Catalysts containing an active nickel phase distributed in a shell

Abstract

Disclosed is a catalyst comprising a nickel-based active phase and an alumina support, characterized in that: the nickel is distributed both in a shell around the support and in the core of the support, the thickness of said shell being between 2% and 15% of the diameter of the catalyst; the nickel density ratio of the shell to the core being strictly greater than 3; and the shell containing between 40% and 80% by weight of elemental nickel relative to the total weight of nickel contained in the catalyst.

Description

[Technical Field]

[0001] The present invention relates to supported nickel-based metal catalysts that are particularly intended for the hydrogenation of unsaturated hydrocarbons, and more particularly for the selective hydrogenation of polyunsaturated compounds or the hydrogenation of aromatic compounds. [Background technology]

[0002] Monounsaturated organic compounds, such as ethylene and propylene, are at the root of the production of polymers, plastics, and other value-added chemical products. These compounds are obtained from natural gas, naphtha, or gas oil and processed by steam cracking or catalytic cracking. These processes, carried out at high temperatures, produce, in addition to the desired monounsaturated compounds, polyunsaturated organic compounds, such as acetylene, propadiene, and methylacetylene (i.e., propyne), 1,2-butadiene and 1,3-butadiene, vinylacetylene and ethylacetylene, and other polyunsaturated compounds whose boiling points correspond to the C5+ gasoline fraction (gasoline containing hydrocarbon compounds with five or more carbon atoms), especially styrene or indene compounds. These polyunsaturated compounds are highly reactive and cause side reactions in the polymerization unit. Therefore, their removal is necessary before economical use of these fractions can be made. Selective hydrogenation is the primary process developed to specifically remove unwanted polyunsaturated compounds from these hydrocarbon feedstocks. This allows for the conversion of polyunsaturated compounds to the corresponding alkenes or aromatic compounds while avoiding complete saturation of the polyunsaturated compounds and the resulting formation of the corresponding alkanes or naphthenes.

[0003] Selective hydrogenation catalysts are generally based on metals from group VIII of the periodic table, such as palladium or nickel. The metal is in the form of metal particles and deposited on a support. The metal content in the support, the size of the metal particles, and the distribution of the active phase are among the criteria that have an influence on the activity and selectivity of the catalyst.

[0004] The macroscopic distribution of metal particles in the support constitutes an important criterion, primarily in terms of rapid and continuous reactions, such as selective hydrogenation. It is generally desirable for these elements to be located in a crust at the periphery of the support to avoid intra-particle mass transfer problems that may result in activity defects and selectivity loss. Such catalysts are also called "eggshell" catalysts.

[0005] Such catalysts are widely known in the case of palladium-based selective hydrogenation catalysts. Indeed, due to the low palladium content (generally less than 1% by weight of palladium relative to the catalyst) and suitable preparation methods, a thin crust of palladium can be obtained around the support particles (Patent Documents 1 and 2).

[0006] It is often proposed to replace palladium with nickel. Nickel is a less active metal than palladium and therefore requires a larger amount in the catalyst. Therefore, nickel-based catalysts generally have a metal content of 5% to 50% by weight of nickel relative to the catalyst. In these catalysts, the nickel is generally uniformly distributed within the support. One possible way to improve these catalysts in terms of activity and selectivity is to control the distribution of nickel within the support by depositing it more densely on a crust at the periphery of the support. Such catalysts are known from the prior art.

[0007] Patent document 3 describes an "eggshell" catalyst containing nickel on a porous support, the porous support having a pore volume of at least 0.2 mL / g for pores with a size of less than 11.7 nm and a pore volume of at least 0.1 mL / g for pores with a size of 11.7 nm or more. More than 50% of the nickel is found in the crust, the thickness of which is equal to 0.15 times the radius of the support. This catalyst is used for the hydrogenation of fats.

[0008] The document (Patent Document 4) describes supported nickel catalysts in which more than 90% of the nickel is found in a crust 700 μm thick. The catalysts are prepared using a solution of ammonia to dissolve the nickel salt. These catalysts are used in selective hydrogenation applications.

[0009] Patent Document 5 describes a supported nickel catalyst in which the nickel crystallite size distribution is bimodal, with 30% to 70% of the nickel crystallites having an average size (diameter) of 1.0 to 2.5 nm and the remaining nickel crystallites having an average size (diameter) of 3.0 to 4.5 nm. The nickel is distributed on a crust having a thickness of 3% to 15% of the diameter and at the core, and the nickel concentration ratio between the crust and the core is 3.0:1 to 1.3:1. At least 75% of the pore volume is found in pores having a size greater than 5.0 nm. [Prior art documents] [Patent documents]

[0010] [Patent Document 1] French Patent Application Publication No. 2922784 (Patent Publication No. 2011-500327) [Patent Document 2] US Patent Application Publication No. 2010 / 217052 [Patent Document 3] U.S. Patent No. 4,519,951 [Patent Document 4] Chinese Patent Application Publication No. 101890351 [Patent Document 5] US Patent Application Publication No. 2012 / 0065442 Summary of the Invention [Means for solving the problem]

[0011] (Object of the invention) Surprisingly, the applicant has discovered that by adding a specific organic additive to a nickel-based catalyst comprising an alumina support obtained by a very specific method, followed by a specific hydrothermal treatment, a catalyst is obtained in which at least a portion of the nickel is distributed throughout a crust at the periphery of the support, while the other portion of the nickel is distributed in the core of the catalyst. Without wishing to be bound by any theory, the hydrothermal treatment carried out after the step of contacting the specific organic additive with the nickel-based catalyst on the specific alumina support, via hydrothermal treatment in the presence of an acid solution, appears to cause the nickel to migrate at least in part from the interior of the support to the periphery of the support, thus forming a nickel crust. Therefore, the present invention relates to a new type of catalyst, which, thanks to its specific preparation method, makes it possible to obtain a catalyst containing at least equally good, or even better, performance qualities in terms of activity and selectivity in the selective hydrogenation of polyunsaturated compounds or aromatic compounds, while using a lower amount of nickel phase than typically used in the prior art, due to a better distribution of the nickel active phase in the support, making it more accessible to reagents.

[0012] The present invention relates to a catalyst comprising a nickel-based active phase and an alumina support, said catalyst comprising 1% by weight to 50% by weight of elemental nickel relative to the total weight of the catalyst, said catalyst comprising: - the nickel is distributed both on a crust at the periphery of the support and in the core of the support, the thickness of said crust being between 2% and 15% of the diameter of the catalyst; - The nickel density ratio between the crust and the core must be strictly greater than 3; - the crust contains more than 25% by weight of elemental nickel relative to the total weight of nickel contained in the catalyst; - The size of nickel particles in the catalyst is 7-25 nm, measured in oxide form. It is characterized in that

[0013] Advantageously, the nickel density ratio between the crust and the core is greater than or equal to 3.5.

[0014] Advantageously, said crust comprises more than 40% by weight of elemental nickel relative to the total weight of nickel contained in the catalyst.

[0015] Advantageously, the transition interval between the core and the crust of the catalyst is between 0.05% and 3% of the diameter of the catalyst.

[0016] Advantageously, the size of the nickel particles in the catalyst is between 8 and 23 nm.

[0017] Advantageously, the sulphur content of the alumina support is between 0.001% and 2% by weight relative to the total weight of the alumina support, and the sodium content of said alumina support is between 0.001% and 2% by weight relative to the total weight of the alumina gel.

[0018] Advantageously, the thickness of said crust is between 2.5% and 12% of the diameter of the catalyst.

[0019] Advantageously, the nickel density ratio between the crust and the core is between 3.8 and 15.

[0020] Another subject of the invention relates to a method for preparing a catalyst according to the invention, which method comprises the following steps: a) providing an alumina gel; b) shaping the alumina gel from step a); c) subjecting the shaped alumina gel obtained at the end of step b) to a heat treatment to obtain an alumina support, said heat treatment comprising at least one hydrothermal treatment step in the presence of an acid solution in an autoclave at a temperature between 100°C and 800°C, and at least one calcination step carried out after the hydrothermal treatment step at a temperature between 400°C and 1500°C; d) contacting the alumina support obtained at the end of step c) with at least one precursor of a nickel active phase to obtain a catalyst precursor; e) drying the catalyst precursor obtained at the end of step d) at a temperature below 250°C; f) contacting the dried catalyst precursor obtained at the end of step e) with at least one solution containing at least one organic additive selected from aldehydes containing 1 to 14 carbon atoms per molecule, ketones or polyketones containing 3 to 18 carbon atoms per molecule, ethers and esters containing 2 to 14 carbon atoms per molecule, alcohols or polyalcohols containing 1 to 14 carbon atoms per molecule and carboxylic acids or polycarboxylic acids containing 1 to 14 carbon atoms per molecule, the molar ratio between the organic additive and nickel being greater than 0.05 mol / mol; g) hydrothermal treatment of the catalyst precursor obtained at the end of step f) at a temperature between 100°C and 200°C under a gas stream containing 5 to 650 grams of water per kg of dry gas. Includes:

[0021] Advantageously, the method further comprises a step h) of drying the catalyst precursor obtained at the end of step g) under a gas stream containing an amount of water strictly less than 5 grams per kg of dry gas at a temperature between 50°C and 200°C.

[0022] Advantageously, the method further comprises a step e1) of calcining the dried catalyst precursor obtained at the end of step e) at a temperature between 250°C and 1000°C under a gas stream containing water in an amount strictly less than 150 grams of water per kg of weight of drying gas.

[0023] Advantageously, in step f), the organic additive is chosen from formic acid, formaldehyde, acetic acid, citric acid, oxalic acid, glycolic acid, malonic acid, ethanol, methanol, ethyl formate, methyl formate, paraldehyde, acetaldehyde, gamma-valerolactone, glucose and sorbitol, trioxane, and preferably, the organic additive is formic acid.

[0024] Another subject of the invention relates to a process for the selective hydrogenation of polyunsaturated compounds containing at least two carbon atoms per molecule contained in a hydrocarbon feedstock having a final boiling point of less than or equal to 300°C, which is carried out in the presence of a catalyst according to the invention, at a temperature of 0°C to 300°C, a pressure of 0.1 to 10 MPa, and, if the process is carried out in the liquid phase, a hydrogen / (polyunsaturated compound to be hydrogenated) molar ratio of 0.1 to 10, and an hourly space velocity of 0.1 to 200 h -1 or if the process is carried out in the gas phase, the hydrogen / (polyunsaturated compound to be hydrogenated) molar ratio is 0.5 to 1000, and the hourly space velocity is 100 to 40,000 h -1 is.

[0025] Another subject of the present invention relates to a process for the hydrogenation of at least one aromatic or polyaromatic compound contained in a hydrocarbon feedstock having a final boiling point of less than or equal to 650°C, which is carried out in the gas or liquid phase in the presence of a catalyst according to the present invention, at a temperature between 30°C and 350°C, at a pressure between 0.1 and 20 MPa, with a hydrogen / aromatic compound to be hydrogenated molar ratio between 0.1 and 10, and with an hourly space velocity (HSV) between 0.05 and 50 h -1 is. DETAILED DESCRIPTION OF THE INVENTION

[0026] DESCRIPTION OF THE DRAWINGS FIG. 1 shows the distribution of nickel in the catalyst. The x-axis corresponds to the thickness of the catalyst (μm) measured from the edge of the catalyst. The y-axis corresponds to the nickel density (grams of Ni / mm 3 ) corresponds to the nickel density d. The nickel is distributed both on a crust of thickness ep1 at the periphery of the support and in the core of the support. crust is the nickel density in the core of the support, d core The transition interval between the catalyst core and crust has a thickness denoted as ep2-ep1.

[0027] (Detailed Description of the Invention) (1.Definition) Hereinafter, the groups of chemical elements are given according to the CAS classification (CRC Handbook of Chemistry and Physics, published by CRC Press, editor-in-chief DR Lide, 81st edition, 2000-2001). For example, group VIII according to the CAS classification corresponds to the metals in columns 8, 9 and 10 according to the new IUPAC classification.

[0028] In the present description, in accordance with the IUPAC convention, "micropores" are understood to mean pores having a diameter of less than 2 nm, i.e. less than 0.002 μm; "mesopores" are understood to mean pores having a diameter of 2 nm or more, i.e. 0.002 μm or more, and 50 nm or less, i.e. 0.05 μm or less, and "macropores" are understood to mean pores having a diameter of more than 50 nm, i.e. more than 0.05 μm.

[0029] To analyze the distribution of metallic phases on the support, the crust thickness is measured by Castaing microprobe (or electron microprobe microanalysis). The device used is a CAMECA XS100 equipped with four monochromator crystals, allowing for the simultaneous analysis of four elements. The Castaing microprobe analysis technique consists of detecting the X-rays emitted by the solid after excitation of the elements by a high-energy electron beam. For this characterization, the catalyst grains are coated on blocks of epoxy resin. These blocks are polished until a cross section through the diameter of the bead or extrudate is obtained, and then metallized by carbon deposition in a metal evaporator. An electron probe is scanned along the diameter of five beads or extrudates to obtain an average distribution profile of the constituent elements of the solid. This method is well known to those skilled in the art and is defined in the publication "Measurement of palladium crust thickness on catalyst by EPMA," by L. Sorbier et al., Materials Science and Engineering 32 (2012). It is then possible to establish the distribution profile within the grain of a given element, here nickel. Furthermore, the Ni concentration is defined for each measurement and therefore for each analytical step. The density of Ni within the grain is therefore given by the volume (mm 3 ) is defined as the concentration of Ni per 1000 ppm.

[0030] The total pore volume was determined by mercury porosimetry according to standard ASTM D4284-92. At an angle of 140°, it is measured, for example, using an Autopore III® model device from the Micromeritics® brand.

[0031] The BET specific surface area is measured by nitrogen physical adsorption according to standard ASTM D3663-03, as described in the study by Rouquerol F., Rouquerol J. and Singh K., "Adsorption by Powders & Porous Solids: Principles, Methodology and Applications", Academic Press, 1999.

[0032] The median mesopore diameter is also defined as the diameter of the combined pores that make up the mesopore volume such that all pores having a size less than this diameter make up 50% of the total mesopore volume as determined by mercury porosimetry intrusion.

[0033] "Nickel particle size" is understood to mean the diameter of nickel crystallites in the oxide form. The diameter of nickel crystallites in the oxide form is determined by X-ray diffraction from the width of the diffraction line located at an angle 2θ=43° (i.e., along the crystallographic direction

[0200] ) using the Scherrer relation. This method, used in X-ray diffraction on polycrystalline samples or powders, connects the full width at half maximum of the diffraction peak to the particle size, and is described in detail in the following reference: Appl. Cryst. (1978), 11, 102-113, "Scherrer after sixty years: A survey and some new results in the determination of crystallite size", JI Langford and AJC Wilson.

[0034] The nickel content is measured by X-ray fluorescence.

[0035] (2. Catalyst) The present invention relates to a catalyst comprising, preferably consisting of, a nickel-based active phase and an alumina support, advantageously containing sulphur and sodium, said catalyst comprising between 1% and 50% by weight of elemental nickel relative to the total weight of the catalyst, said catalyst being characterized in that: - the nickel is distributed both on a crust at the periphery of the support and in the core of the support, the thickness of said crust (also referred to as ep1) being between 2% and 15% of the diameter of the catalyst, preferably between 2.5% and 12% of the diameter of the catalyst, even more preferably between 3% and 10% of the diameter of the catalyst, even more preferably between 3% and 7.5% of the diameter of the catalyst; - Nickel density ratio between the crust and the core (here d crust / d core (also referred to as ) is strictly greater than 3, preferably greater than 3.5, preferably between 3.8 and 15; said crust comprises more than 25% by weight, preferably more than 40% by weight, more preferentially between 45% and 90% by weight, and even more preferably between 60% and 90% by weight, of elemental nickel relative to the total weight of elemental nickel contained in the catalyst; It is characterized by.

[0036] Advantageously, the transition distance between the catalyst core and crust (also referred to herein as the core / crust transition distance, or ep2-ep1 as per the notation in FIG. 1) is very steep, coupled with a variation in nickel density measured across the catalyst thickness from the edge of the catalyst to the center of the catalyst. Preferably, the core / crust transition distance is between 0.05% and 3% of the catalyst diameter, preferably between 0.5% and 2.5% of the catalyst diameter.

[0037] The nickel content in the catalyst according to the invention is advantageously between 1% and 50% by weight relative to the total weight of the catalyst, more preferentially between 2% and 40% by weight relative to the total weight of the catalyst, even more preferentially between 3% and 35% by weight relative to the total weight of the catalyst, and even more preferentially between 5% and 25% by weight relative to the total weight of the catalyst. The "% by weight" values ​​are based on the elemental form of nickel.

[0038] The catalyst according to the present invention may be described as a "semi-eggshell" catalyst, in that the concentration of nickel is higher at the periphery of the support than in the core of the support, and said concentration of nickel in the core of the support is non-zero.

[0039] The specific surface area of ​​a catalyst is generally 10 m 2 / g~200m 2 / g, preferably 25m 2 / g~110m 2 / g, more preferably 40m 2 / g~100m 2 / g.

[0040] The total pore volume of the catalyst is generally 0.1 to 1 mL / g, preferably 0.2 mL / g to 0.8 mL / g, and particularly preferably 0.3 mL / g to 0.7 mL / g.

[0041] The size of the nickel particles, measured in the oxide form, is 7 to 25 nm, preferably 8 to 23 nm in the catalyst.

[0042] The active phase of the catalyst does not contain any metals from group VIB, in particular it does not contain molybdenum or tungsten.

[0043] The catalyst (and the support used for preparing the catalyst) is in the form of grains, advantageously having a diameter of 0.5 to 10 mm. The grains may have any form known to those skilled in the art, such as beads (preferably having a diameter of 1 to 8 mm), extrudates, tablets or hollow cylinders. Preferably, the catalyst (and the support used for preparing the catalyst) is in the form of extrudates, having a diameter of 0.5 to 10 mm, preferably 0.8 to 3.2 mm, and highly preferably 1.0 to 2.5 mm, and a length of 0.5 to 20 mm. The "diameter" of the extrudates is intended to mean the diameter of the circle circumscribing the cross section of these extrudates. The catalyst may advantageously be presented in the form of cylindrical, multilobal, trilobal or tetralobal extrudates. Preferably, the shape will be trilobal or tetralobal. The lobe shape may be adjusted by any method known from the prior art.

[0044] (3. Carrier) The characteristics of the alumina mentioned in this section correspond to the characteristics of the alumina before impregnation with the nickel active phase, i.e. the alumina support obtained at the end of step c) of the process for preparing the catalyst according to the invention.

[0045] According to the invention, the support is an alumina, i.e. it comprises at least 95% by weight, preferably at least 98% by weight, particularly preferably at least 99% by weight, of alumina relative to the weight of the support. The alumina generally has a crystallographic structure of the delta, gamma or theta alumina type, either alone or in a mixture.

[0046] According to the present invention, the alumina support may also contain impurities, such as oxides of metals from groups IIA, IIIB, IVB, IIB, IIIA and IVA according to the CAS classification, preferably silica, titanium dioxide, zirconium dioxide, zinc oxide, magnesium oxide and calcium oxide, or alkali metals, preferably lithium, sodium or potassium, and / or alkaline earth metals, preferably magnesium, calcium, strontium or barium, or sulfur.

[0047] Advantageously, the sulphur content of the alumina support is between 0.001% and 2% by weight relative to the total weight of the alumina support, and the sodium content of said alumina support is between 0.001% and 2% by weight relative to the total weight of the alumina gel.

[0048] The specific surface area of ​​alumina is generally 10m 2 / g~250m 2 / g, preferably 30m 2 / g~200m 2 / g, more preferably 50m 2 / g~150m 2 / g.

[0049] The pore volume of the alumina is generally 0.1 mL / g to 1.2 mL / g, preferably 0.3 mL / g to 0.9 mL / g, and highly preferably 0.5 mL / g to 0.9 mL / g.

[0050] Methods for Preparing the Catalyst Another subject of the invention is a process for preparing a catalyst according to the invention, comprising at least the following steps: a) providing an alumina gel having a sulfur content advantageously ranging from 0.001% to 2% by weight relative to the total weight of said alumina gel, and a sodium content ranging from 0.001% to 2% by weight relative to the total weight of said alumina gel; b) shaping the alumina gel from step a); c) subjecting the shaped alumina gel obtained at the end of step b) to a heat treatment to obtain an alumina support, said heat treatment comprising at least one hydrothermal treatment step in the presence of an acid solution in an autoclave at a temperature between 100°C and 800°C, and at least one calcination step carried out after the hydrothermal treatment step at a temperature between 400°C and 1500°C; d) contacting the alumina support obtained at the end of step c) with at least one precursor of a nickel active phase to obtain a catalyst precursor; e) drying the catalyst precursor obtained at the end of step d) at a temperature below 250°C; e1) optional heat treatment of the dried catalyst precursor obtained at the end of step e) at a temperature between 250°C and 1000°C to obtain a calcined catalyst precursor; f) contacting the dried catalyst precursor obtained at the end of step e) and optionally the calcined catalyst precursor obtained at the end of step e1) with at least one solution containing at least one organic additive selected from aldehydes containing 1 to 14 carbon atoms per molecule, ketones or polyketones containing 3 to 18 carbon atoms per molecule, ethers or esters containing 2 to 14 carbon atoms per molecule, alcohols or polyalcohols containing 1 to 14 carbon atoms per molecule and carboxylic acids or polycarboxylic acids containing 1 to 14 carbon atoms per molecule, the molar ratio between the organic additive and nickel being greater than 0.05 mol / mol; g) hydrothermal treatment of the catalyst precursor obtained at the end of step f) at a temperature between 100°C and 200°C for a period of 30 minutes to 5 hours under a gas flow containing 5 to 650 grams of water per kilogram of dry gas; h) an optional step of drying the catalyst precursor obtained at the end of step g) at temperatures between 50°C and 200°C under a gas stream containing water in an amount strictly less than 5 grams per kilogram of dry gas. The present invention relates to a method, comprising:

[0051] The order of steps a) to h) cannot be changed. However, intermediate steps can be inserted (especially additional drying steps), and certain steps can be performed several times in succession (e.g., step d). Finally, it is possible to add an additional step at the end of step h) before using the catalyst.

[0052] Preferably, the drying step followed by the firing step is carried out at the end of the shaping step b) (but before step c) is carried out).

[0053] Preferably, steps e1) and h) are not optional.

[0054] Steps a) to h) of the preparation method are described in detail below.

[0055] (Step a)) The alumina support that the catalyst according to the invention comprises is obtained from an alumina gel, which essentially comprises a precursor of the aluminium oxy(hydroxide) (AlO(OH)) type, also known as boehmite.

[0056] According to the present invention, the synthesis of alumina gel (or otherwise known as boehmite gel) is carried out by precipitation of basic and / or acidic solutions of aluminum salts induced by a change in pH or any other method known to those skilled in the art (P. Euzen, P. Raybaud, X. Krokidis, H. Toulhoat, JL Le Loarer, JP Jolivet and C. Froidefond, Alumina, in "Handbook of Porous Solids", edited by F. Schuth, KSW Sing and J. Weitkamp, ​​Wiley-VCH, Weinheim, Germany, 2002, pp. 1591-1677).

[0057] Generally, the temperature during the precipitation reaction is 5°C to 80°C, and the pH during the reaction is 6 to 10. Preferably, the temperature is 35°C to 70°C, and the pH is 6 to 10.

[0058] According to one embodiment, the alumina gel is obtained by contacting an aqueous solution of an aluminum acid salt with a basic solution. For example, the aluminum acid salt is selected from the group consisting of aluminum sulfate, aluminum nitrate or aluminum chloride, preferably the aluminum acid salt is aluminum sulfate. The basic solution is preferentially selected from sodium hydroxide or potassium hydroxide.

[0059] Alternatively, an alkaline solution of an aluminum salt, which may be selected from the group consisting of sodium aluminate and potassium aluminate, may be contacted with an acidic solution. In a highly preferred variant, the gel is obtained by contacting a sodium aluminate solution with nitric acid. The sodium aluminate solution is advantageously in a range of 10 -5 ~10 -1 mol·L -1 and preferably, this concentration is 10 -4 ~10 -2 mol·L -1 is.

[0060] According to another embodiment, the alumina gel is obtained by contacting an aqueous solution of an aluminium acid salt with an alkaline solution of an aluminium salt.

[0061] (Step b)) The support may be advantageously shaped by any technique known to those skilled in the art. Shaping may be carried out, for example, by kneading-extrusion, pelletizing, drop coagulation (oil drop) method, granulation on a rotating plate, or any other method known to those skilled in the art. The catalyst according to the invention may optionally be produced and used in the form of extrudates, tablets, or beads. The preferred shaping method according to the invention is extrusion, and preferred extrusion shapes are cylindrical, twisted cylindrical, or multilobed (for example 2-, 3-, 4-, or 5-lobed).

[0062] In a particular embodiment, the alumina gel obtained at the end of step a) is subjected to a kneading step. The kneading step is preferably carried out in an acidic medium. The acid used can be, for example, nitric acid. This step is carried out using known tools capable of converting the gel into a viscous paste, such as a Z-arm mixer, a grinding mixer, or a continuous single- or twin-screw mixer. According to one advantageous embodiment, one or more compounds known as "pore-forming agents" are introduced into the kneading medium. These compounds have the property of degrading upon heating, thus creating porosity in the support. For example, wood flour, charcoal, tar, and plastics can be used as pore-forming compounds. After kneading, the paste thus obtained is passed through an extrusion die. The extrudates generally have a diameter of 0.5 to 10 mm, preferably 0.8 to 3.2 mm, and highly preferably 1.0 to 2.5 mm, and a length of 0.5 to 20 mm. These extrudates can be cylindrical, multilobal (eg, trilobal or tetralobal).

[0063] After shaping, the support is optionally dried before undergoing the hydrothermal treatment according to step c) of the present method. For example, the drying temperature is 50°C to 200°C. The dried support is optionally calcined before undergoing the hydrothermal treatment according to step c) of the present method. For example, the calcination is carried out at a temperature of 200°C to 1000°C, in the presence or absence of a stream of air containing up to 150 grams of water per kilogram of dry air.

[0064] (Step c)) The support obtained at the end of step b) then undergoes a heat treatment step which makes it possible to give it physical properties that meet the application envisaged.

[0065] The term "hydrothermal treatment" means treatment by passage in an autoclave in the presence of water at a temperature above room temperature.

[0066] During this hydrothermal treatment, the shaped alumina can be treated in different ways. Thus, the alumina can be impregnated with an acid solution before passing into the autoclave; the hydrothermal treatment of the alumina can be carried out either in the vapor or liquid phase, the vapor or liquid phase of the autoclave being acidic or non-acidic. This impregnation, which precedes the hydrothermal treatment, can be carried out dry or by immersing the alumina in an acidic aqueous solution. The term "dry impregnation" means that the alumina is placed in contact with a volume of solution that is less than or equal to the total pore volume of the alumina to be treated. Preferably, the impregnation is carried out dry.

[0067] It is also possible to treat the extruded support without prior impregnation with an acidic solution, the acidity in this case being provided by the aqueous liquid of the autoclave.

[0068] The aqueous acidic solution comprises at least one acidic compound for dissolving at least a portion of the alumina of the extrudates. The term "acidic compound for dissolving at least a portion of the alumina of the extrudates" is understood to mean any acidic compound which, when contacted with the alumina extrudates, dissolves at least a portion of the aluminum ions. The acid should preferably dissolve a minimum of 0.5% by weight of the alumina of the alumina extrudates.

[0069] Preferably, the acid is selected from strong acids such as nitric acid, hydrochloric acid, perchloric acid, sulfuric acid, or weak acids such as acetic acid used in a concentration such that their aqueous solutions have a pH of less than 4, or mixtures of these acids.

[0070] According to a preferred embodiment, the hydrothermal treatment is carried out in the presence of nitric acid and acetic acid, used alone or as a mixture. The autoclave is preferably a rotating basket autoclave, such as those defined in patent application EP-A-0 387 109.

[0071] The hydrothermal treatment may be carried out under the saturated steam pressure corresponding to the treatment temperature or under a partial pressure of water vapor at least equal to 70% of the saturated steam pressure.

[0072] Preferably, the temperature at which the hydrothermal treatment is carried out is 100° C. to 800° C., and more preferably 200° C. to 700° C. The hydrothermal treatment is generally carried out for 30 minutes to 8 hours, and preferably 30 minutes to 3 hours.

[0073] Preferably, the calcination step carried out in an autoclave after the hydrothermal treatment is carried out at a temperature generally between 400°C and 1500°C, preferably between 800°C and 1300°C, generally for 1 to 5 hours, in air, the water content of which is generally between 0 and 700 g of water per kilogram of dry air.

[0074] At the end of step c), the alumina obtained exhibits the specific textural properties described above.

[0075] (Step d)) The support may be contacted with the solution containing the nickel precursor by carrying out step d), by dry impregnation or excess impregnation, or by deposition-precipitation, according to methods well known to those skilled in the art.

[0076] Said step d) is preferentially carried out by impregnation of the support, which impregnation consists, for example, in contacting the support with at least one aqueous solution containing a nickel precursor, the pH of which may be modified by the optional addition of an acid or a base.

[0077] Preferably, said step d) is carried out by dry impregnation, which consists in contacting the support with at least one solution containing, preferably consisting of, at least one nickel precursor, the volume of which solution is between 0.25 and 1.5 times the pore volume of the support to be impregnated.

[0078] Preferably, the nickel precursor is introduced into an aqueous solution, for example, in the form of a nitrate, carbonate, acetate, chloride, or oxalate, in the form of a complex formed with a polyacid or acid alcohol and its salt, in the form of a complex formed with an acetylacetonate, or in the form of any other inorganic derivative soluble in an aqueous solution, which is brought into contact with the support. Preferably, nickel nitrate, nickel chloride, nickel acetate, or nickel hydroxycarbonate is advantageously used as the nickel precursor. Highly preferably, the nickel precursor is nickel nitrate.

[0079] According to another variant, the aqueous solution is aqueous ammonia or ammonium NH4 + It may contain ions.

[0080] The concentration of nickel in the solution is adjusted, depending on the type of impregnation (dry impregnation or excess impregnation) and the pore volume of the support, to obtain a nickel content of 1% to 50% by weight, more preferentially 2% to 40% by weight, even more preferentially 3% to 35% by weight, even more preferentially 5% to 25% by weight for supported catalysts, by weight of elemental nickel relative to the total weight of the catalyst.

[0081] (Step e)) The drying step is generally carried out under a gas stream containing water in an amount of less than 150 grams of water per kilogram of dry gas, preferably less than 50 grams of water per kilogram of dry gas, at a temperature of less than 250°C, preferably between 15°C and 240°C, more preferentially between 30°C and 220°C, even more preferentially between 50°C and 200°C, and even more preferentially between 70°C and 180°C, for a period generally between 10 minutes and 24 hours. Longer periods of time are not unspecified, but do not necessarily offer any improvement.

[0082] The gas may contain oxygen, nitrogen or an inert gas, preferably the gas is air.

[0083] (Optional step e1)) The optional calcination step is carried out at temperatures between 250°C and 1000°C, preferably between 250°C and 750°C, under a gas flow containing water in an amount of less than 150 grams of water per kilogram of dry gas, preferably less than 50 grams of water per kilogram of dry gas. The duration of this heat treatment is generally between 15 minutes and 10 hours. Longer periods of time are not excluded, but do not necessarily provide any improvement.

[0084] The gas may contain oxygen, nitrogen or an inert gas, preferably the gas is air.

[0085] At the end of step e) or e1), the nickel is uniformly distributed on the support.

[0086] (Step f)) According to step f) of the method for preparing a catalyst, at the end of step e), optionally the catalyst precursor obtained at the end of step e1), is contacted with at least one solution containing at least one organic additive selected from aldehydes containing 1 to 14 (preferably 2 to 12) carbon atoms per molecule, ketones or polyketones containing 3 to 18 (preferably 3 to 12) carbon atoms per molecule, ethers or esters containing 2 to 14 (preferably 3 to 12) carbon atoms per molecule, alcohols or polyalcohols containing 1 to 14 (preferably 2 to 12) carbon atoms per molecule, and carboxylic acids or polycarboxylic acids containing 1 to 14 (preferably 1 to 12) carbon atoms per molecule. The organic additive may consist of a combination of the various functional groups mentioned above.

[0087] Preferably, the organic additive is selected from formic acid HCOOH, formaldehyde CHO, acetic acid CHCOOH, citric acid, oxalic acid, glycolic acid (HOOC-CH-OH), malonic acid (HOOC-CH-COOH), ethanol, methanol, ethyl formate HCOOCH, methyl formate HCOOCH, paraldehyde (CH-CHO), acetaldehyde CHO, gamma-valerolactone (CHO), glucose, sorbitol, and trioxane.

[0088] Particularly preferably, the organic additive is formic acid.

[0089] It is essential that the step of adding the organic additive to the catalyst (step f)) is carried out after the step of contacting the support with the precursor of the nickel active phase.

[0090] Preferably, step f) is carried out by impregnating the catalyst precursor obtained at the end of step e) or step e1) with a solution containing at least one of the above organic additives. The impregnation is generally carried out in aqueous or organic solution or in suspension in aqueous or organic solution, preferably in aqueous solution. When the operation is carried out in organic solution or suspension, alcohols or polyalcohols, glycols or polyglycols will preferably be used as organic solvents.

[0091] Preferably, said step f) is carried out by dry impregnation, which consists in contacting the catalyst precursor obtained at the end of carrying out step e) or step e1) with a solution containing at least one organic additive as defined above, the volume of which solution is between 0.25 and 1.5 times the pore volume of the catalyst precursor to be impregnated.

[0092] The temperature during impregnation is generally 0°C to 50°C, preferably 10°C to 40°C, and particularly preferably room temperature.

[0093] According to the invention, the molar ratio between the organic additive and the nickel is greater than 0.05 mol / mol, preferably between 0.1 and 5 mol / mol, more preferentially between 0.12 and 3 mol / mol, even more preferably between 0.15 and 2.5 mol / mol.

[0094] (Step g)) According to step g) of the process for preparing a catalyst according to the invention, the hydrothermal treatment of the product from step f) is carried out at a temperature between 100°C and 200°C, preferably between 130°C and 170°C, more particularly at about 150°C, under a gas stream containing 5 to 650 grams of water per kilogram of dry gas, preferably 7 to 150 grams of water per kilogram of dry gas, and even more preferably 10 to 50 grams of water per kilogram of dry gas. The gas may contain oxygen, nitrogen or an inert gas, preferably the gas is air.

[0095] The duration of the hydrothermal treatment is generally 30 minutes to 5 hours, preferably 1 to 3 hours.

[0096] (Step h) (optional)) Step g) may be followed by a step h) of drying at 50°C to 200°C under a gas stream containing water in an amount strictly less than 5 grams of water per kilogram of weight of drying gas, advantageously for a period of 30 minutes to 5 hours, preferably 1 to 3 hours.

[0097] The gas may contain oxygen, nitrogen or an inert gas, preferably the gas is air.

[0098] At the end of step g), or possibly step h), a "semi-eggshell" catalyst is obtained as shown diagrammatically in Figure 1 and whose characteristics are described above.

[0099] (Step i) (optional)) Prior to use of the catalyst in the catalytic reactor and carrying out the hydrogenation process, at least one reduction treatment step i) is advantageously carried out after step g) or h) in the presence of a reducing gas, to obtain a catalyst comprising nickel at least partly in metallic form.

[0100] This treatment makes it possible to activate the catalyst and form metal particles, in particular particles of nickel in the zero-valent state. The reduction treatment can be carried out in situ or ex situ, i.e. after or before loading the catalyst into the hydrogenation reactor.

[0101] The reducing gas is preferably hydrogen. Hydrogen can be used in high purity or as a mixture (for example, a mixture of hydrogen / nitrogen, or hydrogen / argon, or hydrogen / methane). When hydrogen is used as a mixture, all proportions are possible.

[0102] The temperature at which the reduction treatment is carried out is 120°C to 500°C, preferably 150°C to 450°C. When the catalyst is not passivated or is reduced before passivation, the temperature at which the reduction treatment is carried out is 180°C to 500°C, preferably 200°C to 450°C, and more preferentially 350°C to 450°C. When the catalyst has been passivated in advance, the temperature at which the reduction treatment is carried out is generally 120°C to 350°C, preferably 150°C to 350°C.

[0103] The duration of the reduction treatment is generally 2 to 40 hours, preferably 3 to 30 hours. The temperature is generally raised slowly to the desired reduction temperature, for example, at a rate of 0.1 to 10°C / min, preferably 0.3 to 7°C / min.

[0104] The hydrogen flow rate is expressed in L / h / gram of catalyst and is between 0.01 and 100 L / h / gram of catalyst, preferably between 0.05 and 10 L / h / gram of catalyst, and even more preferably between 0.1 and 5 L / h / gram of catalyst.

[0105] (Selective hydrogenation method) Another subject of the present invention is a process for the selective hydrogenation of polyunsaturated compounds containing at least two carbon atoms per molecule, such as diolefinic and / or acetylenic and / or alkenylaromatic compounds (also known as styrene compounds), contained in a hydrocarbon feedstock having a final boiling point of less than or equal to 300°C, said process being carried out in the presence of a catalyst obtained by the preparation process as described above in the present description, at a temperature of 0°C to 300°C, a pressure of 0.1 to 10 MPa, and, if the process is carried out in the liquid phase, a hydrogen / (polyunsaturated compound to be hydrogenated) molar ratio of 0.1 to 10, and an hourly space velocity of 0.1 to 200 h -1 Or, if the process is carried out in the gas phase, the hydrogen / (polyunsaturated compound to be hydrogenated) molar ratio is 0.5 to 1000, and the hourly space velocity is 100 to 40,000 h -1 is.

[0106] Monounsaturated organic compounds, such as ethylene and propylene, are at the root of the production of polymers, plastics, and other value-added chemical products. These compounds are obtained from natural gas, naphtha, or gas oils processed by steam cracking or catalytic cracking. These processes, carried out at high temperatures, produce, in addition to the desired monounsaturated compounds, polyunsaturated organic compounds, such as acetylene, propadiene, and methylacetylene (or propyne), 1,2-butadiene and 1,3-butadiene, vinylacetylene and ethylacetylene, and other polyunsaturated compounds whose boiling points correspond to the C5+ fraction (hydrocarbon-based compounds having at least five carbon atoms), particularly diolefins or styrene or indene compounds. These polyunsaturated compounds are highly reactive and lead to side reactions in the polymerization unit. Therefore, their removal is necessary before these fractions can be used economically.

[0107] Selective hydrogenation is a major process developed specifically to remove unwanted polyunsaturated compounds from these hydrocarbon feedstocks. It allows the conversion of polyunsaturated compounds to the corresponding alkenes or aromatic compounds while avoiding their complete saturation and therefore the formation of the corresponding alkanes or naphthenes. In the case of steam cracked gasoline used as a feedstock, selective hydrogenation also allows the selective hydrogenation of alkenylaromatic compounds to give aromatic compounds while avoiding hydrogenation of the aromatic ring.

[0108] The hydrocarbon feedstocks treated in the selective hydrogenation process have a final boiling point of 300° C. or less, contain at least two carbon atoms per molecule, and comprise at least one polyunsaturated compound. The term "polyunsaturated compounds" is intended to mean compounds containing at least one acetylenic group and / or at least one dienic group and / or at least one alkenyl aromatic group.

[0109] More particularly, the feedstock is selected from the group consisting of steam cracked C2 fraction, steam cracked C2-C3 fraction, steam cracked C3 fraction, steam cracked C4 fraction, steam cracked C5 fraction and steam cracked gasoline, also known as pyrolysis gasoline or C5+ fraction.

[0110] Steam cracked C2 fractions, which are advantageously used for carrying out the selective hydrogenation process according to the invention, have, for example, the following composition: 40% to 95% by weight of ethylene, approximately 0.1% to 5% by weight of acetylene, the remainder essentially being ethane and methane. In some steam cracked C2 fractions, 0.1% to 1% by weight of C3 compounds may be present.

[0111] The steam cracked C3 fractions advantageously used for carrying out the selective hydrogenation process according to the invention have, for example, the following average composition: about 90% by weight of propylene and about 1% to 8% by weight of propadiene and methylacetylene, the remainder essentially being propane. In some C3 fractions, 0.1% to 2% by weight of C2 and C4 compounds may be present.

[0112] The C2-C3 fraction can also be advantageously used for the implementation of the selective hydrogenation process according to the invention. It has, for example, the following composition: about 0.1% to 5% by weight of acetylene, about 0.1% to 3% by weight of propadiene and methylacetylene, about 30% by weight of ethylene and about 5% by weight of propylene, the remainder being essentially methane, ethane and propane. This feedstock may also contain 0.1% to 2% by weight of C4 compounds.

[0113] The steam cracked C4 fraction, which is advantageously used for carrying out the selective hydrogenation process according to the invention, has, for example, the following average composition by weight: 1% by weight of butane, 46.5% by weight of butene, 51% by weight of butadiene, 1.3% by weight of vinylacetylene and 0.2% by weight of butyne. In some C4 fractions, 0.1% to 2% by weight of C3 and C5 compounds may be present.

[0114] The steam cracked C5 fraction, which is advantageously used for carrying out the selective hydrogenation process according to the invention, has, for example, the following composition: 21% by weight of pentane, 45% by weight of pentenes and 34% by weight of pentadiene.

[0115] Steam cracked gasoline or pyrolysis gasoline, which is advantageously used for carrying out the selective hydrogenation process according to the invention, corresponds to a hydrocarbon fraction whose boiling point is generally between 0 and 300°C, preferably between 10 and 250°C. The polyunsaturated hydrocarbons present in the steam cracked gasoline to be hydrogenated are, in particular, diolefin compounds (butadiene, isoprene, cyclopentadiene, etc.), styrene compounds (styrene, α-methylstyrene, etc.) and indene compounds (indene, etc.). Steam cracked gasoline generally contains C5-C12 fractions together with traces of C3, C4, C13, C14 and C15 (for example, 0.1% to 3% by weight of each of these fractions). For example, a feedstock formed from pyrolysis gasoline typically has the following composition: 5% to 30% by weight saturates (paraffins and naphthenes), 40% to 80% by weight aromatics, 5% to 20% by weight monoolefins, 5% to 40% by weight diolefins, and 1% to 20% by weight alkenyl aromatics, which together make up 100%. It also contains 0 to 1000 ppm by weight sulfur, preferably 0 to 500 ppm by weight sulfur.

[0116] Preferably, the polyunsaturated hydrocarbon feedstock to be treated by the selective hydrogenation process according to the invention is a steam cracked C2 fraction or a steam cracked C2-C3 fraction or steam cracked gasoline.

[0117] The selective hydrogenation process according to the present invention aims to remove the polyunsaturated hydrocarbons present in the feedstock to be hydrogenated without hydrogenating the monounsaturated hydrocarbons. For example, when the feedstock is a C2 fraction, the selective hydrogenation process aims to selectively hydrogenate acetylene. When the feedstock is a C3 fraction, the selective hydrogenation process aims to selectively hydrogenate propadiene and methylacetylene. In the case of the C4 fraction, the objective is to remove butadiene, vinylacetylene (VAC), and butyne; and in the case of the C5 fraction, the objective is to remove pentadiene. When the feedstock is steam cracked gasoline, the selective hydrogenation process aims to selectively hydrogenate the polyunsaturated hydrocarbons present in the feedstock to be treated, so that diolefin compounds are specifically hydrogenated to give monoolefins and styrene and indene compounds are specifically hydrogenated to give the corresponding aromatic compounds, while avoiding hydrogenation of aromatic rings.

[0118] The technical implementation of the selective hydrogenation process is, for example, carried out by injecting the polyunsaturated hydrocarbon feedstock and hydrogen into at least one fixed-bed reactor as an upflow or downflow. The reactor may be of isothermal or adiabatic type. Adiabatic reactors are preferred. The polyunsaturated hydrocarbon feedstock can advantageously be diluted by reinjecting the effluent from the reactor in which the selective hydrogenation reaction has been carried out one or more times at various points in the reactor located between the inlet and outlet of the reactor, thereby limiting the temperature gradient in the reactor. The technical implementation of the selective hydrogenation process according to the invention can also advantageously be carried out by implanting at least the supported catalyst in a reactive distillation column, a reactor-exchanger or a slurry-type reactor. The hydrogen flow can be introduced simultaneously with the feedstock to be hydrogenated and / or at one or several different points in the reactor.

[0119] The selective hydrogenation of the steam cracked C2, C2-C3, C3, C4, C5 and C5+ fractions can be carried out in the gas phase or liquid phase, preferably in the liquid phase for the C3, C4, C5 and C5+ fractions and in the gas phase for the C2 and C2-C3 fractions. The liquid phase reaction allows for reduced energy costs and increased catalyst cycle times.

[0120] In general, the selective hydrogenation of a hydrocarbon feedstock containing polyunsaturated compounds containing at least two carbon atoms per molecule and having a final boiling point of 300°C or less is carried out at a temperature of 0°C to 300°C, a pressure of 0.1 to 10 MPa, a hydrogen / (polyunsaturated compounds to be hydrogenated) molar ratio of 0.1 to 10 for processes carried out in the liquid phase, and an hourly space velocity (defined as the ratio of the flow rate by volume of the feedstock to the volume of the catalyst) of 0.1 to 200 h -1 or a process carried out in the gas phase, in which the molar ratio of hydrogen / (polyunsaturated compound to be hydrogenated) is 0.5 to 1000, and the hourly space velocity is 100 to 40,000 h -1 is.

[0121] In one embodiment of the present invention, when a selective hydrogenation process is carried out and the feedstock is steam cracked gasoline containing polyunsaturated compounds, the molar ratio of (hydrogen) / (polyunsaturated compounds to be hydrogenated) is generally 0.5-10, preferably 0.7-5.0, more preferably 1.0-2.0, the temperature is 0°C-200°C, preferably 20°C-200°C, more preferably 30°C-180°C, and the hourly space velocity (HSV) is generally 0.5-100 h -1 , preferably 1 to 50 hours -1 The pressure is generally 0.3 to 8.0 MPa, preferably 1.0 to 7.0 MPa, and even more preferably 1.5 to 4.0 MPa.

[0122] More preferentially, when a selective hydrogenation process is carried out and the feedstock is steam cracked gasoline containing polyunsaturated compounds, the molar ratio of hydrogen / (polyunsaturated compounds to be hydrogenated) is 0.7-5.0, the temperature is 20°C-200°C, and the hourly space velocity (HSV) is generally 1-50 h -1 and the pressure is 1.0 to 7.0 MPa.

[0123] Even more preferentially, when a selective hydrogenation process is carried out and the feedstock is steam cracked gasoline containing polyunsaturated compounds, the hydrogen / (polyunsaturated compounds to be hydrogenated) molar ratio is 1.0-2.0, the temperature is 30°C-180°C, and the hourly space velocity (HSV) is generally 1-50 h -1 and the pressure is 1.5 to 4.0 MPa.

[0124] The hydrogen flow rate is adjusted so that a sufficient amount is available to theoretically hydrogenate all of the polyunsaturated compounds and maintain an excess of hydrogen at the reactor outlet.

[0125] In another embodiment of the present invention, a selective hydrogenation process is carried out in which the feedstock is a steam cracked C2 fraction and / or a steam cracked C2-C3 fraction containing polyunsaturated compounds. The molar ratio of (hydrogen) / (polyunsaturated compounds to be hydrogenated) is generally 0.5 to 1,000, preferably 0.7 to 800, the temperature is 0°C to 300°C, preferably 15°C to 280°C, and the hourly space velocity (HSV) is generally 100 to 40,000 h -1 , preferably 500 to 30,000 h -1 The pressure is generally 0.1 to 6.0 MPa, preferably 0.2 to 5.0 MPa.

[0126] (Method for hydrogenating aromatic compounds) Another subject of the present invention is a process for the hydrogenation of at least one aromatic or polyaromatic compound contained in a hydrocarbon feedstock having a final boiling point below 650° C., generally between 20° C. and 650° C., preferably between 20° C. and 450° C. The hydrocarbon feedstock containing at least one aromatic or polyaromatic compound may be chosen from the following petroleum or petrochemical fractions: reformates from catalytic reforming, kerosene, light gas oils, heavy gas oils, cracking distillates, such as FCC recycle oils, coking unit gas oils or hydrocracked distillates.

[0127] The content of aromatic or polyaromatic compounds contained in the hydrocarbon feedstock to be treated in the hydrogenation process according to the invention is generally 0.1 to 80% by weight, preferably 1 to 50% by weight, particularly preferably 2 to 35% by weight, the percentages being based on the total weight of the hydrocarbon feedstock. Aromatic compounds present in the hydrocarbon feedstock are, for example, benzene or alkylaromatics, such as toluene, ethylbenzene, o-xylene, m-xylene or p-xylene, or aromatic compounds with multiple aromatic rings (polyaromatics), such as naphthalene.

[0128] The sulfur or chlorine content of the feedstock is generally less than 5000 ppm by weight of sulfur or chlorine, preferably less than 100 ppm by weight, and particularly preferably less than 10 ppm by weight.

[0129] The technical implementation of the process for the hydrogenation of aromatic or polyaromatic compounds is carried out, for example, by injecting the hydrocarbon feedstock and hydrogen into at least one fixed-bed reactor as an upflow or downflow. The reactor may be of isothermal or adiabatic type. Adiabatic reactors are preferred. The hydrocarbon feedstock may advantageously be diluted by one or more reinjections of the effluent from the reactor in which the reaction for the hydrogenation of aromatic compounds has been carried out at various points in the reactor located between the inlet and outlet of the reactor, thereby limiting the temperature gradient in the reactor. The technical implementation of the process for the hydrogenation of aromatic compounds according to the invention may advantageously be carried out by implanting at least the supported catalyst in a reactive distillation column, a reactor-exchanger or a slurry-type reactor. The hydrogen flow may be introduced simultaneously with the feedstock to be hydrogenated and / or at one or more different points in the reactor.

[0130] The hydrogenation of aromatic or polyaromatic compounds may be carried out in the gas phase or liquid phase, preferably in the liquid phase. Generally, the temperature during the hydrogenation of aromatic or polyaromatic compounds is 30°C to 350°C, preferably 50°C to 325°C, the pressure is 0.1 to 20 MPa, preferably 0.5 to 10 MPa, the molar ratio of hydrogen / (aromatic compound to be hydrogenated) is 0.1 to 10, and the hourly space velocity is 0.05 to 50 h -1 , preferably 0.1 to 10 hours -1 and the hydrocarbon feedstock contains aromatic or polyaromatic compounds and has a final boiling point of up to 650°C, typically between 20°C and 650°C, preferably between 20°C and 450°C.

[0131] The hydrogen flow rate is adjusted so that a sufficient amount is available to theoretically hydrogenate all of the aromatics and maintain an excess of hydrogen at the reactor outlet.

[0132] The conversion of aromatic or polyaromatic compounds is generally greater than 20 mol%, preferably greater than 40 mol%, more preferably greater than 80 mol%, and particularly preferably greater than 90 mol% of the aromatic or polyaromatic compounds contained in the hydrocarbon feedstock. The conversion is calculated by dividing the difference between the total moles of aromatic or polyaromatic compounds in the hydrocarbon feedstock and in the product by the total moles of aromatic or polyaromatic compounds in the hydrocarbon feedstock.

[0133] According to a specific alternative embodiment of the process according to the invention, a process for the hydrogenation of benzene from a hydrocarbon feedstock, for example a reformate derived from a catalytic reforming unit, is carried out, wherein the benzene content in said hydrocarbon feedstock is generally between 0.1 and 40% by weight, preferably between 0.5 and 35% by weight, particularly preferably between 2 and 30% by weight, the weight percentages being based on the total weight of the hydrocarbon feedstock.

[0134] The sulfur or chlorine content of the feedstock is generally less than 10 ppm by weight, preferably less than 2 ppm by weight of sulfur or chlorine, respectively.

[0135] The hydrogenation of benzene contained in the hydrocarbon feedstock may be carried out in the gas phase or liquid phase, but is preferably carried out in the liquid phase. When it is carried out in the liquid phase, a solvent may be present, such as cyclohexane, heptane, or octane. Generally, the temperature during the hydrogenation of benzene is 30°C to 250°C, preferably 50°C to 200°C, more preferably 80°C to 180°C, the pressure during the hydrogenation is 0.1 to 10 MPa, preferably 0.5 to 4 MPa, the hydrogen / (benzene) molar ratio during the hydrogenation is 0.1 to 10, and the hourly space velocity during the hydrogenation is 0.05 to 50 h -1 , preferably 0.5 to 10 hours -1 is.

[0136] The benzene conversion is generally greater than 50 mol %, preferably greater than 80 mol %, more preferably greater than 90 mol %, particularly preferably greater than 98 mol %.

[0137] The present invention will now be illustrated by the following examples, which are not intended to be limiting in any way.

[0138] (Example) Example 1: Preparation of AL-1 alumina The synthesis of alumina gel is carried out via a mixture of sodium aluminate and aluminum sulfate. The precipitation reaction is carried out at a temperature of 60°C, pH 9, and stirring at 200 rpm for 60 minutes.

[0139] The gel thus obtained is kneaded in a Z-arm mixer to obtain a paste. Extrusion is carried out by passing the paste through a die equipped with a trilobe-shaped 1.6 mm diameter orifice. The extrudates thus obtained are dried at 150°C for 12 hours and then calcined at 450°C under a stream of dry air for 5 hours. The dry air used in this and all following examples contains less than 5 grams of water per kilogram of dry air.

[0140] The extrudates undergo hydrothermal treatment in an autoclave at 650°C for 3 hours in the presence of an aqueous solution containing 6.5% by weight of acetic acid relative to the weight of alumina, and then calcined in a tubular reactor at 1000°C for 2 hours under a stream of dry air to obtain AL-1 alumina.

[0141] The specific surface area of ​​AL-1 alumina is 80m 2 / g, the pore volume (determined by Hg porosimetry) is 0.85 mL / g, the median mesopore diameter is 35 nm, the sodium content is 0.0350 wt. % and the sulfur content is 0.15 wt. %.

[0142] Example 1a: Preparation of AL-2 Alumina The synthesis of alumina gel is carried out via a mixture of sodium aluminate and aluminum sulfate. The precipitation reaction is carried out at a temperature of 60°C, pH 9, and stirring at 200 rpm for 60 minutes.

[0143] The gel thus obtained is kneaded in a Z-arm mixer to give a paste. The paste is extruded by passing it through a die equipped with a trilobe-shaped orifice having a diameter of 1.6 mm. The extrudates thus obtained are dried at 150°C for 12 hours and then calcined at 450°C in a stream of dry air for 5 hours.

[0144] AL-2 alumina is obtained. This alumina does not undergo hydrothermal treatment.

[0145] The specific surface area of ​​AL-2 alumina is 255m 2 / g, the pore volume (determined by Hg porosimetry) is 0.7 mL / g, the median mesopore diameter is 12 nm, the sodium content is 0.0350 wt. % and the sulfur content is 0.15 wt. %.

[0146] Example 2: Preparation of aqueous solution of Ni precursor The aqueous solution of Ni precursor (solution S) used for the preparation of catalysts A, C, D, E and F is prepared by dissolving 43.5 grams (g) of nickel nitrate (NiNO3, supplier Strem Chemicals®) in a volume of 13 mL of distilled water to obtain solution S. The Ni concentration of this solution S is 350 g Ni per liter of solution volume.

[0147] Example 2a: Preparation of a second aqueous solution of Ni precursor The aqueous solution of Ni precursor (solution S') used for the preparation of catalyst B is prepared by dissolving 14.5 grams (g) of nickel nitrate (NiNO3, supplier Strem Chemicals®) in a volume of 13 mL of distilled water to obtain solution S'. The Ni concentration of this solution S' is approximately 116 g of Ni per liter of solution volume.

[0148] Example 3: Preparation of Catalyst A [15 wt% Ni-organic additive: formic acid] according to the present invention Solution S prepared in Example 2 is dry impregnated onto 10 g of AL-1 alumina obtained according to Example 1 by adding it dropwise.

[0149] The solid thus obtained is subsequently dried in an oven at 120° C. for 12 hours and then calcined at 450° C. for 2 hours under a flow of dry air of 1 L / h / g of catalyst.

[0150] The catalyst precursor thus obtained is dry impregnated with an aqueous solution containing formic acid in a molar ratio of HCOOH / Ni equal to 1 mol / mol.

[0151] At the end of the impregnation with the aqueous solution containing formic acid, the catalyst precursor undergoes a heat treatment at 150°C for 2 hours under a flow of air containing 50 grams of water per kilogram of dry air weight at a flow rate of 1 L / h / g of catalyst, then at 120°C for 1 hour under a flow of dry air.

[0152] Catalyst A is obtained containing 15% by weight of elemental nickel relative to the total weight of the catalyst. The characteristics of catalyst A thus obtained are recorded in Table 1 below.

[0153] Example 4: Preparation of Catalyst B according to the present invention [5 wt% Ni-organic additive: formic acid] The solution S' prepared in Example 2a is dry impregnated onto 10 g of AL-1 alumina obtained according to Example 1 by adding it dropwise.

[0154] The solid thus obtained is subsequently dried in an oven at 120° C. for 12 hours and then calcined at 450° C. for 2 hours under a flow of dry air of 1 L / h / g of catalyst.

[0155] The catalyst precursor thus obtained is dry-impregnated with an aqueous solution containing formic acid in a molar ratio of HCOOH / Ni equal to 1 mol / mol. At the end of the impregnation with the aqueous solution containing formic acid, the catalyst precursor undergoes a heat treatment at 150°C for 2 hours under a flow of air containing 50 grams of water per kilogram of dry air weight at a flow rate of 1 L / h / g of catalyst, then at 120°C for 1 hour under a flow of dry air.

[0156] Catalyst B is obtained containing 5% by weight of elemental nickel relative to the total weight of the catalyst. The characteristics of catalyst B thus obtained are reported in Table 1 below.

[0157] Example 5: Preparation of Catalyst C [15 wt% Ni-organic additive: glycolic acid] according to the present invention Solution S prepared in Example 2 is dry-impregnated onto 10 g of AL-1 alumina obtained in Example 1 by adding it dropwise.

[0158] The solid thus obtained is subsequently dried in an oven at 120° C. for 12 hours and then calcined at 450° C. for 2 hours under a flow of dry air of 1 L / h / g of catalyst.

[0159] The catalyst precursor thus obtained is dry impregnated with an aqueous solution containing glycolic acid, in a C2H4O3 / Ni ratio equal to 2 mol / mol.

[0160] At the end of the impregnation with the aqueous solution containing glycolic acid, the catalyst precursor undergoes a heat treatment under a flow of air containing 50 grams of water per kilogram of dry air weight at a flow rate of 1 L / h / g of catalyst at 150°C for 2 hours, then under a flow of dry air at 120°C for 1 hour.

[0161] Catalyst C is obtained containing 15% by weight of elemental nickel relative to the total weight of the catalyst. The characteristics of catalyst C thus obtained are recorded in Table 1 below.

[0162] Example 6: Preparation of Catalyst D (without hydrothermal treatment to obtain alumina support) not in accordance with the present invention Solution S prepared in Example 2 is dry impregnated onto 10 g of AL-2 alumina obtained according to Example 1a by adding it dropwise.

[0163] The solid thus obtained is subsequently dried in an oven at 120° C. for 12 hours and then calcined at 450° C. for 2 hours under a flow of dry air of 1 L / h / g (catalyst).

[0164] The catalyst precursor thus obtained is dry impregnated with an aqueous solution containing formic acid in a ratio HCOOH / Ni equal to 1 mol / mol.

[0165] At the end of the impregnation with the aqueous solution containing formic acid, the catalyst precursor undergoes a heat treatment under a flow of air containing 50 grams of water per kilogram of dry air weight at a flow rate of 1 L / h / g of catalyst at 150°C for 2 hours, then under a flow of dry air at 120°C for 1 hour.

[0166] Catalyst D is obtained containing 15% by weight of elemental nickel relative to the total weight of the catalyst. The characteristics of catalyst D thus obtained are recorded in Table 1 below.

[0167] Example 7: Preparation of Catalyst E Not Conforming to the Invention [No Organic Additives, No Final Hydrothermal Treatment] Solution S prepared in Example 2 is dry-impregnated onto 10 g of AL-1 alumina obtained in Example 1 by adding it dropwise.

[0168] The solid thus obtained is subsequently dried in an oven at 120° C. for 12 hours and then calcined at 450° C. for 2 hours under a flow of dry air of 1 L / h / g of catalyst.

[0169] Catalyst E is then obtained containing 15% by weight of elemental nickel relative to the total weight of the catalyst. The characteristics of catalyst E thus obtained are reported in Table 1 below.

[0170] Example 8: Preparation of Catalyst F [without organic additives] not in accordance with the present invention Solution S prepared in Example 2 is dry-impregnated onto 10 g of AL-1 alumina obtained in Example 1 by adding it dropwise.

[0171] The solid thus obtained is subsequently dried in an oven at 120° C. for 12 hours and then calcined at 450° C. for 2 hours under a flow of dry air of 1 L / h / g of catalyst.

[0172] The solid thus obtained subsequently undergoes a heat treatment under a stream of air containing 50 grams of water per kilogram of dry air weight at a flow rate of 1 L / h / g of catalyst at 150°C for 2 hours, then under a stream of dry air at 120°C for 1 hour.

[0173] Catalyst F is then obtained containing 15% by weight of elemental nickel relative to the total weight of the catalyst. The characteristics of catalyst F thus obtained are reported in Table 1 below.

[0174] [Table 1]

[0175] Example 9: Catalytic testing: Performance in the selective hydrogenation of a mixture containing styrene and isoprene (A HYD1 )) Catalysts A to F described in the above examples are tested in a reaction for the selective hydrogenation of a mixture containing styrene and isoprene.

[0176] The composition of the feedstock to be selectively hydrogenated is as follows: 8% by weight of styrene (supplier Sigma Aldrich®, 99% purity), 8% by weight of isoprene (supplier Sigma Aldrich®, 99% purity), and 84% by weight of n-heptane (solvent) (supplier VWR®, >99% purity Chromanorm® HPLC). This feedstock also contains a very low content of sulfur-containing compounds: 10 ppm by weight of sulfur introduced in the form of pentanethiol (supplier Fluka®, >97% purity) and 100 ppm by weight of sulfur introduced in the form of thiophene (supplier Merck®, 99% purity). This composition corresponds to the initial composition of the reaction mixture. This mixture of model molecules is typical of pyrolysis gasoline.

[0177] The selective hydrogenation reaction is carried out in a 500 mL stainless steel autoclave equipped with a magnetically driven mechanical stirrer and capable of operating at a maximum pressure of 100 bar (10 MPa) and temperatures between 5°C and 200°C.

[0178] Prior to its introduction into the autoclave, a 3 mL quantity of catalyst was reduced ex situ at 400 °C for 16 hours (temperature ramp rate 1 °C / min) under a hydrogen flow of 1 L / h / g of catalyst, then transferred, protected from air, to the autoclave. After the addition of 214 mL of n-heptane (supplier VWR®, purity >99% Chromanorm HPLC), the autoclave was closed, purged, and then pressurized under 35 bar (3.5 MPa) of hydrogen and brought to a test temperature equal to 30 °C. At time t = 0, approximately 30 g of a mixture containing styrene, isoprene, n-heptane, pentanethiol, and thiophene was introduced into the autoclave. The reaction mixture now had the above composition and was stirred at 1600 rpm. In the autoclave, the pressure was maintained constant at 35 bar (3.5 MPa) using a storage cylinder placed upstream of the reactor.

[0179] The progress of the reaction is monitored by taking samples from the reaction medium at regular intervals: styrene is hydrogenated to give ethylbenzene, without hydrogenation of the aromatic ring, and isoprene is hydrogenated to give methylbutene. If the reaction is prolonged longer than necessary, the methylbutenes are then themselves hydrogenated to give isopentane. Hydrogen consumption is also monitored over time by the reduction in pressure in a storage cylinder located upstream of the reactor. The catalytic activity is expressed in moles of H2 consumed per minute and per gram of Ni weight.

[0180] The catalytic activities measured for catalysts A to F are recorded in Table 2 below. They are the catalytic activities measured for catalyst D (A HYD1 )

[0181] Example 10: Catalytic testing: Performance in toluene hydrogenation (A HYD2 )) Catalysts A to F described in the above examples are also tested in the reaction for the hydrogenation of toluene.

[0182] The selective hydrogenation reaction is carried out in the same autoclave as described in Example 9.

[0183] Prior to its introduction into the autoclave, a 2 mL quantity of catalyst is reduced ex situ at 400 °C for 16 hours (temperature ramp rate 1 °C / min) under a hydrogen flow of 1 L / h / g (catalyst), then transferred to the autoclave protected from air. After the addition of 216 mL of n-heptane (supplier VWR®, purity >99% Chromanorm HPLC), the autoclave is closed, purged, and then pressurized under 35 bar (3.5 MPa) of hydrogen to a test temperature equal to 80 °C. At time t = 0, approximately 26 g of toluene (supplier SDS®, purity >99.8%) is introduced into the autoclave (initial composition of the reaction mixture is 6% by weight toluene / 94% by weight n-heptane), and stirring is initiated at 1600 rpm. The pressure in the autoclave is maintained constant at 35 bar (3.5 MPa) using a storage cylinder located upstream of the reactor.

[0184] The progress of the reaction is monitored by taking samples from the reaction medium at regular time intervals: toluene is completely hydrogenated to give methylcyclohexane. Hydrogen consumption is also monitored over time by the drop in pressure in a storage cylinder located upstream of the reactor. The catalytic activity is expressed in moles of H2 consumed per minute and per gram of Ni weight.

[0185] The catalytic activities measured for catalysts A to F are recorded in Table 2 below. They are the catalytic activities measured for catalyst D (A HYD2 ) and related back to it.

[0186] [Table 2] Table 2: Performance of catalysts A-F in the selective hydrogenation of mixtures containing styrene and isoprene (A HYD1 ) and the performance of catalysts A to F in the hydrogenation of toluene (A HYD2 ) comparison

[0187] This clearly shows the improved performance of catalysts A, B and C in accordance with the invention compared to catalysts D, E and F not in accordance with the invention.

[0188] Catalyst D has a lower activity due to the use of support AL-2, the preparation of which does not comply with the procedures described in this invention. Catalysts E and F are prepared on aluminous supports according to the invention, but for catalyst E, steps e) and f) were not carried out, and for catalyst F, step f) was carried out, while step e) of adding the organic additive was not carried out. In these two cases, nickel is uniformly distributed throughout the catalyst grains. Catalysts E and F are therefore considered to be superior to A. HYD1 and A HYD2 Catalysts A, B, and C have much lower activity than catalyst A. This is explained by the distribution of Ni in the crust on catalysts A, B, and C, which gives significantly improved activity, especially in the fast hydrogenation reaction. [Brief explanation of the drawings]

[0189] [Figure 1] FIG. 1 shows the distribution of nickel in the catalyst.

Claims

1. 1. A method for preparing a catalyst comprising a nickel-based active phase and an alumina support, said catalyst comprising 1% to 50% by weight of elemental nickel relative to the total weight of the catalyst, and comprising: the nickel is distributed both on a crust at the periphery of the support and in the core of the support, the thickness of said crust being between 2% and 15% of the diameter of the catalyst; - nickel density ratio between the crust and the core is between 3.8 and 15; - said crust comprises between 45% and 90% by weight of elemental nickel relative to the total weight of nickel contained in the catalyst; The size of the nickel particles in the catalyst, measured in the oxide form, is between 7 and 25 nm. The method is characterized in that it comprises the following steps: a) providing an alumina gel; b) shaping the alumina gel from step a); c) subjecting the shaped alumina gel obtained at the end of step b) to a heat treatment to obtain an alumina support, said heat treatment comprising at least one hydrothermal treatment step in an autoclave in the presence of an acid solution at a temperature between 100°C and 800°C, and at least one calcination step carried out after the hydrothermal treatment step at a temperature between 400°C and 1500°C; d) contacting the alumina support obtained at the end of step c) with at least one precursor of the nickel active phase to obtain a catalyst precursor; e) drying the catalyst precursor obtained at the end of step d) at a temperature below 250°C; f) contacting the dried catalyst precursor obtained at the end of step e) with at least one solution containing at least one organic additive selected from aldehydes containing 1 to 14 carbon atoms per molecule, ketones or polyketones containing 3 to 18 carbon atoms per molecule, ethers and esters containing 2 to 14 carbon atoms per molecule, alcohols or polyalcohols containing 1 to 14 carbon atoms per molecule and carboxylic acids or polycarboxylic acids containing 1 to 14 carbon atoms per molecule, wherein the molar ratio between the organic additive and the nickel is greater than 0.05 mol / mol; g) hydrothermal treatment of the catalyst precursor obtained at the end of step f) at a temperature between 100°C and 200°C under a gas flow containing 5 to 650 grams of water per kg of dry gas. A method comprising:

2. 2. The process according to claim 1, further comprising a step h) of drying the catalyst precursor obtained at the end of step g) under a gas stream containing water in an amount greater than 0 grams and strictly less than 5 grams per kg of weight of drying gas at a temperature between 50°C and 200°C.

3. 3. The method according to claim 1 or 2, further comprising a step e1) of calcining the dried catalyst precursor obtained at the end of step e) at a temperature between 250°C and 1000°C under a gas flow containing water in an amount greater than 0 grams and strictly less than 150 grams per kg of dry gas.

4. 2. The method of claim 1, wherein in step f) the organic additive is selected from formic acid, formaldehyde, acetic acid, citric acid, oxalic acid, glycolic acid, malonic acid, ethanol, methanol, ethyl formate, methyl formate, paraldehyde, acetaldehyde, gamma-valerolactone, glucose, sorbitol, and trioxane.

5. 2. The method of claim 1, wherein in step f) the organic additive is formic acid.

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