Foam sheets and adhesive tapes

Abstract

A foam sheet according to the present invention has a stress relaxation rate of 23% or greater and a 25% compressive strength of 1000 kPa or less. An adhesive tape according to the present invention comprises the foam sheet according to the present invention and an adhesive material provided on at least one surface of a multilayered foam sheet thereof. According to the present invention, it is possible to provide a foam sheet in which permanent strain can be increased and an adhesive tape in which the foam sheet is used.

Description

[Technical Field]

[0001] The present invention relates to a foam sheet and an adhesive tape including the foam sheet. [Background technology]

[0002] In electronic devices such as mobile phones, cameras, displays, game devices, electronic notebooks, and personal computers, pressure-sensitive adhesive tapes using foam sheets are widely used as sealing materials or shock-absorbing materials. As a foam used in pressure-sensitive adhesive tapes used as such sealing materials or shock-absorbing materials, for example, the acrylic foam described in Patent Document 1 is known. Pressure-sensitive adhesive tapes using this acrylic foam can be suitably used as sealing materials or shock-absorbing materials. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Special Publication No. 2012-519750 Summary of the Invention [Problem to be solved by the invention]

[0004] In recent years, electronic devices with curved structures have been increasingly sold for their design. When adhesive tapes using foam sheets are used as sealants or shock absorbers in such electronic devices, the adhesive tape is sometimes applied to curved surfaces to secure components. While the adhesive tape must be flexible to conform to the curved surface, variations in the tolerances of the curved surfaces can sometimes cause problems, such as lifting of the components.

[0005] The present inventors have conducted extensive research to solve the above problems, and have found that problems such as lifting of fixed members can be solved by increasing the permanent set of a foam sheet in addition to imparting flexibility. Therefore, an object of the present invention is to provide a foam sheet capable of increasing the permanent set, and a pressure-sensitive adhesive tape using the foam sheet. [Means for solving the problem]

[0006] The present inventors have conducted extensive research into the permanent set of foam sheets and have found that the above-described problems can be solved by increasing the stress relaxation rate and decreasing the 25% compressive strength of the foam sheet, thereby completing the present invention. That is, the present invention provides the following [1] to

[10] .

[0007] [1] A foam sheet having a stress relaxation rate of 23% or more and a 25% compressive strength of 1000 kPa or less. [2] The foam sheet according to [1] above, having an interlaminar strength of 0.6 MPa or more. [3] The foam sheet according to [1] or [2] above, wherein the closed cell ratio is 80% or more. [4] The foam sheet according to any one of the above [1] to [3], which has a gel fraction of 30 to 80%. [5] The foam sheet according to any one of the above [1] to [4], wherein the larger of the MD flatness and TD flatness of the cells is 2 or more. [6] Density: 0.05 to 0.6 g / cm 3 The foam sheet according to any one of the above items [1] to [5], wherein: [7] The foam sheet according to any one of the above [1] to [6], which has a thickness of 0.03 to 2 mm. [8] The foam sheet according to any one of the above [1] to [7], which has at least one temperature in the range of 15 to 50° C. showing a maximum value of the loss tangent (tanδ) of dynamic viscoelasticity. [9] The foam sheet according to any one of the above [1] to [8], which has a maximum value of the loss tangent (tanδ) of dynamic viscoelasticity of 0.2 or more.

[10] An adhesive tape comprising the foam sheet according to any one of the above [1] to [9] and an adhesive material provided on at least one surface of the foam sheet. [Effects of the Invention]

[0008] According to the present invention, it is possible to provide a foam sheet capable of increasing permanent deformation and a pressure-sensitive adhesive tape using the foam sheet. [Brief explanation of the drawings]

[0009] [Figure 1] FIG. 2 is a schematic diagram showing an interlaminar strength measuring device. DETAILED DESCRIPTION OF THE INVENTION

[0010] The present invention will be described in detail below using embodiments. [Foam sheet] The foam sheet of the present invention has a stress relaxation rate of 23% or more and a 25% compressive strength of 1000 kPa or less. This allows the foam sheet to have a large permanent set. This also prevents problems such as lifting of a member fixed with the adhesive tape, even if the curved surface to which the adhesive tape using the foam sheet is attached has variations in the tolerance of the curved surface.

[0011] (Stress relaxation rate) The stress relaxation rate of the foam sheet of the present invention is 23% or more. If the stress relaxation rate of the foam sheet is less than 23%, the permanent set of the foam sheet may be insufficient, and the foam sheet may not be able to fully relax the tolerance variations of the curved surface. As a result, problems such as lifting may occur in components fixed using an adhesive tape made of the foam sheet. From this perspective, the stress relaxation rate of the foam sheet of the present invention is preferably 25% or more, more preferably 27% or more, even more preferably 30% or more, still more preferably 33% or more, and even more preferably 35% or more. The upper limit of the range of the stress relaxation rate of the foam sheet of the present invention is not particularly limited, but is 60% from the viewpoint of sealing properties. The stress relaxation rate of the foam sheet can be measured by the method described in the Examples below. The stress relaxation rate of the foam sheet can be controlled by adjusting the types and proportions of resins constituting the foam sheet, the flatness of the cells, the thickness of the foam sheet, the density of the foam sheet, the maximum value of the loss tangent (tan δ) of the dynamic viscoelasticity of the foam sheet, and the temperature at which the maximum value is shown (glass transition temperature (Tg)).

[0012] (25% compressive strength) The 25% compression strength of the foam sheet of the present invention is 1000 kPa or less. If the 25% compression strength of the foam sheet is greater than 1000 kPa, the foam sheet may not be able to adequately conform to a curved surface. As a result, problems such as peeling of the adhesive tape made of the foam sheet from a member to which the tape is fixed may occur. From this perspective, the 25% compression strength of the foam sheet is preferably 700 kPa or less, more preferably 500 kPa or less, and even more preferably 200 kPa or less. The lower limit of the range of the 25% compression strength of the foam sheet of the present invention is not particularly limited, but is usually 5 kPa. The 25% compression strength of the foam sheet can be measured by the method described in the Examples below. In addition, the 25% compressive strength of the foam sheet can be controlled by adjusting the type and proportion of resins constituting the foam sheet, the flatness of the cells, the thickness of the foam sheet, the density of the foam sheet, the maximum value of the loss tangent (tan δ) of the dynamic viscoelasticity of the foam sheet, and the temperature at which the maximum value is shown (glass transition temperature (Tg)).

[0013] (Interlaminar strength) The interlaminar strength of the foam sheet of the present invention is preferably 0.6 MPa or more. When the foam sheet has an interlaminar strength of 0.6 MPa or more, the strength of the adhesive tape can be increased when the foam sheet is used in the adhesive tape, thereby preventing the adhesive tape from being destroyed by external impact. From this perspective, the interlaminar strength of the foam sheet is more preferably 1.0 MPa or more, and even more preferably 1.5 MPa or more. The upper limit of the range of the interlaminar strength of the foam sheet of the present invention is not particularly limited, but is typically 10 MPa. The interlaminar strength of the foam sheet can be measured by the method described in the Examples below. The interlaminar strength of the foam sheet can be controlled by adjusting the type and proportion of resins constituting the foam sheet, the cell oblateness, the thickness of the foam sheet, the density of the foam sheet, the maximum value of the loss tangent (tan δ) of the dynamic viscoelasticity of the foam sheet, and the temperature at which this maximum value is reached (glass transition temperature (Tg)).

[0014] (closed cell ratio) The closed cell ratio of the foam sheet of the present invention is preferably 80% or more. If the closed cell ratio of the foam sheet is 80% or more, the dustproof and waterproof properties of the foam sheet can be improved when the foam sheet is used as a sealing material. From this perspective, the closed cell ratio of the foam sheet is more preferably 90% or more, and even more preferably 95% or more. The upper limit of the range of the closed cell ratio of the foam sheet of the present invention is not particularly limited, but is usually 100%. The closed cell ratio of the foam sheet can be measured by the method described in the Examples below.

[0015] (gel fraction) The gel fraction of the foam sheet of the present invention is preferably 30 to 80%. When the gel fraction of the foam sheet is 30 to 80%, the bubbles in the foam sheet can be made smaller and the interlaminar strength can be improved. From these viewpoints, the gel fraction of the multilayer foam sheet is more preferably 35 to 70%, and even more preferably 40 to 65%. The gel fraction of the foam sheet can be measured by the method described in the Examples below.

[0016] (Bubble flatness) Of the MD and TD flattening ratios of the cells of the foam sheet of the present invention, the larger one is preferably 2 or more. In this specification, "MD" refers to machine direction, which is the same direction as the extrusion direction of the sheet, etc. "TD" refers to transverse direction, which is the direction perpendicular to MD and parallel to the surface of the sheet. When the larger one of the MD and TD flattening ratios of the cells is 2 or more, the restoring force of the cells in the thickness direction is suppressed, thereby making it easier to achieve a stress relaxation rate of 23% or more of the foam sheet. From this perspective, the larger one of the MD and TD flattening ratios of the cells is more preferably 3 or more, and even more preferably 4 or more. The MD and TD flattening ratios of the cells in the foam sheet can be measured by the method described in the Examples below. Furthermore, the MD and TD flattening ratios of the cells in the foam sheet can be adjusted by stretching the foam sheet in at least one of MD and TD during the production of the foam sheet. From the viewpoint of the stress relaxation rate of the foam sheet, it is more preferable that both the MD and TD flattening ratios of the cells are 2 or more.

[0017] (average bubble diameter) The average cell diameter of the foam sheet of the present invention is preferably 5 to 400 μm. As described below, the foam sheet may be used in any shape, but is preferably narrow. When the average cell diameter of the foam sheet is 10 to 300 μm, sufficient waterproofing of the foam sheet can be ensured even when the foam sheet is narrow. From this perspective, the average cell diameter of the foam sheet of the present invention is more preferably 10 to 250 μm, and even more preferably 10 to 200 μm. The average cell diameter of the foam sheet can be measured by the method described in the Examples below, and the average cell diameter here refers to the average value of the average cell diameters in MD and TD.

[0018] (density) The density of the foam sheet of the present invention is preferably 0.05 to 0.6 g / cm 3The density of the foam sheet is 0.05 to 0.6 g / cm 3 This makes it easier to set the stress relaxation rate of the foam sheet to 23% or more and the 25% compressive strength of the foam sheet to 1000 kPa or less. From this viewpoint, the density of the foam sheet of the present invention is more preferably 0.07 to 0.57 g / cm. 3 and more preferably 0.10 to 0.55 g / cm 3 The density of the foam sheet can be measured by the method described in the Examples below.

[0019] (Expansion ratio) The expansion ratio of the foam sheet of the present invention is preferably 1.5 times or more. When the expansion ratio of the foam sheet is 1.5 times or more, it becomes easier to achieve a stress relaxation rate of 23% or more and a 25% compressive strength of 1000 kPa or less. From this perspective, the expansion ratio of the foam sheet of the present invention is more preferably 4 times or more, and even more preferably 5 times or more. The upper limit of the range of the expansion ratio of the foam sheet of the present invention is not particularly limited, but is usually 30 times, and preferably 20 times. The expansion ratio of the foam sheet can be measured by the method described in the Examples below.

[0020] (Thickness) The foam sheet of the present invention preferably has a thickness of 0.03 to 2 mm. When the foam sheet has a thickness of 0.03 to 2 mm, it becomes easier to set the stress relaxation rate of the foam sheet to 23% or more and the 25% compressive strength of the foam sheet to 1000 kPa or less. From this perspective, the thickness of the foam sheet of the present invention is more preferably 0.05 to 1.5 mm, and even more preferably 0.07 to 1 mm. The thickness of the foam sheet can be measured by the method described in the Examples below.

[0021] (loss tangent (tanδ)) The foam sheet of the present invention preferably has at least one temperature in the range of 15 to 50°C at which the loss tangent (tan δ) of dynamic viscoelasticity shows a maximum. Having at least one temperature in the range of 15 to 50°C at which the loss tangent (tan δ) of dynamic viscoelasticity shows a maximum makes it easier to achieve a stress relaxation rate of 23% or more. From this perspective, it is more preferable that the loss tangent (tan δ) of dynamic viscoelasticity shows a maximum at least one temperature in the range of 15 to 47°C, and even more preferable that the loss tangent (tan δ) of dynamic viscoelasticity shows a maximum at least one temperature in the range of 23 to 43°C. Note that the tan δ of the foam sheet is the loss tangent measured at a measurement frequency of 10 Hz. Tan δ is the ratio (G'' / G') of the storage shear modulus (G') to the loss shear modulus (G''), and indicates how much energy a material absorbs (converts to heat) when it deforms. The temperature at which the loss tangent (tan δ) of the dynamic viscoelasticity of the foam sheet exhibits a maximum value is usually the glass transition temperature (Tg) of the foam sheet.

[0022] The maximum value of the loss tangent (tan δ) of the foam sheet of the present invention is preferably 0.2 or more. When the tan δ of the foam sheet is 0.2 or more, it becomes easier to achieve a stress relaxation rate of 23% or more of the foam sheet. From this perspective, the maximum value of tan δ of the foam sheet of the present invention is more preferably 0.3 or more, and even more preferably 0.4 or more. The upper limit of the range of the maximum value of tan δ of the foam sheet of the present invention is not particularly limited, but is usually 3. The maximum value here preferably indicates a temperature in the range of 15 to 50°C.

[0023] The maximum value of tan δ of a foam sheet and the temperature at which the maximum value is shown can be measured by the method described in Examples below. The maximum value of tan δ, the number of tan δ maxima, and the temperature at which the maximum value of tan δ is shown can be controlled by adjusting the type and proportion of resins constituting the foam sheet, the cell oblateness, the thickness of the foam sheet, the density of the foam sheet, etc.

[0024] [Resin that makes up the foam sheet] The foam sheet of the present invention may contain an elastomer (A), and preferably contains an elastomer (A) and a polyolefin resin (B). By using an elastomer and a polyolefin resin, it becomes easy to set the stress relaxation rate of the foam sheet to 23% or more and the 25% compressive strength to 1000 kPa or less.

[0025] (Elastomer (A)) Examples of the elastomer (A) include thermoplastic elastomers, ethylene-α-olefin copolymer rubbers, and amorphous 4-methyl-1-pentene copolymers. Examples of the thermoplastic elastomer include olefin thermoplastic elastomers, styrene thermoplastic elastomers, vinyl chloride thermoplastic elastomers, polyurethane thermoplastic elastomers, polyester thermoplastic elastomers, and polyamide thermoplastic elastomers. The elastomer (A) may be used alone or in combination of two or more of these components. Among these, olefin-based thermoplastic elastomers, styrene-based thermoplastic elastomers, ethylene-α-olefin-based copolymer rubbers, and amorphous 4-methyl-1-pentene copolymers are preferred, styrene-based thermoplastic elastomers and amorphous 4-methyl-1-pentene copolymers are more preferred, and styrene-based thermoplastic elastomers are even more preferred.

[0026] <Olefin-based thermoplastic elastomer> Olefin-based thermoplastic elastomers (TPO) generally have polyolefins such as polyethylene and polypropylene as hard segments and rubber components such as butyl rubber, halobutyl rubber, EPDM (ethylene-propylene-diene rubber), EPM (ethylene-propylene rubber), NBR (acrylonitrile-butadiene rubber), and natural rubber as soft segments. Any of the blend, dynamic crosslink, and polymerization types of olefin-based thermoplastic elastomers (TPO) can be used. Specific examples of suitable rubber components include the above-mentioned EPM and EPDM, with EPDM being particularly preferred. EPDM includes ethylene-propylene-5-ethylidene-2-norbornene copolymer rubber and ethylene-propylene-dicyclopentadiene copolymer rubber, with ethylene-propylene-dicyclopentadiene copolymer rubber being preferred.

[0027] Further, the olefin-based thermoplastic elastomer may be a block copolymer type. The block copolymer type may include those having a crystalline block and a soft segment block, and more specifically, a crystalline olefin block-ethylene-butylene copolymer-crystalline olefin block copolymer (CEBC) may be exemplified. In the CEBC, the crystalline olefin block is preferably a crystalline ethylene block. Commercially available products of such CEBC include "DYNARON" manufactured by JSR Corporation. 6200P" and others.

[0028] <Styrene-based thermoplastic elastomer> Examples of styrene-based thermoplastic elastomers include block copolymers having a styrene polymer or copolymer block and a conjugated diene compound polymer or copolymer block, such as isoprene and butadiene. The styrene-based thermoplastic elastomer used in the present invention may or may not be hydrogenated, but is preferably hydrogenated. When hydrogenated, the hydrogenation can be carried out by a known method.

[0029] Styrene-based thermoplastic elastomers are usually block copolymers, such as styrene-isoprene block copolymer (SI), styrene-isoprene-styrene block copolymer (SIS), styrene-butadiene block copolymer (SB), styrene-butadiene-styrene block copolymer (SBS), styrene-ethylene / butylene-styrene block copolymer (SEBS), styrene-ethylene / propylene-styrene block copolymer (SEPS), styrene-ethylene / ethylene / propylene-styrene block copolymer (SEEPS), styrene-ethylene / butylene block copolymer (SEB), styrene-ethylene / propylene block copolymer (SEP), and styrene-ethylene / butylene-crystalline olefin block copolymer (SEBC). The styrene-based thermoplastic elastomer is preferably a block copolymer, and among these, SIS, SEBS, SEPS, SEEPS, and SEBC are more preferred, SEEPS and SEBS are even more preferred, and SIS and SEBS are particularly preferred. Commercially available SIS products include Hybler (registered trademark) 5125 (styrene content 20% by mass, Tg = -13°C) and Hybler (registered trademark) 5127 (styrene content 20% by mass, Tg = 8°C), manufactured by Kuraray Co., Ltd. Commercially available SEBS products include the Tuftec (registered trademark) series and the SOE (registered trademark) series manufactured by Asahi Kasei Corporation.

[0030] The styrene-based thermoplastic elastomer has a structural unit derived from styrene, which enables the foam sheet to have good impact resistance. The styrene content in the styrene-based thermoplastic elastomer is preferably 5 to 50% by mass. By setting the styrene content within this range, excellent impact resistance can be obtained. Furthermore, by setting the styrene content to the above upper limit or less, compatibility with the polyolefin resin (B), which will be described in detail later, is improved, and crosslinkability and foamability tend to be good. From these viewpoints, the styrene content in the styrene-based thermoplastic elastomer is more preferably 7 to 40% by mass, and even more preferably 7 to 30% by mass.

[0031] The number average molecular weight of the styrene-based thermoplastic elastomer is not particularly limited, but from the viewpoints of breaking strength and processability, it is preferably 30,000 to 800,000, more preferably 120,000 to 180,000. The number average molecular weight is a polystyrene-equivalent value measured by gel permeation chromatography (GPC).

[0032] <Ethylene-α-olefin copolymer rubber> The α-olefin used in the ethylene-α-olefin copolymer rubber may be one or more α-olefins having 3 to 15 carbon atoms, preferably 3 to 10 carbon atoms, such as propylene, 1-butene, 2-methylpropylene, 3-methyl-1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-octene, etc. Among these, propylene and 1-butene are preferred, and 1-butene is more preferred. The ethylene-α-olefin copolymer rubber used here is an amorphous or low-crystalline rubber-like substance in which two or more olefin monomers are copolymerized substantially randomly.

[0033] The ethylene-α-olefin copolymer rubber may have other monomer units in addition to the ethylene units and α-olefin units. Examples of monomers that form the other monomer units include conjugated dienes having 4 to 8 carbon atoms, such as 1,3-butadiene, 2-methyl-1,3-butadiene (isoprene), 1,3-pentadiene, and 2,3-dimethyl-1,3-butadiene; non-conjugated dienes having 5 to 15 carbon atoms, such as dicyclopentadiene, 5-ethylidene-2-norbornene, 1,4-hexadiene, 1,5-dicyclooctadiene, 7-methyl-1,6-octadiene, and 5-vinyl-2-norbornene; vinyl ester compounds, such as vinyl acetate; unsaturated carboxylic acid esters, such as methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, and ethyl methacrylate; and unsaturated carboxylic acids, such as acrylic acid and methacrylic acid. These monomers may be used alone or in combination of two or more. Among these, non-conjugated dienes having 5 to 15 carbon atoms are preferred, and from the viewpoint of availability, 5-ethylidene-2-norbornene, 1,4-hexadiene, and dicyclopentadiene (DCPD) are more preferred.

[0034] The ethylene unit content of the ethylene-α-olefin copolymer rubber is usually 30 to 85 mass%, preferably 40 to 80 mass%, more preferably 45 to 75 mass%. The content of α-olefin units having 3 to 15 carbon atoms, preferably 3 to 10 carbon atoms, such as propylene, is usually 10 to 60 mass%, preferably 15 to 50 mass%. The content of other monomer units, such as non-conjugated dienes, is usually 0 to 20 mass%, preferably 1 to 10 mass%.

[0035] As the ethylene-α-olefin copolymer rubber, a terpolymer such as EPDM (ethylene-propylene-diene rubber) or EBDM (ethylene-butene-1-diene rubber) is preferred. As the ethylene-α-olefin copolymer, "EBT" manufactured by Mitsui Chemicals, Inc. is preferred. Examples include "K-9330".

[0036] <Amorphous 4-methyl-1-pentene copolymer> Examples of amorphous 4-methyl-1-pentene copolymers include copolymers of 4-methyl-1-pentene and an α-olefin other than 4-methyl-1-pentene. Examples of the α-olefin include α-olefins having 2 to 20 carbon atoms, preferably ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 1-octene, and 1-decene, and more preferably ethylene and propylene. Among these, a 4-methyl-1-pentene / propylene copolymer is preferred. Examples of the amorphous 4-methyl-1-pentene copolymer include "EP1001" and "EP1013" manufactured by Mitsui Chemicals, Inc.

[0037] (Polyolefin resin (B)) The polyolefin resin is a thermoplastic resin, and specific examples thereof include polyethylene resin, polypropylene resin, polybutene resin, ethylene-vinyl acetate copolymer, etc., and among these, polyethylene resin is preferred. As the polyethylene resin, low-density polyethylene (LDPE) is preferred, and linear low-density polyethylene (LLDPE) is more preferred. Therefore, it is particularly preferred to use a styrene-based thermoplastic elastomer as the elastomer (A) and LLDPE as the polyolefin resin (B). Furthermore, examples of the polyethylene resin include polyethylene resins polymerized with a polymerization catalyst such as a Ziegler-Natta catalyst, a metallocene catalyst, or a chromium oxide compound, and polyethylene resins polymerized with a metallocene catalyst are preferably used.

[0038] (Metallocene catalyst) Examples of metallocene catalysts include compounds such as bis(cyclopentadienyl) metal complexes, which have a structure in which a transition metal is sandwiched between π-electron unsaturated compounds. More specifically, examples include compounds in which one or more cyclopentadienyl rings or analogs thereof exist as ligands on a tetravalent transition metal such as titanium, zirconium, nickel, palladium, hafnium, or platinum. Such metallocene catalysts have uniform properties of active sites, and each active site has the same activity. Polymers synthesized using metallocene catalysts have high uniformity in molecular weight, molecular weight distribution, composition, composition distribution, etc., so when a sheet containing a polymer synthesized using a metallocene catalyst is crosslinked, the crosslinking proceeds uniformly. A uniformly crosslinked sheet is foamed uniformly, making it easier to stabilize its physical properties. In addition, since it can be stretched uniformly, the thickness of the foam can be made uniform.

[0039] Examples of the ligand include a cyclopentadienyl ring and an indenyl ring. These cyclic compounds may be substituted with a hydrocarbon group, a substituted hydrocarbon group, or a hydrocarbon-substituted metalloid group. Examples of hydrocarbon groups include a methyl group, an ethyl group, various propyl groups, various butyl groups, various amyl groups, various hexyl groups, 2-ethylhexyl groups, various heptyl groups, various octyl groups, various nonyl groups, various decyl groups, various cetyl groups, and a phenyl group. Note that "various" refers to various isomers including n-, sec-, tert-, and iso-. Alternatively, a cyclic compound may be polymerized as an oligomer and used as the ligand. Furthermore, in addition to the π-electron unsaturated compounds, monovalent anionic ligands such as chlorine and bromine, or divalent anionic chelate ligands, hydrocarbons, alkoxides, arylamides, aryloxides, amides, phosphides, arylphosphides, etc. may also be used.

[0040] Examples of metallocene catalysts containing a tetravalent transition metal or a ligand include cyclopentadienyltitanium tris(dimethylamide), methylcyclopentadienyltitanium tris(dimethylamide), bis(cyclopentadienyl)titanium dichloride, and dimethylsilyltetramethylcyclopentadienyl-t-butylamide zirconium dichloride. Metallocene catalysts, when combined with a specific cocatalyst (promoter), function as a catalyst during the polymerization of various olefins. Specific examples of the cocatalyst include methylaluminoxane (MAO) and boron-based compounds. The ratio of the cocatalyst to the metallocene catalyst is preferably 100,000 to 1,000,000 moles, and more preferably 50 to 5,000 moles.

[0041] Moreover, the polyethylene resin is preferably a linear low-density polyethylene. The linear low-density polyethylene is more preferably a linear low-density polyethylene obtained by copolymerizing ethylene (for example, 75% by mass or more, preferably 90% by mass or more, based on the total amount of monomers) with a small amount of an α-olefin as needed. Specific examples of the α-olefin include propylene, 1-butene, 1-pentene, 4-methyl-1-pentene, 1-hexene, 1-heptene, and 1-octene. Of these, α-olefins having 4 to 10 carbon atoms are preferred. The density of the polyethylene resin, for example, the linear low-density polyethylene described above, is 0.870 to 0.925 g / cm from the viewpoint of flexibility. 3 is preferable, and 0.890 to 0.925 g / cm 3 More preferably, 0.910 to 0.925 g / cm 3 As the polyethylene resin, a plurality of polyethylene resins may be used, and a polyethylene resin having a density outside the above range may be added.

[0042] The ethylene-vinyl acetate copolymer used as the polyolefin resin is, for example, an ethylene-vinyl acetate copolymer containing 50% by mass or more of ethylene. Examples of polypropylene resins include homopolypropylene and propylene-α-olefin copolymers containing 50% by mass or more of propylene. These may be used alone or in combination of two or more. Specific examples of α-olefins constituting the propylene-α-olefin copolymers include ethylene, 1-butene, 1-pentene, 4-methyl-1-pentene, 1-hexene, 1-heptene, and 1-octene. Of these, α-olefins having 6 to 12 carbon atoms are preferred. Examples of polybutene resins include homopolymers of butene-1 and copolymers with ethylene or propylene.

[0043] [Mass ratio of elastomer (A) to polyolefin resin (B)] The mass ratio of the elastomer (A) to the polyolefin resin (B) is preferably 90:10 to 20:80. Within this range, a foam sheet that exhibits the effects of the present invention can be easily produced. From the viewpoint of obtaining a foam sheet with even greater effects, the mass ratio of the (A) component to the (B) component is more preferably within the range of 80:20 to 25:75, even more preferably within the range of 75:25 to 30:70, and even more preferably within the range of 70:30 to 50:50.

[0044] The foam sheet of the present invention may contain a resin other than the elastomer (A) and the polyolefin resin (B) as long as the effects of the present invention are not impaired. However, from the viewpoint of achieving a stress relaxation rate of 23% or more and a 25% compressive strength of 1000 kPa or less of the foam sheet, it is preferable that the total proportion of the elastomer (A) and the polyolefin resin (B) in the resin component of the foam sheet of the present invention is high. Specifically, the total proportion of the elastomer (A) and the polyolefin resin (B) in the resin component of the foam sheet of the present invention is preferably 80 to 100 mass%, more preferably 90 to 100 mass%, even more preferably 95 to 100 mass%, and still more preferably 99 to 100 mass%.

[0045] [Additives] The foam sheet of the present invention is preferably obtained by foaming a foamable composition containing the above-mentioned resin and a foaming agent, preferably a thermally decomposable foaming agent. The thermal decomposition type blowing agent may be an organic blowing agent or an inorganic blowing agent. Examples of the organic blowing agent include azo compounds such as azodicarbonamide, azodicarboxylic acid metal salts (e.g., barium azodicarboxylate), and azobisisobutyronitrile, nitroso compounds such as N,N'-dinitrosopentamethylenetetramine, hydrazine derivatives such as hydrazodicarbonamide, 4,4'-oxybis(benzenesulfonylhydrazide), and toluenesulfonylhydrazide, and semicarbazide compounds such as toluenesulfonylsemicarbazide. Examples of inorganic foaming agents include ammonium carbonate, sodium carbonate, ammonium hydrogen carbonate, sodium hydrogen carbonate, ammonium nitrite, sodium borohydride, and anhydrous monosodium citrate. Among these, from the viewpoint of obtaining fine bubbles, and from the viewpoints of economy and safety, azo compounds are preferred, and azodicarbonamide is more preferred. The thermal decomposition type foaming agents may be used alone or in combination of two or more.

[0046] The amount of foaming agent in the foamable composition is preferably 1 to 20 parts by mass, more preferably 1.5 to 15 parts by mass, and even more preferably 3 to 10 parts by mass, per 100 parts by mass of resin. By using a foaming agent in an amount of 1 part by mass or more, the foamable sheet is foamed appropriately, making it possible to impart appropriate flexibility and impact absorption to the foam sheet. Furthermore, by using a foaming agent in an amount of 20 parts by mass or less, the foam sheet is prevented from foaming more than necessary, making it possible to improve the mechanical strength of the foam sheet.

[0047] The foamable composition may contain a decomposition temperature regulator. The decomposition temperature regulator is added to have a regulating function, such as lowering the decomposition temperature of the thermally decomposable foaming agent or accelerating the decomposition rate. Specific examples of the decomposition temperature regulator include zinc oxide, zinc stearate, and urea. The decomposition temperature regulator is added in an amount of, for example, 0.01 to 5 parts by mass per 100 parts by mass of the resin in order to adjust the surface condition of the foam sheet.

[0048] The foamable composition may contain an antioxidant. Examples of the antioxidant include phenol-based antioxidants such as 2,6-di-t-butyl-p-cresol, sulfur-based antioxidants, phosphorus-based antioxidants, and amine-based antioxidants. The antioxidant is blended in an amount of, for example, 0.01 to 5 parts by mass per 100 parts by mass of the resin. In addition to the above, the foamable composition may contain additives that are generally used in foams, such as heat stabilizers, colorants, flame retardants, antistatic agents, and fillers.

[0049] In the foam sheet, the elastomer (A) and the polyolefin resin (B) are the main components, and the total content of the (A) component and the (B) component is, for example, 70 mass % or more, preferably 80 mass % or more, and more preferably 90 mass % or more, based on the total amount of the foam sheet.

[0050] [Method of manufacturing foam sheet] The foam sheet of the present invention is not particularly limited, but can be produced by heating a foamable sheet made of a foamable composition containing at least a resin and a thermally decomposable foaming agent to foam the thermally decomposable foaming agent. Preferably, the foamable sheet is crosslinked and the crosslinked foamable sheet is heated to foam. More specifically, the method for producing a foam sheet preferably includes the following steps (1) to (3). Step (1): A step of forming a foamable sheet from a foamable composition containing at least a resin and a thermally decomposable foaming agent. Step (2): A step of irradiating the foamable sheet with ionizing radiation to crosslink the foamable sheet. Step (3): A step of heating the crosslinked expandable sheet to expand the thermally decomposable foaming agent, thereby obtaining a foam sheet.

[0051] In step (1), the method for forming the foamable sheet is not particularly limited, but may be, for example, by feeding the resin and additives to an extruder, melt-kneading them, and extruding the foamable composition from the extruder into a sheet. Alternatively, the foamable sheet may be formed by pressing the foamable composition. The forming temperature of the foamable sheet (i.e., the temperature during extrusion or pressing) is preferably 50 to 250°C, more preferably 80 to 180°C.

[0052] In step (2), the foamable composition is crosslinked by irradiating the foamable sheet with ionizing radiation such as electron beams, α-rays, β-rays, γ-rays, etc. The dose of the ionizing radiation may be adjusted so that the degree of crosslinking of the resulting foam sheet falls within the desired range, and is preferably 1 to 12 Mrad, more preferably 1.5 to 10 Mrad.

[0053] In step (3), the heating temperature when the foamable composition is heated to foam the thermally decomposable foaming agent may be equal to or higher than the foaming temperature of the thermally decomposable foaming agent, but is preferably 200 to 300° C., more preferably 220 to 280° C. In step (3), the foamable composition is foamed to form bubbles, resulting in a foam.

[0054] In the present production method, the foam sheet may be thinned by rolling or stretching, and the cell flatness may be adjusted by rolling or stretching.

[0055] However, the present production method is not limited to the above, and a foam sheet may be obtained by a method other than the above. For example, instead of irradiating with ionizing radiation, crosslinking may be performed by a method in which an organic peroxide is blended in advance with the foamable composition, and the foamable sheet is heated to decompose the organic peroxide. If crosslinking is not required, step (2) may be omitted, and in that case, in step (3), the uncrosslinked expandable sheet may be heated to expand it.

[0056] [Adhesive tape] The pressure-sensitive adhesive tape of the present invention comprises the foam sheet of the present invention and an adhesive material provided on at least one surface of the foam sheet. The adhesive tape can be adhered to another member such as a support member via the adhesive material. The pressure-sensitive adhesive tape may have the adhesive material provided on both surfaces of the foam sheet or on one surface. The adhesive material may be any material that includes at least a pressure-sensitive adhesive layer, and may be a single pressure-sensitive adhesive layer laminated on the surface of a foam sheet, or a double-sided pressure-sensitive adhesive sheet attached to the surface of a foam sheet, but is preferably a single pressure-sensitive adhesive layer. The double-sided pressure-sensitive adhesive sheet includes a substrate and pressure-sensitive adhesive layers provided on both sides of the substrate. The double-sided pressure-sensitive adhesive sheet is used to adhere one pressure-sensitive adhesive layer to a foam sheet and the other pressure-sensitive adhesive layer to another member.

[0057] The adhesive constituting the adhesive layer is not particularly limited, and for example, an acrylic adhesive, a urethane adhesive, a rubber adhesive, a silicone adhesive, etc. Furthermore, a release sheet such as release paper may be further attached onto the adhesive material. The thickness of the pressure-sensitive adhesive layer is preferably 5 to 200 μm, more preferably 7 to 150 μm, and even more preferably 10 to 100 μm.

[0058] [Foam sheet roll] The foam sheet of the present invention can be made into a roll. By making it into a roll, it is easy to store and convenient to transport. When used, it can be unwound from the roll. As described above, the stress relaxation rate of the foam sheet of the present invention is 23% or more, so that when the foam sheet is wound into a roll, problems such as wrinkles can be suppressed. Furthermore, as described above, the 25% compressive strength of the foam sheet of the present invention is a certain value or less, so that when the foam sheet is wound into a roll, defects such as lifting can be suppressed.

[0059] [Uses of foam sheets] The foam sheet of the present invention is not particularly limited in its intended use, but is preferably used in electronic devices. Examples of such electronic devices include mobile phones such as smartphones, game consoles, electronic organizers, tablet devices, and notebook personal computers. The foam sheet can be used as a cushioning material inside electronic devices, preferably as a cushioning material for display devices. It is also preferably used as a sealing material to fill gaps between components inside electronic devices. The foam sheet of the present invention is more preferably used in electronic devices with curved structures, since it can prevent problems such as floating of fixed components due to variations in curved surface tolerances. Furthermore, the foam sheet of the present invention is preferably arranged along the curved components in electronic devices with curved surfaces.

[0060] The foam sheet of the present invention may be used in any shape, for example, a narrow width, specifically, a narrow rectangular shape, a frame shape such as a square frame, an L-shape, a U-shape, etc. The width of these is, for example, 5 mm or less, preferably 3 mm or less, more preferably 1 mm or less, and, for example, 0.1 mm or more.

[0061] The foam sheet used as a cushioning material for a display device may be placed, for example, on the back side of a display panel installed in various electronic devices to cushion impacts acting on the display panel. In this case, the foam sheet may be placed on a support member placed on the back side of the display panel. The support member may be, for example, a part of the housing of the various electronic devices. The foam sheet used in electronic devices may be provided with an adhesive as described above, and may be attached to a display panel, support member, or the like via the adhesive. The foam sheet of the present invention is preferably used in a portion having a curved surface structure, since it can prevent problems such as lifting of the fixed member due to variations in the tolerance of the curved surface. Specifically, the foam sheet of the present invention may be attached to a support member, display panel, or the like having a curved surface structure via the adhesive. This prevents problems such as lifting of other members attached to the member, even if the tolerance of the curved surface of the support member, display panel, or the like varies. [Example]

[0062] The present invention will be explained in more detail by way of examples, but the present invention is not limited to these examples in any way.

[0063] [Measurement method] The methods for measuring and evaluating each physical property are as follows. <Thickness> The measurement was carried out using a dial gauge.

[0064] <Density, expansion ratio> The specific volume (unit: cc / g) of the foam sheet was measured before and after foaming, and the expansion ratio was calculated by dividing the specific volume after foaming by the specific volume before foaming. The density was also calculated from the measured specific volume.

[0065] <Average bubble diameter and bubble flatness> The foam sheet was cut in the thickness direction (ZD) along both the MD and TD, and a 200x magnified photograph was taken using a digital microscope (Keyence Corporation, product name "VHX-900"). In the enlarged photograph, the MD, TD, and ZD diameters of all bubbles present in a 2 mm-long cut surface in each of the MD and TD were measured, and this procedure was repeated five times. The average values ​​of the bubble diameters in the MD, TD, and ZD of all bubbles were taken as the average bubble diameters in the MD, TD, and ZD. The average of the average bubble diameters in the MD and TD was taken as the average bubble diameter. The MD oblateness of the bubbles was calculated by dividing the average MD diameter by the ZD average bubble diameter. The TD oblateness of the bubbles was calculated by dividing the TD average bubble diameter by the ZD average bubble diameter.

[0066] <Maximum value of loss tangent (tanδ) and temperature at which the loss tangent (tanδ) shows its maximum value> The maximum value of tan δ and the temperature at which the maximum value of tan δ is obtained under the following measurement conditions using a tensile storage modulus measuring device, trade name "DVA-200 / L2," manufactured by IT Instrument & Control Co., Ltd. Note that the temperature at which the maximum value of tan δ is obtained usually corresponds to the glass transition temperature (Tg). (Measurement conditions) Gauge length: 2.5cm Sample width: 0.5cm Sample thickness: Thickness of foam sheet Deformation mode: tension Static / dynamic stress ratio: 1.5 Set distortion: 1.0% Set temperature rise rate: 10℃ / min Measurement frequency 10Hz Temperature range: -150℃~100℃

[0067] <25% compressive strength> Measurement was performed at a temperature of 23°C using a measurement method in accordance with JIS K6767.

[0068] <Interlaminar strength> Figure 1 shows a schematic diagram of a test device used to evaluate interlaminar strength. A 25 mm square area of ​​a foam sheet 11 was coated with a primer ("PPX Primer" manufactured by Cemedine Co., Ltd.), and then a 5 mm diameter drop of adhesive 12 ("PPX" manufactured by Cemedine Co., Ltd.) was placed in the center of the applied area. A 25 mm square aluminum jig 13 was then placed on the area where the adhesive had been applied, and the foam sheet and jig 13 were pressed together. The foam sheet was then cut to fit the dimensions of the jig 13. Primer was applied to the side of the cut foam sheet that was not attached to the jig 13, and a 5 mm diameter drop of adhesive 12 was placed in the center of the applied area. A 10 mm square aluminum jig 14 was then placed on the area where the adhesive had been applied, and the foam sheet and jig 14 were pressed together. Any excess adhesive around the periphery of the jig 14 was wiped off, and then a cut 15 was made in the foam sheet along the dimensions of the jig 14. This was left to stand at room temperature for 30 minutes to cure the adhesive, and a sample for measuring interlaminar strength was prepared. Next, a 1 kN load cell was installed in a testing machine (A&D Co., Ltd.'s "Tensilon Universal Material Testing Machine") equipped with a thermostatic chamber to allow testing within the chamber. The sample for measuring interlaminar strength was then attached to the testing machine so that the foam sheet surface was perpendicular to the tensile direction. The temperature of the thermostatic chamber was set to 23°C, and the sample for measuring interlaminar strength was left to cool to 23°C. One side of the jig was then pulled vertically upward at a speed of 100 mm / min, peeling only a 1 cm square area of ​​the foam sheet. The maximum load at this point was measured and used as the first measurement result. The same procedure was repeated three times, and the average value was used as the interlaminar strength.

[0069] <Stress relaxation rate> The foam sheet was cut into a 10 mm x 10 mm planar square and laminated to a thickness of 4 mm to prepare a test specimen. Using a tensile tester (Shimadzu Corporation, Autograph AGS-X), the test specimen was compressed to a stress A of 1.2 MPa at a rate of 5 mm / min and allowed to rest in that state for 1 minute. The lowest stress value B in the rest state was measured, and the stress relaxation rate was calculated using the following formula. The measurement was performed in an environment of 23°C and 50% RH. Stress relaxation rate (%) = (AB) / A × 100

[0070] <Closed bubble rate> A flat square test piece with a side length of 5 cm was cut out from the foam sheet. The thickness of the test piece was measured to calculate the apparent volume V1 of the test piece, and the mass W1 of the test piece was also measured. Next, the volume V2 occupied by the air bubbles was calculated using the following formula. The density of the test piece was defined as ρ (g / cm 3 ) Volume occupied by the bubble V2=V1-W1 / ρ Next, the test piece was submerged in distilled water at 23°C to a depth of 100 mm from the water surface, and a pressure of 15 kPa was applied to the test piece for 3 minutes. After that, the test piece was taken out of the water, and the water adhering to the surface of the test piece was removed. The mass W2 of the test piece was measured, and the closed cell ratio F1 was calculated according to the following formula. Closed cell rate F1 (%) = 100-100 x (W2-W1) / V2

[0071] <Gel fraction> A test piece of about 100 mg was taken from the foam sheet, and the mass C (mg) of the test piece was precisely weighed. Next, this test piece was immersed in 30 cm of xylene at 120°C. 3 After immersing it in water and leaving it for 24 hours, The mixture was filtered through a 200-mesh wire net, and the insoluble matter on the wire net was collected and dried in a vacuum. The mass D (mg) of the insoluble matter was precisely weighed. From the obtained value, the gel fraction (% by mass) was calculated using the following formula. Gel fraction (mass%) = 100 × (D / C)

[0072] <Evaluation of permanent deformation> The foam sheet was cut into a 10 mm x 10 mm planar square and laminated to a thickness of approximately 4 mm to prepare a test piece, and the thickness (E) of the test piece was measured. Using a tensile tester (Shimadzu Corporation, Autograph AGS-X), the test piece was compressed to a stress of 1.2 MPa at a speed of 5 mm / min and held in that state for 1 minute. The compression was then released, and the thickness (F) of the test piece after compression was measured. The permanent set was calculated using the following formula and evaluated as follows. The permanent set was measured in an environment of 23°C and 50% RH. Permanent set rate (%) = (1-F / E) x 100 (Evaluation criteria) ○: Permanent distortion rate is 16% or more △: Permanent distortion rate is 15% ×: Permanent distortion rate is less than 15%

[0073] The materials used in the examples and comparative examples are as follows. Elastomer resin (a): EP1001 (Mitsui Chemicals, Inc., 4-methyl-1-pentene / propylene copolymer) Elastomer resin (b): EP1013 (Mitsui Chemicals, Inc., 4-methyl-1-pentene / propylene copolymer) Elastomer resin (c): SOE (registered trademark) S1605 (manufactured by Asahi Kasei Corporation, hydrogenated styrene-based thermoplastic elastomer (SEBS)) Elastomer resin (d): Hybra (registered trademark) 5127 (manufactured by Kuraray Co., Ltd., styrene-based thermoplastic elastomer (SIS)) Polyolefin resin (a): Kernel (registered trademark) KF283 (Japan Polyethylene Co., Ltd., ethylene / α-olefin copolymer (LLDPE) polymerized with a metallocene catalyst) Thermal decomposition type blowing agent: Azodicarbonamide Decomposition temperature regulator: Zinc oxide, manufactured by Sakai Chemical Industry Co., Ltd., product name "OW-212F" Phenolic antioxidant: 2,6-di-t-butyl-p-cresol

[0074] [How to make foam sheets] The foam sheets of Examples 1 to 12 and Comparative Examples 1 and 2 were produced as follows. Example 1 50 parts by mass of elastomer resin (a), 50 parts by mass of polyolefin resin (a), 3 parts by mass of a thermally decomposable foaming agent, 1 part by mass of a decomposition temperature regulator, and 0.5 parts by mass of a phenolic antioxidant were prepared as raw materials. These materials were melt-kneaded and then pressed to obtain a foamable resin sheet with a thickness of 0.15 mm. Both sides of the obtained foamable resin sheet were irradiated with 6.5 Mrad of electron beams at an acceleration voltage of 500 keV to crosslink the foamable resin sheet. Next, the crosslinked foamable resin sheet was expanded by heating to 250°C while stretching in MD and TD to the aspect ratio listed in Table 1, and the expanded resin sheet had a density of 0.51 g / cm. 3 A foam sheet having a thickness of 0.10 mm was obtained.

[0075] <Example 2> A foam sheet was obtained in the same manner as in Example 1, except that the amount of elastomer resin (a) was changed from 50 parts by mass to 30 parts by mass, the amount of polyolefin resin (a) was changed from 50 parts by mass to 70 parts by mass, and the foam sheet was stretched in MD and TD to have the aspect ratio shown in Table 1.

[0076] Example 3 The amount of elastomer resin (a) was changed from 50 parts by mass to 30 parts by mass, the amount of polyolefin resin (a) was changed from 50 parts by mass to 70 parts by mass, and the amount of thermally decomposable foaming agent was changed from 3 parts by mass to 4.2 parts by mass. The electron beam irradiation dose was changed from 6.5 Mrad to 6 Mrad, and the foamable resin sheet was stretched in MD and TD to have the aspect ratio shown in Table 1. Otherwise, a foam sheet was obtained in the same manner as in Example 1.

[0077] Example 4 A foam sheet was obtained in the same manner as in Example 1, except that the elastomer resin (a) was changed to the elastomer resin (b), the amount of the thermally decomposable foaming agent was changed from 3 parts by mass to 5.5 parts by mass, the electron beam irradiation dose was changed from 6.5 Mrad to 6 Mrad, and the sheet was stretched in MD and TD to have the aspect ratios shown in Table 1.

[0078] <Example 5> A foam sheet was obtained in the same manner as in Example 1, except that the elastomer resin (a) was changed to the elastomer resin (b), the amount of the thermally decomposable foaming agent was changed from 3 parts by mass to 4.5 parts by mass, the electron beam irradiation dose was changed from 6.5 Mrad to 8 Mrad, and the sheet was stretched in MD and TD to have the aspect ratios shown in Table 1.

[0079] Example 6 A foam sheet was obtained in the same manner as in Example 1, except that the elastomer resin (a) was changed to the elastomer resin (c), the amount of the thermally decomposable foaming agent was changed from 3 parts by mass to 5 parts by mass, the electron beam irradiation dose was changed from 6.5 Mrad to 6 Mrad, and the sheet was stretched in MD and TD to have the aspect ratios shown in Table 1.

[0080] Example 7 A foam sheet was obtained in the same manner as in Example 6, except that the amount of elastomer resin (c) was changed from 50 parts by mass to 60 parts by mass, the amount of polyolefin resin (a) was changed from 50 parts by mass to 40 parts by mass, and the electron beam irradiation dose was changed from 6 Mrad to 8 Mrad.

[0081] Example 8 A foam sheet was obtained in the same manner as in Example 6, except that the amount of elastomer resin (c) was changed from 50 parts by mass to 90 parts by mass, the amount of polyolefin resin (a) was changed from 50 parts by mass to 10 parts by mass, the amount of thermally decomposable foaming agent was changed from 5 parts by mass to 4 parts by mass, and the acceleration voltage was changed from 500 keV to 1000 keV.

[0082] Example 9 A foam sheet was obtained in the same manner as in Example 1, except that the elastomer resin (a) was changed to the elastomer resin (d), the amount of the thermally decomposable foaming agent was changed from 3 parts by mass to 5 parts by mass, the electron beam irradiation dose was changed from 6.5 Mrad to 6 Mrad, and the sheet was stretched in MD and TD to have the aspect ratios shown in Table 1.

[0083] Example 10 The amount of elastomer resin (a) was changed from 50 parts by mass to 25 parts by mass, the amount of polyolefin resin (a) was changed from 50 parts by mass to 75 parts by mass, and the amount of thermal decomposition type foaming agent was changed from 3 parts by mass to 5 parts by mass. The electron beam irradiation dose was changed from 6.5 Mrad to 7 Mrad, and the foamable resin sheet was stretched in MD and TD to have the aspect ratio shown in Table 1. Otherwise, a foam sheet was obtained in the same manner as in Example 1.

[0084] Example 11 The elastomer resin (a) was changed to elastomer resin (b), the blending amount was changed from 50 parts by mass to 40 parts by mass, the blending amount of polyolefin resin (a) was changed from 50 parts by mass to 60 parts by mass, and the blending amount of thermal decomposition type foaming agent was changed from 3 parts by mass to 4.5 parts by mass. In addition, the electron beam irradiation dose was changed from 6.5 Mrad to 7 Mrad, and the sheet was stretched in MD and TD to have the aspect ratios shown in Table 1. Otherwise, a foam sheet was obtained in the same manner as in Example 1.

[0085] Example 12 The elastomer resin (a) was changed to elastomer resin (c), the blending amount was changed from 50 parts by mass to 40 parts by mass, the blending amount of polyolefin resin (a) was changed from 50 parts by mass to 60 parts by mass, and the blending amount of thermally decomposable foaming agent was changed from 3 parts by mass to 5.4 parts by mass. The electron beam irradiation dose was changed from 6.5 Mrad to 7 Mrad, and the sheet was stretched in MD and TD to have the aspect ratios shown in Table 1. Otherwise, a foam sheet was obtained in the same manner as in Example 1.

[0086] <Comparative Example 1> A foam sheet was obtained in the same manner as in Example 1, except that the amount of elastomer resin (a) was changed from 50 parts by mass to 0 parts by mass, the amount of polyolefin resin (a) was changed from 50 parts by mass to 100 parts by mass, the electron beam irradiation dose was changed from 6.5 Mrad to 6 Mrad, and the foam sheet was stretched in MD and TD to have the aspect ratio shown in Table 1.

[0087] <Comparative Example 2> A foam sheet was obtained in the same manner as in Example 9, except that the amount of elastomer resin (d) was changed from 50 parts by mass to 10 parts by mass, the amount of polyolefin resin (a) was changed from 50 parts by mass to 90 parts by mass, the electron beam irradiation dose was changed from 6.5 Mrad to 7 Mrad, and the sheet was stretched in MD and TD to have the aspect ratios shown in Table 1.

[0088] Table 1 shows the evaluation results of Examples 1 to 12 and Comparative Examples 1 and 2. [Table 1]

[0089] From the evaluation results of the foam sheets of Examples 1 to 12 and Comparative Examples 1 and 2, it was found that the permanent set of the foam sheet increases when the stress relaxation rate is 23% or more and the 25% compressive strength is 1000 kPa or less. This shows that by using the foam sheets of Examples 1 to 12 for pressure-sensitive adhesive tapes, when the pressure-sensitive adhesive tape is applied to a curved surface to fix a member, it is possible to prevent problems such as lifting of the fixed member due to variations in the tolerance of the curved surface. [Explanation of symbols]

[0090] 1 screen 2 foam tapes 3. Housing 11 Foam sheet 12 Adhesive 13 Jig 14 Jig 15 Cut

Claims

1. The stress relaxation rate is 23% or more, and the 25% compressive strength is 1000 kPa or less. The interlaminar strength is 0.6 MPa or more, The larger of the MD flattening ratio and the TD flattening ratio of the bubbles is 2 or more, The MD flattening ratio of the cells is a value calculated by dividing the average cell diameter of the cells in the MD by the average cell diameter in the ZD, The TD oblateness of the bubbles is a value calculated by dividing the average bubble diameter in the TD of the bubbles by the average bubble diameter in the ZD, A foam sheet containing an elastomer and a polyolefin resin.

2. 2. The foam sheet according to claim 1, wherein the closed cell content is 80% or more.

3. 3. The foam sheet according to claim 1, wherein the gel fraction is 30 to 80%.

4. Density 0.05 to 0.6 g / cm ３ 3. The foam sheet according to claim 1 or 2, wherein

5. 3. The foam sheet according to claim 1, having a thickness of 0.03 to 2 mm.

6. 3. The foam sheet according to claim 1, wherein the loss tangent (tan δ) of dynamic viscoelasticity has a maximum value at at least one temperature in the range of 15 to 50°C.

7. 3. The foam sheet according to claim 1, wherein the maximum value of loss tangent (tan δ) of dynamic viscoelasticity is 0.2 or more.

8. An adhesive tape comprising the foam sheet according to claim 1 or 2 and an adhesive material provided on at least one surface of the foam sheet.

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