Non-aqueous electrolyte secondary battery

Abstract

According to the present invention, a battery (1) is provided with: a laminate film outer package (5) which is configured by bonding film materials; and a flat electrode body (10) which is contained in the laminate film outer package (5). According to the present invention, a positive electrode has a positive electrode non-coated part, in which a positive electrode mixture layer is not present and a positive electrode core body is exposed, in a midway in the longitudinal direction; and a negative electrode has a negative electrode non-coated part, in which a negative electrode mixture layer is not present and a negative electrode core body is exposed, in a midway in the longitudinal direction. The battery (1) is provided with: a positive electrode tab (15) which is bonded and electrically connected to the positive electrode non-coated part; and a negative electrode tab (20) which is bonded and electrically connected to the negative electrode non-coated part. The positive electrode tab (15) and the negative electrode tab (20) generally pass through the center of the flat electrode body (10) in the thickness direction, while being positioned on the same side with respect to a virtual plane that is generally perpendicular to the thickness direction of the flat electrode body.

Description

[Technical Field]

[0001] The present disclosure relates to a non-aqueous electrolyte secondary battery having a laminate film exterior body formed by joining laminate film materials. [Background technology]

[0002] A conventional secondary battery is described in Patent Document 1. This secondary battery is a laminated lithium-ion secondary battery, and includes a flat electrode assembly formed by winding a long positive electrode and a long negative electrode facing each other with a long separator interposed therebetween, and a laminate film exterior housing that houses the flat electrode assembly. In this secondary battery, the positive electrode tab extends upward in the height direction from a positive electrode portion located near the center in the thickness direction of the flat electrode assembly, and the negative electrode tab extends upward in the height direction from a negative electrode portion located near the center in the thickness direction of the flat electrode assembly. Each of the positive electrode tab and the negative electrode tab is folded in the thickness direction of the laminate film exterior housing and then further folded in the height direction at the back side of the laminate film exterior housing. After being folded in the height direction, each of the positive electrode tab and the negative electrode tab extends along the back side and is extended to the outside of the battery via a heat-sealed portion of the laminate film exterior housing. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Application Laid-Open No. 2004-349243 Summary of the Invention [Problem to be solved by the invention]

[0004] Conventionally, in secondary batteries equipped with a flat electrode body and a laminate film exterior body, the positive electrode tab and the negative electrode tab are each joined to the longitudinal end of the long core body because it is not easy to intermittently apply a mixture layer to a long core body, and because there is a concern that when a wound electrode body is press-formed into a flat shape, the electrode body becomes dense in the thickness direction, making it more susceptible to short circuits. For this reason, in the secondary battery of Patent Document 1, the positive electrode tab and the negative electrode tab are each drawn out from an electrode portion located near the center in the thickness direction of the flat electrode body.

[0005] In the secondary battery of Patent Document 1, the positive electrode tab and the negative electrode tab protruding from near the center in the thickness direction of the flat electrode body must extend a long distance in the thickness direction from the center in the thickness direction to the back side of the laminate film casing, which makes it difficult to position the positive electrode tab and the negative electrode tab, and as a result, it is difficult to weld the positive electrode tab and the negative electrode tab to the laminate film casing. Also, because the positive electrode tab and the negative electrode tab are fixed to the longitudinal ends of the long core, it is not possible to provide a mixture layer at the longitudinal ends of the long core, making it difficult to increase the area to which the mixture layer is applied and therefore difficult to increase the capacity.

[0006] Therefore, an object of the present disclosure is to provide a nonaqueous electrolyte secondary battery equipped with a laminate film exterior body that allows easy positioning of the positive electrode tab and the negative electrode tab and facilitates increasing the capacity. [Means for solving the problem]

[0007] In order to solve the above problems, the nonaqueous electrolyte secondary battery according to the present disclosure includes a laminated film exterior body formed by joining film materials, and a flat electrode body housed in the laminated film exterior body and formed by winding a long positive electrode and a long negative electrode that face each other with a long separator interposed therebetween in a flat shape, wherein the positive electrode includes a long positive electrode core and a positive electrode mixture layer provided on the positive electrode core, and has a positive electrode non-coated portion in the middle in the longitudinal direction where the positive electrode mixture layer is not present and the positive electrode core is exposed. the negative electrode includes an elongated negative electrode core and a negative electrode mixture layer provided on the negative electrode core, has a negative electrode non-coated portion midway in the longitudinal direction where the negative electrode mixture layer is not present and the negative electrode core is exposed, and further includes a positive electrode tab joined and electrically connected to the positive electrode non-coated portion, and a negative electrode tab joined and electrically connected to the negative electrode non-coated portion, and the positive electrode tab and the negative electrode tab are located on the same side of an imaginary plane that passes approximately through the center in the thickness direction of the flat electrode body and is approximately perpendicular to the thickness direction.

[0008] Further, a nonaqueous electrolyte secondary battery according to another aspect of the present disclosure includes a laminate film exterior body formed by joining film materials, and a flat electrode body housed within the laminate film exterior body and formed by winding a long positive electrode and a long negative electrode facing each other with a long separator interposed therebetween in a flat shape, wherein the positive electrode includes a long positive electrode core and a positive electrode mixture layer provided on the positive electrode core, and has a positive electrode uncoated portion midway in the longitudinal direction where the positive electrode mixture layer is not present and the positive electrode core is exposed. In both cases, the negative electrode includes a long negative electrode core and a negative electrode mixture layer provided on the negative electrode core, has a negative electrode non-coated portion at the outermost longitudinal portion where the negative electrode mixture layer is not present and the negative electrode core is exposed, and further includes a positive electrode tab joined and electrically connected to the positive electrode non-coated portion, and a negative electrode tab joined and electrically connected to the negative electrode non-coated portion, and the positive electrode tab and negative electrode tab are located on the same side of an imaginary plane that passes approximately through the center in the thickness direction of the flat electrode body and is approximately perpendicular to the thickness direction.

[0009] Furthermore, a nonaqueous electrolyte secondary battery according to a further aspect of the present disclosure includes: a laminate film exterior body formed by bonding film materials; and a flat electrode body housed within the laminate film exterior body and formed by winding a long positive electrode and a long negative electrode facing each other with a long separator interposed therebetween into a flat shape; the positive electrode includes a long positive electrode core and a positive electrode mixture layer provided on the positive electrode core, and has a positive electrode non-coated portion midway along the length where the positive electrode mixture layer is not present and the positive electrode core is exposed; and the negative electrode includes a long negative electrode core and a negative electrode mixture layer provided on the negative electrode core, and has a negative electrode non-coated portion at the innermost portion along the length where the negative electrode mixture layer is not present and the negative electrode core is exposed; and the battery further includes a positive electrode tab joined and electrically connected to the positive electrode non-coated portion, and a negative electrode tab joined and electrically connected to the negative electrode non-coated portion. [Effects of the Invention]

[0010] According to the nonaqueous electrolyte secondary battery according to the present disclosure, the positive electrode tab and the negative electrode tab can be easily positioned, and the capacity can be easily increased. [Brief explanation of the drawings]

[0011] [Figure 1] 1 is a perspective view of a nonaqueous electrolyte secondary battery according to a first embodiment of the present disclosure. [Figure 2] FIG. 2 is a front view of the battery. [Figure 3a] FIG. 3a is a diagram illustrating a method for manufacturing a laminate film exterior body. [Figure 3b] FIG. 3b is a diagram illustrating a method for manufacturing a laminate film exterior body. [Figure 4a] FIG. 4a is a schematic front view of a long positive electrode before being wound, as viewed from one side in the thickness direction. [Figure 4b] FIG. 4b is a schematic front view of the long negative electrode before being wound, as viewed from one side in the thickness direction. [Figure 5] FIG. 2 is a plan view of a flat electrode body included in the battery as viewed from one side in the height direction. [Figure 6]2 is a schematic partial cross-sectional view of the battery taken along a cross section passing through the negative electrode tab and including the thickness direction and height direction. FIG. [Figure 7] 1 is a schematic cross-sectional view of a tab forming device that can be used to form the distal portion of the tab. [Figure 8a] FIG. 8a is a diagram illustrating a method for manufacturing a laminate film exterior body of a battery of a reference example. [Figure 8b] FIG. 8b is a diagram illustrating a method for manufacturing a laminate film exterior body of a battery according to a reference example. [Figure 9a] FIG. 9a is a schematic front view of the positive electrode of the battery of the reference example, corresponding to FIG. 4a. [Figure 9b] FIG. 9b is a schematic front view of the negative electrode of the battery of the reference example, corresponding to FIG. 4b. [Figure 10] 6 is a plan view corresponding to FIG. 5 of a flat electrode body of a battery of a reference example. FIG. [Figure 11] FIG. 7 is a schematic partial cross-sectional view of the battery of the reference example, corresponding to FIG. 6. [Figure 12] FIG. 10 is a schematic cross-sectional view of a tab forming device that can be used to form the tip end portion of the tab of the battery of the reference example. [Figure 13a] FIG. 13a is a front view of a battery in which the welding resin is located outside the sealed portion, resulting in poor sealing. [Figure 13b] FIG. 13b is a front view of a battery in which the welding resin is located inside the sealed portion, resulting in poor sealing. [Figure 14a] FIG. 10 is a schematic front view of a long, unwound positive electrode in a nonaqueous electrolyte secondary battery according to a second embodiment, viewed from one side in the thickness direction (the outer side in the radial direction of a flat electrode body). [Figure 14b] FIG. 10 is a schematic front view of a long positive electrode before being wound in a nonaqueous electrolyte secondary battery according to a second embodiment, as viewed from the other side in the thickness direction (the inner side in the radial direction of the flat electrode body). [Figure 14c] FIG. 10 is a schematic front view of a long negative electrode before being wound in a nonaqueous electrolyte secondary battery according to a second embodiment, as viewed from one side in the thickness direction (the outer side in the radial direction of a flat electrode body). [Figure 14d] 10 is a schematic front view of a long negative electrode before being wound in a nonaqueous electrolyte secondary battery according to a second embodiment, as viewed from the other side in the thickness direction (the inner side in the radial direction of the flat electrode body). FIG. [Figure 15] FIG. 10 is a plan view of a flat electrode body of a second embodiment as viewed from one side in the height direction. [Figure 16a] FIG. 10 is a schematic front view of a long, unwound positive electrode in a nonaqueous electrolyte secondary battery according to a third embodiment, as viewed from one side in the thickness direction (the outer side in the radial direction of a flat electrode body). [Figure 16b] FIG. 10 is a schematic front view of a long positive electrode before being wound in a nonaqueous electrolyte secondary battery according to a third embodiment, as viewed from the other side in the thickness direction (the inner side in the radial direction of the flat electrode body). [Figure 16c] FIG. 10 is a schematic front view of a long negative electrode before being wound in a nonaqueous electrolyte secondary battery according to a third embodiment, as viewed from one side in the thickness direction (the outer side in the radial direction of a flat electrode body). [Figure 16d] FIG. 10 is a schematic front view of a long negative electrode before being wound in a nonaqueous electrolyte secondary battery according to a third embodiment, as viewed from the other side in the thickness direction (the inner side in the radial direction of the flat electrode body). [Figure 17] FIG. 10 is a plan view of a flat electrode body of a third embodiment as viewed from one side in the height direction. [Figure 18a] FIG. 10 is a schematic front view of a long, unwound positive electrode in a nonaqueous electrolyte secondary battery according to a fourth embodiment, viewed from one side in the thickness direction (the outer side in the radial direction of a flat electrode body). [Figure 18b] 10 is a schematic front view of a long positive electrode before being wound in a nonaqueous electrolyte secondary battery according to a fourth embodiment, as viewed from the other side in the thickness direction (the inner side in the radial direction of the flat electrode body). FIG. [Figure 18c] FIG. 10 is a schematic front view of a long negative electrode before being wound in a nonaqueous electrolyte secondary battery according to a fourth embodiment, as viewed from one side in the thickness direction (the outer side in the radial direction of a flat electrode body). [Figure 18d]FIG. 10 is a schematic front view of a long negative electrode before being wound in a nonaqueous electrolyte secondary battery according to a fourth embodiment, as viewed from the other side in the thickness direction (the inner side in the radial direction of the flat electrode body). DETAILED DESCRIPTION OF THE INVENTION

[0012] Hereinafter, embodiments of the present disclosure will be described in detail with reference to the accompanying drawings. It should be noted that, when multiple embodiments or variations are included below, it is assumed from the outset that new embodiments can be constructed by appropriately combining their characteristic features. In the following examples, the same components are denoted by the same reference numerals in the drawings, and redundant explanations will be omitted. The drawings include schematic diagrams, and the dimensional ratios of the length, width, height, etc. of each component between different drawings do not necessarily match.

[0013] In this specification, when the word "approximately" is used, it is used in the same sense as the word "roughly speaking," and the requirement of "approximately..." is met if a person looks roughly like..., and is satisfied if they can recognize it that way. For example, the requirement of "an imaginary plane that passes roughly through the center in the thickness direction of the flat electrode body and is roughly perpendicular to the thickness direction" is satisfied if a person can recognize it as an imaginary plane that passes roughly through the center in the thickness direction of the flat electrode body and is perpendicular to the thickness direction. Furthermore, although the description will be given using a lithium ion battery using a nonaqueous electrolyte solution as an example of a nonaqueous electrolyte secondary battery, the nonaqueous electrolyte secondary battery of the present disclosure may be any nonaqueous electrolyte secondary battery that can have the configuration of the present disclosure and is not limited to a lithium ion battery.

[0014] In the following description and drawings, the X direction indicates the thickness direction of the laminated nonaqueous electrolyte secondary battery 1, the Y direction indicates the width direction of the battery 1, and the Z direction indicates the height direction of the battery 1. The X, Y, and Z directions are perpendicular to one another. The α direction indicates the longitudinal direction of the long positive electrode 40, 140, and the arrow in the α direction points from the winding start side to the winding end side. The β direction indicates the width direction (short direction) of the long positive electrode 40, 140. The γ direction indicates the longitudinal direction of the long negative electrode 50, 150, and the arrow in the γ direction points from the winding start side to the winding end side. The δ direction indicates the width direction (short direction) of the long negative electrode 50, 150. The α direction is perpendicular to the β direction, and the γ direction is perpendicular to the δ direction.

[0015] The nonaqueous electrolyte secondary battery of the present disclosure may be used as a power source for any electrical device, for example, as a driving power source for portable electronic devices such as smartphones, tablet computers, notebook computers, portable music players, etc. Furthermore, among the components described below, components that are not recited in the independent claims that represent the superordinate concept are optional components and are not essential components.

[0016] (First embodiment) Fig. 1 is a perspective view of a nonaqueous electrolyte secondary battery 1 according to a first embodiment of the present disclosure, and Fig. 2 is a front view of the nonaqueous electrolyte secondary battery 1. As shown in Fig. 1, the nonaqueous electrolyte secondary battery (hereinafter simply referred to as battery) 1 is a so-called laminated lithium-ion secondary battery, and includes a laminated film exterior body 5 formed by joining laminated film materials, a flat electrode assembly 10, a positive electrode tab 15, a negative electrode tab 20, a positive electrode tab welding resin (a welding film for the positive electrode tab) 25, and a negative electrode tab welding resin (a welding film for the negative electrode tab) 30. The flat electrode assembly 10 is housed in the film exterior body 5.

[0017] The laminate sheet that constitutes the laminate film exterior body 5 is preferably produced by laminating a metal layer and a resin layer, and it is preferable that at least a resin layer for thermal welding is disposed on the inner surface side of the laminate film exterior body 5. Resin layers may be disposed on both sides of the metal layer, and an adhesive layer may be disposed between the metal layer and the resin layer.

[0018] Examples of the metal layer of the laminate sheet include aluminum and aluminum alloys. Examples of the resin layer of the laminate sheet include polyolefin resins such as polypropylene and polyethylene, polyamide resins such as nylon, and polyester resins such as polyethylene terephthalate. Examples of the adhesive layer include urethane resins and polyolefin resins. In order to improve the adhesion between the polyolefin resin and the metal layer, it is preferable to use a carboxylic acid-modified polyolefin resin to which a carboxyl group has been added as the polyolefin resin of the adhesive layer.

[0019] The laminate sheet has a cup-shaped electrode assembly receiving portion 59 (see FIG. 3b). The flat electrode assembly 10 is produced using a long positive electrode 40 (see FIG. 4a), a long negative electrode 50 (see FIG. 4b), and two long separators 60 (see FIG. 4a). In detail, the flat electrode assembly 10 is produced, for example, by winding the long positive electrode 40 and the long negative electrode 50 with the long separator 60 interposed therebetween to produce a wound electrode assembly, and then press-molding the wound electrode assembly into a flat shape. A positive electrode tab 15 is joined and electrically connected to the positive electrode 40 by spot welding or the like, and a negative electrode tab 20 is joined and electrically connected to the negative electrode 50 by spot welding or the like.

[0020] The positive electrode tab 15 is led out to the outside of the battery via a heat-sealed portion 16 of the laminate film exterior body 5, and the negative electrode tab 20 is led out to the outside of the battery via a heat-sealed portion 21 of the laminate film exterior body 5. In the front view of FIG. 2 , the positive electrode tab 15 and the negative electrode tab 20 are spaced apart in the Y direction and extend approximately in the Z direction. As shown in FIGS. 1 and 2 , the positive electrode tab welding resin 25 includes a portion located between the positive electrode tab 15 and the heat-sealed portion 16, and the negative electrode tab welding resin 30 includes a portion located between the negative electrode tab 20 and the heat-sealed portion 21.

[0021] The battery 1 is fabricated, for example, as follows. First, a laminate sheet having a substantially rectangular shape in plan view is punched and deep-drawn using a punching die to form a substantially rectangular parallelepiped recess 6 as an electrode assembly housing portion in the upper longitudinal half of the laminate sheet, as shown in FIG. 3a. Then, as shown in FIG. 3b, the laminate sheet is folded in half longitudinally at approximately the center of the longitudinal direction, and the overlapped laminate sheets are shaped into a pouch by welding one side of the side seals provided on both Y-direction ends and one side of the top seal provided on one Z-direction end. The flat electrode assembly 10 is housed in the recess 6 before heat welding. After injecting nonaqueous electrolyte from the other end in the Y direction that is not heat-welded, the side seals are heat-welded to seal the interior of the laminate film exterior body 5.

[0022] In this embodiment, the recess 6 is formed so that its planar shape is approximately rectangular. The recess 6 has a main surface facing the opening and four side surfaces surrounding the main surface. As in this embodiment, a corner portion 7 having a curved cross section may be provided between adjacent side surfaces. In this disclosure, the outer surface of the laminate film exterior body 5 that corresponds to the bottom 8 of the recess 6 in the X direction and seals the recess 6 is defined as the back surface 9. The top seal portion is heat-sealed with the positive electrode tab 15 (see FIG. 1) and the negative electrode tab 20 interposed between the laminate sheets and the peripheries of the tabs 15 and 20 covered with welding resins 25 and 30 (see FIG. 1). The positive electrode tab welding resin 25 and the negative electrode tab welding resin 30 are provided to enhance the airtightness of the top seal portion. The positive electrode tab welding resin 25 and the negative electrode tab welding resin 30 may be made of any insulating resin material, such as modified polyolefin, polyester, or polyvinylidene fluoride.

[0023] Next, the structure of the flat electrode body 10 will be described in more detail. Fig. 4a is a schematic front view of a long positive electrode 40 before being wound, as viewed from one side in the thickness direction, and Fig. 4b is a schematic front view of a long negative electrode 50 before being wound, as viewed from one side in the thickness direction. Note that in Figs. 4a and 4b, the left ends of the positive electrode 40 and negative electrode 50 on the paper are the ends where the winding begins. Also, in Figs. 4a and 4b, the longitudinal lengths of the positive electrode 40 and negative electrode 50 are depicted as being significantly shorter than their actual lengths.

[0024] 4a, the positive electrode 40 has a long positive electrode core 41 and positive electrode mixture layers 42 partially and selectively provided on both sides of the positive electrode core 41 in the α direction. The positive electrode 40 has positive electrode uncoated portions 46, 47, 48 in the longitudinal direction where the positive electrode mixture layer is not applied, and the positive electrode core 41 is exposed over the entire area in the β direction. The positive electrode mixture layers 42 are present on both sides of each positive electrode uncoated portion 46, 47, 48 in the α direction.

[0025] The length of the first positive electrode non-coated portion 46 in the α direction is slightly longer than the length of the positive electrode tab 15 in the α direction, and the positive electrode tab 15 is joined by spot welding to the center of the first positive electrode non-coated portion 46 in the α direction. The first positive electrode non-coated portion 46 is a non-coated portion on both sides of the positive electrode core 41 where the positive electrode mixture layer is not coated. The two first positive electrode non-coated portions 46 are provided at approximately the same location in the α direction. The second positive electrode non-coated portion 47 is located on one side surface of the front side in FIG. 4a, spaced apart in the α direction from the first positive electrode non-coated portion 46. The third positive electrode non-coated portion 48 is located on one side surface of the back side in FIG. 4a, spaced apart in the α direction from the second positive electrode non-coated portion 47.

[0026] The α-direction length of each of the second and third positive electrode non-coated portions 47, 48 is equal to or greater than the γ-direction length of a negative electrode non-coated portion 56 described below, and is preferably longer than the γ-direction length. The δ-direction length of the negative electrode substrate 51 is longer than the β-direction length of the positive electrode substrate 41. Within the flat electrode body 10, all portions of the negative electrode non-coated portion 56 in the height direction (Z direction) other than both ends face the second positive electrode non-coated portion 47 in the thickness direction (thickness direction of the flat electrode body 10) and also face the third positive electrode non-coated portion 48 in the thickness direction. Note that the α-direction length of each of the second and third positive electrode non-coated portions 47, 48 may be shorter than the γ-direction length of the negative electrode non-coated portion 56.

[0027] The flat electrode body 10 is produced by press-molding a wound electrode body into a flat shape, so it tends to have a high density in the thickness direction. Therefore, if a positive electrode mixture layer that releases lithium ions is present in a position in the thickness direction opposite the negative electrode non-coated portion 56 where the negative electrode core 51 is exposed, it may react with the surrounding negative electrode, causing excessive lithium deposition on the negative electrode, and in the worst case, causing a short circuit. Therefore, in this embodiment, second and third positive electrode non-coated portions 47, 48 are provided in the positive electrode 40 in positions in the flat electrode body 10 opposite the negative electrode non-coated portion 56 in the thickness direction, thereby eliminating reaction areas between the positive and negative electrodes and reliably preventing short circuits and achieving high safety.

[0028] Insulating tape 43 is applied to the entire first to third positive electrode non-coated portions 46, 47, and 48, as well as to the α-direction ends of the positive electrode mixture layer 42, which face the negative electrode 50 through a separator within the flat electrode body 10. The insulating tape 43 is made of an insulating material such as polyimide. A step corresponding to the thickness of the positive electrode mixture layer 42 is formed at the boundary between the area where the positive electrode mixture layer 42 is present and the area where it is not. In such areas, if an external force is applied to the battery 1, for example, if the battery 1 is accidentally dropped, the positive electrode mixture may slip off, potentially causing a short circuit. The insulating tape 43 is applied to prevent such a short circuit. The α-direction length of the tape 43 applied to the positive electrode non-coated portions 47 and 48 is greater than the γ-direction length of the negative electrode non-coated portion 56.

[0029] The first to third positive electrode non-coated portions 46, 47, 48 are formed by intermittently coating both surfaces of the positive electrode core 41 with a positive electrode mixture, and the positive electrode 40 is fabricated as follows. Specifically, a conductive agent, a binder, etc. are mixed with a positive electrode active material, and the mixture is kneaded in a dispersion medium to prepare a paste-like positive electrode mixture slurry. The positive electrode mixture slurry is then applied to a hoop-shaped positive electrode core 41 formed from a metal foil such as aluminum. The applied positive electrode mixture slurry is then dried and compressed to form a positive electrode mixture layer 42 on the positive electrode core 41. Finally, the positive electrode core 41 with the positive electrode mixture layer 42 disposed thereon is cut to a predetermined size, thereby fabricating the positive electrode 40.

[0030] The intermittent application of the positive electrode mixture slurry can be performed, for example, as follows. Specifically, a long, hoop-shaped positive electrode substrate 41 is unwound by a drive roll (not shown) and transported at a constant speed to one side in the direction α below a discharge unit (for example, composed of a discharge nozzle) of a positive electrode mixture slurry discharge device. In this state, the positive electrode mixture slurry is intermittently discharged from the discharge unit toward the positive electrode substrate 41. After the positive electrode mixture slurry is discharged, the discharge of the positive electrode mixture slurry is temporarily stopped, and then the positive electrode mixture slurry is discharged again.

[0031] In this way, first and second positive electrode non-coated portions 46, 47, which are portions where the positive electrode mixture slurry is not applied, can be formed on one side surface of the positive electrode core 41 at the timing when the discharge of the positive electrode mixture slurry is temporarily stopped, and further, first and third positive electrode non-coated portions 46, 48, which are portions where the positive electrode mixture slurry is not applied, can be formed when the positive electrode mixture slurry is applied on the other side surface of the positive electrode core 41. The first positive electrode non-coated portion 46 is provided on both sides and has approximately the same length in the α direction.

[0032] As shown in FIG. 4b, the negative electrode 50 has a long negative electrode core 51 and a negative electrode mixture layer 52 partially and selectively provided on both sides of the negative electrode core 51 in the γ direction. The negative electrode 50 has a negative electrode uncoated portion 56 where the negative electrode mixture layer is not applied midway in the γ direction, and the negative electrode core 51 is exposed over the entire δ direction. The negative electrode mixture layer 52 is present on both sides of the negative electrode uncoated portion 56 in the γ direction. The γ-direction length of the negative electrode uncoated portion 56 is slightly longer than the γ-direction length of the negative electrode tab 20, and the negative electrode tab 20 is joined to the center of the γ-direction of the negative electrode uncoated portion 56 by spot welding. After the negative electrode tab 20 is joined, insulating tape 53 is applied to the entire negative electrode uncoated portion 56. The negative electrode uncoated portions 56 are provided on both sides. The two negative electrode uncoated portions 56 are provided at approximately the same location in the γ direction and have approximately the same γ-direction length.

[0033] The negative electrode 50 is fabricated, for example, as follows. A conductive agent, a thickener, etc. are mixed with the negative electrode active material, and the mixture is kneaded in a dispersion medium to prepare a paste-like negative electrode mixture slurry. The negative electrode mixture slurry is then intermittently applied to a hoop-shaped negative electrode core 51 formed from a metal foil such as copper. The intermittently applied negative electrode mixture slurry is then dried and compressed to form a negative electrode mixture layer on the negative electrode core. Finally, the negative electrode core with the negative electrode mixture layer disposed thereon is cut to a predetermined size to fabricate the negative electrode 50. The intermittent application of the negative electrode mixture slurry can be performed in the same manner as the intermittent application of the positive electrode mixture slurry. Note that in Figures 4a and 4b, the outer rectangular frame indicates the outer edge of the long separator 60. The width dimension of the elongated separator 60 is longer than the β-direction dimension of the elongated positive electrode core 41 and longer than the δ-direction dimension of the elongated negative electrode core 51, thereby reliably preventing short circuits.

[0034] Fig. 5 is a plan view of the flat electrode assembly 10 as viewed from one side in the Z direction. As shown in Fig. 5, the total thickness of the insulating tape 43 attached to the positive electrode tab 15, its welded portion, and the positive electrode non-coated portion 46 (non-coated on both sides) is approximately the same as the thickness of the positive electrode mixture layer 42. The total thickness of the insulating tape 53 attached to the negative electrode tab 20, its welded portion, and the negative electrode non-coated portion 56 is also approximately the same as the thickness of the negative electrode mixture layer 52. Furthermore, the total thickness of the insulating tape 43 on each of the positive electrode non-coated portions 47, 48 (non-coated on one side) facing the negative electrode tab 20 is approximately the same as the positive electrode mixture layer 42. The stacked thickness of each layer made up of the electrode assembly components is approximately the same at each location. As described above, the positive electrode non-coated portion 46 to which the positive electrode tab 15 is fixed is provided so that the positive electrode mixture layer 42 is present on both sides in the α direction, and the negative electrode non-coated portion 56 to which the negative electrode tab 20 is fixed is provided so that the negative electrode mixture layer 52 is present on both sides in the γ direction. That is, the positive electrode tab 15 is fixed not to an end portion of the positive electrode 40 in the longitudinal direction but midway through the positive electrode 40, and the negative electrode tab 20 is fixed not to an end portion of the negative electrode 50 in the longitudinal direction but midway through the negative electrode 50. The portions of the positive electrode 40 that face the negative electrode tab 20 include core exposed portions 83, 84 (positive electrode non-coated portions 47, 48) where the positive electrode core 41 is exposed.

[0035] As shown in FIG. 5 , the positive electrode tab 15 and the negative electrode tab 20 are located on the same side (the lower side of the paper in FIG. 5 ) of an imaginary plane Q that passes through the thickness center of the flat electrode assembly 10 and is substantially perpendicular to the thickness direction. It is sufficient that the positive electrode tab 15 and the negative electrode tab 20 are located on the same side of the imaginary plane Q. However, the current collection path can be shortened by moving the longitudinal fixing position of the positive electrode tab 15 closer to the longitudinal center of the positive electrode 40. The current collection path can also be shortened by moving the longitudinal fixing position of the negative electrode tab 20 closer to the longitudinal center of the negative electrode 50. Therefore, by moving the longitudinal fixing position of the positive electrode tab 15 closer to the longitudinal center of the positive electrode 40 or the longitudinal fixing position of the negative electrode tab 20 closer to the longitudinal center of the negative electrode 50, the internal resistance of the battery 1 can be reduced, resulting in effective effects such as reduced power loss. In particular, by moving the longitudinal fixing position of the positive electrode tab 15 closer to the longitudinal center of the positive electrode 40 and by moving the longitudinal fixing position of the negative electrode tab 20 closer to the longitudinal center of the negative electrode 50, the internal resistance of the battery 1 can be significantly reduced, and as a result, effective effects such as a significant reduction in power loss can be achieved.

[0036] Therefore, in one side region of the flat electrode body 10 relative to the imaginary plane Q, if the thickness dimension of the stacked area 19 where the positive electrode 40, negative electrode 50, and separator 60 are stacked in the thickness direction is t, then it is preferable that each of the positive electrode tab 15 and the negative electrode tab 20 be located from a position located more than t / 10 outward in the thickness direction from the innermost peripheral position 31 of the stacked area 19 to a position located more than t / 10 inward in the thickness direction from the outermost peripheral position 32 of the stacked area 19.

[0037] Furthermore, with respect to the thickness direction of the flat electrode body 10, each of the positive electrode tab 15 and the negative electrode tab 20 preferably extends from a position located at least t / 7 outward from the innermost peripheral position 31 to a position located at least t / 7 inward from the outermost peripheral position 32, and more preferably extends from a position located at least t / 5 outward from the innermost peripheral position 31 to a position located at least t / 5 inward from the outermost peripheral position 32. Furthermore, each of the positive electrode tab 15 and the negative electrode tab 20 most preferably extends from a position located at least t / 3 outward from the innermost peripheral position 31 to a position located at least t / 3 inward from the outermost peripheral position 32.

[0038] 6 is a schematic partial cross-sectional view of the battery 1 taken along a plane that passes through the negative electrode tab 20 and includes the X and Z directions. The bending structure of the tip end of the negative electrode tab 20 will be described below using FIG. 6 and other figures. The positive electrode tab 15 has a bending structure on its tip end similar to that of the negative electrode tab 20. The bending structure on the tip end of the positive electrode tab 15 will not be described here, as the bending structure on the tip end of the negative electrode tab 20 has already been described.

[0039] 6, the negative electrode tab 20 extends in the Z direction from the X-direction central portion of a region of the flat electrode body 10 that is closer to the back surface 9 of the laminate film exterior body 5 than the X-direction center to a peripheral position of one Z-direction end of the separator 60. The negative electrode tab 20 then bends at an angle close to a right angle from the peripheral position of one Z-direction end of the separator 60 toward the back surface 9 in a direction including the X direction, extends in that direction to near the back surface portion 5a of the laminate film exterior body 5, and then bends in a direction approximately parallel to the Z direction, extending to the outside of the battery 1 while following the back surface portion 5a.

[0040] 7 is a schematic cross-sectional view of a tab forming device 80 that forms the negative electrode tab 20 into such a shape. The tab forming device 80 includes a bending jig 81, a receiving jig 82, and an actuator (not shown). The bending jig 81 and the receiving jig 82 have planar forming surfaces 81a and 82a that are substantially parallel to each other. The receiving jig 82 further has a flat protrusion 82b that protrudes from the forming surface 82a in the normal direction indicated by arrow A, and the actuator includes a motor and linearly moves the bending jig 81 relative to the receiving jig 82 in the normal direction. One side surface 86 of the flat protrusion 82b is substantially parallel to the other side surface 89 of the bending jig 81. At the position where a portion of the negative electrode tab 20 is clamped between the forming surface 81a of the bending jig 81 and the forming surface 82a of the receiving jig 82, one side surface 86 of the protrusion 82b faces the other side surface 89 of the bending jig 81 via a small gap approximately the thickness of the negative electrode tab 20.

[0041] 7 , separator 60 has a protrusion 60a that protrudes outward in the Z direction beyond the Z-direction tip of negative electrode 50, which is located on the outer side in the Z direction, of positive electrode 40 and negative electrode 50. With the height direction tip of protrusion group 65a included in separator group 65 in contact with the other side surface 87 of protrusion 82b without bending, the actuator is driven to bring bending jig 81 close to receiving jig 82, and part of the negative electrode tab 20 is sandwiched between shaping surface 81a of bending jig 81 and shaping surface 82a of receiving jig 82, thereby shaping the portion of negative electrode tab 20 located on the outer side in the height direction beyond protrusion 60a.

[0042] In the battery 1 of this embodiment, the negative electrode tab 20 is fixed not to the longitudinal end of the negative electrode 50 but to the middle of the negative electrode 50 in the γ direction, with the negative electrode mixture layer 52 present on both sides in the γ direction. Therefore, the presence of the negative electrode mixture layer 52 around the negative electrode tab 20 increases the rigidity around the negative electrode tab 20. This stabilizes the starting point of bending. Furthermore, by providing the protrusion 82b on the receiving jig 82, the negative electrode tab 20 can be bent at a substantially right angle on the Z-direction outer side of the protrusion 60a of the separator 60. Furthermore, because the negative electrode tab 20 is fixed to the middle of the negative electrode 50 in the γ direction, the negative electrode tab 20 protrudes in the Z direction from a portion closer to the back surface 9 of the laminate film exterior body 5 than the center of the flat electrode body in the X direction. This means that the negative electrode tab 20 is bent at a portion closer to the back surface 9, thereby shortening the distance of the bent portion from the negative electrode tab 20 to the back surface 5a.

[0043] Therefore, the height of the protrusion 82b can be reduced, allowing the negative electrode tab 20 to be bent with high precision, and the negative electrode tab 20 to be positioned with high precision after bending. This not only allows the bent shape of the negative electrode tab 20 to be stabilized at a substantially right angle, but also reduces variation in the position of the sealing portion (welding resin 30) fixed to the negative electrode tab 20, allowing the sealing portion to be welded in a predetermined position. Furthermore, since the negative electrode tab 20 can be positioned with high precision after bending, interference of the negative electrode tab 20 with the protrusion 60a of the separator 60 can be substantially prevented, and deformation of the separator 60 due to contact with the negative electrode tab 20 can also be substantially prevented. As a result, short circuits can be reliably prevented, significantly improving safety.

[0044] Next, the remarkable effects of the battery 1 of the present disclosure will be described in detail by comparing it with a reference example battery 101 having a conventional structure. FIGS. 8a and 8b are explanatory views corresponding to FIGS. 3a and 3b of the laminate film exterior body 105 of the reference example battery 101. FIG. 9a is a schematic front view corresponding to FIG. 4a of the positive electrode 140 of the reference example battery 101, and FIG. 9b is a schematic front view corresponding to FIG. 4b of the negative electrode 150 of the reference example battery 101. FIG. 10 is a plan view corresponding to FIG. 5 of the flat electrode body 110 of the reference example battery 101. In FIGS. 9a and 9b, reference numeral 160 denotes a separator.

[0045] As shown in Figure 8a, the battery 101 of the reference example differs from the battery 1 of the present disclosure in that it uses a film exterior body 105 in which, when the folding line 157 of a laminate sheet that is approximately rectangular in plan view is taken as the boundary, two approximately rectangular parallelepiped-shaped recesses 106 each having a depth approximately half that of the recess 6 (see Figure 3a) are formed on both sides of the folding line 157 by punching it with a punching die, and then folding it back at the folding line 157 to form a cup-shaped electrode body accommodating section 159. 9a and 9b, the battery 101 of the reference example differs from the battery 1 of the present disclosure in that a positive electrode non-coated portion 146 of the positive electrode mixture is provided at the end of the positive electrode core 141 on the winding start side, and a positive electrode tab 115 is fixed to the positive electrode non-coated portion 146, and a negative electrode non-coated portion 156 of the negative electrode mixture is provided at the end of the negative electrode core 151 on the winding start side, and a negative electrode tab 120 is fixed to the negative electrode non-coated portion 156.

[0046] As shown in FIG. 8a, in the battery 101 of the reference example, recesses 106 are formed on both sides of the fold line 157, so the recesses 106 must be formed at locations spaced apart in the Z direction from the fold line 157. This inevitably results in flat portions 188 around the fold line 157, which make it difficult to increase the volume of the electrode assembly accommodating section 159, making it difficult to accommodate a large-capacity flat electrode assembly in the laminate film exterior body 105. In contrast, as shown in FIG. 3a, in the battery 1 of the present disclosure, recesses 6 are formed only on one side of the fold line 57, so the outer edge of recess 6 can be aligned with the fold line 57. Therefore, compared to the battery 101 of the reference example, the flat portions 188 can be eliminated, and the volume of the electrode assembly accommodating section 59 that accommodates the flat electrode assembly 10 can be increased, resulting in a significantly increased capacity of the battery 1.

[0047] 4a and 4b, the positive electrode 40 and negative electrode 50 of the present disclosure have intermittent layers in areas other than the widthwise ends of the regions where the mixture layers 42 and 52 are formed, and tabs 15 and 20 are attached thereto. Therefore, compared with the positive electrode 140 and negative electrode 150 of the reference example shown in FIGS. 9a and 9b, the end of the positive electrode substrate 141 on the winding start side can be eliminated in the positive electrode 140, and the γ-direction length of the negative electrode substrate 151 on the winding start side can be shortened in the negative electrode 150. As a result, the lengths of the positive electrode mixture layer 42 and the negative electrode mixture layer 52 can be increased overall, and the capacity can be increased.

[0048] More specifically, as shown in Fig. 10, in the battery 101 of the reference example, positive and negative electrode substrate exposed portions 148, 158 where no mixture layer is present are present at the innermost periphery of the flat electrode body 110. In contrast, in the flat electrode body 10 of the present disclosure shown in Fig. 5, the innermost positive and negative electrode substrate exposed portions 148, 158 can be removed, and the mixture layers 42, 52 can be increased by the volume created by this removal. This allows the mixture layers 42, 52 to be increased by approximately one layer, making it possible to increase capacity.

[0049] Therefore, the battery 1 of the present disclosure can have a capacity significantly greater than that of the battery 101 of the reference example due to the synergistic effect of adopting a laminate film exterior body 5 that does not have a flat portion 188, adopting a positive electrode 40 in which an intermittent layer is partially provided in the positive electrode mixture layer 42, and adopting a negative electrode 50 in which an intermittent layer is partially provided in the negative electrode mixture layer 52.

[0050] More specifically, in the case of the battery 101 of the reference example, as shown in FIG. 10 , the tabs 115 and 120 protrude from near the center in the thickness direction of the flat electrode body 110. Therefore, as shown in FIG. 11 , i.e., a schematic partial cross-sectional view of the battery 101 of the reference example corresponding to FIG. 6 , the Z-direction distance from the protruding position of the negative electrode tab 120 in the Z direction to the back surface portion 105a of the laminate film exterior body 105 is long. Furthermore, the periphery of the negative electrode tab 120 becomes a negative electrode core exposed portion 158 (see FIG. 10 ) where the negative electrode mixture layer 152 is not present, and the rigidity around the negative electrode tab 120 is low. Therefore, as shown in FIG. 12 , i.e., a schematic cross-sectional view of a tab forming device 180 that forms the negative electrode tab 120 of the battery 101 of the reference example, the formed length at the tip end side of the negative electrode tab 120 is long, and the starting point of bending becomes unstable, making it difficult to precisely bend the negative electrode tab 120.

[0051] Therefore, as the distance to the sealing portion of the negative electrode tab 120 increases and the shape of the negative electrode tab 120 tends to become unstable, the position of the welding resin tends to vary, increasing the possibility that the welding resins 125, 130 will be positioned outside the sealing portion, resulting in poor sealing, as shown in Fig. 13a, or that the welding resins 135, 130 will be positioned outside the sealing portion, resulting in poor sealing, as shown in Fig. 13b. Furthermore, because the shape of the negative electrode tab 120 becomes unstable, there is a risk that the negative electrode tab 120 will interfere with the separator group 165, deforming a tip 169 of the separator group 165, as shown in Fig. 11, which could reduce safety.

[0052] In contrast, in the battery 1 of the present disclosure, the tabs 15, 20 are attached at high-rigidity positions midway along the electrode plates, which shortens the distance from the tabs 15, 20 to the sealing portion, and allows the base of the protruding portion 60a of the separator 60 at the tabs 15, 20 to be bent at a substantially right angle. This reduces variation in the location of the welding resins 25, 30, resulting in a highly reliable battery 1. It also substantially prevents deformation of the tip 69 of the separator 60 due to contact with the tabs 15, 20, resulting in a highly safe battery 1.

[0053] To put it more simply, if the film exterior shown in Figure 3a, that is, a film exterior in which a recess is formed on only one side of the fold line and the flat section is eliminated, is used in order to increase capacity, the recess becomes deeper and the laminate film becomes stretched, so that when the tab is routed around the top, it may induce deformation of the top of the separator and may also cause variation in the length from the tab attachment section to the sealing position.

[0054] However, in the battery 1 of the present disclosure, the tabs 15, 20 are attached at positions midway along the electrode plates where the rigidity is high, eliminating such a possibility, suppressing variations in the positions of the welding resins 25, 30, and fabricating a highly reliable battery 1. Deformation of the tip 69 of the separator 60 is also substantially prevented, resulting in a highly safe battery 1. Therefore, the advantageous effect of the present disclosure, which can achieve both safety and sealing reliability, is particularly pronounced.

[0055] Furthermore, when the tabs 115, 120 are fixed to the end of the core body at the winding start side without forming a mixture layer at that end, as in the battery 101 of the reference example, when the flat electrode body 110 is formed to a certain thickness, the tabs 115, 120 and the areas where the insulating tape is attached are compressed by that thickness more than other areas. Therefore, local distortion occurs after long-term cycling, which may cause battery swelling and capacity degradation.

[0056] In contrast, in the battery 1 of the present disclosure, the total thickness of the tabs 15, 20, their welded portions, and the insulating tapes 43, 53 attached to the intermittently applied portions is approximately the same as the thickness of the mixture layers 42, 52, so distortion is less likely to occur after long-term charge-discharge cycles. Therefore, the battery 1 of the present disclosure can easily achieve a high capacity retention rate and achieve high reliability.

[0057] Placing the positive electrode tab at the end of the positive electrode winding or the negative electrode tab at the end of the negative electrode winding is effective in suppressing separator deformation and improving the variation in sealing position, but as with placing the positive electrode tab at the end of the positive electrode winding or the negative electrode tab at the end of the negative electrode winding, a large core body exposed portion is required, which results in capacity loss and significant transfer of the tab portion to the film exterior, which is undesirable.

[0058] [Tests to verify the effects of the battery of the present invention and the test results] The inventors fabricated 200 laminated batteries of the Example and 200 laminated batteries of the Reference Example (conventional structure). The Example batteries had the same configuration as Battery 1 described above, while the Reference Example batteries differed from Battery 101 described above only in that the laminated film exterior was replaced by the laminated film exterior 5 shown in FIG. 3B instead of the laminated film exterior 105 shown in FIG. 8B. Each Example battery was fabricated to have a 4.4 V voltage, a thickness of 4.9 mm, a width of 56 mm, a height of 69 mm, and a rated capacity of 3100 mAh. The Reference Example battery was fabricated to have a 4.4 V voltage, a thickness of 4.9 mm, a width of 56 mm, a height of 69 mm, and a rated capacity of 3040 mAh. The difference in rated capacity between the Example and the Reference Example is due to differences in the design of the electrode plate coating length and thickness resulting from differences in the tab attachment locations.

[0059] <Plates and winding> The positive and negative electrodes were coated using the conventional method. In the Example, the position of the intermittent portion was changed from that of the Reference Example, and the mixture slurry was coated to the specified thickness and dimensions. After that, in both the Example and Reference Example, a tab with adhesive resin and the necessary insulating tape were attached, and after cutting to the specified length, the separator was sandwiched between them and the product was wound up.

[0060] <Assembly, injection, and sealing defect check> In both the Examples and the Reference Example, a flat electrode body was inserted into a single-cup-shaped laminate (a laminate with only one recess before folding) preformed to a predetermined size, and the laminate was folded at the bottom of the cup to encase the flat electrode body. At this time, the tab extending from the top of the electrode body was folded back toward the back of the laminate in the thickness direction using a jig, and the sealing portion was sandwiched so that the welding resin (welding film) attached to the tab overlapped the overlapping portion of the upper part of the laminate. The top was then sealed by heating to a predetermined temperature and holding. One side was also sealed by heating and holding the laminate overlapping portion. At this point, the number of batteries with sealing defects among the 200 batteries was counted for both the Examples and the Reference Example. Subsequently, for batteries without sealing defects, a predetermined amount of electrolyte was injected from the unsealed side in a dry environment, and the side on the injection side was also sealed by heating and holding. After the electrolyte penetrated, the battery was subjected to predetermined charge and discharge cycles to complete the battery.

[0061] <Initial capacity test> In both the Example and the Reference Example, 30 batteries were charged and discharged for one cycle at the rated voltage and current (Example 3100 mA, Reference Example 3040 mA), and the discharge capacity at that time was defined as the initial capacity and measured.

[0062] <Shipping charge thickness, internal resistance test> After measuring the initial capacity, both the Example and Reference Examples were charged at the rated current for 18 minutes to charge the batteries to 30%. After leaving them for 1 hour, the thickness at the maximum part was measured, and the internal resistance was measured.

[0063] <Cycle test at room temperature> A charge-discharge cycle test was carried out on five of the 30 batteries in both the Example and the Reference Example. The test was repeated 500 times under the following conditions: current 100 mA in the Example and 040 mA in the Reference Example, voltage 4.4 V (charge) and 3.0 V (discharge), at room temperature, and the capacity and thickness after 500 cycles were measured.

[0064] <External short circuit test> In both the Example and the Reference Example, five of the 30 batteries were fully charged, placed in a thermostatic chamber at 55° C., and subjected to an external short-circuit test in which they were short-circuited by connecting to an external resistance of 30 mΩ.

[0065] <Thermal test> In both the example and the reference example, 5 of the 30 batteries were fully charged and placed in a thermostatic chamber at 150° C. to carry out a thermal test.

[0066] [Test Results] The results of the above test were as shown in Table 1 below. [Table 1]

[0067] As shown in Table 1, with regard to defects in the upper sealing, three sealing defects occurred out of 200 pieces in the Reference Example, while no sealing defects occurred in the Example. The sealing defects in the Reference Example occurred because the distance from the tab position to the back surface was long, and the tab bending angle and other manufacturing variations combined to make it impossible to place the welding resin in the specified position. On the other hand, in the Example, the distance from the tab position to the back surface was short, and there was little variation in the tab bending, so no sealing defects occurred. Therefore, compared to the Reference Example, it was confirmed that the Example could achieve high-precision positioning of the tab and could achieve high reliability.

[0068] Regarding the initial capacity, the average of 30 batteries in the Example was 3175mAh, while the average of 30 batteries in the Reference Example was 3100mAh. In the Example, by changing the joining position of the tab, the coating area of ​​the mixture on the electrode plate can be increased, so the rated capacity was increased by 60mAh compared to the Reference Example, and the actual measured values ​​also showed the same trend, realizing a large increase in capacity.

[0069] Regarding the shipping charge thickness, the average for 30 batteries in the Example was 4.62 mm, while the average for 30 batteries in the Reference Example was 4.69 mm. Because the stacked thickness of the tab section (coating thickness, core thickness, tab thickness, tape thickness, and laminate thickness) was smaller in the Example, the battery thickness was also smaller. Regarding internal resistance, the average for 30 batteries in the Example was 15.3 mΩ, while the average for 30 batteries in the Reference Example was 32.7 mΩ. In the Example, the tab fixing point is located near the center of the electrode plate in the longitudinal direction, allowing for efficient current collection in the longitudinal direction. This reduces internal resistance by half compared to the Reference Example, resulting in a significant reduction in power loss.

[0070] In the room temperature cycle test, the average capacity retention rate of the Examples was 89%, while that of the Reference Example was 86%, lower than 89%. Furthermore, the average thickness of the Examples was 5.13 mm, while that of the Reference Example was 5.24 mm. Because the tab portion was less compressed in the Examples, the overall structure was less susceptible to distortion even when the flat electrode body repeatedly expanded and contracted during charging and discharging, reducing capacity degradation and reducing thickness.

[0071] In the external short circuit test, three out of five Reference Examples caught fire, while none of the Examples caught fire. Therefore, it was confirmed that the Examples were less likely to catch fire even when short-circuited under extremely harsh conditions, and were therefore highly safe. It is believed that the Reference Examples generated a large amount of heat after a short circuit, leading to internal combustion, while the Examples had low internal resistance, which prevented heat generation during a short circuit and prevented them from catching fire.

[0072] In the thermal test, two out of five Reference Examples caught fire, while none of the Examples caught fire. This confirmed that the Reference Examples were susceptible to short circuits and internal combustion due to the separator being deformed and shrinking quickly due to the influence of the bent tab, whereas the Examples did not have the separator around the tab deformed, which extended the time until a short circuit occurred and prevented fire even when exposed to extremely harsh conditions.

[0073] In comparison with the Reference Example, the Examples had no sealing defects and improved sealing reliability. Furthermore, in comparison with the Reference Example, the Examples were able to increase capacity, reduce the initial thickness and the thickness after charge-discharge cycling, and improve the capacity retention rate. Furthermore, in comparison with the Reference Example, the Examples were able to reduce internal resistance, significantly improve safety during external short circuits, suppress deformation of the separator tip, and significantly improve safety in high-temperature environments.

[0074] [Configuration of the battery of the present disclosure and its effects] As described above, the battery 1 of the present disclosure includes a laminate film exterior body 5 formed by joining laminate film materials, and a flat electrode body 10 housed within the laminate film exterior body 5 and formed by winding a long positive electrode 40 and a long negative electrode 50, which are opposed to each other with a long separator 60 interposed therebetween, into a flat shape. The positive electrode 40 includes a long positive electrode core 41 and a positive electrode mixture layer 42 provided on the positive electrode core 41, and has a positive electrode non-coated portion 46 midway along its length where the positive electrode mixture layer 42 is not present and the positive electrode core 41 is exposed. The negative electrode 50 includes a long negative electrode core 51 and a negative electrode mixture layer 52 provided on the negative electrode core 51, and has a negative electrode non-coated portion 56 midway along its length where the negative electrode mixture layer 52 is not present and the negative electrode core 51 is exposed. The battery 1 further includes a positive electrode tab 15 joined and electrically connected to the positive electrode non-coated portion 46, and a negative electrode tab 20 joined and electrically connected to the negative electrode non-coated portion 56. The positive electrode tab 15 and the negative electrode tab 20 are located on the same side of an imaginary plane Q that passes substantially through the center of the flat electrode body 10 in the thickness direction and is substantially perpendicular to the thickness direction.

[0075] According to the present disclosure, precise positioning of the tabs 15 and 20 can be achieved, significantly reducing sealing defects and improving sealing reliability. Furthermore, the positive electrode tab 15 is fixed to the positive electrode non-coated portion 46 provided in the center of the positive electrode 40 so that the positive electrode mixture layer 42 is present on both longitudinal sides of the positive electrode 40. This eliminates or reduces the exposed core portion at the end of the positive electrode 40 near the start of winding. Similarly, the negative electrode tab 20 is fixed to the negative electrode non-coated portion 56 provided in the center of the negative electrode 50 so that the negative electrode mixture layer 52 is present on both longitudinal sides of the negative electrode 50. This eliminates or reduces the exposed core portion at the end of the negative electrode 50 near the start of winding. This significantly increases the capacity of the battery 1. Furthermore, precise positioning of the tabs 15 and 20 can reduce the distance between the tabs 15 and 20 and the back surface 9 of the laminate film exterior body 5, substantially preventing interference between the tabs 15 and 20 and the separator 60. Therefore, deformation of the tip 69 of the separator 60 can be suppressed, short circuit prevention can be reliably achieved, and safety can be significantly improved.

[0076] [Preferable battery configuration and its effects] The positive electrode tab 15 may have a thickness less than that of the positive electrode mixture layer 42 , and the negative electrode tab 20 may have a thickness less than that of the negative electrode mixture layer 52 .

[0077] According to this configuration, the total thickness of the insulating tapes 43, 53 attached to the tabs 15, 20, their welded portions, and the intermittently applied portions can be easily adjusted to be substantially the same as the thickness of the mixture layers 42, 52. Therefore, distortion is less likely to occur after long-term charge / discharge cycles, a high capacity retention rate is easily achieved, and high reliability is easily obtained.

[0078] The laminate film exterior housing 5 may also have a first portion 91 (see FIG. 3a) having a recess 6 that accommodates the flat electrode body 10, a second portion 92 (see FIG. 3a) that is folded back at one heightwise end (fold line) 57 of the first portion 91 and does not have a recess, and welded portions that are provided on both sides of the recess 6 and at the other heightwise end to seal the laminate film exterior housing 5. The positive electrode tab 15 and the negative electrode tab 20 may be sandwiched between the first portion 91 and the second portion 92 at the other end when the laminate film exterior housing 5 is sealed. The positive electrode tab 15 and the negative electrode tab 20 may each protrude from the recess 6 from the back surface portion 5a of the laminate film exterior housing 5 while being approximately parallel to the back surface portion 5a.

[0079] This configuration prevents the occurrence of flat portions 188 around the folded portion of the laminate film exterior body 5, and increases the volume of the electrode body accommodating section 59. Therefore, a large-volume flat electrode body 10 can be accommodated in the electrode body accommodating section 59, and the capacity of the battery 1 can be significantly increased.

[0080] The present disclosure is not limited to the first embodiment and its modifications, and various improvements and modifications are possible within the scope of the claims of the present application and their equivalents.

[0081] For example, in the first embodiment described above, the battery 1 had a laminate film exterior body 5 having a recess 6 on only one side of the fold line 57 before folding, but the battery of the present disclosure may have a laminate film exterior body 105 having a recess 106 on both sides of the fold line 157 before folding.

[0082] In the battery of the present disclosure, the positive electrode tab may have a thickness equal to or greater than the thickness of the positive electrode mixture layer, and the negative electrode tab may have a thickness equal to or greater than the thickness of the negative electrode mixture layer.

[0083] Furthermore, in the battery 1 of the present disclosure, the negative electrode mixture layer 52 is present in the portion of the negative electrode 50 that faces, in the thickness direction, the positive electrode non-coated portion 46 to which the positive electrode tab 15 is joined in the flat electrode body 10. However, a negative electrode non-coated portion may be provided without providing a negative electrode mixture layer in the portion of the negative electrode that faces, in the thickness direction, the positive electrode non-coated portion to which the positive electrode tab is joined in the flat electrode body, thereby reducing the material cost of the negative electrode mixture layer.

[0084] (Second embodiment) In the first embodiment, the positive electrode includes a long positive electrode core and a positive electrode mixture layer provided on the positive electrode core, and has a positive electrode non-coated portion where the positive electrode core is exposed midway in the longitudinal direction, and the negative electrode includes a long negative electrode core and a negative electrode mixture layer provided on the negative electrode core, and has a negative electrode non-coated portion where the negative electrode core is exposed midway in the longitudinal direction. The positive electrode tab is joined to the positive electrode non-coated portion, and the negative electrode tab is joined to the negative electrode non-coated portion, and the positive electrode tab and the negative electrode tab are located on the same side of an imaginary plane that passes substantially through the center of the flat electrode body in the thickness direction and is substantially perpendicular to the thickness direction of the flat electrode body.

[0085] However, if the positive electrode has a positive electrode non-coated portion in the middle of its longitudinal direction where the positive electrode core is exposed, and the positive electrode tab is joined to the positive electrode non-coated portion, then by devising the joining position of the negative electrode tab as described below, the positive electrode tab can be positioned with high precision, and the negative electrode tab can also be positioned with precision at least as high as in the prior art. Thus, compared to the prior art, the advantageous effect of being able to position the positive electrode tab with high precision can be obtained.

[0086] Furthermore, when the positive electrode tab and the negative electrode tab are located on the same side of an imaginary plane that passes substantially through the center in the thickness direction of the flat electrode body and is substantially perpendicular to the thickness direction of the flat electrode body, if the negative electrode tab is joined to the outermost longitudinal portion of the negative electrode core, significant effects associated with this configuration can be obtained, as will be explained below. Also, when the negative electrode tab is joined to the innermost longitudinal portion of the negative electrode core, significant effects associated with this configuration can be obtained, as will be explained below.

[0087] In the second embodiment, a positive electrode has a positive electrode non-coated portion in the middle of its length where the positive electrode core is exposed, and a positive electrode tab is joined to the positive electrode non-coated portion, where the positive electrode tab and the negative electrode tab are located on the same side of an imaginary plane that passes approximately through the center of the flat electrode body in the thickness direction and is approximately perpendicular to the thickness direction of the flat electrode body, and further, the negative electrode tab is joined to the outermost longitudinal portion of the negative electrode core.In addition, in the third embodiment, a positive electrode has a positive electrode non-coated portion in the middle of its length where the positive electrode core is exposed, and a positive electrode tab is joined to the positive electrode non-coated portion, and a negative electrode tab is joined to the innermost longitudinal portion of the negative electrode core.

[0088] Fig. 14a is a schematic front view of a long positive electrode 240 before being wound in a nonaqueous electrolyte secondary battery 201 of the second embodiment, as viewed from one side in the thickness direction (the radially outer side of the flat electrode body 210 (see Fig. 15)). Fig. 14b is a schematic front view of the long positive electrode 240 before being wound, as viewed from the other side in the thickness direction (the radially inner side of the flat electrode body 210). Fig. 14c is a schematic front view of a long negative electrode 250 before being wound in a nonaqueous electrolyte secondary battery 201, as viewed from one side in the thickness direction (the radially outer side of the flat electrode body 210). Fig. 14d is a schematic front view of the long negative electrode 250 before being wound, as viewed from the other side in the thickness direction (the radially inner side of the flat electrode body 210).

[0089] Like the nonaqueous electrolyte secondary battery 1 of the first embodiment, the nonaqueous electrolyte secondary battery 201 of the second embodiment has the appearance shown in FIGS. 1 and 2 and can be fabricated using the exterior package described with reference to FIGS. 3a and 3b, or can be fabricated using the exterior package described with reference to FIGS. 8a and 8b. In FIGS. 14a, 14b, 14c, and 14d, the longitudinal lengths of the positive electrode 240 and the negative electrode 250 are depicted as being significantly shorter than their actual lengths. In the second to fourth embodiments, as in the first embodiment, the α direction indicates the longitudinal direction of the elongated positive electrodes 240, 340, and 440, and the arrows in the α direction point from the winding start side to the winding end side. The β direction indicates the width direction (short direction) of the elongated positive electrodes 240, 340, and 440. The γ direction indicates the longitudinal direction of the elongated negative electrodes 250, 350, and 450, and the arrows in the γ direction point from the winding start side to the winding end side. The δ direction indicates the width direction (short direction) of the long negative electrodes 250, 350, and 450. The α direction is perpendicular to the β direction, and the γ direction is perpendicular to the δ direction.

[0090] 14a and 14b, the positive electrode 240 has a long positive electrode core 241 and positive electrode mixture layers 242 partially and selectively provided on both sides of the positive electrode core 241 in the α direction. The positive electrode 240 has positive electrode uncoated portions 246, 247, and 248 in the longitudinal direction where the positive electrode mixture layer is not applied, and the positive electrode core 241 is exposed over the entire area in the β direction. The positive electrode mixture layers 242 are present on both sides of each positive electrode uncoated portion 246, 247, and 248 in the α direction.

[0091] The length of the first positive electrode non-coated portion 246 in the α direction is slightly longer than the length of the positive electrode tab 215 in the α direction, and the positive electrode tab 215 is joined by spot welding to the center of the first positive electrode non-coated portion 246 in the α direction. The first positive electrode non-coated portion 246 is a non-coated portion on both sides of the positive electrode core 241 where the positive electrode mixture layer is not coated. The two first positive electrode non-coated portions 246 are provided at approximately the same location in the α direction. The second positive electrode non-coated portion 247 is present on the side surface facing outward in the radial direction as shown in FIG. 14a, spaced apart in the α direction from the first positive electrode non-coated portion 246. The third positive electrode non-coated portion 248 is present on the side surface facing inward in the radial direction as shown in FIG. 14b, spaced apart in the α direction from the second positive electrode non-coated portion 247. The second and third positive electrode non-coated portions 247, 248 are located closer to the winding end side in the α direction than the first positive electrode non-coated portion 246.

[0092] The α-direction length of each of the second and third positive electrode non-coated portions 247, 248 is equal to or greater than the γ-direction length of a negative electrode non-coated portion 256 (see FIGS. 14c and 14d) described below, and is preferably longer than the γ-direction length. The δ-direction length of the negative electrode substrate 251 is longer than the β-direction length of the positive electrode substrate 241. Within the flat electrode body 210, all portions of the negative electrode non-coated portion 256 in the height direction (Z direction) except for both ends face the second positive electrode non-coated portion 247 in the thickness direction (thickness direction of the flat electrode body 210) and also face the third positive electrode non-coated portion 248 in the thickness direction. Note that the α-direction length of each of the second and third positive electrode non-coated portions 247, 248 may be shorter than the γ-direction length of the negative electrode non-coated portion 256.

[0093] The flat electrode body 210 is produced by press-molding a wound electrode body into a flat shape, and therefore tends to have a high density in the thickness direction. Therefore, if a positive electrode mixture layer that releases lithium ions is present in a position in the thickness direction opposite the negative electrode non-coated portion 256 where the negative electrode substrate 251 is exposed, it may react with the surrounding negative electrode, causing excessive lithium deposition on the negative electrode, and in the worst case, causing a short circuit. Therefore, in this embodiment, second and third positive electrode non-coated portions 247, 248 are provided in the positive electrode 240 in positions in the flat electrode body 210 opposite the negative electrode non-coated portion 256 in the thickness direction, thereby eliminating reaction areas between the positive and negative electrodes and reliably preventing short circuits and achieving high safety.

[0094] Insulating tape 243 is applied to the entire first to third positive electrode non-coated portions 246, 247, and 248, as well as to the α-direction ends of the positive electrode mixture layer 242, which face the negative electrode 250 via a separator within the flat electrode body 210. The insulating tape 243 is made of an insulating material such as polyimide. A step corresponding to the thickness of the positive electrode mixture layer 242 is formed at the boundary between the area where the positive electrode mixture layer 242 is present and the area where it is not. In such areas, if an external force is applied to the battery 201, for example, if the battery 201 is accidentally dropped, the positive electrode mixture may slide off, potentially causing a short circuit. The insulating tape 243 is applied to prevent such a short circuit. The α-direction length of the tape 243 applied to the positive electrode non-coated portions 247 and 248 is greater than the γ-direction length of the negative electrode non-coated portion 256.

[0095] The material of the positive electrode core 241 is the same as the material of the positive electrode core 41 of the first embodiment, and the material of the positive electrode mixture layer 242 is the same as the material of the positive electrode mixture layer 42 of the first embodiment. The first to third positive electrode uncoated portions 246, 247, 248 are formed by intermittently applying the positive electrode mixture to both surfaces of the positive electrode core 241. The first to third positive electrode uncoated portions 246, 247, 248 can be produced by the same method as the first to third positive electrode uncoated portions 46, 47, 48 of the first embodiment.

[0096] As shown in Figures 14c and 14d, the negative electrode 250 includes a long negative electrode substrate 251 and a negative electrode mixture layer 252 partially and selectively provided on both sides of the negative electrode substrate 251 in the γ direction. The negative electrode 250 has a negative electrode non-coated portion 256 at the end of the winding in the γ direction where the negative electrode mixture layer is not applied, leaving the negative electrode substrate 251 exposed across the entire δ direction. The negative electrode non-coated portion 256 is located at the outermost periphery of the negative electrode 250. The negative electrode mixture layer 252 is located on both sides of the negative electrode non-coated portion 256 in the γ direction. The length of the negative electrode non-coated portion 256 in the γ direction is slightly longer than the length of the negative electrode tab 220 in the γ direction, and the negative electrode tab 220 is joined to the center of the negative electrode non-coated portion 256 in the γ direction by spot welding. After the negative electrode tab 220 is joined, insulating tape 253 is applied to the entire negative electrode non-coated portion 256. The negative electrode non-coated portions 256 are provided on both sides. The two negative electrode non-coated portions 256 are provided at approximately the same position in the γ direction and have approximately the same length in the γ direction.

[0097] The material of the negative electrode core 251 is the same as that of the negative electrode core 51 of the first embodiment, and the material of the negative electrode mixture layer 252 is the same as that of the negative electrode mixture layer 52 of the first embodiment. The negative electrode non-coated portion 256 is formed by intermittently coating both surfaces of the negative electrode core 251 with the negative electrode mixture. The negative electrode 250 and the negative electrode non-coated portion 256 can be produced by the same method as the negative electrode 50 and the negative electrode non-coated portion 56 of the first embodiment. Note that in FIGS. 14a, 14b, 14c, and 14d, the outer rectangular frame indicates the outer edge of the long separator 60. The width dimension of the long separator 60 is longer than the β-direction dimension of the long positive electrode core 241 and longer than the δ-direction dimension of the long negative electrode core 251, thereby reliably preventing short circuits.

[0098] FIG. 15 is a plan view of the flat electrode body 210 of the second embodiment as viewed from one side in the Z direction. Referring to FIGS. 14a, 14b, 14c, 14d and 15, the total thickness of the insulating tape 243 attached to the positive electrode tab 215, its welded portion, and the positive electrode non-coated portion 246 (non-coated on both sides) is approximately the same as the thickness of the positive electrode mixture layer 242. The total thickness of the insulating tape 243 attached to each of the positive electrode non-coated portions 247, 248 (non-coated on one side) facing the negative electrode tab 220 is approximately the same as the positive electrode mixture layer 242. The negative electrode non-coated portion 256 to which the negative electrode tab 220 is joined is located at the outermost peripheral portion of the negative electrode 250. The thickness of the negative electrode tab 220 is preferably thinner than the thickness of the negative electrode mixture layer 252. The portion of the positive electrode 240 facing the negative electrode tab 220 includes substrate exposed portions 280, 281 (positive electrode uncoated portions 247, 248) where the positive electrode substrate 241 is exposed.

[0099] 15, the positive electrode tab 215 and the negative electrode tab 220 are located on the same side of an imaginary plane Q' that passes through approximately the center of the thickness direction of the flat electrode body 210 and is approximately perpendicular to the thickness direction. The range in which the positive electrode tab 215 exists within the flat electrode body 210 can be the same range as the range in which the positive electrode tab 15 exists within the flat electrode body 10, which was explained using t in FIG.

[0100] According to the second embodiment, the positive electrode tab 215 and the negative electrode tab 220 are located on the same side of an imaginary plane Q′ that passes substantially through the center in the thickness direction of the flat electrode body 210 and is substantially perpendicular to the thickness direction of the flat electrode body 210, and further, the negative electrode tab 220 is joined to the outermost peripheral portion of the negative electrode core 251. Therefore, referring to FIG. 6 , the negative electrode tab 220 (not shown in FIG. 6 ) can extend further in the Z direction from the back surface 9 side than the negative electrode tab 20 of the first embodiment. Therefore, compared to the negative electrode tab 20, interference of the negative electrode tab 220 with the separator 60 can be further suppressed, and the negative electrode tab 220 can be positioned with even greater precision than the negative electrode tab 20 and the positive electrode tab 115. Furthermore, because the negative electrode tab 220 is joined to the outermost peripheral portion of the negative electrode core 251, it is possible to reduce the stress (distortion) that occurs in the flat electrode body 210 due to the joining of the negative electrode tab 220 compared to when the negative electrode tab 220 is joined to the center portion in the thickness direction of the flat electrode body 210. Therefore, it is possible to suppress deterioration of the flat electrode body 210 when the battery 201 is used continuously over a long period of time.

[0101] (Third embodiment) Fig. 16a is a schematic front view of a long positive electrode 340 before being wound in a nonaqueous electrolyte secondary battery 301 of the second embodiment, as viewed from one side in the thickness direction (the radially outer side of the flat electrode body 310 (see Fig. 17)). Fig. 16b is a schematic front view of the long positive electrode 340 before being wound, as viewed from the other side in the thickness direction (the radially inner side of the flat electrode body 310). Fig. 16c is a schematic front view of a long negative electrode 350 before being wound in a nonaqueous electrolyte secondary battery 301, as viewed from one side in the thickness direction (the radially outer side of the flat electrode body 310). Fig. 16d is a schematic front view of the long negative electrode 350 before being wound, as viewed from the other side in the thickness direction (the radially inner side of the flat electrode body 310).

[0102] 1 and 2, and can be fabricated using the exterior body described with reference to Figures 3a and 3b, or can be fabricated using the exterior body described with reference to Figures 8a and 8b. In Figures 16a, 16b, 16c, and 16d, the longitudinal lengths of the positive electrode 340 and the negative electrode 350 are depicted as being significantly shorter than their actual lengths.

[0103] 16a and 16b, the positive electrode 340 has a long positive electrode core 341 and positive electrode mixture layers 342 partially and selectively provided on both sides of the positive electrode core 341 in the α direction. The positive electrode 340 has positive electrode uncoated portions 346, 347 in the longitudinal direction where the positive electrode mixture layer is not applied, and the positive electrode core 341 is exposed over the entire area in the β direction. The positive electrode mixture layers 342 are present on both sides of each positive electrode uncoated portion 346, 347 in the α direction.

[0104] The length of the first positive electrode non-coated portion 346 in the α direction is slightly longer than the length of the positive electrode tab 315 in the α direction, and the positive electrode tab 315 is joined by spot welding to the center of the first positive electrode non-coated portion 346 in the α direction. The first positive electrode non-coated portion 346 is a non-coated portion on both sides of the positive electrode core 351 where the positive electrode mixture layer is not coated. The two first positive electrode non-coated portions 346 are provided at approximately the same location in the α direction. The second positive electrode non-coated portion 347 is located on the side surface facing inward in the radial direction shown in FIG. 16b, and is spaced apart from the first positive electrode non-coated portion 346 in the α direction and closer to the start of winding in the α direction than the first positive electrode non-coated portion 346.

[0105] The α-direction length of the second positive electrode non-coated portion 347 is equal to or longer than the γ-direction length of a negative electrode non-coated portion 356 (see FIGS. 16c and 16d) described below, and is preferably longer than the γ-direction length. The δ-direction length of the negative electrode substrate 351 is longer than the β-direction length of the positive electrode substrate 341. Within the flat electrode body 310 (see FIG. 17), all portions of the negative electrode non-coated portion 356 except for both ends in the height direction (Z direction) face the second positive electrode non-coated portion 347 in the thickness direction (thickness direction of the flat electrode body 310). The α-direction length of the second positive electrode non-coated portion 347 may be shorter than the γ-direction length of the negative electrode non-coated portion 356.

[0106] The flat electrode body 310 is produced by press-molding a wound electrode body into a flat shape, and therefore tends to have a high density in the thickness direction. Therefore, if a positive electrode mixture layer that releases lithium ions is present in a position in the thickness direction opposite the negative electrode non-coated portion 356 where the negative electrode substrate 351 is exposed, it may react with the surrounding negative electrode, causing excessive lithium deposition on the negative electrode, and in the worst case, causing a short circuit. Therefore, in this embodiment, a second positive electrode non-coated portion 347 is provided in the positive electrode 340 in a position in the thickness direction opposite the negative electrode non-coated portion 356 within the flat electrode body 310. This eliminates the reaction area between the positive and negative electrodes, reliably preventing short circuits and achieving high safety.

[0107] Insulating tape 343 is applied to the entire first and second positive electrode non-coated portions 346, 347 and to the α-direction ends of the positive electrode mixture layer 342, which face the negative electrode 350 across the separator within the flat electrode body 310. The insulating tape 343 is made of an insulating material such as polyimide. A step corresponding to the thickness of the positive electrode mixture layer 342 is formed at the boundary between the area where the positive electrode mixture layer 342 is present and the area where it is not. In such areas, if an external force is applied to the battery 301, for example, if the battery 301 is accidentally dropped, the positive electrode mixture may slip off, potentially causing a short circuit. The insulating tape 343 is applied to prevent such a short circuit. The α-direction length of the tape 343 applied to the positive electrode non-coated portions 347, 348 is greater than the γ-direction length of the negative electrode non-coated portion 356.

[0108] The material of the positive electrode core 341 is the same as the material of the positive electrode core 41 of the first embodiment, and the material of the positive electrode mixture layer 342 is the same as the material of the positive electrode mixture layer 42 of the first embodiment. The first and second positive electrode uncoated portions 246, 247 are formed by intermittently coating both surfaces of the positive electrode core 241 with the positive electrode mixture. The first and second positive electrode uncoated portions 246, 247 can be produced by the same method as the first to third positive electrode uncoated portions 46, 47, 48 of the first embodiment.

[0109] As shown in FIGS. 16c and 16d, the negative electrode 350 has a long negative electrode core 351 and a negative electrode mixture layer 352 partially and selectively provided on both sides of the negative electrode core 351 in the γ direction. The negative electrode 350 has a negative electrode uncoated portion 356 where the negative electrode mixture layer is not coated at the end of the radially inner side surface at the winding start side in the γ direction, and the negative electrode core 351 is exposed over the entire δ direction. The negative electrode uncoated portion 356 is located at the innermost circumferential portion of the negative electrode 350. The negative electrode mixture layer 352 is located on both sides of the negative electrode uncoated portion 356 in the γ direction. The length in the γ direction of the negative electrode uncoated portion 356 is slightly longer than the length in the γ direction of the negative electrode tab 320, and the negative electrode tab 320 is joined by spot welding to the center of the negative electrode uncoated portion 356 in the γ direction. After the negative electrode tab 320 is joined, insulating tape 353 is attached to the entire negative electrode non-coated portion 356 .

[0110] The material of the negative electrode core 351 is the same as that of the negative electrode core 51 of the first embodiment, and the material of the negative electrode mixture layer 352 is the same as that of the negative electrode mixture layer 52 of the first embodiment. The negative electrode non-coated portion 356 is formed by intermittently applying a negative electrode mixture to the radially inner side surface of the negative electrode core 351. The negative electrode 350 and the negative electrode non-coated portion 356 can be fabricated in the same manner as the negative electrode 50 and the negative electrode non-coated portion 56 of the first embodiment. Note that in FIGS. 16a, 16b, 16c, and 16d, the outer rectangular frame indicates the outer edge of the long separator 60. The width dimension of the long separator 60 is longer than the β-direction dimension of the long positive electrode core 341 and longer than the δ-direction dimension of the long negative electrode core 351, thereby reliably preventing short circuits.

[0111] FIG. 17 is a plan view of a flat electrode assembly 310 of the third embodiment as viewed from one side in the Z direction. Referring to FIGS. 16a, 16b, 16c, 16d, and 17, the total thickness of the positive electrode tab 315, its welded portion, and the insulating tape 343 attached to the positive electrode non-coated portion 346 (non-coated on both sides) is approximately the same as the thickness of the positive electrode mixture layer 342. The total thickness of the positive electrode non-coated portion 347 (non-coated on one side) facing the negative electrode tab 320 and the insulating tape 343 is approximately the same as the thickness of the positive electrode mixture layer 342. The negative electrode non-coated portion 356 to which the negative electrode tab 320 is joined is located at the innermost circumferential portion of the negative electrode 350. The thickness of the negative electrode tab 320 is preferably thinner than the thickness of the negative electrode mixture layer 352. The portion of the positive electrode 340 facing the negative electrode tab 320 includes a core exposed portion 280 where the positive electrode core 341 is exposed. The range in which the positive electrode tab 315 exists within the flat electrode body 310 can be the same as the range in which the positive electrode tab 15 exists within the flat electrode body 10 described using t in FIG.

[0112] According to the third embodiment, as shown in FIG. 17 , the negative electrode tab 220 is joined to the radially inward side of the innermost circumferential portion of the negative electrode core 251. Therefore, the number of positive electrode portions facing the negative electrode tab 220 can be reduced from two positive electrode non-coated portions in the first and second embodiments to one positive electrode non-coated portion 347. As a result, the area of ​​the positive electrode core 341 in the α direction where the positive electrode mixture layer 342 is provided can be increased. This increases the capacity of the battery 301. Furthermore, because the negative electrode tab 320 is joined to the innermost circumferential portion of the negative electrode core 351, stress (strain) generated in the flat electrode body 310 due to the joining of the negative electrode tab 320 can be reduced compared to when the negative electrode tab 320 is joined to the center portion of the flat electrode body 310 in the thickness direction. This reduces deterioration of the flat electrode body 310 when the battery 301 is used continuously over a long period of time.

[0113] (Fourth embodiment) Fig. 18a is a schematic front view of a long positive electrode 440 before being wound in a nonaqueous electrolyte secondary battery 401 of the fourth embodiment, as viewed from one side in the thickness direction (the radially outer side of the flat electrode body), Fig. 18b is a schematic front view of the long positive electrode 440 before being wound, as viewed from the other side in the thickness direction (the radially inner side of the flat electrode body). Fig. 18c is a schematic front view of a long negative electrode 450 before being wound in the nonaqueous electrolyte secondary battery 401, as viewed from one side in the thickness direction (the radially outer side of the flat electrode body), and Fig. 18d is a schematic front view of the long negative electrode 450 before being wound, as viewed from the other side in the thickness direction (the radially inner side of the flat electrode body).

[0114] 1 and 2, and can be fabricated using the exterior body described with reference to Figures 3a and 3b, or can be fabricated using the exterior body described with reference to Figures 8a and 8b. In Figures 18a, 18b, 18c, and 18d, the longitudinal lengths of the positive electrode 440 and the negative electrode 450 are depicted as being significantly shorter than their actual lengths.

[0115] As shown in FIGS. 18a and 18b, the positive electrode 440 has a long positive electrode core 441 and positive electrode mixture layers 442 partially and selectively provided on both sides of the positive electrode core 441 in the α direction. The positive electrode 440 has positive electrode uncoated portions 446, 447 in the longitudinal direction where the positive electrode mixture layer is not applied, and the positive electrode core 441 is exposed over the entire area in the β direction. The positive electrode mixture layers 442 are present on both sides of each positive electrode uncoated portion 446, 447 in the α direction. The first positive electrode uncoated portion 446 is a non-coated portion on both sides of the positive electrode core 415 where the positive electrode mixture layer is not applied. The two first positive electrode uncoated portions 446 are provided at approximately the same location in the α direction. The second positive electrode non-coated portion 447 is located on the radially inward side shown in Figure 18b, spaced apart in the α direction from the first positive electrode non-coated portion 446, and is closer to the start of winding in the α direction than the first positive electrode non-coated portion 446.

[0116] The α-direction length of the second positive electrode non-coated portion 447 is equal to or greater than the γ-direction length of the negative electrode non-coated portion 456 (see FIGS. 18c and 18d) described below, and preferably is longer than the γ-direction length. The β-direction length of the second positive electrode non-coated portion 447 is equal to or greater than the δ-direction length of the negative electrode non-coated portion 456 (see FIGS. 18c and 18d) described below, and preferably is longer than the δ-direction length. The δ-direction length of the negative electrode substrate 451 is longer than the β-direction length of the positive electrode substrate 441. Within the flat electrode body, all portions of the negative electrode non-coated portion 456 except for one end portion in the height direction (Z direction) face the second positive electrode non-coated portion 447 in the thickness direction (thickness direction of the flat electrode body). The α-direction length of the second positive electrode non-coated portion 447 may be shorter than the γ-direction length of the negative electrode non-coated portion 456. The β-direction length of the second positive electrode non-coated portion 447 may be shorter than the δ-direction length of the negative electrode non-coated portion 456. Insulating tape 443 is attached to the entire area of ​​the first and second positive electrode non-coated portions 446, 447 and to the α-direction end portion of the positive electrode mixture layer 442 at a location facing the negative electrode 450 within the flat electrode body with the separator interposed therebetween. The insulating tape 443 is made of an insulating material such as polyimide. The α-direction length and β-direction length of the tape 443 attached to the positive electrode non-coated portion 447 are greater than the γ-direction length and δ-direction length of the negative electrode non-coated portion 456, respectively.

[0117] As shown in FIGS. 18c and 18d, the negative electrode 450 has a long negative electrode core 451 and a negative electrode mixture layer 452 partially and selectively provided on both sides of the negative electrode core 451 in the γ direction. The negative electrode 450 has a negative electrode uncoated portion 456 where the negative electrode mixture layer is not applied to the end of the radially inner side surface at the winding start side in the γ direction, and the negative electrode core 451 is exposed over the entire δ direction. The negative electrode uncoated portion 456 is located at the innermost circumferential portion of the negative electrode 450. The negative electrode mixture layer 452 is located on both sides of the negative electrode uncoated portion 456 in the γ direction. The length in the γ direction of the negative electrode uncoated portion 456 is slightly longer than the length in the γ direction of the negative electrode tab 420, and the negative electrode tab 420 is joined by spot welding to the center of the negative electrode uncoated portion 456 in the γ direction. After the negative electrode tab 420 is joined, insulating tape 453 is attached to the entire negative electrode non-coated portion 456 .

[0118] 18a, 18b, 18c, and 18d, the nonaqueous electrolyte secondary battery 401 of the fourth embodiment differs from the nonaqueous electrolyte secondary battery 301 of the third embodiment only in that the first and second positive electrode uncoated portions 446, 447 are present only in part in the β direction rather than the entire area in the β direction, and the negative electrode uncoated portion 456 is present only in part in the δ direction rather than the entire area in the δ direction. According to the fourth embodiment, the formation area of ​​the positive electrode mixture layer 442 and the formation area of ​​the negative electrode mixture layer 452 can be increased, thereby increasing the capacity of the nonaqueous electrolyte secondary battery 401.

[0119] In comparison with the first and second embodiments, a configuration may be adopted in which the first to third positive electrode uncoated portions are present only in a portion of the β direction rather than the entire area in the β direction, and the negative electrode uncoated portion is present only in a portion of the δ direction rather than the entire area in the δ direction. In these cases, too, the formation area of ​​the positive electrode mixture layer and the formation area of ​​the negative electrode mixture layer can be increased, thereby increasing the capacity of the nonaqueous electrolyte secondary battery.

[0120] [Test Results] The inventors of the present application also conducted the same tests on the batteries 201, 301, and 401 of the second to fourth embodiments as on the first embodiment, and obtained the results shown in Table 2 below. [Table 2]

[0121] As shown in Table 2, in the second to fourth embodiments, compared to the first embodiment, the internal resistance increased slightly due to the difference in the joining position of the negative electrode tab, but the safety was at the same level. Meanwhile, in the second to fourth embodiments, compared to the first embodiment, both the shipping charge thickness and the thickness after cycle testing were reduced. This is because joining the negative electrode tab to the outermost or innermost peripheral portion of the negative electrode facilitates uniform lamination in the thickness direction excluding the joining position of the negative electrode tab. Furthermore, as shown in Table 2, in the second to fourth embodiments, compared to the first embodiment, distortion is less likely to occur in the flat electrode body, deterioration of the flat electrode body can be suppressed, and the capacity retention rate can be improved. Furthermore, joining the negative electrode tab to the outermost peripheral portion of the negative electrode, as in the second embodiment, facilitates bending during sealing with an exterior, improving productivity and reliability. Furthermore, joining the negative electrode tab to the innermost peripheral portion of the negative electrode, as in the third embodiment, increases the formation area of ​​the positive and negative electrode mixture layer, thereby increasing capacity compared to the first embodiment. Furthermore, as in the fourth embodiment, by making the non-coated portions of the attachment portions of the positive and negative electrode tabs only part of the height direction, the formation area of ​​the positive and negative electrode mixture layers can be further increased compared to the third embodiment, and the capacity can be greatly increased. [Explanation of symbols]

[0122] 1,201,301,401 Battery, 5 Laminated film exterior body, 5a Rear portion, 6 Recess, 9 Rear portion, 10 Flat electrode body, 15 Positive electrode tab, 16 Heat-sealed portion of positive electrode tab, 20 Negative electrode tab, 21 Heat-sealed portion of positive electrode tab, 25 Positive electrode tab welding resin, 30 Negative electrode tab welding resin, 40,240,340,440 Positive electrode, 41,241,341,441 Positive electrode core, 42,242,342,442 Positive electrode mixture layer, 43,53,243,253,343,353,443,453 Insulating tape, 46,246,346,446 Positive electrode non-coated portion, 50,250,350,450 Negative electrode, 51,251,351,451 Negative electrode substrate, 52,252,352,452 Negative electrode mixture layer, 56,256,356,456 Negative electrode non-coated portion, 57 Fold-back line, 59 Electrode body accommodating portion, 60 Separator, 60a Separator protrusion, 65 Separator group, 65a Protrusion group, 69 Separator tip, 80 Tab forming device, 83,84,280,281 Substrate exposed portion, 91 First portion, 92 Second portion, 188 Flat portion, Q,Q' Virtual plane.

Claims

1. a laminate film exterior body formed by joining film materials; a flat electrode body that is housed in the laminate film exterior body and that is formed by winding a long positive electrode and a long negative electrode that face each other with a long separator interposed therebetween into a flat shape; the positive electrode includes a long positive electrode core and a positive electrode mixture layer provided on the positive electrode core, and has a positive electrode non-coated portion midway in the longitudinal direction where the positive electrode mixture layer is not present and the positive electrode core is exposed, and the negative electrode includes a long negative electrode core and a negative electrode mixture layer provided on the negative electrode core, and has a negative electrode non-coated portion midway in the longitudinal direction where the negative electrode mixture layer is not present and the negative electrode core is exposed, a positive electrode tab joined and electrically connected to the positive electrode non-coated portion; a negative electrode tab joined and electrically connected to the negative electrode non-coated portion, the positive electrode tab and the negative electrode tab are located on the same side of an imaginary plane that passes through approximately the center of the flat electrode body in the thickness direction and is approximately perpendicular to the thickness direction of the flat electrode body, a portion of the positive electrode facing the negative electrode tab includes a core exposed portion where the positive electrode core is exposed and to which the positive electrode tab is not joined, the positive electrode mixture layer is present on the surface opposite to the exposed portion of the core;

2. a laminate film exterior body formed by joining film materials; a flat electrode body that is housed in the laminate film exterior body and that is formed by winding a long positive electrode and a long negative electrode that face each other with a long separator interposed therebetween into a flat shape; the positive electrode includes a long positive electrode core and a positive electrode mixture layer provided on the positive electrode core, and has a positive electrode uncoated portion midway in the longitudinal direction where the positive electrode mixture layer is not present and the positive electrode core is exposed, and the negative electrode includes a long negative electrode core and a negative electrode mixture layer provided on the negative electrode core, and has a negative electrode uncoated portion at the outermost periphery in the longitudinal direction where the negative electrode mixture layer is not present and the negative electrode core is exposed, a positive electrode tab joined and electrically connected to the positive electrode non-coated portion; a negative electrode tab joined and electrically connected to the negative electrode non-coated portion, the positive electrode tab and the negative electrode tab are located on the same side of an imaginary plane that passes through approximately the center of the flat electrode body in the thickness direction and is approximately perpendicular to the thickness direction of the flat electrode body, a portion of the positive electrode facing the negative electrode tab includes a core exposed portion where the positive electrode core is exposed and to which the positive electrode tab is not joined, the negative electrode mixture layer is present on both sides of the negative electrode non-coated portion in the longitudinal direction.

3. a laminate film exterior body formed by joining film materials; a flat electrode body that is housed in the laminate film exterior body and that is formed by winding a long positive electrode and a long negative electrode that face each other with a long separator interposed therebetween into a flat shape; the positive electrode includes a long positive electrode core and a positive electrode mixture layer provided on the positive electrode core, and has a positive electrode uncoated portion midway in the longitudinal direction where the positive electrode mixture layer is not present and the positive electrode core is exposed, and the negative electrode includes a long negative electrode core and a negative electrode mixture layer provided on the negative electrode core, and has a negative electrode uncoated portion at the innermost periphery in the longitudinal direction where the negative electrode mixture layer is not present and the negative electrode core is exposed, a positive electrode tab joined and electrically connected to the positive electrode non-coated portion; a negative electrode tab joined and electrically connected to the negative electrode non-coated portion, a portion of the positive electrode facing the negative electrode tab includes a core exposed portion where the positive electrode core is exposed and to which the positive electrode tab is not joined, the negative electrode mixture layer is present on both sides of the negative electrode non-coated portion in the longitudinal direction.

4. the thickness of the positive electrode tab is less than the thickness of the positive electrode mixture layer, 4. The nonaqueous electrolyte secondary battery in accordance with claim 1, wherein the thickness of the negative electrode tab is less than the thickness of the negative electrode mixture layer.

5. 5. The nonaqueous electrolyte secondary battery according to claim 1, wherein the positive electrode non-coated portion and the substrate exposed portion are present only in a portion of the elongated positive electrode in the width direction, and the negative electrode non-coated portion is present only in a portion of the elongated negative electrode in the width direction.

6. The film exterior body, a first portion having a recess for accommodating the flat electrode body; a second portion folded back at one end of the first portion in the height direction and having no recess; a welding portion provided on both sides of the recess and on the other end portion in the height direction, the welding portion sealing the laminate film exterior body; the positive electrode tab and the negative electrode tab are sandwiched between the first portion and the second portion at the other end portion when the laminate film exterior body is sealed, 6. The nonaqueous electrolyte secondary battery according to claim 1, wherein the positive electrode tab and the negative electrode tab each protrude from the welded portion from a rear surface side of the laminate film exterior body in a state of being substantially parallel to the rear surface.

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