cocoamidopropylamine oxide, cocoamidopropyl betaine amide MEA chloride, cocoamidopropyl betaine, cocoamidopropyl hydroxysulfide, cocoaminobutyric acid, cocoamine propionic acid, coceth-7 carboxylic acid, coceth-4 glucoside, coco amphodipropionate, coco betaine amide amphopropionate, coco betaine, coco dimonium hydroxypropyl hydrolyzed rice protein, coco dimonium hydroxypropyl hydrolyzed soy protein, coco dimonium hydroxypropyl hydrolyzed wheat protein, coco glucoside, coco glucoside hydroxypropyl trimonium chloride, coco hydroxysulfate, coco morpholine oxide, coconut acid, palm oil glycereth-8 ester, coco / oleamidopropyl betaine, coco sultaine, coco / sunfloweramidopropyl betaine, cocoyl choline, methosulfate, cocoyl glutamate, cocoyl hydrolyzed collagen, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed wheat protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soy protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, corn acid, cottonseed acid, cottonseed oil glycereth-8 ester, C 10-16 Pares-1, C 10-16 Pares-2, C 11-13 Pares-6, C 11-13 Pares-9, C 11-13 Pares-10, C 11-15 Pares-30, C 11-15 Pares-40, C 12-13 Pares-1, C 12-13 Pares-23, C 12-14 Pares-5, C1 2-14 Pares-9, C 13-15 Pares-21, C 14-15 Pares-8, C 20-22 Pares-30, C 20-40 Pares-40, C 20-40 Pares-95, C 22-24 Pares-33, C 30-50 Pares-40, C 9-11 Pares-6 carboxylic acid, C 9-11 Pares-8 carboxylic acid, C11-15 Pares-7 carboxylic acid, C 12-13 Pares-5 carboxylic acid, C 12-13 Pares-7 carboxylic acid, C 12-13 Pares-8 carboxylic acid, C 12-13 Pares-12 carboxylic acid, C 12-15 Pares-7 carboxylic acid, C 12-15 Pares-8 carboxylic acid, C 12-15 Pares-12 carboxylic acid, C 14-15 Pares-8 carboxylic acid, C 6-10 Pares-4 phosphate, C12 - 13 Pares-2 phosphate, C 12-13 Pares-10 phosphate, C 12-15 Pares-6 phosphate, C 12-15 Pares-8 phosphate, C 12-15 Pares-10 phosphate, C 12-16 Pares-6 phosphate, C 4-18 Perfluoroalkyl ethyl thiohydroxypropyl trimonium chloride, Cupuas amido propyl betaine, DEA-C 12-13 Alkyl sulfate, DEA-C 12-15 Alkyl sulfate, DEA-Ceteareth-2 phosphate, DEA-cetyl sulfate, DEA-cocoa amphodiacetate, DEA-C 12-13 Pares-3 sulfate, DEA-cyclocarboxypropionate, DEA-dodecylbenzenesulfonate, DEA-lysostearate, DEA-lauryl sulfate, DEA-lauryl sulfate, DEA-linoleate, DEA-methyl myristate sulfonate, DEA-myristyl sulfate, DEA-myristate, DEA-myristyl sulfate, Oleth-5 phosphate, DEA-Oleth-20 phosphate, DEAPG-Oleth, Deces-7 carboxylic acid, Deces-7 glucoside, Deces-9 phosphate, Decylamine oxide, Decyl betaine, Decyl glucoside, Decyltetradeces-30, Decyltetradecylamine oxide, Di-ammonium lauroamido-MEA sulfosuccinate, Di-ammonium lauryl sulfosuccinate, Di-ammonium oleamide PEG-2 sulfosuccinate, Dibutoxymethane, Di-CI2 - 15 Pares-2 phosphate, Di-CI2 - 15 Pares-4 phosphate, Di-CI2 - 15 Pares-6 phosphate, Di-C 12-15Paleth-8 Phosphate, Di-CI2-15 Paleth-10 Phosphate, Didodecyl Butanetetracarboxylate, Diethylamine Laureth Sulfate, Diethylhexyl Sulfosuccinate Sodium, Di-hydroxyethyl C8-10 Alkoxypropylamine Oxide, Di-hydroxyethyl C9-11 Alkoxypropylamine Oxide, Di-hydroxyethyl C12-15 Alkoxypropylamine Oxide, Di-hydroxyethyl Cocamine Oxide, Di-hydroxyethyl Lanolinamine Oxide, Di-hydroxyethyl Stearamine Oxide, Di-hydroxyethyl Tallowamine Oxide, Dimethicone PEG-7 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG-12 / 4 Phosphate, Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone Propyl PG-Betaine, Dimyristyl Phosphate, Dioleoyl Amidoethyl Hydroxyethyl Ammonium Methosulfate, DIPA-Coconut Acid Hydrogenated, DIPA-Lanolate, DIPA-Myristate, Capryloyl Glutamic Acid Dipotassium, Lauryl Sulfosuccinic Acid Dipotassium, Undecylenoyl Glutamic Acid Dipotassium, Babassu Amido MEA-Sulfosuccinic Acid Disodium, Capro Amphodiacetate Disodium, Capro Amphodipropionate Disodium, Caprylo Amphodiacetate Disodium, Caprylo Amphodipropionate Disodium, Capryloyl Glutamic Acid Disodium, Cetearyl Sulfosuccinic Acid Disodium, Cetyl Phenyl Ether Disulfonic Acid Disodium, Cetyl Sulfosuccinic Acid Disodium, Cocamide MEA-Sulfosuccinic Acid Disodium, Cocamide MIPA PEG-4 Sulfosuccinic Acid Disodium, Cocamide MIPA-Sulfosuccinic Acid Disodium, Cocamide PEG-3 Sulfosuccinic Acid Disodium, Cocs-3 Sulfosuccinic Acid Disodium, Cocoa Amphocarboxyethyl Hydroxypropyl Sulfonic Acid Disodium, Cocoa Amphodiacetate Disodium, Cocoa Amphodipropionate Disodium, Coco-Glucoside Sulfosuccinic Acid Disodium, Coco-Sulfosuccinic Acid Disodium, Cocoyl Butyl Glucosulfosulfo 10, Cocoyl Glutamic Acid Disodium, C 12-14 Paleth-1 Sulfosuccinic Acid Disodium, C12-14 Disodium palas-2-sulfosuccinate, C 12-15 Palas sulfosuccinate, C 12-14 Sec-palas-3-sulfosuccinate disodium, C 12-14 Sec-palas-5-sulfosuccinate disodium, C 12-14 Sec-palas-7-sulfosuccinate disodium, C 12-14 Sec-palas-9-sulfosuccinate disodium, C 12-14Disodium sec-palate-12 sulfosuccinate, disodium deceth-5 sulfosuccinate, disodium deceth-6 sulfosuccinate, disodium decyl phenyl ether disulfonate, disodium dihydroxyethyl sulfosuccinyl undecylenate, disodium ethylenedicocamide PEG-15 disulfate, disodium hydrogenated cottonseed glyceride sulfosuccinate, disodium hydrogenated otafugu glutamate, disodium hydroxydecyl sorbitol citrate, disodium isodecyl sulfosuccinate, disodium isostearamid MEA sulfosuccinate, disodium isostearamid MIPA sulfosuccinate, disodium isostearoamphodiacetate, disodium isostearoamphodipropionate, disodium isostearyl sulfosuccinate, disodium laneth-5 sulfosuccinate, disodium lauramide MEA-sulfosuccinate, disodium lauramide MIPA glycol sulfosuccinate, disodium lauramide PEG-2 sulfosuccinate, disodium lauramide PEG-5 sulfosuccinate, disodium laureth-5 carboxy amphodiacetate, disodium laureth-7 citrate, disodium laureth sulfosuccinate, disodium laureth-6 sulfosuccinate, disodium laureth-9 sulfosuccinate, disodium laureth-12 sulfosuccinate, disodium lauriminobis(hydroxypropyl)sulfonate, disodium lauriminodiacetate, disodium lauriminodipropionate, disodium lauriminodipropionate tocopheryl phosphate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, sodium N-lauroyl aspartate, disodium lauroyl glutamate, disodium lauryl phenyl ether disulfonate, disodium lauryl sulfosuccinate, disodium myristamide MEA-sulfosuccinate, disodium nonoxynol 10 sulfosuccinate, disodium oleamide MEA-sulfosuccinate, disodium oleamide MIPA-sulfosuccinate, disodium oleamide PEG-2 sulfosuccinate, disodium oleoamphodipropionate, disodium oleth-3 sulfosuccinate, disodium oleyl phosphate, disodium oleyl sulfosuccinate,Disodium palmitamide PEG-2 sulfosuccinate, disodium palmitoleamide PEG-2 sulfosuccinate, disodium cocamid MIPA sulfosuccinate PEG4, disodium sulfosuccinate PEG-12 dimethicone, disodium sulfosuccinate PEG-8 palm glyceride, disodium carboxy amphodiacetate PPG-2-lsodeceth-7, disodium sulfosuccinate ricinoleamide MEA, disodium sulfosuccinate cytosterol 14, disodium soy amphodiacetate, disodium stearamide MEA-sulfosuccinate, disodium steariminodipropionate, disodium stearoamphodiacetate, disodium stearoyl glutamate, disodium stearyl sulfosuccinamate, disodium stearyl sulfosuccinate, disodium 2-sulforaurate, disodium 2-sulfopalmitate, disodium talamide MEA sulfosuccinate, disodium tallowamide MEA sulfosuccinate, disodium tallow amphodiacetate, disodium tallowiminodipropionate, disodium tallow·sulfosuccinamate, disodium tridecyl sulfosuccinate, disodium undecylenamide MEA-sulfosuccinate, disodium undecylenamide PEG-2 sulfosuccinate, disodium undecylenoyl glutamate, disodium wheat germ MEA-sulfosuccinate, disodium wheat germ PEG-2 sulfosuccinate, disodium wheat germ diacetate, di-TEA-cocamidodiacetate, di-TEA-oleamide PEG-2 sulfosuccinate, di-TEA-palmitoyl aspartic acid, disodium ditridecyl sulfate, dodecylbenzenesulfonic acid, erucamidopropyl hydroxysulteine, ethylhexane-3-carboxylic acid, ethyl PEG-15 cocoamine sulfate, caprylyl glyceryl ether, hexyl decanoic acid, hydrogenated coconut acid, hydrogenated lanolin-25, hydrogenated menhaden acid, hydrogenated palm acid, hydrogenated palm kernel amine oxide, hydrogenated tallow acid, hydrogenated tallow amine oxide, hydrogenated tallow betaine, hydrogenated tallow es-25, hydrogenated tallow oil glutamate, hydrolyzed candida bombicola extract, hydroxycetes-60, hydroxyethyl acetomonium PG-dimethicone,Hydroxyethylbutylamine lauryl sulfate, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamine oxide, hydroxylated lauryl / hydroxylated myristyl betaine, hydroxystearic acid, hydroxysuccinimidyl C, 10-40 Isoalkyl acidate, hydroxysuccinimidyl C 21-22Isoalkyl acidate, hydroxysulfurene, IPDI / PEG-15 soyamine oxide ester, IPDI / PEG copolymer, IPDI / PEG-15 soy glycinate copolymer, isocetes-30, isolaureth-4 phosphate, isopolyglyceryl-3 dimethicone, isopolyglyceryl-3 dimethiconol, isopropanolamine lanolate, isopropylamine dodecylbenzene sulfonate, isostearamidopropylamine oxide, isostearamidopropyl betaine, isostearamidopropyl morpholine oxide, isosteareth-8, lysosteareth-16, isosteth-22, lysosteth-25, lysosteareth oil PEG-150 ester, jojoba wax PEG-80 ester, jojoba wax PEG-120 ester, laureth-20, laureth-25, laureth-40, laureth-50, laureth-60, laureth-75, lanolin acid, lauramidopropylamine oxide, lauramidopropyl betaine, lauramidopropyl hydroxysultaine, lauramine oxide, lauraminopropionic acid, laurdimonium hydroxypropyl decyl glucoside chloride, laurdimonium hydroxypropyl lauryl glucoside chloride, laureth-16, laureth-20, laureth-21, laureth-23, laureth-25, laureth-30, laureth-38, laureth-40, laureth-3 carboxylic acid, laureth-4 carboxylic acid, laureth-5 carboxylic acid, laureth-6 carboxylic acid, laureth-8 carboxylic acid, laureth-10 carboxylic acid, laureth-11 carboxylic acid, laureth-12 carboxylic acid, laureth-13 carboxylic acid, laureth-14 carboxylic acid, laureth-17 carboxylic acid, laureth-6 citrate, laureth-7 citrate, laureth-1 phosphate, laureth-2 phosphate, laureth-3 phosphate, laureth-6 phosphate, laureth-4 phosphate, laureth-7 phosphate, laureth-8 phosphate, laureth-7 tartrate, lauric acid, lauriminobispropandiol, lauriminodipropionic acid, lauroamphodipropionic acid, lauroyl beta-alanine, lauroyl collagen amino acid, lauroyl ethyltrimonium methosulfate, lauryl hydrolyzed collagen, lauryl hydrolyzed elastin, lauroyl methyl glucamide, lauroyl sarcosine,Lauroyl silk amino acid, lauryl betaine, lauryl dimethicone / polyglycerin 3 copolymer, lauryldimonium hydroxypropyl cocoglucoside chloride, lauryl glucoside, lauryl glucoside hydroxypropyl trimonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysultaine, lauryl malamide, lauryl methyl glucamide, lauryl / myristyl glycol hydroxypropyl ether, lauryl / myristyl wheat bran / , Laureth-16, Laureth-20, Laureth-21, Laureth-23, Laureth-25, Laureth-30, Laureth-38, Laureth-40, Laureth-3 carboxylic acid, Laureth-4 carboxylic acid, Laureth-5 carboxylic acid, Laureth-6 carboxylic acid, Laureth-8 carboxylic acid, Laureth-10 carboxylic acid, Laureth-11 carboxylic acid, Laureth-12 carboxylic acid, Laureth-13 carboxylic acid, Laureth-14 carboxylic acid, Laureth-17 carboxylic acid, Laureth-6 citrate, Laureth-7 citrate, Laureth-1 phosphate, Laureth-2 phosphate, Laureth-3 phosphate, Laureth-6 phosphate, Laureth-4 phosphate, Laureth-7 phosphate, Laureth-8 phosphate, Laureth-7 tartrate, Lauric acid, Lauriminobispropanediol, Lauriminodipropionic acid, Lauroamphodipropionic acid, Lauroyl beta-alanine, Lauroyl collagen amino acid, Lauroyl ethyltrimonium methanesulfate, Lauryl hydrolyzed collagen, Lauryl hydrolyzed elastin, Lauroyl methyl glucamide, Lauroyl sarcosine, Lauroyl silk amino acid, Lauryl betaine, Lauryl dimethicone / polyglycerin 3 copolymer, Lauryl dimonium hydroxypropyl cocoglucoside chloride, Lauryl glucoside, Lauryl glucoside hydroxypropyltrimonium chloride, Lauryl glycol hydroxypropyl ether, Lauryl hydroxysultaine, Lauryl malamide, Lauryl methyl glucamide, Lauryl / myristyl glycol hydroxypropyl ether, Lauryl / myristyl wheat bran / straw glucoside, Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, Lauryl pyrrolidone, Lauryl sultane, Linoleic acid, Linolenic acid, Linseed acid, Lysine cocoate, Macadamia seed oil glyceryl-8 ester, Magnesium coceth sulfate, Magnesium cocosulfate, Magnesium isododecylbenzenesulfonate, Magnesium laureth-11 carboxylate, Magnesium laureth sulfate, Magnesium laureth-5 sulfate, Magnesium laureth-8 sulfate, Magnesium laureth-16 sulfate, Laureth-3 sulfosuccinate, Magnesium lauryl hydroxypropyl sulfonate, Magnesium lauryl sulfate, Magnesium methyl cocoyl taurate, Magnesium myreth sulfateOrace Magnesium Sulfate, Magnesium / TEA-Coco Sulfate, Manicua Gangu Clay, MEA-Coco Acid, MEA-Laureth-6 Carboxylic Acid, MEA-Laureth Sulfate, MEA-Lauryl Sulfate, MEAPPG-6 Laureth-7 Carboxylic Acid, MEA-PPG-8-Stearate-7 Carboxylic Acid, MEA-Undecylenate, Meroxapol 108, Meroxapol 174, Meroxapol 178, Meroxapol 254, Meroxapol 255, Meroxapol 258, Meroxapol 314, MethoxyPEG-450 Amide Glutaryl Succinimide, MethoxyPEG-450 Amide Hydroxy Succinimidyl Succinamate, MethoxyPEG-450 Maleimide, Methyl Morpholine Oxide, Mircamidopropylamine Oxide, Mircamidopropyl Betaine, Minkamidopropylamine Oxide, Minkamidopropyl Betaine, MIPAC12-15 Pareth Sulfate, MEAPPG-6 Laureth-7 Carboxylic Acid, MEA-PPG-8-Stearate-7 Carboxylic Acid, MEA-Undecylenate, Meroxapol 108, Meroxapol 174, Meroxapol 178, Meroxapol 254, Meroxapol 255, Meroxapol 258, Meroxapol 314, MethoxyPEG-450 Amide Glutaryl Succinimide, MethoxyPEG-450 Amide Hydroxy Succinimidyl Succinamate, MethoxyPEG-450 Maleimide, Methyl Morpholine Oxide, Mircamidopropylamine Oxide, Mircamidopropyl Betaine, Minkamidopropylamine Oxide, Minkamidopropyl Betaine, MIPAC12-15 Pareth Sulfate, MIPA Lauryl Sulfate Sodium, MIPA-Lauryl Sulfate Sodium, Mixed Isopropanolamine Lanolate, Mixed Isopropanolamine Lauryl Sulfate Sodium, Mixed Isopropanolamine Myristate, Morpholine Oleate, Morpholine Stearate, Myreth-3 Carboxylic Acid, Myreth-5 Carboxylic Acid, Myristalkonium Chloride, Myristyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristamidopropyl Hydroxysultaine, Myristamidopropyl PG-Dimonium Chloride Phosphate, Myristamine Oxide, Myristaminopropionic Acid, Myristic Acid, Myristoylethyl Trimonium Methosulfate,Myristoyl Glutamic Acid, Myristoyl Hydrolyzed Collagen, Myristoyl Sarcosine, Myristyl Betaine, Myristyl / Cetyl Amine Oxide, Myristyldimonium Hydroxypropyl Cocoglucoside Chloride, Myristyl Glucoside, Myristyl Phosphate, Nonoxynol-20, Nonoxynol-23, Nonoxynol-25, Nonoxynol-30, Nonoxynol-35, Nonoxynol-40, Nonoxynol-44, Nonoxynol-50, Nonoxynol-100, Nonoxynol-120, Nonoxynol-5 Carboxylic Acid, Nonoxynol-8 Carboxylic Acid, Nonyl Nonoxynol-10 Carboxylic Acid, Nonoxynol-3 Phosphate, Nonoxynol-4 Phosphate, Nonoxynol-6 Phosphate, Nonoxynol-9 Phosphate, Nonoxynol-10 Phosphate, Nonyl Nonoxynol-30, Nonyl Nonoxynol-49, Nonyl Nonoxynol 100, Nonyl Nonoxynol 150, Nonyl Nonoxynol-7 Phosphate, Nonyl Nonoxynol-8 Phosphate, Nonyl Nonoxynol-9 Phosphate, Nonyl Nonoxynol-10 Phosphate, Nonyl Nonoxynol-11 Phosphate, Nonyl Nonoxynol-15 Phosphate Nonyl Nonoxynol 24 Phosphate, Lauramidopropyl Betaine, Octoxynol 16, Octoxynol 25, Octoxynol 30, Octoxynol 33, Octoxynol 40, Octoxynol 70, Octoxynol 20 Carboxylic Acid, Octyldodeceth-20, Octyldodeceth-25, Octyldodeceth-30, Oleamidopropyl Amine Oxide, Oleamidopropyl Betaine, Oleamidopropyl Hydroxy Sulfide, Oleamide Oxide, Oleic Acid, Oleyl Hydrolyzed Collagen, Oleoyl Sarcosine, Oleth 20, Oleth 23, Oleth 24, Oleth 25, Oleth 30, Oleth 35, Oleth 40, Oleth 44, Oleth 50, Oleth 3 Carboxylic Acid, Oleth 6 Carboxylic Acid, Oleth 10 Carboxylic Acid, Oleyl Betaine, Olivamidopropyl Amine Oxide, Olivamidopropyl Betaine, Olive Acid, Olivoyl Hydrolyzed Wheat Protein, Ophiopogon Extract Stearate, Ozonated Oleth 10, Ozonated Oleth PEG-10, Ozonated Oleth PEG-14, Ozonated Polysorbate 80, Palmitic Acid, Palmidopropyl Betaine, Palmith 2 Phosphate, Palmidopropyl Amine Oxide,Palmitylmitamine Oxide, Palmitic Acid, Palmitoyl Collagen Amino Acids, Palmitoyl Glycine, Palmitoyl Hydrolyzed Collagen, Palmitoyl Hydrolyzed Casein, Palmitoyl Hydrolyzed Wheat Protein, Palmitoyl Keratin Amino Acids, Palmitoyl Oligopeptide, Palmitoyl Silk Amino Acids, Palm Nucleic Acid, Palm Kernel Amidopropyl Betaine, Peach Kernel Oil Glycereth-8 Ester, Peanut Amide, PEG-10 Castor Oil, PEG-40 Castor Oil, PEG-44 Castor Oil, PEG-50 Castor Oil, PEG-54 Castor Oil, PEG-55 Castor Oil, PEG-60 Castor Oil, PEG-80 Castor Oil, PEG-100 Castor Oil, PEG-200 Castor Oil, PEG-11 Cocamide, Cocamide Phosphate, PEG-4 Cocamine, PEG-8 Cocamine, PEG-12 Cocamine, PEG-150 Dibehenate, PEG-90 Diisostearate, PEG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Dioleate, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl Cocoate, PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Laurate, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Soyate, PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, PEG-28 Glyceryl Tallowate, PEG-80 Glyceryl Tallowate, PEG-82 Glyceryl Tallowate, PEG-130 Glyceryl Tallowate, PEG-200 Glyceryl Tallowate, PEG-45 Hydrogenated Castor Oil, PEG-50 Hydrogenated Castor Oil, PEG-54 Hydrogenated Castor Oil,PEG-55 Hydrogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, PEG-80 Hydrogenated Castor Oil, PEG-100 Hydrogenated Castor Oil, PEG-200 Hydrogenated Castor Oil, PEG-30 Hydrogenated Lanolin, PEG-70 Hydrogenated Lanolin, PEG-50 Hydrogenated Palmide, PEG-2 Isostearate, PEG-3 Isostearate, PEG-4 Isostearate, PEG-6 Isostearate, PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauraminoxide, PEG-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70 Mango Glyceride, PEG-20 Mannitan Laurate, PEG-8 Methyl Ether Dimethicone, PEG-120 Methyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Methyl Glucose Trioleate, PEG-4 Montanic Acid, PEG-30 Oleamine, PEG-20 Oleic Acid, PEG-23 Oleic Acid, PEG-32 Oleic Acid, PEG-36 Oleic Acid, PEG-75 Oleic Acid, PEG-150 Oleic Acid, PEG-20 Palmitate, Polyglyceryl 150 Tristearate, PEG / PPG-28 / 21 Dimethicone Acetate, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer, PEG / PPG-10 / 30 Copolymer, PEG / PPG-10 / 65 Copolymer, PEG / PPG-12 / 35 Copolymer, PEG / PPG-16 / 17 Copolymer, PEG / PPG-20 / 9 Copolymer, PEG / PPG-20 / 20 CopolymerPEG / PPG-20 / 60 copolymer, PEG / PPG-20 / 65 copolymer, PEG / PPG-22 / 25 copolymer, PEG / PPG-28 / 30 copolymer, PEG / PPG-30-35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer, PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG, / PPG-160 / 30 Copolymer, PEG / PPG-190 / 60 Copolymer, PEG / PPG-200 / 40 Copolymer, PEG / PPG-300 / 55 Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG-26-PPG-30 Phosphate, PEG / PPG-4 / 2 Propylheptyl Ether, PEG / PPG-6 / 2 Propylheptyl Ether, PEG-7 / PPG-2 Propylheptyl Ether, PEG / PPG-8 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Propylheptyl Ether, PEG / PPG-14 / 2 Propylheptyl Ether, PEG / PPG-40 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG-32 / 3 Ricinoleic Acid, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol, PEG-10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glyceride, PEG-75 Shorea Butter Glyceride, PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolate, PEG-75 Sorbitan Lanolate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG / PPG-28 / 21 Dimethicone Acetate, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer, PEG / PPG-10 / 30 Copolymer, PEG / PPG-10 / 65 Copolymer, PEG / PPG-12 / 35 Copolymer, PEG / PPG-16 / 17 Copolymer, PEG / PPG-20 / 9 Copolymer, PEG / PPG-20 / 20 Copolymer, PEG / PPG-20 / 60 Copolymer, PEG / PPG-20 / 65 Copolymer, PEG / PPG-22 / 25 Copolymer, PEG / PPG-28 / 30 Copolymer,PEG / PPG-30-35 Copolymer, PEG / PPG-30 / 55 Copolymer, PEG / PPG-35 / 40 Copolymer, PEG / PPG-50 / 40 Copolymer, PEG / PPG-150 / 35 Copolymer, PEG / PPG-160 / 30 Copolymer, PEG / PPG-190 / 60 Copolymer, PEG / PPG-200 / 40 Copolymer, PEG / PPG-300 / 55 Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG-26-PPG-30 Phosphate, PEG / PPG-4 / 2 Propylheptyl Ether, PEG / PPG-6 / 2 Propylheptyl Ether, PEG-7 / PPG-2 Propylheptyl Ether, PEG / PPG-8 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Propylheptyl Ether, PEG / PPG-14 / 2 Propylheptyl Ether, PEG / PPG-40 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG-32 / 3 Ricinoleic Acid, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol, PEG-10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glyceride, PEG-75 Shorea Butter Glyceride, PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolate, PEG-75 Sorbitan Lanolate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soybean Sterol, PEG-2 Stearamide Carboxylic Acid, PEG-9 Stearamide Carboxylic Acid, PEG-20 Stearate, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 StearatePEG-40 Stearate, PEG-45 Stearate, PEG-50 Stearate, PEG-55 Stearate, PEG-75 Stearate, PEG-90 Stearate, PEG-100 Stearate, PEG-120 Stearate, PEG-150 Stearate, PEG-45 Stearate Phosphate, PEG-20 Tallate, PEG-50 Tallow Amide, PEG-2 Tallow Amide DEA, PEG-20 Tallate, PEG-66 Trihydroxystearic, PEG-200 Trihydroxystearic, PEG-60 Camellia Glyceride, Pelargonic Acid, Pentadocynol-200, Phenesic Phosphate-6, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288, Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether·Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether·Silsesquioxane, Polyglyceryl-6 Caprylate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauroyl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octaisononanoate, Polyglyceryl-6 Pentacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomaderris Kumera Flower / Leaf Extract, Polyacorus Extract, Abietoyl Hydrolyzed Collagen, Babassu Potassium, Potassium Adipate Potassium Behenate, C 9-15 Potassium Alkyl Phosphate, C 11-15 Potassium Alkyl Phosphate, C12-13 Potassium alkyl phosphate, C 12-14Potassium alkyl phosphate, potassium caprate, potassium caproyl glutamate, caproyl hydrolyzed rice protein, potassium castorate, potassium cocoyl glycinate, potassium cocoyl glutamate, potassium cocoyl glycinate, cocoyl hydrolyzed casein, cocoyl hydrolyzed collagen, cocoyl hydrolyzed corn protein, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed casein, cocoyl hydrolyzed collagen, cocoyl hydrolyzed collagen, cocoyl hydrolyzed casein, cocoyl hydrolyzed cacao protein, cocoyl hydrolyzed potato protein, cocoyl hydrolyzed rice bran protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soy protein, cocoyl hydrolyzed wheat protein, potassium cocoyl hydrolyzed yeast protein, potassium cocoyl PCA, potassium cocoyl sarcosinate, potassium cocoyl taurine, potassium corneate, potassium cyclocarboxypropylolate, potassium dihydroxyethyl cocamine oxide phosphate, potassium dimethicone PEG-7 phosphate, potassium dodecylbenzene sulfonate, potassium hempseed acid, potassium hydrogenated cocoate, potassium hydrogenated palmitate, potassium hydrogenated tallowate, potassium hydroxystearate, potassium isostearate, potassium lanolate, potassium laurate, potassium laures-3 carboxylate, potassium laures-4 carboxylate, potassium laures-5 carboxylate, potassium laures-6 carboxylate, potassium laures-10 carboxylate, potassium laures phosphate, potassium lauroyl collagen amino acid, potassium lauroyl glutamate, lauroyl hydrolyzed collagen, lauroyl hydrolyzed eda protein, lauroyl hydrolyzed soy protein, potassium lauroyl PCA, potassium lauroyl pea amino acid, potassium lauroyl sarcosinate, potassium lauroyl silk amino acid, potassium lauroyl wheat amino acid, potassium lauryl phosphate, potassium lauryl sulfate, potassium linoleate, potassium metaphosphate, potassium methyl cocoyl taurine, potassium myristate, potassium myristoyl glutamate, myristoyl hydrolyzed collagen, potassium octoxynol 12 phosphate, potassium oleate, oleyl hydrolyzed collagen,Potassium Olivate, Olivine Hydrolyzed Oat Protein Potassium, Olivine Hydrolyzed Wheat Gluten Protein Potassium, Olivoyl / Lauroyl Wheat Amino Acid Potassium, Olivoyl PCA Potassium, Potassium Palmitate, Hydrolyzed Corn Protein, Hydrolyzed Oat Protein, Hydrolyzed Rice Protein, Hydrolyzed Sweet Almond Protein, Potassium of Palmitoyl Hydrolyzed Wheat Gluten Protein, Potassium Palm Kernelate, Potassium Peanutate, Potassium Rapeseedate, Potassium Ricinoleate, Potassium Safflowerate, Potassium Soyate, Potassium Stearate, Potassium Stearoyl Hydrolyzed Collagen, Potassium Tartrate, Potassium Tallowate, Potassium Taurate Taurine Laurate, Potassium Tridecene-3-carboxylate, Potassium Tridecene-4-carboxylate, Potassium Tridecene-7-carboxylate, Potassium Tridecene-15-carboxylate, Potassium Tridecene-19-carboxylate, Potassium Tridecene-6-phosphate, Potassium Tridecene-7-phosphate, Potassium Camellate, Potassium Undecylenate, Undecylenoyl Hydrolyzed Collagen, Undecylenoyl Hydrolyzed Rice Protein, PPG-30-Buteth-30, PPG-36-Buteth-36, PPG-38-Buteth-37, PPG-30-Capryleth-4 Phosphate, PPG-10 Cetyl Ether Phosphate, PPG-2C9-11 Pareth-8, PPG-1-Deceth-5, PPG-3-Deceth-2 Carboxylic Acid, PPG-30 Ethylhexeth-4 Phosphate, PPG-20-Glycereth-30, PPG-2 Hydroxyethyl·Coco / Rostearamide, PPG-2-Laurodeceth-8, PPG-2-Laurodeceth-10, PPG-2-Laurodeceth-18, PPG-2-Laurodeceth-25, PPG-4-Laurodeceth-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Rapeseed Acid, Rice Bran Acid, Rice Bran Oil Glycereth-8 Ester, Ricinoleamidopropyl Betaine, Ricinoleic Acid, Ricinoleyl Ester-40, Safflower Acid, Sapindus Mukorossi Fruit Extract, Saponaria Officinalis Root Powder, Saponin, Soap K, Soap Na / K, Total Soap Finish, Total Soap Finish K, Sesame Oil Glycereth-Eth-8 Ester, Sesamidopropylamine Oxide, Sesamidopropyl Betaine, Shea Butter Amidopropyl BetaineShea Butter Glyceryl-8 Ester, Sodium Arachidate, Sodium Alginam-Hoo Acetate, Sodium Astrokalium Murmurate, Sodium Avocadoate, Sodium Babassu Amphoacetate, Sodium Babassuate, Sodium Babassu Sulfate, Sodium Behenate, Umm, Sodium Bisglycol Lysine Sulfate, Bis-Hydroxyethyl Glycine Na Coco-Glucoside Crosspolymer, Bis-Hydroxyethyl Glycine Lauryl Glucoside Crosspolymer, Borrageamidopropyl PG-Dimonium Chloride Phosphate Sodium, Sodium Butoxynol-12 Sulfate, Sodium Butyl Glucoside Hydroxypropyl Phosphate, C 13-17 Sodium C-Alkanesulfonate, C 14-18 Sodium C-Alkanesulfonate, C 12-15 Sodium Alkoxypropyliminodipropionate, C 10-16 Sodium Alkyl Sulfate, C 11-15 Sodium Alkyl Sulfate, C 12-13 Sodium Alkyl Sulfate, C 12-15 Sodium Alkyl Sulfate C 12-18 Sodium Alkyl Sulfate, C 16-20 Sodium Alkyl Sulfate, C 9-22 Sodium Alkyl Sulfate, C 14-17Sodium alkyl sulfate, sodium caprate, sodium caproamphoacetate, sodium caproamphohydroxypropyl sulfonate, sodium caproamphohydroxy sulfonate, sodium caproamphopropionate, sodium caproyl methyl taurate, sodium caprylate, sodium caprylyl 2-carboxylate, sodium caprylyl 9-carboxylate, sodium capryloamphoacetate, sodium capryloamphohydroxypropyl sulfonate, sodium capryloamphopropionate, sodium capryloyl glutamate, sodium capryloyl hydrolyzed wheat protein, sodium caprylyl PG-sulfonate, sodium caprylyl sulfonate, sodium castorate, sodium cetearyl-13-carboxylate, sodium cetearyl sulfate, sodium ceteth-13-carboxylate, sodium cetyl sulfate, sodium cocamidopropyl PG-dimonium chloride phosphate, sodium cocaminopropionate, sodium coceth sulfate, sodium coceth-30 sulfate, sodium cocoabutter amphoacetate, sodium cocoabutterate, sodium cocoamphoacetate, sodium coco / babassu / andiroba sulfate, sodium coco / babassu sulfate, sodium cocoglucoside hydroxypropyl phosphate, sodium cocoglucoside hydroxypropyl sulfonate, sodium cocoglucoside tartrate, sodium cocoglyceryl ether sulfonate, sodium coco / hydrogenated tallow sulfate, sodium cociminodiacetate sulfonate, sodium cocopropyl PG-diammonium chloride ceteth-13-carboxylate, sodium cetyl sulfate, sodium cocamidopropyl PG-dimonium chloride phosphate, sodium cocaminopropionate, sodium coceth sulfate, sodium coceth-30 sulfate, sodium cocoabutter amphoacetate, sodium cocoabutterate, sodium cocoamphoacetate, sodium coco / babassu / andiroba sulfate, sodium coco / babassu sulfate, sodium cocoglucoside hydroxypropyl phosphate, sodium cocoglucoside hydroxypropyl sulfonate, sodium cocoglucoside tartrate, sodium cocoglyceryl ether sulfonate, sodium coco / hydrogenated tallow sulfate,Cocoyliminodiacetate sodium sulfonate, coco sodium PG-diammonium chloride phosphate, coco sodium sulfate, coco sulfacetate sodium, sodium cocoyl alaninate, sodium cocoyl amino acid, sodium cocoyl collagen amino acid, sodium cocoyl glutamate, sodium cocoyl glutamate / sodium cocoyl glycinate, sodium tallow glutamate, sodium cocoyl hydrolyzed collagen, sodium cocoyl hydrolyzed keratin, sodium cocoyl hydrolyzed rice protein, sodium cocoyl hydrolyzed silk, sodium cocoyl hydrolyzed soy protein, sodium cocoyl hydrolyzed sweet almond protein, sodium cocoyl hydrolyzed wheat protein, sodium cocoyl hydrolyzed wheat protein glutamate, sodium cocoyl isethionate, sodium cocoyl methyl aminopropionate, sodium cocoyl oats amino acid, sodium cocoyl / palmoil / sunflower glutamate, sodium cocoyl proline, sodium cocoyl sarcosinate, sodium cocoyl taurate, sodium cocoyl threonate, sodium cocoyl wheat amino acid, C 12-14 Sodium olefin sulfonate, C 14-16 Sodium olefin sulfonate, C 14-18 Sodium olefin sulfonate, C 16-18 Sodium olefin sulfonate, sodium cocoamphopropionate, sodium cottonseed amphoacetate, C 13-15 Pares-8 sodium butyl phosphate, C 9-11 Pares-6 carboxylate sodium, C 11-15 Pares-7 carboxylate sodium, C 12-13 Pares-5 carboxylate sodium, C 12-13 Pares-8 carboxylate sodium, C 12-13 Pares-12 carboxylate sodium C 12-14 Sodium olefin sulfonate, C 14-16 Sodium olefin sulfonate, C 14-18 Sodium olefin sulfonate, C 16-18Sodium olefin sulfonate, sodium coco propionate, sodium cottonseed amphoacetate, C 13-15 Sodium paleth-8 phosphate, C 9-11 Sodium paleth-6 carboxylate, C 11-15 Sodium paleth-7 carboxylate, C 12-13 Sodium paleth-5 carboxylate, C 12-13 Sodium paleth-8 carboxylate, C 12-13 Sodium paleth-12 carboxylate, C 12-15 Sodium paleth-6 carboxylate, C 12-15 Sodium paleth-7 carboxylate, C 12-15 Sodium pers-8 carboxylate, C 14-15 Sodium pers-8 carboxylate, C 12-14 Sodium secpers-8 carboxylate, C 14-15 Sodium pers PG sulfonate C 12-13 Sodium paleth-2 phosphate, C13-15 Sodium paleth-8 phosphate, C 9-15 Sodium paleth-3 sulfate, C 10-15 Sodium paleth sulfate, C 10-16 Sodium paleth-2 sulfate, C 12-13 Sodium paleth sulfate, C 12-15 Sodium paleth sulfate, C 12-15 Sodium paleth 3 sulfate, C 13-15 Sodium paleth 3 sulfate, C 12-14 Sodium secpaleth 3 sulfate, C 12-15 Sodium paleth-3 sulfonate, C 12-15 Sodium paleth-7 sulfonate, C 12-15Sodium paleth-15-sulfonate, Sodium deceth-2-carboxylate, Sodium deceth sulfate, Sodium decylbenzene sulfonate, Sodium decyl glucoside hydroxypropyl phosphate, Sodium decyl glucoside hydroxypropyl sulfonate, Sodium dilaurate-7 citrate, Sodium dilaurate-10 phosphate, Sodium dilinoleamidopropyl PG-dimonium chloride phosphate, Sodium dilinoleate, Sodium dioleus-8 phosphate, Sodium dodecylbenzene sulfonate, Sodium 2-sulfolaurate ethyl, Sodium glyceryl oleate phosphate, Sodium grape seed amido propyl PG-dimonium chloride phosphate, Sodium grape seed amphoacetate, Sodium grape seed acid, Sodium hemp seed amphoacetate, Sodium hexeth-4-carboxylate, Sodium hydrogenated cocoate, Sodium hydrogenated cocoamethyl isothionate, Sodium hydrogenated palmitate, Sodium hydrogenated tallowate, Sodium hydrogenated tallow glutamate, Sodium hydroxy lauryl dimonium ethyl phosphate, Sodium hydroxypropyl palm kernel acid sulfonate, Sodium hydroxypropyl phosphate decyl glucoside cross polymer, Sodium hydroxypropyl phosphate lauryl glucoside cross polymer, Sodium hydroxypropyl sulfonate coco glucoside cross polymer, Sodium hydroxypropyl sulfonate decyl glucoside cross polymer, Sodium hydroxypropyl sulfonate lauryl glucoside cross polymer, Sodium hydroxystearate, Sodium isostearate, Sodium isosteareth-6-carboxylate, Sodium isosteareth-11-carboxylate, Sodium isostearoamphoacetate, Sodium isostearoyl propionate, Sodium N-isostearoyl methyl taurate, Sodium laneth sulfate, Sodium lanolate, Sodium lardate, Sodium lauramido diacetate, Sodium lauraminopropionate, Sodium laurate, Sodium laureth-3-carboxylate, Sodium laureth-4-carboxylate, Sodium laureth-5-carboxylate, Sodium laureth-6-carboxylate, Sodium laureth-8-carboxylate, Sodium laureth-11-carboxylate,Sodium laures-12 carboxylate, sodium laures-13 carboxylate, sodium laures-14 carboxylate, sodium laures-16 carboxylate, sodium laures-17 carboxylate, sodium lauryl sulfate, sodium laures-5 sulfate, sodium laures-7 sulfate, sodium laures-8 sulfate, sodium laures-12 sulfate, sodium laures-40 sulfate, sodium laures-7 tartrate, sodium lauriminodipropionate, sodium lauroamphoacetate, sodium lauroamphohydroxypropylsulfonate, sodium lauroampho PG-acetate phosphate, sodium lauroamphopropionate, sodium lauroyl aspartate, sodium lauroyl collagen amino acid, sodium lauroyl glycine propionate, sodium lauroyl hydrolyzed collagen, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropylsulfonate, sodium lauroyl isothionate, sodium lauroyl methylaminopropionate, sodium lauroyl methylisothionate, sodium lauroyl millet amino acid, sodium lauroyl myristoyl aspartate, sodium lauroyl oat amino acid, sodium lauroyl sarcosine, sodium lauroyl silk amino acid, sodium lauroyl taurine, sodium lauroyl wheat amino acid, sodium lauryldiethylenediaminoglycine, sodium lauryl glucose carboxylate, sodium lauryl glucoside hydroxypropyl phosphate, sodium lauryl glucoside hydroxypropylsulfonate, sodium lauryl glycol carboxylate, sodium lauryl hydroxyacetamide sulfate, sodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfacetate, sodium linoleate, sodium macadamiate, sodium mango amphoacetate, sodium mango seed, sodium MEA laures-2 sulfosuccinate, sodium methoxy PPG-2 acetate, sodium methylcocoyl taurine, sodium methyl lauroyl taurine, sodium methyl myristoyl taurine, sodium methyl oleoyl taurine, sodium methyl palmitoyl taurine, sodium methyl stearoyl taurine, sodium methyl 2-sulfolaurate,Sodium 2-sulfopalmitate, Sodium methyltaurate isopalmitamide, Sodium methyltaurate cocoyl methyltaurate, Sodium myreth sulfate, Sodium myristate, Sodium myristoamphoacetate, Myristoyl glutamate, Sodium, sodium myristoyl hydrolyzed collagen, sodium myristoyl isethionate, sodium myristoyl sarcosinate, sodium nonoxynol-6 phosphate, sodium myristoyl-9 phosphate, sodium nonoxynol-1 sulfate, sodium nonoxynol-3 sulfate, sodium nonoxynol-4 sulfate, sodium nonoxynol-6 sulfate, sodium nonoxynol-8 sulfate, sodium nonoxynol-10 sulfate, sodium nonoxynol-25 sulfate, sodium octoxynol-2 ethane sulfonate, sodium octoxynol-2 sulfate, sodium octoxynol-6 sulfate, sodium octoxynol-9 sulfate, sodium oleate, sodium oleoamphoacetate, sodium oleoamphohydroxypropyl sulfonate, sodium oleopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl sodium oleoyl methyl isethionate, sodium oleyl sulfate, sodium olivamphoacetate, sodium olivate, sodium oligoyl glutamate, sodium sodipalmamphoacetate, sodium palmitate, sodium palm glyceride sulfonate, sodium palmitate, sodium palmitoyl hydrolyzed collagen, sodium palmitoyl hydrolyzed wheat protein, sodium palmitoyl sarcosinate, sodium palm kernelate, sodium palm kernel isethionate, sodium palmoil glutamate, sodium peanut amphoacetate, sodium peanutate, sodium PEG-6 cocamidocarboxylate, sodium PEG-8 cocamidocarboxylate, sodium PEG-4 cocamidosulfate, sodium PEG-3 lauramidocarboxylate, sodium PEG-4 lauramidocarboxylate, sodium PEG-8 palm glyceride carboxylate, pentaerythrityl hydroxypropyl lmino-diacetate dendrimer sodium, sodium propoxypPG-2 acetate, sodium rapeseed acetate, sodium ricinoleate, sodium ricinoleoamphoacetate, sodium rosehip amphoacetate, sodium rosin acid, sodium safflower acid, sodium saffraloyl hydrolyzed soy protein, sodium sesame seed acid, sodium sesamphoacetate, sodium cibotteran amphoacetate,Sodium soyaate, hydrolyzed soy collagen, sodium stearate, sodium stearoamphoacetate, sodium stearoamphohydroxypropylsulfonate, sodium stearoamphopropionate, sodium stearoyl caseinate, sodium stearoyl glutamate, sodium stearoyl hyaluronate, sodium stearoyl hydrolyzed collagen, sodium stearoyl hydrolyzed corn protein, sodium stearoyl hydrolyzed silk, sodium stearoyl hydrolyzed soy protein, sodium stearoyl hydrolyzed wheat protein, sodium stearoyl lactalbumin, sodium stearoyl methylisothionate, sodium stearoyl oat protein, sodium stearoyl pea protein, sodium stearoyl soybean protein, sodium stearyldimethyl glycine, sodium stearyl sulfate, sodium sunflower seed amphoacetate, sodium surfactin, sodium sweet almond amphoacetate, sodium sweet almondate, sodium tara amphopropionate, sodium tarate, sodium tara amphoacetate, sodium tara sulfate, sodium tamanset, sodium taurate, sodium taurocholyl methyltaurine, sodium lauroyl taurine, sodium / TEA-lauroyl collagen amino acids, sodium / TEA-lauroyl hydrolyzed collagen, sodium / TEA-lauroyl hydrolyzed keratin, sodium / TEA-lauroyl keratin amino acids, sodium / TEA-undecylenoyl collagen amino acids, sodium / TEA-undecylenoyl, sodium / TEA-undecylenoyl hydrolyzed corn protein, sodium / TEA-undecylenoyl hydrolyzed soy protein, sodium / TEA-undecylenoyl hydrolyzed wheat protein, sodium theobroma grandiflorum seedate, sodium trideceth-3 carboxylate, sodium trideceth-4 carboxylate, sodium trideceth-6 carboxylate, sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate, sodium trideceth-19 carboxylate, sodium trideceth sulfate,Sodium tridecylbenzenesulfonate, Sodium tridecylsulfate, Sodium trimehtylolpropane hydroxypropyliminodiacetate dendrimer, Sodium undeces-5-carboxylate, Sodium undecylbenzoate, Sodium undecylenamphoacetate, Sodium undecylenamphopropionate, Sodium undecylenoylglutamate, Sodium wheat germ amphoacetate, Sorves-160 tristearate, Soy acid, Oxidized soyamidopropylamine, Soyamidopropyl betaine, Soybean oil glyceryl 8 ester stearamidopropylamine oxide, Stearamidopropyl betaine, Stearamine oxide, Steareth-15, Steareth-16, Steareth-20, Steareth-21, Steareth-25, Steareth-27, Steareth-30, Steareth-40, Steareth-50, Steareth-80, Steareth-100, Steareth-2 phosphate, Steareth-3 phosphate, Stearic acid, Stearoxypropyltrimonium chloride, Stearoylglutamic acid, Stearoylsarcosine, Stearyl betaine, Stearyldimonium hydroxypropyl butyl glucoside chloride, Stearyldimonium hydroxypropyl decyl glucoside chloride, Stearyldimonium hydroxypropyl lauryl glucoside chloride, Sulfated castor oil, Sodium sulfated undeces-19-carboxylate, Sodium tridecylsulfate, Sodium tridecylbenzenesulfonate, Sodium tridecylsulfate, Sodium trimehtylolpropane hydroxypropyliminodiacetate dendrimer, Sodium undeces-5-carboxylate, Sodium undecylbenzoate, Sodium undecylenamphoacetate, Sodium undecylenamphopropionate, Sodium undecylenoylglutamate, Sodium wheat germ amphoacetate, Sorves-160 tristearate, Soy acid, Oxidized soyamidopropylamine, Soyamidopropyl betaine, Soybean oil glyceryl 8 ester stearamidopropylamine oxide, Stearamidopropyl betaine, Stearamine oxide, Steareth-15, Steareth-16, Steareth-20, Steareth-21, Steareth-25, Steareth-27, Steareth-30, Steareth-40, Steareth-50, Steareth-80, Steareth-100,Stearyl-2-phosphate, stearyl-3-phosphate, stearic acid, stearoxypropyltrimonium chloride, stearoylglutamic acid, stearoylsarcosine, stearyl betaine, stearyldimonium hydroxypropyl butyl glucoside chloride, stearyldimonium hydroxypropyl decyl glucoside chloride, stearyldimonium hydroxypropyl lauryl glucoside chloride, sulfated castor oil, sulfated coconut oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower amide MEA, sunflower seed oil fatty acid, sunflower seed oil amide propyl hydroxyethyl dimonium chloride, sunflower seed oil glyceryl esters-8, tall oil fatty acid, tallow acid, tallow amide propyl amine oxide, tallow amide propyl betaine, tallow amide propyl hydroxysultaine, tallow amine oxide, tallow betaine, tallow dihydroxyethyl betaine, tallowoyl ethyl glucoside, TEA-abietoyl hydrolyzed collagen, TEA-C 12-14 Alkyl phosphate, TEA-C 10-15 Alkyl sulfate, TEA-C 11-15 Alkyl sulfate, TEA-C 12-13 Alkyl sulfate, TEA-C 12-14 Alkyl sulfate, TEA-C 12-15Alkyl sulfate, TEAC14 - 17 alkyl sex sulfonate, TEA - canolate, TEA - cocamidodiacetate, TEA - cocoate, TEA - cocosulfate, TEA - cocoyl alaninate, TEA - cocoyl glutamate, TEA - cocoyl glycinate, TEA - cocoyl hydrolyzed collagen, TEA - cocoyl protein, TEA - cocoyl sarcosinate, TEA dimethicone PEG - 7 phosphate, TEA dodecylbenzene sulfonate, hydrogenated cocoate, TEA hydrogenated tallowoyl glutamate, TEA rosinoleate, TEA rosinoyl highly degraded collagen, TEA lauraminopropionate, TEA laurate, TEA laurate / mystate, TEA lauryl sulfate, TEA lauroyl collagen amino acid, TEA - lauroyl glutamate, TEA - lauroyl hydrolyzed collagen, TEA - lauroyl keratin amino acid, TEA - lauroyl methylaminopropionate, TEA - lauroyl / myristoyl aspartic acid, TEA lauroyl sarcosinate, TEA lauryl phosphate, TEA lauryl sulfate, TEA myristoaminopropionate, TEA myristate, TEA myristoyl hydrolyzed collagen, TEA oleate, hydrolyzed collagen, TEA oleoyl sarcosinate, TEA oleyl sulfate, TEA palmitate, TEA palm kernel sarcosinate, TEA cocamidosulfate, TEA rosinic acid, TEA stearate, TEA talic acid, TEA lidecylbenzenesulfonate, TEA undecylenate, hydrolyzed collagen, tetramethyldecenediol, tetrasodium dicarboxyethyl stearyl sulfosuccinamate, TIPA - lauryl sulfate, TIPA - lauryl sulfate, TIPA - mystate, TIPA - stearate, tocopheryl phosphate, trehalose undecylenate, TM - C 12-15 Pares - 2 phosphate, TM - C 12-15 Pares - 6 phosphate, TM - C 12-15 Pares - 8 phosphate, TM - C 12-15Paleth-10 phosphate, Trideceth-20, Trideceth-50, Trideceth-3 carboxylic acid, Trideceth-4 carboxylic acid, Trideceth-7 carboxylic acid, Trideceth-8 carboxylic acid, Trideceth-15 carboxylic acid, Trideceth-19 carboxylic acid, Trideceth-10 phosphate, Tridecylbenzene sulfonic acid, Trilauryl citrate-9, Trimethylolpropane hydroxypropyl bis-hydroxyethylamine dendrimer, Lauroampho PG-acetate chloride trisodium phosphate, Undecanoic acid, Undeceth-5 carboxylic acid, Undecylenamide propylamine oxide, Undecylenamide propyl betaine, Undecylenic acid, Undecylenoyl collagen amino acid, Undecylenoyl glycine, Undecylenoyl hydrolyzed collagen, Undecylenoyl wheat amino acid, Undecyl glucoside, Wheat germ acid, Wheat germ amide propylamine oxide, Wheat germ amide propyl betaine, Yucca Schidigera leaf / root / stem extract, Yucca Schidigera stem extract, Zinc coco sulfate, Zinc cocosulfate.

[0042] Preferably, it is at least one compound selected from the group consisting of sodium lauryl sulfate, cocamidopropyl betaine, sodium cocoamphoacetate, coco glucoside, and ammonium lauryl sulfosuccinate.

[0043] The content ratio of the surfactant in the preparation may be 0.1-10% by weight based on the preparation, and preferably 0.5-5% by weight.

[0044] Oil body Suitable oil bodies forming the components of the O / W emulsion are, for example, gel bett alcohols based on fatty alcohols having 6-18, preferably 8-10 carbon atoms, linear C6-C 22 -fatty acids and linear or branched C6-C 22 -esters of fatty acids or branched C6-C 13 -carboxylic acids and linear or branched C6-C 22- It is an ester of fatty acids. For example, myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl behenate, behenyl erucate, behenyl myristate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, ethyl erucate, ethyl myristate, ethyl palmitate, ethyl stearate, ethyl isostearate, ethyl oleate, ethyl behenate and ethyl erucate. Also, esters of linear C6-C 22 fatty acids with branched alcohols, especially 2-ethylhexanol, C 18 -C 38 -alkyl hydroxycarboxylic acids with linear or branched C6-C 22 -aliphatic alcohols, especially dioctyl malate, esters of linear and / or branched fatty acids with polyhydric alcohols (e.g., propylene glycol, dimer diol or trimer triol) and / or gelbet alcohols, C6-C 10 - triglycerides based on fatty acids, C6-C 18 - liquid mono / di / triglyceride mixtures based on fatty acids, C6-C 22 esters of fatty alcohols and / or gelbet alcohols with aromatic carboxylic acids, especially benzoic acid, C2-C 12- Esters of dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C6-C 22 - Aliphatic alcohol carbonates, such as dicaprylyl carbonate (Cetiol® CC), gelbetocarbonates based on fatty alcohols having 6 to 18, preferably 8 to 10 carbon atoms, benzoic acid and linear and / or branched C6-C 22 - Esters with alcohols (e.g., Finsolv® TN), linear or branched, symmetric or asymmetric dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as dicaprylyl ether (Cetiol® OE), ring-opening products of epoxidized fatty acid esters and polyols, silicone oils (cyclomethicone, silicone methicone grade, etc.) and / or aliphatic or naphthenic hydrocarbons, such as squalane, squalene or dialkylcyclohexane, etc., are also suitable.

[0045] Emulsifier Other non-ionic or cationic surfactants can also be added to the formulation as emulsifiers, for example, the following ones can be mentioned. · Linear C 8-22 Fatty alcohols, C 12 - C 22 Fatty acids, and addition products of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to alkylphenols containing 8 to 15 carbon atoms in the alkyl group, · C12 / 18 fatty acid monoesters and diesters which are addition products of 1 to 30 mol of ethylene oxide to glycerol, · Glycerol mono- and diesters of saturated and unsaturated fatty acids having 6 to 22 carbon atoms, sorbitan mono- and diesters and their ethylene oxide addition products, · Addition products of 15 to 60 mol of ethylene oxide to castor oil and / or hydrogenated castor oil, · Polyol esters, especially polyglycerol esters such as polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimereate isostearate, and mixtures of several compounds of these classes are also suitable. · Addition products of 2 - 15 mol of ethylene oxide to castor oil and / or hydrogenated castor oil, · Partial esters based on linear, branched, unsaturated or saturated C6 / 22 fatty acids, ricinoleic acid and 12 - hydroxy stearic acid with glycerol, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (e.g., sorbitol), alkyl glucosides (e.g., methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (e.g., cellulose), · Mono - di - and trialkyl phosphates, and mono - di - and / or tri - PEG - alkyl phosphates and their salts, · Wool wax alcohol, · Polysiloxane / polyalkyl polyether copolymers and corresponding derivatives, · Mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohols and / or C 6-22 Mixed esters of fatty acids, methyl glucose and polyols (preferably glycerol or polyglycerol), · Polyalkylene glycols, and · Glycerol carbonate.

[0046] Addition products of ethylene oxide and / or propylene oxide to fatty alcohols, fatty acids, alkyl phenols, glycerol mono - and diesters, sorbitan mono - and diesters, or addition products to castor oil are known as commercial products. These are homologous mixtures where the average degree of alkoxylation corresponds to the ratio of the amount of ethylene oxide and / or propylene oxide performing the addition reaction to the substrate. C 12 / 18Fatty acid monoesters and diesters are known as lipid layer enhancers for cosmetic formulations. Preferred emulsifiers will be described in more detail as follows.

[0047] Partial glyceride Typical examples of suitable partial glycerides are monoglyceryl hydroxystearate, diglyceryl hydroxystearate, monoglyceryl isostearate, diglyceryl isostearate, monoglyceryl oleate, diglyceryl oleate, monoglyceryl ricinoleate, diglyceryl ricinoleate, monoglyceryl linoleate, diglyceryl linoleate, monoglyceryl linolenate, diglyceryl linolenate, monoglyceryl erucate, diglyceryl erucate, monoglyceryl tartrate, diglyceryl tartrate, monoglyceryl citrate, diglyceryl citrate, monoglyceryl malate, diglyceryl malate and technical mixtures thereof (which may still contain small amounts of triglycerides from the manufacturing process). Also suitable are addition products of 1 - 30, preferably 5 - 10 mol of ethylene oxide to the partial glycerides mentioned.

[0048] Sorbitan ester Suitable sorbitan esters are sorbitan monoisostearate, sorbitan sesquisoisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoelicate, sorbitan sesquielicate, sorbitan monoelicate, sorbitan sesquielicate, sorbitan, sorbitan trilinoleate, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan monocitrate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate and their technical mixtures. Also suitable are the addition products of 1 - 30, preferably 5 - 10 mol of ethylene oxide to the above sorbitan esters.

[0049] Polyglycerol ester Typical examples of suitable polyglycerol esters include polyglyceryl-2 dipolyhydroxystearate (Dehymuls™ PGPH), polyglycerin-3-diisostearate (Lameform™ TGI). Polyglyceryl-4 isostearate (Isolan™ GI34), polyglyceryl-3 oleate, polyglyceryl-3 diisostearate (Isolan™ PDI), polyglyceryl-3 methylglucose distearate (Tego Care™ 450). Polyglyceryl-3 beeswax (CeraBellina™), polyglyceryl-4 caprylate (Polyglycerol Caprate T2010 / 90), polyglyceryl-3 cetyl ether (Chimexane™ NL), polyglyceryl-3 distearate (Cremophor™ GS32) and polyglyceryl ricinoleate (Admul™ WOL1403), polyglyceryl dimer isostearate and mixtures thereof. Examples of other suitable polyesters include those obtained by optionally reacting trimethylolpropane or pentaerythritol with lauric acid, coconut fatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid, etc. in mono-, di-, triesters with 1-30 mol ethylene oxide.

[0050] Tetraalkylammonium salt Cationic surfactants dissociate in aqueous solution to form a hydrophobic polymer group necessary for the surface activity of cations. As an important representative of cationic surfactants, a group of tetraalkylammonium salts of the general formula can be mentioned. (R 1 R 2 R 3 R 4 N + ) X - . Here, R1 represents C1-C8 alkyl (alkenyl), R 2 , R 3 and R 4Each independently represents a radical of an alkyl(alkenyl) having 1 to 22 carbon atoms. X is a counter ion, preferably selected from the group consisting of halides, alkyl sulfates and alkyl carbonates. A cationic surfactant in which the nitrogen group is substituted with two long acyl groups and two short alkyl(alkenyl) groups is particularly preferred.

[0051] Esterquat A further class of cationic surfactants that are particularly useful as co-surfactants in the present invention is represented by so-called ester quats. The esters are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by relevant methods of preparative organic chemistry. In this regard, reference is made to International Publication WO91 / 01295A1. According to this, triethanolamine is partially esterified with a fatty acid in the presence of hypophosphorous acid, air is passed through the reaction mixture, and then the whole is quaternized with dimethyl sulfate. Ethylene oxide. Further, German Patent DE4308794C1 describes a method for producing solid ester quats in which the quaternization of triethanolamine esters is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0052] Typical examples of esterquats suitable for use according to the present invention are products in which the acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, where RCO is an acyl group containing from 6 to 10 carbon atoms and the amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid, and technical mixtures thereof, such as so-called head fraction fatty acids. It is preferred to use esterquats in which the acyl component is derived from monocarboxylic acids containing 8 - 10 carbon atoms. Other esterquats are those in which the acyl component is derived from dicarboxylic acids such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, preferably adipic acid. Overall, esterquats derived from mixtures of monocarboxylic acids containing from 6 to 22 carbon atoms and adipic acid are preferably used. The molar ratio of mono- and dicarboxylic acids in the final esterquat can range from 1:99 to 99:1, preferably from 50:50 to 90:10, more specifically from 70:30 to 80:20. In addition to quaternized fatty acid triethanolamine esters salts, other suitable esterquats are quaternized ester salts of mono- / dicarboxylic acids and diethanolalkylamines or 1,2-dihydroxypropyldialkylamines. Esterquats can be obtained from fatty acids or from the corresponding triglycerides which are mixtures with the corresponding dicarboxylic acids. One of the processes representative of the related prior art is proposed in European Patent EP0750606B1. To produce the quaternized ester, a mixture of mono- and dicarboxylic acids and triethanolamine (based on the available carboxyl functions) can be used in a molar ratio of 1.1:1 - 3:1. Considering the performance characteristics of the estercut, a ratio of 1.2:1 - 2.2:1, preferably 1.5:1 - 1.9:1 has proven to be particularly advantageous. Preferred esterquats are technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 - 1.9.

[0053] Superfatting agent and consistency factor The defatting agent can be selected from substances such as lanolin and lecithin, and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides, and fatty acid alkanolamides. Fatty acid alkanolamides also serve as foam stabilizers.

[0054] The consistency factors mainly used are fatty alcohols or hydroxy fatty alcohols containing 12 to 22, preferably 16 to 18 carbon atoms, as well as partial glycerides, fatty acids, or hydroxy fatty acids. Combinations of these substances with alkyl oligoglucosides and / or fatty acid N-methyl glucamides and / or polyglycerol poly-12-hydroxystearate of the same chain length are preferably used.

[0055] Thickener and rheology additive Suitable thickeners include polymeric thickeners such as Aerosil (trademark) type (hydrophilic silica), polysaccharides, especially xanthan gum, guar gum, agar agar, alginates, and tylose, carboxymethyl cellulose and hydroxyethyl cellulose, as well as relatively high molecular weight polyethylene glycol monoesters and diesters of fatty acids. Examples include polyacrylates (such as Carbopols (trademark) [Goodrich] or Synthalens (trademark) [Sigma]), polyacrylamides, polyvinyl alcohol, and polyvinylpyrrolidone, such as ethoxylated fatty acid glycerides, esters of fatty acids and polyols (such as pentaerythritol or trimethylolpropane), narrow-range fatty alcohol ethoxylates, and surfactants such as electrolytes (such as sodium chloride and ammonium chloride).

[0056] Polymer Suitable cationic polymers include, for example, cationic cellulose derivatives such as quaternized hydroxyethyl cellulose available from Amerchol under the name Polymer JR400 (trademark), cationic starch, copolymers of diallyl ammonium salts and acrylamide, quaternized vinyl pyrrolidone / vinyl imidazole polymers such as Luviquat (trademark) (BASF), condensates of polyglycols and amines, quaternized collagen polypeptides such as lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat (trademark) L, Grunau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers such as amodimethicone, copolymers of adipic acid and dimethylaminohydroxypropyl diethylenetriamine (Cartaretine (trademark) Sandoz), copolymers of acrylic acid and dimethyldiallylammonium chloride (Merquat (trademark) 550, Chemviron), polyaminopolyamides and their crosslinked water-soluble polymers, cationic chitin derivatives such as quaternized chitosan (optionally with a microcrystalline distribution), condensates of dihaloalkyls such as dibromobutane and bis-dialkylamines such as bis-dimethylamino-1,3-propane, cationic guar gums such as Celanese's Jaguar (trademark) CBS, Jaguar (trademark) C-17, Jaguar (trademark) C-16, etc., quaternary ammonium salt polymers such as Milano's Mirapol (trademark) A-15, Mirapol Mirapol (trademark) AD-1, Mirapol (trademark) AZ-1, and various polyquaternium types (such as 6, 7, 32, 37, etc.) of polymers commercially available under the trade names Rheocare (trademark) CC and Ultragel (trademark) 300, etc.

[0057] Suitable anionic, zwitterionic, amphoteric and nonionic polymers are, for example, vinyl acetate / crotonic acid copolymers, vinyl pyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / maleic anhydride copolymers and their esters, uncrosslinked and polyol-crosslinked polyacrylic acids, acrylamidopropyltrimethylammonium chloride / acrylate copolymers, octyl acrylamide / methyl methacrylate / butylaminoethyl methacrylate / hydroxypropyl methacrylate copolymers, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymers, vinyl pyrrolidone / dimethylaminoethyl methacrylate / vinyl caprolactam terpolymers, and optionally derivatized cellulose ethers and silicones.

[0058] Pearl wax Suitable pearl waxes are, for example, alkylene glycol esters, especially ethylene glycol distearate; fatty acid alkanolamides, especially coco fatty acid diethanolamide; partial glycerides, especially stearic acid monoglyceride; esters of polybasic, optionally hydroxylated carboxylic acids with fatty alcohols containing 6 - 22 carbon atoms, especially long-chain esters of tartaric acid, fatty compounds such as fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, containing in total at least 24 carbon atoms, especially lauron and distearyl ether; fatty acids such as stearic acid, hydroxystearic acid or behenic acid, ring-opening products of olefin epoxides having 12 - 22 carbon atoms with fatty alcohols having 12 - 22 carbon atoms and / or polyols having 2 - 15 carbon atoms and 2 - 10 hydroxyl groups, and mixtures thereof.

[0059] Silicone Suitable silicones can be selected from the group consisting of: acetylmethylsilanol mannurate, acetylmethionylmethylsilanol elastonate acrylate / behenyl, acrylate / dimethicone methacrylate copolymer, acrylate / behenyl methacrylate / dimethicone methacrylate copolymer, acrylates / bishydroxypropyl dimethicone crosspolymer, acrylates / dimethicone copolymer, acrylates / dimethyl silicone methacrylate / ethylhexyl acrylate copolymer, acrylates / dimethylconol acrylate copolymer, acrylates / ethylhexyl methacrylate / dimethyl silicone methacrylate copolymer, acrylates / octylacrylamide / diphenyl amodimethicone copolymer, acrylates / polytrimethylsiloxymethacrylate copolymer, acrylates / propyltrimethicone methacrylate copolymer, acrylates / stearyl acrylate / dimethicone methacrylate copolymer, acrylates / tridecyl acrylate / triethoxysilylpropyl methacrylate / dimethicone methacrylate copolymer, acrylates / trifluoropropyl methacrylate / polytrimethylsiloxymethacrylate copolymer, aminobispropyl dimethicone, aminoethylaminopropyl dimethicone, aminopropyl dimethicone, aminopropyl phenyltrimethicone, aminopropyltriethoxysilane, dimethicone PEG-7 ammonium sulfate, amodimethicone, amodimethicone hydroxystearate, amodimethicone / silsesquioxane copolymer, ascorbyl carboxydecyltrisiloxane, ascorbylmethylsilanol pectin, behenoxy dimethicone, behentrimonium dimethicone PEG-8 phthalate, behenyldimethicone, bisamino PEG / PPG-41 / 3 aminoethyl PG-propyl dimethicone, bisaminopropyl / ethoxyaminopropyl dimethicone, bis(butylbenzoate) diaminotriazine aminopropyltrisiloxane, bis-butyl dimethicone polyglyceryl-3, bisbutyloxy amodimethicone / PEG-60 copolymer, bis(C 13-15 alkoxy)hydroxybutyramide amodimethicone, bis(C 13-15(Alkoxy)PG-Amodimethicone, Bis-(C1-8 Alkyl Lauroyl Lysine Decylcarboxamide) Dimethicone, Bis-Cetyl Cetyl·Dimethicone, Bis-Cetyl / PEG-8 Cetyl Dimethicone, Bis-Diphenylethyl Disiloxane, Bis-Ethylethyl Methicone, Bis-Glucamide Ethylaminopropyl Dimethicone, Bis-Hydrogen Dimethicone, Bis-Hydroxyethoxypropyl Dimethicone Bis-Hydroxylauryl Dimethicone / IPDI Copolymer Bis-Hydroxy / Methoxy Amodimethicone Behenic Acid Bis-Hydroxypropyl Dimethicone Bis-Hydroxypropyl Dimethicone / SMDI Copolymer, Bis-Isobutyl PEG-14 / Amodimethicone Copolymer, Bis-Isobutyl PEG-15 / Amodimethicone Copolymer, Bis-Isobutyl PEG / PPG-20 / 35 / Amodimethicone Copolymer, Bis-Isobutyl PEG / PPG-10 / 7 / Dimethicone Copolymer, Bis-Isobutyl PEG-24 / PPG-7 / Dimethicone Copolymer, Bis-PEG-1 Dimethicone, Bis-PEG-4 Dimethicone, Bis-PEG-8 Dimethicone, Bis-PEG-12 Dimethicone, Bis-PEG-20 Dimethicone, Bis-PEG-12 Dimethicone Beeswax, Bis-PEG-12 Dimethicone Candelilla Wax, Bis-PEG-15 Dimethicone / IPDI Copolymer, Bis-PEG-15 Methyl Ether Dimethicone, Bis-PEG-18 Methyl Ether Dimethylsilane, Bis-PEG / PPG-14 / 14 Dimethicone, Bis-PEG / PPG-15 / 5 Dimethicone, Bis-PEG / PPG-18 / 6 Dimethicone, Bis-PEG / PPG-20 / 20 Dimethicone, Bis-PEG / PPG-16 / 16 PEG / PPG-16 / 16 Dimethicone, Bis-PEG / PPG-20 / 5 PEG / PPG-20 / 5 Dimethicone, Bis-Phenyl Hexamethicone, Bis-Phenylpropyl Dimethicone, Bis-Polyethylene Dimethicone, Bis-(Polyglyceryl-3 Oxypropyl) Dimethicone, Bis-(Polyglyceryl-7 Oxypropyl) Dimethicone, Bis-PPG-15 Dimethicone / IPDI Copolymer, Bis-(PPG-7 Undecene-21) Dimethicone, Bis-Stearyl Dimethicone, Bis-Trimethoxysilylethyl Tetramethyldisiloxyethyl Dimethicone, Bis-Vinyl Dimethicone, Bis-Vinyl Dimethicone / Dimethicone Copolymer,Borage seed oil PEG-7 dimethicone ester, butyl acrylate / 6-14 perfluoroalkyl ethyl acrylate / dimethyl silicone mercaptopropyl copolymer, butyl acrylate / hydroxypropyl dimethyl silicone copolymer, butyl acrylate / cyclohexyl methacrylate / ethylhexyl acrylate copolymer, butyl methacrylate dimethyl silicone / methyl methacrylate cross-polymer, t-butyldimethylsilyl grape seed extract, butyl polydimethylsiloxylethylene / propylene / vinyl norbornene copolymer, C 6-8 Alkyl C 3-6 Alkyl glucoside dimethicone, C 20-24 Alkyl dimethicone, C 24-28 Alkyl dimethicone, C 26-28 Alkyl dimethicone, C 30-45 Alkyl dimethicone, C 30-60 Alkyl dimethicone, C 32 Alkyl dimethicone, C 30-45 Alkyl dimethicone / polycyclohexene oxide cross-polymer, C 26-28 Alkyl dimethylsilyl polypropyl sesquioxane, C 30-45 Alkyl dimethylsilyl polypropyl sesquioxane, C 20-24 Alkyl methicone, C 24-28 Alkyl methicone, C 26-28 Alkyl methicone, C 30-45 Alkyl methicone, C 20-28 Alkyl perfluorodecyl ethoxydimethicone, C 26-54Alkyltetradecyldimethicone, caprylyldimethicone, caprylyldimethicone ethoxyglycoside, caprylylmethicone, carboxydecyltrisiloxane, castor oil bis-hydroxypropyl dimethicone ester cerityl dimethicone, cetearyldimethicone crosspolymer, cetearyldimethicone / vinyl dimethicone crosspolymer, cetearylmethicone, cetrimonium carboxydecyl PEG-8 dimethicone, cetrimonium dimethicone PEG-7 phthalate, cetyl behenyl dimethicone, cetyl dimethicone, cetyl dimethicone / bisvinyl dimethicone crosspolymer, cetyl hexacosyldimethicone, cetoxy dimethicone, cetyl PEG-8 dimethicone, cetyl PEG / PPG-15 / 15 butyl ether dimethicone, cetyl PEG / PPG-7 / 3 dimethicone, cetyl PEG / PPG-10 / 1 dimethicone, cetyl triethylmonium dimethicone PEG-8 phthalate, cetyl triethylmonium dimethicone PEG-8 succinate, acetyl tyrosine copper methanol, PCA copper methanol, C4-14 perfluoroalkyl ethoxy dimethicone, cycloethoxymethicone, cycloheptasiloxane, cyclohexasiloxane, cyclomethicone, cyclopentasiloxane, cyclophenylmethicone, cyclotetrasiloxane, m-cyclovinylmethicone, cystine bis PG-propyl silanetrio, DEAPG-propyl PEG / PPG-18 / 21 dimethicone, diisostearoyl trimethylolpropane siloxysilicate, dilauroyl trimethylolpropane siloxysilicate, dilinoleamidopropyl dimethylamine dimethicone PEG-7 phosphate, dimethicone, dimethicone crosspolymer, dimethicone crosspolymer-3, dimethicone / di vinyl dimethicone / silsesquioxane crosspolymer, dimethicone ethoxyglycoside, dimethicone hydroxypropyltrimonium chloride, dimethicone / mercaptopropylmethicone copolymer, dimethicone PEG-15 acetate, dimethicone PEG-8 adipate, dimethicone PEG-7 avocadoate, dimethicone PEG-8 beeswax dimethicone PEG-8 benzoate, dimethicone PEG-8 borate, dimethicone PEG-7 cocoate, dimethicone PEG-10 crosspolymer, dimethicone PEG-10 / 15 crosspolymer,Dimethicone PEG-15 Crosspolymer, Dimethicone PEG-7 Isostearate, Dimethicone PEG-8 Isostearate, Dimethicone PEG-7 Lactate, Dimethicone PEG-8 Lanolate, Dimethicone PEG-8 Laurate, Dimethicone PEG-8 Meadowfoamate, Dimethicone PEG-7 Octyldodecyl Citrate, Dimethicone PEG-7 Olivate, Dimethicone PEG-8 Olivate, Dimethicone PEG-7 Phosphate, Dimethicone PEG-8 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG-7 Phthalate, Dimethicone PEG-8 Phthalate, Dimethicone PEG-8 Polyacrylate, Dimethicone PEG / PPG-20 / 23 Benzoate, Dimethicone PEG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG-12 / 4 Phosphate, Dimethicone PEG-7 Succinate, Dimethicone PEG-8 Succinate, Dimethicone PEG-7 Sulfate, Dimethicone PEG-7 Undecylenate, Dimethicone PG-Diethylmonium Chloride, Dimethicone / Phenylvinyl Dimethicone Crosspolymer, Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone / PPG-20 Crosspolymer, Dimethicone Propylene Diamine Behenate, Dimethicone Pyrrolidone Betaine, Dimethicone / Silsesquioxane Copolymer, Silylated Dimethicone, Dimethicone / Inyl Dimethicone Crosspolymer, Dimethicone / Vinyltrimethylsiloxysilicate Crosspolymer, Dimethiconol, Dimethiconol Arginine, Dimethiconol Beeswax, Dimethiconol Behenate, Dimethiconol Boric Acid, Dimethiconol Candelilla Acid, Dimethiconol Carnauba Acid, Dimethiconol Cysteine, Dimethiconol Dupabaterate, Fluoroalcohol Dilinoleic Acid Dimethiconol, Dimethiconol Hydroxystearate, Dimethiconol Lip Butter Acid, Dimethiconol / IPDI Copolymer, Dimethiconol Isostearate, Dimethiconol Kokum Butter Acid, Dimethiconol Lactate, Dimethiconol Meadowfoam Acid, Dimethiconol Methionine, Dimethicone PEG-7 Undecylenate, Dimethicone PG-Diethylmonium Chloride, Dimethicone / Phenylvinyl Dimethicone Crosspolymer, Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone / PPG-20 Crosspolymer,Dimethicone propylene diamine behenate, Dimethicone copolyol PG-betaine, Dimethicone / silsesquioxane copolymer, Silylated dimethicone, Dimethicone / vinyl dimethicone cross polymer, Dimethicone / vinyl trimethylsiloxysilicate cross polymer, Dimethiconol, Dimethiconol arginine, Dimethiconol beeswax, Dimethiconol behenate, Dimethiconol boric acid, Dimethiconol candelilla wax acid, Dimethiconol carnauba wax acid, Dimethiconol cysteine, Dimethiconol dupabate, Fluoroalcohol dilinoleic acid dimethiconol, Dimethiconol hydroxystearate, Dimethiconol lip butter acid, Dimethiconol / IPDI copolymer, Dimethiconol isostearate, Dimethiconol kokum butter acid, Dimethiconol lactate, Dimethiconol meadowfoam acid, Methionine, Dimethiconol / methylsilanol / silicate cross polymer, Dimethiconol moa butter acid, Panthenol, Dimethiconol sal butter acid, Dimethiconol / silica cross polymer, Dimethiconol / silsesquioxane copolymer, Dimethiconol stearate, Dimethiconol / stearyl, Methicone / phenyl trimethicone copolymer, Dimethoxysilyl ethylene diamine propyl dimethicone, Dimethylamine propyl amide PCA dimethicone, Dimethyloxobenzodioxasilane, Hyaluronic acid dimethylsilanol, Dioleyl tocopheryl methylsilanol, Diphenyl amodimethicone, Diphenyl dimethicone, Diphenyl dimethicone cross polymer, Diphenyl dimethicone / silsesquioxane cross polymer, Diphenyl ethyl benzyl oxy disiloxane, Diphenyl isopropyl dimethicone, Diphenyl siloxy phenyl / propyl trimethicone, Diphenyl siloxy phenyl trimethicone disiloxane, Amodimethicone disuccinamide disodium, PEG-12 dimethicone sulfosuccinate disodium, PEG-8 lauryl dimethicone sulfosuccinate disodium, Divinyl dimethicone / dimethicone copolymer, Divinyl dimethicone / dimethicone cross polymer, Drometrizole trisiloxane, Ethylhexyl acrylate / VP / dimethicone copolymer, Ethyl methicone, Ethyl trisiloxane, Fluoro C2-8 alkyl dimethicone,Gluconamidopropylaminopropyldimethicone, 4-(2-β-glucopyranosyloxy)propoxy-2-hydroxybenzophenone, Glyceryl undecyldimethicone, Glycidoxydimethicone, Hexadecylmethylsilicone, Hexyldimethylsilicone, Hexylmethylsilicone, Hexyltrimethoxysilane, Hydrogenated dimethicone, Hydrogen dimethicone / Octylsilsesquioxane copolymer, Hydrolyzed collagen PG-propyl dimethiconol, Hydrolyzed collagen PG-propylmethyl silanediol, Hydrolyzed collagen PG-propyl silanetriol, Hydrolyzed keratin PG-propylmethyl silanediol, Hydrolyzed sesame protein PG-propylmethyl silanediol, Hydrolyzed silk PG-propylmethyl silanediol, Hydrolyzed silk PG-propylmethyl silanediol cross polymer, Hydrolyzed soybean protein / Dimethicone PEG-7 acetate, Hydrolyzed soybean protein PG-propylmethyl silanediol, Hydrolyzed vegetable protein PG-propyl silanetrio, Hydrolyzed wheat protein / Cystine bis PG-propyl silanetrio copolymer, Hydrolyzed wheat protein / Dimethicone PEG-7 acetate, Hydrolyzed wheat protein / Dimethicone PEG-7 phosphate copolymer, Hydrolyzed wheat protein PG-propylmethyl silanediol, Hydrolyzed wheat protein PG-propyl silanetriol, Hydroxyethyl acetonium PG-dimethicone, Hydroxypropyl dimethicone, Hydroxypropyl dimethicone behenate, Hydroxypropyl dimethicone isostearate, Hydroxypropyl dimethicone stearate, Isobutyl methacrylate / Bis-hydroxypropyl dimethicone acrylate copolymer, Isobutyl methacrylate / Trifluoroethyl methacrylate / Bis-hydroxypropyl dimethicone acrylate copolymer, Isopentyl trimethoxysinnamate trisiloxane, Isopolyglyceryl-3 dimethicone, Isopolyglyceryl-3 dimethiconol, Isopropyl titanium triisostearate / Triethoxysilylethyl, Polydimethylsiloxyethyl dimethicone cross polymer, Isostearyl carboxydecyl PEG-8 dimethicone, Lactoyl methyl silanol elastinate, Lauryl dimethicone, Lauryl dimethicone PEG-15 cross polymer,Lauryl dimethicone PEG-10 phosphate, lauryl dimethicone / polyglycerin-3 copolymer, lauryl methicone, lauryl PEG-8 dimethicone, lauryl PEG-10 methyl ether dimethicone, lauryl PEG-9 polydimethylsiloxyethyl dimethicone, lauryl PEG / PPG-18 / 18 methicone, lauryl phenyl isopropyl methicone, lauryl phenyl propyl methicone, lauryl polydimethylsiloxyethyl dimethicone / bisvinyl dimethicone copolymer, lauryl polyglyceryl 3 polydimethylsiloxyethyl dimethicone, lauryl trimethicone, linoleamidopropyl PG-dimonium chloride phosphate dimethicone, methacryloylpropyl trimethoxysilane, methicone, methoxy amodimethicone / silsesquioxane copolymer, methoxy cinnamidopropyl polysilsesquioxane, methoxy cinnamylopropyl silsesquioxane silica, methoxy PEG-13 ethyl polysilsesquioxane, methoxy PEG / PPG-7 / 3 aminopropyl dimethicone, methoxy PEG / PPG-25 / 4 dimethicone, methoxy PEG-10 propyl trimethoxysilane, methyl urea PEG-8 dimethicone, methyl polysiloxane emulsion, methyl silanol acetyl methionate, methyl silanol acetyl tyrosine, methyl silanol ascorbic acid, methyl silanol acetyl methionate, methyl silanol acetyl tyrosine, methyl silanol ascorbic acid,Methylsilanol carboxymethyltheophylline, methylsilanol alginate, methylsilanol elastrate, methylsilanol glycyrrhizinate, methylsilanol hydroxyproline, methylsilanol hydroxyproline aspartate, methyls, Lanolmannuronic acid, Methylsilanol PCA, Methylsilanol PEG-7 Glyceryl Cocoate, Methylsilanol / Silica Crosspolymer, Methylsilanol Spilaminato, Methylsilanol TriPEG-8 Glyceryl Cocoate, Methyltrimethicone, Methyltrimethoxysilane, Myristylamidopropyl Dimethicone PEG-7 Phosphate, Myristylmethicone, Myristricyclosiloxane, Nylon 611 / Dimethicone Copolymer, PCA Dimethicone, PEG-7 Amodimethicone, PEG-8 Amodimethicone, PEG-8 Cetyl Dimethicone, PEG-3 Dimethicone, PEG-6 Dimethicone, PEG-7 Dimethicone, PEG-8 Dimethicone, PEG-9 Dimethicone, PEG-10 Dimethicone, PEG-12 Dimethicone, PEG-14 Dimethicone, PEG-17 Dimethicone, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-8 Dimethicone Dimer Dilinoate, PEG-8 Dimethicone / Dimer Dilinoate Copolymer, PEG-10 Dimethicone / Vinyl Dimethicone Crosspolymer, PEG-8 Distearyldimonium Chloride PG Dimethicone, PEG-10 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, PEG-8 Methicone, PEG-6 Acetate Methicone, PEG-6 Methyl Ether Dimethicone, PEG-7 Methyl Ether Dimethicone, PEG-8 Methyl Ether Dimethicone, PEG-9 Methyl Ether Dimethicone, PEG-10 Methyl Ether Dimethicone, PEG-11 Methyl Ether Dimethicone, PEG-32 Methyl Ether Dimethicone, PEG-8 Methyl Ether Triethoxysilane, PEG-10 Nonafluorohexyl Dimethicone Copolymer, PEG-4PEG-12 Dimethicone, PEG-8PG-Coco-Glucoside Dimethicone, PEG-9 Polydimethylsiloxyethyl Dimethicone, PEG / PPG-20 / 22 Butyl Ether Dimethicone, PEG / PPG-22 / 22 Butyl Ether Dimethicone, PEG / PPG-23 / 23 Butyl Ether Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-27 / 9 Butyl Ether Dimethicone, PEG / PPG-3 / 10 Dimethicone,PEG / PPG-4 / 12 Dimethicone, PEG / PPG-6 / 4 Dimethicone, PEG / PPG-6 / 11 Dimethicone, PEG / PPG-8 / 14 Dimethicone, PEG / PPG-8 / 26 Dimethicone, PEG / PPG-10 / 2 Dimethicone, PEG / PPG-12 / 16 Dimethicone 1, PEG / PPG-12 / 18 Dimethicone, PEG / PPG-14 / 4 Dimethicone, PEG / PPG-15 / 5 Dimethicone, PEG / PPG-15 / 15 Dimethicone, PEG / PPG-16 / 2 Dimethicone, PEG / PPG-16 / 8 Dimethicone, PEG / PPG-17 / 18 Dimethicone, PEG / PPG-18 / 6 Dimethicone, PEG / PPG-18 / 12 Dimethicone, PEG / PPG-18 / 18 Dimethicone, PEG / PPG-19 / 19 Dimethicone, PEG / PPG-20 / 6 Dimethicone, PEG / PPG-20 / 15 Dimethicone, PEG / PPG-20 / 20 Dimethicone, PEG / PPG-20 / 23 Dimethicone, PEG / PPG-20 / 29 Dimethicone, PEG / PPG-22 / 23 Dimethicone, PEG / PPG-22 / 24 Dimethicone, PEG / PPG-23 / 6 Dimethicone, PEG / PPG-25 / 25 Dimethicone, PEG / PPG-27 / 27 Dimethicone, PEG / PPG-30 / 10 Dimethicone, PEG / PPG-25 / 25 Dimethicone / Acrylate Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG / PPG-24 / 24 Methyl Ether Glycidoxy Dimethicone, PEG / PPG-10 / 3 Oleyl Ether Dimethicone, PEG / PPG-5 / 3 Trisiloxane, PEG-4 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trifluoropropyl Dimethicone Copolymer, PEG-10 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trisiloxane, Perfluorocaprylyl Ethoxysilyl Ethyl Methicone, Perfluorononyldimethylsilicone, Perfluorononyldimethylsilicone / Methicone / Amodimethicone Crosspolymer, Perfluorononyl Carboxydecyl Behenyl Dimethicone, Parfluorononyl Carboxydecyl Hexacosyl Dimethicone, Perfluorononyl Ethyl Carboxydecyl Lauryl / Behenyl Dimethicone, Perfluorononyl Ethyl Carboxydecyl Lauryl Dimethicone, Perfluorononyl Ethyl Carboxydecyl PEG-8 DimethiconePerfluorononyl ethyl carboxy decyl PEG-10 dimethicone, perfluorononyl ethyl dimethicone / methicone copolymer, perfluorononyl ethyl PEG-8 dimethicone, perfluorononyl ethyl stearyl dimethicone, perfluorooctyl ethyl / diphenyldimethylsilicone copolymer, perfluorooctyl ethyl triethoxysilane, perfluorooctyl ethyl trimethoxysilane, perfluorooctyl trisloxane, PG-aminodimethicone, phenethyl dimethicone, phenethyl disiloxane phenyl dimethicone, phenyl isopropyl dimethicone, phenyl methicone, phenyl methiconol, phenylpropyl dimethylsiloxysilicate, phenylpropyl ethyl methicone, phenylpropyl trimethicone, phenyl trimethicone / diphenyl methicone, phenyl trimethicone, platinum divinyldisiloxane, polyacrylate 6, polyether siloxane polydimethylsiloxyethyl dimethicone / bisvinyl dimethicone cross polymer, polydimethylsiloxyethyl dimethicone / methicone copolymer, polydimethylsiloxy PEG / PPG-24 / 19 butyl ether silsesquioxane, polydimethylsiloxy PPG-13 butyl ether silsesquioxane, polyglyceryl 3 disiloxane dimethicone, polyglyceryl-3 / lauryl polydimethylsiloxyethyl dimethicone cross polymer, polyglyceryl-3 polydimethylsiloxyethyl dimethicone, poly(glycol adipate) / bishydroxyethoxypropyl dimethicone copolymer, polymethyl silsesquioxane, polymethyl silsesquioxane / trimethylsiloxysilicic acid, polyphenyl silsesquioxane, polypropyl silsesquioxane, polysilicone-1, polysilicone-2, polysilicone-3, polysilicone-4, polysilicone-5, polysilicone-6, polysilicone-7, polysilicone-8, polysilicone-9, polysilicone-10, polysilicone-11, polysilicone-12, polysilicone-13, polysilicone-14, polysilicone-15, polysilicone-16, polysilicone-17, polysilicone-18, polysilicone-19, polysilicone-20, polysilicone-21, cetyl phosphate of polysilicone-18Polysilicone-1 Crosspolymer, Polysilicone-18 Stearate, Polyurethane-10, Dimethicone PEG-7 Potassium Pantothenate, Dimethicone PEG-7 Potassium Phosphate, PPG-12 Butyl Ether Dimethicone, PPG-2 Dimethicone, PPG-12 Dimethicone, PPG-27 Dimethicone, PPG-4 Oleth-10 Dimethicone, Propoxytrimethylpiperidinyl Dimethicone, Propyltrimethicone, Quaternium-80, Retinoxytrimethylsilane, Salicylic Acid Silanediol, Silanetriol, Silanetriol Alginate, Silanetriol Glutamate, Silanetriol Lysine, Silanetriol Melanin, Silanetriol Trehalose Ester, Silica, Silica Dimethicone Silylated Resin, Silica Dimethylsilylate, Silica Silylate, Silicon Carbide, Silicone Quaternium-1, Silicone Quaternium-2, Silicone Quaternium-2 Panthenol Adduct, Silicone Quaternium-3, Silicone Quaternium-4, Silicone Quaternium-5, Silicone Quaternium-6, PPG-4 Oleth-10 Dimethicone, Propoxytrimethylpiperidinyl Dimethicone, Propyltrimethicone, Quaternium-80, Retinoxytrimethylsilane, Salicylic Acid Silanediol, Silanetriol, Silanetriol Alginate, Silanetriol Glutamate, Silanetriol Lysine, Silanetriol Melanin, Silanetriol Trehalose Ester, Silica, Silica Dimethicone Silylated Resin, Silica Dimethylsilylate, Silica Silylate, Silicon Carbide, Silicone Quaternium-1, Silicone Quaternium-2, Silicone Quaternium-2 Panthenol Adduct, Silicone Quaternium-3, Silicone Quaternium-4, Silicone Quaternium-5, Silicone Quaternium-6, Silicone Quaternium-7, Silicone Quaternium-8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium-12, Silicone Quaternium-15, Silicone Quaternium-16, Silicone Quaternium-16 / Glycidoxy Dimethicone Crosspolymer, Silicone Quaternium-17, Silicone Quaternium-18, Silicone Quaternium-19, Silicone Quaternium-20Silicone Quaternium-21, Silicone Quaternium-22, Silicone Quaternium-24, Silicone Quaternium-25, Siloxanetriol Alginate, Siloxanetriol Phytate, Simethicone, Carboxydecyl PEG-8 Dimethicone Sodium, Dimethicone PEG-7 Acetylmethyl Taurine Sodium, Hyaluronic Acid Dimethylsilanol Sodium, Methylsilanol Lactate Sodium, Methylsilanol Mannuronate Cocosanol Sodium, PCA Sodium Methylsilanol, PG-Propyl Dimethicone Thioglycolic Acid Sodium Copolymer, PG-Propyl Thioglycolic Acid Dimethicone, Propoxyhydroxypropyl Thioglycolic Acid Sodium Silica, Sorbitol Silandiol, Soybean Chloride Triethoxysilylpropyl Dimonium, Stearconium Phthalate Dimethicone PEG-8, Stearamidopropyl Dimethicone, Stearimonium Hydroxypropyl Panthenyl PEG-7 Dimethicone Phosphate Chloride, Stearoxydimethicone, Stearoxymethicone / Dimethicone Copolymer, Stearoxytrimethylsilane, Stearylaminopropyl Methicone, Stearyldimethicone, Stearyl / Lauryl Methacrylate Crosspolymer, Stearylmethicone, Stearyl Triethoxysilane Nex, Stearyltrimethicone, Styrene / Acrylate / Dimethicone Acrylate Crosspolymer, Styrene / Acrylate / Dimethicone Copolymer, TEA-Dimethicone PEG-7 Phosphate, Tetrabutoxypropyl Trisiloxane, Tetramethylhexaphenyltetrasiloxane, Tetramethyltetraphenyltrisiloxane, Tocopheryl Oxypropyltrisiloxane, Trideceth-9 PG-Amodimethicone, Triethoxycaprylylsilane, Triethoxysilylethyl Dimethicone / Methicone Copolymer, Triethoxysilylethyl Polydimethylsiloxyethyl Dimethicone, Triethoxysilylethyl Polydimethylsiloxyethyl Hexyldimethicone, Triethoxysilyl Fluosilcarbamoylethoxypropyl·Butyldimethicone, Trifluoromethyl C 1-4Alkyl dimethicone, trifluoropropyl cyclopentasiloxane, trifluoropropyl cyclotetrasiloxane, trifluoropropyl dimethicone, trifluoropropyl dimethicone / PEG-10 copolymer, trifluoropropyl dimethicone / trifluoropropyl divinyldimethylsilicone cross-polymer, trifluoropropyl dimethicone / vinyltrifluoropropyl, dimethicone / silsesquioxane cross-polymer, trifluoropropyl dimethiconol, trifluoropropyl dimethyl / trimethylsiloxysilicic acid, trifluoropropyl methylsilicone, trimethoxycaprylylsilane, trimethoxysilyl dimethicone, trimethylpentaphenyltrisiloxane, trimethylsiloxyamidodimethicone, trimethylsiloxyphenyldimethicone, trimethylsiloxysilicic acid, trimethylsiloxysilicic acid / dimethicone cross-polymer, trimethylsiloxysilicic acid / dimethiconol cross-polymer, trimethylsiloxysilyl carbamoyl pullulan, trimethylsilyl hydrolyzed conchiolin PG-propylmethylsilanediol cross-polymer, trimethylsilyl hydrolyzed silk PG-propylmethylsilanediol cross-polymer, trimethylsilyl hydrolyzed wheat gluten PG-propylmethylsilanediol cross-polymer, trimethylsilyl pullulan, trimethylsiloxy glycolic acid trimethylsilyl, trimethylsiloxy lactic acid trimethylsilyl, trimethylsiloxy salicylic acid trimethyl, triphenyltrimethyltrisiloxane, tris-tributoxysiloxymethylsilane, undecyl acrylate dimethicone, vinyldimethicone, vinyldimethicone / lauryldimethicone cross-polymer, vinyldimethicone / methicone silsesquioxane cross-polymer, vinyldimethyl / trimethylsiloxysilicic acid stearyldimethicone cross-polymer, VP / dimethylconyl acrylate / polycarbamyl / polyglycol ester, carboxydecyl trisloxane zinc, dimethicone PEG-8 succinate zinc and mixtures thereof.

[0060] More preferably, the silicone contained in the mixture according to the present invention is dimethicone, cyclomethicone, phenyltrimethicone, cyclohexasiloxane, cyclopentasiloxane. A detailed overview of suitable volatile silicones is disclosed in Todd et al., Cosm. Toil. 91, 27 (1976).

[0061] Wax and stabilizer In addition to the natural oils used, waxes may also be present in the formulation, in particular natural waxes such as, for example, candelilla wax, carnauba wax, Japan wax, esparto grass wax, cork wax, guarma wax, rice bran wax, sugar cane wax, beeswax, montan wax, beeswax, shellac wax, spermaceti, lanolin (wool wax), scale fat, ceresin, ozokerite (earth wax), petrolatum, paraffin wax and micro wax, chemically modified waxes (hard waxes), for example montan ester wax, sasol wax, hydrogenated jojoba wax, synthetic waxes such as polyalkylene wax, polyethylene glycol wax and the like.

[0062] As stabilizers, for example, metal salts of fatty acids such as magnesium stearate, aluminum and / or zinc, ricinoleic acid can be used.

[0063] Primary sun protection factor The primary sunscreen factor referred to in the present invention is, for example, an organic substance (light filter) that is liquid or crystalline at room temperature, absorbs ultraviolet rays, and can release the absorbed energy in the form of long-wave radiation, for example heat.

[0064] The formulations according to the invention advantageously contain at least one UV-A filter and / or at least one UV-B filter and / or broadband filter and / or at least one inorganic pigment. The formulations according to the invention preferably contain at least one UV-B filter or broadband filter, more preferably at least one UV-A filter and at least one UV-B filter.

[0065] Preferred cosmetic compositions, preferred topical formulations according to the invention, contain one, two, three or more sun protection factors selected from the following groups: 4-aminobenzoic acid and its derivatives, salicylic acid derivatives, benzophenone derivatives, dibenzoylmethane derivatives, diphenylacrylate, 3-imidazol-4-yl acrylate and its esters, benzofuran derivatives, benzylidene malonate derivatives, polymeric UV absorbers containing one or more organosilicon radicals, cinnamic acid derivatives, camphor derivatives, trianilinino-s-triazine derivatives, 2-hydroxyphenylbenzotriazole derivatives, phenylbenzimidazole sulfonic acid derivatives and their salts, menthyl anthranilate, benzotriazole derivatives and indole derivatives.

[0066] Furthermore, it is advantageous to combine the compound of formula (I) with an active ingredient that penetrates the skin and protects skin cells from damage by sunlight from the inside and reduces the level of skin matrix metalloprotease. Preferred respective components, so-called aryl hydrocarbon receptor antagonists, are described in WO 2007 / 128723 which is incorporated herein by reference. Preferred is 2-benzylidene-5,6-dimethoxy-3,3-dimethylindan-1-one.

[0067] The UV filters cited below that can be used in the context of the present invention are preferred, but of course not limiting.

[0068] The preferably used UV filters are selected from the group consisting of the following. · p-aminobenzoic acid · Ethyl p - aminobenzoate ethoxylated (25 moles) (INCI name: PEG - 25 PABA) · 2 - Ethylhexyl p - dimethylaminobenzoate · N - propoxylated form of ethyl p - aminobenzoate (2 moles) · Glyceryl p - aminobenzoate · Homomenthyl salicylate (homosalate) (NeoHeliopan™ HMS) · 2 - Ethylhexyl salicylate (NeoHeliopan™ OS) · Triethanolamine salicylate · 4 - Isopropylbenzyl salicylate · Menthyl anthranilate (Neo Heliopan™ MA) · Diisopropyl ethyl cinnamate · 2 - Ethylhexyl p - methoxycinnamate (NeoHeliopan™ AV) · Diisopropyl methyl cinnamate · Isoamyl p - methoxycinnamate (NeoHeliopan™ E1000) · Diethanolamine salt of p - methoxycinnamic acid · Isopropyl p - methoxycinnamate · 2 - Phenylbenzimidazole sulfonic acid and its salts (NeoHeliopan™ Hydro) · 3 - (4’ - Trimethylammonium) benzylidene bornan - 2 - one methyl sulfate · β - Imidazole - 4(5) - acrylic acid (urocanic acid) · 3 - (4’ - Sulfo) benzylidene bornan - 2 - one and its salts · 3 - (4’ - Methylbenzylidene) - D,L - camphor (Neoheliopan MBC) · 3 - Benzylidene - D,L - camphor · N - [(2 and 4) - [2 - (Oxoborn - 3 - ylidenemethyl) benzyl]] acrylamide polymer · 4,4'-(6-4-(1,1-dimethyl)aminocarbonyl)phenylamino-1,3,5-triazine-2,4-diyl)diimino-bis-(benzoic acid-2-ethylhexyl ester) (Uvasorb™ HEB) · Benzylidene polysiloxane malonate (Parsol™ SLX) · Glyceryl dimethoxycinnamate ethylhexanoate · Dipropylene glycol salicylate · Tris(2-ethylhexyl)-4,4',4''-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate (= 2,4,6-trianiolino-(p-carbo-2'-ethylhexyl-1'-oxy)-1,3,5-triazine) (Uvinul™ T150).

[0069] In the preparation according to the invention, the broadband filter preferably combined with one or more compounds of formula (I) is selected from the group consisting of the following. · 2-Ethylhexyl-2-cyano-3,3-diphenylacrylate (Neo Heliopan™ 303). · Ethyl-2-cyano-3,3'-diphenylacrylate · 2-Hydroxy-4-methoxybenzophenone (Neo Heliopan™ BB) · 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid · Dihydroxy-4-methoxybenzophenone · 2,4-Dihydroxybenzophenone · Tetrahydroxybenzophenone · 2,2'-Dihydroxy-4,4'-dimethoxybenzophenone · 2-Hydroxy-4-n-octoxybenzophenone · 2-Hydroxy-4-methoxy-4'-methylbenzophenone · Sodium hydroxymethoxybenzophenone sulfonate · 2,2'-Dihydroxy-4,4'-dimethoxy-5,5'-disulfobenzophenone 2,2'-dimethoxy-5,5'-disulfobenzophenone · Phenol, 2-(2H-benzotriazol-2-yl)-4-methyl-6-(2-methyl-3(1,3,3,3-tetramethyl-1-(trimethylsilyl)oxy)disiloxyanilyl)propyl)(Mexoryl(trademark)XL · 2,2'-Methylenebis-(6-(2H-benzotriazol-2-yl)-4-1,1,3,3-tetramethylbutyl)phenol) (Tinosorb(trademark)M) · 2,4-Bis-4-(2-ethylhexyloxy)-2-hydroxyphenyl-1,3,5-triazine · 2,4-Bis-(4-(2-ethylhexyloxy)-2-hydroxyphenyl)-6-(4-methoxyphenyl)-1,3,5-triazine (Tinosorb(trademark)S) · 2,4-Bis-(4-(3-sulfonate)-2-hydroxypropyloxy)-2-hydroxyphenyl-6-(4-methoxyphenyl)-1,3,5-triazine sodium salt · 2,4-Bis-(3-(2-propynyloxy)-2-hydroxypropyloxy)-2-hydroxyphenyl-6-(4-methoxyphenyl)-1,3,5-triazine · 2,4-Bis-4-(2-ethylhexyloxy)-2-hydroxyphenyl-6-4-(2-methoxyethylcarbonyl)phenylamino-1,3,5-triazine · 2,4-Bis-4-(3-(2-propynyloxy)-2-hydroxypropyloxy)-2-hydroxyphenyl-6-4-(2-ethylcarboxyl)phenylamino-1,3,5-triazine · 2,4-Bis-4-(2-ethylhexyloxy)-2-hydroxyphenyl-6-(1-methylpyrrol-2-yl)-1,3,5-triazine · 2,4-Bis-4-tris-(trimethylsiloxysilylpropyloxy)-2-hydroxyphenyl-6-(4-methoxyphenyl)-1,3,5-triazine · 2,4 - Bis - 4 - (2’’ - methylpropenyloxy) - 2 - hydroxyphenyl - 6 - (4 - methoxyphenyl) - 1,3,5 - triazine · It contains 2,4 - bis - 4 - (1’,1’,3’,5’,5’ - heptamethylsiloxy - 2’’ - methylpropoxy) - 2 - hydroxyphenyl - 6 - (4 - methoxyphenyl) - 1,3,5 - triazine.

[0070] The composition can further contain typical detergent and cleansing composition components such as UV - A filters which are preferably combined with one or more compounds of formula (I) in the preparation according to the present invention, and are selected from the group consisting of the following. · 4 - Isopropyldibenzoylmethane · terephthalylidene dibornanesulfonic acid and its salts (Mexoryl (trademark) SX) · 4 - t - butyl - 4’ - methoxydibenzoylmethane (avobenzone) / (NeoHeliopan (trademark) 357) · Disodium salt of phenylenebisbenzimidazolyltetrasulfonic acid (NeoHeliopan (trademark) AP) · 2,2’ - (1,4 - phenylene) - bis - (1H - benzimidazole - 4,6 - disulfonic acid), sodium salt · Hexyl ester of 2 - (4 - diethylamino - 2 - hydroxybenzoyl) benzoic acid (Uvinul (trademark) APlus) · Indanilidene compounds disclosed in DE10055940A1 (= WO2002038537A1).

[0071] The composition can more preferably further contain typical detergent and cleansing composition components such as UV filters which are combined with one or more compounds of formula (I) in the preparation according to the present invention, and are selected from the group consisting of the following. p - Aminobenzoic acid · 3 - (4’ - trimethylammonium) benzylidene bornan - 2 - one methyl sulfate · Homomenthyl salicylate (Neo Heliopan (trademark) HMS) · 2-Hydroxy-4-methoxybenzophenone (NeoHeliopan® BB) · 2-Phenylbenzimidazole sulfonic acid (NeoHeliopan® Hydro) · terephthalylidene dibornane sulfonic acid and its salts (Mexoryl® SX) · 4-tert-Butyl-4'-methoxydibenzoylmethane (NeoHeliopan® 357) · 3-(4'-Sulfo)benzylidene bornan-2-one and its salts · 2-Ethylhexyl 2-cyano-3,3-diphenylacrylate (NeoHeliopan® 303) · N-[(2,4)-[2-(Oxoborn-3-ylidene)methyl]benzyl]acrylamide polymer · 2-Ethylhexyl p-methoxycinnamate (Neo Heliopan AV) · Ethyl p-aminobenzoate (25 mol) ethoxylated (INCI name: PEG-25PABA) · Isoamyl p-methoxycinnamate (NeoHeliopan® E1000) · 2,4,6-Trianilino-(p-carbo-2'-ethylhexyl-1'-oxy)-1,3,5-triazine (Uvinul® T150) · Phenol, 2-(2H-benzotriazol-2-yl)-4-methyl- 6-(2-methyl-3(1,3,3,3-tetramethyl-1-(trimethylsilyl)oxy)-disiloxyanilyl)propyl) (Mexoryl® XL) · 4,4'-(6-4-(1,1-dimethyl)aminocarbonyl)phenylamino-1,3,5-triazine-2,4-diyl)diimino-bis-(benzoic acid-2-ethylhexyl ester) (Uvasorb HEB) · 3-(4'-Methylbenzylidene)-D,L-camphor (NeoHeliopan® MBC) · 3-Benzylidene camphor · 2-Ethylhexyl salicylate (NeoHeliopan™ OS) · 2-Ethylhexyl 4-dimethylaminobenzoate (Padimate O) · Hydroxy-4-methoxybenzophenone-5-sulfonic acid and Na salt · 2,2’-Methylenebis-(6-(2H-benzotriazol-2-yl)-4-1,1,3,3-tetramethylbutyl)phenol) (Tinosorb™ M) · Disodium salt of phenylenebisbenzimidazole tetrasulfonic acid (NeoHeliopan™ AP) · 2,4-Bis-(4-(2-ethylhexyloxy)-2-hydroxyphenyl-6-(4-methoxyphenyl)-1,3,5-triazine (Tinosorb™ S) · Benzylidene malonic acid polysiloxane (Parsol™ SLX) · Mentyl anthranilate (NeoHeliopan™ MA) · Hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate (Uvinul™ APlus) · Indanilide compounds according to DE10055940 (=WO02 / 38537).

[0072] Advantageous primary and also secondary sun protection factors are described in WO2005123101A1. Advantageously, these preparations contain at least one UVA filter and / or at least one UVB filter and / or at least one inorganic pigment. The preparations can be present here in various forms as conventionally used in sun protection preparations. Thus, they can be in the form of a solution, a water-in-oil (W / O) or oil-in-water (O / W) emulsion, or for example a multiple emulsion of the water-in-oil-in-water type (W / O / W), a gel, a water dispersion, a solid stick, or an aerosol.

[0073] In a further preferred embodiment, the formulations according to the invention contain a total amount of sunscreen agents, in particular UV filters and / or inorganic pigments (UV filter pigments). For this reason, the formulations according to the invention have a photoprotection factor of 2 or more (preferably 5 or more). Such formulations according to the invention are particularly suitable for protecting the skin and hair.

[0074] Secondary sun protection factor In addition to the above-mentioned group of primary sunscreen factors, antioxidant secondary sunscreen factors can also be used. The anti-oxidative secondary sunburn prevention factor interferes with the chain of photochemical reactions that start when ultraviolet rays penetrate the skin. Typical examples include amino acids (such as glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (such as urocanic acid) and their derivatives, peptides, such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (such as anserine), carotenoids, carotenes (such as α-carotene, β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (such as dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (such as thioredoxin, glutathione, cysteine, cystine, cystamine and glycosyl, N-acetyl,Methyl, ethyl, propyl, amyl, butyl, lauryl, palmitoyl, oleyl, α-linoleyl, cholesteryl, glyceryl esters) and their salts, dilauryl thiodipropionate, distearyl (R) thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, glyceryl esters, nucleosides and their salts), very small amounts of compatible dosages of sulfoximine compounds (e.g., buthionine sulfoximine, homocysteine sulfoximine, buthionine sulfone, penta-, hexa- and hepta-thionine sulfoximine), also (metal) chelators (e.g., (metal) chelating agents (e.g., α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (e.g., citric acid, lactic acid, malic acid), humic acid, bile acids, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g., linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and its derivatives (e.g., ascorbyl palmitate, ascorbyl phosphate Mg, ascorbyl acetate), tocopherol and its derivatives (e.g., vitamin E acetate), vitamin A and its derivatives (vitamin A palmitate) and coniferyl of benzoin resin, rutinic acid and its derivatives, etc., glycosylrutin, ferulic acid, furfurylidene glucitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (dispersion in ethanol, etc.), etc., zinc and its derivatives (e.g., ZnO, ZnSO4), selenium and its derivatives (e.g., selenium methionine), stilbene and its derivatives (e.g., stilbene oxide, trans-stilbene oxide) and derivatives of these active substances suitable for the purposes of the present invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides, lipids), etc.

[0075] Advantageous inorganic secondary sun protection pigments are the finely dispersed metal oxides and metal salts also described in WO 2005123101A1. The total amount of inorganic pigments, in particular hydrophobic inorganic micropigments, in the finished cosmetic preparation according to the invention is advantageously, in each case, 0.1 - 30% by weight, preferably 0.5 - 10.0% by weight, based on the total weight of the preparation.

[0076] Also preferred is the use of particulate UV filters or optionally hydrophobizable inorganic pigments such as oxides of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g. MnO), aluminum (Al2O3), cerium (such as Ce2O3) and / or mixtures thereof.

[0077] Agent for regulating hair pigmentation Preferred active ingredients for hair lightning are selected from the group consisting of the following. Kojic acid (5-hydroxy-2-hydroxymethyl-4-pyranone), kojic acid derivatives, preferably kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone, hydroquinone derivatives. Resorcinol, resorcinol derivatives, preferably 4-alkylresorcinol and 4-(1-phenylethyl)1,3-dihydroxybenzene (phenylethylresorcinol), cyclohexylcarbamate (preferably one or more cyclohexylcarbamates disclosed in WO2010 / 122178 and WO2010 / 097480), sulfur-containing molecules, preferably glutathione or cysteine, α-hydroxy acids (preferably citric acid, lactic acid, malic acid), salts and esters thereof, N-acetyltyrosine and derivatives, undecylenoyl phenylalanine. Gluconic acid, chromone derivatives, preferably aloesin, flavonoids, 1-aminoethylphosphinic acid, thiourea derivatives, ellagic acid, nicotinamide (niacinamide), zinc salts, preferably zinc chloride or zinc gluconate, tsuyapurin and its derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranones, preferably senkyunolide, vinyl guaiacol, ethyl guaiacol, dioic acids, preferably octadecenedioic acid and / or azelaic acid, nitric oxide synthase inhibitors, preferably L-nitroarginine and its derivatives, 2,7-dinitroindazole or thiocitrulline, metal chelating agents (preferably, α-hydroxy fatty acids, phytic acid, fulvic acid, bile acids, bile extracts, EDTA, EGTA and their derivatives), retinoids, soy milk and extracts, serine protease inhibitors or lipoic acid or other synthetic or natural active ingredients for skin and hair lightning. The latter are preferably extracts from plants, preferably in the form of mugwort extract, rice extract, papaya extract, turmeric extract, mulberry extract, spinach extract, coconut extract, licorice root extract or components concentrated or separated therefrom.Preferably, it is grabrin or licocalcon A, artocarpus extract, extracts of rumex and ramulus species, extract of pinus species, extract of vitis species or stilbene derivatives isolated or concentrated therefrom, saxifraga extract, scutellaria extract, grape extract and / or microalgae extract, particularly tetraselmis sueica extract.

[0078] Skin and hair tanning active ingredients that are advantageous in this regard are substrates or substrate analogs of tyrosinase such as L-tyrosine, N-acetyltyrosine, L-DOPA or L-dihydroxyphenylalanine, xanthine alkaloids such as caffeine, theobromine and theophylline and their derivatives, ACTH, α-MSH, peptide analogs thereof, proopiomelanocortin peptides that bind to melanocortin receptors, peptides such as Val-Gly-Val-Ala-Pro-Gly, Lys-Ile-Gly-Arg-Lys or Leu-Ile-Gly-Lys, purines, pyrimidines, folic acid, copper salts such as copper gluconate, copper chloride or pyrrolidone acid, 5-pyrazin-2-yl 1,3,4-oxadiazole-2-thiol, curcumin, zinc diglycinate (Zn(Gly)2), for example, the manganese bicarbonate complex described in EP0584178 (“pseudocatalase”), for example, the tetrasubstituted cyclohexene derivative described in WO 2005 / 032501, isoprenoids described in WO 2005 / 102252 and WO 2006 / 010661, melanin derivatives such as melanin 100 and melanzen, diacylglycerol, aliphatic or cyclic diols, psoralen, prostaglandins and their analogs, activators of adenylate cyclase, compounds that activate the transfer of melanosomes to keratinocytes such as serine protease and agonists of the PAR-2 receptor. Extracts of plants and plant parts such as Chrysanthemum, Arnica, Walnut, Urushi, Rhubarb, microalgae, especially Isochrysis galbana, trehalose, erythrulose, and dihydroxyacetone. Also, flavonoids that cause skin and hair coloring or browning (for example, quercetin, rhamnetin, kaempferol, fisetin, genistein, daidzein, chrysin and apigenin, epicatechin, diosmin and diosmetin, morin, quercitrin, naringenin, hesperidin, phloridzin and phloretin) can also be used.

[0079] Next, the amount of the aforementioned example (one or more compounds) of the additional active ingredient for skin and hair pigmentation regulation in the product according to the present invention is preferably 0.00001 - 3% by weight, preferably 0.0001 - 20% by weight, particularly preferably 0.001 - 5% by weight, based on the total weight of the preparation.

[0080] Hair growth activator or hair growth inhibitor The formulations and products according to the present invention may contain one or more hair growth activators, i.e., agents that stimulate hair growth. The hair growth activating agent is preferably a pyrimidine derivative such as 2,4-diaminopyrimidine-3-oxide (aminoxyl), 2,4-diamino-6-piperidinopyrimidine-3-oxide (minoxidil) and their derivatives, 6-amino-1,2-dihydro-1-hydroxy-2-imino-4-piperidinopyrimidine and its derivatives, xanthine alkaloids such as caffeine, theobromine, theophylline and their derivatives, quercetin and its derivatives, dihydroquercetin (taxifolin) and its derivatives, potassium channel openers. Antiandrogens, synthetic or natural 5-reductase inhibitors, nicotinic acid esters such as nicotinic acid tocopheryl, nicotinic acid benzyl, nicotinic acid C1-C6 alkyl, for example, proteins such as tripeptide Lys-Pro-Val, difenicipren, hormones, etc.Finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and its derivatives, diuretics such as cyproterone acetate, spironolactone, calcineurin inhibitors such as FK506 (tacrolimus, Fujimycin) and its derivatives, cyclosporine A and its derivatives, zinc and zinc salts, polyphenols, procyanidins, proanthocyanidins, plant sterols (e.g., β-sitosterol), biotin, eugenol, (±)-β-citronellol, panthenol, glycogen from, for example, abalone, microorganisms, algae, plants, and extracts from parts of plants such as those of the genus Leontodon or Taraxacum, Orthosiphon, Vitex, Coffea, Paullinia, Theobroma, Asiasarum, Cucurbita or Styphnolobium, Serenoa repens (saw palmetto), Sophora flavescens, Pygeum africanum, Panicum miliaceum, Cimicifuga racemosa, Glycine max, Eugenia caryophylata, Cotin sinensis, Ilex paraguariensis, Isochrysis galbana, licorice, grapes, apples, barley, hops, or hydrolysates from rice or wheat.

[0081] Alternatively, the formulations and products according to the present invention may contain one or more hair growth inhibitors (described above), i.e., agents that reduce or prevent hair growth. The hair growth inhibitors are preferably activin, an activin derivative or an activin agonist, an ornithine decarboxylase inhibitor such as α-difluoromethylornithine or pentacyclic triterpenes such as ursolic acid, betulin, betulinic acid, oleanolic acid and its derivatives, a 5α-reductase inhibitor, an androgen receptor antagonist, an S-adenosylmethionine decarboxylase inhibitor, a gamma-glutamyltranspeptidase inhibitor, a transglutaminase inhibitor, a serine protease inhibitor derived from soybeans, a microorganism, an alga, an extract from different microalgae or plants, for example, from the group consisting of parts of plants of the Fabaceae, Solanaceae, Asclepiadaceae or Cucurbitaceae, Chondrus, Gloiopeltis, Ceramium, Durvillea, Glycine max, Sanguisorba officinalis, Calendula officinalis, Hamamelis virginiana, Arnica montana, Salix alba, Hypericum perforatum or Gymnema sylvestre genera etc. can be selected.

[0082] Physiological coolant The composition may also contain one or more substances (cooling agents) having a physiological cooling effect, which are preferably selected here from the following list. Menthol and menthol derivatives (e.g., L-menthol, D-menthol, racemic menthol, isomenthol, neoisomenthol) Menthylic ethers (e.g., (I-menthoxy)-1,2-propanediol, (l-menthoxy)-2-methyl-1,2-propanediol, L-menthyl-methyl ether). Menthylic esters (e.g., menthyl formate, menthyl acetate, menthyl isobutyrate, menthyl lactate, L-menthyl-L-lactate, L-menthyl-D-lactate, menthyl-(2-methoxy)acetate, menthyl-(2-methoxyethoxy)acetate, menthyl pyroglutamate), menthyl carbonates (e.g., menthyl propylene glycol carbonate, menthyl ethylene glycol carbonate, menthyl glycerol carbonate or a mixture thereof), semi-esters of menthol with dicarboxylic acids or their derivatives (e.g., monomenthyl succinate, monomenthyl glutarate, monomenthyl malonate, O-menthyl succinate ester-N,N-(dimethyl)amide, O-menthyl succinate ester amide), mentanecarboxylic acid amides (in this case, preferably mentanecarboxylic acid-N-ethylamide [WS3] or Nα-(mentanecarbonyl)glycine ethyl ester [WS5], as described in US4,150,052).Menthanecarboxylic acid-N-(4-cyanophenyl)amide or menthanecarboxylic acid-N-(4-cyanomethylphenyl)amide, metanecarboxylic acid-N-(alkoxyalkyl)amide), menthone and menthone derivatives (e.g., L-menthone glycerol ketal), 2,3-dimethyl-2-(2-propyl)-butyric acid derivatives (e.g., 2,3-dimethyl-2-(2-propyl)-butyric acid N-methylamide [WS23]), isopulegol or its esters (I-(-)-isopulegol, I-(-)-isopulegol acetate), menthane derivatives (e.g., p-menthane-3,8-diol), cubebol or a synthetic or natural mixture containing cubebol, pyrrolidone derivatives of cycloalkyldione derivatives (e.g., 3-methyl-2(1-pyrrolidinyl)-2-cyclopenten-1-one) or tetrahydropyrimidin-2-one (e.g., isirine or related compounds described in WO2004 / 026840), carboxamides (e.g., N-(2-(pyridin-2-yl)ethyl)-3-pimenter carboxamide or related compounds), (1R,2S,5R)-N-(4-methoxyphenyl)-5-methyl-2-(1-isopropyl)cyclohexane-carboxamide [WS12], oxamate (preferably those described in EP2033688A2), etc.

[0083] Anti-inflammatory agent Suitable anti-inflammatory agents can be selected from the group formed by the following. (i) Steroidal anti-inflammatory substances of the corticosteroid type, particularly hydrocortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone. (ii) Non-steroidal anti-inflammatory substances, particularly oxicams such as piroxicam or tenoxicam, salicylates such as aspirin, disalcid, solprin or fendosal, acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac. Fenamates such as tolmetin or clidanac, mefenamic, meclofenamic, flufenamic or niflumic, propionic acid derivatives such as ibuprofen, naproxen or benoxaprofen, pyrazoles such as phenylbutazone, oxyphenbutazone, febrazone or azapropazone, etc. (iii) Natural or naturally occurring anti-inflammatory substances or substances that relieve redness and / or itching, particularly extracts or fractions from chamomile, aloe vera, Commiphora species, Rubia species, willow, willow-herb, oats, centaury, arnica, St. John's wort, ivy, rosemary, Passiflora incarnata, mansaqu, ginger or echinacea or their single active compounds. (iv) Histamine receptor antagonists, serine protease inhibitors (e.g., soy extract), TRPV1 antagonists (e.g., 4-t-butylcyclohexanol), NK1 antagonists (e.g., aprepitant, hydroxyphenylplamidobenzoic acid), cannabinoid receptor agonists (e.g., palmitoylethanolamine), TRPV3 antagonists.

[0084] Antibacterial agent Suitable antibacterial agents are, in principle, all substances effective against Gram-positive bacteria. For example, 4-hydroxybenzoic acid and its salts and esters, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea, 2,4,4'-trichloro-2'-hydroxydiphenyl ether (triclosan), 4-chloro-3,5-dimethyl-phenol, 2,2'-methylenebis(6-bromo-4-chlorophenol), 3-methyl-4-(1-methylethyl)phenol, 2-benzyl-4-chloro-phenol, 3-(4-chlorophenoxy)-1,2-propanediol, 3-iodo-2-propynyl butylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antibacterial fragrances, thymol, thyme oil, eugenol, clove oil, menthol, mint oil, farnesol, phenoxyethanol, glycerol monocaprate, glycerol monocaprylate, glycerol monolaurate (GML), diglycerol monocaprate (DMC), N-alkylamides of salicylic acid, for example, n-octyl salicylamide or n-decyl salicylamide, and the like.

[0085] Enzyme inhibitor Suitable enzyme inhibitors are, for example, esterase inhibitors. These are preferably trialkyl citrates, for example, trimethyl citrate, tripropyl citrate, tributyl citrate, especially triethyl citrate (hidagen CAT). These substances inhibit enzyme activity and thereby reduce the formation of odors. Other substances that are suitable esterase inhibitors are, for example, sterol sulfates or phosphates such as sulfates or phosphates of lanosterol, cholesterol, campesterol, stigmasterol, and sitosterol, dicarboxylic acids and their esters, for example, glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid, and diethyl malonate, hydroxycarboxylic acids and their esters, for example, citric acid, malic acid, tartaric acid, or diethyl tartrate, and zinc glycinate.

[0086] Odor absorber and antiperspirant active agentA suitable odor absorbent is a substance that can absorb odor-forming compounds and retain most of them. The absorbent reduces the partial pressure of each component and decreases the diffusion rate. It is important that the perfume is not impaired in this process. Odor absorbents are ineffective against bacteria. They are composed of, for example, as the main component, the complex zinc salt of ricinoleic acid, or certain almost odorless fragrances known to those skilled in the art as "fixatives", such as extracts of labdanum or styrax, and certain abietic acid derivatives. An odor masking agent is a fragrance or perfume oil, and in addition to its function as an odor masking agent, it imparts each fragrance note to the deodorant. Examples of perfume oils include mixtures of natural fragrances and synthetic fragrances. Natural fragrances are extracts from flowers, stems, leaves, fruits, peels, roots, woods, herbs, grasses, needles, branches, and resins, balsams. Also, for example, animal-derived ones such as civet and castoreum are suitable. Typical synthetic fragrance compounds are products of the ester, ether, aldehyde, ketone, alcohol, and hydrocarbon types. Ester-type fragrance compounds are, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styrallyl propionate, and benzyl salicylate. Examples of ethers include benzyl ethyl ether, and examples of aldehydes include straight-chain alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial, bourgeonal, etc. Examples of ketones include ionones, methyl cedryl ketone, and examples of alcohols include anethole, citronellol, eugenol, iso-eugenol, geraniol, linalool, phenylethyl alcohol, terpineol, and hydrocarbons mainly include terpenes, balsams. However, it is preferred to use mixtures of different scents that create a pleasant fragrance note together.Relatively low volatility essential oils, which are mainly used as fragrance components, are also suitable as perfumes, such as sage oil, chamomile oil, clove oil, Melissa oil, mint oil, cinnamon leaf oil, linden flower oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil, labdanum oil and lavandin oil. Bergamot oil, dihydromyrcenol, lilial, citronellol, phenylethyl alcohol, α-hexylcinnamaldehyde, geraniol, benzylacetone, cyclamen aldehyde, linalool, boisambrene forte, ambroxan, indole, hedione, sandelis, lemon oil, mandarin oil, orange oil, allyl amyl glycolate, cyclovertal, lavandin oil, clary sage oil, β-damascone, bourbon geranium oil, cyclohexyl salicylate, beltfix cool, iso E super, fixolide NP, evernyl, iraldein γ, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, iloty and floramat, either alone or in a mixture, are preferably used.

[0087] Suitable astringent antiperspirant active ingredients are mainly salts of aluminum, zirconium or zinc. Such suitable antiperspirant active ingredients are, for example, aluminum chloride, aluminum chlorohydrate, aluminum dichlorohydrate, aluminum sesquichlorohydrate and their complex compounds, such as 1,2-propylene glycol, aluminum hydroxyalantoinate, aluminum tartrate chloride, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate, aluminum zirconium pentachlorohydrate and their complex compounds combined with amino acids such as glycine.

[0088] Film former and anti-dandruff agent Standard film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, acrylic acid series polymers, quaternary cellulose derivatives, collagen, hyaluronic acid and its salts and similar compounds.

[0089] Suitable anti-dandruff agents are piroctone olamine (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), Baypiva (trademark) (climbazole), Ketoconazol (trademark) (4-acetyl-1-{4-[2-(2,4-dichlorophenyl)r-2-(1H-imidazol-1-ylmethyl)-1,3-dioxolane-c-4-ylmethoxyphenyl]piperazine, ketoconazole, erbium, selenium disulfide, colloidal sulfur. Polyethylene glycol sorbitan monooleate sulfur, ricinole polyethoxylate sulfur, tar distilled sulfur, salicylic acid (or in combination with hexachlorophene), undecylenic acid, monoethanolamide sulfosuccinate Na salt, Lamepon (trademark) UD (protein / undecylenic acid condensate), zinc pyrithione, aluminum pyrithione and dipyrithione magnesium sulfate.

[0090] Carrier and hydrotropic Preferred cosmetic carrier materials are solid or liquid (including high-viscosity substances) at 25°C and 1013 mbar, such as glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, ethanol, water and a mixture of two or more of the liquid carrier materials and water. Optionally, these preparations according to the invention can be produced using preservatives or solubilizers. Other preferred liquid carrier substances that can be components of the preparations according to the invention are selected from the group consisting of oils such as vegetable oils, neutral oils and mineral oils.

[0091] Preferred solid carrier materials which can be components of the preparations according to the invention are starch, degraded starch, chemically or physically modified starch, dextrin, (powdered) maltodextrin (preferably with a dextrose equivalent value of 5-25, preferably 10-20), lactose, silicon dioxide, glucose, modified cellulose, hydrocolloids such as gum arabic, ghatti gum, tragacanth, karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar flour, carob bean flour, alginates, agar, pectin and inulin and mixtures of two or more of these solids, in particular mixtures of maltodextrin (preferably with a dextrose equivalent value of 15-20), lactose, silicon dioxide and / or glucose.

[0092] Furthermore, in order to improve the flow behavior, hydrotropes such as ethanol, isopropyl alcohol or polyols can be used. Suitable polyols preferably contain from 2 to 15 carbon atoms and at least 2 hydroxyl groups. The polyol may contain other functional groups, more particularly amino groups, or may be modified with nitrogen. Typical examples are as follows. · Glycerol · Alkylene glycols such as ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycol with an average molecular weight of 100-1000 daltons. · Technical oligoglycerol mixtures with a self-condensation degree of 1.5-10, for example technical diglycerol mixtures with a diglycerol content of 40-50% by weight. · Methylol compounds such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol. · Lower alkyl glucosides, in particular those containing 1-8 carbon atoms in the alkyl group, such as methyl glucoside and butyl glucoside. · Sugar alcohols containing from 5 to 12 carbon atoms, such as sorbitol or mannitol. · Sugars containing from 5 to 12 carbon atoms, such as glucose or sucrose. · Amino sugars, such as glucosamine. · Dialcohol amines such as diethanolamine or 2-aminopropane-1,3-diol.

[0093] Preservative Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid, and other classes of compounds described in Appendix 6, Parts A and B of the Cosmetics Regulation (Kosmetikverordnung).

[0094] Dye Suitable dyes are, for example, any of the substances suitable and approved for cosmetics described in the publication "Kosmetische Farbemittel" of the Farbstoffkommission der Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, pages 81 - 106. For example, cochineal red A (C.I. 16255), patent blue V (C.I. 42051), indigotin (C.I. 73015), chlorophyllin (C.I. 75810), quinoline yellow (C.I. 47005), titanium dioxide (C.I. 77891), indanthrene blue RS (C.I. 69800) and madder lake (C.I. 58000), etc. Luminol may also be present as a luminescent dye. Advantageous coloring pigments are, for example, titanium dioxide, mica, iron oxides (e.g., Fe2O3, Fe3O4, FeO(OH)) and / or tin oxides. Advantageous dyes are, for example, carmine, Berlin blue, chromium oxide green, ultramarine blue and / or manganese violet.

[0095] Formulation Preferred compositions according to the invention are preferably leave-on products (one or more compounds of formula (I) remain on the skin and / or hair for a longer time compared to rinse-off products, thus making their moisturizing and / or anti-aging and / or wound healing promoting effects more prominent) as products for the treatment, protection, care and cleansing of the skin and / or hair, or makeup products, and are preferably selected from the group thereof.

[0096] The formulations according to the invention can preferably be in the form of an emulsion, such as a W / O (water-in-oil), O / W (oil-in-water), W / O / W (water-in-oil-in-water) emulsion, PIT emulsion, pickering emulsion, low-oil emulsion, micro- or nanoemulsion, solution, for example in an oil (fatty oil or fatty acid ester, in particular a C6-C32 fatty acid C2-C30 ester) or silicone oil, a dispersion, suspension, cream, lotion, milk, gel (including hydrogel, hydrodispersion gel, oleogel) depending on the production method and components, spray (e.g. pump spray or propellant spray) or impregnating liquid for cosmetic wipes, cleaning agents, such as soap, synthetic detergents, liquid cleaners, shower and bath agents, bath products (capsules, oils, tablets, salts, bath salts, soaps, etc.), foaming preparations, skin care products, such as emulsions (as described above), ointments, pastes, gels (as described above), oils, balsams, beauty fluids, powders (e.g. face powder, body powder), eau de parfum, eau de toilette, aftershave, masks, pencils, sticks, roll-ons, pumps, aerosols (foaming, non-foaming or post-foaming), deodorants and / or antiperspirants, mouthwashes and oral rinses, foot care products (including keratolytic agents, deodorants), insect repellents, sunscreens, aftersun products, shaving products, aftershave balm, pre- and aftershave lotions, depilatory agents, hair care products (e.g. shampoos (2-in-1 shampoos, anti-dandruff shampoos, baby shampoos, shampoos for dry scalps, intensive shampoos), conditioners, hair tonics, hair waters, hair rinses, styling creams, pomades, perm-set lotions, hair sprays, styling agents (gels, waxes, etc.), hair dyes (temporary hair dyes, semi-permanent hair dyes, permanent hair dyes), hair conditioners, hair mousses, eye care products, makeup, makeup removers or baby products, etc.).

[0097] The preparations according to the invention are, particularly preferably, in the form of emulsions, in particular W / O, O / W, W / O / W, O / W / O emulsions, PIT emulsions, Pickering emulsions, low-oil emulsions, micro- or nanoemulsions, gels (including hydrogels, hydrodispersion gels, oleogels), solutions, for example, solutions in oils (fatty oils or fatty acid esters, in particular C6-C32 fatty acid C2-C30 esters) or silicone oils, or sprays (for example, pump sprays or propellant sprays).

[0098] Auxiliary substances and additives can be included in an amount of 5-99% by weight, preferably 10-80% by weight, based on the total weight of the preparation. The amounts of the cosmetic or dermatological auxiliary substances and additives and fragrances to be used in each case can be easily determined by a person skilled in the art by simple trial and error depending on the nature of the particular product.

[0099] The preparation can also contain water in an amount of up to 99% by weight, preferably 5-80% by weight, based on the total weight of the preparation.

[0100] Detergent composition Another object of the present invention relates to a detergent composition comprising any of the perfume oil mixtures or capsules described above. This composition can represent a light detergent, a heavy detergent, a fabric softener, a manual dishwashing detergent or a cleaner. Also, this composition can represent a powder, granule, tablet, liquid, gel or capsule.

[0101] The detergent composition according to the invention may contain additional auxiliaries such as any components customarily found in such compositions, for example, anionic, nonionic, cationic, amphoteric or zwitterionic (co)surfactants, organic solvents, builders, enzymes and soil repellents, thickeners, colorants and fragrances.

[0102] Anionic and zwitterionic co-surfactants Suitable anionic and zwitterionic surfactants have already been disclosed in the context of cosmetic compositions as described above.

[0103] Nonionic (co-)surfactant Alcohol alkoxylates The nonionic surfactants added are preferably alkoxylated and / or propoxylated, particularly preferably primary alcohols having 8-18 carbon atoms and on average 1-12 mol of ethylene oxide (EO) and / or 1-10 mol of propylene oxide (PO) per mole of alcohol. C8-C16-alcohol alkoxylates, preferably ethoxylated and / or propoxylated C10-C15-alcohol alkoxylates, particularly C12-C14 alcohol alkoxylates, with an ethoxylation degree of 2-10, preferably 3-8, and / or a propoxylation degree of 1-6, preferably 1.5-5, are particularly preferred. The cited ethoxylation and propoxylation degrees constitute statistical average values that can be integers or fractions for a particular product. Preferred alcohol ethoxylates and propoxylates have a narrow range of homologues (narrow range ethoxylates / propoxylates, NRE / NRP). In addition to these nonionic surfactants, fatty alcohols having 12 or more EO can also be used. Examples of these include (tallow) fatty alcohols with 14EO, 16EO, 20EO, 25EO, 30EO or 40EO.

[0104] Alkyl glycosides (APG (trademark)) Furthermore, as an additional nonionic surfactant, an alkyl glucoside satisfying the general formula RO(G)x can be added, for example, especially as a compound with an anionic surfactant. Here, R represents a primary linear or methyl-branched, especially 2-methyl, aliphatic group containing 8-22, preferably 12-18 carbon atoms, and G represents a glucose unit containing 5 or 6 carbon atoms, preferably a glucose unit of glucose. The degree of oligomerization x that defines the distribution of monoglycoside and oligoglycoside is any number from 1-10, preferably 1.1-1.4.

[0105] Fatty acid ester alkoxylates. Another class of preferred nonionic surfactants, used as the sole nonionic surfactant or in combination with other nonionic surfactants, especially together with alkoxylated fatty alcohols and / or alkyl glucosides, are those that are alkoxylated. Preferably, ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters containing 1-4 carbon atoms in the alkyl chain, more preferably fatty acid methyl esters produced by the process described in, for example, JP-A-58 / 217598 or International Publication WO90 / 13533. Methyl esters of C12-C18 fatty acids containing an average of 3-15 EO, especially an average of 5-12 EO, are particularly preferred.

[0106] Amine oxides. Nonionic surfactants of the amine oxide type, for example, N-cocoalkyl-N,N-dimethylamine oxide, N-tallowalkyl-N,N-dihydroxyethylamine oxide, fatty acid alkanolamides can also be preferably used. The usage amount of these nonionic surfactants is preferably not more than the usage amount of the ethoxylated fatty alcohol, and particularly preferably not more than half of it.

[0107] Gemini type surfactants. As a further surfactant, so-called gemini surfactants can be mentioned. Generally, such compounds are understood to mean compounds having two hydrophilic groups and two hydrophobic groups per molecule. In principle, these groups are separated from each other by a "spacer". The spacer is usually a hydrocarbon chain and is intended to provide a sufficient distance such that the hydrophilic groups can act independently of each other. This type of surfactant generally has an unusually low critical micelle concentration and is characterized by strongly reducing the surface tension of water. However, exceptionally, not only dimeric but also trimeric surfactants are meant by the term gemini surfactant. Suitable gemini surfactants are, for example, sulfated hydroxy mixed ethers according to German Patent Publication DE4321022A1, or dimer alcohol bis- and trimer alcohol tris sulfate esters and ether sulfate esters according to International Publication WO96 / 23768A1. Block end group dimers and trimer mixed ethers according to German Patent Publication DE19513391A1 are particularly characterized by bifunctionality and polyfunctionality. Gemini polyhydroxy fatty acid amides or polyhydroxy fatty acid amides as described in International Publications WO95 / 19953A1, WO95 / 19954A1 and WO95 / 19955A1 can also be used.

[0108] Cationic co-surfactant Tetraalkylammonium salts. Cationic surfactants dissociate in aqueous solution to form a hydrophobic polymer group necessary for the surfactant properties of the cation. An important representative group of cationic surfactants are the tetraalkylammonium salts of the general formula (R1R2R3R4N+)X-. Here, R1 represents C1-C8 alkyl (alkenyl), and R2, R3 and R4 each independently represent a radical of an alkyl (alkenyl) having 1-22 carbon atoms. X is a counterion and is preferably selected from the group of halides, alkyl sulfates and alkyl carbonates. Cationic surfactants in which the nitrogen group is substituted by two long acyl groups and two short alkyl (alkenyl) groups are particularly preferred.

[0109] Ester quats. A further class of cationic surfactants that are particularly useful as co-surfactants in the present invention is represented by the so-called ester quats. Ester quats are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by relevant methods of preparative organic chemistry. In this context, reference is made to International Publication WO91 / 01295A1, where triethanolamine is partially esterified with a fatty acid in the presence of hypophosphorous acid, air is passed through the reaction mixture, and then the whole is quaternized with dimethyl sulfate or ethylene oxide. Further, German Patent DE 4308794C1 describes a process for the production of solid ester quats in which the quaternization of triethanolamine esters is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0110] Typical examples of esterquats suitable for use according to the present invention are those in which the acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, RCO is an acyl group containing 6 to 10 carbon atoms, and the amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are, for example, caproic acid, caprylic acid, capric acid, and technical mixtures thereof, such as so-called head fraction fatty acids. Esterquats in which the acyl component is derived from a monocarboxylic acid containing 8 - 10 carbon atoms are preferably used. Other esterquats are those in which the acyl component is derived from a dicarboxylic acid such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, preferably adipic acid. Overall, esterquats derived from a mixture of a monocarboxylic acid containing 6 - 22 carbon atoms and adipic acid are preferably used. The molar ratio of monocarboxylic acid to dicarboxylic acid in the final esterquat may range from 1:99 - 99:1, preferably from 50:50 - 90:10, and more particularly from 70:30 - 80:20. In addition to quaternized fatty acid triethanolamine esters, other suitable esterquats are quaternized ester salts of a mono / dicarboxylic acid mixture with diethanolalkylamine or 1,2-dihydroxypropyldialkylamine. Esterquats can be obtained from fatty acids or from the corresponding triglycerides which are mixtures with the corresponding dicarboxylic acids. One such process, which is intended to be representative of the relevant prior art, is proposed in European Patent EP0750606B1. To produce the quaternized ester, a mixture of mono- and dicarboxylic acids and triethanolamine (based on the available carboxyl functions) can be used in a molar ratio of 1.1:1 - 3:1. Considering the performance characteristics of the esterquat, a ratio of 1.2:1 - 2.2:1, preferably 1.5:1 - 1.9:1, has proven to be particularly advantageous. Preferred esterquats are technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 - 1.9.

[0111] Amphoteric co-surfactant Betaines. Amphoteric or zwitterionic surfactants have multiple functional groups that can be ionized in an aqueous solution, thereby imparting anionic or cationic properties to the compound depending on the conditions of the medium (see DIN 53900, July 1972). Near the isoelectric point (around pH 4), zwitterionic surfactants form inner salts and become poorly soluble or insoluble in water. Zwitterionic surfactants are classified into zwitterions and betaines, the latter existing as zwitterions in solution. Ampholytes are compounds that have both acidic and basic hydrophilic groups and act as acids or bases depending on the conditions. In particular, betaines are known surfactants mainly produced by the carboxyalkylation, preferably carboxymethylation, of amine compounds. The starting materials are preferably condensed with a halocarboxylic acid or its salt, more preferably sodium chloroacetate, and one mole of salt is formed per mole of betaine. In addition, the addition of an unsaturated carboxylic acid such as acrylic acid is also possible. Examples of suitable betaines are carboxyalkylation products of secondary and especially tertiary amines corresponding to the formula R1R2R3N-(CH2)qCOOX, where R1 is an alkyl group having 6-22 carbon atoms, R2 is hydrogen or an alkyl group having 1-4 carbon atoms, R3 is an alkyl group having 1-4 carbon atoms, q is a number from 1-6, and X is an alkali and / or alkaline earth metal or ammonium. Representative examples include carboxymethylation products such as hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, C12 / 14-cocoalkyldimethylamine, myristyldimethylamine, cetyl-dimethylamine, stearyldimethylamine, etc. Also included are stearylethylmethylamine, oleyl-dimethylamine, C16 / 18-tallowalkyldimethylamine and their technical mixtures, especially dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine and their technical mixtures.

[0112] Alkylamidobetaines. Other suitable betaines are carboxyalkylated products of amidoamines corresponding to the formula R1CO(R3)(R4)-NH-(CH2)pN-(CH2)qCOOX, where R1CO is an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds; R2 is hydrogen or an alkyl radical having 1 to 4 carbon atoms; R3 is an alkyl radical having 1 to 4 carbon atoms; p is a number from 1 to 6; q is a number from 1 to 3; and X is an alkali and / or alkaline earth metal or ammonium. Typical examples are reaction products of fatty acids having 6 to 22 carbon atoms, such as, for example, caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, eleostearic acid, arachidonic acid, gadleic acid, behenic acid, erucic acid, and technical mixtures thereof with N,N-dimethylaminoethylamine, N,N-dimethylaminopropylamine, N,N-diethylamino-ethylamine, and N,N-diethylaminopropylamine (which are condensed with sodium chloroacetate). Commercially available products include Dehyton™ K and Dehyton™ PK (Cognis Deutschland GmbH & Co., KG), and Tego™ Betaine (Goldschmidt).

[0113] Imidazolines. Other suitable starting materials for the purposes of the present invention are the imidazolines. These substances are also known and can be obtained, for example, by cyclocondensation of 1 or 2 moles of a C6-C22 fatty acid with a polyfunctional amine such as aminoethylethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylated products are mixtures of different open-chain betaines. A typical example is the condensation product of the above fatty acid with an imidazoline based on AEEA, preferably lauric acid, which is then betainized with sodium chloroacetate. Commercially available is Dehyton(trademark) G (Cognis Deutschland GmbH&Co.)

[0114] The amount of (co)surfactant contained in the composition of the present invention is advantageously 0.1% to 90% by weight, in particular 10% to 80% by weight, particularly preferably 20% to 70% by weight.

[0115] Organic solvent The liquid light-duty or heavy-duty detergent may contain an organic solvent, preferably one miscible with water. As organic solvents for this purpose, polyols, ethers, alcohols, ketones, amides and / or esters are preferably used in an amount of 0 to 90% by weight, preferably 0.1 to 70% by weight, in particular 0.1 to 60% by weight. As low molecular weight polar substances, for example, methanol, ethanol, propylene carbonate, acetone, acetonylacetone, diacetone alcohol, ethyl acetate, 2-propanol, ethylene glycol, propylene glycol, glycerin, diethylene glycol, dipropylene glycol monomethyl ether and dimethylformamide or mixtures thereof are preferably used.

[0116] Enzyme Cellulase enzyme. The cellulase enzyme optionally used in the instant detergent composition, when present, is preferably incorporated at a level sufficient to provide up to about 5 mg, more preferably about 0.01 mg - about 3 mg of active enzyme per gram of the composition. Unless otherwise specified, the compositions herein preferably comprise from about 0.001% to about 5% by weight, preferably from 0.01% to 1% by weight of a commercially available enzyme preparation.

[0117] Suitable cellulases for the present invention can include either bacterial cellulases or fungal cellulases. Preferably, they have an optimal pH of 5 - 9.5. Suitable cellulases include fungal cellulases produced from Humicola insolens and Humicola strain DSM1800 or a cellulase 212-producing bacterium belonging to the genus Aeromonas, and cellulases extracted from the hepatopancreas of the marine mollusk (Dolabella Auricula Solander). Suitable cellulases are also disclosed in published patent GB2,075,028A. Furthermore, cellulases particularly suitable for use herein are disclosed in International Publication WO1992013057A1. Most preferably, the cellulase used in the instant detergent composition is purchased as those commercially available under the product names CAREZYMEO and CELLUZYMEO from NOVO Industries A / S.

[0118] Other enzymes. Additional enzymes can be included in the detergent compositions herein for a variety of fabric washing purposes, including, for example, the removal of protein-based, carbohydrate-based, or triglyceride-based soils, and the prevention of fugitive dye transfer, and fabric restoration. Additional enzymes to be incorporated include proteases, amylases, lipases, and peroxidases, and mixtures thereof. It is also possible to include other types of enzymes. They can be of any suitable origin, such as plant, animal, bacterial, fungal, yeast, etc. However, their selection is governed by several factors such as the optimal values of pH-activity and / or stability, heat resistance, stability to active detergents, builders, and the potential to cause malodors during use. In this regard, bacterial or fungal enzymes are preferred, for example, bacterial amylases and proteases.

[0119] Enzymes are typically incorporated at levels sufficient to provide up to about 5 weight mg of active enzyme per gram of composition, more typically from about 0.01 mg to about 3 mg. Stated another way, the compositions herein typically contain from about 0.001 weight % to about 5 weight %, preferably from 0.01 weight % to 1 weight % of a commercially available enzyme preparation. Protease enzymes are typically present in such commercially available preparations at levels sufficient to provide from 0.005 to 0.1 Anson units (AU) of activity per gram of composition.

[0120] Suitable examples of proteases are subtilisins obtained from Bacillus subtilis and specific strains of Bacillus subtilis. Another suitable protease is obtained from a Bacillus strain having maximum activity throughout the pH range of 8 - 12 and is sold by Novo Industries under the registered trade name ESPERASE™. Preparations of this enzyme and similar enzymes are described in Novo's GB 1,243,784. Proteolytic enzymes suitable for removing commercially available protein-based stains include those sold under the trade names ALCALASE™ and SAVINASE™ of Novo Industries and MAXATASE™ of International Bio-Synthetics, Inc. Other proteases include protease A. Protease B and proteases manufactured by Genencor International, Inc. in accordance with U.S. Patent No. 5,204,015 and U.S. Patent No. 5,244,791 are included.

[0121] Amylases include, for example, α - amylases such as RAPIDASE™ of International Bio-Synthetics and TERMAMYL™ of Novo Industries.

[0122] Suitable lipase enzymes for use in detergents include those produced by microorganisms of the Pseudomonas group of Pseudomonas stutzeri ATCC 19154. This lipase is available under the trade name Lipase P "Amano" from Amano Pharmaceutical Co., Ltd. Other commercially available lipases include Amano-CES, lipases from Chromobacterium viscosum, such as Chromobacterium viscosum var lipolyticum NRRLB3673 commercially available from Toyo Jozo Co., Ltd., further Chromobacterium viscosum lipases from US Biochemicals and De Soint, and lipases from Pseudomonas gladioli. The LIPOLASE™ enzyme derived from Humicola lanuginosa (commercially available from Novo Industries) is a preferred lipase for use herein.

[0123] Peroxidase enzymes are used in combination with an oxygen source, such as percarbonate, perborate, persulfate, hydrogen peroxide, etc. These are used for "solution bleaching", i.e., to prevent dyes or pigments removed from the substrate during the washing operation from migrating to other substrates in the wash liquor. Peroxidase enzymes are known in the art and include, for example, horseradish peroxidase, ligninase, and haloperoxidases such as chloroperoxidase and bromoperoxidase. Peroxidase-containing detergent compositions are disclosed, for example, in International Publication WO1989099813A1.

[0124] Stabilizers for enzymes. The enzymes employed herein are stabilized by the presence of a water-soluble source of calcium ions and / or magnesium ions in the finished detergent composition, which provides such ions to the enzyme. (Calcium ions are generally somewhat more effective than magnesium ions, and when only one type of cation is used, calcium is preferred herein). Additional stabilizers can be provided by the presence of various other art-disclosed stabilizers, particularly borate species; see U.S. Patent 4,537,706, which is hereby incorporated by reference in its entirety. A typical detergent, particularly a liquid, will contain from about 1 to about 30, preferably from about 2 to about 20, more preferably from about 5 to about 15, and most preferably from about 8 to about 12 millimoles of calcium ions per liter of the finished composition. In a solid detergent composition, the formulation can include an amount of a water-soluble calcium ion source sufficient to provide such an amount in the wash liquor. Alternatively, the hardness of natural water is sufficient.

[0125] It is understood that the foregoing levels of calcium ions and / or magnesium ions are sufficient to provide enzyme stability. To provide an additional measure of grease removal performance, more calcium and / or magnesium ions can be added to the composition. Thus, as a general proposition, the compositions herein will typically contain from about 0.05 wt% to about 2 wt% of a water-soluble source of calcium or magnesium ions, or both. The amount can, of course, vary depending on the amount and type of enzyme employed in the composition.

[0126] The compositions of the present specification can also optionally, but preferably, contain various additional stabilizers, especially borate type stabilizers. Typically, such stabilizers will be used at levels of about 0.25% - about 10%, preferably about 0.5% - about 5%, more preferably about 0.75% - about 3% by weight (calculated on the basis of boric acid) of boric acid or other borate compounds capable of forming boric acid in the composition. Boric acid is preferred, but other compounds such as boron oxide, borax and other alkali metal borates (e.g., sodium ortho-, meta- and pyroborates, as well as sodium pentaborate) are suitable. It is also possible to use substituted boric acids (e.g., phenylboronic acid, butaneboronic acid, p-bromophenylboronic acid) instead of boric acid.

[0127] Builder Zeolite. Synthetic zeolite in the form of microcrystals containing bound water can be used as a builder, for example, preferably zeolite A and / or P, zeolite MAP.RTM (a commercial product from Crosfield) can be used. However, zeolite X, as well as mixtures of A, X, Y and / or P are also suitable. The co-crystallized sodium / potassium aluminosilicate of zeolite A and zeolite X (Vegobond (trademark) RX (a commercial product from Condea Augusta S.p.A.) is also of particular interest. Preferably, the zeolite can be used as a spray-dried powder. When the zeolite is added as a suspension, this can consist of a small amount of non-ionic surfactant as a stabilizer, for example, an ethoxylated C12-C18 fatty alcohol having 2-5 ethylene oxide groups, a C12-C14 fatty alcohol having 4-5 ethylene oxide groups or an ethoxylated isotridecanol in an amount of 1-3% by weight based on the zeolite. Suitable zeolites have an average particle size of less than 10 μm (test method: volume distribution Coulter counter) and are preferably composed of 18-22% by weight, especially 20-22% by weight of bound water. Alternatively, phosphates can also be used as builders.

[0128] Layered silicate. Suitable alternatives or partial alternatives to phosphates and zeolites are crystalline sodium layered silicates. These types of crystalline layered silicates are described, for example, in Patent Publication EP0164514A1. Preferred crystalline layered silicates are, for example, those obtained from the process described in International Publication WO91 / 08171A1.

[0129] Amorphous silicate. Preferred builders also include amorphous silicates with a modulus (Na2O:SiO2 ratio) of 1:2 - 1:3.3, preferably 1:2 - 1:2.8, more preferably 1:2 - 1:2.6, which dissolve slowly and exhibit multiple wash cycle characteristics. The delay in dissolution compared to conventional amorphous sodium silicate can be obtained by various methods, such as surface treatment, compounding, compression / molding, or over-drying. In the context of the present invention, the term "amorphous" also means "X-ray amorphous". That is, the silicate does not produce any sharp X-ray reflections typical of crystalline substances in an X-ray diffraction experiment, and at most one or more maxima of scattered X-rays with a width of a few degrees of diffraction angle occur. However, particularly excellent builder properties can be achieved even when the silicate particles produce unclear or sharp diffraction maxima in an electron diffraction experiment. This is interpreted to mean that the product has microcrystalline regions with a size of 10 - several hundred nm, and values up to 50 nm, particularly up to 20 nm, are preferred. This type of X-ray amorphous silicate also has a delayed dissolution compared to conventional water glass and is described, for example, in German Patent Publication DE4400024A1. Compressed / densified amorphous silicates, compounded amorphous silicates, and over-dried X-ray amorphous silicates are particularly preferred.

[0130] Phosphate. Also, unless use should be avoided for ecological reasons, generally known phosphates can also be added as builders. Sodium salts of orthophosphates, pyrophosphates, and especially tripolyphosphates are particularly suitable. Their contents are generally 25% by weight or less, preferably 20% by weight or less, based on the finished composition. In some cases, especially tripolyphosphates, are already present in low amounts, up to a maximum of 10% by weight, based on the finished composition, and in combination with other builders, have been shown to provide a synergistic improvement in secondary detergency. The preferred amount of phosphate is 10% by weight or less, especially 0% by weight.

[0131] Co-builder Polycarboxylic acids. Useful organic cobuilders are, for example, polycarboxylic acids that can be used in the form of their sodium salts, where the polycarboxylic acid is understood to be a carboxylic acid carrying two or more acid functions. These include, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA) and its derivatives, and mixtures thereof. Preferred salts are salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids, and mixtures thereof.

[0132] Organic acids. Also, the acid itself can be used. In addition to its building effect, the acid also typically has the properties of an acidifying component and, therefore, also serves to establish a relatively low and mild pH in the detergent or cleansing composition. Citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid, and any mixtures thereof are particularly mentioned in this regard. Further suitable acidifying agents are known pH adjusters such as sodium hydrogen carbonate and sodium hydrogen sulfate.

[0133] Polymers. Particularly preferred polymer cobuilders are polyacrylates, which preferably have a molecular weight of 2,000 - 20,000 g / mol. Due to their excellent solubility, the preferred representatives of this group are also short-chain polyacrylates, which have a molecular weight of 2,000 - 10,000 g / mol, more particularly 3,000 - 5,000 g / mol. Suitable polymers may also include substances consisting partly or wholly of vinyl alcohol units or their derivatives.

[0134] Even more preferred copolymer polycarboxylates are, in particular, those of acrylic acid and methacrylic acid, and those of acrylic acid or methacrylic acid and maleic acid. Copolymers of acrylic acid and maleic acid, consisting of 50 - 90% by weight of acrylic acid and 50 - 10% by weight of maleic acid, have proven to be particularly suitable. Their relative molecular weight, based on the free acid, generally ranges from 2,000 - 70,000 g / mol, preferably 20,000 - 50,000 g / mol, particularly 30,000 - 40,000 g / mol. The (co)polymer polycarboxylate can be added as an aqueous solution or preferably as a powder. To improve water solubility, it is also possible for the polymer to contain allylsulfonic acids such as allyloxybenzenesulfonic acid and methallylsulfonic acid as monomers, as in European patent EP0727448B1.

[0135] Biodegradable polymers containing two or more different monomer units are particularly preferred, for example, those containing salts of acrylic acid and maleic acid as monomers, those containing vinyl alcohol or vinyl alcohol derivatives as in published DE4300772A1, or those containing monomers, salts of acrylic acid and 2-alkylallylsulfonic acid, and sugar derivatives. Even more preferred copolymers are those described in German published applications DE4303320A1 and DE4417734A1, preferably containing acrolein and acrylic acid / acrylic acid salt or acrolein and vinyl acetate as monomers.

[0136] Similarly, other preferred builders are polymeric aminodicarboxylic acids, their salts or precursors. Polyaspartic acid or its salts and derivatives disclosed in DE19540086A1 as having a bleaching stabilizing effect in addition to the properties of cobuilders are particularly preferred.

[0137] Further suitable builders are polyacetals which can be obtained by treating a polyol carboxylic acid having 5-7 carbon atoms and at least 3 hydroxyl groups with a dialdehyde as described in EP0280223A1. Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof, and polycarboxylic acids such as gluconic acid and / or glucoheptonic acid.

[0138] Carbohydrates. Further preferred organic cobuilders are dextrins, i.e., oligomers or polymers of carbohydrates which can be obtained by partial hydrolysis of starch. Hydrolysis can be carried out using typical processes, e.g., acidic processes or enzyme-catalyzed processes. The hydrolysis products preferably have an average molecular weight in the range of 400-500,000 g / mol. Polysaccharides having a dextrose equivalent (DE) of 0.5-40, more particularly 2-30, are preferred, where DE is a measure of the reducing effect of the polysaccharide compared to dextrose having a DE of 100. Both maltodextrins having a DE of 3-20 and dry glucose syrups having a DE of 20-37, as well as relatively high so-called yellow dextrins and white dextrins having a molecular weight of 2000-30000 g / mol can be used. Preferred dextrins are described in British patent application 9419091.

[0139] Such oxidized derivatives of dextrin relate to reaction products with an oxidizing composition capable of oxidizing at least one alcohol functional group of the saccharide ring to a carboxylic acid functional group. Such oxidized dextrins and methods for their production are known, for example, from published EP0232202A1. Products oxidized at C6 of the saccharide ring can be particularly advantageous.

[0140] Oxydisuccinates and other derivatives of succinates, preferably ethylenediamine disuccinate, are also more suitable cobuilders. Here, ethylenediamine-N,N'-disuccinate (EDDS), the synthesis of which is described, for example, in US3,158,615, is preferably used in the form of its sodium or magnesium salt. In this context, glycerol disuccinate and glycerol trisuccinate are also particularly preferred, such as those described in US4,524,009. Suitable addition amounts in zeolite-containing and / or silicate-containing formulations range from 3 - 15% by weight.

[0141] Lactone. Other useful organic cobuilders are, for example, acetylated hydroxycarboxylic acids and their salts, which may optionally also be present in lactone form and contain at least 4 carbon atoms, at least one hydroxyl group and at most 2 acid groups. Such cobuilders are described, for example, in international publication WO1995020029A1.

[0142] Bleaching compound, bleaching agent and bleaching activator The detergent compositions herein can optionally include a bleaching agent or a bleaching composition comprising a bleaching agent and one or more bleach activators. When present, the bleaching agent is typically at a level of about 1% to about 30%, more generally about 5% to about 20% of the detergent composition, particularly in the case of fabric washing. When present, the amount of bleach activator is typically from about 0.1% to about 60%, more typically from about 0.5% to about 40% of the bleaching composition comprising the bleaching agent + bleach activator.

[0143] The bleaching agents used in this specification can be any of the bleaching agents useful in detergent compositions for fabric washing, hard surface cleaning, or other cleaning purposes now known or which become known. These include oxygen bleaching agents and other bleaching agents. Sodium perborate bleaching agents, such as sodium perborate (e.g., monohydrate or tetrahydrate), can be used in this specification.

[0144] Another category of bleaching agents that can be used without limitation includes percarboxylic acid bleaching agents and their salts. Suitable examples of agents in this class include magnesium monoperoxyphthalate hexahydrate, magnesium salts of metachloroperbenzoic acid, 4-nonylamino-4-oxoperoxybutyric acid, and diperoxydodecanedioic acid.

[0145] Peroxygen bleaching agents can also be used. Suitable peroxygen bleaching compounds include sodium carbonate peroxyhydrate and equivalent "percarbonate" bleaching agents, sodium peroxypyrophosphate, urea peroxide hydrate, and sodium peroxide. Persulfate bleaching agents (e.g., OXONEO™ commercially manufactured by DuPont) can also be used.

[0146] Preferred percarbonate bleaching agents consist of dry particles having an average particle size in the range of about 500 micrometers to about 1,000 micrometers, with no more than about 10 weight percent of said particles being smaller than about 200 μm and no more than about 10 weight percent of said particles being larger than about 1,250 μm. Optionally, the percarbonate can be coated with a silicate, borate, or water-soluble surfactant. Percarbonates are available from a variety of commercial sources.

[0147] It is also possible to use bleaching agents in combination.

[0148] Peroxygen bleaching agents, perborates, percarbonates, etc. are preferably combined with a bleach activator, whereby the peroxy acid corresponding to the bleach activator is formed in situ in the aqueous solution (i.e., during the washing process). Nonanoyloxybenzenesulfonate (NOBS) and tetraacetylethylenediamine (TAED) activators are representative, and mixtures thereof can also be used.

[0149] Preferred amide-derived bleach activators include (6-octanamido-caproyl)oxybenzene-sulfonate, (6-nonanamido-caproyl)oxybenzene-sulfonate, (6-decanamido-caproyl)oxybenzene-sulfonate, and mixtures thereof.

[0150] Another class of bleach activators includes benzoxazine-type activators disclosed in U.S. Patent No. 4,966,723, which is incorporated herein by reference.

[0151] Highly preferred lactam activators include benzoylcaprolactam, octanoylcaprolactam, 3,5,5-trimethylhexanoylcaprolactam, nonanoylcaprolactam, decanoylcaprolactam, undecenoylcaprolactam, benzoylvalerolactam, octanoylvalerolactam, decanoylvalerolactam, undecenoylvalerolactam, nonanoylvalerolactam, 3,5,5-trimethylhexanoylvalerolactam, and mixtures thereof, optionally adsorbed on a solid carrier, such as acylcaprolactam, preferably benzoylcaprolactam, and adsorbed on sodium perborate.

[0152] Bleaching agents other than oxygen bleaching agents are also known in the art and can be utilized herein. One type of non-oxygen bleaching agent of particular interest includes photoactivatable bleaching agents such as sulfonated zinc and / or aluminum phthalocyanine. When used, the detergent composition typically contains from about 0.025% to about 1.25% by weight of such a bleaching agent, particularly zinc phthalocyanine sulfonate.

[0153] Optionally, the bleaching compound can be catalyzed by a manganese compound. Such manganese-based catalysts are well known in the art and include MnIV2(μ-O)3(1,4,7-trimethyl-1,4,7-triazacyclononane)2(PF6)2, MnIII2(μ-O)1(μ-OAc )2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)2, MnIV4(μ-O)6(1,4,7-triazacyclononane)4(ClO4)4, MnIIIMnIV4(μ-O)1(μ-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)3, MnIV(1,4,7-trimethyl-1,4,7-triazacyclononane)-(OCH3)3(PF6), and mixtures thereof.

[0154] As a practical matter, and not by way of limitation, the compositions and processes of this specification can be adjusted to provide on the order of one part per ten million of the active bleach catalyst species in the aqueous cleaning liquid, preferably providing from about 0.1 ppm to about 700 ppm, more preferably from about 1 ppm to about 500 ppm of the catalyst species in the wash liquor.

[0155] Polymeric antifouling agent The detergent compositions and processes of the present invention can optionally employ any polymeric soil release agent known to those skilled in the art. The polymeric soil release agent has a hydrophilic segment for hydrophilizing the surface of hydrophobic fibers such as polyester and nylon, and a hydrophobic segment that deposits on the hydrophobic fibers and remains attached thereto throughout the washing and rinsing cycles, thus functioning as an anchor for the hydrophilic segment. Thereby, the soil generated after treatment with the mold release agent can be more easily washed in a subsequent washing step.

[0156] Polymeric soil release agents useful herein include, in particular, soil release agents having the following. (a) One or more nonionic hydrophilic components consisting essentially of the following. (i) a polyoxyethylene segment with a degree of polymerization of 2 or more, or (ii) an oxypropylene or polyoxypropylene segment with a degree of polymerization of 2 - 10, provided that the hydrophilic segment does not contain any oxypropylene units unless they are bonded to adjacent sites at each end by an ether bond, or (iii) a mixture of oxyalkylene units consisting of oxyethylene and 1 - about 30 oxypropylene units. Here, the mixture contains a sufficient amount of oxyethylene units such that the hydrophilic component has a hydrophilicity large enough to enhance the hydrophilicity of the surface of a conventional polyester synthetic fiber during the deposition of the antifouling agent on such a surface. The hydrophilic segment preferably consists of at least about 25% oxyethylene units, and more preferably, for such a component having particularly about 20 - 30 oxypropylene units, it consists of at least about 50% oxyethylene units. Or (b) one or more hydrophobic components including the following. (i) A C3 oxyalkylene terephthalate segment. When the hydrophobic component also contains oxyethylene terephthalate, the ratio of oxyethylene terephthalate to oxyethylene terephthalate is 1:1. The C3 oxyalkylene terephthalate unit is about 2:1 or less. (ii) A C4 - C6 alkylene segment or an oxy C4 - C6 alkylene segment, or a mixture thereof. (iii) A poly(vinyl ester) segment having a degree of polymerization of at least 2, preferably poly(vinyl acetate), or (iv) A C1 - C4 alkyl ether or a C4 hydroxyalkyl ether substituent, or a mixture thereof. Here, the substituent is present in the form of a C1-C4 alkyl ether or a C4 hydroxyalkyl ether cellulose derivative or a mixture thereof, and such a cellulose derivative is amphiphilic, whereby a level of C1-C4 alkyl ether units and / or C4 hydroxyalkyl ether units sufficient to deposit on the surface of a conventional polyester synthetic fiber is provided, and once attached to such a conventional synthetic fiber surface, it retains a level of hydroxyl groups sufficient to increase the hydrophilicity of the fiber surface, or a combination of (a) and (b) is included.

[0157] Typically, the polyoxyethylene segment of (a)(i) can use a higher level, but will have a degree of polymerization from about 200, preferably from 3 to about 150, more preferably from 6 to about 100. Suitable oxy C4-C6 alkylene hydrophobic segments include, but are not limited to, end caps of high molecular weight antifouling agents.

[0158] Also, examples of the high molecular weight antifouling agents useful in the present invention include cellulose derivatives such as hydroxyether cellulose-based polymers, and copolymer blocks of ethylene terephthalate or propylene terephthalate and polyethylene oxide or polypropylene oxide terephthalate. Such agents are commercially available, and examples include hydroxyethers of cellulose such as METHOCEL (registered trademark) (manufactured by Dow). The cellulose-based antifouling agents used herein also include those selected from the group consisting of C1-C4 alkyl and C4 hydroxyalkyl celluloses.

[0159] Antifouling agents characterized by a poly(vinyl ester) hydrophobic segment include graft copolymers of poly(vinyl ester), for example, poly(vinyl acetate) grafted onto a polyalkylene oxide backbone such as a C1-C6 vinyl ester, preferably a polyethylene oxide backbone. See EP0219048. Commercially available antifouling agents of this type include SOKALAN (trademark) type materials, for example, SOKALAN (trademark) HP-22 available from BASF.

[0160] As one of the preferred antifouling agents, there may be mentioned a copolymer having random blocks of ethylene terephthalate and polyethylene oxide (PEO) terephthalate. The molecular weight of this polymeric antifouling agent is preferably in the range of about 25,000 to about 55,000.

[0161] Another preferred polymeric antifouling agent is a polyester having repeating units of ethylene terephthalate units and containing 10 - 15% by weight of ethylene terephthalate units together with 90 - 80% by weight of polyoxyethylene terephthalate units obtained from polyoxyethylene glycol having an average molecular weight of 300 - 5,000. Examples of this polymer include commercially available materials such as ZELCON™ 5126 (manufactured by DuPont) and MILEASE™ T (manufactured by ICI).

[0162] Another preferred polymeric antifouling agent is a sulfonated product of a substantially linear ester oligomer consisting of a terephthaloyl and oxyalkyleneoxy repeating unit oligomeric ester backbone and terminal sites covalently bonded to the backbone. These antifouling agents are fully described in US4,968,451. Other suitable polymeric antifouling agents include the terephthalic acid polyester of US4,711,730, the anionic end - capped oligomeric ester of US4,721,580, the block polyester oligomer compound of US4,702,857, and the anionic, particularly sulfoaroyl, end - capped terephthalate ester of US4,877,896, and all cited patents are incorporated herein by reference in their entirety.

[0163] Yet another preferred antifouling agent is an oligomer having repeating units of terephthaloyl units, sulfoisoterephthaloyl units, oxyethyleneoxy units and oxy-1,2-propylene units. The repeating units form the backbone of the oligomer and are preferably terminated with modified isethionate end caps. A particularly preferred antifouling agent of this type consists of about 1 sulfoisophthaloyl unit, 5 terephthaloyl units, a ratio of oxyethyleneoxy units and oxy-1,2-propyleneoxy units of from about 1.7 to about 1.8, and two end cap units of sodium 2-(2-hydroxyethoxy)-ethanesulfonate. The antifouling agent also consists of a crystalline reducing stabilizer selected from the group consisting of about 0.5% - about 20%, preferably xylene sulfonate, cumene sulfonate, toluene sulfonate, and mixtures thereof, by weight of the oligomer.

[0164] When utilized, the antifouling agent will generally constitute from about 0.01% - about 10.0% by weight, typically from about 0.1% - about 5% by weight, preferably from about 0.2% - about 3.0% by weight of the detergent compositions herein.

[0165] Polymeric dispersant The polymeric dispersant can be advantageously utilized at levels of from about 0.1% to about 7% by weight in the detergent compositions herein, particularly in the presence of zeolites and / or layered silicate builders. Suitable polymeric dispersants include polymeric polycarboxylates and polyethylene glycols, but other ones known in the art can also be used. Without intending to be limited by theory, it is believed that polymeric dispersants enhance the overall detergent builder performance by crystal growth inhibition, particulate soil release peptization, and anti-redeposition when used in combination with other builders (including low molecular weight polycarboxylates).

[0166] The coincident polycarboxylate material can be prepared by polymerizing or copolymerizing a suitable unsaturated monomer, preferably in its acid form. Unsaturated monomer acids that can be polymerized to form a suitable polymerizable polycarboxylate include acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid, and methylenemalonic acid. The presence of monomer segments free of carboxylate radicals such as vinyl methyl ether, styrene, ethylene, etc. in the polymeric polycarboxylate herein is suitable provided that such segments do not constitute more than about 40% by weight.

[0167] Particularly suitable polymerizable polycarboxylates can be derived from acrylic acid. Such acrylic acid-based polymers useful herein are water-soluble salts of polymerized acrylic acid. The average molecular weight of the acid form of such polymers is preferably in the range of about 2,000 - 10,000, more preferably about 4,000 - 7,000, and most preferably about 4,000 - 5,000. Examples of such water-soluble salts of acrylic acid polymers include alkali metal salts, ammonium salts, and substituted ammonium salts. This type of water-soluble polymer is a known material. The use of this type of polyacrylate in detergent compositions is disclosed, for example, in US 3,308,067.

[0168] In addition, it is also possible to use an acrylic / maleic acid copolymer as a preferred component of the dispersant / anti-redeposition agent. Examples of such materials include water-soluble salts of copolymers of acrylic acid and maleic acid. The average molecular weight of the acid form of such a copolymer is preferably in the range of about 2,000 - 100,000, more preferably about 5,000 - 75,000, and most preferably about 7,000 - 65,000. The ratio of acrylate segments to maleic acid segments in such a copolymer generally ranges from about 30:1 to about 1:1, more preferably from about 10:1 to 2:1. Examples of such water-soluble salts of acrylic acid / maleic acid copolymers include alkali metal salts, ammonium salts, and substituted ammonium salts. This type of water-soluble acrylic acid / maleic acid copolymer is a known material described in published EP0193360A1, which also describes such polymers composed of hydroxypropyl acrylate. Further useful dispersants include maleic acid / acrylic acid / vinyl alcohol terpolymers, such as a 45 / 45 / 10 terpolymer of acrylic acid / maleic acid / vinyl alcohol.

[0169] In addition, a polymer material such as polyethylene glycol (PEG) may also be included. PEG can exhibit performance as a dispersant and also act as an antifouling agent - anti-deposition agent. The typical molecular weight range for these purposes is from about 500 to about 100,000, preferably from about 1,000 to about 50,000, and more preferably from about 1,500 to about 10,000.

[0170] Dispersants such as polyaspartate and polyglutamate can also be used, especially in combination with zeolite builders. Dispersants such as polyaspartate preferably have a molecular weight (average) of about 10,000.

[0171] Foam inhibitor / foam suppressant In particular, when used in the automatic washing process, it may be advantageous to add a conventional anti-foaming agent to the composition. Suitable anti-foaming agents include, for example, soaps of natural or synthetic origin rich in C18-C24 fatty acids. Suitable non-surfactant type anti-foaming agents are, for example, organopolysiloxanes and fine particles, optionally their mixtures with silanized silica, and also paraffin, wax, microcrystalline wax and their mixtures with silanized silica or bis-stearylethylenediamide. Mixtures of various anti-foaming agents, for example, mixtures of silicone, paraffin or wax are also advantageously used. Preferably, the anti-foaming agent, especially the silicone-containing and / or paraffin-containing anti-foaming agent, is supported on a granular, water-soluble or dispersible carrier material. In particular in this case, a mixture of paraffin and bis-stearylethylenediamide is preferred.

[0172] Compounds for reducing or suppressing the formation of foam can be incorporated into the detergent composition of the present invention. Foam suppression can be particularly important in so-called "high-concentration washing processes" and front-loading European washing machines.

[0173] Also, a wide variety of materials can be used as the foam suppressant, and foam suppressants are well known to those skilled in the art. See, for example, Kirk Othmer Encyclopedia of Chemical Technology, Third Edition, Volume 7, pages 430-447 (John Wiley & Sons, Inc., 1979). One category of foam suppressants of particular interest includes monocarboxylic acid fatty acids and their soluble salts. The monocarboxylic acids and their salts used as foam suppressants typically have a hydrocarbyl chain of 10 - about 24 carbon atoms, preferably 12 - 18 carbon atoms. Suitable salts include alkali metal salts such as sodium salt, potassium salt, lithium salt, ammonium salt, alkanolammonium salt and the like.

[0174] The detergent composition of the present specification may also contain a foam inhibitor which is a non-surfactant. These include, for example, high molecular weight hydrocarbons such as paraffin, fatty acid esters (e.g., fatty acid triglycerides), fatty acid esters of monohydric alcohols, aliphatic C18-C40 ketones (e.g., stearone), etc. Other foam inhibitors include N-alkylated aminotriazines such as tri-hexalkylmelamine or di-tetraalkyldiamine chlorotriazine, propylene oxide formed as a product of cyanuric chloride and a first or second amine containing 1-24 carbon atoms in an amount of 2-3 moles, monostearyl phosphate esters and monostearyl dialkali metal (e.g., K, Na, and Li) phosphates and phosphate esters such as monostearyl phosphate. Hydrocarbons such as paraffin and haloparaffin can be used in a liquid state. The liquid hydrocarbon will be liquid at room temperature and atmospheric pressure, and will have a pouring point in the range of about -40°C to about 50°C, and a minimum boiling point of about 110°C (atmospheric pressure) or higher. Also, it is known to use waxy hydrocarbons preferably having a melting point of about 100°C or lower. Hydrocarbon-based foam inhibitors are known in the art and include aliphatic, alicyclic, aromatic, and heterocyclic saturated or unsaturated hydrocarbons having about 12 - about 70 carbon atoms. The term "paraffin" used in the discussion of this foam inhibitor is intended to include mixtures of true paraffins and cyclic hydrocarbons.

[0175] Another preferred category of foam inhibitors that are non-surfactants consists of silicone foam inhibitors. This category includes the use of polyorganosiloxane oils such as polydimethylsiloxane, dispersions or emulsions of polyorganosiloxane oils or resins, and combinations with silica particles in which the polyorganosiloxane is chemisorbed or fused onto the silica. Silicone foam inhibitors are well known in the art.

[0176] Other silicone foam suppressants are disclosed in US 3,455,839, which is incorporated herein by reference in its entirety, and relate to compositions and processes for defoaming aqueous solutions by incorporating small amounts of polydimethylsiloxane fluid therein.

[0177] Mixtures of silicone and silanized silica are described, for example, in DE-OS 2124526, which is incorporated herein by reference in its entirety. Silicone defoamers and foam control agents in granular detergent compositions are disclosed in US 4,652,392, which is incorporated herein by reference in its entirety.

[0178] In the preferred silicone foam suppressants used herein, the solvent of the continuous phase is preferably a specific polyethylene glycol or polyethylene - polypropylene glycol copolymer or mixtures thereof, or consists of polypropylene glycol. The primary silicone foam suppressant is branched / crosslinked and preferably not linear.

[0179] The silicone foam suppressants herein preferably consist of polyethylene glycol and polyethylene glycol / polypropylene glycol copolymers, both having an average molecular weight of less than about 1000, preferably about 100 - 800. The polyethylene glycol and polyethylene / polypropylene copolymers herein have a solubility in water at room temperature of about 2 wt% or more, preferably about 5 wt% or more.

[0180] The preferred solvents herein are polyethylene glycols with an average molecular weight of less than about 1000, more preferably about 100 - 800, most preferably 200 - 400, and polyethylene glycol / polypropylene glycol copolymers, preferably those of PPG200 / PEG300. Preferably, the weight ratio of polyethylene glycol: polyethylene - polypropylene glycol copolymer is about 1:1 - 1:10, most preferably 1:3 - 1:6.

[0181] Preferred silicone foam suppressants used herein do not contain polypropylene glycol, especially those having a molecular weight of 4,000. Also preferably, they do not contain block copolymers of ethylene oxide and propylene oxide such as PLURONIC (trademark) L101.

[0182] Other foam suppressants useful herein consist of secondary alcohols (e.g., 2-alkylalkanols) and mixtures of such alcohols with silicone oil. The secondary alcohols include C6-C16 alkyl alcohols having a C1-C16 chain. A preferred alcohol is 2-butyloctanol, which is available from Condea under the name ISOFOL (trademark) 12. A mixture of secondary alcohols is available from Enichem under the name ISALCHEM (trademark) 123. The mixed suppressors usually consist of a mixture of alcohol + silicone in a weight ratio of 1:5 to 5:1.

[0183] The compositions of this specification will generally contain from 0% to about 5% of a foam suppressant. When utilized as a foam suppressant, monocarboxylic acids, and their salts will typically be present in amounts up to about 5% by weight of the detergent composition. Preferably, a foam suppressant of an aliphatic monocarboxylate from about 0.5% to about 3% is utilized. Silicone foam suppressants are typically utilized in amounts up to about 2.0% by weight of the detergent composition, although higher amounts can be used. This upper limit has a realistic nature mainly from concerns about minimizing costs and the effectiveness of low amounts for effectively controlling foaming. Preferably, from about 0.01% to about 1% of a silicone foam suppressant is used, more preferably from about 0.25% to about 0.5%. As used herein, these weight percent values include any silica that can be utilized in combination with the polyorganosiloxane, and any auxiliary materials that can be utilized. Monostearyl phosphate foam suppressants are generally utilized in amounts in the range of about 0.1% to about 2% by weight of the composition. Hydrocarbon-based foam suppressants are generally utilized in amounts in the range of about 0.01% to about 5.0%, although higher levels can also be used. Alcohol foam suppressants are typically utilized at 0.2% to 3% by weight of the finished composition.

[0184] Blocking agent and chelating agent Salts of polyphosphonic acids can be considered as sequestering agents or stabilizers, especially for peroxide compounds and enzymes sensitive to heavy metal ions. Here, for example, the sodium salts of 1-hydroxyethane-1,1-diphosphonic acid, diethylenetriaminepentamethylenephosphonic acid or ethylenediaminetetramethylenephosphonic acid are used in amounts of 0.1 - 5% by weight.

[0185] In addition, the detergent composition of the present specification can optionally contain one or more chelating agents for iron and / or manganese. Such chelating agents can be selected from the group consisting of aminocarboxylates, aminophosphonates, polyfunctional substituted aromatic chelating agents, and mixtures thereof, all as defined below. Without wishing to be bound by theory, the advantages of these materials are thought to be due in part to their exceptional ability to remove iron and manganese ions from the washing solution by forming soluble chelates. Some of the detergent builders described herein can function as chelating agents, and it is understood that when such detergent builders are present in sufficient amounts, both functions can be provided.

[0186] Aminocarboxylates useful as optional chelating agents include ethylenediamine¬tetraacetate, N-hydroxyethylethylenediaminetriacetate, nitrilotriacetate, ethylenediaminetetrapropionate, triethylenetetraminehexacetate, diethylenetriaminepentacetate, and ethanol diglycine, their alkali metal, ammonium, and substituted ammonium salts, and mixtures thereof.

[0187] Aminophosphonates are also suitable for use as chelating agents in the compositions of the present invention when low levels of total phosphorus release in the detergent composition are acceptable, and include ethylenediaminetetrakis(methylenephosphonate) as DEQUEST. Preferably, these aminophosphonates do not contain an alkyl or alkenyl group having more than about 6 carbon atoms.

[0188] Polyfunctional substituted aromatic chelating agents are also useful in the compositions herein. Preferred compounds of this type in acid form are dihydroxydisulfobenzenes such as 1,2-dihydroxy-3,5-disulfobenzene.

[0189] Preferred biodegradable chelating agents for use herein are ethylenediamine disuccinate ("EDDS"), particularly the [S,S] isomer.

[0190] When utilized, these chelating agents will generally constitute from about 0.1% to about 10% by weight of the detergent compositions herein. More preferably, when utilized, the chelating agent will constitute from about 0.1% to about 3.0% by weight of such compositions.

[0191] Soil release agent / anti-deposition agent Also, the detergent compositions of the present invention can optionally contain water-soluble ethoxylated amines having soil removal and anti-deposition properties. Granular detergent compositions containing these compounds typically contain from about 0.01% to about 10.0% by weight of the water-soluble ethoxylate amine, and liquid detergent compositions typically contain from about 0.01% to about 5%.

[0192] The most preferred soil removal and anti-deposition agents are ethoxylated tetraethylenepentamine. Exemplary ethoxylated amines are further described in US 4,597,898. Other groups of preferred soil removal and anti-deposition agents are the cationic compounds disclosed in EP 0111965 A1, the ethoxylated amine polymers disclosed in EP 0111984 A1, the zwitterionic polymers disclosed in EP 0112592 A1, and the amine oxides disclosed in US 4,548,744. Another type of preferred anti-deposition agent includes carboxymethyl cellulose (CMC) materials. These materials are well known in the art.

[0193] Graining inhibitor The anti-redeposition agent has a function of floating the dirt removed from the fiber in the cleaning liquid and preventing the redeposition of the dirt. For this, water-soluble colloids mainly composed of organic substances are suitable, and examples thereof include water-soluble salts of (co)polymeric carboxylic acids, pastes, gelatin, starches, and salts of ether carboxylic acids and ether sulfonic acids of cellulose, or salts of acidic sulfuric esters of cellulose and starch. Further, water-soluble polyamides containing acidic groups are also suitable. Further, as the above starches, soluble starch preparations and the like can also be used, and for example, starch degradation products, aldehyde starches and the like can also be used. Further, polyvinylpyrrolidone can also be used. However, carboxymethyl cellulose (Na salt), methyl cellulose, hydroxyalkyl cellulose and methylhydroxyethyl cellulose, methylhydroxypropyl cellulose, methylcarboxymethyl cellulose and mixed ethers such as mixtures thereof, and polyvinylpyrrolidone can be preferably used, and these can be added in an amount of, for example, 0.1 to 5% by weight based on the composition.

[0194] Fluorescent brightener and ultraviolet absorber Any fluorescent brightener or other brightening agent or whitening agent known in the art can typically be incorporated into the detergent compositions herein at levels from about 0.05% to about 1.2% by weight. Commercially available fluorescent brighteners that can be useful in the present invention can be classified into subgroups, which include, but are not necessarily limited to, derivatives of stilbene, pyrazoline, coumarin, carboxylic acid, methine cyanine, dibenzothiophene-5,5-dioxide, azole, 5- and 6-membered heterocycles, and other miscellaneous agents.

[0195] Preferred brighteners include the PHORWHITE (trademark) series from Verona. Other brighteners disclosed in this reference are as follows. Tinopal (trademark) UNPA, Tinopal CBS and Tinopal 5BM; available from Ciba-Geigy; ArticWhite (trademark) CC and ArticWhite CWD, available from Hilton-Davis; 2-(4-stryl-phenyl)-2H-naphthol[1,2-d]triazole; 4,4'-bis-(1,2,3-triazol-2-yl)-stilbene; 4,4'-bis(stryl)bisphenol; and aminocoumarin. Specific examples of these brighteners include 4-methyl-7-diethyl-aminocoumarin; 1,2-bis(-benzimidazol-2-yl)ethylene; 1,3-diphenyl-furazoline; 2,5-bis(benzoxazol-2-yl)thiophene; 2-stryl naphtho-[1,2-d]oxazole; and 2-(stilben-4-yl)-2H-naphtho-[1,2-d]triazole. In this specification, anionic brighteners are preferred.

[0196] The composition may contain, for example, a derivative of diaminostilbene disulfonic acid or its alkali metal salt as a fluorescent brightener. Suitable fluorescent brighteners are, for example, salts of 4,4'-bis-(2-anilino-4-morpholino-1,3,5-triazinyl-6-amino)stilbene-2,2'-di-sulfonic acid or compounds with a similar structure having a diethanolamine group, a methylamine group, an aniline group or a 2-methoxyethylamine group instead of the morpholino group. Also, substituted diphenylstyryl type brighteners, for example, alkali metal salts of 4,4'-bis(2-sulfostyryl)diphenyl, 4,4'-bis(4-chloro-3-sulfostyryl)diphenyl or 4-(4-chlorostyryl)-4'-(2-sulfostyryl)diphenyl may be present. Also, mixtures of the aforementioned brighteners may be used.

[0197] Furthermore, an ultraviolet absorber may be added. These are compounds having a distinct absorption capacity for ultraviolet rays, which contribute as ultraviolet stabilizers and improve the light stability of colorants and pigments for both fiber fiber products and the skin of the wearer of fiber products by protecting them from ultraviolet rays passing through the fibers. Generally, efficient non-radiative inactivation compounds are derivatives of benzophenone substituted with a hydroxyl group and / or an alkoxy group, mainly substituted at the positions (2-position and / or 4-position). Also, substituted benzotriazoles, further acrylates (cinnamic acid derivatives) with a phenyl substitution at the 3-position, optionally having a cyano group at the 2-position, salicylates, organic Ni complexes, and also natural products such as umbelliferone and endogenous urocanic acid are suitable. In a preferred embodiment, the ultraviolet absorbers absorb UV-A and UV-B radiation as well as possible UV-C radiation and re-emit light of blue wavelengths, and thus they further have an optical brightening effect. Preferred ultraviolet absorbers include triazine derivatives, for example, hydroxyallyl-1,3,5-triazine, sulfone 1,3,5-triazine, o-hydroxyphenyl¬benzotriazole and 2-aryl-2H-benzotriazole and bis(anilinotriazinyl-amino) distyrylbenzene sulfonic acid and their derivatives. Also, as the ultraviolet absorber, an ultraviolet absorbing pigment such as titanium oxide can be used.

[0198] Dye migration inhibitor The detergent composition of the present invention can also contain one or more materials effective for suppressing the transfer of dyes from one fabric to another during the washing process. Generally, such dye transfer inhibitors include polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese phthalocyanine, peroxidase, and mixtures thereof. When used, these agents typically consist of about 0.01 wt% - about 10 wt%, preferably about 0.01% - about 5 wt%, more preferably about 0.05% - about 2 wt% of the composition.

[0199] More specifically, the polyamine N-oxide polymers preferred for use herein are described in US 6,491,728, which is incorporated herein by reference.

[0200] Any polymer backbone can be used as long as the amine oxide polymer formed is water-soluble and has dye transfer inhibition properties. Examples of suitable polymer backbones are polyvinyl, polyalkylene, polyester, polyether, polyamide, polyimide, polyacrylate, and mixtures thereof. These polymers include random copolymers or block copolymers where one monomer type is an amine N-oxide and the other monomer type is an N-oxide. The amine N-oxide polymers typically have a ratio of amine to amine N-oxide from 10:1 to 1:1,000,000. However, the number of amine oxide groups present in the polyamine oxide polymer can be varied by appropriate copolymerization or appropriate degree of N-oxidation. Also, the polyamine oxide can be obtained at substantially any degree of polymerization. Generally, the average molecular weight ranges from 500 to 1,000,000, more preferably from 1,000 to 500,000, and most preferably from 5,000 to 100,000. This preferred class of materials can be referred to as "PVNO".

[0201] The most preferred polyamine N-oxide useful in the detergent compositions herein is poly(4-vinylpyridine-N-oxide) having an average molecular weight of about 50,000 and an amine to amine N-oxide ratio of about 1:4.

[0202] Copolymers of N-vinylpyrrolidone and N-vinylimidazole polymer (referred to as "PVPVI" as a class) are also preferred for use herein. Preferably, PVPVI has an average molecular weight in the range of 5,000 to 1,000,000, more preferably 5,000 to 200,000, and most preferably 10,000 to 20,000. The PVPVI copolymer typically has a molar ratio of N-vinylimidazole to N-vinylpyrrolidone of 1:1 to 0.2:1, more preferably 0.8:1 to 0.3:1, and most preferably 0.6:1 to 0.4:1. These copolymers can be either linear or branched.

[0203] The compositions of the present invention can also employ polyvinylpyrrolidone ("PVP") having an average molecular weight of from about 5,000 to about 400,000, preferably from about 5,000 to about 200,000, and more preferably from about 5,000 to about 50,000. PVP is known to those skilled in the detergent art. Compositions containing PVP can also include polyethylene glycol ("PEG") having an average molecular weight of from about 500 to about 100,000, preferably from about 1,000 to about 10,000. Preferably, the ratio of PEG to PVP on a ppm basis delivered in the cleaning solution is from about 2:1 to about 50:1, more preferably from about 3:1 to about 10:1.

[0204] The detergent compositions herein can also optionally contain from about 0.005 wt% to 5 wt% of certain hydrophilic optical brighteners that also provide a dye transfer inhibition effect. When used, the compositions herein will preferably contain from about 0.01 wt% to 1 wt% of such optical brighteners.

[0205] One preferred brightener is 4,4’-bis[(4-anilino-6-(N-2-bishydroxyethyl)-s-triazin-2-yl)amino]-2,2’-stilbenedisulfonic acid disodium salt. This particular brightener species is commercially available from Ciba-Geigy under the trade name Tinopal-UNPA-GX™. Tinopal-UNPA-GX™ is a preferred hydrophilic fluorescent brightening agent useful in the detergent compositions of the present specification.

[0206] Another preferred brightener is 4,4’-bis[(4-anilino-6-(N-2-hydroxyethyl-N-methylamino)-s-triazin-2-yl)amino]2,2’-stilbenedisulfonic acid disodium salt. This particular brightener species is commercially available from Ciba-Geigy under the trade name Tinopal 5BM-GX™.

[0207] Another preferred brightener is 4,4’-bis[(4-anilino-6-morpholino-s-triazin-2-yl)amino]2,2’-stilbenedisulfonic acid, sodium salt. This particular brightener species is commercially available from Ciba-Geigy under the trade name “Tinopal AMS-GX™”.

[0208] The specific fluorescent brightener species selected for use in the present invention, when used in combination with the selected polymeric dye migration inhibitors described above herein, provide the advantage of particularly effective dye migration inhibition performance. Such a combination of a selected polymeric material (e.g., PVNO and / or PVPVI) and such a selected fluorescent brightener (e.g., Tinopal UNPA-GX, Tinopal 5BM-GX and / or Tinopal AMS-GX) provides significantly better dye migration inhibition in an aqueous cleaning solution than when either of the components of these two detergent compositions is used alone. Without being bound by theory, it is believed that such brighteners function in this way because they have a high affinity for fabrics in the washing solution and thus deposit on these fabrics relatively rapidly. The extent to which a brightener precipitates on the fabric of a washing solution can be defined by a variable called the "decay coefficient". The decay coefficient is generally the ratio of a) the brightener substance deposited on the fabric, b) the initial brightener concentration of the washing solution. Brighteners with a relatively high decay coefficient are most suitable for inhibiting dye migration in the context of the present invention.

[0209] Of course, it will be understood that other conventional fluorescent brightener type compounds can be optionally used in the composition to provide the advantage of the "brightness" of conventional fabrics rather than the true dye migration inhibition effect. Such usage is conventional and well known for detergent formulations. Thickener The composition can also consist of common thickeners and anti-precipitation compositions, and viscosity modifiers such as polyacrylates, polycarboxylic acids, polysaccharides and their derivatives, polyurethanes, polyvinylpyrrolidone, castor oil derivatives, polyamine derivatives such as quaternized and / or ethoxylated hexamethylenediamine and any mixtures thereof. Preferred compositions have a viscosity of less than 10,000 mPa*s as measured with a Brookfield viscometer at a temperature of 20°C and a shear rate of 50 min-1.

[0210] Inorganic salts Even more suitable components of the composition are water-soluble inorganic salts such as bicarbonates, carbonates, amorphous silicates or mixtures thereof. Alkali carbonates and amorphous silicates are particularly used, and those having a molar ratio of Na2O:SiO2 of 1:1 to 1:4.5, preferably 1:2 to 1:3.5, mainly sodium silicate, are used. Preferred compositions contain alkali salts, builders and / or cobuilders, preferably sodium carbonate, zeolite, crystalline, layered sodium silicate and / or trisodium citrate, in an amount of 0.5 to 70% by weight, preferably 0.5 to 50% by weight, particularly 0.5 to 30% by weight of the anhydrous substance.

[0211] For industrial application examples Another object of the present invention is for other fragrances (a) enhancing the musk note and freshness, and / or (b) introducing a marine note, and / or (c) imparting the effect of natural geranium, and / or (d) creating a dry orris aspect; and / or (e) enhancing the impact of the green note. And the method consists of the following steps. (i) Providing at least one fragrance different from carvone, optionally dissolved in a cosmetically acceptable carrier. (ii) Blending the at least one fragrance or fragrance solution with an effective amount of carvone.

[0212] Finally, another object of the present invention is directed to the use of carvone for the following. For other fragrances (a) enhancing the musk scent and freshness, and / or (b) introducing a marine note, and / or (c) imparting the natural geranium effect, and / or (d) creating the aspect of dry orris, and / or (e) enhancing the impact of the green note.

[0213] For good fragrance, it is emphasized that all the preferred embodiments, combination ranges, etc. disclosed above are also applicable to the industrial applications of the mixtures, capsules and compositions of the present invention. Therefore, it is not necessary to repeat them.

Example 1

[0214] Enhancement of musk fragrance A 1% by weight solution of muscone in triethyl citrate (TEC) was prepared and formulated with 0.001% by weight of carvomenthol. This mixture was used in different amounts as a fragrance for formulating detergents and personal care products using standard formulations. For comparison, a similar composition consisting of the same amount of muscone but without carvomenthol was used for the preparation of the same products.

[0215] The following product formulations were tested (the amounts of fragrance are in parentheses). A) Body lotion type O / W (0.3% by weight) B) Shampoo, transparent (0.5% by weight) C) Antiperspirant, roll-on 15% ACH (1.0% by weight) D) Fabric softener (0.6% by weight) E) High durability powder detergent (0.3% by weight) F) All-purpose cleaner, liquid pH = 8 - 10 (0.3% by weight) G) Manual dishwashing machine, liquid (0.5% by weight) H) High viscosity liquid detergent (0.5% by weight) I) EDT / ethanol 80% by weight (4.0% by weight) J) Soap (1.2% by weight)

[0216] All products were stored for 10 hours and judged by 5 testers for the intensity (immediate) and persistence (after 20 minutes) of the musk fragrance on a scale from (5) = very strong to (1) = weak. The results are shown in Table 2A.

Table 15

[0217] In the examples of the present invention and the comparative examples, it has been clearly shown that by adding a small amount of carvone that has no musk note at all, the scent of a typical musk fragrance such as muscone can be significantly enhanced and made to last longer.

[0218] Essential oil mixture In the following four perfume mixtures, those named P1 - P4 are provided. All amounts are shown in weight %. [Table 16] [Table 17] [Table 18] [Table 19]

[0219] Formulation examples of cosmetic and detergent compositions The following Examples F1 to F56 show various preparations of cosmetic compositions and pharmaceutical compositions containing the perfume mixtures P1 to P4 of the present invention. [Table 20] [Table 21] [Table 22] [Table 23] [Table 24]

Table 25

Table 26

Table 27

Table 28

Table 29

Table 30

Table 31

Table 32

Table 33

Table 34

Table 35

Table 36

Table 37

Table 38

Table 39

Table 40

Table 41

Table 42

Table 43

Table 44

Table 45

Table 46

Table 47

Table 48

Table 49

Table 50

Table 51

Table 52

Table 53

Table 54

Table 55

Table 56

Table 57

Table 58

Table 59

Table 60

Table 61

Table 62

Table 63

Table 64

Table 65

Table 66

Table 67

Table 68

Table 69

Table 70

Table 71

Table 72

Table 73

Table 74

Table 75

Claims

1. (a) carvone, (b) at least one perfume different from compound (a), and (c) optionally at least one cosmetically acceptable carrier, consisting of or consisting only of, the perfume of the component (b) is a perfume mixture selected from the group consisting of globanone, cyclohexadecenone-8, globalide, habanolide, macrolide, cyclopentadecanolide, exaltolide, pentalide galaxolide, tonalide, helvetolide, ethylene brassylate, romandolide, ambrettolide, dihydroambrettolide, aureolide, exaltenone, isomuscone, muscone, muscenone, verveione, civetone, ambretteseed oil, musk ketone, ambroxanide, cetalox, and mixtures thereof.

2. The perfume mixture according to claim 1, wherein the carvone is at least one selected from the following compounds I to XIII, mixtures thereof and racemates. I: cyclohexanone, 2-methyl-5-(1-methylethyl)-, (2S) (CAS registration number 1933680-55-7) II: cyclohexanone, 2-methyl-5-(1-methylethyl)-, (2R) (CAS registration number 1933468-55-3) III: cyclohexanone, 2-methyl-5-(1-methylethyl)-, (5S) (CAS registration number 160168-89-8) IV: cyclohexanone, 2-methyl-5-(1-methylethyl)-, didehydro derivative (9CI) (CAS registration number 147965-30-8) V: cyclohexanone, 2-methyl-5-(1-methylethyl)-, (5R) (CAS registration number 127911-15-3) VI: cyclohexanone, 2-methyl-5-(1-methylethyl)- (CAS registration number 59471-80-6) VII: cyclohexanone, 2-methyl-5-(1-methylethyl)-, (2R,5S)-(CAS registration number 13163-74-1) VIII: cyclohexanone, 2-methyl-5-(1-methylethyl)-, (2S,5S)-(CAS registration number 13163-73-0) IX: cyclohexanone, 2-methyl-5-(1-methylethyl)-, (2S,5R)-(CAS registration number 7065-48-7) X: cyclohexanone, 2-methyl-5-(1-methylethyl)-, (2R,5R)-(CAS registration number 5206-83-7) XI: Cyclohexanone, 2-methyl-5-(1-methylethyl)-, (2R,5S)-rel- (CAS Registry Number 3901-91-5) XII: p-menthan-2-one-1,3,3-d3 (7CI,8CI) (CAS Registry Number 1012-38-0) XIII: Cyclohexanone, 2-methyl-5-(1-methylethyl)-, (2R,5R)-rel- (CAS Registry Number 499-70-7)

3. The perfume mixture according to claim 1, wherein the carvone (a) is 0.0001 - 0.01% by weight.

4. The perfume mixture according to claim 1, wherein the carvone (a) is 0.0005 - 0.005% by weight.

5. The perfume mixture according to claim 1, wherein the carrier (c) is water, ethanol, triethyl citrate or a mixture thereof.

6. (a) 0.00001 - 5% by weight of carvone, (b) 99.9999 - 95% by weight of at least one perfume different from component (a), and (c) 0 - 4.99999% by weight of at least one carrier, with all amounts being subject to the condition that they total 100% by weight, the perfume mixture according to claim 1.

7. A capsule containing the perfume mixture according to claim 1.

8. A cosmetic composition containing either the perfume mixture according to claim 1 or the capsule according to claim 7.

9. The cosmetic composition according to claim 8, which represents a skin care, personal care, hair care or sun care composition.

10. W / O (water-in-oil), O / W (oil-in-water), W / O / W (water-in-oil-in-water) emulsions, PIT emulsions, pickering emulsions, emulsions with low oil content, micro or nano emulsions, solutions, in oil or silicone oil, dispersions, suspensions, creams, lotions or milks, hydrogels, hydrodispersion gels, oleogels, sprays or foams or impregnating liquids for cosmetic wipes, soaps, synthetic detergents, liquid detergents, shower and bath agents, bath salts, foaming agents, ointments, pastes, oils, balsams, beauty liquids, powders, perfumes, eau de toilette, aftershave, masks, pencils, sticks, roll-ons, pumps, aerosols, deodorants and / or antiperspirants, mouthwashes, foot care products, insect repellents, sunscreens, aftersun lotions, shaving products, aftershave balms, pre & aftershave lotions, depilatory agents, 2-in-1 shampoos, anti-dandruff shampoos, baby shampoos, shampoos for dry scalps, concentrated shampoos, conditioners, hair tonics, hair waters, hair rinses, styling creams, pomades, perm setting lotions, hair sprays, styling agents, hair smoothing agents, hair dyes, temporary hair dyes, semi-permanent hair dyes, permanent hair dyes, hair conditioners, hair mousses, eye care products, make-up, make-up removers or baby products, the composition according to claim 8.

11. A detergent composition comprising any one of the perfume oil mixture according to claim 1 or the capsules according to claim 7.

12. The detergent composition according to claim 11, representing a light detergent, a heavy detergent, a fabric softener, a manual dishwashing detergent or a cleaner.

13. The detergent composition according to claim 11, representing a powder, a granule, a tablet, a liquid, a gel or a capsule.

14. A method for enhancing the musk note and freshness of other fragrances, comprising: (i) providing at least one fragrance different from carvone, optionally dissolved in a cosmetically acceptable carrier; and (ii) blending said at least one fragrance or fragrance solution with an effective amount of carvone. A method, wherein the fragrance different from said carvone is selected from the group consisting of globanone, cyclohexadecenone-8, globalide, habanolide, macrolide, cyclopentadecanolide, exaltolide, pentalide galaxolide, tonalide, helvetolide, ethylene brassylate, muscone T, romandolide, ambretolide, dihydroambretolide, aureline, exaltenone, isomuscone, muscone, muscenone, verveione, civetone, ambretteseed oil, musk ketone, ambroxide, cetalox, and mixtures thereof.

15. The use of carvone for enhancing the musk note and freshness of other fragrances, wherein the fragrance different from said carvone is selected from the group consisting of globanone, cyclohexadecenone-8, globalide, habanolide, macrolide, cyclopentadecanolide, exaltolide, pentalide galaxolide, tonalide, helvetolide, ethylene brassylate, muscone T, romandolide, ambretolide, dihydroambretolide, aureline, exaltenone, isomuscone, muscone, muscenone, verveione, civetone, ambretteseed oil, musk ketone, ambroxide, cetalox, and mixtures thereof; the use of carvone.

Images