Metal casting and rolling lines

Abstract

To provide a continuous casting and rolling line for casting, rolling and preparing a metal strip, which can produce a distributable metal strip without requiring cold rolling or the use of a solution heat treatment line.SOLUTION: A metal strip can be continuously cast from a continuous casting device and coiled into a metal coil, optionally after being subjected to post-casting quenching. This intermediate coil can be stored until hot rolling is ready. The as-cast metal strip can undergo reheating prior to the hot rolling, either during the coil storage or immediately prior to the hot rolling. The heated metal strip can be cooled to a rolling temperature and hot-rolled through one or more roll stands. The rolled metal strip can optionally be reheated and quenched prior to the coiling for delivery. This final coiled metal strip can be of the desired gauge and have the desired physical characteristics for distribution to a manufacturing facility.SELECTED DRAWING: Figure 25

Description

Technical Field

[0001] Cross - reference to Related Applications This application claims the benefit of U.S. Patent Application No. 62 / 413,591, filed Oct. 27, 2016, "Separate Continuous Casting and Rolling Line"; U.S. Patent Application No. 62 / 505,944, filed May 14, 2017, "Separate Continuous Casting and Rolling Line"; U.S. Patent Application No. 62 / 413,764, filed Oct. 27, 2016, "High - Strength 7XXX Series Aluminum Alloy and Method of Manufacturing the Same"; U.S. Patent Application No. 62 / 413,740, filed Oct. 27, 2016, "High - Strength 6XXX Series Aluminum Alloy and Method of Manufacturing the Same"; and U.S. Patent Application No. 62 / 529,028, filed Jul. 6, 2017, "System and Method for Manufacturing Aluminum Alloy Sheets", and incorporates herein by reference in its entirety.

[0002] This disclosure relates to the manufacture of metal materials such as metal strip coils, and particularly to the continuous casting and rolling of metals such as aluminum.

Background Art

[0003] Semi - continuous (DC) casting and continuous casting are two methods of casting solid metal from liquid metal. In DC casting, liquid metal is poured into a mold having a flexible bottom that can withdraw the internal liquid metal at a solidification rate, and often large and relatively thick ingots (e.g., 1500 mm × 500 mm × 5 m) are obtained. This ingot can be processed, homogenized, hot - rolled, cold - rolled, annealed and / or heat - treated before being attached to a metal strip product (e.g., automotive manufacturing equipment) that can be supplied to consumers of metal strip products.

[0004] Continuous casting involves continuously injecting molten metal into a casting cavity defined between a pair of moving, opposing casting surfaces, and withdrawing a casting metal mold (e.g., a metal strip) from the outlet of the casting cavity. Continuous casting was desirable when the entire product could be manufactured in a single, fully coupled processing line. Such a fully coupled processing line involves matching or "coupling" the speed of the continuous casting equipment with the speed of the downstream processing equipment. [Brief explanation of the drawing]

[0005] This specification refers to the following attached drawings, and similar reference numbers used in different drawings indicate similar or similar components. [Figure 1] This is a schematic diagram illustrating a separation-type metal casting and rolling system according to some aspects of the present disclosure. [Figure 2] This is a manufacturing timing chart for various coils using a separate metal casting and rolling system according to some aspects of the present disclosure. [Figure 3] This is a schematic diagram illustrating a separate continuous casting system according to some aspects of the present disclosure. [Figure 4] This is a schematic diagram showing an intermediate coil vertical storage system according to some aspects of the present disclosure. [Figure 5] This is a schematic diagram showing an intermediate coil lifting and storage system according to some aspects of the present disclosure. [Figure 6] This is a schematic diagram showing a hot rolling system according to some aspects of the present disclosure. [Figure 7] These are schematic diagrams and charts illustrating the relevant temperature profiles of a hot rolling system and a metal strip rolled thereon, according to some aspects of the present disclosure. [Figure 8] This invention relates to several aspects of a hot rolling system having an intentionally supercooled rolling stand and a combination schematic diagram and chart showing the relevant temperature profiles of a metal strip rolled thereon. [Figure 9]These are combined flowcharts and schematic diagrams illustrating a process for casting and rolling metal strips in relation to a first variant and a second variant of a separable system according to some aspects of the present disclosure. [Figure 10] This is a schematic diagram illustrating a process for casting and rolling a metal strip according to some aspects of the present disclosure. [Figure 11] This chart shows the temperature profile of a metal strip that is cast without post-casting quenching and stored at a high temperature before rolling, according to some aspects of the present disclosure. [Figure 12] This chart shows the temperature profile of a cast metal strip that is preheated before rolling but does not undergo quenching after casting, according to some aspects of the present disclosure. [Figure 13] This chart shows the temperature profile of a metal strip that is cast, quenched after casting, and stored at a high temperature before rolling, according to some aspects of the present disclosure. [Figure 14] This chart shows the temperature profile of a metal strip that is quenched after casting and preheated before rolling, according to some aspects of the present disclosure. [Figure 15] These are a series of magnified images showing the intermetallic compounds in aluminum alloy AA6014 for a standard DC cast metal strip compared to a metal strip cast using a separate casting and rolling system according to some aspects of the present disclosure. [Figure 16] These are a series of scanning transmission electron microscope images showing dispersed phases in 6xxx series aluminum alloy metal strips reheated at 550°C for 1 hour, comparing metal strips cast without post-quenching and metal strips cast with post-quenching, according to several aspects of the present disclosure. [Figure 17] This chart compares the yield strength and three-point bending test results of 7xxx series metal strips manufactured using conventional semi-continuous casting technology and 7xxx series metal strips manufactured using separate continuous casting and rolling, according to several aspects of this disclosure. [Figure 18]This chart compares the yield strength and solution heat treatment immersion time results of 6xxx series metal strips manufactured using conventional semi-continuous casting technology and 6xxx series metal strips manufactured using separate continuous casting and rolling, according to some aspects of this disclosure. [Figure 19] A series of scanning transmission electron microscope images showing dispersed phases in AA6111 aluminum alloy metal strips reheated at 550°C for 8 hours, comparing metal strips cast without post-quenching and metal strips cast with post-quenching, according to several aspects of the present disclosure. [Figure 20] This chart shows the precipitation of Mg2Si in aluminum metal strips during hot rolling and quenching, according to some aspects of the present disclosure. [Figure 21] These are schematic diagrams and charts illustrating the relevant temperature profiles of a hot rolling system and a metal strip rolled thereon, according to some aspects of the present disclosure. [Figure 22] This is a schematic diagram illustrating a hot band continuous casting system according to some aspects of the present disclosure. [Figure 23] This chart shows the precipitation of Mg2Si in aluminum metal strips during hot rolling and quenching, according to some aspects of the present disclosure. [Figure 24] This flowchart shows a process for casting a thermometallic strip according to some aspects of the present disclosure. [Figure 25] This is a schematic diagram illustrating a hot band continuous casting system according to some aspects of the present disclosure. [Figure 26] This is a schematic diagram illustrating a continuous casting system according to some aspects of the present disclosure. [Figure 27] This flowchart shows a process for casting extrudeable metal products according to some aspects of the present disclosure. [Figure 28] This graph shows the log-normal density distribution of iron (Fe) constituent particles per square micron (μm²) with respect to particle size of an alloy manufactured according to the method described herein. [Figure 29]A series of scanning electron microscope (SEM) micrographs showing Fe - constituent particles in AA6111 processed according to the method described herein. [Figure 30] A graph showing the log - normal number density distribution of iron (Fe) - constituent particles per square micron (μm2) with respect to the particle size of an alloy manufactured according to the method described herein. [Figure 31] A graph showing the log - normal number density distribution of iron (Fe) - constituent particles per square micron (μm2) with respect to the particle size of an alloy manufactured according to the method described herein. [Figure 32] A graph showing the log - normal number density distribution of iron (Fe) - constituent particles per square micron (μm2) with respect to the particle size of an alloy manufactured according to the method described herein. [Figure 33] A graph showing the log - normal number density distribution of iron (Fe) - constituent particles per square micron (μm2) with respect to the particle size of an alloy manufactured according to the method described herein. [Figure 34] A graph showing the log - normal number density distribution of iron (Fe) - constituent particles per square micron (μm2) with respect to the particle size of an alloy manufactured according to the method described herein. [Figure 35] A micrograph showing the microstructure of AA6014 aluminum alloy called "R1", which is continuously cast into a slab with a gauge thickness of 19 mm, cooled and stored, pre - heated and hot - rolled to a thickness of 11 mm, and further hot - rolled to a thickness of 6 mm. [Figure 36] A micrograph showing the microstructure of AA6014 aluminum alloy called "R2", which is continuously cast into a slab with a gauge thickness of 10 mm, cooled and stored, pre - heated and hot - rolled to a thickness of 5.5 mm. [Figure 37] A micrograph showing the microstructure of AA6014 aluminum alloy called "R3", which is continuously cast into a slab with a gauge thickness of 19 mm, cooled and stored, cold - rolled to a thickness of 11 mm, pre - heated, and then hot - rolled to a thickness of 6 mm. [Figure 38]This graph shows the effect of preheating on the formability of AA6014 aluminum alloy. [Figure 39] These are a series of scanning electron microscope (SEM) images showing Fe constituent particles in an 11.3 mm gauge cross-section of AA6111 metal. [Figure 40] This graph shows the equivalent circular diameter (ECD) of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 39. [Figure 41] This graph shows the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 39. [Figure 42] This graph shows the median and distribution data of the equivalent circular diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 39. [Figure 43] This graph shows the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 39. [Figure 44] These are a series of scanning electron microscope (SEM) images showing Fe constituent particles in an 11.3 mm gauge cross-section of AA6111 metal. [Figure 45] This graph shows the median and distribution data of the equivalent circular diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 44. [Figure 46] This graph shows the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 44. [Figure 47] These are a series of scanning electron microscope (SEM) images showing Fe constituent particles in an 11.3 mm gauge cross-section of AA6111 metal. [Figure 48] This graph shows the median and distribution data of the equivalent circular diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 47. [Figure 49] This graph shows the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 47. [Figure 50]These are a series of scanning electron microscope (SEM) images showing Fe constituent particles in a cross-section of AA6111 metal after undergoing various processing steps to obtain a band of 3.7-6 mm gauge. [Figure 51] This graph shows the median and distribution data of the equivalent circular diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 50. [Figure 52] This graph shows the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 50. [Figure 53] These are a series of scanning electron microscope (SEM) images showing Fe constituent particles in a cross-section of AA6111 metal after undergoing various processing steps to obtain a 2.0 mm gauge strip. [Figure 54] This graph shows the median and distribution data of the equivalent circular diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 53. [Figure 55] This graph shows the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 53. [Figure 56] These are a series of scanning electron microscope (SEM) images showing Fe constituent particles in a cross-section of AA6111 metal after undergoing various processing steps to obtain a 2.0 mm gauge strip. [Figure 57] This graph shows the median and distribution data of the equivalent circular diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 56. [Figure 58] This graph shows the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 56. [Figure 59] These are a series of scanning electron microscope (SEM) images showing Fe constituent particles in a cross-section of AA6451 metal after undergoing various processing steps to obtain a band of 3.7-6 mm gauge. [Figure 60] This graph shows the median and distribution data of the equivalent circular diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 59. [Figure 61]This graph shows the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 59. [Figure 62] These are a series of scanning electron microscope (SEM) images showing Fe constituent particles in a cross-section of AA6451 metal after undergoing various processing steps to obtain a 2.0 mm gauge strip. [Figure 63] This graph shows the median and distribution data of the equivalent circular diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 62. [Figure 64] This graph shows the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 62. [Figure 65] These are a series of scanning electron microscope (SEM) and optical microscope images showing Mg2Si melting and void formation in a cross-section of AA6451 metal cast and cold-rolled to obtain a 2.0 mm gauge strip. [Figure 66] These are a series of scanning electron microscope (SEM) images showing Fe constituent particles in a cross-section of AA6451 metal after undergoing various processing steps to obtain a 2.0 mm gauge strip. [Figure 67] This graph shows the median and distribution data of the equivalent circular diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 66. [Figure 68] This graph shows the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 66. [Figure 69] These are a series of scanning electron microscope (SEM) images showing Fe constituent particles in a cross-section of the metal AA5754. [Figure 70] This graph shows the median and distribution data of the equivalent circular diameter of Fe constituent particles within the metal piece illustrated and explained with reference to Figure 69. [Figure 71] This graph shows the median and distribution data of the aspect ratio of Fe constituent particles within the metal piece, as illustrated and explained with reference to Figure 69. [Modes for carrying out the invention]

[0006] Some aspects and features of this disclosure relate to separate and partially separate continuous casting and rolling lines for casting, rolling, and otherwise manufacturing metal articles (e.g., metal strips) suitable for providing supplyable coils of metal strips. In some embodiments, the metal articles are manufactured without requiring the use of cold rolling or continuous annealing solution heat treatment (CASH) lines. The metal strips can be continuously cast from a continuous casting apparatus such as a belt casting machine, optionally treated with post-casting quenching, and then wound into metal coils. The wound as-cast metal strips can be stored until ready for hot rolling. The as-cast metal strips can be reheated before hot rolling, either while in coil storage or immediately before hot rolling. The heated metal strips can be cooled to rolling temperature and hot-rolled by one or more rolling stands. The rolled metal strips can optionally be reheated and quenched before being wound for delivery. This final coiled metal strip can be of desired specifications and have desirable physical properties for supply to a manufacturing facility.

[0007] Some aspects and features of this disclosure relate to casting aluminum alloys at a high solidification rate and subsequently hot or warm rolling the metal articles to reduce their thickness by at least about 30%, or about 30% to 80%, 40% to 70%, 50% to 70%, or 60% to produce hot bands. In some cases, before hot or warm rolling, the metal articles may be passed through an in-line furnace that can be maintained at a metal peak temperature of about 400°C to 580°C for about 10 to 300 seconds, 60 to 180 seconds, or 120 seconds. Hot band products can be made to final gauge, final gauge and tempered, or prepared for further processing such as cold rolling and solution heat treatment. In some cases, the in-line furnace is particularly useful in facilitating greater thickness reduction of 5xxx alloys during hot or warm rolling. As used herein, the term “thickness reduction” means a form of cross-sectional reduction due to the use of rolling. Other types of cross-sectional reduction may include a reduction in the diameter of an extruded metal article. Hot rolling and warm rolling can each be a type of hot working or warm working. Another type of hot rolling or warm rolling may include hot extrusion or warm extrusion.

[0008] In some cases, the desired shape and size of intermetallic compound particles can be achieved by continuous casting (e.g., at a high solidification rate), heating in an optional in-line furnace, and in-line hot or warm rolling that reduces the thickness by approximately 50% to 70%. These desired shapes and sizes of intermetallic compound particles can facilitate further processing, such as cold rolling, as well as user applications such as bending and forming.

[0009] As used herein, temperature may refer to peak metal temperature as appropriate. Similarly, references to duration at a particular temperature may refer to the duration beginning from the time the metal article reaches the desired peak metal temperature (excluding, for example, ramp-up time), but not always.

[0010] The embodiments and features of this disclosure can be used with any suitable metal, but may be particularly effective when casting and rolling aluminum alloys. In particular, desirable results can be obtained when casting alloys such as 2xxx, 3xxx, 4xxx, 5xxx, 6xxx, 7xxx, or 8xxx series aluminum alloys. For example, several embodiments and features of this disclosure enable the casting of 5xxx and 6xxx series alloys without requiring continuous annealing solution heat treatment. As another example, several embodiments and features of this disclosure enable more efficient and reliable casting of 7xxx series alloys compared to conventional casting methods. In this description, alloys identified by aluminum industry symbols, e.g., “series”, “AA6xxx”, or “6xxx”, are referred to. For understanding the numbering system most commonly used for naming and identifying aluminum and its alloys, refer to the “International Alloy Symbols and Chemical Composition Restrictions for Forged Aluminum and Forged Aluminum Alloys” or the “Registered Record of Alloy Symbols and Chemical Composition Restrictions for Aluminum Alloys in Casting and Ingot Forms”, both published by the Aluminum Industry Association.

[0011] In some cases, certain aspects and features of this disclosure are suitable for use with aluminum, aluminum alloys, titanium, titanium-based materials, steel, steel-based materials, magnesium, magnesium-based materials, copper, copper-based materials, composite materials, sheets used in composite materials, or other suitable combinations of metals, nonmetals, or materials. Where the embodiment in which the material is cast includes a metal, the metal may be an ferrous metal or a nonferrous metal.

[0012] Traditionally, metal strips produced by continuous casting equipment are fed directly into a hot rolling mill, where they are reduced to a predetermined thickness. The obvious advantage of continuous casting is that, unlike traditional DC casting, as-cast metal strips can be fed directly into the process line. Because continuously cast products are fed directly into the rolling mill, the casting speed and rolling speed must be carefully matched to avoid creating undesirable tensions in the metal strips, which could lead to unusable products, equipment damage, or hazardous conditions.

[0013] Surprisingly, beneficial results can be achieved by intentionally separating the casting process from the hot rolling process in a continuous casting and rolling system. By separating the continuous casting process from the hot rolling process, it becomes unnecessary to strictly match the casting rate and the rolling rate. Rather, the casting rate can be selected to produce the desired properties in the metal strip, and the rolling rate can be selected based on the requirements and limitations of the rolling equipment. In a separated continuous casting and rolling system, the continuous casting equipment can cast metal strips that are wound immediately or shortly thereafter onto intermediate coils or transfer coils. The intermediate coils can be stored or immediately transported to the rolling equipment. In the rolling equipment, the intermediate coils are unwound, allowing the metal strips to pass through the rolling equipment for hot rolling and other processing. The final result of the hot rolling process is a metal strip with properties desirable for a particular user. The metal strips can be wound and supplied to an automobile factory, for example, where automotive parts can be formed from the metal strips. In some cases, after being initially cast in a continuous casting process (for example, by a continuous casting machine), the metal strip may be heated at various points, but the metal strip is kept below its solidus temperature.

[0014] As used herein, the term “separation” refers to the removal of the speed link between the casting apparatus and the rolling stand. As described above, a coupling system (sometimes referred to herein as an in-line system) includes a continuous casting apparatus that feeds directly to the rolling stand, and therefore the output speed of the casting apparatus must match the input speed of the rolling stand. In a separation system, the casting speed can be set independently of the input speed of the rolling stand, and the speed of the rolling stand can be set independently of the output speed of the casting apparatus. In various embodiments described herein, the casting apparatus is separated from the rolling stand by having the casting apparatus output a metal coil at a first speed and then feeding that coil to the rolling stand for rolling at a second speed. If it is desired that the casting speed be faster than the speed at which the desired rolling speed can be supplied, the use of an accumulator placed between the casting apparatus and the rolling stand makes it possible to provide a limited separation between the output speed of the casting apparatus and the input speed of the rolling stand, even when the casting apparatus feeds the cast metal strips directly to the rolling stand.

[0015] The casting apparatus may be any suitable continuous casting apparatus. However, remarkably desirable results can be achieved using a belt casting apparatus, for example, the one described in U.S. Patent No. 6755236, entitled “Belt Cooling and Induction Means for Continuous Belt Casting of Metal Strips,” the disclosure thereof is incorporated herein by reference in its entirety. In some cases, particularly desirable results can be achieved using a belt casting apparatus having a belt made of a metal with high thermal conductivity, such as copper. The belt casting apparatus includes a belt, the belt of which can be made of a metal having a thermal conductivity of at least 250, 300, 325, 350, 375, or 400 watts / meter per Kelvin at the casting temperature. The casting apparatus can cast metal strips of any suitable thickness, but desirable results have been achieved with thicknesses of approximately 7 mm to 50 mm.

[0016] Several aspects of this disclosure can improve the formation and distribution of dispersed phases within an aluminum matrix. Dispersed phases are aggregates of other solid phases located within the first phase of a solidified aluminum alloy. Various factors during casting, handling, heating, and rolling can significantly affect the size and distribution of dispersed phases within a metal strip. Dispersed phases are known to aid in the bending performance and other properties of aluminum alloys, and are preferably about 10 nm to about 500 nm in size, and are desirable to be relatively uniformly distributed throughout the metal strip. In some cases, the desired dispersed phases may be about 10 nm to 100 nm or 10 nm to 500 nm in size. In DC casting, long homogenization cycles (e.g., 15 hours or more) are required to produce a desirable distribution of dispersed phases. In standard continuous casting, dispersed phases are always absent or present in small amounts, and they cannot provide any beneficial effect.

[0017] Some aspects of this disclosure relate to metal strips, as well as systems and methods for forming metal strips having a desired dispersed phase (e.g., a desired distribution of dispersed phase of a desired size). In some cases, the casting apparatus can be configured to provide rapid solidification of the metal strip (e.g., at a rate about 10 times faster than standard DC casting solidification, e.g., at least about 1°C / sec, at least about 10°C / sec, or at least about 100°C / sec) and rapid cooling (e.g., at a rate of at least about 1°C / sec, at least about 10°C / sec, or at least about 100°C / sec), which can facilitate improving the microstructure of the final metal strip. In some cases, the solidification rate can be 100 times or more faster than the solidification rate of conventional DC casting. Rapid solidification can result in a unique microstructure, including a unique distribution of dispersed phase-forming elements that are very uniformly distributed throughout the solidified aluminum matrix. Rapid cooling of this metal strip, for example, immediately quenching the metal strip upon exiting the casting apparatus or quenching it shortly thereafter, can facilitate the fixation of the dispersed phase-forming elements into a solid solution. The resulting metal strip can then be supersaturated with the dispersed phase-forming elements. The supersaturated metal strip can then be wound into an intermediate coil and further processed in a separate casting and rolling system. In some cases, the desired dispersed phase-forming elements include manganese, chromium, vanadium, and / or zirconium. When reheated, this metal strip, supersaturated with the dispersed phase-forming elements, can very rapidly induce the precipitation of uniformly distributed dispersed phases of a desired size.

[0018] In some cases, rapid solidification and rapid cooling can be performed by the casting apparatus alone. The casting apparatus has sufficient length and sufficient heat removal properties to produce metal strips supersaturated with dispersed phosphate-forming elements. In some cases, the casting apparatus has sufficient length and sufficient heat removal properties to reduce the temperature of the cast metal strip to 250°C, 240°C, 230°C, 220°C, 210°C, or below 200°C (other values ​​may also be used). Generally, such casting apparatus occupies considerable space or must be operated at slow casting speeds. In some cases, if a smaller and faster casting apparatus is desired, the metal strip can be quenched immediately after or shortly thereafter leaving the casting apparatus. By placing one or more nozzles downstream of the casting apparatus, the temperature of the metal strip can be reduced to 250°C, 240°C, 230°C, 220°C, 210°C, 200°C, 175°C, 150°C, 125°C, or below 100°C (other values ​​may also be used). The quenching process can be carried out sufficiently rapidly or quickly to fix the dispersed phosphate-forming elements to the supersaturated metal strip.

[0019] Traditionally, rapid solidification and rapid cooling have been avoided because the resulting metal strips have undesirable properties. Surprisingly, however, it has been discovered that metal strips supersaturated with disperse-forming elements may be efficient precursors for metal strips having a desired disperse-forming configuration. Unique disperse-forming element-supersaturated metal strips can be reheated during storage or immediately before hot rolling, thereby converting the supersaturated matrix of disperse-forming elements into a strip containing disperse of a desired distribution (e.g., uniformly distributed) and size (e.g., about 10 nm to about 500 nm or about 10 nm to about 100 nm). Because the metal strip is supersaturated with disperse-forming elements, the driving force for precipitation of disperse of a desired size is greater than in the case of an unsupersaturated matrix. In other words, certain modes of rapid solidification and / or cooling, such as those disclosed herein, can be used to prepare or prime metal strips, which can then be reheated for a short time to generate the desired disperse-forming configuration. For example, it has been found that some aspects of this disclosure can produce metal strips supersaturated with dispersion-forming elements that can be reheated to precipitate a dispersion of a desired size in a reheating time 10 to 100 times shorter than existing techniques (e.g., DC casting). Furthermore, the speed at which this reheating can occur allows the reheating to be performed on a hot rolling line, for example, at the start of the hot rolling line. However, in some cases, one or more coils of the metal strip supersaturated with dispersion-forming elements can be reheated before being wound on the hot rolling line. Because the dispersion of a desired size can be extracted more quickly, considerable time and energy can be saved when producing the desired metal strip. Furthermore, the improved dispersion distribution allows the desired performance to be achieved with the use of smaller amounts of alloying elements. In other words, some aspects and features of this disclosure enable the more efficient use of alloying elements than conventional DC or continuous casting.

[0020] Furthermore, the size and distribution of the dispersed phase can be specifically created as required by using one or more operations among the solidification rate, cooling (e.g., quenching) rate, and reheating time. A controller controls the solidification rate, cooling rate, and reheating time by being coupled to the system. If it is desired that the metal strip have specific properties due to a particular dispersed phase arrangement (e.g., size and / or distribution), the controller produces the desired metal strip by manipulating various rates / times. In this way, a metal strip with a desired dispersed phase arrangement can be produced as required. Since control of the dispersed phase arrangement can provide more or less efficiency in how the alloying elements are utilized, the controller can compensate for deviations in the alloying elements of a particular mixture of liquid metals by controlling the dispersed phase arrangement as required. For example, when manufacturing deliverable metal strips with certain desired properties, the controller can compensate for slight deviations in the concentration of alloying elements between castings by adjusting the system's solidification rate, cooling rate, and / or reheating time, thereby generating a dispersed phase arrangement that provides a more or less efficient use of the alloying elements (for example, when a negative deviation of alloying elements is determined, a more efficient use is desirable). Such compensation can be performed automatically or automatically recommended to the user.

[0021] The intermediate coil can be stored before hot rolling, so the casting apparatus can output at a speed faster than the hot rolling stand can supply, and the excess metal strip is stored in a wound state until the hot rolling stand becomes available. In the case of storage, the intermediate coil may optionally be reheated. For example, using various types of aluminum alloys, the intermediate strip can be reheated to a temperature of 500°C or higher, or 530°C or higher. The reheating temperature is kept lower than the solidus temperature of the metal strip.

[0022] In some cases, the intermediate coil is maintained at a temperature of approximately 100°C or higher, 200°C or higher, 300°C or higher, or 400°C or higher, or 500°C or higher (other values ​​may also be used). In some cases, the intermediate coil can be stored in a manner that minimizes non-uniform radial forces, which may prevent unwinding during the hot rolling process. In some cases, the intermediate coil may be stored vertically so that the transverse axis of the coil extends vertically. In some cases, the intermediate coil may be stored horizontally so that the transverse axis of the coil extends horizontally. In some cases, the intermediate coil can be suspended from the central spindle, thus minimizing the weight that compresses the coil loops toward each other, especially the portion of the coil located below the spindle. In some cases, the intermediate coil can be rotated periodically or continuously about a horizontal axis (e.g., the transverse axis of the coil when stored horizontally).

[0023] During the hot rolling process, the intermediate coil may be unwound, surface-treated, reheated, rolled to the desired thickness, rolled again after reheating, quenched, and wound for feeding. The hot rolling process includes one or more hot rolling stands, each containing a working roll for applying force to reduce the thickness of the metal strip. In some cases, the total amount of thickness reduction during hot rolling may be about 70%, 65%, 60%, 55%, 50%, 45%, 40%, 35%, 30%, 25%, 20%, or 15% or less (other values ​​may also be used). Hot rolling can be carried out at a relatively high speed, for example, an entry speed of about 50 to about 60 meters per minute (m / min) (other entry speeds may also be used) (e.g., the speed of the metal strip as it enters the first hot rolling stand). The exit speed (e.g., the speed of the metal strip as it leaves the last hot rolling stand) is much faster due to the percentage of thickness reduction given by the hot rolling stand, and other exit speeds may occur, but are, for example, about 300 to about 800 m / min. To obtain the desired results, hot rolling can be carried out at the hot rolling temperature. The hot rolling temperature is around 350°C and may be, for example, between 340°C and 360°C, between 330°C and 370°C, between 330°C and 380°C, between 300°C and 400°C, or between 250°C and 400°C (other ranges may also be used). In some cases, the desired hot rolling temperature for the metal strip may be the alloy recrystallization temperature. In some cases, the temperature of the metal strip can move from the starting hot rolling temperature (e.g., the temperature of the metal strip when it enters the first hot rolling stand) through one or more intermediate hot rolling temperatures (e.g., the temperature of the metal strip between two adjacent hot rolling stands) to the ending hot rolling temperature (e.g., the temperature of the metal strip when it leaves the last hot rolling stand). Other ranges may also be used, but any of these temperatures may fall within the above-described range of hot rolling temperatures. The starting hot rolling temperature, the temperature between any stands, and the ending hot rolling temperature may be the same (see, for example, Figure 7) or different (see, for example, Figure 8).

[0024] In some cases, the metal strip may enter the hot rolling process at a high temperature and be reheated immediately after being unwound in the hot rolling system, as disclosed above. The temperature of the metal strip in this regard may exceed 500°C, 510°C, 520°C, or 530°C, but other ranges below the melting point are usable. The metal strip may be cooled to the above hot rolling temperature before entering the hot rolling stand. After passing through the hot rolling stand, the metal strip may be heated to the post-rolling temperature, as is sometimes the case. For heat-treatable alloys such as 6xxx and 7xxx series aluminum alloys, the post-rolling temperature may be the solution temperature or near the solution temperature, but for non-heat-treatable alloys such as 5xxx series aluminum alloys, the post-rolling temperature may be the recrystallization temperature. In some cases, for example for non-heat-treatable alloys, especially if the metal strip exits the hot rolling process at a temperature above the recrystallization temperature (e.g., above approximately 350°C), post-rolling heating may not be used. For heat-treatable alloys, the post-rolling temperature or solution temperature may vary depending on the alloy, but may be approximately 450°C, 460°C, 470°C, 480°C, 490°C, 500°C, 510°C, 520°C, 530°C or higher. In some cases, the solution temperature may be 20°C to 40°C or approximately 20°C to 40°C, lower than the solidus temperature of the alloy in question, and more preferably 30°C. The metal strip may be quenched immediately after or after reheating to the post-rolling temperature. The metal strip may be quenched at a winding temperature of 150°C, 140°C, 130°C, 120°C, 110°C, or 100°C or lower, although other values ​​may be used. The metal strip may then be wound and fed. In this respect, the coiled metal strip may have desired physical properties for distributions such as desired specifications and desired tempering.

[0025] After hot rolling and quenching, metal strips may have the desired specifications and tempering, such as T4 tempering. In this application, the tempering or state of alloys is referred to. For understanding the most commonly used descriptions of alloy tempering, refer to "United States National Standard (ANSI) H35 for Alloy and Tempering System." Condition F or tempering refers to the aluminum alloy as it was made. Condition O or tempering refers to the aluminum alloy after annealing. Condition W or tempering refers to the aluminum alloy after solution heat treatment, although it may be an unstable temper at room temperature. Condition T or tempering refers to the aluminum alloy after a specific heat treatment that results in stable tempering. Condition T3 or tempering refers to the aluminum alloy after solution heat treatment (i.e., solution treatment), cold working, and natural aging. Condition T4 or tempering refers to the aluminum alloy after natural aging following solution heat treatment (i.e., solution treatment). Condition T6 or tempering refers to the aluminum alloy after artificial aging following solution heat treatment. Condition T8 or tempering refers to aluminum alloys that have undergone artificial aging following cold working and solution heat treatment.

[0026] In some cases, the metal strip may undergo dynamic recrystallization during hot rolling by starting the hot rolling process at a high temperature (e.g., a hot rolling inlet temperature higher than the preheating temperature, such as approximately 550°C or higher) and allowing the metal strip to cool to the hot rolling outlet temperature during the hot rolling process. In some cases, dynamic recrystallization during hot or warm rolling may occur by applying a force sufficient to cause sufficient strain to the metal article during rolling at a specific temperature, thereby causing the metal article to recrystallize.

[0027] Dynamic recrystallization eliminates the need to reheat the metal strip (for example, until it exceeds the recrystallization temperature) and allows the metal strip to be quenched immediately after hot rolling. Rapid quenching immediately after hot rolling can also help avoid undesirable precipitates. At certain temperatures, precipitates such as the Mg2Si phase begin to form over time. A high-precipitation region may be defined based on the temperature and the time it is expected that precipitates will rapidly form at that temperature, with 1% to 90% of the precipitation completed. Therefore, it may be desirable to minimize the time spent in the high-precipitation region to minimize precipitate formation. Dynamic recrystallization followed by rapid quenching can minimize the time the metal strip spends at temperatures within the high-precipitation region. In some cases, the desired metallurgical properties may be achieved by hot rolling and quenching a metal strip, where the temperature of the metal strip decreases monotonically from just before entering the first hot rolling stand until just after leaving the quenching region (for example, the temperature decreases monotonically throughout the hot rolling and quenching process).

[0028] Depending on the circumstances, the metal strip may be subjected to hot rolling after minimal or no initial quenching. During hot rolling, the temperature of the metal strip may be reduced from a hot rolling inlet temperature higher than the recrystallization temperature (e.g., a preheating temperature of 550°C or higher) to a hot rolling outlet temperature lower than the hot rolling inlet temperature. The temperature reduction from the hot rolling inlet temperature to the hot rolling outlet temperature may be monotonically reduced. To achieve the temperature reduction during hot rolling, each stand of the hot rolling mill may extract heat from the metal strip. For example, heat may be extracted from the metal strip passing through the work rolls of the hot rolling mill by sufficiently cooling the hot rolling mill stand and allowing the metal strip to pass through the hot rolling mill stand. Depending on the circumstances, heat may be extracted from the metal strip between the hot rolling mill stands by using a lubricant or other cooling material (e.g., a fluid such as air or water) instead of, or in addition to, heat removal by the hot rolling mill stand itself. Depending on the circumstances, the last and second-to-last hot rolling stands may roll the metal strip at a gradually decreasing temperature. Depending on the circumstances, the last and second-to-last hot rolling stands may roll the metal strip at the same or approximately the same temperature.

[0029] Instead of relying on post-rolling recrystallization (e.g., after hot rolling) during a heat treatment process, which may require raising the temperature before quenching and potentially prolong the duration in the high-precipitation region, the metal strip may undergo dynamic recrystallization during the hot rolling process, as described herein. Dynamic recrystallization may involve rolling the metal strip at a sufficiently high strain rate and a sufficiently high temperature. Dynamic recrystallization may occur at the final rolling stand of the hot rolling mill. Dynamic recrystallization depends on the strain rate and temperature of the metal strip during processing. The Zener-Hollomon parameter (Z) is given by:

number

number

[0030] Furthermore, in order to minimize the time spent in the high-precipitation region, it may be desirable to operate the hot rolling mill at high speed. For example, in a hot rolling mill using three stands to reduce a metal strip from a 16 mm standard to a 2 mm standard, if the strip speed at the inlet of the hot rolling mill is approximately 50 m / min, the strip speed at the outlet of the hot rolling mill will be approximately 400 m / min. Therefore, in order to achieve a suitable minimum period in the high-precipitation region, the quenching process may need to reduce the temperature of the metal strip by approximately 400°C (e.g., to 100°C) while the metal strip is moving at a speed of approximately 400 m / min. For some metals, such as steel, such rapid quenching may be impossible, impractical, and may require large, expensive, and inefficient equipment. In aluminum, it is possible to provide quenching as described herein, particularly when the recrystallization temperature is minimized by shifting part of the thickness reduction from the initial hot rolling stand to the final hot rolling stand. Furthermore, if the hot rolling process is separated from the casting process, the hot rolling process may be permitted to proceed at high speed as described herein. High speed during the hot rolling process may help minimize the time spent in the high precipitation region. In addition, as described herein, a high hot rolling rate may facilitate the achievement of the appropriate high strain rate required to achieve a low recrystallization temperature.

[0031] Furthermore, using relatively thin metal strips may facilitate dynamic recrystallization and rapid quenching, minimizing precipitate formation. By casting metal strips in relatively thin specifications as described herein, the hot rolling process can proceed at high speed, followed by a rapid quenching process, thereby reducing the time spent in the high-precipitation region. Thin specifications also facilitate the hot rolling speed. The techniques for dynamic recrystallization and rapid quenching described herein can facilitate the production of metal strips or other metallurgical products bearing T4 temper and having less precipitate than expected. For example, a metal strip manufactured according to a particular aspect of the present disclosure may have a T4 temper and contain a volume fraction of Mg2Si of about 4.0%, 3.9%, 3.8%, 3.7%, 3.6%, 3.5%, 3.4%, 3.3%, 3.2%, 3.1%, 3.0%, 2.9%, 2.8%, 2.7%, 2.6%, 2.5%, 2.4%, 2.3%, 2.2%, 2.1%, 2.0%, 1.9%, 1.8%, 1.7%, 1.6%, 1.5%, 1.4%, 1.3%, 1.2%, 1.1%, 1.0%, 0.9%, 0.8%, 0.7%, 0.6%, 0.5%, 0.4%, 0.3%, 0.2%, or 0.1% or less. In some cases, metal strips manufactured according to certain aspects of this disclosure have a T4 temper and are approximately 10%, 9.9%, 9.8%, 9.7%, 9.6%, 9.5%, 9.4%, 9.3%, 9.2%, 9.1%, 9%, 8.9%, 8.8%, 8.7%, 8.6%, 8.5%, 8.4%, 8.3%, 8.2%, 8.1%, 8%, 7.9%, 7.8%, 7.7%, 7.6%, 7.5%, 7.4%, 7.3% The volume fraction of Mg2Si may be %, 7.2%, 7.1%, 7%, 6.9%, 6.8%, 6.7%, 6.6%, 6.5%, 6.4%, 6.3%, 6.2%, 6.1%, 6%, 5.9%, 5.8%, 5.7%, 5.6%, 5.5%, 5.4%, 5.3%, 5.2%, 5.1%, 5%, 4.9%, 4.8%, 4.7%, 4.6%, 4.5%, 4.4%, 4.3%, 4.2%, or 4.1% or less. As used herein, when referring to the volume fraction of Mg2Si, it may refer to the volume fraction of Mg2Si relative to the total amount of Mg2Si that may be formed in a particular alloy being cast.The percentage of the volume fraction of Mg2Si may also refer to the percentage of completion of the precipitation reaction that forms Mg2Si.

[0032] Specific aspects and features of this disclosure relate to techniques for taming the size, shape, and size distribution of iron-containing (Fe-containing) intermetallic compounds. Taming the properties of Fe-containing intermetallic compounds is important to achieve optimal product performance to meet the required specifications, particularly for 6xxx alloys, especially aluminum automotive parts. However, conventional DC casting may require prolonged (e.g., several hours) high-temperature (e.g., >530°C) homogenization to convert beta-Fe (β-Fe) to alpha-Fe (α-Fe) intermetallic compounds, and specific aspects of this disclosure are suitable for producing metallic products with desired Fe-containing intermetallic compounds. As described herein, specific aspects of this disclosure relate to producing intermediate-standard products from a continuous casting machine. Intermediate specification products can be finished into T4 tempered products by i) cold rolling and solution heat treatment up to the final specification, ii) hot rolling and solution heat treatment up to the final specification, iii) hot rolling up to the final specification, reheating with a magnetic heater and in-line quenching, iv) hot rolling up to the final specification and solution heat treatment, or v) hot rolling up to the final specification and dynamic recrystallization to produce T4 temper.

[0033] In some cases, metal strips cast from a continuous casting machine may be rolled (e.g., hot-rolled) before winding. Pre-winding rolling can result in a significant thickness reduction of at least 30% or generally around 50% to 75%. In some cases, additional stands may be used, but more effective results have been found when continuously cast metal strips are rolled on a single hot-rolling stand before winding. In some cases, this high-pressure hot-rolling after continuous casting (e.g., thickness reduction of 30%, 35%, 40%, 45%, 50%, 55%, 60%, 65%, 70%, or 75% or more) can help crush Fe-containing particles in the metal strip, among other advantages. If the thickness of the metal strip is reduced by rolling after continuous casting and before winding, the hot-rolling process performed after unwinding requires one less hot-rolling stand and / or one less pass, since the thickness of the metal strip has already been reduced between unwinding and winding.

[0034] In some cases, metal strips can be flash-homogenized. Flash homogenization may involve heating the metal strip to a temperature above 500°C (e.g., 500-570°C, 520-560°C, or approximately 560°C) for a relatively short period of time (e.g., about 1 to 10 minutes, e.g., 30 seconds, 45 seconds, 1 minute, 1 minute 30 seconds, 2 minutes, 3 minutes, 4 minutes, 5 minutes, 6 minutes, 7 minutes, 8 minutes, 9 minutes, or 10 minutes, or any range in between). This heating is performed between the continuous casting machine and the initial winding, more specifically between the continuous casting machine and the hot rolling stand before winding, or between the hot rolling stand and winding. This flash homogenization helps to reduce the aspect ratio of Fe-containing intermetallic compounds (e.g., α or β type) and can also reduce the size of these intermetallic compounds. In some cases, flash homogenization (e.g., at 570°C for about 2 minutes) can successfully achieve beneficial spheroidization and / or purification of Fe component particles, but requires broader homogenization at higher temperatures.

[0035] In some cases, as described herein, a combination of flash homogenization and hot rolling under high pressure after continuous casting may be particularly useful for purifying (e.g., grinding) Fe-containing particles.

[0036] As one example, the casting system may include a continuous casting machine, a furnace (e.g., a tunnel furnace), a hot rolling stand, and a coiler. In some cases, quenching is performed one or more times before and / or after the hot rolling stand. The hot rolling stand can result in a reduction of at least 30% or 50-70% in the thickness of the metal strip. Quenching before the hot rolling stand is optional but can effectively pulverize Fe-containing particles and improve precipitation properties. In some cases, after hot rolling, quenching, and coiling, the metal strip may be gradually / rapidly heated and immersed at a relatively high temperature (e.g., >500°C) before being hot-rolled. In some cases, after hot rolling, quenching, and coiling, the metal strip may be gradually / rapidly heated to a relatively low temperature (e.g., <350°C) before being warm-rolled. After hot rolling, quenching, and coiling, the metal strip may be cold-rolled without further heat treatment. As described herein, these various techniques result in a variety of properties with respect to Fe-containing particles, such as different Fe component size distributions.

[0037] In some cases, the metal strip may be reheated at various points within the hot rolling system by using a heating device such as an induction heater or a magnetic heater such as a rotating magnetic heater. A non-limiting example of a suitable rotating magnetic heater is disclosed in U.S. Provisional Patent Application No. 62 / 400,426, “Rotating Magnetic Heating Induction,” filed September 27, 2016.

[0038] Generally, the rolling stand of a hot rolling system is cooled by a coolant system that includes, for example, nozzles that spray a coolant onto the rolls of the rolling stand and / or the metal strip itself. This coolant system may extract enough heat so that the mechanical action of reducing the thickness of the metal strip by passing it through the hot rolling stand does not raise the temperature of the metal strip. However, in some cases, the metal strip can be intentionally reheated by reducing the amount of coolant added by the coolant system, thereby enabling the mechanical action of reducing the thickness of the metal strip by passing it through the hot rolling stand and giving the metal strip a positive temperature change.

[0039] As used herein, various cooling and / or quenching apparatuses are described in relation to coolants supplied by one or more nozzles. Rapid cooling of a metal strip can be provided using other mechanisms, whether fluid-based or nozzle-based. In some cases, for example, a metal strip can be cooled or quenched using a large amount of coolant supplied directly from a hose, conduit, tank or other such structure for transporting the coolant to the metal strip.

[0040] While aspects and features of the present disclosure are described herein in relation to the manufacture of metal strips, aspects of the present disclosure may also be used to manufacture metal products of any preferred size or shape, such as foils, sheets, slabs, plates, shades, or other metal products.

[0041] These exemplary examples are provided to introduce the reader to the general subject matter described herein and are not intended to limit the scope of the disclosed concepts. The following sections describe various additional features and embodiments with reference to the drawings, but should not be used to limit this disclosure in the same way as the exemplary embodiments, and in the drawings, the same numbers indicate the same elements, and the directional descriptions are used to describe the exemplary embodiments. The elements included in the embodiments herein are not drawn to scale.

[0042] Figure 1 is a schematic diagram showing a separate metal casting and rolling system 100 according to a particular aspect of the present disclosure. The separate metal casting and rolling system 100 may include a casting system 102, a storage system 104, and a hot rolling system 106. The separate metal casting and rolling system 100 may be considered as a single continuous processing line having separate subsystems. Metal strips 110 cast by the casting system 102 can proceed downstream through the storage system 104 and the hot rolling system 106. Since the metal strips 110 are intermittently produced by the casting system 102, stored by the storage system 104, and hot-rolled by the hot rolling system 106, the separate metal casting and rolling system 100 may be considered continuous. In some cases, the separate metal casting and rolling system 100 may be located within a single building or facility, but in some cases, the subsystems of the separate metal casting and rolling system 100 may be located separately. In some cases, a single casting system 102 can be associated with one or more storage systems 104 and one or more hot rolling systems 106, thereby enabling the casting system 102 to operate continuously at a speed much higher than the speed or allowable speed of a single storage system 104 or hot rolling system 106.

[0043] The casting system 102 includes a continuous casting apparatus, such as a belt-type continuous casting machine 108, for continuously casting metal strips 110. The casting system 102 may optionally include a rapid quenching system 114 located directly downstream of or immediately after the belt-type continuous casting machine 108. The casting system 102 may include a winding device that can wind the metal strips 110 onto an intermediate coil 112.

[0044] The intermediate coil 112 can accumulate a portion of the metal strip 110 coming out of the belt-type continuous casting machine 108 and, after the metal strip has been cut by a shearing machine or other suitable device, be transported to another location, and then a new intermediate coil 112 can be formed from additional metal strip 110 coming out of the belt-type continuous casting machine 108, thus enabling the belt-type continuous casting machine 108 to operate continuously or semi-continuously.

[0045] The intermediate coil 112 may be supplied directly to the hot rolling system 106, or it may be stored and / or processed within the storage system 104. The storage system 104 may include various storage mechanisms, such as vertical or horizontal storage mechanisms, and periodically or continuously rotating storage mechanisms. In some cases, the intermediate coil 112 may be preheated in a preheater 116 (e.g., a furnace) when it is stored within the storage system 104. Preheating may be performed for part or all of the time the intermediate coil 112 is in the storage system 104. After being stored within the storage system 104, the metal strip 110 may be supplied to the hot rolling system 106.

[0046] The hot rolling system 106 can reduce the thickness of the metal strip 110 from the as-cast specification to a specification desired for supply. In some cases, the desired gauge for supply may be exactly or about 0.7 mm to 4.5 mm, or exactly or about 1.5 mm to 3.5 mm. The hot rolling system 106 may include a series of hot rolling stands 118 for reducing the thickness of the metal strip 110. In some cases, the series of hot rolling stands 118 may include a single hot rolling stand, but may be any number, e.g., two, three, or more hot rolling stands. In some cases, using a large number of hot rolling stands (e.g., three, four, or more) results in better surface quality for a given total thickness reduction (e.g., thickness reduction from before the first hot rolling stand to after the last hot rolling stand) because each rolling stand needs to reduce the thickness of the metal by a smaller amount and generally results in fewer surface defects on the metal strip. The hot rolling system 106 can further perform other processing on the metal strip, such as surface finishing (e.g., texturing), preheating, and heat treatment. The metal strip 110 exiting the hot rolling system 106 may be supplied as is to further processing equipment (e.g., a blanking machine or a bending machine) or wound into a supplyable coil 120 (e.g., a finished coil). As used herein, the term supplyable can describe a metal product having the desired properties of the metal strip, such as a coiled metal strip. For example, a supplyable coil 120 may include a coiled metal strip having physical and / or chemical properties that meet the specifications of the requesting equipment manufacturer. The supplyable coil 120 may be tempered to W or T. The supplyable coil 120 may be stored, sold, and shipped as needed.

[0047] The separate metal casting and rolling system 100 shown in Figure 1 allows the speed of the casting system 102 to be separated from the speed of the hot rolling system 106. As shown in the figure, the separate metal casting and rolling system 100 uses a storage system 104 for storing intermediate coils 112, and the metal strips 110 coming out of the belt-type continuous casting machine 108 are wound into separate units and stored until they are available for the hot rolling system 106 to process them. Instead of storing intermediate coils 112, in some cases the storage system 104 allows the continuous metal strips 110 to be supplied to the hot rolling system 106 at a second speed different from the first speed, using an in-line accumulator that receives the metal strips 110 from the casting system 102 at a first speed and accumulates them between a series of moving rollers. The in-line accumulator can be sized to adapt to a predetermined time difference between the first speed and the second speed, based on the desired casting period of the casting system 102. In a system where continuous operation of the casting system 102 is desired, a coil base storage system 104 is desirable.

[0048] Figure 2 is a timing chart 200 for manufacturing various coils using a separate metal casting and rolling system according to a particular embodiment of the present disclosure. The timing chart 200 shows the position of each of the various coils and the process performed on them as a function of time as the coil passes from the casting system 202 through the storage system 204 and through the hot rolling system 206. The casting system 202, storage system 204 and hot rolling system 206 can be the casting system 102, storage system 104 and hot rolling system 106 of the separate metal casting and rolling system 100 of Figure 1.

[0049] As described above, the casting system 202 can cast intermediate coils. Blocks 222A, 222B, 222C, 222D, and 222E represent the casting times for intermediate coils A, B, C, D, and E, respectively. The casting system 202 can cast each intermediate coil at a specific casting speed. Therefore, the coil casting time 228 can represent the time required for the casting system 202 to cast and wind a single intermediate coil. In some cases, the casting system 202 undergoes a reset time during which it is reset to cast and wind the next intermediate coil. In other cases, the casting system 202 can immediately begin casting and winding the next intermediate coil. As shown in Figure 2, the casting system 202 can output intermediate coils continuously and repeatedly.

[0050] The intermediate coils can be transported to the storage system 204 for storage and / or any processing (e.g., reheating). Blocks 224A, 224B, 224C, 224D, and 224E represent the storage periods for intermediate coils A, B, C, D, and E, respectively. Since the speed of the casting system 202 is separated from the speed of the hot rolling system 206, the storage system 204 can store any appropriate number of intermediate coils for various time periods, depending on the number of available hot rolling systems 206 and the speeds of the casting system 202 and the hot rolling system 206.

[0051] In some cases, each intermediate coil can remain in the storage system 204 for a minimum storage time 230, which can be the minimum time required to perform any processing during storage. In some cases, there is no minimum storage time 230, and the intermediate coil can be delivered to the hot rolling system 206 without storage if the hot rolling system 206 is available to receive the intermediate coil. For example, if there is no minimum storage time 230, intermediate coil A is delivered directly to the hot rolling system 206, and block 224A does not exist.

[0052] Intermediate coils supplied to the hot rolling system 206 may be rolled or processed into supplyable coils. Blocks 226A, 226B, 226C, 226D, and 226E represent the time the hot rolling system 206 takes for intermediate coils A, B, C, D, and E, respectively. The hot rolling system 206 can operate at a set speed, thereby generating a coil rolling time 232, which represents the time required to hot roll or process the intermediate rolls within the hot rolling system 206.

[0053] The process of casting, storing, and hot-rolling metal strips can be considered continuous when, during separation, the metal strips pass continuously from one system to the next. The storage system 204 is particularly desirable when the coil casting time 228 is shorter than the coil rolling time 232. The difference between the coil casting time 228 and the coil rolling time 232 can be used as a function of the overall casting period (e.g., the length of time during which it is desirable for the casting system 202 to continuously cast intermediate coils before stopping) to determine the required size of the storage system 204.

[0054] Figure 3 is a schematic diagram showing a separate continuous casting system 300 according to a particular embodiment of the present disclosure. The separate continuous casting system 300 includes a continuous casting apparatus, for example, a belt-type continuous casting machine 308. The belt-type continuous casting machine 308 includes opposing belts 334 that can extract heat from the liquid metal 336 at a cooling rate sufficient to solidify the liquid metal 336, and the solid is discharged from the belt-type continuous casting machine 308 as a metal strip 310. The belt-type continuous casting machine 308 can operate at a desired casting speed. The opposing belts 334 can be manufactured from any suitable material, but in some cases the belts 334 are manufactured from copper. The cooling system within the belt-type continuous casting machine 308 is able to extract sufficient heat from the liquid metal 336, so that the metal strip 310 exiting the belt-type continuous casting machine 308 has a temperature between 200 and 530°C, although other ranges may also be used.

[0055] In some cases, rapid solidification and rapid cooling can be achieved by using a belt-type continuous casting machine 308 configured to extract sufficient heat from the metal so that the metal strip 310 exiting the belt-type continuous casting machine 308 has a temperature of less than 200°C. In other cases, rapid cooling after casting can be performed by a quenching system 314 located directly downstream of or immediately after the belt-type continuous casting machine 308. The quenching system 314 can extract sufficient heat from the metal strip 310 so that, regardless of the temperature at which the metal strip 310 exits the belt-type continuous casting machine 308, the metal strip exits the quenching system 314 at a temperature of 100°C or less. As one example, the quenching system 314 can be configured to lower the temperature of the metal strip 310 to 100°C or less within about 10 seconds.

[0056] The quenching system 314 may include one or more nozzles 340 for distributing a coolant 342 to a metal strip 310. The coolant 342 can be supplied to the nozzles 340 from a coolant source 346 connected to the nozzles 340 by appropriate piping. The quenching system 314 may include one or more valves 344 to adjust the amount of coolant 342 applied to the metal strip 310, and the valves 344 may include valves 344 associated with one or more nozzles 340 and / or valves 344 associated with the coolant source 346. In some cases, the coolant source 346 may include a temperature control device for setting a desired temperature for the coolant 342. A controller 352 may be operably connected to the valves 344, the coolant source 346 and / or a sensor 350 to control the quenching system 314. The sensor 350 may be any suitable sensor for determining the temperature of the metal strip 310, for example, the temperature of the metal strip 310 when it leaves the quenching system 314. Based on the detected temperature, the controller 352 can adjust the temperature or flow rate of the coolant 342 to maintain the temperature of the metal strip 310 within a desired parameter (e.g., below 100°C) when the metal strip 310 exits the quenching system 314.

[0057] The quenching system 314 can be positioned to begin cooling the metal strip 310 over a distance 348 downstream of the distance 348, at which point the metal strip 310 exits the belt-type continuous casting machine 308. The distance 348 can be as small as feasible. In some cases, the distance 348 is 5m, 4m, 3m, 2m, 1m, 50cm, 25cm, 20cm, 15cm, 10cm, 5cm, 2.5cm, or less than 1cm.

[0058] The metal strip 310 exiting the quenching system 314 can have a desirable distribution of dispersed phase-forming elements and therefore be in a desirable state for subsequent dispersed phase formation (e.g., dispersed phase precipitation) as disclosed herein. The metal strip 310 exiting the quenching system 314 can be wound into an intermediate coil by a winding device.

[0059] Figure 4 is a schematic diagram showing an intermediate coil vertical storage system 400 according to a particular embodiment of the present disclosure. The intermediate coil vertical storage system 400 may be the storage system 104 of Figure 1. The intermediate coil vertical storage system 400 can be used to store an intermediate coil 412, for example, an intermediate coil 412 including a metal strip 410 wound around a spindle 452. The intermediate coil 412 is lifted vertically and placed on a storage rack 454 having a vertical support 456. The vertical support 456 interacts with the spindle 452 to ensure that the intermediate coil 412 is held vertically. In some cases, the vertical support 456 may be an extended projection that fits into an opening in the spindle 452, but other members may also be used. In some cases, the storage rack 454 may include shoulders 458 for holding the metal strip 410 of the intermediate coil 412 at a distance from the storage rack 454. In some cases, the intermediate coil 412 may include a spindleless metal strip 410, in which case the vertical support 456 can be fitted into a central opening formed by the coiled metal strip 410.

[0060] Figure 5 is a schematic diagram showing an intermediate coil horizontal storage system 500 according to a particular embodiment of the present disclosure. The intermediate coil horizontal storage system 500 may be the storage system 104 of Figure 1. The intermediate coil horizontal storage system 500 can be used to store an intermediate coil 512, for example, an intermediate coil 512 including a metal strip 510 wound around a spindle 552. The intermediate coil horizontal storage system 500 may include one or more horizontal supports 562 for horizontally supporting the spindle 552 of the intermediate coil 512. In some cases, one or more horizontal supports 562 may be fixed to a single structure 564, for example, a wall or other suitable structure.

[0061] In some cases, the intermediate coil 512 can rotate in the rotational direction 560 while stored. The rotation can occur periodically (for example, rotating for 30 seconds every 10 minutes) or continuously. In some cases, the horizontal support 562 may include a motor or other power source to rotate the intermediate coil 512.

[0062] In some cases, the intermediate coil 512 may include a metal strip 510 without a spindle, in which case the horizontal support 562 may include a spindle or other member that supports the intermediate coil 512 horizontally. In some cases, the horizontal support may support such a spindleless intermediate coil from a central opening formed by the coiled metal strip 510, thus avoiding the increased weight being added to the portion of the metal strip 510 that is gravity-dependent below the opening. However, in some cases, the horizontal support 562 may include a roller or other such member that supports the intermediate coil horizontally from below the bottom of the intermediate coil. In some cases, such a roller may facilitate the rotation of the intermediate coil.

[0063] Figure 6 is a schematic diagram showing a hot rolling system 600 according to some aspects of the present disclosure. The hot rolling system 600 may be the hot rolling system 106 of Figure 1. The hot rolling system 600 can receive a metal strip 610 in the form of an intermediate coil unwound by, for example, a rewinding device (e.g., a rewinding machine). The metal strip 610 can pass through various zones of the hot rolling system 600, such as an initial quenching zone 668, a hot rolling zone 670, a heat treatment zone 672, and a heat treatment quenching zone 674. The hot rolling system may include fewer or more zones.

[0064] In the initial quenching zone 668, the metal strip 610 can be cooled to a hot rolling temperature suitable for hot rolling in the hot rolling zone 670. The hot rolling temperature may be 350°C or approximately 350°C, but other values ​​may be used. Any suitable heat extraction device can be used in the initial quenching zone 668, such as an initial quenching nozzle 678 that supplies the initial quenching coolant 680 to the metal strip 610. Various controllers and sensors can be used to ensure that the heat extraction device cools the metal strip 610 by the desired amount. The initial quenching zone 668 can be located upstream of the hot rolling zone 670, such as directly upstream of the hot rolling zone 670.

[0065] In the hot rolling zone 670, one or more hot rolling stands can reduce the thickness of the metal strip 610. Hot rolling may include reducing the thickness of the metal strip 610 when the metal strip 610 is at a hot rolling temperature of 350°C or approximately 350°C. Each hot rolling stand may include a pair of work rolls 682 that are in direct contact with the metal strip 610 and a pair of backup rolls 684 that apply rolling force to the metal strip 610 through the work rolls 682. Other types of hot rolling stands may be used, such as duo stands, quart stands, sext stands, or other stands with any appropriate number of backup rolls, including zero stands. Various heat extraction devices may be used on the metal strip 610, work rolls 682 and / or backup rolls 684 to counteract the mechanically induced heat generated during hot rolling.

[0066] In the heat treatment zone 672, heating devices such as a pair of rotating magnetic heaters 688 can heat the metal strip 610. The metal strip can be heated to a heat treatment temperature of 500°C or approximately 500°C or higher within the heat treatment zone 672. The heat treatment zone 672 can rapidly heat the metal strip 610 after it has left the hot rolling zone 670. Various controllers and sensors can be used to ensure that the heating devices heat the metal strip 610 to the heat treatment temperature. The rotating magnetic heaters 688 may include an electromagnet or permanent magnet rotor that rotates in close proximity to the metal strip 610 without contacting the metal strip 610. These rotating magnetic heaters 688 can generate a changing magnetic field that can induce eddy currents within the metal strip 610, thereby heating the metal strip 610.

[0067] In some cases, heating normally performed within the heat treatment zone 672 is carried out entirely or partially in the hot rolling zone 670 by allowing the mechanically induced heat generated during hot rolling to heat the metal strip 610 toward, or to, or beyond, the heat treatment temperature. Therefore, any additional heating devices in the heat treatment zone 672 (e.g., rotating magnetic heater 688) are used less frequently or excluded from the hot rolling system 600.

[0068] In the heat treatment quenching zone 674, the metal strip 610 can be rapidly cooled to a desired output temperature of 100°C or approximately 100°C. In some cases, the metal strip is cooled to a desired winding temperature (e.g., approximately 100°C), and then reheated to the desired winding temperature using any suitable reheating device, such as a rotating magnetic heater. The heat treatment quenching zone 674 can be located directly downstream of the heat treatment zone 672 and at a distance sufficient to ensure that the metal strip 610 is maintained above the heat treatment temperature for a period of no more than 5 seconds or 1 second. In some cases, the desired period is as short as possible, and the distance between the heat treatment zone 672 and the heat treatment quenching zone 674 is shortened. The heat treatment quenching zone 674 may include one or more heat treatment quenching nozzles 690 that supply heat treatment quenching coolant 692 to the metal strip 610. In some cases, the heat treatment quenching coolant 692 is the same coolant as the initial quenching coolant 680.

[0069] Various support rolls 686 can be used throughout the entire hot rolling system 600 to facilitate the passage of the metal strip 610 through the hot rolling system 600.

[0070] Figure 7 is a schematic diagram and chart showing a combination of relevant temperature profiles 701 for a hot rolling system 700 and a metal strip 710 rolled thereon, according to several embodiments of the present disclosure. The hot rolling system 700 can be the hot rolling system 106 shown in Figure 1.

[0071] The hot rolling system 700 includes a preheating zone 794, an initial quenching zone 768, a hot rolling zone 770, a heat treatment zone 772, and a heat treatment quenching zone 774, from upstream unwinding to downstream winding. The temperature profile 701 shows that the metal strip 710 enters the hot rolling system 700 at either a standard temperature (e.g., 350°C, indicated by the dotted line) or a preheating temperature (e.g., 530+°C, indicated by the dotted line). If it enters at the preheating temperature, the preheating zone 794 adds little to no additional heat to the metal strip 710. However, if it enters at any temperature lower than the desired preheating temperature (e.g., 530°C or higher), one or more heating devices in the preheating zone 794 add heat to the metal strip 710 to raise the temperature of the metal strip above the desired preheating temperature. As disclosed herein, preheating (795) the metal strip 710 can improve the dispersion of the dispersed phase within the metal strip 710. In some cases, the preheating zone 794 may include a set of rotating permanent magnets 788, but other heating devices may also be used.

[0072] Before entering the hot rolling zone 770, the metal strip 710 can undergo initial quenching 769 in the initial quenching zone 768. In the initial quenching zone 768, an initial quenching coolant 780 supplied by one or more initial quenching nozzles 778 can lower the temperature of the metal strip 710 to the hot rolling temperature (e.g., 350°C or around 350°C) for the subsequent hot rolling (770).

[0073] During the hot rolling process within the hot rolling zone 770, the thickness of the metal strip 710 decreases due to the force applied from the backup roll 784 through the work roll 782. To counteract the mechanically induced heat generated by hot rolling, one or more rolling coolant nozzles 796 can supply rolling coolant 798 to one or more metal strips 710, work rolls 782, or backup rolls 784. Thus, as seen in the temperature profile 701, the temperature of the metal strip 710 can be maintained at or near the rolling temperature throughout the entire hot rolling zone 770.

[0074] In the heat treatment zone 772, the metal strip 710 can be heated 773 to a heat treatment temperature (e.g., 500°C or near or above). The heat treatment zone 772 may include a set of rotating permanent magnets 788, but other heating devices may also be used. In the heat treatment quenching zone 774, the metal strip 710 can be quenched 775 to a temperature below the hot rolling temperature, such as an output temperature (e.g., below 100°C). The heat treatment quenching zone 774 can cool the metal strip 710 by supplying a heat treatment quenching coolant 792 from one or more heat treatment quenching nozzles 790. In some cases, the initial quenching coolant 780, the rolling coolant 798, and the heat treatment quenching coolant 792 may or may not originate from the same coolant source.

[0075] Figure 8 is a combined schematic diagram and chart showing the associated temperature profiles 801 of a hot rolling system 800 having an intentionally supercooled rolling stand and a metal strip 810 rolled thereon, according to some aspects of the present disclosure. The hot rolling system 800 may be the hot rolling system 106 of Figure 1.

[0076] The hot rolling system 800 includes a preheating zone 894, an initial quenching zone 868, a hot rolling zone 870, a heat treatment zone 872, and a heat treatment quenching zone 874, from upstream unwinding to downstream winding. The temperature profile 801 shows that the metal strip 810 enters the hot rolling system 800 at either a standard temperature (e.g., 350°C, indicated by the dotted line) or a preheating temperature (e.g., 530+°C, indicated by the dotted line). If it enters at the preheating temperature, the preheating zone 894 adds little to no additional heat to the metal strip 810. However, if it enters at any temperature lower than the desired preheating temperature (e.g., 530°C or higher), one or more heating devices in the preheating zone 894 add heat to the metal strip 810 to raise the temperature of the metal strip above the desired preheating temperature. As disclosed herein, preheating (895) the metal strip 810 can improve the dispersion arrangement within the metal strip 810. In some cases, the preheating zone 894 may include a set of rotating permanent magnets 888, but other heating devices may also be used.

[0077] Before entering the hot rolling zone 870, the metal strip 810 can undergo initial quenching 869 in the initial quenching zone 868. In the initial quenching zone 868, an initial quenching coolant 880 supplied by one or more initial quenching nozzles 878 can lower the temperature of the metal strip 810 to the hot rolling temperature (e.g., 350°C or around 350°C) for the subsequent hot rolling (870).

[0078] In the hot rolling process within the hot rolling zone 870, the thickness of the metal strip 810 decreases due to the force applied from the backup roll 884 through the work roll 882. To counteract the mechanically induced heat generated by hot rolling, one or more rolling coolant nozzles 896 can supply rolling coolant 898 to one or more metal strips 810, work rolls 882, or backup rolls 884. However, in contrast to the hot rolling system 700 in Figure 7, the hot rolling system 800 includes a deliberately supercooled rolling stand. To completely counteract the mechanically induced heat, the rolling stand 898 is deliberately supercooled by adding less rolling coolant 898 than necessary to the rolling coolant nozzle 896. Thus, as seen in the temperature profile 801, the metal strip 810 can have its temperature rise above the rolling temperature as it passes through the hot rolling zone 870, for example, towards, or up to, or even beyond, the target heat treatment temperature. In some cases, instead of adding less rolling coolant 898, less thermal extraction can be provided by using rolling coolant 898 at different temperatures or in different mixtures.

[0079] In the heat treatment zone 872, the metal strip 810 can be heated 873 to a heat treatment temperature (e.g., 500°C or near or above). The heat treatment zone 872 may include a set of rotating permanent magnets 888, but other heating devices may also be used. If the hot rolling stand is intentionally overcooled, the heat treatment zone 872 will add or not add most additional heat to achieve the desired heat treatment temperature in the metal strip 810.

[0080] In the heat treatment quenching zone 874, the metal strip 810 can be quenched to a temperature below the hot rolling temperature, such as the output temperature (e.g., below 100°C). The heat treatment quenching zone 874 can cool the metal strip 810 by supplying a heat treatment quenching coolant 892 from one or more heat treatment quenching nozzles 890. In some cases, the initial quenching coolant 880, the rolling coolant 898, and the heat treatment quenching coolant 892 may or may not originate from the same coolant source.

[0081] Figure 9 is a combined flowchart and schematic diagram showing a process for casting and rolling a metal strip in relation to a first variant and a second variant of a separation system according to several embodiments of the present disclosure. In block 903, the metal strip can be cast using a continuous casting apparatus such as a belt-type continuous casting machine. The metal strip can be cast at a first speed. In block 905, the metal strip can be stored, for example, in the form of an intermediate coil. In block 907, the metal strip can be reheated to a reheating temperature (e.g., 550°C or about 500°C or above) or above. In some cases, the reheating temperature may be 400°C to 580°C or about 400°C to 580°C. The metal strip can be reheated for a reheating period. In some cases, the reheating period may be 6 hours or less, 2 hours or less, 1 hour or less, 5 minutes or less, or 1 minute or less. In some cases, the reheating period can be selected to induce a desired amount of dispersion precipitate. In block 909, a metal strip can be hot-rolled to reduce its thickness to a desired thickness. The metal strip can be hot-rolled at a second speed different from the first speed. The second speed may be slower than the first speed. In any block 911, the metal strip can be wound up for delivery.

[0082] The right-hand portion of Figure 9 is a schematic diagram showing which blocks of process 900 can be executed by several subsystems of the first variant 901A and the second variant 901B of the separation-type casting and rolling system.

[0083] In the first variant 901A, casting in block 903 is performed by the casting system 902A. Storage of the metal strips in block 905 and reheating of the metal strips in block 907 are performed by the storage system 904A. Hot rolling of the metal strips in block 909 and arbitrary winding of the metal strips in block 911 are performed by the hot rolling system 906A.

[0084] In the second variant 901B, casting in block 903 is performed by the casting system 902B. Storage of the metal strips in block 905 is performed by the storage system 904B. Reheating of the metal strips in block 907, hot rolling of the metal strips in block 909, and optional winding of the metal strips in block 911 are performed by the hot rolling system 906B.

[0085] Figure 10 is a schematic diagram showing a process 1000 for casting and rolling a metal strip according to some aspects of the present disclosure. In block 1002, a continuous casting apparatus, such as a belt-type continuous casting machine, casts the metal strip. The metal strip can be cast at a first speed. In block 1004, the metal strip can be quenched (e.g., rapidly cooled) when it leaves the continuous casting apparatus, for example, immediately after leaving the casting apparatus or shortly thereafter. In block 1006, the metal strip can be wound into an intermediate coil.

[0086] The intermediate coil can be stored in block 1008. Storing the intermediate coil may optionally include storing the intermediate coil vertically or horizontally, and may optionally include suspending and / or rotating the intermediate coil. The intermediate coil can optionally be preheated to a preheating temperature in block 1008.

[0087] In block 1010, the metal strip can be unwound from the intermediate coil, for example, by a rewinding device in a hot rolling system. In any block 1014, the metal strip can be reheated to the reheating temperature. If the intermediate coil has been reheated to the reheating temperature in block 1008, reheating in block 1014 is avoided.

[0088] In block 1016, the metal strip can be quenched to the hot rolling temperature. In block 1018, the metal strip can be hot rolled to a desired thickness. The metal strip can be hot rolled at a second speed different from the first speed. The second speed may be slower than the first speed.

[0089] In any block 1020, the metal strip can be heated to a heat treatment temperature. Heating the metal strip to a heat treatment temperature may include rapidly applying heat to the metal strip after it has left the hot-rolling zone or immediately thereafter. Heating the metal strip to a heat treatment temperature may include rapidly applying heat to the metal strip over a short period of time. In block 1022, the metal strip can be fast-quenched. Fast-quenching the metal strip in block 1022 may allow the heat treatment of block 1020 to be stopped after a desired duration. Fast-quenching the metal strip in block 1022 may reduce the temperature of the metal strip to an output temperature, for example, 100°C or around 100°C or below. In any block 1024, the metal strip can be wound into a supplyable coil (e.g., a finished coil). In block 1024, the metal strip has the physical and / or chemical properties required for supply to the customer (e.g., properties that meet the desired specifications).

[0090] Figure 11 is Chart 1100 showing the temperature profile of a metal strip cast without post-quenching and stored at high temperatures before rolling, according to several embodiments of the present disclosure. The X-axis of Chart 1100 represents the distance from upstream to downstream (e.g., left to right) along the separate continuous casting and rolling system. The Y-axis of Chart 1100 is temperature (°C). Line 1102 of Chart 1100 represents the approximate temperature of the metal as it moves along the separate continuous casting and rolling system. The metal strip is shown to exit the casting apparatus at approximately 560°C, but in some cases, the metal strip may exit the casting apparatus at temperatures between approximately 200°C and 560°C, including approximately 350°C and 450°C.

[0091] If quenching is not performed after casting, the temperature of the metal strip exiting the casting apparatus may not decrease, or may decrease only slightly, before winding. If preheating occurs between casting and hot rolling (e.g., preheating during storage), the metal strip may be maintained at a high temperature (e.g., 530°C or around 530°C or above) and supplied to the hot rolling system at or near that temperature. During hot rolling, the metal strip may be allowed to cool down to the hot rolling temperature (e.g., 350°C or around 350°C) for at least the duration that the metal strip passes through the rolling stand of the hot rolling system. The metal strip may be rapidly reheated to a heat treatment temperature (e.g., 500°C or around 500°C or above) before being quenched to the output temperature (e.g., 100°C or around 100°C or below).

[0092] Figure 12 is Chart 1200 showing the temperature profile of a cast metal strip preheated before rolling without post-casting quenching, according to several embodiments of the present disclosure. The X-axis of Chart 1200 represents the distance from upstream to downstream (e.g., left to right) along the separate continuous casting and rolling system. The Y-axis of Chart 1200 is temperature (°C). Line 1202 of Chart 1200 represents the approximate temperature of the metal as it moves along the separate continuous casting and rolling system. The metal strip is shown to exit the casting apparatus at approximately 560°C, but in some cases, the metal strip may exit the casting apparatus at temperatures between approximately 200°C and 560°C, including approximately 350°C and 450°C.

[0093] If quenching is not performed after casting, the temperature of the metal strip exiting the casting apparatus may not decrease, or may only slightly, before winding. If preheating is performed in-line in the hot rolling system (e.g., immediately before hot rolling), the metal strip may enter the hot rolling system at approximately 350°C after temperature drop during storage. In-line preheating performed in the hot rolling system can rapidly raise the temperature of the metal strip to the preheating temperature (e.g., 530°C or around 530°C or above). Immediately after reheating, the metal strip can be quenched to the hot rolling temperature (e.g., 350°C or around 350°C) and maintained for at least the duration that the metal strip passes through the rolling stand of the hot rolling system. The metal strip can be rapidly reheated to the heat treatment temperature (e.g., 500°C or around 500°C or above) before being quenched to the output temperature (e.g., 100°C or around 100°C or below).

[0094] Figure 13 is Chart 1300 showing the temperature profile of a metal strip cast with post-quenching and stored at high temperatures before rolling, according to several embodiments of the present disclosure. The X-axis of Chart 1300 represents the distance from upstream to downstream (e.g., left to right) along the separate continuous casting and rolling system. The Y-axis of Chart 1300 is temperature (°C). Line 1302 of Chart 1300 represents the approximate temperature of the metal as it moves along the separate continuous casting and rolling system. The metal strip is shown to exit the casting apparatus at approximately 560°C, but in some cases, the metal strip may exit the casting apparatus at temperatures between approximately 200°C and 560°C, including approximately 350°C and 450°C.

[0095] If quenching is performed after casting, the temperature of the metal strip as it exits the casting apparatus can drop rapidly before winding. This rapid quenching can lower the temperature of the metal strip to approximately 500°C, 400°C, 300°C, 200°C, or 100°C or below. If preheating occurs between casting and hot rolling (e.g., preheating during storage), the metal strip may be maintained at a high temperature (e.g., 530°C or around 530°C or above) and supplied to the hot rolling system at or near that temperature. During hot rolling, the metal strip can be cooled down to the hot rolling temperature (e.g., 350°C or around 350°C) for at least the period during which the metal strip passes through the rolling stand of the hot rolling system. The metal strip can be rapidly reheated to a heat treatment temperature (e.g., 500°C or around 500°C or above) before being quenched to the output temperature (e.g., 100°C or around 100°C or below).

[0096] Figure 14 is Chart 1400, showing the temperature profile of a metal strip that has been cast with post-quenching and preheated before rolling, according to several embodiments of the present disclosure. The X-axis of Chart 1400 represents the distance from upstream to downstream (e.g., left to right) along the separate continuous casting and rolling system. The Y-axis of Chart 1400 is the temperature (°C). Line 1402 of Chart 1400 represents the approximate temperature of the metal as it moves along the separate continuous casting and rolling system. The metal strip is shown to exit the casting apparatus at approximately 560°C, but in some cases, the metal strip may exit the casting apparatus at temperatures between approximately 200°C and 560°C, including approximately 350°C and 450°C.

[0097] If quenching is performed after casting, the temperature of the metal strip exiting the casting apparatus can decrease rapidly before coiling. This rapid quenching can lower the temperature of the metal strip to approximately 500°C, 400°C, 300°C, 200°C, or 100°C or below. The metal strip may decrease in temperature or be heated during coiling. Depending on the temperature of the metal strip during coiling, the metal strip may decrease in temperature or be heated during coiling. The metal strip can enter the hot rolling system at approximately 350°C, but in some cases, it can enter the hot rolling system at a lower temperature. In-line preheating performed in the hot rolling system can rapidly raise the temperature of the metal strip to the preheating temperature (e.g., 530°C or around 530°C or above). Immediately after reheating, the metal strip is quenched to the hot rolling temperature (e.g., 350°C or around 350°C) and can be maintained at least for the period during which the metal strip passes through the rolling stand of the hot rolling system. The metal strip can be rapidly reheated to a heat treatment temperature (e.g., 500°C or around 500°C or above) before being quenched to the output temperature (e.g., 100°C or around 100°C or below).

[0098] Figure 15 is a series of enlarged images showing iron-containing (Fe-containing) intermetallic compounds in aluminum alloy AA6014 for a standard DC-cast metal strip 1500 compared to a metal strip 1501 cast using a separate-type casting and rolling system according to several embodiments of the present disclosure. Metal strip 1500 was manufactured according to a standard direct chill casting technique, which involves a long heat treatment time (e.g., several hours or several days). Metal strip 1501 was manufactured according to several embodiments of the present disclosure.

[0099] Comparing images of metal strips 1500 and 1501, DC cast metal strip 1500 exhibits many large intermetallic compounds with sizes of tens of microns, while the intermetallic compounds observed in metal strip 1501 are much smaller, with even the largest being less than a few microns in length. These different arrangements of intermetallic compounds indicate that solidification in DC cast metal strip 1500 occurred relatively slowly compared to solidification in metal strip 1501. In fact, solidification in metal strip 1501 occurred at a rate approximately 100 times faster than that of DC cast metal strip 1500.

[0100] Figure 16 is a series of scanning transmission electron microscope images showing dispersed phases in 6xxx-type aluminum alloy metal strips reheated at 550°C for 1 hour, comparing a metal strip 1601 cast without post-casting quenching and a metal strip 1600 cast with post-casting quenching, according to several embodiments of the present disclosure. Each of the metal strips 1600 and 1601 was manufactured using a continuous casting system as described herein, such as the continuous casting system 102 in Figure 1; however, the casting system used for metal strip 1600 included a fast quenching system, such as the fast quenching system 314 in Figure 3, while the casting system used for metal strip 1601 did not include a fast quenching system.

[0101] Metal strip 1601 was removed from the continuous belt casting machine at approximately 450°C and air-cooled to approximately 100°C over 3 hours. Metal strip 1600 was removed from the continuous belt casting machine at approximately 450°C and immediately quenched to 100°C in less than 10 seconds. Both metal strips 1601 and 1600 were reheated in a conventional resistance furnace preheated to 550°C for 1 hour.

[0102] The dispersed phase arrangement of metal strip 1601 shows a small number of dispersed phases of desirable size, with the majority being either too large or too small. In contrast, the dispersed phase arrangement of metal strip 1600 shows a well-distributed arrangement of dispersed phases of desirable size. The dispersed phases of desirable size can, on average, have diameters of 10 nm to 500 nm or 10 nm to 100 nm. For reference, 50 nm dots (e.g., intermediate-range desired dispersed phases) and 100 nm dots (e.g., largest desired dispersed phases) are shown on the left side of each micrograph, approximated to the scale of the micrograph.

[0103] Due to immediate quenching after continuous casting, the precursor metal strip to metal strip 1600 (for example, before reheating as shown) contained many small, well-dispersed dispersed-phase elements supersaturated within the aluminum matrix. This matrix, supersaturated with dispersed-phase elements, is uniquely advantageous as a precursor metal that can be reheated to produce the desired dispersed-phase configuration shown in Figure 16. Upon reheating of the precursor metal strip to metal strip 1600, the dispersed phase began to precipitate from the supersaturated matrix into the desired dispersed-phase configuration shown. In contrast, without post-casting quenching, the dispersed-phase configuration of metal strip 1601 is poorly distributed and contains undesirable large dispersed phases.

[0104] Figure 17 is Chart 1700, comparing the yield strength and three-point bending test results of 7xxx series metal strips manufactured using conventional semi-continuous casting technology and 7xxx series metal strips manufactured using separable continuous casting and rolling, according to several embodiments of this disclosure. Chart 1700 shows that, compared to conventional direct chill casting technology, the same three-point bending characteristics can be achieved while simultaneously achieving improved yield strength (e.g., 15% improvement) by using the separable continuous casting and rolling systems disclosed herein.

[0105] Figure 18 is Chart 1800, comparing the yield strength and solution heat treatment immersion time results of 6xxx metal strips manufactured using conventional semi-continuous casting technology and 6xxx metal strips manufactured using separate continuous casting and rolling, according to several embodiments of this disclosure. Chart 1800 shows that a desired yield strength characteristic (e.g., 290 MPa or around 290 MPa) typically requires an immersion time of at least 60 seconds at the solution temperature for metal casting using conventional semi-continuous casting technology (e.g., 520°C or around 520°C). However, for metal casting using the separate continuous casting and rolling systems disclosed herein, the desired yield strength characteristic can be achieved with an immersion time of zero seconds at the solution temperature.

[0106] Conventional DC casting techniques require this 60-second immersion time to return various reinforcing particles to the solution. However, due to the desired arrangement of particles in the metal casting according to various embodiments of this disclosure, it is not necessary to hold the metal at its temperature for several seconds, one second, or even more than 0.5 seconds; the desired strength can be achieved simply by heating the metal strip to its solution temperature.

[0107] This significant saving of immersion time is particularly important when it is desirable that the solution heat treatment be performed in-line with the hot rolling mill. Since the metal strip can move at speeds of approximately 300 m / min to over 800 m / min at the exit of the hot rolling stand, the amount of processing line required to provide a 60-second immersion for a DC-cast metal strip can exceed 300-800 meters. In contrast, the amount of processing line required to provide a desired immersion time for metal strips manufactured according to various embodiments of this disclosure is negligible. This distance can be substantially zero or as small as the minimum distance required between the heating device (e.g., a rotating magnetic heater) and the quenching device immediately downstream.

[0108] Figure 19 is a series of scanning transmission electron microscope images showing dispersed phases in AA6111 aluminum alloy metal strips reheated at 550°C for 8 hours, comparing a metal strip 1901 cast without post-casting quenching and a metal strip 1900 cast with post-casting quenching, according to several embodiments of the present disclosure. Each of the metal strips 1900 and 1901 was manufactured using a continuous casting system as described herein, such as the continuous casting system 102 in Figure 1; however, the casting system used for metal strip 1900 included a fast quenching system, such as the fast quenching system 314 in Figure 3, while the casting system used for metal strip 1901 did not include a fast quenching system.

[0109] Metal strip 1901 was removed from the continuous belt casting machine at approximately 450°C and air-cooled to approximately 100°C over 3 hours. Metal strip 1900 was removed from the continuous belt casting machine at approximately 450°C and immediately quenched (for example, to 100°C in less than approximately 10 seconds). Both metal strips 1901 and 1900 were gradually reheated to 540°C at a rate of 50°C / hour and held at 540°C for 8 hours.

[0110] The dispersed phase arrangement of metal strip 1901 shows coarse dispersed phase and only a few dispersed phases of the desired size. In contrast, the dispersed phase arrangement of metal strip 1900 shows a well-distributed arrangement of many dispersed phases of the desired size. The dispersed phases of the desired size can have, on average, diameters of 10 nm to 500 nm or 10 nm to 100 nm. For reference, 50 nm dots (e.g., intermediate-range desired dispersed phases), 100 nm dots, and 500 nm dots are shown on the left side of each micrograph, approximated to the scale of the micrograph.

[0111] Due to immediate quenching after continuous casting, the precursor metal strip to metal strip 1900 (for example, before reheating as shown) contained many small, well-dispersed dispersed-phase elements supersaturated within the aluminum matrix. This matrix, supersaturated with dispersed-phase elements, is uniquely advantageous as a precursor metal that can be reheated to produce the desired dispersed-phase configuration shown in Figure 19. When the precursor metal strip to metal strip 1900 was reheated, the dispersed phase began to precipitate from the supersaturated matrix into the desired dispersed-phase configuration shown. In contrast, without post-casting quenching, the dispersed-phase configuration of metal strip 1901 is less distributed and contains less and coarser dispersed phase.

[0112] Figure 20 is Chart 2000 showing the precipitation of Mg2Si in an aluminum metal strip during hot rolling and quenching according to several embodiments of the present disclosure. Chart 2000 shows the expected precipitation of Mg2Si for an aluminum alloy such as a 6xxx series aluminum alloy, depending on the time spent at a particular temperature. A strong precipitation zone 2001 is shown. The boundary of the strong precipitation zone 2001 indicates the expected precipitation of Mg2Si between 1% and 90% (e.g., between a volume fraction of 0.01 and 0.9). Thus, when the line crosses the left edge of the strong precipitation zone 2001, the metal following that line is expected to have a precipitation of approximately 1% Mg2Si, and it grows until the line crosses the right edge of the strong precipitation zone 2001, at which point the metal following that line is expected to have a precipitation of at least 90% Mg2Si. For example, a metal held at approximately 400°C is expected to have a deposition of less than 1% Mg2Si up to approximately 1.7 seconds, and if held at that temperature for 407 seconds, it is expected to have a deposition of at least 90% Mg2Si. Within the high deposition zone 2001, the deposition of Mg2Si proceeds rapidly, progressing quickly from 1% to 90% deposition. Therefore, in some cases, it may be desirable to minimize the amount of time the metal strip spends in the high deposition zone 2001. In some cases, it may be desirable to exit the high deposition zone 2001 after a specific amount of time calculated to achieve a desired volume fraction of Mg2Si or any other precipitate.

[0113] Line 2003 shows the temperature of a metal strip before, during, and after hot rolling, including quenching, where the metal strip is preheated and cooled before hot rolling, rolled at a hot rolling temperature below its recrystallization temperature, then heated after hot rolling, and finally quenched. Line 2003 can track the temperature of a metal strip, such as metal strip 710 in Figure 7, as it passes through the initial quenching zone 768, the hot rolling zone 770, the heat treatment zone 772, and the heat treatment quenching zone 774.

[0114] Line 2003 shows the initial temperature decrease to the hot rolling temperature. The metal strip remains at the hot rolling temperature throughout the entire hot rolling process, which may include passing through the first rolling stand 2007, the second rolling stand 2009, and the third rolling stand 2011. It should be noted that line 2003 is within the high deposition zone of Mg2Si 2001 as the metal strip passes through the first rolling stand 2009 and the third rolling stand 2011. Line 2003 may indicate that the metal strip is heat-treated after hot rolling and then quenched. Point 2005 indicates the start time of quenching.

[0115] Line 2003 enters the high-precipitation zone 2001 in approximately 2.5 seconds and exits it in approximately 19.2 seconds, thus spending approximately 16.7 seconds within the high-precipitation zone 2001. In some cases, line 2003 briefly exits the high-precipitation zone 2001 near the end of the heat treatment as the temperature rises to the leftmost part of the high-precipitation zone 2001, before the temperature drops rapidly once quenching begins.

[0116] Line 2013 shows the temperature of the metal strip before, during, and after hot rolling, including quenching, where the metal temperature is gradually cooled during hot rolling before final quenching. Line 2013 can track the temperature of the metal strip, such as metal strip 2110 in Figure 21, as it passes through the hot rolling zone 2170 and the heat treatment quenching zone 2174.

[0117] Line 2013 shows little to no initial quenching before hot rolling. Rather, the metal strip can be reduced during hot rolling from a hot rolling inlet temperature higher than the recrystallization temperature (e.g., preheating temperature such as 530°C or higher) to a hot rolling outlet temperature lower than the hot rolling inlet temperature. To achieve the temperature reduction during hot rolling shown in Line 2013, each stand of the hot rolling mill can extract heat from the metal strip. During the heat treatment process, the metal strip can undergo dynamic recrystallization during the hot rolling process instead of relying on recrystallization after rolling (e.g., after hot rolling). Line 2013 can follow a monotonically decreasing path from just before the first hot rolling stand to just after the quenching process.

[0118] It may be desirable to control the precipitation of precipitates such as Mg2Si. In some cases, the amount of precipitation can be minimized or controlled to a predetermined desired amount. For example, if it is desired to minimize precipitation, the amount of time spent in the high-precipitation zone 2001 can be minimized. To minimize the amount of time spent in the high-precipitation zone 2001, the metal strip can be exited from the final hot-rolling stand at the hot-rolling exit temperature and then rapidly quenched to a temperature lower than the temperature at which substantial precipitation is expected (e.g., a temperature lower than the high-precipitation region 2001 for that particular time frame). Therefore, it may be desirable to minimize the hot-rolling exit temperature and / or maximize the cooling rate during quenching. As described herein, it may be desirable to minimize the time spent in the high-precipitation zone 2001 by maximizing the reduction (e.g., thickness reduction rate) of the final hot-rolling stand (e.g., third hot-rolling stand 2021) or by selecting at least a reduction suitable for achieving a hot-rolling exit temperature suitable for fast quenching. For example, in some cases, the reduction performed at the first hot rolling stand 2017, the second hot rolling stand 2019, and the third hot rolling stand 2021 may be a 50% reduction (e.g., from 16 mm to 8 mm, then from 8 mm to 4 mm, and further from 4 mm to 2 mm). In some cases, the reduction performed at the third hot rolling stand 2021 may exceed 40%, 45%, 50%, 55%, 60%, 65%, or 70%.

[0119] The hot-rolling exit temperature may be any suitable temperature. In some cases, it may be desirable to remove a considerable amount of heat during the hot-rolling process so that the metal exits the final hot-rolling stand at a hot-rolling exit temperature of approximately 450°C, 445°C, 440°C, 435°C, 430°C, 425°C, 420°C, 415°C, 410°C, 405°C, 400°C, 395°C, 390°C, 385°C, 380°C, 375°C, 370°C, 365°C, 360°C, 355°C, 350°C, 345°C, 340°C, 335°C, 330°C, 325°C, 320°C, 315°C, 310°C, 305°C, or 300°C or lower. In some cases, the hot rolling exit temperature may be desirable to be approximately 375°C–405°C, 380°C–400°C, 385°C–395°C, or approximately 390°C. Dynamic recrystallization can be performed within the metal strip during the hot rolling process by entering the first hot rolling stand 2017 at a temperature higher than the recrystallization temperature and allowing the temperature to decrease to the hot rolling exit temperature as the metal strip passes through the second hot rolling stand 2019 and the third hot rolling stand 2021. A number of other rolling stands may be used.

[0120] As shown in Chart 2000, line 2003 enters the high-precipitation zone 2001 in approximately 3.1 seconds and exits it in approximately 7.4 seconds, thus spending approximately 4.3 seconds within the high-precipitation zone 2001. Therefore, the duration of line 2013 within the high-precipitation zone 2001 may be approximately 25% of the duration of line 2003 within the high-precipitation zone 2001. This difference in duration can substantially affect the amount of Mg2Si or other precipitates precipitated. Chart 2000 shows the precipitation of MG2Si, but similar charts exist for other precipitates, and the same principles can be applied.

[0121] Figure 21 is a combined schematic diagram and chart showing the associated temperature profiles 2101 of a hot rolling system 2100 and a metal strip 2110 rolled thereon, according to some aspects of the present disclosure. The hot rolling system 2100 can be the hot rolling system 106 of Figure 1 and can operate on the principle outlined with respect to line 2013 of Figure 20.

[0122] The hot rolling system 2100 includes an optional preheating zone 2194, a hot rolling zone 2170, and a quenching zone 2174, from upstream unwinding to downstream winding. The temperature profile 2101 shows that the metal strip 2110 enters the hot rolling system 2100 at either a standard temperature (e.g., 350°C, indicated by the dotted line) or a preheating temperature (e.g., 530+°C, indicated by the dotted line). If it enters at the preheating temperature, the preheating zone 2194 adds little or no additional heat to the metal strip 2110. However, if it enters at any temperature lower than the desired preheating temperature (e.g., 530°C or higher), one or more heating devices in the preheating zone 2194 add heat to the metal strip 2110 to raise the temperature of the metal strip above the desired preheating temperature. As disclosed herein, preheating 2195 of the metal strip 2110 can improve the dispersion of the dispersed phase within the metal strip 2110. In some cases, the preheating zone 2194 may include one or more sets of rotating permanent magnets 2188, but other heating devices may also be used.

[0123] Before entering the hot rolling zone 2170, the metal strip 2110 undergoes little to no initial quenching. Therefore, when the metal strip 2110 enters the hot rolling zone 2170, it can be at a high temperature (e.g., above approximately 530°C).

[0124] During the hot rolling process within the hot rolling zone 2170, the thickness of the metal strip 2110 can be reduced due to the force applied from the backup roll 2184 through the work roll 2182. To counteract the mechanically induced heat generated by hot rolling and provide a cooling effect to the metal strip 2110, one or more rolling coolant nozzles 2196 can supply rolling coolant 2198 to one or more metal strips 2110, work rolls 2182, or backup rolls 2184. The coolant 2198 may be any suitable coolant such as lubricating oil, air, water, or a mixture thereof. Thus, as seen in the temperature profile 2101, the temperature of the metal strip 2110 can be monotonically reduced throughout the hot rolling zone 2170 from the hot rolling inlet temperature (e.g., above about 530°C) to a hot rolling outlet temperature lower than the hot rolling inlet temperature (e.g., about 400°C). In some cases, it is desirable to minimize the hot-rolling exit temperature while ensuring dynamic recrystallization. This minimization can be achieved, for example, by maintaining a high degree of strain at the final rolling stand, such as through relatively high-speed rolling with relatively rapid thickness reduction.

[0125] The metal strip 2110 can be quenched immediately after exiting the hot rolling zone 2170 (e.g., without reheating). In the quenching zone 2174, the metal strip 2110 can be quenched to a temperature below the hot rolling exit temperature, such as the output temperature (e.g., below 100°C) (2175). The heat treatment quenching zone 2174 can cool the metal strip 2110 by supplying quenching coolant 2192 from one or more quenching nozzles 2190. In some cases, the rolling coolant 2198 and the quenching coolant 2192 may or may not originate from the same coolant source.

[0126] Figure 22 is a schematic diagram showing a hot band continuous casting system 2200 according to some aspects of the present disclosure. The hot band continuous casting system 2200 may be a partially isolated continuous casting system similar to the isolated continuous casting system 300 of Figure 3, with some in-line additions to improve certain metallurgical properties. The hot band continuous casting system 2200 can optionally produce coiled hot bands 2212 in final gauge and final temper. In some cases, as described herein, the hot bands 2212 may be used as intermediate coils and further processed. However, in some cases, the hot bands 2212 themselves may be the final product in the desired gauge and optionally tempered state.

[0127] The hot band continuous casting system 2200 includes a continuous casting apparatus such as a twin-belt continuous casting machine 2208, but other continuous casting apparatus such as a twin-roll casting machine may also be used. The belt continuous casting machine 2208 includes opposing belts that can extract heat from the liquid metal 2236 at a cooling rate sufficient to solidify the liquid metal 2236, and this cooling rate causes the solid to flow out of the belt continuous casting machine 2208 as a metal strip 2210. The thickness of the metal strip 2210 as it comes out of the belt continuous casting machine 2208 may be 50 mm or less, but other thicknesses may be used. The belt continuous casting machine 2208 can be operated at a desired casting speed. The opposing belts can be manufactured from any suitable material, but in some cases the belts are manufactured from copper. The cooling system within the belt-type continuous casting machine 2208 is able to extract sufficient heat from the liquid metal 2236, thereby keeping the temperature of the metal strip 2210 exiting the belt-type continuous casting machine 2208 between 200°C and 530°C, although other ranges may also be used. In some cases, the temperature exiting the belt-type continuous casting machine 2208 (e.g., peak metal temperature) may be between approximately 350°C and approximately 450°C.

[0128] In some cases, an arbitrary soaking furnace 2217 (e.g., a tunnel furnace) can be placed downstream of the belt-type continuous casting machine 2208, near the exit of the machine. The use of the soaking furnace 2217 can facilitate the achievement of a uniform temperature profile across the lateral width of the metal strip 2210. Furthermore, the soaking furnace 2217 can flash homogenize the metal strip 2210, thereby producing a metal strip 2210 with improved decomposition of iron components during hot or warm rolling. In some cases, an arbitrary pinch roll 2215 can be placed between the belt-type continuous casting machine 2208 and the soaking furnace 2217. In some cases, an arbitrary pair of magnetic heaters 2288 (e.g., a magnetic rotor or magnets rotating around a pivot axis) can be placed between the belt-type continuous casting machine or pinch roll 2215 and the soaking furnace 2217. The magnetic heater 2288 can raise the temperature of the metal strip 2210 to the temperature of the soaking furnace 2217 or approximately that temperature, which may be about 570°C (e.g., 500-570°C, 520-560°C, or about 560°C or 570°C). The soaking furnace 2217 may be long enough to allow the metal strip 2210 to pass through the soaking furnace 2217 in about 1 to 10 minutes, preferably 1 to 3 minutes, or preferably about 2 minutes, while moving at the outlet speed of the belt-type continuous casting machine 2208.

[0129] In some cases, the rolling stand 2284 can be positioned downstream of the soaking furnace 2217 and upstream of the winding device. The rolling stand 2284 may be a hot rolling stand or a warm rolling stand. In some cases, warm rolling is performed at a temperature below 400°C but above the cold rolling temperature, and hot rolling is performed at a temperature above 400°C but below the melting temperature. The rolling stand 2284 can reduce the thickness of the metal strip 2210 by at least 30%, or 50% to 75%. Post-rolling quenching 2219 can reduce the temperature of the metal strip 2210 after it leaves the rolling stand 2284. Post-rolling quenching 2219 can impart beneficial metallurgical properties, such as those related to dispersed phase formation, as described with reference to Figure 3. In some cases, one or more rolling stands 2284, such as two, three, or more, can be used, but it is not necessary to have more than one.

[0130] In some cases, any pre-rolling quenching 2213 can lower the temperature of the metal strip 2210 between the soaking furnace 2217 and the rolling stand 2284, thereby imparting beneficial metallurgical properties to the metal strip 2210. Pre-rolling quenching 2213 and / or post-rolling quenching 2219 can lower the temperature of the metal strip 2210 at a rate of approximately 200°C / second. Pre-rolling quenching 2213 can lower the peak metal temperature of the metal strip 2210 to approximately 350°C to 450°C, although other temperatures can also be used.

[0131] Before winding, the metal strip 2210 can be edge-trimmed by the edge trimmer 2221. During winding, the metal strip 2210 can be wound onto a coil of hot band 2212, and when the coil of hot band 2212 reaches the desired length or size, the shearer 2223 can cut the metal strip 2210. In some cases, the hot band 2212 does not need to be wound but may be supplied directly to other processes. In some cases, winding can be carried out at a temperature of about 50°C to about 400°C.

[0132] As shown by block 2286, the hot band 2212 can be in the final gauge. In such cases, the rolling stand 2284 can be configured to reduce the thickness of the metal strip 2210 to the desired final gauge for the hot band 2212. In some cases, as shown by block 2287, the hot band 2212 can be in the final gauge and tempered. In such cases, the rolling stand 2284 can be configured to reduce the thickness of the metal strip 2210 to the desired final gauge for the hot band 2212, and other temperings can be used, but the temperature can be carefully controlled through the hot band continuous casting system 2200 to achieve the desired tempering, such as O tempering or T4 tempering. In some cases, as shown by block 2289, the hot band 2212 can be stored, optionally reheated with reference to an intermediate coil as described above, and then finished, cold-rolled, and / or heat-treated. The hot band 2212 produced using the hot band continuous casting system 2200 may have a fine structure more suitable for cold rolling. For example, 6xxx series aluminum alloy hot bands manufactured using the 2200 hot band continuous casting system may have smaller, more spheroidal intermetallic compounds that react better to cold rolling than standard intermetallic compounds, which can cause problematic voids and crack formation during cold rolling.

[0133] In some cases, when the metal strip 2210 is soaked in a soaking furnace 2217 in line after continuous casting, at a peak metal temperature of at least about 560°C or 570°C for at least about 1.5 or 2 minutes before hot rolling or warm rolling, with a thickness reduction of about 50% to 70%, the hot band 2212 may include a desirable iron particle distribution (e.g., decomposition and spheroidization of iron components) in 6xxx and 5xxx series aluminum alloys. The iron particle distribution can play an important role in the cracking sites and deformability of metal products manufactured using the hot band 2212. Using certain embodiments of this disclosure, the hot band 2212 may be manufactured with highly crushed and spheroidized iron components, thus improving deformability and reducing crack susceptibility.

[0134] In some alternative embodiments, the rolling stand 2284 may be located upstream of the soaking furnace 2217 (e.g., on the left side, see Figure 22). While such a position can produce desirable results, it requires a longer soaking furnace 2217 because the speed of the metal strip 2210 increases as a result of a relatively high reduction in thickness (e.g., 50% to 70%), thus requiring higher installation costs, operating costs, and physical footprint. In some alternative embodiments, an additional soaking furnace may be located downstream of the rolling stand 2284 to further control the temperature of the metal strip 2210 after the reduction in thickness. However, the increased speed of the metal strip after rolling requires an additional soaking furnace, which has a relatively large footprint and higher associated costs.

[0135] Figure 23 is Chart 2300, showing the precipitation of Mg2Si in an aluminum metal strip during hot rolling and quenching according to a particular aspect of the present disclosure. Chart 2300 is similar to Chart 2000 in Figure 20 and shows the expected precipitation of Mg2Si for an aluminum alloy such as a 6xxx series aluminum alloy, depending on the time spent at a particular temperature. A high precipitation region 2301 is shown, similar to the high precipitation region 2001 in Figure 20.

[0136] Line 2303 indicates the temperature of a processed metal strip according to a particular aspect of the present disclosure, where the metal strip is cooled to a warm rolling temperature, warm-rolled while being further cooled, and then further cooled. Warm-rolling while being cooled further occurs in section 2307. By controlling the time and temperature of the metal strip, the temperature line 2303 can remain outside the high-precipitation region 2301, minimizing Mg2Si precipitation.

[0137] In some cases, the metal strip may be passed through two rolling stands while being warm-rolled. During the first engagement (e.g., between the rollers of the first rolling stand), the metal strip may be quenched to a sufficiently low temperature to avoid the precipitation of undesirable intermetallic compounds (e.g., Mg2Si). During the second engagement, the metal strip may be thinned with sufficient force to recrystallize at the temperature of the metal strip upon entering the second engagement.

[0138] Line 2305 indicates the temperature of a processed metal strip according to a particular aspect of the present disclosure, where the metal strip is maintained at a high temperature (e.g., about 510°C, 515°C, or 517°C or higher) from casting to rolling. After rolling, the metal strip may be rapidly quenched so that the amount of time the temperature line 2305 of the metal strip remains within the high deposition region 2301 can be minimized. In this case, the metal strip can retain an unwork-hardened particle structure, at least partially due to the high temperature during rolling.

[0139] Figure 24 is a flowchart of process 2400 for casting a thermometal strip according to a particular aspect of the present disclosure. In block 2402, a metal strip can be cast using a continuous casting apparatus, such as a belt casting machine. The use of a continuous casting apparatus, such as a belt casting machine, ensures a rapid solidification rate.

[0140] In an optional block 2404, the metal strip can be flash-homogenized after exiting the belt casting machine. Flash homogenization may include selectively reheating the metal strip to a soaking temperature (e.g., about 400°C to 580°C, or more preferably about 570°C to 580°C) and maintaining the metal strip at the soaking temperature for a period of time. The duration may be about 10 to 300 seconds, 60 to 180 seconds, or 120 seconds.

[0141] Flash homogenization can be particularly useful for pulverizing and / or spheroidizing large and / or blade-like intermetallic compounds. For example, AA6111 and AA6451 alloys may have relatively large intermetallic compounds at casting time, and these intermetallic compounds may be improved by flash homogenization as disclosed herein. However, since AA5754 alloys are not manufactured as needle-like or blade-like intermetallic compounds, flash homogenization can be omitted for AA5754 and similar alloys. In some cases, the decision of when to use and when not to use flash homogenization may be based on the iron-to-silicon ratio, where alloys with a higher silicon content (e.g., a silicon-to-iron ratio of 1:5 or higher) can benefit from flash homogenization. In some cases, alloys with a lower silicon content (e.g., a silicon-to-iron ratio of 1:5 or lower) may preferably be cast without flash homogenization or with flash homogenization at a lower temperature (e.g., about 500°C to about 520°C).

[0142] In some cases, flash homogenization can be performed at lower temperatures for certain alloys. For example, 7xxx series alloys may be successfully flash homogenized at temperatures of approximately 350°C to 480°C.

[0143] In optional block 2406, the metal strip may be cooled before hot rolling or warm rolling. In some cases, cooling the metal strip before hot rolling or warm rolling may be beneficial, especially when it is desired to suppress chromium deposition. Cooling in block 2406 involves cooling the metal strip to a temperature of approximately 350°C to approximately 450°C, but other temperatures may be used.

[0144] In block 2408, the metal strip may be hot-rolled or warm-rolled if the thickness reduction is at least about 30% and less than about 80%. In some cases, the thickness reduction may be at least about 50%, 55%, 60%, 65%, 70%, or 75%. In some cases, the hot-rolling or warm-rolling in block 2408 may optionally include, but is not required, quenching the metal strip during rolling (e.g., within the meshing between the rolls of the rolling stand). In some cases, the hot-rolling or warm-rolling in block 2408 is carried out while maintaining the metal strip at a temperature of 500°C, 505°C, 510°C, 515°C, 520°C, or 525°C or higher.

[0145] In block 2410, the metal strip can be quenched after hot rolling or warm rolling. Quenching in block 2410 may include cooling the metal strip at a high speed, such as 200°C / second, but other speeds may also be used. Quenching in block 2410 can reduce the temperature of the metal strip to approximately 50°C to 400°C, for example, 50°C to 300°C, but other temperatures may be used.

[0146] In block 2412, a metal strip can be wound as a hot band. The hot band may be in final gauge and tempered, final gauge, or intermediate gauge. If it is in final gauge and tempered, or final gauge, the wound hot band may be further delivered to the customer for its intended use. If it is in intermediate gauge, the hot band may be processed into a final product by reheating, rolling (e.g., cold rolling or hot rolling), heat treatment, or other means, and then delivered to the customer.

[0147] In an optional block 2414, the hot band can be reheated to further improve the metallurgical properties described herein, as included in the following embodiments.

[0148] Figure 25 is a schematic diagram showing a hot band continuous casting system 2500 according to a particular aspect of the present disclosure. The hot band continuous casting system 2500 may be identical or similar to the hot band continuous casting system 2200 of Figure 22, but having an additional supply coil 2513. The hot band continuous casting system 2500 can operate in casting mode and processing mode. In casting mode, the hot band continuous casting system 2500 can utilize a continuous belt casting machine 2508 to produce a metal strip 2510, which can then be directed through various components of the hot band continuous casting system 2500, for example, passing the metal strip 2510 through a rolling stand 2584, as shown with respect to the hot band continuous casting system 2200 of Figure 22.

[0149] However, in processing mode, the hot band continuous casting system 2500 can provide a metal strip 2510 (e.g., a hot band that is not the final gauge) from an additional supply coil 2513 to one or more components of the hot strip continuous casting system 2500, including at least a rolling stand 2584. The metal strip 2510 from the additional supply coil 2513 may be rolled (e.g., hot-rolled or warm-rolled) and then wound onto a coil of hot band 2512.

[0150] Therefore, the same rolling stand 2584 may be used for both in-line rolling of metal strips that have just been continuously cast and for rolling of previously cast and wound metal strips 2510. The operation of the hot band continuous casting system 2500 in processing mode may be particularly useful when the continuous casting equipment requires repair or while waiting for the liquid metal 2536 to be prepared.

[0151] Figure 26 is a schematic diagram showing a continuous casting system 2600 according to a particular aspect of the present disclosure. The continuous casting system 2600 is similar to the hot band continuous casting system 2200 of Figure 22, but uses a continuous casting apparatus 2608 to cast extrudeable metal articles 2610 (e.g., billets) instead of a continuous casting machine that casts metal strips. The extrudeable metal articles 2610 can be processed using the same or similar apparatus as described above with reference to the metal strip 2210 of Figure 22, but the rolling stand can be replaced with a die 2684. The continuous casting system 2600 can produce coiled products 2612. The coiled products 2612 are similar to the hot band 2212 of Figure 22 and can be in final gauge, final gauge and tempering, or in intermediate gauge for further processing.

[0152] Figure 27 is a flowchart of process 2700 for casting an extruded metal product according to a particular aspect of the present disclosure. In block 2702, an extrudeable metal article, such as a billet, can be cast using a continuous casting apparatus. The use of a continuous casting apparatus ensures a rapid solidification rate.

[0153] In an optional block 2704, the extrudeable metal articles can be flash-homogenized after leaving the casting apparatus. Flash homogenization may include selectively reheating the extrudeable metal articles to a soaking temperature (e.g., about 400°C to 580°C, or more preferably about 570°C to 580°C) and maintaining the extrudeable metal articles at the soaking temperature for a certain period of time. The duration may be about 10 to 300 seconds, 60 to 180 seconds, or 120 seconds.

[0154] Flash homogenization can be particularly useful for pulverizing and / or spheroidizing large and / or blade-like intermetallic compounds. For example, AA6111 and AA6451 alloys may have relatively large intermetallic compounds at casting time, and these intermetallic compounds may be improved by flash homogenization as disclosed herein. However, since AA5754 alloys are not manufactured as needle-like or blade-like intermetallic compounds, flash homogenization can be omitted for AA5754 and similar alloys. In some cases, the decision of when to use and when not to use flash homogenization may be based on the iron-to-silicon ratio, where alloys with a higher silicon content (e.g., a silicon-to-iron ratio of 1:5 or higher) can benefit from flash homogenization. In some cases, alloys with a lower silicon content (e.g., a silicon-to-iron ratio of 1:5 or lower) may preferably be cast without flash homogenization or with flash homogenization at a lower temperature (e.g., about 500°C to about 520°C).

[0155] In some cases, flash homogenization can be performed at lower temperatures for certain alloys. For example, 7xxx series alloys may be successfully flash homogenized at temperatures of approximately 350°C to 480°C.

[0156] In an optional block 2706, the extrudeable metal article may be cooled through a die at a hot or warm extrusion temperature before extrusion. Extrusion at a hot or warm extrusion temperature may be one type of hot or warm work. In some cases, cooling the extrudeable metal article before hot or warm extrusion may be beneficial, particularly when it is desired to suppress chromium deposition. Cooling in block 2706 includes cooling the extrudeable metal article to a temperature of about 350°C to about 450°C, but other temperatures may be used.

[0157] In block 2708, extrudeable metal articles can be hot-extruded or warm-extruded if the diameter reduction (e.g., cross-sectional reduction) is at least about 30% and less than about 80%. In some cases, the diameter reduction may be at least about 50%, 55%, 60%, 65%, 70%, or 75%. In some cases, hot-extrusion or warm-extrusion in block 2708 may selectively include quenching the metal article during extrusion (e.g., in the die), but is not required. In some cases, hot-extrusion or warm-extrusion in block 2708 is carried out while maintaining the metal article at a temperature of 500°C, 505°C, 510°C, 515°C, 520°C, or 525°C or higher.

[0158] In block 2710, extruded metal articles (e.g., extrudeable metal articles after extrusion) can be quenched after hot or warm extrusion. Quenching in block 2710 may include cooling the extruded metal articles at a high speed, such as 200°C / second, but other speeds may also be used. Quenching in block 2710 can reduce the temperature of the extruded metal articles to approximately 50°C to 400°C, for example, 50°C to 300°C, but other temperatures may also be used.

[0159] In block 2712, extruded metal articles may be stored in coil form or by other means. Extruded metal articles may be in final gauge and tempered, final gauge, or intermediate gauge. If in final gauge and tempered, or final gauge, the extruded metal articles may be further delivered to the customer for their intended use. If in intermediate gauge, the extruded metal articles may be reheated, further extruded (e.g., cold extrusion or hot extrusion), heat treated, or otherwise processed into a final product and delivered to the customer in that manner.

[0160] In an optional block 2714, the extruded metal article can be reheated to further improve its metallurgical properties, as described herein with respect to the hot band included in the following embodiments.

[0161] Examples The following embodiments are helpful in further illustrating the present invention, but are not limiting. Rather, it should be clearly understood after reading this description that various embodiments, modifications, and equivalents can be made, without departing from the spirit of the invention, and may be suggested to those skilled in the art.

[0162] Various alloys were tested using specific embodiments and features of this disclosure. Aluminum alloys are described in terms of their elemental composition as a weight percentage (wt%) based on the total weight of the alloy. In specific examples of each alloy, the remainder is aluminum, with a maximum wt% of 0.15% of the total impurities. Table 1 shows some such alloys, including their approximate solidus temperature and sorbus temperature. [Table 1]

[0163] Table 1 shows some examples of common 5xxx, 6xxx, and 7xxx alloys, but other 5xxx, 6xxx, and 7xxx alloys may exist, with their components (e.g., alloying elements) present in different weight percentages, the remainder being aluminum and optional trace amounts (e.g., less than 0.15%) of impurities. Accompanying elements such as grain refiners and deoxidizers, or other additives, may also be present.

[0164] Alloys AA6111 and AA6451 were manufactured according to the method described herein. Alloys AA6111 and AA6451 were continuously cast into slabs having a gauge of 11 mm. As shown in Table 2, alloy AA6111 further underwent flash homogenization procedures carried out at various temperatures and for various durations. [Table 2]

[0165] Figure 28 is a graph showing the log-normal density distribution of iron (Fe)-constituent particles per square micron (μm²) with respect to particle size of alloys produced according to the method described herein. Sample A was an as-cast AA6111 alloy that had not undergone the disclosed flash homogenization procedure or hot rolling. Sample B was an 11 cm slab of continuously cast AA6111 that had undergone the disclosed flash homogenization procedure without further hot rolling. Sample C was an 11 cm slab of continuously cast AA6111 that had undergone the disclosed flash homogenization procedure and was hot-rolled to a thickness reduction of 50% (i.e., 6.5 mm gauge). Sample D was an 11 cm slab of continuously cast AA6111 that had undergone the disclosed flash homogenization procedure, was thermally quenched in room temperature water to a temperature of 350°C, and hot-rolled to a thickness reduction of 50% (i.e., 6.5 mm gauge). Sample E was an 11 cm slab of continuously cast AA6111 that underwent arbitrary flash homogenization (see Table 2) and was hot-rolled to a 50% reduction (i.e., 6.5 mm gauge). Sample F was an 11 cm slab of continuously cast AA6111 that underwent arbitrary flash homogenization (see Table 2) and was hot-rolled to a 50% reduction (i.e., 6.5 mm gauge). Sample A (a slab of as-cast AA6111) showed a broad particle size distribution and a broad peak indicating a lack of refinement of the Fe component. Sample C (an 11 mm slab of cast AA6111 that underwent the disclosed flash homogenization and was hot-rolled to a 50% reduction) showed a narrow particle size distribution indicating refinement of Fe constituent particles. Samples D and E (underwent arbitrary low-temperature flash homogenization, 400°C for Sample D and 380°C for Sample E) showed a broad particle size distribution, which indicated less refinement of Fe constituent particles.

[0166] Figure 29 is a series of scanning electron microscope (SEM) micrographs showing Fe constituent particles in AA6111 alloy treated according to the method described herein. Panels A, B, C, D, E, and F in Figure 29 correspond to samples A, B, C, D, E, and F in Figure 28, respectively. Panel A shows large needle-shaped Fe constituent particles 2401 in sample A (see Table 2). Panel B shows refinement (i.e., grinding) of Fe constituent particles after the AA6111 alloy has undergone the disclosed flash homogenization without hot rolling (sample B, Table 2). Panel C shows further refinement of Fe constituent particles in sample C. An 11 mm gauge slab of AA6111 alloy, continuously cast, underwent the disclosed flash homogenization and then hot-rolled to further reduce its thickness by 50%. Panel C shows further refinement, as evidenced by the log-normal distribution fit depicted as sample C in Figure 28. Panel D shows the refinement of Fe constituent particles in sample D, similar to the refinement seen in sample C. An 11 mm gauge slab of AA6111 alloy, continuously cast, underwent the disclosed flash homogenization and then water quenched to 350°C before hot rolling to reduce thickness by 50%. Panel E shows the lack of refinement of Fe constituent particles and non-dissolving magnesium silicide (Mg2Si) particles present in sample E. An 11 mm slab of AA6111 alloy, continuously cast, underwent flash homogenization at 400°C for 1 minute and was then hot-rolled to reduce thickness by 50%. Panel F shows the lack of refinement of Fe constituent particles and non-dissolving magnesium silicide (Mg2Si) particles present in sample F. An 11 mm slab of AA6111 alloy, continuously cast, underwent flash homogenization at 380°C with no residence time and was then hot-rolled to reduce thickness by 50%.

[0167] Figure 30 shows the grain size of the alloy produced according to the method described herein, with respect to 1 square micron (μm). 2This graph shows the log-normal density distribution of iron (Fe) constituent particles per unit area. Samples C, D, and E (see Table 2) underwent further homogenization after being hot-rolled to reduce their thickness by 50%. The additional homogenization procedures are summarized in Table 3. [Table 3]

[0168] All samples, after the disclosed flash homogenization and subsequent hot rolling to a 50% reduction, followed by further homogenization at various temperatures, exhibited a narrow particle size distribution indicating refinement of Fe constituent particles. High-temperature flash homogenization (e.g., 570°C, samples C and D (tests G, H, V, and W)) continued to show more refinement of Fe constituent particles than low-temperature flash homogenization (e.g., below 400°C, sample E (tests I, J, X, and Y)).

[0169] Figure 31 shows the grain size of the alloy produced according to the method described herein, with respect to 1 square micron (μm). 2 This graph shows the log-normal density distribution of iron (Fe) constituent particles per unit area. For each of these flash homogenization tests, an 11 mm metal strip was hot-rolled to 2 mm. In some cases, the initial hot-rolling (e.g., "Q1" reduction) was performed with a 50% thickness reduction, followed by a final thickness reduction of 68% to obtain a 2 mm strip. In other cases, the initial hot-rolling was performed with a 70% thickness reduction, followed by a final thickness reduction of 40% to obtain a 2 mm strip. Additional homogenization and hot-rolling parameters are summarized in Table 4. [Table 4]

[0170] All samples that underwent the disclosed flash homogenization and were initially hot-rolled to reduce their particle size by at least 50%, followed by further homogenization and hot-rolling to the desired gauge (e.g., 2 mm), exhibited a narrow particle size distribution indicating refinement of Fe-constituent particles. Samples that underwent the disclosed flash homogenization (e.g., samples C and D, tests G, H, Z, AA, AB, and AC, at 570°C for 5 minutes) showed a narrower distribution of pure Fe-constituent particles than samples that underwent low-temperature flash homogenization (e.g., sample E, tests I, J, AD, and AE, at 400°C), suggesting that further homogenization is not required when using the disclosed high-temperature flash homogenization.

[0171] Figure 32 shows the grain size of the alloy produced according to the method described herein, with respect to 1 square micron (μm). 2 This graph shows the log-normal density distribution of iron (Fe) constituent particles per unit area. Sample F (see Table 2) underwent further homogenization and further hot rolling to reduce its thickness by 70% (i.e., Sample F was initially hot-rolled to reduce its thickness by a further 20%), and was compared to an 11 mm slab (Sample A, see Table 2) of continuous casting of as-cast AA6111 alloy. The as-cast AA6111 alloy did not undergo the disclosed flash homogenization. The as-cast AA6111 alloy underwent the same further homogenization and hot rolling as Sample F. The parameters are summarized in Table 5. [Table 5]

[0172] All samples that underwent the disclosed flash homogenization, followed by hot rolling to a reduction of at least 50%, and then further homogenization and hot rolling to the desired gauge (e.g., 2 mm), showed a narrow particle size distribution indicating refinement of Fe-constituent particles. Samples that did not undergo the disclosed flash homogenization showed less refinement of Fe-constituent particles.

[0173] As shown in Table 6, alloy AA6451 underwent further flash homogenization procedures carried out at various temperatures and for various durations. [Table 6]

[0174] Figure 33 shows the grain size of the alloy produced according to the method described herein, with respect to 1 square micron (μm). 2 This graph shows the log-normal density distribution of iron (Fe) constituent particles per unit area. Sample AAA (shown as a solid blue line) was as-cast AA6451 that did not undergo the disclosed flash homogenization procedure or hot rolling. Sample CCC (shown as a small dashed green line) was an 11 cm slab of continuous cast AA6451 that underwent the disclosed flash homogenization and was hot-rolled to a thickness reduction of 50% (i.e., 6.5 mm gauge). Sample DDD (shown as a dotted purple line) was an 11 cm slab of continuous cast AA6451 that underwent the disclosed flash homogenization, was thermally quenched in room temperature water to a temperature of 350°C, and was hot-rolled to a thickness reduction of 50% (i.e., 6.5 mm gauge). Sample EEE (shown as a black dashed line) was an 11 cm slab of continuous cast AA6451 that underwent arbitrary flash homogenization (see Table 2) and was hot-rolled to a 50% reduction (i.e., 6.5 mm gauge). Sample FFF (shown as an orange solid line) was an 11 cm slab of continuous cast AA6451 that underwent arbitrary flash homogenization (see Table 2) and was hot-rolled to a 50% reduction (i.e., 6.5 mm gauge). Sample AAA (a slab of as-cast AA6451) showed a broad peak indicating a broad particle size distribution and a lack of refinement of the Fe component. Sample CCC (an 11 mm slab of cast AA6451 that underwent the disclosed flash homogenization and was hot-rolled to a 50% reduction) showed a narrow particle size distribution indicating refinement of the Fe constituent particles. Samples DDD and EEE (undergoing arbitrary low-temperature flash homogenization, 400°C for sample DDD and 380°C for sample EEE) showed a broad particle size distribution, indicating minimal refinement of Fe constituent particles.

[0175] Figure 34 shows the grain size of the alloy produced according to the method described herein, with respect to 1 square micron (μm). 2 This graph shows the log-normal density distribution of iron (Fe) constituent particles per unit area. Sample FFF (see Table 2) underwent further homogenization and further hot rolling to reduce its thickness by 70% (i.e., sample FFF was initially hot-rolled to reduce its thickness by a further 20%), and was compared to an 11 mm slab (sample AAA, see Table 2) of continuous casting of as-cast AA6451 alloy. The as-cast AA6451 alloy did not undergo the disclosed flash homogenization. The as-cast AA6451 alloy underwent similar further homogenization and hot rolling as sample FFF. The parameters are summarized in Table 7. [Table 7]

[0176] All samples (except UU) that underwent the disclosed flash homogenization and were hot-rolled to reduce thickness by at least 50%, followed by further homogenization and hot-rolling to the desired gauge (e.g., 2 mm), showed a narrow particle size distribution indicating refinement of Fe-constituent particles. Samples that did not undergo the disclosed flash homogenization showed less refinement of Fe-constituent particles. Sample UU underwent the disclosed flash homogenization (e.g., 570°C for 5 minutes), was immediately hot-rolled to reduce thickness by 70%, and showed excellent refinement of Fe-constituent particles after further homogenization and an additional 40% hot-rolling.

[0177] Figures 35, 36, and 37 are micrographs showing the microstructure of AA6014 aluminum alloy. Figure 35 shows AA6014 aluminum alloy called "R1", which was continuously cast into a slab with a thickness of 19 mm gauge, cooled and stored, preheated and hot-rolled to a thickness of 11 mm, and then hot-rolled again to a thickness of 6 mm. Preheating was performed by heating the cooled slab under two conditions: (i) heating to 550°C in 1 minute, or (ii) heating to 420°C in 30 seconds. The rolling direction is indicated by arrow 3001. Figure 35 shows the effect on grain size and recrystallization after hot rolling. Figure 36 shows the microstructure of AA6014 aluminum alloy called "R2", which was continuously cast into a slab with a thickness of 10 mm gauge, cooled and stored, preheated and hot-rolled to a thickness of 5.5 mm. Preheating was performed by heating cooled slabs under two conditions: (i) heating to 550°C in 1 minute, or (ii) heating to 420°C in 30 seconds. The rolling direction is indicated by arrow 3101. Figure 36 shows the effect on grain size and recrystallization after hot rolling. Figure 37 shows the microstructure of AA6014 aluminum alloy called "R3", which was continuously cast into a slab with a thickness of 19 mm gauge, cooled and stored, cold-rolled to a thickness of 11 mm, preheated, and hot-rolled to a thickness of 6 mm. Preheating was performed by heating cooled slabs under two conditions: (i) heating to 550°C in 1 minute, or (ii) heating to 420°C in 30 seconds. The rolling direction is indicated by arrow 3201. Figure 37 shows the effect on grain size and recrystallization after hot rolling.

[0178] Figure 38 is a graph showing the effect of preheating on the formability of AA6014 aluminum alloy. The AA6014 aluminum alloys were referred to as "R1, R2, and R3," respectively, and underwent the heating and rolling treatments described above for Figures 30-32. Preheating the AA6014 aluminum alloy at 550°C for 1 minute (referred to as "HO1," the histogram on the left for each group) resulted in an aluminum alloy with excellent formability, indicated by an internal bending angle of less than 20°. Preheating the AA6014 aluminum alloy at 420°C for 1 minute (referred to as "HO2," the histogram on the right for each group) resulted in an aluminum alloy with very low formability, indicated by a relatively high internal bending angle (e.g., greater than 20°). All samples were hot-rolled (referred to as "WQ"), then quenched in water, and pre-stretched by 10% before the bending test.

[0179] Figure 39 shows a series of scanning electron microscope (SEM) images of Fe constituent particles in an 11.3 mm gauge cross-section of AA6111 metal. Panels α1, α2, α3, α5, and α6 show metals cast using continuous casting equipment such as the continuous belt casting machine 2208 of the hot band continuous casting system 2200 in Figure 22. Panel α1 shows as-cast metal with large needle-shaped Fe constituent particles. Panel α4 shows a comparable metal piece from a direct chill casting system with very large Fe constituent particles. Panels α2, α3, α5, and α6 were all heated after casting in a soaking furnace (e.g., soaking furnace 2217 in Figure 22) at peak metal temperatures of 540°C, 550°C, 560°C, and 570°C for 2 minutes, respectively. Smaller Fe components are observed in each of panels α2, α3, α5, and α6, with the smallest being in panel α6. Furthermore, spheroidization is hardly observed in the panels except for panel α6.

[0180] Figure 40 is a graph showing the equivalent circle diameter (ECD) of Fe constituent particles in a metal piece illustrated and described with reference to Figure 39. The graph in Figure 40 is based on a log-normal probability density function. The equivalent circle diameter used herein can be calculated by measuring the area of ​​a particle (e.g., Fe constituent particle) and determining the diameter of a circle having the same total area. In other words,

number

[0181] Figure 41 is a graph showing the aspect ratio of Fe constituent particles in a metal piece illustrated and described with reference to Figure 39. The graph in Figure 41 is based on a log-normal probability density function. The aspect ratio can be determined by dividing the length of the particle in the first direction by the width of the particle in the vertical direction. The aspect ratio can indicate the amount of spheroidization undergone by the particle.

[0182] Figure 42 is a graph showing the median and distribution data of the equivalent circle diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 39.

[0183] Figure 43 is a graph showing the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 39.

[0184] Figures 39–43 show that flash homogenization of continuously cast metal articles can yield a smaller Fe component, particularly at temperatures of approximately 570°C. Furthermore, higher peak metal temperatures in flash homogenization appear to indicate finer particles. Finally, substantial spheroidization (e.g., smaller aspect ratio) is evident when reaching a peak metal temperature of approximately 570°C, with little to no spheroidization at lower temperatures.

[0185] Figure 44 shows a series of scanning electron microscope (SEM) images of Fe constituent particles in an 11.3 mm gauge cross-section of AA6111 metal. Panels α7, α8, α9, and α11 show metals cast using continuous casting equipment such as the continuous belt casting machine 2208 of the hot band continuous casting system 2200 in Figure 22. Panel α7 shows as-cast metal with large needle-shaped Fe constituent particles. Panel α10 shows an equivalent metal piece from a direct chill casting system with very large Fe constituent particles. Panel α11 shows an equivalent metal piece from the direct chill casting system after homogenization for 2 minutes at a peak metal temperature of 570°C. Panels α8, α9, and α12 are all heated to a peak metal temperature of 570°C in a soaking furnace (e.g., soaking furnace 2217 in Figure 22) for periods of 1 minute, 2 minutes, and 3 minutes, respectively, after casting. Smaller Fe components were observed in panels α8, α9, and α11, with the smallest being in panel α11. Longer immersion times resulted in more spheroidization, with desirable spheroidization achieved at 2 and 3 minutes. Immersion of the direct chill-cast ingot for 2 minutes did not show significant changes in microstructure.

[0186] Figure 45 is a graph showing the median and distribution data of the equivalent circle diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 44.

[0187] Figure 46 is a graph showing the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 44.

[0188] Figures 45 and 46 show that a smaller Fe content can be achieved by flash homogenization of continuously cast metal articles, particularly at a temperature of 570°C or about 570°C, with an immersion time of at least 1 or 2 minutes or about 1 or 2 minutes.

[0189] Figure 47 shows a series of scanning electron microscope (SEM) images of Fe constituent grains in an 11.3 mm gauge cross-section of AA6111 metal. Panel α13 shows metal cast using continuous casting equipment such as the continuous belt casting machine 2208 of the hot band continuous casting system 2200 in Figure 22, flash homogenized at 565°C for 5 minutes (e.g., using the soaking furnace 2217 in Figure 22), and then not hot-rolled. Panels α14, α15, α16, α17, α18, and α19 show metals cast using continuous casting equipment such as the continuous belt casting machine 2208 of the hot band continuous casting system 2200 in Figure 22, flash homogenized at 565°C for 5 minutes (e.g., using the soaking furnace 2217 in Figure 22), and then hot-rolled (e.g., using the rolling stand 2284 in Figure 22) with thickness reductions of 10%, 20%, 30%, 40%, 50%, 60%, and 70%, respectively. There appears to be a plateau where higher thickness reductions yield smaller gains, but a smaller Fe component is shown after flash homogenization and subsequent higher hot rolling.

[0190] Figure 48 is a graph showing the median and distribution data of the equivalent circle diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 47.

[0191] Figure 49 is a graph showing the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 47.

[0192] Figures 48 and 49 show that a smaller Fe content can be achieved by flash homogenization of continuously cast metal articles followed by hot rolling, particularly at thickness reductions of approximately 40%–70%. Hot reductions of 50%–70% appear to provide a relatively similar amount of collapse, but higher hot reductions show more collapse of Fe constituent particles.

[0193] Figure 50 is a series of scanning electron microscope (SEM) images showing Fe constituent particles in cross-sections of AA6111 metal after undergoing various processing paths to obtain 3.7–6 mm gauge bands. Panel α20 shows directly chill-cast metal re-rolled to approximately 3.7–6 mm gauge. Panels α21, α22, α23, α24, α25, and α26 show metal cast using continuous casting equipment such as the continuous belt casting machine 2208 of the hot band continuous casting system 2200 in Figure 22, and subjected to some degree of hot rolling (e.g., using the rolling stand 2284 in Figure 22). Panels α21, α22, and α23 did not undergo flash homogenization, while panels α24, α25, and α26 underwent flash homogenization. Panels α21 and α24 underwent a 45% thickness reduction, panels α22 and α25 underwent a 45% thickness reduction and reheating to 530°C for 2 hours, and panels α23 and α26 underwent a 60% thickness reduction. Smaller Fe constituent particles were observed after flash homogenization and subsequent higher hot rolling. Reheating after hot rolling also appeared to promote spheroidization.

[0194] Figure 51 is a graph showing the median and distribution data of the equivalent circular diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 50.

[0195] Figure 52 is a graph showing the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 50.

[0196] Figures 51 and 52 show that flash homogenization of continuously cast metal articles followed by hot rolling, particularly hot rolling without flash homogenization, can achieve a lower Fe content. Furthermore, reheating after hot rolling appeared to improve spheroidization.

[0197] Figure 53 is a series of scanning electron microscope (SEM) images showing Fe constituent particles in a cross-section of AA6111 metal after undergoing various processing paths to obtain a 2.0 mm gauge strip. Panel α27 shows the directly chill-cast metal rolled to a final gauge of 2.0 mm. Panels α28, α29, α30, α31, α32, α33, and α34 show the metal cast using continuous casting equipment such as the continuous belt casting machine 2208 of the hot band continuous casting system 2200 in Figure 22. Panel α31 was continuously cast and then cold-rolled to a final gauge of 2.0 mm. Panels α28, α29, α30, α32, α33, and α34 underwent some hot rolling (e.g., using the rolling stand 2284 in Figure 22). Panels α28, α29, and α30 did not undergo flash homogenization, while panels α32, α33, and α34 underwent flash homogenization. Panels α28 and α32 were hot-rolled, resulting in a 45% reduction in thickness, followed by cold-rolling to a final gauge of 2.0 mm. Panels α29 and α33 were hot-rolled, resulting in a 45% reduction in thickness, reheated to 530°C for 2 hours, and then warm-rolled to a final gauge of 2.0 mm. Panels α30 and α34 were hot-rolled, resulting in a 60% reduction in thickness, followed by cold-rolling to a final gauge of 2.0 mm.

[0198] Figure 54 is a graph showing the median and distribution data of the equivalent circular diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 53.

[0199] Figure 55 is a graph showing the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 53.

[0200] Figures 54 and 55 show that flash homogenization of continuously cast metal articles, followed by hot rolling and reheating, can achieve a smaller Fe content, particularly when compared to hot rolling and cold rolling alone. Reheating after hot rolling showed improved spheroidization of Fe particle size. Cold rolling after continuous casting showed some breakdown of Fe particle size, but it did not achieve the desired spheroidization.

[0201] In addition, bending tests were performed on samples from Figure 53 according to the German Association of the Automotive Industry (VDA) standard 238-100 for conducting bending tests and standard 232-200 for normalizing the tests to 2.0 mm. Samples from panels α27, α28, α29, α30, α31, α32, α33, and α34 achieved alpha (external) bending angles of 80°, 79°, 75°, 67°, 66°, 96°, 102°, and 95°, respectively.

[0202] Figure 56 is a series of scanning electron microscope (SEM) images showing Fe constituent particles in a cross-section of AA6111 metal after undergoing various processing paths to obtain a 2.0 mm gauge strip. Panels α35, α36, α37, and α38 show metal cast using continuous casting equipment such as the continuous belt casting machine 2208 of the hot band continuous casting system 2200 in Figure 22, flash homogenized (e.g., using the soaking furnace 2217 in Figure 22), and hot rolled with a 45% thickness reduction (e.g., using the rolling stand 2284 in Figure 22). Panels α35, α36, and α37 were then reheated at a temperature of 530°C for 2 hours, while panel α38 was immediately cold rolled to a final gauge of 2.0 mm. After reheating, panel α35 was warm rolled to a final gauge of 2.0 mm. After reheating, panel α36 was hot-rolled again with a 50% reduction in thickness, then quenched, and finally cold-rolled to a final gauge of 2.0 mm. After reheating, panel α37 was quenched and then cold-rolled to a final gauge of 2.0 mm.

[0203] Figure 57 is a graph showing the median and distribution data of the equivalent circle diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 56.

[0204] Figure 58 is a graph showing the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 56.

[0205] Figures 57 and 58 show that flash homogenization of continuously cast metal articles, followed by hot rolling and reheating, can achieve a smaller Fe content, particularly when compared to hot rolling and cold rolling alone. Reheating after hot rolling showed improved spheroidization of Fe particle size. Cold rolling after continuous casting showed some breakdown of Fe particle size, but it did not achieve the desired spheroidization.

[0206] In addition, bending tests were performed on samples from Figure 56 according to the German Association of the Automotive Industry (VDA) standard 238-100 for conducting bending tests and standard 232-200 for normalizing the tests to 2.0 mm. Samples from panels α35, α36, α37, and α38 achieved alpha (external) bending angles of 96°, 95°, 104°, and 93°, respectively.

[0207] Figure 59 is a series of scanning electron microscope (SEM) images showing Fe constituent particles in cross-sections of AA6451 metal after undergoing various processing paths to obtain 3.7–6 mm gauge bands. Panel β1 shows directly chill-cast metal re-rolled to approximately 3.7–6 mm gauge. Panels β2, β3, β4, β5, β6, β7, and β8 show metal cast using continuous casting equipment such as the continuous belt casting machine 2208 of the hot band continuous casting system 2200 in Figure 22. Panel β2 shows an as-cast 6 mm strip. Panels β2, β3, β4, β6, β7, and β8 underwent some degree of hot rolling (e.g., using the rolling stand 2284 in Figure 22). Panels β2, β3, and β4 did not undergo flash homogenization, while panels β6, β7, and β8 underwent flash homogenization. Panels β2 and β6 showed a 45% reduction in thickness without reheating. Panels β3 and β6 showed a 45% reduction in thickness and were reheated to 530°C for 2 hours. Panels β4 and β8 showed a 60% reduction in thickness without reheating. Smaller Fe constituent particles were observed after flash homogenization and subsequent higher hot rolling. Reheating after hot rolling also appeared to promote spheroidization. Notably, the dark spots observed in panel β3 were determined to be anomalous based on further testing.

[0208] Figure 60 is a graph showing the median and distribution data of the equivalent circle diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 59.

[0209] Figure 61 is a graph showing the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 59.

[0210] Figures 60 and 61 show that flash homogenization of continuously cast metal articles followed by hot rolling, particularly hot rolling without flash homogenization, can achieve a lower Fe content. Furthermore, reheating after hot rolling appeared to improve spheroidization.

[0211] Figure 62 is a series of scanning electron microscope (SEM) images showing Fe constituent particles in a cross-section of AA6451 metal after undergoing various processing paths to obtain a 2.0 mm gauge strip. Panel β9 shows the directly chill-cast metal rolled to a final gauge of 2.0 mm. Panels β10, β11, β12, β13, β14, β15, and β16 show the metal cast using continuous casting equipment such as the continuous belt casting machine 2208 of the hot band continuous casting system 2200 in Figure 22. Panel β13 was continuously cast and then cold-rolled to a final gauge of 2.0 mm. Panels β10, β11, β12, β14, β15, and β16 underwent some hot rolling (e.g., using the rolling stand 2284 in Figure 22). Panels β10, β11, and β12 did not undergo flash homogenization, while panels β14, β15, and β16 underwent flash homogenization. Panels β10 and β14 were reduced in thickness by 45% under hot rolling and then cold-rolled to a final gauge of 2.0 mm. Panels β11 and β15 were reduced in thickness by 45% under hot rolling, reheated to 530°C or approximately 530°C for 2 hours, and then warm-rolled to a final gauge of 2.0 mm. Panels β12 and β16 were reduced in thickness by 60% under hot rolling and then cold-rolled to a final gauge of 2.0 mm.

[0212] Figure 63 is a graph showing the median and distribution data of the equivalent circle diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 62.

[0213] Figure 64 is a graph showing the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 62.

[0214] Figures 63 and 64 show that flash homogenization of continuously cast metal articles, followed by hot rolling and reheating, can achieve a smaller Fe content, particularly when compared to hot rolling and cold rolling alone. Reheating after hot rolling showed improved spheroidization of Fe particle size. Cold rolling after continuous casting showed some breakdown of Fe particle size, but it did not achieve the desired spheroidization.

[0215] In addition, bending tests were performed on samples from Figure 62 in accordance with the German Association of the Automotive Industry (VDA) standard 238-100 for conducting bending tests and the standard 232-200 for normalizing the tests to 2.0 mm. Samples from panels β9, β10, β11, β12, β13, β14, β15, and β16 achieved alpha (external) bending angles of 70°, 67°, 88°, 75°, 65°, 75°, 80°, and 81°, respectively.

[0216] Figure 65 shows a series of scanning electron microscope (SEM) and optical microscope images showing Mg2Si melt and voids in a cross-section of AA6451 metal cast and cold-rolled to obtain a 2.0 mm gauge strip. Panels β17, β18, β21, and β22 are SEM microscope images, while panels β19, β20, β23, and β24 are optical microscope images. Without following the processes of this disclosure, each sample was continuously cast and then cold-rolled. Panels β17, β18, β19, and β20 are based on the metal under F tempering (e.g., without solution heat treatment), while panels β21, β22, β23, and β24 are based on the metal under T4 tempering (e.g., with additional solution heat treatment). The results indicate that solution heat treatment of cold-rolled samples reveals numerous voids, which may be at least partially due to the presence of coarse as-cast Mg2Si during F tempering. Therefore, it is clear that improving the microstructure of the intermetallic compound may be beneficial in obtaining the desired T4 tempered product.

[0217] Figure 66 is a series of scanning electron microscope (SEM) images showing Fe constituent particles in a cross-section of AA6451 metal after undergoing various processing paths to obtain 2.0 mm gauge strips. Panels β25, β26, β27, and β28 show metal cast using continuous casting equipment such as the continuous belt casting machine 2208 of the hot band continuous casting system 2200 in Figure 22, and then hot-rolled (e.g., using the rolling stand 2284 in Figure 22) to reduce the thickness by 45%. Panel β25 was then reheated at 530°C for 2 hours and subsequently hot-rolled to the final gauge. Panel β26 was then reheated at 530°C for 2 hours and subsequently hot-rolled to reduce the thickness by a further 50%, then water-quenched and then cold-rolled to the final gauge. Panel β27 was then reheated at 530°C for 2 hours and subsequently water-quenched and then cold-rolled to the final gauge. Subsequently, panel β28 was cold-rolled. The most improved spheroidization of the Fe component in the final gauge was found when the metal strip was flash-homogenized, hot- or warm-rolled, then preheated, and subsequently water-quenched before cold-rolling to the final gauge.

[0218] Figure 67 is a graph showing the median and distribution data of the equivalent circle diameter of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 66.

[0219] Figure 68 is a graph showing the median and distribution data of the aspect ratio of Fe constituent particles in the metal piece illustrated and explained with reference to Figure 66.

[0220] Figures 67 and 68 show that flash homogenization of continuously cast metal articles, followed by hot rolling and reheating, particularly when combined with subsequent water quenching and cold rolling to the final gauge, can yield a smaller Fe content. It was determined that homogenization (e.g., reheating) may be beneficial for spheroidization, and quenching after homogenization may be beneficial for particle distribution.

[0221] In addition, bending tests were performed on samples from Figure 66 in accordance with the German Association of the Automotive Industry (VDA) standard 238-100 for conducting bending tests and the standard 232-200 for normalizing the tests to 2.0 mm. Samples from panels β25, β26, β27, and β28 achieved alpha (external) bending angles of 75°, 67°, 78°, and 71°, respectively.

[0222] Figure 69 is a series of scanning electron microscope (SEM) images showing Fe constituent grains in a cross-section of AA5754 metal. Panel γ4 shows metal that was directly chill-cast and reduced to its final gauge. Panels γ1, γ2, γ3, γ5, and γ6 show metal that was cast using a continuous casting apparatus such as the continuous belt casting machine 2208 of the hot band continuous casting system 2200 in Figure 22 and hot-rolled to varying thicknesses (e.g., using the rolling stand 2284 in Figure 22). Panels γ1, γ2, γ5, and γ6 were not flash-homogenized before hot-rolling, while panels γ3 and γ7 were flash-homogenized before hot-rolling. Panel γ1 was hot-rolled 50% to its final gauge. Panel γ2 was hot-rolled 70% to its final gauge. Panel γ3 was hot-rolled 70% to its final gauge. Panel γ5 was hot-rolled to 50% and then cold-rolled to the final gauge. Panel γ6 was hot-rolled to 70% and then cold-rolled to the final gauge. Panel γ7 was hot-rolled to 70% and then cold-rolled to the final gauge. It was found that the most improved breakdown and / or spheroidization of Fe constituent particles was observed when the metal strips were continuously cast, flash-homogenized, and then hot-rolled.

[0223] Figure 70 is a graph showing the median and distribution data of the equivalent circular diameter of Fe constituent particles within a metal piece, as illustrated and explained with reference to Figure 69.

[0224] Figure 71 is a graph showing the median and distribution data of the aspect ratio of Fe constituent particles within a metal piece, as illustrated and explained with reference to Figure 69.

[0225] Figures 70 and 71 show that a smaller Fe component can be achieved through flash homogenization of continuously cast metal articles followed by hot rolling, especially when compared to hot rolling without flash homogenization.

[0226] In addition, bending tests were performed on samples selected from FIG. 69 in accordance with the German Automotive Industry Association (VDA) standard 238-100 for performing bending tests and the standard 232-200 for normalizing the test to 2.0 mm. Samples from panels γ5 and γ7 achieved alpha (external) bending angles of 160° and 171°, respectively.

[0227] The foregoing description of embodiments including the illustrated embodiments is presented only for purposes of illustration and description and is not intended to be exhaustive or to limit to the precise form disclosed. Numerous modifications, adaptations, and uses will be apparent to those skilled in the art.

[0228] As used hereinafter, any reference to a series of examples should be understood separately as a reference to each of those examples (e.g., "Examples 1-4" is understood as "Examples 1, 2, 3, or 4").

[0229] Example 1 shows a metal casting processing system that includes a continuous casting apparatus for casting a metal strip at a first speed and a hot rolling stand operating at a second speed different from the first speed.

[0230] Example 2 shows the system of Example 1, which further includes a winding device operably coupled to the continuous casting apparatus for winding the metal strip onto an intermediate coil, and an unwinding device operably coupled to the hot rolling stand for receiving the intermediate coil and providing the metal strip to the nip of the hot rolling stand.

[0231] Example 3 shows the system of Example 2, which further includes a preheating device for receiving the intermediate coil.

[0232] Example 4 shows the system of Example 2 or Example 3, and the system further includes a storage system for storing the intermediate coil in the vertical direction.

[0233] Example 5 shows the system of Examples 2 to 4, and the system further includes a storage system for storing the intermediate coil, and the storage system includes a motor for rotating the intermediate coil.

[0234] Example 6 shows the system of Examples 1 to 5, and the system further includes a heat source arranged downstream of the hot rolling stand and a quenching system arranged immediately downstream of the heat source.

[0235] Example 7 shows the system of Examples 1 to 6, and the system further includes a preheating heat source arranged downstream of the hot rolling stand and a quenching system arranged between the preheating heat source and the hot rolling stand.

[0236] Example 8 shows the system of Example 1 or Examples 6 to 7, and the system further includes an accumulator operably arranged between the continuous casting apparatus and the hot rolling stand to absorb the difference between the first speed and the second speed.

[0237] Example 9 shows the system of Examples 1 to 8, and the system further includes a post-quenching device arranged immediately downstream of the continuous casting apparatus.

[0238] Example 10 shows the system of Examples 1 to 9, and the continuous casting apparatus is a belt-type casting apparatus.

[0239] Example 11 shows a metal casting processing system, which includes a belt-type continuous casting apparatus for casting a metal strip, a winding device associated with the continuous casting apparatus for winding the metal strip onto an intermediate coil, and a pay-off device operably coupled to at least one hot rolling stand for accommodating the intermediate coil and reducing the thickness of the metal strip to a desired thickness.

[0240] Example 12 shows the system of Example 11, which further includes a preheating device that receives an intermediate coil.

[0241] Example 13 shows the system of Example 11 or Example 12, which further includes a storage system for vertically storing the intermediate coil.

[0242] Example 14 shows the system of Examples 11-13, which further includes a storage system for housing an intermediate coil, the storage system including a motor for rotating the intermediate coil.

[0243] Example 15 shows the system of Examples 11-14, which further includes a heat source located downstream of the hot rolling stand and a quenching system located directly downstream of the heat source.

[0244] Example 16 shows the system of Examples 11-15, which further includes a preheating heat source located downstream of the hot rolling stand and a quenching system located between the preheating heat source and the hot rolling stand.

[0245] Example 17 shows the system of Examples 11-16, which further includes a post-casting quenching device located directly downstream of the continuous casting apparatus.

[0246] Example 17.5 shows the system of Examples 11-17, in which at least one hot rolling stand is placed between the belt-type continuous casting apparatus and the winding device to reduce the thickness of the metal strip when the belt-type continuous casting apparatus is not casting a metal strip.

[0247] Example 18 illustrates a casting and rolling method, which includes continuously casting a metal strip at a first speed and hot rolling the metal strip at a second speed, the first speed being different from the second speed.

[0248] Example 19 shows the method of Example 18, which further includes winding the cast metal strip into an intermediate coil, and hot rolling the metal strip includes unwinding the intermediate coil.

[0249] Example 20 shows the method of Example 19, which further includes preheating the intermediate coil.

[0250] Example 21 shows the method of Example 19 or Example 20, which further includes storing the intermediate coil in a vertical direction.

[0251] Example 22 shows the methods of Examples 19 - 21, which further includes storing the intermediate coil, and storing the intermediate coil includes rotating the intermediate coil periodically or continuously.

[0252] Example 23 shows the methods of Examples 18 - 22, which further includes heat - treating the metal strip after hot rolling the metal strip, and heat - treating the metal strip includes applying heat to the metal strip and immediately quenching the metal strip.

[0253] Example 24 shows the methods of Examples 18 - 23, which further includes reheating the metal strip before hot rolling the metal strip, and reheating the metal strip includes heating the metal strip to a temperature higher than the hot - rolling temperature and quenching the metal strip to the hot - rolling temperature.

[0254] Example 25 shows the method of Example 18 or Examples 23 - 24, which further includes passing the metal strip through an accumulator, and the accumulator compensates for the difference between the first speed and the second speed.

[0255] Example 26 shows the methods of Examples 18 - 25, and continuously casting the metal strip includes passing liquid metal through a pair of rollers, extracting heat from the liquid metal, and solidifying the liquid metal.

[0256] Example 27 shows an intermediate metal product comprising a first phase of solid aluminum formed by cooling liquid metal in strip thicknesses of 7 mm to 50 mm in a continuous casting apparatus, and a second phase containing alloying elements, wherein the alloying elements become supersaturated in the first phase by rapidly cooling the newly solidified metal to a temperature below its solution temperature.

[0257] Example 28 shows the metal product of Example 27, which is formed in the form of a metal strip wound on an intermediate coil.

[0258] Example 30 shows a metal strip obtained by heating the intermediate metal products of Examples 27-28, the metal strip containing a dispersed phase uniformly distributed throughout the first phase, the dispersed phase having an average size of 10 nm to 500 nm.

[0259] Example 30 illustrates a metal casting system comprising a continuous casting apparatus for casting metal strips and at least one nozzle positioned adjacent to the continuous casting apparatus to supply the metal strips with enough coolant to rapidly cool the metal strips as they exit the continuous casting apparatus.

[0260] Example 31 shows the system of Example 30, in which the continuous casting apparatus is arranged to cast metal strips to a thickness of 7 mm to 50 mm.

[0261] Example 32 shows the system of Example 30 or Example 31, wherein at least one nozzle is positioned to rapidly cool the metal strip to a temperature of 100°C or less within 10 seconds as the metal strip exits the continuous casting apparatus.

[0262] Example 33 shows the system of Examples 30-32, which further includes a reheater positioned downstream of at least one nozzle to heat the metal strip to a temperature above the solution temperature.

[0263] Example 34 shows the system of Example 33, where the solution temperature is approximately 30°C lower than the solidus temperature of the metal in the metal strip. In some cases, the solution temperature is approximately 25°C to 35°C lower than the solidus temperature of the metal in the metal strip.

[0264] Example 34.5 shows the system of Example 33 or Example 34, with a solution temperature of 450°C or higher.

[0265] Example 35 shows the system of Example 33 or Example 34, further comprising a quenching device positioned downstream of the reheater to rapidly cool the metal strip to a temperature below the solution temperature, wherein the quenching device is positioned at a distance from the reheater, suitable for enabling the metal strip to be kept at a temperature above the solution temperature for a period of two hours or less.

[0266] Example 36 shows the system of Example 35, where the distance between the quencher and the reheater is suitable to allow the metal strip to be kept at a temperature above the solution temperature for a period of one hour or less.

[0267] Example 37 shows the system of Example 35, where the distance between the quencher and the reheater is suitable to allow the metal strip to be kept at a temperature above the solution temperature for a period of 5 minutes or less.

[0268] Example 38 shows the system from Examples 30 to 37, and the continuous casting apparatus is a belt-type casting machine.

[0269] Example 39 shows the system of Examples 30-38, which further includes a winding device positioned downstream of at least one nozzle for winding a metal strip onto an intermediate coil.

[0270] Example 40 illustrates a method which includes continuously casting a metal strip using a continuous casting apparatus and quenching the metal strip as it exits the continuous casting apparatus.

[0271] Example 41 illustrates the method of Example 40, and the continuous casting of the metal strips includes continuously casting the metal strips to a thickness of 7 mm to 50 mm.

[0272] Example 42 illustrates the method of Example 40 or Example 41, wherein quenching the metal strip involves adding enough coolant to the metal strip to cool it to a temperature of 100°C or less within 10 seconds when the metal strip exits the continuous casting apparatus.

[0273] Example 43 illustrates the method of Examples 40-42, which further includes quenching the metal strip and then reheating the metal strip, the reheating of the metal strip including heating the metal strip to its solution temperature.

[0274] Example 44 shows the method of Example 43, with a solution temperature of 480°C or higher.

[0275] Example 45 illustrates the method of Example 43 or Example 44, further comprising reheating the metal strip and then quenching the metal strip to cool it below its solution temperature, the quenching being performed after enabling the metal strip to be kept at a temperature above its solution temperature for a period of 2 hours or less.

[0276] Example 46 shows the method of Example 45, but with a duration of 1 hour or less.

[0277] Example 47 shows the method of Example 45, with a duration of 1 minute or less.

[0278] Example 48 illustrates the method of Examples 40-47, in which continuous casting of metal strips involves passing liquid metal through a pair of rollers to extract heat from the liquid metal and solidify it.

[0279] Example 49 illustrates the method of Examples 40-48, which further includes quenching the metal strip and then winding the metal strip onto an intermediate coil.

[0280] Example 50 shows a system according to any of Examples 1-5 or Examples 8-10, the system further comprising a quenching system located directly downstream of the hot rolling stand, the hot rolling stand being positioned to receive the metal strip at a temperature higher than the recrystallization temperature in order to dynamically recrystallize the metal strip during hot rolling.

[0281] Example 50.5 shows a system according to any of Examples 1-5 or Examples 8-10, which further includes a quenching system located directly downstream of a hot rolling stand, the hot rolling stand being positioned to receive a metal strip at rolling temperature and configured to apply sufficient force to the metal strip to reduce its thickness and recrystallize it at rolling temperature.

[0282] Example 51 shows the system of Example 50, which further includes a heat source located upstream of the hot rolling stand for heating the metal strip to a temperature higher than the recrystallization temperature of the metal strip in the hot rolling stand.

[0283] Example 51.5 shows the system of Example 50.5, which further includes a heat source located upstream of the hot rolling stand for heating the metal strip to the rolling temperature.

[0284] Example 52 shows the system of Examples 50-51.5, where the hot rolling stand and quenching system are arranged to monotonically decrease the temperature of the metal strip from directly in front of the hot rolling stand to directly in front of the quenching system.

[0285] Example 53 illustrates the system of Examples 11-14 or Example 17, further comprising a quenching system located directly downstream of at least one hot rolling stand, the at least one hot rolling stand being positioned to receive the metal strip at a temperature higher than the recrystallization temperature in order to dynamically recrystallize the metal strip as it passes through the hot rolling stand furthest downstream of the at least one hot rolling stand.

[0286] Example 53.5 illustrates the system of Examples 11-14 or Example 17, further comprising a quenching system located immediately downstream of at least one hot rolling stand, the hot rolling stand furthest downstream of at least one hot rolling stand being positioned to receive a metal strip at rolling temperature and configured to apply sufficient force to the metal strip to reduce its thickness and recrystallize it at rolling temperature.

[0287] Example 54 shows the system of Example 53, which further includes a heat source located all upstream of at least one hot rolling stand to heat the metal strip to a temperature higher than the recrystallization temperature of the metal strip at the furthest downstream hot rolling stand.

[0288] Example 54.5 shows the system of Example 53.5, which further includes a heat source located all upstream of at least one hot rolling stand to heat the metal strip to a temperature above the rolling temperature.

[0289] Example 55 shows a system of either Example 53 or Example 54, in which at least one hot rolling stand and a quenching system are arranged to monotonically decrease the temperature of the metal strip from all in front of at least one hot rolling stand to immediately after the quenching system.

[0290] Example 56 illustrates the methods of Examples 18-22 or 25-26, the methods further comprising quenching the metal strip immediately after hot rolling the metal strip, the hot rolling of the metal strip comprising passing the metal strip to a final hot rolling stand at a temperature higher than the recrystallization temperature.

[0291] Example 57 illustrates the method of Example 56, which further includes preheating the metal strip immediately before hot rolling it.

[0292] Example 58 illustrates the method of Example 56 or Example 57, wherein the temperature of the metal strip decreases monotonically from a temperature higher than the recrystallization temperature during the hot rolling and quenching of the metal strip.

[0293] Example 59 illustrates a method comprising preheating a metal strip to a temperature higher than its recrystallization temperature, hot rolling the metal strip, passing the metal strip through a final hot rolling stand at a temperature higher than its recrystallization temperature, and quenching the metal strip, which is performed immediately after hot rolling.

[0294] Example 59.5 illustrates a method which includes preheating the metal strip to a temperature above the rolling temperature, hot rolling the metal strip by passing it through a final hot rolling stand at the rolling temperature and applying sufficient force to the metal strip to reduce its thickness and recrystallize it at the rolling temperature, and quenching the metal strip immediately after hot rolling the metal strip.

[0295] Example 60 illustrates the method of Example 59 or Example 59.5, in which hot rolling of a metal strip involves monotonically decreasing the temperature of the metal strip from when the metal strip enters the first hot rolling stand until when the metal strip exits the final hot rolling stand.

[0296] Example 61 illustrates the method of Example 59 or Example 59.5, in which hot rolling of a metal strip involves monotonically decreasing the temperature of the metal strip from the moment the metal strip enters the first hot rolling stand until immediately after the metal strip is quenched during the hot rolling of the metal strip.

[0297] Example 62 illustrates the method of Examples 59-61, wherein hot rolling of the metal strip includes making the rate of thickness reduction at the final hot rolling stand greater than that at one or more preceding hot rolling stands.

[0298] Example 63 illustrates the method of Examples 59-62, in which hot rolling of a metal strip involves extracting heat from the metal strip using multiple work rolls.

[0299] Example 64 illustrates the method of Example 63, wherein extracting heat from the metal strip involves extracting enough heat to bring the metal strip to a desired temperature when passing it through the final hot rolling stand, the desired temperature being determined based on the strain rate associated with reducing the thickness of the metal strip using the final hot rolling stand.

[0300] Example 64.5 illustrates the method of Example 63, in which extracting heat from the metal strip includes extracting enough heat to raise the temperature of the metal strip to the rolling temperature, which is determined based on the strain rate associated with reducing the thickness of the metal strip using the final hot rolling stand.

[0301] Example 65 illustrates the method of Example 63, wherein the final hot rolling stand is configured to reduce the thickness of the metal strip by a preset thickness reduction rate, and the preset thickness reduction rate and desired temperature are determined to minimize the period during which precipitates form within the metal strip.

[0302] Example 66 illustrates the method of Example 63, wherein the final hot rolling stand is configured to reduce the thickness of the metal strip by a preset thickness reduction rate, and the preset thickness reduction rate and rolling temperature are determined to cause the metal strip to form a desired amount of precipitate.

[0303] Example 67 shows the method of Example 65 or 66, and the precipitate is Mg2Si.

[0304] Example 68 shows a metallurgical product manufactured by the methods of Examples 59 to 67, which is tempered to T4 standards and contains a volume fraction of Mg2Si precipitate of 4.0% or less.

[0305] Example 69 shows a metallurgical product manufactured by the methods of Examples 59 to 67, which is tempered to T4 standards and contains a volume fraction of Mg2Si precipitate of 3.0% or less.

[0306] Example 70 shows a metallurgical product manufactured by the methods of Examples 59 to 67, which is tempered to T4 standards and contains a volume fraction of Mg2Si precipitate of 2.0% or less.

[0307] Example 71 shows a metallurgical product manufactured by the methods of Examples 59 to 67, which is tempered to T4 standards and contains a volume fraction of Mg2Si precipitate of 1.0% or less.

[0308] Example 72 shows the system of Examples 11-17, in which at least one hot rolling stand is positioned between the belt-type continuous casting machine and the winding machine to reduce the thickness of the metal strip when the belt-type continuous casting machine is not casting the metal strip.

[0309] Example 73 shows an intermediate metal product comprising a first phase of solid aluminum formed by cooling liquid metal to a strip thickness of 7 mm to 50 mm in a continuous casting apparatus, and a second phase containing alloying elements, the second phase being spheroidized by hot or warm working of the first and second phases with a reduction in cross-sectional area of ​​approximately 30% to 80%. In some cases, the reduction in cross-sectional area is approximately 50% to 70%.

[0310] Example 73.5 shows an intermediate metal product of Example 73, where hot or warm working includes hot or warm rolling, and the reduction in cross-section is the reduction in thickness.

[0311] Example 74 shows the metal product of Example 73, which is formed in the shape of a metal strip wound on a coil.

[0312] Example 75 shows the metal product of Examples 73-74, wherein the second phase is further spheroidized by maintaining a peak metal temperature of approximately 450°C-580°C in the first and second phases for approximately 1-3 minutes before hot or warm working.

[0313] Example 75.5 shows the metal product of Examples 73-74, wherein the second phase is further spheroidized by maintaining the peak metal temperature in the first and second phases to be approximately 15°C to 45°C lower than the solidus temperature of the metal product, and the peak metal temperature is maintained for approximately 1 to 3 minutes before hot or warm working.

[0314] Example 76 illustrates a metal casting system comprising a continuous casting apparatus for casting metal strips and one or more rolling stands located downstream of the continuous casting apparatus for receiving the metal strips and reducing the thickness of the metal strips by about 50% to 70% at a hot or warm rolling temperature.

[0315] Example 77 shows the system of Example 76, in which the continuous casting apparatus is configured to cast metal strips to a thickness of 7 mm to 90 mm.

[0316] Example 78 shows the system of Example 76 or 77, where the hot or warm rolling temperature is at least about 400°C.

[0317] Example 79 illustrates the system of Examples 76-78, further comprising a soaking furnace positioned in a straight line between the continuous casting apparatus and the rolling stand, which maintains the metal strip at a peak metal temperature about 15°C to 45°C below the solidus temperature of the metal strip for about 1 to 3 minutes. In some cases, the peak metal temperature is maintained at about 450°C to 580°C.

[0318] Example 80 illustrates the systems of Examples 76-79, where one or more rolling stands include a single rolling stand capable of achieving a reduction rate of 50% to 70% of the thickness of the metal strip.

[0319] Example 81 shows the system of Examples 76-80, and the continuous casting apparatus is a belt-type casting machine.

[0320] Example 82 illustrates the system of Examples 76-81, which further includes a winding device positioned downstream of one or more rolling stands for winding metal strips into coils.

[0321] Example 83 describes a method that includes continuously casting a metal strip using a continuous casting apparatus, and then hot or warm rolling the metal strip after it has exited the continuous casting apparatus, with a thickness reduction rate of approximately 50% to 70%.

[0322] Example 84 illustrates the method of Example 83, and the continuous casting of the metal strips includes continuously casting the metal strips to a thickness of 7 mm to 50 mm.

[0323] Example 85 illustrates the method of Example 83 or 84, wherein the hot or warm rolling includes hot rolling at a temperature of at least about 400°C.

[0324] Example 86 illustrates the method of Examples 83-85, which further includes maintaining a peak metal temperature about 15°C to 45°C lower than the solidus temperature of the metal strip for about 1 to 3 minutes between casting and rolling the metal strip. In some cases, the peak metal temperature is maintained at about 450°C to 580°C.

[0325] Example 87 illustrates the method of Example 86, which involves hot or warm rolling a metal strip using a single rolling stand to reduce the thickness of the metal strip by approximately 50% to 70%.

[0326] Example 88 illustrates the method of Examples 83-87, in which continuous casting of a metal strip involves passing a pair of rollers through the liquid metal to extract heat from the liquid metal and solidify the liquid metal.

[0327] Example 89 illustrates the method of Examples 83-88, further comprising warm or hot rolling of the metal strip and then winding the metal strip into a coil.

[0328] Example 90 illustrates the method of Examples 83-89, in which hot or warm rolling of a metal strip involves extracting heat from the metal strip in the meshing of the rolling stand, and applying force to the metal strip to reduce its thickness, wherein the applied force is sufficient to recrystallize the metal strip at the temperature of the metal strip.

[0329] Example 91 illustrates the method of Example 90, in which heat extraction and force application are performed in a single rolling stand.

[0330] Example 92 illustrates the method of Example 90, where heat extraction is performed at the first rolling stand and force is applied at the subsequent rolling stand.

[0331] Example 93 shows an aluminum metal product comprising a continuously cast aluminum alloy with a thickness reduced to approximately 35 mm or less, wherein the continuously cast aluminum alloy contains iron in an amount of at least 0.2 wt%, and the median equivalent circle diameter of the iron-based intermetallic compound particles is less than approximately 0.8 μm.

[0332] Example 94 shows the aluminum metal product of Example 93, where the median equivalent circle diameter of the iron-based intermetallic compound particles is less than approximately 0.75 μm.

[0333] Example 95 shows the aluminum metal product of Example 93, where the median equivalent circle diameter of the iron-based intermetallic compound particles is less than approximately 0.65 μm.

[0334] Example 96 shows the aluminum metal products of Examples 93-95, where the median aspect ratio of the iron-based intermetallic compound particles is less than approximately 4.

[0335] Example 97 shows the aluminum metal products of Examples 93-96, and the continuously cast aluminum alloy is in the final specification.

[0336] Example 98 shows the aluminum metal product of Examples 93-97, where the aluminum alloy is of a standard size of approximately 2.0 mm.

[0337] Example 99 shows the aluminum metal products of Examples 93-98, and the aluminum alloy is a 6xxx series aluminum alloy. Some embodiments of this disclosure are described below in <Aspect 1> to <Aspect 31>: <Aspect 1> The first phase of solid aluminum formed by cooling liquid metal to a strip thickness of 7 mm to 50 mm in a continuous casting apparatus; and A second phase containing alloying elements, wherein the second phase is spheroidized by hot or warm working the first and second phases with a reduction in cross-sectional area of ​​approximately 30% to 80%. Intermediate metal products containing these metals. <Aspect 2> The metal product according to Embodiment 1, wherein the hot or warm working includes hot or warm rolling, and the reduction rate of the cross-section is the reduction rate of the thickness. <Aspect 3> The metal product according to embodiment 1, wherein the reduction rate of the cross-section is approximately 50% to 70%. <Aspect 4> The metal product described above is the metal product according to embodiment 1, which is formed in the shape of a metal strip wound on a coil. <Aspect 5> The metal product according to embodiment 1, wherein the second phase is further spheroidized by maintaining the peak metal temperature in the first and second phases to be approximately 15°C to 45°C lower than the solidus temperature of the metal product, and the peak metal temperature is maintained for approximately 1 to 3 minutes before hot or warm working. <Aspect 6> The metal product according to embodiment 1, wherein the second phase is further spheroidized by maintaining a peak metal temperature of approximately 450°C to 580°C in the first and second phases for approximately 1 to 3 minutes prior to the hot or warm working process. <Aspect 7> A continuous casting apparatus for casting metal strips; and One or more rolling stands positioned downstream of the continuous casting apparatus, which receive the metal strip and reduce the thickness of the metal strip by approximately 50% to 70% at a hot or warm rolling temperature. A metal casting system including <Aspect 8> The metal casting system according to embodiment 7, wherein the continuous casting apparatus is configured to cast the metal strip to a thickness of 7 mm to 50 mm. <Pattern 9> The metal casting system according to embodiment 7, wherein the hot or warm rolling temperature is at least about 400°C. <Aspect 10> The metal casting system according to embodiment 7, further comprising a soaking furnace positioned in a straight line between the continuous casting apparatus and the rolling stand, for maintaining the metal strip at a peak metal temperature about 15°C to 45°C lower than the solidus temperature of the metal strip for about 1 to 3 minutes. <Aspect 11> The metal casting system according to embodiment 7, wherein the one or more rolling stands include a single rolling stand capable of achieving a reduction rate of 50% to 70% of the thickness of the metal strip. <Aspect 12> The metal casting system according to embodiment 7, wherein the continuous casting apparatus is a belt-type casting machine. <Aspect 13> The metal casting system according to embodiment 7, further comprising a winding device positioned downstream of one or more rolling stands for winding the metal strip into a coil. <Aspect 14> Continuous casting of metal strips using a continuous casting apparatus; and After the metal strip leaves the continuous casting apparatus, the metal strip is hot-rolled or warm-rolled to a thickness reduction rate of approximately 50% to 70%. A method that includes this. <Aspect 15> The method according to embodiment 14, wherein the continuous casting of the metal strip includes continuously casting the metal strip to a thickness of 7 mm to 50 mm. <Aspect 16> The method according to embodiment 14, wherein hot or warm rolling includes hot rolling at a temperature of at least about 400°C. <Aspect 17> The method according to embodiment 14, further comprising maintaining a peak metal temperature about 15°C to 45°C lower than the solidus temperature of the metal strip for about 1 to 3 minutes between casting and rolling the metal strip. <Aspect 18> The method according to embodiment 14, wherein the hot or warm rolling of the metal strip is performed using a single rolling stand to reduce the thickness of the metal strip by about 50% to 70%. <Aspect 19> The method according to embodiment 14, wherein the continuous casting of the metal strip is further comprising passing a pair of rollers through the liquid metal to extract heat from the liquid metal and to solidify the liquid metal. <Aspect 20> The method according to embodiment 14, further comprising hot or warm rolling the metal strip and then winding the metal strip into a coil. <Aspect 21> Hot or warm rolling of metal strips In the meshing of the rolling stand, heat is extracted from the metal strip; and The method according to embodiment 14, which includes applying force to a metal strip to reduce its thickness such that the applied force is sufficient to recrystallize the metal strip at the temperature of the metal strip: <Aspect 22> The method according to embodiment 21, wherein the extraction of heat and the application of force are performed in a single rolling stand. <Aspect 23> The method according to embodiment 21, wherein heat extraction is performed in the first rolling stand and force is applied in the subsequent rolling stand. <Aspect 24> A continuous casting apparatus for casting metal strips at a first speed; and A hot rolling stand operating at a second speed different from the first speed. A metal casting processing system encompassing all of the above. <Aspect 25> A belt-type continuous casting apparatus for casting metal strips; A winding device associated with a continuous casting apparatus for winding the metal strip onto an intermediate coil; and An unwinding device for receiving the intermediate coil, the unwinding device being coupled to at least one hot rolling stand for reducing the metal strip to a desired thickness, A metal casting system including the following: <Aspect 26> Continuous casting of metal strips at a first speed; and Hot-roll the metal strip at a second speed different from the first speed. A casting and rolling method that includes [a specific element]. <Aspect 27> The first phase of solid aluminum formed by cooling liquid metal to a strip thickness of 7 mm to 50 mm in a continuous casting apparatus; and The second phase contains alloying elements that are supersaturated in the first phase by rapidly cooling the newly solidified metal to a temperature below its solution temperature. Intermediate metal products including those containing metal. <Aspect 28> A continuous casting apparatus for casting metal strips; and A nozzle positioned adjacent to the continuous casting apparatus, which supplies a sufficient amount of coolant to the metal strip to rapidly cool the metal strip as it exits the continuous casting apparatus. A metal casting system encompassing all of these. <Aspect 29> Continuous casting of metal strips using a continuous casting apparatus; and A method comprising rapidly quenching the metal strip as it exits the continuous casting apparatus. <Aspect 30> Preheating the metal strip to a temperature above the rolling temperature; and Hot rolling the metal strip, which includes passing the metal strip through a final hot rolling stand at the rolling temperature and applying a force to the metal strip sufficient to reduce its thickness and recrystallize it at the rolling temperature; and The metal strip is quenched immediately after hot rolling. A method of including. <Aspect 31> An aluminum metal product comprising a continuously cast aluminum alloy whose thickness has been reduced to approximately 35 mm or less, wherein the continuously cast aluminum alloy contains iron in an amount of at least 0.2% by weight, and the median equivalent circle diameter of the iron-based intermetallic compound particles is less than approximately 0.8 μm.

Claims

1. A method for manufacturing an intermediate metal product which is an aluminum alloy of the 3xxx, 5xxx, 6xxx, or 7xxx series, The aforementioned intermediate metal product The first phase of solid aluminum; and Second phase containing alloying elements, It contains, In the above method, The first phase of solid aluminum is formed by cooling the liquid metal to a strip thickness of 7 mm to 50 mm in a continuous casting apparatus. By hot or warm working the first and second phases with a reduction in cross-sectional area of ​​30% to 80%, the second phase is made spheroidal, and The second phase is further sphericalized by maintaining the peak metal temperature in the first and second phases at 450°C to 580°C and 15°C to 45°C lower than the solidus temperature of the intermediate metal product, wherein the peak metal temperature is maintained for 1 to 3 minutes before the hot or warm working process. method.

2. The method for manufacturing an intermediate metal product according to claim 1, wherein the hot or warm working includes hot or warm rolling, and the reduction rate of the cross-section is the reduction rate of the thickness.

3. The method for manufacturing an intermediate metal product according to claim 1, wherein the reduction rate of the cross-section is 50% to 70%.

4. The method for manufacturing an intermediate metal product according to claim 1, wherein the intermediate metal product is formed in the shape of a metal strip wound on a coil.

5. The method for manufacturing an intermediate metal product according to claim 1, wherein the second phase is further spheroidized by maintaining a peak metal temperature of 450°C to 580°C in the first and second phases for 1 to 3 minutes prior to the hot or warm working.

6. Continuous casting of metal strips using a continuous casting apparatus. After the metal strip leaves the continuous casting apparatus, the metal strip is hot or warm rolled to a thickness reduction rate of 50% to 70%; and Between the casting and rolling of the metal strip, maintain a peak metal temperature of 450°C to 580°C and 15°C to 150°C lower than the solidus temperature of the metal strip for 1 to 10 minutes. A method including, Hot or warm rolling of metal strips In the meshing of the rolling stand, heat is extracted from the metal strip; and This includes applying force to a metal strip to reduce its thickness, such that the applied force is sufficient to recrystallize the metal strip at the metal strip's temperature. The extraction of heat and the application of force are performed in a single rolling stand. A method wherein the metal strip is an aluminum alloy of the 3xxx, 5xxx, 6xxx, or 7xxx series.

7. Continuous casting of metal strips using a continuous casting apparatus; After the metal strip leaves the continuous casting apparatus, the metal strip is hot or warm rolled to a thickness reduction rate of 50% to 70%; and Between the casting and rolling of the metal strip, maintain a peak metal temperature of 450°C to 580°C and 15°C to 150°C lower than the solidus temperature of the metal strip for 1 to 10 minutes. A method including, Hot or warm rolling of metal strips In the meshing of the rolling stand, heat is extracted from the metal strip; and This includes applying force to a metal strip to reduce its thickness, such that the applied force is sufficient to recrystallize the metal strip at the metal strip's temperature. The extraction of heat is performed in the first rolling stand, and the application of force is performed in the subsequent rolling stand. A method wherein the metal strip is an aluminum alloy of the 3xxx, 5xxx, 6xxx, or 7xxx series.

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