Composition for cosmetic

Abstract

To provide a cosmetic composition with low fusion temperature which can significantly improve touch of hair, and can maintain its effect for a long period of time even if shampooing is repeated.SOLUTION: A cosmetic composition containing the following components (A) and (B) is used. (A) A compound expressed by the following general formula (1) or salt thereof (Chemical formula 1), (in the formula, R1 denotes a straight-chain saturated hydrocarbon group with a carbon number 11 to 23, n denotes an integer from 1 to 10). (B) One or more selected from the following components (B1) and (B2): (B1) ester oil that is liquid at 25°C, branched higher alcohol, branched higher fatty acid, and unsaturated higher fatty acid; and (B2) polyoxyethylene fatty acid ester and polyoxyethylene alkyl ether.SELECTED DRAWING: None

Description

Technical Field

[0001] The present invention relates to a composition for cosmetics.

Background Art

[0002] Hair is constantly damaged daily by chemical treatments such as perms, bleaches, hair colors, ultraviolet rays from sunlight, heat from dryers, brushing, etc. When hair is damaged in this way, it has been found that the long-chain fatty acids on the surface of the cuticle are desorbed, and this damage to the surface of the cuticle worsens the slipperiness and combability of the hair, and is one of the factors causing the feeling of hair damage. As a method for improving such hair damage, methods using long-chain fatty acids or quaternary compounds of long-chain fatty acids have been attempted (Patent Documents 1 and 2). However, with these methods, the components are washed away by daily hair washing, etc., and it is difficult to maintain the effect for a long period of time.

[0003] Lactic acid fatty acid esters (acyl lactic acids) have long been used mainly for hair cosmetic applications as cosmetic raw materials, and are used not only to impart detergency as surfactants but also as components for improving the feel of hair (for example, Patent Documents 3 to 5). However, the improvement effect is not always sufficient. Patent Document 6 describes that oligo lactic acid fatty acid esters can be used as surfactants for detergents, but the effect of improving hair with this compound is not described.

Prior Art Documents

Patent Documents

[0004]

Patent Document 1

Patent Document 2

Patent Document 3

Patent Document 4

Patent Document 5

Patent Document 6

Summary of the Invention

Problems to be Solved by the Invention

[0005] An object of the present invention is to provide a cosmetic composition that has an excellent effect of improving the feel of hair and can exhibit this effect for a long period of time.

[0006] As a result of intensive studies to solve the above problems, the present inventors have found that the compound represented by the following general formula (1) has an excellent effect of improving the feel of hair and can maintain this effect for a long period of time even when hair washing is repeated.

Chem.

[0007] However, it was found that the compound represented by the general formula (1) has a high melting point. When such a high-melting-point compound is distributed as a raw material for cosmetics, a method of processing it into flakes or pellets is used to improve handleability. However, during the processing of flakes or pellets, since they are exposed to air at a high temperature and with a large specific surface area, there is a concern of coloring and off-odor, and also, since new processing equipment needs to be introduced, it becomes a burden in terms of cost. On the other hand, it is more advantageous in terms of coloring and off-odor and cost to fill and distribute the high-melting-point compound from the kettle in a molten state after production into a 60-kilogram can or a drum can. However, in this case, it is necessary to reheat and melt the raw material filled in the 60-kilogram can or the drum can and take it out. For this reason, equipment for heating the 60-kilogram can or the drum can at a temperature sufficiently higher than the melting point is required, and there is a problem that it cannot be used by cosmetics manufacturers who do not have such equipment. Therefore, another object of the present invention is to provide a cosmetic composition that does not require equipment for melting at a high temperature in cosmetics manufacturers when filling and distributing the compound represented by the general formula (1) as a raw material for cosmetics into a 60-kilogram can or a drum can.

Means for Solving the Problems

[0008] As a result of intensive studies to solve the above problems, the present inventors have found that a cosmetic composition containing the following components (A) and (B) can solve the problems of the present invention, and have completed the present invention. (A) A compound represented by the following general formula (1) or a salt thereof

Chem.

[0009] The cosmetic composition of the present invention has an excellent effect of improving the feel on hair and can exhibit this effect for a long period of time. In addition, compared with only component (A), it can be melted at a lower temperature, and when filling and distributing as a raw material for cosmetics in a keg or a drum can, there is no need for equipment to melt it at a high temperature. [Modes for Carrying Out the Invention]

[0010] The cosmetic composition of the present invention contains the following components (A) and (B). (A) A compound represented by the following general formula (1) or a salt thereof [Chemical formula] (In the formula, R1 is a linear saturated hydrocarbon group having 11 to 23 carbon atoms, and n represents an integer of from 1 to 10.) (B) One or more selected from the following components (B1) and (B2) (B1) An ester oil, a branched higher alcohol, a branched higher fatty acid, and an unsaturated higher fatty acid that are liquid at 25°C (B2) A polyoxyethylene fatty acid ester and a polyoxyethylene alkyl ether

[0011] The compound represented by the general formula (1) of component (A) used in the present invention is synthesized by an esterification reaction of a higher fatty acid and lactic acid.

[0012] As the lactic acid used in the synthesis of the compound represented by the general formula (1) of the present invention, any of L-lactic acid, D-lactic acid, and DL-lactic acid can be used, but L-lactic acid can be preferably used from the viewpoints of availability and economy. Further, oligolactic acid obtained by polymerizing lactic acid may be used as a starting material. Oligolactic acid can be produced by polycondensing lactic acid while distilling off the generated water by heating it at 100 to 180°C, more preferably 130 to 170°C.

[0013] R1 of the compound represented by the general formula (1) of the present invention represents a residue of a higher fatty acid, that is, a hydrocarbon group excluding the carboxyl group portion of the higher fatty acid. As the higher fatty acid used in the synthesis of the compound represented by the general formula (1) of the present invention, a higher fatty acid having a linear saturated hydrocarbon group with 11 to 23 carbon atoms can be used, and 15 to 21 carbon atoms are more preferable. Specific examples of the higher fatty acid include dodecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, heptadecanoic acid, octadecanoic acid, nonadecanoic acid, eicosanoic acid, docosanoic acid, and the like. These may be used alone or in combination of two or more. Among these, hexadecanoic acid, octadecanoic acid, eicosanoic acid, and docosanoic acid are preferable, and octadecanoic acid is most preferable from the viewpoints of availability and more effectively exerting the hair feel improving effect.

[0014] The manufacturing method of the compound of general formula (1) of the present invention will be described. First, the charging ratio of the raw material higher fatty acid and lactic acid may be 1.0:1.0 to 1.0:10.0 in molar ratio, preferably 1.0:1.1 to 1.0:8.0, more preferably 1.0:1.2 to 1.0:7.0, and most preferably 1.0:1.5 to 1.0:6.0. A basic catalyst is preferably used as the catalyst. Specifically, metal hydroxides such as potassium hydroxide, sodium hydroxide, and lithium hydroxide; metal carbonates such as sodium hydrogen carbonate, potassium hydrogen carbonate, potassium carbonate, and sodium carbonate; metal alkoxides such as potassium methoxide, sodium methoxide, potassium ethoxide, sodium ethoxide, potassium - t - butoxide, and sodium - t - butoxide can be mentioned. Among these, potassium hydroxide, sodium hydroxide, potassium carbonate, sodium carbonate, potassium methoxide, and sodium methoxide are preferably mentioned. The amount of the catalyst used is preferably 0.1 to 2.0 moles per 1 mole of the fatty acid, and more preferably 0.2 to 1.5 moles. The reaction temperature is preferably carried out at 100 to 260 °C, preferably 150 to 220 °C. The reaction time is preferably 0.5 to 10 hours, preferably 0.5 to 3 hours. The reaction product obtained under such conditions can be used as the compound of the present invention as it is, but it may also be neutralized and used in the form of a salt, or further purified by extraction, deacidification, washing with water, recrystallization, adsorption purification, distillation, column purification, etc. and then used.

[0015] In the compound of the general formula (1) of the present invention, n represents the degree of polymerization of lactic acid. In the present invention, those with n in the range of 1 to 10 can be used, and those in the range of 1 to 8 are more preferably used. In the present invention, a compound with a single degree of polymerization can be used as the compound of the general formula (1). However, according to the aforementioned production method, since it is obtained as a mixture of compounds with different degrees of polymerization, it is preferable to use such a mixture in the present invention. Further, in the present invention, it is preferable to contain a compound with a degree of polymerization of 2 or more. By containing a compound with a degree of polymerization of 2 or more, the effect of the present invention can be further improved. From such a viewpoint, the average degree of polymerization of lactic acid is preferably greater than 1.0. Specifically, the average degree of polymerization of lactic acid is preferably 1.05 or more, more preferably 1.1 or more, and most preferably 1.2 or more. If the average degree of polymerization is smaller than this, the content of the compound with a degree of polymerization of 2 or more will be reduced, and the effect of the present invention may not be fully exhibited. Also, the upper limit of the average degree of polymerization of lactic acid is preferably 6.0 or less, more preferably 4.0 or less, and most preferably 3.0 or less. If the average degree of polymerization is greater than this, the content of the compound with a high degree of polymerization will be too high, and the effect of the present invention may not be fully exhibited. In the above production method, the closer the charging ratio of lactic acid to 1.0 mol of fatty acid is to 1.0 mol, the more the compound with n = 1 is produced. As the charging ratio of lactic acid to 1.0 mol of fatty acid increases beyond 1.0 mol, more compounds with n greater than 1 are produced. Therefore, it is possible to adjust the average degree of polymerization of lactic acid by changing the charging ratio. Further, according to the aforementioned production method, in addition to the compound represented by the general formula (1), the reaction product contains unreacted higher fatty acid and lactic acid as reaction raw materials, and also contains a polymer of lactic acid (oligo lactic acid) as a by-product. In the present invention, those containing such components can be used as they are.

[0016] The compound represented by the general formula (1) of the present invention has a structure with a carboxylic acid at the terminal and is in the acid form, but in the present invention, those in the form of a salt of a carboxylic acid can also be used. The salt is not particularly limited, but specifically, alkali metal salts such as sodium and potassium; alkaline earth metal salts such as calcium and magnesium; metal salts such as aluminum, iron, and zinc; basic amino acid salts such as lysine, arginine, guanidine, histidine, and ornithine; organic amine salts such as ammonium, monoethanolamine, diethanolamine, triethanolamine, and stearylamine, etc. can be mentioned. The hair improving effect of the present invention can exhibit its effect in either the acid form or the salt form.

[0017] Component (B1) used in the present invention is an ester oil, a branched higher alcohol, a branched higher fatty acid, and an unsaturated higher fatty acid that are liquid at 25°C, and there is no particular limitation as long as the compound corresponds to these. Specific examples are as follows. As the ester oil that is liquid at 25°C, there are diethylhexyl succinate, diisopropyl adipate, diisobutyl adipate, diethyl sebacate, diisopropyl sebacate, diethylhexyl sebacate, isopropyl myristate, hexyldecyl myristate, octyldodecyl myristate, isopropyl palmitate, ethylhexyl palmitate, octyldodecyl palmitate, cetyl ethylhexanoate, hexyldecyl ethylhexanoate, isononyl isononanoate, isodecyl isononanoate, isotridecyl isononanoate, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyldodecyl neodecanoate, ethyl oleate, oleyl oleate, octyldodecyl oleate, isopropyl isostearate, octyldodecyl isostearate, octyldodecyl erucate, isopropyl lanolin fatty acid, octyldodecyl lanolin fatty acid, glyceryl triethylhexanoate, glyceryl tricaprylate, glyceryl tricaprate, glyceryl tri(caprylate / caprate), glyceryl trioleate, glyceryl triisostearate, glyceryl isostearate, diglyceryl diisostearate, polyglyceryl-2 isostearate, polyglyceryl-2 diisostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 oleate, trimethylolpropane triethylhexanoate, pentaerythrityl tetraethylhexanoate, 3-methyl-1,5-pentanediol dineopentanoate, 2,4-diethyl-1,5-pentanediol dineopentanoate, sorbitan oleate, sorbitan isostearate, ethylhexyl hydroxystearate, triethyl citrate, diisostearyl malate, dicaprylyl carbonate, and vegetable oils such as jojoba oil, etc. Examples of branched higher alcohols that are liquid at 25°C include 2-ethylhexanol, 6-methyl-2-heptanol, isononyl alcohol, isodecyl alcohol, isoundecyl alcohol, isododecyl alcohol, 2-butyloctanol, isotridecyl alcohol, isotetradecyl alcohol, isopentadecyl alcohol, isohexadecyl alcohol, 2-hexyldecanol, isoheptadecyl alcohol, isostearyl alcohol, isononadecyl alcohol, isoeicosanol, 2-octyldodecanol, isoheneicosanol, 18-methyleicosanol, isodocosanol, 2-decyltetradecanol, etc. Examples of branched higher fatty acids that are liquid at 25°C include isononanoic acid, isodecanoic acid, dimethyloctanoic acid, isoundecanoic acid, isododecanoic acid, isotridecanoic acid, isotetradecanoic acid, isopentadecanoic acid, isohexadecanoic acid, isoheptadecanoic acid, isostearic acid, isononadecanoic acid, isoeicosanoic acid, 2-ethylhexanoic acid, 2-butyloctanoic acid, 2-hexyldecanoic acid, 2-octyldodecanoic acid, 2-decyltetradecanoic acid, 2-dodecylhexadecanoic acid, 2-tetradecyloctadecanoic acid, 2-hexadecyleicosanoic acid, etc. Examples of unsaturated higher fatty acids that are liquid at 25°C include undecenoic acid, myristoleic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid, elaidic acid, gadoleic acid, eicosapentaenoic acid, docosahexaenoic acid, erucic acid, brassidic acid, arachidonic acid, etc.

[0018] Among these, from the viewpoints of availability and more fully exhibiting the effects of the invention, diethylhexyl succinate, diisopropyl adipate, diethylhexyl adipate, diethyl sebacate, diisopropyl sebacate, diethylhexyl sebacate, isopropyl myristate, hexyldecyl myristate, isopropyl palmitate, ethylhexyl palmitate, cetyl ethylhexanoate, ethyl oleate, glyceryl triethylhexanoate, tri(caprylic acid / capric acid) glyceryl, glyceryl isostearate, diglyceryl diisostearate, polyglyceryl-2 isostearate, polyglyceryl-2 diisostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 oleate, trimethylolpropane triethylhexanoate, pentaerythrityl tetraethylhexanoate, sorbitan oleate, sorbitan isostearate, ethylhexyl hydroxystearate, distearyl malate, jojoba oil, isostearyl alcohol, octyldodecanol, isostearic acid, oleic acid are preferably exemplified.

[0019] As the polyoxyethylene fatty acid ester and polyoxyethylene alkyl ether of the component (B2) used in the present invention, there is no particular limitation as long as they are compounds corresponding thereto. Specific examples are as follows. As the polyoxyethylene fatty acid ester, polyoxyethylene monocaprate, polyoxyethylene monocaprylate, polyoxyethylene monolaurate, polyoxyethylene monomyristate, polyoxyethylene monopalmitate, polyoxyethylene monostearate, polyoxyethylene monooleate, polyoxyethylene monoisostearate, polyoxyethylene monobehenate, polyoxyethylene dicape rate, polyoxyethylene dicaprylate, polyoxyethylene dilaurate, polyoxyethylene dimyristate, polyoxyethylene dipalmitate, polyoxyethylene distearate, polyoxyethylene dioleate, polyoxyethylene diisostearate, polyoxyethylenedibehenate and the like are exemplified. Examples of the polyoxyethylene alkyl ether include polyoxyethylene caprylether, polyoxyethylene caprylylether, polyoxyethylene laurylether, polyoxyethylene myristylether, polyoxyethylene cetylether, polyoxyethylene stearylether, polyoxyethylene oleylether, polyoxyethylene behenyl ether, polyoxyethylene isostearylether, polyoxyethylene octyldodecyl ether, polyoxyethylene cholesteryl ether, polyoxyethylene phytosterol ether and the like.

[0020] Among these, from the viewpoints of availability and more effectively exerting the effects of the invention, polyoxyethylene monolaurate, polyoxyethylene monopalmitate, polyoxyethylene monostearate, polyoxyethylene monooleate, polyoxyethylene monoisostearate, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene behenyl ether, polyoxyethylene isostearyl ether, polyoxyethylene octyldodecyl ether are preferably mentioned.

[0021] Component (B) used in the present invention is selected from one or more selected from the above-mentioned components (B1) and (B2). The cosmetic composition of the present invention is obtained by mixing and dissolving components (A) and (B) at a temperature equal to or higher than the melting temperature. By doing so, the melting temperature can be lowered as compared with the case of only component (A).

[0022] In the composition for cosmetics of the present invention, the blending amounts of components (A) and (B) are not particularly limited. However, it is preferable that the blending amount of component (A), which is the active ingredient for improving hair in the present invention, is larger, because the effect can be exerted with a smaller addition amount as a cosmetic raw material. On the other hand, if the blending amount of component (A) is large, the melting temperature may not be sufficiently reduced. From such a viewpoint, the blending amount of component (A) is 10 to 90% by mass, preferably 30 to 90% by mass, more preferably 50 to 85% by mass. In view of the blending amount of component (A), the blending amount of component (B) is 10 to 90% by mass, preferably 10 to 70% by mass, more preferably 15 to 50% by mass.

[0023] Component (B) used in the present invention is selected from one or more selected from the above-mentioned components (B1) and (B2). However, from the viewpoint of further reducing the melting temperature of the composition for cosmetics of the present invention, it is more preferable to contain both components (B1) and (B2). In this case, the blending ratio of components (B1) and (B2) is 8:2 to 2:8 by mass ratio, preferably 7:3 to 3:7.

[0024] The composition for cosmetics of the present invention can improve the feel of hair when applied to the hair. The application method is not particularly limited as long as it can be uniformly applied to the hair. For example, it can be directly applied to the hair, or dissolved or dispersed in a solvent such as ethanol and then applied to the hair. After the composition for cosmetics of the present invention is applied to the hair, the effect can be improved by subjecting the hair to heat treatment, and the effect can be continuously exerted. When performing heat treatment, devices such as a hair iron (straight iron, curling iron, brush iron, etc.) and a dryer can be used. Alternatively, it can also be performed simultaneously with a perm treatment involving heating such as a digital perm or a hot perm. As the heat treatment conditions, if it is a hair iron, the set temperature is 60 to 180°C and it is treated about 1 to 10 times; if it is a digital perm, it is treated at 60 to 120°C for about 1 to 60 minutes; if it is a dryer, it is treated with hot air for about 1 minute to 10 minutes.

[0025] As a method of applying the cosmetic composition of the present invention to hair, in addition to the aforementioned method, it can also be applied to hair by blending it into known general hair cosmetics for use. When blending the cosmetic composition of the present invention into hair cosmetics, the blending amount is not particularly limited, but is preferably 0.001 to 50% by weight, more preferably 0.005 to 20% by weight.

[0026] The hair cosmetics containing the cosmetic composition of the present invention may contain, if necessary, additive components generally blended in hair cosmetics, such as oily bases, surfactants, alcohols, moisturizers, polymers, thickeners, gelling agents, antioxidants, preservatives, bactericides, chelating agents, pH adjusters, acids, alkalis, ultraviolet absorbers, whitening agents, solvents, keratolytic agents, antipruritics, anti-inflammatory agents, antiperspirants, cooling agents, antihistamines, astringents, stimulants, hair growth agents, blood circulation promoters, reducing agents, oxidizing agents, polymer powders, hydroxy acids, vitamins and their derivatives, saccharides and their derivatives, organic acids, enzymes, nucleic acids, hormones, inorganic powders, fragrances, dyes, etc., as long as the effects of the present invention are not impaired.

[0027] As the oily base, higher alcohols such as cetyl alcohol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, arachyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, ceraryl alcohol, batyl alcohol, hexyl decanol, isostearyl alcohol, 2-octyldodecanol, dimer diol, etc.; aralkyl alcohols such as benzyl alcohol and derivatives; higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, palmitooleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexadecanoic acid, anteisoheneicosanoic acid, long-chain branched fatty acids, dimer acid, hydrogenated dimer acid, etc. and their aluminum salts, calcium salts, magnesium salts, zinc salts, potassium, sodium salts, etc. of metal soaps, and nitrogen-containing derivatives such as amides; hydrocarbons such as liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, petrolatum, solid paraffin, etc.; waxes such as candelilla wax, carnauba wax, rice wax, wood wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, Fischer-Tropsch wax, polyethylene wax, ethylene-propylene copolymer, etc.; vegetable oils and fats such as coconut oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, meadowfoam oil, persic oil, tea tree oil, mint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cocoa butter, shea butter, hydrogenated coconut oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil, etc.; animal fats and oils such as beef tallow, milk fat, horse fat, egg yolk oil, mink oil, turtle oil, etc.; animal waxes such as whale oil, lanolin, orange raffia oil, etc.;Lanolin derivatives such as liquid lanolin, reduced lanolin, adsorbed and purified lanolin, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetate (cetyl·lanyl) ester; Sphingolipids such as lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin, phosphatidic acid, cyclic lysophosphatidic acid or its salts, lysophospholipids such as lysophosphatidylcholine; Phospholipid derivatives such as hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid; Saponins; Saponins; Acyl sarcosine alkyl esters such as cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, N-lauroyl-L-glutamic acid di (cholesteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamic acid di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamic acid di (phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamic acid di (phytosteryl / octyldodecyl), N-lauroyl sarcosine isopropyl, cholesteryl 12-hydroxystearate, cholesteryl macadamia nut oil fatty acid, phytosteryl macadamia nut oil fatty acid, phytosteryl sunflower seed oil fatty acid, phytosteryl isostearate, cholesteryl soft lanolin fatty acid, cholesteryl hard lanolin fatty acid, cholesteryl long-chain branched fatty acid, cholesteryl long-chain α-hydroxy fatty acid, etc.; Lipid complexes such as phospholipid-cholesterol complex, phospholipid-phytosterol complex;Octyldodecyl myristate, hexyl decyl myristate, octyldodecyl isostearate, cetyl palmitate, octyldodecyl palmitate, cetyl octanoate, hexyl decyl octanoate, isotridecyl isononanoate, isononyl isononanoate, octyl isononanoate, isotridecyl isononanoate, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, octyldodecyl lanolin fatty acid, dicaprylyl carbonate, hexyl decyl dimethyl octanoate, octyldodecyl erucate, hydrogenated castor oil isostearate, ethyl oleate, ethyl avocado oil fatty acid, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, isopropyl lanolin fatty acid, methyl heptyl laurate, methyl heptyl myristate, methyl heptyl palmitate, methyl heptyl isostearate, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl adipate, dioctyl succinate, triethyl citrate and other monoalcohol carboxylic acid esters; cetyl lactate, diisostearyl malate, hydrogenated castor oil monoisostearate, γ-elaeolactone and other oxyacid esters;Glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, glyceryl tri(caprylic / capric acid), glyceryl tri(caprylic / capric / myristic / stearic acid), hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl behenate eicosanedioate, trimethylolpropane trioctanoate, trimethylolpropane triisostearate, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl, ditrimethylolpropane triethylhexanoate, ditrimethylolpropane (isostearic acid / sebacic acid), pentaerythrityl triethylhexanoate, dipentaerythrityl (hydroxystearic acid / stearic acid / rosinic acid), diglyceryl diisostearate, polyglyceryl tetraisostearate, polyglyceryl-10 nonaisostearate, polyglyceryl-8 deca(erucic acid / isostearic acid / ricinoleic acid), diglyceryl oligoster ester (hexyl decanoic acid / sebacic acid), ethylene glycol distearate (distearic acid ethylene glycol), 3-methyl-1,5-pentanediol dineopentanoate, 2,4-diethyl-1,5-pentanediol dineopentanoate and other polyhydric alcohol fatty acid esters; alkyl ethers such as dicaprylyl ether; derivatives of dimer acid or dimer diol such as diisopropyl dimer dilinoleate, diisostearyl dimer dilinoleate, di(isostearyl / phytosteryl) dimer dilinoleate, (phytosteryl / behenyl) dimer dilinoleate, (phytosteryl / isostearyl / cetyl / stearyl / behenyl) dimer dilinoleate, dimer dilinoleyl dimer dilinoleate, diisostearyl dimer dilinoleate, hydrogenated rosin condensate of dimer dilinoleic acid, hydrogenated castor oil of dimer dilinoleic acid, hydroxyalkyl dimer dilinoleyl ether, etc.Fatty acid alkanolamides such as coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (palmitamide MEA), palmitic acid diethanolamide (palmitamide DEA), coconut oil fatty acid methylethanolamide (cocamide methyl MEA); silicones such as dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethylsilicone, phenyldimethylsilicone, (aminoethylaminopropylmethylsilicone / dimethylsilicone) copolymer, dimethiconol, dimethiconol cross polymer, silicone resin, silicone rubber, amino-modified silicones such as aminopropyldimethylsilicone and amodimethicone, cation-modified silicone, polyether-modified silicones such as dimethicone copolyol, polyglycerin-modified silicone, sugar-modified silicone, carboxylic acid-modified silicone, phosphoric acid-modified silicone, sulfuric acid-modified silicone, alkyl-modified silicone, fatty acid-modified silicone, alkyl ether-modified silicone, amino acid-modified silicone, peptide-modified silicone, fluorine-modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether-modified silicone, alkyl-modified and polyether-modified silicone, amidoalkyl-modified silicone, aminoglycol-modified silicone, aminophenyl-modified silicone, silicone-oxyalkylene copolymers such as polysiloxane·oxyalkylene copolymer; fluorine-based oils such as perfluorodecane, perfluorooctane, perfluoropolyether are preferably mentioned.;

[0028] As the humectant and feel improver, polyols and their polymers such as glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol-propylene glycol copolymer; glycol alkyl ethers such as diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether; water-soluble esters such as (eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10, tetradecanedioic acid polyglyceryl-10, cyclohexanedicarboxylic acid bisethoxydiglycol; sugar alcohols such as sorbitol, xylitol, erythritol, mannitol, maltitol; sugars and their derivatives such as glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and modified cyclodextrins such as maltosylated, hydroxyalkylated cyclodextrin), β-glucan, chitin, chitosan, heparin and its derivatives, pectin, arabinogalactan, dextrin, dextran, glycogen, ethyl glucoside, glucosylethyl methacrylate polymer or copolymer; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucitin sulfate, caronin sulfate, keratosulfate, dermatan sulfate; jellyfish extract, jellyfish polysaccharide; fructans such as inulin, levan; fucoidan; tuberose polysaccharide, natural-derived polysaccharide; organic acids such as citric acid, tartaric acid, lactic acid and their salts; urea; 2-pyrrolidone-5-carboxylic acid and its salts such as its sodium salt;Amino acids such as betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and their salts; protein peptides such as collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen-degrading peptides, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin-degrading peptides, keratin-degrading peptides, hydrolyzed keratin, conchiolin-degrading peptides, hydrolyzed conchiolin, silk protein-degrading peptides, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soybean protein-degrading peptides, wheat protein-degrading peptides, hydrolyzed wheat protein, casein-degrading peptides, acylated peptides and their derivatives; acylated peptides such as palmitoyl oligopeptide, palmitoyl pentapeptide, palmitoyl tetrapeptide; silylated peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesame lignan glycoside, glutathione, albumin, whey; choline chloride, phosphorylcholine; animal and plant extract components such as placenta extract, aeroelastin, collagen, aloe extract, witch hazel water, loofah water, chamomile extract, licorice extract, comfrey extract, silk extract, rosa multiflora extract, plantain extract, eucalyptus extract, melilot extract, ceramides such as natural ceramides (type 1, 2, 3, 4, 5, 6), hydroxyceramides, pseudo-ceramides, sphingoglycolipids, ceramides and extracts containing glycoceramides are preferably mentioned.;

[0029] As the surfactant, anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, polymer surfactants, etc. are preferably exemplified. There is no particular limitation on the HLB of the surfactant, and those with a low HLB of about 1 to those with a high HLB of about 20 can be used, and it is also preferable to combine those with a low HLB and those with a high HLB. Examples of preferable surfactants include, among anionic surfactants, fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfate ester salts such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; polyoxyethylene alkyl sulfate salts such as sodium laureth sulfate and triethanolamine laureth sulfate; acyl N-methyl amino acid salts such as sodium cocoyl methyl taurate, potassium cocoyl methyl taurate, sodium lauroyl methyl taurate, sodium myristoyl methyl taurate, sodium lauroyl methyl alaninate, sodium lauroyl sarcosinate, triethanolamine lauroyl sarcosinate, and sodium lauroyl glutamate methyl alaninate; acyl amino acid salts such as sodium cocoyl glutamate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, triethanolamine cocoyl alaninate, and lysine Na dilauroyl glutamate; polyoxyethylene alkyl ether acetate salts such as sodium laureth acetate; succinate ester salts such as sodium lauroyl monoethanolamide succinate; fatty acid alkanolamide ether carboxylate salts; polyoxyethylene fatty amine sulfates; fatty acid alkanolamide sulfates; fatty acid glyceride sulfate salts such as sodium hardened coconut oil fatty acid glycerol sulfate; polyoxyethylene alkylbenzene sulfates; olefin sulfonate salts such as sodium α-olefin sulfonate; alkyl sulfosuccinate salts such as sodium lauryl sulfosuccinate and sodium dioctyl sulfosuccinate;Alkyl ether sulfosuccinates such as sodium lauryl sulfosuccinate, sodium monolauroyl monoethanolamine polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate; alkyl benzene sulfonates such as sodium tetradecyl benzene sulfonate, triethanolamine tetradecyl benzene sulfonate; alkyl naphthalene sulfonates; alkane sulfonates; α-sulfo fatty acid methyl ester salts; acyl isethionates; alkyl glycidyl ether sulfonates; alkyl sulfacetates; alkyl ether phosphate ester salts such as sodium lauryl phosphate, sodium dilauryl phosphate, sodium trilauryl phosphate, sodium monooleyl phosphate; alkyl phosphate ester salts such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphates; fatty acid amide ether phosphates; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, cyclic lysophosphatidic acid or its salts; silicone-based anionic surfactants such as carboxylic acid-modified silicone, phosphate-modified silicone, sulfuric acid-modified silicone, etc.; For nonionic surfactants, various polyoxyethylene adduct numbers of polyoxyethylene alkyl ethers such as laureths (polyoxyethylene lauryl ethers), cetes (polyoxyethylene cetyl ethers), stearates (polyoxyethylene stearyl ethers), behenes (polyoxyethylene behenyl ether), isostearates (polyoxyethylene isostearyl ether), octyldeces (polyoxyethylene octyldodecyl ether); polyoxyethylene alkyl phenyl ether; polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearate diester, polyoxyethylene hydrogenated castor oil maleic acid and other castor oil and hydrogenated castor oil derivatives; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin;Polyoxyethylene-polyoxypropylene cetyl ether, polyoxyethylene-polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene-polyoxypropylene monobutyl ether, polyoxyethylene-polyoxypropylene hydrogenated lanolin, polyoxyethylene-polyoxypropylene glycerin ether and other polyoxyethylene-polyoxypropylene alkyl ethers; polyoxyethylene-polyoxypropylene glycol; (poly)glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; glycerin fatty acid partial esters such as glyceryl stearate, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, glyceryl coconut oil fatty acid, glycerin mono-cottonseed oil fatty acid, glycerin monoerucate, glyceryl sesquioleate, α,α'-glyceryl oleate pyroglutamate, glyceryl monostearate malate; polyglyceryl fatty acid esters such as polyglyceryl-2 stearate, polyglyceryl-3 stearate, polyglyceryl-4 stearate, polyglyceryl-5 stearate, polyglyceryl-6 stearate, polyglyceryl-8 stearate, polyglyceryl-10 stearate, polyglyceryl-6 distearate, polyglyceryl-10 distearate, polyglyceryl-2 tristearate, polyglyceryl-10 decastearate, polyglyceryl-2 isostearate, polyglyceryl-3 isostearate, polyglyceryl-4 isostearate, polyglyceryl-5 isostearate, polyglyceryl-6 isostearate, polyglyceryl-8 isostearate, polyglyceryl-10 isostearate, polyglyceryl-2 diisostearate (diglyceryl diisostearate), polyglyceryl-3 diisostearate, polyglyceryl-10 diisostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, polyglyceryl-10 decaisostearate, polyglyceryl-2 oleate, polyglyceryl-3 oleate, polyglyceryl-4 oleate, polyglyceryl-5 oleate, polyglyceryl-6 oleate, polyglyceryl-8 oleate, polyglyceryl-10 oleate, polyglyceryl-6 dioleate, polyglyceryl-2 trioleate, polyglyceryl-10 decaoleate; ethylene glycol mono-fatty acid esters such as ethylene glycol monostearate; propylene glycol mono-fatty acid esters such as propylene glycol monostearate; pentaerythritol partial fatty acid esters; sorbitol partial fatty acid esters; maltitol partial fatty acid esters; maltitol ether;Sorbitan fatty acid esters such as sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexanoate, diglycerol sorbitan tetra-2-ethylhexanoate; sugar derivative partial esters such as sucrose fatty acid ester, methyl glucoside fatty acid ester, trehalose undecylenate; alkyl glucosides such as caprylyl glucoside; alkyl polyglycosides; glycolipids such as mannosylerythritol lipid; lanolin alcohol; reduced lanolin; polyoxyethylene fatty acid mono- and diesters such as polyoxyethylene distearate, polyethylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene dioleate; polyoxyethylene-propylene glycol fatty acid ester; polyoxyethylene glycerol fatty acid esters such as polyoxyethylene glycerol monostearate, polyoxyethylene glycerol monoisostearate, polyoxyethylene glycerol triisostearate; polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol fatty acid esters such as polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol pentaoleate, polyoxyethylene sorbitol monostearate; polyoxyethylene methyl glucoside fatty acid ester; polyoxyethylene alkyl ether fatty acid ester; polyoxyethylene animal and vegetable oils and fats such as polyoxyethylene sorbitol beeswax; alkyl glyceryl ethers such as isostearyl glyceryl ether, chimyl alcohol, ceralkyl alcohol, batyl alcohol; polyhydric alcohol alkyl ethers; polyoxyethylene alkylamine; tetra-polyoxyethylene·tetra-polyoxypropylene-ethylenediamine condensates; natural surfactants such as saponin, sophorolipid;Polyoxyethylene fatty acid amides; fatty acid alkanolamides such as coconut fatty acid monoethanolamide (cocamide MEA), coconut fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (paltamide MEA), palmitic acid diethanolamide (paltamide DEA), coconut fatty acid methylethanolamide (cocamide methyl MEA), etc.; alkyldimethylamine oxides such as lauramine oxide, cocoamine oxide, stearamine oxide, behenamine oxide, etc.; alkyethoxydimethylamine oxide; polyoxyethylene alkyl mercaptan; silicone-based nonionic surfactants such as polyether-modified silicone like dimethicone copolyol, polysiloxane-oxyalkylene copolymer, polyglycerin-modified silicone, sugar-modified silicone, etc.; for cationic surfactants, alkyltrimethylammonium chlorides such as behentrimonium chloride, steartrimonium chloride, cetrimonium chloride, lauryltrimonium chloride, etc.; alkyltrimethylammonium bromides such as stearyltrimonium bromide, etc.; dialkyldimethylammonium chlorides such as distearyldimonium chloride, dicocodimonium chloride, etc.; fatty acid amide amines and their salts such as stearamide propyldimethylamine, stearamide ethyldiethylamine, etc.; alkyl ether amines and their salts or quaternary salts such as stearoxypropyldimethylamine, etc.; fatty acid amide type quaternary ammonium salts such as long-chain branched fatty acid (12 - 31) aminopropylethyldimethylammonium ethyl sulfate, lanolin fatty acid aminopropylethyldimethylammonium ethyl sulfate, etc.; polyoxyethylene alkylamines and their salts or quaternary salts; alkylamine salts; fatty acid amide guanidinium salts; alkyl ether amine monium salts; alkyltrialkylene glycol ammonium salts; benzalkonium salts; benzethonium salts; pyridinium salts such as cetylpyridinium chloride, etc.; imidazolinium salts; alkylisoquinolinium salts; dialkylmorphonium salts; polyamine fatty acid derivatives;Silicone-based cationic surfactants such as aminopropyl dimethicone and amino-modified silicones such as amodimethicone, cationic-modified silicones, cationic-modified and polyether-modified silicones, amino-modified and polyether-modified silicones; among amphoteric surfactants, N-alkyl-N,N-dimethylamino acid betaines such as lauryl betaine (lauryldimethylaminoacetic acid betaine); fatty acid amide alkyl-N,N-dimethylamino acid betaines such as cocamidopropyl betaine and lauramidopropyl betaine; imidazoline-type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkyl sulfobetaines such as alkyldimethyltaurine; sulfate-type betaines such as alkyldimethylaminoethanol sulfate ester; phosphate-type betaines such as alkyldimethylaminoethanol phosphate ester; phosph; Sphingolipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, sphingomyelin, etc., phospholipids such as lysophosphatidylcholine, hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid, hydroxylated lecithin, etc.; silicone-based amphoteric surfactants, etc.; among polymeric surfactants, polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum, acrylic acid·methacrylic acid alkyl copolymers; various silicone-based surfactants are preferably mentioned.

[0030] Examples of polymers, thickeners, and gelling agents include guar gum, locust bean gum, carob seed, carrageenan, galactan, gum arabic, tara gum, tamarind, farselan, karaya gum, trollius, carrageenan, tragacanth gum, pectin, pectic acid and its salts such as sodium salt, alginic acid and its salts such as sodium salt, mannan; starches such as rice, corn, potato, and wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salts, xanthan gum, pullulan, gellan gum, chitin, chitosan, agar, cassowary extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose and its salts such as sodium salt, methylhydroxypropylcellulose, sodium cellulose sulfate, dialkyldimethylammonium sulfate cellulose, crystalline cellulose, cellulose derivatives such as cellulose powder; starch-based polymers such as soluble starch, carboxymethyl starch, methylhydroxypropyl starch, methyl starch, starch derivatives such as hydroxypropyltrimonium chloride starch, octenyl succinic anhydride corn starch aluminum; alginic acid derivatives such as sodium alginate, propylene glycol alginate; polyvinyl pyridone (PVP), polyvinyl alcohol (PVA), vinyl pyridone-vinyl alcohol copolymer, polyvinyl methyl ether; polyethylene glycol, polypropylene glycol, polyoxyethylene-polyoxypropylene copolymer; amphoteric methacrylic acid ester copolymers such as (methacryloyloxyethyl carboxybetaine / methacrylic acid alkyl) copolymer, (acrylates / stearyl acrylate / ethylamine oxide methacrylate) copolymer; (dimethyl silicone / vinyl dimethicone) cross-polymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; partially saponified polyvinyl acetate, maleic acid copolymer; vinyl pyridone-dialkylaminoalkyl methacrylate copolymer; acrylic resin alkanolamine; polyester, water-dispersible polyester;Polyacrylamide; polyacrylate copolymers such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its salts such as sodium salt, acrylic acid·methacrylic acid ester copolymer; acrylic acid·methacrylic acid alkyl copolymer; cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride·acrylamide copolymer such as polyquaternium-7, acrylic acid·diallyldimethylammonium chloride copolymer such as polyquaternium-22, acrylic acid·diallyldimethylammonium chloride·acrylamide copolymer such as polyquaternium-39, acrylic acid·cationized methacrylic acid ester copolymer, acrylic acid·cationized methacrylamide copolymer, acrylic acid·methyl acrylate·methacrylamidopropyltrimethylammonium chloride copolymer such as polyquaternium-47, choline methacrylate chloride polymer; cationized oligosaccharide, cationized dextran, cationized polysaccharides such as guar hydroxypropyltrimonium chloride; polyethyleneimine; cationic polymer; polymers of 2-methacryloyloxyethyl phosphorylcholine such as polyquaternium-51 and copolymers with butyl methacrylate etc.; acrylic resin emulsion, polyethyl acrylate emulsion, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion, natural rubber latex, synthetic latex and other polymer emulsions; nitrocellulose; polyurethanes and various copolymers; various silicones; various silicone copolymers such as acrylic-silicone graft copolymer; various fluorine-based polymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate, dextrin myristate; silicic anhydride, fumed silica (ultrafine particle silicic anhydride), magnesium aluminum silicate, sodium magnesium silicate, metal soap, metal dialkyl phosphate, bentonite, hectorite, organically modified clay minerals, sucrose fatty acid ester, fructooligosaccharide fatty acid ester are preferably mentioned.;

[0031] As solvents and propellants, lower alcohols such as ethanol, 2-propanol (isopropyl alcohol), butanol, isobutyl alcohol, etc.; glycols such as propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isopentyl diol, etc.; glycol ethers such as diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether, etc.; glycol ether esters such as ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate, etc.; glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate, etc.; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate, acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbons, next-generation chlorofluorocarbons; propellants such as LPG, dimethyl ether, carbon dioxide gas, etc. are preferably listed.

[0032] As antioxidants, tocopherol derivatives such as tocopherol (vitamin E), tocopherol acetate, etc.; BHT, BHA; gallic acid derivatives such as propyl gallate, etc.; vitamin C (ascorbic acid) and / or its derivatives; erythorbic acid and its derivatives; sulfites such as sodium sulfite, etc.; bisulfites such as sodium bisulfite, etc.; thiosulfates such as sodium thiosulfate, etc.; metabisulfite; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride are preferably listed. As reducing agents, thioglycolic acid, cysteine, cysteamine, etc. are preferably listed. As oxidants, hydrogen peroxide solution, ammonium persulfate, sodium bromate, percarbonate, etc. are preferably listed.

[0033] Examples of antibacterial agents or preservatives include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, and butylparaben; phenoxyethanol; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, and 1,2-octanediol; alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); glycerin fatty acid esters such as glyceryl caprylate, glyceryl caprate, and (caprylic acid / capric acid) glyceryl; salicylic acid; sodium benzoate; isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; imidazolinium urea; dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, hinokitiol; other phenols such as phenol, isopropylphenol, cresol, thymol, parachlorophenol, phenylphenol, and sodium phenylphenol; phenylethyl alcohol, photosensitizers, antibacterial zeolites, and silver ions. However, when used as an antibacterial agent or preservative for the purpose of preservation, from the perspective of the safety of cosmetics or topical skin preparations, phenoxyethanol; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, and 1,2-octanediol; alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether are more preferably used.

[0034] Chelating agents include preferably edetates such as EDTA, EDTA2Na, EDTA3Na, EDTA4Na (ethylenediaminetetraacetates); hydroxyethylethylenediaminetriacetates such as HEDTA3Na; pentetates (diethylenetriaminepentaacetates); phytic acid; phosphonic acids such as etidronic acid and salts thereof such as sodium salts; sodium oxalate; polyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine, gluconic acid, ascorbic acid, succinic acid, tartaric acid. pH adjusters, acids and alkalis include preferably citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanolamine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, sodium hydroxide, potassium hydroxide, aqueous ammonia, guanidine carbonate, ammonium carbonate.

[0035] Examples of powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, red mica, biotite, vermiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstates, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorapatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, metal soaps (e.g., zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, cobalt blue, carbon black, titanium oxide, fine and ultrafine titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultrafine anhydrous silicic acid), mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorophlogopite, fine particle composite powder, gold, aluminum, and other inorganic powders of various sizes and shapes, and inorganic powders such as those obtained by treating these with various surface treatment agents such as hydrogen silicone, cyclic hydrogen silicone, or other silanes or titanium coupling agents to make them hydrophobic or hydrophilic; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, polyester powder, benzoguanamine resin powder, laminated powder of polyethylene terephthalate and polymethyl methacrylate, laminated powder of polyethylene terephthalate, aluminum, and epoxy, etc., urethane powder, silicone powder, Teflon (registered trademark) powder, and other organic powders, surface-treated powders, and organic-inorganic composite powders of various sizes and shapes are preferred.Examples of inorganic salts include sodium chloride-containing salts such as table salt, refined salt, rock salt, sea salt, and natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, aluminum potassium sulfate (alum), aluminum ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na·2Na·3Na phosphates, potassium phosphates, calcium phosphates, and magnesium phosphates are preferably mentioned.

[0036] Examples of ultraviolet absorbers include benzoic acid - based ultraviolet absorbers such as para - aminobenzoic acid, monoglycerin ester of para - aminobenzoic acid, ethyl N,N - dipropoxy para - aminobenzoate, ethyl N,N - diethoxy para - aminobenzoate, ethyl N,N - dimethyl para - aminobenzoate, butyl N,N - dimethyl para - aminobenzoate, ethyl N,N - dimethyl para - aminobenzoate; anthranilic acid - based ultraviolet absorbers such as homomenthyl - N - acetylanthranilate; salicylic acid and its sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p - isopropanolphenyl salicylate and other salicylic acid - based ultraviolet absorbers; cinnamic acid - based ultraviolet absorbers such as octyl cinnamate, ethyl 4 - isopropyl cinnamate, methyl 2,5 - diisopropyl cinnamate, ethyl 2,4 - diisopropyl cinnamate, methyl 2,4 - diisopropyl cinnamate, propyl p - methoxy cinnamate, isopropyl p - methoxy cinnamate, isoamyl p - methoxy cinnamate, 2 - ethylhexyl p - methoxy cinnamate (octyl paramethoxycinnamate), 2 - ethoxyethyl - p - methoxy cinnamate (sinoxate), cyclohexyl - p - methoxy cinnamate, ethyl α - cyano - β - phenyl cinnamate, 2 - ethylhexyl α - cyano - β - phenyl cinnamate (octocrylene), glyceryl mono - 2 - ethylhexanoyl - diparamethoxy cinnamate, ferulic acid and its derivatives;Benzophenone-based ultraviolet absorbers such as 2,4-dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2',4,4'-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone; 3-(4'-methylbenzylidene)-d,l-camphor, 3-benzylidene-d,l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-methylphenylbenzotriazole; 2-(2'-hydroxy-5'-t-octylphenyl)benzotriazole; 2-(2'-hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 5-(3,3-dimethyl-2-norbornylidene)-3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octyltriazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2-(2'-hydroxy-5'-methylphenyl)benzotriazole, 1-(3,4-dimethoxyphenyl)-4,4-dimethyl-1,3-pentanedione, hydantoin derivatives such as ethyl 2-ethylhexyl dimethoxybenzylidene dioxoimidazolidinepropionate, phenylbenzimidazolesulfonic acid, terephthalylidene dicamphorsulfonic acid, droxmetrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives are preferably mentioned.;

[0037] Examples of skin-whitening agents include hydroquinone glycosides such as arbutin and α-arbutin and their esters; ascorbic acid phosphate ester salts such as ascorbic acid, sodium ascorbic acid phosphate ester, and magnesium ascorbic acid phosphate ester, ascorbic acid fatty acid esters such as ascorbic acid tetraisopalmitate, ascorbic acid alkyl ethers such as ascorbic acid ethyl ether, ascorbic acid glucosides such as ascorbic acid-2-glucoside and their fatty acid esters, ascorbic acid sulfate esters, ascorbic acid derivatives such as tocopheryl ascorbate; kojic acid, ellagic acid, tranexamic acid and its derivatives, ferulic acid and its derivatives, placenta extract, glutathione, oryzanol, butylresorcinol, oil-soluble chamomile extract, oil-soluble licorice extract, tamarix chinensis extract, saxifraga stolonifera extract and other plant extracts are preferably mentioned.

[0038] Examples of vitamins and their derivatives include vitamin A compounds such as retinol, retinol acetate, and retinol palmitate; vitamin B group compounds such as thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, flavin adenine dinucleotide, cyanocobalamin, folic acids, nicotinic acid compounds such as nicotinamide and benzyl nicotinate, and choline compounds; vitamin C compounds such as ascorbic acid and its salts such as sodium ascorbate; vitamin D; vitamin E compounds such as α, β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphate salts such as sodium ascorbic acid phosphate and magnesium ascorbic acid phosphate, ascorbic acid fatty acid esters such as ascorbic acid tetraisopalmitate, stearyl ascorbate, palmitoyl ascorbate, and dipalmitoyl ascorbate, ascorbic acid alkyl ethers such as ascorbic acid ethyl ether, ascorbic acid glucosides such as ascorbic acid-2-glucoside and their fatty acid esters, ascorbic acid derivatives such as ascorbyl phosphate tocopherol; vitamin derivatives such as tocopherol derivatives such as nicotinic acid tocopherol, tocopherol acetate, tocopherol linoleate, tocopherol ferulate, and tocopherol phosphate ester, tocotrienol, and other various vitamin derivatives are preferably mentioned.

[0039] As anti-inflammatory agents, glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphenhydramine hydrochloride, chlorpheniramine maleate; plant extracts such as peach leaf extract and mugwort leaf extract are preferably mentioned. As hair growth agents, blood circulation promoters and stimulants, plant extracts and tinctures such as centella extract, capsicum tincture, ginger tincture, ginger extract, cantharis tincture; capsaicin, nonivamide, zingerone, ichthyol, tannic acid, borneol, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, celeferin, γ-oryzanol, celeferin, derivatives such as vitamin E and tocopheryl nicotinate · tocopheryl acetate, γ-oryzanol, nicotinic acid and derivatives such as nicotinamide · benzyl nicotinate · inositol hexanicotinate, nicotinyl alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, monoglyceride pentadecanoate, flavanonol derivatives, stigmasterol or stigmastanol and its glycosides, minoxidil are preferably mentioned. As hormones, estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone, etc. are preferably mentioned.As other medicinal agents such as anti-wrinkle agents, anti-aging agents, tightening agents, cooling agents, warming agents, wound healing accelerators, irritation relievers, analgesics, cell activators, etc., retinol derivatives, retinoic acid derivatives, tocopheryl retinoate; lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and its glycosides and esterified derivatives, etc., α- or β-hydroxy acids such as hydroxycapric acid, long-chain α-hydroxy fatty acids, cholesteryl long-chain α-hydroxy fatty acids and their derivatives; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosine; creatine; ceramides, sphingosines; caffeine, xanthine and their derivatives; antioxidants and active oxygen scavengers such as coenzyme Q10, carotene, lycopene, astaxanthin, lutein, α-lipoic acid, platinum nanocolloid, fullerenes; catechins; flavones such as quercetin; isoflavones; gallic acid and ester sugar derivatives; polyphenols such as tannins, sesamin, proanthocyanidins, chlorogenic acid, apple polyphenols; derivatives such as rutin and its glycosides; derivatives such as hesperidin and its glycosides; lignan glycosides; licorice-related substances such as glabridin, glabrene, liquiritin, isoliquiritin; lactoferrin; gingerols such as shogaol, gingerol; fragrance substances such as menthol, camphor, cedrol and their derivatives; capsaicin, vanillin and their derivatives; insect repellents such as diethyltoluamide; complexes of bioactive substances and cyclodextrins are preferably mentioned.

[0040] Examples of plant, animal, and microbial extracts include iris extract, ashitaba extract, asunaro extract, asparagus extract, avocado extract, amacha extract, almond extract, hollyhock extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo extract, ginseng extract, wikyo extract, turmeric extract, oolong tea extract, Japanese lacquer extract, eiditsu extract, etinashi leaf extract, enmei mushroom extract, gold extract, houou extract, uren extract, barley extract, otane carrot extract, pansy extract, viola extract, ononis extract, Dutch horseradish extract, orange extract, dried sea products, seaweed extract, oyster leaf extract, kakiok extract, hydrolyzed elastin, hydrolyzed wheat flour, hydrolyzed silk, kakkon extract, chamomile extract, oil-soluble chamomile extract, carrot extract, kawarayomogi extract, karasumugi extract, calcade extract, licorice extract, oil-soluble licorice extract, kiwi extract, kio extract, shiitake mushroom extract, cinchona extract, cucumber extract, kiri leaf extract, guanosine, guava extract, kujin extract, gardenia extract, kuma sasae extract, clara extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, black sugar extract, black vinegar, chlorella extract, kuwa extract, gentiana extract, gennosyouko extract, black tea extract, yeast extract, koubok extract, coffee extract, burdock extract, rice extract, fermented rice extract, rice bran fermented extract, rice germ oil, comfrey extract, collagen, kokemomo extract, saishin extract, saiko extract, saitai extract, saffron extract, salvia extract, soapwort extract, sasae extract, sanzashi extract, sansha extract, sanshou extract, shiitake mushroom extract, jio extract, shikon extract, perilla extract, sinanoki extract, shimotsukesou extract, jatoba extract, peony extract, shoukyuu extract, shoubu root extract, shirakaba extract, white shiitake mushroom extract, sugina extract, stevia extract, fermented stevia, tamarix chinensis extract, European ivy extract, European sanzashi extract, European nivatoko extract, European pansy extract, European mint extract, sage extract, zeniaoi extract, senkyuu extract, senburi extract, souhakuhi extract, daiou extractExtracts such as soybean extract, kale extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, chigaya extract, chimpi extract, tea tree oil, sweet tea extract, capsicum extract, atractylodes extract, tokiensenca extract, toki extract, douglas fir extract, dokudami extract, tomato extract, natto extract, carrot extract, garlic extract, rose extract, hibiscus extract, buckmoundou extract, lotus extract, parsley extract, birch extract, honey, witch hazel extract, parietaria extract, hikiokoshi extract, bisabolol, hinoki extract, bifidobacterium extract, loquat extract, fuki dandelion extract, fuki no tou extract, bukuryou extract, butcher's bloom extract, grape extract, grape seed extract, propolis, loofah extract, safflower extract, peppermint extract, bodaiju extract, button extract, hop extract, mykaika extract, pine extract, maronie extract, mizubashou extract, mulberry extract, melissa extract, mozuku extract, peach extract, yaguruma giku extract, eucalyptus extract, snowdrop extract, yuzu extract, lily extract, yokuin nin extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, raisin extract, lettuce extract, lemon extract, kelp extract, renge sou extract, rose extract, rosemary extract, roman chamomile extract, royal jelly extract, waremokou extract, etc. are preferably listed as such.

[0041] Examples of antipruritics include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitors, and the like. Examples of keratolytic and resolvent agents include salicylic acid, sulfur, resorcinol, selenium sulfide, pyridoxine, and the like. Examples of antiperspirants include hydroxyaluminum chloride, aluminum chloride, zinc oxide, zinc paraphenolsulfonate, and the like. Examples of cooling agents include menthol, methyl salicylate, and the like. Examples of astringents include citric acid, tartaric acid, lactic acid, aluminum potassium sulfate, tannic acid, and the like. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease, and the like. Preferred examples of nucleic acids include ribonucleic acid and its salts, deoxyribonucleic acid and its salts, and disodium adenosine triphosphate.

[0042] As spices, there are acetyl cedrene, amyl cinnamaldehyde, allyl amyl glycolate, β-ionone, isoeugenol, isobutyl quinoline, iris oil, iron, indole, ylang-ylang oil, undecanal, undecenal, γ-undecalactone, estragole, eugenol, oak moss, opoponax resinoid, orange oil, eugenol, aurantiol, galaxolide, carvacrol, L-carboxylic, camphor, canon, carrot seed oil, clove oil, methyl caffeate, geraniol, geranyl nitrile, isobornyl acetate, geranyl acetate, dimethyl benzyl carbinyl acetate, styrallyl acetate, cedryl acetate, terpinyl acetate, p-t-butyl cyclohexyl acetate, vetiveryl acetate, benzyl acetate, linalyl acetate, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamen aldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromyrcenol, jasmine absolute, jasmine lactone, cis-jasmone, citral, citronellol, citronellal, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, styrax resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascone, damasconene, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, triplal, nerol, nonanal, 2,6-Nonadienol, nonalactone, patchouli alcohol, vanilla absolute, vanillin, basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, ptycholen oil, hexyl cinnamaldehyde, cis-3-hexenol, Peru balsam, vetiver oil, vetiverol, peppermint oil, pepper oil, heliotropin, bergamot oil, benzyl benzoate, borneol, myrrh resinoid, musk ketone, methyl nonyl acetaldehyde, γ-methyl ionone, menthol, L-menthol, L-mentone, eucalyptus oil, β-ionone, lime oil, lavender oil, D-limonene, linalool, lilial, lilyal, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, synthetic fragrances and natural fragrances such as various essential oils, and various compounded fragrances are preferably listed as such.,

[0043] As pigments, colorants, dyes, and pigments, there are legal pigments such as Brown No. 201, Black No. 401, Violet No. 201, Violet No. 401, Blue No. 1, Blue No. 2, Blue No. 201, Blue No. 202, Blue No. 203, Blue No. 204, Blue No. 205, Blue No. 403, Blue No. 404, Green No. 3, Green No. 201, Green No. 202, Green No. 204, Green No. 205, Green No. 3, Green No. 401, Green No. 402, Red No. 102, Red No. 104-1, Red No. 105-1, Red No. 106, Red No. 2, Red No. 3, Red No. 201, Red No. 202, Red No. 203, Red No. 204, Red No. 205, Red No. 206, Red No. 207, Red No. 208, Red No. 213, Red No. 214, Red No. 215, Red No. 218, Red No. 219, Red No. 220, Red No. 221, Red No. 223, Red No. 225, Red No. 226, Red No. 227, Red No. 228, Red No. 230-1, Red No. 230-2, Red No. 231, Red No. 232, Red No. 3, Red No. 401, Red No. 404, Red No. 405, Red No. 501, Red No. 502, Red No. 503, Red No. 504, Red No. 505, Red No. 506, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 205, Orange No. 206, Orange No. 207, Orange No. 401, Orange No. 402, Orange No. 403, Yellow No. 201, Yellow No. 202-1, Yellow No. 202-2, Yellow No. 203, Yellow No. 204, Yellow No. 205, Yellow No. 4, Yellow No. 401, Yellow No. 402, Yellow No. 403-1, Yellow No. 404, Yellow No. 405, Yellow No. 406, Yellow No. 407, Yellow No. 5, etc.; other acid dyes such as Acid Red 14; basic dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow, etc.; nitro dyes such as HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N,N’-bis(2-hydroxyethyl)-2-nitro-p-phenylenediamine, HC Blue 2, Basic Blue 26, etc.; disperse dyes; inorganic white pigments such as titanium dioxide and zinc oxide; inorganic red pigments such as iron oxide (red iron oxide) and iron titanate; inorganic brown pigments such as γ-iron oxide; inorganic yellow pigments such as yellow iron oxide and loess; inorganic black pigments such as black iron oxide and lower-order titanium oxide;Inorganic purple pigments such as mango violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide, and cobalt titanate; inorganic blue pigments such as ultramarine and navy blue; pearl pigments such as titanium oxide-coated mica, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, colored titanium oxide-coated mica, bismuth oxychloride, and fish scale foil; metal powder pigments such as aluminum powder, copper powder, and gold; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenares, capsanthin, chalcones, carthamin, quercetin, crocin, chlorophyll, curcumin, cochineal, and shikonin; natural pigments and dyes such as bixin, flavones, betacyanidin, henna, hemoglobin, lycopene, riboflavin, and rutin; oxidation dye intermediates and couplers such as p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol, resorcinol, 1-naphthol, 2,6-diaminopyridine, and their salts; and auto-oxidation type dyes such as indoline; dihydroxyacetone is preferably mentioned.;

[0044] As water, in addition to tap water and purified water, hard water, soft water, natural water, deep ocean water, electrolyzed alkaline ion water, electrolyzed acidic ion water, ionized water, and cluster water are preferably mentioned.;

[0045] In addition to these, components described in cosmetic raw material standards, ingredient specifications for different types of cosmetics, the list of ingredient display names of the Japan Cosmetic Industry Association, the INCI Dictionary (The International Cosmetic Ingredient Dictionary and Handbook), quasi-drug raw material standards, the Japanese Pharmacopoeia, pharmaceutical additive standards, the Food Additive Codex, etc., and components described in Japanese and foreign patent gazettes and patent publication gazettes (including published gazettes and re-published gazettes) belonging to the classifications of A61K7 and A61K8 in the International Patent Classification IPC, etc., known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc. can be contained in known combinations and blending ratios and amounts.;

[0046] To explain the types of the hair cosmetics of the present invention in more detail, shampoos such as oil shampoo, cream shampoo, conditioning shampoo, dandruff shampoo, shampoo for hair color, integrated rinse shampoo, etc.; rinses, treatments, hair packs, hair foams, hair mousses, hair sprays, hair mists, hair waxes, hair gels, water greases, setting lotions, color lotions, hair tonics, hair liquids, pomades, chicks, hair creams, hair blows, branch hair coats, hair oils, permanent wave agents, straight perm agents, oxidative hair dyes, hair bleaches, hair color pretreatment agents, hair color aftertreatment agents, perm pretreatment agents, perm aftertreatment agents, hair manicures, and hair growth agents are preferably exemplified.

[0047] As the dosage forms of the hair cosmetics of the present invention, emulsion cosmetics such as oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W / O type, oily cosmetics, solid cosmetics, liquid cosmetics, kneaded cosmetics, stick cosmetics, volatile oil type cosmetics, powdery cosmetics, jelly cosmetics, gel cosmetics, paste cosmetics, emulsion polymer type cosmetics, sheet cosmetics, mist cosmetics, spray type cosmetics, etc. are preferably exemplified.

Examples

[0048] Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples.

[0049] Synthesis Example 1 Into a 300 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 50.0 g (0.176 mol) of stearic acid, 42.2 g (0.422 mol) of L-lactic acid (90%), and 8.8 g (0.105 mol) of a 48% aqueous sodium hydroxide solution were charged, and the reaction was carried out at 190 °C for 1 hour under a nitrogen atmosphere while distilling off the generated water to obtain a reaction product as a pale yellow solid.

[0050] Synthesis Example 2 In a 300 mL reactor equipped with a stirrer, a thermometer, and a gas inlet tube, 40.0 g (0.141 mol) of stearic acid, 38.0 g (0.380 mol) of L-lactic acid (90%), and 11.7 g (0.141 mol) of a 48% aqueous sodium hydroxide solution were charged. While distilling off the generated water, the reaction was carried out at 190 °C for 1 hour under a nitrogen atmosphere to obtain a reaction product as a pale yellow solid.

[0051] Synthesis Example 3 In a 300 mL reactor equipped with a stirrer, a thermometer, and a gas inlet tube, 30.0 g (0.1 mol) of stearic acid, 60.0 g (0.6 mol) of L-lactic acid (90%), and 8.3 g (0.1 mol) of a 48% aqueous sodium hydroxide solution were charged. While distilling off the generated water, the reaction was carried out at 190 °C for 1 hour under a nitrogen atmosphere to obtain a reaction product as a pale yellow solid.

[0052] Synthesis Example 4 In a 300 mL reactor equipped with a stirrer, a thermometer, and a gas inlet tube, 50.0 g (0.176 mol) of stearic acid and 42.2 g (0.422 mol) of L-lactic acid (90%) were charged. While distilling off the generated water, the reaction was carried out at 190 °C for 1 hour under a nitrogen atmosphere to obtain a reaction product as a pale yellow solid.

[0053] Synthesis Example 5 In a 300 mL reactor equipped with a stirrer, a thermometer, and a gas inlet tube, 45.0 g (0.132 mol) of behenic acid, 35.7 g (0.357 mol) of L-lactic acid (90%), and 11.0 g (0.132 mol) of a 48% aqueous sodium hydroxide solution were charged. While distilling off the generated water, the reaction was carried out at 190 °C for 1 hour under a nitrogen atmosphere to obtain a reaction product as a pale yellow solid.

[0054] Comparative Synthesis Example 1 In a 300 mL reactor equipped with a stirrer, a thermometer, and a gas inlet tube, 60.0 g (0.211 mol) of stearic acid, 21.1 g (0.211 mol) of L-lactic acid (90%), and 15.8 g (0.190 mol) of a 48% aqueous sodium hydroxide solution were charged. While distilling off the generated water, the reaction was carried out at 190 °C for 1 hour under a nitrogen atmosphere to obtain a reaction product as a pale yellow solid.

[0055] Comparative Synthesis Example 2 (Oligolactic acid) Into a 300 mL reactor equipped with a stirrer, a thermometer, and a gas inlet tube, 250 g (2.5 mol) of L-lactic acid (90%) was charged, and the reaction was carried out at 190 °C for 7 hours under a nitrogen atmosphere while distilling off the generated water, to obtain a reaction product as a pale yellow liquid substance.

[0056] After subjecting the reaction products of Synthesis Examples 1 to 5 and Comparative Synthesis Examples 1 to 2 to trimethylsilylation treatment, gas chromatography (GC) measurement was carried out under the following conditions. From the obtained results, the range of the degree of polymerization of lactic acid of the compound of the general formula (1) contained in the reaction product, and the average of the degree of polymerization of lactic acid were calculated. The obtained results are shown in Table 1. <GC analysis conditions> Apparatus: GC-2014 (Shimadzu Corporation) Column: CP-SimDist UltiMetal (Inner diameter 0.53 mm, film thickness 0.53 μm, length 10 m, manufactured by Agilent) Carrier gas: He (linear velocity 114.4 cm / s) Detector: Flame ionization detector Detector temperature: 380 °C Injection temperature: 380 °C Measurement conditions: 60 °C → 10 °C / min → 380 °C (8 min)

[0057]

Table 1

[0058] From the results in Table 1, the compounds of the general formula (1) contained in the reaction products of Synthesis Examples 1 to 5 had a degree of polymerization of lactic acid in the range of 1 to 10, and an average degree of polymerization of lactic acid in the range of 1.05 to 6.0.

[0059] <Evaluation 1 of hair damage improvement effect> Using the composition of Table 2, a diluted solution of the compound of Synthesis Example 1 corresponding to Component (A) of the present invention was prepared (Diluted Solution 1). Further, as a comparison, a solution not containing Component (A) of the present invention was prepared (Comparative Solution 1). These were applied to hair to evaluate the effect of improving the feel of the hair. The test method was carried out as follows. The results are shown in Table 3. (Test Method) Healthy black human hair was bleached once with a commercially available two-component bleaching agent to prepare a bundle of damaged hair. Next, 4 g of the bundle of damaged hair was immersed in 1.6 g of the diluted solution, uniformly applied, and then air-dried to obtain Hair Bundle A1 (application only). A part of Hair Bundle A1 was heat-treated twice with a hair iron at 140 °C for 15 seconds to obtain Hair Bundle B1 (after heat treatment). Further, a part of Hair Bundle B1 was washed with a 3% aqueous solution of sodium lauryl sulfate and rinsed with water 5 times, and then air-dried to obtain Hair Bundle C1 (after shampooing). Similarly, Hair Bundles A2 to C2 were prepared using the comparative solution. For each of the prepared hair bundles, the effect of improving the feel of the hair was evaluated by sensory evaluation (7 panelists). The evaluation was carried out by comparing with the untreated hair bundle (damaged hair) in terms of four aspects: smoothness, combability, stiffness, and moistness.

[0060]

Table 2

[0061]

Table 3

[0062] From the results in Table 3, it was found that there was almost no improvement effect with the solution not containing Component (A) of the present invention, while the feel of the hair was significantly improved with the diluted solution containing Component (A) of the present invention. It was confirmed that the effect was enhanced by heat treatment. Also, for the heat-treated hair bundles, even after repeated washing with a 3% aqueous solution of sodium lauryl sulfate and rinsing with water, the improvement effect was not reduced with the diluted solution containing Component (A) of the present invention, and it was found that the effect could be sustained over a long period.

[0063] <Evaluation 2 of the effect of improving hair damage> Using the compositions in Table 4, hair conditioners containing the compounds of Synthesis Examples 1 to 5 corresponding to Component (A) of the present invention were prepared. For comparison, hair conditioners containing the compounds of Comparative Synthesis Example 1 or Comparative Synthesis Example 2 were prepared. Also, as a control, a hair conditioner without the test compound was prepared. The obtained hair conditioners were evaluated for the effect of improving the feel of hair by the following method. The results are also shown in Table 4. <Evaluation method> Healthy black human hair was bleached once with a commercially available two-agent bleaching agent to prepare 5 g of damaged hair bundles. 0.5 g of each hair conditioner was applied to the prepared hair bundles, left for 2 minutes, rinsed under running water for 30 seconds, towel-dried, and then heat-treated twice with a hair iron at 140 °C for 15 seconds. The obtained hair bundles were evaluated for the effect of improving the feel by sensory evaluation (7 panelists). The evaluation was performed by comparing with the control for four points: smoothness, combability, stiffness, and moistness. Also, the obtained hair bundles were washed with a 3% aqueous solution of sodium lauryl sulfate and then washed with water, and the durability of the effect was evaluated from the changes before and after washing.

[0064]

Table 4

[0065] From the results in Table 4, the hair conditioner containing Component (A) of the present invention was excellent in the effect of improving the feel of hair, and the effect persisted even after washing.

[0066] <Evaluation of melting temperature> Using the compositions in Tables 5 and 6, the cosmetic compositions of the present invention were prepared and the melting temperature was evaluated. The evaluation method is described in the lower part of each table.

[0067]

Table 5

[0068]

Table 6

[0069] From the results of Tables 5 and 6, it was confirmed that the melting temperature of the cosmetic composition of the present invention was decreased as compared with that of only the component (A).

[0070] Example 16 Hair Mist Component Blending amount (wt%) ------------------------------------ Cosmetic composition of Example 13 0.2 Neosolue-DiSM (Nippon Fine Chemical) 0.1 Diethyl sebacate (Nippon Fine Chemical) 0.1 Caprylyl glucoside 0.15 Dimethicone 0.1 Cetrimonium chloride (30%) 6.0 EDTA-4Na 0.1 Ethanol 8.0 Purified water An amount to make 100 in total ------------------------------------ (Preparation method) Each component was stirred and mixed uniformly.

[0071] Example 17 Hair Essence Component Blending amount (wt%) ------------------------------------ Part A Cosmetic composition of Example 13 0.3 Neosolue-DiSM (Nippon Fine Chemical) 0.2 Neosolue-Aqulio (Nippon Fine Chemical) 1.0 Diethyl sebacate (Nippon Fine Chemical) 0.5 Cetanol 1.0 Steartrimonium chloride (63%) 0.8 Chloride (75%) 2.8 Sorbitan tetraoleate-60 1.0 PEG-40 hydrogenated castor oil 0.2 Part B Methylparaben 0.1 Etidronic acid 0.1 Purified water in an amount to make a total of 100 ------------------------------------ (Preparation method) The components of Part A were heated to about 80 °C and dissolved. The components of Part B were placed in another container, heated to about 80 °C and dissolved. Part B was gradually added to Part A and mixed uniformly.

[0072] Example 18 Hair lotion Component Blending amount (wt%) ------------------------------------ Part A Cosmetic composition of Example 13 0.2 Diethyl sebacate (Nippon Fine Chemical) 0.2 PEG-4 3.0 Menthol 0.05 Ethanol 50.0 Part B Pyridoxine HCl 0.1 Glycyrrhizic acid 2K 0.1 Licorice extract 0.05 BG 3.0 Ascorbic acid 0.2 Panthenol 2.0 Purified water in an amount to make a total of 100 ------------------------------------ (Preparation method) Mix the components of Part A (Part A). Mix the components of Part B (Part B). Add Part B to Part A and mix uniformly.

[0073] Example 19 Hair cream Component Blending Ratio (wt%) ------------------------------------ Part A Cosmetic composition of Example 13 5.0 Diethyl sebacate (Nippon Fine Chemical) 2.0 Plandool-G (Nippon Fine Chemical) 1.5 Cetanol 4.0 Dimethicone (500 cs) 5.0 Dimethicone (100,000 cs) 1.0 Glyceryl stearate 2.8 Oles-10 phosphate 0.8 Glyceryl stearate (SE) 1.6 Part B 1,3 - Propanediol 10.0 Phenoxyethanol 0.4 Methylparaben 0.2 10% NaOH 0.6 Purified water An amount that totals 100 ------------------------------------ (Preparation Method) Part A was heated to about 80°C and dissolved. Part B was added to a separate container, heated to about 80°C, and dissolved. Part B was added to Part A and stirred and mixed.

[0074] Example 20 Shampoo Component Blending Ratio (wt%) -------------------------------------- Part A Cosmetic composition of Example 13 0.5 Diethyl sebacate (Nippon Fine Chemical) 0.2 TEA - cocoyl glutamate (30%) 50.0 Sodium lauroyl sarcosinate (30%) 10.0 Sodium tetradecene sulfonate (36%) 15.0 PEG - 150 distearate 5.0 Methylparaben 0.2 Phenoxyethanol 0.5 Propylene Glycol 1.0 Inulin-SC (Nippon Seika) 1.0 Neosolue-AquaS (Nippon Seika) 1.5 Section B Cationized Guar Gum 0.2 Purified Water in an amount to make a total of 100 Section C Phosphoric Acid (10%) appropriate amount -------------------------------------- (Preparation Method) Each of Section A and Section B was taken, heated to about 80°C, and uniformly mixed. Section A was added to Section B, uniformly mixed, and then cooled (Section D). Section C was added to Section D, and the pH was adjusted to 6 - 6.5.

[0075] Example 21 Rinse Shampoo Ingredient Blending Amount (wt%) ------------------------------------ Section A Cosmetic Composition of Example 13 0.5 Diethyl Sebacate (Nippon Seika) 0.5 Cocamidopropyl Betaine (30%) 20.0 TEA Lauryl Sulfate (40%) 15.0 Cocamide DEA 2.0 TEA Cocoyl Glutamate (30%) 30.0 Ethylene Glycol Distearate 1.2 Polyquaternium-10 1.6 Stearyl Trimonium Bromide (70%) 0.6 Phenoxyethanol 0.2 Section B Methylparaben 0.2 Sodium Benzoate 0.4 Purified Water in an amount to make a total of 100 ------------------------------------ (Preparation method) The A part and the B part were each taken, heated to about 80°C, and uniformly mixed. The A part was added to the B part, uniformly mixed, and then cooled.

[0076] Example 22 Shampoo for hair coloring Component Blending amount (wt%) -------------------------------------- Cosmetic composition of Example 13 0.6 Diethyl sebacate (Nippon Fine Chemical) 0.5 Cocoyl methyl taurine Na (30%) 15.0 Na olefin (C14-16) sulfonate (36%) 13.0 Cocoa amphoacetate Na (30%) 8.0 PPG-12-PEG-50 lanolin 2.5 Cocoyl glutamate (30%) 7.0 Polyquaternium-10 1.0 Lauramidopropyl hydroxysultaine / water 4.0 PEG-20 hydrogenated castor oil 2.0 Etidronic acid 0.2 PG 0.2 Benzyl alcohol 2.0 Methylparaben 0.2 Phenoxyethanol 0.2 Purified water An amount that totals 100 -------------------------------------- (Preparation method) All the components were taken evenly, heated to 80°C, stirred and mixed uniformly, and then cooled.

[0077] Example 23 Shampoo Component Blending amount (wt%) ---------------------------------- Part A Cosmetic composition of Example 15 1.0 PPG-3 Caprylyl Ether 0.2 Ammonium Lauryl Sulfate 5.0 Sodium Lauryl Sulfate (25%) 10.0 Lauryl Hydroxysultaine (30%) 10.0 Potassium Laurate 1.0 Glycol Distearate 0.5 Toluenesulfonic Acid 0.3 Stearoxypropyl Dimethylamine 0.5 PPG-17 0.3 Dimethicone (6cs) 0.1 PEG-9 Dimethicone 0.1 Amodimethicone 0.1 Diethyl Sebacate (Nippon Fine Chemical) 0.5 Neopentyl Glycol Diethylhexanoate 0.4 Lanolin Fatty Acid 0.3 Isodecyl Glyceryl Ether 0.4 Cocamide MEA 1.0 Laureth-4 0.3 Laureth-16 0.2 Steareth-6 0.2 Phenoxyethanol 0.3 Part B Methylparaben 0.2 Sodium Benzoate 0.3 Purified Water in an amount to make a total of 100 Part C NanoRepair-CMC (Nippon Fine Chemical) 5.0 Polyquaternium-10 0.2 Guar Hydroxypropyltrimonium Chloride 0.1 Tremoist-SL (Nippon Fine Chemical) 3.0 Purified Water 6.7 ---------------------------------- (Preparation Method) The A part was uniformly mixed at about 80°C. The separately prepared B part was heated to about 60°C and made uniform. The B part was gradually added to the A part while stirring, and after being uniformly mixed, it was cooled to about 50°C. Further, the C part was added and uniformly mixed.

[0078] Example 24 Lotion Component Blending amount (wt%) ------------------------------------ Part A Cosmetic composition of Example 13 2.0 Diethyl sebacate (Nippon Fine Chemical) 0.5 Neosolue - DiSM (Nippon Fine Chemical) 0.5 Plandool - H (Nippon Fine Chemical) 0.5 Cetrimonium chloride (30%) 5.2 Octyldodecanol 4.7 Cetanol 2.8 Steartrimonium chloride (63%) 0.6 Diethylhexyl sebacate (Nippon Fine Chemical) 0.3 Squalane 0.3 Sodium myristyl sulfate 0.2 Ceteareth - 40 0.1 Oleth - 5 0.1 Sodium cetyl sulfate 0.1 Part B Citric acid 0.1 Glucono - δ - lactone 0.5 Polylysine 0.1 Polyaspartic acid 0.5 Methylparaben 0.1 Purified water An amount to make a total of 100 ------------------------------------ (Preparation method) The A part was heated to about 80°C and dissolved. The B part was heated to about 80°C and dissolved. The B part was gradually added to the A part while stirring, uniformly mixed, and after stirring, it was rapidly cooled.

[0079] Example 25 Treatment Component Dosage (wt%) ------------------------------------- Part A Cosmetic composition of Example 13 2.5 Diethyl sebacate (Nippon Fine Chemical) 0.5 Propylene glycol 1.0 Steartrimonium chloride (63%) 3.8 Steartrimonium bromide (70%) 1.0 Ceteareth-18 0.8 Oleyl alcohol 3.0 Cetanol 4.0 LUSPLAN DD-DA5 (Nippon Fine Chemical) 0.1 LUSPLAN DD-DHR (Nippon Fine Chemical) 0.3 Plandool-ISS (Nippon Fine Chemical) 0.2 Dimethylaminopropylamide stearate 2.0 Part B Hydrolyzed collagen 1.0 Citric acid Appropriate amount Purified water Amount to make 100 in total ------------------------------------- (Preparation method) Part A was heated to about 80°C. Part B was added to a separate container, heated, and dissolved. While stirring, Part A was gradually added to Part B, uniformly mixed, stirred for 1 minute, and then rapidly cooled.

[0080] Example 26 Non-silicone hair treatment Component Dosage (wt%) -------------------------------------- Part A Cosmetic composition of Example 13 2.5 Diethyl sebacate (Nippon Fine Chemical) 0.5 Neosolue-DiSM (Nippon Fine Chemical) 0.5 Plandool-LG2 (refined in Japan) 0.2 LUSPLAN DD-IS (refined in Japan) 0.05 Plandool-MAS (refined in Japan) 0.2 Propane diol 3.0 Behenamidopropyl dimethylamine 1.5 Cetanol 2.2 Stearyl alcohol 0.8 Hydrogenated rapeseed oil alcohol 0.5 Neopentyl glycol diethylhexanoate 0.8 Jojoba seed oil 1.0 Glyceryl stearate 0.4 Propylparaben 0.1 Cocamide MEA 0.8 Caesalpinia spinosa hydroxypropyltrimonium chloride 0.1 Commiphora wax 0.5 Glycerin 1.0 Part B Methylparaben 0.1 Lactic acid 0.4 Purified water in an amount that totals 100 Part C Methyl heptyl caprylate 1.0 PPG-3 caprylyl ether 1.0 Polyquaternium-7 0.15 PPG-3 benzyl ether myristate 0.5 -------------------------------------- (Preparation method) Part A was uniformly mixed at about 80°C. Separately prepared Part B was heated to about 60°C and made uniform. Part B was gradually added to Part A with stirring, and after uniformly mixing, it was cooled to about 50°C. Further, Part C was added and uniformly mixed.

[0081] Example 27 Non-rinse hair treatment Ingredient Blending amount (wt%) -------------------------------------- Section A Cosmetic composition of Example 13 0.5 Diethyl sebacate (Nippon Fine Chemical) 0.5 Neosolue-DiSM (Nippon Fine Chemical) 0.2 Neosolue-Aqulio (Nippon Fine Chemical) 2.0 LUSPLAN SR-DM4 (Nippon Fine Chemical) 0.1 Cetrimonium chloride (25%) 3.8 Caprylyl glucoside (50%) 0.8 Glycerin 4.0 Phenoxyethanol 0.2 Section B Ethanol 20.0 Section C Polyquaternium-6 0.6 Polyquaternium-7 0.4 Tremoist-TP (Nippon Fine Chemical) 0.05 Purified water in an amount to make a total of 100 -------------------------------------- (Preparation method) Section C was heated to about 80°C and dissolved. Next, Section A was heated to about 80°C and dissolved. Section A was added while stirring Section C, and after uniformly mixing, it was cooled to about 40°C. Then, Section B was added and uniformly mixed.

[0082] Example 28 Leave-on treatment Ingredient Dosage (wt%) ------------------------------------ Section A Cosmetic composition of Example 15 1.0 Diethyl sebacate (Nippon Fine Chemical) 1.0 Neosolue-DiSM (Nippon Fine Chemical) 0.5 Isopropyl palmitate (Nippon Fine Chemical) 4.0 Plandool-LG4 (Nippon Seika) 0.2 Cetanol 5.0 Isostearic acid 2.0 Stearyl trimonium chloride (63%) 3.2 Behenyl trimonium chloride (80%) 1.0 Squalane 1.0 Sunflower seed extract 0.5 Glycerin 1.0 Part B Methylparaben 0.1 Inulin-SC (Nippon Seika) 1.0 Purified water in an amount to make 100 in total ------------------------------------ (Preparation method) Part A was heated to about 80°C and dissolved. Part B was heated to about 80°C and dissolved. Part B was gradually added to Part A and mixed uniformly.

[0083] Example 29 Hair oil Ingredient Blending amount (wt%) ------------------------------------ Cosmetic composition of Example 13 1.0 Diethyl sebacate (Nippon Seika) 0.5 Dimethicone (30 million cps) 5.0 Dimethicone (4 million cps) 5.0 Ethanol 20.0 Olive oil 1.0 Shea butter 1.0 Plandool-S (Nippon Seika) 1.0 Glyceryl tri(caprylate / caprate) (Nippon Seika) 1.0 Dimethiconol 1.0 Tocopherol 0.05 Cyclopentasiloxane in an amount to make 100 in total ------------------------------------ (Preparation method) The components were stirred and mixed uniformly.

[0084] In the above formulation, the details of the components described by the product name are as follows. 〇LUSPLAN DD-IS: Dimer dilinoleyl diisostearate 〇LUSPLAN DD-DHR: Dimer dilinoleyl hydrogenated rosin condensate 〇LUSPLAN DD-DA5: Dimer dilinoleic acid dimer dilinoleyl 〇LUSPLAN SR-DM4: Dimer dilinoleic acid dimer dilinoleyl, glyceryl tri(caprylate / caprate) ○LUSPLAN DA-R: Dimer dilinoleic acid dimer dilinoleyl, triglyceryl hydrogenated rosinate 〇Inulin-SC: Inulin 〇NanoRepair-CMC: Quaternium-18, Quaternium-33, Cholesterol, Ceramide 2, Ceramide 3, Ceramide 6, PG-containing composition 〇Neosolue-Aqulio: Bis(ethoxydiglycol) cyclohexanedicarboxylate 〇Neosolue-AquaS: Polyglyceryl-10 (eicosanedioic acid / tetradecanedioic acid), Glycerin 〇Neosolue-DiSM: Diisostearyl malate 〇Plandool-H: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) 〇Plandool-S: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) 〇Plandool-G: Dimer dilinoleic acid dimer dilinoleyl bis(behenyl / isostearyl / phytosteryl) 〇Plandool-ISS: Phytosteryl isostearate 〇Plandool-MAS: Phytosteryl macadamia nut oil fatty acid 〇Plandool-LG2: Di(phytosteryl / octyldodecyl) lauroyl glutamate 〇Plandool-LG4: Di(phytosteryl / octyldodecyl / behenyl) lauroyl glutamate 〇Tremoist-TP: Jellyfish polysaccharide 〇Tremoist-SL: Aqueous solution of jellyfish polysaccharide (1%)

Claims

1. A cosmetic composition containing the following components (A) and (B), wherein the content of component (A) is 30 to 90% by mass and the content of component (B) is 10 to 70% by mass. (A) A mixture of compounds represented by the following general formula (1) having different degrees of polymerization or salts thereof, wherein the average degree of polymerization n of the mixture is 1.05 to 6.0 【Chemical 1】 (In the formula, R1 is a linear saturated hydrocarbon group having 11 to 23 carbon atoms, and n represents an integer of 1 to 10.) (B) One or more selected from the following component (B1) (B1) Ester oils that are liquid at 25°C, branched higher alcohols, branched higher fatty acids, and unsaturated higher fatty acids

2. The cosmetic composition according to claim 1, wherein component (B1) is selected from diethylhexyl succinate, diisopropyl adipate, diethylhexyl adipate, diethyl sebacate, diisopropyl sebacate, diethylhexyl sebacate, isopropyl myristate, hexyl decyl myristate, isopropyl palmitate, ethylhexyl palmitate, cetyl ethylhexanoate, ethyl oleate, glyceryl triethylhexanoate, glyceryl tri(caprylic acid / capric acid), glyceryl isostearate, diglyceryl diisostearate, polyglyceryl-2 isostearate, diglyceryl diisostearate polyglyceryl-2, polyglyceryl-2 triisostearate, polyglyceryl-2 oleate, trimethylolpropane triethylhexanoate, pentaerythrityl tetraethylhexanoate, sorbitan oleate, sorbitan isostearate, ethylhexyl hydroxystearate, distearyl malate, jojoba oil, isostearyl alcohol, octyldodecanol, isostearic acid, and oleic acid.

3. The cosmetic composition according to claim 1 or 2, further containing one or more selected from the following component (B2) as component (B). (B2) Polyoxyethylene fatty acid esters and polyoxyethylene alkyl ethers

4. The cosmetic composition according to claim 3, wherein the component (B2) is selected from polyoxyethylene monolaurate, polyoxyethylene monopalmitate, polyoxyethylene monostearate, polyoxyethylene monooleate, polyoxyethylene monoisostearate, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene behenyl ether, polyoxyethylene isostearyl ether and polyoxyethylene octyldodecyl ether.

5. The cosmetic composition according to claim 3 or 4, wherein the blending ratio of the components (B1) and (B2) is 8:2 to 2:8 by mass ratio.

6. The composition according to any one of claims 1 to 5, which is for hair cosmetics.

7. A hair cosmetic containing the composition according to any one of claims 1 to 6.

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