fuel cell system

Abstract

To prevent electrical connection between a fuel cell stack and a humidifier via generated water.SOLUTION: A fuel cell system includes a fuel cell stack (12), and a predetermined device (62), and a gas receiving unit (82) is formed in the device to receive exhaust gas discharged from the fuel cell stack. A gas outlet (40b) of the fuel cell stack and the gas receiving unit are connected via a pipe (70). An upstream end (102) of a relay pipe (100) made of an insulator is inserted into a downstream opening (94) in the pipe. The relay pipe includes a hollow protrusion (116) having a smaller outer diameter than the upstream end. The hollow protrusion protrudes further upstream (inward of the pipe) in the exhaust gas flow direction than the upstream end.SELECTED DRAWING: Figure 3

Description

[Technical Field]

[0001] The present invention relates to a fuel cell system including a fuel cell stack. [Background technology]

[0002] In recent years, research and development into fuel cells, which contribute to energy efficiency, has been conducted to ensure that more people have access to affordable, reliable, sustainable, and advanced energy. Furthermore, regulations on automobile exhaust gases have become more stringent to reduce the burden on the global environment. From this perspective, attempts have been made to install fuel cell systems in automobiles instead of internal combustion engines. Fuel cell systems emit less CO2, SO X and NO X This is because no waste products or the like are discharged.

[0003] A fuel cell system includes a fuel cell stack in which a plurality of unit cells are stacked. When the fuel cell stack is operated, fuel gas is supplied to the anode electrode of each unit cell, and oxidant gas is supplied to the cathode electrode of each unit cell. Water is produced at the cathode electrode through an electrode reaction. Therefore, excess oxidant gas and produced water are discharged from the cathode electrode together. Hereinafter, the excess oxidant gas discharged from the cathode electrode will be referred to as cathode off-gas.

[0004] The cathode off-gas is sent to a humidifier, as described in Patent Document 1, for example. A porous membrane is provided inside the humidifier. The generated water in the cathode off-gas is separated from the oxidant gas by the porous membrane. Here, the oxidant gas newly supplied to the cathode electrode flows through the humidifier. The generated water separated from the cathode off-gas is supplied to the oxidant gas. The oxidant gas, moistened by the generated water, is supplied from the humidifier to the cathode electrode. [Prior art documents] [Patent documents]

[0005] [Patent Document 1] Japanese Patent Application Publication No. 2017-79158 Summary of the Invention [Problem to be solved by the invention]

[0006] The separators that make up the unit cells are electrically conductive. Furthermore, the material of the container that makes up the humidifier is typically metal. That is, the container is also electrically conductive. The produced water contains conductive ions eluted from the unit cells, so the produced water is also electrically conductive. Therefore, if the produced water adheres continuously from the fuel cell stack to the humidifier, it is possible for current to flow from the fuel cell stack to the humidifier via the produced water. When the fuel cell system is installed in a vehicle, it is also possible for current to flow through the vehicle body.

[0007] Therefore, it is necessary to prevent the fuel cell stack and the humidifier from being electrically connected via the generated water.

[0008] The present invention aims to solve the above-mentioned problems. [Means for solving the problem]

[0009] According to one embodiment of the present invention, there is provided a fuel cell system comprising a fuel cell stack, an equipment to which exhaust gas discharged from the fuel cell stack is sent, and piping connecting the fuel cell stack and the equipment, wherein the fuel cell stack is formed with a gas outlet through which the exhaust gas is discharged, and the equipment is formed with a gas receiving section that receives the exhaust gas, the piping extends from the gas outlet toward the gas receiving section, an intermediate pipe made of an insulator is interposed between the piping and the gas receiving section, the upstream end of the intermediate pipe is inserted inside a downstream opening of the piping, and a sealing member is provided between the intermediate pipe and the piping to seal the space between the upstream end of the intermediate pipe and the inner wall of the piping, and the intermediate pipe is provided with a hollow protrusion that protrudes upstream in the flow direction of the exhaust gas more than the upstream end and has an outer diameter smaller than the upstream end. [Effects of the Invention]

[0010] In the present invention, a hollow protrusion, which is also part of the relay pipe, protrudes from the upstream end, which is also part of the relay pipe. Here, a seal member is provided between the relay pipe and the pipe to seal between the outer wall of the upstream end and the inner wall of the pipe. That is, the outer wall of the upstream end abuts against the inner wall of the pipe via the seal member. Meanwhile, the outer diameter of the hollow protrusion is smaller than the outer diameter of the upstream end. Therefore, the outer wall of the hollow protrusion is separated from the inner wall of the pipe. This forms a pocket between the inner wall of the pipe and the outer wall of the hollow protrusion.

[0011] Water (liquid water) in a pipe generally flows along the inner wall of the pipe in a band-like or streaky state. Therefore, the water flowing in the pipe is blown out of the pipe by the exhaust gas and turns into droplets, which then enter the interior of the hollow protrusion from the inner wall of the pipe. Alternatively, the water enters the pocket and is then blown out of the end of the outer wall of the hollow protrusion by the exhaust gas. In this case, the water also turns into droplets and enters the interior of the hollow protrusion. Here, "droplets" includes mist.

[0012] In other words, the water that has entered the relay pipe is separated from the water inside the piping. Therefore, the water inside the piping and the water that has entered the relay pipe are electrically insulated. In addition, the relay pipe is an electrical insulator.

[0013] For the reasons described above, the fuel cell stack and the specified devices are prevented from being electrically connected via water. In other words, it is possible to prevent current from flowing from the fuel cell stack to the devices. When the fuel cell system is installed in the body of an automobile, it is also possible to prevent current from flowing through the body of the automobile. [Brief explanation of the drawings]

[0014] [Figure 1] FIG. 1 is a schematic system diagram of a fuel cell system. [Figure 2]FIG. 2 is a schematic cross-sectional side view of a connection portion between an outlet for cathode off-gas in a fuel cell stack and an inlet for cathode off-gas in a device (humidifier). [Figure 3] FIG. 3 is an enlarged view of the main part of FIG. [Figure 4] FIG. 4 is a partial cross-sectional view taken along line IV-IV in FIG. DETAILED DESCRIPTION OF THE INVENTION

[0015] In the following, anode off-gas refers to excess fuel gas discharged from the anode electrode 22 of the fuel cell stack 12 shown in Fig. 1. Cathode off-gas refers to excess oxidant gas discharged from the cathode electrode 24 of the fuel cell stack 12. Furthermore, "upstream" and "downstream" refer to the upstream and downstream, respectively, in the flow direction of the cathode off-gas.

[0016] First, a fuel cell system 10 shown in Fig. 1 will be described. Note that Fig. 1 is simplified to facilitate understanding of the flow processes of fuel gas and oxidant gas. Therefore, the directions shown in Fig. 1 do not necessarily match the directions in the actual fuel cell system 10. Also, valves, bypass lines, etc. are omitted from Fig. 1.

[0017] The fuel cell system 10 includes a fuel cell stack 12. The fuel cell stack 12 is formed by stacking a plurality of unit cells 14. The unit cell 14 is formed by sandwiching a membrane electrode assembly (MEA) 16 between a first separator 18 and a second separator 20. The MEA 16 is formed by sandwiching an electrolyte membrane 26 between an anode electrode 22 and a cathode electrode 24. The first separator 18 and the second separator 20 are made of a material such as a metal. The electrolyte membrane 26 is made of a material such as a water-containing solid polymer such as perfluorosulfonic acid.

[0018] A first gas flow path 30 is formed in the first separator 18. Hydrogen gas (fuel gas) supplied to the anode electrode 22 flows through the first gas flow path 30. A second gas flow path 32 is formed in the second separator 20. Compressed air (oxidizer gas) supplied to the cathode electrode 24 flows through the second gas flow path 32. In adjacent unit cells 14, a coolant flow path (not shown) is formed between the first separator 18 and the second separator 20. A coolant flows through the coolant flow path.

[0019] The fuel cell stack 12 is formed with a first hydrogen inlet 34a, a second hydrogen inlet 34b, a first hydrogen outlet 36a, and a second hydrogen outlet 36b. The fuel cell stack 12 is formed with a first air inlet 38a, a second air inlet 38b, a first air outlet 40a, and a second air outlet 40b. That is, the fuel cell stack 12 has two inlets and two outlets for hydrogen gas. Similarly, the fuel cell stack 12 also has two inlets and two outlets for compressed air. There may be only one hydrogen inlet and one air inlet.

[0020] The first hydrogen inlet 34a and the second hydrogen inlet 34b communicate with the inlet of the first gas flow path 30. The outlet of the first gas flow path 30 communicates with the first hydrogen outlet 36a and the second hydrogen outlet 36b. The first air inlet 38a and the second air inlet 38b communicate with the inlet of the second gas flow path 32. The outlet of the second gas flow path 32 communicates with the first air outlet 40a and the second air outlet 40b.

[0021] The fuel cell system 10 includes a high-pressure tank 50 and an ejector 52. The high-pressure tank 50 is filled with hydrogen gas. The ejector 52 is a device for supplying hydrogen gas to the anode electrode 22. A first supply manifold 54 is provided between the ejector 52 and the fuel cell stack 12. The first supply manifold 54 distributes the hydrogen gas sent from the ejector 52 in two directions. The hydrogen gas distributed in one direction flows toward the first hydrogen inlet 34a. The remaining hydrogen gas distributed in one direction flows toward the second hydrogen inlet 34b.

[0022] A gas-liquid separator 58 is connected to the fuel cell stack 12 via a first exhaust manifold 56. The anode off-gas discharged from the first hydrogen outlet 36a and the second hydrogen outlet 36b are collected in the first exhaust manifold 56 and sent to the gas-liquid separator 58. The anode off-gas is separated into hydrogen gas and water in the gas-liquid separator 58. The hydrogen gas is returned to the ejector 52 and then re-supplied to the anode electrode 22.

[0023] The fuel cell system 10 further includes an air pump 60, a humidifier 62, and a circulation pump 64. The air pump 60 generates compressed air by compressing atmospheric air, for example. The fuel cell stack 12 and the humidifier 62 are connected via a second supply manifold 68 and a second exhaust manifold 70. The humidifier 62 supplies water generated during power generation by the fuel cell stack 12 during power generation, i.e., generated water PW, to be described later, to the compressed air obtained by the air pump 60. This moistens the compressed air. The moistened compressed air is distributed in two directions by the second supply manifold 68. The compressed air distributed in one direction is directed toward the first air inlet 38a. The compressed air distributed in the other direction is directed toward the second air inlet 38b. The circulation pump 64 may be omitted.

[0024] The cathode off-gas discharged from the first air outlet 40a and the second air outlet 40b are collected in the second exhaust manifold 70 and sent to the humidifier 62. The water in the cathode off-gas is separated from the compressed air in the humidifier 62. The compressed air is resupplied to the cathode electrode 24 by, for example, a circulation pump 64. Meanwhile, the water is added to new compressed air sent from the air pump 60, as described above.

[0025] The fuel cell system 10 is controlled by a control device 72. The fuel cell system 10 configured in this manner is mounted on the body of an automobile, for example.

[0026] 2 is a schematic side cross-sectional view of the connection between the cathode offgas outlet of the fuel cell stack 12 and the cathode offgas inlet of the humidifier 62. As described above, the fuel cell system 10 includes the second exhaust manifold 70 that connects the fuel cell stack 12 and the humidifier 62. The humidifier 62 corresponds to a device connected downstream of the fuel cell stack 12 in the flow direction of the cathode offgas discharged from the fuel cell stack 12. The second exhaust manifold 70 corresponds to a pipe.

[0027] As described above, the fuel cell stack 12 is formed with a first air outlet 40a and a second air outlet 40b (both of which are gas outlets). Meanwhile, the humidifier 62 is formed with an air inlet 80. The humidifier 62 is provided with a gas receiving section 82. The gas receiving section 82 has a first section 84a extending in the left-right direction of FIG. 2 and a second section 84b covering the air inlet 80. As shown in FIG. 3, which is an enlarged view of a main portion of FIG. 2, an annular stopper section 86 is provided inside the first section 84a to narrow the interior of the first section 84a. The second section 84b is bent at approximately 90° with respect to the first section 84a directly above the air inlet 80 and faces the air inlet 80. As can be seen from this, the gas receiving section 82 is approximately L-shaped.

[0028] The second exhaust manifold 70 has a shape that extends from the first air outlet 40a and the second air outlet 40b toward the gas receiving portion 82 (see FIG. 2). Specifically, the second exhaust manifold 70 has a first introduction portion 88a connected to the first air outlet 40a, a second introduction portion 88b connected to the second air outlet 40b, and a collecting portion 90. In this embodiment, the first introduction portion 88a is located below the second introduction portion 88b in the direction of gravity, and the collecting portion 90 extends in the vertical direction.

[0029] The first introduction part 88a and the second introduction part 88b are individually connected to a collecting part 90. A drain hole 92 is formed in the collecting part 90 near the first introduction part 88a. A drain tube 93 may be connected to the drain hole 92.

[0030] A downstream opening 94 is formed in the collecting section 90 at a position approximately 180° away from the second introduction section 88b. The collecting section 90 has a connecting tube 91 in which the downstream opening 94 is formed. A relay pipe 100 is inserted into the connecting tube 91. The connecting tube 91 surrounds the relay pipe 100. The cathode off-gas that flows into the first introduction section 88a and the second introduction section 88b flows through the collecting section 90 toward the downstream opening 94. On the inner wall of the collecting section 90, protruding walls 95a and 95b that protrude toward the front of the paper in FIG. 4 are provided near the downstream opening 94. A guide groove 96 is formed between the protruding wall 95a and the protruding wall 95b. The guide groove 96 is a wide groove that extends in the up-down direction, which is the extension direction of the collecting section 90. Note that only the protruding wall 95a is shown in FIG. 3.

[0031] 3, an upstream opening 98 is formed in the gas receiving portion 82. The upstream opening 98 is located downstream of the downstream opening 94 of the second exhaust manifold 70 in the flow direction of the cathode offgas. However, the upstream opening 98 is upstream of the air supply port 80 in the flow direction of the cathode offgas. In other words, the upstream opening 98 is located between the downstream opening 94 of the second exhaust manifold 70 and the air supply port 80 of the humidifier 62.

[0032] The second exhaust manifold 70 and the gas receiving section 82 are connected via a relay pipe 100. Here, the relay pipe 100 is made of an insulating material. The relay pipe 100 is preferably made of an elastic material. In this case, the relay pipe 100 is sufficiently compressed when subjected to compressive stress, and easily returns to its original shape when the compressive stress is removed. Specific examples of suitable materials for the relay pipe 100 include rubber, elastomer, and resin.

[0033] As shown in Fig. 3, the relay pipe 100 has an upstream end portion 102, an intermediate portion 104, and a downstream end portion 106. A first annular groove 108 extending in the circumferential direction is formed in the upstream end portion 102, which is a flange-like portion with a slightly larger diameter. A first elastic seal member 110 is fitted in the first annular groove 108. The first seal member 110 provides a seal between the outer peripheral wall of the upstream end portion 102 and the inner wall of the collecting portion 90 of the second exhaust manifold 70 near the downstream opening 94.

[0034] The downstream end 106, which has a slightly larger diameter and is flange-shaped, abuts against the annular stopper portion 86. This positions the relay pipe 100 relative to the gas receiving portion 82. A second annular groove 112 extending in the circumferential direction is formed in the downstream end 106. A second elastic seal member 114 is fitted in the second annular groove 112. The second seal member 114 provides a seal between the outer peripheral wall of the downstream end 106 and the inner wall of the gas receiving portion 82 near the upstream opening 98. The outer diameters of the upstream end 102 and the downstream end 106 are approximately equal to each other.

[0035] The relay pipe 100 further has a hollow protrusion 116 protruding from the upstream end 102. The protrusion direction of the hollow protrusion 116 is the upstream direction in the flow direction of the cathode off-gas. Therefore, the hollow protrusion 116 is located upstream of the upstream end 102 (and the first seal member 110) in the flow direction of the cathode off-gas. The outer diameter of the hollow protrusion 116 is smaller than the outer diameter of the upstream end 102. Therefore, an annular pocket 118 is formed between the inner wall of the collecting section 90 in the second exhaust manifold 70 and the outer peripheral wall of the hollow protrusion 116.

[0036] The outer periphery of the tip 116a of the hollow protrusion 116 is separated from the inner wall of the connecting tube 91 along its entire circumference. The annular pocket 118 is an annular groove recessed from the tip 116a of the hollow protrusion 116 toward the downstream end 106. The annular pocket 118 opens toward the upstream in the flow direction of the cathode off-gas. One end face (annular side surface) of the upstream end 102 forms the groove bottom of the annular pocket 118.

[0037] The inner diameter of the relay pipe 100 is smallest at the most upstream hollow protruding portion 116 facing the fuel cell stack 12, and gradually increases from the upstream end 102 toward the middle portion 104. The inner diameter of the relay pipe 100 is largest at the downstream end 106 facing the humidifier 62. That is, the inner diameter of the relay pipe 100 is small upstream and large downstream. The inner diameter of the hollow protruding portion 116 is approximately constant, and the inner diameter of the downstream end 106 is also approximately constant.

[0038] The fuel cell system 10 according to this embodiment is basically configured as described above. Next, the effects of the fuel cell system 10 will be described.

[0039] When assembling the fuel cell system 10, the downstream end 106 of the relay pipe 100 is inserted into the upstream opening 98 of the gas receiving section 82 of the humidifier 62 (see FIG. 3). The end face of the downstream end 106 abuts against the annular stopper portion 86 provided inside the gas receiving section 82. This abutment positions the relay pipe 100 relative to the gas receiving section 82. Meanwhile, the second exhaust manifold 70 is attached to the fuel cell stack 12. Next, the hollow protruding portion 116 of the relay pipe 100 is inserted into the downstream opening 94 of the collecting section 90 of the second exhaust manifold 70. In this state, the fuel cell stack 12, the second exhaust manifold 70, and the humidifier 62 are positioned and fixed to, for example, the body of an automobile.

[0040] Here, the dimensions (inner diameter, etc.) of the second exhaust manifold 70 and the like may be larger than the nominal value within the tolerance range. In this case, the relay pipe 100 is slightly compressed due to its elasticity. This makes it easy to align the positions of the connecting parts (bolt holes, etc.) of the fuel cell stack 12, the second exhaust manifold 70, and the humidifier 62 with the positions of the connecting parts (bolt holes, etc.) of the vehicle body. This makes it easy to install the fuel cell system 10 on the vehicle body.

[0041] When the fuel cell stack 12 is operated, hydrogen gas is supplied from a high-pressure tank 50 (see FIG. 1). The hydrogen gas passes through an ejector 52 and flows into a first supply manifold 54. After being distributed in two directions within the first supply manifold 54, the hydrogen gas flows into the first gas flow passage 30 from the first hydrogen inlet 34a and the second hydrogen inlet 34b. While flowing through the first gas flow passage 30, the hydrogen gas comes into contact with the anode electrode 22 and undergoes an oxidation reaction. Excess hydrogen gas (anode off-gas), which contains moisture, is discharged from the first gas flow passage 30 through the first hydrogen outlet 36a or the second hydrogen outlet 36b to the first exhaust manifold 56.

[0042] In the first exhaust manifold 56, the anode off-gas discharged from the first hydrogen outlet 36a and the anode off-gas discharged from the second hydrogen outlet 36b join together. Then, in the gas-liquid separator 58, water in the anode off-gas is separated from hydrogen gas. The hydrogen gas from which the water has been removed flows to the ejector 52. In the ejector 52, new hydrogen gas supplied from the high-pressure tank 50 joins with the hydrogen gas discharged from the gas-liquid separator 58. The joined hydrogen gas flows into the first gas flow path 30 via the same route as above. Thereafter, the above circulation is repeated.

[0043] Meanwhile, compressed air is supplied from the air pump 60. The compressed air flows through the humidifier 62. At this time, moisture is added to the compressed air. That is, the humidity of the compressed air increases. The compressed air flows into the second supply manifold 68 and is distributed in two directions within the second supply manifold 68. The compressed air then flows into the second gas flow path 32 from the first air inlet 38a and the second air inlet 38b. While flowing through the second gas flow path 32, oxygen in the compressed air comes into contact with the cathode electrode 24 and undergoes a reduction reaction. In this reduction reaction, water is produced. This water is the produced water PW.

[0044] The produced water PW is discharged together with excess compressed air (cathode off-gas) from the second gas flow path 32 through the first air outlet 40a or the second air outlet 40b into the second exhaust manifold 70. Specifically, the cathode off-gas and produced water PW discharged from the first air outlet 40a flow into the collecting section 90 through the first introduction section 88a shown in FIG. 2. The cathode off-gas and produced water PW discharged from the second air outlet 40b flow into the collecting section 90 through the second introduction section 88b shown in FIG. 2. In the collecting section 90, the cathode off-gas discharged from the first air outlet 40a and the cathode off-gas discharged from the second air outlet 40b join together.

[0045] The combined cathode off-gas flows into the humidifier 62 through the air inlet 80. When the cathode off-gas passes through a porous membrane (not shown) in the humidifier 62, it is separated into compressed air and produced water PW. That is, the humidity of the compressed air decreases. All or part of the compressed air is returned to the humidifier 62 by the circulation pump 64 (see FIG. 1). Along the way, the compressed air and new compressed air sent from the air pump 60 are combined. The combined compressed air flows into the humidifier 62. At this time, the produced water PW is supplied as moisture to the compressed air in the same manner as above. The compressed air to which moisture has been supplied flows into the second gas flow path 32 via the same route as above. Thereafter, the above circulation is repeated.

[0046] Here, the cathode off-gas contains the produced water PW as described above. Therefore, as shown in FIG. 2, the produced water PW flows into the second exhaust manifold 70. Because the cathode off-gas flows toward the air inlet 80, the produced water PW is subjected to pressure from the cathode off-gas in a direction toward the air inlet 80. Therefore, the produced water PW flows toward the downstream opening 94 of the collecting section 90. While the fuel cell stack 12 is operating, the produced water PW is continuously produced as a reaction product at the cathode electrode 24. Therefore, the produced water PW continues along the inner wall of the second exhaust manifold 70, for example, in the form of a strip or stripe.

[0047] In this embodiment, the hollow protrusion 116 of the relay pipe 100 is inserted into the downstream opening 94 of the collecting section 90. The outer diameter of the hollow protrusion 116 is smaller than the inner diameter of the collecting section 90. Therefore, the produced water PW that flows down the inner wall of the second exhaust manifold 70 is temporarily stored in the annular pocket 118. When the cathode off-gas comes into contact with the produced water PW in the annular pocket 118, a portion of the produced water PW is pushed out of the annular pocket 118 and flows along the outer wall of the hollow protrusion 116 to reach the opening of the hollow protrusion 116. Because the cathode off-gas flows into the interior of the hollow protrusion 116 through the opening of the hollow protrusion 116, a portion of the produced water PW is blown into the interior of the hollow protrusion 116 by the cathode off-gas. As a result, a portion of the produced water PW is separated and becomes liquid droplet water DW.

[0048] Alternatively, the produced water PW outside the annular pocket 118 is blown into the interior of the hollow protrusion 116 by the cathode off-gas. This also causes a portion of the produced water PW to be split into droplet water DW. As described above, a portion of the produced water PW enters the interior of the hollow protrusion 116 as droplet water DW.

[0049] As described above, the inner diameter of the relay pipe 100 is smallest at the hollow protrusion 116, which is located at the most upstream position in the flow direction of the cathode off-gas (the direction of travel of the liquid droplet water DW). Therefore, the flow rate of the cathode off-gas increases at the upstream opening of the hollow protrusion 116. In other words, negative pressure is likely to occur at the upstream opening of the hollow protrusion 116. As a result, the produced water PW is sucked into the interior of the relay pipe 100 relatively quickly. This suction also causes a portion of the produced water PW to break up and become liquid droplet water DW.

[0050] As described above, according to this embodiment, the relay pipe 100 interrupts the flow of the produced water PW. Furthermore, the relay pipe 100 is made of an insulator. Therefore, the fuel cell stack 12 and the humidifier 62 are electrically insulated from each other. Therefore, even if the concentration of conductive ions contained in the produced water PW is high and the conductivity of the produced water PW is high, current is prevented from flowing downstream of the relay pipe 100. This makes it possible to prevent current from flowing to the humidifier 62, the vehicle body, etc.

[0051] A portion of the droplet water DW flows into the interior of the humidifier 62 through the air intake port 80. The droplet water DW inside the humidifier 62 is supplied to new compressed air supplied from the air pump 60, as described above. The remainder of the droplet water DW collects inside the relay pipe 100 to form collected water CW. When the collected water CW reaches a certain amount, the collected water CW flows out from the opening of the hollow protrusion 116 into the collecting section 90. The lowest end of the air intake port 80 is higher than the lowest end of the opening of the hollow protrusion 116. This prevents the collected water CW from flowing into the interior of the humidifier 62 through the air intake port 80.

[0052] Meanwhile, a portion of the produced water PW stored in the annular pocket 118 flows out from the annular pocket 118 into the collecting section 90. The produced water PW that has flowed out into the collecting section 90 joins with the collected water CW that has flowed out into the collecting section 90 from the opening of the hollow protrusion 116.

[0053] As described above, the guide groove 96 (see FIGS. 2 to 4) is formed on the inner wall of the collecting section 90. The produced water PW and collected water CW that flow into the collecting section 90 flow down within the collecting section 90, for example, along the vicinity of the protruding walls 95a, 95b of the guide groove 96. The descending produced water PW and collected water CW are discharged to the outside of the second exhaust manifold 70 via the drain hole 92 and the drain tube 93. Note that FIG. 4 does not show the produced water PW rising toward the annular pocket 118.

[0054] 4, the inclined grooves 120 may be formed by cutting out the inner walls of the connecting tube 91 and the collecting portion 90. In this case, the produced water PW in the annular pocket 118 can easily move along the inclined grooves 120 to the guide groove 96.

[0055] As described above, this embodiment is a fuel cell system (10) including a fuel cell stack (12), a device (62) to which exhaust gas discharged from the fuel cell stack is sent, and piping (70) connecting the fuel cell stack and the device, wherein the fuel cell stack is formed with gas outlets (40a, 40b) through which the exhaust gas is discharged, and the device is formed with a gas receiving section (82) that receives the exhaust gas, and the piping extends from the gas outlets toward the gas receiving section and The present invention discloses a fuel cell system in which an insulator-made relay pipe (100) is interposed between the piping and the gas receiving section, an upstream end (102) of the relay pipe is inserted into a downstream opening (94) of the piping, a sealing member (110) is provided between the relay pipe and the piping to seal between the upstream end of the relay pipe and the inner wall of the piping, and the relay pipe is provided with a hollow protruding portion (116) that protrudes upstream in the flow direction of the exhaust gas more than the upstream end and has an outer diameter smaller than that of the upstream end.

[0056] A hollow protrusion protrudes from the upstream end of the relay pipe. A seal member is provided at the upstream end to seal between the outer wall of the upstream end and the inner wall of the pipe. The outer diameter of the hollow protrusion is smaller than the outer diameter of the upstream end. Therefore, the outer wall of the hollow protrusion is spaced from the inner wall of the pipe. Based on this, a pocket is formed between the outer wall of the hollow protrusion and the inner wall of the pipe.

[0057] Water in a pipe generally flows along the inner wall of the pipe in a band-like or streaky manner. Therefore, the water flowing inside the pipe is blown out of the pipe by the exhaust gas and turns into droplets, which then enter the hollow protrusion. Alternatively, the water enters the pocket and is then blown out of the end of the outer wall of the hollow protrusion by the exhaust gas. In this case, the water also turns into droplets and enters the hollow protrusion.

[0058] In other words, the water (droplets) that has entered the relay pipe is separated from the water inside the piping. Therefore, the water inside the piping and the water that has entered the relay pipe are electrically insulated. In addition, the relay pipe is an insulator.

[0059] For the reasons described above, the fuel cell stack and a predetermined device are prevented from being electrically connected via water. Therefore, even if the conductivity of the produced water becomes high, it is possible to prevent current from flowing from the fuel cell stack to the device (such as a humidifier). When the fuel cell system is installed in a vehicle body, current is also prevented from flowing through the vehicle body.

[0060] This embodiment discloses a fuel cell system in which the inner diameter of the relay pipe is smallest at the hollow protruding portion and increases toward the downstream in the flow direction of the exhaust gas.

[0061] With this configuration, the flow velocity of the exhaust gas increases near the upstream opening of the hollow protrusion. This allows water to be drawn into the hollow protrusion relatively quickly. This suction more easily separates some of the generated water. This makes it easier to electrically insulate the water in the piping from the water that has entered the relay pipe.

[0062] This embodiment discloses a fuel cell system in which the piping is formed with a drain hole (92) for discharging moisture that flows together with the exhaust gas.

[0063] Excess water in the piping is discharged to the outside of the piping through the drain hole. That is, excess water that does not flow into the inside of the device can be discharged to the outside of the piping through the drain hole.

[0064] This embodiment discloses a fuel cell system in which a guide groove (96) for guiding the water to the drain hole is formed on the inner wall of the pipe.

[0065] The excess water flows down the guide groove toward the drain hole. That is, the guide groove efficiently guides the excess water to the drain hole. This allows the excess water to be efficiently discharged outside the piping.

[0066] This embodiment discloses a fuel cell system in which the relay pipe is made of an elastic material.

[0067] The dimensions of the fuel cell stack, piping, or equipment may be larger than the nominal values ​​within the tolerance range. In such cases, the relay pipe is slightly compressed due to its elasticity. This makes it easy to align the positions of the connecting parts (bolt holes, etc.) of the fuel cell stack, piping, and equipment with the positions of the connecting parts (bolt holes, etc.) of the object on which the fuel cell system is to be installed. This makes it easy to install the fuel cell system on the object on which it is to be installed. The object on which it is to be installed is, for example, the body of an automobile.

[0068] In a fuel cell stack, water is produced by a reduction reaction at the cathode electrode. That is, the cathode off-gas contains a large amount of produced water. The cathode off-gas containing the produced water is sent to the humidifier. In this way, in a fuel cell system, the cathode off-gas flows with the fuel cell stack upstream and the humidifier downstream. Therefore, in this case, electrical connection between the fuel cell stack and the humidifier via the produced water is avoided.

[0069] As can be understood from this, a specific example of the device is a humidifier, and in other words, this embodiment discloses a fuel cell system in which the device is a humidifier.

[0070] The present invention is not limited to the above disclosure, and various configurations can be adopted without departing from the gist of the present invention. [Explanation of symbols]

[0071] 10...Fuel cell system 12...Fuel cell stack 14...unit cell 22...anode electrode 24...Cathode electrode 26...Electrolyte membrane 30...first gas flow path 32...second gas flow path 34a...First hydrogen inlet 34b...Second hydrogen inlet 36a...First hydrogen outlet 36b...Second hydrogen outlet 38a...First air inlet 38b...Second air inlet 40a...First air outlet 40b...Second air outlet 50...High pressure tank 54...First supply manifold 56...First exhaust manifold 60...Air pump 62... Humidifier 64... Circulation pump 68...Second supply manifold 70...Second exhaust manifold 80...Air intake port 82...Gas receiving section 88a...First introduction part 88b...Second introduction part 90...Collecting portion 92...Drain hole 94...Downstream opening 96...Guide groove 98...Upstream opening 100...Relay pipe 102...Upstream end 106...Downstream end 108...first annular groove 110...first seal member 112... Second annular groove 114... Second seal member 116...Hollow protrusion 118...Annular pocket

Claims

1. A fuel cell system comprising a fuel cell stack, a device to which exhaust gas discharged from the fuel cell stack is sent, and a pipe connecting the fuel cell stack and the device, a gas outlet through which the exhaust gas is discharged is formed in the fuel cell stack, and a gas receiving section that receives the exhaust gas is formed in the device, and the piping extends from the gas outlet toward the gas receiving section; a relay pipe made of an insulator is interposed between the piping and the gas receiving section, The upstream end of the relay pipe is inserted into the downstream opening of the piping, a seal member is provided between the relay pipe and the piping to seal between the upstream end of the relay pipe and an inner wall of the piping; The relay pipe is provided with a hollow protruding portion that protrudes upstream in the flow direction of the exhaust gas beyond the upstream end portion and has an outer diameter smaller than that of the upstream end portion.

2. 2. The fuel cell system according to claim 1, wherein the inner diameter of the relay pipe is smallest at the hollow protruding portion and increases toward the downstream side in the flow direction of the exhaust gas.

3. 3. The fuel cell system according to claim 2, wherein the pipe is formed with a drain hole for discharging water that flows together with the exhaust gas.

4. 4. The fuel cell system according to claim 3, wherein a guide groove for guiding the water to the drain hole is formed on the inner wall of the pipe.

5. 2. The fuel cell system according to claim 1, wherein the relay pipe is made of an elastic material.

6. 6. The fuel cell system according to claim 1, wherein the device is a humidifier.

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