High viscosity resin polymerization reactor

Abstract

A polymerization reaction apparatus for a high-viscosity resin such as a biodegradable resin is disclosed. The polymerization reaction apparatus for a high-viscosity resin includes a cylindrical reactor including an inlet formed at an upper portion and an outlet formed at a lower portion, and an impeller rotatably disposed inside the reactor to mix materials in the reactor. The materials in the reactor are mixed by the impeller and polymerized into a high-viscosity resin, and the polymerized high-viscosity resin is discharged to the outside of the reactor through the outlet by adding an inert gas. The ratio of the diameter of the outlet to the diameter of the reactor may be set so that 80% or more of the high-viscosity resin is discharged from the reactor from the time when the inert gas starts to be added to the time when the inert gas reaches the outlet.

Description

[Technical Field]

[0001] Cross-citation with related applications (etc.) This application claims the benefit of priority based on Korean Patent Application No. 10-2021-0106873, filed August 12, 2021, and Korean Patent Application No. 10-2022-0093906, filed July 28, 2022, and all contents disclosed in the documents of said Korean patent applications are incorporated herein by reference.

[0002] The present invention relates to a polymerization reaction apparatus for high-viscosity resins, and more particularly to a polymerization reaction apparatus for high-viscosity resins that can increase the discharge speed of high-viscosity resins such as biodegradable resins and reduce the amount of non-discharge. [Background technology]

[0003] Biodegradable resins such as PLA, PLH, and PBAT are produced by polymerizing monomers and initiators in a polymerization reactor. These biodegradable resins have high viscosity, with viscosities ranging from tens to millions of cP, so it is necessary to design an impeller and polymerization reactor that is suitable for them.

[0004] Furthermore, the polymerized resin is discharged through the lower part of the polymerization reactor by adding pressurizing nitrogen above it. However, the resin discharge speed varies depending on the shape and size of the discharge port at the bottom of the polymerization reactor. If the resin discharge speed is too fast, the time required for the pressurizing nitrogen to reach the discharge port at the bottom of the polymerization reactor may be too short, resulting in an increase in the amount of resin not being discharged. In other words, before the pressurizing nitrogen reaches the discharge port at the bottom of the polymerization reactor, the resin is pressed with sufficient pressure to be discharged. However, after the pressurizing nitrogen reaches the discharge port at the bottom of the polymerization reactor, the pressurizing nitrogen itself escapes to the outside of the polymerization reactor through the discharge port, reducing the efficiency of resin discharge. This may result in an increase in the amount of resin not being discharged.

[0005] The matters described in this background art section are prepared to enhance understanding of the background of the invention, and may include matters that are not prior art already known to those having ordinary skill in the field to which this technology belongs. Summary of the Invention [Problem to be solved by the invention]

[0006] An embodiment of the present invention provides a polymerization reaction apparatus for high-viscosity resin, which can increase the discharge rate of high-viscosity resin such as biodegradable resin while reducing the amount of high-viscosity resin that is not discharged. [Means for solving the problem]

[0007] A polymerization reaction apparatus for a high-viscosity resin according to an embodiment of the present invention includes a cylindrical reactor having an inlet formed at an upper portion and an outlet formed at a lower portion, and an impeller rotatably disposed inside the reactor to mix materials in the reactor.

[0008] The materials in the reactor are mixed by an impeller and polymerized into a high-viscosity resin, and the polymerized high-viscosity resin is discharged to the outside of the reactor through a discharge port by adding an inert gas.

[0009] The ratio of the diameter of the discharge port to the diameter of the reactor may be set so that 80% or more of the high-viscosity resin is discharged from the reactor from the time when the inert gas begins to be added until the inert gas reaches the discharge port.

[0010] In some cases, the ratio of the diameter of the outlet to the diameter of the reactor may be 1 / 15 or less.

[0011] The lower portion of the reactor may be formed as a cone whose diameter decreases downward toward the outlet, and the angle between the side surface of the cone and a horizontal plane may be set to correspond to the angle between the surface of the high-viscosity resin remaining in the reactor and the horizontal plane when the inert gas reaches the outlet.

[0012] In some examples, the angle between the side of the cone and the horizontal plane may be between 40° and 50°.

[0013] The impeller may include a vertical frame that is vertically installed inside the reactor and rotates by receiving rotational power, at least one horizontal frame that is attached to the vertical frame and extends in a radial direction, at least one blade that is attached to the at least one horizontal frame and formed in a spiral shape to surround the vertical frame, and an anchor that is attached to a lowermost horizontal frame of the at least one horizontal frame and protrudes downward at a position corresponding to the cone portion.

[0014] The anchor may include a first portion provided at the radially outer end of the lowest horizontal frame and extending diagonally downward to correspond to the side of the cone portion, and a second portion provided at the lowest horizontal frame radially inward of the first portion, extending downward and connected to the first portion.

[0015] The second portion may be spaced radially outward from an outer circumferential surface of the outlet by a set distance.

[0016] The inert gas may be nitrogen.

[0017] The high-viscosity resin may be a biodegradable resin. [Effects of the Invention]

[0018] According to the embodiment of the present invention, the discharge rate of the high-viscosity resin can be increased in the first phase by appropriately setting the ratio of the diameter of the discharge port to the diameter of the reactor, thereby increasing the discharge rate of the high-viscosity resin while reducing the amount of non-discharged high-viscosity resin.

[0019] Furthermore, by forming the lower part of the reactor as a cone part, the high viscosity resin is more susceptible to the influence of gravity when being discharged.

[0020] Furthermore, by appropriately setting the angle between the side of the cone and the horizontal plane, the amount of high-viscosity resin extruded in the first phase can be further increased.

[0021] Other advantages obtained or expected by the embodiments of the present invention will be directly or implicitly disclosed in the detailed description of the embodiments of the present invention. In other words, various advantages expected by the embodiments of the present invention will be disclosed in the detailed description below.

[0022] The embodiments herein may be better understood by reference to the following description in conjunction with the accompanying drawings, where like reference numbers indicate identical or functionally similar elements and wherein: [Brief explanation of the drawings]

[0023] [Figure 1] 1 is a schematic diagram of a polymerization reaction apparatus for a high-viscosity resin according to an embodiment of the present invention. [Figure 2] FIG. 2 is another schematic diagram of a polymerization reaction apparatus for a high-viscosity resin according to an embodiment of the present invention. [Figure 3] FIG. 1 is a schematic diagram showing the flow of high-viscosity resin in a reactor over time when pressurizing with nitrogen. [Figure 4] 1 is a graph showing the amount of high-viscosity resin discharged and the amount of high-viscosity resin remaining in a reactor over time when pressurizing nitrogen is added. [Figure 5] FIG. 1 is a schematic diagram showing the flow of a high-viscosity resin in a reactor over time when the ratio of the diameter of the discharge port to the diameter of the reactor is 4 / 30. [Figure 6] FIG. 1 is a schematic diagram showing the flow of a high-viscosity resin in a reactor over time when the ratio of the diameter of the discharge port to the diameter of the reactor is 2 / 30. [Figure 7] 1 is a schematic diagram showing the flow of high-viscosity resin during mixing when the angle between the side of the cone part and the horizontal plane is 30°. [Figure 8] 1 is a schematic diagram showing the flow of high-viscosity resin during mixing when the angle between the side of the cone part and the horizontal plane is 45°.

[0024] It should be understood that the above-referenced drawings are not necessarily drawn to scale, but rather present somewhat simplified representations of various preferred features illustrating the underlying principles of the present invention. Specific design features of the present invention, including, for example, specific dimensions, orientations, locations, and shapes, are determined in part by the particular intended application and environment of use. DETAILED DESCRIPTION OF THE INVENTION

[0025] The terminology used herein is for the purpose of describing particular embodiments only and is not intended to limit the present invention. As used herein, the singular forms "a," "an," "the," and "the" are intended to include the plural forms "a," "the," and the like, unless the context clearly dictates otherwise. It should also be understood that the terms "comprise" and / or "comprising," when used herein, specify the presence of stated features, integers, steps, operations, elements, and / or components, but do not exclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and / or groups thereof. As used herein, the term "and / or" includes any one or all combinations of the associated listed items.

[0026] In the high-viscosity resin polymerization reaction apparatus according to the embodiment of the present invention, the discharge amount of high-viscosity resin can be increased in the first phase by appropriately setting the ratio of the diameter of the discharge port to the diameter of the reactor and the angle between the side of the cone and the horizontal plane, thereby reducing the amount of high-viscosity resin that cannot be discharged from the reactor and remains in the reactor.

[0027] Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

[0028] FIG. 1 is a schematic diagram of a polymerization reaction apparatus for a high-viscosity resin according to an embodiment of the present invention, and FIG. 2 is another schematic diagram of a polymerization reaction apparatus for a high-viscosity resin according to an embodiment of the present invention.

[0029] As shown in FIGS. 1 and 2, a polymerization reactor 10 for a high-viscosity resin according to an embodiment of the present invention includes a reactor 11 and an impeller 20 inside the reactor 11.

[0030] The reactor 11 is formed in a roughly cylindrical shape and includes an inlet 12 formed at the top and a discharge port 14 formed at the bottom. The monomers and initiator used in the polymerization reaction are introduced into the reactor 11 through the inlet 12, and the high-viscosity resin after polymerization is discharged out of the reactor 11 through the discharge port 14 by the pressure inert gas (e.g., nitrogen) and gravity.

[0031] The reactor 11 includes, from top to bottom, an upper section, a middle section, and a lower section. The reactor 11 has a generally constant diameter D1 from the upper section (e.g., inlet 12) where the impeller 20 is located to the middle section, and is formed into a cone section 16 whose diameter gradually decreases from the middle section to the lower section (e.g., outlet 14). That is, the outlet 14 has the smallest diameter of the reactor 11, and the diameter of the reactor 11 is referred to as D2. Furthermore, the rate at which the diameter of the reactor 11 decreases, i.e., the angle between the side of the cone section 16 and the horizontal plane, is referred to as θ1. While the reactor 11 is typically formed into an oval shape, in this embodiment of the present invention, the lower section of the reactor 11 is formed into a cone section 16 with an optimized θ1, thereby increasing the influence of gravity when discharging a high-viscosity resin.

[0032] In an embodiment of the present invention, the ratio of the diameter D2 of the discharge port 14 to the diameter D1 of the reactor 11 is set to 1 / 15 or less in order to increase the discharge rate of the high-viscosity resin while reducing the amount of non-discharge. Also, in order to increase the discharge rate of the high-viscosity resin while further reducing the amount of non-discharge, the angle θ1 between the side surface of the cone portion 16 and the horizontal plane is set in the range of 40° to 50°. This will be explained in more detail later.

[0033] The impeller 20 is rotatably disposed inside the reactor 11 and mixes the monomer and initiator introduced into the reactor 11 through the inlet 12 to facilitate the polymerization reaction. In one example, the impeller 20 may be a double-spiral ribbon impeller 20, but the type of the impeller 20 is not limited thereto.

[0034] In this example, the impeller 20 includes a rod-shaped vertical frame 22 , at least one rod-shaped horizontal frame 24 , and at least one blade 26 .

[0035] The vertical frame 22 is installed vertically (i.e., vertically) in the center of the reactor 11, and its upper end is connected to a power source (not shown) to transmit rotational power.

[0036] At least one horizontal frame 24 is attached to the vertical frame 22 at a predetermined position and extends radially. When two or more horizontal frames 24 are attached to the vertical frame 22, the two or more horizontal frames 24 may be attached to the vertical frame 22 at a distance from each other. Both ends of the horizontal frame 24 may extend to the vicinity of the outer periphery of the reactor 11.

[0037] At least one blade 26 may be spirally attached to the end of at least one horizontal frame 24 so as to surround the vertical frame 22. By extending the horizontal frame 24 to the vicinity of the outer circumferential surface of the reactor 11 and attaching the blade 26 spirally to the end of the horizontal frame 24, the mixing efficiency of the high-viscosity resin by the impeller 20 can be improved.

[0038] The impeller 20 further includes at least one anchor 28. The anchor 28 is disposed at a position corresponding to the cone portion 16 of the reactor 11. That is, the anchor 28 protrudes downward from the lowest horizontal frame 24 among the at least one horizontal frame 24 and is formed to correspond to the shape and position of the cone portion 16. The anchor 28 is provided at the bottom of the reactor 11, particularly in the cone portion 16, to facilitate smooth mixing of the high-viscosity resin.

[0039] The anchor 28 may include first and second portions 30 and 32 formed integrally. The first portion 30 of the anchor 28 is provided at the radially outer end of the lowest horizontal frame 24 and extends obliquely downward. The first portion 30 of the anchor 28 extends obliquely downward to correspond to the side of the cone portion 16. That is, the angle between the first portion 30 and the horizontal plane is θ1 or is close to θ1. The second portion 32 of the anchor 28 may be provided at the lowest horizontal frame 24 radially inward of the first portion 30 and extend vertically or nearly vertically downward to be connected to the first portion 30. The second portion 32 is positioned radially outward from the outer circumferential surface of the discharge port 14 by a set distance D3 so as not to interfere with the discharge of resin through the discharge port 14.

[0040] The operation of the high-viscosity resin polymerization reaction apparatus according to the embodiment of the present invention will now be briefly described.

[0041] When the monomer and initiator are introduced into the reactor 11 through the inlet 12, the impeller 20 receives rotational power from the power source and rotates. At this time, at least one horizontal frame 24, at least one blade 26, and anchor 28 attached to the vertical frame 22 rotate together with the vertical frame 22, mixing the monomer and initiator inside the reactor 11 and starting the polymerization reaction.

[0042] When the polymerization reaction is completed and the impeller 20 stops rotating, an inert pressurizing gas (such as nitrogen) is added to the reactor 11 through the inlet 12 to start discharging the high viscosity resin.

[0043] The flow of the high viscosity resin in the reactor 11 when pressurizing with nitrogen will now be described.

[0044] FIG. 3 is a schematic diagram showing the flow of high-viscosity resin in a reactor over time when pressurizing with nitrogen.

[0045] As shown in FIG. 3, when the polymerization reaction of a high-viscosity resin such as a biodegradable resin is completed, pressurizing nitrogen begins to be applied to the high-viscosity resin (see 0 seconds). As a result, the high-viscosity resin begins to be discharged from the reactor 11 through the discharge port 14. At this time, due to its high viscosity, the high-viscosity resin near the central axis of the reactor 11 moves downward faster than the high-viscosity resin near the outer periphery of the reactor 11, resulting in the surface of the high-viscosity resin forming a downward depression in the center in the radial direction (see 5 seconds). As time passes, the depth of the depression in the surface of the high-viscosity resin becomes deeper (see 10 seconds).

[0046] As time passes, the pressurizing nitrogen reaches the discharge port 16 of the reactor 11, thereby completing the first phase (Phase 1) (see 15 seconds). Here, the first phase refers to the period from when the pressurizing nitrogen is added to when the pressurizing nitrogen reaches the discharge port 16. In the first phase, the high-viscosity resin can be discharged in a manner controlled by the pressurizing nitrogen.

[0047] The high-viscosity resin that was not discharged in the first phase and remains inside the reactor 11 is located near the wall of the reactor 11, and an angle θ2 is formed between the surface of the remaining high-viscosity resin and the horizontal plane. The angle θ2 between the surface of the remaining high-viscosity resin and the horizontal plane is formed when pressurizing nitrogen forcibly discharges the high-viscosity resin through the discharge port 16. Therefore, if the angle θ1 between the side surface of the cone portion 16 and the horizontal plane is set to correspond to the angle θ2 between the surface of the remaining high-viscosity resin and the horizontal plane, the discharge amount of the high-viscosity resin in the first phase can be increased and the amount of remaining high-viscosity resin (i.e., the amount not discharged) can be reduced.

[0048] Then, the second phase (Phase 2) begins (see 15 to 35 seconds). In the second phase, the high-viscosity resin flows down the walls of the reactor 11 and the cone 16 due to gravity rather than pressurizing nitrogen, so it may be difficult to discharge the high-viscosity resin in a controlled manner like in the first phase. Also, since the pressurizing nitrogen does not have a significant effect on the discharge of the high-viscosity resin, the angle θ2 between the surface of the remaining high-viscosity resin and the horizontal plane does not change significantly.

[0049] Figure 4 is a graph showing the amount of high-viscosity resin discharged over time and the amount of high-viscosity resin remaining in the reactor when pressurizing nitrogen is added. In Figure 4, the solid line shows the amount of high-viscosity resin discharged from the reactor 11, and the dotted line shows the amount of high-viscosity resin remaining in the reactor 11 without being discharged.

[0050] As shown in Figure 4, when pressurizing nitrogen is added, the discharge rate of high-viscosity resin increases steadily in the first phase. The rate of increase in the discharge rate of high-viscosity resin in the first phase (corresponding to the discharge rate) is usually related to the nitrogen pressure (e.g., 3 bar to 7 bar). However, increasing the nitrogen pressure and increasing the discharge rate may shorten the time it takes for the nitrogen to reach the discharge port 16. In other words, the first phase may be shortened. In this case, the shortened first phase may actually reduce the discharge rate of high-viscosity resin in the first phase.

[0051] Then, in the second phase, the increase in the amount of high-viscosity resin discharged is somewhat alleviated, and the high-viscosity resin is discharged in an uncontrolled manner.

[0052] As mentioned above, the high-viscosity resin is discharged in a controlled manner in the first phase and in an uncontrolled manner in the second phase, so in order to increase the discharge rate of the high-viscosity resin and reduce the amount of non-discharge, it is necessary to maximize the amount of high-viscosity resin discharged in the first phase. Below, we will explain the relationship between the ratio of the diameter of the discharge port to the diameter of the reactor and the amount of high-viscosity resin discharged in the first phase.

[0053] Figure 5 is a schematic diagram showing the flow of high-viscosity resin in a reactor over time when the ratio of the outlet diameter to the reactor diameter is 4 / 30, and Figure 6 is a schematic diagram showing the flow of high-viscosity resin in a reactor over time when the ratio of the outlet diameter to the reactor diameter is 2 / 30. Figures 5 and 6 show the flow of high-viscosity resin in the reactor at the same point in time.

[0054] As shown in Figure 5, when the ratio of the outlet diameter to the reactor diameter is 4 / 30, the surface of the remaining high-viscosity resin sinks downward relatively quickly, and the time it takes for nitrogen to reach the outlet 16 is relatively short. In other words, the first phase is short.

[0055] In contrast, as shown in Figure 6, if the ratio of the diameter of the outlet to the diameter of the reactor is 2 / 30, the surface of the remaining high-viscosity resin remains on a generally horizontal plane for a longer period of time, and the time it takes for nitrogen to reach the outlet 16 is relatively longer. In other words, the first phase is longer.

[0056] The discharge amount of high-viscosity resin in the first phase at various ratios of the outlet diameter D2 to the reactor diameter D1 is shown in Table 1. [Table 1]

[0057] In Table 1, the discharge amount is the percentage of the discharge amount of the high-viscosity resin in the first phase relative to the amount of the high-viscosity resin in the reactor 11 before discharge.

[0058] Referring to Table 1, if the diameter D2 of the discharge port is relatively large relative to the diameter D1 of the reactor (for example, 4 / 30 or more), the discharge speed of the high-viscosity resin is too fast, causing the nitrogen to reach the discharge port 16 very quickly. Therefore, the first phase is shortened, and half of the high-viscosity resin is not discharged during the first phase.

[0059] However, if the diameter D2 of the discharge port is relatively small relative to the diameter D1 of the reactor (for example, if it is 3 / 30 or less), the first phase becomes longer, and about 65% or more of the high-viscosity resin is discharged during the first phase. In particular, if the diameter D2 of the discharge port relative to the diameter D1 of the reactor is 1 / 15 or less, about 82% or more of the high-viscosity resin is discharged during the first phase.

[0060] On the other hand, during the first phase, the high-viscosity resin near the side of the cone portion 16 is not significantly affected by the addition of nitrogen and may remain in the reactor 11 during the first phase. Thus, to reduce the amount of high-viscosity resin remaining in the reactor 11 during the first phase, the angle θ1 between the side of the cone portion 16 and the horizontal plane can be set to correspond to the angle θ2 between the surface of the remaining high-viscosity resin and the horizontal plane. In this case, the amount of high-viscosity resin that is not affected by nitrogen is reduced, and the amount of high-viscosity resin remaining in the reactor 11 during the first phase is reduced.

[0061] Through various experiments, it was found that the angle θ2 between the surface of the remaining high-viscosity resin and the horizontal plane is approximately 45°. Therefore, the angle θ1 between the side of the cone part 16 and the horizontal plane can be set in the range of 40° to 50°.

[0062] However, it is known that the angle θ1 between the side surface of the cone portion 16 and the horizontal plane affects the mixing performance of high-viscosity resins. The effect of the angle θ1 between the side surface of the cone portion 16 and the horizontal plane on the mixing performance of high-viscosity resins will be explained below.

[0063] Figure 7 is a schematic diagram showing the flow of high-viscosity resin during mixing when the angle between the side of the cone and the horizontal plane is 30°, demonstrating the mixing performance of a commonly used reactor.

[0064] FIG. 8 is a schematic diagram showing the flow of high-viscosity resin during mixing when the angle between the side of the cone section and the horizontal plane is 45°, demonstrating the mixing performance of the reactor according to the embodiment of the present invention.

[0065] 7 and 8, when the angle θ1 between the side surface of the cone section 16 and the horizontal plane is 30°, the mixing performance of the reactor 11 is not significantly different from that of the reactor 11 when the angle θ1 between the side surface of the cone section 16 and the horizontal plane is 45°. The power consumption per unit volume (P / V) and the up / down circulation time, which indicate the mixing performance, are listed in Table 2. [Table 2]

[0066] Referring to [Table 2], the power consumption per unit volume (P / V) in the comparative example is 96.97kW / m 3 In the example, the power consumption per unit volume (P / V) is 95.40 kW / m 3 The power consumption per unit volume is not only almost the same between the comparative example and the example, but is actually even lower in the example.

[0067] In addition, the upper / lower circulation time in the comparative example was 2.79 seconds, while in the example the upper / lower circulation time was 2.73 seconds. There was almost no difference in the upper / lower circulation time between the comparative example and the example, and in fact it was even shorter in the example.

[0068] Therefore, it can be seen that setting the angle θ1 between the side surface of the cone portion 16 and the horizontal plane in the range of 40° to 50° does not significantly change the mixing performance of the reactor 11, and in fact, it slightly increases it. However, if the angle θ1 between the side surface of the cone portion 16 and the horizontal plane is set in the range of 40° to 50°, the amount of high-viscosity resin in the reactor 11 that is affected by the addition of nitrogen may further increase, and the amount of high-viscosity resin discharged from the reactor 11 during the first phase may increase.

[0069] Although the preferred embodiments of the present invention have been described above, the present invention is not limited to the above embodiments and includes all modifications that can be easily made by a person having ordinary skill in the art to which the invention pertains and that are deemed equivalent to the embodiments of the present invention.

Claims

1. a cylindrical reactor including an inlet formed at an upper portion and a discharge port formed at a lower portion; an impeller rotatably disposed within the reactor for mixing materials within the reactor; Including, The materials in the reactor are mixed by an impeller and polymerized into a high-viscosity resin, and the polymerized high-viscosity resin is discharged to the outside of the reactor through a discharge port by adding an inert gas; a ratio of the diameter of the discharge port to the diameter of the reactor is set so that 80% or more of the high-viscosity resin is discharged from the reactor from the time when the inert gas starts to be added until the inert gas reaches the discharge port; The ratio of the diameter of the outlet to the diameter of the reactor is 1 / 15 or less. Polymerization reactor for high viscosity resin.

2. The lower portion of the reactor is formed into a cone shape whose diameter decreases as it goes downward toward the discharge port, 2. The polymerization reaction apparatus for high-viscosity resins according to claim 1, wherein the angle between the side surface of the cone portion and the horizontal plane is set to correspond to the angle between the surface of the high-viscosity resin remaining in the reactor and the horizontal plane when the inert gas reaches the discharge outlet.

3. 3. The polymerization reaction apparatus for high-viscosity resins according to claim 2, wherein the angle between the side surface of the cone portion and the horizontal plane is 40° to 50°.

4. The impeller is a vertical frame installed vertically inside the reactor and rotating by receiving rotational power; at least one horizontal frame attached to the vertical frame and extending radially; At least one blade attached to the at least one horizontal frame and spirally formed around the vertical frame; an anchor attached to a lowermost horizontal frame among the at least one horizontal frame and protruding downward at a position corresponding to the cone portion; The polymerization reactor for high-viscosity resins according to claim 2, comprising:

5. The anchor is a first portion provided at a radially outer end of the lowermost horizontal frame and extending obliquely downward so as to correspond to a side surface of the cone portion; a second portion provided on the lowermost horizontal frame radially inside the first portion, extending downward and connected to the first portion; The polymerization reactor for high-viscosity resins according to claim 4, comprising:

6. 6. The polymerization reaction apparatus for a high-viscosity resin according to claim 5, wherein the second portion is spaced radially outward from the outer circumferential surface of the discharge port by a set distance.

7. 2. The polymerization reaction apparatus for high-viscosity resins according to claim 1, wherein the inert gas is nitrogen.

8. 2. The polymerization reaction apparatus for a high-viscosity resin according to claim 1, wherein the high-viscosity resin is a biodegradable resin.

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