Electrolysis system control device and electrolysis system

Abstract

SOLUTION: A control device 11 of an electrolysis system 10 comprises a deterioration prediction unit 244 for predicting the degree of deterioration of each of a water electrolysis stack 72 and a boosting stack 150 and a supply current control unit 242 for controlling supply currents to a water electrolysis stack and a boosting stack. The supply current control unit includes: controlling the supply current so as to be constantly supplied to the larger stack in degree of deterioration among the water electrolysis stack and the boosting stack; and being able to control the supply current so as to be adaptively supplied to the smaller stack in degree of deterioration among the water electrolysis stack and the boosting stack.SELECTED DRAWING: Figure 4

Description

[Technical Field]

[0001] The present disclosure relates to a control device for an electrolysis system and an electrolysis system. [Background technology]

[0002] In recent years, technological developments have been underway in electrolysis systems that contribute to energy efficiency, ensuring that more people have access to affordable, reliable, sustainable and advanced energy.

[0003] For example, Japanese Patent No. 7421581 discloses an electrolysis system including a water electrolysis device and a booster. The water electrolysis device electrolyzes water by supplying current to a water electrolysis stack. The booster supplies current to a booster stack into which hydrogen gas generated in the water electrolysis stack is introduced, thereby boosting the pressure of the hydrogen gas. The electrolysis system is controlled by a control device. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] Patent No. 7421581 Summary of the Invention [Problem to be solved by the invention]

[0005] There is a need for better electrolysis system control devices and electrolysis systems.

[0006] The present disclosure aims to solve the above-mentioned problems. [Means for solving the problem]

[0007] A first aspect of the present disclosure provides a control device for an electrolysis system including a water electrolysis device that electrolyzes water by supplying a current to a water electrolysis stack, and a booster device that boosts the pressure of hydrogen gas generated in the water electrolysis stack by supplying a current to a booster stack into which hydrogen gas is introduced, the control device further comprising: a degradation prediction unit that predicts the degree of degradation of each of the water electrolysis stack and the booster stack; and a supply current control unit that controls the supply current to the water electrolysis stack and the booster stack, wherein the supply current control unit controls the supply current to the stack that is more deteriorated of the water electrolysis stack or the booster stack to a constant value, and adaptively controls the supply current to the stack that is less deteriorated of the water electrolysis stack or the booster stack.

[0008] A second aspect of the present disclosure is an electrolysis system comprising the control device according to the first aspect. [Effects of the Invention]

[0009] According to the present disclosure, a better electrolysis system control device and electrolysis system can be obtained. [Brief explanation of the drawings]

[0010] [Figure 1] FIG. 1 is a schematic diagram of an energy system including an electrolysis system according to an embodiment. [Figure 2] FIG. 2 is a cross-sectional view of a water electrolysis cell. [Figure 3] FIG. 3 is a cross-sectional view of a booster cell. [Figure 4] FIG. 4 is a block diagram illustrating the control device. [Figure 5] FIG. 5 is a flowchart illustrating a method for controlling the electrolysis system. DETAILED DESCRIPTION OF THE INVENTION

[0011] In an electrolysis system, in a water electrolysis stack, a portion of the hydrogen gas generated by the electrolysis of water permeates an electrolyte membrane and is guided to an oxygen gas transport channel. The flow rate of the hydrogen gas permeating the electrolyte membrane varies depending on the pressure in the oxygen gas transport channel, the temperature of the water electrolysis stack, and other factors. Therefore, even when a constant current is supplied to the water electrolysis stack, the flow rate of the hydrogen gas output from the water electrolysis stack fluctuates. In this state, if a constant current is supplied to the booster stack to boost the hydrogen gas, the amount of hydrogen gas present in the channel that guides the hydrogen gas generated in the water electrolysis stack to the booster stack fluctuates, which may prevent the booster stack from efficiently boosting the hydrogen gas.

[0012] For example, if the supply current to the water electrolysis stack is adaptively controlled and the supply current to the boost stack is controlled to a constant value in order to adjust the amount of hydrogen gas present in a flow path that guides hydrogen gas generated in the water electrolysis stack to the electrolysis stack, the water electrolysis stack will be more susceptible to deterioration than the boost stack. On the other hand, if the supply current to the water electrolysis stack is controlled to a constant value and the supply current to the boost stack is adaptively controlled, the boost stack will be more susceptible to deterioration than the water electrolysis stack. The present disclosure can provide an electrolysis system control device and an electrolysis system that can efficiently boost hydrogen gas using the boost stack while suppressing variation in the deterioration levels of the water electrolysis stack and the boost stack.

[0013] FIG. 1 is a schematic diagram of an energy system 12 including an electrolysis system 10 according to an embodiment. As shown in FIG. 1, the energy system 12 is a circulatory renewable energy system. The energy system 12 is a system that combines a fuel cell system 14 and an electrolysis system 10. The fuel cell system 14 generates electricity and water through an electrochemical reaction between oxygen gas and hydrogen gas. The electrolysis system 10 electrolyzes water to generate oxygen gas and hydrogen gas. The electrolysis system 10 utilizes the water generated in the fuel cell system 14. The fuel cell system 14 utilizes the oxygen gas and hydrogen gas generated in the electrolysis system 10.

[0014] Such an energy system 12 may be installed, for example, on the Earth or on the moon, or may be installed on an artificial satellite such as the International Space Station (ISS).

[0015] The fuel cell system 14 includes a fuel cell stack 16. The fuel cell stack 16 is a polymer electrolyte fuel cell (PEFC). The fuel cell stack 16 includes a plurality of power generating cells 18 and a pair of end plates 20. The power generating cells 18 are stacked on top of each other. The pair of end plates 20 sandwich the power generating cells 18 in the stacking direction.

[0016] Detailed illustration of the power generation cell 18 is omitted. The power generation cell 18 includes a membrane electrode assembly (MEA) and a pair of separators. The membrane electrode assembly is sandwiched between the pair of separators. The membrane electrode assembly has an electrolyte membrane, an anode electrode, and a cathode electrode. The electrolyte membrane is a solid polymer electrolyte membrane. The power generation cell 18 generates electricity through an electrochemical reaction between hydrogen gas and oxygen gas. When the power generation cell 18 generates electricity, water is produced at the cathode electrode.

[0017] The fuel cell system 14 further includes an oxygen gas tank 22, an oxygen gas supply channel 24, an oxygen gas discharge channel 26, a gas-liquid separator 28, an oxygen gas circulation channel 30, and a first drainage channel 32. The oxygen gas tank 22 is filled with high-pressure oxygen gas. The oxygen gas supply channel 24 supplies the oxygen gas filled in the oxygen gas tank 22 to the fuel cell stack 16. An on-off valve 34 is provided in the oxygen gas supply channel 24. The on-off valve 34 opens and closes the oxygen gas supply channel 24.

[0018] The oxygen gas discharge channel 26 connects the fuel cell stack 16 and the gas-liquid separator 28 to each other. Oxygen exhaust gas (off-gas) discharged from the fuel cell stack 16 flows through the oxygen gas discharge channel 26. The oxygen exhaust gas contains unreacted oxygen gas that did not react in the power generation cell 18. The oxygen exhaust gas also contains water (water vapor) produced at the cathode electrode of the power generation cell 18.

[0019] The gas-liquid separator 28 separates the oxygen exhaust gas guided from the oxygen gas discharge path 26 into gas and liquid. That is, the gas-liquid separator 28 removes water vapor from the oxygen exhaust gas. The gas-liquid separator 28 stores the water (liquid water) separated from the oxygen exhaust gas. The oxygen gas circulation path 30 connects the gas-liquid separator 28 and the oxygen gas supply path 24 to each other. The oxygen gas circulation path 30 guides the oxygen exhaust gas from which water vapor has been removed by the gas-liquid separator 28 to the oxygen gas supply path 24. The oxygen gas circulation path 30 is provided with an oxygen pump 36. The oxygen pump 36 sends the oxygen exhaust gas circulating through the oxygen gas circulation path 30 to the oxygen gas supply path 24.

[0020] The first drainage channel 32 is a flow path for discharging water stored in the gas-liquid separator 28 to the outside of the gas-liquid separator 28. A first drainage valve 38 is provided in the first drainage channel 32. The first drainage valve 38 is an on-off valve that opens and closes the first drainage channel 32.

[0021] The fuel cell system 14 further includes a hydrogen gas tank 40, a hydrogen gas supply channel 42, a hydrogen gas discharge channel 44, a gas-liquid separator 46, a hydrogen gas circulation channel 48, and a second drainage channel 50. The hydrogen gas tank 40 is filled with high-pressure hydrogen gas. The hydrogen gas supply channel 42 supplies the hydrogen gas filled in the hydrogen gas tank 40 to the fuel cell stack 16. An on-off valve 52 is provided in the hydrogen gas supply channel 42. The on-off valve 52 opens and closes the hydrogen gas supply channel 42.

[0022] The hydrogen gas discharge channel 44 connects the fuel cell stack 16 and the gas-liquid separator 46 to each other. Hydrogen exhaust gas (off-gas) discharged from the fuel cell stack 16 flows through the hydrogen gas discharge channel 44. The hydrogen exhaust gas contains unreacted hydrogen gas that did not react in the power generation cell 18. The hydrogen exhaust gas also contains moisture that has permeated from the cathode electrode of the power generation cell 18 through the electrolyte membrane and been guided to the anode electrode.

[0023] The gas-liquid separator 46 separates the hydrogen exhaust gas guided from the hydrogen gas discharge channel 44 into gas and liquid. That is, the gas-liquid separator 46 removes water vapor from the hydrogen exhaust gas. The gas-liquid separator 46 stores the water (liquid water) separated from the hydrogen exhaust gas. The hydrogen gas circulation channel 48 connects the gas-liquid separator 46 to the hydrogen gas supply channel 42. The hydrogen gas circulation channel 48 guides the hydrogen exhaust gas from which water vapor has been removed by the gas-liquid separator 46 to the hydrogen gas supply channel 42. A hydrogen pump 54 is provided in the hydrogen gas circulation channel 48. The hydrogen pump 54 sends the hydrogen exhaust gas flowing through the hydrogen gas circulation channel 48 to the hydrogen gas supply channel 42.

[0024] The second drainage channel 50 is a flow path for discharging water stored in the gas-liquid separator 46 to the outside of the gas-liquid separator 46. A second drainage valve 56 is provided in the second drainage channel 50. The second drainage valve 56 is an on-off valve that opens and closes the second drainage channel 50.

[0025] The fuel cell system 14 may include components other than those described above. That is, the fuel cell system 14 may include, for example, a cooling device for circulating a cooling medium through the fuel cell stack 16.

[0026] The electrolysis system 10 includes a gas-liquid separator 58, a water electrolysis device 60, and a booster device 62. A water supply channel 64 is connected to the gas-liquid separator 58 of the electrolysis system 10. The water supply channel 64 is connected to the first drainage channel 32 and the second drainage channel 50. The water supply channel 64 guides water from the first drainage channel 32 and water from the second drainage channel 50 to the gas-liquid separator 58. A pump 66 and an on-off valve 68 are provided in the water supply channel 64. The pump 66 sends water circulating through the water supply channel 64 to the gas-liquid separator 58. The on-off valve 68 opens and closes the water supply channel 64. The gas-liquid separator 58 has a reservoir 70 that stores water. The water stored in the reservoir 70 of the gas-liquid separator 58 is used in the water electrolysis device 60.

[0027] In the water electrolysis device 60, water (pure water) is electrolyzed to generate oxygen gas and hydrogen gas. The water electrolysis device 60 is, for example, a solid polymer water electrolysis device.

[0028] The water electrolysis device 60 includes a water electrolysis stack 72, a first power source 73, a water electrolysis supply channel 74, a water electrolysis discharge channel 76, a first oxygen gas transfer channel 78, a gas-liquid separator 80, a third drainage channel 82, and a second oxygen gas transfer channel 84. The water electrolysis stack 72 includes a plurality of water electrolysis cells 86 and a pair of end plates 88. The plurality of water electrolysis cells 86 are stacked on top of each other. The pair of end plates 88 sandwich the plurality of water electrolysis cells 86 in the stacking direction.

[0029] Fig. 2 is a cross-sectional view of a water electrolysis cell 86. In Fig. 2, the X direction is the stacking direction of the multiple water electrolysis cells 86. As shown in Fig. 2, in the water electrolysis cell 86, water is supplied to the cathode electrode 110. The water electrolysis cell 86 electrolyzes water to generate oxygen gas at the anode electrode 112 and hydrogen gas at the cathode electrode 110.

[0030] The water electrolysis cell 86 is a differential pressure water electrolysis cell in which the pressure of oxygen gas in the anode electrode 112 is higher than the pressure of water in the cathode electrode 110. The water electrolysis cell 86 may also be a constant pressure water electrolysis cell in which the pressure of oxygen gas in the anode electrode 112 is approximately equal to the pressure of water in the cathode electrode 110. The water electrolysis device 60 can generate oxygen gas at the anode electrode 112 at 14.7 MPa, for example.

[0031] Each water electrolysis cell 86 is provided with a water supply passage 94, a water discharge passage 96, and an oxygen gas discharge passage 98, which pass through the water electrolysis cell 86 in the X direction. The water supply passages 94 of the multiple water electrolysis cells 86 are in communication with one another. The water discharge passages 96 of the multiple water electrolysis cells 86 are in communication with one another. The oxygen gas discharge passages 98 of the multiple water electrolysis cells 86 are in communication with one another.

[0032] The water supply passage 94 and the water discharge passage 96 are provided on the outer periphery of the water electrolysis cell 86. The oxygen gas discharge passage 98 is provided in the center of the water electrolysis cell 86. The water supply passage 94 supplies water to the cathode electrode 110. The water discharge passage 96 discharges water that has flowed through the cathode electrode 110 and hydrogen gas generated at the cathode electrode 110 to the outside. The oxygen gas discharge passage 98 discharges oxygen gas generated at the anode electrode 112 to the outside.

[0033] The water electrolysis cell 86 includes a membrane electrode assembly 100, a pair of separators 102, and a frame member 104. The membrane electrode assembly 100 is sandwiched between the pair of separators 102. The frame member 104 is formed in an annular shape so as to surround the membrane electrode assembly 100. A seal member 106 is provided between the frame member 104 and the separators 102 to prevent fluids (water and hydrogen gas) from leaking to the outside.

[0034] The separator 102 is made of, for example, stainless steel. The separator 102 is coated with, for example, a material containing niobium. Hereinafter, in FIG. 2, the separator 102 of the pair of separators 102 located in the X1 direction of the membrane electrode structure 100 may be referred to as the "first electrolytic separator 102a," and the separator 102 of the pair of separators 102 located in the X2 direction of the membrane electrode structure 100 may be referred to as the "second electrolytic separator 102b."

[0035] The membrane electrode assembly 100 includes an electrolyte membrane 108, a cathode electrode 110, and an anode electrode 112. The electrolyte membrane 108 is sandwiched between the cathode electrode 110 and the anode electrode 112. The electrolyte membrane 108 is an ion exchange membrane. Specifically, the electrolyte membrane 108 is, for example, a proton exchange membrane (PEM). The proton exchange membrane is, for example, a fluorine-based polymer membrane. The electrolyte membrane 108 may also be an anion exchange membrane (AEM). The electrolyte membrane 108 prevents oxygen gas generated at the anode electrode 112 from passing through to the cathode electrode 110.

[0036] The cathode electrode 110 has a cathode catalyst layer 114, a protective sheet 116, and a cathode current collector 118. The cathode catalyst layer 114 is bonded to one surface 108a of the electrolyte membrane 108 (the surface of the electrolyte membrane 108 facing the X1 direction). The cathode current collector 118 also serves as a diffusion layer for supplying water to the cathode catalyst layer 114. The cathode current collector 118 has a portion formed of a porous material. The protective sheet 116 is disposed between the cathode catalyst layer 114 and the cathode current collector 118. The protective sheet 116 prevents the electrolyte membrane 108 from being damaged by being pressed by the cathode current collector 118 due to high-pressure oxygen gas generated in the anode electrode 112. The protective sheet 116 has a plurality of through-holes 120 formed therein.

[0037] The anode electrode 112 has an anode catalyst layer 122 and an anode power supply 124. The anode catalyst layer 122 is bonded to the other surface 108b of the electrolyte membrane 108 (the surface of the electrolyte membrane 108 facing the X2 direction). The anode catalyst layer 122 may contain, for example, iridium, ruthenium, or the like. The anode power supply 124 also serves as a gas diffusion layer for discharging oxygen gas generated in the anode catalyst layer 122. The anode power supply 124 has a portion formed of a porous material.

[0038] A support member 126 that supports the membrane electrode assembly 100 is provided between the first electrolytic separator 102a and the cathode current collector 118. A communication passage 128 is formed in the support member 126. The communication passage 128 guides water introduced from the water supply passage 94 into the cathode current collector 118. The communication passage 128 also guides a mixed fluid of water and hydrogen gas inside the cathode current collector 118 to the water discharge passage 96.

[0039] A load-applying mechanism 130 that biases the anode power supply 124 in the X1 direction is provided between the second electrolytic separator 102b and the anode power supply 124. The load-applying mechanism 130 includes, for example, a leaf spring 132, a holder 134, and a conductive sheet 136.

[0040] An annular member 138 is provided between the second electrolytic separator 102b and the outer periphery of the electrolyte membrane 108. The annular member 138 is in liquid-tight and air-tight contact with the other surface 108b of the electrolyte membrane 108.

[0041] An annular seal member 140 is disposed between the annular member 138 and the load-applying mechanism 130. The seal member 140 is in liquid-tight and airtight contact with each of the second electrolytic separator 102b and the electrolyte membrane 108. A space (anode chamber 142) for accommodating the anode electrode 112 is formed inside the seal member 140. The load-applying mechanism 130 is disposed in the anode chamber 142. The leaf spring 132 and holder 134 constituting the load-applying mechanism 130 are made of, for example, stainless steel. The leaf spring 132 and holder 134 are each coated with, for example, a material containing niobium.

[0042] 1, the first power supply 73 is a DC power supply. The first power supply 73 supplies current to the water electrolysis stack 72. In other words, the first power supply 73 applies a voltage between the cathode power supply 118 and the anode power supply 124 of the water electrolysis cell 86 (see FIGS. 1 and 2).

[0043] The water electrolysis supply channel 74 connects the gas-liquid separator 58 and the water electrolysis stack 72. The water electrolysis supply channel 74 communicates with the water supply passage 94 (see FIG. 2 ) of the water electrolysis cell 86. The water electrolysis supply channel 74 guides water stored in the gas-liquid separator 58 to the water electrolysis stack 72. A water pump 143 is provided in the water electrolysis supply channel 74. The water pump 143 sends water flowing through the water electrolysis supply channel 74 to the water electrolysis stack 72.

[0044] The water electrolysis discharge channel 76 connects the gas-liquid separator 58 and the water electrolysis stack 72. The water electrolysis discharge channel 76 communicates with the water discharge passage 96 (see FIG. 2 ) of the water electrolysis cell 86. The water electrolysis discharge channel 76 guides a mixed fluid of hydrogen generated at the cathode electrode 110 of the water electrolysis cell 86 and water that was not electrolyzed to the gas-liquid separator 58. The gas-liquid separator 58 separates the mixed fluid guided from the water electrolysis discharge channel 76 into gas and liquid. The water separated from the mixed fluid is stored in the reservoir 70 of the gas-liquid separator 58.

[0045] The first oxygen gas transfer passage 78 communicates with the oxygen gas discharge passage 98 (see FIG. 2) of the water electrolysis cell 86. The first oxygen gas transfer passage 78 guides the oxygen gas generated by the water electrolysis stack 72 to the gas-liquid separator 80. The gas-liquid separator 80 separates the oxygen gas guided from the first oxygen gas transfer passage 78 into gas and liquid. In other words, the gas-liquid separator 80 removes water vapor from the oxygen gas. The gas-liquid separator 80 can store water (liquid water) separated from the oxygen gas.

[0046] The third drainage channel 82 guides the water stored in the gas-liquid separator 80 to the gas-liquid separator 58. A third drainage valve 144 is provided in the third drainage channel 82. The third drainage valve 144 is an on-off valve that opens and closes the third drainage channel 82.

[0047] The second oxygen gas transfer path 84 transfers the oxygen gas from which water vapor has been removed by the gas-liquid separator 80 to the oxygen gas tank 22. The second oxygen gas transfer path 84 is provided with a first back pressure valve 146. The first back pressure valve 146 opens when the pressure of the oxygen gas transferred from the water electrolysis stack 72 is equal to or higher than a predetermined oxygen gas pressure threshold. The first back pressure valve 146 closes when the pressure of the oxygen gas transferred from the water electrolysis stack 72 is lower than the oxygen gas pressure threshold.

[0048] The water electrolysis device 60 may include components other than those described above. For example, the water electrolysis device 60 may include an ion exchange resin for converting the water supplied to the water electrolysis stack 72 into pure water.

[0049] The booster device 62 includes a booster stack 150, a second power source 152, a booster supply channel 154, a booster discharge channel 156, a first hydrogen gas transfer channel 158, a gas-liquid separator 160, a fourth drain channel 162, and a second hydrogen gas transfer channel 164. The booster stack 150 boosts the hydrogen gas generated in the water electrolysis stack 72. The booster stack 150 includes a plurality of booster cells 166 and a pair of end plates 168. The plurality of booster cells 166 are stacked on top of each other. The pair of end plates 168 sandwich the plurality of booster cells 166 in the stacking direction.

[0050] FIG. 3 is a cross-sectional explanatory view of the booster cell 166. In FIG. 3, the Y direction is the stacking direction of the multiple booster cells 166. As shown in FIG. 3, in the booster cell 166, humidified hydrogen gas is supplied to the anode electrode 186. The booster cell 166 generates hydrogen gas at the cathode electrode 188 by supplying a current to the anode electrode 186 and the cathode electrode 188. In the booster device 62, for example, 70 MPa of hydrogen gas can be generated at the cathode electrode 188.

[0051] The pressurizing cell 166 is provided with a supply passage 170, a discharge passage 172, and a hydrogen gas discharge passage 174 that penetrate the pressurizing cell 166 in the Y direction. The supply passages 170 of the multiple pressurizing cells 166 are connected to one another. The discharge passages 172 of the multiple pressurizing cells 166 are connected to one another. The hydrogen gas discharge passages 174 of the multiple pressurizing cells 166 are connected to one another.

[0052] The supply passage 170 and the discharge passage 172 are provided on the outer periphery of the booster cell 166. The hydrogen gas discharge passage 174 is provided in the center of the booster cell 166. The supply passage 170 supplies hydrogen gas to the anode electrode 186. The discharge passage 172 discharges hydrogen gas (unreacted hydrogen gas) that has flowed through the anode electrode 186 to the outside. The hydrogen gas discharge passage 174 discharges hydrogen gas generated at the cathode electrode 188 to the outside.

[0053] The booster cell 166 has a membrane electrode assembly 176, a pair of separators 178, and a frame member 180. The membrane electrode assembly 176 is sandwiched between the pair of separators 178. The frame member 180 is formed in an annular shape so as to surround the membrane electrode assembly 176. A seal member 182 is provided between the frame member 180 and the separator 178 to prevent fluids (water and hydrogen gas) from leaking to the outside.

[0054] The separator 178 is made of, for example, titanium. Hereinafter, in Fig. 3, the separator 178 of the pair of separators 178 that is located in the Y1 direction of the membrane electrode assembly 176 may be referred to as the "first boost separator 178a," and the separator 178 of the pair of separators 178 that is located in the Y2 direction of the membrane electrode assembly 176 may be referred to as the "second boost separator 178b."

[0055] The membrane electrode assembly 176 has an electrolyte membrane 184, an anode electrode 186, and a cathode electrode 188. The electrolyte membrane 184 is sandwiched between the anode electrode 186 and the cathode electrode 188. The electrolyte membrane 184 is an ion exchange membrane. Specifically, the electrolyte membrane 184 is, for example, a proton exchange membrane (PEM). The proton exchange membrane is, for example, a fluorine-based polymer membrane. The electrolyte membrane 184 may also be an anion exchange membrane (AEM). The electrolyte membrane 184 prevents hydrogen gas generated at the cathode electrode 188 from passing to the anode electrode 186.

[0056] The anode electrode 186 has an anode catalyst layer 190, a protective sheet 192, and an anode power supply 194. The anode catalyst layer 190 is bonded to one surface 184a of the electrolyte membrane 184 (the surface of the electrolyte membrane 184 facing the Y1 direction). The anode power supply 194 also serves as a gas diffusion layer for supplying hydrogen gas to the anode catalyst layer 190. The anode power supply 194 has a portion formed of a porous material. The protective sheet 192 is disposed between the anode catalyst layer 190 and the anode power supply 194. The protective sheet 192 prevents the electrolyte membrane 184 from being damaged by being pressed against the anode power supply 194 by high-pressure hydrogen gas generated in the cathode electrode 188. The protective sheet 192 has a plurality of through-holes 196 formed therein.

[0057] The cathode electrode 188 has a cathode catalyst layer 198 and a cathode power supply 200. The cathode catalyst layer 198 is joined to the other surface 184b of the electrolyte membrane 184 (the surface of the electrolyte membrane 184 facing the Y2 direction). The cathode power supply 200 also serves as a gas diffusion layer for guiding hydrogen gas generated in the cathode catalyst layer 198. The cathode power supply 200 has a portion formed of a porous material.

[0058] A support member 202 that supports the membrane electrode assembly 176 is provided between the first boost separator 178a and the anode current collector 194. A communication passage 204 is formed in the support member 202. The communication passage 204 guides hydrogen gas introduced from the supply passage 170 into the anode current collector 194. The communication passage 204 also guides unreacted hydrogen gas in the anode current collector 194 to the discharge passage 172.

[0059] A load applying mechanism 206 that biases the cathode power supply 200 in the Y1 direction is provided between the second boost separator 178b and the cathode power supply 200. The load applying mechanism 206 has, for example, a leaf spring 208, a holder 210, and a conductive sheet 212.

[0060] An annular member 214 is provided between the second booster separator 178b and the outer periphery of the electrolyte membrane 184. The annular member 214 is in liquid-tight and air-tight contact with the other surface 184b of the electrolyte membrane 184.

[0061] An annular seal member 216 is disposed between the annular member 214 and the load-applying mechanism 206. The seal member 216 is in liquid-tight and airtight contact with each of the second boost separator 178b and the electrolyte membrane 184. A space (cathode chamber 218) for accommodating the cathode electrode 188 is formed inside the seal member 216. The load-applying mechanism 206 is disposed in the cathode chamber 218. The leaf spring 208 and holder 210 constituting the load-applying mechanism 206 are made of, for example, a material containing iron. The leaf spring 208 and the holder 210 are each coated with, for example, a material containing niobium.

[0062] 1, the second power supply 152 is a DC power supply. The second power supply 152 supplies current to the boost stack 150. In other words, the second power supply 152 applies a voltage between the cathode power supply 200 and the anode power supply 194 of the boost cell 166 (see FIGS. 1 and 2).

[0063] The booster supply channel 154 connects the gas-liquid separator 58 and the booster stack 150. The booster supply channel 154 guides the hydrogen gas in the gas-liquid separator 58 to the booster stack 150. A hydrogen pump 220 is provided in the booster supply channel 154. The hydrogen pump 220 sends the hydrogen gas flowing through the booster supply channel 154 to the booster stack 150. The hydrogen gas supplied from the booster supply channel 154 to the booster stack 150 contains an appropriate amount of water vapor. As a result, the electrolyte membrane 184 of the booster cell 166 is humidified by the water vapor.

[0064] The pressurized discharge passage 156 connects the gas-liquid separator 58 and the pressurized stack 150. The pressurized discharge passage 156 guides unreacted hydrogen gas from the pressurized stack 150 to the gas-liquid separator 58 together with water vapor.

[0065] The first hydrogen gas transfer path 158 communicates with the hydrogen gas discharge passage 174 (see FIG. 3) of the booster cell 166. The first hydrogen gas transfer path 158 guides the hydrogen gas generated in the booster stack 150 to the gas-liquid separator 160. The gas-liquid separator 160 separates the hydrogen gas guided from the first hydrogen gas transfer path 158 into gas and liquid. In other words, the gas-liquid separator 160 removes water vapor from the hydrogen gas. The gas-liquid separator 160 can store water (liquid water) separated from the hydrogen gas.

[0066] The fourth drainage channel 162 guides the water stored in the gas-liquid separator 160 to the gas-liquid separator 58. A fourth drainage valve 222 is provided in the fourth drainage channel 162. The fourth drainage valve 222 is an on-off valve that opens and closes the fourth drainage channel 162.

[0067] The second hydrogen gas transfer path 164 guides the hydrogen gas from which water vapor has been removed by the gas-liquid separator 160 to the hydrogen gas tank 40. The second hydrogen gas transfer path 164 is provided with a second backpressure valve 224. The second backpressure valve 224 opens when the pressure of the hydrogen gas guided from the booster stack 150 is equal to or greater than a predetermined hydrogen gas pressure threshold. The second backpressure valve 224 closes when the pressure of the hydrogen gas guided from the booster stack 150 is less than the hydrogen gas pressure threshold.

[0068] The boost device 62 may include components other than those described above.

[0069] 1 , the energy system 12 includes a first ion measurement unit 226, a second ion measurement unit 228, a third ion measurement unit 230, a fourth ion measurement unit 232, and a fifth ion measurement unit 234. The first ion measurement unit 226 is provided in the water electrolysis device 60. The second ion measurement unit 228 is provided in the booster device 62. The third ion measurement unit 230 is provided in the gas-liquid separator 58. The fourth ion measurement unit 232 and the fifth ion measurement unit 234 are provided in the fuel cell system 14.

[0070] The first ion measuring unit 226 measures the amount of ions eluted from the water electrolysis stack 72. The first ion measuring unit 226 measures the amount of ions eluted in the oxygen gas produced by the water electrolysis stack 72. Specifically, the first ion measuring unit 226 is provided in the gas-liquid separator 80 of the water electrolysis apparatus 60. The first ion measuring unit 226 measures the amount of ions eluted in the water stored in the gas-liquid separator 80, for example, at predetermined time intervals.

[0071] In the water electrolysis cell 86, fluoride ions may be eluted due to decomposition of the electrolyte membrane 108. In the water electrolysis cell 86, niobium ions may be eluted due to peeling of the coatings on the separator 102, the leaf spring 132, and the holder 134. In addition, iron ions may be eluted from the portions where the coatings have peeled off. In the water electrolysis cell 86, iridium ions and ruthenium ions may be eluted due to deterioration of the anode catalyst layer 122.

[0072] The first ion measuring unit 226 may measure, for example, fluorine ions, niobium ions, iron ions, iridium ions, ruthenium ions, etc. The first ion measuring unit 226 may sequentially measure the amount of eluted ions present in the water stored in the gas-liquid separator 80. The first ion measuring unit 226 may also measure the amount of eluted ions directly from the oxygen gas produced by the water electrolysis stack 72.

[0073] The second ion measuring unit 228 measures the amount of ions eluted from the booster stack 150. The second ion measuring unit 228 measures the amount of ions eluted contained in the hydrogen gas pressurized by the booster stack 150. Specifically, the second ion measuring unit 228 is provided in the gas-liquid separator 160 of the booster device 62. The second ion measuring unit 228 measures the amount of ions eluted in the water stored in the gas-liquid separator 160, for example, at predetermined time intervals.

[0074] In the booster cell 166, fluoride ions may be eluted due to decomposition of the electrolyte membrane 184. In the booster cell 166, niobium ions may be eluted due to peeling of the coatings on the leaf spring 208 and the holder 210. In the booster cell 166, iron ions may be eluted from the areas where the coatings have peeled off. In the booster cell 166, titanium ions may be eluted due to deterioration of the separator 178.

[0075] The second ion measuring unit 228 can measure, for example, fluoride ions, niobium ions, iron ions, titanium ions, etc. The second ion measuring unit 228 may sequentially measure the amount of eluted ions present in the water stored in the gas-liquid separator 160. The second ion measuring unit 228 may also measure the amount of eluted ions directly from the hydrogen gas pressurized in the booster stack 150.

[0076] The third ion measuring unit 230 is provided in the gas-liquid separator 58. The third ion measuring unit 230 measures the amount of eluted ions present in the water stored in the gas-liquid separator 58, for example, at predetermined time intervals. The third ion measuring unit 230 may sequentially measure the amount of eluted ions present in the water stored in the gas-liquid separator 58.

[0077] The fourth ion measuring unit 232 is provided in the gas-liquid separator 28 of the fuel cell system 14. The fourth ion measuring unit 232 measures the amount of eluted ions present in the water stored in the gas-liquid separator 28, for example, at predetermined time intervals. The fourth ion measuring unit 232 may sequentially measure the amount of eluted ions present in the water stored in the gas-liquid separator 28.

[0078] The fifth ion measuring unit 234 is provided in the gas-liquid separator 46 of the fuel cell system 14. The fifth ion measuring unit 234 measures the amount of eluted ions present in the water stored in the gas-liquid separator 46, for example, at predetermined time intervals. The fifth ion measuring unit 234 may sequentially measure the amount of eluted ions present in the water stored in the gas-liquid separator 46.

[0079] The third ion measuring section 230, the fourth ion measuring section 232, and the fifth ion measuring section 234 can each measure, for example, fluoride ions, niobium ions, iron ions, iridium ions, ruthenium ions, titanium ions, and the like.

[0080] The energy system 12 includes a control device 11. Fig. 4 is a block diagram illustrating the control device 11. As shown in Fig. 4, the control device 11 includes a calculation unit 236 and a storage unit 238. The calculation unit 236 is configured by a processor such as a CPU (Central Processing Unit) or a GPU (Graphics Processing Unit). In other words, the calculation unit 236 is configured by processing circuitry.

[0081] The calculation unit 236 has a control unit 240, a supply current control unit 242, a deterioration prediction unit 244, an eluted ion amount information acquisition unit 246, and a determination unit 248. The control unit 240 is responsible for overall control of the energy system 12. The supply current control unit 242 controls the supply current to the water electrolysis stack 72 and the supply current to the booster stack 150. That is, the supply current control unit 242 controls the first power source 73 and the second power source 152. The deterioration prediction unit 244 predicts the degree of deterioration of each of the water electrolysis stack 72 and the booster stack 150. The eluted ion amount information acquisition unit 246 acquires first eluted ion amount information and second eluted ion amount information. The first eluted ion amount information is information related to the amount of ions eluted from the water electrolysis stack 72. The second eluted ion amount information is information related to the amount of ions eluted from the booster stack 150.

[0082] The control unit 240, the supply current control unit 242, the deterioration prediction unit 244, the eluted ion amount information acquisition unit 246, and the determination unit 248 can be realized by the calculation unit 236 executing a program stored in the storage unit 238. Note that at least a portion of the control unit 240, the supply current control unit 242, the deterioration prediction unit 244, the eluted ion amount information acquisition unit 246, and the determination unit 248 may be realized by an integrated circuit such as an ASIC (Application Specific Integrated Circuit) or an FPGA (Field-Programmable Gate Array). Furthermore, at least a portion of the control unit 240, the supply current control unit 242, the deterioration prediction unit 244, the eluted ion amount information acquisition unit 246, and the determination unit 248 may be configured by an electronic circuit including discrete devices.

[0083] The storage unit 238 is composed of a volatile memory (not shown) and a non-volatile memory (not shown). Examples of the volatile memory include RAM (Random Access Memory). The volatile memory is used as a working memory for the processor, and temporarily stores data necessary for processing or calculation. Examples of the non-volatile memory include ROM (Read Only Memory) and flash memory. The non-volatile memory is used as a storage memory, and stores programs, tables, maps, etc. At least a part of the storage unit 238 may be provided in the processor, integrated circuit, etc. described above.

[0084] Next, a description will be given of the control of the electrolysis system 10. Fig. 5 is a flowchart illustrating a control method for the electrolysis system 10.

[0085] As shown in FIG. 5, in step S1, the control unit 240 drives the energy system 12. Specifically, as shown in FIG. 1, the control unit 240 controls the fuel cell system 14 to start power generation. That is, the control unit 240 controls the on-off valve 34 to open the oxygen gas supply path 24. As a result, oxygen gas stored in the oxygen gas tank 22 is supplied to the fuel cell stack 16 via the oxygen gas supply path 24. The control unit 240 also controls the on-off valve 52 to open the hydrogen gas supply path 42. As a result, hydrogen gas stored in the hydrogen gas tank 40 is supplied to the fuel cell stack 16 via the hydrogen gas supply path 42. The fuel cell stack 16 generates power through an electrochemical reaction between oxygen gas and hydrogen gas. The power generated by the fuel cell stack 16 can be used to drive the energy system 12. The power generated by the fuel cell stack 16 can also be charged into a battery (not shown).

[0086] The oxidant exhaust gas (off-gas) from the fuel cell stack 16 is guided to the gas-liquid separator 28 via the oxygen gas discharge path 26. The gas-liquid separator 28 removes moisture from the oxygen exhaust gas. The moisture removed from the oxygen exhaust gas is stored in the gas-liquid separator 28. The control unit 240 drives the oxygen pump 36. As a result, the oxygen exhaust gas from which moisture has been removed is guided from the gas-liquid separator 28 to the oxygen gas supply path 24 via the oxygen gas circulation path 30.

[0087] The hydrogen exhaust gas (off-gas) from the fuel cell stack 16 is guided to the gas-liquid separator 46 via the hydrogen gas discharge path 44. The gas-liquid separator 46 removes moisture from the hydrogen exhaust gas. The moisture removed from the hydrogen exhaust gas is stored in the gas-liquid separator 46. The control unit 240 drives the hydrogen pump 54. As a result, the hydrogen exhaust gas from which moisture has been removed is guided from the gas-liquid separator 46 to the hydrogen gas supply path 42 via the hydrogen gas circulation path 48.

[0088] The control unit 240 controls the first drain valve 38 to open the first drain channel 32, and also controls the on-off valve 68 to open the water supply channel 64. The control unit 240 also drives the pump 66. This causes the water stored in the gas-liquid separator 28 to be introduced into the gas-liquid separator 58 via the first drain channel 32 and the water supply channel 64. Drainage from the gas-liquid separator 28 to the gas-liquid separator 58 is carried out at an appropriate timing.

[0089] The control unit 240 controls the second drain valve 56 to open the second drain channel 50, and also controls the on-off valve 68 to open the water supply channel 64. The control unit 240 also drives the pump 66. This causes the water stored in the gas-liquid separator 46 to be introduced into the gas-liquid separator 58 via the second drain channel 50 and the water supply channel 64. Drainage from the gas-liquid separator 46 to the gas-liquid separator 58 is carried out at an appropriate timing.

[0090] The control unit 240 also controls the water electrolysis device 60 to generate oxygen gas and hydrogen gas. That is, the control unit 240 drives the water pump 143 and controls the first power source 73 to supply current to the water electrolysis stack 72. When the water pump 143 is driven, as shown in FIGS. 1 and 2 , water stored in the reservoir 70 of the gas-liquid separator 58 is supplied to the cathode electrode 110 of the water electrolysis cell 86 via the water electrolysis supply path 74. As shown in FIG. 2 , the water supplied to the cathode electrode 110 moves from the cathode electrode 110 to the anode electrode 112 within the electrolyte membrane 108. At the anode electrode 112, water is electrolyzed to generate hydrogen ions and oxygen gas. The hydrogen ions generated at the anode electrode 112 move from the anode electrode 112 to the cathode electrode 110 within the electrolyte membrane 108. At the cathode electrode 110, the hydrogen ions combine to generate hydrogen gas. The water and hydrogen gas that have not reacted in the cathode electrode 110 are discharged to the gas-liquid separator 58 via the water discharge passage 96 and the water electrolysis discharge channel 76 (see FIG. 1).

[0091] As shown in FIG. 1 , oxygen gas generated in the water electrolysis stack 72 is guided to the gas-liquid separator 80 via a first oxygen gas transfer path 78. The gas-liquid separator 80 removes moisture from the oxygen gas. The moisture removed from the oxygen gas is stored in the gas-liquid separator 80. The water stored in the gas-liquid separator 80 is drained to the gas-liquid separator 58 via a third drainage path 82 at an appropriate time. The oxygen gas from which the moisture has been removed is guided to a second oxygen gas transfer path 84. When the pressure of the oxygen gas generated in the water electrolysis stack 72 reaches or exceeds the oxygen gas pressure threshold, the first back pressure valve 146 opens, and the oxygen gas tank 22 is filled with oxygen gas.

[0092] Furthermore, the control unit 240 controls the pressure boosting device 62 to boost the hydrogen gas. That is, the control unit 240 drives the hydrogen pump 220 and controls the second power supply 152 to supply current to the pressure boosting stack 150. When the hydrogen pump 220 is driven, as shown in FIGS. 1 and 3, the hydrogen gas in the gas-liquid separator 58, together with an appropriate amount of water, is supplied to the anode electrode 186 of the pressure boosting cell 166 via the pressure boosting supply channel 154. As shown in FIG. 3, hydrogen ions are generated at the anode electrode 186. The hydrogen ions generated at the anode electrode 186 travel through the electrolyte membrane 184 from the anode electrode 186 to the cathode electrode 188. At the cathode electrode 188, the hydrogen ions combine to generate hydrogen gas. The hydrogen gas and water supplied to the anode electrode 186 that did not react are returned to the gas-liquid separator 58 via the discharge communication hole 172 and the pressure boosting discharge channel 156 (see FIG. 1).

[0093] As shown in FIG. 1, hydrogen gas generated at the cathode electrode 188 is guided to the gas-liquid separator 160 via the first hydrogen gas transfer path 158. The gas-liquid separator 160 removes moisture from the hydrogen gas. The moisture removed from the hydrogen gas is stored in the gas-liquid separator 160. The water stored in the gas-liquid separator 160 is drained to the gas-liquid separator 58 via the fourth drainage path 162 at an appropriate time. The hydrogen gas from which the moisture has been removed is guided to the second hydrogen gas transfer path 164. When the pressure of the hydrogen gas generated in the booster stack 150 reaches or exceeds the hydrogen gas pressure threshold, the second backpressure valve 224 opens, and the hydrogen gas is filled into the hydrogen gas tank 40.

[0094] As shown in FIG. 5, after step S1, the process proceeds to step S2. In step S2, the eluted ion amount information acquisition unit 246 acquires first eluted ion amount information and second eluted ion amount information. The first eluted ion amount information is information related to the amount of ions eluted from the water electrolysis stack 72. The first eluted ion amount information is information acquired based on the amount of ions eluted in the oxygen gas generated by the water electrolysis stack 72. In this embodiment, the eluted ion amount information acquisition unit 246 acquires the first eluted ion amount information based on information output from the first ion measurement unit 226 to the control device 11. That is, the eluted ion amount information acquisition unit 246 may acquire information related to the amount of eluted ions, such as fluoride ions, niobium ions, iron ions, iridium ions, and ruthenium ions. The amount of eluted ions may be the eluted ion concentration or an integrated value of eluted ions from a predetermined time point.

[0095] The second eluted ion amount information is information relating to the amount of ions eluted from the booster stack 150. The second eluted ion amount information is information acquired based on the amount of ions eluted in the hydrogen gas boosted by the booster stack 150. In this embodiment, the eluted ion amount information acquisition unit 246 acquires the second eluted ion amount information based on information output from the second ion measurement unit 228 to the control device 11. That is, the eluted ion amount information acquisition unit 246 can acquire information relating to the amount of eluted ions such as fluoride ions, niobium ions, iron ions, and titanium ions, for example.

[0096] In this embodiment, when one of the first eluted ion amount information and the second eluted ion amount information cannot be acquired and the other of the first eluted ion amount information and the second eluted ion amount information can be acquired, the eluted ion amount information acquisition unit 246 estimates one of the first eluted ion amount information and the second eluted ion amount information based on information regarding the eluted ion amount in the water stored in the storage unit 70 and the other of the first eluted ion amount information and the second eluted ion amount information.

[0097] Specifically, for example, if the first ion measuring unit 226 breaks down, the eluted ion amount information acquiring unit 246 is unable to acquire the first eluted ion amount information from the first ion measuring unit 226. In this case, the eluted ion amount information acquiring unit 246 estimates the first eluted ion amount information based on, for example, information on the amount of eluted ions in the water stored in the storage unit 70 of the gas-liquid separator 58 and the second eluted ion amount information. The eluted ion amount information acquiring unit 246 can acquire information on the amount of eluted ions in the water stored in the storage unit 70 of the gas-liquid separator 58 based on information output from the third ion measuring unit 230 to the control device 11.

[0098] The water stored in the reservoir 70 of the gas-liquid separator 58 contains ions eluted from the water electrolysis stack 72 and ions eluted from the booster stack 150. That is, the ions eluted from the water electrolysis stack 72, together with oxygen gas generated in the water electrolysis stack 72, are guided to the gas-liquid separator 28 via the first oxygen gas transfer channel 78, the gas-liquid separator 80, the second oxygen gas transfer channel 84, the oxygen gas tank 22, the oxygen gas supply channel 24, the fuel cell stack 16, and the oxygen gas discharge channel 26. Therefore, the ions eluted from the water electrolysis stack 72 are contained in the water stored in the gas-liquid separator 28 of the fuel cell system 14. The water stored in the gas-liquid separator 28 is guided to the gas-liquid separator 58 via the first drainage channel 32 and the water supply channel 64. Furthermore, the water stored in the gas-liquid separator 80 of the water electrolysis device 60 can be drained into the reservoir 70 of the gas-liquid separator 58 via the third drainage channel 82. Therefore, the water stored in the reservoir 70 of the gas-liquid separator 58 contains ions eluted from the water electrolysis stack 72 .

[0099] The ions eluted from the booster stack 150, together with the hydrogen gas pressurized by the booster stack 150, are guided to the gas-liquid separator 46 via the first hydrogen gas transport channel 158, the gas-liquid separator 160, the second hydrogen gas transport channel 164, the hydrogen gas tank 40, the hydrogen gas supply channel 42, the fuel cell stack 16, and the hydrogen gas discharge channel 44. Therefore, the ions eluted from the booster stack 150 are contained in the water stored in the gas-liquid separator 46 of the fuel cell system 14. The water stored in the gas-liquid separator 46 is guided to the gas-liquid separator 58 via the second drainage channel 50 and the water supply channel 64. Furthermore, the water stored in the gas-liquid separator 160 of the booster device 62 can be drained into the reservoir 70 of the gas-liquid separator 58 via the fourth drainage channel 162. Therefore, the water stored in the reservoir 70 of the gas-liquid separator 58 contains the ions eluted from the booster stack 150.

[0100] Therefore, the eluted ion amount information acquisition unit 246 can estimate the first eluted ion amount information based on information regarding the amount of eluted ions in the water stored in the storage unit 70 of the gas-liquid separator 58 and the second eluted ion amount information. In this case, the eluted ion amount information acquisition unit 246 may consider, for example, information regarding the amount of eluted ions in the water stored in the gas-liquid separator 28 of the fuel cell system 14 and information regarding the amount of eluted ions in the water stored in the gas-liquid separator 46 of the fuel cell system 14. This makes it possible to estimate the first eluted ion amount information with greater accuracy. The eluted ion amount information acquisition unit 246 can acquire information regarding the amount of eluted ions in the water stored in the gas-liquid separator 28 based on information output from the fourth ion measurement unit 232 to the control device 11. The eluted ion amount information acquisition unit 246 can acquire information regarding the amount of eluted ions in the water stored in the gas-liquid separator 46 based on information output from the fifth ion measurement unit 234 to the control device 11.

[0101] Furthermore, for example, if the second ion measuring unit 228 breaks down, the eluted ion amount information acquiring unit 246 is unable to acquire the second eluted ion amount information from the second ion measuring unit 228. In this case, the eluted ion amount information acquiring unit 246 estimates the second eluted ion amount information based on, for example, information on the amount of eluted ions in the water stored in the storage unit 70 of the gas-liquid separator 58 and the first eluted ion amount information. In this case, the eluted ion amount information acquiring unit 246 may take into account, for example, information on the amount of eluted ions in the water stored in the gas-liquid separator 28 of the fuel cell system 14 and information on the amount of eluted ions in the water stored in the gas-liquid separator 46 of the fuel cell system 14. This enables the second eluted ion amount information to be estimated with even greater accuracy.

[0102] After step S2, the process proceeds to step S3. In step S3, the degradation prediction unit 244 predicts the degradation levels of the water electrolysis stack 72 and the booster stack 150. Specifically, the degradation prediction unit 244 predicts the degradation level of the water electrolysis stack 72 based on the first eluted ion amount information. That is, the degradation prediction unit 244 can predict the degradation level of the electrolyte membrane 108 of the water electrolysis stack 72 based on, for example, information on the eluted ion amount of fluoride ions (first eluted ion amount information). The degradation prediction unit 244 can also predict the degradation level of the anode catalyst layer 122 of the water electrolysis stack 72 based on, for example, information on the eluted ion amount of at least one of iridium ions and ruthenium ions (first eluted ion amount information). The degradation prediction unit 244 can also predict the degradation level of the separator 102 of the water electrolysis stack 72 based on, for example, information on the eluted ion amount of at least one of niobium ions and iron ions (first eluted ion amount information).

[0103] The deterioration prediction unit 244 also predicts the degree of deterioration of the booster stack 150 based on the second eluted ion amount information. That is, the deterioration prediction unit 244 can predict the degree of deterioration of the electrolyte membrane 184 of the booster stack 150 based on, for example, information on the eluted ion amount of fluoride ions (second eluted ion amount information). The deterioration prediction unit 244 can predict the degree of deterioration of the separator 178 of the booster stack 150 based on, for example, information on the eluted ion amount of at least one of niobium ions, iron ions, and titanium ions (second eluted ion amount information).

[0104] After step S3, the process proceeds to step S4. In step S4, the determination unit 248 determines whether the amount of ions eluted from the water electrolysis stack 72 has reached a first threshold value, and whether the amount of ions eluted from the booster stack 150 has reached a second threshold value. The first threshold value and the second threshold value are determined in advance and stored in the memory unit 238. If the determination unit 248 determines that the amount of ions eluted from the water electrolysis stack 72 has not reached the first threshold value, and if the determination unit 248 determines that the amount of ions eluted from the booster stack 150 has not reached the second threshold value (NO in step S4), the process proceeds to step S5.

[0105] In step S5, the supply current control unit 242 executes supply current control. That is, the supply current control unit 242 controls the supply current to the stack that is more deteriorated, either the water electrolysis stack 72 or the booster stack 150, to be constant, and adaptively controls the supply current to the stack that is less deteriorated, either the water electrolysis stack 72 or the booster stack 150. This makes it possible to suppress further deterioration of the stack that is more deteriorated, either the water electrolysis stack 72 or the booster stack 150.

[0106] In the water electrolysis stack 72, some of the hydrogen gas generated at the cathode electrode 110 permeates the electrolyte membrane 108 and is guided to the anode electrode 112. The flow rate of the hydrogen gas permeating the electrolyte membrane 108 varies depending on the pressure in the first oxygen gas transport channel 78, the temperature of the water electrolysis stack 72, and other factors. Therefore, even if the current supplied to the water electrolysis stack 72 and the booster stack 150 is constant, the amount of hydrogen gas present in the flow path (such as the gas-liquid separator 58) that guides the hydrogen gas generated in the water electrolysis stack 72 to the booster stack 150 is not constant and is prone to fluctuate. In this case, the booster stack 150 may not be able to efficiently boost the hydrogen gas pressure.

[0107] However, in this embodiment, the amount of hydrogen gas present in the flow path (such as the gas-liquid separator 58) that guides the hydrogen gas generated in the water electrolysis stack 72 to the booster stack 150 can be adjusted by adaptively controlling the supply current to either the water electrolysis stack 72 or the booster stack 150, whichever is less deteriorated. In other words, it is possible to prevent the amount of hydrogen gas in the gas-liquid separator 58 from becoming excessively small or large. Therefore, the hydrogen gas can be efficiently boosted by the booster stack 150. After this, the process proceeds to step S6.

[0108] In step S6, the determination unit 248 determines whether or not there has been a request to stop the operation of the energy system 12. If the determination unit 248 determines that there has not been a request to stop the operation of the energy system 12 (NO in step S6), the process proceeds to step S2. If the determination unit 248 determines that there has been a request to stop the operation of the energy system 12 (YES in step S6), the process proceeds to step S7.

[0109] In step S7, the control unit 240 stops the operation of the energy system 12. That is, the supply current control unit 242 stops the supply of current to the water electrolysis stack 72 and the booster stack 150. This stops the operation of each of the water electrolysis stack 72 and the booster stack 150. The control unit 240 also stops the supply of oxygen gas and fuel gas to the fuel cell stack 16. After this, the processing in FIG. 5 is completed.

[0110] If the judgment unit 248 determines that the amount of ions eluted from the water electrolysis stack 72 has reached the first threshold, or if the judgment unit 248 determines that the amount of ions eluted from the boost stack 150 has reached the second threshold (YES in step S4), the process proceeds to step S8.

[0111] In step S8, the determination unit 248 determines whether the amount of ions eluted from the water electrolysis stack 72 has reached a third threshold value, and determines whether the amount of ions eluted from the booster stack 150 has reached a fourth threshold value. The third threshold value is greater than the first threshold value. The fourth threshold value is greater than the second threshold value. The third threshold value and the fourth threshold value are determined in advance and stored in the memory unit 238.

[0112] If the judgment unit 248 determines that the amount of ions eluted from the water electrolysis stack 72 has not reached the third threshold value and the judgment unit 248 determines that the amount of ions eluted from the boost stack 150 has not reached the fourth threshold value (NO in step S8), the process proceeds to step S9.

[0113] In step S9, the supply current control unit 242 executes supply current suppression control to suppress the supply current to the water electrolysis stack 72 and the booster stack 150. Specifically, while suppressing the supply current to the water electrolysis stack 72 and the booster stack 150, the supply current control unit 242 controls the supply current to the more deteriorated stack of the water electrolysis stack 72 or the booster stack 150 to be constant, and adaptively controls the supply current to the less deteriorated stack of the water electrolysis stack 72 or the booster stack 150. That is, the current supplied to the water electrolysis stack 72 and the booster stack 150 in the supply current suppression control is smaller than the current supplied to the water electrolysis stack 72 and the booster stack 150 in the supply current control (step S5). This allows the booster stack 150 to efficiently boost the hydrogen gas while further suppressing further deterioration of the water electrolysis stack 72 and the booster stack 150. After this, the process proceeds to step S6.

[0114] If the judgment unit 248 determines that the amount of ions eluted from the water electrolysis stack 72 has reached the third threshold, or if the judgment unit 248 determines that the amount of ions eluted from the boost stack 150 has reached the fourth threshold (YES in step S8), the process proceeds to step S10.

[0115] In step S10, the supply current control unit 242 stops supplying current to the water electrolysis stack 72 and the booster stack 150. This stops the operation of the water electrolysis stack 72 and the booster stack 150, thereby preventing further deterioration of the water electrolysis stack 72 and the booster stack 150. In this case, the control unit 240 may stop supplying oxygen gas and fuel gas to the fuel cell stack 16. After this, the processing in FIG. 5 is completed.

[0116] According to this embodiment, the supply current control unit 242 controls the supply current to the more deteriorated stack of the water electrolysis stack 72 and the booster stack 150 at a constant level, and adaptively controls the supply current to the less deteriorated stack of the water electrolysis stack 72 and the booster stack 150. This makes it possible to suppress further deterioration of the more deteriorated stack of the water electrolysis stack 72 and the booster stack 150. Furthermore, since the amount of hydrogen gas present in the flow path that guides the hydrogen gas generated in the water electrolysis stack 72 to the booster stack 150 can be adjusted, the hydrogen gas can be efficiently boosted by the booster stack 150.

[0117] The following additional notes are further disclosed regarding the above embodiment.

[0118] (Appendix 1) A control device (11) for an electrolysis system (10) according to the present disclosure includes a water electrolysis device (60) that electrolyzes water by supplying a current to a water electrolysis stack (72), and a booster device (62) that boosts the pressure of hydrogen gas by supplying a current to a booster stack (150) to which hydrogen gas generated in the water electrolysis stack is introduced. The control device includes a deterioration prediction unit (244) that predicts the degree of deterioration of each of the water electrolysis stack and the booster stack, and a supply current control unit (242) that controls the supply current to the water electrolysis stack and the supply current to the booster stack. The supply current control unit is capable of controlling the supply current to the stack that is more deteriorated of the water electrolysis stack or the booster stack to be constant, and adaptively controlling the supply current to the stack that is less deteriorated of the water electrolysis stack or the booster stack.

[0119] This configuration can prevent further deterioration of the more deteriorated of the water electrolysis stack or the booster stack. Furthermore, because the amount of hydrogen gas present in the flow path that guides the hydrogen gas generated in the water electrolysis stack to the booster stack can be adjusted, the hydrogen gas can be efficiently boosted by the booster stack.

[0120] (Appendix 2) The control device for an electrolysis system according to Supplementary Note 1 may further include an eluted ion amount information acquisition unit (246) that acquires first eluted ion amount information, which is information on the amount of ions eluted from the water electrolysis stack, and second eluted ion amount information, which is information on the amount of ions eluted from the booster stack, wherein the deterioration prediction unit may predict the degree of deterioration of the water electrolysis stack based on the first eluted ion amount information and predict the degree of deterioration of the booster stack based on the second eluted ion amount information.

[0121] With this configuration, the deterioration level of the water electrolysis stack can be accurately predicted using the first eluted ion amount information, and the deterioration level of the booster stack can be accurately predicted using the second eluted ion amount information.

[0122] (Appendix 3) In the control device for the electrolysis system described in Appendix 2, the first eluted ion amount information may be information obtained based on an amount of eluted ions in oxygen gas produced by the water electrolysis stack, and the second eluted ion amount information may be information obtained based on an amount of eluted ions in hydrogen gas boosted by the booster stack.

[0123] According to this configuration, the first eluted ion amount information and the second eluted ion amount information can be obtained with high accuracy.

[0124] (Appendix 4) In the control device for an electrolysis system according to Supplementary Note 3, the electrolysis system includes a storage unit (70) for storing water contained in off-gas discharged from a fuel cell stack (16) that generates electricity by an electrochemical reaction between oxygen gas produced by the water electrolysis stack and hydrogen gas pressurized by the booster stack, and water discharged from the water electrolysis stack. When one of the first eluted ion amount information and the second eluted ion amount information is unavailable and the other of the first eluted ion amount information and the second eluted ion amount information is available, the eluted ion amount information acquisition unit may estimate one of the first eluted ion amount information and the second eluted ion amount information based on information on the amount of eluted ions in water stored in the storage unit and the other of the first eluted ion amount information and the second eluted ion amount information.

[0125] According to this configuration, even if one of the first eluted ion amount information and the second eluted ion amount information cannot be obtained, the deterioration levels of the water electrolysis stack and the booster stack can be predicted.

[0126] (Appendix 5) The control device for an electrolysis system according to Supplementary Note 2 may further include a determination unit (248) that determines whether an amount of ions eluted from the water electrolysis stack has reached a first threshold and that determines whether an amount of ions eluted from the booster stack has reached a second threshold, and when the determination unit determines that the amount of ions eluted from the water electrolysis stack has reached the first threshold or when the determination unit determines that the amount of ions eluted from the booster stack has reached the second threshold, the supply current control unit may execute supply current suppression control to suppress the current supplied to the water electrolysis stack and the booster stack.

[0127] According to this configuration, when at least one of the water electrolysis stack and the booster stack has deteriorated to a certain extent, the current supplied to these stacks can be reduced to prevent further deterioration of the water electrolysis stack and the booster stack.

[0128] (Appendix 6) In the control device for an electrolysis system according to Supplementary Note 5, the determination unit may determine whether an amount of ions eluted from the water electrolysis stack has reached a third threshold value that is greater than the first threshold value, and determine whether an amount of ions eluted from the booster stack has reached a fourth threshold value that is greater than the second threshold value, and the supply current control unit may stop supplying current to the water electrolysis stack and the booster stack when the determination unit determines that the amount of ions eluted from the water electrolysis stack has reached the third threshold value or when the determination unit determines that the amount of ions eluted from the booster stack has reached the fourth threshold value.

[0129] According to this configuration, the operation of the water electrolysis stack and the booster stack can be safely stopped before the water electrolysis stack and the booster stack are excessively deteriorated.

[0130] (Appendix 7) The electrolysis system of the present disclosure includes the control device described in any one of Supplementary Notes 1 to 6.

[0131] An electrolysis system having the effects described in Supplementary Notes 1 to 6 can be obtained.

[0132] Although the present disclosure has been described in detail, the present disclosure is not limited to the individual embodiments described above. Various additions, substitutions, modifications, partial deletions, etc. are possible in these embodiments without departing from the gist of the present disclosure or the spirit of the present disclosure derived from the content of the claims and their equivalents. These embodiments can also be implemented in combination. For example, in the above-described embodiments, the order of each operation and the order of each process are shown as examples and are not limited to these. The same applies when numerical values ​​or mathematical expressions are used in the description of the above-described embodiments. [Explanation of symbols]

[0133] 10...Electrolysis system 11...Control device 16... fuel cell stack 60... water electrolysis device 62... Pressure booster device 70... Storage section 72...Water electrolysis stack 150...Boost stack 242...Supply current control unit 244...Deterioration prediction unit 246... Elution ion amount information acquisition unit 248... Determination unit

Claims

1. a water electrolysis device that electrolyzes water by supplying an electric current to a water electrolysis stack; a booster device that boosts the hydrogen gas by supplying an electric current to a booster stack into which the hydrogen gas generated in the water electrolysis stack is introduced; A control device for an electrolysis system, comprising: a deterioration prediction unit that predicts the deterioration levels of the water electrolysis stack and the booster stack; a supply current control unit that controls a supply current to the water electrolysis stack and a supply current to the booster stack; and the supply current control unit controls the supply current to one of the water electrolysis stack and the booster stack, whichever is more deteriorated, to a constant level, and adaptively controls the supply current to the other of the water electrolysis stack and the booster stack, whichever is less deteriorated.

2. The control device for an electrolysis system according to claim 1, an eluted ion amount information acquisition unit that acquires first eluted ion amount information that is information about the amount of ions eluted from the water electrolysis stack and second eluted ion amount information that is information about the amount of ions eluted from the booster stack, the deterioration prediction unit predicts the deterioration level of the water electrolysis stack based on the first eluted ion amount information, and predicts the deterioration level of the booster stack based on the second eluted ion amount information.

3. The control device for an electrolysis system according to claim 2, the first eluted ion amount information is information acquired based on an amount of eluted ions in oxygen gas generated by the water electrolysis stack, A control device for an electrolysis system, wherein the second eluted ion amount information is information obtained based on the amount of eluted ions in the hydrogen gas pressurized by the booster stack.

4. The control device for an electrolysis system according to claim 3, the electrolysis system includes a storage unit for storing moisture contained in off-gas discharged from a fuel cell stack that generates electricity through an electrochemical reaction between oxygen gas produced by the water electrolysis stack and hydrogen gas pressurized by the booster stack, and moisture discharged from the water electrolysis stack; the eluted ion amount information acquisition unit estimates one of the first eluted ion amount information and the second eluted ion amount information based on information about the eluted ion amount in the water stored in the storage unit and the other of the first eluted ion amount information and the second eluted ion amount information, when one of the first eluted ion amount information and the second eluted ion amount information cannot be acquired and the other of the first eluted ion amount information and the second eluted ion amount information is acquireable.

5. The control device for an electrolysis system according to claim 2, a determination unit that determines whether an amount of ions eluted from the water electrolysis stack has reached a first threshold value and that determines whether an amount of ions eluted from the booster stack has reached a second threshold value, and when the determination unit determines that the amount of ions eluted from the water electrolysis stack has reached the first threshold value, or when the determination unit determines that the amount of ions eluted from the booster stack has reached the second threshold value, the supply current control unit executes supply current suppression control to suppress the current supplied to the water electrolysis stack and the booster stack.

6. The control device for an electrolysis system according to claim 5, the determination unit determines whether an amount of ions eluted from the water electrolysis stack has reached a third threshold value that is greater than the first threshold value, and determines whether an amount of ions eluted from the boosting stack has reached a fourth threshold value that is greater than the second threshold value; when the determination unit determines that the amount of ions eluted from the water electrolysis stack has reached the third threshold, or when the determination unit determines that the amount of ions eluted from the booster stack has reached the fourth threshold, the supply current control unit stops supply of current to the water electrolysis stack and the booster stack.

7. An electrolysis system comprising the control device according to any one of claims 1 to 6.

Images