Hair dye composition

Abstract

To provide hair dye compositions excellent in hair dyeing properties and skin staining suppression properties.SOLUTION: The present invention provides a hair dye composition containing: (a) a compound represented by the following general formula (1) as a component; (b) benzyl alcohol, benzyl glycol, or a mixture thereof as a component; and (c) an acid dye as a component, the mass ratio of the contents of the components (a) and (b) in the hair dye composition being 10:90 to 90:10 (in the formula, R1 represents a hydrocarbon group with 6 to 8 carbon atoms).SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a hair dye composition that exhibits excellent hair dyeing properties and suppression of skin staining. [Background technology]

[0002] In the field of hair dyes, including permanent and temporary hair dyes, various compositions of hair dyes and their additives have been developed to improve dyeing properties and usability. For example, Patent Document 1 proposes an acidic hair dye composition for the scalp comprising glycolic acid and / or pyrrolidone carboxylic acid and / or salts thereof, and a specific dye. Patent Document 2 proposes an acidic hair dye composition for the scalp containing a carboxyvinyl polymer, alcohols selected from monohydric alcohols such as ethyl alcohol, butyl alcohol, cyclohexanol, benzyl alcohol, phenoxyethanol, and polyhydric alcohols, and a dye. Patent Document 3 proposes a hair dye comprising a first agent adjusted to pH 1.5 to 4 and a second agent adjusted to pH 1.5 to 4 containing an acidic dye, with at least one of the first and second agents containing a thickening agent. Patent Document 4 proposes a hair dye composition in which an acidic dye is dissolved in an aqueous solvent, and hydrogel particles containing aromatic alcohols are dispersed in the aqueous solvent. Patent Document 5 proposes a hair dye composition comprising at least one selected from the group consisting of n-hexylglyceryl ether, cyclohexylglyceryl ether, and 1,2-hexanediol, and at least one selected from the group consisting of acid dyes, basic dyes, and HC dyes, with a pH of 4.5 to 12.5.

[0003] However, with these hair dye compositions, while high hair dyeing ability was desirable, there was a problem in that they also dyed the scalp and other skin, which was undesirable for users. Therefore, there was a market demand for the development of a hair dye composition that had high hair dyeing ability while also being excellent in suppressing skin staining. [Prior art documents] [Patent Documents]

[0004] [Patent Document 1] Japanese Patent Application Publication No. 6-298630 [Patent Document 2] Japanese Patent Application Publication No. 7-101841 [Patent Document 3] Japanese Patent Application Publication No. 11-071248 [Patent Document 4] Japanese Patent Publication No. 2018-083777 [Patent Document 5] International Publication No. 2020 / 189365 [Overview of the Initiative] [Problems that the invention aims to solve]

[0005] Therefore, the present invention aims to provide a hair dye composition that is excellent in hair dyeing ability and suppression of skin staining. [Means for solving the problem]

[0006] Therefore, the inventors diligently conducted research and found that a hair dye composition containing a specific compound exhibits excellent hair dyeing properties and suppression of skin staining, leading to the present invention. Specifically, the present invention is a hair dye composition comprising (a) a compound represented by the following general formula (1) as component, (b) benzyl alcohol, benzyl glycol, or a mixture thereof as component, and (c) an acid dye as component, wherein the mass ratio of the content of component (a) to component (b) in the hair dye composition is 10:90 to 90:10.

[0007] [ka]

[0008] (In the formula, R 1 (This represents a hydrocarbon group with 6 to 8 carbon atoms.) [Effects of the Invention]

[0009] The hair dye composition of the present invention is excellent in hair dyeing property and can significantly suppress skin staining.

Mode for Carrying Out the Invention

[0010] The hair dye composition of the present invention contains, as component (a), a compound represented by the following general formula (1).

[0011]

Chemical formula

[0012] (In the formula, R 1 represents a hydrocarbon group having 6 to 8 carbon atoms)

[0013] In general formula (1), R 1 represents a hydrocarbon group having 6 to 8 carbon atoms. Examples of such groups include a linear alkyl group having 6 to 8 carbon atoms, a branched alkyl group having 6 to 8 carbon atoms, an alicyclic hydrocarbon group having 6 to 8 carbon atoms, an aromatic hydrocarbon group having 6 to 8 carbon atoms, and the like. In the present invention, by containing such a compound as component (a), not only an excellent hair dyeing property but also a hair dye composition excellent in skin staining inhibitory property can be obtained. Furthermore, since the above component (a) also acts as an antibacterial agent, a hair dye composition having antibacterial properties and excellent storage stability can be obtained. In the present invention, from the viewpoints of the hair dyeing property and skin staining inhibitory property of the hair dye composition, it is preferable that component (a) contains at least one compound in which R 1 is a linear alkyl group having 6 to 8 carbon atoms, a branched alkyl group having 6 to 8 carbon atoms, or an alicyclic hydrocarbon group having 6 to 8 carbon atoms (for example, cyclohexyl group, cycloheptyl group, cyclooctyl group), and it is more preferable to contain at least one compound in which R 1 is a linear alkyl group having 6 to 8 carbon atoms or an alicyclic hydrocarbon group having 6 carbon atoms (for example, cyclohexyl group), and it is even more preferable to contain at least one compound in which R 1 is a linear alkyl group having 6 carbon atoms or an alicyclic hydrocarbon group having 6 carbon atoms (particularly, cyclohexyl group).

[0014] The content of component (a) in the hair dye composition of the present invention is not particularly limited. However, from the viewpoints of the hair dyeing property and the inhibition of skin staining of the hair dye composition, the content of component (a) in the hair dye composition is preferably 0.01% by mass to 20% by mass based on the total amount of the hair dye composition. In the present invention, when the content of component (a) in the hair dye composition is within such a range, due to the synergistic effect with component (b), component (c) can easily penetrate into the surface and inside of hair and the like, thereby enhancing the hair dyeing property, and at the same time, a hair dye composition excellent in the inhibition of skin staining can be obtained. From the viewpoints of the hair dyeing property and the inhibition of skin staining of the hair dye composition, the content of component (a) in the hair dye composition is more preferably 0.02% by mass to 15% by mass, even more preferably 0.02% by mass to 10% by mass, and most preferably 0.05% by mass to 5% by mass based on the total amount of the hair dye composition.

[0015] The hair dye composition of the present invention contains, as component (b), benzyl alcohol, benzyl glycol or a mixture thereof. In the present invention, by containing such a compound as component (b), due to the synergistic effect with component (a), a hair dye composition excellent not only in the hair dyeing property but also in the inhibition of skin staining can be obtained. The content of component (b) in the hair dye composition of the present invention is not particularly limited. However, from the viewpoints of the hair dyeing property and the inhibition of skin staining of the hair dye composition, the content of component (b) in the hair dye composition is preferably 0.01% by mass to 20% by mass, more preferably 0.02% by mass to 15% by mass, even more preferably 0.05% by mass to 12% by mass, and most preferably 0.05% by mass to 10% by mass based on the total amount of the hair dye composition.

[0016] The hair dye composition of the present invention is a hair dye composition in which the mass ratio of the content of component (a) to component (b) in the hair dye composition is 10:90 to 90:10. By having the mass ratio of the content of component (a) to component (b) in the hair dye composition within this range, the hair dye composition of the present invention not only has significantly better hair dyeing properties compared to a hair dye composition containing only component (a) or only component (b), but also significantly better skin stain suppression properties compared to a hair dye composition containing only component (b), due to the synergistic effect of component (a) and component (b). From the viewpoint of further improving the hair dyeing properties and skin stain suppression properties of the hair dye composition, it is preferable that the mass ratio of the content of component (a) to component (b) in the hair dye composition is 15:85 to 80:60, more preferably 20:80 to 60:40, and even more preferably 20:80 to 50:50.

[0017] In the hair dye composition of the present invention, the total content of component (a) and component (b) in the hair dye composition is not particularly limited, but is preferably 0.1% to 30% by mass relative to the total amount of the hair dye composition. In the present invention, by having the total content of component (a) and component (b) in the hair dye composition within this range, it is possible to obtain a hair dye composition that not only has remarkably excellent hair dyeing properties due to the synergistic effect of component (a) and component (b), but also remarkably excellent in suppressing skin staining. From the viewpoint of further improving the hair dyeing properties and skin staining suppression of the hair dye composition, it is more preferable that the total content of component (a) and component (b) in the hair dye composition is 1% to 20% by mass, even more preferably 3% to 15% by mass, and particularly preferable 5% to 15% by mass relative to the total amount of the hair dye composition.

[0018] The hair dye composition of the present invention is a hair dye composition comprising an acid dye as component (c). The acid dyes that can be used in the present invention are not particularly limited and known dyes can be used, for example, Red No. 2, Red No. 3, Red No. 102, Red No. 104, Red No. 105, Red No. 106, Red No. 201, Red No. 206, Red No. 227, Red No. 230, Red No. 231, Red No. 232, Red No. 401, Red No. 502, Red No. 503, Red No. 504, Red No. 506, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow Examples include No. 203, Yellow No. 402, Yellow No. 403, Yellow No. 406, Yellow No. 407, Blue No. 1, Blue No. 2, Blue No. 202, Blue No. 203, Blue No. 205, Orange No. 205, Orange No. 207, Orange No. 403, Green No. 3, Green No. 201, Green No. 204, Green No. 205, Green No. 401, Green No. 402, Brown No. 201, Brown No. 201, Purple No. 401, Black No. 401, etc., and one or more of these can be used.

[0019] The content of component (c) in the hair dye composition of the present invention is not particularly limited, but from the viewpoint of the hair dyeing properties and the ability to suppress skin staining, the content of component (c) in the hair dye composition is preferably 0.001% to 10% by mass, more preferably 0.01% to 5% by mass, and even more preferably 0.05% to 3% by mass, based on the total amount of the hair dye composition.

[0020] The mass ratio of the content of component (a) and component (c) in the hair dye composition of the present invention is not particularly limited, but from the viewpoint of the hair dyeing properties and the ability to suppress skin staining, the mass ratio of the content of component (a) and component (c) in the hair dye composition is preferably 30:70 to 98:2, more preferably 40:60 to 95:5, and even more preferably 50:50 to 92:8.

[0021] The mass ratio of the content of component (b) and component (c) in the hair dye composition of the present invention is not particularly limited, but from the viewpoint of the hair dyeing properties and the ability to suppress skin staining of the hair dye composition, the mass ratio of the content of component (b) and component (c) in the hair dye composition is preferably 50:50 to 99:1, more preferably 60:40 to 98:2, even more preferably 70:30 to 97:3, even more preferably 70:30 to 95:5, and particularly preferably 80:20 to 92:8.

[0022] The mass ratio of the total content of component (a) and component (b) to the content of component (c) in the hair dye composition of the present invention is not particularly limited, but from the viewpoint of the hair dyeing properties and the ability to suppress skin staining, the mass ratio of the total content of component (a) and component (b) to the content of component (c) in the hair dye composition is preferably 50:50 to 99:1, more preferably 70:30 to 98:2, and even more preferably 80:20 to 96:4.

[0023] The pH of the hair dye composition of the present invention is not particularly limited and can be adjusted depending on the application and purpose. However, from the viewpoint of the hair dyeing ability and the ability to suppress skin staining, the pH is preferably 2.0 to 12.5, more preferably 2.0 to 8.0, and even more preferably 2.0 to 4.0. The method for adjusting the pH to this range in the present invention is not particularly limited, but examples include adding a pH adjusting agent to the hair dye composition.

[0024] The pH adjusting agents that can be used in the present invention are not particularly limited, but examples include organic acids such as citric acid, glycolic acid, succinic acid, tartaric acid, lactic acid, malic acid, levulinic acid, acetic acid, butyric acid, valeric acid, oxalic acid, maleic acid, fumaric acid, and mandelic acid, and their salts; inorganic acids such as phosphoric acid, pyrophosphate, hydrochloric acid, sulfuric acid, and nitric acid; alkaline agents such as ammonia, alkanolamines, silicates, carbonates, bicarbonates, metasilicates, sulfates, chlorides, phosphates, organic amines (e.g., tetrahydroxypropylethylenediamine), basic amino acids, and hydroxides of alkali metals or alkaline earth metals. Among these, citric acid, succinic acid, tartaric acid, lactic acid, and hydroxides of alkaline earth metals are preferred, and citric acid or potassium hydroxide is more preferred. The amount of pH adjuster in the hair dye composition of the present invention is not particularly limited, but for example, it is preferably an amount that results in a pH of 2.0 to 12.5, more preferably an amount that results in a pH of 2.0 to 8.0, and even more preferably an amount that results in a pH of 2.0 to 4.0.

[0025] The hair dye composition of the present invention may or may not contain a thickening agent, but from the viewpoint of the hair dyeing properties and the ability to suppress skin staining, it is preferable to contain at least one thickening agent. The thickening agents that can be used in the present invention are not particularly limited, but examples include dimethyldiallylammonium chloride / acrylamide copolymer, acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer, polyacrylate crosspolymer-6, cellulose or its derivatives (e.g., hydroxyethylcellulose), keratin and collagen or their derivatives, calcium alginate, pullulan, agar, gelatin, tamarind seed polysaccharide, xanthan gum, carrageenan, high methoxyl pectin, low methoxyl pectin, guar gum, acacia gum, crystalline cellulose, arabinogalactan, karaya gum, tragacanth gum, alginic acid, albumin, casein, curdlan, β-glucan, β-glucan derivatives, gellan gum, dextran, α-glucose and α-glucose derivatives, and one or more of these can be used. Among these, it is preferable to contain cellulose or its derivatives, polyacrylate crosspolymer-6, xanthan gum, carrageenan, or guar gum, and it is more preferable to contain polyacrylate crosspolymer-6 or xanthan gum. When the hair dye composition of the present invention contains a thickening agent, the amount of the thickening agent is not particularly limited, but from the viewpoint of the hair dyeing properties and the ability to suppress skin staining, it is preferable that the amount of the thickening agent in the hair dye composition be 0.01% to 10% by mass, more preferably 0.1% to 7% by mass, and even more preferably 1% to 5% by mass, based on the total amount of the hair dye composition.

[0026] The hair dye composition of the present invention may or may not contain a solvent, but from the viewpoint of the hair dyeing properties and the ability to suppress skin staining, it is preferable to contain at least one solvent. The solvents that can be used in the present invention are not particularly limited, but examples include ethanol, isopropyl alcohol, butanol, isobutyl alcohol, acetone, ethyl acetate, ethylene glycol monoethyl ether, water, etc., and one or more of these may be included. The solvent content in the hair dye composition of the present invention is not particularly limited, but from the viewpoint of the hair dyeing properties and the ability to suppress skin staining, it is preferably 10% to 98% by mass, more preferably 30% to 96% by mass, and even more preferably 50% to 94% by mass, based on the total amount of the hair dye composition.

[0027] The hair dye composition of the present invention may contain components commonly used in hair dye compositions to improve and modify various properties (stability, feel, applicability, penetration, moisturizing properties, safety, aesthetic appeal, fragrance, etc.) during storage, use, and after use, depending on the intended use and application. Examples of such components include higher alcohols, hydrocarbon oils, ester oils, silicone oils, anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, powder components, higher fatty acids, humectants, metal ion chelating agents, sugars and their derivatives, amino acids and their derivatives, antioxidants, UV absorbers, antimicrobial preservatives, basic dyes, HC dyes, fragrances, etc., and may contain one or more of these.

[0028] Examples of higher alcohols include behenyl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, and cetearyl alcohol. When the hair dye composition of the present invention contains higher alcohols, the content of higher alcohols in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 20% by mass, more preferably 0.1% to 15% by mass, and even more preferably 1% to 10% by mass, based on the total amount of the hair dye composition.

[0029] Examples of hydrocarbon oils include liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum, polyisobutene, polyisoprene, isodecane, isododecane, isohexadecane, n-pentane, isopentane, n-hexane, isohexane, kerosene, decalin, tetralin, and microcrystalline wax, and one or more of these can be used. When the hair dye composition of the present invention contains hydrocarbon oil, the content of hydrocarbon oil in the hair dye composition is not particularly limited, but for example, it is preferably 0.1% to 50% by mass and more preferably 1% to 30% by mass relative to the total amount of the hair dye composition.

[0030] Examples of ester oils include ethyl acetate, butyl acetate, hexyl acetate, decyl acetate, butyl propionate, cetyl octanoate, hexyldecyl dimethyloctanoate, isononyl isononanoate, isononyl isononanoate, isotridecyl isononanoate, ethyl laurate, hexyl laurate, myristyl myristate, isopropyl myristate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, 2-heptylundecyl palmitate, decyl oleate, oleyl oleate, octyldodecyl oleate, isocetyl stearate, glyceryl stearate, butyl stearate, ethylhexyl hydroxystearate, ethylene glycol stearate, octyl oxystearate, diethyl phthalate, que Examples include synthetic ester oils such as triethyl phosphate, 2-ethylhexyl succinate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, myristyl lactate, diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, cetyl ethylhexanoate, triethylhexanoin, polyglyceryl-2 triisostearate, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, pentaerythrityl tetraisostearate, and hexa(hydroxystearate / stearic acid / rosinic acid)dipentaerythrityl; and animal and plant ester oils such as lanolin, mink oil, cocoa butter, coconut oil, palm kernel oil, camellia oil, sesame oil, castor oil, and olive oil. One or more of these can be used. When the hair dye composition of the present invention contains ester oil, the amount of ester oil in the hair dye composition is not particularly limited, but for example, it is preferably 0.1% to 50% by mass, and more preferably 1% to 30% by mass, based on the total amount of the hair dye composition.

[0031] Examples of silicone oils include linear silicone oils such as dimethylpolysiloxane (dimethicone), diphenylpolysiloxane, diphenylsiloxyphenyl trimethicone, and octamethyltrisiloxane; cyclic silicone oils such as decamethylcyclotetrasiloxane, dodecamethylcyclotetrasiloxane, octamethylcyclotetrasiloxane, cyclopentasiloxane, dodecamethylcyclopentasiloxane, octamethylcyclopentasiloxane, decamethylcyclohexasiloxane, dodecamethylcyclohexasiloxane, and octamethylcyclohexasiloxane; modified silicone oils such as alkyl-modified dimethylpolysiloxane, polyether-modified dimethylpolysiloxane, fatty acid-modified polysiloxane, higher alcohol-modified polysiloxane, amino-modified polysiloxane, and fluorine-modified polysiloxane. One or more of these can be used. When the hair dye composition of the present invention contains silicone oil, the content of silicone oil in the hair dye composition is not particularly limited, but for example, it is preferably 0.1% to 50% by mass, and more preferably 1% to 30% by mass, based on the total amount of the hair dye composition.

[0032] Examples of anionic surfactants include higher fatty acid salts, higher alcohol sulfate salts, sulfated olefin salts, higher alkyl sulfonates, α-olefin sulfonates, sulfated fatty acid salts, sulfonated fatty acid salts, phosphate ester salts, sulfate salts of fatty acid esters, glyceride sulfate salts, sulfonates of fatty acid esters, α-sulfo fatty acid methyl ester salts, polyoxyalkylene alkyl ether sulfate salts, polyoxyalkylene alkylphenyl ether sulfate salts, polyoxyalkylene alkyl ether carboxylate salts, acylated peptides, fatty acid alkanolamides or sulfate salts of their alkylene oxide adducts. Examples include sulfosuccinates, alkylbenzene sulfonates, alkylnaphthalene sulfonates, alkylbenzimidazole sulfonates, polyoxyalkylene sulfosuccinates, salts of N-acyl-N-methyltaurine, N-acyl glutamic acid or its salts, acyloxyethanesulfonates, alkoxyethanesulfonates, N-acyl-β-alanine or its salts, N-acyl-N-carboxyethyltaurine or its salts, N-acyl-N-carboxymethylglycine or its salts, acyl lactates, N-acyl sarcosine salts, and alkyl or alkenylaminocarboxymethyl sulfates, and one or more of these may be included. When the hair dye composition of the present invention contains anionic surfactants, the content of anionic surfactants in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 20% by mass, and more preferably 0.02% to 10% by mass, based on the total amount of the hair dye composition.

[0033] Examples of cationic surfactants include alkyl(alkenyl)trimethylammonium salts (e.g., cetrimonium chloride), dialkyl(alkenyl)dimethylammonium salts, alkyl(alkenyl)quaternary ammonium salts, mono or dialkyl(alkenyl)quaternary ammonium salts containing an ether group, ester group, or amide group, alkyl(alkenyl)pyridinium salt, alkyl(alkenyl)dimethylbenzylammonium salt, alkyl(alkenyl)isoquinolinium salt, dialkyl(alkenyl)morphonium salt, polyoxyethylene alkyl(alkenyl)amine, alkyl(alkenyl)amine salt, polyamine fatty acid derivatives, amyl alcohol fatty acid derivatives, benzalkonium chloride, benzethonium chloride, etc., and one or more of these may be included. When the hair dye composition of the present invention contains a cationic surfactant, the content of the cationic surfactant in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 20% by mass, and more preferably 0.02% to 10% by mass, based on the total amount of the hair dye composition.

[0034] Examples of amphoteric surfactants include carboxybetaine-type surfactants, sulfobetaine-type surfactants, phosphobetaine-type surfactants, amide-amino acid-type surfactants, and imidazolinium-betaine-type surfactants, and one or more of these may be included. When the hair dye composition of the present invention contains an amphoteric surfactant, the content of the amphoteric surfactant in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 20% by mass, and more preferably 0.02% to 10% by mass, based on the total amount of the hair dye composition.

[0035] Examples of nonionic surfactants include polyoxyalkylene alkyl ethers, polyoxyalkylene alkenyl ethers, polyoxyethylene polyoxypropylene alkyl ethers (the addition of ethylene oxide and propylene oxide may be random or blocky), polyethylene glycol propylene oxide adducts, polypropylene glycol ethylene oxide adducts, glycerin fatty acid esters or their ethylene oxide adducts, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, alkyl polyglucosides, fatty acid monoethanolamides or their ethylene oxide adducts, fatty acid-N-methyl monoethanolamides or their ethylene oxide adducts, fatty acid diethanolamides or their ethylene oxide adducts, sucrose fatty acid esters, alkyl polyglycerin ethers, polyglycerin fatty acid esters, polyethylene glycol fatty acid esters, fatty acid methyl ester ethoxylates, N-long-chain alkyldimethylamine oxides, etc., and one or more of these may be included. When the hair dye composition of the present invention contains a nonionic surfactant, the content of the nonionic surfactant in the hair dye composition is not particularly limited, but is preferably 0.01% to 20% by mass, and more preferably 0.02% to 10% by mass, based on the total amount of the hair dye composition.

[0036] Examples of powder components include inorganic powders such as talc, kaolin, mica, sericite, muscovite, phlogopite, synthetic mica, rose mica, biotite, vermiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate salts, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorapatite, hydroxyapatite, ceramic powder, metal soap, and boron nitride; and organic powders such as polyamide resin powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene-acrylic acid copolymer resin powder, benzoguanamine resin powder, polytetrafluoroethylene powder, and cellulose powder. One or more of these can be included. When the hair dye composition of the present invention contains a powder component, the amount of the powder component in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 20% by mass, and more preferably 0.02% to 10% by mass, relative to the total amount of the hair dye composition.

[0037] Examples of higher fatty acids include lauric acid, undecylenic acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, 12-hydroxystearic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid, docosahexaenoic acid, isostearic acid, 12-hydroxystearic acid, lanolin fatty acid, etc., and one or more of these may be included. When the hair dye composition of the present invention contains higher fatty acids, the content of higher fatty acids in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 20% by mass, and more preferably 0.02% to 10% by mass, based on the total amount of the hair dye composition.

[0038] Examples of humectants include deoxyribonucleic acid, mucopolysaccharides, chondroitin sulfate, hyaluronic acid, glycerin, collagen, elastin, chitin, chitosan, hydrolyzed eggshell membrane, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside, sodium lactate, urea, sodium pyrrolidone carboxylate, betaine, whey, ceramide, cholesterol, amino acids, fatty acids, phospholipids (including polymers), etc., and one or more of these may be included. When the hair dye composition of the present invention contains a humectant, the content of the humectant in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 20% by mass, and more preferably 0.02% to 10% by mass, based on the total amount of the hair dye composition.

[0039] Examples of metal ion chelating agents include aminopolycarboxylic acids, aromatic or aliphatic carboxylic acids, amino acids, ether polycarboxylic acids, phosphonic acids, phosphoric acids, hydroxycarboxylic acids, polymer electrolytes (including oligomeric electrolytes), dimethylglyoxime, ascorbic acid, thioglycolic acid, phytic acid, glyoxylic acid, glyoxalic acid, and others, and one or more of these may be included. When the hair dye composition of the present invention contains a metal ion chelating agent, the content of the metal ion chelating agent in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 10% by mass, and more preferably 0.02% to 5% by mass, based on the total amount of the hair dye composition.

[0040] Examples of sugars and their derivatives include D-glyceryl aldehyde, dihydroxyacetone, D-erythritol, D-erythritol, D-threose, erythritol, L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, D-glucose, D-talose, D-buscose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, aldoheptose, heprose, octulose, 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose, D-glucosamine, D-ga Examples include monosaccharides such as lactosamine, sialic acid, aminouronic acid, muramic acid, D-glucuronic acid, D-mannuronic acid, L-glucuronic acid, D-galacturonic acid, and L-iduronic acid; oligosaccharides such as sucrose, umbelliferose, lactose, planteose, isolichnoses, α,α-trehalose, raffinose, lycnoses, unpyricin, stachyose, and verbascose; and polysaccharides such as quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, heparan sulfate, hyaluronic acid, keratan sulfate, chondroitin, mucoitin sulfate, keratosulfate, and carotenic acid. One or more of these may be included. When the hair dye composition of the present invention contains sugars and their derivatives, the content of sugars and their derivatives in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 10% by mass, and more preferably 0.02% to 5% by mass, based on the total amount of the hair dye composition.

[0041] Examples of amino acids and their derivatives include neutral amino acids such as threonine and cysteine; basic amino acids such as hydroxylysine; and amino acid derivatives of acyl sarcosinate sodium (lauroyl sarcosinate sodium), acyl glutamate, acyl β-alanine sodium, glutathione, and pyrrolidone carboxylic acid. One or more of these may be included. When the hair dye composition of the present invention contains amino acids and their derivatives, the content of amino acids and their derivatives in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 10% by mass, and more preferably 0.02% to 5% by mass, based on the total amount of the hair dye composition.

[0042] Examples of antioxidants include tocopherol, butylhydroxyanisole, dibutylhydroxytoluene, and phytic acid, and the hair dye composition may contain one or more of these. When the hair dye composition of the present invention contains an antioxidant, the amount of the antioxidant in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 10% by mass, and more preferably 0.02% to 5% by mass, relative to the total amount of the hair dye composition.

[0043] Examples of UV absorbers include 2,4-dihydroxybenzophenone, 5,5'-methylenebis(2-hydroxy-4-methoxybenzophenone), 2-(2-hydroxy-5-methylphenyl)benzotriazole, 2-(2-hydroxy-5-tert-octylphenyl)benzotriazole, 2-(2-hydroxy-3,5-di-tert-butylphenyl)-5-chlorobenzotriazole, 2-(2-hydroxy-3-tert-butyl-5-methylphenyl)-5-chlorobenzotriazole, and 2-(2-hydroxy-3,5-di Cumylphenyl)benzotriazole, 2,2'-methylenebis(4-tert-octyl-6-benzotriazolylphenol), polyethylene glycol ester of 2-(2-hydroxy-3-tert-butyl-5-carboxyphenyl)benzotriazole, 2-[2-hydroxy-3-(2-acryloyloxyethyl)-5-methylphenyl]benzotriazole, 2-[2-hydroxy-3-(2-methacryloyloxyethyl)-5-tert-butylphenyl]benzotriazole, 2-[2-hydroxy-3-(2-methacryloyloxyethyl)-5-methylphenyl]benzotriazole [Royloxyethyl)-5-tert-octylphenyl]benzotriazole, 2-[2-hydroxy-3-(2-methacryloyloxyethyl)-5-tert-butylphenyl]-5-chlorobenzotriazole, 2-[2-hydroxy-5-(2-methacryloyloxyethyl)phenyl]benzotriazole, 2-[2-hydroxy-3-tert-butyl-5-(2-methacryloyloxyethyl)phenyl]benzotriazole, 2-[2-hydroxy-3-tert-amyl-5-(2-methacryloyloxyethyl)phenyl] Benzotriazole, 2-[2-hydroxy-3-tert-butyl-5-(3-methacryloyloxypropyl)phenyl]-5-chlorobenzotriazole, 2-[2-hydroxy-4-(2-methacryloyloxymethyl)phenyl]benzotriazole, 2-[2-hydroxy-4-(3-methacryloyloxy-2-hydroxypropyl)phenyl]benzotriazole, 2-[2-hydroxy-4-(3-methacryloyloxypropyl)phenyl]benzotriazole, phenyl salicylate, resorcinol monobenzoate, 2,4-di-tert-butylphenyl-3,5-di-tert-butyl-4-hydroxybenzoate, octyl(3,5-di-tert-butyl-4-hydroxy)benzoate, dodecyl(3,5-di-tert-butyl-4-hydroxy)benzoate, tetradecyl(3,5-di-tert-butyl-4-hydroxy)benzoate, hexadecyl(3,5-di-tert-butyl-4-hydroxy)benzoate, octadecyl(3,5-di-tert-butyl-4-hydroxy)benzoate, behenyl(3,5-di-tert Examples include butyl-4-hydroxy)benzoate, 2-ethyl-2'-ethoxyoxanilide, 2-ethoxy-4'-dodecyloxanilide, ethyl-α-cyano-β,β-diphenyl acrylate, methyl-2-cyano-3-methyl-3-(p-methoxyphenyl)acrylate, ethylhexyl methoxycinnamate, bis-ethylhexyloxyphenol methoxyphenyl triazine, diethylamino hydroxybenzoyl hexyl benzoate, various metal salts or metal chelates, and one or more of these may be included. When the hair dye composition of the present invention contains an ultraviolet absorber, the amount of ultraviolet absorber in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 10% by mass, and more preferably 0.02% to 5% by mass, relative to the total amount of the hair dye composition.

[0044] Examples of antimicrobial preservatives include paraben-based antimicrobial agents such as methylparaben and ethylparaben; imidazole-based antimicrobial agents such as thiabendazole and methylpreventol 2-bentuimidazolcarbamate; carvanilide-based antimicrobial agents such as trichlorocarbanilide and clofulcarban; thiazole-based antimicrobial agents such as benzothiazole; triazine-based antimicrobial agents such as debuconazole and cavinone; and biguanide-based antimicrobial agents such as chlorhexidine hydrochloride and polyhexamethylene biguanide. One or more of these may be included. When the hair dye composition of the present invention contains an antimicrobial preservative, the content of the antimicrobial preservative in the hair dye composition is not particularly limited, but for example, it is preferably 0.001% to 10% by mass, and more preferably 0.01% to 5% by mass, relative to the total amount of the hair dye composition.

[0045] Examples of basic dyes include basic blue 7, basic blue 16, basic blue 22, basic blue 26, basic blue 75, basic blue 99, basic violet 10, basic violet 14, basic brown 12, basic brown 16, basic brown 17, basic red 2, basic red 12, basic red 22, basic red 51, basic red 76, basic yellow 57, basic yellow 87, basic orange 31, basic black 2, etc., and one or more of these can be used. When the hair dye composition of the present invention contains basic dyes, the content of basic dyes in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 10% by mass, and more preferably 0.02% to 5% by mass, based on the total amount of the hair dye composition.

[0046] Examples of HC dyes include HC Blue 2, HC Blue 5, HC Blue 6, HC Blue 9, HC Blue 10, HC Blue 11, HC Blue 12, HC Blue 13, HC Violet 1, HC Violet 2, HC Red 1, HC Red 3, HC Red 7, HC Red 10, HC Red 11, HC Red 13, HC Red 14, HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, HC Yellow 9, HC Yellow 10, HC Yellow 11, HC Yellow 12, HC Yellow 13, HC Yellow 14, HC Yellow 15, HC Orange 1, HC Orange 2, HC Orange 3, etc., and one or more of these can be used. When the hair dye composition of the present invention contains an HC dye, the content of the HC dye in the hair dye composition is not particularly limited, but for example, it is preferably 0.01% to 10% by mass, and more preferably 0.02% to 5% by mass, relative to the total amount of the hair dye composition.

[0047] Fragrance ingredients include, for example, acetylcedrene, allyl amyl glycolate, β-ionone, isobutylquinoline, iris oil, ylone, indole, undecanal, undecenal, γ-undecalactone, estragol, eugenol, oakmoss, opoponax resinoid, orange oil, eugenol, aurantiol, galacsolid, carvacrol, camphor, carrot seed oil, clove oil, methyl cinnamate, geraniol, and geranyl. Nitrile, isobornyl acetate, geranyl acetate, dimethylbenzylcarbinyl acetate, styraryl acetate, cedyl acetate, terepinel acetate, vetiveryl acetate, benzyl acetate, linalyl acetate, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamenaldehyde, cyclopentadecanol, methyl dihydrojasmonate, dihydromyrcenolate, jasmine absolute, jasmine lactone, citral, citronenol, Citronellal, cinnamon bark oil, styrax resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascone, damascenone, thymol, tuberose absolute, terpineol, gamma-terpinene, tripral, vanilla absolute, vanillin, basil oil, patchouli oil, hydroxycitronellal, alpha-pinene, piperitone, Peru balsam, vetiver oil, vetiverol, peppermint oil, pepper oil, helioth Examples of fragrances include ropin, bergamot oil, benzyl benzoate, borneol, myrrhizinoid, musk ketone, methyl nonylacetaldehyde, γ-methylionone, menthol, L-menthol, L-menthone, eucalyptus oil, β-ionone, lime oil, lavender oil, D-limonene, linalool, liral, lilial, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, etc., and one or more of these may be included. When the hair dye composition of the present invention contains a fragrance, the amount of fragrance in the hair dye composition is not particularly limited, but for example, it is preferably 0.0001% to 1% by mass relative to the total amount of the hair dye composition.

[0048] The hair dye composition of the present invention is not particularly limited as long as it is used as a hair dye. For example, it can be used as a permanent hair dye, semi-permanent hair dye, temporary hair dye, etc. for hair, eyelashes, and eyebrows. The dosage form of the hair dye composition of the present invention is also not particularly limited and can be selected according to the embodiment and the purpose of use. For example, liquid forms such as aqueous solutions, dispersions, and emulsions, gel forms, foam forms, cream forms, etc. can be mentioned, and each component of the hair dye composition can be produced by mixing by known methods.

[0049] The hair dye composition of the present invention can be used as a hair dye for dyeing human body hair such as hair, eyelashes, mustaches, eyebrows, leg hair, and arm hair, and is preferably used as a hair dye composition for human hair. In addition, it may be used to dye the body hair of animals such as pets.

Examples

[0050] Hereinafter, the details of the present invention will be described with reference to Examples and Comparative Examples, but the present invention is not limited thereto. In the following Examples, etc., % is based on mass unless otherwise specified.

[0051] <Preparation 1 of Hair Dye Composition> The component (a), component (b), component (c) and other components of the present invention were mixed as shown in Table 1, and the hair dye compositions (hair care) of Examples 1 to 7 and Comparative Examples 1 to 4 having each pH were prepared by known methods, respectively. The numerical values of each component in the table represent the mass % concentration of each component with respect to the total amount of the hair dye composition.

[0052] <Evaluation of Hair Dyeing Property> 1.5 g of each prepared hair dye composition was applied to 1 g of a white hair bundle (human white hair 100% manufactured by Bureau Lux Co., Ltd.). After standing for 10 minutes, it was rinsed with warm water at 40°C for 1 minute and dried with warm air from a dryer to perform hair dyeing treatment. The color tone of the hair after each hair dyeing treatment was measured by a spectrophotometer (Ultraviolet-Visible-Near-Infrared Spectrophotometer V-770 manufactured by JASCO Corporation) using the CIE color system (L * , a * , b *) is measured, and the difference (ΔL) between each value before and after processing is measured. * Δa * Δb * Using ), ΔE is calculated using the following formula. * ΔE was calculated. * A larger value indicates that the hair dye composition has superior hair dyeing properties. * The dyeing properties of each hair dye composition were evaluated using the following evaluation criteria. The evaluation results for the dyeing properties of each hair dye composition are shown in Table 1.

[0053]

number

[0054] [Evaluation Criteria for Hair Dyeability] ◎=ΔE * 27 or more ○=ΔE * ga 22~26 ×=ΔE * is 21 or less

[0055] <Evaluation of skin stain suppression> Each of the three panelists applied 0.05g of each prepared hair dye composition to the inner side of their forearm, left it to stand at 25°C for 10 minutes, rinsed it with 40°C water, and dried it at room temperature to perform the skin dyeing treatment. After treatment, each panelist visually observed their skin and evaluated the skin staining inhibition of each hair dye composition on a scale of 1 to 5 points (higher scores indicate less skin staining) based on the evaluation criteria below. If the average score of the three panelists was 3.0 points or higher, the skin staining inhibition evaluation was marked as ○; if the average score was less than 3.0 points, the skin staining inhibition evaluation was marked as ×. The evaluation results for the skin staining inhibition of each hair dye composition are shown in Table 1.

[0056] [Evaluation Criteria for Skin Stain Inhibition] ○: Excellent resistance to skin staining (less likely to stain the skin) ×: Poor ability to prevent skin staining (easily stains skin)

[0057] [Table 1]

[0058] <Preparation of hair dye composition 2> As described in Tables 2 and 3, components (a), (b), (c) and other components of the present invention were mixed to prepare hair dye compositions (hair manicures) for Examples 8-13 and Comparative Examples 5-11, each having a different pH, using known methods. The numerical values ​​for each component in the table represent the mass % concentration of each component relative to the total amount of the hair dye composition.

[0059] Each of the hair dye compositions prepared in Examples 8-13 and Comparative Examples 5-11 was evaluated for its hair dyeing ability and its ability to suppress skin staining using the same method as described above. The evaluation results for the ability to suppress skin staining of each hair dye composition are shown in Tables 2 and 3, respectively.

[0060] [Table 2]

[0061] [Table 3]

[0062] From the above results, it can be seen that the hair dye composition of the present invention, unlike the comparative hair dye compositions containing only component (a) or component (b), was superior in both hair dyeing ability and skin stain suppression. Therefore, it has been shown that the hair dye composition of the present invention not only has significantly superior hair dyeing ability due to the synergistic effect of component (a) and component (b), but also significantly superior skin stain suppression compared to the hair dye composition containing only component (b).

Claims

1. A hair dye composition comprising (a) a compound represented by the following general formula (1) as component, (b) benzyl alcohol, benzyl glycol, or a mixture thereof as component, and (c) an acid dye as component, wherein the mass ratio of the content of component (a) to component (b) in the hair dye composition is 10:90 to 90:10, and the pH of the hair dye composition is 2.0 to 4.

0. 【Chemistry 1】 (In the formula, R １ (This represents a hydrocarbon group with 6 to 8 carbon atoms.)

2. (a) The component is R in general formula (1) １ The hair dye composition according to claim 1, comprising at least one compound in which is a C6 alkyl group or a C6 cyclic alkyl group.

3. The hair dye composition according to claim 1 or 2, wherein the total content of component (a) and component (b) in the hair dye composition is 0.1 to 30% by mass relative to the total amount of the hair dye composition.

4. A hair dye composition according to any one of claims 1 to 3, wherein the mass ratio of the total content of component (a) and component (b) to the content of component (c) in the hair dye composition is 50:50 to 99:

1.

5. A method for suppressing skin staining by an acid dye, comprising: blending a compound represented by the following general formula (1) and benzyl alcohol, benzyl glycol, or a mixture thereof in a mass ratio of 10:90 to 90:10 in a hair dye composition containing an acid dye; adjusting the pH of the hair dye composition to 2.0 to 4.0; and applying the obtained hair dye composition to body hair. 【Chemistry 2】 (In the formula, R １ (This represents a hydrocarbon group with 6 to 8 carbon atoms.)

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