ACTIVE MIXTURES AS INSECTICIDES, COMPRISING A CARBOXAMIDE COMPOUND

Abstract

The present invention relates to pesticide mixtures comprising as active compound I a carboxamide derivative active as an insecticide and at least one active compound II selected from group M comprising acetylcholine esterase inhibitors, GABA-regulated chloride channel antagonists, sodium channel modulators, nicotinic acetylcholine receptor agonists / antagonists, allosteric nicotinic acetylcholine receptor activators, chloride channel activators, juvenile hormone mimics, homopteran feeding blockers, mite growth inhibitors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers, chitin biosynthesis inhibitors, molting disruptors, ecdyson receptor agonists, octamine receptor agonists, MET inhibitors, voltage-gated sodium channel blockers, lipid synthesis inhibitors,ryanodine receptor modulators and other compounds defined in the description, in synergistically effective amounts. The invention also relates to methods and the use of these mixtures to combat and control insects, arachnids, or nematodes in plants, and to protect these plants against pest infestation, in particular also to protect plant propagation material, such as seeds.

Claims

1. Pesticide mixtures comprising as active compounds 1) at least one carboxamide compound active as a pesticide I of Formula (I): or the tautomers, enantiomers, diastereomers or salts thereof, and 2) al menos un compuesto activo como plaguicida II seleccionado del grupo M que consiste en: I l-M .3 Moduladores del canal de sodio de la clase de: II-M.3A piretroides, que incluyen acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, b io al I et h r i η, bioallethrin S-cylclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfIuthriη, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alfa-cypermethrin, betacypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, heptafluth rin, imiprothrin, meperfluthrin, metofluthrin, momfluorothrin, permethrin, phenothrin, prallethrin, profluthrin, pyrethrin 128 (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethy If I uth r¡ n, tetramethrin,tralomethrin and tran sf I uth r¡ n; in synergistically effective amounts.

2. An agricultural mixture according to claim 1, wherein the mixture also comprises at least one fungicidal active compound III selected from group F consisting of: Fl) Respiration inhibitors Fl 1) Complex III inhibitors at the Qo site (e.g., strobilins): azoxystrobin, coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, phenaminostrobin, phenoxystrobin / fluphenoxystrobin, fluoxastrobin, kresoxim-methyl, mandestrobine, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyramethostrobin, pyraoxystrobin, trifloxystrobin and 2-(2-(3-(2,6-dichlorophenyl)-1-methyl-allylidenamineoxymethyl)phenyl)-2-methoxyimino-N-methylacetamide, pyribencarb, triclopyricarb / chlorodincarb, famoxadone, fenamidone; Fl 2) Complex III inhibitors at the Q1 site: cyazofamid, amisulbrom, 2-methylpropanoate of [(3S,6S,7R,8R)-8-bencyl-3-[(3acetoxi-4-methox-p¡r¡d¡n-2-carbon¡l)am¡no]-6-met¡l-4,9-d¡oxo-1,5-dioxonan-7-yl], 2-methylpropanoate de [(3S,6S,7R,8R)-8-bencyl-3-[[3(acetoximethox)-4-methox-p¡r¡d¡n-2-carbon¡l]am¡no]-6-met¡l-4,9-dioxo-1,5-dioxonan-7-yl], 2-methylpropanoate de [(3S,6S,7R,8R)-8benc¡l-3-[(3-¡sobutoxycarbon¡lox¡-4-methox¡-p¡r¡d¡n-2-carbon¡l)am¡no]6-methyl-4,9-dioxo-1,5-dioxonan-7-ilo], 2-methylpropanoate de 77fcQnn / l 7Π7 / Β / ΥΙΛΙ 129 [(3S,6S,7R,8R)-8-bencyl-3-[[3-(1,3-benzodioxol-5-ylmethox¡)-4-methox¡pir¡d¡n-2-carbon¡l]am¡no]-6-methyl-4,9-d¡oxo-1,5-dioxonan-7-ilo]; [(3S,6S,7R,8R)-8-bencyl-3-[[3-(1,3-benzodioxol-5-ylmethoxy)-4-methoxy-pyridin-2-carbonyl]amino]-6-methyl-4,9-dioxo-1,5dioxonan-7-yl] 2-methylpropanoate; (3S,6S,7R,8R)-3-[[(3-hydroxy-4-methoxy-2-pyridyl)carbonyl]amino]-6-methyl-4,9-d-oxo-8-(phenylmethyl)1,5-dioxonan-7-yl] 2-methylpropanoate; Fl 3) Inhibitors of complex II (for example, carboxamidas): benodanil, benzovindiflupyr, bixafen, boscalid, carboxin, fenfuram, fluopyram,flutolanil, fluxapyroxade, furametpyr, isofetamide, isopyrazam, mepronil, oxycarboxin, penflufen, penthiopyrad, sedaxane, teclophthalam, thifluzamide, N-(4'-trifluoromethylthiobifen¡I-2¡l)-3-difluoromethyl-1-1 H-pyrazole-4-carboxamide, N-(2-(1,3,3trimethyl-butyl)-phenyl)-1,3-dimethyl-5-fluoro-1 H-pyrazole-4-carboxamide, 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide, 3-(trifluoromethyl)-1 - methyl-N-(1,1,3-tr¡ methi lindane-4yl)pyrazol-4-carboxamide, 1,3-dim ethyl-N-(1,1,3-trimethyl¡ndan-4yl)pyrazol-4-carboxamide, 3-(trifluoromethyl)-1,5-dimethyl-N-(1,1,3trimethyl¡ndan-4-¡l)p¡razol-4-carboxamide, 1,3,5 -1 rim et i I - N - (1,1,3trimethylindan-4-¡l)p¡razol-4-carboxamide, N-fluoro-trimethyl¡dan-4-¡l) ndan-4-i I) -1,3-dimethyl-p¡razol-4-carboxam¡da, N-[2-(2,4dichlorophen¡l)-2-methox¡-1-met¡l-et¡l]-3-(difluorometh¡l)-1 -methyl-pyrazol-4carboxamide; N-[2-(2,4-difluorophenyl)phenyl]-3-(trifluoromethyl)pyrazine-2carboxamide; Fl 4) Other respiratory inhibitors (e.g.,complex I, 130 uncouplers): diflumetorim, (5,8-difluoroquinazolin-4-1l)-{2-[2-fluoro-4-(4-trifluoromethylpyridin-2-yloxy)-phenyl]-ethyl}-amine; nitrophenyl derivatives: binapacryl, dinobuton, dinocap, fluazinam; ferimzone; organometal compounds: fentin salts, such as fentin acetate, fentin chloride or fentin hydroxide; ametoctradin; and silthiofam; F.ll) Sterol biosynthesis inhibitors (SBI fungicides) F.ll 1) C14 demethylase inhibitors (DMI fungicides): triazoles: azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, diniconazole-M, epoxiconazole, fenbuconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, propiconazole, oxpoconazole, paclobutrazole, penconazole, prothioconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triticonazole, uniconazole, 1 -[ re / -(2S ;3R)-3-(2-cl orof in i I)-2-(2,4-d if I u orof en i I)-oxirane i I methy I] 5-thiocyanate-1 H-[1,2,4]triazole, 2-[re / -(2S;3R)-3-(2-chlorophenyl)-2-(2,4difluorophenyl)-ox¡ran¡lmeth¡l]-2H-[1,2,4]triazol-3-thiol, 2-[2-chloro-4-(4chlorophenoxy)phenyl]-1-(2,1-1,4-triazol -yl)pentan-2-ol, 1 -[4-(4chlorophenoxy)-2-(trifluoromet¡l)phen¡l]-1 -cyclopropyl-2-(1,2,4-triazol-1 ¡ I )ethane o 1, 2-[4-(4-chlorophenoxy)-2-(trifluoromet¡l)phen¡l]-1-(1,2,4-triazol1 -i I) is tan-2-01, 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1 - (1,2,4-triazol-1-yl-butan, 2-[4-(4-chlorophenoxy)-2-(trifluoromet¡l)phen¡l]-3-met¡l-1 (1,2,4-triazol-1 -yl)butan-2-ol, 2-[4-(4-chlorophenox¡)-2(trifluoromethyl)phen¡l]-1-(1,4-1-triazol yl)propan-2-ol, 2-[2-chloro-4-(4chlo rof en ox i )pheny I]-3-m et i I -1 -(1,2,4-1 riazol -1 -yl)butan-2-ol, 2-[4-(4 chlo rof en oxy)-2-(trif lu oro me I tri) -1-(4-1) -1 -i I )pen tan-2-01, 2-[4-(4-fluorophenoxy)-2-(trifluoromethyl)phenyl]-1 - (1,2,4-triazole-1 i I )propane-2-01; imidazoles: imazalil, pefurazoate, prochloraz,triflumizole; pyrimidines, pyridines and piperazines: fenarimol, nuarimol, 131 pyrifenox, triforine, [3-(4-chloro-2-fluoro-phenyl)-5-(2,4d¡fluorophen¡l)¡soxazol-4-yl]-(3-pyr¡d¡l)methanol; F.ll 2) Delta4-reductase inhibitors: aldimorph, dodemorph, dodemorph-acetate, fenpropimorph, tridemorph, fenpropidin, piperalin, spiroxamine; F.ll 3) 3-keto reductase inhibitors: fenhexamid; F.lll) Inhibitors of nucleic acid synthesis F.lll 1) Acylamino acid or phenylamide fungicides: benalaxyl, benalaxyl-M, kiralaxyl, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixyl; F.lll 2) Others: hymexazole, octhilinone, oxolinic acid, bupirimate, 5-fluorocytosine, 5-fluoro-2-(p-tolylmethoxy)primidin-4-amine, 5fluoro-2-(4-fluorophenylmethoxy)primidin-4-amine; F.IV) Inhibitors of cell division and cytoskeleton F.IV 1) Tubulin inhibitors, such as benzimidazoles, thiophanates: benomyl, carbendazim, fuberidazole, thiabendazole,thiophanate-stripes; triazolopyrimidines: 5-chloro-7-(4-methylpiper¡d¡n1-yl)-6-(2,4,6-trifluorophen¡l)-[1,2,4]triazolo[1,5-a]pyrmidine; F.IV 2) Other inhibitors of cell division: diethofencarb, ethaboxam, pencycuron, f I u opico I ide, zoxamide, metraphenone, pyriophenone; FV) Inhibitors of amino acid and protein synthesis FV 1) Inhibitors of methionine synthesis (an i I in op irim id ins): cyprodinil, mepanipyrim, pyrimethanil; FV 2) Protein synthesis inhibitors: blasticidin-S, kasugamycin, kasugamycin hydrochloride-hydrate, mildiomycin, 77fcQnn / l 7Π7 / Β / ΥΙΛΙ 132 streptomycin, oxytetracycline, polyoxin, validamycin A; F.VI) Signal transduction inhibitors F.VI 1) MAP / histidine kinase inhibitors: fluoroimide, iprodione, procymidone, vinclozolin, phenpiclonil,fludioxonil; F.VI 2) G protein inhibitors: quinoxyfen; F.VII) Lipid and membrane synthesis inhibitors F.VII 1) Phospholipid biosynthesis inhibitors: edifenphos, iprobenphos, pyrazophos, isoprothiolane; F.VII 2) Lipid peroxidation: dicloran, quintozene, tecnazene, tolclofos-methyl, biphenyl, chloroneb, etridiazole; F.VII 3) Phospholipid biosynthesis and cell wall deposition: dimethomorph, flumorph, mandipropamid, pyrimorph, benthiavalicarb, iprovalicarb, valifenalate and (4-f I uo rof en i I) ester of N-(1 - (1 - (4-cyano-phenyl)ethansulfonyl)-but-2-yl)carbamic acid; F.VII 4) Compounds affecting cell membrane permeability and fatty acids: propamocarb, propamocarb hydrochloride; F.VII 5) Fatty acid amide hydrolase inhibitors: oxath iapip ro I in; F.VIII) Inhibitors with action at multiple sites F.VIII 1) Inorganic active substances: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride,basic cobre sulphate, blue; F.VIII 2) Tío- and ditiocarbamatos: ferbam, mancozeb, maneb, metam, metiram, propineb, thiram, zineb, ziram; F.VIII 3) Compounds of organochlorine (por ejemplo: ftalimidas, 77hQnn / l 7Π7 / Β / ΥΙΛΙ 133 sulfamidas, cloronitrilos): anilazine, chlorothalonil, captafol, captan, folpet, dichlofluanid, dichlorophen, hexachlorobenzene, pentachlorphenole y sus sales, phthalide, tolyIfIuanid, N-(4-cloro-2nitro-fenil)-N-et¡l-4-met¡l-bencen su Ifon amida; F.VIII 4) Guanidinas y otros: guanidina, dodina, base libre de dodina, guazatine, guazatine-acetato, iminoctadine, iminoctadinetriacetato, im¡noctadine-tr¡s(albes¡late), dithianon, 2,6-dimetil1H,5H-[1,4]dit¡¡no[2,3-c:5,6-c']d¡p¡rrol-1,3,5,7(2H,6H)-tetraona; F.IX) Inhibidores de la síntesis de la pared celular F.IX 1) Inhibidores de la síntesis de glucano: validamycin, polyoxin B; F.IX-2) Inhibitors of melanin synthesis: pyroquilon, tricyclazole, carpropamide, dicyclomet,fenoxanil; FX) Plant defense inducers FX 1) Acibenzolar-S-methylo, probenazole, isotianil, tiadinil, prohexadione-calcium; FX 2) Phosphonates: fosetyl, fosetyl-aluminium, phosphorous acid and its sales, 4-c¡cloprop¡lN-(2,4-dimethox¡phenyl)thiadiazol-5-carboxamida; (F. oxathiapiprolin, picarbutrazox, tolprocarb, 2-[3,5-b¡s(difIuoromethiI)-1 H-pyrazol-1-yl]1 -[4- (4-{5- [2 - (prop-2- in -1 -iloxi)fen¡l]-4,5-d¡h¡dro-1,2-oxazol-3-il}-1,377hQnn / l 7Π7 / Β / ΥΙΛΙ 134 thiazol-2-yl)p¡per¡d¡n-1 - il]etanona, 2-[3,5-bis(d¡fluoromethyl)-1Hpyrazol-1 - il]-1 - [4-(4-{5-[2-fluoro-6-(prop-2-in-1 -iloxi)phenyl]-4,5d ihidro -1,2-ox azo I-3-i I} -1,3-ti azo I - 2-il) pipe rid in -1 - il]etanona, 2-[3,5bis(difluoromethyl)-1 H-pyrazole-1 - yl]-1 - [4-(4-{5-[2-chloro-6-(prop-2-in-1 iloxi)phen¡l]-4,5-d¡hydro-1,2-oxazol-3-yl}-1,3-thiazol-2-pyrazol-1-ylpietanone,] oxina-copper, proquinazide, tebufloquine, teclophthalam, triazoxide, 2-butoxy-6-¡odo-3-propylchromen-4-one, N(cyclopropylmethoxy¡¡m¡no-(6-d¡fluoro-methoxy¡-2,3-d¡fluoro-phen¡l)-met¡l)2-phenylacetamide, N'-(4-(4-chloro-3-trifluoromethyl-phenoxy¡)-2,5-d¡meth¡lphenyl)-N-ethyl-N-meth¡lformam¡na, N'-(4-(4-fluoro-3-trifluoromethylphenoxy)-2,5-d¡met¡l-phen¡l)-N-et¡lN-methylformam¡dine, N'-(2-methyl-5trifluoromethyl-4-(3-trimethylsilanyl-propoxy)-phenyl)-N-ethylformamidine,N N'-(5-trifluorometh¡l-2-met¡l-4-(3-trimeth¡ls¡lan¡lpropoxy)-phen¡l)-N-ethyl-N-methylformam¡na, 6-ter-butyl-8-fluoro-2,3dimethyl-quinoline-4-yl ester of oxyacetic acid, 3-[5-(4-methylphen¡I)2,3-dimeth¡l-¡soxazol¡n-3-¡l]-p¡r¡d¡na, 3-[5-(4-chloro-phenyl)-2,3-dimeth¡l soxazo l¡ di n-3-l¡¡¡¡¡¡l rhizode-amidate (amide) N-(6methoxy-pyrid¡n-3-¡l)cyclopropanecarboxylic acid, 5-chloro-1-(4,6-dimethox¡pirim¡d¡n-2-¡l)-2-met¡l-1 H-benzoimidazol, 2-(4-chloro-phenyl)-N-[4-(3,4d¡methiox¡-phen¡l)-¡soxazol-5-¡l]-2-prop-2-¡n¡lox¡-acetam¡da, (Z)-3-amino-2-cyano-3-phen¡l-prop-2-ethyl enoate, N-[6-[[(Z)-[(1 met¡ltetrazol·5-¡l)-phen¡l·met¡len]am¡no]ox¡met¡l]-2-p¡r¡d¡l]carbamate de penti I o, 2-[2-[(7,8-difluoro-2-methyl-3-qu¡nolyl)oxi]-6-fluorophenyl]propan-2-ol, 2-[2-fluoro-6-[(8-fluoro-2-methyl-3-quinol¡l)ox¡]phenyl]propan-2-ol, 3-(5-fluoro-3,3,4,4-tetramethyl-3,4-d¡h¡dro¡soqu¡nol¡n 77hQnn / l 7Π7 / Β / ΥΙΛΙ 135 1 -yl)quinoline, 3-(4,4-d¡fluoro-3,3-d¡methyl-3,4-d¡h¡dro¡soqu¡nol¡n-1yl)quinoline, 3-(4,4,5-trifluoro-3,3-d¡met¡l-3,4-d¡h¡dro¡soqu¡nolin-1¡l)quinoline; F.XII) Bioplaguicidas F.XII 1) Microbial plaguicidades with fungicidal, bactericidal, antiviral and / or plant protection activity: Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus amyloliquefaciens, B. mojavensís, B. pumilus, B. simplex, B. solisalsi, B. subtilis,B. subtilis var. amyloliquefaciens, Candida oleophila, C. saitoana, Clavibacter michiganensis (bacteriophages), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Dilophosphora alopecuri, Fusarium oxysporum, Clonostachys rosea f. catenulate (also called Gliocladium catenulatum), Gliocladium roseum, Lysobacter antibioticus, L. enzymogenes, Metschnikowia fructicola, Microdochium dimerum, Microsphaeropsis ochracea, Musco dor albus, Paenibacillus polymyxa, Pantoea vagans, Phlebiopsis gigantea, Pseudomonas sp., Pseudomonas chloraphis, Pseudozyma flocculosa, Pichia anómala, Pythium oligandrum, Sphaerodes mycoparasitica, Streptomyces griseoviridis, S. lydicus, S. violaceusniger, Talaromyces flavus, Trichoderma asperellum, T. atroviride, T. fertile, T. gamsii, T. harmatum; T. harzianum, mixture of T. harzianum and T. viride; mixture of T. polysporum and T. harzianum; T. stromaticum, T. virens (also called Gliocladium virens), T. viride, Typhula phacorrhiza,Ulocladium 136 oudemansii, Verticillium dahlia, zucchini yellow mosaic virus (antivirulent strain); F.XII 2) Biochemical pesticides with fungicidal, bactericidal, antiviral and / or plant defense activating activity: chitosan (hydrolyzed), hairpin protein, laminarin, menhaden fish oil, natamycin, plum pox virus coating protein, potassium or sodium bicarbonate, Reynoutria sachlinensis extract, salicylic acid, tea tree oil.

3. An agricultural mixture according to claim 1 or 2, wherein the mixture also comprises 2, 3, or 4 fungicidal active compounds III selected from group F.

4. Pesticide mixtures according to claim 1, 2, or 3, wherein at least one active compound II is selected from II-M.3A within the pyrethroid class of acrinathrin, bifenthrin, cyfluthrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, deltamethrin, esfenvalerate, fenpropathrin, flucythrinate,tefluthrin, tau-fluvalinate, silafluofen, or tralomethrin.

5. Pesticide mixtures according to claims 1, 2, or 3, wherein at least one active compound II is lambda-cyhalothrin or alpha-cypermethrin.

6. Pesticide mixtures according to claims 1, 2, or 3, wherein at least one active compound II is selected from acrinathrin, bifenthrin, cyfluthrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, deltamethrin, esfenvalerate, fenpropathrin, flucythrinate, tau-fluvalinate, silafluofen, or tralomethrin.

7. Pesticide mixtures according to claims 1, 2, or 3, wherein at least one active compound II is selected from bifenthrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, tefluthrin, or deltamethrin.

8. Pesticide mixtures according to claims 1, 2, or 3, wherein the additional fungicidal active compound III is pyraclostrobin.

9. Pesticide mixtures according to claims 1, 2, or 3,wherein the additional active compound III is fluxapyroxad.

10. The pesticide mixtures of claims 1, 2 or 3, wherein the additional active compound III is selected from the group comprising 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1 (1,2,4-triazol-1-yl), 1 -2-olpentane [4-(4-chlorophenoxy)-2-(trifluoromet¡l)phen¡l]-1 cyclopropy 1-2-(1,2,4-triazol-1 - i I) ethane o 1, 2-[4-(4-chlorophenoxy¡)-2(trifluoromethyl)phen¡l]-1,2-1,4-1-triazol yl)butan-2-ol, 2-[2-chloro-4-(4chlo rof en oxy)f en yl]-1 -(1,2,4-triazol-1 - yl)butan-2-ol, 2-[4-(4chlorophenoxy)-2-(trifluoromethyl)phenyl]-3-methyl-1,2-(1,4-triazol-1) -yl)butan2-o I, 2-[4-(4-chlorophenoxy)-2-(trifluorometh¡l)phen¡l]-1 -(1,2,4-triazol-1 yl)propan-2-ol, 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-3-methyl-1,14-(1) yl)butan-2-ol, 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1(1,2,4-triazol-1 -yl)pentan-2-ol o 2-[4-(4-fluorophenoxy¡)-2(trifluoromethyl)phenyl]-1 - (1,2,24-triazol-1-yl)propan-2-ol.

11. Pesticide mixtures according to any one of claims 1 to 10, comprising active compound I of Formula I and active compound II in a weight ratio of 500:1 to 1:

100.

12. A method for protecting plants against attack or infestation by insects, mites, or nematodes, comprising contacting the plant, or the soil or water where the plant grows, with a mixture according to any one of claims 1 to 11 in amounts effective as a pesticide.

13. A method for controlling insects, arachnids, or nematodes, comprising contacting an insect, mite, or nematode, or its food supply, habitat, breeding site, or locus, with a mixture according to any one of claims 1 to 11 in quantities effective as a pesticide.

14. A method for protecting plant propagation material,comprising contacting plant propagation material with a mixture as defined in any of claims 1 to 11 in quantities effective as a pesticide.

15. Seed, comprising the mixture according to any of claims 1 to 11 in an amount of 0.1 g / 100 kg per 100 kg of seed.

16. The use of a mixture according to any of claims 1 to 11 to control insects, arachnids, or nematodes.

17. A pesticide composition, comprising a liquid or solid carrier and a mixture according to any of claims 1 to 11.