Optical component for use in a display device and display device including the same

Abstract

The present invention provides an optical member for use in a display device having a specific light-emitting part, the optical member including a specific light-bending part and a light-absorbing part which has an absorption waveform selected from specific absorption waveforms A to D and which also has the absorption waveform B or C. The present invention also provides a display device including the same.　Absorption waveform B: a specific absorption waveform in which two wavelengths giving half the absorbance of an absorption maximum exist in the wavelength region exceeding λBMax and less than λGMax Absorption waveform C: a specific absorption waveform in which two wavelengths giving half the absorbance of an absorption maximum exist in the wavelength region exceeding λGMax and less than λRMax Additionally, the units of wavelength are all nm in the above formulas (1) and (2).　λBMax: maximum emission wavelength exhibited by blue light emission by display device λGMax: maximum emission wavelength exhibited by green light emission by display device λRMax: maximum emission wavelength exhibited by red light emission by display device

Description

[Technical Field]

[0001] The present invention relates to an optical component for use in a display device and a display device including the same. [Background technology]

[0002] An organic light-emitting diode (OLED) is a type of self-luminescent device comprising an anode, an organic light-emitting layer, and a cathode. When a voltage is applied between the anode and the cathode, holes are injected from the anode into the organic light-emitting layer, and electrons are injected from the cathode into the organic light-emitting layer. At this time, the holes and electrons injected into the organic light-emitting layer recombine in the organic light-emitting layer to generate excitons, and these excitons emit light as they transition from the excited state to the ground state. Therefore, display devices that use the self-emissive properties of OLEDs to display images have advantages over various other display devices such as liquid crystal displays and plasma displays, including a high contrast ratio, high color reproduction, a wide viewing angle, fast response time, and the ability to be made thinner and lighter. In addition to these advantages, their flexibility has also led to active research and development of OLEDs as a next-generation display device.

[0003] On the other hand, because OLEDs use organic materials as light-emitting elements, the issue of lifespan due to the degradation of these organic materials is a core aspect of OLED technology development, and technological development is underway to overcome this problem. As part of this effort, a technology that introduces a microcavity (micro-resonator) structure is known. This technology utilizes the resonance effect of light between electrodes. By designing the distance between the anode and cathode electrodes (optical path length) to match the wavelengths of red (R), green (G), or blue (B), only light of wavelengths matching the optical path length resonates, and light of other wavelengths is weakened. This allows for the direct extraction of light with a narrow half-width and high light intensity. As a result, both brightness and color purity are increased, and it is expected that the improved brightness will reduce power consumption, leading to a longer lifespan for OLEDs.

[0004] However, in the above microcavity structure, it is known that the wavelength of light that causes resonance also changes depending on the angle from which the OLED is viewed. When viewing the OLED from an oblique angle compared to viewing it from the front, the resonant wavelength shifts to the shorter wavelength side (blue shift) as the angle from the front increases. For example, Patent Document 1 proposes a technique to improve the blue shift phenomenon associated with the introduction of the above-mentioned microcavity structure. This technique involves using a structure that includes structures with different refractive indices to convert a portion of the straight-traveling light into an oblique direction, thereby diffusing light of various wavelengths in the oblique direction and adjusting the color (hereinafter referred to as "oblique color") when viewing the display device from an oblique angle to a neutral state. [Prior art documents] [Patent Documents]

[0005] [Patent Document 1] Japanese Patent Publication No. 2014-123568 [Overview of the project] [Problems that the invention aims to solve]

[0006] Through further investigation, the inventors have found that while the technology described in Patent Document 1 can be used to adjust the color tone in diagonal directions to a neutral level, the circular polarizer used for preventing reflection of ambient light becomes ineffective, making it impossible to sufficiently suppress ambient light reflection. Therefore, the object of the present invention is to provide an optical element that, even when used on the front surface of an organic electroluminescent display device having a microcavity structure as described in Patent Document 1, can neutralize the color tone in an oblique direction by providing a light bending portion, and that can achieve an excellent level of both suppression of external light reflection and suppression of brightness reduction, and a display device including the same. [Means for solving the problem]

[0007] In view of the above problems, the inventors conducted diligent studies and found that by using a light-absorbing section that absorbs specific light in place of a circular polarizer, and applying an optical member equipped with this light-absorbing section and a light-bending section, external light reflection can be suppressed, but it is difficult to say that a sufficient suppression effect of external light reflection is obtained compared to when a circular polarizer is used. Furthermore, increasing the amount of light absorption to enhance the suppression effect of external light reflection reduces brightness. However, the inventors found that by using a light-absorbing section with an absorption waveform that absorbs light of wavelengths located between blue and green, or between green and red, as emitted by the light-emitting section of a display device, an excellent suppression effect of external light reflection and an excellent suppression effect of brightness reduction can be obtained. The present invention was completed after further studies based on this finding.

[0008] In other words, the above problems were solved by the following means. <1> An optical component for use in a display device, The above-mentioned display device has a light-emitting section, and this light-emitting section is an organic electroluminescent light-emitting element or a microlight-emitting diode. The above optical component includes a light bending portion that bends and emits a portion of the amount of light from the incident straight-traveling light, and a light absorbing portion containing a dye. An optical component for use in a display device, wherein the absorption waveform of the above-mentioned light-absorbing part is selected from the following absorption waveforms A to D, and the above-mentioned light-absorbing part has the following absorption waveform B or C. Absorption waveform A:λ BMax Absorption waveforms having a main absorption wavelength band in the wavelength range below [a certain wavelength] Absorption waveform B:λ BMax Over λ GMax An absorption waveform in which two wavelengths exist in the wavelength range less than 1, which give an absorbance of half the absorption maximum, and the width between the two wavelengths FWHM b The absorption waveform that satisfies the relationship in equation (1) below. Equation (1) FWHM b ≥ 50 - x / 2 - y / 2 Absorption waveform C:λ GMax Over λ RMaxAn absorption waveform in which there are two wavelengths that give an absorbance of half of the absorption maximum in a wavelength range less than that, and the width FWHM between the two wavelengths c is an absorption waveform that satisfies the relationship of the following formula (2) Formula (2) FWHM c ≧60 - y / 2 - z / 2 Absorption waveform D: λ RMax is an absorption waveform having a main absorption wavelength band in a wavelength range exceeding In the description of the absorption waveforms A to D above, each symbol has the following meaning. Also, in the above formulas (1) and (2), the unit of wavelength is nm in both cases.. λ BMax : The maximum emission wavelength indicated by the blue emission of the display device λ GMax : The maximum emission wavelength indicated by the green emission of the display device λ RMax : The maximum emission wavelength indicated by the red emission of the display device x: The width between two wavelengths that give an absorbance of half of the maximum emission indicated by the blue emission of the display device y: The width between two wavelengths that give an absorbance of half of the maximum emission indicated by the green emission of the display device z: The width between two wavelengths that give an absorbance of half of the maximum emission indicated by the red emission of the display device <2> The optical member includes a light bending filter that forms the light bending portion and a light absorption filter that forms the light absorption portion, and is an optical member for use in the display device according to <1>. <3> The light bending filter bends 1 to 20% of the amount of incident direct light, and is an optical member for use in the display device according to <2>. <4> The total light transmittance of the light bending filter is 99% or more, and is an optical member for use in the display device according to <2> or <3>. <5> The light bending filter has at least a region I and a region II that exhibits a refractive index different from that of the region I, and is an optical member for use in the display device according to any one of <2> to <4>. <6> Region I above contains zirconium oxide particles. <5> An optical component for use in the display device described above. <7> Region II above contains adhesive or hollow particles. <5> or <6> An optical component for use in the display device described above. <8> The dye contained in the light absorption filter exhibiting the above absorption waveform B or C includes a squalin-based dye represented by the following general formula (1). <2> ~ <7> An optical component for use in the display device described in any one of the following. [ka] In the above formula, A and B each independently represent an optionally substituted aryl group, an optionally substituted heterocyclic group, or -CH=G. G represents an optionally substituted heterocyclic group. <9> The dye contained in the light absorption filter showing the above absorption waveform A includes a pigment represented by the following general formula (A1): <2> ~ <8> An optical component for use in the display device described in any one of the following. [ka] In the above formula, R 1 and R 2 Each independently represents an alkyl group or an aryl group, R 3 ~R 6 Each of these independently represents a hydrogen atom or a substituent, R 5 and R 6 These may be bonded to each other to form a six-membered ring. <10> The dye contained in the light absorption filter exhibiting the above absorption waveform D includes at least one of the dyes represented by the following general formula (D1) and the dye represented by the following general formula (1). <2> ~ <9> An optical component for use in the display device described in any one of the following. [ka] In the above formula, R 1A and R 2Aeach independently represents an alkyl group, an aryl group or a heteroaryl group, R 4A and R 5A each independently represents a heteroaryl group, R 3A and R 6A each independently represents a substituent. X 1 and X 2 each independently represents -BR 21a R 22a represents, R 21a and R 22a each independently represents a substituent, R 21a and R 22a may be bonded to each other to form a ring. [Chemical formula] In the above formula, A and B each independently represent an aryl group which may have a substituent, a heterocyclic group which may have a substituent or -CH=G. G represents a heterocyclic group which may have a substituent. <11> The optical member for use in the display device according to any one of <2> to <10>, wherein the light absorption filter contains a fading inhibitor represented by the following general formula (IV). [Chemical formula] In the above formula, R 10 each independently represents an alkyl group, an alkenyl group, an aryl group, a heterocyclic group or a group represented by R 18 CO-, R 19 SO2- or R 20 NHCO-. R 18 , R 19 and R 20 each independently represents an alkyl group, an alkenyl group, an aryl group or a heterocyclic group. R 11 and R 12 each independently represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkoxy group or an alkenyloxy group, R 13 ~R 17 each independently represents a hydrogen atom, an alkyl group, an alkenyl group or an aryl group. <12> The optical member for use in the display device according to any one of <2> to <11>, wherein the light absorption filter contains a polystyrene resin or a cyclic polyolefin resin. <13> The optical member for use in the display device according to any one of <2> to <12>, wherein the light absorption filter exhibits all of the absorption waveforms A to D. <14> A display device including an optical member for use in the display device according to any one of <1> to <13> and a light emitting portion, wherein the light emitting portion is an organic electroluminescence light emitting element or a micro light emitting diode. <15> The display device according to <14>, including a quantum dot sheet for wavelength conversion on the viewing side of the light emitting portion of the display device. <16> The display device according to <14> or <15>, wherein the display device includes a matrix that absorbs or scatters external light, and the matrix is disposed between light emitting elements constituting the light emitting portion.

[0009] In the present invention, when there are a plurality of substituents or linking groups (hereinafter referred to as substituents, etc.) represented by specific symbols or formulas, or when a plurality of substituents, etc. are defined simultaneously, unless otherwise specified, each of the substituents, etc. may be the same as or different from each other. This also applies to the definition of the number of substituents, etc. Further, when a plurality of substituents, etc. are close to each other (particularly when adjacent), unless otherwise specified, they may be linked to each other to form a ring. Further, unless otherwise specified, a ring, for example, an alicyclic ring, an aromatic ring, or a heterocyclic ring may be further condensed to form a condensed ring. In the present invention, unless otherwise specified, each component that can constitute a light-absorbing portion (dye, resin, dye browning inhibitor, and other components, etc.) may be contained in the light-absorbing portion as one type or as two or more types. Similarly, unless otherwise specified, each component that can constitute a light-bending portion (material that constitutes a high refractive index region such as region I, material that constitutes a low refractive index region such as region II) may be contained in the light-bending portion as one type or as two or more types. In the present invention, unless otherwise specified, the double bond may be either an E-type or a Z-type double bond, or a mixture thereof, if both are present in the molecule. In this invention, the term "compound" (including complexes) is used to mean not only the compound itself, but also its salts and ions. It also means that the compound may have a modified structure as long as it does not impair the effects of this invention. Furthermore, for compounds where substitution or unsubstituted status is not specified, it means that they may have any substituents as long as it does not impair the effects of this invention. The same applies to substituents and linking groups. Furthermore, in this invention, a numerical range represented using "~" means a range that includes the numerical values ​​written before and after "~" as the lower limit and upper limit, respectively. In the present invention, the term "composition" includes not only mixtures in which the component concentrations are constant (i.e., each component is uniformly dispersed), but also mixtures in which the component concentrations fluctuate within a range that does not impair the desired function. In this invention, having a main absorption wavelength band in a specific wavelength range X means that the wavelength exhibiting maximum absorption (i.e., the maximum absorption wavelength) exists in that specific wavelength range X. Therefore, if this maximum absorption wavelength is within the above wavelength range X, the entire absorption band including this wavelength may be within the above wavelength range X, or it may extend outside the above wavelength range X. Also, if there are multiple maximum absorption wavelengths, it is sufficient that the maximum absorption wavelength exhibiting the largest absorbance is located within the above wavelength range X. In other words, maximum absorption wavelengths other than the maximum absorption wavelength exhibiting the largest absorbance may be located either inside or outside the above wavelength range X. [Effects of the Invention]

[0010] The optical component of the present invention, even when used on the front surface of an organic electroluminescent display device having a microcavity structure as described in Patent Document 1, is an optical component that can neutrally adjust the color tone in an oblique direction by providing a light bending portion, and can achieve an excellent level of both suppression of external light reflection and suppression of brightness reduction. Furthermore, the display device of the present invention includes the above-mentioned optical member and is a display device that can adjust the color tone in the oblique direction to a neutral state, and is also excellent in suppressing external light reflection and brightness reduction. [Brief explanation of the drawing]

[0011] [Figure 1] Figure 1 is a schematic cross-sectional view showing an example of an optical component for use in the display device of the present invention. [Figure 2] Figure 2 is an enlarged view illustrating the shape of the high refractive index portion in a schematic cross-sectional view of the optical element for use in the display device of the present invention described in Figure 1. [Figure 3] Figure 3 is an absorption-emission spectrum schematically showing the relationship between the absorption waveforms A to D that can be exhibited by the light-absorbing portion of the optical element used in the display device of the present invention and the emission waveform of the display device. [Modes for carrying out the invention]

[0012] [Optical components for use in display devices] The optical component for use in the display device of the present invention is an optical component for use in a display device having an organic electroluminescent light-emitting element or a microlight-emitting diode as a light-emitting part. The optical component for use in the display device of the present invention includes a light bending portion that bends and emits a portion of the amount of light from the incident straight-traveling light, and a light absorbing portion containing a dye, wherein the absorption waveform of the light absorbing portion is selected from absorption waveforms A to D described later, and the light absorbing portion has absorption waveform B or C described later. In the optical member for use in the display device of the present invention, the light-absorbing portion and the light-bending portion may be mixed together or may exist separately, as long as the effects of the present invention are not impaired. An example of a form in which the light-absorbing portion and the light-bending portion are mixed together is a form in which hollow particles corresponding to the light-bending portion are discontinuously mixed within the light-absorbing portion. In particular, it is preferable that the light-absorbing portion and the light-bending portion are not mixed together, and it is even more preferable that the light-bending portion is formed by a light-bending filter and the light-absorbing portion is formed by a light-absorbing filter. In the above-mentioned light-flexing filter and light-absorbing filter, the term "filter" refers to a film that has light-flexibility or light-absorbing properties.

[0013] The optical component for use in the display device of the present invention (hereinafter also simply referred to as "the optical component of the present invention") includes the above-mentioned light bending portion and the above-mentioned light absorbing portion, and when used on the front surface of an organic electroluminescent display device having a microcavity structure, it can adjust the color tone in the oblique direction to a neutral state and is excellent in suppressing external light reflection and brightness reduction. The reason for this is presumed to be as follows. The optical component of the present invention, by providing a light bending portion, can neutralize the color in oblique directions when used on the front surface of an organic electroluminescent display device having a microcavity structure, as described in Patent Document 1. Furthermore, by using a light absorbing portion exhibiting a specific absorption waveform in place of a circular polarizer, the optical component of the present invention solves the problem that circular polarizers used for anti-reflective purposes become ineffective due to the light bending portion. By having an absorption waveform selected from absorption waveforms A to D that satisfy a specific relationship with the absorption band of the emission spectrum of the display device, and by including at least absorption waveform B or C in the light absorbing portion, it is considered that excellent levels of suppression of external light reflection and suppression of brightness reduction can be achieved.

[0014] <<Light-absorbing section>> In the optical member of the present invention, the light absorption portion has an absorption waveform selected from the following absorption waveforms A to D, and the light absorption portion has the following absorption waveform B or C. Absorption waveform A: λ BMax An absorption waveform having a main absorption wavelength band in a wavelength range less than Absorption waveform B: λ BMax Beyond λ GMax An absorption waveform in which there are two wavelengths that give an absorbance of half of the absorption maximum in a wavelength range less than, and the width FWHM b Satisfies the relationship of the following formula (1) Formula (1) FWHM b ≧50 - x / 2 - y / 2 Absorption waveform C: λ GMax Beyond λ RMax An absorption waveform in which there are two wavelengths that give an absorbance of half of the absorption maximum in a wavelength range less than, and the width FWHM c Satisfies the relationship of the following formula (2) Formula (2) FWHM c ≧60 - y / 2 - z / 2 Absorption waveform D: λ RMax An absorption waveform having a main absorption wavelength band in a wavelength range beyond In the description of the above absorption waveforms A to D, each symbol has the following meaning. Also, in the above formulas (1) and (2), the unit of wavelength is nm in both cases. λ BMax : The maximum emission wavelength indicated by the blue emission of the display device λ GMax : The maximum emission wavelength indicated by the green emission of the display device λ RMax : The maximum emission wavelength indicated by the red emission of the display device x: The width between two wavelengths that give an absorbance of half of the maximum emission indicated by the blue emission of the display device y: The width between two wavelengths that give an absorbance of half of the maximum emission indicated by the green emission of the display device z: The width between two wavelengths that give an absorbance of half of the maximum emission indicated by the red emission of the display device

[0015] In the present invention, the main absorption wavelength band of the light-absorbing portion is measured in the state of the light-absorbing portion or the light-absorbing portion with a substrate, according to the conditions described in the section on the absorption waveform of the light-absorbing filter in the embodiments described later.

[0016] The absorption waveforms A to D that the above-mentioned light-absorbing section can exhibit are, as schematically shown in Figure 3, the maximum emission wavelength λ of the blue, green, and red light emitted by a display device (hereinafter also referred to as "the display device of the present invention") having an organic electroluminescent light-emitting element or a microlight-emitting diode as the light-emitting section. BMax , λ GMax and λ RMax The region other than the specified area has a main absorption wavelength band that satisfies the provisions of the present invention. Therefore, the light absorbing portion of the optical member of the present invention having an absorption waveform selected from absorption waveforms A to D can suppress the reflection of ambient light while suppressing the decrease in brightness of the display device of the present invention. Figure 3 shows the main absorption wavelength bands of absorption waveforms A to D that the above-mentioned light absorbing section can exhibit, and the width FWHM between the two wavelengths that give half the absorbance of the absorption maxima of absorption waveforms B and C. b and FWHM c The maximum emission wavelength λ shown by the blue, green, and red light emission of the display device of the present invention. BMax , λ GMax and λ RMax The figure also schematically shows the relationship between the widths x, y, and z of two wavelengths that give half the absorbance of the maximum emission of each color. Absorption waveforms A to D in Figure 3 represent typical absorption waveforms that satisfy absorption waveforms A to D as defined in the present invention. The maximum emission wavelength λ shown by the blue, green, and red light emitted by the display device of the present invention BMax , λ GMax and λ RMax Furthermore, the widths x, y, and z between two wavelengths that give half the absorbance of the maximum emission shown by the blue, green, and red light emitted by each of the blue, green, and red colors of the display device of the present invention are not particularly limited, as long as the light-emitting part is an organic EL light-emitting element or a micro-LED. For example, λ BMax Examples include 400-500 nm, with 430-480 nm being preferred. λ GMaxExamples include 500-600 nm, with 500-550 nm being preferred. λ RMax Examples include 600-700nm, with 600-650nm being preferred. Furthermore, for example, x can range from 15 to 40 nm, with 15 to 20 nm being preferred. For y, a range of 15 to 50 nm is possible, with 25 to 40 nm being preferred. For z, a range of 15 to 50 nm is possible, with 15 to 40 nm being preferred.

[0017] The above-mentioned light-absorbing portion can suppress external light reflection by exhibiting at least the above-mentioned absorption waveform B or C, which is located in the wavelength region with high relative luminous efficiency. The above absorption waveform B satisfies the relationship given by equation (1) above (hereinafter also referred to as relation (1)). From the viewpoint of absorbing wavelengths other than those of the light-emitting part over a wider range and further improving the suppression of reflectance, it is preferable that the relationship given by equation (1a) below be satisfied, more preferably that the relationship given by equation (1b) below be satisfied, and even more preferably that the relationship given by equation (1c) below be satisfied. Equation (1a) FWHM b ≥ 55 - x / 2 - y / 2 Equation (1b) FWHM b ≥60-x / 2-y / 2 Equation (1c) FWHM b ≥65-x / 2-y / 2 Furthermore, the absorption waveform C satisfies the relationship given by equation (2) above (hereinafter also referred to as relation (2)). Similar to the absorption waveform B, it is preferable that the absorption waveform C satisfies the relationship given by equation (2a) below, and more preferably satisfies the relationship given by equation (2b) below, from the viewpoint of absorbing wavelengths other than those of the light-emitting portion over a wider range and further improving the suppression of reflectance. Equation (2a) FWHM c ≥63-y / 2-z / 2 Equation (2b) FWHM c ≥66-y / 2-z / 2 In equations (1a) to (1c), (2a), and (2b) above, the unit of wavelength is nm.

[0018] The above absorption waveform A is λ BMaxPreferably, it has a main absorption wavelength band in a wavelength range of -20 or less, λ BMax More preferably, it has a main absorption wavelength band in a wavelength range of -30 or less. The absorption waveform B is such that λ BMax is +20 or more and λ GMax Preferably, it is an absorption waveform in which there are two wavelengths that give an absorbance of half of the absorption maximum in a wavelength range of -3 or less, λ BMax is +30 or more and λ GMax More preferably, it is an absorption waveform in which there are two wavelengths that give an absorbance of half of the absorption maximum in a wavelength range of -6 or less. The absorption waveform C is such that λ GMax is +20 or more and λ RMax Preferably, it is an absorption waveform in which there are two wavelengths that give an absorbance of half of the absorption maximum in a wavelength range of -10, λ GMax is +30 or more and λ RMax More preferably, it is an absorption waveform in which there are two wavelengths that give an absorbance of half of the absorption maximum in a wavelength range of -20. The absorption waveform D preferably has a main absorption wavelength band in a wavelength range of λ RMax +20 or more, and more preferably has a main absorption wavelength band in a wavelength range of λ RMax +30 or more. In the definition of the main absorption wavelength band possessed by the absorption waveforms A to D described above, the unit of the wavelength range is nm in all cases. To explain with an example, the wavelength range of λ BMax -20 or less means a wavelength range of [λ BMax -20] nm or less.

[0019] The light absorption part has the absorption waveforms A to D so as to satisfy the provisions of the present invention, and as long as it can be used in a display device, the material constituting the light absorption part can be used without particular limitation. Among others, it is preferable that the light absorption part exhibits the absorption waveforms A to D by containing a dye, and it more preferably contains the dye and a resin described later, and the dye is dispersed (preferably dissolved) in the resin, and is a light absorption filter that exhibits the absorption waveforms A to D derived from the dye. This dispersion may be random, regular, or the like. The following details the components that can constitute the light-absorbing part.

[0020] <dye> The light-absorbing portion preferably contains dyes exhibiting the above absorption waveforms A to D in a manner that satisfies the provisions of the present invention. Examples of the above-mentioned dyes include dye A (hereinafter also simply referred to as "dye A") which exhibits absorption waveform A in the light-absorbing area, dye B (hereinafter also simply referred to as "dye B") which exhibits absorption waveform B in the light-absorbing area, dye C (hereinafter also simply referred to as "dye C") which exhibits absorption waveform C in the light-absorbing area, and dye D (hereinafter also simply referred to as "dye D") which exhibits absorption waveform D in the light-absorbing area. The above dyes A to D can be incorporated into the light-absorbing portion in accordance with the absorption waveform shown by the light-absorbing portion. When the above absorption waveforms A to D of the light-absorbing portion are shown by the dyes, the light-absorbing portion in the optical member of the present invention contains at least dye B or dye C. Furthermore, the dye A that may be contained in the light-absorbing portion may be one type or two or more types. Similarly, the dyes B to D that may be contained in the light-absorbing portion may each be one type or two or more types, independently of dye A. The above light-absorbing portion may also contain dyes other than dyes A to D, as long as it does not impair the effects of the present invention. That is, the above light-absorbing portion may also exhibit absorption waveforms other than absorption waveforms A to D, as long as it does not impair the effects of the present invention. An example of such a material is absorption waveform B and λ GMax Over λ RMax An optical absorption section exhibiting an absorption waveform that does not satisfy the relationship in equation (2) above, although there are two wavelengths in the wavelength range below that give an absorbance of half the absorption maximum (i.e., an absorption waveform c whose width of the absorption peak is narrower than the specified absorption waveform C), and the above absorption waveform C and λ BMax Over λ GMaxExamples of light-absorbing sections include those exhibiting an absorption waveform that does not satisfy the relationship in equation (1) above, even though there are two wavelengths in the wavelength range below that give an absorbance of half the absorption maximum (i.e., an absorption waveform b whose absorption peak width is narrower than that of absorption waveform B). In these examples, the absorption peak of absorption waveform b or c is too sharp, and therefore a suppression effect on ambient light reflection cannot be obtained by itself. However, when the light-absorbing section exhibits a combination of absorption waveforms B and c, or absorption waveforms b and C, it is possible to achieve an excellent level of suppression of ambient light reflection and suppression of brightness reduction.

[0021] In particular, the light-absorbing portion exhibits an absorption spectrum that has a negative correlation with the emission spectrum exhibited by the light-emitting portion, and from the viewpoint of bringing out the original color of the image of the display device of the present invention, it is preferable that the dyes A, B, C, and D included in the light-absorbing portion be a combination of at least two types, including at least dye B or dye C; more preferably a combination of at least three types, including at least dye B or dye C; and even more preferably containing all four types. In this paragraph, the types of dyes are counted as one type each for dyes A, B, C, and D. For example, even if the light-absorbing portion contains two types of dyes corresponding to dye A, the light-absorbing portion is counted as containing only one type of dye, dye A, from dyes A to D. In other words, the light absorbing portion preferably exhibits at least two types of absorption waveforms, including at least absorption waveform B or C, among absorption waveforms A to D; more preferably exhibits at least three types of absorption waveforms, including at least absorption waveform B or C; and even more preferably exhibits all of absorption waveforms A to D.

[0022] In particular, from the viewpoint of bringing out the original color tones of the image of the display device of the present invention, it is preferable that the light-absorbing portion contains all four types of dyes A to D and satisfies the following relational formulas (I) to (VI). A light-absorbing portion having such a configuration can suppress external light reflection and brightness reduction, as well as maintain the original color tones of the image of the display device of the present invention at an excellent level. Relation (I): Ab(450) / Ab(430)<1.0 Relation (II) Ab(450) / Ab(500)<1.0 Relation (III) Ab(540) / Ab(500)<1.0 Relation (IV) Ab(540) / Ab(600)<1.0 Relation (V) Ab(630) / Ab(600)≦0.5 Relation (VI) Ab(630) / Ab(700)<1.0 The absorbance ratios described in the above relational equations (I) to (VI) are values ​​calculated using the absorbance Ab(λ) value at wavelength λnm, measured in the state of the light-absorbing part or the light-absorbing part with substrate, under the conditions described in the section on the absorption waveform of the light-absorbing filter in the examples described later. For preferred forms of relational equations (I) to (VI), the descriptions in paragraphs

[0016] to

[0017] of International Publication No. 2021 / 014973 can be preferably applied. In this case, wavelength selective absorption filter should be read as light absorption unit, and the original color of the image of the OLED display device should be read as the original color of the display device.

[0023] (dye A) Dye A is not particularly limited as long as it exhibits the above-mentioned absorption waveform A in the light-absorbing portion, and various dyes can be used.

[0024] As for the dye A mentioned above, a dye represented by the following general formula (A1) is preferred because its absorption waveform in the main absorption wavelength band easily satisfies the preferred range of absorption waveform A, and it can be displayed without significantly impairing the brightness of a display device having an organic electroluminescent light-emitting element or a microlight-emitting diode as the light-emitting part to which the optical member of the present invention is applied.

[0025] [ka]

[0026] In general formula (A1), R 1 and R 2each independently represents an alkyl group or an aryl group, R 3 ~R 6 each independently represents a hydrogen atom or a substituent, R 5 and R 6 may be bonded to each other to form a 6-membered ring.

[0027] R 1 and R 2 Examples of the alkyl group that can be adopted as R

[0028] and R

[0029] include both an unsubstituted alkyl group and a substituted alkyl group having a substituent, and may be either linear or branched, and may have a cyclic structure. (Substituent group A) A halogen atom, an alkyl group, a cycloalkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a cyano group, a hydroxy group, a nitro group, a carboxyl group (which may be in the form of a salt), an alkoxy group, an aryloxy group, a silyloxy group, a heterocyclic oxy group, an acyloxy group, a carbamoyloxy group, a sulfonyloxy group, an alkoxycarbonyloxy group, an aryloxycarbonyloxy group, an amino group (in addition to -NH2, a substituted amino group represented by -NR a 2 is included. R a each independently represents a hydrogen atom, an alkyl group, an aryl group or a heteroaryl group. However, at least one R aThe group is an alkyl group, an aryl group, or a heteroaryl group. This includes acylamino groups, aminocarbonylamino groups, alkylcarbonylamino groups, alkoxycarbonylamino groups, aryloxycarbonylamino groups, sulfamoylamino groups, alkylsulfonylamino groups, arylsulfonylamino groups, sulfonamide groups, mercapto groups, alkylthio groups, arylthio groups, heterocyclic thio groups, sulfamoyl groups, sulfo groups (may be in salt form), alkylsulfinyl groups, arylsulfinyl groups, alkylsulfonyl groups, arylsulfonyl groups, acyl groups, aryloxycarbonyl groups, alkoxycarbonyl groups, carbamoyl groups, imide groups, phosphino groups, phosphinyl groups, phosphinyloxy groups, phosphinylamino groups, and silyl groups, as well as monovalent groups formed by linking at least two of these groups.

[0030] Among the substituent group A described above, preferred examples of substituents that a substituted alkyl group may have include halogen atoms, aryl groups, alkoxy groups, acyl groups, and hydroxyl groups.

[0031] The total number of carbon atoms in the above-mentioned substituted alkyl group is preferably 1 to 12. Examples include benzyl group, hydroxybenzyl group, and methoxyethyl group. The total carbon number of a substituted alkyl group refers to the total number of carbon atoms in the substituted alkyl group, including any substituents it may have. The same meaning applies to other groups below.

[0032] Note, R 1 and R 2 If both represent alkyl groups, the alkyl groups may be the same or different.

[0033] R 1 and R 2 The aryl group that can be used may be either an unsubstituted aryl group or a substituted aryl group with a substituent.

[0034] The unsubstituted aryl group mentioned above is preferably an aryl group having 6 to 12 carbon atoms, for example, a phenyl group.

[0035] Examples of substituents that the above-mentioned substituted aryl group can adopt include those included in the substituent group A above. Among the substituent group A described above, preferred examples of substituents that a substituted aryl group may have include halogen atoms (e.g., chlorine atoms, bromine atoms, and iodine atoms), hydroxyl groups, carboxyl groups, sulfonamide groups, and amino groups (preferably -NR). a A substituted amino group represented by 2. a Each independently represents a hydrogen atom or an alkyl group. However, at least one R a Examples include alkyl groups (preferably with 1 to 4 carbon atoms), alkyl groups (preferably alkyl groups with 1 to 4 carbon atoms; for example, methyl, ethyl, n-propyl, and isopropyl), alkoxy groups (preferably alkoxy groups with 1 to 4 carbon atoms; for example, methoxy, ethoxy, n-propoxy, and isopropoxy), alkoxycarbonyl groups (preferably alkoxycarbonyl groups with 2 to 5 carbon atoms; for example, methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, and isopropoxycarbonyl), and sulfonyloxy groups, as well as monovalent groups formed by linking at least two of these.

[0036] The substituted aryl group is preferably an aryl group having a total of 6 to 18 carbon atoms. Examples include 4-chlorophenyl group, 2,5-dichlorophenyl group, hydroxyphenyl group, 4-carboxyphenyl group, 3,5-dicarboxyphenyl group, 4-methanesulfonamidephenyl group, 4-methylphenyl group, 4-methoxyphenyl group, 4-(2-hydroxyethoxy)phenyl group, N,N-dimethylaminophenyl group, 4-(N-carboxymethyl-N-ethylamino)phenyl group, 4-ethoxycarbonylphenyl group, and 4-methanesulfonyloxyphenyl group.

[0037] Note, R 1 and R 2 If both represent an aryl group, the aryl groups may be the same or different.

[0038] R 3 , R 4 , R 5 and R 6 Examples of substituents that can be chosen include those included in the substituent group A mentioned above. Among the substituent group A above, R 3 , R 5 and R 6 The alkyl group or aryl group is preferred. That is, R 3 , R 5 and R 6 Preferably, each of these is independently a hydrogen atom, an alkyl group, or an aryl group. Furthermore, among the substituent group A above, R 4 The alkyl group or aryl group is preferred. That is, R 4 Preferably, the element is a hydrogen atom, an alkyl group, or an aryl group.

[0039] R 3 , R 5 and R 6 The alkyl group that can be used may be an unsubstituted alkyl group or a substituted alkyl group having a substituent, and may be linear or branched, and may have a cyclic structure.

[0040] The above R 3 , R 5 and R 6 Examples of unsubstituted alkyl groups that can be used include methyl, ethyl, n-propyl, and isopropyl groups. 3 , R 5 and R 6 The number of carbon atoms in the unsubstituted alkyl group that can be used is preferably 1 to 8, and more preferably 1 to 4.

[0041] The above R 3 , R 5 and R 6 Examples of substituents that the substituted alkyl group in this can have include substituents included in the substituent group A mentioned above. The above R 3 , R 5 and R6 Preferred examples of substituents that the substituted alkyl group in this compound may have include aryl groups (preferably phenyl groups), carboxyl groups, and hydroxyl groups. The above R 3 , R 5 and R 6 The total number of carbon atoms in the substituted alkyl group that can be selected is preferably 1 to 8. Examples include the benzyl group, carboxymethyl group, and hydroxymethyl group.

[0042] Note, R 3 , R 5 and R 6 If both represent alkyl groups, the alkyl groups may be the same or different.

[0043] The above R 3 , R 5 and R 6 The aryl group that can be used as is either an unsubstituted aryl group or a substituted aryl group.

[0044] The above R 3 , R 5 and R 6 As for the unsubstituted aryl group that can be taken, an aryl group having 6 to 10 carbon atoms is preferred, for example, a phenyl group.

[0045] The above R 3 , R 5 and R 6 Examples of substituents that the substituted aryl group in this compound may have include those included in the substituent group A mentioned above. The above R 3 , R 5 and R 6 Preferred examples of substituents that the substituted aryl group in this compound may have include halogen atoms (e.g., chlorine, bromine, and iodine atoms), hydroxyl groups, carboxyl groups, and alkyl groups (preferably C1-C4 alkyl groups; for example, methyl, ethyl, n-propyl, and isopropyl).

[0046] The above R 3, R 5 and R 6 Preferred substituted aryl groups include aryl groups with a total of 6 to 10 carbon atoms. Examples include 4-chlorophenyl, 2,5-dichlorophenyl, hydroxyphenyl, carboxyphenyl, 3,5-dicarboxyphenyl, and 4-methylphenyl groups.

[0047] R 5 and R 6 If both are substituents, R 3 It is preferable that it be a hydrogen atom. Note, R 3 , R 5 and R 6 If all of them are aryl groups, the aryl groups may be the same or different.

[0048] R 4 The alkyl group that can be used may be an unsubstituted alkyl group or a substituted alkyl group having a substituent, may be linear or branched, or may have a cyclic structure.

[0049] The above R 4 Examples of unsubstituted alkyl groups that can be taken as R include methyl, ethyl, n-propyl, isopropyl, and cyclohexyl groups. 4 The number of carbon atoms in the unsubstituted alkyl group that can be used is preferably 1 to 8, and more preferably 1 to 4.

[0050] The above R 4 Examples of substituents that the substituted alkyl group in this can have include substituents included in the substituent group A mentioned above. The above R 4Preferred examples of substituents that the substituted alkyl group in the above may have include aryl groups (preferably phenyl groups), heterocyclic groups, carboxyl groups, hydroxyl groups, alkyl groups (preferably C1-C4 alkyl groups; e.g., methyl, ethyl, n-propyl, and isopropyl), alkoxy groups (preferably C1-C4 alkoxy groups; e.g., methoxy, ethoxy, n-propoxy, and isopropoxy), aryloxy groups, alkoxycarbonyl groups (preferably C2-C5 alkoxycarbonyl groups; e.g., methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, and isopropoxycarbonyl), alkylamino groups (preferably C1-C4 alkylamino groups; e.g., dimethylamino group), alkylcarbonylamino groups (preferably C1-C4 alkylcarbonylamino groups; e.g., methylcarbonylamino group), cyano groups, and acyl groups, as well as monovalent groups formed by linking at least two of these.

[0051] The above R 4 The total number of carbon atoms in the substituted alkyl group that can be selected is preferably 1 to 18. Examples include benzyl group, carboxybenzyl group, hydroxybenzyl group, methoxycarbonylethyl group, ethoxycarbonylmethyl group, 2-cyanoethyl group, 2-propionylaminoethyl group, dimethylaminomethyl group, methylcarbonylaminopropyl group, di(methoxycarbonylmethyl)aminopropyl group, and phenacyl group.

[0052] The above R 4 The aryl group that can be used may be either an unsubstituted aryl group or a substituted aryl group with a substituent.

[0053] The above R 4 As for the unsubstituted aryl group that can be taken, an aryl group having 6 to 12 carbon atoms is preferred, for example, a phenyl group.

[0054] The above R 4Examples of substituents that the substituted aryl group in this compound may have include those included in the substituent group A mentioned above. The above R 4 Preferred substituents that the substituted aryl group in this compound may have include halogen atoms (e.g., chlorine, bromine, iodine), hydroxyl groups, carboxyl groups, sulfonamide groups, amino groups, alkyl groups (preferably C1-C4 alkyl groups; e.g., methyl, ethyl, n-propyl, isopropyl), alkoxy groups (preferably C1-C4 alkoxy groups; e.g., methoxy, ethoxy, n-propoxy, isopropoxy), alkoxycarbonyl groups (preferably C2-C5 alkoxycarbonyl groups; e.g., methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, isopropoxycarbonyl), and sulfonyloxy groups, as well as monovalent groups formed by linking at least two of these groups.

[0055] The above R 4 The amino groups that a substituted aryl group in this can have are an unsubstituted amino group (-NH2) and a substituted amino group having a substituent (-NR in the substituent group A above). a Either option 2) is acceptable. The above R 4 The substituted aryl group in the amino group (-NR a 2) is R a As above, R 4 Similar groups to the substituted alkyl groups in the above can be cited. As the substituted amino group, an alkylamino group is preferred in which one or two hydrogen atoms of the amino group are substituted with an alkyl group. Examples of alkylamino groups include methylamino groups, dimethylamino groups, diethylamino groups, and pyrrolidino groups. The alkylamino group preferably has 1 to 8 carbon atoms, and more preferably 1 to 4 carbon atoms.

[0056] The above R 4As for the substituted aryl group that can be taken, aryl groups with a total of 6 to 22 carbon atoms are preferred. For example, 4-chlorophenyl group, 2,5-dichlorophenyl group, hydroxyphenyl group, 2,5-methoxyphenyl group, 2-methoxy-5-ethoxycarbonylphenyl group, 4-ethyloxycarbonylphenyl group, 4-propyloxycarbonylphenyl group, 4-butoxycarbonylphenyl group, 4-octyloxycarbonylphenyl group, 4-carboxyphenyl group, 3,5-dicarboxyphenyl group, 4-methanesulfonamidephenyl group, 4-methylphenyl group, 4-methoxyphenyl group, 4-ethoxyphenyl group, 4-(2- Examples include the hydroxyethoxy)phenyl group, N,N-dimethylaminophenyl group, N,N-diethylaminophenyl group, 4-(N-carboxymethyl-N-ethylamino)phenyl group, 4-{N,N-di(ethoxycarbonylmethyl)amino}phenyl group, 4-{di(ethoxycarbonylmethyl)amino}carbonylphenyl, 4-ethoxycarbonylphenyl group, 4-methanesulfonyloxyphenyl group, 4-acetylsulfamoylphenyl, 4-propionylsulfamoylphenyl, and 4-methanesulfonamidephenyl.

[0057] R 5 and R 6 These may be bonded to each other to form a six-membered ring. R 5 and R 6 The six-membered ring formed by the bonding of these elements is preferably a benzene ring.

[0058] In particular, from the viewpoint of lightfastness, R in general formula (A1) 1 and R 2 Of these, R 1 It is preferable that R is an alkyl group, 1 is an alkyl group, and R 2 It is more preferable that R is an alkyl group or an aryl group. Also from a similar viewpoint, 1 and R 2 It is even more preferable that each of these is an alkyl group, and it is particularly preferable that they are alkyl groups having 1 to 8 carbon atoms.

[0059] Furthermore, in terms of heat resistance and light resistance, R in general formula (A1) 1 and R 2 It is also preferable that all of them are aryl groups. R 1 and R 2 When each of these independently represents an aryl group, R 3 , R 5 and R 6 Each of these is independently a hydrogen atom, an alkyl group, or an aryl group, and R 3 and R 6 Preferably, at least one of them is a hydrogen atom. In particular, R is preferred from the viewpoint of heat resistance and light resistance. 3 represents a hydrogen atom, R 5 and R 6 It is more preferable that each independently represents an alkyl group or an aryl group, 3 represents a hydrogen atom, R 5 and R 6 It is even more preferable that each of them independently represents an alkyl group, 3 represents a hydrogen atom, R 5 and R 6 Each of them independently represents an alkyl group, and R 5 and R 6 It is particularly preferable that the elements are bonded to each other to form a ring which is condensed with the pyrrole ring, and together with the pyrrole ring, an indole ring is formed. That is, it is particularly preferable that the dye represented by the above general formula (A1) is the dye represented by the following general formula (A2).

[0060] [ka]

[0061] In general formula (A2), R 1 ~R 4 R in general formula (A1) 1 ~R 4 These are synonymous, and the same applies to the preferred form.

[0062] In general formula (A2), R 15 R indicates a substituent. 15Examples of substituents that can be chosen include those included in the above-mentioned substituent group A. 15 Preferred members include alkyl groups, aryl groups, halogen atoms, acyl groups, or alkoxycarbonyl groups. R 15 The alkyl and aryl groups that can be taken as are R 3 , R 5 and R 6 These are synonymous with alkyl and aryl groups, respectively, and the preferred embodiments are the same for each. R 15 Examples of halogen atoms that can be used include chlorine, bromine, and iodine atoms. R 15 Examples of acyl groups that can be used include acetyl, propionyl, and butyroyl groups. R 15 The alkoxycarbonyl groups that can be selected are preferably alkoxycarbonyl groups having 2 to 5 carbon atoms, such as methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, and isopropoxycarbonyl.

[0063] n is an integer between 0 and 4. While n is not particularly restricted, 0 or 1 are preferred, for example.

[0064] The following are specific examples of dyes represented by general formula (A1). However, the present invention is not limited to these. In the specific example below, Me represents a methyl group.

[0065] [ka]

[0066] [ka]

[0067] [ka]

[0068] As dye A, in addition to the dye represented by general formula (A1) or (A2), the compounds described in paragraphs

[0012] to

[0067] of Japanese Patent Publication No. 5-53241 and the compounds described in paragraphs

[0011] to

[0076] of Japanese Patent Publication No. 2707371 can also be preferably used.

[0069] (Dye B, Dye C) Dye B is not particularly limited as long as it exhibits the above-mentioned absorption waveform B in the light-absorbing portion, and various dyes can be used. Furthermore, the dye C is not particularly limited as long as it exhibits the above-mentioned absorption waveform C in the light-absorbing portion, and various dyes can be used.

[0070] Specific examples of dye B include pyrrole methine (PM), rhodamine (RH), boron dipyrromethene (BODIPY), and squarine (SQ) dyes. Specific examples of dye C include, for instance, tetraaza porphyrin (TAP), squaline, and cyanine (CY) pigments (dyes).

[0071] Among these, squalin-based dyes are preferred as dyes B and C above, because their absorption waveforms in the main absorption wavelength band tend to satisfy the preferred range of absorption waveform B or C, and squalin-based dyes represented by the following general formula (1) are more preferred. By using dyes that satisfy the above absorption waveforms B and C as dyes B and C, it is possible to display information without significantly impairing the brightness of a display device having an organic electroluminescent light-emitting element or a microlight-emitting diode as the light-emitting part, while satisfying the effect of suppressing external light reflection. In other words, from the viewpoint of achieving a better level of both suppression of external light reflection and suppression of brightness reduction, it is preferable that at least one of dye B and dye C is a squalin-based dye (preferably a squalin-based dye represented by the following general formula (1)), and it is more preferable that both dye B and dye C are squalin-based dyes (preferably a squalin-based dye represented by the following general formula (1)). In the present invention, in the dyes represented by the following general formulas, the cations are delocalized and multiple tautomer structures exist. Therefore, in the present invention, if at least one tautomer structure of a certain dye corresponds to each general formula, then that dye is a dye represented by each general formula. Thus, a dye represented by a specific general formula can also be said to be a dye whose at least one tautomer structure can be represented by that specific general formula. In the present invention, a dye represented by a general formula may take any tautomer structure, as long as at least one of its tautomer structures corresponds to this general formula.

[0072] [ka]

[0073] In general formula (1), A and B each independently represent an optionally substituted aryl group, an optionally substituted heterocyclic group, or -CH=G. G represents an optionally substituted heterocyclic group.

[0074] The aryl group that can be taken as A or B is not particularly limited and may be a monocyclic group or a fused ring group. The number of carbon atoms in the aryl group is preferably 6 to 30, more preferably 6 to 20, and even more preferably 6 to 12. Examples of aryl groups include groups consisting of a benzene ring or a naphthalene ring, and more preferably a group consisting of a benzene ring.

[0075] There are no particular restrictions on the heterocyclic group that can be taken as A or B, and it includes groups consisting of aliphatic heterocyclic or aromatic heterocyclic groups, with groups consisting of aromatic heterocyclic groups being preferred. Examples of heteroaryl groups that are aromatic heterocyclic groups include the heteroaryl group that can be taken as substituent X described later. The aromatic heterocyclic group that can be taken as A or B is preferably a 5-membered ring or a 6-membered ring, and more preferably a nitrogen-containing 5-membered ring. Specifically, groups consisting of any of the pyrrole ring, furan ring, thiophene ring, imidazole ring, pyrazole ring, thiazole ring, oxazole ring, triazole ring, indole ring, indorenine ring, indoline ring, pyridine ring, pyrimidine ring, quinoline ring, benzothiazole ring, benzoxazole ring, and pyrazolotriazole ring are preferred. Among these, groups consisting of any of the pyrrole ring, pyrazole ring, thiazole ring, pyridine ring, pyrimidine ring, and pyrazolotriazole ring are preferred. A pyrazolotriazole ring is a fused ring consisting of a pyrazole ring and a triazole ring, and any fused ring formed by the fusion of at least one of these rings is acceptable. Examples include the fused rings in general formulas (4) and (5) described later.

[0076] A and B may be bonded to the squalate moiety (the four-membered ring shown in general formula (1)) at any moiety (ring constituent atom) without any particular restrictions, but it is preferable that they be bonded at a carbon atom.

[0077] In -CH=G, which can be taken as A or B, G represents a heterocyclic group which may have substituents, and examples of which are shown above as heterocyclic groups that can be taken as A or B are preferred. Among these, a group consisting of any of a benzoxazole ring, a benzothiazole ring, or an indoline ring is preferred.

[0078] At least one of A and B may have a hydrogen bonding group that forms an intramolecular hydrogen bond. A, B, and G may each have substituent X, and if substituent X is present, adjacent substituents may bond to each other to form a ring structure. Furthermore, there may be multiple substituent X molecules. Examples of substituent X include the following groups. Alkyl alkyl groups (preferably with 1 to 20 carbon atoms, more preferably 1 to 15, and even more preferably 1 to 8 carbon atoms. For example, methyl, ethyl, propyl, isopropyl, butyl, t-butyl, isobutyl, pentyl, hexyl, octyl, dodecyl, trifluoromethyl, cyclopentyl, cyclohexyl, etc.), Alkenyl group (preferably 2 to 20 carbon atoms, more preferably 2 to 12, and even more preferably 2 to 8 carbon atoms; for example, vinyl, allyl, etc.), Alkynyl group (preferably with 2 to 40 carbon atoms, more preferably 2 to 30, and particularly preferably 2 to 25 carbon atoms. For example, ethynyl, propargyl, etc.) Aryl group (preferably with 6 to 30 carbon atoms, more preferably 6 to 20, and even more preferably 6 to 12 carbon atoms. For example, phenyl, naphthyl, etc.) Heterocyclic groups (including aromatic heterocyclic groups and aliphatic heterocyclic groups; including groups consisting of monocyclic or fused rings, preferably monocyclic or fused rings with 2 to 8 rings, more preferably monocyclic or fused rings with 2 to 4 rings. The number of heteroatoms constituting the ring is preferably 1 to 3, and examples of heteroatoms constituting the ring include nitrogen atoms, oxygen atoms, or sulfur atoms, and groups consisting of 5-membered or 6-membered rings are preferred. The number of carbon atoms constituting the ring of a heteroaryl group is preferably 3 to 30, more preferably 3 to 18, and even more preferably 3 to 12. For example, furyl, thienyl, pyridyl, pyridazyl, pyrimidyl, pyrazyl, triazyl, imidazolyl, pyrazolyl, thiazolyl, benzimidazolyl, benzoxazolyl, quinazolyl, phthalazyl, pyrrolidyl, imidazolidyl, morpholyl, oxazolidyl, etc.) Aralkyl group (the alkyl portion of the aralkyl group is the same as the alkyl group described above. The aryl portion of the aralkyl group is the same as the aryl group described above. The number of carbon atoms in the aralkyl group is preferably 7 to 40, more preferably 7 to 30, and even more preferably 7 to 25.) Ferrocenyl group, -OR 10(For example, hydroxyl groups, alkoxy groups (methoxy, ethoxy, propyloxy, etc.), cycloalkoxy groups (cyclopentyloxy, cyclohexyloxy, etc.), aryloxy groups (phenoxy, naphthyloxy, etc.), and heteroaryloxy groups (aromatic heterocyclic oxy groups) are examples.) -C(=O)R 11 (Examples of acyl groups include acetyl, ethylcarbonyl, propylcarbonyl, cyclohexylcarbonyl, octylcarbonyl, 2-ethylhexylcarbonyl, phenylcarbonyl, naphthylcarbonyl, and pyridylcarbonyl.) -C(=O)OR 12 (For example, carboxyl groups, alkoxycarbonyl groups (methyloxycarbonyl, ethyloxycarbonyl, butyloxycarbonyl, octyloxycarbonyl, etc.), and aryloxycarbonyl groups (phenyloxycarbonyl, naphthyloxycarbonyl, etc.) are examples.) -OC(=O)R 13 (Examples of acyloxy groups include acetyloxy, ethylcarbonyloxy, butylcarbonyloxy, octylcarbonyloxy, and phenylcarbonyloxy.) -NR 14 R 15 (Examples of amino groups include amino(-NH2), ethylamino, dimethylamino, butylamino, dibutylamino, cyclopentylamino, 2-ethylhexylamino, dodecylamino, anilino, naphthylamino, and 2-pyridylamino.) -NHCOR 16 (Examples of amide groups include methylcarbonylamino, ethylcarbonylamino, dimethylcarbonylamino, propylcarbonylamino, pentylcarbonylamino, cyclohexylcarbonylamino, 2-ethylhexylcarbonylamino, octylcarbonylamino, dodecylcarbonylamino, phenylcarbonylamino, and naphthylcarbonylamino.) -CONR 17 R 18(Examples of carbamoyl groups include aminocarbonyl, methylaminocarbonyl, dimethylaminocarbonyl, propylaminocarbonyl, pentylaminocarbonyl, cyclohexylaminocarbonyl, octylaminocarbonyl, 2-ethylhexylaminocarbonyl, dodecylaminocarbonyl, phenylaminocarbonyl, naphthylaminocarbonyl, and 2-pyridylaminocarbonyl.) -NHCONR 19 R 20 (Examples of ureid groups include methyl ureid, ethyl ureid, pentyl ureid, cyclohexyl ureid, octyl ureid, dodecyl ureid, phenyl ureid, naphthyl ureid, and 2-pyridylaminoureid.) -NHCOOR 21 , -SR 22 (For example, alkylthio groups (methylthio, ethylthio, propylthio, etc.), cycloalkylthio groups (cyclopentylthio, cyclohexylthio, etc.), arylthio groups (phenylthio, naphthylthio, etc.), and heteroarylthio groups (aromatic heterocyclic thio groups) are examples.) -SO2R 23 (For example, alkylsulfonyl groups (methylsulfonyl, ethylsulfonyl, butylsulfonyl, cyclohexylsulfonyl, 2-ethylhexylsulfonyl, etc.) and arylsulfonyl groups (phenylsulfonyl, naphthylsulfonyl, 2-pyridylsulfonyl, etc.) are examples.) -OSO2R 24 (Examples include alkylsulfonyloxy groups such as methanesulfonyloxy.) -NHSO2R 25 (Examples of sulfonilamide groups include methylsulfonylamino, octylsulfonylamino, 2-ethylhexylsulfonylamino, and trifluoromethylsulfonylamino.) -SO2NR 26 R 27(Examples of sulfamoyl groups include aminosulfonyl, methylaminosulfonyl, dimethylaminosulfonyl, butylaminosulfonyl, cyclohexylaminosulfonyl, octylaminosulfonyl, phenylaminosulfonyl, and 2-pyridylaminosulfonyl.) -P(=O)(OR 28 )2 (Examples of phosphoryl groups include dimethoxyphosphoryl and diphenylphosphoryl.) Halogen atoms (fluorine atoms, chlorine atoms, bromine atoms, and iodine atoms), Cyano group, Nitro group. Furthermore, in addition to the ferrocenyl group described above, substituent X may also preferably have an electron-transfer type colorfastness inhibitor portion, as described later.

[0079] Note that the above R 10 ~R 28 Each of these independently represents a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclic group. 10 ~R 28 The aliphatic and aromatic groups that can be taken as substituent X are not particularly limited, and can be appropriately selected from alkyl groups, alkenyl groups, and alkynyl groups, which are classified as aliphatic groups, and aryl groups, which are classified as aromatic groups, among the substituents that can be taken as substituent X. 10 ~R 28 The heterocyclic group that can be chosen as substituent X may be aliphatic or aromatic, and can be appropriately selected from the heterocyclic groups (aromatic heterocyclic group or aliphatic heterocyclic group) that can be chosen as substituent X. The alkyl group, alkenyl group, and alkynyl group that can be taken as the substituent X may each be linear, branched, or cyclic, with linear or branched being preferred. Note -COOR 12 R 12 If it is a hydrogen atom (i.e., a carboxyl group), the hydrogen atom may dissociate (i.e., a carbonate group), and it may be in the form of a salt. Also, -SO3R 24 R 24 If the atom is a hydrogen atom (i.e., a sulfo group), the hydrogen atom may dissociate (i.e., a sulfonate group), or it may be in the form of a salt.

[0080] The substituent that can be taken as substituent X may have further substituents. Examples of substituents that may have further substituents include the above substituent X. Furthermore, when adjacent substituents X bond to each other to form a ring structure, the two substituents X may form a ring with a heteroatom such as a boron atom in between. This boron atom may be further substituted with substituents such as alkyl groups and aryl groups. An example of a ring formed by the bonding of two substituents X is, for example, two -NR groups. 14 R 15 A ring formed by the bonding of two -NR 14 R 15 Examples include rings formed by bonding with a boron atom in between. The size of the formed ring is not particularly limited, but it is preferably a 5-membered or 6-membered ring. The number of rings formed is also not particularly limited and may be one or two or more.

[0081] The ferrocenyl group that can be taken as substituent X is preferably represented by the general formula (2M).

[0082] [ka]

[0083] In general formula (2M), L represents a single bond or a divalent linking group that is not conjugated with A, B, or G in general formula (1). 1m ~R 9m Each of the above represents a hydrogen atom or a substituent. M is an atom that can constitute a metallocene compound and represents Fe, Co, Ni, Ti, Cu, Zn, Zr, Cr, Mo, Os, Mn, Ru, Sn, Pd, Rh, V, or Pt. * indicates a bond with A, B, or G. In this invention, when L in general formula (2M) is a single bond, the cyclopentadienyl ring (R in general formula (2M)) is directly bonded to A, B, or G. 1m A ring containing ( ) is not included in the conjugated structure conjugated with A, B, or G.

[0084] The divalent linking group that can be taken as L is not particularly limited as long as it is a linking group that is not conjugated with A, B, or G, and may contain the above-mentioned conjugated structure inside or at the cyclopentadiene ring end in general formula (2M). Examples of divalent linking groups include alkylene groups having 1 to 20 carbon atoms, arylene groups having 6 to 20 carbon atoms, divalent heterocyclic groups obtained by removing two hydrogen atoms from a heterocycle, -CH=CH-, -CO-, -CS-, -NR- (where R represents a hydrogen atom or a monovalent substituent), -O-, -S-, -SO2- or -N=CH-, or divalent linking groups obtained by combining multiple (preferably 2 to 6) of these. Preferably, the linking group is a divalent linking group formed by combining two or more (preferably 2 to 6) groups selected from the group consisting of an alkylene group having 1 to 8 carbon atoms, an arylene group having 6 to 12 carbon atoms, a group selected from the group consisting of -CH=CH-, -CO-, -NR- (R is as described above), -O-, -S-, -SO2-, and -N=CH-, and particularly preferably, a linking group formed by combining an alkylene group having 1 to 4 carbon atoms, a phenylene group, a group selected from the group consisting of -CO-, -NH-, -O-, and -SO2-, or two or more (preferably 2 to 6) groups selected from this group. The combined divalent linking groups are not particularly limited, but groups containing -CO-, -NH-, -O-, or -SO2- are preferred. Examples include linking groups formed by combining two or more of -CO-, -NH-, -O-, or -SO2-, or linking groups formed by combining at least one of -CO-, -NH-, -O-, and -SO2- with an alkylene group or an arylene group. Examples of linking groups formed by combining two or more of -CO-, -NH-, -O-, or -SO2- include -COO-, -OCO-, -CONH-, -NHCOO-, -NHCONH-, and -SO2NH-. Examples of linking groups formed by combining at least one of -CO-, -NH-, -O-, and -SO2- with an alkylene group or an arylene group include groups formed by combining -CO-, -COO-, or -CONH- with an alkylene group or an arylene group. The substituents that can be taken as R are not particularly limited and are synonymous with substituent X described above.

[0085] L is preferably a single bond, or a group selected from the group consisting of alkylene groups having 1 to 8 carbon atoms, arylene groups having 6 to 12 carbon atoms, -CH=CH-, -CO-, -NR- (R is as described above), -O-, -S-, -SO2-, and -N=CH-, or a combination of two or more groups selected from this group.

[0086] L may have one or more substituents. The substituents that L may have are not particularly limited and are, for example, synonymous with substituent X described above. If L has multiple substituents, substituents bonded to adjacent atoms may bond to each other to further form a ring structure.

[0087] The alkylene group that can be taken as L can be any group with 1 to 20 carbon atoms, whether linear, branched, or cyclic, for example, methylene, ethylene, propylene, methylethylene, methylmethylene, dimethylmethylene, 1,1-dimethylethylene, butylene, 1-methylpropylene, 2-methylpropylene, 1,2-dimethylpropylene, 1,3-dimethylpropylene, 1-methylbutylene, 2-methylbutylene, 3-methylbutylene, 4-methylbutylene, 2,4-dimethylbutylene, 1,3-dimethylbutylene, pentylene, Examples include hexylene, heptylene, octylene, ethane-1,1-diyl, propane-2,2-diyl, cyclopropane-1,1-diyl, cyclopropane-1,2-diyl, cyclobutane-1,1-diyl, cyclobutane-1,2-diyl, cyclopentane-1,1-diyl, cyclopentane-1,2-diyl, cyclopentane-1,3-diyl, cyclohexane-1,1-diyl, cyclohexane-1,2-diyl, cyclohexane-1,3-diyl, cyclohexane-1,4-diyl, and methylcyclohexane-1,4-diyl. When L is a linking group that includes at least one of -CO-, -CS-, -NR- (R is as described above), -O-, -S-, -SO2-, and -N=CH- in the alkylene group, groups such as -CO- may be incorporated at any position in the alkylene group, and there is no particular limit on the number of groups incorporated.

[0088] The arylene group that can be taken as L is not particularly limited as long as it has 6 to 20 carbon atoms. For example, groups obtained by removing one more hydrogen atom from each of the aryl groups with 6 to 20 carbon atoms that can be taken as A in general formula (1) are included. There are no particular restrictions on the heterocyclic groups that can be taken as L. For example, groups obtained by removing one more hydrogen atom from each of the heterocyclic groups exemplified above that can be taken as A are included.

[0089] In general formula (2M), the remaining substructure after removing the linking group L corresponds to a structure obtained by removing one hydrogen atom from a metallocene compound (metallocene structure portion). In the present invention, the metallocene compound that becomes the metallocene structure portion can be any known metallocene compound without particular limitation, as long as it is a compound that conforms to the substructure defined by general formula (2M) above (a compound in which a hydrogen atom is bonded in place of L). The metallocene structure portion defined by general formula (2M) will be described in detail below.

[0090] In general formula (2M), R 1m ~R 9m Each of these represents a hydrogen atom or a substituent. 1m ~R 9m There are no particular restrictions on the substituents that can be taken as substituent X, but for example, they can be selected from among the substituents that can be taken as substituent X above. 1m ~R 9m Each of these is preferably a hydrogen atom, a halogen atom, an alkyl group, an acyl group, an alkoxy group, an amino group, or an amide group; more preferably a hydrogen atom, a halogen atom, an alkyl group, an acyl group, or an alkoxy group; even more preferably a hydrogen atom, a halogen atom, an alkyl group, or an acyl group; particularly preferably a hydrogen atom, a halogen atom, or an alkyl group; and most preferably a hydrogen atom.

[0091] R 1m ~R 9mAmong the alkyl groups that can be selected as substituent X, alkyl groups having 1 to 8 carbon atoms are preferred, for example, methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, tert-butyl, isobutyl, pentyl, tert-pentyl, hexyl, octyl, and 2-ethylhexyl. This alkyl group may have a halogen atom as a substituent. Examples of alkyl groups substituted with halogen atoms include chloromethyl, dichloromethyl, trichloromethyl, bromomethyl, dibromomethyl, tribromomethyl, fluoromethyl, difluoromethyl, trifluoromethyl, 2,2,2-trifluoroethyl, perfluoroethyl, perfluoropropyl, and perfluorobutyl. Also, R 1m The alkyl groups that can be selected as such may have at least one methylene group forming the carbon chain substituted with -O- or -CO-. Examples of alkyl groups in which the methylene group is substituted with -O- include methoxy, ethoxy, propoxy, isopropoxy, butoxy, tertiary butoxy, 2-methoxyethoxy, chloromethyloxy, dichloromethyloxy, trichloromethyloxy, bromomethyloxy, dibromomethyloxy, tribromomethyloxy, fluoromethyloxy, difluoromethyloxy, trifluoromethyloxy, 2,2,2-trifluoroethyloxy, perfluoroethyloxy, perfluoropropyloxy, and perfluorobutyloxy alkyl groups in which the end methylene groups are substituted, as well as alkyl groups in which the internal methylene groups of the carbon chain, such as 2-methoxyethyl, are substituted. Examples of alkyl groups in which the methylene group is substituted with -CO- include acetyl, propionyl, monochloroacetyl, dichloroacetyl, trichloroacetyl, trifluoroacetyl, propan-2-on-1-yl, and butan-2-on-1-yl.

[0092] In the general formula (2M), M is an atom that can constitute a metallocene compound, and represents Fe, Co, Ni, Ti, Cu, Zn, Zr, Cr, Mo, Os, Mn, Ru, Sn, Pd, Rh, V, or Pt. Among these, M is preferably Fe, Ti, Co, Ni, Zr, Ru, or Os, more preferably Fe, Ti, Ni, Ru, or Os, even more preferably Fe or Ti, and most preferably Fe.

[0093] The groups represented by the general formula (2M) are L and R. 1m ~R 9m A group formed by combining preferred elements of M is preferred, for example, L may be a single bond, or a group selected from the group consisting of alkylene groups having 2 to 8 carbon atoms, arylene groups having 6 to 12 carbon atoms, -CH=CH-, -CO-, -NR- (R is as described above), -O-, -S-, -SO2-, and -N=CH-, or a group formed by combining two or more groups selected from this group, and R 1m ~R 9m Examples include groups formed by combining a hydrogen atom, a halogen atom, an alkyl group, an acyl group, or an alkoxy group with Fe as M.

[0094] The substituent X can be an alkyl group, alkenyl group, alkynyl group, aralkyl group, aryl group and heteroaryl group, and R 10 ~R 28The aliphatic group, aromatic group, and heterocyclic group that can be selected may each have further substituents or may be unsubstituted. There are no particular restrictions on the substituents that may be further present, but substituents selected from alkyl groups, aryl groups, amino groups, alkoxy groups, aryloxy groups, aromatic heterocyclic oxy groups, acyl groups, alkoxycarbonyl groups, aryloxycarbonyl groups, acyloxy groups, acylamino groups, alkoxycarbonylamino groups, aryloxycarbonylamino groups, sulfonylamino groups, alkylthio groups, arylthio groups, aromatic heterocyclic thio groups, sulfonyl groups, ferrocenyl groups, hydroxyl groups, mercapto groups, halogen atoms, cyano groups, sulfo groups, and carboxyl groups are preferred, and substituents selected from alkyl groups, aryl groups, alkoxy groups, aryloxy groups, aromatic heterocyclic oxy groups, acyl groups, alkoxycarbonyl groups, aryloxycarbonyl groups, acyloxy groups, alkylthio groups, arylthio groups, aromatic heterocyclic thio groups, sulfonyl groups, ferrocenyl groups, hydroxyl groups, mercapto groups, halogen atoms, cyano groups, sulfo groups, and carboxyl groups are more preferred. These groups can be appropriately selected from the substituents that can be taken as substituent X above.

[0095] One preferred embodiment of the dye represented by the above general formula (1) is the dye represented by the following general formula (2).

[0096] [ka]

[0097] In general formula (2), A 1 This is the same as A in general formula (1). Among these, a heterocyclic group that is a nitrogen-containing five-membered ring is preferred.

[0098] In general formula (2), R 1 and R 2 Each of these independently represents a hydrogen atom or a substituent. 1 and R 2 These elements may be identical or different, and they may also be joined together to form a ring. R 1 and R 2 There are no particular restrictions on the substituents that can be taken as such, but for example, the substituents that can be taken as substituent X above are listed below. Among these, alkyl groups, alkenyl groups, aryl groups, or heteroaryl groups are preferred, alkyl groups, aryl groups, or heteroaryl groups are more preferred, and alkyl groups are even more preferred.

[0099] R 1 and R 2 The substituents that can be chosen may have further substituents. Examples of substituents that may have further substituents include the substituent X mentioned above. Also, R 1 and R 2 These may bond with each other to form a ring, R 1 or R 2 And, B 2 or B 3 The substituents on may bond to form a ring. The ring formed at this time is preferably a heterocycle or a heteroaryl ring, and the size of the formed ring is not particularly limited, but it is preferably a 5-membered ring or a 6-membered ring. Also, the number of rings formed is not particularly limited, and there may be one or two or more. An example of a form in which two or more rings are formed is R 1 and B 2 The substituents that R has, and 2 and B 3 One possible configuration is one in which the substituents on each component bond to each other to form two rings.

[0100] In general formula (2), B 1 B 2 B 3 and B 4 Each of these independently represents either a carbon atom or a nitrogen atom. 1 B 2 B 3 and B 4 The ring containing B is an aromatic ring. 1 ~B 4 Preferably, at least two of them are carbon atoms, B 1 ~B 4It is more preferable that all of them are carbon atoms. B 1 ~B 4 The carbon atoms that can be taken as are hydrogen atoms or substituents. 1 ~B 4 The number of substituted carbon atoms among the carbon atoms that can be taken as is not particularly limited, but it is preferably 0, 1, or 2, and more preferably 1. In particular, B 1 and B 4 Preferably, the atom is a carbon atom, and at least one of them has a substituent. B 1 ~B 4 The substituents that can be taken as carbon atoms are not particularly limited, and the above substituent X is an example. Preferably, alkyl groups, alkoxy groups, alkoxycarbonyl groups, aryl groups, acyl groups, amide groups, sulfonylamide groups, carbamoyl groups, alkylsulfonyl groups, arylsulfonyl groups, amino groups, cyano groups, nitro groups, halogen atoms, or hydroxyl groups, and more preferably alkyl groups, alkoxy groups, alkoxycarbonyl groups, aryl groups, acyl groups, amide groups, sulfonylamide groups, carbamoyl groups, amino groups, cyano groups, nitro groups, halogen atoms, or hydroxyl groups. B 1 ~B 4 The substituents on the carbon atom that can be selected may have further substituents. Examples of these further substituents include the substituent X mentioned above.

[0101] B 1 and B 4 The substituents that can be taken from the carbon atom are more preferably alkyl groups, alkoxy groups, hydroxyl groups, amide groups, sulfonylamide groups, or carbamoyl groups, particularly preferably alkyl groups, alkoxy groups, hydroxyl groups, amide groups, or sulfonylamide groups, and most preferably hydroxyl groups, amide groups, or sulfonylamide groups. B 2 and B 3The substituents that can be taken from the carbon atom are more preferably alkyl groups, alkoxy groups, alkoxycarbonyl groups, acyl groups, amino groups, cyano groups, nitro groups, or halogen atoms, and it is particularly preferable that one of the substituents is an electron-withdrawing group (for example, an alkoxycarbonyl group, acyl group, cyano group, nitro group, or halogen atom).

[0102] The dye represented by the above general formula (2) is preferably a dye represented by any of the following general formulas (3), (4), and (5).

[0103] [ka]

[0104] In general formula (3), R 1 and R 2 Each of these independently represents a hydrogen atom or a substituent, and R in the above general formula (2) 1 and R 2 It is synonymous with the same thing, and the preferred range is also the same. In general formula (3), B 1 ~B 4 Each of these independently represents a carbon atom or a nitrogen atom, and B in the above general formula (2) 1 ~B 4 It is synonymous with the same thing, and the preferred range is also the same.

[0105] In general formula (3), R 3 and R 4 Each of these independently represents a hydrogen atom or a substituent. 3 and R 4 The substituents that can be taken are not particularly limited, and the above R 1 and R 2 The same substituents that can be adopted can be listed. However, R 3The substituents that can be taken are preferably alkyl groups, alkoxy groups, amino groups, amide groups, sulfonylamide groups, cyano groups, nitro groups, aryl groups, heteroaryl groups, heterocyclic groups, alkoxycarbonyl groups, carbamoyl groups, or halogen atoms, more preferably alkyl groups, aryl groups, or amino groups, and even more preferably alkyl groups. R 4 Preferred substituents include alkyl groups, aryl groups, heteroaryl groups, heterocyclic groups, alkoxy groups, alkoxycarbonyl groups, acyl groups, acyloxy groups, amide groups, carbamoyl groups, amino groups, or cyano groups; more preferably alkyl groups, alkoxycarbonyl groups, acyl groups, carbamoyl groups, or aryl groups; and even more preferably alkyl groups.

[0106] R 3 and R 4 The alkyl group that can be used may be linear, branched, or cyclic, but linear or branched is preferred. The number of carbon atoms in the alkyl group is preferably 1 to 12, and more preferably 1 to 8. Examples of alkyl groups include methyl, ethyl, n-propyl, isopropyl, t-butyl, 2-ethylhexyl, and cyclohexyl groups, with methyl and t-butyl groups being more preferred.

[0107] [ka]

[0108] In general formula (4), R 1 and R 2 Each of these independently represents a hydrogen atom or a substituent, and R in the above general formula (2) 1 and R 2 It is synonymous with the same thing, and the preferred range is also the same. In general formula (4), B 1 ~B 4 Each of these independently represents a carbon atom or a nitrogen atom, and B in the above general formula (2) 1 ~B 4 It is synonymous with the same thing, and the preferred range is also the same.

[0109] In general formula (4), R 5 and R 6 Each of these independently represents a hydrogen atom or a substituent. 5 and R 6 The substituents that can be taken are not particularly limited, and the above R 1 and R 2 The same substituents that can be adopted can be listed. However, R 5 The substituents that can be taken are preferably alkyl groups, alkoxy groups, aryloxy groups, amino groups, cyano groups, aryl groups, heteroaryl groups, heterocyclic groups, acyl groups, acyloxy groups, amide groups, sulfonylamide groups, ureido groups, or carbamoyl groups, more preferably alkyl groups, alkoxy groups, acyl groups, amide groups, or amino groups, and even more preferably alkyl groups. R 5 The alkyl group that can be taken as is R in general formula (3). 3 This is synonymous with the alkyl group that can be adopted, and the preferred range is also the same.

[0110] In general formula (4), R 6 The substituents that can be taken as are preferably alkyl groups, alkenyl groups, aryl groups, heteroaryl groups, heterocyclic groups, alkoxy groups, cycloalkoxy groups, aryloxy groups, alkoxycarbonyl groups, acyl groups, acyloxy groups, amide groups, sulfonylamide groups, alkylsulfonyl groups, arylsulfonyl groups, carbamoyl groups, amino groups, cyano groups, nitro groups, or halogen atoms, more preferably alkyl groups, aryl groups, heteroaryl groups, or heterocyclic groups, and even more preferably alkyl groups or aryl groups. R 6 The alkyl group that can be taken as is R in general formula (3). 4 This is synonymous with the alkyl group that can be adopted, and the preferred range is also the same. R 6The aryl group that can be used is preferably an aryl group having 6 to 12 carbon atoms, and more preferably a phenyl group. This aryl group may have substituents, and examples of such substitutions include groups included in the following substituent group A, with alkyl groups having 1 to 10 carbon atoms, sulfonyl groups, amino groups, acylamino groups, sulfonylamino groups, etc., being particularly preferred. These substituents may have further substituents. Specifically, alkylsulfonylamino groups are preferred substituents.

[0111] - Substituent group A - Halogen atoms, alkyl groups, alkenyl groups, alkynyl groups, aryl groups, heterocyclic groups, cyano groups, hydroxyl groups, nitro groups, carboxyl groups, alkoxy groups, aminooxy groups, aryloxy groups, silyloxy groups, heterocyclic oxy groups, acyloxy groups, carbamoyloxy groups, amino groups, acylamino groups, aminocarbonylamino groups, alkoxycarbonylamino groups, aryloxycarbonylamino groups, sulfamoylamino groups, sulfonylamino groups (including alkyl or arylsulfonylamino groups), mercapto groups, alkylthio groups, arylthio groups, heterocyclic thio groups, sulfamoyl groups, sulfo groups, alkyl or arylsulfinyl groups, sulfonyl groups (including alkyl or arylsulfonyl groups), acyl groups, aryloxycarbonyl groups, alkoxycarbonyl groups, carbamoyl groups, aryl or heterocyclic azo groups, imide groups, phosphino groups, phosphinyl groups, phosphinyloxy groups, phosphinylamino groups, silyl groups, etc.

[0112] [ka]

[0113] In general formula (5), R 1 and R 2 Each of these independently represents a hydrogen atom or a substituent, and R in the above general formula (2) 1 and R 2 It is synonymous with the same thing, and the preferred range is also the same. In general formula (5), B 1 ~B 4Each of these independently represents a carbon atom or a nitrogen atom, and B in the above general formula (2) 1 ~B 4 It is synonymous with the same thing, and the preferred range is also the same.

[0114] In general formula (5), R 7 and R 8 Each of these independently represents a hydrogen atom or a substituent. 7 and R 8 The substituents that can be taken are not particularly limited, and the above R 1 and R 2 The same substituents that can be adopted can be listed. However, R 7 The preferred group, more preferred group, and even more preferred group of the substituent that can be taken as are R in general formula (4). 5 It is the same as the substituent that can be taken as R. 5 The alkyl groups that can be taken as are the above R 3 This is synonymous with the alkyl group that can be adopted, and the preferred range is also the same.

[0115] In general formula (5), R 8 The preferred range, more preferred range, and even more preferred range of substituents that can be taken as are R in general formula (4). 6 It is the same as the substituent that can be taken as R. 8 The preferred range of alkyl and aryl groups that can be taken as is R in the above general formula (4). 6 This is synonymous with alkyl and aryl groups that can be adopted, and the preferred range is also the same.

[0116] In the present invention, when a squalin-based dye is used as dye B or C, any squalin-based dye represented by any of the general formulas (1) to (5) can be used without particular limitation. Examples include compounds described in Japanese Patent Publication No. 2006-160618, International Publication No. 2004 / 005981, International Publication No. 2004 / 007447, Dyes and Pigment, 2001, 49, pp. 161-179, International Publication No. 2008 / 090757, International Publication No. 2005 / 121098, and Japanese Patent Publication No. 2008-275726.

[0117] The following are specific examples of dyes represented by any of the general formulas (1) to (5). However, the present invention is not limited to these. In the specific examples below, Me represents methyl, Et represents ethyl, Bu represents butyl, and Ph represents phenyl.

[0118] [ka]

[0119] [ka]

[0120] [ka]

[0121] [ka]

[0122] In addition to the examples above, specific examples of dyes represented by any of the general formulas (3) to (5) are listed below. Substituent B in the table below has the following structure. In the structure and table below, Me represents methyl, Et represents ethyl, i-Pr represents i-propyl, Bu represents n-butyl, t-Bu represents t-butyl, and Ph represents phenyl. In the structure below, * represents the bond to the four-membered carbon ring in each general formula.

[0123] [ka]

[0124] [ka]

[0125] [ka]

[0126] [ka]

[0127] [ka]

[0128] [ka]

[0129] [ka]

[0130] [ka]

[0131] [ka]

[0132] A preferred embodiment of the dye represented by the above general formula (1) is the dye represented by the following general formula (6).

[0133] [ka]

[0134] In general formula (6), R 3 and R 4 Each of these independently represents a hydrogen atom or a substituent, and R in the above general formula (3) 3 and R 4 It is synonymous with [the same thing], and the desirable ones are also the same. In general formula (6), A 2 This is the same as A in general formula (1). Among these, a heterocyclic group that is a nitrogen-containing five-membered ring is preferred.

[0135] The dye represented by the above general formula (6) is preferably a dye represented by any of the following general formulas (7), (8), and (9).

[0136] [ka]

[0137] In general formula (7), R 3 and R 4 Each of these independently represents a hydrogen atom or a substituent, and R in the above general formula (3) 3 and R 4 This is synonymous with the same preferred range. 3 and two R 4 These may be the same or different.

[0138] [ka]

[0139] In general formula (8), R 3 and R 4 Each of these independently represents a hydrogen atom or a substituent, and R in the above general formula (3) 3 It is synonymous with the same thing, and the preferred range is also the same. In general formula (8), R 5 and R 6Each of these independently represents a hydrogen atom or a substituent, and R in the above general formula (4) 5 and R 6 It is synonymous with the same thing, and the preferred range is also the same.

[0140] [ka]

[0141] In general formula (9), R 3 and R 4 Each of these independently represents a hydrogen atom or a substituent, and R in the above general formula (3) 3 It is synonymous with the same thing, and the preferred range is also the same. In general formula (9), R 7 and R 8 Each of these independently represents a hydrogen atom or a substituent, and R in the above general formula (5) 7 and R 8 It is synonymous with the same thing, and the preferred range is also the same.

[0142] In the present invention, when a squalin-based dye is used as dye B, any squalin-based dye represented by any of the general formulas (6) to (9) can be used without particular limitation. Examples include the compounds described in Japanese Patent Publication No. 2002-97383 and Japanese Patent Publication No. 2015-68945.

[0143] The following are specific examples of dyes represented by any of the general formulas (6) to (9). However, the present invention is not limited to these. In the specific examples below, Me represents methyl, Et represents ethyl, i-Pr represents i-propyl, t-Bu represents t-butyl, and Ph represents phenyl. In the structures below, * indicates the bond to the four-membered carbon ring in each general formula.

[0144] [ka]

[0145] [ka]

[0146] [ka]

[0147] [ka]

[0148] (Dye containing a light-quenching agent) The squalin-based dye represented by the above general formula (1) may also be a quencher-embedded dye in which the quencher portion is covalently bonded to the dye via a linking group. The above quencher-embedded dye can also be preferably used as at least one of dyes B and C. That is, the above quencher-embedded dye is classified as dye B or dye C depending on the wavelength having the main absorption wavelength band. Examples of the quenching agent portion include the ferrocenyl group in the substituent X described above. Furthermore, examples of the quenching agent portion in the quenching agent compounds described in paragraphs

[0199] to

[0212] and paragraphs

[0234] to

[0310] of International Publication No. 2019 / 066043 can be cited.

[0149] The following are specific examples of squalin-based dyes represented by general formula (1) that contain a quencher. However, the present invention is not limited to these examples. In the following specific examples, Me represents methyl, Et represents ethyl, and Bu represents butyl.

[0150] [ka]

[0151] [ka]

[0152]

change

[0153]

change

[0154]

change

[0155]

change

[0156]

change

[0157]

change

[0158]

change

[0159]

change

[0160]

change

[0161]

change

[0162]

change

[0163] [ka]

[0164] [ka]

[0165] [ka]

[0166] [ka]

[0167] (Dye D) The dye D is not particularly limited as long as it exhibits the above-mentioned absorption waveform D in the light-absorbing portion, and various dyes can be used. Specific examples of dye D include, for instance, porphyrin-based, squalin-based, and cyanine (CY)-based pigments (dyes).

[0168] With respect to the dye D described above, it is preferable that it is at least one of the dyes represented by the following general formula (D1) and the dye represented by the general formula (1) described later, in order to easily satisfy the preferred range of the absorption waveform D described above and to be able to display without significantly impairing the brightness of a display device having an organic electroluminescent light-emitting element or a microlight-emitting diode as a light-emitting part to which the optical member of the present invention is applied.

[0169] (A pigment represented by the general formula (D1))

[0170] [ka]

[0171] In general formula (D1), R 1A and R 2AEach independently represents an alkyl group, an aryl group, or a heteroaryl group, and R 4A and R 5A Each independently represents a heteroaryl group, and R 3A and R 6A Each of these independently represents a substituent. 1 and X 2 Each of them is independent, -BR 21a R 22a Show, R 21a and R 22a Each of these independently represents a substituent, R 21a and R 22a They may be joined to each other to form a ring.

[0172] R 1A and R 2A Each of these independently represents an alkyl group, an aryl group, or a heteroaryl group. The number of carbon atoms in the alkyl group is preferably 1 to 40. The lower limit is more preferably 3 or more, even more preferably 5 or more, even more preferably 8 or more, and particularly preferably 10 or more. The upper limit is more preferably 35 or less, and even more preferably 30 or less. The alkyl group may be linear, branched, or cyclic, but linear or branched is preferred, and branched is particularly preferred. The number of carbon atoms in the branched alkyl group is preferably 3 to 40. The lower limit is, for example, more preferably 5 or more, even more preferably 8 or more, and even more preferably 10 or more. The upper limit is more preferably 35 or less, and even more preferably 30 or less. The number of branches in the branched alkyl group is, for example, preferably 2 to 10, and more preferably 2 to 8. If the number of branches is within the above range, the solvent solubility is good. The number of carbon atoms in the aryl group is preferably 6 to 30, more preferably 6 to 20, and even more preferably 6 to 12. Among these, the phenyl group is preferred. The heteroaryl group is preferably a monocyclic or fused ring, preferably a monocyclic or fused ring with 2 to 8 fused rings, and more preferably a monocyclic or fused ring with 2 to 4 fused rings. The number of heteroatoms constituting the heteroaryl group is preferably 1 to 3. The heteroatoms constituting the heteroaryl group are preferably nitrogen, oxygen, or sulfur atoms. The number of carbon atoms in the heteroaryl group is preferably 3 to 30, more preferably 3 to 18, even more preferably 3 to 12, and particularly preferably 3 to 5. The heteroaryl group is preferably a 5-membered or 6-membered ring. Specific examples of heteroaryl groups include, for example, imidazolyl group, pyridyl group, pyrazyl group, pyrimidyl group, pyridazyl group, triazyl group, quinolyl group, quinoxalyl group, isoquinolyl group, indolenyl group, furyl group, thienyl group, benzoxazolyl group, benzimidazolyl group, benzthiazolyl group, naphthiazolyl group, m-carbazolyl group, and azepinyl group.

[0173] R 1A and R 2A The alkyl, aryl, and heteroaryl groups in the formula may have substituents or be unsubstituted. Examples of substituents that may include hydrocarbon groups containing an oxygen atom, heteroaryl groups, amino groups, acylamino groups, alkoxycarbonylamino groups, aryloxycarbonylamino groups, sulfonylamino groups, sulfamoyl groups, carbamoyl groups, alkylthio groups, arylthio groups, heteroarylthio groups, alkylsulfonyl groups, arylsulfonyl groups, sulfinyl groups, ureido groups, phosphate amide groups, mercapto groups, sulfo groups, carboxyl groups, nitro groups, hydroxamic acid groups, sulfino groups, hydrazino groups, imino groups, silyl groups, hydroxyl groups, halogen atoms, cyano groups, and the like. As for the heteroaryl group, the above R 1A and R 2A The description of heteroaryl groups in the above can be preferably applied. Examples of halogen atoms include fluorine, chlorine, bromine, and iodine. Examples of hydrocarbon groups include alkyl groups, alkenyl groups, and aryl groups. As an alkyl group, the above R 1A and R 2A The description of alkyl groups in this context can be preferably applied. The number of carbon atoms in the alkenyl group is preferably 2 to 40. The lower limit is, for example, more preferably 3 or more, even more preferably 5 or more, even more preferably 8 or more, and particularly preferably 10 or more. The upper limit is more preferably 35 or less, and even more preferably 30 or less. The alkenyl group may be linear, branched, or cyclic, but linear or branched is preferred, and branched is particularly preferred. The number of carbon atoms in the branched alkenyl group is preferably 3 to 40. The lower limit is, for example, more preferably 5 or more, even more preferably 8 or more, and even more preferably 10 or more. The upper limit is more preferably 35 or less, and even more preferably 30 or less. The number of branches in the branched alkenyl group is preferably 2 to 10, and more preferably 2 to 8. If the number of branches is within the above range, solvent solubility is good. The number of carbon atoms in the aryl group is preferably 6 to 30, more preferably 6 to 20, and even more preferably 6 to 12. Examples of hydrocarbon groups containing an oxygen atom include -LR. x1 Examples of groups represented by the following are given. L is -O-, -CO-, -COO-, -OCO-, -(OR x2 ) m -or-(R x2 O) m - represents R x1 R represents an alkyl group, an alkenyl group, or an aryl group. x2 represents an alkylene group or arylene group. m represents an integer greater than or equal to 2, and m R x2 They may be the same or they may be different. L is preferably -O-, -COO-, or -OCO-, and more preferably -O-. R x1 The alkyl group, alkenyl group, and aryl group represented by are synonymous with those described above, and the preferred range is also the same. x1 The group is preferably an alkyl group or an alkenyl group, and more preferably an alkyl group. x2The number of carbon atoms in the alkylene group represented by is preferably 1 to 20, more preferably 1 to 10, and even more preferably 1 to 5. The alkylene group may be linear, branched, or cyclic, but linear or branched is preferred. R x2 The number of carbon atoms in the arylene group represented by is preferably 6 to 20, and more preferably 6 to 12. m represents an integer greater than or equal to 2, preferably between 2 and 20, and more preferably between 2 and 10.

[0174] R 1A and R 2A The substituents that the alkyl, aryl, and heteroaryl groups in the compound may have are preferably hydrocarbon groups that may contain an oxygen atom, and more preferably hydrocarbon groups that contain an oxygen atom. Hydrocarbon groups containing an oxygen atom are -OR x1 A group represented by R is preferred. x1 The alkyl group is preferably an alkyl group or an alkenyl group, more preferably an alkyl group, and particularly preferably a branched alkyl group. That is, R 1A and R 2A The substituent represented by is preferably an alkoxy group. 1A and R 2A However, because it is an alkoxy group, it can be suitably used as dye D in the present invention as a near-infrared absorbing substance with excellent solvent solubility, lightfastness, and visible light transmittance. The number of carbon atoms in the alkoxy group is preferably 1 to 40. The lower limit is, for example, more preferably 3 or more, even more preferably 5 or more, even more preferably 8 or more, and particularly preferably 10 or more. The upper limit is more preferably 35 or less, and even more preferably 30 or less. The alkoxy group may be linear, branched, or cyclic, but linear or branched is preferred, and branched is particularly preferred. The number of carbon atoms in the branched alkoxy group is preferably 3 to 40. The lower limit is, for example, more preferably 5 or more, even more preferably 8 or more, and even more preferably 10 or more. The upper limit is more preferably 35 or less, and even more preferably 30 or less. The number of branches in the branched alkoxy group is preferably 2 to 10, and more preferably 2 to 8.

[0175] R 1A and R 2AA heteroaryl group or an aryl group is preferred, an aryl group is more preferred, and a phenyl group having a substituent at the 3-position is even more preferred.

[0176] R 3A and R 6A Each of these independently represents a substituent. Examples of substituents include alkyl groups, alkenyl groups, alkynyl groups, aryl groups, heteroaryl groups, amino groups (including alkylamino groups, arylamino groups, and heterocyclic amino groups), alkoxy groups, aryloxy groups, heteroaryloxy groups, acyl groups, alkylcarbonyl groups, arylcarbonyl groups, alkoxycarbonyl groups, aryloxycarbonyl groups, acyloxy groups, acylamino groups, alkoxycarbonylamino groups, aryloxycarbonylamino groups, sulfonylamino groups, sulfamoyl groups, carbamoyl groups, alkylthio groups, arylthio groups, heteroarylthio groups, alkylsulfonyl groups, arylsulfonyl groups, sulfinyl groups, ureido groups, phosphate amide groups, hydroxyl groups, mercapto groups, halogen atoms, cyano groups, sulfo groups, carboxyl groups, nitro groups, hydroxamic acid groups, sulfino groups, hydrazino groups, imino groups, and silyl groups.

[0177] R 3A and R 6A It is preferable that the group is an electron-withdrawing group. Substituents with a positive σp (sigma-para) value in Hammett's spectrum act as electron-withdrawing groups. In the present invention, substituents of Hammett with a σp value of 0.2 or higher can be exemplified as electron-withdrawing groups. Preferably, the σp value is 0.25 or higher, more preferably 0.3 or higher, and particularly preferably 0.35 or higher. There is no particular upper limit, but it is preferably 0.80. Specific examples of electron-withdrawing groups include cyano groups (0.66), carboxyl groups (-COOH: 0.45), alkoxycarbonyl groups (-COOMe: 0.45), aryloxycarbonyl groups (-COOPh: 0.44), carbamoyl groups (-CONH2: 0.36), alkylcarbonyl groups (-COMe: 0.50), arylcarbonyl groups (-COPh: 0.43), alkylsulfonyl groups (-SO2Me: 0.72), and arylsulfonyl groups (-SO2Ph: 0.68). Cyano groups are particularly preferred. Here, Me represents a methyl group and Ph represents a phenyl group. For Hammett's σp value, refer to paragraphs

[0024] to

[0025] of Japanese Patent Publication No. 2009-263614, for example, and this content is incorporated herein.

[0178] R 4A and R 5A Each of these independently represents a heteroaryl group. The heteroaryl group is preferably a monocyclic or fused ring, preferably a monocyclic or fused ring with 2 to 8 fused rings, and more preferably a monocyclic or fused ring with 2 to 4 fused rings. The number of heteroatoms constituting the heteroaryl group is preferably 1 to 3. The heteroatoms constituting the heteroaryl group are preferably nitrogen atoms, oxygen atoms, or sulfur atoms. The number of carbon atoms in the heteroaryl group is preferably 3 to 30, more preferably 3 to 18, even more preferably 3 to 12, and particularly preferably 3 to 5. The heteroaryl group is preferably a 5-membered or 6-membered ring. A specific example of a heteroaryl group is R 1A and R 2A The groups described above are examples, and pyridyl group, pyrimidyl group, triazyl group, quinolyl group, quinoxalyl group, isoquinolyl group, indolenyl group, benzoxazolyl group, and benzthiazolyl group are preferred. The heteroaryl group may have substituents or may be unsubstituted. Examples of substituents include alkyl groups, alkenyl groups, alkynyl groups, aryl groups, amino groups (including alkylamino groups, arylamino groups, and heterocyclic amino groups), alkoxy groups, aryloxy groups, acyl groups, alkylcarbonyl groups, arylcarbonyl groups, alkoxycarbonyl groups, aryloxycarbonyl groups, acyloxy groups, acylamino groups, alkoxycarbonylamino groups, aryloxycarbonylamino groups, sulfonylamino groups, sulfamoyl groups, carbamoyl groups, alkylthio groups, arylthio groups, heteroarylthio groups, sulfonyl groups, alkylsulfonyl groups, arylsulfonyl groups, sulfinyl groups, ureido groups, phosphate amide groups, hydroxyl groups, mercapto groups, halogen atoms, cyano groups, sulfo groups, carboxyl groups, nitro groups, hydroxamic acid groups, sulfino groups, hydrazino groups, imino groups, and silyl groups. Halogen atoms, alkyl groups, and alkoxy groups are preferred. Preferred halogen atoms include fluorine, chlorine, bromine, and iodine atoms, with chlorine atoms being particularly preferred. The alkyl group has 1 to 40 carbon atoms, more preferably 1 to 30, and particularly preferably 1 to 25. The alkyl group may be linear, branched, or cyclic, but linear or branched is preferred, and linear is particularly preferred. The number of carbon atoms in the alkoxy group is preferably 1 to 40, more preferably 1 to 30, and particularly preferably 1 to 25. The alkoxy group may be linear, branched, or cyclic, but linear or branched is preferred, and linear is particularly preferred.

[0179] R 3A and R 4A , R 5A and R 6A These elements may be joined together to form a ring. R 3A and R 4A , R 5A and R 6AWhen the elements bond to each other to form a ring, it is preferable to form a 5- to 7-membered ring (preferably a 5 or 6-membered ring). The ring formed is preferably a merocyanine dye used as an acid nucleus. Specific examples include the following: (a) 1,3-Dicarbonyl ring: e.g., 1,3-Indanedione, 1,3-Cyclohexanedione, 5,5-Dimethyl-1,3-Cyclohexanedione, 1,3-Dioxane-4,6-dione, etc. (b) Pyrazolinone rings: e.g., 1-phenyl-2-pyrazolin-5-one, 3-methyl-1-phenyl-2-pyrazolin-5-one, 1-(2-benzothiazoyl)-3-methyl-2-pyrazolin-5-one, etc. (c) Isoxazolinone ring: e.g., 3-phenyl-2-isoxazolin-5-one, 3-methyl-2-isoxazolin-5-one, etc. (d) Oxindole ring: for example, 1-alkyl-2,3-dihydro-2-oxyindole. (e) 2,4,6-Tricetohexahydropyrimidine ring: for example, barbituric acid or 2-thiobarbituric acid and its derivatives. Examples of derivatives include 1-alkyl compounds such as 1-methyl and 1-ethyl, 1,3-dialkyl compounds such as 1,3-dimethyl, 1,3-diethyl and 1,3-dibutyl, 1,3-diaryl compounds such as 1,3-diphenyl, 1,3-di(p-chlorophenyl) and 1,3-di(p-ethoxycarbonylphenyl), 1-alkyl-1-aryl compounds such as 1-ethyl-3-phenyl, and 1,3-diheterocyclic substituted compounds such as 1,3-di(2-pyridyl). (f) 2-thio-2,4-thiazolidinedione ring: for example, rhodanine and its derivatives. Examples of derivatives include 3-alkylrhodanines such as 3-methylrhodanine, 3-ethylrhodanine, and 3-allylrhodanine, 3-arylrhodanines such as 3-phenylrhodanine, and 3-(2-pyridyl)rhodanine, etc. (g) 2-thio-2,4-oxazolidinedione (2-thio-2,4-(3H,5H)-oxazoldione ring: e.g., 3-ethyl-2-thio-2,4-oxazolidinedione). (h) Thianaphthenone ring: e.g., 3(2H)-thianaphthenone-1,1-dioxide. (i) 2-thio-2,5-thiazolidinedione ring: e.g., 3-ethyl-2-thio-2,5-thiazolidinedione. (j) 2,4-thiazolidinedione ring: e.g., 2,4-thiazolidinedione, 3-ethyl-2,4-thiazolidinedione, 3-phenyl-2,4-thiazolidinedione, etc. (k) Thiazolin-4-one ring: e.g., 4-thiazolinone, 2-ethyl-4-thiazolinone, etc. (l) 4-thiazolidinone ring: e.g., 2-ethylmercapto-5-thiazolin-4-one, 2-alkylphenylamino-5-thiazolin-4-one, etc. (m) 2,4-Imidazolidinedione (hydantoin) ring: e.g., 2,4-Imidazolidinedione, 3-ethyl-2,4-Imidazolidinedione, etc. (n) 2-thio-2,4-imidazolidinedione (2-thiohydantoin) ring: e.g., 2-thio-2,4-imidazolidinedione, 3-ethyl-2-thio-2,4-imidazolidinedione, etc. (o) Imidazolin-5-one ring: e.g., 2-propylmercapto-2-imidazolin-5-one. (p)3,5-pyrazolidinedione ring: e.g., 1,2-diphenyl-3,5-pyrazolidinedione, 1,2-dimethyl-3,5-pyrazolidinedione, etc. (q) Benzothiophene-3-one ring: e.g., benzothiophene-3-one, oxobenzothiophene-3-one, dioxobenzothiophene-3-one, etc. (r) Indanone ring: for example, 1-indanone, 3-phenyl-1-indanone, 3-methyl-1-indanone, 3,3-diphenyl-1-indanone, 3,3-dimethyl-1-indanone, etc.

[0180] R 3A and R 4A , R 5A and R 6AThe rings formed by the bonding of these rings to each other are preferably a 1,3-dicarbonyl ring, a pyrazolinone ring, a 2,4,6-tricetohexahydropyrimidine ring (including thioketone bodies), a 2-thio-2,4-thiazolidinedione ring, a 2-thio-2,4-oxazolidinedione ring, a 2-thio-2,5-thiazolidinedione ring, a 2,4-thiazolidinedione ring, a 2,4-imidazolidinedione ring, a 2-thio-2,4-imidazolidinedione ring, a 2-imidazolin-5-one ring, a 3,5-pyrazolidinedione ring, a benzothiophen-3-one ring, or an indanone ring, and more preferably a 1,3-dicarbonyl ring, a 2,4,6-tricetohexahydropyrimidine ring (including thioketone bodies), a 3,5-pyrazolidinedione ring, a benzothiophen-3-one ring, or an indanone ring.

[0181] Note, R 3A and R 4A , R 5A and R 6A When R is bonded to each other to form a ring, 3A ~R 6A Although the σp value of cannot be defined, in the present invention, R 3A ~R 6A We define the σp value for ring formation by assuming that each of the ring substructures is substituted. For example, R 3A and R 4A When R is bonded to form a 1,3-indanedione ring, 3A and R 4A Consider each of these as being substituted with a benzoyl group.

[0182] X 1 and X 2 These are, independently, -BR 21 R 22 This indicates. R 21 and R 22 Each of these independently represents a substituent, R 21 and R 22 They may be joined to each other to form a ring. R 21 and R 22The substituents represented are preferably halogen atoms, alkyl groups, alkoxy groups, aryl groups, heteroaryl groups, and groups represented by the following formula (2-4), more preferably halogen atoms, aryl groups, or heteroaryl groups, and even more preferably aryl groups. Preferred halogen atoms include fluorine, chlorine, bromine, and iodine atoms, with fluorine atoms being particularly preferred. The alkyl group preferably has 1 to 40 carbon atoms. The lower limit is more preferably 3 or more carbon atoms. The upper limit is more preferably 30 or less carbon atoms, and even more preferably 25 or less carbon atoms. The alkyl group may be linear, branched, or cyclic, but linear or branched is preferred, and linear is particularly preferred. The alkoxy group preferably has 1 to 40 carbon atoms. The lower limit is more preferably 3 or more carbon atoms. The upper limit is more preferably 30 or less carbon atoms, and even more preferably 25 or less carbon atoms. The alkoxy group may be linear, branched, or cyclic, but linear or branched is preferred, and linear is particularly preferred. The aryl group preferably has 6 to 20 carbon atoms, and more preferably 6 to 12 carbon atoms. A phenyl group is preferred as the aryl group. The heteroaryl group may be monocyclic or polycyclic, with monocyclic being preferred. The number of heteroatoms constituting the heteroaryl group is preferably 1 to 3. The heteroatoms constituting the heteroaryl group are preferably nitrogen, oxygen, or sulfur atoms. The number of carbon atoms in the heteroaryl group is preferably 3 to 30, more preferably 3 to 18, even more preferably 3 to 12, and particularly preferably 3 to 5. The heteroaryl group is preferably a 5-membered or 6-membered ring. A specific example of a heteroaryl group is R 1A and R 2A The examples given are those explained above.

[0183] [ka]

[0184] In equation (2-4), R a5 ~R a9 Each of these independently represents a hydrogen atom or substituent. * indicates a link with general formula (D1). a5~R a9 The substituents represented by include alkyl groups, alkoxy groups, aryl groups, and heteroaryl groups, with alkyl groups being preferred.

[0185] R 21 and R 22 They may be bonded to each other to form a ring. 21 and R 22 Examples of rings formed by the bonding of these include the structures shown in (2-1) to (2-3) below. In the following, R represents a substituent, and R a1 ~R a4 Each of these independently represents a hydrogen atom or substituent, and each of m1 to m3 independently represents an integer from 0 to 4. a1 ~R a4 The substituent represented by is R 21 and R 22 Examples of substituents described above include alkyl groups, with alkyl groups being preferred.

[0186] [ka]

[0187] The dye represented by the above general formula (D1) is preferably the dye represented by the following general formula (D2).

[0188] [ka]

[0189] In general formula (D2), R 1a and R 2a Each of these independently represents a substituent, R 3a and R 6a Each of these independently represents a substituent, R 4a and R 5a Each of these independently represents a heteroaryl group. 3a and R 4a , R 5a and R 6a These may be joined together to form a ring. 1a and X2a These are, independently, -BR 21a R 22a Represents R 21a and R 22a Each of these independently represents a substituent, R 21a and R 22a They may be joined to each other to form a ring. In general formula (D2), R 3a ~R 6a , X 1a , X 2a , R 21a and R 22a These are, respectively, the R mentioned above. 3A ~R 6A , X 1 , X 2 , R 21 and R 22 This is synonymous with the same thing, and the preferred range is also similar. R 1a and R 2a The substituents in R 1A and R 2A This is synonymous with substituents that alkyl groups, aryl groups, and heteroaryl groups may have, and the preferred range is also the same.

[0190] The dye represented by the above general formula (D1) is more preferably the dye represented by the following general formula (D3).

[0191] [ka]

[0192] In the general formula (D3), R 1b and R 2b Each of these independently represents a branched alkyl group, and R 3b and R 6b Each of these independently represents a substituent, R 4b and R 5b Each of these independently represents a heteroaryl group. 3b and R 4b , R 5b and R 6b These may be joined together to form a ring.21b and R 22b Each of these independently represents a substituent, R 21b and R 22b They may be joined together to form a ring.

[0193] R 1b and R 2b Each of these independently represents a branched alkyl group. The number of carbon atoms is preferably 3 to 40. The lower limit is, for example, more preferably 5 or more, even more preferably 8 or more, and even more preferably 10 or more. The upper limit is more preferably 35 or less, and even more preferably 30 or less. The number of branches of the branched alkyl group is preferably 2 to 10, and more preferably 2 to 8. R 3b ~R 6b , R 21b and R 22b These are, respectively, the R mentioned above. 3A ~R 6A , R 21 and R 22 This is synonymous with the same thing, and the preferred range is also similar. That is, R 3b and R 6b The group is preferably an electron-withdrawing group, and more preferably a cyano group. R 21b and R 22b Each of these is independently preferably a halogen atom, an alkyl group, an alkoxy group, an aryl group, or a heteroaryl group, more preferably a halogen atom, an aryl group, or an aryl group, and even more preferably an aryl group.

[0194] The following are specific examples of dye D. Compounds D-1 to D-24 and D-28 to D-90 shown below are dyes represented by the general formula (D1). Note that in the following structural formula, iC 10 H 21 The "i" in these examples indicates a branching pattern. Furthermore, Bu represents a butyl group, and Ph represents a phenyl group.

[0195] [ka]

[0196] [ka]

[0197] [ka]

[0198] [ka]

[0199] [ka]

[0200] [ka]

[0201] [ka]

[0202] [ka]

[0203] [ka]

[0204] (Dyes represented by general formula (1))

[0205] [ka]

[0206] The possible substituent forms for A and B in general formula (1) are as described above for dyes B and C, respectively, as shown for A and B in general formula (1).

[0207] If dye D is a pigment represented by general formula (1), it is preferable that it is a pigment represented by the following general formula (14).

[0208] [ka]

[0209] In general formula (14), R 1 and R 2 This is R in the general formula (2) mentioned above. 1 and R 2 It is synonymous with R. 41 and R 42 Also, R in the general formula (2) mentioned above. 1 and R 2 It is synonymous with [the above]. R 1 , R 2 , R 41 and R 42 Among these, alkyl groups, alkenyl groups, aryl groups, or heteroaryl groups are preferred, alkyl groups, aryl groups, or heteroaryl groups are more preferred, and alkyl groups or aryl groups are even more preferred. R 1 , R 2 , R 41 and R 42 The substituent may further have substituents. An example of a substituent that may further have substituents is the substituent X mentioned above.

[0210] B in general formula (14) 1 B 2 B 3 and B 4 These are, respectively, B in the general formula (2) mentioned above. 1 B 2 B 3 and B 4 This is equivalent to the same thing. Also, B in general formula (14) 5 B 6 B 7 and B 8 These are, respectively, B in the general formula (2) mentioned above. 1 B2 B 3 and B 4 It is synonymous with [the above]. B 1 B 2 B 3 B 4 B 5 B 6 B 7 and B 8 The substituents on the carbon atom that can be selected may have further substituents. Examples of these further substituents include the substituent X mentioned above.

[0211] In general formula (14), R 1 and R 2 These may bond with each other to form a ring, R 1 or R 2 And, B 2 or B 3 The substituents on may bond to form a ring. Also, R 41 and R 42 These may bond with each other to form a ring, R 41 or R 42 And, B 6 or B 7 The substituents on may bond to form a ring. In the above, the formed ring is preferably a heterocyclic or heteroaryl ring, and the size of the formed ring is not particularly limited, but it is preferably a 5-membered or 6-membered ring. Also, the number of rings formed is not particularly limited, and may be one or two or more. An example of a form in which two or more rings are formed is R 1 and B 2 The substituents that R has, and 2 and B 3 One possible configuration is one in which the substituents on each component bond to each other to form two rings.

[0212] Among dye D, the squalin-based dye represented by general formula (1) may be a quencher-containing dye. For quencher-containing dyes, the description of quencher-containing dyes in dyes B or C described above may be applied.

[0213] The following are specific examples of dye D. Compounds F-1 to F-44 below are dyes represented by general formula (1). Of these, compounds F-24 to F-33 and F-44 are dyes containing a quencher.

[0214] [ka]

[0215] [ka]

[0216] [ka]

[0217] [ka]

[0218] The total content of dyes A to D in the light-absorbing portion is not particularly limited as long as the effects of the present invention are achieved, but is preferably 0.10% by mass or more, more preferably 0.50% by mass or more, even more preferably 1% by mass or more, and particularly preferably 5% by mass or more. When the total content of dyes A to D in the light-absorbing portion is above the above preferred lower limit, a good effect of suppressing external light reflection can be obtained. Furthermore, from the viewpoint of suppressing a decrease in brightness, the total content of dyes A to D in the light-absorbing portion is usually 50% by mass or less, preferably 40% by mass or less, and more preferably 35% by mass or less.

[0219] The amounts of dyes A to D that may be contained in the light-absorbing portion are preferably as follows: The content of dye A in the light-absorbing portion is preferably 0.01 to 45% by mass, more preferably 1 to 30% by mass, and even more preferably 5 to 30% by mass. The content of dye B in the light-absorbing portion is preferably 0.01 to 45% by mass, more preferably 0.1 to 30% by mass, and even more preferably 0.1 to 20% by mass. The content of dye C in the light-absorbing portion is preferably 0.01 to 30% by mass, more preferably 0.1 to 25% by mass. The content of dye D in the light-absorbing portion is preferably 0.05 to 50% by mass, more preferably 0.2 to 40% by mass, and even more preferably 0.2 to 20% by mass. When the above light-absorbing portion contains all four types of dyes A to D, the preferred mass ratio of each dye A to D in the light-absorbing portion is dye A:dye B:dye C:dye D = 1:0.05~10:0.05~5:0.1~10, and more preferably 1:0.1~5:0.1~3:0.2~5.

[0220] Furthermore, if at least one of dyes B and C is a quencher-containing dye, the content of the quencher-containing dye in the light-absorbing portion is preferably 0.1% by mass or more from the viewpoint of suppressing external light reflection. The upper limit is preferably 45% by mass or less from the viewpoint of suppressing brightness reduction.

[0221] <Resin> The light-absorbing portion described above preferably contains a resin (hereinafter also referred to as "matrix resin"). The resin is not particularly limited as long as it can disperse (preferably dissolve) the dye and achieve an excellent balance between the effect of suppressing external light reflection and the effect of suppressing brightness reduction. Furthermore, if the resin contains a fade-preventing agent for the dye described below in addition to the dye, it is preferable that the fade-preventing agent can be dispersed (preferably dissolved) and that the reduction in the lightfastness of the dye due to the fade-preventing agent can be suppressed. It is also preferable that the original color of the image on the display device can be maintained at an excellent level.

[0222] When at least one of dyes B and C is a squalin-based dye represented by general formula (1), the matrix resin is preferably a low-polarity matrix resin capable of suitably satisfying the absorption waveform B or C with respect to this squalin-based dye. By using a squalin-based dye as dye B or C exhibiting the absorption waveform B or C, as described above, it is possible to display information without significantly impairing the brightness of a display device having an organic electroluminescent light-emitting element or a microlight-emitting diode as the light-emitting part, while satisfying the effect of suppressing ambient light reflection. Here, low polarity is preferably defined as an fd value of 0.50 or higher, as shown in the following relational equation I. Relational expression I:fd=δd / (δd+δp+δh) In relation I, δd, δp, and δh represent terms corresponding to the London dispersion force, the inter-dipole force, and the hydrogen bonding force, respectively, with respect to the solubility parameter δt calculated by the Hoy method. The specific calculation method is described below. That is, fd represents the ratio of δd to the sum of δd, δp, and δh. By setting the fd value to 0.50 or higher, it becomes easier to obtain suitable absorption waveforms B and C. Furthermore, if the light-absorbing portion contains two or more types of matrix resin, the fd value is calculated as follows. fd=Σ(w i ·fd i ) Here, w i is the mass fraction of the i-th matrix resin, fd i This indicates the fd value of the i-th matrix resin.

[0223] - Term δd corresponding to London dispersion force - The term δd, which corresponds to the London dispersion force, is found in the document "Properties of Polymers 3 rdThis refers to the δd obtained for Amorphous Polymers as described in the "2) Method of Hoy (1985,1989)" section on pages 214-220 of "ELSEVIER, (1990)," and is calculated according to the description in the above section of the aforementioned document.

[0224] - δp term corresponding to the inter-dipole force - The term δp, which corresponds to the inter-dipole force, is described in the literature “Properties of Polymers 3 rd This refers to the δp obtained for Amorphous Polymers as described in "2) Method of Hoy (1985, 1989)" on pages 214-220 of "ELSEVIER, (1990)", and is calculated according to the description in the above section of the above-mentioned literature.

[0225] - Term δh corresponding to hydrogen bonding force - The term δh, which corresponds to the hydrogen bonding force, is described in the literature “Properties of Polymers 3 rd This refers to the δh obtained for Amorphous Polymers as described in "2) Method of Hoy (1985, 1989)" on pages 214-220 of "ELSEVIER, (1990)", and is calculated according to the description in the above section of the above-mentioned literature.

[0226] Furthermore, if the matrix resin is a resin that exhibits a certain degree of hydrophobicity, the water content of the light-absorbing portion can be reduced to a low water content, for example, 0.5% or less, which is preferable from the viewpoint of improving the light resistance of the optical component of the present invention including the light-absorbing portion. The resin may contain any conventional components in addition to the polymer. However, the fd of the matrix resin mentioned above is a calculated value for the polymer constituting the matrix resin.

[0227] Preferred examples of the matrix resin include, for example, polystyrene resin and cyclic polyolefin resin, and it is more preferable to include polystyrene resin or cyclic polyolefin resin. Typically, the fd value of polystyrene resin is 0.45 to 0.60, and the fd value of cyclic polyolefin resin is 0.45 to 0.70. As mentioned above, it is preferable to use a material with an fd value of 0.50 or higher. Furthermore, in addition to these preferred resins, it is also preferable to use resin components that impart functionality to the light-absorbing portion, such as stretchable resin components and release-controlling resin components, which will be described later. That is, in the present invention, the term "matrix resin" is used to mean that, in addition to the resins mentioned above, the stretchable resin components and release-controlling resin components are included.

[0228] (Polystyrene resin) The polystyrene contained in the above polystyrene resin refers to a polymer containing a styrene component. It is preferable that the polystyrene contains 50% by mass or more of the styrene component. The above light-absorbing portion may contain one type of polystyrene or two or more types. Here, the styrene component refers to a structural unit derived from a monomer having a styrene skeleton in its structure. Polystyrene is more preferably composed of 70% by mass or more of styrene components, and even more preferably 85% by mass or more, in order to control the photoelastic coefficient and hygroscopicity to values ​​within a desirable range for the light-absorbing portion. Furthermore, it is also preferable that the polystyrene is composed solely of styrene components.

[0229] Polystyrenes composed solely of the styrene component include homopolymers of styrene compounds and copolymers of two or more styrene compounds. Here, a styrene compound is a compound having a styrene skeleton in its structure, and includes not only styrene but also compounds in which substituents have been introduced to the extent that the ethylenically unsaturated bond of styrene can act as a reactive (polymerizable) group. Specific styrene compounds include, for example, styrene; alkyl styrenes such as α-methylstyrene, o-methylstyrene, m-methylstyrene, p-methylstyrene, 3,5-dimethylstyrene, 2,4-dimethylstyrene, o-ethylstyrene, p-ethylstyrene, and tert-butylstyrene; and substituted styrenes in which a hydroxyl group, alkoxy group, carboxyl group, and halogen atom are introduced to the benzene ring of styrene, such as hydroxystyrene, tert-butoxystyrene, vinylbenzoic acid, o-chlorostyrene, and p-chlorostyrene. Among these, polystyrene homopolymers (i.e., polystyrene) are preferred from the viewpoint of availability and material cost.

[0230] Furthermore, the components other than the styrene component that may be included in the above-mentioned polystyrene are not particularly limited. That is, the polystyrene may be a styrene-diene copolymer or a styrene-polymerizable unsaturated carboxylic acid ester copolymer, etc. A mixture of polystyrene and synthetic rubber (for example, polybutadiene and polyisoprene) can also be used. High-impact polystyrene (HIPS) obtained by graft polymerization of styrene onto synthetic rubber is also preferred. In addition, polystyrene obtained by dispersing a rubbery elastomer in a continuous phase of a polymer containing a styrene component (for example, a copolymer of a styrene component and a (meth)acrylic acid ester component), and graft polymerization of the copolymer onto the rubbery elastomer (graft-type high-impact polystyrene "graft HIPS") is also preferred. Furthermore, so-called styrene-based elastomers can also be suitably used. Furthermore, the above polystyrene may be hydrogenated (it may also be hydrogenated polystyrene). The above hydrogenated polystyrene is not particularly limited, but hydrogenated styrene-diene copolymers such as hydrogenated styrene-butadiene-styrene block copolymer (SEBS) obtained by hydrogenating SBS (styrene-butadiene-styrene block copolymer), and hydrogenated styrene-isoprene-styrene block copolymer (SEPS) obtained by hydrogenating SIS (styrene-isoprene-styrene block copolymer) are preferred. Only one type of hydrogenated polystyrene may be used, or two or more types may be used. Furthermore, the polystyrene mentioned above may be modified polystyrene. The modified polystyrene is not particularly limited, but examples include polystyrene into which reactive groups such as polar groups have been introduced, and specifically, acid-modified polystyrene such as maleic acid-modified polystyrene and epoxy-modified polystyrene are preferred.

[0231] Multiple types of polystyrene with different compositions, molecular weights, etc., can be used in combination. Polystyrene resins can be obtained by conventional methods such as anionic polymerization, bulk polymerization, suspension polymerization, emulsification, or solution polymerization. Furthermore, in polystyrene, at least a portion of the unsaturated double bonds of the benzene rings of the conjugated diene and styrene monomer may be hydrogenated. The hydrogenation rate can be measured by nuclear magnetic resonance (NMR) spectroscopy.

[0232] As for the polystyrene resin, commercially available products may be used, for example, "Clearlen 530L" and "Clearlen 730L" from Denki Kagaku Kogyo Co., Ltd., "Toughprene 126S" and "Asaprene T411" from Asahi Kasei Corporation, "Kraton D1102A" and "Kraton D1116A" from Kraton Polymer Japan Co., Ltd., "Styrolux S" and "Styrolux T" from Styrolusion Corporation, "Asaflex 840" and "Asaflex 860" (both SBS) from Asahi Kasei Chemicals Corporation, "679", "HF77", and "SGP-10" from PS Japan Co., Ltd., "Dick Styrene XC-515" and "Dick Styrene XC-535" (both GPPS) from DIC Corporation, "475D", "H0103", and "HT478" from PS Japan Co., Ltd., and "Dick Styrene" from DIC Corporation. Examples include GH-8300-5 (HIPS). Examples of hydrogenated polystyrene resins include Asahi Kasei Chemicals Corporation's "ToughTec H series", Shell Japan Co., Ltd.'s "Clayton G series" (SEBS), JSR Corporation's "Dynalon" (hydrogenated styrene-butadiene random copolymer), and Kuraray Co., Ltd.'s "Septon" (SEPS). Examples of modified polystyrene resins include Asahi Kasei Chemicals Corporation's "ToughTec M series", Daicel Corporation's "Epofriend", JSR Corporation's "Polar Group Modified Dynalon", and Toagosei Co., Ltd.'s "Rezeda".

[0233] The light-absorbing portion may also preferably contain polyphenylene ether resin in addition to the polystyrene resin. By including both polystyrene resin and polyphenylene ether resin, the toughness of the light-absorbing portion can be improved, and the occurrence of defects such as cracks can be suppressed even in harsh environments such as high temperature and high humidity. However, if the light-absorbing portion of the present invention contains polyphenylene ether resin in addition to the polystyrene resin, the fd value of the polyphenylene ether resin is not considered in the calculation of the fd value. As the polyphenylene ether resin mentioned above, Asahi Kasei Corporation's Zylon S201A, 202A, S203A, etc., can be preferably used. Alternatively, a resin that has been pre-mixed with polystyrene resin and polyphenylene ether resin may be used. As the mixed resin of polystyrene resin and polyphenylene ether resin, for example, Asahi Kasei Corporation's Zylon 1002H, 1000H, 600H, 500H, 400H, 300H, 200H, etc., can be preferably used. In the above-mentioned light-absorbing portion, when polystyrene resin and polyphenylene ether resin are included, the mass ratio of the two is preferably 99 / 1 to 50 / 50, more preferably 98 / 2 to 60 / 40, and even more preferably 95 / 5 to 70 / 30, in terms of polystyrene resin / polyphenylene ether resin. By setting the blending ratio of polyphenylene ether resin within the above preferred range, the light-absorbing portion has sufficient toughness, and when a solution film is formed, the solvent can be appropriately volatilized.

[0234] (Cyclic polyolefin resin) The cyclic olefin compounds that form the cyclic polyolefin contained in the cyclic polyolefin resin are not particularly limited as long as they are compounds having a ring structure containing a carbon-carbon double bond. Examples include norbornene compounds, monocyclic cyclic olefin compounds other than norbornene compounds, cyclic conjugated diene compounds, and vinyl alicyclic hydrocarbon compounds. Examples of cyclic polyolefins include (1) polymers containing structural units derived from norbornene compounds, (2) polymers containing structural units derived from monocyclic cyclic olefin compounds other than norbornene compounds, (3) polymers containing structural units derived from cyclic conjugated diene compounds, (4) polymers containing structural units derived from vinyl alicyclic hydrocarbon compounds, and hydrides of polymers containing structural units derived from each of the compounds in (1) to (4). In the present invention, polymers containing structural units derived from norbornene compounds and polymers containing structural units derived from monocyclic cyclic olefin compounds include ring-opened polymers of each compound.

[0235] While there are no particular limitations on the cyclic polyolefin, polymers having structural units derived from norbornene compounds, represented by the following general formulas (A-II) or (A-III), are preferred. Polymers having structural units represented by the following general formula (A-II) are addition polymers of norbornene compounds, and polymers having structural units represented by the following general formula (A-III) are ring-opening polymers of norbornene compounds.

[0236] [ka]

[0237] In general formulas (A-II) and (A-III), m is an integer between 0 and 4, preferably 0 or 1. In general formulas (A-II) and (A-III), R 3 ~R 6 Each of these independently represents either a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms. The hydrocarbon group in general formulas (AI) to (A-III) is not particularly limited as long as it is a group consisting of a carbon atom and a hydrogen atom, and examples include alkyl groups, alkenyl groups, alkynyl groups, and aryl groups (aromatic hydrocarbon groups). Among these, alkyl groups or aryl groups are preferred. In general formulas (A-II) and (A-III), X 2 and X 3 , Y 2 and Y 3 Each of these independently consists of a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms substituted with a halogen atom, and -(CH2)nCOOR 11 、-(CH2)nOCOR 12 , -(CH2)nNCO, -(CH2)nNO2, -(CH2)nCN, -(CH2)nCONR 13 R 14 ,-(CH2)nNR 13 R 14 -(CH2)nOZ or -(CH2)nW, or X 2 and Y 2 Or X 3 and Y 3These combine with each other to form (-CO)2O or (-CO)2NR 15 This indicates. Here, R 11 ~R 15 Each of the following independently represents a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms, Z represents a hydrocarbon group or a hydrocarbon group substituted with a halogen, and W represents Si(R 16 ) p D (3-p) (R 16 -OCOR indicates a hydrocarbon group with 1 to 10 carbon atoms, where D is a halogen atom, and -OCOR 17 OR 17 (R 17 (where is a hydrocarbon group having 1 to 10 carbon atoms). (where is an integer from 0 to 3). (where is an integer from 0 to 10, preferably from 0 to 8, and more preferably from 0 to 6.)

[0238] In general formulas (A-II) and (A-III), R 3 ~R 6 Each of these is preferably a hydrogen atom or -CH3, and more preferably a hydrogen atom in terms of water vapor permeability. X 2 and X 3 These are preferably hydrogen atoms, -CH3, or -C2H5, respectively, with hydrogen atoms being more preferable in terms of water vapor permeability. Y 2 and Y 3 These are, respectively, a hydrogen atom, a halogen atom (especially a chlorine atom), or -(CH2)nCOOR 11 (Especially -COOCH3) is preferred, and hydrogen atoms are more preferred in terms of moisture permeability. Other elements are selected as appropriate.

[0239] A polymer having a structural unit represented by general formula (A-II) or (A-III) may further contain at least one structural unit represented by the following general formula (AI).

[0240] [ka]

[0241] In the general formula (AI), R 1 and R 2 Each independently represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, X 1 and Y 1 Each of these independently consists of a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms substituted with a halogen atom, and -(CH2)nCOOR 11 、-(CH2)nOCOR 12 , -(CH2)nNCO, -(CH2)nNO2, -(CH2)nCN, -(CH2)nCONR 13 R 14 ,-(CH2)nNR 13 R 14 -(CH2)nOZ, -(CH2)nW, or X 1 and Y 1 These combine with each other to form (-CO)2O or (-CO)2NR 15 This indicates. Here, R 11 ~R 15 Each of the following independently represents a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms, Z represents a hydrocarbon group or a hydrocarbon group substituted with a halogen, and W represents Si(R 16 ) p D (3-p) (R 16 -OCOR indicates a hydrocarbon group with 1 to 10 carbon atoms, where D is a halogen atom, and -OCOR 17 OR 17 (R 17 (where represents a hydrocarbon group with 1 to 10 carbon atoms). (where p is an integer from 0 to 3). (where n is an integer from 0 to 10).

[0242] From the viewpoint of adhesion, a cyclic polyolefin having structural units represented by general formula (A-II) or (A-III) preferably contains structural units derived from the above-mentioned norbornene compound in an amount of 90% by mass or less, more preferably 30-85% by mass, even more preferably 50-79% by mass, and most preferably 60-75% by mass, relative to the total mass of the cyclic polyolefin. Here, the proportion of structural units derived from the norbornene compound represents the average value in the cyclic polyolefin.

[0243] Addition (co)polymers of norbornene compounds are described in Japanese Patent Publication No. 10-7732, Japanese Patent Publication No. 2002-504184, U.S. Patent Publication No. 2004 / 229157A1, and International Publication No. 2004 / 070463, among others. Polymers of norbornene compounds can be obtained by addition polymerization of norbornene compounds (for example, polycyclic unsaturated compounds of norbornene).

[0244] Furthermore, as polymers of norbornene compounds, if necessary, include copolymers obtained by addition copolymerization of norbornene compounds with olefins such as ethylene, propylene, and butene, conjugated dienes such as butadiene and isoprene, unconjugated dienes such as ethylidene norbornene, and ethylenically unsaturated compounds such as acrylonitrile, acrylic acid, methacrylic acid, maleic anhydride, acrylic acid esters, methacrylic acid esters, maleimide, vinyl acetate, and vinyl chloride. Among these, copolymers of norbornene compounds and ethylene are preferred. Examples of such norbornene addition (co)polymers include APL8008T (Tg 70°C), APL6011T (Tg 105°C), APL6013T (Tg 125°C), and APL6015T (Tg 145°C), which are sold by Mitsui Chemicals under the trade name APL, and have different glass transition temperatures (Tg). In addition, pellets such as TOPAS8007, TOPAS6013, and TOPAS6015 are commercially available from Polyplastics. Furthermore, Appear3000 is commercially available from Ferrania.

[0245] The norbornene compound polymers mentioned above can be commercially available. For example, they are sold by JSR under the trade names Arton G or Arton F, and by Zeon Corporation under the trade names Zeonor ZF14, ZF16, Zeonex 250, or Zeonex 280.

[0246] Hydrogenated polymers of norbornene compounds can be synthesized by addition polymerization or metathesis ring-opening polymerization of norbornene compounds, etc., followed by hydrogenation. Synthesis methods are described in various publications, for example, Japanese Patent Publication Nos. Hei 1-240517, Hei 7-196736, Sho 60-26024, Sho 62-19801, 2003-159767, and 2004-309979.

[0247] The molecular weight of the above-mentioned cyclic polyolefin is appropriately selected depending on the intended use, but is the mass-average molecular weight in terms of polyisoprene or polystyrene, measured by gel permeation chromatography in a cyclohexane solution (or toluene solution if the polymer does not dissolve). Typically, it is preferably 5,000 to 500,000, more preferably 8,000 to 200,000, and even more preferably 10,000 to 100,000. Polymers having molecular weights within this range can achieve a good balance between the mechanical strength and moldability of molded articles.

[0248] The light-absorbing portion preferably contains 5% by mass or more of the matrix resin, more preferably 20% by mass or more, even more preferably 30% by mass or more, and particularly preferably 45% by mass or more. The content of the matrix resin in the light-absorbing portion is usually 99.90% by mass or less, and preferably 99.85% by mass or less. Each component of the matrix resin contained in the light-absorbing portion may be two or more types, and polymers with different composition ratios and molecular weights may be used in combination. In this case, the total content of each polymer will be within the above range.

[0249] (Stretchable resin component) The light-absorbing portion described above may contain, as appropriate, a component exhibiting stretchability (also referred to as a stretchable resin component) as a resin component. Specifically, examples include acrylonitrile-butadiene-styrene resin (ABS resin), styrene-butadiene resin (SB resin), isoprene resin, butadiene resin, polyether-urethane resin, and silicone resin. Furthermore, these resins may be further hydrogenated as appropriate. As the above-mentioned stretchable resin component, it is preferable to use ABS resin or SB resin, and more preferably SB resin.

[0250] The above-mentioned SB resin can be, for example, a commercially available product. Examples of such commercially available products include TR2000, TR2003, TR2250 (all product names, manufactured by JSR Corporation), Clearlen 210M, 220M, 730V (all product names, manufactured by Denka Co., Ltd.), Asaflex 800S, 805, 810, 825, 830, 840 (all product names, manufactured by Asahi Kasei Corporation), and Eporex SB2400, SB2610, SB2710 (all product names, manufactured by Sumitomo Chemical Co., Ltd.).

[0251] The above-mentioned light-absorbing portion preferably contains 15 to 95% by mass of the stretchable resin component in the matrix resin, more preferably 20 to 50% by mass, and even more preferably 25 to 45% by mass.

[0252] As for the above-mentioned stretchable resin component, it is preferable that the stretchable resin component alone is used to prepare a sample with a thickness of 30 μm and a width of 10 mm, and when the elongation at break at 25°C is measured according to JIS 7127, the elongation at break shows 10% or more, and it is more preferable that it shows 20% or more.

[0253] (Release-controlling resin component) When the above-mentioned light-absorbing portion is manufactured by a method that includes a step of peeling the light-absorbing portion from the release film, as described later, it is preferable that the resin component include a component that controls the peelability (a resin component that controls the peelability). By controlling the peelability of the light-absorbing portion from the release film, it is possible to prevent peeling marks from being left on the light-absorbing portion after peeling, and it also becomes possible to accommodate various processing speeds in the peeling process. As a result, favorable effects can be obtained in improving the quality and productivity of the light-absorbing portion.

[0254] There are no particular restrictions on the above-mentioned release-controlling resin component, and it can be appropriately selected depending on the type of release film. As will be described later, when a polyester polymer film is used as the release film, for example, polyester resin (also referred to as a polyester additive) is preferred as the release-controlling resin component.

[0255] The above polyester-based additives can be obtained by conventional methods such as the dehydration condensation reaction of a polyhydric basic acid and a polyhydric alcohol, and the addition of a dibasic anhydride to a polyhydric alcohol and the subsequent dehydration condensation reaction. Polycondensed esters formed from a dibasic acid and a diol are preferred.

[0256] The mass-average molecular weight (Mw) of the above polyester-based additive is preferably 500 to 50,000, more preferably 750 to 40,000, and even more preferably 2,000 to 30,000. If the mass-average molecular weight of the polyester additive is above the preferred lower limit, it is preferable from the viewpoint of brittleness and resistance to moist heat, and if it is below the preferred upper limit, it is preferable from the viewpoint of compatibility with the resin. The mass-average molecular weight of the above polyester additive is the value of the mass-average molecular weight (Mw) on a standard polystyrene basis, measured under the following conditions. The molecular weight distribution (Mw / Mn) can also be measured under the same conditions. Note that Mn is the number-average molecular weight on a standard polystyrene basis. GPC: Gel permeation chromatography system (HLC-8220GPC manufactured by Tosoh Corporation) Columns: Tosoh Corporation's Guard Column HXL-H, TSK gel G7000HXL, two TSK gel GMHXLs, and TSK gel G2000HXL are connected in sequence. Eluent; tetrahydrofuran, Flow rate; 1mL / min, Sample concentration: 0.7-0.8% by mass. Sample injection volume: 70 μL, Measurement temperature: 40℃, Detector; differential refractometer (RI) (40°C), Standard material: TSK Standard Polystyrene (manufactured by Tosoh Corporation)

[0257] Dicarboxylic acids are preferred as dibasic acid components that make up polyester-based additives. Examples of dicarboxylic acids include aliphatic dicarboxylic acids and aromatic dicarboxylic acids, and aromatic dicarboxylic acids, or mixtures of aromatic dicarboxylic acids and aliphatic dicarboxylic acids, can be preferably used.

[0258] Among aromatic dicarboxylic acids, those having 8 to 20 carbon atoms are preferred, and those having 8 to 14 carbon atoms are more preferred. Specifically, at least one of phthalic acid, isophthalic acid, and terephthalic acid is preferred.

[0259] Among aliphatic dicarboxylic acids, those having 3 to 8 carbon atoms are preferred, and those having 4 to 6 carbon atoms are more preferred. Specifically, at least one of succinic acid, maleic acid, adipic acid, and glutaric acid is preferred, and at least one of succinic acid and adipic acid is more preferred.

[0260] Furthermore, examples of diol components constituting the polyester additive include aliphatic diols and aromatic diols, with aliphatic diols being preferred. Among aliphatic diols, those with 2 to 4 carbon atoms are preferred, and those with 2 to 3 carbon atoms are more preferred. Examples of aliphatic diols include ethylene glycol, diethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, and 1,4-butylene glycol, which can be used individually or in combination of two or more.

[0261] The polyester additive is preferably a compound obtained by condensing at least one of phthalic acid, isophthalic acid, and terephthalic acid with an aliphatic diol.

[0262] The ends of the polyester additive may be encapsulated by reacting them with a monocarboxylic acid. Aliphatic monocarboxylic acids are preferred as the monocarboxylic acid used for encapsulation, with acetic acid, propionic acid, butanoic acid, benzoic acid and their derivatives being preferred, acetic acid or propionic acid being more preferred, and acetic acid being even more preferred.

[0263] Examples of commercially available polyester-based additives include ester resins from Nippon Synthetic Chemical Industry Co., Ltd. (e.g., LP050, TP290, LP035, LP033, TP217, TP220) and ester resins from Toyobo Co., Ltd. (e.g., Byron 245, Byron GK890, Byron 103, Byron 200, Byron 550, Byron GK880).

[0264] The content of the release-controlling resin component in the light-absorbing portion is preferably 0.05% by mass or more, and more preferably 0.1% by mass or more, in the matrix resin. Furthermore, the upper limit is preferably 25% by mass or less, more preferably 20% by mass or less, and even more preferably 15% by mass or less. From the viewpoint of obtaining appropriate adhesion, it is preferable to have the content within the above preferred range.

[0265] <Fade-resistant agent> The light-absorbing portion described above preferably contains a dye fade inhibitor (also simply referred to as a fade inhibitor) to prevent the dye from fading. The fade inhibitor can effectively suppress dye fading by, for example, being dispersed (preferably dissolved) in the resin described above, by capturing radicals such as singlet oxygen or being oxidized in place of the dye. The above-mentioned anti-fading agent can be any commonly used anti-fading agent without particular limitation, such as the antioxidants described in paragraphs

[0143] to

[0165] of International Publication No. 2015 / 005398, the radical scavengers described in paragraphs

[0166] to

[0199] , and the degradation inhibitors described in paragraphs

[0205] to

[0206] .

[0266] As the above-mentioned anti-fading agent, a compound represented by the following general formula (IV) can be preferably used.

[0267] [ka]

[0268] In general formula (IV), R 10 Each of these is independently an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, or R 18 CO-, R 19 SO2- or R 20 This shows the group represented by NHCO-. Here R 18 , R 19 and R 20 Each of these independently represents an alkyl group, an alkenyl group, an aryl group, or a heterocyclic group. 11 and R 12 Each of these independently represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkoxy group, or an alkenyloxy group, and R 13 ~R 17 Each of these independently represents a hydrogen atom, an alkyl group, an alkenyl group, or an aryl group. However, R 10 ~R 20 The alkyl group in this context includes an aralkyl group.

[0269] R in general formula (IV)10 Examples of alkyl groups represented by include methyl, ethyl, propyl, and benzyl; examples of alkenyl groups include allyl; examples of aryl groups include phenyl; and examples of heterocyclic groups include tetrahydropyranyl and pyrimidyl. 18 , R 19 and R 20 Each of these independently represents an alkyl group (e.g., methyl, ethyl, n-propyl, n-butyl, benzyl, etc.), an alkenyl group (e.g., allyl, etc.), an aryl group (e.g., phenyl, methoxyphenyl, etc.), or a heterocyclic group (e.g., pyridyl, pyrimidyl, etc.).

[0270] R in general formula (IV) 11 or R 12 Examples of halogen atoms represented by include chlorine and bromine; examples of alkyl groups include methyl, ethyl, n-butyl, and benzyl; examples of alkenyl groups include allyl; examples of alkoxy groups include methoxy, ethoxy, and benzyloxy; and examples of alkenyloxy groups include 2-propenyloxy.

[0271] R in general formula (IV) 13 , R 14 , R 15 , R 16 and R 17 Examples of alkyl groups represented by include methyl, ethyl, n-butyl, and benzyl; examples of alkenyl groups include 2-propenyl; and examples of aryl groups include phenyl, methoxyphenyl, and chlorophenyl. R 10 ~R 20 The substituent may further have substituents, such as R 10 ~R 20 The following are examples of the groups indicated by [the symbols]. Specific examples of compounds represented by general formula (IV) are shown below. However, the present invention is not limited to these.

[0272] [ka]

[0273] [ka]

[0274] As the above-mentioned anti-fading agent, compounds represented by the following general formula [III] can also be preferably used.

[0275] [ka]

[0276] In general formula [III], R 31 represents an aliphatic or aromatic group, and Y represents a group of nonmetallic atoms necessary to form a 5-7 membered ring together with the nitrogen atom.

[0277] In general formula [III], R 31 The group represents an aliphatic or aromatic group, preferably an alkyl group, an aryl group, or a heterocyclic group (preferably an aliphatic heterocyclic group), and more preferably an aryl group. Examples of heterocycles formed by Y together with a nitrogen atom include piperidine rings, piperazine rings, morpholine rings, thiomorpholine rings, thiomorpholine-1,1-dione rings, pyrrolidine rings, and imidazolidine rings. Furthermore, the above heterocycle may have substituents, such as alkyl groups and alkoxy groups.

[0278] Specific examples of compounds represented by general formula [III] are shown below. However, the present invention is not limited to these.

[0279] [ka]

[0280] In addition to the above specific examples, other specific examples of compounds represented by the above general formula [III] include exemplary compounds B-1 to B-65 described on pages 8 to 11 of the specification of Japanese Patent Publication No. Hei 2-167543, and exemplary compounds (1) to (120) described on pages 4 to 7 of the specification of Japanese Patent Publication No. Sho 63-95439.

[0281] The content of the fade inhibitor in the light-absorbing portion is preferably 0.1 to 15% by mass, more preferably 1 to 15% by mass, even more preferably 5 to 15% by mass, particularly preferably 5 to 12.5% ​​by mass, with 5 to 10% by mass being the most preferred, and 5 to 8% by mass being the most preferred, based on 100% by mass of the total mass of the light-absorbing portion. By including a fade-preventing agent within the above preferred range, the optical component of the present invention can improve the lightfastness of dyes (pigments) without causing side effects such as discoloration of the light-absorbing portion.

[0282] <Other ingredients> The light-absorbing portion may also contain, as other components besides the aforementioned dye, matrix resin, and dye fade inhibitor, a matting agent or a leveling (surfactant) agent.

[0283] (Mat agent) It is preferable to add fine particles to the surface of the light-absorbing portion to provide slipperiness and prevent blocking. Preferably, silica (silicon dioxide, SiO2) with a hydrophobic surface and in the form of secondary particles is used as the fine particles. Alternatively, fine particles of titanium dioxide, aluminum oxide, zirconium oxide, calcium carbonate, talc, clay, calcined kaolin, calcined calcium silicate, hydrated calcium silicate, aluminum silicate, magnesium silicate, and calcium phosphate may be used in place of silica. Examples of commercially available fine particles include R972 and NX90S (both manufactured by Nippon Aerosil Co., Ltd., trade names).

[0284] These fine particles function as a so-called matting agent, and the addition of these fine particles creates minute irregularities on the surface of the light-absorbing portion. These irregularities prevent the light-absorbing portions from sticking together or from overlapping with other films, ensuring smoothness. When the above light-absorbing portion contains a matting agent as fine particles, the minute irregularities caused by protrusions of fine particles from the filter surface are such that there are 10 protrusions with a height of 30 nm or more. 4 pieces / mm 2 When these are present, the improvement in slipperiness and blocking properties is particularly significant.

[0285] Applying the matting agent fine particles to the surface is particularly preferable from the viewpoint of improving blocking and slipperiness. Methods for applying the fine particles to the surface include multi-layer casting and coating. The amount of matting agent in the light-absorbing section described above is adjusted as appropriate depending on the purpose. However, when a gas barrier layer is provided in the optical member of the present invention, it is preferable to apply the above-mentioned matting agent fine particles to the surface of the light-absorbing portion that is in contact with the gas barrier layer, to the extent that the effects of the present invention are not impaired.

[0286] (Leveling agent) A leveling agent (surfactant) can be appropriately mixed into the light-absorbing portion described above. Commonly used compounds can be used as the leveling agent, and fluorine-containing surfactants are particularly preferred. Specifically, for example, the compounds described in paragraphs

[0028] to

[0056] of the Japanese Patent Publication No. 2001-330725 can be cited. The amount of leveling agent in the light-absorbing section described above is adjusted as appropriate depending on the purpose.

[0287] In addition to the above components, the light-absorbing portion may also contain low molecular weight plasticizers, oligomeric plasticizers, retardation modifiers, ultraviolet absorbers, degradation inhibitors, peeling accelerators, infrared absorbers, antioxidants, fillers, and compatibilizers.

[0288] <Method for manufacturing the light-absorbing part> The above-mentioned light-absorbing portion can be manufactured by conventional methods, such as solution film formation, melt extrusion, or a method of forming a coating layer on a base film (release film) by any method (coating method), and stretching may be combined as appropriate. The above-mentioned light-absorbing portion is preferably manufactured by the coating method.

[0289] (solution film forming method) In the solution-based film formation method, a solution is prepared by dissolving the light-absorbing material in an organic solvent or water. After performing concentration and filtration steps as appropriate, the solution is uniformly cast onto a support. Next, the semi-dry film is peeled from the support, and the solvent is dried in a drying zone while holding both ends of the web with clips or the like as appropriate. Stretching can also be performed separately during and after the film is drying.

[0290] (Melting extrusion method) In the melt extrusion method, the material constituting the light-absorbing portion (hereinafter also simply referred to as "light-absorbing portion material") is melted by heat, and after appropriate processes such as filtration are carried out, it is uniformly cast onto a support. Next, the film, which has solidified by cooling, can be peeled off and stretched as appropriate. When the main material of the light-absorbing portion is a thermoplastic polymer resin, the main material of the release film is also selected to be a thermoplastic polymer resin, and the molten polymer resin can be used to produce a film by a known co-extrusion method. In this case, the adhesion strength between the light-absorbing portion and the release film can be controlled by adjusting the type of polymer of the light-absorbing portion and the release film, the additives mixed in each layer, and by adjusting the stretching temperature, stretching speed, stretching ratio, etc., of the co-extruded film.

[0291] Examples of co-extrusion methods include the co-extrusion T-die method, the co-extrusion inflation method, and the co-extrusion lamination method. Among these, the co-extrusion T-die method is preferred. The co-extrusion T-die method includes a feed block method and a multi-manifold method. Of these, the multi-manifold method is particularly preferred because it can reduce variations in thickness.

[0292] When employing the co-extrusion T-die method, the melting temperature of the resin in the extruder with the T-die is preferably 80°C higher than the glass transition temperature (Tg) of each resin, more preferably 100°C higher, and the upper limit is preferably 180°C higher or lower, more preferably 150°C higher or lower. By setting the melting temperature of the resin in the extruder to be above the lower limit of the above preferred range, the fluidity of the resin can be sufficiently increased, and by setting it to be below the upper limit of the above preferred range, resin degradation can be prevented.

[0293] Typically, the sheet-like molten resin extruded from the die opening is made to adhere closely to the cooling drum. The method for adhering the molten resin to the cooling drum is not particularly limited and includes, for example, an air knife method, a vacuum box method, or an electrostatic adhesion method. There are no particular restrictions on the number of cooling drums, but there are usually two or more. The arrangement of the cooling drums is also not particularly restricted, although examples include linear, Z-shaped, and L-shaped configurations. Furthermore, there are no particular restrictions on how the molten resin extruded from the die opening is passed through the cooling drums.

[0294] The degree to which the extruded sheet-like resin adheres to the cooling drum changes depending on the temperature of the cooling drum. Increasing the temperature of the cooling drum improves adhesion, but if the temperature is too high, the sheet-like resin may not detach from the cooling drum and may wrap around the drum. Therefore, the cooling drum temperature is preferably in the range of (Tg+30)°C or lower, and more preferably in the range of (Tg-5)°C to (Tg-45)°C, where Tg is the glass transition temperature of the resin layer that comes into contact with the drum from the resin extruded from the die. By setting the cooling drum temperature within the above preferred range, defects such as slippage and scratches can be prevented.

[0295] Here, it is preferable to reduce the residual solvent content in the film before stretching. Means for achieving this include, for example, (1) reducing the residual solvent in the raw material resin; and (2) pre-drying the resin before forming the film before stretching. Pre-drying is performed, for example, by putting the resin into a pellet form and using a hot air dryer. The drying temperature is preferably 100°C or higher, and the drying time is preferably 2 hours or higher. By performing pre-drying, it is possible to reduce the residual solvent in the film before stretching and to prevent foaming of the extruded sheet-like resin.

[0296] (Coating method) In the coating method, a solution of the light-absorbing material is applied to a release film to form a coating layer. A release agent or the like may be applied to the surface of the release film beforehand to control the adhesion to the coating layer. The coating layer can be used after being laminated with other components via an adhesive layer in a subsequent process, and then the release film is peeled off. Any adhesive can be used as the adhesive that constitutes the adhesive layer. The release film can be stretched as appropriate while it is either coated with the light-absorbing material solution or with the coating layer laminated on it.

[0297] The solvent used in the solution of the light-absorbing material can be appropriately selected from the viewpoint of being able to dissolve or disperse the light-absorbing material, easily forming a uniform surface during the coating and drying processes, ensuring liquid storage, and having an appropriate saturated vapor pressure.

[0298] - Addition of dyes (pigments) - The timing of adding the above dye to the light-absorbing material is not particularly limited, as long as it is added at the time of film formation. For example, it may be added at the time of synthesis of the matrix resin, or it may be mixed with the light-absorbing material when preparing the coating solution for the light-absorbing material. The same applies to other various additives.

[0299] -Release film- The release film used to form the light-absorbing portion by a coating method or the like preferably has a film thickness of 5 to 100 μm, more preferably 10 to 75 μm, and even more preferably 15 to 55 μm. If the film thickness is above the preferred lower limit, it is easier to ensure sufficient mechanical strength and failures such as curling, wrinkling, and buckling are less likely to occur. Furthermore, if the film thickness is below the preferred upper limit, when the multilayer film of the light-absorbing portion and the release film is stored, for example, in a long roll form, it is easier to adjust the surface pressure on the multilayer film to an appropriate range and adhesion failures are less likely to occur.

[0300] The surface energy of the release film is not particularly limited, but the adhesive strength between the light-absorbing portion and the release film can be adjusted by adjusting the relationship between the surface energy of the light-absorbing portion material and coating solution and the surface energy of the side of the release film where the light-absorbing portion is formed. Reducing the surface energy difference tends to increase the adhesive strength, while increasing the surface energy difference tends to decrease the adhesive strength, and this can be set as appropriate.

[0301] The surface energy of the release film can be calculated from the contact angle values ​​of water and methylene iodide using Owens' method. For measuring the contact angle, for example, a DM901 (contact angle meter manufactured by Kyowa Interface Science Co., Ltd.) can be used. The surface energy of the side of the release film that forms the light-absorbing portion is preferably 41.0 to 48.0 mN / m, and more preferably 42.0 to 48.0 mN / m. If the surface energy is above the above preferred lower limit, the uniformity of the thickness of the light-absorbing portion can be improved, and if it is below the above preferred upper limit, the peeling force between the light-absorbing portion and the release film can be easily controlled within an appropriate range.

[0302] Furthermore, while the surface irregularities of the release film are not particularly limited, they can be adjusted, for example, to prevent adhesive failure when storing a multilayer film of the light-absorbing portion and release film in a long roll form, depending on the relationship between the surface energy, hardness, and surface irregularities of the light-absorbing portion surface and the surface energy and hardness of the surface of the release film opposite to the side where the light-absorbing portion is formed. Increasing the surface irregularities tends to suppress adhesive failure, while decreasing the surface irregularities tends to reduce the surface irregularities of the light-absorbing portion and thus reduce the haze of the light-absorbing portion, and can be set as appropriate.

[0303] Any material and film can be used as such a release film. Specific materials include polyester polymers (including polyethylene terephthalate films), olefin polymers, cycloolefin polymers, (meth)acrylic polymers, cellulose polymers, and polyamide polymers. Furthermore, surface treatments can be applied as appropriate to adjust the surface properties of the release film. To lower the surface energy, for example, corona treatment, room-temperature plasma treatment, or saponification treatment can be performed, while to increase the surface energy, silicone treatment, fluorine treatment, or olefin treatment can be performed.

[0304] -Peel strength between the light-absorbing part and the release film- When the above-mentioned light-absorbing portion is formed by a coating method, the peeling force between the light-absorbing portion and the release film can be controlled by adjusting the material of the light-absorbing portion, the material of the release film, the internal strain of the light-absorbing portion, etc. This peeling force can be measured, for example, by a test in which the release film is peeled in a 90° direction, and when measured at a speed of 300 mm / min, the peeling force is preferably 0.001 to 5 N / 25 mm, more preferably 0.01 to 3 N / 25 mm, and even more preferably 0.05 to 1 N / 25 mm. If it is above the above preferred lower limit, peeling outside of the release film peeling process can be prevented, and if it is below the above preferred upper limit, peeling defects in the peeling process (e.g., zipping and cracking of the light-absorbing portion) can be prevented.

[0305] <Thickness of the light-absorbing layer> The film thickness of the light-absorbing portion described above is not particularly limited, but is preferably 1 to 18 μm, more preferably 1 to 12 μm, and even more preferably 2 to 8 μm. If it is below the above preferred upper limit, adding a high concentration of dye to a thin film can suppress the decrease in polarization degree due to fluorescence emitted by the dye (pigment). In addition, the effects of quenchers and fade inhibitors are also easily exhibited. On the other hand, if it is above the above preferred lower limit, it becomes easier to maintain uniformity of absorbance within the surface. In this invention, a film thickness of 1 to 18 μm means that the thickness of the light-absorbing portion is within the range of 1 to 18 μm regardless of where it is measured. The same applies to film thicknesses of 1 to 12 μm and 2 to 8 μm. The film thickness can be measured using an electronic micrometer manufactured by Anritsu Corporation.

[0306] <Absorbance of the light-absorbing part> The absorbance of absorption waveforms A to D in the above-mentioned light-absorbing section can be appropriately adjusted by the type and amount of dye added, within the range in which the effects of the present invention are achieved.

[0307] <Moisture content of the light-absorbing area> From the viewpoint of durability, the water content of the light-absorbing portion is preferably 0.5% by mass or less, and more preferably 0.3% by mass or less, under conditions of 25°C and 80% relative humidity, regardless of the film thickness. In this specification, the moisture content of the light-absorbing portion can be measured using a sample with a thicker film thickness as needed. After humidifying the sample for 24 hours or more, the moisture content can be measured using the Karl Fischer method with a moisture meter, sample drying apparatus "CA-03" and "VA-05" (both manufactured by Mitsubishi Chemical Corporation), and calculated by dividing the moisture content (g) by the sample mass (g, including moisture content).

[0308] <Glass transition temperature (Tg) of the light-absorbing region> The glass transition temperature of the light-absorbing portion described above is preferably 50°C to 140°C. More preferably, it is 60°C to 130°C, and even more preferably 70°C to 120°C. If the glass transition temperature is above the preferred lower limit, degradation of the polarizer when used at high temperatures can be suppressed, and if the glass transition temperature is below the preferred upper limit, the likelihood of the organic solvent used in the coating solution remaining in the light-absorbing portion can be suppressed. The glass transition temperature of the light-absorbing region can be measured by the following method. Using a differential scanning calorimetry system (X-DSC7000, manufactured by IT Measurement & Control Co., Ltd.), 20 mg of the light-absorbing element was placed in a measurement pan. This was heated from 30°C to 120°C at a rate of 10°C / min in a nitrogen stream and held for 15 minutes, then cooled to 30°C at -20°C / min. After this, the temperature was heated again from 30°C to 250°C at a rate of 10°C / min, and the temperature at which the baseline began to shift from the lower temperature side was defined as the glass transition temperature (Tg). The glass transition temperature of the light-absorbing portion can be adjusted by mixing two or more polymers with different glass transition temperatures, or by changing the amount of low-molecular-weight compounds such as anti-fading agents added.

[0309] <Treatment of light-absorbing areas> The light-absorbing portion may be subjected to hydrophilic treatment by any glow discharge treatment, corona discharge treatment, or alkaline saponification treatment, with corona discharge treatment being preferred. It is also preferable to apply methods disclosed in Japanese Patent Publication No. 6-94915 or No. 6-118232, etc.

[0310] The resulting film can be subjected to heat treatment, superheated steam contact, organic solvent contact, and other processes as needed. Surface treatment may also be performed as appropriate.

[0311] Furthermore, an adhesive layer can also be applied, consisting of an adhesive composition that uses (meth)acrylic resin, styrene resin, silicone resin, etc., as a base polymer, to which a crosslinking agent such as an isocyanate compound, epoxy compound, or aziridine compound is added. Preferably, the description of the adhesive layer in the display device of the present invention, as described later, can be applied.

[0312] <<Gas barrier layer>> The optical component of the present invention may also have a gas barrier layer on at least one side of the light-absorbing portion. This gas barrier layer contains a crystalline resin, has a thickness of 0.1 μm to 10 μm, and has an oxygen permeability of 60 cc / m². 2 It is less than or equal to the day and ATM. In the gas barrier layer described above, the "crystalline resin" is a resin that has a melting point at which it undergoes a phase transition from crystal to liquid when the temperature is raised, and which can impart gas barrier properties related to oxygen gas to the gas barrier layer.

[0313] The optical component of the present invention has a gas barrier layer on at least the surface on which the light-absorbing portion comes into contact with air when the optical component of the present invention is used, thereby suppressing a decrease in the absorption intensity of the dye in the light-absorbing portion. As long as the gas barrier layer is provided at the interface of the light-absorbing portion that comes into contact with air, the gas barrier layer may be provided on only one side of the light-absorbing portion or on both sides.

[0314] (Crystalline resin) The crystalline resin included in the gas barrier layer can be any crystalline resin having gas barrier properties, and can be used without particular limitations as long as it can impart a desired oxygen permeability to the gas barrier layer. Examples of the crystalline resins mentioned above include polyvinyl alcohol and polyvinylidene chloride, and polyvinyl alcohol is preferred because the crystalline portion can effectively suppress gas permeation. The polyvinyl alcohol described above may or may not be modified. Examples of modified polyvinyl alcohol include those to which groups such as acetoacetyl groups and carboxyl groups have been introduced. From the viewpoint of further enhancing the oxygen gas barrier properties, the degree of saponification of the above polyvinyl alcohol is preferably 80.0 mol% or higher, more preferably 90.0 mol% or higher, even more preferably 97.0 mol% or higher, and particularly preferably 98.0 mol% or higher. There is no particular upper limit, but 99.99 mol% or lower is practical. The degree of saponification of the above polyvinyl alcohol is a value calculated based on the method described in JIS K 6726 1994. The above gas barrier layer may contain any components that are normally included in a gas barrier layer, as long as they do not impair the effects of the present invention. For example, in addition to the above crystalline resin, amorphous resin materials, organic-inorganic hybrid materials such as sol-gel materials, SiO2, SiO2 x , SiON, SiN x It may also contain inorganic materials such as Al2O3. Furthermore, the gas barrier layer may contain solvents such as water and organic solvents resulting from the manufacturing process, to the extent that it does not impair the effects of the present invention. The content of crystalline resin in the gas barrier layer described above is preferably 90% by mass or more, and more preferably 95% by mass or more, of 100% by mass of the total mass of the gas barrier layer. There is no particular upper limit, but it can also be 100% by mass.

[0315] The oxygen permeability of the above gas barrier layer is 60 cc / m³. 2 • Day • ATM or less, 50cc / m 2 It is preferable that the daily atm is less than or equal to 30cc / m 2 It is more preferable that it is less than or equal to day·atm, 10cc / m 2 It is even more preferable that it be less than or equal to 5cc / m² / day·atm. 2 It is particularly preferable that it be less than or equal to 1 cc / m³ / day·atm. 2 It is most preferable that the value be less than or equal to 0.001 cc / m³. A practical lower limit is 0.001 cc / m³. 2 • day • atm or higher, for example, 0.05 cc / m 2 It is preferable that the oxygen permeability exceeds day·atm. Having the oxygen permeability within the above preferred range can further improve light resistance. The oxygen permeability of the gas barrier layer was measured according to the gas permeability test method based on JIS K 7126-2 2006. For example, a MOCON OX-TRAN2 / 21 oxygen permeability meter can be used as the measuring device. The measurement conditions were 25°C and 50% relative humidity. Oxygen permeability can be expressed in SI units as (fm) / (s·Pa). (1 fm) / (s·Pa) = 8.752(cc) / (m 2 It is possible to convert using the format (day / atm). fm is read as femtometer, and 1 fm = 10 -15 Represents m.

[0316] From the viewpoint of further improving light resistance, the thickness of the gas barrier layer is preferably 0.5 μm to 5 μm, and more preferably 1.0 μm to 4.0 μm. The thickness of the gas barrier layer described above can be measured, for example, by taking a cross-sectional photograph of the optical component of the present invention using a field emission scanning electron microscope S-4800 (product name) manufactured by Hitachi High-Technologies Corporation.

[0317] The degree of crystallinity of the crystalline resin contained in the gas barrier layer is preferably 25% or more, more preferably 40% or more, and even more preferably 45% or more. There is no particular upper limit, but it is practical to be 55% or less, and preferably 50% or less. The degree of crystallinity of the crystalline resin contained in the above gas barrier layer is measured and calculated using the following method, based on the method described in J. Appl. Pol. Sci., 81, 762 (2001). Using a DSC (Scanning Calorimeter), the heat of fusion 1 of the sample peeled from the gas barrier layer is measured by increasing the temperature at a rate of 10°C / min from 20°C to 260°C. The value described in J. Appl. Pol. Sci., 81, 762 (2001) is used as the heat of fusion 2 for a perfect crystal. The degree of crystallinity is calculated using the following formula based on the obtained heats of fusion 1 and 2. [Degree of crystallinity (%)] = ([Heat of fusion 1] / [Heat of fusion 2]) × 100 Specifically, the above degree of crystallinity is a value measured and calculated by the method described in the examples below. Note that the heat of fusion 1 and heat of fusion 2 can be in the same unit, usually Jg. -1 That is the case.

[0318] <Method for manufacturing a gas barrier layer> The method for forming the gas barrier layer is not particularly limited, but conventional methods such as spin coating and casting methods such as slit coating are examples. Another example is a method of laminating a commercially available resin gas barrier film or a pre-fabricated resin gas barrier film to the light-absorbing portion.

[0319] <<Light bending part>> The light bending portion in the optical component of the present invention has the function of bending and emitting a portion of the amount of light from the incident straight-traveling light. The above-mentioned light bending portion preferably bends 1 to 20% of the amount of light from the incident straight-traveling light, that is, it is preferable that the bending ratio is 1 to 20%. The refractive index R is calculated using the following formula by irradiating the low refractive index portion of the light bending section (preferably the light bending filter) with measurement light using a Haze Meter NDH2000 (product name) manufactured by Nippon Denshoku Industries Co., Ltd., measuring the parallel line transmittance Pt and the total light transmittance Tt. (Formula) R = (Tt - Pt) / Tt × 100

[0320] The total light transmittance of the above-mentioned light-bending portion is preferably 99% or higher from the viewpoint of visibility when the display device is lit. There is no particular upper limit, but it is practical to have a value of 99.9% or lower. Total light transmittance is a value measured using the Haze Meter NDH2000 (product name) manufactured by Nippon Denshoku Industries Co., Ltd.

[0321] The above-mentioned light bending portion preferably has regions with different refractive indices, from the viewpoint of refracting light at the interface and bending a portion of the incident straight-traveling light, and more preferably has at least region I and region II which has a refractive index different from region I. The above-mentioned light bending portion may have one or more regions with refractive indices different from both region I and region II. In the following explanation, we will assume that Region I is a region exhibiting a higher refractive index than Region II (hereinafter referred to as the "high refractive index region"), and Region II is a region exhibiting a lower refractive index than Region I (hereinafter referred to as the "low refractive index region").

[0322] Materials constituting the above-mentioned high refractive index region include metals such as indium, tin, titanium, zinc, zirconium, niobium, magnesium, bismuth, cerium, tantalum, aluminum, germanium, potassium, antimony, neodymium, lanthanum, thorium, and hafnium, as well as alloys composed of two or more of these metals, and oxides, fluorides, sulfides, and nitrides thereof. Specifically, examples include titanium oxide, niobium oxide, zirconium oxide, tantalum oxide, zinc oxide, indium oxide, and cerium oxide. These are preferably in particle form. From the viewpoint of refractive index, the above-mentioned high refractive index region preferably contains zirconium oxide particles.

[0323] The particle size of the particles constituting the high refractive index region described above is not particularly limited, but is preferably 1 to 120 nm, more preferably 1 to 60 nm, and even more preferably 2 to 40 nm. The particle size described above and the particle size described in the examples below are values ​​measured by the particle size measurement method for hollow particles described below. The particles constituting the high refractive index region described above are preferably contained in the resin. The resin is not particularly limited, but examples include urethane acrylate cured products, epoxy acrylate cured products, polyether acrylate cured products, polyester acrylate cured products, and polythiol cured products.

[0324] The content of the above particles in the high refractive index region is preferably 5 to 30% by mass, more preferably 10 to 30% by mass, and even more preferably 20 to 30% by mass. The refractive index in the high refractive index region described above is not particularly limited as long as it exceeds the refractive index in the low refractive index region, but it is preferably 1.49 or higher, more preferably above 1.49, even more preferably 1.53 or higher, and particularly preferably 1.58 or higher. The refractive index described above and the refractive index described in the examples below are values ​​measured by the refractive index measurement method in the low refractive index region described below.

[0325] The low refractive index region described above preferably contains an adhesive or hollow particles.

[0326] (Adhesive) As for the adhesive included in the low refractive index region mentioned above, any ordinary adhesive can be used without any particular restrictions, as long as it can impart low refractive index. Examples include adhesives containing acrylic resin or methacrylic resin. As a commercially available product, for example, the Opteria D692 (product name) manufactured by Lintec Corporation can be used.

[0327] (hollow particles) In this invention, a hollow particle refers to a particle having an outer shell layer, in which the interior of the particle surrounded by this outer shell layer is porous or hollow, and which contains air inside the particle. By including the above-mentioned hollow fine particles, the refractive index in the low refractive index region can be adjusted to be low. The refractive index of the hollow particles is preferably 1.49 or less, and more preferably 1.45 or less, from the viewpoint of imparting a low refractive index.

[0328] The outer shell layer of the hollow particle described above may be made of either organic or inorganic material. Examples of organic materials include (meth)acrylic resins and styrene-based resins. Examples of inorganic materials include metal oxides, more specifically silica, titania, zirconia, and antimony pentoxide. Silica is more preferably used as the outer shell layer of the hollow particles.

[0329] The shape of the hollow particles described above is not particularly limited, but examples include approximately spherical, chain-like, needle-like, plate-like, flake-like, rod-like, and fibrous shapes such as perfect spheres, ellipsoidal, and polyhedral shapes that can approximate a sphere. More preferably, a spherical shape is used.

[0330] The particle size of the hollow particles described above is not particularly limited, but the average particle size (hereinafter sometimes simply referred to as "average particle size (d50)"), which is defined as the 50% particle size (d50 median diameter) when the particle size distribution measured by the dynamic light scattering method is expressed as a volume cumulative distribution, is preferably 5 to 120 nm, more preferably 10 to 100 nm, and most preferably 40 to 90 nm. If the average particle size (d50) of the hollow particles is below the upper limit, the resulting low refractive index region will have excellent transparency. If it is above the lower limit, these hollow particles will be easily dispersed uniformly in the low refractive index region, making it easier to impart low refractive index properties to the low refractive index region. Furthermore, the average particle size (d50) mentioned above shall be the average particle size (d50) of the primary particle size if the hollow particles are not aggregated, and the average particle size (d50) of the secondary particle size if the hollow particles are aggregated. Furthermore, the above average particle size (d50) can be measured using a Microtrac particle size analyzer or a Nanotrac particle size analyzer manufactured by Nikkiso Co., Ltd.

[0331] Furthermore, if the low refractive index region is a cured product, it can be measured from TEM (Transmission Electron Microscope) or SEM (Scanning Electron Microscope) images of the low refractive index region after curing. The average particle size of the hollow particles is not particularly limited, but it is preferably 40 nm or larger. The above method for measuring the average particle size involves, for example, observing the particles using TEM or SEM images taken at 50 to 2 million times magnification, and using the average value of the particle sizes of 100 observed particles as the average particle size. If the shape of the hollow particle is a spheroid or rod-shaped form with a minor and major axis, which involves the concept of aspect ratio, the particle size of this hollow particle should be the average of the minor and major axes. Furthermore, the average particle size measured from TEM or SEM images shall be the average particle size of the primary particle if the hollow particles are not aggregated, and the average particle size of the secondary particle if the hollow particles are aggregated.

[0332] The content of the hollow particles is preferably 10 to 80 parts by mass per 100 parts by mass of the binder resin, as described later. A content of hollow particles above the lower limit makes it easier to impart low refractive index properties, while a content below the upper limit improves the film strength in the low refractive index region formed. The refractive index in the low refractive index region is not particularly limited as long as it is less than the refractive index in the high refractive index region, but it is preferably 1.49 or less, more preferably 1.47 or less, and even more preferably 1.45 or less. The above refractive index can be measured using an Abbe refractometer (for example, the RX-7000α manufactured by Atago Corporation).

[0333] The above-mentioned light bending portion is preferably a light bending filter having a high-refractive index region and a low-refractive index region on a support substrate, and more preferably a light bending filter having a high-refractive index region in a striped pattern on the support substrate, with a low-refractive index region provided so as to cover the surface on which the high-refractive index region is provided and the exposed support substrate and the striped high-refractive index region. The above-mentioned support substrate can be used without particular limitations as long as it does not impair the effects of the present invention, and is preferably a film formed from a resin exhibiting optical isotropy, and more preferably a triacetylcellulose film.

[0334] <Film thickness in the light-bending section> The film thickness of the above-mentioned light-bending portion is not particularly limited, but a total thickness of 30 to 70 μm is preferred, and 45 to 65 μm is more preferred. The thickness of the support substrate is preferably 35 to 60 μm, more preferably 45 to 55 μm; the thickness of the high refractive index region (the thickness of the thickest part when arranged in a stripe pattern) is preferably 5 to 20 μm, more preferably 5 to 15 μm; and the thickness of the low refractive index region (the thickness of the thickest part) is preferably 10 to 30 μm, more preferably 10 to 20 μm. The film thickness can be measured using an electronic micrometer manufactured by Anritsu Corporation.

[0335] The method for manufacturing the above-mentioned light-bending portion is not particularly limited, but for example, it can be manufactured by forming a high-refractive index region on a support substrate in a desired shape using a mold roll or the like, and then laminating a film showing a low-refractive index region onto it. As an optical bending portion (preferably an optical bending filter) having a high refractive index region and a low refractive index region, the description of an optical film having a high refractive index pattern layer and a low refractive index pattern layer as described in Japanese Patent Application Publication No. 2014-123568 can be applied, to the extent that it does not impair the effects of the present invention.

[0336] <Optical film> In addition to the light-absorbing portion and the light-bending portion, and the gas barrier layer described above, the optical member of the present invention may also have any optical film as appropriate, as long as it does not impair the effects of the present invention. There are no particular restrictions on the optical properties or materials of the above-mentioned optical film, but films containing (or primarily composed of) at least one of cellulose ester resin, acrylic resin, cyclic olefin resin, and polyethylene terephthalate resin are preferably used. Furthermore, either optically isotropic films or optically anisotropic phase-difference films may be used. For the optical films mentioned above, those containing cellulose ester resin include, for example, Fujitac TD80UL, TG60UL, and TJ40UL (all manufactured by Fujifilm Corporation). Regarding the above-mentioned arbitrary optical films, those containing acrylic resin can include an optical film containing a (meth)acrylic resin containing a styrene-based resin as described in Japanese Patent Publication No. 4570042, an optical film containing a (meth)acrylic resin having a glutarimide ring structure as its main chain as described in Japanese Patent Publication No. 5041532, an optical film containing a (meth)acrylic resin having a lactone ring structure as described in Japanese Patent Application Publication No. 2009-122664, and an optical film containing a (meth)acrylic resin having glutaric acid anhydride units as described in Japanese Patent Application Publication No. 2009-139754. Furthermore, for the above-mentioned arbitrary optical film, as one containing a cyclic olefin resin, it is possible to use a cyclic olefin resin film described in paragraph

[0029] and subsequent paragraphs of Japanese Patent Publication No. 2009-237376, a cyclic olefin resin film containing an additive that reduces Rth as described in Japanese Patent Publication No. 4881827, and Japanese Patent Publication No. 2008-063536.

[0337] Furthermore, any of the above optical films may contain an ultraviolet absorber. Any commonly used compound can be used as the ultraviolet absorber without any particular limitations. The amount of UV absorber in the UV-absorbing layer described above is adjusted as appropriate depending on the purpose.

[0338] <<Manufacturing Method for Optical Components>> The light-absorbing portion in the optical component of the present invention can be manufactured by the method for manufacturing the light-absorbing portion described above. The optical bending portion in the optical component of the present invention can be manufactured by the method for manufacturing the optical bending portion described above. The optical component of the present invention is preferably manufactured by bonding a light-bending portion and a light-absorbing portion, both produced by the manufacturing method described above, together with an adhesive. Furthermore, if a gas barrier layer is present, it can be manufactured by the gas barrier layer manufacturing method described above. For example, one method is to directly manufacture the gas barrier layer on the light-absorbing portion manufactured by the manufacturing method described above. In this case, it is also preferable to perform corona treatment on the surface of the light-absorbing portion on which the gas barrier layer is to be installed. Furthermore, if any of the above-mentioned optical films are provided, it is also preferable to bond them together via an adhesive layer. As for the adhesive, the description of the adhesive in the display device of the present invention, as described later, can be preferably applied.

[0339] [Display device of the present invention] The display device of the present invention includes an optical element for use in the display device of the present invention and a light-emitting part, wherein the light-emitting part is an organic electroluminescent light-emitting element (organic EL light-emitting element) or a micro light-emitting diode (micro LED). As the light-emitting part, for example, an organic electroluminescent light-emitting element described in Japanese Patent Publication No. 2020-187261, or a microLED described in International Publication No. 2014 / 204694, etc., are preferred. The optical member of the present invention can also be applied to the optical member of the present invention in configurations that do not have a microcavity structure. In particular, it can be suitably used in a display device having a microcavity structure. The above-described organic EL light-emitting element has a structure in which an anode electrode, a light-emitting layer, and a cathode electrode are stacked in that order. Between the anode electrode and the cathode electrode, in addition to the light-emitting layer, a hole injection layer, a hole transport layer, an electron transport layer, and an electron injection layer are included. For further information, see, for example, Japanese Patent Application Publication No. 2014-132522. Even when these light-emitting elements have a microcavity structure, the optical components of the present invention can be used to adjust the color tone in oblique directions to a neutral level, and can achieve an excellent balance between suppressing external light reflection and suppressing brightness reduction.

[0340] As long as the present invention includes a display device in which the light-emitting portion is an organic electroluminescent light-emitting element or a microlight-emitting diode, and the optical component of the present invention is located on the side of the ambient light side of the light-emitting portion, and the light-absorbing portion of the optical component of the present invention is located on the side of the ambient light side of the light-bending portion, then other components can be those of a commonly used display device without particular limitation. As long as the display device has the specific light-emitting part described above, it can be used without any particular limitations, and for example, OLED display devices, microLED display devices, etc., can be preferably used. Examples of the configuration of the display device of the present invention are not particularly limited, but include a display device comprising, in order from the side opposite to ambient light, glass, a layer containing a TFT (thin film transistor), a light-emitting section, a barrier film, a color filter, glass, an adhesive layer, the optical component of the present invention, an adhesive layer, and a surface film. The light source of the present invention may be a single blue color, or it may use the three primary colors of blue, green, and red. When using a single blue color as the light source, the blue light can be converted into green and red light using a wavelength conversion material such as a phosphor or quantum dot.

[0341] The wavelength conversion materials mentioned above refer to materials that convert wavelengths by absorbing light of a specific wavelength and emitting light of a different wavelength on the longer side of the absorption wavelength. Specifically, examples include phosphors containing quantum dots. In the display device of the present invention, the wavelength conversion material may be installed so as to be incorporated into the LED light source, or it may be installed as a wavelength conversion sheet at a location other than the light source. When installed at a location other than the light source, it can be provided as a wavelength conversion sheet on the viewer side relative to the light-emitting part (light-emitting element), and it is preferable to provide a quantum dot sheet (also called a QD sheet) on the viewer side relative to the light-emitting part (light-emitting element). Since the QD sheet is a scatterer, when a circular polarizer is used for anti-reflection purposes, the polarization of the circular polarizer is eliminated and the reflectance suppression function is not exhibited. In contrast, in the display device of the present invention, the synergistic effect of light diffusion in the QD sheet and absorption of a specific wavelength range by the light-absorbing part makes it possible to suppress ambient light reflection at a better level while simultaneously suppressing ambient light reflection and brightness reduction. In particular, the method of stacking color filters on a layer made of wavelength conversion materials such as quantum dots is preferable to the conventional method of incidenting white light onto the color filter because it provides display light with high light transmittance and high color purity.

[0342] Wavelength conversion materials are described below.

[0343] (Green phosphor) Green phosphors are wavelength conversion materials that absorb a portion of the light emitted by blue LEDs and emit green light with an emission peak in the 500-595 nm wavelength range. An example of such a green phosphor is Y3Al5O 12 :Ce 3+ Tb3Al5O 12 :Ce 3+ BaY2SiAl4O 12 :Ce 3+ Ca3Sc2Si3O 12 :Ce 3+ (Ba,Sr)2SiO4:Eu 2+ CaSc2O4:Ce 3+ Ba3Si6O 12 N2:Eu 2+ β-SiAlON:Eu 2+ SrGa2S4:Eu 2+ LaSiN:Ce 3+ CaSi2O2N2:Eu 2+ Lu3Al5O 12 :Ce 3+ (LAG) or SrSi2O2N2:Eu 2+ These are some examples.

[0344] (Red phosphor) A red phosphor is a wavelength conversion material that absorbs at least one of the light emitted from a blue LED and a portion of the light emitted from a green phosphor, and emits red light with an emission peak in the 600-690 nm wavelength range. An example of such a red phosphor is Ca-α-SiAlON:Eu 2+ CaAlSiN3:Eu 2+ (Sr,Ca)AlSiN3:Eu 2+ Sr2Si5N8:Eu 2+ Sr2(Si,Al)5(N,O)8:Eu 2+ CaS:Eu 2+ La2O2S:Eu 3+ K2SiF6:Mn 4+ These are some examples.

[0345] (Quantum dots) As the wavelength conversion material described above, quantum dots are particularly preferred because they provide a sharp emission spectrum. Quantum dots are particles with a major axis of about 1 to 100 nm and have discrete energy levels. Since the energy state of a quantum dot depends on its size, it is possible to freely select the emission wavelength by changing its size. Examples of quantum dots include compounds of group 12 and group 16 elements, compounds of group 13 and group 16 elements, or compounds of group 14 and group 16 elements, such as CdSe, CdTe, ZnS, CdS, InP, PbS, PbSe, and CdHgTe. In addition to quantum dots, quantum rods and the like can also be used as quantum nanomaterials.

[0346] (A matrix that absorbs or scatters ambient light) From the viewpoint of further enhancing the effect of suppressing ambient light reflection, the display device of the present invention may include a matrix that absorbs or scatters ambient light (hereinafter also simply referred to as "matrix"), and it is preferable to have the matrix between the light-emitting elements constituting the light-emitting part.

[0347] Among the matrices described above, an example of a matrix that absorbs ambient light is the black matrix described in paragraph

[0069] of Japanese Patent Publication No. 2018-18807, which is placed between each color of an RGB color filter to prevent reflected light. By placing such a black matrix between each color light-emitting part of the display device of the present invention, ambient light entering the display device of the present invention can be absorbed, and the effect of suppressing ambient light reflection can be further enhanced.

[0348] Among the matrices described above, an example of a matrix that scatters ambient light is the structure having irregularities on its surface, as described in Japanese Patent Publication No. 2019-82594. By arranging such a structure in each color light-emitting section of the display device of the present invention, ambient light entering the display device of the present invention can be scattered, further enhancing the effect of suppressing ambient light reflection.

[0349] When the display device of the present invention includes the above-mentioned matrix, the included matrix may be of one type or of two or more types.

[0350] In addition to conventional color filters, color filters with stacked quantum dots can also be used as color filters. Instead of the glass mentioned above, a resin film can also be used.

[0351] The method for forming a color image applicable to the display device of the present invention is not particularly limited, and any of the following methods can be used: a three-color coloring method using R (red), G (green), and B (blue), a color conversion method, and a color filter method, with the three-color coloring method being preferable. Therefore, each light-emitting layer corresponding to the above-described image forming method can also be applied as a light source for the display device of the present invention.

[0352] <Adhesive layer> In the display device of the present invention, it is preferable that the optical member of the present invention is bonded to glass (substrate) via an adhesive layer such that the light-absorbing portion is on the side of the light-bending portion that is closer to the ambient light.

[0353] The composition of the adhesive composition used to form the adhesive layer is not particularly limited, and for example, the mass-average molecular weight (M w An adhesive composition containing a base resin with a mass-average molecular weight of 500,000 or more may be used. When the mass-average molecular weight of the base resin is less than 500,000, the durability and reliability of the adhesive may decrease, such as the occurrence of bubbles or peeling phenomena under at least one of high temperature and high humidity conditions due to a decrease in cohesive force. There is no particular upper limit to the mass-average molecular weight of the base resin, but if the mass-average molecular weight increases excessively, the coating properties may decrease due to an increase in viscosity, so it is preferable to have a mass-average molecular weight of 2,000,000 or less.

[0354] The specific type of base resin is not particularly limited; examples include acrylic resins, silicone resins, rubber resins, and EVA (ethylene-vinyl acetate) resins. When applied to optical devices such as liquid crystal displays, acrylic resins are mainly used due to their excellent transparency, oxidation resistance, and resistance to yellowing, but the application is not limited to these. Furthermore, the above adhesive composition may contain other components (additives) such as crosslinking agents, antistatic agents, coordination-bonding compounds, and tackifying resins. The components that the above-mentioned acrylic resin and adhesive composition may contain are those described in paragraphs

[0296] to

[0347] of International Publication No. 2021 / 014973, including acrylic resins and other components (additives) such as crosslinking agents, antistatic agents, coordination-bonding compounds, and tackifying resins, and can be applied to the present invention without particular limitation.

[0355] <Base material> In the display device of the present invention, it is preferable that the optical member of the present invention is bonded to glass (substrate) via an adhesive layer such that the light-absorbing portion is on the side of the light-bending portion that is closer to the ambient light.

[0356] The method for forming the adhesive layer is not particularly limited. For example, one method involves applying the adhesive composition to the light-absorbing portion using conventional means such as a bar coater, and then drying and curing it. Another method involves first applying the adhesive composition to the surface of a releaseable substrate, drying it, and then transferring the adhesive layer to the light-absorbing portion using the releaseable substrate, followed by maturation and curing. The release substrate is not particularly limited, and any release substrate can be used, for example, the release film in the above-described method for manufacturing the light-absorbing part. Furthermore, the conditions for application, drying, maturation, and curing can be adjusted as appropriate in accordance with conventional methods. [Examples]

[0357] The present invention will be described in more detail below based on examples. The materials, amounts used, proportions, processing content, and processing procedures shown in the following examples can be modified as appropriate, as long as they do not depart from the spirit of the present invention. Therefore, the scope of the present invention is not limited to the examples shown below. In the following examples, "parts" and "%" representing the composition are based on mass unless otherwise specified. Also, the λ of each dye is... max This refers to the maximum absorption wavelength that shows the highest absorbance originating from each dye in the measurement of the absorption waveform of the light absorption filter described later.

[0358] Examples [1] Fabrication of light-absorbing filters The materials used to fabricate the light absorption filter are listed below.

[0359] <Matrix resin> (Resin 1) Polystyrene resin (manufactured by PS Japan Co., Ltd., PSJ-Polystyrene GPPS, SGP-10 (product name)) (Resin 2) Polyphenylene ether resin (manufactured by Asahi Kasei Corporation, Zylon S201A (product name), poly(2,6-dimethyl-1,4-phenylene oxide), Tg 210℃) (Release-controlling resin component 1) Byron 550 (product name, manufactured by Toyobo Co., Ltd., polyester additive)

[0360] <dye> The following dyes were used as dyes.

[0361] [ka]

[0362] Dye B-2: 1-(methylamino)anthraquinone (purchased from Tokyo Chemical Industry Co., Ltd.) Dye C-2: Manufactured by Yamada Chemical Industry Co., Ltd., FDG-007 (product name) Dye C-3: Quinizalin Blue (Purchased from Tokyo Chemical Industry Co., Ltd.)

[0363] (Fade-resistant agent 1) [ka]

[0364] (Leveling agent 1) A polymer surfactant composed of the following components was used as leveling agent 1. In the following structural formula, the proportion of each component is expressed as a molar ratio, and t-Bu represents a tert-butyl group.

[0365] [ka]

[0366] (Base material 1) Polyethylene terephthalate film Lumirror XD-510P (product name, film thickness 50 μm, manufactured by Toray Industries, Inc.) was used as the base material 1.

[0367] <Fabrication of light-absorbing filter 1 with substrate> (1) Preparation of light-absorbing filter forming solution 1 Each component was mixed in the composition shown below to prepare light-absorbing filter forming solution 1. ------------------------------------------------------------------ Composition of light-absorbing filter-forming solution 1 ------------------------------------------------------------------ Resin 1 49.2 parts by mass Resin 2 17.5 parts by mass Release-controlling resin component 1: 0.20 parts by mass Leveling agent 1 0.08 parts by mass Dye A 13.8 parts by mass Dye C-1 11.7 parts by mass Anti-fading agent 1: 7.5 parts by mass Toluene (solvent) 1710.0 parts by mass Cyclohexanone (solvent) 190.0 parts by mass ------------------------------------------------------------------

[0368] Next, the obtained light absorption filter forming solution 1 was filtered using a filter with an absolute filtration accuracy of 5 μm (product name: Hydrophobic Fluorepore Membrane, manufactured by Millex).

[0369] (2) Fabrication of light-absorbing filter 1 with substrate The light-absorbing filter forming solution 1, after the above filtration treatment, was applied to the substrate 1 using a bar coater so that the film thickness after drying would be 2.5 μm, and dried at 120°C to produce a light-absorbing filter 1 with a substrate.

[0370] <Fabrication of light-absorbing filters 2-7 and C1-C5 with substrates> Except for changing the type and content of the dye as described in Table 1 below, light-absorbing filters 2-7 and C1-C5 with substrates were prepared in the same manner as the preparation of light-absorbing filter 1 with substrates.

[0371] (Absorption waveform of light absorption filter) Using a Shimadzu UV3150 spectrophotometer (product name), the absorbance of a substrate-mounted light absorption filter was measured at 1 nm intervals in the wavelength range of 380 nm to 800 nm. Absorbance Ab of the substrate-mounted light absorption filter at each wavelength λ nm. x (λ) and the absorbance difference between Ab0(λ) of a light-absorbing filter with a substrate that does not contain dye, Ab x (λ)-Ab0(λ) was calculated. Furthermore, the maximum value of this absorbance difference was defined as the absorption maximum, and the wavelength at which this absorption maximum (maximum absorbance) occurs was defined as the maximum absorption wavelength λ. max , two wavelengths λ that give an absorbance half of this absorption maximum value half max and these two wavelengths λ half max The width FWHM between them was calculated.

[0372] (Determination of whether the absorption waveforms A to D as defined in this invention are present) Whether each dye exhibits absorption waveforms A to D as defined in this invention was determined as follows. The maximum emission wavelength λ of the blue, green, and red light emitted by the display device. BMax , λ GMax and λ RMax Furthermore, the values ​​of the display emission spectrum S(λ) used in the evaluation of brightness reduction suppression described later were used as the widths x, y, and z between two wavelengths that give half the absorbance of the maximum emission exhibited by each emission. That is, λ BMax 449nm, λ GMax 535nm, λ RMax The wavelength is 631nm, x is 19nm, y is 37nm, and z is 39nm. Using these values, we determined whether each dye exhibited absorption waveforms A to D as defined in this invention, based on the criteria 1 and 2 shown in Table A below. These results are summarized in Table A.

[0373] [Table A]

[0374] (Notes in the table) In the table, the unit of wavelength is always nm. In the absorption waveform column, A to D mean that each satisfies the requirements for absorption waveforms A to D as defined in this invention, and "-" means that none of the requirements for absorption waveforms A to D as defined in this invention are met. Note that the table indicates that dyes A, B-1, C-1, and D satisfy the requirements for absorption waveforms A to D as defined in this invention, and the specific absorption waveforms shown by dyes A, B-1, C-1, and D are different from the general absorption waveforms A to D as defined in this invention shown in Figure 3. In the judgment column, "〇" means that the judgment criteria listed above are met, and "×" means that the judgment criteria listed above are not met.

[0375] As shown in Table A above, when a light absorption filter containing each of the above dyes is used in the display used in the evaluation of brightness reduction suppression described later, dyes A, B-1, C-1, and D each exhibit absorption waveforms A to D as defined in the present invention. On the other hand, dyes B-2 and C-3 have at least one of two wavelengths that give an absorbance of half the maximum absorption of the dye, within the wavelength range between the maximum emission wavelengths of the display device located on either side of the absorption (between blue and green emission, λ BMax Over λ GMax This refers to the wavelength range less than λ, between green and red emission. GMax Over λ RMax This refers to the wavelength range less than ). As they exist outside this range, they do not exhibit the absorption waveform B or C as defined in this invention. Furthermore, dye C-2 does not satisfy the absorption width defined by relation (2) and does not exhibit the absorption waveform C as defined in this invention.

[0376] [2] Fabrication of the light-bending section The mold roll and nip roll were rotated while supplying a urethane acrylate composition (containing 20% ​​by mass of zirconium oxide particles with a particle size of 20 nm) constituting a high refractive index portion 22 between a support substrate 21 made of a cellulose acylate film 1 prepared as described below and a mold roll having a specific shape. In this way, the urethane acrylate composition was molded onto the cellulose acylate film 1 along the surface shape of the mold roll, and light (ultraviolet light) was irradiated from the molded urethane acrylate composition side using a light irradiation device to cure the urethane acrylate composition. As described above, a film A having a desired shape was obtained on a support substrate 21 composed of a cellulose acylate film 1, with a film having a high refractive index portion 22 composed of a cured product of a urethane acrylate composition. In this film A, the cured urethane acrylate (high refractive index portion 22) has a trapezoidal shape when cut perpendicular to the rotation axis of the mold roll and nip roll, as shown in Figures 1 and 2. The width w1 on the side in contact with the cellulose acylate film 1 (support substrate 21) is 15 μm, the width w2 on the side facing the cellulose acylate film 1 (support substrate 21) is 13 μm, and the thickness h of the high refractive index portion 22 is 10 μm. The distance t between adjacent high refractive index portions on the side in contact with the cellulose acylate film 1 (support substrate 21) is 2 μm. This cross-sectional shape has a striped shape, with the stripes being continuously connected in a direction parallel to the rotation axis of the mold roll and nip roll. The refractive index of the high refractive index portion 22 was 1.60.

[0377] A low refractive index portion 23 was formed by laminating Lintec's Opteria D692 (product name, adhesive, thickness 15 μm) to the side of film A obtained above where the high refractive index portion 22 was formed. The refractive index of the low refractive index portion 23 was 1.49. The thickness of the low refractive index portion 23 (thickness of the thickest part from the support substrate 21 side) was 15 μm. In this way, a light-bending section 2 was fabricated, which is a laminate in which a cellulose acylate film 1 (support substrate 21), a high refractive index section 22, and a low refractive index section 23 are laminated in that order.

[0378] <Preparation of Cellulose Acrylate Film 1> (1) Preparation of cellulose acylate doped core layer The following compositions were placed in a mixing tank and stirred to dissolve each component, preparing a cellulose acetate solution to be used as a cellulose acylate dope for the core layer. ------------------------------------------------------------------ Core layer cellulose acylate doped ------------------------------------------------------------------ 100 parts by mass of cellulose acetate with an acetyl substitution degree of 2.88 The examples described in Japanese Patent Publication No. 2015-227955 Polyester compound B: 12 ​​parts by mass Compound F (listed below): 2 parts by mass Methylene chloride (first solvent) 430 parts by mass Methanol (second solvent) 64 parts by mass ------------------------------------------------------------------

[0379] Compound F [ka]

[0380] (2) Preparation of outer layer cellulose acylate dope A cellulose acetate solution to be used as the outer layer cellulose acylate dope was prepared by adding 10 parts by mass of the following mat agent dispersion to 90 parts by mass of the above core layer cellulose acylate dope.

[0381] ------------------------------------------------------------------ Mat agent dispersion ------------------------------------------------------------------ Silica particles with an average particle size of 20 nm (Product name: AEROSIL R972, manufactured by Nippon Aerosil Co., Ltd.) 2 parts by mass Methylene chloride (first solvent) 76 parts by mass Methanol (second solvent) 11 parts by mass 1 part by mass of the above-mentioned core layer cellulose acylate doped ------------------------------------------------------------------

[0382] (3) Preparation of Cellulose Acrylate Film 1 The core layer cellulose acylate dope and the outer layer cellulose acylate dope were filtered using filter paper with an average pore size of 34 μm and a sintered metal filter with an average pore size of 10 μm, respectively. Then, using a band casting machine, the three layers were simultaneously cast from the casting port onto a drum at 20°C, so that the filtered outer layer cellulose acylate dope was placed on both sides of the filtered core layer cellulose acylate dope. Next, the cast film was peeled from the drum with a solvent content of approximately 20% by mass, and both ends of the film in the width direction were fixed with tenter clips. The film was then dried while being stretched transversely at a stretching ratio of 1.1 times. After that, the film was further dried by being transported between the rolls of a heat treatment apparatus to produce an optical film (transparent support) with a thickness of 40 μm, which was designated as cellulose acylate film 1.

[0383] [3] Fabrication of the laminate Laminates for reflectance measurement of Nos. 101-107 and c11-c17 listed in Table 1 were fabricated as follows, comprising at least one of the light-absorbing filters (light-absorbing portion) from the substrate-attached light-absorbing filters 1-7 and C1-C5 fabricated above, or a circular polarizer, and the light-bending portion (light-bending filter) fabricated above. Laminates No. 101 to 107 are laminates equipped with a light-absorbing portion and a light-bending portion used in the present invention, while laminates No. c11 to c17 are comparative laminates that do not have a light-absorbing portion used in the present invention. Based on the measurement method described above, it was confirmed that the light-bending section fabricated as described above bends 1-20% of the amount of incident straight-traveling light, and that the total light transmittance is 99% or more. Furthermore, the aluminum foil in the laminate used for reflectance measurement shown below is provided to simulate the reflection of ambient light from the metal plate of the light-emitting part of the display device.

[0384] (1) Preparation of laminates without QD sheets A commercially available aluminum foil and a TAC film (triacetylcellulose film, product name: Fujitac TD80UL, manufactured by Fujifilm Corporation) were laminated together using an adhesive A (product name: SK2057, manufactured by Soken Chemical Co., Ltd.) with a thickness of approximately 20 μm. Next, the low refractive index portion 23 side of the light bending portion 2 prepared above was laminated to the matte side (non-glossy side) of the laminated aluminum foil via the adhesive A. Furthermore, the coated film side of the light absorption filter with substrate prepared above was laminated to the cellulose acylate film 1 (support substrate 21) side of the light bending portion 2 via the adhesive A, and the substrate 1 of the light absorption filter with substrate was peeled off. The resulting laminate has a structure in which a light absorption portion 4 consisting of TAC film / adhesive A / aluminum foil / adhesive A / light bending portion 2 / adhesive A / light absorption filter is laminated in this order. Furthermore, when a circular polarizer is used as an anti-reflection means instead of the light-absorbing filter with a substrate prepared above, the laminate equipped with the circular polarizer was prepared in the same manner as above, except that the circular polarizer was used instead of the light-absorbing filter with a substrate.

[0385] (2) Fabrication of a laminate having QD sheets Commercially available aluminum foil and TAC film (triacetylcellulose film, product name: Fujitac TD80UL, manufactured by Fujifilm Corporation) were bonded together via the above-mentioned adhesive A. Next, a QD sheet taken from a display device 8XKB2D6ALBT (product name, manufactured by SEC Corporation) was bonded to the matte side (non-glossy side) of the bonded aluminum foil via the above-mentioned adhesive A. Furthermore, the low refractive index portion 23 side of the light bending portion 2 prepared above was bonded to the QD sheet side via the above-mentioned adhesive A. Furthermore, the coated film side of the light absorption filter with substrate prepared above was bonded to the cellulose acylate film 1 (support substrate 21) side of the light bending portion 2 via the above-mentioned adhesive A, and the substrate 1 of the light absorption filter with substrate was peeled off. The resulting laminate has a structure in which a light absorption portion 4 consisting of TAC film / adhesive A / aluminum foil / adhesive A / QD sheet / adhesive A / light bending portion 2 / adhesive A / light absorption filter is laminated in this order. Furthermore, when a circular polarizer is used as an anti-reflection means instead of the light-absorbing filter with a substrate prepared above, the laminate equipped with the circular polarizer was prepared in the same manner as above, except that the circular polarizer was used instead of the light-absorbing filter with a substrate.

[0386] [evaluation] For each laminate fabricated in [3] above, the effect of suppressing ambient light reflection was evaluated according to the following. In addition, the effect of suppressing brightness reduction was evaluated as described below. The results are summarized in Table 1.

[0387] <1. Effect of suppressing external light reflection> Using a spectrophotometer (Konica Minolta, product name: CM2022), measurements were taken three times, changing the measurement position within the plane, with the measurement light incident from either the light-absorbing section 4 of the laminate or the circular polarizer side. The average of the three Y values ​​in the SCI (Specular Component Include) measurement method was taken as the reflectance, and the effect of suppressing external light reflection was evaluated according to the evaluation criteria below. - Evaluation Criteria - A: The reflectance is less than 5.0%. B: Reflectance is 5.0% or more and less than 5.7% C: Reflectance is between 5.7% and less than 6.3% D: Reflectance is between 6.3% and less than 7.0% E: Reflectance is 7.0% or higher.

[0388] <2. Effect of suppressing brightness reduction> The relative luminance when using the light absorption filter fabricated above was calculated as follows. The emission spectrum S(λ) of the display was calculated using the backlight spectrum of a Samsung 55" Q7F (quantum dot LCD TV, product name). The transmission spectrum of the light absorption filter was defined as T(λ). The luminance without a light absorption filter was calculated by correcting the spectral S(λ) for luminous efficiency, and this luminance was set to 100 (reference value). The luminance of spectral S(λ) × T(λ) with a light absorption filter was calculated as the relative luminance to the luminance without the light absorption filter. In cases where a circular polarizer was used instead of a light absorption filter (No. c11 and c12), the transmittance %T at 550 nm of the circular polarizer was measured using a UV3150 spectrophotometer (product name) manufactured by Shimadzu Corporation, and this transmittance value was defined as the relative luminance.

[0389] Using the relative luminance values ​​obtained from the above simulation, the effect of suppressing luminance reduction was evaluated based on the following evaluation criteria. - Evaluation Criteria - A: 35 < Relative luminance ≤ 100 B: 0 ≤ Relative Brightness ≤ 35

[0390] [Table 1]

[0391] (Notes in the table) The dye content refers to the percentage of dye by mass in the light absorption filter, and the unit is mass%. Each dye refers to dyes A, B-1, B-2, C-1, C-2, C-3, and D as described above. In the columns for the type and dye of the light-absorbing section, the circular polarizer, and the wavelength conversion QD sheet, the notation "-" indicates that the corresponding type and dye of the light-absorbing section and the circular polarizer are not present.

[0392] From the results in Table 1, the following can be seen. Laminates No. c11 and c12 have circular polarizers instead of the light-absorbing portion defined in this invention as an anti-reflection measure, and further have light-bending portions. In these comparative laminates No. c11 and c12, the polarization is eliminated in the light-bending portion, so the reflection suppression of the circular polarizers does not function sufficiently, and external light reflection cannot be sufficiently suppressed. Furthermore, as shown in Table A, the absorption waveform of laminate No. c13, derived from dye C-2, does not satisfy relational equation (2) defined in this invention. Laminate No. c13 used for this comparison was unable to sufficiently suppress ambient light reflection. Furthermore, as shown in Table A, the absorption waveform of the No. c14 laminate originating from dye B-2 is the maximum absorption wavelength λ max One of the two wavelengths that gives half the absorbance is the maximum emission wavelength λ of the display device. BMax 449nm and λ GMax It does not exist in the wavelength range between 535 nm and does not satisfy the definition of the absorption waveform in this invention. As shown in Table A, the absorption waveform of the No. c15 laminate originating from dye C-3 is at the maximum absorption wavelength λ max Both wavelengths that give half the absorbance are the maximum emission wavelength λ of the display device. GMax 535nm and λ RMax The wavelength range between 631 nm is not present, and therefore the absorption waveform does not meet the requirements of the present invention. The No. c14 and c15 laminates used for comparison were unable to sufficiently suppress the decrease in brightness. Furthermore, while No. c16 contains dye B-1 which exhibits absorption waveform B as defined in the present invention, it also contains dye C-3 which does not satisfy the absorption waveform defined in the present invention, and while No. c17 contains dye C-1 which exhibits absorption waveform C as defined in the present invention, it also contains dye B-2 which does not satisfy the absorption waveform defined in the present invention. The laminates of No. c16 and c17 used for comparison also failed to sufficiently suppress the decrease in brightness. In contrast, the laminates No. 101 to 107, which have a light-absorbing portion and a light-bending portion as defined in the present invention, all exhibited excellent suppression of both ambient light reflection and brightness reduction. In particular, the comparison between the laminate No. 106 and the laminate No. c13 clearly demonstrates that the effect of suppressing ambient light reflection can be obtained by satisfying relation (2) in absorption waveform C. This is thought to be an effect caused by the width of the absorption wavelength of the dye, and it is considered that the effect of suppressing ambient light reflection can be similarly obtained when relation (1) in absorption waveform B is satisfied. Furthermore, the comparison between the No. 105 laminate and the No. c14 laminate, and the comparison between the No. 106 laminate and the No. c15 laminate, clearly demonstrates that the luminance reduction suppression effect can be obtained by satisfying the provisions of the present invention such that the absorption located between the blue and green emission wavelength ranges of the display device, and the absorption located between the green and red emission wavelength ranges of the display device, each have two wavelengths that give an absorbance of half the absorption maximum within the maximum emission wavelength of the light located on both sides of the absorption. Furthermore, by comparing the laminate of No. 103, which has a light-absorbing portion and a light-bending portion as defined in the present invention, with the laminate of No. 104, it can be seen that by providing a QD sheet for wavelength conversion on the viewing side of the light-emitting portion, light diffusion occurs in the QD sheet, achieving both suppression of ambient light reflection and suppression of brightness reduction, while suppressing ambient light reflection to a more superior level. This effect of improving the suppression of ambient light reflection is thought to be obtainable by the same principle as long as the light-absorbing portion as defined in the present invention is provided. For example, in the laminates of No. 101, 102, 105-107 as well, ambient light reflection can be suppressed to a more superior level by providing a QD sheet for wavelength conversion on the viewing side of the light-emitting portion. In contrast, by comparing the No. c11 laminate, which has a circular polarizer instead of the light-absorbing portion defined in the present invention as an anti-reflection means, and further has a light-bending portion, with the No. c12 laminate, it can be seen that by providing a QD sheet, the polarization is eliminated by the diffusion of light in the QD sheet, and the reflection suppression by the circular polarizer cannot function sufficiently, and external light reflection actually increases.

[0393] Although we have described the present invention along with its embodiments, we do not intend to limit our invention in any detail of the description unless specifically designated, and we believe that it should be interpreted broadly without contradicting the spirit and scope of the invention as set forth in the appended claims.

[0394] This application claims priority based on Japanese Patent Application No. 2021-056294, filed in Japan on 29 March 2021, the contents of which are incorporated herein by reference as part of this specification. [Explanation of Symbols]

[0395] 1 Optical component 2 Light bending part 21 Supporting base material 22 High refractive index areas 23 Low refractive index areas 3. Adhesive 4. Light-absorbing section 5. Adhesive 6. Surface film w1 Width of the support substrate side of the high refractive index portion w2 Width of the side of the high refractive index portion that opposes the supporting substrate h Thickness of the high refractive index region t: Distance between adjacent high refractive index regions λ BMax The maximum emission wavelength indicated by the blue light emitted by the display device. λ GMax The maximum emission wavelength indicated by the green light emitted by the display device. λ RMax The maximum emission wavelength indicated by the red light emitted by the display device. x The width between two wavelengths that gives half the absorbance of the maximum emission shown by the blue light emitted by the display device. y The width between two wavelengths that gives half the absorbance of the maximum emission shown by the green light emitted by the display device. z: The width between two wavelengths that gives half the absorbance of the maximum emission shown by the red light emitted by the display device.

Claims

1. An optical component for use in a display device, The display device has a light-emitting section and a microcavity structure, wherein the light-emitting section is an organic electroluminescent light-emitting element or a microlight-emitting diode. The optical member includes a light bending portion that bends and emits a portion of the amount of light from the incident straight-traveling light, and a light absorbing portion containing a dye. An optical component for use in a display device, wherein the absorption waveform of the light absorbing portion is selected from the following absorption waveforms A to D, and the light absorbing portion has the following absorption waveform B or C. Absorption waveform A: λ ＢＭａｘ Absorption waveforms having a main absorption wavelength band in the wavelength range below [a certain wavelength] Absorption waveform B: λ ＢＭａｘ Over λ ＧＭａｘ An absorption waveform in which two wavelengths exist in the wavelength range less than 1, which give an absorbance of half the absorption maximum, and the width between the two wavelengths FWHM ｂ The absorption waveform that satisfies the relationship in equation (1) below. Formula (1) FWHM ｂ ≧ 50 - x / 2 - y / 2 Absorption waveform C: λ ＧＭａｘ Over λ ＲＭａｘ An absorption waveform in which two wavelengths exist in the wavelength range less than 1, which give an absorbance of half the absorption maximum, and the width between the two wavelengths FWHM ｃ The absorption waveform that satisfies the relationship in equation (2) below. Formula (2) FWHM ｃ ≧ 60 - y / 2 - z / 2 Absorption waveform D: λ ＲＭａｘ Absorption waveforms having a main absorption wavelength band in the wavelength range beyond this range In the description of the absorption waveforms A to D, each symbol has the following meaning. Also, in equations (1) and (2), the unit of wavelength is nm. λ ＢＭａｘ : The maximum emission wavelength shown by the blue light emitted by the display device. λ ＧＭａｘ : Maximum emission wavelength indicated by the green light emitted by the display device λ ＲＭａｘ : The maximum emission wavelength shown by the red light emitted by the display device. x: The width between two wavelengths that gives half the absorbance of the maximum blue light emitted by the display device. y: The width between two wavelengths that gives half the absorbance of the maximum emission shown by the green light emitted by the display device. z: The width between two wavelengths that gives half the absorbance of the maximum emission shown by the red light emitted by the display device.

2. The optical member for use in a display device according to claim 1, wherein the optical member includes an optical bending filter that forms the optical bending portion and an optical absorbing filter that forms the optical absorbing portion.

3. The optical member for use in the display device according to claim 2, wherein the optical bending filter bends 1 to 20% of the amount of light from the incident straight-traveling light.

4. An optical member for use in a display device according to claim 2 or 3, wherein the total light transmittance of the light bending filter is 99% or more.

5. An optical member for use in a display device according to any one of claims 2 to 4, wherein the optical bending filter has at least a region I and a region II exhibiting a refractive index different from that of region I.

6. An optical member for use in a display device according to claim 5, wherein the region I contains zirconium oxide particles.

7. An optical member for use in a display device according to claim 5 or 6, wherein region II includes an adhesive or hollow particles.

8. An optical member for use in a display device according to any one of claims 2 to 7, wherein the dye contained in the light absorption filter exhibiting the absorption waveform B or C includes a squalin-based dye represented by the following general formula (1). 【Chemistry 1】 In the above formula, A and B each independently represent an optionally substituted aryl group, an optionally substituted heterocyclic group, or -CH=G. G represents an optionally substituted heterocyclic group.

9. An optical member for use in a display device according to any one of claims 2 to 8, wherein the light absorbing portion has the absorption waveform A, and the dye contained in the light absorbing filter exhibiting the absorption waveform A includes a dye represented by the following general formula (A1). 【Chemistry 2】 In the above formula, R １ and R ２ Each independently represents an alkyl group or an aryl group, R ３ ~R ６ Each of these independently represents a hydrogen atom or a substituent, R ５ and R ６ These may be bonded to each other to form a six-membered ring.

10. An optical member for use in a display device according to any one of claims 2 to 9, wherein the light absorbing portion has the absorption waveform D, and the dye contained in the light absorbing filter exhibiting the absorption waveform D includes at least one of the dyes represented by the following general formula (D1) and the dyes represented by the following general formula (1). 【Transformation 3】 In the above formula, R １Ａ and R ２Ａ Each independently represents an alkyl group, an aryl group, or a heteroaryl group, R ４Ａ and R ５Ａ Each independently represents a heteroaryl group, R ３Ａ and R ６Ａ Each of these independently represents a substituent. １ and X ２ Each of them independently, -BR ２１ａ R ２２ａ R ２１ａ and R ２２ａ Each of these independently represents a substituent, R ２１ａ and R ２２ａ They may be joined to each other to form a ring. 【Chemistry 4】 In the above formula, A and B each independently represent an optionally substituted aryl group, an optionally substituted heterocyclic group, or -CH=G. G represents an optionally substituted heterocyclic group.

11. An optical member for use in a display device according to any one of claims 2 to 10, wherein the light-absorbing filter contains a fade-preventing agent represented by the following general formula (IV). 【Transformation 5】 In the above formula, R １０ Each of these is independently an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, or R １８ CO-, R １９ SO ２ - or R ２０ The group represented by NHCO- is shown, R １８ , R １９ and R ２０ Each of these independently represents an alkyl group, an alkenyl group, an aryl group, or a heterocyclic group. １１ and R １２ Each independently represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkoxy group, or an alkenyloxy group, R １３ ~R １７ Each of these independently represents a hydrogen atom, an alkyl group, an alkenyl group, or an aryl group.

12. An optical member for use in a display device according to any one of claims 2 to 11, wherein the light-absorbing filter comprises a polystyrene resin or a cyclic polyolefin resin.

13. An optical member for use in a display device according to any one of claims 2 to 12, wherein the light absorption filter exhibits all of the absorption waveforms A to D.

14. A display device comprising an optical member for use in the display device according to any one of claims 1 to 13 and a light-emitting part, wherein the light-emitting part is an organic electroluminescent light-emitting element or a microlight-emitting diode, A display device having a microcavity structure.

15. The display device according to claim 14, further comprising a quantum dot sheet for wavelength conversion on the viewing side of the light-emitting portion of the display device.

16. The display device according to claim 14 or 15, wherein the display device includes a matrix that absorbs or scatters ambient light, and the matrix is ​​arranged between light-emitting elements constituting the light-emitting portion.

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