Cosmetics

Abstract

To provide a cosmetic that has a skin tone correcting effect without paleness, yet has a luster without glare, and can quickly create a uniform makeup film without user intervention.SOLUTION: The cosmetic according to the present invention contains: plate-like powders of a specific color tone, containing iron and coated with titanium oxide, with an average particle size of 3 to 30 μm; an oil solution with a refractive index of 1.455 or higher; and one or more selected from phospholipids, 2-methacryloyloxyethylphosphorylcholine (MPC) group-containing polymers, ceramides, and N-acylamino acids and salts thereof.SELECTED DRAWING: None

Description

Technical Field

[0001] The present invention relates to a liquid cosmetic.

Background Art

[0002] Conventional makeup cosmetics are mainly used for beautifying the skin by hiding unevenness on the skin surface such as pores and wrinkles, and color unevenness, and giving luster to the skin. In order to give luster while making the skin look uniform, conventionally, a high-brightness plate-like powder or an oil agent that returns strong reflected light has been used. Although cosmetics containing a high content of them have the effect of giving a glossy feeling to the skin, they have the drawback of giving an unnatural impression artificially and depending on the angle. In order to solve such an unnatural finish problem, for example, for a dark-colored part of the skin (color tone trouble part) caused by skin moles, hemangiomas, red faces, freckles, millet seeds, etc., a complementary color or a color gamut near the complementary color is used as a substance having transmitted interference light. A skin color adjusting composition characterized by containing has been proposed (see, for example, Patent Document 1). According to this method, it is possible to improve color tone trouble without dulling the skin. On the other hand, as a powder having a color close to that of natural skin, by heat-treating iron-containing synthetic mica at a specific temperature, a new synthetic mica having a bright red appearance with light resistance that was not found in conventional synthetic mica at all, and moreover, excellent ultraviolet blocking ability has been obtained. Attempts have also been made to contain synthetic mica that effectively blocks ultraviolet rays as well as color in cosmetics (see, for example, Patent Document 2). In addition, a skin cosmetic containing a specific powder with little change in color depending on the observation direction of the reflected light of the interference color and an iron oxide / titanium oxide sintered colored pigment has been proposed (see, for example, Patent Document 3). According to this method, it is proposed that a cosmetic can be obtained that can change the skin hue by combination while having a transparent feeling and does not cause makeup collapse due to sebum. While incorporating powders into cosmetics can lead to issues such as a sticky or heavy feeling during application, a proposal has been made to address these problems by combining synthetic fluorphlogopite or synthetic iron fluorphlogopite with an oil having a specific structure to provide a smooth feel. (See, for example, Patent Document 4.) [Prior art documents] [Patent Documents]

[0003] [Patent Document 1] Japanese Patent Application Publication No. 8-081332 [Patent Document 2] Japanese Patent Application Publication No. 6-009210 [Patent Document 3] Japanese Patent Application Publication No. 11-43414 [Patent Document 4] Japanese Patent Publication No. 2013-234133 [Overview of the Initiative] [Problems that the invention aims to solve]

[0004] However, the technology described in Patent Document 1 has a surface gloss, which can result in an unnatural covering effect, and the glossiness can also appear artificial and undesirable. Furthermore, the technology described in Patent Document 2 has high glossiness, and the angle-dependent variation in glossiness can sometimes create an unnatural impression. In addition, the technology described in Patent Document 3 has high powder cohesiveness, and in Patent Document 4, the oily agent tends to slide around on the skin, making it difficult to quickly create a uniform cosmetic film on the skin. Thus, conventional technologies have been unable to cover uneven skin tone with reflected light that closely resembles the skin's natural luster, and there has been no conception of a cosmetic that evenly corrects the skin with a natural-looking sheen from any angle. However, the inventors of this invention have attempted to provide a cosmetic that simultaneously satisfies these effects. This invention has been made in view of the above circumstances, and its main purpose is to provide a cosmetic product that does not leave a pale, opaque film, has the effect of correcting skin tone with a moderate sheen without glare, and can quickly create a uniform cosmetic film regardless of the user.

Means for Solving the Problems

[0005] As a result of intensive studies to solve the above problems, the present inventors have found that by containing plate-like powder whose color tone is adjusted with iron oxide and coated with titanium oxide, an oil agent with a high refractive index, and a biocompatible component with high skin affinity, it is possible to solve the above problems by exhibiting a color unevenness correction effect without a bluish white film hiding feeling, giving an appropriate gloss without a gimmicky feeling, and quickly and uniformly finishing the cosmetic film. The present invention has been completed.

[0006] That is, the present invention is as follows. [1] The following components (A) to (C); (A) Plate-like powder having an average particle diameter of 3 to 30 μm, containing iron and coated with titanium oxide (B) An oil agent having a refractive index of 1.455 or more at 24°C (C) One or more selected from phospholipids, polymers containing 2-methacryloyloxyethyl phosphorylcholine (MPC) groups, ceramides, and N-acyl amino acids and their salts containing, and the cosmetic in which the component (A) has brilliance, and in the measurement with an incident angle of -45° and a light receiving angle of 0° using a spectrocolorimeter, the colorimetric values L* (lightness), C* (chroma), and h (hue) defined in the CIE1976L*a*b* color system are 60 < L* < 83, 12 < C* < 32, 40 < h < 76. [2] The component (A) is applied to the adhesive surface of a transparent adhesive tape at 0.05 g per unit area of [5×8] cm 2 and when the reflectance is measured using a variable-angle spectrophotometer with a D65 light source at an incident angle of -45 degrees using a black non-reflective background, the ratio [I(45)] / [I(O)] of the reflectance [I(45)] at a light receiving angle of 45 degrees and the reflectance [I(O)] at a light receiving angle of 0 degrees at wavelengths 450 nm and 650 nm is 1 to 4 in both cases, which is the cosmetic according to [1]. [3] The cosmetic according to [1] or [2], wherein the coating amount of titanium oxide in the component (A) is 5 to 20% by mass. [4] The above component (A) is a cosmetic composition according to any one of items [1] to [3], which is based on synthetic fluorphlogopite iron. [5] The cosmetic composition according to any one of items [1] to [4], wherein component (B) is one or more selected from ultraviolet absorbers, phenyl-modified silicones, and tridecyl trimellitic acid. [6] The cosmetic composition described in any one of items [1] to [5] further contains hydrophobized fine metal oxide particles as component (D). [7] Furthermore, the cosmetic composition described in any one of items [1] to [6] contains silica as ingredient (E). [8] A cosmetic composition according to any one of items [1] to [7], wherein the mass content ratio of components (A) and (C) is (A) / (C) = 0.5 to 100. [9] The above component (A) is applied to the adhesive surface of the transparent adhesive tape in a [5 × 8] cm area. 2 The cosmetic composition is as described in any one of items [1] to [8], wherein when 0.05 g is applied per unit area and the reflectance intensity is measured using a D65 light source with a variable angle spectrophotometer at an incident angle of -45 degrees against a black non-reflective background, the ratio of the reflectance intensity [I(45)] at a receiving angle of 45 degrees at wavelengths of 450 nm and 650 nm is [I(45)](450 nm):[I(45)](650 nm) = 1.5:1 to 1:3.

[10] The cosmetic is an emulsified cosmetic as described in any one of items [1] to [9]. [Effects of the Invention]

[0007] The present invention provides a cosmetic composition that provides a skin tone correction effect without paleness, has a non-greasy sheen, and allows for a quick and uniform finish of the cosmetic film. This is achieved by including plate-like powder particles with an average particle size of 5 to 15 μm, containing iron and coated with titanium dioxide, of a specific color tone; an oil with a refractive index of 1.460 or higher; and one or more selected from phospholipids, 2-methacryloyloxyethyl phosphorylcholine (MPC) group-containing polymers, ceramides, and N-acyl amino acids and their salts. [Brief explanation of the drawing]

[0008] [Figure 1] Component (A) was applied to the adhesive surface of the transparent adhesive tape at a rate of 0.05 g per unit area of [5×8] cm2. When measuring the reflection intensity using a variable-angle spectrophotometer with a D65 light source and a black non-reflective background at an incident angle of -45 degrees, the reflection intensities [I(45)] at a light-receiving angle of 45 degrees and [I(0)] at a light-receiving angle of 0 degrees at wavelengths of 450 nm and 650 nm are described in terms of angles. [Figure 2] Component (A) Titanium oxide-coated synthetic phlogopite iron (average particle size 5 - 11 μm, titanium oxide 11 - 14%, tin oxide-coated) Comparison of reflection intensities at light-receiving angles of 0° and 45° [Figure 3] Component (A) Titanium oxide, iron oxide-coated mica: (※1) RELIEF COLOR BEIGE (manufactured by JGC Catalysts & Chemicals Ltd.) (titanium oxide content 14.5 - 17.5%, iron oxide content 1.5 - 5.5%, silica content 7 - 10%) Comparison of reflection intensities at light-receiving angles of 0° and 45° [Figure 4] Titanium oxide-coated synthetic mica (※2) HELIOS R10R (manufactured by Toppy Industries Ltd.) (average particle size 11 - 16 μm, titanium oxide 40 - 55%, tin oxide-coated) Comparison of reflection intensities at light-receiving angles of 0° and 45° [Figure 5] Titanium oxide 25 - 40%, iron oxide 2 - 7%, coated mica (※3) Blondiee Metallic Gold N-2000S (manufactured by CQV) (average particle size 9 - 45 μm) Comparison of reflection intensities at light-receiving angles of 0° and 45° [Figure 6] Iron oxide 25 - 4%, coated mica (※4) BLONDIEE SUPER BRONZE N-2220S (manufactured by CQV) (average particle size 9 - 45 μm) Comparison of reflection intensities at light-receiving angles of 0° and 45°

Mode for Carrying Out the Invention

[0009] Hereinafter, preferred embodiments of the present invention will be described in detail. However, the present invention is not limited to the following preferred embodiments and can be freely modified within the scope of the present invention. In this specification, percentages are by mass (mass / mass%) unless otherwise specified. Also, the upper limit (hereinafter) and the lower limit (above) of each numerical range (~) can be arbitrarily combined as desired. Further, the "average particle diameter" in this specification is a value (median diameter D50) obtained by observing the surface state using a scanning electron microscope (manufactured by JEOL, JSM-7800prime) and measuring it with an image analyzer (Luzex AP, manufactured by Nireco), and refers to the major axis of the particles.

[0010] <Component (A)> Component (A) used in the present invention is a plate-like powder containing iron and coated with titanium oxide, having an average particle diameter of 3 to 30 μm. It is obtained by coating titanium oxide on the surface of the plate-like powder matrix, and the plate-like powder of the matrix is not particularly limited. For example, mica, sericite, synthetic phlogopite or synthetic mica such as (fluoride / hydroxide / oxide) / (Mg / K / silicon), calcined sericite, talc, calcined talc, aluminum silicate, magnesium silicate, aluminum magnesium silicate, glass powder, cleaved talc, anhydrous silicic acid, aluminum oxide, kaolin, boron nitride, barium sulfate, aluminum oxide, bismuth oxychloride, fish scale foil and other inorganic powders, cellulose, polyethylene terephthalate·aluminum·epoxy laminate powder, polyethylene terephthalate·polyolefin laminate film powder, polyethylene terephthalate·polymethyl methacrylate laminate film powder and other organic powders can be mentioned, and one or more of these can be used in combination. Luminosity means imparting a good sense of luster to the skin after use, and it does not mean that there is no angular dependence. It gives a glossy feeling. It is not a matte finish like granular composite powders with the same composition for the purpose of UV blocking, and a moderate gloss is required. The plate-like powder containing iron and coated with titanium oxide is not particularly limited and may be a plate-like powder in which titanium oxide and iron oxide and / or iron hydroxide are each coated onto the base plate-like powder, or iron and titanium are added and precipitated as iron oxide and / or iron hydroxide and titanium oxide on the surface of the base plate-like powder, or a plate-like powder containing iron in the base and coated with titanium oxide. Specifically, examples include iron oxide coated titanium mica, titanium oxide iron oxide coated synthetic mica, titanium oxide coated synthetic iron fluorphlogopite, titanium oxide iron oxide coated silica, titanium oxide iron oxide coated glass powder, titanium oxide iron oxide coated plate-like barium sulfate, titanium oxide iron oxide coated plate-like aluminum oxide, etc. Among these, the base is preferably mica, sericite, synthetic fluorphlogopite, or talc, more preferably synthetic fluorphlogopite, and even more preferably synthetic iron fluorphlogopite. This base is preferable because it provides a non-glare gloss and a faster rate of uniform finishing of the cosmetic film. Furthermore, the composite powder may be one in which a colored layer with a refractive index of 2 or more is coated as a plate-like coating layer, and an inorganic layer with a refractive index of 1.30 to 1.99 is present between the colored layers or in the outermost layer. Preferably, the inorganic layer is one or more selected from anhydrous silicic acid, aluminum oxide, and tin oxide.

[0011] The titanium oxide coating method for component (A) used in the present invention can be carried out by known coating methods. For example, the base powder can be suspended in a dilute titanic acid aqueous solution, heated to 70-100°C, hydrolyzed to precipitate hydrated titanium oxide particles on the powder, and then fired at a high temperature of 700-1000°C to produce the coating. Alternatively, the surface may be acid-treated before the reaction and then coated. The amount of surface treatment of each metal contained in the sample (powder) can be obtained by measuring the sample prepared using a general method by ICP (Inductively Coupled Plasma; ARCOS (Spectro GmbH)) emission spectrometry. When coating titanium oxide, it is more preferable to coat it with tin oxide as a binder for the titanium oxide. The amount of tin oxide is not particularly limited, but a coating of 0.5-2.0% is a preferred example, and an amount that can form rutile is preferred. The coating method for component (A) used in the present invention can be any known coating method. For example, one method involves heating a caustic soda aqueous solution to 30-35°C, dispersing the powder particles, adding and stirring an aqueous solution containing ferric sulfate, and reacting it at 90°C for about 2 hours. The resulting powder is washed with water, neutralized, and dried. After pulverization, the raw material particles and iron oxide or hydroxide can be calcined (for example, at about 750-900°C for about 1-3 hours) to obtain the final product. The method for producing synthetic mica powder containing iron in the crystalline structure of component (A) can be a melt synthesis method, or a known dissolution synthesis method may be used. To produce synthetic mica containing iron by the melt synthesis method, raw materials such as potassium fluorosilica, magnesium oxide, aluminum oxide, silicon dioxide, and iron oxide are mixed in predetermined mole amounts, melted at 1400°C to 1600°C, cooled and crystallized, the resulting crystalline mass is pulverized by a known pulverization method, treated in an acidic aqueous solution with stirring, then dehydrated, washed, and dried. This dried powder can be heat-treated at 700 to 1200°C to obtain synthetic phlogopite iron powder containing iron in the crystalline structure. Component (A) may be obtained by further coating the synthetic phlogopite iron powder with a metal oxide such as titanium oxide.

[0012] The component (A) used in this invention is preferably one that yields both specular and diffuse reflected light, with a small difference in reflectivity between them. In that case, it is desirable because it does not exhibit excessive gloss that could be perceived as glare. Component (A) is applied to the adhesive surface of the transparent adhesive tape in a [5 × 8] cm area. 2When 0.05 g per unit area is applied and the reflectance intensity is measured using a D65 variable-angle spectrophotometer light source at an incident angle of -45 degrees against a black non-reflective background, the ratio [I(45)] / [I(O)] of the reflectance intensity at a receiving angle of 45 degrees to the reflectance intensity at a receiving angle of 0 degrees [I(O)] at wavelengths of 450 nm and 650 nm is preferably in the range of 1 to 5, and more preferably in the range of 1 to 3. This range is preferable because it provides excellent gloss without excessive shine or glare, and allows for a fast and uniform finish of the cosmetic film. Furthermore, the ratio of the reflectance intensity [I(45)] at a receiving angle of 45 degrees at wavelengths of 450 nm and 650 nm is preferably [I(45)](450 nm):[I(45)](650 nm) = 3:2 to 1:3, more preferably 1:1 to 2:5, and even more preferably 1:1 to 1:2. Within this range, it is more preferable because it provides superior skin tone correction without a pale appearance. Examples of commercially available components (A) include luminous powders with a mica base coated with red iron oxide and titanium oxide, such as RELIEF COLOR BEIGE, RELIEF COLOR PINK (both manufactured by JGC Catalysts & Chemicals Co., Ltd.), and DUOCROME YR (manufactured by BASF). Furthermore, as a developed product, as shown in Figure 2, titanium oxide-coated synthetic fluorphlogopite iron (average particle size 5-11 μm, titanium oxide 11-14%, tin oxide coating) is more preferable.

[0013] The average particle size of component (A) used in the present invention is 3 to 30 μm. Preferably, it is 5 to 25 μm, more preferably 5 to 20 μm, and even more preferably 5 to 15 μm. This range is preferable because it allows for uniform and selective spreading on the ridges of the skin, without emphasizing unevenness, provides a high skin tone correction effect without paleness, and balances a non-glossy sheen.

[0014] The color tone of component (A) used in the present invention, in the measurement with an incident angle of -45° and a light-receiving angle of 0° using a spectrocolorimeter, the colorimetric values L* (lightness), C* (chroma), and h (hue) defined in the CIE1976L*a*b* color system are such that 60 < L* < 83, 12 < C* < 32, and 40 < h < 76. Preferably, 60 < L* < 75, 17 < C* < 25, and 50 < h < 70, and more preferably, 68 < L* < 75, 18 < C* < 25, and 55 < h < 70. When component (A) is within these color tone ranges, it has an excellent skin color correction effect without bluishness and is more preferably a color tone that suits the standard skin color of yellow races.

[0015] The titanium oxide in component (A) used in the present invention is not particularly limited, but preferably 5 to 25%, more preferably 5 to 22%, and still more preferably 5 to 20% coated, which can give appropriate gloss. The iron content in component (A) used in the present invention is not particularly limited as long as it falls within the specified hue. In the case of synthetic phlogopite iron coated with titanium oxide on a plate-like powder containing iron in the matrix, as a suitable lower limit in terms of iron oxide Fe2O3 conversion, 8% or more is preferable, 9% or more is more preferable, 10% or more is still more preferable, and as a suitable upper limit, 25% or less is preferable, 20% or less is more preferable, 17% or less is more preferable, 15% or less is more preferable, and 14% or less is more preferable. Specific commercially available products include PDM-FE (manufactured by Toppy Industries). In the case of those obtained by coating titanium oxide and iron oxide on the surface of the plate-like powder of the matrix respectively, or those obtained by adding iron and titanium and depositing iron oxide and / or iron hydroxide, titanium oxide or a mixture thereof on the surface of the plate-like powder of the matrix, this is not the case. In any case, the iron oxide Fe2O3 conversion content in component (A) is set to a preferable amount with respect to the amount of titanium oxide, and the iron oxide mass / titanium oxide mass = 0.05 to 2.0 is preferable, and it is not particularly limited as long as it is within the specified color tone range.

[0016] The component (A) used in this invention possesses the spectral reflectance characteristics described above, which means that the reflection intensity does not change in an angle-dependent manner, thus avoiding a contrived appearance and enabling the application of a skin tone correction effect. Furthermore, the properties of the contained titanium dioxide allow for the application of a blue light blocking effect.

[0017] The content of component (A) used in the present invention is not particularly limited, but the lower limit is preferably 0.2% or more, more preferably 1% or more. The upper limit is preferably 20% or less, more preferably 15% or less, even more preferably 10% or less, and even more preferably 5% or less. The range is preferably 0.2 to 10%, more preferably 1 to 8%, and even more preferably 1 to 5%. Within this range, a moderate color unevenness correction effect and the effect of quickly and uniformly finishing a film without aggregation can be obtained.

[0018] <Component B> The oily agent of component (B) used in the present invention is an oily agent with a refractive index of 1.455 or higher at 24°C. Any oily agent that satisfies this condition and is commonly used in cosmetics can be used without particular restriction, regardless of its origin, such as animal oil, vegetable oil, or synthetic oil. It is preferable that it be liquid or paste-like at 25°C.

[0019] The refractive index of component (B) used in this invention is not particularly limited as long as it is measured using a commercially available refractometer. For example, the handheld refractometer R-5000 (manufactured by Atago Co., Ltd.) can be used. The measurement method should be carried out in accordance with the instructions for the handheld refractometer R-5000. That is, the sample to be measured is filled into a glass bottle with an outer diameter of 45 mm, an inner diameter of 38 mm, and a height of 82 mm so as not to leave any air space, the lid is closed, and it is left in a 24°C constant temperature bath for 24 hours. The next day, the measured value can be read using the refractometer to obtain the refractive index.

[0020] The refractive index of component (B) used in the present invention is preferably 1.455 or higher, more preferably 1.458 or higher, more preferably 1.47 or higher, and preferably 1.550 or lower, in order to provide a moderate gloss without being overly technical.

[0021] Examples of oily components (B) used in the present invention include polybutene, heavy liquid isoparaffin, liquid lanolin acetate, diphenyl dimethicone, diphenyl disiloxy phenyl trimethicone, tridecyl trimellitate, dimer acid ester, ethylhexyl methoxycinnamate, diglyceryl triisostearate, and trimethylolpropane triisostearate, which satisfy the above conditions. These commercially available products include: refined polybutene HV-100F(SB) (manufactured by Nippon Natural Products Co., Ltd.) (refractive index 1.492), polybutene 35R (refractive index 1.489), polybutene 2000H (refractive index 1.503) (manufactured by Idemitsu Kosan Co., Ltd.), Pearlream 18 (refractive index 1.491), Pearlream 24 (refractive index 1.496), Pearlream 46 (refractive index 1.502) (manufactured by NOF Corporation), ACELAN SP (refractive index 1.485) (manufactured by Croda Japan Co., Ltd.), KF-54 (refractive index 1.502), KF-56 (refractive index 1.455) (manufactured by Shin-Etsu Chemical Co., Ltd.), LIPONATE TD™ (refractive index 1.480) (manufactured by LIPO CHEMICALS INC.), and LUSPLAN. Examples include DA-DD-IS (refractive index 1.472), PLANDOOR-S (refractive index 1.479) (manufactured by Nippon Seika Co., Ltd.), ethylhexyl methoxycinnamate (refractive index 1.508) (BASF), Eldew PS-203 (refractive index 1.479), Eldew PS-306 (refractive index 1.480) (manufactured by Ajinomoto Co., Ltd.), refined olive oil (refractive index 1.465), macadamia nut oil (refractive index 1.465), Saracos 6318V (refractive index 1.463), Cosmoll 222 (refractive index 1.458), Cosmoll 43V (refractive index 1.463) (manufactured by Nisshin Oillio Co., Ltd.), etc.

[0022] The structure of the oil agent (B) used in the present invention is preferably ethylhexyl methoxycinnamate, diphenyl dimethicone, diphenyl disiloxyphenyl trimethicone, or tridecyl trimellitate, and more preferably ethylhexyl methoxycinnamate, diphenyl dimethicone, or diphenyl disiloxyphenyl trimethicone. The component (B) used in the present invention is more preferable because it can impart a uniform, moisturizing shine to the non-greasy, uniform cosmetic film surface of component (A), and helps to quickly create a uniform film without slipping on the skin.

[0023] The content of component (B) used in the present invention is preferably 1 to 20%, more preferably 2 to 17%, and even more preferably 2 to 15%, in order to provide a moderate gloss and to quickly form a uniform film.

[0024] <Component C> The component (C) used in the present invention is one or more selected from phospholipids, 2-methacryloyloxyethyl phosphorylcholine (MPC) group-containing polymers, ceramides, and N-acyl amino acids and their salts. The phospholipid used as component (C) in the present invention is any lipid having a phosphate group, regardless of whether it is animal-derived, plant-derived, hydrogenated, or unhydrogenated, or the purity of its PC (phosphatidylcholine). While the composition is not particularly limited, examples include those containing phosphatidylcholine (PC), phosphatidylinositol (PI), phosphatidylethanolamine (PE), phosphatidic acid, phosphatidylserine, phosphatidylglycerol, sphingumyelin, and lysophosphatidylcholine. Those containing phosphatidylcholine (PC) are particularly preferred, but are not limited. Specifically, examples include commercially available products such as Ajinomoto lecithin (manufactured by Ajinomoto Co., Inc.), which is a soybean phospholipid, and hydrogenated soybean lecithin such as Resinol S-10 and S-10E (both manufactured by Nikko Chemicals Co., Ltd.). The 2-methacryloyloxyethyl phosphorylcholine (MPC) group-containing polymer used as component (C) in the present invention is one or more selected from MPC homopolymers or copolymers of MPC and hydrophobic monomers. The molecular weight is 5000 or more, more preferably 10000 or more. In the case of copolymers with hydrophobic monomers, the type of hydrophobic monomer is not particularly limited, but it is styrene, acrylic acid ester, or methacrylic acid ester. From the viewpoint of non-stickiness, the molar ratio of MPC to hydrophobic monomer is preferably in the range of 50:50 to 97:3. To give more specific examples of component (C) used in the present invention, such as the MPC homopolymer and the copolymer of MPC and a hydrophobic monomer, examples of MPC homopolymers include Lipidure-HM and Lipidure-HM-500 (both manufactured by NOF Corporation), and examples of copolymers of MPC and butyl methacrylate include commercially available products such as Lipidure-PMB, Lipidure-A, Lipidure-B, Lipidure-NA, and Lipidure-NR (all manufactured by NOF Corporation). The N-acylated amino acids and their salts used as component (C) in the present invention are those in which a hydrogen atom of the amino group of an amino acid is replaced by an acyl group, and the acyl group is a saturated or unsaturated linear or cyclic group having 1 to 20 carbon atoms. Examples include N-acetylglutamic acid, N-lauroylglutamic acid, N-myristylalanine, NN-oleylthreonine, N-cinnamoylglycine, and N-nicotinoylglutamic acid. Examples of salts include sodium salts, potassium salts, and triethanolamine salts. The ceramides used as component (C) in the present invention include ceramides and their derivatives, and may be natural extracts or synthetic products. While not limited to those generally usable in cosmetics, examples include a series of ceramides expressed as nonionic amphiphilic substances having one or more long-chain linear and / or branched alkyl or alkenyl groups in the molecule, and further having at least two or more hydroxyl groups and one or more amide groups (and / or amino groups), or derivatives in which a phosphatidylcholine residue or sugar residue is bonded to the hydroxyl group of the nonionic amphiphilic substance. Specifically, these include natural ceramides such as sphingosine, phytosphingosine, and their long-chain fatty acid amides, such as ceramide 1, ceramide 2, ceramide 3, ceramide 3B, ceramide 4, ceramide 5, ceramide 6, ceramide 6I, and ceramide 6II; sphingophospholipids such as sphingomyelin and phytosphingomyelin, which are phospholipid derivatives of sphingosine and phytosphingosine; and sphingoglycolipids and phytosphingoglycolipids such as cerebrosides and gangliosides, which are glycosides of these ceramides. Among these, phospholipids and ceramides are more preferred in terms of providing a non-glossy sheen and the speed at which the cosmetic film sets evenly, with phospholipids being even more preferred.

[0025] The content of component (C) used in the present invention is preferably 0.01 to 8%, more preferably 0.1 to 7%, and even more preferably 0.1 to 6%. Within this range, it is preferable because it is possible to enhance the speed at which the cosmetic film is completed uniformly while making use of the non-glossy shine of component (A).

[0026] The component (C) used in the present invention can further increase the speed at which the cosmetic film of component (A) is completed uniformly while also suppressing stickiness. Therefore, the mass content ratio of component (A) to component (C) is preferably (A) / (C) = 0.5 to 100, more preferably (A) / (C) = 0.5 to 50.0, even more preferably (A) / (C) = 0.5 to 30.0, even more preferably (A) / (C) = 1.0 to 10.0, and most preferably (A) / (C) = 1.0 to 6.0.

[0027] <Component D> The present invention further preferably contains hydrophobically treated fine particle metal oxide as component (D). Examples of fine particle metal oxides include ultraviolet blocking agents such as zinc oxide, titanium oxide, cerium oxide, and iron oxide. One or more of these can be used in combination, and composites may also be used. However, the shape is not particularly limited, such as spherical, plate-like, needle-like, or spindle-like, and the particle structure is not particularly limited, such as porous or non-porous. The average particle diameter is also not particularly limited, but an average particle diameter of 0.01 to 10 μm is typical. Fine particle titanium oxide, fine particle zinc oxide, and fine particle cerium oxide are particularly preferred, more preferably fine particle titanium oxide, fine particle zinc oxide, and even more preferably fine particle titanium oxide. Furthermore, component (D) may be in the form of a composite powder in which it is adsorbed on the surface of a matrix such as mica, synthetic mica, glass, silica, or alumina.

[0028] Specific commercially available products include, for example, MP-1133, MP-701, MP-40, MP-100, MT-500SAS (manufactured by Teika Co., Ltd.); XZ-100F, XZ-300F, XZ-3000, STR-100C-LF (manufactured by Sakai Chemical Industry Co., Ltd.); ZnO-610Si(4)G (manufactured by Sumitomo Osaka Cement Co., Ltd.); ST-461EC, ST-710EC (manufactured by Titanium Industry Co., Ltd.). For cerium oxide, examples include CERIGUARD W-500 (manufactured by Daito Chemical Co., Ltd., average particle size 1800 nm). Examples of iron oxides include the TAROX series (manufactured by Titanium Industries, various P, HP, or CS grades: R-516P, YP1200P, BL-100P, R-516CS, LL-100CS, ABL-205CS, etc., or composite powders thereof), the FESOIE series (manufactured by Titanium Industries), the SUN PURO series (C33-8001, C33-9001, C33-7001 (manufactured by Sun Chemical), the UNIPURE series (manufactured by SENSIENT), etc.). Furthermore, component (D) may be manufactured by known manufacturing methods and is not particularly limited.

[0029] Furthermore, it is preferable that the metal oxides other than iron oxide in component (D) used in the present invention are further coated on the surface with iron oxide or hydroxide. In addition to iron oxide or hydroxide, component (D) used in the present invention may also be coated with silicon oxide or hydroxide, or aluminum oxide or hydroxide as layers. When component (D) is further coated with iron oxide, the amount of coating is not particularly limited, but from the viewpoint of natural coverage, in the iron oxide-coated metal oxide (preferably in iron oxide-coated titanium dioxide or iron oxide-coated zinc oxide), a suitable lower limit is preferably 0.5% or more, more preferably 0.6% or more, and even more preferably 0.7% or more, and a suitable upper limit is preferably 5% or less, more preferably 3.5% or less, and even more preferably 3%, with a suitable numerical range of 0.5 to 5%, more preferably 0.7 to 3.5%, and even more preferably 0.9 to 3%. In the present invention, component (D) can be used in the form of one or more types as needed.

[0030] The hydrophobic treatment agent used for component (D) in the present invention is not particularly limited as long as it is a hydrophobic treatment agent commonly used in cosmetics, quasi-drugs, pharmaceuticals, etc. Examples include silicone treatment agents, fluorine treatment agents, organic titanate treatment agents, metal soap treatment agents, phospholipid treatment agents, and acylated amino acid treatment agents. In terms of emulsification state immediately after manufacturing, emulsification stability over time at high temperatures, SPF effect, and water resistance, silicone treatment agents, organic titanate treatment, metal soap treatment agents, and acylated amino acid treatment are preferred, and component (C) may also be used as the hydrophobic treatment agent for component (D). Specifically, examples of silicone treatment agents include chain-like silicones such as low-molecular-weight dimethylpolysiloxane, high-molecular-weight dimethylpolysiloxane, and methylphenylpolysiloxane; modified silicones such as amino-modified silicones, alkyl-modified silicones, and alkoxy-modified silicones; silicone resins such as trimethylsiloxysilicate and acrylic-silicone graft copolymers; silicone rubbers; partially or fully crosslinked organopolysiloxanes; silylation agents; silane coupling agents; and one or more of these can be used. Among silane coupling agents, trialkoxyalkylsilanes are preferred. Trialkoxyalkylsilanes are compounds in which three alkoxy groups and one alkyl group are bonded to a silicon atom. These alkoxy groups react with hydroxyl groups and other elements on the powder surface, thereby chemically modifying the powder surface. In the trialkoxyalkylsilane, the alkoxy group is preferably a C1-C3 alkoxy group such as methoxy, ethoxy, or propoxy. Furthermore, the alkyl group in the trialkoxyalkylsilane is preferably a C6-C18 alkyl group such as hexyl, octyl, decyl, or octadecyl. Examples of such trialkoxyalkylsilanes include trimethoxyhexylsilane, trimethoxyoctylsilane, trimethoxydecylsilane, trimethoxyoctadecylsilane, triethoxyhexylsilane, triethoxyoctylsilane (OTS), triethoxydecylsilane, and triethoxyoctadecylsilane. Among these, trimethoxyoctylsilane and triethoxyoctylsilane (OTS) are more preferred in terms of emulsification state immediately after production, emulsification stability over time at high temperatures, SPF effect, and water resistance. Examples of organic titanate treatment agents include alkyl titanates of the long-chain carboxylic acid type, pyrophosphate type, phosphorous acid type, amino acid type, etc., with alkyl titanates having an alkyl group with 8 to 24 carbon atoms being preferred. Specifically, examples of the alkyl titanates include isopropyl triisostearoyl titanate (ITT), isopropyl trioctanoyl titanate, isopropyl dimethacrylate isostearoyl titanate, isopropyl isostearoyl diacrylic titanate, and diisostearoylethylene titanate as long-chain carboxylic acid type alkyl titanates, and tetraisopropyl bis(dioctyl phosphite) titanate and tetraoctyl bis(ditridecyl phosphite) titanate as pyrophosphate type alkyl titanates. Examples include phyto(titanate), tetra(2,2-diallyloxymethyl-1-butyl)bis(ditridecylphosphite)titanate, and as phosphite-type alkyl titanates, examples include isopropyltri(dioctyl pyrophosphate)titanate, bis(dioctyl pyrophosphate)oxyacetate titanate, and bis(dioctyl pyrophosphate)ethylene titanate, and as amino acid-type alkyl titanates, examples include isopropyltri(N-amidoethyl-aminoethyl)titanate. In the present invention, among these alkyl titanates, long-chain carboxylic acid type alkyl titanates are preferred in terms of emulsification state immediately after production, emulsification stability over time at high temperatures, SPF effect, and water resistance, and isopropyl triisostearoyl titanate (ITT) is more preferred. Examples of metal soap treatment agents include fatty acids and their metal salts, with fatty acids having 12 to 18 carbon atoms being preferred. Examples of salts thereof include calcium, magnesium, zinc, and aluminum, with aluminum salts being particularly preferred. As for metal soap treatment agents, one or more selected from the group consisting of aluminum stearate, aluminum isostearate, aluminum distearate, aluminum oleate, aluminum palmitate, aluminum laurate, aluminum myristate, and aluminum dimyritate are preferred in terms of emulsification state immediately after production, emulsification stability over time at high temperatures, lack of stickiness, SPF effect, and water resistance. One or more selected from the group consisting of aluminum stearate and aluminum isostearate are more preferred, and aluminum stearate is even more preferred in terms of emulsification stability over time at high temperatures and water resistance. Examples of amino acids used in acylated amino acid treatment include proline, hydroxyproline, alanine, glycine, sarcosine, lysine, aspartic acid, and glutamic acid, and their salts are included. Specifically, the fatty acids constituting the acyl group in acylated amino acid treatment are preferably fatty acids with 1 to 23 carbon atoms, more preferably fatty acids with 8 to 20 carbon atoms, and even more preferably one or more selected from the group consisting of stearoyl glutamic acid, lauroyl aspartic acid, dilauroyl glutamic acid lysine, and lauroyl lysine. Examples of salts of these include Na, Ca, Al, Mg, Zn, Zr, and Ti salts. As for acylated amino acid treatment, lauroyl lysine is preferred from the viewpoint of emulsification state immediately after production, emulsification stability over time at high temperatures, SPF effect, and water resistance.

[0031] The average particle size of component (D) used in the present invention is preferably 10 nm or more, more preferably 15 nm or more, and even more preferably 20 nm or more, as a preferred lower limit, and preferably 100 nm or less, more preferably 80 nm or less, and even more preferably 50 nm or less as a preferred upper limit. Within this range, it is preferable from the viewpoint of improving the continuity of the film by filling the gaps between powder particles and quickly producing a uniform film.

[0032] The content of component (D) in the cosmetic composition of the present invention is not particularly limited, but is preferably 1% or more as a suitable lower limit, more preferably 3% or more, and even more preferably 5% or more. It is also preferably 20% or less as a suitable upper limit, more preferably 15% or less, and even more preferably 12% or less. The suitable numerical range is preferably 1 to 20%, more preferably 3 to 15%, and even more preferably 5 to 12%. Within this range, the powder spreads smoothly on the skin without agglomerating, resulting in a uniform and quick finish, which is preferable.

[0033] <Component E> In the present invention, it is preferable to use silica as component (E). Any silica commonly used in cosmetics can be used, regardless of its shape (spherical, amorphous, etc.), and regardless of whether it has pores or surface treatment. The size is not particularly limited, but it is preferably 0.005 to 40 μm, and more preferably 0.01 to 30 μm. A suitable size may be set depending on the dosage form of the cosmetic; for oily dosage forms, 0.005 to 0.5 μm and / or 10 to 40 μm is preferred, and for powder or emulsifier dosage forms, 1 to 20 μm is preferred. This range is preferable because it does not hinder the skin tone correction effect without paleness and the glossiness without greasiness. Furthermore, spherical silica is preferred in that it can provide a smooth finish and reduce stickiness. In addition, using hydrophobized silica is more preferable in terms of long-term stability. Examples include anhydrous silica, hydrated silica, silylated silica, and dimethylsilylated silica. Commercially available products include Silysia 770 (average particle size 6.9 μm, amorphous, porous), 550 (average particle size 3.9 μm, amorphous, porous), 320 (average particle size 3.2 μm, amorphous, porous) (all manufactured by Fuji Silysia Chemical Co., Ltd.), and AEROSIL. 200 (average particle size 12 nm, amorphous smoke, nonporous), 300 (average particle size 7 nm, amorphous smoke, nonporous), 380S (6 nm, amorphous smoke, nonporous) , R972 (16 nm, amorphous smoke, non-porous), R974 (12 nm, amorphous smoke, non-porous), R976S (7 nm, amorphous smoke, non-porous) RX300 (7 nm, amorphous, non-porous) (manufactured by Nippon Aerosil), Sunsphere NP-30 (average particle size 4 μm, spherical, non-porous), NP-100 (10 μm, spherical, non-porous), NP-200 (20 μm, spherical, non-porous) (manufactured by AGC SI Tech), God Ball Examples include D11-796C (average particle size 3.5 μm, spherical, porous) and E2-824C (average particle size 1 μm, spherical, porous) (both manufactured by Suzuki Oil & Fat Industry Co., Ltd.).

[0034] The content of component (E) used in the present invention is preferably 1 to 15%, more preferably 1 to 12%, and even more preferably 1 to 10%. Within this range, it is preferable without hindering the skin tone correction effect without paleness and the glossiness without greasiness.

[0035] <Ingredients other than ingredients (A) to (E)> In addition to the above-mentioned components, the cosmetic composition of the present invention may appropriately contain any components other than those listed above, such as aqueous components, water-soluble polymers, ultraviolet absorbers, parahydroxybenzoic acid derivatives, preservatives such as phenoxyethanol, vitamins, beauty ingredients, moisturizers, surfactants, cross-linked emulsifying silicone elastomers, and powders other than the above-mentioned components (A) to (D) and (E), as long as they do not impair the effects of the present invention. The cosmetic composition of the present invention can be prepared in the desired type and form by appropriately employing known manufacturing methods such as inclusion, mixing, and emulsification using the above-mentioned components (A) to (D) and (E).

[0036] <Regarding dosage forms> Furthermore, the form of the cosmetic composition of the present invention is not particularly limited, but may be in the form of a powder, liquid, paste, emulsion, cream, gel, or solid, and one or more of these can be selected. In particular, emulsified cosmetics, oily cosmetics, powder cosmetics, and powder-solid cosmetics are preferred for exhibiting the desired effect, and emulsified cosmetics that exhibit a glossy finish are especially preferred.

[0037] <Cosmetics> The cosmetic composition of the present invention can be applied to makeup cosmetics such as eye color, eyebrow powder, foundation, blush, face powder, and primer; skincare cosmetics such as lotions, creams, serums, and body powders; and sunscreen cosmetics, from which one or more can be selected. Furthermore, the cosmetic composition of the present invention may be in the form of a composition or may be used as a topical skin preparation.

[0038] Furthermore, as another aspect of the present invention, the cosmetic composition of the present invention may be a cosmetic composition used to cover unevenness on the skin surface (pores, wrinkles, etc.) and to naturally cover discoloration problems on the skin surface (spots, freckles, uneven skin tone, etc.). [Examples]

[0039] The present invention will be described in detail below with reference to examples. However, these examples do not limit the present invention in any way.

[0040] The color measurement CIE1976 L*a*b* color system measurement test method and the reflection intensity test method using a variable-angle color difference meter in component (A) are shown below, and the results are shown in Table 1. <CIE1976 L*a*b* Color System Measurement Test> Using a spectrocolorimeter SE7700 (manufactured by Nippon Denshoku Industries Co., Ltd.), when measuring at an incident angle of -45° and a light-receiving angle of 0°, and tapping the cell 20 times with component (A), the colorimetric values L* (lightness), C* (chroma), and h (hue) of the color values defined in the CIE1976 L*a*b* color system were obtained. The results are shown in Table 1 below. <Reflection Intensity Test Using a Variable-Angle Color Difference Meter> Component (A) was applied to the adhesive surface of a transparent adhesive tape at 0.05 g per unit area of [5×8] cm 2 and the reflection intensity was measured using a D65 light source with a variable-angle spectrocolorimetric system GCMS-3B type (manufactured by Murakami Color Research Laboratory Co., Ltd.) at an incident angle of -45 degrees with a black non-reflective background. An explanation of the evaluation angle is shown in Figure 1, and the results are shown in Figures 2 to 6. The ratio [I(45)] / [I(O)] of the reflection intensity [I(45)] at a light-receiving angle of 45 degrees and the reflection intensity [I(O)] at a light-receiving angle of 0 degrees, and the ratio of the reflection intensity [I(45)] at a light-receiving angle of 45 degrees at wavelengths 450 nm and 650 nm, [I(45)](450 nm):[I(45)](650 nm), were measured and calculated.

[0041]

Table 1

[0042] The color tones of the three samples of component (A) were in the range of 60 < L* < 75, 12 < C* < 25, and 40 < h < 70. In particular, the color tone of the titanium oxide-coated synthetic phlogopite iron was in the range of 68 < L* < 75, 18 < C* < 25, and 55 < h < 70. Also, according to the results of the reflection intensity test of each wavelength by the variable angle spectrocolorimeter, for component (A), the ratio [I(45)] / [I(0)] of the reflection intensity [I(45)] at a light-receiving angle of 45 degrees to the reflection intensity [I(0)] at a light-receiving angle of 0 degrees at wavelengths 450 nm and 650 nm of each result was in the range of 1 to 5. Furthermore, the ratio of the reflection intensity [I(45)] at wavelengths 450 nm and 650 nm at a light-receiving angle of 45 degrees was in the range of [I(45)](450 nm):[I(45)](650 nm) = 1:1 to 1:2.

[0043] ≪Examples 1 to 21 and Comparative Examples 1 to 8: Water-in-oil type emulsified cosmetics (foundation)≫ The water-in-oil type emulsified cosmetics (foundation) shown in Tables 2 to 4 were prepared, and the following evaluations were carried out regarding the skin color correction effect without bluishness, the non-glaring glossiness, and the speed at which the makeup film was uniformly finished, and the determination was made according to the following criteria. The results are also shown together.

[0044]

Table 2

[0045] [Table 3] *13: Lecithin CLO (manufactured by Ajinomoto Co., Inc.) *14: Ceramide TIC-001 (manufactured by Takasago International Corporation) *15: Amisoft HA-P (manufactured by Ajinomoto Co., Inc.) *22: Solid content of SIMULGEL EG QD (37.5% dispersion) (manufactured by SEPPIC).

[0046] [Table 4]

[0047] (Manufacturing Method) (Tables 2-4: Ingredients not listed shall not be included.) A. Disperse components 1-15. B. Mix ingredients 16-33 uniformly. C. Mix components 34-44 uniformly. Add B to DC and emulsify. A was added to ED, mixed, and then defoamed to obtain foundation.

[0048] (Evaluation method) Each of the following evaluation items was evaluated using the method described below. (Evaluation criteria) I. Skin tone correction effect without a pale appearance. B. A glossy finish without glare. H. The speed at which the cosmetic film sets evenly.

[0049] (Evaluation Method 1) The aforementioned foundation underwent usage tests by a panel of 20 experts. Each panelist evaluated the foundation on a 5-point scale using the absolute evaluation method below, assigning scores for the following aspects: skin tone correction effect without paleness, glossiness without greasiness, and speed at which the makeup film sets evenly. For each sample, the average score was calculated from the total scores of all panelists and judged according to the following 4-point evaluation criteria. Specifically, "skin tone correction effect without paleness" was evaluated as whether there was an unnatural bluish-white film immediately after application; "glossiness without greasiness" was evaluated as whether there was a reflection that provided a moderate brightness that did not look unnatural from any angle immediately after application; and "speed at which the makeup film sets evenly" was evaluated as whether the powder or liquid components adhered to the skin immediately after application without sliding around, and whether the makeup film settled quickly.

[0050] <Absolute evaluation criteria> (Rating): (Evaluation) 5: Very good 4: Good 3: Normal 2: Bad 1: Very bad <Judgment criteria> (Judgment): (Average score) AA: 4.5 points or higher: Very good A: Over 4 points but 4.5 points or less: Good B: Over 3 points but 4 points or less: Fairly good C: Over 2 points but 3 points or less: Slightly poor D: 2 points or less: Defective

[0051] As is clear from the results in Tables 2-3, the foundations of Examples 1-21, which are embodiments of the present invention, were oil-in-water emulsion liquid cosmetics that excelled in all aspects, including skin tone correction effect without paleness, glossiness without greasiness, and speed of uniform finish of the cosmetic film. On the other hand, as shown in the results in Table 4, Comparative Examples 1-4, which did not contain ingredient (A), were not satisfactory in terms of skin tone correction effect without paleness and glossiness without greasiness due to some large pearl particles. Furthermore, Comparative Examples 5-7, which did not contain ingredient (B), had low glossiness without greasiness, and the speed of uniform finish of the cosmetic film was not sufficient. Comparative Example 8, which contained stearic acid instead of ingredient (C), did not have a sufficiently fast finish of the cosmetic film.

[0052] Example 22: Powder foundation (powdered solid cosmetic) Powder foundation was manufactured using the slurry method according to the following formula and manufacturing process. (Ingredients) (%) 1. Titanium oxide coated synthetic fluorphlogopite iron (Average particle size 5-11 μm, iron oxide coating 11-14%, tin oxide coating: Figure 2) 5.0 2. Ceramide-treated titanium dioxide*23 10.0 3. Particulate zinc oxide *24 5.0 4. Boron nitride *25 8.0 5. Bismuth oxychloride *26 5.0 6. Red iron oxide *8 0.5 7. Yellow iron oxide *9 1.7 8. Black iron oxide *10 0.15 9. Talc *27 remaining amount 10. Spherical silica *28 10.0 11. Lauroyl lysine *29 4.0 12. Silicone-treated mica *30 10.0 13. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 2.0 14. Diphenylsiloxyphenyl trimethicone *17 (refractive index 1.455) 8.0 15. Isotridecyl isononanoate *31 (refractive index 1.445) 5.0 16. Diisostearyl malate *32 (refractive index 1.460) 2.0 17. Chlorphenesin 0.2 18. Lemon extract 0.001 19. Job's Tears Extract 0.001 20. Green tea extract 0.001 21. Rice fermentation extract 0.001 22. Rice bran extract 0.001 23. Sodium Hyaluronate 0.001 24. Hydrolyzed collagen 0.001 25. Proteoglycan 0.001 26. Scutellaria baicalensis extract 0.001 27. Hydrolyzed soybean extract 0.001 28. Astaxanthin 0.001 29. Rose Honey 0.001 30. Shea butter 0.001 31. Ceramide NG 0.001 32. Hummus extract 0.001 33. Kaiketto extract 0.001 34. Theanine 0.001 35. Alum 0.001 36. Chlorohydroxyaluminum 0.001 *23: MP-1133 (manufactured by Teika Co., Ltd., average particle size 0.27 μm) 94.4% Treatment with 2.6% aluminum hydroxide, treatment with 2.7% (palmitic acid / ethylhexanoic acid) dextrin. Ceramide NG 0.3% treatment *24: MZ-500 (manufactured by Teika Corporation, average particle size 25nm) *25: SHP-3 (Manufactured by Mizushima Iron Alloy Co., Ltd., average particle size 6 μm, aspect ratio 10) *26:PEARL-GLO UVR (manufactured by ENGELHARD) *27: JA-46R (Manufactured by Asada Flour Milling Co., Ltd., average particle size 9 μm, aspect ratio 50) *28: Sunsphere NP-30 (manufactured by AGC SI-TEC, average particle size 4μm) *29: Amihope LL (manufactured by Ajinomoto Co., Inc.) *30: Y-3000 (manufactured by Yamaguchi Mica Co., Ltd., average particle size 23 μm, aspect ratio 70) 2% dimethicone treatment *31: Saracos 913 (manufactured by Nisshin Oillio Co., Ltd.) *32: High Malate DIS (manufactured by Higher Alcohol Industry Co., Ltd.)

[0053] (Manufacturing method) A. Mix ingredients 1-12 uniformly in a super mixer. A uniform mixture of ingredients 13-36 was added to BA, uniformly dispersed, and then pulverized to obtain a cosmetic base. C. 50 parts of solvent (isododecane) were added to 100 parts of the cosmetic base material and mixed to obtain a slurry-like mixture. D. Fill a round metal pan (5.5 cm in diameter) with 11 g of the above mixture and press it under a pressure of 2.0 kgf / cm². 2 The mixture was compressed four times under the conditions of a 4-second press time and 6 sheets of paper, partially removing the solvent. Then, it was dried at 70°C overnight to remove the remaining solvent and obtain the foundation.

[0054] The resulting powder foundation (solid powder cosmetic) was excellent in its skin tone correction effect without a pale appearance, its non-greasy shine, and the speed at which the makeup film applied evenly.

[0055] Example 23: Foundation (properties between solid powder and oil-based solid) A foundation with properties between a solid powder and an oil-based solid was manufactured using the following formulation and manufacturing method. (Ingredients) (%) 1. Titanium oxide coated synthetic fluorphlogopite iron (Average particle size 5-11 μm, iron oxide coating 11-14%, tin oxide coating: Figure 2) 6.0 2. Silicone treatment, aluminum hydroxide, and hydrated silica treatment. Fine particle titanium dioxide *11 2.0 3. Ceramide-treated titanium dioxide *23 8.0 4. Zinc oxide *24 1.0 5. Boron nitride *33 5.0 6. Synthetic fluorphlogopite *34 remaining amount 7. Red iron oxide *8 0.5 8. Yellow iron oxide *9 1.7 9. Black iron oxide *10 0.15 10. Spherical silica *35 5.0 11. Dimethylsilylated silica *36 0.2 12. Spherical cellulose powder *37 0.5 13. (Dimer dilinoleate (phytosteryl / isostearyl / cetyl)) Stearyl / Behenyl (Refractive index 1.487) *38 5.0 14. Diphenylsiloxyphenyl trimethicone *17 (refractive index 1.455) 15.0 15. Triisostearin*39 (refractive index 1.458) 1.0 16. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 15.0 17. Hydrogenated phospholipids *12 0.5 18. Isododecane 5.0 *33: BORON NITRADE POWDER CCS-102 (manufactured by Momentive) *34: Micromica MK-200K (manufactured by Katakura Co-op Agri Co., Ltd., average particle size 7μm, aspect ratio 60) *35:CHIFFONSIL P-3R (manufactured by JGC Catalysts & Chemicals, average particle diameter 6μm) *36: AEROSIL R-976S (manufactured by Nippon Aerosil Co., Ltd.) *37: CELLULOBEADS D-30 (manufactured by Daito Kasei Kogyo Co., Ltd.) *38: PLANDOOL-S (manufactured by Nippon Seika Co., Ltd.) *39: Saracos 3318 (manufactured by Nisshin Oillio Co., Ltd.)

[0056] (Manufacturing method) A: Disperse and swell ingredients 7-17 using a three-roller system. B: Add ingredients 1-6 and 18 to A and knead under reduced pressure using a planetary mixer. C:B was filled into a container to obtain a foundation with properties between a solid powder and an oily solid.

[0057] The resulting foundation excelled in correcting skin tone without a pale appearance, providing a non-greasy sheen, and achieving a smooth, even finish.

[0058] Example 24: O / W Emulsified Liquid Primer A water-in-oil type liquid makeup base was manufactured using the following formulation and manufacturing method. (Ingredients) (%) 1. Titanium oxide coated synthetic fluorphlogopite iron (Average particle size 5-11 μm, iron oxide coating 11-14%, tin oxide coating: Figure 2) 6.0 2. Phospholipid-treated titanium dioxide *40 2.0 3. Talc *27 1.0 4. Silicone treatment, aluminum hydroxide, and hydrated silica treatment. Fine particle titanium dioxide *11 4.0 5. Red iron oxide *8 0.1 6. Yellow iron oxide *9 0.1 7. Black iron oxide *10 0.01 8. Treatment with amodimethicone distearyldimonium chloride Spherical silica*41 3.0 9. Titanium oxide coated synthetic fluorphlogopite 4.0 10. Lauroyl lysine *29 1.0 11. BG 20.0 12. Ethanol 2.0 13. (Acrylates / C10-30 Alkyl Acrylate) Crosspolymer 10.0 14. Carbomer 5.0 15. Purified water remaining amount 16. Ethylhexyl Methoxycinnamate 8.0 17. Diethylaminohydroxybenzoyl hexyl benzoate 1.0 18. Methylenebisbenzotriazolyltetramethylbutylphenol 0.5 19. Polyglyceryl-10 Laurate 0.1 20. Hydrogenated phospholipids *12 0.5 21. Sodium stearoyl glutamate *42 0.1 22. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 4.0 23. Triethylhexanoin *43 0.5 24. Diphenylsiloxyphenyl trimethicone *17 (refractive index 1.455) 1.0 25. PG dicaprate *44 1.0 26. Polysorbate 80 *45 0.5 27. Behenyl alcohol *46 0.5 *40: CR-50 (manufactured by Ishihara Sangyo Co., Ltd., average particle size 0.25 μm) 99.46% Phospholipids 0.54% *41: TMS-05DCA (manufactured by Teika Co., Ltd., average particle size 5μm) *42: Amisoft HS-11P(F) (manufactured by Ajinomoto Co., Inc.) *43: MYRITOL GTEH (manufactured by BASF) *44: NIKKOL PDD (manufactured by Japan Surfactant Industry Co., Ltd.) *45: Polysorbate 80 (manufactured by Kao Corporation) *46: Conol 2265 (manufactured by Shin Nippon Rika Co., Ltd.)

[0059] (Manufacturing method) A: Disperse and swell components 1-15. B: Add ingredients 16-27 to A and emulsify. C:B was filled into a tube container to obtain an O / W emulsion type liquid base.

[0060] The resulting O / W emulsion liquid primer excelled in correcting skin tone without a pale appearance, providing a non-greasy sheen, and creating a smooth, even makeup finish quickly.

[0061] Example 25: W / O Emulsified Liquid Foundation We developed a water-in-oil liquid foundation using the following formulation and manufacturing method. (Ingredients) (%) 1. Titanium oxide coated synthetic fluorphlogopite iron (Average particle size 5-11 μm, iron oxide coating 11-14%, tin oxide coating: Figure 2) 5.0 2. Silicone treatment, aluminum hydroxide, and hydrated silica treatment. Fine particle titanium dioxide *11 4.0 3. Silica-coated / silicone-treated zinc oxide microparticles *47 2.0 4. Dimethicone-treated red iron oxide 0.3 5. Dimethicone-treated yellow iron oxide 1.2 6. Dimethicone-treated black iron oxide 0.1 7. Boron nitride *25 1.0 8. Spherical silica *48 2.0 9. Dimethicone Crosspolymer *49 1.0 10.Synthetic phlogopite *34 1.0 11. Bis(PEG / PPG-14 / 14) Dimethicone *50 1.0 12. Isotridecyl isononanoate *31 2.5 13. Alkyl (C12-15) benzoate 1.5 14. Ethylhexyl Methoxycinnamate 3.0 15. Diisostearyl malate *32 (refractive index 1.460) 0.5 16. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 10.0 17. (Acrylates / Dimethicone) Copolymer *51 4.0 18. Purified water remaining amount 19. Tremella fuciformis polysaccharide *52 4.0 20. Ethanol 4.0 21. Ethylhexylglycerin *53 0.1 22. Phenoxyethanol 0.3 *47: MZ-510HPSX (Manufactured by Teika Corporation, average particle size 25nm) *48: TMS-10 (Teika Co., Ltd., average particle size 10 μm) *49: DOWSIL 9040 SILICONE ELASTOMER BLEND (manufactured by Dow Corning) (Solids content: Dimethicone crosspolymer 12.6%, Solvent: Cyclomethicone 87.4%) *50: ABIL EM 97S (manufactured by Evonik Industries) *51: KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.) *52: TREMOIST-TP (manufactured by Nippon Seika Co., Ltd.) *53: Adekanol GE-RF (manufactured by ADEKA)

[0062] (Manufacturing method) A: Disperse components 1-14 using a three-roller system. B: Add components 15-17 to A and disperse. Add ingredients 18-22 to C:B and emulsify. D:C was filled into a tube container to obtain a water-free emulsion liquid foundation.

[0063] The resulting W / O emulsion liquid foundation excelled in skin tone correction without a pale appearance, a non-greasy sheen, and the speed at which the makeup film applied evenly.

[0064] Example 26: Powder Foundation The powder foundation was developed using the following formulation and manufacturing method. (Ingredients) (%) 1. Titanium oxide coated synthetic fluorphlogopite iron (Average particle size 5-11 μm, iron oxide coating 11-14%, tin oxide coating: Figure 2) 4.0 2. Dimethicone-treated zinc oxide (average particle size 3.0 μm, hexagonal plate-shaped) 6.0 3. Phospholipid-treated titanium dioxide *40 4.0 4. Silicone-treated mica *30 remaining amount 5. Lauroyl lysine *29 3.0 6. Boron nitride *33 10.0 7. Barium sulfate (plate-shaped, average particle size 15 μm) 1.0 8. Spherical silica *41 2.0 9. Red iron oxide *8 1.5 10. Yellow iron oxide *9 1.0 11. Black iron oxide *10 0.5 12. Ethylhexyl Methoxycinnamate 6.0 13. (Acrylates / Stearyl Acrylate / Dimethicone Methacrylate) Copolymer *54 0.5 14. Sorbitan sesquistearate *55 1.0 15. Isotridecyl isononanoate *31 0.5 16. Chlorphenesin 0.1 17. Ethanol 0.5 *54: KP-561P (manufactured by Shin-Etsu Chemical Co., Ltd.) *55: NIKKOL SS-15V (manufactured by Nippon Surfactant Industry Co., Ltd.)

[0065] (Manufacturing method) A: Components (1) to (11) were mixed and dispersed. B: The dispersed components (12) to (17) were added to A and pulverized using a pulverizer. C: Powder foundation was obtained by compression molding into a metal dish container. During this process, component (17) evaporated.

[0066] The resulting powder foundation excelled in its ability to correct skin tone without appearing pale, its non-greasy sheen, and its ability to create a smooth, even finish.

[0067] Example 27: Oil-based blush (Ingredients) (%) 1. Dextrin palmitate *56 10.0 2. Microclustered wax (melting point 77-82°C) 4.0 3. Trimethylsiloxysilicate *57 6.0 4. Diglyceryl triisostearate (refractive index 1.463) 15.0 5,2-Cetyl ethylhexanoate (refractive index 1.443) 35.0 6. Dimethylpolysiloxane (at 25°C, viscosity 6CS) 2.0 7. Dimer dilinoleate (phytosteryl / isostearyl / cetyl) Stearyl / Behenyl (refractive index 1.487) *38 2.0 8. Sorbitan sesquioleate 2 9. Hydrogenated phospholipids *12 0.5 10. Red No. 202 0.5 11. Yellow No. 4 0.5 12. Black iron oxide *10 0.1 13. Talc *27 remaining amount 14. Dimethylsilylated silica *36 2.0 15. Spherical cellulose powder *37 3.0 16. Polyethylene powder *58 0.2 17. Titanium oxide coated synthetic fluorphlogopite iron (Average particle size 5-11 μm, iron oxide coating 11-14%, tin oxide coating: Figure 2) 2.0 18. Silica-coated / silicone-treated zinc oxide microparticles *47 1.0 *56: Leopard TL2 (manufactured by Chiba Flour Milling Co., Ltd.) *57: KF-9021 (50% solid content decamethylcyclopentasiloxane solution) (manufactured by Shin-Etsu Chemical Co., Ltd.) *58: Miperon PM-200 (manufactured by Mitsui Chemicals, Inc.) These are Red No. 202 (generic name: Lithol Rubine BCA) and Yellow No. 4 (generic name: Tartrazine).

[0068] (Manufacturing method) A. Heat ingredients (1) to (8) until uniformly dissolved. Add components (9) to (18) to BA and disperse them uniformly. The CB was poured into a gold dish and cooled and solidified to obtain an oily blush.

[0069] The resulting oil-based blush excelled in correcting skin tone without causing a pale appearance, providing a non-greasy sheen, and quickly creating a uniform makeup finish.

[0070] Example 28: Powdered solid blush (Ingredients) (%) 1. Titanium oxide coated synthetic fluorphlogopite iron (Average particle size 5-11 μm, iron oxide coating 11-14%, tin oxide coating: Figure 2) 20.0 2. Silicone-treated mica *30 remaining amount 3.Synthetic phlogopite *34 10.0 4. Triethoxycaprylylsilane-treated red iron oxide 0.2 5. Red No. 226 0.5 6. Talc *27 5.0 7. Silica-coated / silicone-treated zinc oxide microparticles *47 2.0 8. Spherical cellulose powder *37 2.0 9. Spherical silica *28 1.0 10. Chlorphenesin 0.2 11. Diglyceryl triisostearate (refractive index 1.463) 1.0 12. Diisostearyl malate *32 (refractive index 1.460) 1.0 13. Heavy liquid isoparaffin (refractive index 1.491) 0.5 14. Squalane (refractive index 1.457) 1.0 15. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 7.0 16. ((Dimer dilinoleate (phytosteryl / isostearyl / cetyl) Stearyl / Behenyl (refractive index 1.487) *38 1.0 17. Rosemary leaf extract 0.1 18. Glycerin 0.5 19. Avocado oil 0.1 20. Mineral oil 0.2 21. Tocopherol 0.01

[0071] (Manufacturing method) A. Mix ingredients (1) to (10) uniformly. A mixture of ingredients (11) to (21) was added to BA, uniformly dispersed, and then pulverized to obtain a cosmetic base. C. This was compressed and filled into an airtight resin container to obtain blush.

[0072] The resulting powdered blush exhibited excellent skin tone correction without a pale appearance, a non-greasy sheen, and a fast, even finish.

[0073] Example 29: White powder (Ingredients) (%) 1. Titanium oxide coated synthetic fluorphlogopite iron (Average particle size 5-11 μm, iron oxide coating 11-14%, tin oxide coating: Figure 2) 10.0 2. Dimethicone-treated synthetic fluorphlogopite iron *5 15.0 3. Talc *27 remaining amount 4. Titanium mica *59 10.0 5. Silica-coated / silicone-treated zinc oxide microparticles *47 8.0 6. Boron nitride *25 5.0 7. Spherical polyethylene powder *58 5.0 8. Spherical cellulose powder *37 10.0 9. Calcium carbonate *60 1.0 10. Spherical silica *48 2.0 11. Bengara 1.0 12. Yellow iron oxide *9 2.0 13. Black iron oxide *10 0.3 14. Methyl parahydroxybenzoate 0.2 15. Ethylhexyl Methoxycinnamate 2.0 16. Pentaerythrityl tetraisostearate (refractive index 1.467) 0.5 17. Octyldodecyl stearoyl oxystearate 0.5 18. Triethylhexanoin (refractive index 1.443) 3.0 19. (VP / Hexadecene) Copolymer *61 0.5 20. Squalane (refractive index 1.452) 0.2 21. Stearanium Heclite *62 1.0 22. 2% aqueous solution of cellulose nanofibers *63 0.2 23. Rice bran sphingoglycolipid 0.1 24. Watercress extract 0.1 25. Hydrogenated phospholipids *12 0.2 *59:TIMIRON STARLUSTER MP-115 (Merck, average particle size 20 μm, aspect ratio 300) *60: PC Chalk (manufactured by Shiraishi Kogyo Co., Ltd., average particle size 1 μm) *61: ANTARON V-216 (Ashland Japan Co., Ltd.) *62: BENTONE 27V (manufactured by Elementis) *63: Leocrysta C-2SP (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.)

[0074] (Manufacturing method) A. Mix ingredients (1) to (14) uniformly. A uniform mixture of ingredients (15) to (25) was added to BA, uniformly dispersed, and then pulverized to obtain a cosmetic base. C. 100 parts of the cosmetic base material were mixed with 70 parts of the solvent listed in the table to obtain a slurry-like mixture. D. 10.0 g of the above mixture was placed in a round metal dish container (7 cm in diameter), and compressed twice under the conditions of a press pressure of 2.0 kgf / cm2, a press time of 4 seconds, and 6 sheets of paper, to partially remove the solvent. Then, it was dried at 70°C for 10 hours to remove the solvent and obtain a white powder.

[0075] The resulting face powder excelled in correcting skin tone without a pale appearance, providing a non-greasy sheen, and creating a smooth, even makeup finish quickly.

[0076] Example 30: Eyebrow (Ingredients) (%) 1. Talc *27 20.0 2. Silicone-treated mica *30 remaining amount 3. Black iron oxide *10 10.0 4. Bengara 4.0 5. Aluminum hydroxide-treated titanium dioxide (average particle size 1.0 μm) 6.0 6. Titanium oxide coated synthetic fluorphlogopite iron (Average particle size 5-11 μm, iron oxide coating 11-14%, tin oxide coating: Figure 2) 10.0 7. Black iron oxide coated titanium mica 15.0 8. Particulate zinc oxide *24 2.0 9. Zinc stearate *64 1.0 10. Spherical silica *28 1.0 11. Red No. 226 0.1 12. Yellow No. 4 0.1 13. Red No. 202 0.1 14. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 10.0 15. Phenylentrimethicone *16 (refractive index 1.458) 3.0 16. Dimer dilinoleate (phytosteryl / isostearyl / cetyl) Stearyl / Behenyl (refractive index 1.487) *38 3.0 17. Carnauba wax 0.5 18. Microcrystalline wax (melting point 77-82°C) 0.5 19. Trimethylsiloxysilicate *57 1.0 20. Paraffin 0.3 21. Beeswax 0.2 22. Dextrin isostearate 1.0 23. Hydrogenated phospholipids *12 1.0 24. Damask rose flower extract 0.2 25. Lemon fruit extract 0.1 26. Ethanol 0.1 27.Purified water 0.2 *64:MZ-2 (manufactured by NOF Corporation, average particle size 1.5μm)

[0077] (Manufacturing method) A. Mix ingredients (1) to (13) uniformly. A uniform mixture of ingredients (14) to (27) was added to BA, uniformly dispersed, and then pulverized to obtain a cosmetic base. C. 100 parts of the cosmetic base material were mixed with 40 parts of isododecane solvent to obtain a slurry-like mixture. D. 2.0 g of the above mixture was placed in a round metal dish container (2 cm in diameter), and compressed twice under the conditions of a press pressure of 2.0 kgf / cm2, a press time of 4 seconds, and 6 sheets of paper, to partially remove the solvent. Then, it was dried at 70°C for 10 hours to remove the solvent and obtain the eyebrow product.

[0078] The resulting eyebrow product excelled in its non-greasy shine and the speed at which it created a uniform, even finish.

[0079] Example 31: Solid powder eyeshadow (Ingredients) (%) 1. Titanium oxide coated synthetic fluorphlogopite iron (Average particle size 5-11 μm, iron oxide coating 11-14%, tin oxide coating: Figure 2) 10.0 2. Talc *27 remaining amount 3. Titanium dioxide treated with disodium stearoyl glutamate *65 15.0 4. Silicone treatment, aluminum hydroxide, and hydrated silica treatment. Fine particle titanium dioxide *11 2.0 5. Boron nitride *25 5.0 6. Spherical silica *48 5.0 7. Ultramarine 2.0 8. Red No. 202 0.5 9. Organopolysiloxane elastomer powder *66 1.0 10. Chlorphenesin 0.1 11. Bismuth oxychloride *26 5.0 12. Barium sulfate (plate-like, average particle size: 15 μm) 3.0 13. Macadamia nut oil (refractive index 1.465) 1.0 14. Dimethylpolysiloxane (6CS: 25℃) 7.0 15. Diphenylsiloxyphenyl trimethicone *17 (refractive index 1.455) 2.0 16. Lauroyl glutamate di(phytosteryl / octyldodecyl) *67 (Refractive index 1.479) 1.0 17. Hydrogenated phospholipids *12 0.5 18. Refined olive oil (refractive index 1.465) 0.5 19.Fragrance 0.01 *65: NAI-Titanium MP-1133 (manufactured by Miyoshi Chemical Co., Ltd., average particle size 0.27 μm) *66: KSP-300 (manufactured by Shin-Etsu Chemical Co., Ltd., average particle size 5 μm) *67: Eldew PS-203 (manufactured by Ajinomoto Co., Inc.)

[0080] (Manufacturing method) A. Disperse ingredients (1) to (12) uniformly using a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.). B. Mix ingredients (13) to (19) uniformly. While stirring CA in a Henschel mixer, add B and disperse it uniformly. The DC is crushed using a pulverizer. The ED was filled into a metal dish and compressed to obtain a solid powder eyeshadow.

[0081] The resulting eyeshadow excelled in its ability to correct skin tone without appearing pale, its non-glossy sheen, and its ability to create a smooth, even finish.

[0082] Example 32: Aerosol-type foundation cosmetic (Ingredients) (%) 1. Phospholipid-treated aluminum hydroxide-treated titanium dioxide (Average particle size 0.27μm) 10.0 2. Triethoxycaprylylsilane-treated red iron oxide 0.8 3. Triethoxycaprylylsilane-treated yellow iron oxide powder 1.0 4. Triethoxycaprylylsilane-treated black iron oxide powder 0.5 5. Titanium oxide coated synthetic fluorphlogopite iron (Average particle size 5-11 μm, iron oxide coating 11-14%, tin oxide coating: Figure 2) 10.0 6. Silicone treatment, aluminum hydroxide, and hydrated silica treatment Fine particle titanium dioxide *11 2.0 7. Spherical silica *28 2.0 8. Polyglyceryl-3 / Polydimethylsiloxyethyl Dimethicone 1.0 9. Decamethylcyclopentasiloxane 5.0 10. Dimethylpolysiloxane (remaining amount) 11. (Trifluoropropyl dimethicone / Trifluoro Propyldivinyldimethicone) Crosspolymer 2.0 12. Ethylhexyl Methoxycinnamate 8.0 13. (Trifluoropropyldimethylsiloxy / Trimethylsiloxy(silsesquioxane) *68 5.0 14. PEG-9 Polydimethylsiloxyethyl Dimethicone *69 2.0 15. Mixture of cross-linked organopolysiloxane polymers 2.0 16. Trimethylolpropane triisostearate (refractive index 1.463) 0.5 17.2-Methacryloyloxyethyl phosphorylcholine (MPC) group-containing polymer *70 1.0 18. Agar 0.1 19. Bis-ethylhexyloxyphenol methoxyphenyl Triazine Emulsion 2.0 20. Tripropylene glycol 3.0 21.Purified water 15.0 *68: FR-5 (manufactured by Momentive) *69: KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.) *70: Lipidure-PMB (manufactured by NOF Corporation)

[0083] (Manufacturing method) A. Mix ingredients (1) to (7) using a three-roller mixer. Heat BA and components (8) to (16) at 50°C and mix until uniformly dispersed. C. Components (17) to (21) were mixed and added to B, and emulsified at room temperature to obtain the stock solution. After filling 9g of the stock solution obtained by DC into an aluminum pressure vessel, a valve was attached, and 10g of LPG 0.15 and 2g of dimethyl ether were filled into the pressure vessel through the valve to obtain an aerosol foundation.

[0084] The resulting aerosol foundation excelled in skin tone correction without a pale appearance, a non-greasy sheen, and the speed at which the makeup film applied evenly.

Claims

1. The following components (A) to (C): (A) Plate-shaped powder containing iron and coated with titanium dioxide, with an average particle size of 3 to 30 μm. (B) Oils with a refractive index of 1.455 or higher at 24°C (C) One or more selected from phospholipids, 2-methacryloyloxyethyl phosphorylcholine (MPC) group-containing polymers, ceramides, and N-acyl amino acids and their salts. It contains, The aforementioned component (A) is luminous, and when measured using a spectrocolorimeter at an incident angle of -45° and a receiving angle of 0°, the colorimetric values ​​L* (lightness), C* (chroma), and h (hue) defined in the CIE 1976 L*a*b* color system are 60 < L* < 83, 12 < C* < 32, 40 < h < 76, and, A cosmetic in which the plate-like powder of component (A) is synthetic fluorphlogopite coated with titanium dioxide, with synthetic fluorphlogopite iron as the base material.

2. The above component (A) is applied to the adhesive surface of the transparent adhesive tape in a [5 x 8] cm area. ２ The cosmetic composition according to claim 1, wherein when 0.05 g is applied per unit area and the reflectance intensity is measured using a D65 light source with a variable angle spectrophotometer at an incident angle of -45 degrees against a black non-reflective background, the ratio [I(45)] / [I(O)] of the reflectance intensity at a receiving angle of 45 degrees to the reflectance intensity at a receiving angle of 0 degrees [I(O)] at wavelengths of 450 nm and 650 nm is 1 to 4.

3. The cosmetic composition according to claim 1 or 2, wherein the coating amount of titanium dioxide in component (A) is 5 to 20% by mass.

4. The cosmetic composition according to any one of claims 1 to 3, wherein component (B) is one or more selected from ultraviolet absorbers, phenyl-modified silicones, and tridecyl trimellitic acid.

5. Furthermore, the cosmetic composition according to any one of claims 1 to 4, further comprising hydrophobized fine particle metal oxide as component (D).

6. Furthermore, the cosmetic composition according to any one of claims 1 to 5, further comprising silica as component (E).

7. The cosmetic composition according to any one of claims 1 to 6, wherein the mass content ratio of the aforementioned components (A) and (C) is (A) / (C) = 0.5 to 100.

8. The above component (A) is applied to the adhesive surface of the transparent adhesive tape in a [5 x 8] cm area. ２ A cosmetic composition according to any one of claims 1 to 7, wherein when 0.05 g is applied per unit area and the reflectance intensity is measured using a D65 light source with a variable angle spectrophotometer at an incident angle of -45 degrees against a black non-reflective background, the ratio of the reflectance intensity [I(45)] at a receiving angle of 45 degrees at wavelengths of 450 nm and 650 nm is [I(45)](450 nm): [I(45)](650 nm) = 1:1 to 1:

2.

9. The cosmetic composition according to any one of claims 1 to 8, wherein the cosmetic composition is an emulsified cosmetic composition.

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