Silane-terminated polymers

Abstract

The present invention relates to a method for producing a storage stable silane-terminated polymer of formula (I) or (II), wherein D is a linear or branched hydrocarbon group having 1 to 20 hydrocarbon atoms, optionally interrupted by heteroatoms selected from the group consisting of oxygen, nitrogen and sulfur, A is a polymer backbone selected from the group consisting of polycarbonates, polyesters, copolymers of polyesters and / or polycarbonates, and copolymers having at least one ester group and / or carbonate group, R1, R1', R2 and R2' are each independently a group consisting of 1 to 10 carbon atoms. n is 1, 2 or 3; x and y are natural numbers from 1 to 10; G is a linear or branched hydrocarbon group having 1 to 20 hydrocarbon atoms, optionally interrupted by heteroatoms selected from the group consisting of oxygen, nitrogen and sulfur; F is a linear, branched or cyclic organic radical not containing an isocyanate-reactive group; m is a natural number greater than 1; E is a reactive group that reacts with an isocyanate group, and is selected from the group consisting of NH2, NHR 4 and SH, where R 4 is a linear, branched or cyclic hydrocarbon radical having 1 to 10 carbon atoms, optionally containing one or more heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen. JPEG2024504197000031.jpg107155

Description

[Technical Field]

[0001] The present invention relates to a method for producing silane-terminated polymers that may be used in sealants, adhesives, and coating materials and that are long-term storage stable. [Background technology]

[0002] Silane-terminated polymers are produced by known methods, including, for example, the reaction of polyols, especially hydroxy-terminated polyethers, polyurethanes or polyesters, and also hydroxy-functional polyacrylates, with (isocyanatoalkyl)alkoxysilanes.

[0003] Another method considers the reaction of the aforementioned polyols with diisocyanates or polyisocyanates, the latter being used in excess, thereby producing an isocyanate-functional polymer in this first reaction step, which is then reacted in a second reaction step with an alkoxysilane having alkyl-linked isocyanate-reactive groups.

[0004] The reaction of the hydroxy-functional polymer with the isocyanate is carried out in the presence of an additional catalyst, since only in this way is it possible to achieve a sufficiently high reaction rate in the relevant reaction step to economically produce the alkoxysilane-terminated polymer.

[0005] EP 1 995 261 A1 discloses prepolymers containing alkoxysilane groups based on specific low-viscosity polyester polyols with particularly high strength, a method for their production, and their use as binders for adhesives, primers, or coatings. For example, as described in WO 2005090428 A1, organotin compounds are used to produce OH-functional prepolymers and to cap the prepolymers or polyester polyols to promote the reaction. Organotin compounds have the disadvantage that they adversely affect the storage stability of adhesives by transesterification of the polyester backbone. Another problem with tin catalysts is that they are difficult to completely remove after the reaction, raising both toxic and environmental concerns.

[0006] WO 2010 / 136511 discloses silane-functional polyesters, which are used as components of moisture-curable compositions, such as adhesives, sealants, coatings, etc., based on silane-terminated polymers.

[0007] Various methods for producing silane-terminated polymers have been described in the literature. EP 3 744 748 A1 discloses a method for producing silane-terminated polymers, in which the urethanization reaction is carried out in the presence of at least one catalyst that does not contain organically bound tin. US 2019 / 0031812 A1 discloses a method for producing silane-terminated polymers. The reaction is carried out in the presence of bismuth neodecanoate. US 9,321,878 A1 discloses a method for producing silane-terminated polymers in the presence of a tin-free catalyst. EP 2 930 197 A1 discloses a silane-terminated adhesive for grouting joints in marine applications. Described therein is the reaction of polypropylene ether polyol with IPDI and diethyl N-(2-triethoxysilylpropyl)aminosuccinate in the presence of a titanium catalyst. U.S. Patent Application Publication No. 2017 / 0240689 discloses a method for producing a silane-terminated polymer by reacting polypropylene glycol with IPDI, (isocyanatopropyl)triethoxysilane, and / or N-(2-triethoxysilylpropyl)-2-hydroxypropanamide in the presence of bismuth neodecanoate. U.S. Patent Application Publication No. 2020 / 0339729 discloses a method for producing a silane-terminated polymer by reacting polypropylene glycol with IPDI, (3-isocyanatopropyl)trimethoxysilane, and diethyl N-(2-triethoxysilylpropyl)aminosuccinate.

[0008] The use of bismuth catalysts, such as those described in EP 1 535 940 A, provides high catalytic activity and thus promotes the reaction of isocyanatosilanes with hydroxy-terminated polyols. However, the polyol to be reacted with the isocyanate-functional compound must be dried before using the bismuth catalyst to avoid side reactions between the isocyanate functional groups and water that would otherwise be present, which would impair the activity of the bismuth catalyst. This is a major drawback of the proposed reaction. Furthermore, bismuth catalysts cannot be used to produce hydroxy-terminated polyols, particularly hydroxy-terminated polyesters and hydroxy-terminated polycarbonates.

[0009] WO 2020 / 035154 discloses that reactions using bismuth catalysts with a water content of less than 250 ppm are possible without significantly limiting activity. In this method, the drying effort can be limited but cannot be avoided. Furthermore, adhesives, sealants, and coating materials containing polymers produced using bismuth catalysts show a significant increase in viscosity during storage, and therefore exhibit poor storage stability. Summary of the Invention [Problem to be solved by the invention]

[0010] It is an object of the present invention to provide an efficient method for producing silane-terminated polymers with excellent storage stability. [Means for solving the problem]

[0011] This object is achieved by the method according to the invention. Preferred embodiments are the subject matter of the dependent claims. DETAILED DESCRIPTION OF THE INVENTION

[0012] Surprisingly, the silane-terminated polymer of formula (I) or (II) can be prepared by [ka] [ka] It can be produced by the method according to the invention and has been found to exhibit significantly higher storage stability in adhesive, sealant and coating materials.

[0013] The method according to the present invention can avoid degradation of polymer backbones selected from the group consisting of polycarbonates, polyesters, copolymers containing polyesters and / or polycarbonates, and polymers containing at least one ester and / or carbonate group. These polymer backbones can be degraded by the presence of tin catalysts, which can be avoided by the method according to the present invention. Degradation of the polymer chains—or even scission of the polymer chains of silane-terminated polymers—results in a significant decrease in the mechanical properties of the composition after storage. In the present invention, it has been found that even traces of the tin catalyst used in the production of the reactants can lead to such degradation. Therefore, it is also very important that the reactants used do not contain tin catalysts.

[0014] According to the present invention, the silane-terminated polymer of formula (I) is prepared by reacting a hydroxy-terminated organic polymer of formula (III) with [ka] with an isocyanate of formula (IV), [ka] The silane-terminated polymer of formula (II) is prepared by reacting a hydroxy-terminated organic polymer of formula (III) with [ka] reacting with a polyfunctional isocyanate of formula (V), [ka] It is then obtained by reacting with an alkoxysilane of formula (VI). [ka]

[0015] This reaction is carried out in the presence of a catalyst. For compounds of general formula I and II: D is a linear or branched hydrocarbon group having 1 to 20 hydrocarbon atoms, which may optionally be interrupted by heteroatoms selected from the group consisting of oxygen, nitrogen and sulfur; - A is a polymer backbone selected from the group consisting of polycarbonates, polyesters, copolymers comprising polyesters and / or polycarbonates, and polymers comprising at least one ester and / or carbonate group, R1, R1', R2 and R2' are each independently a linear, branched or cyclic hydrocarbon radical having 1 to 10 carbon atoms, optionally containing one or more heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen; - n is 1, 2 or 3; - x and y are natural numbers from 1 to 10, F is a linear, branched or cyclic organic radical that does not contain any isocyanate-reactive groups, i.e. in particular does not contain any primary or secondary amine groups, G is a linear or branched hydrocarbon group having 1 to 20 hydrocarbon atoms, which may optionally be interrupted by heteroatoms selected from the group consisting of oxygen, nitrogen and sulfur; - m is a natural number greater than 1, - E is a reactive group that reacts with an isocyanate group, such as NH2, NHR 4 and SH, wherein R 4 is a linear, branched or cyclic hydrocarbon radical having 1 to 10 carbon atoms, which may optionally contain one or more heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen.

[0016] It is essential to the present invention that neither the reactants used in the process according to the invention nor the reaction itself contain a tin catalyst. The term tin catalyst is understood to mean any compound containing tin ions and / or organometallic tin compounds, which is capable of promoting the formation or reaction of the reactants used. Typical tin catalysts are, for example, tributyltin, dibutyltin oxide, dioctyltin oxide, dibutyltin dilaurate, dioctyltin dilaurate, and tin fatty acid salts (such as tin(II) stearate or tin(II) laurate).

[0017] It has been found that the absence of tin catalysts is not only necessary in the reaction itself, i.e., in the reaction of the hydroxy-terminated organic polymer of formula (III) with the isocyanate of formula (IV), or in the reaction of the hydroxy-terminated organic polymer of formula (III) with the polyfunctional isocyanate of formula (V) and the subsequent reaction with the alkoxysilane of formula (VI), but also in particular in the reactants, i.e., the hydroxy-terminated organic polymer of formula (III), the isocyanate of formula (IV), the polyfunctional isocyanate of formula (V) and the alkoxysilane of formula (VI), which must be free of tin catalysts, thereby resulting in a storage-stable sealant.

[0018] Tin catalysts are widely used in the production of hydroxy-terminated polyesters and polycarbonates, i.e., hydroxy-terminated organic polymers of formula (III) having a polyester or polycarbonate backbone. At least traces of these catalysts remain in the prepolymer as active catalysts, which are then used as reactants for the production of silane-terminated polymers. In sealant, adhesive, or coating materials produced from the polymers, the tin catalysts cause degradation of the polymer chains of the silane-terminated polymers, thus resulting in a significant decrease in the mechanical properties of the composition after storage, particularly in Shore A hardness and / or tensile strength. Adhesive, sealant, and coating compositions using the silane-terminated polymers of the present invention are storage stable for several months. No decrease in the mechanical properties is observed, especially when the adhesive, sealant, or coating compositions are stored at relatively high temperatures, such as 50°C.

[0019] Preferably, the method involves producing a silane-terminated polymer of formula (I) by reacting a hydroxy-terminated organic polymer of formula (III) with [ka] by reacting with an isocyanate of formula (IV); [ka] This is because the reaction involves only one reaction step and is therefore more cost-effective.

[0020] In one embodiment, the silane-terminated polymer relates to a linear polymer of general formula (IA): [ka] where R1, R2, D and n have the same definitions as above. Linear silane-terminated polymers are particularly preferably used for sealant and coating materials requiring greater elasticity, such as for joint compounds, elastic adhesives, surface sealants, or in the marine sector, such as for teak grouting.

[0021] In a second embodiment, the silane-terminated polymer relates to a branched polymer of general formula (IB), [ka] wherein R1, R2, D, n, x, and y have the same definitions as above. Preferably, the silane-terminated polymer of formula (IB) has substantially no free OH groups, i.e., y and x are essentially the same, and therefore the difference between y and x is about 0. The branched silane-terminated polymer of formula (IB) is particularly preferably used in adhesive, sealant, and coating compositions that require higher Shore A hardness and higher crosslink density, such as in the case of high-elasticity adhesives, surface sealants, or floor coatings.

[0022] Preferably, bismuth and / or zinc catalysts are not used in the reaction because these catalysts have poor hydrolytic stability, may cause side reactions, and / or are complicated to handle. In particular, bismuth and / or zinc catalysts cannot be used for the production of hydroxy-terminated polymers, especially polyesters and polycarbonates. However, according to the present invention, the same catalysts used in the production of hydroxy-terminated polymers are preferably used in the reaction, which is advantageous for environmental and economic reasons. Furthermore, adhesives, sealants, and coating materials containing polymers produced using bismuth catalysts exhibit significant viscosity increases during storage and therefore exhibit poor storage stability.

[0023] Preferably, at least one catalyst is used in the process according to the present invention, which may be used both in the production of the hydroxy-terminated prepolymer and in the reaction of the isocyanatosilane with the hydroxy-terminated polymer, and which does not adversely affect the storage stability of the adhesive, sealant, and coating materials produced therefrom. The at least one catalyst is particularly preferably a titanium-containing organometallic compound, which may optionally be combined with other catalysts, such as lithium compounds. Optionally, this additional catalyst may be added only during the reaction of the hydroxy-terminated prepolymer with the isocyanatosilane. These catalysts do not adversely affect the storage stability of the adhesive, sealant, and coating materials produced therefrom, and do not need to be removed from the polymer in a complicated manner.

[0024] Titanium-containing organometallic compounds are preferably used as catalysts in the process according to the invention, preferably having a ligand selected from: -alkoxy groups, such as isobutoxy, n-butoxy, isopropoxy, ethoxy, and 2-ethylhexoxy; sulfonate groups, such as aromatic sulfonates in which the aromatic group is substituted with an alkyl group, and - carboxylate groups, such as, for example, carboxylates of fatty acids; ketoester groups, such as acetoacetate derivatives; and -dialkylphosphate group, Here, all the ligands may be identical or different from one another.

[0025] Alternatively or additionally, the titanium-containing organometallic compound particularly preferably has at least one polydentate ligand as a ligand, which allows chelation. The polydentate ligand is preferably a bidentate ligand.

[0026] The titanium-containing organometallic compound is particularly preferably selected from the group consisting of bis(ethylacetoacetato)diisobutoxytitanium(IV), bis(ethylacetoacetato)diisopropoxytitanium(IV), bis(acetylacetonato)diisopropoxytitanium(IV), bis(acetylacetonato)diisobutoxytitanium(IV), tris(oxyethyl)amineisopropoxytitanium(IV), bis[tris(oxyethyl)amine]diisopropoxytitanium(IV), bis(2-ethylhexane-1,3-dioxy)titanium(IV), tris(oxyethyl)amineisopropoxytitanium(IV), Examples of suitable titanium acetylacetonates include bis[2-((2-aminoethyl)amino)ethoxy]ethoxytitanium(IV), bis(neopentyl(diallyl)oxydiethoxytitanium(IV), titanium(IV) tetrabutoxide, tetra(2-ethylhexyloxy)titanate, tetra(isopropoxy)titanate, tetrabutyl titanate, tetraisopropyl titanate, tetra-2-ethylhexyl titanate, and titanium acetylacetonate, as well as polybutyl titanate. Tetrabutyl titanate and tetraisopropyl titanate are particularly preferred due to their good price-performance ratio.

[0027] The hydroxy-terminated organic polymer of formula (III) is [ka] Preferably, they have a polymer backbone A selected from the group consisting of polyesters, polycarbonates, and copolymers with polyesters and / or polycarbonates. The expression "copolymers with polyesters and / or polycarbonates" is understood to mean polymers composed of two or more monomer units. In addition to alternating copolymers and graft copolymers, this term also includes, in particular, block polymers, which consist of relatively long sequences or blocks of each monomer, which may be linked to one another via linker compounds. Preferred combinations of blocks are as follows: - polyester and polycarbonate, -Various polyesters, polyesters and polyethers, or -Polycarbonates and polyethers.

[0028] The expression "copolymers with polyester and / or polycarbonate" means copolymers having at least one block composed of polyester and / or polycarbonate and containing additional blocks. In such copolymers, the polyester or polycarbonate content is at least 10% by weight, preferably at least 25% by weight, and most preferably at least 50% by weight. As a general rule, the higher the polyester and / or polycarbonate content, the higher the risk of degradation of the polymer backbone.

[0029] Examples of such a linker compound include the above-mentioned preferred combinations. Preferred linker compounds are urethane compounds, ester compounds and amide compounds, and particularly preferred are urethane compounds.

[0030] The polymer backbone A has one or more ester and / or carbonate groups. They preferably have more than two, particularly preferably more than 10, ester and / or carbonate groups. Within the present invention, the definition of polymer backbone A also includes: polymers extended with linker compounds, such as polymers end-extended with diols, polymers dimerized or oligomerized with diisocyanates or dicarboxylic acid dichlorides, and copolymers copolymerized with diisocyanates or dicarboxylic acid dichlorides. Such polymers may have one, two, or preferably three or more ester and / or carbonate groups in the polymer backbone. The greater the number of ester and / or carbonate groups, the greater the risk of degradation of the polymer backbone, which in turn affects the stability of the final product.

[0031] The term "hydroxy-terminated" refers to a polymer having free hydroxy groups at the ends of the molecule. y is a natural number between 1 and 10. In a preferred embodiment, y is 1, corresponding to an α,ω-dihydroxy-terminated organic polymer, i.e., a polymer having two terminal OH groups. When y is greater than 1, the hydroxy-terminated polyol has more than two terminal OH groups, i.e., it is a polyol whose OH groups are intended to react with the isocyanate of formula (IV). In the case of branched hydroxy-terminated polymers, the OH groups are preferably not directly attached to the polymer backbone, but rather to the ends of side chains of the polymer backbone. These can be obtained, for example, by reaction with polyols or polycarboxylic acids. Both linear and branched hydroxy-terminated organic polymers are known to those skilled in the art and are commercially available.

[0032] Polycarbonates can be obtained, for example, by reacting a diol (such as propylene glycol, butane-1,4-diol, hexane-1,6-diol, diethylene glycol, triethylene glycol, tetraethylene glycol, or a mixture of two or more thereof) with a diaryl carbonate (such as diphenyl carbonate or phosgene). However, the term polyester also includes polyester polyols, which are formed by reacting a low molecular weight alcohol or a mixture thereof, in particular ethylene glycol, diethylene glycol, propanediol, dipropylene glycol, neopentyl glycol, hexanediol, butanediol, pentanediol, hexanediol, propylene glycol, glycerol, or trimethylolpropane, with caprolactone, and whose terminal hydroxy groups are the hydroxy groups of the organic polymer of formula (III). Particularly preferably, the polymer backbone has a branched diol component. The branched diol component of such low molecular weight alcohols is used to produce polyesters or polycarbonates, and is particularly preferably a branched diol selected from the group consisting of 3-methylpentane-1,5-diol, 2-methylpropane-1,3-diol, 3-ethylpentane-1,5-diol, propane-1,2-diol, and 2,4-diethylpentane-1,5-diol, because the polymers produced therefrom have particularly good processability and durability.

[0033] A is particularly preferably a polycarbonate selected from the group consisting of polypropylene carbonate, polycyclohexene carbonate, poly(4,4'-isopropylidenediphenyl carbonate), poly(4,4'-diphenyl-1,1'-cyclohexane carbonate) and poly(propylenecyclohexene carbonate), etc.; or a polyester selected from the group consisting of poly(ethylene terephthalate) (PET), poly(ethylene naphthalate), poly(propylene terephthalate), polybutylene terephthalate (PBT), polycyclohexylene dimethylene-2,5-furandicarboxylate (PCF), polybutylene adipate-co-terephthalate (PBAT), polybutylene sebacate-co-terephthalate (PBSeT), polybutylene succinate-co-terephthalate (PBST), polybutylene 2,5-furandicarboxylate. -co-succinate (PBSF), polybutylene 2,5-furandicarboxylate-co-adipate (PBAF), polybutylene 2,5-furandicarboxylate-co-azelate (PBAzF), polybutylene 2,5-furandicarboxylate-co-sebacate (PBSeF), polybutylene 2,5-furandicarboxylate-co-brassate (PBBrF), polybutylene succinate (PBS), polybutylene adipate (PBA), poly(butylene succinate-co-adipate) (PBSA), poly(butylene succinate and poly(butylene-co-sebacate) (PBSSe), polybutylene sebacate (PBSe), or polyester polyols of at least one hydroxy group-containing component and at least one carboxy group-containing component, the at least one hydroxy group-containing component being, for example: propane-1,2-diol, 3-methylpentane-1,5-diol, 2-methylpropane-1,3-diol, 3-ethylpentane-1,5-diol, 2,4-diethylpentane-1,5-diol, neopentyl glycol, and 1,1,1-trimethylolpropane, and and mixtures thereof, wherein the at least one carboxy group-containing component is selected from: an aliphatic acid having two carboxy groups (e.g., succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, brassylic acid, dimer acid, etc.), or a dialkyl ester of an acid having two carboxy groups (e.g., dimethyl ester, diethyl ester, dipropyl ester, dibutyl ester, etc.), or a carboxylic acid chloride (e.g., acrylic acid chloride, methacrylic acid chloride, etc.);The acid may be selected from alicyclic dicarboxylic acids (e.g., 1,4-cyclohexanedicarboxylic acid, etc.), dialkyl ester acids having two carboxy groups (e.g., dimethyl ester, diethyl ester, dipropyl ester, dibutyl ester, etc.), aromatic acids having two carboxy groups (e.g., phthalic acid, isophthalic acid, terephthalic acid, naphthalenedicarboxylic acid, etc.), or dialkyl esters of acids having two carboxy groups (e.g., dimethyl ester, diethyl ester, dipropyl ester, dibutyl ester, etc.). Among these examples, the following are preferred: adipic acid, azelaic acid, sebacic acid, terephthalic acid, isophthalic acid, and naphthalenedicarboxylic acid. Alternatively, cyclic carboxylic anhydrides (e.g., phthalic anhydride, maleic anhydride, succinic anhydride, etc.), or cyclic carboxylic anhydrides having a side group (e.g., 3-methylglutaric anhydride, etc.) may be used. Aliphatic dicarboxylic acids or their esters having side groups, such as 2,4-diethylglutaric acid, 2,4-methylglutaric acid, 3-methylglutaric acid, and methylmalonic acid, may also be used. Particularly preferred are polyester polyols and polycarbonates containing more than 10 mol% of branched diols (e.g., 3-methylpentane-1,5-diol, 2-methylpropane-1,3-diol, 3-ethylpentane-1,5-diol, propane-1,2-diol, and 2,4-diethylpentane-1,5-diol) as hydroxyl group-containing components, since these have proven to be particularly stable. The proportion of branched diols is particularly preferably more than 50 mol% of the diols used. Preferred dicarboxylic acids are aliphatic dicarboxylic acids. The diols and dicarboxylic acids may also be petroleum-based or derived from renewable raw materials.

[0034] Preferably, the hydroxy-terminated organic polymer is liquid at room temperature, i.e., has a viscosity of 1 to 10 at 20°C. 6"viscosity" is understood to mean mPa·s. This viscosity is optimal for handling the compositions according to the invention, especially for producing sealant products. This is particularly true for hydroxy-terminated polymers having a polycarbonate homopolymer or a polyester homopolymer as the polymer backbone. In general, polyesters according to the invention have a relatively low viscosity and are cost-effective. Therefore, they are more suitable for some applications than polycarbonates according to the invention.

[0035] The hydroxy-terminated organic polymer preferably has an average molecular weight of 1000 to 20000 g / mol, in particular 2000 to 12000 g / mol, since this is the optimum for handling the polymer. In this specification, "molecular weight" is understood to mean the molar mass (grams / mol) of a molecule. "Average molecular weight" is the number-average molecular weight Mn of a polydisperse mixture of oligomeric or polymeric molecules, which is usually determined by titrating the acid number and OH number. The OH number (hydroxy number) is a measure of the hydroxy group content in a polymer and is a quantity known to those skilled in the art. The acid number is a measure of the acid group content in a polymer and is a quantity known to those skilled in the art.

[0036] The hydroxy-terminated organic polymers of formula (III) used in accordance with the present invention may be commercially available compounds, which may be optionally diluted with a plasticizer or solvent for better handling. However, it is important that they are produced tin-free (without tin), because even traces of tin catalyst in the hydroxy-terminated organic polymer of formula (III) will adversely affect the storage stability of the silane-terminated polymer, particularly the adhesive, sealant, and coating compositions produced therefrom. The same catalyst is preferably used in the production of the hydroxy-terminated organic polymer and the silane-terminated polymer, thereby eliminating the need to remove the catalyst from the hydroxy-terminated organic polymer, which is rational from a process engineering perspective and more environmentally friendly.

[0037] The catalyst is preferably used in an amount of 0.5 to 500 ppm of the hydroxy-terminated organic polymer of formula (III).

[0038] The isocyanates of formula (IV) used according to the invention are [ka] They are commercially available or may be prepared by standard methods in silicon chemistry. R1 and R2 are each independently a linear, branched, or cyclic hydrocarbon radical having 1 to 10 carbon atoms, optionally containing one or more heteroatoms selected from the group consisting of oxygen, sulfur, and nitrogen. n may have the value 1, 2, or 3, with values ​​2 or 3 being preferred because the silane-terminated polymers prepared therefrom have particularly balanced reactivity.

[0039] Preferably, R 1 and R 2 are each independently an alkyl radical, such as a methyl radical, ethyl radical, n-propyl radical, isopropyl radical, n-butyl radical, isobutyl radical, tert-butyl radical, n-pentyl radical, isopentyl radical, neopentyl radical, tert-pentyl radical, n-hexyl radical, n-heptyl radical, octyl radical, n-octyl radical, isooctyl radical, 2,2,4-trimethylpentyl radical, n-nonyl radical, decyl radical, n-decyl radical, dodecyl radical, or n-dodecyl radical. However, they may also be alkenyl radicals, such as vinyl or allyl radicals; cycloalkyl radicals, such as cyclopentyl, cyclohexyl, cycloheptyl and methylcyclohexyl radicals; allyl radicals, such as phenyl and naphthyl radicals; alkaryl radicals, such as o-, m-, p-tolyl, xylyl and ethylphenyl radicals; aralkyl radicals, such as benzyl, α-phenylethyl and β-phenylethyl radicals. The substituted radical R 1 Examples of are alkoxyalkyl radicals such as the ethoxyethyl and methoxyethyl radicals.

[0040] Preferably, the radical R 1 and R 2 are each independently a hydrocarbon radical having 1 to 6 carbon atoms, particularly preferably an alkyl radical having 1 to 4 carbon atoms, in particular a methyl or ethyl radical.

[0041] D is a linear or branched hydrocarbon group having 1 to 20 hydrocarbon atoms, which may optionally be interrupted by heteroatoms selected from the group consisting of oxygen, nitrogen and sulfur. Preferably, D is selected from the group consisting of methylene, ethylene, propylene, butylene, methylene oxide, ethylene oxide and propylene oxide, particularly preferably propylene or methylene, since this gives polymers with particularly balanced reactivity.

[0042] Examples of isocyanates of formula (IV) are isocyanatomethyldimethoxysilane, isocyanatopropyldimethylmethoxysilane, isocyanatomethylmethyldimethoxysilane, isocyanatopropylmethyldimethoxysilane, isocyanatomethyltrimethoxysilane, isocyanatomethyltriethoxysilane, and isocyanatopropyltrimethoxysilane, preferably isocyanatomethylmethyldimethoxysilane, isocyanatopropylmethyldimethoxysilane, isocyanatopropyltrimethoxysilane, isocyanatopropyltriethoxysilane, and isocyanatomethyltriethoxysilane.

[0043] The process according to the present invention for producing a silane-terminated polymer of formula (II) comprises reacting a hydroxy-terminated organic polymer of formula (III) with [ka] reacting with a polyfunctional isocyanate of formula (V), [ka] and then reacting with an alkoxysilane of formula (VI), [ka] Also here, neither the reactants nor the reaction used contain a tin catalyst.

[0044] Particularly suitable polyfunctional isocyanates of formula (V) are those containing two or more, preferably 2 to 10, isocyanate groups in the molecule. Suitable for this purpose are known aliphatic, cycloaliphatic, aromatic, oligomeric, and polymeric polyfunctional isocyanates that are free of isocyanate-reactive groups, i.e., in particular free of primary and / or secondary amino groups. A representative example of an aliphatic polyfunctional isocyanate is hexamethylene diisocyanate (HDI); a representative example of a cycloaliphatic polyfunctional isocyanate is 1-isocyanato-3-(isocyanatomethyl)-3,5,5-trimethylcyclohexane. Representative aromatic polyfunctional isocyanates include 2,4- and 2,6-diisocyanatotoluene and the corresponding technical isomer mixtures (TDI); diphenylmethane diisocyanates, such as diphenylmethane-4,4'-diisocyanate, diphenylmethane-2,4'-diisocyanate, diphenylmethane-2,2'-diisocyanate and the corresponding technical isomer mixtures (MDI). Furthermore, naphthalene-1,5-diisocyanate (NDI) and 4,4',4''-triisocyanatriphenylmethane should also be mentioned.

[0045] The alkoxysilane of formula (VI) is preferably selected from the group consisting of 3-aminopropyltrimethoxysilane, 3-aminopropyldimethoxymethylsilane, 3-amino-2-methylpropyltrimethoxysilane, 4-aminobutyltrimethoxysilane, 4-aminobutyldimethoxymethylsilane, 4-amino-3-methylbutyltrimethoxysilane, 4-amino-3,3-dimethylbutyltrimethoxysilane, 4-amino-3,3-dimethylbutyldimethoxymethylsilane, 2-aminoethyltrimethoxysilane, 2-aminoethyldimethoxysilane. Dimethylsilane, aminomethyltrimethoxysilane, aminomethyldimethoxymethylsilane, aminomethylmethoxydimethylsilane, and 7-amino-4-oxaheptyldimethoxymethylsilane, N-(2-aminoethyl)-3-aminopropyltrimethoxysilane, N-(2-aminoethyl)-3-aminopropylmethyldimethoxysilane, N-(2-aminoethyl)-3-aminopropyltriethoxysilane, 3-[2-(2-aminoethylamino)ethylamino]propyltrimethoxysilane, 3-[2-(2-aminoethylamino)ethylamino]propyltrimethoxysilane, ]propyltriethoxysilane, 3-[2-(2-aminoethylamino)ethylamino]propylmethyldimethoxysilane, [3-(1-piperazinyl)propyl]triethoxysilane, [3-(1-piperazinyl)propyl]trimethoxysilane, [3-(1-piperazinyl)propyl]methyldimethoxysilane, N-(n-butyl)-3-aminopropyltrimethoxysilane, N-(n-butyl)-3-aminopropylmethyldimethoxysilane, N-(n-butyl)-3-aminopropyltriethoxysilane, N-ethylaminoisobutyltrimethoxy Silane, N-ethylaminoisobutylmethyldimethoxysilane, N-cyclohexyl-3-aminopropyltriethoxysilane, N-cyclohexyl-3-aminopropyltrimethoxysilane, N-cyclohexylaminomethyltriethoxysilane, N-cyclohexylaminomethyltrimethoxysilane, N-cyclohexylaminomethyldimethoxymethylsilane, bis(trimethoxysilylpropyl)amine, 3-mercaptopropyltrimethoxysilane, 3-mercaptopropyltriethoxysilane, 3-mercaptopropylmethyldimethoxysilane.

[0046] An additional catalyst may optionally be used to promote urethane or urea linkages, which does not adversely affect the shelf stability of the product and the adhesive, sealant or coating material produced therefrom.

[0047] Preferably, the catalyst comprises: alkali metal carboxylates, such as lithium neodecanoate, lithium ethylhexanoate, lithium laurate, lithium stearate, potassium neodecanoate, potassium ethylhexanoate, or potassium laurate; alkaline earth metal carboxylates, such as calcium trimethylhexanoate, calcium neodecanoate, calcium laurate, strontium ethylhexanoate or strontium laurate; - Carboxylate salts of transition group elements, such as cobalt ethylhexanoate, cobalt stearate, cobalt laurate, cobalt neodecanoate, manganese ethylhexanoate, manganese stearate, manganese laurate, iron stearate, iron ethylhexanoate, iron laurate, copper stearate, copper laurate, copper neodecanoate, copper ethylhexanoate, etc. - carboxylates from group 13 elements, such as indium salts and aluminium salts, - salts from group 14 elements, such as lead salts, salts from group 15 elements, such as phosphorus salts and phosphate esters or antimony salts; tertiary amines, such as tributylamine, 1,4-diazabicyclo[2.2.2]octane, 1,8-diazabicyclo[5.4.0]undec-7-ene, 1,5-diazabicyclo[4.3.0]non-5-ene, N,N-bis(N,N-dimethyl-2-aminoethyl)methylamine, N,N-dimethylcyclohexylamine, N,N-dimethylphenylamine or ethylmorpholinine; - ionic liquids, such as those based on ammonium, imidazolium, phosphonium, pyridinium, pyrrolidinium or sulfonium; short-chain organic acids having 1 to 10 carbon atoms, such as acetic acid, - inorganic acids such as phosphoric acid and its monoesters, such as butyl phosphate, dibutyl phosphate, and propyl phosphate.

[0048] These additional catalysts may be used alone or in combination.

[0049] Very particularly preferably, the additional catalyst is selected from the group consisting of: lithium neodecanoate, lithium ethylhexanoate, lithium laurate, lithium stearate, manganese ethylhexanoate, manganese neodecanoate, manganese laurate, manganese stearate, cobalt ethylhexanoate, cobalt laurate, cobalt stearate, and cobalt neodecanoate. Particularly preferably, the additional catalyst is formulated together with the titanium-containing organometallic compound.

[0050] The catalyst is preferably added in an amount of 1 to 1000 ppm, particularly preferably 5 to 500 ppm, very particularly preferably 5 to 200 ppm.

[0051] Particularly preferably, the linear silane-terminated polymer is selected from the group consisting of the following formulas: where A is the polymer backbone as defined above. [ka]

[0052] The reaction is preferably carried out at a temperature of 50° C. to 150° C., particularly preferably 60° C. to 120° C., and preferably at standard pressure.

[0053] The crosslinkable compositions produced according to the present invention are outstandingly suitable as sealing compounds for joints (including vertical joints) and similar gaps, for example, in buildings, land vehicles, water vehicles, and air vehicles, or as adhesives or cement compounds, for example, in the manufacture of window structures or showcases, and also for the production of protective coatings or elastomeric moldings and the insulation of electrical or electronic equipment. The compositions according to the present invention are particularly suitable as sealant compounds for joints with as high a resistance to movement as possible. The adhesives, sealants, and coating materials according to the present invention have significantly better weathering stability than standard products. As a result of their significantly better weathering stability, the coating materials according to the present invention are particularly suitable for roof waterproofing and surface waterproofing, or for coating other surfaces exposed to severe weather.

[0054] The normal water content of air is sufficient for crosslinking the compositions according to the invention. Crosslinking can be carried out at room temperature or, if desired, at higher or lower temperatures, for example, between -5°C and 10°C or between 30°C and 50°C. Crosslinking is preferably carried out at standard pressure.

[0055] The silane-terminated polymers according to the present invention may be formulated as a two-component system. In addition to the coagent, the second component also contains water, which significantly promotes deep penetration curing after mixing with the first component. Corresponding two-component systems are known to those skilled in the art and are described, for example, in EP 2009063 A1 or EP 2535376 A1, the contents of which are incorporated by reference.

[0056] The product according to the present invention may also contain additional auxiliaries and additives, which likewise must not contain any tin catalyst. Such auxiliaries and additives include, for example, additional silane-terminated polymers, plasticizers, stabilizers, antioxidants, fillers, reactive diluents, drying agents, adhesion promoters and UV stabilizers, rheological aids, color pigments or color pastes, and / or optionally also small amounts of solvents. Such auxiliaries and additives are known to those skilled in the art.

[0057] Example [Example]

[0058] Example 1 (according to the invention) 234 g of polyester polyol P-4010 (Kuraray Co., Ltd.), synthesized using an organotitanate catalyst (titanium(IV) isopropoxide) and having a hydroxyl value of 28.7 mg KOH / g, was heated to 90°C with stirring. 22.4 g of (trimethoxysilyl)propyl isocyanate was added and stirred at 90°C. After 90 minutes, no free isocyanate was detected by FT-IR. The resulting trimethoxysilane-terminated polyester was used to formulate an adhesive. [Example]

[0059] Example 2 (according to the invention) 229 g of polyester polyol SS 4080 (Songstar), synthesized using an organotitanate catalyst and having a hydroxyl value of 29.4 mg KOH / g, was heated to 90°C with stirring. 22.4 g of (trimethoxysilyl)propyl isocyanate was added and stirred at 90°C. After 90 minutes, no free isocyanate was detected by FT-IR. The resulting trimethoxysilane-terminated polyester was used to formulate an adhesive.

[0060] Comparative Example 3 (not according to the invention) 240 g of polyester polyol SS 4080S (Songstar), synthesized using an organotin catalyst and having a hydroxyl value of 28.0 mg KOH / g, was heated to 90°C with stirring. 22.4 g of (trimethoxysilyl)propyl isocyanate was added and stirred at 90°C. After 600 minutes, no free isocyanate was detected by FT-IR. The resulting trimethoxysilane-terminated polyester was used to formulate an adhesive.

[0061] Comparative Example 4 (not according to the invention) 229 g of polyester polyol SS 4080 (Songstar), synthesized using an organotitanate catalyst and having a hydroxyl value of 29.4 mg KOH / g, was heated to 90°C with stirring. 63 mg of dibutyltin dilaurate as a tin catalyst and 22.4 g of (trimethoxysilyl)propyl isocyanate were added, and the mixture was stirred at 90°C. After 90 minutes, no free isocyanate was detected by FT-IR. The resulting trimethoxysilane-terminated polyester was used to formulate an adhesive.

[0062] Comparative Example 5 (not according to the invention) 240 g of polyester polyol SS 4080S (Songstar), synthesized using an organotin catalyst and having a hydroxyl value of 28.0 mg KOH / g, was heated to 90°C with stirring. 75 mg of dibutyltin dilaurate as a tin catalyst and 22.4 g of (trimethoxysilyl)propyl isocyanate were added, and the mixture was stirred at 90°C. After 90 minutes, no free isocyanate was detected by FT-IR. The resulting trimethoxysilane-terminated polyester was used to formulate an adhesive. The results are shown in Figure 1 (Table 1).

[0063] The final adhesive is stable only if tin catalysts are not present during the formation of the hydroxy-terminated polyester, its reaction with the isocyanate silane, and its formulation as an adhesive, sealant, or coating material. Otherwise, the Shore A hardness (measured according to DIN 53505) and tensile strength (measured according to DIN 53504) decrease significantly after the sealant has been stored in a cartridge at room temperature for 4 to 8 weeks. At higher storage temperatures, the mechanical properties decrease even more rapidly in the presence of tin catalysts.

[0064] The following table shows the stability of the compositions after 8 weeks and after 32 weeks:

[0065] [Table 1]

[0066] [Table 2]

[0067] [Table 3]

[0068] nc indicates normal climate, 23°C, relative humidity 50%, * indicates within the specified curing time This means that no cross-linking occurs. The present disclosure includes the following aspects. <Aspect 1> A method for producing a silane-terminated polymer of formula (I) or (II): [ka] [ka] In the presence of a catalyst, a hydroxy-terminated organic polymer of formula (III): [ka] a) by reacting with an isocyanate of formula (IV): [ka] b) reacting with a polyfunctional isocyanate of formula (V): [ka] Then, by reacting with an alkoxysilane of formula (VI): [ka] forming a silane-terminated polymer of formula (I) or formula (II), D is a linear or branched hydrocarbon group having 1 to 20 hydrocarbon atoms, which may optionally be interrupted by heteroatoms selected from the group consisting of oxygen, nitrogen, and sulfur; A is a polymer backbone selected from the group consisting of polycarbonates, polyesters, copolymers comprising polyesters and / or polycarbonates, and polymers comprising at least one ester and / or carbonate group; R 1 、R 1 ’、R 2 and R 2 each independently represents a linear, branched, or cyclic hydrocarbon group having 1 to 10 carbon atoms, which may optionally contain one or more heteroatoms selected from the group consisting of oxygen, sulfur, and nitrogen; n is 1, 2 or 3; x and y are natural numbers from 1 to 10, G is a linear or branched hydrocarbon group having 1 to 20 hydrocarbon atoms, which may optionally be interrupted by heteroatoms selected from the group consisting of oxygen, nitrogen, and sulfur; F is a linear, branched, or cyclic organic group that does not contain an isocyanate-reactive group; m is a natural number greater than 1, E is a reactive group that reacts with an isocyanate group, NH 2 , NHR 4 and SH, wherein R 4 is a linear, branched or cyclic hydrocarbon group having 1 to 10 carbon atoms, which may optionally contain one or more heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen; A method characterized in that neither the reactants nor the reaction used contain a tin catalyst. <Aspect 2> 2. The method of aspect 1, wherein A is a polymer backbone selected from the group consisting of polycarbonates, polyesters, copolymers comprising polyesters and / or polycarbonates, and polymers comprising at least three ester and / or carbonate groups, preferably a polymer backbone selected from polycarbonates, polyesters, and copolymers comprising polyesters and / or polycarbonates. <Aspect 3> the polymer backbone has a branched diol moiety; Preferably, it is selected from the group consisting of 3-methylpentane-1,5-diol, 2-methylpropane-1,3-diol, 3-ethylpentane-1,5-diol and 2,4-diethylpentane-1,5-diol, Particularly preferably, the branched diol component is selected from the group consisting of 3-methylpentane-1,5-diol, 2-methylpropane-1,3-diol, 3-ethylpentane-1,5-diol, propane-1,2-diol, and 2,4-diethylpentane-1,5-diol, which account for more than 10 mol % of the hydroxy group-containing components of the polyester or polycarbonate. 3. The method according to aspect 1 or 2, <Aspect 4> A method according to any one of aspects 1 to 3, characterized in that the reaction is carried out using an isocyanate of formula (IV).

change

change

change

Claims

1. 1. A method for producing a silane-terminated polymer of formula (I) or (II) for use as an adhesive, sealant or coating material, comprising: 【Chemistry 1】 【Chemistry 2】 In the presence of a catalyst, a hydroxy-terminated organic polymer of formula (III): 【Transformation 3】 a) by reacting with an isocyanate of formula (IV): 【Chemistry 4】 b) reacting with a polyfunctional isocyanate of formula (V): 【Transformation 5】 Then, by reacting with an alkoxysilane of formula (VI): 【Transformation 6】 forming a silane-terminated polymer of formula (I) or formula (II), D is a linear or branched hydrocarbon group having 1 to 20 hydrocarbon atoms, which may optionally be interrupted by heteroatoms selected from the group consisting of oxygen, nitrogen, and sulfur; A is a polymer backbone selected from the group consisting of polycarbonates, polyesters, copolymers comprising polyesters and / or polycarbonates, and polymers comprising at least one ester and / or carbonate group; R 1 , R 1 ', R 2 and R 2 ' are each independently a linear, branched or cyclic hydrocarbon group having 1 to 10 carbon atoms, which may optionally contain one or more heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen; n is 1, 2 or 3; x and y are natural numbers from 1 to 10, G is a linear or branched hydrocarbon group having 1 to 20 hydrocarbon atoms, which may optionally be interrupted by heteroatoms selected from the group consisting of oxygen, nitrogen, and sulfur; F is a linear, branched, or cyclic organic group that does not contain an isocyanate-reactive group; m is a natural number greater than 1, E is a reactive group that reacts with an isocyanate group, and is NH ２ , N.H.R. ４ and SH, wherein R ４ is a linear, branched or cyclic hydrocarbon group having 1 to 10 carbon atoms, which may optionally contain one or more heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen; 1. A process characterized in that none of the reactants or reactions used contain a tin catalyst, and the polymer backbone has branched diol components selected from the group consisting of 3-methylpentane-1,5-diol, 2-methylpropane-1,3-diol, 3-ethylpentane-1,5-diol, propane-1,2-diol, and 2,4-diethylpentane-1,5-diol, which account for greater than 10 mole percent of the hydroxy group-containing components of the polyester or polycarbonate.

2. 2. The method of claim 1, wherein A is a polymer backbone selected from the group consisting of polycarbonates, polyesters, copolymers comprising polyesters and / or polycarbonates, and polymers comprising at least three ester and / or carbonate groups.

3. 3. The process according to claim 1 or 2, characterized in that the reaction is carried out with an isocyanate of formula (IV). 【Transformation 7】

4. The silane-terminated polymer is a linear polymer of the following general formula (IA): 【Transformation 8】 The method according to any one of claims 1 to 3, wherein D, A, R 1 , R 2 and n are the same as D, A, R 1 , R 2 and n in formula (I), respectively.

5. The silane-terminated polymer is a branched polymer of the following general formula (IB): 【Chemistry 9】 where x and y each correspond to a natural number from 2 to 10, The method according to any one of claims 1 to 3, wherein D, A, R 1 , R 2 and n are the same as D, A, R 1 , R 2 and n in formula (I), respectively.

6. 6. The method of claim 5, wherein the silane-terminated polymer of formula (IB) is free of free hydroxy groups.

7. 7. The method according to claim 1, wherein both the formation of the reactant and the formation of the silane-terminated polymer of general formula (I) or (II) are carried out using the same catalyst.

8. 8. The process according to claim 1, wherein the reaction is carried out in the presence of a titanium-containing organometallic compound.

9. The titanium-containing organometallic compound is selected from the group consisting of bis(ethylacetoacetato)diisobutoxytitanium(IV), bis(ethylacetoacetato)diisopropoxytitanium(IV), bis(acetylacetonato)diisopropoxytitanium(IV), bis(acetylacetonato)diisobutoxytitanium(IV), tris(oxyethyl)amineisopropoxytitanium(IV), bis[tris(oxyethyl)amine]diisopropoxytitanium(IV), bis(2-ethylhexane-1,3-dioxy)titanium(IV), tris 9. The method of claim 8, wherein the titanium acetylacetonate is selected from the group consisting of [2-((2-aminoethyl)amino)ethoxy]ethoxytitanium(IV), bis(neopentyl(diallyl)oxydiethoxytitanium(IV), titanium(IV) tetrabutoxide, tetra(2-ethylhexyloxy)titanate, tetra(isopropoxy)titanate, tetrabutyl titanate, tetraisopropyl titanate, tetra-2-ethylhexyl titanate, and titanium acetylacetonate, and polybutyl titanate.

10. 10. The method of claim 9, wherein the titanium-containing organometallic compound is selected from the group consisting of tetrabutyl titanate and tetraisopropyl titanate.

11. 11. The process according to any one of claims 1 to 10, characterized in that the reaction is carried out in the presence of an additional catalyst.

12. 12. The method of claim 11, wherein the additional catalyst is selected from the group consisting of alkali metal carboxylates, alkaline earth metal carboxylates, transition group element carboxylates, Group 13 carboxylates, lead salts, phosphorus salts, phosphate esters, antimony salts, tertiary amines, ionic liquids, organic acids having 1 to 10 carbon atoms, and inorganic acids.

13. 13. The method according to any one of claims 1 to 12, characterized in that the catalyst is not removed after the reaction is complete.

14. The method according to any one of claims 1 to 13, characterized in that the polymer backbone is a polyester.

15. 15. The method according to any one of claims 1 to 14, characterized in that the isocyanate of formula (IV) is selected from the group consisting of (isocyanatopropyl)trimethoxysilane, (isocyanatopropyl)methyldimethoxysilane, (isocyanatopropyl)triethoxysilane, (isocyanatomethyl)methyldimethoxysilane and (isocyanatomethyl)triethoxysilane.

16. 16. A composition comprising the silane-terminated polymer of any one of claims 1 to 15 for use as an adhesive, sealant or coating material, characterized in that the composition does not contain a tin catalyst.

Images