Solid binder

Abstract

The present invention is directed to a solid binder composition, particularly a solid binder composition for preparing mineral fiber products.

Description

[Technical Field]

[0001] The present invention relates to a binder for mineral fiber products, a method for producing bound mineral fiber products using the binder, and a mineral fiber product comprising mineral fibers in contact with the cured binder. [Background technology]

[0002] Mineral wool (mineral cotton) products (also called mineral fiber products) generally include man-made vitreous fibers (MMVF) such as glass fibers, ceramic fibers, basalt fibers, slag fibers, mineral fibers, and stone fibers (rock fibers), which are bonded together by a cured thermosetting polymer binder material. For use as thermal insulation or soundproofing products, bonded mineral fiber mats are usually manufactured by converting a molten material made from suitable raw materials into fibers using conventional methods, such as the spinning cup process or the cascade rotor process.

[0003] The binder material may be applied to the mineral fibers immediately after fiber formation. Alternatively, the binder material may be applied to the mineral fibers in an offline process separate from the fiber formation process. In the latter case, the binder material is traditionally a solid binder, not in a diluted aqueous solution. Such a binder is also called a dry binder.

[0004] Mineral fiber products using a dry binder are formed by mixing mineral fibers with a binder material to form a mixture, and then applying heat and pressure to this mixture in a sheet pressing device to harden it and provide mineral fiber products.

[0005] In the past, the selected binder resin was phenol-formaldehyde resin, which can be manufactured economically and extended with urea before use as a binder. However, in consideration of existing and proposed laws regarding the reduction or elimination of formaldehyde emissions, formaldehyde-free binders have been developed, such as binder compositions based on polycarboxypolymers and polyols or polyamines.

[0006] Another group of non-phenol-formaldehyde binders are addition / elimination reaction products of aliphatic anhydrides and / or aromatic anhydrides with alkanolamines, as disclosed, for example, in International Publication No. 99 / 36368, International Publication No. 01 / 05725, International Publication No. 01 / 96460, International Publication No. 02 / 06178, International Publication No. 2004 / 007615 and International Publication No. 2006 / 061249. These binder compositions are water-soluble and exhibit excellent binding properties in terms of curing rate and curing density. International Publication No. 2008 / 023032 discloses a urea-modified binder of its type that provides mineral wool products with reduced water absorption.

[0007] Since some of the starting materials used in the manufacture of known binders are fairly expensive chemicals, there is an ongoing need for a phenol-free and formaldehyde-free binder that is economically feasible to manufacture while exhibiting good bonding properties for producing bonded mineral fiber products. Further demand is directed towards phenol-free binders.

[0008] A further effect of previously known binder compositions from mineral fibers is that at least a large portion of the starting materials used in the manufacture of these binders are derived from fossil fuels. The consumer trend of preferring products manufactured at least partially from renewable materials continues, and therefore, there is a need to provide binders for mineral wool that are manufactured at least partially from renewable materials.

[0009] A further consequence associated with previously known binder compositions for mineral fibers is that they contain harmful components. Emissions from production when using binders containing phenol and formaldehyde also pose health concerns. This necessitates safety measures for people in the work environment, which leads to increased costs and health problems; therefore, there is a need to provide binder compositions for mineral fibers with reduced levels of harmful substances.

[0010] On the other hand, many mineral fiber binders are available that are largely based on renewable starting materials. In many cases, these binders, which are largely based on renewable resources, are also formaldehyde-free.

[0011] However, many of these binders are still relatively expensive because they are based on relatively expensive base materials. [Prior art documents] [Patent Documents]

[0012] [Patent Document 1] International Publication No. 99 / 36368 pamphlet [Patent Document 2] International Publication No. 01 / 05725 Pamphlet [Patent Document 3] International Publication No. 01 / 96460 Pamphlet [Patent Document 4] International Publication No. 02 / 06178 Pamphlet [Patent Document 5] International Publication No. 2004 / 007615 Pamphlet [Patent Document 6] International Publication No. 2006 / 061249 Pamphlet [Patent Document 7] International Publication No. 2008 / 023032 Pamphlet [Overview of the project] [Problems that the invention aims to solve]

[0013] Therefore, an object of the present invention is to provide a binder composition that is particularly suitable for binding mineral fibers, has a reduced content of harmful substances and emissions, is relatively inexpensive to manufacture, has good storage properties, exhibits good properties for binding mineral fiber products, and contains a renewable material as a starting material. The binder should be suitable for preparing a high-density mineral fiber product or a hard plate, respectively. The binder should be free of formaldehyde and, optionally, free of phenol.

Means for Solving the Problems

[0014] According to a first aspect of the present invention, there is provided a solid binder composition, particularly a solid binder composition free of formaldehyde, comprising component (i) in the form of one or more lignosulfonate lignins having a carboxylic acid group content of 0.03 to 1.4 mmol / g based on the dry weight of the lignosulfonate lignin, and component (ii) in the form of one or more crosslinking agents A solid binder composition is provided.

[0015] According to a second aspect of the present invention, there is provided a method for producing a bonded mineral fiber product, the method comprising contacting mineral fibers with the solid binder composition defined above and curing the binder composition while in contact with the mineral fibers.

[0016] According to a third aspect of the present invention, there is provided a mineral fiber product comprising mineral fibers in contact with a cured solid binder composition defined above, preferably obtainable by the method defined above.

[0017] According to a fourth aspect of the present invention, the solid binder composition defined above is used as a binder for mineral fibers or as an adhesive for adhering components to each other.

[0018] In further embodiments, the binder composition is (iii) Components in the form of one or more plasticizers It also includes.

[0019] The inventors have surprisingly found that it is possible to prepare binder compositions for mineral fibers based on combinations of components (i) and (ii) as defined above, and optionally component (iii). It is quite remarkable that by combining these components, it is possible to prepare solid binder compositions suitable for binding mineral fibers.

[0020] Furthermore, the binder composition can be manufactured largely from inexpensive renewable materials and contains no or only trace amounts of any corrosive and / or harmful substances. At the same time, relatively inexpensive components can be used. Since "biomaterials" are often more expensive than conventional materials, the combination of low cost and renewable resource utilization is particularly noteworthy.

[0021] What is even more surprising is that a binder composition based on the above combination of components can be used as a solid binder.

[0022] At the same time, the binder according to the present invention exhibits excellent properties when used to bond mineral fibers. Its mechanical strength is unexpectedly high when subjected to aging conditions.

[0023] The reaction loss from curing achieved with the binder according to an embodiment of the present invention is at the same level as or higher than the reaction loss of the reference binder. [Brief explanation of the drawing]

[0024] [Figure 1] A commonly used model structure for lignosulfonates is shown. [Modes for carrying out the invention]

[0025] The solid binder composition according to the present invention is • Component (i) is a lignosulfonate lignin of one or more types, having a carboxylic acid group content of 0.03 to 1.4 mmol / g based on the dry weight of the lignosulfonate lignin. • One or more crosslinking agents as components (ii), • Optionally, one or more components in the form of plasticizers (iii) and Includes.

[0026] In particular, according to the first embodiment, the solid binder is, • Component (i) in the form of lignosulfonate trinin having a carboxylic acid group content of 0.03 to 2.0 mmol / g, for example 0.03 to 1.4 mmol / g, for example 0.075 to 2.0 mmol / g, for example 0.075 to 1.4 mmol / g based on the dry weight of the lignosulfonate trinin, • One or more crosslinking agents as components (ii), • Optionally, one or more components in the form of plasticizers (iii) and This includes, however, the binder composition is • Molecular weight M of 500 or less W epoxy compounds having A solid binder is provided that does not contain a crosslinking agent selected from the above.

[0027] In particular, according to the first embodiment, the solid binder is, • Component (i) in the form of lignosulfonate trinin having a carboxylic acid group content of 0.03 to 2.0 mmol / g, for example 0.03 to 1.4 mmol / g, for example 0.075 to 2.0 mmol / g, for example 0.075 to 1.4 mmol / g based on the dry weight of the lignosulfonate trinin, • One or more crosslinking agents as components (ii), • Optionally, one or more components in the form of plasticizers (iii) and This includes, however, the binder composition is ·Formula R-[C(O)R1] x A carbonyl compound selected from the aldehyde and carbonyl compounds, wherein in the above formula, R represents a saturated or unsaturated linear, branched, or cyclic hydrocarbon group, a group containing an aromatic nucleus consisting of one or more 5 or 6 carbon atoms, or a group containing an aromatic heterocycle containing one or more 4 or 5 carbon atoms and an oxygen atom, a nitrogen atom, or a sulfur atom, and this R group may contain other functional groups. R1 is a hydrogen atom or C1~C 10 Represents an alkyl group, x is a carbonyl compound in the range of 1 to 10. A solid binder free of crosslinking agents selected from is provided.

[0028] In particular, according to the first embodiment, the solid binder is, • Component (i) in the form of lignosulfonate trinin having a carboxylic acid group content of 0.03 to 2.0 mmol / g, for example 0.03 to 1.4 mmol / g, for example 0.075 to 2.0 mmol / g, for example 0.075 to 1.4 mmol / g based on the dry weight of the lignosulfonate trinin, • One or more crosslinking agents as components (ii), • Optionally, one or more components in the form of plasticizers (iii) and This includes, however, the binder composition is • Polyamines A solid binder free of crosslinking agents selected from is provided.

[0029] In particular, according to the first embodiment, the solid binder is, • Component (i) in the form of lignosulfonate trinin having a carboxylic acid group content of 0.03 to 2.0 mmol / g, for example 0.03 to 1.4 mmol / g, for example 0.075 to 2.0 mmol / g, for example 0.075 to 1.4 mmol / g based on the dry weight of the lignosulfonate trinin, • One or more crosslinking agents as components (ii), • Optionally, one or more components in the form of plasticizers (iii) and This includes, however, the binder composition is Monosaccharides and oligosaccharides A solid binder free of crosslinking agents selected from is provided.

[0030] In one embodiment, the solid binder is • Component (i) in the form of lignosulfonate trinin having a carboxylic acid group content of 0.03 to 2.0 mmol / g, for example 0.03 to 1.4 mmol / g, for example 0.075 to 2.0 mmol / g, for example 0.075 to 1.4 mmol / g based on the dry weight of the lignosulfonate trinin, (ii) A component in the form of one or more crosslinking agents, • β-hydroxyalkylamide crosslinking agent, and / or • Epoxy compounds having a molecular weight greater than 500, for example, epoxidized oils based on fatty acid triglycerides, or one or more flexible oligomers or polymers containing reactive functional groups, for example, carbodiimide groups, for example, anhydride groups, for example, oxazoline groups, for example, amino groups, for example, epoxy groups, for example, low-Tg acrylic polymers, for example, low-Tg vinyl polymers, for example, low-Tg polyethers, and / or • One or more crosslinking agents in the form of polyfunctional carbodiimides, e.g., aliphatic polyfunctional carbodiimides, and / or Primid XL-552 (ii) a component in the form of one or more crosslinking agents selected from, • Optionally, one or more components in the form of plasticizers (iii) and This includes, however, the binder composition is • Molecular weight M of 500 or less W epoxy compounds having ·Formula R-[C(O)R1] x A carbonyl compound selected from the aldehyde and carbonyl compounds, wherein in the above formula, R represents a saturated or unsaturated linear, branched, or cyclic hydrocarbon group, a group containing an aromatic nucleus consisting of one or more 5 or 6 carbon atoms, or a group containing an aromatic heterocycle containing one or more 4 or 5 carbon atoms and an oxygen atom, a nitrogen atom, or a sulfur atom, and this R group may contain other functional groups. R1 is a hydrogen atom or C1~C 10 Represents an alkyl group, x is a carbonyl compound in the range of 1 to 10. • Polyamines It does not contain any crosslinking agents selected from the above.

[0031] In preferred embodiments, the solid binder composition and the mineral fiber product obtained therefrom according to the present invention are formaldehyde-free.

[0032] For the purposes of this application, the terms "formaldehyde-free" and "formaldehyde-free" refer to a mineral wool product with an emission level of 5 μg / m². 2 Less than / h, preferably 3 μg / m² 2 This is defined to characterize mineral wool products with formaldehyde levels below 1 / h. Preferably, the test is carried out in accordance with ISO 16000 for testing aldehyde emissions.

[0033] Preferably, the binder composition does not contain added formaldehyde. The solid binder composition according to the present invention and the mineral fiber product obtained therefrom may not contain phenol, or may have a relatively low phenol content.

[0034] In one embodiment, the binder composition does not contain added formaldehyde.

[0035] In one embodiment, the binder composition does not contain added phenol.

[0036] For the purposes of this invention, the term "monosaccharides and oligosaccharides" is defined to include monosaccharides and oligosaccharides having 10 or fewer sugar units.

[0037] For the purposes of this invention, the term "sugar" is defined to include monosaccharides and oligosaccharides having 10 or fewer sugar units.

[0038] In a preferred embodiment, the solid binder composition according to the present invention has a water content of 30% or less, particularly 25% or less, and more preferably 10% or less, calculated as the weight of water relative to the total weight of the solid binder.

[0039] The water content in the solid binder composition can be determined based on the weight of water that evaporates from the binder at ambient pressure for 1 hour at 105°C.

[0040] The binder composition of the present invention is a solid binder composition. In preferred embodiments, the solid binder composition of the present invention is in powder form. Unless otherwise explicitly stated, the solid binder composition generally refers to an uncured binder composition.

[0041] Preferably, 50% by weight of the components of the solid binder composition have particle sizes (particle diameters) of less than 500 μm, for example less than 200 μm, for example less than 100 μm, and greater than 10 μm, for example greater than 20 μm, for example greater than 25 μm.

[0042] The particle size is defined by adding a binder to a sieve whose mesh width is the desired particle size, for example, 200 μm. Therefore, the particles recovered after sieving have a particle size of 200 μm or less. The weight percentage of the sieved particles can then be determined.

[0043] In a preferred embodiment, component (i) has a carboxylic acid group content of 0.05 to 0.6 mmol / g based on the dry weight of lignosulfonate lignin.

[0044] In a preferred embodiment, the solid binder composition of the present invention is a free-flow binder composition.

[0045] In one embodiment, the solid binder composition can be discharged from a model silo in a mass flow pattern, the model silo having a stainless steel wall with a circular hopper, a hopper angle of 30°, and a hopper opening diameter of 20 cm.

[0046] A suitable test for determining whether a binder sample is "free-flowing" is to determine whether the binder can flow out of a standardized hopper in a mass flow pattern. The term "mass flow" is well known in the art of silo design and refers to the fact that the entire contents of a silo move when the material is drawn from the bottom of the silo, i.e., the "first-in, first-out" principle applies to the flow, and such a flow is regular and easily controllable. Less desirable flow patterns are "core flow" or "funnel flow," in which the material flows through the core (center) of the silo, and a stagnant zone where the material remains still is found along the wall region of the silo. The presence of mass flow depends on the internal friction of the material, wall friction, hopper shape, hopper angle, and the size of the hopper opening. For a given hopper, the "mass flow angle" is the angle of the hopper (relative to the vertical) in which mass flow can still occur, and this mass flow angle may be calculated (if internal and wall friction are known) or determined empirically. For hoppers with angles greater than the mass flow angle, i.e., not too steep, funnel flow occurs.

[0047] To test the flow characteristics of a binder sample, a model silo with a circular hopper, a 30° hopper angle, and stainless steel walls with a 20cm hopper opening diameter may be employed. For testing, this silo is filled to a minimum filling level of 30cm above the transition point from the silo to the hopper, and a maximum filling level of no more than 3m. When filling a completely empty silo, a small amount of binder (e.g., about 5 liters) should be removed when the filling level reaches the transition point to avoid the "bridging" effect caused by the binder at the bottom of the silo being subjected to higher pressure. The material should be drawn out evenly across the entire area of ​​the opening. Using such a standard hopper, a binder is defined as "free-flowing" if it can flow out of the hopper in a mass flow pattern. A non-free-flowing binder, on the other hand, flows in a funnel flow pattern if it can flow out of the hopper. The flow pattern in any given case can be easily determined by visual observation.

[0048] Preferably, the free-flowing binder flows in a mass flow pattern using the same type of hopper and the same procedure, but even with a hopper opening diameter of 15 cm.

[0049] Ingredient (i) Component (i) is one or more lignosulfonate lignins, in the form of lignosulfonate lignins having a carboxylic acid group content of 0.03 to 2.0 mmol / g, for example 0.03 to 1.4 mmol / g, for example 0.075 to 2.0 mmol / g, for example 0.075 to 1.4 mmol / g based on the dry weight of the lignosulfonate lignin.

[0050] Lignin, cellulose, and hemicellulose are the three main organic compounds in plant cell walls. Lignin can be thought of as an adhesive that holds cellulose fibers together. Lignin contains both hydrophilic and hydrophobic groups. Lignin is the second most abundant natural polymer in the world, second only to cellulose, and is estimated to account for about 20-30% of the total carbon contained in biomass totaling over 1 billion tons.

[0051] The lignosulfonate process introduces a large number of sulfonate groups to make lignin soluble not only in water but also in acidic aqueous solutions. Lignosulfonates contain up to 8% sulfur as sulfonates, while Kraft lignin contains 1-2% sulfur, most of which is bound to the lignin. The molecular weight of lignosulfonates is 15,000-50,000 g / mol. The typical hydrophobic core of lignin, along with numerous ionized sulfonate groups, makes this lignin attractive as a surfactant, and lignin often finds applications in dispersing cement and other materials.

[0052] To produce value-added lignin-based products, lignin must first be separated from biomass, and several methods can be used for this purpose. Kraft and sulfite pulping processes are well-known for their effective separation of lignin from wood and are therefore used worldwide. Kraft lignin is separated from wood with the help of NaOH and Na2S. Lignin from the sulfite pulping process is expressed as lignosulfonate and is produced by using sulfites containing sulfite and / or magnesium, calcium, sodium, or ammonium at various pH levels. Currently, lignosulfonate accounts for 90% of the entire market for commercially available lignin, and the total annual global production of lignosulfonate is approximately 1.8 million tons. Lignosulfonate generally has abundant sulfonic acid groups and therefore contains more sulfur than kraft lignin. Due to the presence of sulfonating groups, lignosulfonate is anionically charged and water-soluble. The molecular weight (Mw) of lignosulfonate can be similar to or greater than that of kraft lignin. Due to its unique properties, lignosulfonates have a wide range of applications, including animal feed, insecticides, surfactants, additives in oil drilling, stabilizers in colloidal suspensions, and plasticizers in concrete admixtures. However, most new pulp mills employ kraft technology for pulp production, and therefore kraft lignin is more readily available for value-added production.

[0053] However, lignosulfonates and Kraft lignin have different properties due to different isolation processes and therefore different functional group distributions. The high level of sulfonic acid groups in lignosulfonates, generally at least one for every four C9 units, makes lignosulfonates strongly charged at all pH levels in water. This abundance of ionizable functional groups can explain most of the differences compared to other industrial lignins. The higher charge density allows for easier water solubility and a higher solids content in solution compared to Kraft lignin. Also for the same reason, lignosulfonates have a lower solution viscosity compared to Kraft lignin at the same solids content, which can make them easier to handle and process. A commonly used model structure of lignosulfonate is shown in Figure 1.

[0054] In one embodiment, component (i) has a carboxylic acid group content of 0.05 to 0.6 mmol / g, for example, 0.1 to 0.4 mmol / g, based on the dry weight of lignosulfonate lignin.

[0055] In one embodiment, component (i) is in the form of one or more lignosulfonate lignins having an average carboxylic acid group content of less than 1.8 groups per polymer, e.g., less than 1.4, e.g., less than 1.1, e.g., less than 0.7, e.g., less than 0.4, considering the Mn weight average of component (i).

[0056] In one embodiment, component (i) has a phenolic OH group content of 0.3 to 2.5 mmol / g, for example 0.5 to 2.0 mmol / g, or for example 0.5 to 1.5 mmol / g, based on the dry weight of lignosulfonate lignin.

[0057] In one embodiment, component (i) has an aliphatic OH group content of 1.0 to 8.0 mmol / g, for example 1.5 to 6.0 mmol / g, or for example 2.0 to 5.0 mmol / g, based on the dry weight of lignosulfonate lignin.

[0058] In one embodiment, component (i) includes ammonium lignosulfonate (ammonium lignosulphonate) and / or calcium lignosulfonate (calcium lignosulphonate) and / or magnesium lignosulfonate (magnesium lignosulphonate), and any combination of any of these.

[0059] In one embodiment, component (i) includes ammonium lignosulfonate and calcium lignosulfonate, and the molar ratio of NH4 + to Ca 2+ is in the range of 5:1 to 1:5, particularly 3:1 to 1:3.

[0060] For the purposes of the present invention, the terms lignosulfonate, lignosulfonate salt include sulfonated kraft lignin.

[0061] In one embodiment, component (i) is sulfonated kraft lignin.

[0062] In one embodiment, the solid binder composition contains added sugar in an amount of 0 to 5% by weight, for example less than 5% by weight, for example 0 to 4.9% by weight, for example 0.1 to 4.9% by weight, based on the weight of the lignosulfonate and the sugar.

[0063] In one embodiment, the solid binder composition contains component (i), i.e., lignosulfonate, in an amount of 50 to 98% by weight, for example 65 to 98% by weight, for example 80 to 98% by weight, based on the total weight of components (i) and (ii).

[0064] In one embodiment, the solid binder composition contains component (i), i.e., lignosulfonate, in an amount of 50 to 88% by weight, for example 50 to 87% by weight, for example 65 to 88% by weight, for example 65 to 87% by weight, for example 80 to 88% by weight, for example 80 to 87% by weight, based on the total weight of components (i) and (ii).

[0065] In one embodiment, the solid binder composition contains component (i) in an amount of 50 to 98% by weight, for example 65 to 98% by weight, for example 80 to 98% by weight, based on the dry weight of components (i), (ii), and (iii).

[0066] In one embodiment, the solid binder composition contains component (i) in an amount of 50 to 88% by weight, for example 50 to 87% by weight, for example 65 to 88% by weight, for example 65 to 87% by weight, for example 80 to 88% by weight, for example 80 to 87% by weight, based on the dry weight of components (i), (ii), and (iii).

[0067] For the purposes of the present invention, the lignin functional group content is used as a characterization method. 31 This is determined by using 1P NMR.

[0068] 31 Sample preparation for 1P NMR is performed using 2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphosphoran (TMDP) as the phophytylation reagent and cholesterol as the internal standard. Integration follows the work of Granata and Argyropoulos (J.Agric.Food Chem. 43:1538-1544).

[0069] Components of the solid binder composition (ii) Component (ii) is in the form of one or more crosslinking agents. The crosslinking agent used is preferably a solid at room temperature (21°C), for example, a powder.

[0070] In one embodiment, component (ii) is, a) β-hydroxyalkylamide crosslinking agents and / or oxazoline crosslinking agents, and / or b) A group consisting of polyfunctional organic amines such as alkanolamines, diamines such as hexamethyldiamine, triamines, and / or c) Epoxy compounds having a molecular weight greater than 500, for example, one or more flexible oligomers or polymers containing reactive functional groups, for example, carbodiimide groups, for example, anhydride groups, for example, oxazoline groups, for example, amino groups, for example, epoxy groups, for example, low Tg acrylic polymers, for example, low Tg vinyl polymers, for example, low Tg polyethers, and / or d) One or more crosslinking agents selected from the group consisting of polyethyleneimine, polyvinylamine, and fatty amine, and / or e) One or more crosslinking agents in the form of fatty amides, and / or f) One or more crosslinking agents selected from the group consisting of aromatic aldehydes, e.g., hydroxybenzaldehyde, e.g., aminobenzaldehyde, e.g., hydroxy-methoxybenzaldehyde, and / or from the group consisting of aliphatic aldehydes, e.g., decanal, and / or g) One or more crosslinking agents selected from polyester polyols such as polycaprolactone, and / or h) One or more crosslinking agents selected from the group consisting of starch, modified starch, and CMC, and / or i) One or more crosslinking agents in the form of aliphatic polyfunctional carbodiimides, and / or j) One or more crosslinking agents selected from melamine-based crosslinking agents such as hexakis(methylmethoxy)melamine (HMMM)-based crosslinking agents. It is in the form of one or more crosslinking agents selected from the following.

[0071] In one embodiment, component (ii) comprises one or more crosslinking agents selected from β-hydroxyalkylamide crosslinking agents and / or oxazoline crosslinking agents.

[0072] β-hydroxyalkylamide crosslinkers are curing agents for acid-functional polymers. These β-hydroxyalkylamide crosslinkers provide a hard, durable, corrosion-resistant, and solvent-resistant crosslinked polymer network. The β-hydroxyalkylamide crosslinkers are thought to cure through esterification reactions, forming multiple ester bonds. The hydroxyl functionality of the β-hydroxyalkylamide crosslinkers should be at least 2 on average, preferably greater than 2, and more preferably 2-4, to obtain an optimal curing response.

[0073] Oxazoline group-containing crosslinking agents are polymers containing one or more oxazoline groups in each molecule, and generally, oxazoline-containing crosslinking agents can be readily obtained by polymerizing oxazoline derivatives. U.S. Patent No. 6,818,699,B2 provides disclosure of such a process.

[0074] In one embodiment, component (ii) is one or more crosslinking agents selected from the group consisting of polyfunctional organic amines such as alkanolamines, diamines such as hexamethyldiamine, and triamines.

[0075] In one embodiment, component (ii) is one or more epoxy compounds having a molecular weight greater than 500, one or more flexible oligomers or polymers containing reactive functional groups, such as carbodiimide groups, anhydride groups, oxazoline groups, amino groups, epoxy groups, or β-hydroxyalkylamide groups, such as low-Tg acrylic polymers, low-Tg vinyl polymers, or low-Tg polyethers.

[0076] In one embodiment, component (ii) is one or more crosslinking agents selected from the group consisting of polyethyleneimine and polyvinylamine.

[0077] In one embodiment, component (ii) is one or more crosslinking agents selected from the group consisting of fatty amines.

[0078] In one embodiment, component (ii) is one or more crosslinking agents in the form of fatty amides.

[0079] In one embodiment, component (ii) is one or more crosslinking agents from the group consisting of aromatic aldehydes, e.g., hydroxybenzaldehyde, e.g., aminobenzaldehyde, e.g., hydroxy-methoxybenzaldehyde, and / or aliphatic aldehydes, e.g., decanal.

[0080] In one embodiment, component (ii) is one or more crosslinking agents selected from polyester polyols such as polycaprolactone.

[0081] In one embodiment, component (ii) is one or more crosslinking agents selected from the group consisting of starch, modified starch, and CMC.

[0082] In one embodiment, component (ii) is one or more crosslinking agents in the form of polyfunctional carbodiimides, such as aliphatic polyfunctional carbodiimides.

[0083] In one embodiment, component (ii) is one or more crosslinking agents in the form of aziridines such as CX100 and NeoAdd-Pax 521 / 523.

[0084] In one embodiment, component (ii) is one or more crosslinking agents selected from melamine-based crosslinking agents such as hexakis(methylmethoxy)melamine (HMMM)-based crosslinking agents.

[0085] Examples of such compounds include Picassian XL 701, 702, 725 (Stahl Polymers), ZOLDINE® XL-29SE (Angus Chemical Company), CX300 (DSM), and Carbodilite V-02-L2 (Nisshinbo Chemical Co., Ltd.).

[0086] In one embodiment, component (ii) is Primid XL552 having the following structure:

[0087] Component (ii) may also be a mixture of any of the above compounds.

[0088] In one embodiment, the binder composition according to the present invention comprises component (ii) in an amount of 1 to 50% by weight, for example, 4 to 20% by weight, for example, 6 to 12% by weight, based on the dry weight of component (i).

[0089] In one embodiment, component (ii) is, • β-hydroxyalkylamide crosslinking agents, e.g., N-(2-hydroxyisopropyl)amide crosslinking agents, e.g., N-(2-hydroxyethyl)amide crosslinking agents, e.g., N-(2-hydroxyethyl)adipoamide crosslinking agents, e.g., N,N,N',N'-tetrakis(2-hydroxyethyl)adipoamide, and / or • A group consisting of polyfunctional organic amines such as alkanolamines, diamines such as hexamethyldiamine, and / or • Epoxy compounds having a molecular weight greater than 500, for example, epoxidized oils based on fatty acid triglycerides, or one or more flexible oligomers or polymers containing reactive functional groups, for example, carbodiimide groups, for example, anhydride groups, for example, oxazoline groups, for example, amino groups, for example, epoxy groups, for example, low Tg acrylic polymers, for example, low Tg vinyl polymers, for example, low Tg polyethers, and / or • One or more crosslinking agents in the form of polyfunctional carbodiimides, e.g., aliphatic polyfunctional carbodiimides. It is in the form of one or more crosslinking agents selected from the following.

[0090] In one embodiment, component (ii) is, • β-hydroxyalkylamide crosslinking agents, such as N-(2-hydroxyisopropyl)amide crosslinking agents, such as N-(2-hydroxyethyl)amide crosslinking agents, such as N-(2-hydroxyethyl)adipoamide crosslinking agents, such as N,N,N',N'-tetrakis(2-hydroxyethyl)adipoamide It contains one or more crosslinking agents selected from the following.

[0091] In one embodiment, component (ii) is in an amount of 2 to 90% by weight, for example 6 to 60% by weight, for example 10 to 40% by weight, for example 25 to 40% by weight, based on the dry weight of component (i).

[0092] (iii) Components of the solid binder composition Optionally, and preferably, the solid binder composition may contain component (iii), which is in the form of one or more plasticizers.

[0093] In one embodiment, component (iii) is, One or more plasticizers selected from the group consisting of polyethylene glycol, polyethylene glycol ether, polyether, hydride sugar, phthalate and / or acids such as adipic acid, vanillic acid, lactic acid and / or ferulic acid, acrylic polymer, polyvinyl alcohol, polyurethane dispersion, ethylene carbonate, propylene carbonate, lactone, lactam, lactide, acrylic polymer having free carboxyl groups and / or polyurethane dispersion having free carboxyl groups, and / or One or more plasticizers selected from the group consisting of fatty alcohols, monohydroxy alcohols, such as stearyl alcohol, and / or One or more plasticizers selected from the group consisting of alkoxylates, e.g., ethoxylates, e.g., butanol ethoxylate, e.g., butoxytriglycol, and / or One or more plasticizers in the form of propylene glycol, and / or One or more plasticizers in the form of glycol esters, and / or One or more plasticizers selected from the group consisting of adipate (adipate ester), acetate (acetic acid ester), benzoate (benzoic acid ester), cyclobenzoate (cyclobenzoic acid ester), citrate (citric acid ester), stearate (stearate ester), sorbate (sorbate ester), sebacate (sebacate ester), azelate (azelaic acid ester), butyrate (butyrate ester), valerate (valeric acid ester), and / or One or more plasticizers selected from the group consisting of phenol derivatives such as alkyl or aryl-substituted phenols, and / or One or more plasticizers selected from the group consisting of silanols and siloxanes, and / or One or more plasticizers selected from the group consisting of sulfates (sulfate esters) such as alkyl sulfates, sulfonates (sulfonic acid esters) such as alkylaryl sulfonates and alkyl and / or sulfonates, and phosphates (phosphate esters) such as tripolyphosphates (tripolyphosphate esters), and / or One or more plasticizers in the form of hydroxy acids, and / or One or more plasticizers selected from the group consisting of monomer amides such as acetamide and benzamide, and fatty acid amides such as tall oil amide, and / or One or more plasticizers selected from the group consisting of quaternary ammonium compounds such as trimethylglycine and distearyldimethylammonium chloride, and / or One or more plasticizers selected from methyl acid esters, and / or One or more plasticizers selected from the group consisting of alkyl polyglucosides, gluconamides, aminoglucoseamides, sucrose esters, and sorbitan esters, and / or One or more plasticizers selected from the group consisting of polyethylene glycol and polyethylene glycol ether. It is in the form of.

[0094] In one embodiment, component (iii) is in the form of one or more plasticizers selected from the group consisting of propylene glycol, phenol derivatives, silanols, siloxanes, hydroxy acids, vegetable oils, polyethylene glycol, polyethylene glycol ethers, triethanolamine, or mixtures thereof.

[0095] Another particular and remarkable aspect of the present invention is that the use of plasticizers having a boiling point of over 100 to 380°C, more preferably 120 to 300°C, and more preferably 140 to 250°C, strongly improves the mechanical properties of the mineral fiber products according to the present invention, despite the fact that these plasticizers may, given their boiling points, at least partially evaporate during the curing of the solid binder in contact with the mineral fibers.

[0096] In one embodiment, component (iii) comprises one or more plasticizers having a boiling point greater than 100°C, for example, 110 to 280°C, more preferably 120 to 260°C, and more preferably 140 to 250°C.

[0097] The effectiveness of these plasticizers in the solid binder composition according to the present invention is thought to be related to their effect of increasing the mobility of oxidized lignin during the curing process. The increased mobility of lignin or oxidized lignin during the curing process is thought to promote effective crosslinking.

[0098] In one embodiment, component (iii) comprises one or more polyethylene glycols having an average molecular weight of 150 to 50,000 g / mol, particularly 150 to 4,000 g / mol, more particularly 150 to 1,000 g / mol, preferably 150 to 500 g / mol, and more preferably 200 to 400 g / mol.

[0099] In one embodiment, component (iii) comprises one or more polyethylene glycols having an average molecular weight of 4,000 to 25,000 g / mol, particularly 4,000 to 15,000 g / mol, and more particularly 8,000 to 12,000 g / mol.

[0100] In one embodiment, component (iii) can form a covalent bond with component (i) and / or component (ii) during the curing process. Such a component will not evaporate and will remain as part of the composition, but will be effectively modified so as not to introduce undesirable side effects to the cured product, such as water absorption. Non-limiting examples of such components are caprolactone and acrylic polymers having free carboxyl groups.

[0101] In one embodiment, component (iii) is selected from the group consisting of fatty alcohols, monohydroxy alcohols, such as pentanol and stearyl alcohol.

[0102] In one embodiment, component (iii) is selected from one or more plasticizers selected from the group consisting of alkoxylates, e.g., ethoxylates, e.g., butanol ethoxylate, e.g., butoxytriglycol.

[0103] In one embodiment, component (iii) is selected from one or more propylene glycols.

[0104] In one embodiment, component (iii) is selected from one or more glycol esters.

[0105] In one embodiment, component (iii) is selected from one or more plasticizers selected from the group consisting of adipate, acetate, benzoate, cyclobenzoate, citrate, stearate, sorbate, sebacate, azelate, butyrate, and valerate.

[0106] In one embodiment, component (iii) is selected from one or more plasticizers selected from the group consisting of phenol derivatives such as alkyl or aryl-substituted phenols.

[0107] In one embodiment, component (iii) is selected from one or more plasticizers selected from the group consisting of silanols and siloxanes.

[0108] In one embodiment, component (iii) is selected from one or more plasticizers selected from the group consisting of sulfates such as alkyl sulfates, sulfonates such as alkylaryl sulfonates and alkyl sulfonates, phosphates such as tripolyphosphates, for example tributyl phosphate (tributyl phosphate).

[0109] In one embodiment, component (iii) is selected from one or more hydroxy acids.

[0110] In one embodiment, component (iii) is selected from one or more plasticizers selected from the group consisting of monomer amides such as acetamide and benzamide, and fatty acid amides such as tall oil amide.

[0111] In one embodiment, component (iii) is selected from one or more plasticizers selected from the group consisting of quaternary ammonium compounds such as trimethylglycine and distearyldimethylammonium chloride.

[0112] In one embodiment, component (iii) is selected from one or more plasticizers selected from the group consisting of vegetable oils such as castor oil, palm oil, linseed oil, tall oil, and soybean oil.

[0113] In one embodiment, component (iii) is in the form of tall oil.

[0114] In one embodiment, component (iii) is selected from one or more plasticizers selected from the group consisting of hardened oils (hydrogenated oils) and acetylated oils.

[0115] In one embodiment, component (iii) is selected from one or more fatty acid methyl esters.

[0116] In one embodiment, component (iii) is selected from one or more plasticizers selected from the group consisting of alkyl polyglucosides, gluconamides, aminoglucoseamides, sucrose esters, and sorbitan esters.

[0117] In one embodiment, component (iii) is selected from the group consisting of polyethylene glycol and polyethylene glycol ether.

[0118] In one embodiment, component (iii) is selected from the group consisting of triethanolamine.

[0119] In one embodiment, component (iii) is in the form of one or more plasticizers, which include propylene glycol, phenol derivatives, silanols, siloxanes, hydroxy acids, vegetable oils, polyethylene glycol, polyethylene glycol ethers, and / or polyols such as 1,1,1-tris(hydroxymethyl)propane, triethanolamine, or any mixture thereof.

[0120] Surprisingly, it was found that including a plasticizer in the solid binder composition according to the present invention significantly improves the mechanical properties of the mineral fiber product according to the present invention.

[0121] The term "plasticizer" refers to a substance added to a material to make it softer, more flexible (by lowering the glass transition temperature Tg), and easier to process.

[0122] Component (iii) may also be a mixture of any of the above compounds. In one embodiment, component (iii) is present in an amount of 0.5 to 50% by weight, preferably 2.5 to 25% by weight, and more preferably 3 to 15% by weight, based on the dry weight of component (i).

[0123] In one embodiment, the solid binder is Component (i) in an amount of 25-95% by weight, for example 30-90% by weight, for example 35-85% by weight, based on the dry weight of the binder composition, and / or Component (ii) in an amount of 1 to 40% by weight, for example 4 to 20% by weight, or for example 6 to 12% by weight, based on the dry weight of component (i). The system includes and / or component (iii) is present in an amount of 0.5 to 50% by weight, preferably 2.5 to 25% by weight, and more preferably 3 to 15% by weight, based on the dry weight of component (i).

[0124] Solid binder composition for mineral fibers comprising components (i) and (iia) In one embodiment, the present invention relates to a solid binder composition for mineral fibers, • One or more components in the form of oxidized lignin (i), • One or more modifier components (iia) and This is intended for solid binder compositions containing [the specified ingredient].

[0125] The inventors have found that excellent binder properties can also be achieved with a two-component system comprising one or more components in the form of oxidized lignin (i), one or more components in the form of modifiers (iia), and optionally any of the other components listed above and below.

[0126] In one embodiment, component (iia) is a modifier in the form of one or more compounds selected from the group consisting of fatty acid triglyceride-based epoxidized oils.

[0127] In one embodiment, component (iia) is a modifier in the form of one or more compounds selected from molecules having three or more epoxy groups.

[0128] In one embodiment, component (iia) is a modifier in the form of one or more flexible oligomers or polymers containing reactive functional groups, such as carbodiimide groups, anhydride groups, oxazoline groups, amino groups, or epoxy groups, such as low-Tg acrylic polymers, low-Tg vinyl polymers, or low-Tg polyethers.

[0129] In one embodiment, component (iia) is one or more modifiers selected from the group consisting of polyethyleneimines, polyvinylamines, and fatty amines.

[0130] In one embodiment, component (iia) is one or more modifiers selected from aliphatic polyfunctional carbodiimides.

[0131] Component (iia) may also be a mixture of any of the above compounds.

[0132] While we do not wish to be bound by any particular theory, we believe that the excellent binder properties achieved by the mineral fiber binder composition comprising components (i) and (iia) and any further optional components are at least partially attributable to the effect that the modifier used as component (iia) performs at least partially the functions of a plasticizer and a crosslinking agent.

[0133] In one embodiment, the solid binder composition contains component (iia) in an amount of 1 to 40% by weight, for example, 4 to 20% by weight, for example, 6 to 12% by weight, based on the dry weight of component (i).

[0134] Further ingredients In some embodiments, the solid binder composition according to the present invention comprises further components. The further components used are preferably solid at room temperature (21°C), for example, in the form of a powder.

[0135] In one embodiment, the binder composition according to the present invention comprises a catalyst selected from inorganic acids, such as sulfuric acid, sulfamic acid, nitric acid, boric acid, hypophosphorous acid, and / or phosphoric acid, and / or any salt thereof, such as sodium hypophosphite, and / or ammonium salts, such as sulfuric acid, sulfamic acid, nitric acid, boric acid, hypophosphorous acid, and / or ammonium salts of phosphoric acid, and / or sodium polyphosphate (STTP), and / or sodium metaphosphate (STMP), and / or phosphorus oxychloride. The presence of such a catalyst can improve the curing properties of the solid binder composition according to the present invention.

[0136] In one embodiment, the solid binder composition according to the present invention is a Lewis acid capable of accepting electron pairs from a donor compound to form a Lewis adduct, such as ZnCl2, Mg(ClO4)2, Sn[N(SO2-n-C8F 17 )2]4, comprising a catalyst selected from.

[0137] In one embodiment, the solid binder composition according to the present invention comprises a catalyst selected from metal chlorides, such as KCl, MgCl2, ZnCl2, FeCl3, and SnCl2.

[0138] In one embodiment, the solid binder composition according to the present invention comprises a catalyst selected from organometallic compounds such as titanate catalysts and tin catalysts.

[0139] In one embodiment, the binder composition includes a catalyst selected from a chelating agent, such as a transition metal, such as iron ions, chromium ions, manganese ions, or copper ions, and / or a peroxide, such as an organic peroxide, such as a dicumyl peroxide.

[0140] In one embodiment, the binder composition according to the present invention comprises a catalyst selected from phosphites (phosphorous esters), such as alkyl phosphites, such as aryl phosphites, and such as triphenyl phosphites (triphenyl phosphorous esters).

[0141] In one embodiment, the binder composition according to the present invention comprises a catalyst selected from the group of tertiary amines such as tris-2,4,6-dimethylaminomethylphenol.

[0142] In one embodiment, the solid binder composition according to the present invention further comprises (iv) a further component in the form of one or more silanes.

[0143] In one embodiment, the solid binder composition according to the present invention comprises one or more coupling agents, for example, a further component (iv) in the form of an organically functionalized silane.

[0144] In one embodiment, component (iv) is selected from the group consisting of organic functionalized silanes, such as primary or secondary amino functionalized silanes; epoxy functionalized silanes, such as polymeric or oligomeric epoxy functionalized silanes; methacrylate functionalized silanes; alkyl and aryl functionalized silanes; urea functionalized silanes; or vinyl functionalized silanes.

[0145] In one embodiment, the binder composition further comprises component (v) in the form of one or more components selected from the group consisting of bases, such as ammonia, such as alkali metal hydroxides, such as KOH, such alkali metal hydroxides, such as alkaline earth alkali metal hydroxides, such as Ca(OH)2, such as Mg(OH)2, such as amines, or salts of any of these.

[0146] In one embodiment, the solid binder composition according to the present invention further comprises a further component in the form of urea in an amount of 5 to 40% by weight, for example, 10 to 30% by weight, or 15 to 25% by weight, based particularly on the dry weight of component (i).

[0147] In one embodiment, the solid binder composition according to the present invention further comprises one or more carbohydrate components selected from the group consisting of sucrose, reducing sugars, particularly dextrose, polycarbohydrates, and mixtures thereof, preferably dextrin and maltodextrin, more preferably glucose syrup, more preferably glucose syrup having a dextrose equivalent value of DE=30 to less than 100, for example DE=60 to less than 100, for example DE=60 to 99, for example DE=85 to 99, for example DE=95 to 99.

[0148] In one embodiment, the solid binder composition according to the present invention further comprises an amount of 5 to 50% by weight, for example less than 5 to 50% by weight, for example 10 to 40% by weight, for example 15 to 30% by weight, based on the dry weight of component (i), in the form of one or more carbohydrates selected from the group consisting of sucrose and reducing sugars.

[0149] In one embodiment, the mineral fiber product according to the present invention comprises mineral fibers in contact with a binder composition comprising one or more components in the form of silicone resins.

[0150] In one embodiment, the binder composition according to the present invention comprises a further component (vi) in the form of one or more reactive or non-reactive silicones.

[0151] In one embodiment, component (vi) is selected from the group consisting of silicones comprising a main chain of organosiloxane residues, particularly diphenylsiloxane residues, alkylsiloxane residues, preferably dimethylsiloxane residues, having at least one hydroxyl, carboxyl, anhydride, amine, epoxy, or vinyl functional group that can react with at least one of the components of the binder composition, and is preferably present in an amount of 0.025 to 15% by weight, preferably 0.1 to 10% by weight, and more preferably 0.3 to 8% by weight, based on the binder solids content.

[0152] In one embodiment, the mineral fiber product according to the present invention comprises mineral fibers in contact with a binder composition comprising a further component in the form of one or more mineral oils.

[0153] In the context of the present invention, a binder composition having a sugar content of 50% by weight or more based on the total dry weight of the binder components is considered a sugar-based binder. In the context of the present invention, a binder composition having a sugar content of less than 50% by weight based on the total dry weight of the binder components is considered a non-sugar-based binder.

[0154] In one embodiment, the solid binder composition according to the present invention further comprises a further component in the form of one or more surfactants, such as a nonionic and / or ionic emulsifier, such as polyoxyethylene (4) lauryl ether, such as soy lecithin, such as sodium dodecyl sulfate.

[0155] In one embodiment, the solid binder composition according to the present invention is • Component (i) is a lignosulfonate lignin of one or more types, having a carboxylic acid group content of 0.03 to 1.4 mmol / g based on the dry weight of the lignosulfonate lignin. (ii) a component in the form of one or more crosslinking agents selected from β-hydroxyalkylamide crosslinking agents and / or oxazoline crosslinking agents, and / or one or more crosslinking agents selected from the group consisting of polyfunctional organic amines such as alkanolamines, diamines such as hexamethyldiamine, and triamines, (iii) A component in the form of polyethylene glycol having an average molecular weight of 150 to 50000 g / mol, particularly 150 to 4000 g / mol, more particularly 150 to 1000 g / mol, preferably 150 to 500 g / mol, more preferably 150 to 300 g / mol, or polyethylene glycol having an average molecular weight of 4000 to 25000 g / mol, particularly 4000 to 15000 g / mol, more particularly 8000 to 12000 g / mol and The solid binder composition comprises, preferably, 1 to 40% by weight, for example, 4 to 20% by weight, 6 to 12% by weight of component (i), and (iii) is present in an amount of 0.5 to 50% by weight, preferably 2.5 to 25% by weight, more preferably 3 to 15% by weight, based on the dry weight of component (i).

[0156] In one embodiment, the solid binder composition according to the present invention is essentially • Component (i) is a lignosulfonate lignin of one or more types, having a carboxylic acid group content of 0.03 to 1.4 mmol / g based on the dry weight of the lignosulfonate lignin. • One or more crosslinking agents as components (ii), • One or more components in the form of plasticizers (iii), • One or more coupling agents, for example, a component in the form of an organically functional silane (iv), Optionally, one or more compounds selected from the group consisting of ammonia, amines, or salts thereof, • Optionally, the components in the form of urea, • Optionally, a component in the form of a more reactive or less reactive silicone, Optionally, hydrocarbon oil and • Optionally, one or more surfactants The solid binder composition consists of, but preferably, the solid binder composition is • Molecular weight M of 500 or less W epoxy compounds having It does not contain a crosslinking agent selected from and / or However, the solid binder composition is ·Formula R-[C(O)R1] x A carbonyl compound selected from the aldehyde and carbonyl compounds, wherein in the above formula, R represents a saturated or unsaturated linear, branched, or cyclic hydrocarbon group, a group containing an aromatic nucleus consisting of one or more five or six carbon atoms, or a group containing an aromatic heterocycle containing one or more four or five carbon atoms and an oxygen atom, a nitrogen atom, or a sulfur atom. This R group may contain other functional groups. R1 is a hydrogen atom or C1~C 10 Represents an alkyl group, x is a carbonyl compound in the range of 1 to 10. It does not contain a crosslinking agent selected from and / or However, the solid binder composition is • Polyamines It does not contain a crosslinking agent selected from and / or However, the solid binder composition is Monosaccharides and oligosaccharides It does not contain any crosslinking agents selected from the above.

[0157] In one embodiment, the solid binder composition according to the present invention is essentially • One or more lignosulfonate lignins, the component in the form of lignosulfonate lignin having a carboxylic acid group content of 0.03 to 1.4 mmol / g based on the dry weight of the lignosulfonate lignin, and / or • One or more crosslinking agents as components (ii) • One or more plasticizer components (iii) • One or more coupling agents, for example, components in the form of organically functional silanes (iv) Optionally, one or more compounds selected from ammonia, amines, or salts thereof, as components. • Optionally, the component in the form of urea, • Optionally, a component in the form of a more reactive or less reactive silicone. Optional: hydrocarbon oils, • Optional selection of one or more surfactants The solid binder composition consists of, but preferably, the solid binder composition is • Molecular weight M of 500 or less W epoxy compounds having It does not contain a crosslinking agent selected from and / or However, the solid binder composition is ·Formula R-[C(O)R1] x A carbonyl compound selected from the aldehyde and carbonyl compounds, wherein in the above formula, R represents a saturated or unsaturated linear, branched, or cyclic hydrocarbon group, a group containing an aromatic nucleus consisting of one or more five or six carbon atoms, or a group containing an aromatic heterocycle containing one or more four or five carbon atoms and an oxygen atom, a nitrogen atom, or a sulfur atom. This R group may contain other functional groups. R1 is a hydrogen atom or C1~C 10 Represents an alkyl group, x is a carbonyl compound in the range of 1 to 10. It does not contain a crosslinking agent selected from and / or However, the solid binder composition is • Polyamines It does not contain a crosslinking agent selected from and / or However, the solid binder composition is Monosaccharides and oligosaccharides It does not contain any crosslinking agents selected from the above.

[0158] In one embodiment, the solid binder composition according to the present invention is essentially • Component (i) is a lignosulfonate lignin of one or more types, having a carboxylic acid group content of 0.03 to 1.4 mmol / g based on the dry weight of the lignosulfonate lignin. • One or more crosslinking agents as components (ii), • One or more coupling agents, for example, a component in the form of an organically functional silane (iv), Optionally, one or more compounds selected from the group consisting of ammonia, amines, or salts thereof, • Optionally, the components in the form of urea, • Optionally, a component in the form of a more reactive or less reactive silicone, Optionally, hydrocarbon oil and • Optionally, one or more surfactants The solid binder composition consists of, but preferably, the solid binder composition is • Molecular weight M of 500 or less W epoxy compounds having It does not contain a crosslinking agent selected from and / or However, the solid binder composition is ·Formula R-[C(O)R1] x A carbonyl compound selected from the aldehyde and carbonyl compounds, wherein in the above formula, R represents a saturated or unsaturated linear, branched, or cyclic hydrocarbon group, a group containing an aromatic nucleus consisting of one or more five or six carbon atoms, or a group containing an aromatic heterocycle containing one or more four or five carbon atoms and an oxygen atom, a nitrogen atom, or a sulfur atom. This R group may contain other functional groups. R1 is a hydrogen atom or C1~C 10Represents an alkyl group, x is a carbonyl compound in the range of 1 to 10. It does not contain a crosslinking agent selected from and / or However, the solid binder composition is • Polyamines It does not contain a crosslinking agent selected from and / or However, the solid binder composition is Monosaccharides and oligosaccharides It does not contain any crosslinking agents selected from the above.

[0159] In one embodiment, the solid binder composition according to the present invention is essentially • One or more lignosulfonate lignins, the component in the form of lignosulfonate lignin having a carboxylic acid group content of 0.03 to 1.4 mmol / g based on the dry weight of the lignosulfonate lignin, and / or • One or more crosslinking agents as components (ii) • One or more coupling agents, for example, components in the form of organically functional silanes (iv) Optionally, one or more compounds selected from ammonia, amines, or salts thereof, as components. • Optionally, the component in the form of urea, • Optionally, a component in the form of a more reactive or less reactive silicone. Optional: hydrocarbon oils, • Optional selection of one or more surfactants The solid binder composition consists of, but preferably, the solid binder composition is • Molecular weight M of 500 or less W epoxy compounds having It does not contain a crosslinking agent selected from and / or However, the solid binder composition is ·Formula R-[C(O)R1] x A carbonyl compound selected from the aldehyde and carbonyl compounds, wherein in the above formula, R represents a saturated or unsaturated linear, branched, or cyclic hydrocarbon group, a group containing an aromatic nucleus consisting of one or more five or six carbon atoms, or a group containing an aromatic heterocycle containing one or more four or five carbon atoms and an oxygen atom, a nitrogen atom, or a sulfur atom. This R group may contain other functional groups. R1 is a hydrogen atom or C1~C 10 Represents an alkyl group, x is a carbonyl compound in the range of 1 to 10. It does not contain a crosslinking agent selected from and / or However, the solid binder composition is • Polyamines It does not contain a crosslinking agent selected from and / or However, the solid binder composition is Monosaccharides and oligosaccharides It does not contain any crosslinking agents selected from the above.

[0160] The method according to the present invention The present invention also relates to a method for producing a bound mineral fiber product, comprising the steps of contacting mineral fibers with the solid binder composition of the present invention described above, and curing the binder composition in contact with the mineral fibers. Any optional / preferred features of the solid binder composition described above also apply to the method of the present invention.

[0161] As described in detail above, the solid binder composition is • Component (i) is a lignosulfonate lignin of one or more types, having a carboxylic acid group content of 0.03 to 1.4 mmol / g based on the dry weight of the lignosulfonate lignin. • One or more crosslinking agents as components (ii), • Optionally, one or more components in the form of plasticizers (iii) and Includes.

[0162] To bring the mineral fibers and the solid binder composition into contact with each other, the mineral fibers and the solid binder composition may be simply mixed together, for example, in a stirring device. The resulting mixture can then be transferred to a curing device, such as a curing oven or a heated press. The solid binder composition is generally cured thermally, for example, by chemical and / or physical reactions of the binder components, usually by chemical reactions (crosslinking) and optionally by physical reactions.

[0163] In a preferred embodiment, the binder composition in contact with the mineral fibers is cured by hot pressing.

[0164] The curing of a binder composition in contact with mineral fibers during hot pressing has the special advantage that the curing enables the manufacture of high-density products. The binder composition according to the present invention is a solid binder, and therefore evaporation of the solution water is avoided, making it particularly suitable for use in such a method.

[0165] Preferably, the binder composition in contact with the mineral fibers is cured at a temperature of 150-300°C, preferably 170-250°C, and particularly 190-230°C, preferably by hot pressing.

[0166] In one embodiment, curing is carried out over a period of 30 seconds to 20 minutes, for example, 1 to 15 minutes, or for example, 2 to 10 minutes. In a typical embodiment, curing is carried out over a period of 30 seconds to 20 minutes at a temperature of 150 to 250°C. The above temperature is preferably the set temperature of the hot press.

[0167] There are several methods for preparing the solid binder according to the present invention from the starting components.

[0168] In a preferred embodiment, the binder that comes into contact with the mineral fibers is prepared by mixing the components of a solid binder composition, where the average water content of the components, calculated as the weight of water relative to the total weight of the solid binder, is 30% or less, particularly 25% or less, and more preferably 10% or less.

[0169] In an alternative preferred embodiment, the solid binder composition that comes into contact with the mineral fibers is prepared by dissolving all its components in water, and then evaporating the water or a portion of the water to form a powder or any other solid state.

[0170] A preferred method for evaporating water or a portion of water to form a powder or any other solid state includes the use of spray drying of a solid binder composition.

[0171] Generally, whether a solid binder composition is already obtained by mixing the components, or whether further measures such as the removal of water or part of the water contained in the mixed components should be taken, depends on the components used in the binder composition. Alternatively or additionally, the type and amount of crosslinking agents and / or plasticizers, if used, can be appropriately selected to obtain a solid binder composition.

[0172] As described above, water removal can be performed before and / or after the components of the binder composition are mixed. For example, if one or more lignosulfonates, one or more crosslinking agents, and one or more plasticizers (if added) are all in solid form, the mixture of all components usually yields a solid binder composition. If one or more crosslinking agents and / or one or more plasticizers (if added) are in liquid form, it may be necessary to remove water or a portion of the water to obtain a solid binder composition.

[0173] Water is usually present in one or more lignosulfonate lignins, and this water may be removed before or after mixing the components.

[0174] Binder composition for mineral fibers in slurry form In one embodiment, the present invention relates to a binder composition for mineral fibers in the form of a slurry, • Component (i) is a lignosulfonate lignin of one or more types, having a carboxylic acid group content of 0.03 to 1.4 mmol / g based on the dry weight of the lignosulfonate lignin. • One or more crosslinking agents as components (ii), • Optionally, one or more components in the form of plasticizers (iii) and This is intended for binder compositions for mineral fibers that include [the specified ingredient].

[0175] The present inventors have found that a binder composition comprising one or more components in the form of lignosulfonate lignin (i), one or more components in the form of a crosslinking agent (ii), optionally one or more components in the form of a plasticizer (iii), and optionally any of the other components described above and below, can also achieve good binder properties even when the binder composition is in the form of a slurry.

[0176] With regard to the lignosulfonate lignin, crosslinking agent, plasticizer, and other components contained in this binder composition, refer to the description given for the solid binder above.

[0177] A binder composition in slurry form is a binder composition in liquid form in which at least lignosulfonate lignin is normally present as a solid. Such a binder composition in slurry form also includes paste-like binder compositions, i.e., binder compositions in paste form.

[0178] The binder composition in slurry form may contain water. However, this water is usually bound to one or more lignosulfonates and lignins. The liquid contained in the binder composition in slurry form may contain one or more crosslinking agents and / or one or more plasticizers, if added, in liquid form. The liquid contained in the binder composition in slurry form preferably has a low water content, for example, 5 to 20% by weight of water based on the total weight of the binder composition, or is water-free. In this regard, the binder composition in slurry form of the present invention can be considered a non-aqueous binder composition.

[0179] Mineral fiber products according to the present invention The present invention is also directed to mineral fiber products comprising mineral fibers in contact with the hardened solid binder composition described above. The mineral fiber products of the present invention are generally bonded mineral fiber products. The mineral fiber products of the present invention can preferably be obtained by the method of the present invention described above. Any / preferred features of the solid binder composition described above and the method described above also apply to the mineral fiber products of the present invention.

[0180] The mineral fibers used may be any of the following: artificial glass fibers (MMVF), glass fibers, ceramic fibers, basalt fibers, slag fibers, rock fibers, stone fibers, etc. These fibers may exist as wool products, such as stone wool products. In a preferred embodiment, the mineral fibers are stone fibers.

[0181] Fiber / Melted Composition Artificial glass fibers (MMVF) can have any suitable oxide composition. The fibers may be glass fibers, ceramic fibers, basalt fibers, slag fibers, or rock or stone fibers. The fibers are preferably of the type commonly known as rock fibers, stone fibers, or slag fibers, and most preferably stone fibers.

[0182] Stone fibers typically contain the following oxides by weight percentage: SiO2: 30~51 Al2O3: 12-30 CaO: 8-30 MgO: 2~25 FeO (including Fe2O3): 2-15 Na2O + K2O: 10 or less CaO + MgO: 10-30

[0183] In a preferred embodiment, MMVF has the following elemental levels, calculated as weight percent as oxide: SiO2: at least 30, 32, 35 or 37; 51, 48, 45 or 43 or less Al2O3: at least 12, 16, or 17; 30, 27, or 25 or less CaO: at least 8 or 10; 30, 25, or 20 or less. MgO: at least 2 or 5; 25, 20, or 15 or less FeO (including Fe2O3): at least 4 or 5; 15, 12, or 10 or less FeO + MgO: at least 10, 12, or 15; 30, 25, or 20 or less Na2O + K2O: Zero or at least 1; ≤ 10 CaO + MgO: at least 10 or 15; 30 or 25 or less TiO2: Zero or at least 1; 6, 4, or 2 or less TiO2 + FeO: at least 4 or 6; 18 or 12 or less B2O3: Zero or at least 1; 5 or 3 or less P2O5: Zero or at least 1; 8 or 5 or less Other: Zero or at least 1; 8 or 5 or less.

[0184] The MMVF produced by the method of the present invention preferably has the following composition in weight percent. SiO235~50 Al2O3 12~30 Up to TiO22 Fe2O33~12 CaO 5-30 MgO up to 15 Na2O 0~15 K2O 0-15 Up to P2O53 Up to MnO3 Up to B2O33

[0185] Another preferred composition for MMVF is as follows, in weight percent: SiO2 39-55%, preferably 39-52% Al2O3 16-27%, preferably 16-26% CaO 6-20%, preferably 8-18% MgO 1-5%, preferably 1-4.9% Na2O 0-15%, preferably 2-12% K2O 0-15%, preferably 2-12% R2O(Na2O+K2O) 10-14.7%, preferably 10-13.5% P2O 50-3%, preferably 0-2% Fe2O3 (total iron) 3-15%, preferably 3.2-8% B2O 30-2%, preferably 0-1% TiO2 0-2%, preferably 0.4-1% Other 0-2.0%

[0186] Glass fibers typically contain the following oxides by weight percentage: SiO2: 50~70 Al2O3 10-30 CaO: 27 or less MgO: 12 or less

[0187] Glass fibers may also contain the following oxides by weight percentage: Na2O + K2O: 8-18, especially more than CaO + MgO. B2O3: 3-12

[0188] Several glass fiber compositions, Al2O3: Less than 2% It can contain.

[0189] Suitable fiber-forming methods for producing mineral fiber products and subsequent manufacturing processes are conventional in the art. The mineral fiber products produced are, for example, woven fabrics and non-woven fabrics, mats, bats, slabs, sheets, plates, strips, rolls, and, for example, as heat insulation materials or sound insulation materials, vibration damping materials, building materials, such as exterior profiles for windows, facade insulation materials, roofing materials or floor materials for reinforcement, as filter stock, and in other forms of molded products for other uses.

[0190] According to the present invention, it is also possible to produce a composite material by combining a bonded mineral fiber product with a suitable composite layer or laminate layer, such as metal, wood, gypsum board, glass surface finishing mat and other woven or non-woven materials.

[0191] In a preferred embodiment, the mineral fiber product is a plate, preferably a rigid plate such as a clad plate, and the mineral fiber is preferably a stone fiber. These plates are particularly suitable for facade cladding.

[0192] The mineral fiber product may have a density of 80 to ˆ 1400 kg / m 3 However, the mineral fiber product of the present invention is preferably a high-density product. Therefore, the mineral fiber product, particularly when the mineral fiber product is in the form of a plate, has a density of 500 to ^ 1400 kg / m 3 More preferably 1000 to ˆ 1300 kg / m 3 Particularly preferably 1100 to ˆ 1200 kg / m 3 It is preferable to have a density of.

[0193] Preferably, the mineral fiber product according to the present invention has a loss on ignition of 3 to 3ˆ weight%, particularly 5 to 25 weight%, more particularly 10 to 20 weight%.

[0194] The use according to the present invention The binder composition according to the present invention is particularly useful for binding mineral fibers, but may also be used as a binder for other typical uses of binders, such as for casting sand, chipboard, glass fiber tissue, cellulose fibers, non-woven paper products, composites, molded products, coatings, and the like.

[0195] In particular, the present invention also relates to the use of the above solid binder composition as a binder for mineral fibers or as an adhesive for adhering components to each other. The optional / preferred features of the above solid binder composition, the above method, and the above mineral fiber product of the present invention also apply to the mineral fiber product of the present invention.

[0196] When the solid binder composition is used as an adhesive for adhering components to each other, those components may be two components of the same material or different materials.

[0197] In a preferred embodiment, the solid binder composition is used as an adhesive for adhering a sheet material onto components such as stone wool products. This sheet material can be, for example, a fleece or a foil.

Examples

[0198] In the following examples, several binders falling within the definition of the present invention were prepared and compared with binders according to the prior art.

[0199] Unless otherwise specified, the following reagents were used as received.

[0200] Prefere (registered trademark) 94 8182U0 novolak resin was supplied by Prefere Resins and used as received. This resin has a hexamine content of 9.0 ± 0.5%.

[0201] Lignosulfonates were supplied as liquids with approximately 50% solids content by Borregaard, Norway and LignoTech, Florida. Primid XL552 was supplied by EMS-CHEMIE AG.

[0202] Fiber bar test Stone wool fibers were manufactured in a stone wool manufacturing facility by adding silane (Dynasylan HYDROSIL 1151; silane content: 4.8 l / ton), surfactant (Tegopren 5840; 0.5% aqueous solution at 55 l / ton), and oil (Tudalen 3912, 0.4 l / ton). The stone wool fibers used had a coating content of 27-137 mg / kg; an average fiber diameter of 4.2-5.8 μm; and shot content (>63 μm: <37%; >250 μm: <10% and >600 μm: <1.7%). This stone wool was used as supplied and opened in a loadinger mixer to ensure proper mixing with the binder. This was done by filling the mixer with ±1.7 kg of wool and mixing / opening for 8 seconds. After opening the wool, the stone wool fibers are mixed with the required proportion of dry binder in a Stephan mixer for 30 seconds. This mixture is transferred to a mold and cold-pressed. A laboratory hot press with a preheating cycle is used for hot-pressing the panels. Pressing times and temperatures are shown in Table 1. After the panels have cooled, they are cut to dimensions of 320 × 50 mm.

[0203] The density and flexural strength of the samples were determined according to NEN-EN-323 (density) and NEN-EN-310 (flexural strength). Five test specimens were aged in (tap) water at 70°C for 30 minutes (containing a surface tension alteration additive: e.g., 0.5 ml Triton per liter). The flexural strength after aging was determined according to EN-310 within 20 minutes after the aging period in a test chamber at an air temperature of 17-23°C. The density and flexural strength before and after aging are also shown in part in Table 1.

[0204] Comparative Example 300g of material (264g of stone wool fiber and 36g of Prelere® 94 8182U0 novolac resin) was mixed and used as described in the "Fiber Bar Test".

[0205] Example 1 1500.0 g of lignosulfonate solution (50% solids) was mixed with 545.0 g of Primid XL552 solution (a pre-prepared 31% by weight aqueous solution). This mixture was dried in an oven at 105°C. The resulting material was ground little by little using a Herzog grinder (50-100 g per batch) (running time: 30 seconds per batch).

[0206] Example 1.1 300g of material (264g of stone wool fibers and 36g of pulverized and dried binder from Example 1) was mixed and used as described in the "Fiber Bar Test".

[0207] Example 1.2 300g of the material (225g of stone wool fibers and 75g of the pulverized and dried binder from Example 1) was mixed and used as described in the "Fiber Bar Test".

[0208] [Table 1]

Claims

1. A solid binder composition for mineral fibers, Component (i) in the form of a lignosulfonate lignin having a carboxylic acid group content of 0.03 to 1.4 mmol / g based on the dry weight of the lignosulfonate lignin, (ii) one or more crosslinking agent components and Includes, The component (i) is a solid binder composition having a phenolic OH group content of 0.3 to 2.5 mmol / g based on the dry weight of the lignosulfonate lignin.

2. The binder composition is One or more plasticizer components (iii) The solid binder composition according to claim 1, further comprising:

3. The solid binder composition according to claim 1 or claim 2, wherein the water content, calculated as the weight of water relative to the total weight of the solid binder composition, is 30% or less.

4. The solid binder composition according to any one of claims 1 to 3, which is in powder form and / or 50% by weight of the components of the solid binder composition having particle sizes of less than 500 μm and greater than 10 μm.

5. The solid binder composition according to any one of claims 1 to 4, wherein component (i) has a carboxylic acid group content of 0.05 to 0.6 mmol / g based on the dry weight of the lignosulfonate lignin.

6. The solid binder composition according to any one of claims 1 to 5, wherein component (i) is in the form of one or more lignosulfonate lignins having an average carboxylic acid group content of less than 1.8 groups per polymer, taking into consideration the M-n weight average of component (i).

7. The solid binder composition according to any one of claims 1 to 6, wherein component (i) contains 0.5 to 2.0 mmol / g of phenolic OH groups based on the dry weight of the lignosulfonate lignin.

8. The solid binder composition according to any one of claims 1 to 7, wherein component (i) has an aliphatic OH group content of 1.0 to 8.0 mmol / g based on the dry weight of the lignosulfonate lignin.

9. The solid binder composition according to any one of claims 1 to 8, wherein component (i) comprises ammonium lignosulfonate and / or calcium lignosulfonate and / or magnesium lignosulfonate, or any combination thereof.

10. The component (i) comprises ammonium lignosulfonate and calcium lignosulfonate, and NH ４ ＋ vs Ca ２＋ The solid binder composition according to any one of claims 1 to 9, wherein the molar ratio is in the range of 5:1 to 1:

5.

11. The solid binder composition according to any one of claims 1 to 10, wherein the binder composition contains an amount of added sugar in the form of 0.1 to 4.9% by weight based on the weight of the lignosulfonate and the sugar.

12. The binder composition according to any one of claims 1 to 11, comprising 50 to 98% by weight of component (i) based on the dry weight of components (i) and (ii).

13. The solid binder composition according to any one of claims 1 to 12, comprising 50 to 88% by weight of component (i) based on the dry weight of components (i) and (ii).

14. The aforementioned component (ii) is, a) β-hydroxyalkylamide crosslinking agents and / or oxazoline crosslinking agents, and / or b) A group consisting of polyfunctional organic amines, diamines, and triamines, and / or c) Epoxy compounds having a molecular weight greater than 500, and / or d) One or more crosslinking agents selected from the group consisting of polyethyleneimine, polyvinylamine, and fatty amine, and / or e) One or more crosslinking agents in the form of fatty amides, and / or f) One or more crosslinking agents selected from aromatic aldehydes and / or aliphatic aldehydes, and / or g) One or more crosslinking agents selected from polyester polyols, and / or h) One or more crosslinking agents selected from the group consisting of starch, modified starch, and CMC, and / or i) One or more crosslinking agents in the form of aliphatic polyfunctional carbodiimides, and / or j) One or more crosslinking agents selected from melamine-based crosslinking agents A solid binder composition according to any one of claims 1 to 13, wherein the form is one or more crosslinking agents selected from the above.

15. The solid binder composition according to any one of claims 1 to 14, wherein component (ii) comprises one or more crosslinking agents selected from β-hydroxyalkylamide crosslinking agents and / or oxazoline crosslinking agents.

16. The solid binder composition according to any one of claims 1 to 15, comprising 1 to 50% by weight of component (ii) based on the dry weight of component (i).

17. The aforementioned component (ii) is, β-hydroxyalkylamide crosslinking agent, and / or A group consisting of polyfunctional organic amines, diamines, and / or Epoxy compounds having a molecular weight greater than 500, and / or One or more crosslinking agents in the form of polyfunctional carbodiimides A solid binder composition according to any one of claims 1 to 16, wherein the form is one or more crosslinking agents selected from the above.

18. The aforementioned component (ii) is, A solid binder composition according to any one of claims 1 to 17, comprising a β-hydroxyalkylamide crosslinking agent.

19. The solid binder composition according to any one of claims 1 to 18, comprising 2 to 90% by weight of component (ii) based on the dry weight of component (i).

20. The component (iii) is one or more plasticizers selected from the group consisting of polyethylene glycol, polyethylene glycol ether, polyether, hydride sugar, phthalate and / or acid, acrylic polymer, polyvinyl alcohol, polyurethane dispersion, ethylene carbonate, propylene carbonate, lactone, lactam, lactide, acrylic polymer having a free carboxyl group and / or polyurethane dispersion having a free carboxyl group, and / or One or more plasticizers selected from the group consisting of fatty alcohols and monohydroxy alcohols, and / or Plasticizers comprising alkoxylates, and / or One or more plasticizers in the form of propylene glycol, and / or One or more plasticizers in the form of glycol esters, and / or One or more plasticizers selected from the group consisting of adipate, acetate, benzoate, cyclobenzoate, citrate, stearate, sorbate, sebacate, azelate, butyrate, and valerate, and / or One or more plasticizers selected from the group consisting of phenol derivatives, and / or One or more plasticizers selected from the group consisting of silanols and siloxanes, and / or One or more plasticizers selected from the group consisting of sulfates, sulfonates, and phosphates, and / or Plasticizers in the form of hydroxy acids, and / or One or more plasticizers selected from the group consisting of monomer amides and fatty acid amides, and / or Plasticizers comprising quaternary ammonium compounds, and / or One or more plasticizers selected from methyl acid esters, and / or One or more plasticizers selected from the group consisting of alkyl polyglucosides, gluconamides, aminoglucoseamides, sucrose esters, and sorbitan esters, and / or One or more plasticizers selected from the group consisting of polyethylene glycol and polyethylene glycol ether. A solid binder composition according to any one of claims 1 to 19, in the form of a solid binder composition according to any one of claims 1 to 19.

21. The solid binder composition according to any one of claims 1 to 20, wherein component (iii) is in the form of propylene glycol, a phenol derivative, silanol, siloxane, hydroxy acid, vegetable oil, polyethylene glycol, polyethylene glycol ether, triethanolamine, or a mixture thereof.

22. The solid binder composition according to any one of claims 1 to 21, wherein component (iii) comprises one or more plasticizers having a boiling point of 100 to 380°C.

23. The solid binder composition according to any one of claims 1 to 22, wherein component (iii) comprises one or more polyethylene glycols having an average molecular weight of 150 to 50,000 g / mol.

24. The component (i) in an amount of 25 to 95% by weight based on the dry weight of the binder composition, and / or Based on the dry weight of component (i), an amount of component (ii) of 1 to 40% by weight. A solid binder composition according to any one of claims 1 to 23, comprising and / or wherein component (iii) is present in an amount of 0.5 to 50% by weight based on the dry weight of component (i).

25. One or more coupling agent components (iv), and / or The base form component (v), and / or A component in the form of urea in an amount of 5 to 40% by weight based on the dry weight of component (i) A solid binder composition according to any one of claims 1 to 24, further comprising:

26. A solid binder composition according to any one of claims 1 to 25, comprising one or more reactive or non-reactive silicone components (vi).

27. A method for producing a bonded mineral fiber product, comprising the steps of: contacting mineral fibers with a solid binder composition according to any one of claims 1 to 26; and curing the binder composition while in contact with the mineral fibers.

28. The method according to claim 27, wherein the hardening of the solid binder composition in contact with the mineral fibers is performed by hot pressing.

29. The method according to claim 27 or claim 28, wherein the curing of the solid binder composition in contact with the mineral fibers is carried out at a temperature of 150 to 300°C.

30. A mineral fiber product comprising mineral fibers in contact with a hardened solid binder composition according to any one of claims 1 to 26.

31. A mineral fiber product according to claim 30, having a density of 80 to 1400 kg / m³.

32. The mineral fiber product according to claim 30 or claim 31, having a loss on ignition of 3 to 30% by weight.

33. The mineral fiber product according to any one of claims 30 to 32, wherein the mineral fiber product is a panel and / or the mineral fiber is a stone fiber.

34. Use of the solid binder composition according to any one of claims 1 to 26 as a binder for mineral fibers or as an adhesive for bonding components together.

35. The use according to claim 34 as an adhesive for bonding sheet material to stone wool products.

36. Use of one or more lignin components in the form of lignosulfonate lignin having the characteristics of component (i) according to any one of claims 1 to 11, for the preparation of a phenol and formaldehyde-free binder composition for mineral wool.

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