Nbc protective clothing with improved protective effect in the seam region
Incorporating a multi-layered textile adsorption filter material in the seam area of NBC protective clothing addresses the issue of pollutant penetration through seams, offering enhanced protection and comfort by absorbing harmful substances and maintaining mechanical stability.
Patent Information
- Application Number
- PCT/EP2024/063189
- Authority / Receiving Office
- WO · WO
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2023-08-23
- Filing Date
- 2024-05-14
- Publication Date
- 2025-01-02
AI Technical Summary
Existing NBC protective clothing faces challenges in providing effective sealing against chemical, biological, and radioactive pollutants at seam connections, which are weak points that can lead to penetration of harmful substances, especially under high concentrations or mechanical stress, and existing solutions like seam sealing tapes have limitations in durability and compatibility.
The use of a multi-layered, textile air-permeable adsorption filter material as an additional layer in the seam area, connected via the same seam as the other layers, to absorb and prevent the penetration of pollutants, enhancing the protective function while maintaining wearing comfort and mechanical stability.
This solution provides a durable and flexible seal that effectively prevents the entry of pollutants through seams, reducing the burden on the adsorption filter material and ensuring a high level of protection against chemical, biological, and radioactive threats, even under adverse conditions.
Smart Images

Figure EP2024063189_02012025_PF_FP_ABST
Abstract
Description
[0001] ABC protective clothing with improved protection in the seam area
[0002] The present invention relates to the technical field of protective clothing with a protective function against chemical and / or biological and / or radioactive pollutants or toxic substances (such as hazardous substances, warfare agents or the like), as it can be used in particular in the military and civilian sectors.
[0003] In particular, the present invention specifically relates to NBC protective clothing or CBRN protective clothing (where ABC stands for atomic, biological, and chemical, and CBRN stands for chemical, biological, radioactive, and nuclear; the terms ABC and CBRN are used synonymously within the scope of the present invention). In this context, the present invention also relates to the technical field of corresponding NBC or CBRN protective clothing, such as can be used in particular for military purposes or for civilian purposes, for example in the field of hazard prevention, firefighting, disaster control, or the like.
[0004] Against this background, the present invention relates in particular to protective clothing with a protective function against chemical or biological or radioactive pollutants or toxins (i.e. chemical pollutants and / or toxins, biological pollutants and / or toxins and / or radioactive pollutants and / or toxins), such as warfare agents, wherein the protective clothing according to the invention has a first layer in the form of a multi-layer, textile, air-permeable adsorption filter material and a second layer in the form of a textile, air-permeable cover material on the one hand and, in addition, a third layer in the form of a non-textile and air-impermeable sheet material (which is also, in particular, water (vapor)-impermeable and, in particular, single-layered) on the other hand, wherein the layers are connected to one another in a connecting region with a common seam (layer connecting seam).are sewn together, wherein in addition, a specially designed and specially arranged additional textile adsorption filter material, which is multi-layered and air-permeable, is present or used, wherein the additional textile adsorption filter material is connected or sewn to the aforementioned layers by means of the same seam (namely the layer connecting seam). Furthermore, the present invention also relates to a related protective material as such, which equally has a protective function against chemical, biological, or radioactive pollutants and toxins. Furthermore, the present invention also relates to protective equipment or protective articles as well as filters and filter materials which are produced using the protective material according to the invention or which comprise such a protective material according to the invention.In this context, the present invention also relates to the use of the protective material according to the invention for the production of protective equipment or protective articles as well as for the production of filters and filter materials.
[0005] The present invention further relates to a method for sealing against chemical and / or biological and / or radioactive pollutants or toxins a connecting region of textile layers on the one hand and a non-textile (sealing) layer on the other hand, a protective clothing or a protective material using an additional adsorption filter material.
[0006] Furthermore, the present invention also relates to the use of an additional adsorption filter material in the connection area of textile layers on the one hand and a non-textile (sealing) layer on the other hand, a protective clothing or a protective material for sealing the connection of the textile layers overlapping in the connection area on the one hand and the non-textile layer on the other hand.
[0007] Furthermore, the present invention also relates to the use of an additional adsorption filter material for sealingly connecting a transition region between textile layers or materials on the one hand and a non-textile layer or material on the other hand.
[0008] Harmful or toxic substances generally pose a high level of danger and can have a detrimental effect on the health of anyone who comes into contact with them. Any exposure to or contact with them, for example through contact with skin or mucous membranes, inhalation, ingestion, or the like, must therefore be avoided or at least minimized. This is particularly important given that the health impairments and toxic potential of such substances can sometimes be considerable, and that contact with or ingestion of even small amounts of such substances can lead to long-term health problems or even death in those affected. In this context, it should also be noted that toxic or harmful substances can exist in numerous chemical and physical forms, for example as gases, liquids, or solids, and in the form of finely divided or finely particulate aerosols.from pollutant particles or the like present in the (ambient) air.
[0009] Not least against this background, there is a great need or necessity to provide people who are at risk of coming into contact with toxic or harmful substances, such as soldiers, firefighters, police officers, members of special or special units or the like, with appropriate protective clothing with ABC or CBRN protection function, in order to prevent the absorption of corresponding toxic or harmful substances when deployed in a contaminated or polluted environment by wearing the protective clothing.
[0010] Especially for groups of people such as soldiers, firefighters, police officers, members of special units, or the like, who are at increased risk of coming into contact with toxic or harmful substances, it is particularly advisable and necessary to ensure appropriate protection against these toxic or harmful substances, including by wearing respiratory masks (ABC respiratory masks or CBRN protective masks). Furthermore, toxic or harmful substances can often be absorbed or absorbed through the skin in addition to the respiratory tract, which represents a further high risk potential. In this respect, it is often necessary for these people to wear appropriate protective clothing (ABC or CBRN protective clothing) in addition to a respiratory mask in order to prevent contact of the toxic or harmful substances with the skin or body.In this context, such protective clothing, which may be in the form of protective suits, protective jackets or the like, often also includes a corresponding headgear or hood, for example in the form of a hood or a balaclava.
[0011] In this context, the general purpose of ABC or CBRN protective clothing is to provide the wearer or user with optimal or additional protection against harmful or toxic substances, particularly insofar as the wearer or user of such protective clothing is, on the one hand, protected as best as possible and, on the other hand, can continue to carry out their operational duties or activities as unhindered as possible. Thus, in addition to providing appropriate protection against toxic or warfare agents, the wearing comfort provided by the protective clothing also plays a major role, both with regard to a good fit and the provision of moisture or thermoregulatory properties when the protective clothing is worn. With regard to the provision of this type of protective clothing, a major challenge is to provide the most holistic and / or versatile orTo provide comprehensive and reliable protection, ensuring protection against a wide variety of different toxins and harmful substances, or those present in various (physicochemical) forms. The often conflicting properties of providing a high level of protection on the one hand and a high level of comfort on the other should be equally fulfilled in one and the same material.
[0012] With regard to protective clothing, it is also necessary to ensure the longest-lasting and most versatile protection possible against toxins and harmful substances, whereby the protective function is guaranteed even in the event of high local pollutant or toxic substance concentrations (e.g. in the event that a drop of a pollutant or toxic substance comes into direct contact with the protective clothing) and thus in the event of high local pollutant or toxic substance concentrations. The protective function must also be guaranteed for long periods of time and under adverse operating conditions, and this must also apply to particularly critical sections or areas of the protective clothing, such as seams and end or transition areas, for example for connecting individual surface sections or layers of the components used, as well as in the area of transition or opening areas (passage areas) of the protective clothing, for example head orNeck openings, field of vision openings, abdominal or pelvic openings, arm or hand openings, leg or foot openings or the like. The same applies to transition or connecting areas between protective clothing worn together or at the same time, such as between a jacket and trousers or between a sleeve of a jacket and a glove or a protective system (such as the transition or connecting area or interface between a headgear or hood and a breathing mask or the like). Such locations or sections and transition areas are particularly problematic with regard to providing an efficient and permanent seal against the ingress of harmful or toxic substances. In order to improve wearer comfort while at the same time providing a high level of protection against harmful or toxic substances.In principle, air-permeable, permeable protective clothing systems are known in the prior art for the protection against harmful or toxic substances. These systems can be equipped with an adsorption filter layer, particularly to ensure protection against harmful or toxic substances. Due to the increased exchange of air and water or water vapor, such protective systems offer improved wearer comfort while generally providing good protection against toxic or harmful substances. With regard to such protective clothing, it is sometimes also the case that the adsorption material used, if any, is arranged on the side of the material facing the wearer or user when worn, so that any toxic or harmful substances that have previously penetrated the material can be absorbed by the adsorption material.
[0013] The aforementioned air-permeable protective clothing is often manufactured using different, particularly layered or arranged textile materials for function- or wear-specific training, with the corresponding layers or sections being permanently connected to one another by seams or seam connections. The seam connections used for this purpose generally run through the surface of the material, with the underlying protective material in its thickness or the layers used for this purpose often being completely encompassed or penetrated by a seam connection. However, in the case of high concentrations or large quantities of, in particular, liquid pollutants or toxic substances, such seam connections represent weak points with regard to the possible entry of these pollutants or toxic substances, since seams running through the cross-section of the material in particular can act as breakthrough or penetration points.Represent or form entry openings for harmful or toxic substances coming into contact with the protective clothing from the outside, for example in the form of drops or aerosols or the like, especially since the yarns or threads used to form the seam can conduct harmful or toxic substances through the material along the yarn or thread path. On this basis, particularly in the case of high (local) hazardous substance contamination, local breakthroughs of harmful or toxic substances can occur, which is associated with a corresponding risk to the wearer or user of the protective clothing, especially since the adsorption materials sometimes used can quickly or locally be overloaded at the underlying (seam) breakthrough points and the harmful or toxic substances that have penetrated or penetrated can spread on the inside and thus on the side of the protective clothing facing the wearer. In this context, the prior art can in principle provide for such seams orSeam joints are sealed to a certain extent with so-called seam sealing tapes. For this purpose, air- and water- or vapor-impermeable materials, such as polymer or plastic tapes, are generally used. These tapes are generally flat and are applied, for example, along the seam line to externally cover the seam joint. Adhesives are generally used for this purpose.
[0014] In this way, a certain degree of sealing can be provided against harmful or toxic substances acting on the material from the outside. However, such sealing concepts are inadequate because, for example, the adhesive bond can loosen, particularly when the material is subjected to mechanical or thermal stress, as often occurs during application or use, so that the previously covered seam is exposed again. In addition, harmful or toxic substances can bead up or flow off the seam sealing tape and be transferred in larger quantities to the adjacent (textile) material, thus overloading the latter. There are also production-related disadvantages because the air and water vapor impermeable seam sealing tape has to be applied subsequently, which requires separate production processes or steps. In addition, the stability and / orThe function of the seal and the protective material equipped with it may be reduced due to material incompatibilities or the like.
[0015] Furthermore, wearing comfort can be reduced because the seam sealing tapes used are often thick and inflexible, although these properties are further enhanced by the additional use of an adhesive. The washing and regeneration resistance of such systems is also inadequate because the associated high material stress can lead to the seam sealing tape becoming detached. In particular, it is difficult to carry out a visual inventory or wear inspection, particularly with regard to detecting minor detachments or similar of the seam sealing tape. Furthermore, air- or water-impermeable seam sealing tapes with the associated adhesive are not suitable for sealing orCovering seams used to connect (surface) sections made of different materials, since material incompatibilities can also arise here, particularly with regard to the adhesive used. Furthermore, the prior art uses textile reinforcement layers to connect inserts or sections of an outer textile layer of protective clothing in the seam area. In this context, WO 2019 / 129656 A1 and EP 3 731 939 A1, which belongs to the same patent family, relate to protective clothing with an air-permeable textile layer as the outer layer, based on a plurality of inserts or sections that are connected to one another by sewing, and with a textile layer as the filtering material layer.The protective clothing has a textile layer called a reinforcement layer in the area of a joint. This layer is both hydrophilic and oleophilic and is connected to two inserts or sections of the outer textile layer by the same seam. Due to the properties of the reinforcement layer, harmful or toxic substances penetrating the material or through the seam are specifically absorbed by the absorbent properties or high affinity of the reinforcement layer and passed on to the filtering material layer.
[0016] Thus, a concept is pursued whereby harmful or toxic substances that impact the protective clothing are specifically absorbed and transferred to the filtering material layer or to the adjacent material structures. However, this can be accompanied by rapid depletion or local overload of the adjacent materials, especially the filtering material layer, so that optimal protection is not always achieved. In particular, the material used as the reinforcement layer has no or at least insufficient adsorptive properties.
[0017] A particularly critical structure with regard to an unwanted breakthrough or penetration of harmful or toxic substances is the area of openings in protective clothing for the reception or passage of body parts of a wearer or user. The same applies to the transition area or contact area between different elements of protective clothing, for example a jacket on the one hand and trousers on the other, or a jacket or a sleeve of a jacket on the one hand and a glove on the other. The transition area of protective clothing for the sealing accommodation of other protective items or equipment, such as a respiratory mask in the field of vision, in particular the mask body of a respiratory mask, is also critical with regard to the penetration of harmful or toxic substances.In the aforementioned areas, non-textile, air- and water-impermeable surface materials are often used in sections, for example those based on polymers or plastics. The corresponding air- and water-impermeable or non-textile layers or sections are connected to the other textile layers or components of the protective clothing via seams. In the underlying connection area between textile components or layers on the one hand and non-textile, air-impermeable components or layers on the other, the risk of harmful or toxic substances entering or breaking through and / or passing through is particularly high, especially since the non-textile and air-impermeable layer itself is not designed to absorb harmful or toxic substances. Since harmful or toxic substances can adhere to the surface of the non-textile and air-impermeable component or layer.If the harmful or toxic substances are present in larger quantities or concentrations on the adjacent textile surface materials, particularly on the side facing the environment, there is an increased risk that the harmful or toxic substances can penetrate the material or protective clothing through the seam as a weak point and penetrate it.
[0018] Even an oleophobic and / or hydrophobic treatment, which is generally provided for in the prior art, in particular of the outer layer of textile sheet materials forming the (main) surfaces of protective clothing, cannot sufficiently counteract the penetration of harmful or toxic substances, in particular in the area of seam connections, and in particular with regard to the transition area between textile sheet material on the one hand and air- and water-impermeable sheet materials on the other.
[0019] In particular, hydrophobic or oleophobic treatment of textile surface materials can result in harmful or toxic substances beading up or flowing off the surface when they come into contact with the protective clothing and also affecting the corresponding seam areas, accumulating or agglomerating there, in addition to the harmful or toxic substances coming into contact with the non-textile or air- and water-impermeable sections or materials. This can lead to local overloading in the area of the corresponding seam connections between these materials and to a risk of harmful or toxic substances penetrating or seeping through these areas. In general, the seams or seam connections used to connect the respective surface materials in protective clothing represent weak points or locations with regard to the penetration or seeping through of harmful or toxic substances that come into contact with the protective clothing.Toxic substances represent a potential source of danger, as the surface materials forming the protective clothing are pierced or penetrated in the area of their connections by the thread or yarn forming the seam, thereby weakening the structure. Harmful or toxic substances that impact or act on the protective clothing from the outside can be conducted or transported inward along the thread or yarn through the material or the associated material arrangement, which is generally undesirable, especially since any existing adsorption layer in the area of the penetration point can also be locally overloaded.
[0020] Critical areas with regard to the penetration of harmful or toxic substances are particularly found in openings for the sealed insertion or passage of body parts (e.g., arm, leg, or foot openings) or for the sealed insertion of additional protective devices, such as respiratory masks (e.g., in conjunction with a field of vision opening), since these are penetrated or perforated by the thread or yarn forming the seam when sewn to the other surface materials of a protective clothing, creating corresponding weak points. As a result, harmful or toxic substances acting on the material can penetrate through the opening or along the thread or yarn into the protective clothing with comparatively little resistance and reach the wearer and / or user of the protective clothing.
[0021] This entails a corresponding risk of excessive exposure or exposure of a person in the danger zone to the pollutants or toxic substances in question.
[0022] Thus, textile seams for fastening non-textile and air- and water-impermeable surface materials do indeed ensure a certain degree of mechanical stability and flexibility. However, with regard to the unwanted penetration of harmful or toxic substances, corresponding breakthroughs or weak points, i.e. areas of weakness, are created. In this respect, the corresponding seam connections represent a weak point or impairment with regard to the protective properties against harmful or toxic substances acting on or impinging on the protective clothing. Overall, in order to provide effective sealing of the special transition area between textile components or layers on the one hand and non-textile and air- and water-impermeable components or layers on the other, the seam connection present there against harmful orToxic substances place particularly high demands on the product, taking into account the different material properties of the components or layers used on the one hand and the surface-specific contact of harmful or toxic substances, particularly in the seam area, on the other.
[0023] Against this background, there is therefore a great need in the state of the art to provide technical solutions for the effective sealing of the critical transition or connection area of protective clothing from textile and in particular air-permeable components or layers (in particular in the form of textile sheet materials) on the one hand and non-textile, air-impermeable components or layers (in particular in the form of non-textile sheet materials) on the other hand.
[0024] In this context, there is also a great need, in particular, to effectively protect the corresponding transition area or opening area in protective clothing, in which such a material combination or connection based on textile and in particular air-permeable surface materials on the one hand and non-textile and air-impermeable surface materials on the other hand, also in the seam connection area against the entry or breakthrough or penetration of harmful or toxic substances hitting the material.
[0025] In particular, there is also a great need in the state of the art to effectively protect the opening area of protective clothing (for example in the form of a hood or hooded jacket or a head cap or the like) in the edge area of the field of vision against the entry of harmful or toxic substances, also with regard to the specific transition or sealing area with a respiratory mask or a mask body of a relevant respiratory mask.
[0026] In this regard, the concepts available in the prior art often do not provide a satisfactory solution to the underlying problem, as previously mentioned. Against this background, the present invention is based on the object of providing an efficient technical solution for providing effective sealing of a seam connection in the transition or connection area of the sheet materials or layers of the components used in protective clothing, whereby the previously described disadvantages of the prior art are to be at least largely avoided or at least mitigated.
[0027] In this context, a particular object of the present invention is to provide protective clothing which has an ABC protection function (CBRN protection function) and which can preferably be used or employed for the civilian and / or military sector and which has improved sealing properties against harmful or toxic substances in the transition or connection area of the surface materials or layers which specifically form the protective clothing, wherein the transition or connection area is to be sealed against harmful or toxic substances, so that the entry of harmful or toxic substances in the transition or connection area with a corresponding contact of the wearer or user of such protective clothing is to be prevented.
[0028] Furthermore, a further object of the present invention is to protect the transition or connection area of a corresponding protective clothing, in which the respective surface materials or layers of the components used meet and are sewn or permanently connected by means of seams to form the protective clothing, in an efficient manner against the entry or penetration of harmful or toxic substances acting on or impacting the protective clothing or the transition or connection area, wherein in particular the entry or passage of such harmful or toxic substances through the seam or seam connection as such or the relevant seam area / section is to be prevented or at least reduced.
[0029] In this context, the area of protective clothing that serves to sealably accommodate or pass through a body section or to sealably accommodate or connect to other protective equipment, such as a respirator, should also be protected against the ingress or penetration of harmful or toxic substances, particularly with regard to the connection area of the underlying material components or surface materials of the protective clothing. In this regard, too, the ingress or penetration and / or breakthrough of harmful or toxic substances in the seams or seam connections / stitching used to connect the components should be prevented.
[0030] Furthermore, against this background, one object of the present invention is to efficiently protect the connecting area between textile, air-permeable sheet materials on the one hand and non-textile, air-impermeable sheet materials on the other hand from the ingress of harmful or toxic substances. This applies in particular against the background of a sealing function when protective clothing is worn or used to seal body parts of a wearer or user and / or other protective equipment, such as a respirator. The focus here is on the seams or stitching used in this regard, as they are used to connect the respective sheet materials.
[0031] Furthermore, a further object of the present invention is to provide a suitable seal for corresponding connecting areas of textile, air-permeable sheet materials on the one hand and non-textile, air-impermeable sheet materials on the other hand of ABC protective clothing or NBRC protective clothing against harmful or toxic substances that act externally on the protective clothing or the connecting area when the protective clothing is worn or in use. In this case, a high level of protection against the entry or penetration of the harmful or toxic substances in question should be ensured even in the presence of high quantities or concentrations of toxic substances or pollutants in the area where the sheet materials are connected.
[0032] In addition, a further object of the present invention is to provide corresponding sealing properties against harmful or toxic substances in the connection area in question, wherein the measures in this regard should not negatively affect the wearing comfort or the functional properties - for example with regard to the seal against other protective equipment, such as a respiratory mask. In addition, it should also be ensured overall that the underlying measures lead to a permanent and mechanically stable seal. In particular, a connection area underlying the clothing should be able to withstand strong mechanical stress during use or application while at the same time being highly flexible. In particular, a further object of the present invention is to provide a corresponding concept for preventing the entry or entry of harmful or toxic substances.The aim is to provide a seal to prevent the penetration of harmful or toxic substances into such a connecting area between textile, air-permeable surface materials on the one hand and non-textile, air-impermeable surface materials on the other, as is used or exists specifically for headgear or head hoods, for example in the form of a hood or balaclava, for the sealing transition or for the sealing reception of additional protective equipment in the form of a respiratory mask, in particular an ABC respiratory mask. In addition to preventing the entry or passage of harmful or toxic substances in the connecting area itself, a good seal against the respiratory mask should also be provided, while at the same time being highly adaptable, for example with regard to different types or designs of respiratory masks.
[0033] Furthermore, a further object of the present invention is to provide a general technical concept for sealing the underlying connection area or a seam connection between textile air-permeable sheet materials on the one hand and non-textile air-impermeable sheet materials on the other hand, which can be used for a variety of different designs of the underlying protective clothing, for example with regard to different transition or opening areas for receiving or passing through different body sections or for receiving different protective equipment or the like.
[0034] The measures used to solve the underlying problem according to the present invention should be optimized in terms of process and conception and be able to be implemented universally and should also enable the production of corresponding protective clothing on an industrial scale.
[0035] To achieve the above-described problem, the present invention thus proposes—according to a first aspect of the present invention—the inventive protective clothing with a protective function against chemical or biological or radioactive pollutants and / or poisons (warfare agents), in particular NBC protective clothing, preferably for civil or military purposes, according to patent claim 1; further advantageous developments and refinements of this aspect of the invention are the subject of the corresponding subsidiary claims and dependent claims relating to the inventive protective clothing.
[0036] A further subject matter of the present invention—according to a second aspect of the present invention—is the protective material according to the invention as such with a protective function against chemical, biological, or radioactive pollutants or toxins according to the relevant independent patent claim; further advantageous developments and refinements of this aspect of the invention are the subject matter of the corresponding subclaim.
[0037] A further subject matter of the present invention - according to a third aspect of the present invention - are also protective equipment or protective articles as well as filters and filter materials, which are each produced by producing the protective material according to the invention or have such a protective material, according to the relevant independent patent claims.
[0038] A further subject matter of the present invention - according to a fourth aspect of the present invention - are also the uses of the protective material according to the invention for the production of protective equipment or protective articles or for the production of filters and filter materials according to the relevant independent patent claims.
[0039] A further subject matter of the present invention—according to a fifth aspect of the present invention—also relates to the method for sealing a connecting region of textile layers on the one hand and a non-textile layer on the other hand, of protective clothing or a protective material according to the independent patent claim relating to the method according to the invention; further advantageous developments and refinements of this aspect of the invention are the subject matter of the relevant subclaim.
[0040] Finally, according to a sixth aspect of the present invention, the present invention also relates to the use of an additional adsorption filter material according to the relevant independent patent claims; further advantageous developments and refinements of this aspect of the invention are the subject of the corresponding subclaim. It goes without saying that in the following description of the present invention, such refinements, embodiments, advantages, examples, or the like which are explained below only for a single aspect of the invention—in order to avoid unnecessary repetition—will of course also apply accordingly to the remaining aspects of the invention, without the need for express mention.
[0041] Furthermore, it goes without saying that the following specifications of values, numbers, and ranges are not to be understood as limiting; it is self-evident to the person skilled in the art that, depending on the individual case or application, deviations from the specified ranges or specifications may occur without departing from the scope of the present invention.
[0042] Furthermore, all values or parameters mentioned below, or similar, can generally be determined using standardized or explicitly specified determination procedures or, alternatively, using determination or measurement methods familiar to those skilled in the art. Unless otherwise stated, the underlying values or parameters are determined under standard conditions (i.e., in particular, at a temperature of 20 °C and / or at a pressure of 1,013.25 hPa or 1.01325 bar).
[0043] Furthermore, it should be noted that with all relative or percentage quantities listed below, especially those based on weight, these quantities must be selected or combined by the person skilled in the art within the scope of the present invention in such a way that the total – optionally including other components or ingredients, in particular as defined below – always amounts to 100% or 100% by weight. However, this is self-evident to the person skilled in the art.
[0044] Furthermore, it is understood that a person skilled in the art may, depending on the application or the specific case, deviate from the values or ranges of the amounts or contents of the ingredients or components provided below, if necessary, without departing from the scope of the present invention. Furthermore, it goes without saying that individual aspects and embodiments of the present invention are also deemed to be disclosed in any combination with other aspects and embodiments of the present invention, and in particular, any combination of features and embodiments, as derived from the references to all patent claims, is also deemed to be comprehensively disclosed, with regard to all resulting combination possibilities.
[0045] In particular, with regard to the features characterizing the invention, any combination of these features is deemed to be disclosed, whereby embodiments of the various features with the same preference are preferred in their combination (e.g., amounts or ranges of amounts of the relevant ingredients with the same preference, or the like). Likewise, all other combinations (i.e., combinations based on different preferences or different levels of preference) are also disclosed.
[0046] With this in mind, the present invention is described and explained in more detail below, also with reference to drawings or figure representations showing preferred embodiments or exemplary embodiments.
[0047] The subject matter of the present invention - according to a first aspect of the present invention - is thus protective clothing with a protective function against chemical and / or biological and / or radioactive pollutants and / or poisons (warfare agents) ("ABC or CBRN protective function"), in particular ABC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, wherein the protective clothing
[0048] (a) a first, in particular flat and / or two-dimensional, layer in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric"), in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer and a textile carrier layer ("adsorption layer carrier"),
[0049] (b) a second, in particular flat and / or two-dimensional, layer in the form of a textile, air-permeable covering material ("top layer", "outer fabric") and (c) a third, in particular flat and / or two-dimensional, layer in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers (i.e. the first layer, the second layer and the third layer) are arranged and / or positioned overlapping one another in a connecting region and are connected, in particular sewn, to one another in the connecting region with a common seam forming a seam region ("layer connecting seam"), wherein at least in the seam region an additional multi-layer, in particular at least two-layer, textile, air-permeable, preferably strip-shaped orband-shaped adsorption filter material, in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area (or in the connection area), is arranged and / or provided and / or is present, wherein the additional adsorption filter material is connected, in particular sewn, to the layers (ie to the first layer, the second layer and the third layer) by means of the seam (the same seam).
[0050] A central idea of the present invention is therefore to be seen in particular in the fact that, for the special area of sewing or connecting the layers forming the protective clothing according to the invention, on the one hand, based on the first and second layers, each of which is in particular flat or two-dimensional in the form of respective textile, air-permeable (textile) materials, and on the other hand, the third layer, which is in the form of a non-textile and air-impermeable sheet material and is used in particular as a transition area for receiving or passing through a body section or for sealingly receiving or connecting further protective equipment, additionally a textile adsorption filter material is provided, which is multi-layered and air-permeable and preferably in the form of a strip and / or band.
[0051] In this context, the invention specifically provides for the additional adsorption filter material to be connected by means of the same seam that connects the aforementioned layers, namely the first, second, and third layers, in the seam or connection area. According to the invention, the first layer ("inner layer", "inner fabric"), the second layer ("top layer", "outer fabric"), and the third non-textile, air-impermeable layer in the form of the particularly polymer-based or plastic-based sheet material and the additional adsorption filter material are connected in the seam or connection area.
[0052] According to the present invention, the first, second, and third layers forming the protective clothing, on the one hand, and the additional adsorption filter material, on the other hand, are connected to one another by one and the same seam. Within the scope of the present invention, this is particularly the case that the additional adsorption filter material is, on the one hand, itself permeable to air and, on the other hand, is preferably strip-shaped or band-shaped, so that on this basis, the wearing comfort of the protective clothing according to the invention, while simultaneously providing a high level of protection against harmful or toxic substances, is not negatively affected, even in the seam area connecting the first, second, and third layers.
[0053] The applicant has discovered, quite surprisingly, that the targeted and purposeful use of a special adsorption filter material, namely in the form of a multi-layered, in particular at least two-layered, textile, air-permeable, preferably strip- or band-shaped, adsorption filter material as an additional layer in a seam area with an overlapping arrangement of the additional layers, leads to a significantly improved protective function against harmful or toxic substances. The overlap takes the form of a first layer, which is designed as a textile, air-permeable adsorption filter material ("inner layer", "inner fabric"), a second layer in the form of a textile, air-permeable covering material ("top layer", "outer fabric"), and a third layer in the form of a non-textile, in particular polymer-based or plastic-based, air-impermeable sheet material.The additional adsorption filter material arranged in the seam area is particularly strip-shaped or band-shaped and is connected to the aforementioned first, second, and third layers by the same seam. Harmful or toxic substances are effectively prevented from penetrating or passing through the protective clothing.
[0054] Within the scope of the present invention, a technical solution is therefore provided overall by means of which the transition area, which is particularly sensitive to the penetration of harmful or toxic substances, is effectively protected against harmful or toxic substances acting on the protective clothing in this area by means of a seam connection between air-permeable materials on the one hand and air-impermeable materials on the other hand in the form of the aforementioned first, second and third layers, thereby resulting in less stress or greater protection for a wearer of such protective clothing.
[0055] The present invention particularly aims to ensure that the additional adsorption filter material, particularly in the form of an additional strip or band, further protects the seam in question, which connects the first, second, and third layers of the protective clothing in the transition or seam area, against the penetration of harmful or toxic substances. This seam, which represents a particularly vulnerable point of penetration for harmful or toxic substances – particularly due to the phenomenon of "beading" or "agglomeration" of harmful or toxic substances hitting the protective clothing on the air-impermeable, non-textile third layer and the second (cover) layer, and the increased concentration or longer residence time of the harmful or toxic substances in the area of the connecting seam – is secured with appropriate resistance by the measure according to the invention.
[0056] The additional adsorption filter material absorbs any harmful or toxic substances that may penetrate the area of or through the seam, preventing them from penetrating further into the protective clothing or from penetrating it. In a corresponding manner, the first layer or inner layer in the form of the textile, air-permeable adsorption filter material is sustainably relieved of stress in the local seam or connection area, so that on this basis, too, the protective clothing according to the invention provides an overall high level of protection, since the inventive design prevents or suppresses (local) overloading of the first layer in the form of the adsorption filter material or the inner layer.
[0057] This is a key difference to the aforementioned prior art, in particular in the form of WO 2019 / 129656 A1 and EP 3 731 939 A1, according to which, within the scope of the present invention, no harmful substances are diverted to subsequent layers, which would otherwise be overloaded or concentrated in the subsequent layers, but rather any harmful or toxic substances penetrating through the seam are absorbed or rendered harmless by the additional layer used according to the invention due to its special adsorptive properties. This results in a further optimization of the protective effect provided in this regard within the scope of the present invention. By using a seam to join or sew the first, second orThe third layer and the additional adsorption material in the connection area ensure a mechanically resilient and permanent connection between the individual components, while simultaneously providing a high level of protection against the penetration of harmful or toxic substances. Using a common or identical seam to connect the aforementioned components also minimizes the number of weak points with regard to the potential ingress of harmful or toxic substances, as only a limited number of threads or yarns pass through the layers of the protective material, namely based on a single common seam. In other words, the third non-textile, polymer, or plastic-based layer is not excessively penetrated or "perforated," so to speak, by the thread or yarn guide.
[0058] A further advantage of the present invention is that, due to the targeted and purposeful use and arrangement of an additional, particularly strip- or band-shaped, adsorption filter material in the connection area, the use of (additional) sealing tapes, for example, rubber-based ones, can be avoided. In particular, the use of adhesives for connecting the underlying layers or components or for attaching sealing tapes can also be avoided.
[0059] In contrast, within the scope of the present invention, a high durability of the connection is also ensured, both with regard to the provision of a protective function against harmful or toxic substances and from a mechanical point of view with the high load-bearing capacity of the underlying (layer) connection.
[0060] In particular, within the scope of the present invention, undesirable delamination, such as can occur particularly with sealing tapes or the like applied by means of an adhesive bond, is avoided. Furthermore, due to the layers or components used and the special connection based on a common seam, the underlying connection area of the protective clothing according to the invention exhibits high flexibility or elasticity, which benefits wearer comfort and also enables good adaptability to corresponding body parts of the wearer or to other protective items, such as respiratory masks. Accordingly, this excellent adaptability also provides further improved protection against harmful or toxic substances.
[0061] Due to the high mechanical stability, the protective clothing according to the invention can also be subjected to appropriate regeneration treatments (e.g. washing treatments) without the protective function or the mechanical stability of the underlying compound being negatively affected in the long term.
[0062] Furthermore, the present invention is associated with assembly and production-specific advantages, since the additional adsorption material can be directly incorporated or sewn during the production of the connection between the underlying layers, based on a common seam connection. This also eliminates the need for subsequent fixing, thereby reducing production steps. Furthermore, the invention can provide for the additional adsorption material to be made essentially of the same material as the first layer, so that, for example, corresponding cutting or assembly remnants of the material of the first layer can also be used for the additional adsorption material, which is particularly strip-shaped. This is associated with corresponding material utilization and thus with improved process economy.
[0063] The term "seam" used in the context of the present invention is to be understood in particular as a connection of the underlying layers or materials by sewing. For the seam, at least one yarn or thread is generally used, which is repeatedly passed through the sewing material in the form of the respective layers and the additional adsorption filter material, whereby the yarn or thread is connected or intertwined with the sewing material or the respective layers and the additional adsorption filter material. Thus, in the context of the seam connecting the first, second, or third layer and the additional adsorption filter material ("layer connection seam"), it is in particular a yarn- or thread-based seam. Accordingly, the seam in question is not a threadless connection or an adhesive seam or welded seam.
[0064] The use or formation of a corresponding seam ("layer connecting seam") for the joint connection of the first, second and third layers as well as the additional adsorption filter material is accompanied by a high level of stability or resilience and flexibility, so that a connection of the respective layers as well as the additional adsorption filter material that can withstand high force or mechanical loads while simultaneously providing a high level of protection against harmful or toxic substances is provided within the scope of the present invention.
[0065] The term "seam region," as used in the context of the present invention, is to be understood in this context in particular as representing a section or region of the connecting region with the overlapping arrangement or positioning of the layers, which is formed by the formed common seam with the corresponding seam-like engagement or connection of the first, second, and third layers as well as the additional adsorption filter material. The seam region thus refers in particular to the region of the connecting region in which the underlying layers and the additional adsorption filter material are connected or engaged by the common seam.
[0066] In this context, the terms "yarn" and "thread" are used synonymously within the scope of the present invention, with the aforementioned terms generally representing a collective term for all linear textile structures. In this context, a yarn or thread can comprise one or more fibers or filaments.
[0067] The term "connecting region" as used in the context of the present invention represents in particular the transition region between textile layers, in particular the first layer and the second layer of the protective clothing according to the invention, on the one hand, and a non-textile and in particular air-impermeable layer, in particular the third layer of the protective clothing according to the invention, on the other hand, i.e. in particular the region of the fixed or permanent connection of the layers in question. The connecting region is located or present in particular in the region of openings for the sealing reception or passage of body parts of a wearer or user or for the sealing reception or sealing contact with further protective equipment, such as a respiratory mask. Thus, the connecting region also defines a transition from the protective clothing to body parts of a wearer or user (i.e. in the wearing or(condition of use) or with respect to other protective items, such as a respirator. In particular, the connecting area within a headgear can define a field of vision or a field of vision opening for, in particular, sealingly accommodating a respirator.
[0068] The term "sealing" or "sealing", as used in the invention with regard to the protective clothing and the underlying connection area, is to be understood very broadly within the scope of the present invention and relates in particular to the prevention or at least the lasting reduction of the entry or penetration or permeation of gases, vapors, aerosols or liquids, in particular of toxic or harmful substances, i.e. hazardous substances, warfare agents or the like.
[0069] Sealing is to be understood in particular with reference to penetration through the protective clothing or the corresponding connecting area, in particular the seam area present in the connecting area in particular, and thus in particular to a transition area between textile components or layers on the one hand and a non-textile component or layer on the other, e.g., an opening area for receiving or connecting to additional protective equipment, such as a respiratory mask, or body parts of a wearer or user. Furthermore, the term "sealing" or "sealing" can also refer, for example, to the connection to or receiving of protective equipment, such as a respiratory mask, or body parts of a wearer or user, in particular through or by means of the non-textile third (sealing) layer.
[0070] In the following, the present invention is described with reference to preferred embodiments and illustrative drawings or figures. The relevant statements apply to all aspects of the invention and the corresponding preferred embodiments or configurations of the present invention are in no way limiting. Further advantages, properties, aspects, and features of the present invention are also shown within the scope of the figure description. The figures show:
[0071] Fig. 1 is a schematic cross-sectional view showing the arrangement and connection of the layers forming the basis of the protective clothing according to the invention in the connection area with the arrangement of the additional adsorption filter material according to a first embodiment of the invention, according to which the third layer with the additional adsorption filter material is arranged between the first layer and the second layer, wherein the additional adsorption filter material is positioned between the third layer and the first layer and thus, so to speak, below the third layer; furthermore, the enlarged detail shows an embodiment of the invention with a three-layer structure of the first layer in the form of the textile, air-permeable adsorption filter material or the inner layer; Fig.1 also shows the inventive concept, according to which the first, second and third layers are connected in the connection area with the additional adsorption filter material with a common seam forming a seam area;.
[0072] Fig. 2 shows a further schematic cross-sectional view of the protective clothing according to the invention with the relevant layer arrangement and design of the connecting region, according to which, in the connecting region, the third layer with the additional adsorption filter material is arranged on the surface or side of the second layer facing away from the first layer, and according to which the additional adsorption filter material is arranged between the third layer and the second layer and thus, so to speak, below the third layer. Fig. 2 also illustrates that, in the connecting region, the corresponding layers and the additional adsorption filter material are connected by a common seam.
[0073] Fig. 3 shows yet another schematic cross-sectional view of the protective clothing according to the invention with the layer arrangement and formation of the connecting region according to yet another embodiment, according to which the third layer is arranged on the surface or side of the second layer facing away from the first layer, and according to which the additional adsorption filter material is positioned on the surface or side of the third layer facing away from the second layer and thus, so to speak, on the outside or above the third layer. Fig. 3 also shows that the first, second, and third layers, as well as the additional adsorption filter material, are connected in the connecting region with a common seam.
[0074] Fig. 4 is yet another schematic cross-sectional view of the protective clothing according to the invention with the connecting region and the related layer arrangement, according to which the third layer with the additional adsorption filter material is arranged between the first layer and the second layer, wherein the additional adsorption filter material is positioned between the third layer and the first layer and thus, so to speak, below the third layer; Fig. 4 also illustrates an embodiment according to the invention, according to which the first layer and the second layer are each folded over in the direction of the third layer; moreover, Fig. 4 shows that the first, second and third layers as well as the additional adsorption filter material are connected in the connecting region with a common seam, wherein the first layer is only covered by the common seam in the folded over region;
[0075] Fig. 5 is a further cross-sectional view of the protective clothing according to the invention with the connecting region and the related layer arrangement, according to which the third layer with the additional adsorption filter material is arranged on the surface or side of the second layer facing away from the first layer and according to which the additional adsorption filter material is positioned between the third layer and the second layer and thus, so to speak, below the third layer and according to which the first layer and the second layer are folded away from the third layer and are connected to the third layer and the additional adsorption filter material by a common seam;
[0076] Fig. 6A is yet another cross-sectional view of the protective clothing according to the invention with the connecting region and the related layer arrangement, according to which the third layer with the additional adsorption filter material is arranged between the first layer and the second layer, and according to which the additional adsorption filter material is positioned between the third layer and the first layer and thus, so to speak, underneath the third layer, and according to which the first layer and the second layer are each folded over in the connecting region in the direction of the third layer; Fig. 6A also shows a preferred embodiment according to the invention, according to which, for this case, the common seam which connects the first, second and third layers as well as the additional adsorption filter material to one another is designed such that they only lie (directly) on the third layer or on the additional adsorption filter material, and also on the folded over region orSection of the first layer or the second layer and thereby connects the first or second layer to the third layer and the additional adsorption filter material, wherein the non-folded area of the first layer or the second layer in the connection area is not covered by the common seam and the seam is, so to speak, additionally covered by these areas or on the top and bottom sides; Fig. 6A also shows a further embodiment which is independent of the aforementioned design, namely that the additional adsorption filter material is hemmed in its edge area or provided with an edge reinforcement or topstitching seam or finishing seam, specifically as far as the edge of the additional adsorption filter material oriented towards the main extension of the third layer is concerned;.
[0077] Fig. 6B is yet another cross-sectional view based on Fig. 6A, with the proviso that the connecting region of the protective clothing according to the invention with the respective layer arrangement is provided with an additional securing and / or stabilizing seam, in particular a topstitching seam, which encompasses all layers as well as the additional adsorption filter material;
[0078] Fig. 6C is yet another cross-sectional view based on Fig. 6A, with the proviso that the edge of the additional adsorption filter material oriented toward the main extension of the first layer or the second layer is (also) hemmed or provided with a (further or second) edge reinforcement or topstitching seam or finishing seam;
[0079] Fig. 7 shows schematic enlarged sections of the first layer with respective configurations of the layer structure of the first layer, according to which the first layer can have a two-, three-, or four-layer structure; Fig. 8 shows schematic enlarged sections of the second layer with respective configurations of the layer structure of the second layer, according to which the second layer can have a two-, three-, or four-layer structure;
[0080] Fig. 9A is a schematic side view of a protective clothing according to the invention with a corresponding hood in the worn or used state with the reception or sealing connection of a respiratory mask in the field of vision area and the corresponding schematic representation of the connection area of the protective clothing according to the invention;
[0081] Fig. 9B is an enlarged cross-sectional view along line I shown in Fig. 1 with the schematic view and structure of the connection area according to an embodiment of the invention (corresponding to Fig. 1 ) of the protective clothing according to the invention and the sealing fit of the third layer against a respiratory mask;
[0082] Fig. 9C is an enlarged cross-sectional view along line I shown in Fig. 1 with the schematic view and structure of the connection area according to a further embodiment of the invention (corresponding to Fig. 4) of the protective clothing according to the invention and the sealing fit of the third layer against a respiratory mask.
[0083] The figures according to Fig. 1 to Fig. 9A and 9B particularly illustrate the first aspect of the present invention, according to which, according to the invention, a protective clothing 1 with a protective function against chemical and / or biological and / or radioactive pollutants and / or poisons (warfare agents) ("ABC or CBRN protective function"), in particular ABC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, is proposed, wherein the protective clothing 1
[0084] (a) a first, in particular flat and / or two-dimensional, layer 2 in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer 2a and a textile carrier layer 2b ("adsorption layer carrier"),
[0085] (b) a second, in particular flat and / or two-dimensional, layer 3 in the form of a textile air-permeable covering material ("top layer", "outer fabric") and
[0086] (c) a third, in particular flat and / or two-dimensional, layer 4 in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers 2, 3, 4 are arranged and / or positioned overlapping one another in a connecting region 5 and are connected, in particular sewn, to one another in the connecting region 5 with a common seam 7 forming a seam region 6 ("layer connecting seam"), wherein at least in the seam region 6 an additional multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped and / or band-shaped, adsorption filter material 8,in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area 6 and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area 6 (or in the connecting area 5), wherein the additional adsorption filter material 8 is connected, in particular sewn, to the layers 2, 3, 4 by means of the seam 7 (the same seam 7).
[0087] According to the invention, the seam 7 is produced or formed by sewing, in particular using at least one yarn and / or thread. This ensures a resilient and thus stable connection between the respective layers or the additional adsorption filter material.
[0088] In particular, the seam 7 can be produced or formed by repeatedly guiding at least one yarn or thread through the layers 2, 3, 4 and the additional adsorption filter material 8.
[0089] In general, it can be provided according to the invention that the yarn or thread of the seam 7 comprises or consists of a material, in particular textile fiber material, from the group of natural materials and synthetic materials, preferably selected from the group of cotton; wool; linen; polyesters; polyolefins, polyvinyl chlorides; polyvinylidene chlorides; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; polyacrylic; polyamides; polyvinyl alcohols; polyurethanes; polyvinyl esters; viscoses; and mixtures or combinations thereof.
[0090] According to the invention, in this context, the yarn or thread of the seam 7 can be designed as a monofilament yarn or as a multifilament yarn.
[0091] The multifilament yarn can be based on corresponding single filaments.
[0092] The special seam design, as provided for in the present invention, makes it possible to avoid, in particular, the use of adhesives to connect the respective components in the connection area or to form weld seams or the like. In particular, this avoids the disadvantages associated with the use of adhesives or weld seams, such as insufficient flexibility or elasticity, as well as sometimes insufficient stability, for example, due to material incompatibilities or the like.
[0093] Against this background, it is therefore provided according to the invention in particular that the seam 7 is not designed as an adhesive seam (adhesive connection or adhesive connection seam) or at least substantially has no adhesive or is not formed by gluing the layers 2, 3, 4 and the additional adsorption filter material 8.
[0094] Likewise, it is particularly provided according to the invention that the seam 7 is not designed as a weld seam or is not formed by welding the layers 2, 3, 4 and the additional adsorption filter material 8.
[0095] In this context, the invention is particularly such that, through the targeted and purposeful use with the special arrangement of the additional adsorption filter material 8 when the protective clothing 1 is worn or in use, harmful or toxic substances acting on the connection or seam area 5, 6 can be prevented from entering or passing through the protective clothing 1 according to the invention by being effectively absorbed by the additional adsorption filter material 8. Thus, according to the invention, further protection is also ensured, particularly in the underlying connection or seam area 5, 6, with the fixation of the non-textile and in particular polymer- or plastic-based third layer 4, which is penetrated or punctured by the seam-forming yarn or thread, which represents a vulnerable entry point for harmful or toxic substances.
[0096] According to the invention, a connection of the respective layers 2, 3, 4 or components is thus provided which is both mechanically stable and capable of withstanding force and which is also protected against the entry or passage of harmful or toxic substances.
[0097] According to a particularly preferred embodiment of the invention, the additional adsorption filter material 8 comprises an adsorption layer 8a and a textile carrier layer 8b, as particularly illustrated in Fig. 8. Furthermore, the additional adsorption filter material 8 may also comprise further layers, as defined in detail below (see in particular Fig. 8 A2, B2, C2, and D2).
[0098] As illustrated in particular in Fig. 9A and also in Fig. 1 to Fig. 6A or Fig. 6B, according to the invention it is particularly such that the additional adsorption filter material 8 is designed flat or two-dimensionally, in particular in the form of a strip and / or band or strip-shaped and / or band-shaped.
[0099] In this context, the additional adsorption filter material 8 can have a width b in the range from 2 mm to 50 mm, in particular in the range from 4 mm to 35 mm, preferably in the range from 6 mm to 30 mm, preferably in the range from 8 mm to 25 mm, particularly preferably in the range from 10 mm to 20 mm.
[0100] Due to the strip-shaped or band-shaped design of the additional adsorption filter material 8, a corresponding positioning or arrangement of the additional adsorption filter material 8 along the course of the common seam 7 can be achieved with optimized material use (cf. e.g. Fig. 9A), equally accompanied by the guarantee of a corresponding protective function against the entry or passage of harmful or toxic substances along the seam 7. According to the invention, it is therefore provided in particular that the additional adsorption filter material 8 is designed in the form of a strip and / or band or strip-shaped and / or band-shaped and is arranged along the seam 7, in particular along the seam course of the seam 7 (cf. e.g. Fig. 9A or 9B).
[0101] According to the invention, the seam 7 is arranged or configured in particular such that the seam 7 engages, in particular penetrates and / or passes through, the additional adsorption filter material 8. This ensures, in particular, that harmful or toxic substances penetrating through the seam 7 can be directly absorbed by the additional adsorption filter material 8, so that they do not penetrate the protective clothing 1. This also results in a corresponding reduction in load, in particular on the first layer 2 in the form of the underlying adsorption filter material 8 or the corresponding inner layer.
[0102] In a corresponding manner, according to the invention, the seam 7 also encompasses the first layer 2, the second layer 3 and the third layer 4, in particular penetrating or passing through each of them.
[0103] As can be seen in particular from Fig. 9A and 9B, it is provided in particular according to the invention that the additional adsorption filter material 8 is arranged and / or positioned at least substantially completely along the seam 7, in particular along the seam course of the seam 7, and / or extends at least substantially completely along the seam 7, in particular along the seam course of the seam 7.
[0104] In particular, the invention provides that the seam 7 is connected to the additional adsorption filter material 8 along at least substantially its entire seam length and / or encompasses the additional adsorption filter material 8. This ensures the most comprehensive possible protective function by the additional adsorption filter material 8.
[0105] As illustrated, for example, in Fig. 1 to Fig. 6A or Fig. 6B as well as in Figs. 9A and 9B, it is particularly provided according to the invention that the additional adsorption filter material 8 extends on both sides along the seam 7, in particular on both sides of the seam path of the seam 7. Furthermore, it can be provided according to the invention that the opposite edges of the additional adsorption filter material 8 running and / or arranged along the seam 7, in particular along the seam path of the seam 7, are each spaced from the seam 7, in particular independently of one another. In other words, it is particularly provided according to the invention that the seam 7 is flanked along its path, in particular on both sides, by the additional adsorption filter material 8.
[0106] This means that harmful or toxic substances penetrating along the seam 7 can be absorbed particularly effectively by the additional adsorption filter material 8. In particular, this results in a uniform distribution of any penetrating harmful or toxic substances in the additional adsorption filter material 8, so that the adjacent layers, in particular the first layer 2, are also sustainably relieved of contamination with harmful and toxic substances, accompanied by overall improved protection.
[0107] In this context, it can be provided in particular that the opposite edges of the additional adsorption filter material 8 running and / or arranged along the seam 7, in particular along the seam profile of the seam 7, in particular independently of one another, each have a distance from the seam 7, preferably perpendicular to the seam profile of the seam 7, of at least 1 mm, in particular at least 2 mm, preferably at least
[0108] 3 mm, preferably at least 4 mm, particularly preferably at least 5 mm.
[0109] Likewise, it can be provided according to the invention that the opposite edges of the additional adsorption filter material 8, which run and / or are arranged along the seam 7, in particular along the seam profile of the seam 7, in particular independently of one another, each have a distance from the seam 7, preferably perpendicular to the seam profile of the seam 7, in the range from 1 mm to 20 mm, in particular in the range from 2 mm to 17.5 mm, preferably in the range from 3 mm to 15 mm, preferably in the range from
[0110] 4 mm to 12.5 mm, particularly preferably in the range of 5 mm to 10 mm.
[0111] In this context, it has equally proven advantageous within the scope of the present invention that the opposite edges of the additional adsorption filter material 8 running and / or arranged along the seam 7, in particular along the seam profile of the seam 7, preferably perpendicular to the seam profile of the seam 7, have at least substantially an identical distance from the seam 7. In particular, it can be provided according to the invention that the seam 7 runs along the longitudinal profile of the additional adsorption filter material 8 through the additional adsorption filter material 8 and / or is arranged and / or positioned at least substantially centrally to the additional adsorption filter material 8. This can also be seen illustratively in Fig. 1 to Fig. 6A, Fig. 6B and Figs. 9A and 9B.
[0112] In general, it can equally be provided according to the invention that the additional adsorption filter material 8 is arranged or provided in the seam region 6 and also in the connection region 5. In particular, the additional adsorption filter material 8 can also extend into the connection region 5, as illustrated, for example, in Fig. 1 to Fig. 6A / B. By this measure according to the invention, the protection against harmful or toxic substances can be further increased or adapted. In particular, by adapting the surface area of the additional adsorption filter material 8, its adsorption capacity can be increased or tailored.
[0113] In this context, the additional adsorption filter material 8 can cover the connecting area 5 at least partially and / or in sections, preferably at least substantially completely.
[0114] In general, it can be provided according to the invention that the additional adsorption filter material 8 also extends beyond the connecting region 5, in particular at least on one side or on both sides.
[0115] As shown in particular in Fig. 1 to Fig. 6A / B, it is particularly provided according to the invention that the layers 2, 3, 4 and the additional adsorption filter material 8 are arranged or positioned in a stack in the connecting region 5, in particular in the seam region 6. According to the invention, this can in particular be such that the layers 2, 3, 4 are arranged overlapping one another in the connecting region 5, in particular in the seam region 6. According to the invention, the arrangement of the respective layers in the form of the first layer 2, the second layer 3 and the third layer 4 on the one hand and of the additional adsorption filter material 8 on the other hand can vary, in particular against the background of the intended use of the protective clothing 1 according to the invention or the concrete functional design of the connecting region with the third layer 4 as a sealing element against body sections of a wearer orUser or other equipment, such as an ABC protective mask (see, for example, Fig. 9A and Fig. 9B). In general, within the scope of the present invention, it can be provided in this context that the additional adsorption filter material 8 in the connection region 5, in particular in the seam region 6, is in direct contact with the third layer 4 and / or directly adjoins and / or rests on the third layer 4, as indicated, for example, in Fig. 1 or Fig. 3. The term "directly" is to be understood in particular to mean that no further layers or the additional adsorption filter material 8 is arranged or positioned between the respective referenced layers.
[0116] In particular, in this context, the seam 7 can connect the additional adsorption filter material 8 to the third layer 4 directly (ie without further intermediate layers), as shown, for example, equally in Fig. 1 and Fig. 2.
[0117] In general, the respective contact surfaces refer to the underlying sections of the respective main extension planes of the mentioned layers 2, 3, 4 or the additional adsorption filter material 8.
[0118] In general, with regard to the arrangement or positioning of the layers 2, 3, 4 or of the additional adsorption filter material 8, it can be provided according to the invention that in the connection region 5, in particular in the seam region 6, the additional adsorption filter material 8 is arranged and / or positioned in the wearing and / or use state of the protective clothing 1 on the surface or side facing the wearer and / or user of the protective clothing 1 or the surface or side facing away from it, preferably on the surface or side of the third layer 4 facing the wearer and / or user of the protective clothing 1.
[0119] In particular, in the connecting region 5, in particular in the seam region 6, the additional adsorption filter material 8 can be arranged and / or positioned in the wearing and / or use state of the protective clothing 1 on the surface or side facing away from a source of harmful and / or toxic substances or on the surface or side facing towards a source of harmful and / or toxic substances, preferably on the surface or side facing away from a source of harmful and / or toxic substances, of the third layer 4.
[0120] In other words, according to the invention, the additional adsorption filter material 8 is arranged or positioned, so to speak, behind or downstream of a source of pollutants or toxins, or facing the user or wearer, with respect to the third layer 3. As a result, pollutants or toxins penetrating the third layer 4 in the form of the air-impermeable plastic or rubber material, for example, in the area of the seam perforations, are effectively absorbed by the additional adsorption filter material 8 without premature depletion.
[0121] The respective embodiments with the specific arrangement or positioning of the layers 2, 3, 4 or the additional adsorption filter material 8 in the connecting region 5 or in the seam region 6 are discussed below.
[0122] According to a first embodiment preferred according to the invention (as also referred to in Fig. 1), it can generally be provided according to the invention that, in particular in the seam region 6, the additional adsorption filter material 8, in particular with its surface and / or side facing away from the third layer 4, is in direct contact with the first layer 2 and / or lies directly against and / or on the first layer 2.
[0123] In particular, the seam 7 can directly connect the additional adsorption filter material 8 to the first layer 2.
[0124] In this context, Fig. 1 also illustrates the preferred embodiment according to the invention, according to which in the connecting region 5, in particular in the seam region 6, the second layer 3 on the surface and / or side of the third layer 4 facing away from the additional adsorption filter material 8 is in direct contact with the third layer 4 and / or directly adjoins and / or rests on the third layer 4.
[0125] In this context, it can also be provided in particular that the seam 7 directly connects the second layer 3 to the third layer 4.
[0126] In addition, as also illustrated in Fig. 1, it can be provided according to the invention that in the connecting region 5, in particular in the seam region 6, the third layer 4 with the additional adsorption filter material 8 is arranged or positioned between the first layer 2 and the second layer 3.
[0127] According to this embodiment of the present invention, which is generally shown in particular in Fig. 1, it can also be provided that in the connection area 5, in particular in the seam area 6, the first layer 2 is arranged or positioned in the wearing and / or use state of the protective clothing 1 on the side of the protective clothing 1 facing the wearer and / or user of the protective clothing 1 ("inside of the protective clothing 1").
[0128] Likewise, it can be provided in this regard that in the connecting region 5, in particular in the seam region 6, the second layer 3 is arranged or positioned in the wearing and / or use state of the protective clothing 1 on the side of the protective clothing 1 facing away from the wearer and / or user of the protective clothing 1 ("outer side of the protective clothing 1").
[0129] In this context, it can be provided according to the invention in particular that in the connection area 5, in particular in the seam area 6, the first layer 2 is arranged or positioned in the wearing and / or use state of the protective clothing 1 on the side of the protective clothing 1 facing away from a source of harmful and / or toxic substances.
[0130] In this regard, it can also be provided that in the connection area 5, in particular in the seam area 6, the second layer 3 is arranged or positioned in the wearing and / or application state of the protective clothing 1 on the side of the protective clothing 1 facing a source of harmful and / or toxic substances.
[0131] The preferred embodiment of the invention, as shown in particular in Fig. 1, is described in more detail below:
[0132] - Thus, Fig. 1 specifically shows the preferred embodiment according to the invention, according to which the additional adsorption filter material 8 is arranged or positioned between the third layer 4 and the first layer 2 in the connecting region 5, in particular in the seam region 6.
[0133] - In this context, it can be provided in particular that the additional adsorption filter material 8 is in direct contact with the third layer 4, in particular lies directly against or on the third layer 4.
[0134] - In addition, the additional adsorption filter material 8 can be in direct contact with the third layer 4 and, in particular opposite the third layer 4, with the first layer 2, in particular directly against the third layer 4 and, in particular opposite the third layer 4, against the first layer 2. - Fig. 1 also shows specifically that in the connection region 5, in particular in the seam region 6, the second layer 3 can be arranged or positioned on the surface or side of the third layer 4 opposite the additional adsorption filter material 8.
[0135] - In particular, in the connecting region 5, in particular in the seam region 6, the second layer 3 can be in direct contact with the third layer 4, preferably directly against or on the third layer 4, in particular on the surface or side of the third layer 4 opposite the additional adsorption filter material 8, as similarly specifically stated in Fig. 1.
[0136] - Fig. 1 also shows in particular that in the connecting region 5, in particular in the seam region 6, the layers 2, 3, 4 and the additional adsorption filter material 8 can be arranged or positioned in the following sequence: (i) first layer 2, (ii) additional adsorption filter material 8, (iii) third layer 4, (iv) second layer 3.
[0137] - In this context, the additional adsorption filter material 8 can be arranged or positioned on the surface or side of the third layer 4 facing a wearer and / or user of the protective clothing 1 when the protective clothing 1 is worn and / or used.
[0138] - In this context, the first layer 2 can also be arranged or positioned on the side (inside) of the protective clothing 1 facing a wearer and / or user of the protective clothing 1 in the wearing and / or use state of the protective clothing 1.
[0139] - Furthermore, the second layer 3 can be arranged or positioned on the side (outside) of the protective clothing 1 facing away from a wearer and / or user of the protective clothing 1 when the protective clothing 1 is in the wearing and / or use state.
[0140] According to a further embodiment of the invention, as illustrated in particular in Fig. 2, it can be provided according to the invention that in the connecting region 5, in particular in the seam region 6, the additional adsorption filter material 8, in particular with its surface and / or side facing away from the third layer 4, is in direct contact with the second layer 3 and / or directly abuts or rests on the second layer 3. In this context, the seam 7 can directly connect the additional adsorption filter material 8 to the second layer 3.
[0141] Fig. 2 also generally illustrates that in the connecting region 5, in particular in the seam region 6, the second layer 3 with the surface and / or side of the second layer 3 facing away from the additional adsorption filter material 8 is in direct contact with the first layer 2 and / or can lie directly against or on the first layer 2.
[0142] In particular, the seam 7 can directly connect the second layer 3 to the first layer 2.
[0143] Fig. 2 also illustrates that in the connecting region 5, in particular in the seam region 6, the third layer 4 with the additional adsorption filter material 8 is arranged or positioned on the second layer 3, in particular wherein the additional adsorption filter material 8 can be arranged or positioned between the third layer 4 and the second layer 3.
[0144] In this context, according to the present embodiment, it can be provided that in the connection area 5, in particular in the seam area 6, the first layer 2 is arranged or positioned in the wearing and / or use state of the protective clothing 1 on the side of the protective clothing 1 facing the wearer and / or user of the protective clothing 1 ("inside of the protective clothing 1").
[0145] In addition, in the connecting region 5, in particular in the seam region 6, the third layer 4 can be arranged and / or positioned in the wearing and / or use state of the protective clothing 1 on the side of the protective clothing 1 facing away from the wearer and / or user of the protective clothing 1 ("outer side of the protective clothing 1"), in particular wherein the additional adsorption filter material 8 is arranged or positioned between the third layer 4 and the second layer 3 ("intermediate layer").
[0146] In particular, it can be provided in this context that in the connecting region 5, in particular in the seam region 6, the first layer 2 is arranged or positioned on the side of the protective clothing 1 facing away from a source of harmful and / or toxic substances in the protective clothing 1 when the protective clothing 1 is worn and / or used. Furthermore, according to the present embodiment, in the connecting region 5, in particular in the seam region 6, the third layer 4 can be arranged or positioned on the side of the protective clothing 1 facing away from a source of harmful and / or toxic substances in the protective clothing 1 when the protective clothing 1 is worn and / or used.
[0147] The following is a detailed description of the embodiment of the invention, particularly shown in Fig. 2, with the relevant layer arrangement and positioning:
[0148] - In particular, according to the invention, according to the present embodiment, it can be provided that, as illustrated in Fig. 2, in the connecting region 5, in particular in the seam region 6, the additional adsorption filter material 8 is arranged between the third layer 4 and the second layer 3.
[0149] - In this context, the additional adsorption filter material 8 can be in direct contact with the third layer 4, in particular can be directly adjacent to or resting on the third layer 4.
[0150] In addition, the additional adsorption filter material 8 can be in direct contact with the third layer 4 and, in particular opposite the third layer 4, with the second layer 3, in particular directly against or rest on the third layer 4 and, in particular opposite the third layer 4, on the second layer 3.
[0151] - As also specifically shown in Fig. 2, it can be provided according to the present embodiment of the present invention that in the connecting region 5, in particular in the seam region 6, the first layer 2 is arranged or positioned on the surface or side of the second layer 3 opposite the additional adsorption filter material 8.
[0152] - In this regard, in the connecting region 5, in particular in the seam region 6, the first layer 2 can be in direct contact with the second layer 3, preferably directly against or resting on the second layer 3, in particular on the surface or side of the second layer 3 opposite the additional adsorption filter material 8. - Fig. 2 also specifically illustrates that in the connecting region 5, in particular in the seam region 6, the layers 2, 3, 4 and the additional adsorption filter material 8 can be arranged or positioned in the following sequence: (i) first layer 2, (ii) second layer 3, (iii) additional adsorption filter material 8, (iv) third layer 4.
[0153] - In this context, it can be provided in particular that the additional adsorption filter material 8 is arranged or positioned on the surface or side of the third layer 4 facing a wearer and / or user of the protective clothing 1 in the wearing and / or use state of the protective clothing 1.
[0154] - In this regard, it can also be provided that the first layer 2 is arranged or positioned on the side (inside) of the protective clothing 1 facing a wearer and / or user of the protective clothing 1 when the protective clothing 1 is in the wearing and / or use state.
[0155] - In particular, it can be provided in this regard that the third layer 4 is arranged or positioned on the side (outside) of the protective clothing 1 facing away from a wearer and / or user of the protective clothing 1 in the wearing and / or use state of the protective clothing 1.
[0156] According to a further embodiment which is less preferred according to the invention, it can also be provided, as illustrated in particular in Fig. 3, that in the connecting region 5, in particular in the seam region 6, the additional adsorption filter material 8 is not connected to a further layer on its surface and / or side facing away from the third layer 4 and / or is not in contact with a further layer.
[0157] In particular, in this context, the surface and / or side of the additional adsorption filter material 8 facing away from the third layer 4 can be free and / or uncovered.
[0158] In addition, the seam 7 can directly connect the additional adsorption filter material 8 to the second layer 3, as similarly shown in Fig. 3. As a result, the perforations in the third layer 4 caused by the seam 7 are further protected against the ingress of harmful or toxic substances. In this context, the additional adsorption filter material 8 thus functions in particular as an (outer) cover layer for the third layer 4. Fig. 3 similarly illustrates the embodiment according to the invention, according to which, in the connecting region 5, in particular in the seam region 6, the third layer 4, with its surface and / or side facing away from the additional adsorption filter material 8, is in direct contact with the second layer 3 or directly abuts or rests against the second layer 3.
[0159] In this context, the seam 7 can directly connect the third layer 4 to the second layer 3.
[0160] According to this embodiment of the present invention, which is shown in particular in Fig. 3, it can also be provided that in the connecting region 5, in particular in the seam region 6, the third layer 4 with the additional adsorption filter material 8 is arranged or positioned on the second layer 3, in particular wherein the additional adsorption filter material 8 is arranged or positioned on the surface and / or side of the third layer 4 facing away from the second layer 3.
[0161] In particular, in the connection area 5, in particular in the seam area 6, the first layer 2 can face the wearer and / or user of the protective clothing 1 in the wearing and / or use state of the protective clothing 1 ("inside of the protective clothing 1").
[0162] Likewise, in the connection area 5, in particular in the seam area 6, the third layer 4 can face away from the wearer and / or user of the protective clothing 1 when the protective clothing 1 is worn and / or used ("outer side of the protective clothing 1"). In this context, the additional adsorption filter material 8 can be arranged or positioned on the side and / or surface of the third layer 4 facing away from the second layer 3 ("outermost layer").
[0163] In addition, according to the present embodiment, as also illustrated in Fig. 3, in the connecting region 5, in particular in the seam region 6, the first layer 2 can be arranged or positioned on the side of the protective clothing 1 facing away from a source of harmful and / or toxic substances in the protective clothing 1 when the protective clothing 1 is worn and / or used. In particular, in the connecting region 5, in particular in the seam region 6, the additional adsorption layer 8 can be arranged or positioned on the side of the protective clothing 1 facing toward a source of harmful and / or toxic substances in the protective clothing 1 when the protective clothing 1 is worn and / or used.
[0164] The following is a detailed description of the embodiment of the present invention shown in particular in Fig. 3:
[0165] - According to the embodiment of the present invention shown in Fig. 3, it can be provided in particular that in the connecting region 5, in particular in the seam region 6, the additional adsorption filter material 8 is arranged or positioned on the third layer 4.
[0166] - In particular, in the connecting region 5, in particular in the seam region 6, the third layer 4 can be arranged or positioned between the additional adsorption filter material 8 and the second layer 3.
[0167] - In addition, the additional adsorption filter material 8 can be in direct contact with the third layer 4, in particular can be directly adjacent to or resting on the third layer 4.
[0168] - Similarly, the third layer 4 can be filled with the additional
[0169] Adsorption filter material 8 and, in particular, the additional
[0170] Adsorption filter material 8 opposite, are in direct contact with the second layer 3, in particular directly on the third layer 4 and, in particular opposite the third layer 4, on or rest on the second layer 3.
[0171] - As indicated in Fig. 3, it can be provided in particular that in the connecting region 5, in particular in the seam region 6, the first layer 2 is arranged or positioned on the surface or side of the second layer 3 opposite the third layer 4.
[0172] - In particular, in the connecting region 5, in particular in the seam region 6, the first layer 2 can be in direct contact with the second layer 3, preferably directly against or resting on the second layer 3, in particular on the surface or side of the second layer 3 opposite the third layer 4. - According to the present embodiment, as shown in Fig. 3, it can be provided in particular that in the connecting region 5, in particular in the seam region 6, the layers 2, 3, 4 and the additional adsorption filter material 8 are arranged or positioned in the following sequence: (i) first layer 2, (ii) second layer 3, (iii) third layer 4, (iv) additional adsorption filter material 8.
[0173] - In this context, the additional adsorption filter material 8 can be arranged or positioned on the surface or side of the third layer 4 facing away from a wearer and / or user of the protective clothing 1 when the protective clothing 1 is being worn and / or used.
[0174] - In this context, the first layer 2 can also be arranged or positioned on the side (inside) of the protective clothing 1 facing a wearer and / or user of the protective clothing 1 in the wearing and / or use state of the protective clothing 1.
[0175] - In addition, the additional adsorption filter material 8 can be arranged or positioned on the side (outside) of the protective clothing 1 facing away from a wearer and / or user of the protective clothing 1 when the protective clothing 1 is being worn and / or used.
[0176] As illustrated in particular in Figs. 4 to 6, it can be provided according to an embodiment of the invention that the first layer 2 and the second layer 3 are turned over in the connecting region 5, in particular are turned over together, preferably by means of the seam 7, preferably including and / or co-covering the third layer 4 and the additional adsorption filter material 8.
[0177] The previously described overlapping of the first layer 2 and the second layer 3 is also particularly advantageous according to the invention in that the seam 7 used for this purpose also equally encompasses the third layer 4 and the additional adsorption filter material 8 or connects them to the further layers 2, 3. The overlapping of the first layer 2 and the second layer 3 is particularly advantageous in that the seam 7 can be designed such that only the inner sections of the first layer 2 and the second layer 3 are encompassed, thus providing a covering by the respective outwardly extending layer sections, which leads to a further improvement in the protective function against harmful or toxic substances in the connection area 5, since the seam 7 is, so to speak, additionally covered on the outside (cf. in particular Fig. 6A).In this context, the invention can equally provide for the first layer 2 and / or the second layer 3 to be hemmed independently of one another in the connecting region 5. This can increase the stability of the respective edge region of the first layer 2 or the second layer 3.
[0178] 4 to 6A / B as well as Fig. 9C further show a preferred embodiment of the present invention in that the first layer 2 and / or the second layer 3, independently of one another, are folded over and / or turned over in the connecting region 5, in particular folded over and / or turned over at the edge. According to a preferred embodiment of the invention, this is particularly such that both the first layer 2 and the second layer 3 are folded over or turned over in the connecting region 5. In this context, the folding or turning over relates in particular to the edge region of the first layer 2 or the second layer 3. With regard to the folding or turning overBy folding the respective layers 2, 3 at the connecting region 5, the stability of the connection of the components in the connecting region 5 can be increased, in particular since in this context it is possible to proceed in such a way that the seam 7 covers the respective layer 2, 3 several times, as shown in Fig. 4 for the second layer 3 and as shown in Fig. 5 for the first layer 2 and the second layer 3.
[0179] According to a first embodiment of the present invention, as particularly illustrated in Fig. 4 and Fig. 6A / B, the first layer 2 and / or the second layer 3, in particular the first layer 2 and the second layer 3, can be folded and / or folded over in the connecting region 5 in the direction of the third layer 4 and / or the additional adsorption filter material 8, in particular folded and / or folded over at the edges. In this regard, the invention particularly provides that the third layer 4 with the additional adsorption filter material 8 is arranged and / or positioned between the first layer 2 and the second layer 3, preferably as defined above.
[0180] According to this embodiment, the additional adsorption filter material 8 is in direct contact with the third layer 4, and the third layer 4 with the additional adsorption filter material 8 is, so to speak, enclosed by the first layer 2 and the second layer 3, wherein the layers 2, 3 are folded over in the connection region 5 in the direction of the third layer 4 with the additional adsorption filter material 8. This is also illustrated in Fig. 9C. In this case, it can be provided according to the invention, in particular, as shown in Fig.6A / B shows that the seam 7, with respect to the first layer 2 and the second layer 3, only covers the folded and / or turned-over areas of the first layer 2 and the second layer 3, in particular the folded and / or turned-over areas of the first layer 2 and the second layer 3 that are in direct contact with the third layer 4 or the additional adsorption filter material 8, and connects them to the third layer 4 and the additional adsorption filter material 8.
[0181] As illustrated in Fig. 4 and Fig. 6A / B, it can be provided according to the invention that the seam 7 does not (also) encompass the non-folded and / or non-folded region of the first layer 2 and / or the non-folded and / or non-folded region of the second layer 3, in particular the non-folded and / or non-folded region of the first layer 2. In other words, it can be provided according to the invention that the seam 7 in the connection region, with respect to one of the layers 2, 3, encompasses both the folded and the non-folded region of one of these layers 2, 3, in particular the second layer 3, and with respect to the other layer, in particular the first layer 2, encompasses only the folded region and / or the region in direct contact with the additional adsorption filter material 8 or the third layer 4 (see in particular Fig. 4).
[0182] In particular, the area of the first layer 2 which is not folded over and, when worn, is oriented towards the wearer or user of the protective clothing 1 is not covered by the seam 7, so that the seam 7 is, so to speak, additionally covered on the inside by the area of the first layer 2 which is not covered by the seam, as illustrated in Fig. 4 and Fig. 6A / B. As a result, the protective function against harmful or toxic substances in the binding area or in relation to the seam 7 can be further increased, since any harmful or toxic substances penetrating through the seam 7 can be further absorbed by the area of the first layer 2 which is not covered by the seam in the form of the corresponding adsorption filter material 8.
[0183] With regard to the folding or turning over of the layers 2, 3, the situation is particularly such that the respectively folded or turned over area of a respective layer 2, 3 and the respectively non-folded or non-folded area of a respective layer 2, 3 lie on top of one another, so that the respectively non-folded or non-folded area (section) of a respective layer 2, 3 is, so to speak, that section or area of the main extension plane of the respective layer 2, 3 which rests on or covers the corresponding folded or folded area (section). A further embodiment of the present invention with the folding over of the layers 2, 3 is shown in Fig.5: In this context, it can be provided according to the invention that the first layer 2 and / or the second layer 3, in particular the first layer 2 and the second layer 3, are each folded and / or turned over in the connecting region 5, pointing away and / or leading away from the third layer 4 and / or the further adsorption filter material 8, in particular folded over and / or turned over at the edges.
[0184] In this context, it can be provided in particular within the scope of the present invention that in the connection area 5, in particular seam area 6, based on the non-turned and / or non-folded area of the first layer 2 and / or the second layer 3, the second layer 3 is arranged and / or positioned on the first layer 2 and that the third layer 4 with the additional adsorption filter material 8 is arranged and / or positioned on the surface or side of the second layer 3 facing away from the first layer 2, preferably as previously stated.
[0185] Furthermore, as regards the structure of the connecting region 5 of the protective clothing 1 according to the invention or the arrangement of the layers or components underlying the connecting region 5, the situation according to the invention is, as also illustrated in Fig. 1 to Fig. 6A / B, in particular such that the first layer 2 and the second layer 3 on the one hand and the third layer 4 on the other hand extend from the connecting region 5 in different directions, in particular in at least substantially opposite directions.
[0186] As explained in more detail below, in this context it is particularly such that the first layer 2 and the second layer 3 serve in particular to protectively cover body sections of a wearer or user of the protective clothing 1 according to the invention and that the third layer 3 serves to sealingly accommodate a body section, in particular in the region of openings in the protective clothing 1 or to sealingly connect or accommodate another protective article, such as a respiratory mask 10. As also illustrated in the figures according to Fig. 1 to Fig. 6A / B and in Fig. 9A to Fig. 9C, it is preferably provided according to the invention that the first layer 2, the second layer 3, the third layer 4 and the additional adsorption filter material 8 are arranged and / or positioned overlapping one another only in the connection region 5, in particular including the seam region 6.
[0187] As illustrated, for example, in Fig. 9A, the arrangement of the layers of the protective clothing 1 according to the invention is particularly such that the first layer 2 and the second layer 3, in particular far away from and / or outside the connecting region 5, define and / or form a covering and / or covering region (covering and / or covering section), preferably for covering at least one body section, in particular body part, of a wearer and / or user of the protective clothing 1 to protect against the effects of harmful and / or toxic substances.
[0188] As illustrated in Fig. 9B and Fig. 9C, within the scope of the present invention, the first layer 2, in particular far away from and / or outside the connection region 5, is arranged and / or positioned on the side of the protective clothing 1 facing the wearer and / or user of the protective clothing 1 ("inside of the protective clothing 1") in the wearing and / or use state of the protective clothing 1.
[0189] In particular, the first layer 2 can be arranged and / or positioned, in particular far away from and / or outside the connection area 5, in the wearing and / or use state of the protective clothing 1, on a side of the protective clothing 1 facing away from the source of the harmful and / or toxic substance ("inner side of the protective clothing 1").
[0190] The following section focuses on the special properties and formations of the first layer 2 and the layers underlying the first layer 2:
[0191] According to the invention, it can be provided, in particular, that the first layer 2 is and / or is designed to be gas-permeable, in particular air-permeable. In particular, the first layer 2 can be and / or be designed as a gas-permeable, in particular air-permeable, textile fabric. This results in a high level of wearing comfort with regard to the protective clothing 1 according to the invention.
[0192] As previously stated, the first layer 2 has in particular a layered structure or consists of several layers.
[0193] In general, in this context, the textile carrier layer 2b can be present or formed as a preferably gas-permeable, in particular air-permeable, textile sheet structure.
[0194] In this context, the textile carrier layer 2b can be designed as a knitted fabric, in particular as a warp-knitted fabric (knitted fabric) or a knitted fabric (knitted fabric), woven fabric, scrim or textile composite material, in particular as a knit fabric.
[0195] According to the invention, the textile carrier layer 2b can comprise or be formed from natural fibers and / or synthetic fibers (chemical fibers), preferably natural fibers, particularly preferably cotton fibers.
[0196] In particular, the textile carrier layer 2b may comprise or be formed from natural fibers, particularly preferably cotton fibers, optionally in combination with synthetic fibers (chemical fibers).
[0197] In this context, it can be provided in particular that the textile carrier layer 2b is a material, in particular textile fiber material, preferably textile fibers, in particular as a yarn and / or thread, selected from the group of natural materials and synthetic materials, in particular selected from the group of cotton (CO); wool; linen; polyesters; polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; aramids, in particular meta- and / or para-amides; optionally modified and / or regenerated celluloses; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof, preferably selected from the group of modified and / or regenerated celluloses, in particular viscose; aramids, in particular meta- and / or para-amides;Polyamide and mixtures or combinations thereof, or consists thereof. In particular, the textile carrier layer 2b can consist of a material, in particular textile fiber material, preferably textile fibers, in particular as yarn and / or thread, in the form of a mixture of cotton and polyester (CO / PES); or a mixture of polyamide and polyester (PA / PES); or a mixture of cotton and elastane (CO / EL); or a mixture of polyester and elastane (PES / EL); or a mixture of polyamide and elastane (PA / EL), preferably a mixture of cotton and elastane (CO / EL).
[0198] According to the invention, the textile carrier layer 2b can be elastic and / or reversibly stretchable. In this context, the textile carrier layer 2b can comprise elastane, in particular elastane fibers, preferably in an amount of at most 20 wt.%, preferably at most 15 wt.%, based on the textile carrier layer 2b.
[0199] According to the invention, the textile carrier layer 2b can consist of a material, in particular textile fiber material, preferably textile fibers, in particular as yarn and / or thread, in the form of cotton (CO) or polyester (PES).
[0200] In general, the textile carrier layer 2b can have a basis weight in the range of
[0201] 2 2 2 2
[0202] 10 g / m to 350 g / m , in particular in the range from 20 g / m to 300 g / m , 2 2 preferably in the range from 30 g / m to 250 g / m , particularly preferably in the range from 50 g / m to 175 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%.
[0203] According to the invention, it is particularly provided that the textile carrier layer 2b, in particular far away from and / or outside the connection region 5, is arranged and / or positioned on the side of the first layer 2 facing the wearer and / or user of the protective clothing 1 ("inner side of the first layer 2") in the wearing and / or use state of the protective clothing 1.
[0204] In this context, it is equally provided in particular that the textile carrier layer 2b, in particular far away from and / or outside the connection region 5, is arranged and / or positioned on the side of the first layer 2 facing away from a source of harmful and / or toxic substances ("inner side of the first layer 2") when the protective clothing 1 is worn and / or used. Furthermore, with regard to the adsorption layer 2a of the first layer 2, the following embodiments have proven particularly advantageous within the scope of the present invention. Thus, according to the invention, it is particularly provided that the adsorption layer 2a is discontinuous. In particular, the adsorption layer 2a is gas-permeable, preferably air-permeable.
[0205] As illustrated in the enlarged detail according to Fig. 1 and further in Fig. 7, it is particularly provided that the adsorption layer 2a comprises or is formed from adsorbent particles 2c, in particular a plurality of individual and / or discrete adsorbent particles 2c. According to the invention, the first layer 2 has at least two layers (cf., for example, Fig. 1 and Fig. 7 A1). Fig. 7 A1 illustrates a two-layer structure of the first layer 2, while Figs. 7 B1 to D1 illustrate three- and four-layer structures.
[0206] In general, the adsorbent particles 2c of the adsorption layer 2a can be selected from the group of
[0207] (i) in particular particulate activated carbon and / or activated carbon particles, preferably in the form of activated carbon particles in granular form ("granular carbon") or activated carbon particles in spherical form ("spherical carbon");
[0208] (ii) zeolites, in particular natural and / or synthetic zeolites;
[0209] (iii) molecular sieves, in particular zeolitic molecular sieves, synthetic molecular sieves and / or in particular synthetic molecular sieves based on carbon, oxides and / or glasses;
[0210] (iv) metal oxide and / or metal particles;
[0211] (v) ion exchange resins, in particular polydisperse and / or monodisperse cation and / or anion exchangers, in particular of the gel type and / or macroporous type;
[0212] (vi) inorganic oxides, in particular silicon dioxides, silica gels and / or aluminum oxides;
[0213] (vii) porous organic polymers and / or porous organic-inorganic hybrid polymers and / or metal-organic framework materials, in particular MOFs (metal organic framework), COFs (covalent organic framework), ZI Fs (zeolite imidazolate framework), POMs (polymer organic material) and / or OFCs;
[0214] (viii) mineral granules;
[0215] (ix) clathrates; and
[0216] (x) mixtures and / or combinations thereof; with (i) being particularly preferred. In particular, the adsorbent particles 2c of the adsorption layer 2a can be activated carbon particles, preferably in the form of granular activated carbon particles ("granular carbon") or spherical activated carbon particles ("spherical carbon"), preferably in the form of spherical activated carbon particles.
[0217] According to the invention, however, it can also be provided in principle that the activated carbon fibers or activated carbon filaments are in the form of an activated carbon fiber sheet.
[0218] According to an embodiment of the invention, the adsorber particles 2c of the adsorption layer 2a are, in particular, activated carbon particles, preferably in the form of activated carbon particles in granular form ("granular carbon") or activated carbon particles in spherical form ("spherical carbon"), preferably activated carbon particles in spherical form.
[0219] In this context, according to the invention, the specific design of the adsorber particles 2c in the form of activated carbon particles in grain or spherical form can be as follows:
[0220] - In this context, the activated carbon can have a total pore volume, in particular a total pore volume according to Gurvich, in the range of 0.3 cm 3 / g up to 3.8 cm 3 / g, especially in the range of 0.4 cm 3 / g up to 3.5 cm 3 / g, preferably in the range of 0.5 cm 3 / g up to 3 cm 3 / g, particularly preferably in the range of 0.6 cm 3 / g up to 2.5 cm 3 / g, most preferably in the range of 0.5 cm 3 / g to 1.5 cm 3 / g.
[0221] - In addition, at least 65%, in particular at least 70%, preferably at least 75%, preferably at least 80%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon can be formed by pores with pore diameters of at most 50 nm, in particular by micropores and / or mesopores.
[0222] - Furthermore, 50% to 95%, in particular 60% to 90%, preferably 70% to 85%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon can be formed by pores with pore diameters of at most 50 nm, in particular by micropores and / or mesopores. - According to the invention, it is also such that 1% to 60%, in particular 5% to 50%, preferably 10% to 40%, more preferably 15% to 35%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon is formed by pores with pore diameters of more than 2 nm, in particular by mesopores and / or macropores.
[0223] - In addition, according to the invention, the activated carbon can have a pore volume formed by pores with pore diameters of at most 2 nm (ie < 2 nm), in particular micropore volume according to carbon black, in the range of 0.05 cm 3 / g up to 2.5 cm 3 / g, especially 0.15 cm 3 / g up to 2 cm 3 / g, preferably 0.3 cm 3 / g to 1.5 cm 3 / g, in particular wherein 15% to 98%, in particular 25% to 95%, preferably 35% to 90%, of the total pore volume of the activated carbon is formed by pores with pore diameters of at most 2 nm, in particular by micropores.
[0224] - According to the invention, the activated carbon can have a specific BET surface area in the range of 600 m 2 / g up to 4,000 m 2 / g, especially 800 m 2 / g up to 3,500 m 2 / g, preferably 1,000 m 2 / g up to 3,000 m 2 / g, particularly preferably 1,200 m 2 / g up to 2,750 m 2 / g, most preferably 1,300 m 2 / g up to 2,500 m 2 / g.
[0225] - In addition, the activated carbon may have a surface area in the range of 400 to 3,500 m formed by pores with a maximum diameter of 2 nm, in particular by micropores. 2 / g, especially 500 to 3,000 m 2 / g, preferably 600 to 2,500 m 2 / g, preferably 700 to 2,000 m 2 / g.
[0226] - In addition, the activated carbon can have a surface area in the range of 200 to 2,000 m formed by pores with pore diameters in the range of 2 nm to 50 nm, in particular by mesopores 2 / g, especially 300 to 1,900
[0227] 2 2 2 m / g, preferably 400 to 1,800 m / g, preferably 500 to 1,700 m / g.
[0228] - Furthermore, the activated carbon can have an average pore diameter in the range from 0.1 nm to 55 nm, in particular 0.2 nm to 50 nm, preferably 0.5 nm to 45 nm, more preferably 1 nm to 40 nm.
[0229] As far as the previously mentioned parameters or properties of the activated carbon are concerned, the following should also be noted (whereby the following statements also apply accordingly to the activated carbon used for the additional adsorption filter material 8): As far as the determination of the total pore volume according to Gurvich is concerned, this is a measurement or determination method that is well known to those skilled in the art. For further details regarding the determination of the total pore volume according to Gurvich, reference can be made, for example, to L. Gurvich (1915), J. Phys. Chem. Soc. Russ. 47, 805, as well as to S. Lowell et al., Characterization of Porous Solids and Powders: Surface Area Pore Size and Density, Kluwer Academic Publishers, Article Technology Series, pages 111 ff. In particular, the pore volume of the activated carbon can be determined on the basis of the Gurvich rule according to the formula Vp = W a / pi, where W ais the adsorbed amount of an underlying adsorbate and pi is the density of the adsorbate used (see also formula (8.20) according to page 111, chapter 8.4.) by S. Lowell et al.).
[0230] The method for determining carbon black is known per se to the person skilled in the art, and for further details on determining the pore surface area and pore volume according to carbon black, reference can be made, for example, to RW Magee, Evaluation of the External Surface Area of Carbon Black by Nitrogen Adsorption, Presented at the Meeting of the Rubber Division of the American Chem. Soc., October 1994, e.g. referred to in: Quantachrome Instruments, AUTOSORB-1, AS1 WinVersion 1.50, Operating Manual, OM, 05061, Quantachrome Instruments 2004, Florida, USA, pages 71 ff. In particular, the relevant evaluation can be carried out using the t-plot method.
[0231] For further details on the determination of the BET surface area and the BET method, reference can be made to the aforementioned ASTM D6556-04 as well as to Römpp Chemielexikon, 10th edition, Georg Thieme Verlag, Stuttgart / New York, keyword: "BET method", including the literature cited therein, and to Winnacker-Küchler (3rd edition), volume 7, pages 93 ff., as well as to Z. Anal. Chem. 238, pages 187 to 193 (1968).
[0232] In the context of the present invention, the term "micropores" refers to pores with pore diameters of less than 2 nm, whereas the term "mesopore" refers to pores with pore diameters in the range from 2 nm (i.e., 2 nm inclusive) to 50 nm inclusive, and the term "macropores" refers to pores with pore diameters of more than 50 nm (i.e., > 50 nm). Adsorbers or adsorber particles 2c (or 8c) suitable for the invention, particularly in the form of activated carbons, as described below, are commercially available, e.g., from Blücher GmbH, Erkrath, Germany, or other commercial manufacturers.
[0233] Adsorbers or adsorber particles 2c (or 8c) which can preferably be used according to the invention and have the properties and parameters mentioned below are described in particular in the following prior art documents: DE 20 2006 016 898 U1, EP 1 918 022 and US 2008 / 0107589 A1, WO 01 / 83688 (PCT / EP 01 / 04615), WO 2011 / 003434 (PCT / EP 2009 / 007172), WO 2008 / 110233 (PCT / EP 2008 / 000606) and WO 2013 / 068060 (PCT / EP 2012 / 003743).
[0234] Particularly good results are also obtained when the adsorbent particles 2c (or 8c), especially the activated carbon particles, are obtained by carbonization and subsequent activation of a synthetic and / or non-natural product-based particulate starting material, especially based on organic polymer particles. This results in activated carbons with particularly defined adsorptive properties and a defined pore system.
[0235] In this context, it is equally preferred according to the invention that the adsorbent particles 2c, in particular the activated carbon particles, are obtained from a particulate starting material based on organic polymers, in particular based on sulfonated organic polymers, preferably based on divinylbenzene-crosslinked polystyrene, preferably based on styrene / divinylbenzene copolymers, in particular by carbonization and subsequent activation of the starting material, in particular wherein the content of divinylbenzene in the starting material is in the range from 1 wt.% to 20 wt.%, in particular 1 wt.% to 15 wt.%, preferably 1.5 wt.% to 12.5 wt.%, preferably 2 wt.% to 10 wt.%, based on the starting material.
[0236] According to a preferred embodiment of the invention, it is provided that the adsorber particles 2c (or 8c), in particular the activated carbon particles, are formed from a polymer-based spherical activated carbon (PBSAC) and / or that the adsorber particles 4a, in particular the activated carbon particles, are formed from a polymer-based spherical activated carbon (PBSAC). This achieves particularly good adsorption results with high mechanical stability of the underlying activated carbon particles. Regarding the adsorber particles 2c, in particular the activated carbon particles, of the adsorption layer 2a, these can be formed in particular as follows:
[0237] - Thus, the adsorbent particles 2c of the adsorption layer 2a, in particular the activated carbon particles, can have a particle size, in particular a particle diameter, in the range from 0.05 mm to 2 mm, in particular in the range from 0.075 mm to 1 mm, preferably in the range from 0.1 mm to 0.5 mm, preferably in the range from 0.125 mm to 0.4 mm, particularly preferably in the range from 0.15 mm to 0.35 mm, in particular determined according to ASTM D2862.
[0238] - In this context, at least 80% by weight, in particular at least 90% by weight, preferably at least 95% by weight, preferably at least 99% by weight, of the adsorbent particles (2c), in particular the activated carbon particles, can have particle sizes, in particular particle diameters, in the aforementioned ranges.
[0239] - In addition, the adsorbent particles 2c of the adsorption layer 2a, in particular the activated carbon particles, can have an average particle size (D50), in particular an average particle diameter (D50), in the range from 0.05 mm to 1.5 mm, in particular in the range from 0.08 mm to 1 mm, preferably in the range from 0.1 mm to 0.75 mm, preferably in the range from 0.12 mm to 0.5 mm, particularly preferably in the range from 0.15 mm to 0.3 mm, in particular determined according to ASTM D2862.
[0240] This also ensures good adsorption capacity and loading capacity with toxic or harmful substances while maintaining acceptable layer thicknesses and low mechanical stress on the other layers.
[0241] Furthermore, it can be provided according to the invention that the adsorber particles 2c of the adsorption layer 2a, in particular the activated carbon particles, are present in an amount in the range of 5 g / m 2 up to 500 g / m 2 , especially 10 g / m2 up to 300 g / m 2 , preferably 30 g / m 2 up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2 , are used. In particular, the first layer 2, in particular the adsorption layer 2a, the adsorbent particles 2c, in particular the activated carbon particles, in an amount in the range of 5 g / m 2 up to 500 g / m 2 , especially 10 g / m 2 up to 300 g / m 2 , preferably 30 g / m 2 up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2 , In particular, the adsorption layer 2a can have a basis weight, in particular determined as dry weight, in the range of 5 g / m 2 up to 500 g / m 2 , especially 10 g / m 2 up to 300 g / m 2 , preferably 30 g / m 2 up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2, in particular determined according to DIN EN 12127, preferably after drying for 1 hour at 105 °C.
[0242] Based on the above-mentioned quantities of the areas, effective absorption or adsorption of pollutants or toxins is made possible.
[0243] As also illustrated in the enlarged detail according to Fig. 1 and in Fig. 7 (cf. enlarged details B1, C1 and D1 therein), it can be provided according to the invention that the first layer has a textile spacer and / or intermediate layer 2d. In this context, the textile spacer and / or intermediate layer 2d can be arranged in particular on the surface and / or side of the adsorption layer 2a opposite the carrier layer 2b. Through the targeted and purposeful use of a spacer or intermediate layer 2d, the other layers of the first layer 2 can be further protected, for example with regard to the adsorption layer 2a and the particle or aerosol filter layer 2e mentioned below and which may be present.
[0244] In general, the textile spacer and / or intermediate layer 2d can be present and / or formed as a preferably gas-permeable, in particular air-permeable, textile fabric.
[0245] In this context, the textile spacer and / or intermediate layer 2d can be designed as an air-permeable textile fabric, in particular as a knitwear, woven fabric, scrim or textile composite material, preferably nonwoven, particularly preferably as a nonwoven.
[0246] In addition, the textile spacer and / or intermediate layer 2d may comprise or be formed from natural fibers and / or synthetic fibers (chemical fibers), preferably synthetic fibers.
[0247] According to the invention, the textile spacer or intermediate layer can comprise or consist of a material, in particular textile fiber material, preferably textile fibers, in particular as yarn and / or thread, selected from the group of synthetic materials, in particular selected from the group of polyesters; polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates; aramids, in particular meta- and / or para-amides; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof; preferably polyesters.
[0248] In general, the textile spacer and / or intermediate layer 2d can be a 2 2
[0249] Basis weight in the range of 5 g / m to 150 g / m , especially in the range of
[0250] 2 2 2 2
[0251] 10 g / m to 125 g / m , preferably in the range of 15 g / m to 100 g / m , particularly preferably in the range of 20 g / m to 75 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%.
[0252] Furthermore, Fig. 7 (extensive details C1 and D1 therein) illustrates an embodiment according to the invention, according to which the first layer 2 additionally has a particle and / or aerosol filter layer 2e, preferably a particle and aerosol filter layer 2e.
[0253] On this basis, the first layer 2 can additionally be equipped with particle or aerosol filter properties. This further increases the protective function against harmful or toxic substances, whereby, as a result of this inventive measure, the adsorption layer 2a is further relieved and thus does not deplete as quickly. This can further extend the use or wear time of the protective clothing 1 according to the invention.
[0254] In this context, the particle and / or aerosol filter layer 2e can be present and / or formed as a gas-permeable textile fabric comprising or formed from a plurality of individual textile fibers. Furthermore, the particle and / or aerosol filter layer 2e can comprise or consist of at least one functional layer with particle and / or aerosol filter properties, in particular with particle and aerosol filter properties.
[0255] Furthermore, the particle and / or aerosol filter layer 2e can be gas-permeable, in particular air-permeable, and / or water vapor-permeable, preferably gas-permeable, in particular air-permeable, and water vapor-permeable, preferably air-permeable and water vapor-permeable. In particular, it can be provided according to the invention that the particle and / or aerosol filter layer 2e has a (total) basis weight in the range from 5 g / m to 200 g / m, in particular in the range from 10 g / m to 150 g / m, 2 2 preferably in the range from 15 g / m to 120 g / m, preferably in the range from 20 g / m to 100 g / m, particularly preferably in the range from 25 g / m to 80 g / m, in particular determined according to DIN EN 12127, preferably after 24 hours of air conditioning at a temperature of 20 °C and a relative humidity of 65%.
[0256] In addition, the particle and / or aerosol filter layer 2e can have a thickness, in particular total cross-sectional thickness, in the range from 0.01 mm to 5 mm, in particular in the range from 0.03 mm to 3 mm, preferably in the range from 0.05 mm to 2 mm, preferably in the range from 0.07 mm to 1 mm, particularly preferably in the range from 0.09 mm to 0.75 mm, further preferably in the range from 0.1 mm to 0.5 mm, in particular determined according to DIN EN ISO 9073-2.
[0257] In general, the particle and / or aerosol filter layer 2e, in particular the functional layer, can have a separation efficiency (separation efficiency), in particular fractional separation efficiency, of at least 80%, in particular of at least 85%, preferably of at least 90%, preferably of at least 95%, determined according to DIN EN 1822 at a pressure difference of 15 Pascal with potassium chloride (KCl) as test substance (in particular 1%) as minimum efficiency (MPPS, in particular MPPS = 0.1 pm to 0.3 pm).
[0258] According to the invention, it can be provided overall that the particle and / or aerosol filter layer 2e is designed as a HEPA filter (High Efficiency Penetration or Particulate Air) or ULPA filter (Ultra Low Penetration or Particulate Air).
[0259] In addition, the particle and / or aerosol filter layer 2e, in particular the functional layer, can comprise and / or be formed from at least one textile fiber (functional layer textile fiber), preferably a plurality of textile fibers, in particular wherein the particle and / or aerosol filter layer 2e, in particular the functional layer, comprises and / or is formed from a plurality of individual textile fibers (functional layer textile fibers). In this context, the textile fibers of the particle and / or aerosol filter layer 2e, in particular the functional layer, can have a fiber diameter in the range from 10 nm to 1,500 nm, in particular in the range from 50 nm to 1,000 nm, preferably in the range from 100 nm to 800 nm, preferably in the range from 150 nm to 600 nm, particularly preferably in the range from 200 nm to 400 nm, in particular determined according to DIN 53 811.
[0260] In addition, the textile fibers of the particle and / or aerosol filter layer 2e, in particular of the functional layer, can be synthetic fibers (chemical fibers), in particular wherein the textile fibers of the functional layer are a material from the group of polyurethanes (PU); polyesters (PES); polyolefins (PO), such as polyethylene (PE), polypropylene (PP), polyoxyethylene and polyoxypropylene; polyvinyl chlorides (CLF); polyvinylidene chlorides (CLF); acetates (CA); triacetates (CTA); polyacrylic (PAN), in particular polyacrylonitriles; polyamides (PA); polyvinyl alcohol (PVAL); polyvinyl esters; poly(meth-)acrylates; polyvinylidene fluorides (PVDF); as well as mixtures and combinations thereof, preferably from the group of polyurethanes; polyesters, polyolefins, polyamides, polyacrylonitriles, poly(meth-)acrylates and polyvinylidene fluorides; their copolymers and their mixtures and combinations, preferably from the group of polyurethanes; Polyesters, polyolefins and polyamides;their copolymers and their mixtures and combinations, most preferably polyurethanes;
[0261] Furthermore, the textile fibers of the particle and / or aerosol filter layer 2e, in particular the functional layer, can be polyurethane fibers. In particular, the particle and / or aerosol filter layer 2e, in particular the functional layer, can comprise or consist of polyurethane fibers.
[0262] In general, the particle and / or aerosol filter layer 2e, in particular the functional layer, can have an average pore size or average mesh size, in particular average pore size, in the range from 0.05 pm to 100 pm, in particular in the range from 0.1 pm to 50 pm, preferably in the range from 0.2 pm to 20 pm, more preferably in the range from 0.3 pm to 10 pm, particularly preferably in the range from 0.4 pm to 5 pm, further preferably in the range from 0.5 pm to 3 pm, in particular determined according to ASTM F316-86.According to the invention, it can also be provided that the particle and / or aerosol filter layer 2e is designed in multiple layers, in particular in three layers, wherein the particle and / or aerosol filter layer 2e has at least one outer carrier layer and at least one functional layer arranged between the outer carrier layers, in particular connected to the outer carrier layers, with particle and / or aerosol filter properties, in particular with particle and aerosol filter properties, in particular wherein the particle and / or aerosol filter layer 2e is designed as a gas-permeable, in particular air-permeable, composite, preferably a laminate.
[0263] With regard to the particle or aerosol filter layer 2e, it has proven advantageous if the particle and / or aerosol filter layer 2e, in particular the functional layer, is produced by electrospinning, spunbonding processes, meltblow processes or a combination of these processes, preferably by a combination of electrospinning and meltblow processes, or by electrospinning, preferably by electrospinning.
[0264] Likewise, with regard to the filter properties against particles or aerosols, it is advantageous if the particle and / or aerosol filter layer 2e, in particular the functional layer, is designed as a scrim or textile composite material, in particular nonwoven, particularly preferably as a nonwoven.
[0265] According to a preferred embodiment of the invention, the particle and / or aerosol filter layer 2e, in particular the functional layer, is formed and / or present as a scrim or textile composite material, in particular nonwoven, particularly preferably as a nonwoven, based on and / or made of polyurethane fibers.
[0266] Based on the aforementioned technical measures, particularly defined fiber arrangements can be realized in the particle or aerosol filter layer, which leads to further defined particle or aerosol filter properties with simultaneous high gas or air permeability.
[0267] According to the invention, numerous arrangements are possible for the particle or aerosol filter layer 2e: Thus, according to the invention, it can be provided that the particle and / or aerosol filter layer 2e is arranged directly on the adsorption layer 2a (cf. Fig. 7 C1 ) or on the spacer and / or intermediate layer 2d (cf. Fig. 7 D1 ) and / or is connected thereto.
[0268] Within the scope of the present invention, the particle and / or aerosol filter layer 2e, if present, is generally arranged or positioned in front of the adsorption layer 2a in the direction of a pollutant or toxic substance source, and thus in particular on the side or surface of the adsorption layer 2a facing away from the wearer or user of the protective clothing 1. This can relieve the adsorption layer 2a of the burden of absorbing pollutants or toxic substances, since these can largely already be absorbed by the particle or aerosol filter layer 2e.
[0269] According to the invention, it can also be provided that the particle and / or aerosol filter layer 2e is arranged on the spacer and / or intermediate layer 2d and / or is connected thereto, wherein the spacer and / or intermediate layer 2d is arranged on the surface and / or side facing away from the particle and / or aerosol filter layer 2e and / or is connected thereto (cf. Fig. 7 D1 ). According to this embodiment, the spacer or intermediate layer 2d is located in particular between the particle or aerosol filter layer 2e and the adsorption layer 2a. This results in particular in a mechanical relief of the particle or aerosol filter layer 2e, which also increases the durability and thus the service life of the protective clothing 1 according to the invention.
[0270] According to a further embodiment of the present invention, it can also be provided that the particle and / or aerosol filter layer 2e is arranged between the adsorption layer 2a and the spacer and / or intermediate layer 2d and / or is connected thereto (not shown in the figures). In this case, the spacer or intermediate layer thus functions as the outer layer of the first layer 2. This can also ensure mechanical protection of the particle or aerosol filter layer 2e.
[0271] According to the invention, it can be provided that the spacer and / or intermediate layer 2d is arranged between the adsorption layer 2a and the particle and / or aerosol filter layer 2e and / or is firmly connected (attached, fixed) to the adsorption layer 2a and / or the particle and / or aerosol filter layer 2e, in particular (only) to the adsorption layer 2a, in particular by means of a preferably discontinuously, preferably punctiform, applied adhesive and / or by means of lamination.
[0272] According to the invention, it can further be provided that the first layer 2 has a textile cover layer (not shown in the figures). The textile cover layer can equally function as the outer layer of the first layer 2 (in particular on the side of the first layer 2 facing away from the wearer or user when the protective clothing 1 is worn or in use).
[0273] As regards the textile covering layer (covering layer of the first layer 2) that may be provided, this may in particular have one or more of the following properties:
[0274] - Thus, the textile covering layer can be arranged on the side of the adsorption layer 2a opposite the carrier layer 2b.
[0275] - Furthermore, the textile covering layer can be designed as a gas-permeable, in particular air-permeable, textile fabric, in particular as a textile knitwear, preferably as a warp-knitted fabric (knitted fabric) or a woven fabric (knitted fabric), or in particular as a woven fabric, scrim, nonwoven or textile composite material.
[0276] - In addition, the textile covering layer can comprise or be formed from natural textile fibers and / or synthetic textile fibers (chemical fibers), preferably synthetic textile fibers.
[0277] - Furthermore, the textile covering layer can comprise or be formed from synthetic fibres (chemical fibres), optionally in combination with natural fibres, preferably cotton fibres.
[0278] - Furthermore, the textile covering layer can comprise elastane (EL), in particular elastane fibers. This allows the covering layer to be elastic or reversibly stretchable.
[0279] - In general, the textile covering layer can have a basis weight in the range
[0280] 2 2 2 2 from 5 g / m to 400 g / m , in particular in the range from 10 g / m to 300 g / m , 2 2 preferably in the range from 20 g / m to 250 g / m , particularly preferably in the range from 30 g / m to 175 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%. - In addition, the textile cover layer can have a thickness, in particular cross-sectional thickness, in the range from 0.001 mm to 10 mm, in particular in the range from 0.01 mm to 8 mm, preferably in the range from 0.05 mm to 4 mm, preferably in the range from 0.075 mm to 2 mm, particularly preferably in the range from 0.1 mm to 2 mm, further preferably in the range from 0.15 mm to 1 mm, in particular determined according to DIN EN ISO 5084.
[0281] - Furthermore, the textile covering layer can comprise or consist of a material, in particular textile fiber material, preferably textile fibers, selected from the group of natural materials and synthetic materials, in particular selected from the group of cotton (CO); wool; linen; polyesters; polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; aramids, in particular meta- and / or para-amides; optionally modified and / or regenerated celluloses; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof, preferably selected from the group of modified and / or regenerated celluloses, in particular viscose; aramids, in particular meta- and / or para-amides; polyamide and mixtures or combinations thereof.
[0282] According to the invention, it can be provided in particular that the textile cover layer is arranged directly on the adsorption layer 2a or on the particle and / or aerosol filter layer 2e or is connected thereto.
[0283] In addition, the particle and / or aerosol filter layer 2e can be arranged between the textile cover layer on the one hand and the adsorption layer 2a or the spacer and / or intermediate layer 2d on the other hand or can be connected thereto.
[0284] According to the invention, the adsorption layer 2a can be fixed to the textile carrier layer 2b in particular by means of an adhesive that is preferably applied discontinuously, preferably in a point-like manner.
[0285] In particular, the spacer and / or intermediate layer 2d can be fixed to the adsorption layer 2a by means of an adhesive that is preferably applied discontinuously, preferably in a point-like manner. According to a further embodiment of the invention, it can also be provided that the textile cover layer is fixed to the adsorption layer 2a or to the particle and / or aerosol filter layer 2e by means of an adhesive that is preferably applied discontinuously, preferably in a point-like manner, or by lamination.
[0286] As far as the first layer 2 as a whole is concerned, this can be designed as a composite or laminate.
[0287] Furthermore, the first layer 2 can have at least one of the following properties:
[0288] - Thus, according to the invention, it can be provided that the first layer 2 has a basis weight in the range of 10 g / m 2 up to 600 g / m 2, especially in the range of 50 g / m 2 up to 500 g / m 2 , preferably in the range of 100 g / m 2 up to 450 g / m 2 , particularly preferably in the range of 150 g / m 2 up to 410 g / m 2 , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65 %.
[0289] - Furthermore, the first layer 2 can have a thickness, in particular total cross-sectional thickness, in the range from 0.01 mm to 10 mm, in particular in the range from 0.05 mm to 5 mm, preferably in the range from 0.1 mm to 3 mm, preferably in the range from 0.2 mm to 2 mm, particularly preferably in the range from 0.5 mm to 2 mm, in particular determined according to DIN EN ISO 5084.
[0290] - According to the invention, it is also advantageous if the first layer 2 and / or the protective material 1 has a gas permeability, in particular air permeability, of at least 1 mm / s, in particular at least 2 mm / s, preferably at least 5 mm / s, preferably at least 7 mm / s, particularly preferably at least 10 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal.
[0291] - Furthermore, it is advantageous according to the invention if the first layer 2 and / or the protective material 1 has a gas permeability, in particular air permeability, in the range from 1 mm / s to 500 mm / s, in particular in the range from 2 mm / s to 400 mm / s, preferably in the range from 5 mm / s to 200 mm / s, preferably in the range from 7 mm / s to 150 mm / s, particularly preferably in the range from 10 mm / s to 100 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal.
[0292] Furthermore, the first layer 2 or the protective material 1 can have at least one of the following properties:
[0293] - Thus, the first layer 2 or the protective material 1 can have a bursting pressure, in particular determined according to DIN EN ISO 13938-2, of at least 50 kPa (kilopascals), in particular of at least 75 kPa, preferably of at least 90 kPa, particularly preferably of at least 100 kPa.
[0294] - In addition, the first layer 2 or the protective material 1 can have a bursting pressure, in particular determined according to DIN EN ISO 13938-2, in the range from 50 kPa (kilopascals) to 1,000 kPa, in particular in the range from 75 kPa to 800 kPa, preferably in the range from 90 kPa to 600 kPa, particularly preferably in the range from 100 kPa to 500 kPa.
[0295] - Furthermore, the first layer 2 or the protective material 1 can have a tensile load and / or stretchability (elongation) in at least one direction, in particular in the longitudinal or transverse direction, determined according to DIN 53835-14 at 20 Newtons, of at least 2.5%, preferably of at least 5%, preferably of at least 7%.
[0296] - In addition, the first layer 2 and / or the protective material 1 can have a shrinkage in at least one direction, in particular in the longitudinal or transverse direction, determined according to DIN EN 5077, of at most 12%, preferably of at most 10%, preferably of at most 6%.
[0297] The aforementioned properties ensure that the first layer 2 or the protective material 1 as a whole exhibits high wear resistance. This ensures, in addition to good wear resistance, that the first layer 2 or the protective material 1 according to the invention is also resistant to regeneration treatments, in particular to washing or cleaning treatments.
[0298] As far as the second layer 3 is concerned, it can in particular be three-layered and in particular be designed as a composite or laminate. In this context, the second layer 3 can comprise or consist of (i) a textile carrier layer 2b (textile carrier layer of the second layer 3), in particular as defined above; (ii) an adsorption layer 2a (adsorption layer of the second layer 3), in particular as defined above; and (iii) a textile cover layer (cover layer of the second layer 3), in particular as defined above, or a textile spacer and / or intermediate layer 2d (textile spacer and / or intermediate layer of the second layer 3), in particular as defined above.
[0299] In this context, the second layer 3 may comprise the aforementioned layers (i) to (iv) in the order and / or sequence (i), (ii), (iii), (iv).
[0300] According to a further embodiment of the invention, it can also be provided that the second layer 3 is four-layered and in particular is designed as a composite and / or laminate.
[0301] In this context, the second layer 3 can comprise or consist of (i) a textile carrier layer 2b (textile carrier layer of the second layer 3), in particular as defined above; (ii) an adsorption layer 2a (adsorption layer of the second layer 3), in particular as defined above; (iii) a particle and / or aerosol filter layer 2e (particle and / or aerosol filter layer of the second layer 3), in particular as defined above; and (iv) a textile cover layer (cover layer of the second layer 3), in particular as defined above, or a textile spacer and / or intermediate layer 2d (textile spacer and / or intermediate layer of the second layer 3), in particular as defined above.
[0302] In this context, the second layer 3 may comprise the aforementioned layers (i) to (iv) in the order and / or sequence (i), (ii), (iii), (iv).
[0303] The design and arrangement of the second layer 3 underlying the protective clothing 1 according to the invention is described in more detail below:
[0304] In particular, according to the invention, the second layer 3, in particular far away from and / or outside the connection area 5, is arranged and / or positioned on the side of the protective clothing 1 facing away from the wearer and / or user of the protective clothing 1 ("outer side of the protective clothing 1") when the protective clothing 1 is worn and / or used. For illustrative purposes, reference can also be made to Figs. 9B and 9C. In particular, the second layer 3, in particular far away from and / or outside the connection area 5, can be arranged or positioned on the side of the protective clothing 1 facing a source of harmful and / or toxic substances ("outer side of the protective clothing 1") when the protective clothing 1 is worn and / or used.
[0305] The second layer 3 is also particularly designed to be gas-permeable, particularly air-permeable. Since the first layer 2 is also fundamentally designed to be gas- and air-permeable, the protective clothing 1 according to the invention is also gas- and air-permeable overall, resulting in a correspondingly high level of comfort, while dissipating air humidity and preventing heat buildup or the like.
[0306] Thus, within the scope of the present invention, the second layer 3 is present or formed as a gas-permeable, in particular air-permeable, textile fabric.
[0307] The second layer 3, which functions particularly as the outer layer or outer material, also has a high level of stability and mechanical resilience.
[0308] Against this background, it can be provided in particular that the second layer 3 is designed as a textile knitwear, preferably as a warp-knitted fabric (knitted fabric) or a knitted fabric (knitted fabric), or in particular as a woven fabric, scrim, nonwoven or textile composite material.
[0309] In the context of the present invention, it has proven advantageous if the second layer 3 comprises or is formed from natural textile fibers and / or synthetic textile fibers (chemical fibers), preferably synthetic textile fibers, in particular as yarn and / or thread, in particular wherein the second layer 3 comprises or is formed from synthetic fibers (chemical fibers), optionally in combination with natural fibers, preferably cotton fibers, in particular as yarn and / or thread.
[0310] In particular, the second layer 3 can comprise or consist of a material, in particular textile fiber material, preferably textile fibers, in particular as a yarn and / or thread, selected from the group of natural materials and synthetic materials, in particular selected from the group of cotton (CO); wool; linen; polyesters; polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; aramids, in particular meta- and / or para-amides; optionally modified and / or regenerated celluloses; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof, preferably selected from the group of modified and / or regenerated celluloses, in particular viscose; aramids, in particular meta- and / or para-amides; polyamide and mixtures or combinations thereof.
[0311] Based on the specific design of the second layer 3, the material properties of the second layer 3 can be specifically specified or tailored while maintaining high mechanical and chemical resistance.
[0312] In addition, it can be provided according to the invention that the second layer 3 is elastic and / or reversibly stretchable. In this context, it can be provided in particular that the second layer 3 comprises elastane, in particular elastane fibers, in particular as a yarn and / or thread, in particular in an amount of at most 10 wt. %, preferably at most 5 wt. %, based on the second layer 3. As a result, the elasticity or the reversible stretchability of the second layer 3 can be increased or adjusted. With regard to the protective clothing 1 according to the invention, the wearing comfort and the fit of the protective clothing 1 can be specifically adjusted or improved on this basis. In particular, the wearing comfort is also improved as a result of an optimized fit of the protective clothing 1.
[0313] In addition, the second layer 3 can have a basis weight in the range of 5 g / m 2 up to 400 g / m 2 , especially in the range of 10 g / m 2up to 300 g / m 2 , preferably in the range of 20 g / m 2 up to 250 g / m 2 , particularly preferably in the range of 30 g / m 2 up to 175 g / m 2 , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%. In general, the second layer 3 can also have a basis weight in the range of 10 g / m 2 up to 600 g / m 2Furthermore, the second layer 3 can have a thickness, in particular cross-sectional thickness, in the range from 0.001 mm to 10 mm, in particular in the range from 0.01 mm to 8 mm, preferably in the range from 0.05 mm to 4 mm, more preferably in the range from 0.075 mm to 2 mm, particularly preferably in the range from 0.1 mm to 2 mm, further preferably in the range from 0.15 mm to 1 mm, in particular determined according to DIN EN ISO 5084. According to the invention, the second layer 3 can be flame-retardant and / or flame-retardant and / or fire-resistant and / or flame-resistant. In this context, the second layer 3 can have at least one flame-retardant or flame-retardant or fire-resistant or flame-resistant material, in particular in the form of or as a component of a yarn and / or thread.
[0314] In this context, the fire-resistant and / or flame-resistant material can be at least one aramid, in particular meta-aramid and / or para-aramid, and / or a modified and / or regenerated cellulose. Furthermore, the second layer 3 can comprise the flame-resistant and / or flame-retardant and / or fire-resistant and / or flame-resistant material in an amount ranging from 1 wt.% to 100 wt.%, in particular 2 wt.% to 95 wt.%, preferably 5 wt.% to 90 wt.%, based on the second layer 3.
[0315] Furthermore, the second layer 3 can be antistatic. In this context, the second layer 3 can comprise at least one antistatic material, in particular in the form of or as a component of a yarn and / or thread and / or thread. Furthermore, the second layer 3 can comprise the antistatic agent in an amount ranging from 0.1 wt.% to 10 wt.%, in particular 0.2 wt.% to 5 wt.%, preferably 0.5 wt.% to 3 wt.%, based on the second layer 3.
[0316] According to an embodiment of the invention, the second layer 3 may further comprise an oleophobic and / or hydrophobic finish. In this context, the finish may be in the form of an impregnation or coating, in particular using at least one fluorocarbon and / or at least one fluorohydrocarbon, in particular a fluorinated polymer.
[0317] As a result, the protective function against harmful or toxic substances can be further improved, since these can already bead up or be stopped on the surface of the protective clothing 1 according to the invention.
[0318] Furthermore, with regard to the arrangement of the second layer 3 in relation to the first layer 2, according to a first preferred embodiment of the invention, it can be provided that the second layer 3, in particular far away from and / or outside the connection region 5, is firmly connected (attached or fixed to) the first layer 2 only in sections, in particular linearly and / or at the edges, and is otherwise arranged loosely and / or unconnected to the first layer 2, in particular resting on it. This provides a certain degree of displaceability of the second layer 3 or the outer material with respect to the underlying first layer 2 or the inner material, which can be advantageous for the protective clothing 1 according to the invention, since this further improves the flexibility and conformability of the material.In particular, this also further improves wearing comfort.
[0319] According to an alternative embodiment to this, it can also be provided within the scope of the present invention that the second layer 3, in particular far away and / or outside the connection region 5, and the first layer 2 are firmly connected to one another (fastened, fixed) and / or adhered at their contact surfaces, in particular are firmly connected (fastened, fixed) and / or adhered at least substantially over the entire surface and / or at least substantially over the entire side, in particular are laminated, preferably are firmly connected (fastened, fixed) and / or adhered at least substantially over the entire surface, in particular are laminated.
[0320] In this context, the firm connection (fastening, fixing) and / or adhesion, in particular lamination, can be formed, for example, over the entire surface or over the entire contact surface, but discontinuously, preferably pointwise and / or with interruptions, in particular so that a composite and / or laminate results, in particular wherein the resulting composite and / or the laminate based on the first layer 2 and the third layer 3 is designed to be gas-permeable, in particular air-permeable, overall.
[0321] For this purpose, a water vapor and / or gas-permeable, preferably air-permeable, and / or discontinuous adhesive layer, in particular based on a corresponding bonding agent or adhesive, can be used. According to this embodiment of the invention, the second layer 3 or the outer fabric is attached or fixed to the first layer 2, in particular over its entire surface. Thus, a composite or laminate with correspondingly high mechanical strength or durability can also be used or present on this basis.
[0322] In addition, the second layer 3 can also be characterized by at least one of the following properties: - According to the invention, it can be provided that the second layer 3 has a gas permeability, in particular air permeability, of at least 2 mm / s, in particular at least 3 mm / s, preferably at least 7 mm / s, preferably at least 9 mm / s, particularly preferably at least 12 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal.
[0323] - Furthermore, the second layer 3 can have a gas permeability, in particular air permeability, in the range from 2 mm / s to 600 mm / s, in particular in the range from 3 mm / s to 500 mm / s, preferably in the range from 7 mm / s to 300 mm / s, preferably in the range from 9 mm / s to 200 mm / s, particularly preferably in the range from 12 mm / s to 150 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal.
[0324] Furthermore, as regards the third layer 4 of the protective clothing 1 according to the invention, it can be arranged as follows or in the protective clothing 1:
[0325] According to the invention, it can particularly be such that the third layer 4, in particular far away from and / or outside the connection area 5, defines and / or forms a transition area (transition section), in particular an opening area (opening section), and / or a sealing area, preferably for the particularly sealing reception (sealing contact) and / or passage of a body section, in particular a body part, of a wearer and / or user of the protective clothing 1 and / or preferably for the particularly sealing reception (sealing contact) and / or connection to further protective equipment, such as a respiratory mask 10, preferably an ABC respiratory mask, or the like. In this context, the third layer 4 can particularly be designed or function as a sealing element. In this context, reference can be made, for example, to Fig. 9A, Fig. 9B and Fig.9C, which illustrate an embodiment of the present invention, according to which the third layer 4 or the connecting region 5 is arranged in the region of a field of vision opening of a hood as a component of the protective clothing 1 according to the invention, namely for sealingly receiving (sealing fit) or for connection to a respiratory mask 10. In particular, Fig. 9A, Fig. 9B and Fig. 9C illustrate an embodiment of the invention, according to which the third layer 4, in particular far away from and / or outside the connecting region 5, defines or forms a field of vision opening, head opening, neck opening, abdominal and / or pelvic opening, arm and / or hand opening or a foot and / or leg opening, in particular a field of vision opening.
[0326] According to the invention, it can generally be provided that the third layer 4 is designed in the form of a band, in particular a flat band, or that the third layer 4 is designed in the form of a flat band with two opposite flat sides, as illustrated in particular in Fig. 9B and 9C (cf. also schematic illustration according to Fig. 1 to Fig. 6A / B).
[0327] In principle, the invention can provide for the third layer 4 to be formed in one piece and / or in one piece, in particular in one piece and / or in one piece, preferably with two ends. Thus, the third layer can have an interruption with a view to providing a circumferential seal, for example, to enable opening or closing by means of a zipper or the like.
[0328] According to a further embodiment of the invention, it can be provided that the third layer 4 is formed as a single piece and / or is integrally closed and / or continuous. This can enable particularly good sealing.
[0329] Specifically, according to the invention, as illustrated in Fig. 9A, Fig. 9B and Fig. 9C, it can be provided that the third layer 4, in particular far away from and / or outside the connecting region 5, defines and / or forms a field of vision opening for, in particular, sealingly receiving (sealing fit) and / or edge-covering a respiratory mask 10. In this context, the third layer 4 with the connecting region 5 can be part of a hood, (head) cap and / or balaclava (of the protective clothing 1). Furthermore, the third layer 4 with the connecting region 5 can be arranged in a hood, (head) cap and / or balaclava (of the protective clothing 1). In this regard, the third layer 4 can be designed to be elastic or reversibly stretchable or can be present as an elastic and / or reversibly stretchable sealing element.In this context, it can be provided in particular that the third layer 4 is designed as a preferably elastic and / or reversibly stretchable sealing element for preferably sealing contact with a respiratory mask 10, in particular wherein the third layer 4 is designed in the form of a band, in particular a flat band.
[0330] In particular, the third layer 4 is designed in the form of a flat band with two opposite flat sides. In this context, it can be provided in particular according to the invention that the third layer 4 is arranged or provided circumferentially in the edge region of a field of vision opening of the protective clothing 1 (cf. Fig. 9A, Fig. 9B and Fig. 9C). Furthermore, the third layer 4 can delimit the protective clothing 1 circumferentially at the edge to the field of vision opening, as also illustrated in particular in Fig. 9A. Furthermore, it can be provided according to the invention that the third layer 4, in particular the surface (sealing surface) of the third layer 4 that rests against the respiratory mask 10 when worn and / or in use, is at least substantially flat, in particular band-shaped or strip-shaped, as also shown in particular in Fig. 9B and Fig. 9C.
[0331] In addition, in the worn or used state, the third layer 4, in particular the surface (sealing surface) of the third layer 4 lying against the respiratory mask 10, can be at least substantially flat, in particular band-shaped or strip-shaped, lying against the respiratory mask 10 or can be designed to lie against it (cf. Fig. 9A, Fig. 9B and Fig. 9C).
[0332] Furthermore, the third layer 4, in the worn and / or used state, can rest with one of its flat sides, in particular at the edge, against the respiratory mask 10 and / or be positioned or arranged with one of its flat sides towards the respiratory mask 10, as shown in particular in Fig. 9A. In particular, the third layer 4, in the worn and / or used state, can have one of its flat sides facing the respiratory mask, as shown in particular in Fig. 9B and Fig. 9C. According to the invention, an effective seal against a respiratory mask in the field of vision of a wearer or user can thus be achieved.
[0333] Furthermore, according to the invention, it can also be provided that the third layer 4 is designed as a preferably elastic and / or reversibly stretchable sealing element for preferably sealingly abutting a body section, in particular a body part, of a wearer and / or user of the protective clothing 1. In this context, the third layer 4 can be arranged and / or provided circumferentially in the edge region of an opening in the protective clothing 1, wherein the third layer 4 delimits the protective clothing 1 circumferentially at the edge side from the opening. Furthermore, the third layer 4, in particular the surface (sealing surface) of the third layer 4 which bears against the body section, in particular a body part, in the worn and / or used state, can be designed to be at least substantially flat, in particular band-shaped or strip-shaped.
[0334] Furthermore, when worn or in use, the third layer 4, in particular the surface (sealing surface) of the third layer 4 that abuts the body portion, in particular the body part, can be designed to be at least substantially flat, in particular band-shaped or strip-shaped, against or adjacent to the body portion, in particular the body part. According to the invention, in addition to effective sealing against a respiratory mask, excellent sealing can also be achieved when accommodating or passing through body portions of the protective clothing 1, for example with regard to the arms and legs, the neck, or the field of vision of the wearer or user of the protective clothing 1 according to the invention.
[0335] According to the invention, it can also be provided that the third layer 4, in particular the flat side(s) of the third layer 4, is / are at least substantially bead-free and / or has / have at least substantially no elevations and / or at least substantially no projections and / or substantially no thickened portions. This can ensure particularly good sealing.
[0336] Furthermore, the third layer 4 can have a width in the range from 1 mm to 70 mm, in particular in the range from 5 mm to 50 mm, preferably in the range from 10 mm to 40 mm, more preferably in the range from 15 mm to 35 mm, particularly preferably in the range from 20 mm to 30 mm. Furthermore, the third layer 4 can have a height (thickness) in the range from 0.1 mm to 10 mm, in particular in the range from 0.2 mm to 8 mm, preferably in the range from 0.5 mm to 5 mm, preferably in the range from 0.75 mm to 4 mm, particularly preferably in the range from 1 mm to 3 mm.
[0337] In addition, the third layer 4 can have a basis weight in the range of 10 g / m 2 up to 1,000 g / m 2 , especially in the range of 50 g / m 2 up to 800 g / m 2 , preferably in the range of 100 g / m 2 up to 600 g / m 2 , particularly preferably in the range of 150 g / m 2 up to 500 g / m 2 , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%. In particular, the invention provides that the third layer 4 is water-impermeable and / or water vapor-impermeable, or that the third layer 4 is air-impermeable and water-impermeable and / or water vapor-impermeable.
[0338] According to the invention, the third layer 4 is generally designed to be elastic and / or reversibly stretchable. According to the invention, it has proven advantageous if the third layer 4 comprises or consists of at least one particularly elastic and / or particularly reversibly stretchable material. In this context, the particularly elastic and / or particularly reversibly stretchable material can comprise or consist of at least one elastomer, in particular a naturally based and / or synthetically based elastomer.
[0339] Furthermore, the particularly elastic and / or particularly reversibly stretchable material of the third layer 4 can be a rubber and / or caoutchouc material, in particular silicone rubber and / or butyl rubber, preferably butyl rubber.
[0340] In addition, the particularly elastic and / or particularly reversibly stretchable material of the third layer 4 can be a polyisoprene material.
[0341] Furthermore, the particularly elastic and / or particularly reversibly stretchable material of the third layer 4 can be a synthetic polymer, preferably based on a block copolymer with the components polyurethane and polyethylene glycol.
[0342] In other words, according to the invention, the third layer 4 comprises or consists of a rubber and / or caoutchouc material, in particular silicone rubber and / or butyl rubber, preferably butyl rubber.
[0343] Furthermore, the third layer 4 can comprise or consist of a polyisoprene material. Furthermore, the third layer 4 can comprise or consist of a synthetic polymer, preferably based on a block copolymer with the components polyurethane and polyethylene glycol. Based on the aforementioned materials, the third layer 4 ensures excellent elastic properties combined with high durability. Furthermore, the aforementioned materials also exhibit high chemical resistance, particularly against harmful or toxic substances.
[0344] According to an alternative embodiment of the present invention, it can also be provided in principle that the third layer 4 is formed as a multifilament yarn with a plurality of individual filaments made of the elastic and / or reversibly stretchable material of the third layer 4 and / or comprises such a multifilament yarn. In this case, it can also be provided in principle that the third layer 4 additionally contains a textile component. Nevertheless, even according to this embodiment, the third layer 4 is fundamentally a non-textile component within the meaning of the present invention, in particular since the functional properties are provided significantly by the polymer- or plastic-based components of the third layer 4, in particular with regard to the sealing provided according to the invention against body parts or items of equipment or the like.
[0345] According to a further embodiment of the invention, it can also be provided that the third layer 4 has a coating, preferably for the purposes of (supplementary) sealing, (supplementary) adhesion and / or (supplementary) non-slipping of the sealing element 4, in particular with respect to accommodated body portions of the wearer and / or user of the protective clothing 1 and / or with respect to the respiratory mask 10.
[0346] In this context, the coating can be arranged and / or applied on the side, in particular the flat side, of the third layer 4 facing the wearer and / or user of the protective clothing 1 in the wearing and / or use state of the respiratory mask 3 and / or the wearer and / or user of the protective clothing 1.
[0347] In this context, the coating may comprise or consist of a silicone and / or a silicone rubber.
[0348] Further details regarding embodiments or arrangements of the additional adsorption filter material 8 according to the invention are provided below: Thus, according to a preferred embodiment of the invention, the additional adsorption filter material 8 can be and / or configured to be gas-permeable, in particular air-permeable. In this regard, the additional adsorption filter material 8 can be present and / or configured as a gas-permeable, in particular air-permeable, textile fabric.
[0349] Fig. 8 A2 illustrates a two-layer structure of the additional adsorption filter material 8, while Fig. 8 B2 to D2 illustrate three- and four-layer structures.
[0350] Furthermore, the additional adsorption filter material 8 can have a textile carrier layer 8b (textile carrier layer of the additional adsorption filter material 8). In this context, the textile carrier layer 8b can be present and / or formed as a preferably gas-permeable, in particular air-permeable, textile sheet structure. Furthermore, the textile carrier layer 8b can be formed as a knitted fabric, in particular as a warp-knitted fabric (knitted fabric) or weft-knitted fabric (knitted fabric), woven fabric, scrim or textile composite material, in particular as a knit fabric.
[0351] In this regard, the textile carrier layer 8b may comprise or be formed from natural fibers and / or synthetic fibers (chemical fibers), preferably natural fibers, particularly preferably cotton fibers.
[0352] Likewise, the textile carrier layer 8b may comprise or be formed from natural fibers, particularly preferably cotton fibers, optionally in combination with synthetic fibers (chemical fibers).In addition, the textile carrier layer 8b can comprise or consist of a material, in particular textile fiber material, preferably textile fibers, in particular as a yarn and / or thread, selected from the group of natural materials and synthetic materials, in particular selected from the group of cotton (CO); wool; linen; polyesters; polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; aramids, in particular meta- and / or para-amides; optionally modified and / or regenerated celluloses; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof, preferably selected from the group of modified and / or regenerated celluloses, in particular viscose; aramids, in particular meta- and / or para-amides; polyamide and mixtures or combinations thereof.In addition, the textile carrier layer 8b can consist of a material, in particular textile fiber material, preferably textile fibers, in particular as yarn and / or thread, in the form of a mixture of cotton and polyester (CO / PES); or a mixture of polyamide and polyester (PA / PES); or a mixture of cotton and elastane (CO / EL); or a mixture of polyester and elastane (PES / EL); or a mixture of polyamide and elastane (PA / EL), preferably a mixture of cotton and elastane (CO / EL).
[0353] Furthermore, the textile carrier layer 8b can be designed to be elastic and / or reversibly stretchable, in particular wherein the textile carrier layer 2b comprises elastane, in particular elastane fibers, preferably in an amount of at most 20% by weight, preferably at most 15% by weight, based on the textile carrier layer 8b.
[0354] According to the invention, it can also be provided that the textile carrier layer 8b consists of a material, in particular textile fiber material, preferably textile fibers, in particular as yarn and / or thread, in the form of cotton (CO) or polyester (PES). Finally, the textile carrier layer 8b can have an antimicrobial, in particular antibacterial, finish.
[0355] In general, the textile carrier layer 8b can have a basis weight in the range of 2 2 2 2
[0356] 10 g / m to 350 g / m , in particular in the range from 20 g / m to 300 g / m , 2 2 preferably in the range from 30 g / m to 250 g / m , particularly preferably in the range from 50 g / m to 175 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%.
[0357] According to the invention, the textile carrier layer 8b can be arranged and / or positioned on the surface and / or side of the additional adsorption filter material 8 facing the wearer and / or user of the protective clothing 1 when the protective clothing 1 is worn and / or used ("inside of the additional adsorption filter material 8"). Furthermore, the textile carrier layer 8b can be arranged and / or positioned on the surface and / or side of the additional adsorption filter material 8 facing away from a source of pollutants and / or toxins ("inside of the additional adsorption filter material 8") when the protective clothing 1 is worn and / or used. According to a particularly preferred embodiment of the invention, the additional adsorption filter material 8 can have an adsorption layer 8a (adsorption layer of the additional adsorption filter material 8). In this context, the adsorption layer 8a can be discontinuous.Furthermore, the adsorption layer 8a can be gas-permeable, preferably air-permeable (cf. Fig. 8 A2, B2, C2 or D2).
[0358] In this context, the adsorption layer 8a may comprise or be formed from adsorber particles 8c (adsorber particles of the additional adsorption filter material 8), in particular a plurality of individual and / or discrete adsorber particles 8c.
[0359] In general, the adsorbent particles 8c of the adsorption layer 8a can be selected from the group of
[0360] (i) in particular particulate activated carbon and / or activated carbon particles, preferably in the form of activated carbon particles in granular form ("granular carbon") or activated carbon particles in spherical form ("spherical carbon");
[0361] (ii) zeolites, in particular natural and / or synthetic zeolites;
[0362] (iii) molecular sieves, in particular zeolitic molecular sieves, synthetic molecular sieves and / or in particular synthetic molecular sieves based on carbon, oxides and / or glasses;
[0363] (iv) metal oxide and / or metal particles;
[0364] (v) ion exchange resins, in particular polydisperse and / or monodisperse cation and / or anion exchangers, in particular of the gel type and / or macroporous type;
[0365] (vi) inorganic oxides, in particular silicon dioxides, silica gels and / or aluminum oxides;
[0366] (vii) porous organic polymers and / or porous organic-inorganic hybrid polymers and / or metal-organic framework materials, in particular MOFs (metal organic framework), COFs (covalent organic framework), ZI Fs (zeolite imidazolate framework), POMs (polymer organic material) and / or OFCs;
[0367] (viii) mineral granules;
[0368] (ix) clathrates; and
[0369] (x) mixtures and / or combinations thereof; with (i) being particularly preferred. According to a preferred embodiment of the invention, the adsorbent particles 8c of the adsorption layer 8a are activated carbon particles, preferably in the form of granular activated carbon particles ("granular carbon") or spherical activated carbon particles ("spherical carbon"), preferably in the form of spherical activated carbon particles.
[0370] According to the invention, however, it is also possible for the adsorber particles 8c of the adsorption layer 8a to be activated carbon fibers and / or activated carbon filaments, in particular in the form of an activated carbon fiber sheet.
[0371] In the preferred manner according to the invention, the adsorber particles 8c of the adsorption layer 8a are activated carbon particles, preferably in the form of activated carbon particles in granular form ("granular carbon") or activated carbon particles in spherical form ("spherical carbon"), preferably activated carbon particles in spherical form.
[0372] In this context, the adsorption layer 8a of the additional adsorption filter material 8 may have the following properties:
[0373] - In particular, it can be provided that the activated carbon has a total pore volume, in particular a total pore volume according to Gurvich, in the range of 0.3 cm 3 / g up to 3.8 cm 3 / g, especially in the range of 0.4 cm 3 / g up to 3.5 cm 3 / g, preferably in the range of 0.5 cm 3 / g up to 3 cm 3 / g, particularly preferably in the range of 0.6 cm 3 / g up to 2.5 cm 3 / g, most preferably in the range of 0.5 cm 3 / g to 1.5 cm 3 / g.
[0374] - In addition, it can be provided that at least 65%, in particular at least 70%, preferably at least 75%, preferably at least 80%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon is formed by pores with pore diameters of at most 50 nm, in particular by micropores and / or mesopores.
[0375] - According to the invention, it can also be such that 50% to 95%, in particular 60% to 90%, preferably 70% to 85%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon is formed by pores with pore diameters of at most 50 nm, in particular by micropores and / or mesopores. - In addition, it can be provided that 1% to 60%, in particular 5% to 50%, preferably 10% to 40%, more preferably 15% to 35%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon is formed by pores with pore diameters of more than 2 nm, in particular by mesopores and / or macropores.
[0376] - Furthermore, it can be provided according to the invention that the activated carbon has a pore volume formed by pores with pore diameters of at most 2 nm (ie < 2 nm), in particular micropore volume according to carbon black, in the range of 0.05 cm 3 / g up to 2.5 cm 3 / g, especially 0.15 cm 3 / g up to 2 cm 3 / g, preferably 0.3 cm 3 / g to 1.5 cm 3 / g, in particular wherein 15% to 98%, in particular 25% to 95%, preferably 35% to 90%, of the total pore volume of the activated carbon is formed by pores with pore diameters of at most 2 nm, in particular by micropores.
[0377] - Particularly good adsorption properties result when the activated carbon has a specific BET surface area in the range of 600 m 2 / g up to 4,000 m 2 / g, especially 800 m 2 / g up to 3,500 m 2 / g, preferably 1,000 m 2 / g up to 3,000 m 2 / g, particularly preferably 1,200 m 2 / g up to 2,750 m 2 / g, most preferably 1,300 m 2 / g up to 2,500 m 2 / g.
[0378] - Similarly, the activated carbon may have a surface area of 400 to 3,500 m formed by pores with diameters of not more than 2 nm, in particular by micropores 2 / g, especially 500 to 3,000 m 2 / g, preferably 600 to 2,500 m 2 / g, preferably 700 to 2,000 m 2 / g.
[0379] - According to the invention, it can also be provided that the activated carbon has a surface formed by pores with pore diameters in the range from 2 nm to 50 nm, in particular by mesopores, in the range from 200 to
[0380] 2 2
[0381] 2,000 m / g, in particular 300 to 1,900 m / g, preferably 400 to 1,800 m 2 / g, preferably 500 to 1,700 m 2 / g.
[0382] - In general, the activated carbon can have an average pore diameter in the range of 0.1 nm to 55 nm, in particular 0.2 nm to 50 nm, preferably 0.5 nm to 45 nm, more preferably 1 nm to 40 nm.
[0383] In addition, the adsorbent particles 8c of the adsorption layer 8a, in particular the activated carbon particles, can have a particle size, in particular a particle diameter, in the range from 0.05 mm to 2 mm, in particular in the range from 0.075 mm to 1 mm, preferably in the range from 0.1 mm to 0.5 mm, preferably in the range from 0.125 mm to 0.4 mm, particularly preferably in the range from 0.15 mm to 0.35 mm, in particular determined according to ASTM D2862.
[0384] In this context, it is particularly provided that at least 80 wt.%, in particular at least 90 wt.%, preferably at least 95 wt.%, preferably at least 99 wt.%, of the adsorbent particles 8c, in particular the activated carbon particles, have particle sizes, in particular particle diameters, in the aforementioned ranges.
[0385] According to the invention, it is also advantageous if the adsorbent particles 8c of the adsorption layer 8a, in particular the activated carbon particles, have an average particle size (D50), in particular an average particle diameter (D50), in the range from 0.05 mm to 1.5 mm, in particular in the range from 0.08 mm to 1 mm, preferably in the range from 0.1 mm to 0.75 mm, preferably in the range from 0.12 mm to 0.5 mm, particularly preferably in the range from 0.15 mm to 0.3 mm, in particular determined according to ASTM D2862.
[0386] In general, it can also be provided that the adsorber particles 8c of the additional adsorption filter material 8, in particular the activated carbon particles, are present in an amount in the range of 5 g / m 2 up to 500 g / m 2 , especially 10 g / m 2 up to 300 g / m 2 , preferably 30 g / m 2 up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2 , are used.
[0387] In this regard, it can also be provided according to the invention that the additional adsorption filter material 8, in particular the adsorption layer 8a, the adsorber particles 8c, in particular the activated carbon particles, in an amount in the range of 5 g / m 2 up to 500 g / m 2 , especially 10 g / m 2 up to 300 g / m 2 , preferably 30 g / m 2 up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2 , has.
[0388] In addition, the adsorption layer 8a can have a basis weight, in particular determined as dry weight, in the range of 5 g / m 2 up to 500 g / m 2 , especially 10 g / m 2 up to 300 g / m 2 , preferably 30 g / m 2 up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2 , in particular determined according to DIN EN 12127, preferably after drying for 1 hour at 105 °C.
[0389] According to an embodiment of the invention, the additional adsorption filter material 8 can have a textile spacer and / or intermediate layer 8d (cf. Fig. 8 B2 or D2). In particular, according to the invention, the textile spacer and / or intermediate layer 8d can be arranged in particular on the surface and / or side of the adsorption layer 8a opposite the carrier layer 8b.
[0390] In this context, the textile spacer and / or intermediate layer 8d can be present and / or formed as a preferably gas-permeable, in particular air-permeable, textile fabric.
[0391] In addition, the textile spacer and / or intermediate layer 8d can be designed as an air-permeable textile fabric, in particular as a knitwear, woven fabric, scrim or textile composite material, preferably nonwoven, particularly preferably as a nonwoven.
[0392] According to the invention, the textile spacer and / or intermediate layer 8d can comprise or be formed from natural fibers and / or synthetic fibers (chemical fibers), preferably synthetic fibers.
[0393] In this context, the textile spacer and / or intermediate layer 8d can comprise or consist of a material, in particular textile fiber material, preferably textile fibers, in particular as yarn and / or thread, selected from the group of synthetic materials, in particular selected from the group of polyesters; polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates; aramids, in particular meta- and / or para-amides; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof; preferably polyesters.
[0394] In general, the textile spacer and / or intermediate layer 8d can be a 2 2
[0395] Basis weight in the range of 5 g / m to 150 g / m , in particular in the range of 2 2 2 2
[0396] 10 g / m to 125 g / m , preferably in the range of 15 g / m to 100 g / m , particularly preferably in the range of 20 g / m to 75 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%.
[0397] Furthermore, the additional adsorption filter material 8 can have a particle and / or aerosol filter layer 8e (particle and / or aerosol filter layer of the additional adsorption filter material 8), preferably a particle and aerosol filter layer 8e (cf. Fig. 8 C2 and D2, respectively). In this context, the particle and / or aerosol filter layer 8e can be present and / or formed as a gas-permeable textile fabric comprising or formed from a plurality of individual textile fibers.
[0398] In addition, the particle and / or aerosol filter layer 8e can have or consist of at least one functional layer with particle and / or aerosol filter properties, in particular with particle and aerosol filter properties.
[0399] According to the invention, the particle and / or aerosol filter layer 8e can be designed to be gas-permeable, in particular air-permeable, and / or water vapor-permeable, preferably gas-permeable, in particular air-permeable, and water vapor-permeable, preferably air-permeable and water vapor-permeable.
[0400] According to the invention, the particle and / or aerosol filter layer 8e can in particular also have the following properties:
[0401] - In particular, the particle and / or aerosol filter layer 8e can have a (total)
[0402] 2 2
[0403] Basis weight in the range from 5 g / m to 200 g / m , in particular in the range from 10 g / m to 150 g / m , preferably in the range from 15 g / m to 120 g / m , preferably in the range from 20 g / m to 100 g / m , particularly preferably in the range from 25 g / m to 80 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%.
[0404] - In addition, the particle and / or aerosol filter layer 8e can have a thickness, in particular total cross-sectional thickness, in the range from 0.01 mm to 5 mm, in particular in the range from 0.03 mm to 3 mm, preferably in the range from 0.05 mm to 2 mm, preferably in the range from 0.07 mm to 1 mm, particularly preferably in the range from 0.09 mm to 0.75 mm, further preferably in the range from 0.1 mm to 0.5 mm, in particular determined according to DIN EN ISO 9073-2.
[0405] - Likewise, the particle and / or aerosol filter layer 8e, in particular the functional layer, can have a separation efficiency, in particular fractional separation efficiency, of at least 80%, in particular of at least 85%, preferably of at least 90%, preferably of at least 95%, determined according to DIN EN 1822 at a pressure difference of 15 Pascal with potassium chloride (KCl) as the test substance (in particular 1%) as the minimum efficiency (MPPS, in particular MPPS = 0.1 pm to 0.3 pm). - According to one embodiment of the invention, it is provided in particular that the particle and / or aerosol filter layer 8e is designed as a HEPA filter (High Efficiency Penetration or Particulate Air) or ULPA filter (Ultra Low Penetration or Particulate Air).
[0406] With regard to the particle and / or aerosol filter layer 8e, this or the corresponding functional layer can comprise and / or be formed from at least one textile fiber (functional layer textile fiber), preferably a plurality of textile fibers. Furthermore, the particle and / or aerosol filter layer 2e, in particular the functional layer, can comprise and / or be formed from a plurality of individual textile fibers (functional layer textile fibers).
[0407] In this regard, the textile fibers of the particle and / or aerosol filter layer 8e may behave in particular as follows:
[0408] - Thus, according to the invention, it can be provided that the textile fibers of the particle and / or aerosol filter layer 8e, in particular of the functional layer, have a fiber diameter in the range from 10 nm to 1,500 nm, in particular in the range from 50 nm to 1,000 nm, preferably in the range from 100 nm to 800 nm, preferably in the range from 150 nm to 600 nm, particularly preferably in the range from 200 nm to 400 nm, in particular determined according to DIN 53 811.
[0409] - In addition, it can be provided according to the invention that the textile fibers of the particle and / or aerosol filter layer 8e, in particular of the functional layer, are synthetic fibers (chemical fibers), in particular wherein the textile fibers of the functional layer are a material from the group of polyurethanes (PU); polyesters (PES); polyolefins (PO), such as polyethylene (PE), polypropylene (PP), polyoxyethylene and polyoxypropylene; polyvinyl chlorides (CLF); polyvinylidene chlorides (CLF); acetates (CA); triacetates (CTA); polyacrylic (PAN), in particular polyacrylonitriles; polyamides (PA); polyvinyl alcohol (PVAL); polyvinyl esters; poly(meth-)acrylates; polyvinylidene fluorides (PVDF); and mixtures and combinations thereof, preferably from the group of polyurethanes; polyesters, polyolefins, polyamides, polyacrylonitriles, poly(meth-)acrylates and polyvinylidene fluorides; their copolymers and their mixtures and combinations, preferably from the group of polyurethanes;Polyesters, polyolefins, and polyamides; their copolymers and their mixtures and combinations, most preferably polyurethanes. - According to the invention, it can also be such that the particle and / or aerosol filter layer 8e, in particular the functional layer, is polyurethane fibers and / or that the particle and / or aerosol filter layer 8e, in particular the functional layer, comprises or consists of polyurethane fibers.;
[0410] According to the invention, the particle and / or aerosol filter layer 8e, in particular the functional layer, can have an average pore size or average mesh size, in particular average pore size, in the range from 0.05 pm to 100 pm, in particular in the range from 0.1 pm to 50 pm, preferably in the range from 0.2 pm to 20 pm, more preferably in the range from 0.3 pm to 10 pm, particularly preferably in the range from 0.4 pm to 5 pm, further preferably in the range from 0.5 pm to 3 pm, in particular determined according to ASTM F316-86.
[0411] In addition, the particle and / or aerosol filter layer 8e can be formed in multiple layers, in particular in three layers, wherein the particle and / or aerosol filter layer 8e has at least one outer carrier layer and at least one functional layer arranged between the outer carrier layers, in particular connected to the outer carrier layers, with particle and / or aerosol filter properties, in particular with particle and aerosol filter properties, in particular wherein the particle and / or aerosol filter layer 8e is formed as a gas-permeable, in particular air-permeable, composite, preferably a laminate.
[0412] According to the invention, it is also advantageous if the particle and / or aerosol filter layer 8e, in particular the functional layer, is produced by electrospinning, spunbonding processes, meltblow processes or a combination of these processes, preferably by a combination of electrospinning and meltblow processes, or by electrospinning, preferably by electrospinning.
[0413] It is equally advantageous if the particle and / or aerosol filter layer 8e, in particular the functional layer, is formed as a scrim or textile composite material, in particular a nonwoven, particularly preferably as a nonwoven. Furthermore, the invention can provide that the particle and / or aerosol filter layer 8e, in particular the functional layer, is formed and / or is present as a scrim or textile composite material, in particular a nonwoven, particularly preferably as a nonwoven, based on and / or made of polyurethane fibers.
[0414] As regards the arrangement or positioning of the particle or aerosol filter layer 8e, it can be arranged directly on the adsorption layer 8a or on the spacer and / or intermediate layer 8d or connected thereto.
[0415] According to the invention, the particle and / or aerosol filter layer 8e can be arranged on the spacer and / or intermediate layer 8d and / or connected thereto, wherein the spacer and / or intermediate layer 8d is arranged on the surface and / or side facing away from the particle and / or aerosol filter layer 8e and / or connected thereto on the adsorption layer 8a.
[0416] According to the invention, the particle and / or aerosol filter layer 8e can be arranged between the adsorption layer 8a and the spacer and / or intermediate layer 8d or connected thereto.
[0417] In addition, it can be provided within the scope of the present invention that the spacer and / or intermediate layer 8d is arranged between the adsorption layer 8a and the particle and / or aerosol filter layer 8e and / or is firmly connected (attached, fixed) to the adsorption layer 8a and / or the particle and / or aerosol filter layer 8e, in particular (only) to the adsorption layer 8a, in particular by means of a preferably discontinuously, preferably punctiform, applied adhesive and / or by means of lamination.
[0418] According to an embodiment of the invention, the additional adsorption filter material 8 can have a textile cover layer (cover layer of the additional adsorption filter material 8).
[0419] In this context, the textile cover layer of the additional adsorption filter material 8 can in particular have the following properties: The textile cover layer can be arranged on the side of the adsorption layer 2a opposite the carrier layer 2b.
[0420] In addition, the textile covering layer can be designed as a gas-permeable, in particular air-permeable, textile fabric, in particular as a textile knitwear, preferably as a warp-knitted fabric (knitted fabric) or a woven fabric (knitted fabric), or in particular as a woven fabric, scrim, nonwoven or textile composite material.
[0421] Furthermore, the textile covering layer can comprise or be formed from natural textile fibers and / or synthetic textile fibers (chemical fibers), preferably synthetic textile fibers.
[0422] According to the invention, it can also be provided that the textile covering layer comprises synthetic fibers (chemical fibers), optionally in combination with natural fibers, preferably cotton fibers, or is formed therefrom.
[0423] According to the invention, it can also be provided that the textile cover layer of the additional adsorption filter material 8 comprises elastane (EL), in particular elastane fibers.
[0424] According to the invention, it can be provided in particular that the textile covering layer has a basis weight in the range of 5 g / m to 400 g / m ,
[0425] 2 2 in particular in the range from 10 g / m to 300 g / m , preferably in the range 2 2 2 from 20 g / m to 250 g / m , particularly preferably in the range from 30 g / m to o
[0426] 175 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65 %.
[0427] In addition, the textile cover layer can have a thickness, in particular cross-sectional thickness, in the range from 0.001 mm to 10 mm, in particular in the range from 0.01 mm to 8 mm, preferably in the range from 0.05 mm to 4 mm, preferably in the range from 0.075 mm to 2 mm, particularly preferably in the range from 0.1 mm to 2 mm, further preferably in the range from 0.15 mm to 1 mm, in particular determined according to DIN EN ISO 5084.
[0428] According to one embodiment of the invention, the textile covering layer can be a material, in particular textile fiber material, preferably textile fibers, selected from the group of natural materials and synthetic materials, in particular selected from the group of cotton (CO); wool; linen; polyesters; polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; aramids, in particular meta- and / or para-amides; optionally modified and / or regenerated celluloses; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof, preferably selected from the group of modified and / or regenerated celluloses, in particular viscose; aramids, in particular meta- and / or para-amides;polyamide and mixtures or combinations thereof;
[0429] According to the invention, the textile cover layer of the additional adsorption filter material 8 can be arranged directly on the adsorption layer 8a or on the particle and / or aerosol filter layer 8e and / or connected thereto. In particular, the particle and / or aerosol filter layer 8e can be arranged between the textile cover layer on the one hand and the adsorption layer 8a or the spacer and / or intermediate layer 8d on the other hand, or connected thereto.
[0430] According to the invention, it can also be provided that the adsorption layer 8a is fixed to the textile carrier layer 8b in particular by means of an adhesive that is preferably applied discontinuously, preferably in a point-like manner.
[0431] In addition, within the scope of the present invention, it may also be such that the spacer and / or intermediate layer 8d is fixed to the adsorption layer 8a in particular by means of an adhesive that is preferably applied discontinuously, preferably in a point-like manner.
[0432] Likewise, it is possible according to the invention for the textile covering layer to be fixed to the adsorption layer 8a or to the particle and / or aerosol filter layer 8e, in particular by means of an adhesive applied preferably discontinuously, preferably in a point-like manner, or by means of lamination.
[0433] In general, the additional adsorption filter material 8 can have a basis weight in the range of 10 g / m 2 up to 600 g / m 2 , especially in the range of 50 g / m 2 up to 500 g / m 2 , preferably in the range of 100 g / m 2 up to 450 g / m 2 , particularly preferably in the range of 150 g / m 2 up to 410 g / m 2, in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%. In addition, the additional adsorption filter material 8 can have a thickness, in particular a total cross-sectional thickness, in the range from 0.01 mm to 10 mm, in particular in the range from 0.05 mm to 5 mm, preferably in the range from 0.1 mm to 3 mm, preferably in the range from 0.2 mm to 2 mm, particularly preferably in the range from 0.5 mm to 2 mm, in particular determined according to DIN EN ISO 5084.
[0434] According to the invention, it can further be provided that the additional adsorption filter material 8 has a gas permeability, in particular air permeability, of at least 1 mm / s, in particular at least 2 mm / s, preferably at least 5 mm / s, preferably at least 7 mm / s, particularly preferably at least 10 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal.
[0435] In addition, within the scope of the present invention, the additional adsorption filter material 8 can have a gas permeability, in particular air permeability, in the range from 1 mm / s to 500 mm / s, in particular in the range from 2 mm / s to 400 mm / s, preferably in the range from 5 mm / s to 200 mm / s, preferably in the range from 7 mm / s to 150 mm / s, particularly preferably in the range from 10 mm / s to 100 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal.
[0436] In addition, the additional adsorption filter material 8 can also be characterized by one or more of the following properties:
[0437] - In particular, the additional adsorption filter material 8 can have a bursting pressure, in particular determined according to DIN EN ISO 13938-2, of at least 50 kPa (kilopascals), in particular of at least 75 kPa, preferably of at least 90 kPa, particularly preferably of at least 100 kPa.
[0438] - In addition, the additional adsorption filter material 8 can have a bursting pressure, in particular determined according to DIN EN ISO 13938-2, in the range from 50 kPa (kilopascals) to 1,000 kPa, in particular in the range from 75 kPa to 800 kPa, preferably in the range from 90 kPa to 600 kPa, particularly preferably in the range from 100 kPa to 500 kPa. - In addition, the additional adsorption filter material 8 can have a tensile stress and / or extensibility (elongation) in at least one direction, in particular in the longitudinal or transverse direction, determined according to DIN 53835-14 at 20 Newtons, of at least 2.5%, preferably of at least 5%, preferably of at least 7%.
[0439] - In addition, the additional adsorption filter material 8 can have a shrinkage in at least one direction, in particular in the longitudinal or transverse direction, determined according to DIN EN 5077, of at most 12%, preferably of at most 10%, preferably of at most 6%.
[0440] According to the present invention, it can be provided in particular that the additional adsorption filter material 8 consists of the same material as the first layer 2 or that the additional adsorption filter material 8 has the same structure and / or the same components and / or the same properties as the first layer 1. In this context, a material from the first layer 2 can thus be used for the additional adsorption filter material 8. This is accompanied by advantages in terms of manufacturing technology and better material utilization. In particular, there is also improved economics, namely also insofar as additional adsorption filter material 8 can be produced or provided, for example, from cutting remnants or the like of the material used for the first layer 2.
[0441] According to one embodiment of the invention, it has proven advantageous if the additional adsorption filter material 8 is three-layered and in particular designed as a composite and / or laminate. In this context, the additional adsorption filter material 8 can comprise or consist of (i) a textile carrier layer 8b (textile carrier layer of the additional adsorption filter material 8, in particular as defined above); (ii) an adsorption layer 8a (adsorption layer of the additional adsorption filter material 8), in particular as defined above; and (iii) a textile cover layer (cover layer of the additional adsorption filter material 8), in particular as defined above, or a textile spacer and / or intermediate layer 8d (textile spacer and / or intermediate layer of the additional adsorption filter material 8), in particular as defined above.Furthermore, the additional adsorption filter material 8 in this context can comprise the aforementioned layers (i) to (iv) in the order and / or sequence (i), (ii), (iii), (iv).
[0442] According to a further embodiment of the invention, it can also be provided that the additional adsorption filter material 8 is four-layered and in particular is designed as a composite and / or laminate.
[0443] In this context, it can be provided that the additional adsorption filter material 8 comprises or consists of (i) a textile carrier layer 8b (textile carrier layer of the additional adsorption filter material 8), in particular as defined above; (ii) an adsorption layer 8a (adsorption layer of the additional adsorption filter material 8), in particular as defined above; (iii) a particle and / or aerosol filter layer 8e (particle and / or aerosol filter layer of the additional adsorption filter material 8), in particular as defined above; and (iv) a textile cover layer (cover layer of the additional adsorption filter material 8), in particular as defined above, or a textile spacer and / or intermediate layer 8d (textile spacer and / or intermediate layer of the additional adsorption filter material 8), in particular as defined above.In this regard, it can be provided according to the invention that the additional adsorption filter material 8 has the aforementioned layers (i) to (iv) in the series and / or sequence (i), (ii), (iii), (iv).
[0444] As shown or illustrated in Fig. 6A and Fig. 6B or Fig. 6C, it can be provided according to an embodiment of the invention that at least one of the opposite edges and / or edges running and / or arranged along the seam 7, in particular along the seam path of the seam 7, of the additional adsorption filter material 8, in particular the edge of the additional adsorption filter material 8 oriented towards the main extension of the third layer 4 and / or in particular the edge of the additional adsorption filter material 8 oriented towards the main extension of the first layer 2 and / or the second layer 3, preferably the edge of the additional adsorption filter material 8 oriented towards the main extension of the third layer 4, is hemmed and / or is provided and / or equipped with at least one hem and / or edge reinforcement and / or securing means 9, in particular in the form of a closing and / or sealing seam.This also counteracts premature wear. In particular, it prevents any possible loss or leakage of the adsorption material, such as activated carbon beads or the like. Furthermore, fraying or similar phenomena in the edge region of the additional adsorption filter material 8 can be counteracted.
[0445] In particular, it can be provided according to the invention that the edge of the additional adsorption filter material 8 oriented towards the main extension of the third layer 4 is hemmed and / or provided and / or equipped with at least one hem and / or edge reinforcement and / or securing means 9 (first hem and / or edge reinforcement and / or securing means 9), in particular in the form of a finishing and / or closure seam, preferably a finishing seam (cf. Fig. 6A, 6B).
[0446] According to the invention, it can also be provided that the edge of the additional adsorption filter material 8 oriented towards the main extension of the first layer 2 and / or the second layer 3 is hemmed and / or provided and / or equipped with at least one hem and / or edge reinforcement and / or securing means 9' (second hem and / or edge reinforcement and / or securing means 9'), in particular in the form of a finishing and / or closure seam, preferably a finishing seam.
[0447] The first hem and / or edge reinforcement and / or securing means 9' and the second hem and / or edge reinforcement and / or securing means 9' can be realized independently of one another or can be realized together (cf. Fig. 6C).
[0448] Furthermore, Fig. 6B shows an embodiment according to the invention, according to which the protective clothing has a securing and / or stabilizing seam 11, in particular a topstitching seam, in the connecting region 5, in particular wherein the connecting region 5 has a securing seam 11, in particular a topstitching seam.
[0449] In this context, the securing and / or stabilizing seam 11 can run at least substantially parallel to the seam 7.
[0450] In addition, the securing and / or stabilizing seam 11 can be arranged on the side of the seam 4 facing away from the direction of extension of the third layer 4, in particular wherein the securing and / or stabilizing seam 11 is arranged on the side of the seam 4 facing the direction of extension of the first layer 2 and / or the second layer 3. Furthermore, the securing and / or stabilizing seam 11 can encompass the first layer 2, the second layer 3, the third layer 4, and the additional adsorption filter material 8, in particular penetrating or passing through each of them.
[0451] Furthermore, in this context it can further be provided in particular that the securing and / or stabilizing seam 11, in the event of the first layer 2 and / or the second layer 3, in particular the first layer 2 and the second layer 3, being turned over and / or folded over, in particular as previously defined, encompasses, in particular penetrates or passes through, both the turned over and / or folded over area and the non-turned over and / or non-folded area of the first layer 2 and / or the second layer 3, in particular the first layer 2 and the second layer 3.
[0452] The securing or stabilizing seam also further fixes the non-folded part or section of the second layer 3, which prevents displacement or slipping of the second carrier layer 3, in particular in the direction of the third (sealing) layer 4.
[0453] According to the invention, the protective clothing can be designed in particular in the form of a headgear and / or hood, in particular in the form of a hood or a balaclava, in particular as illustrated in Fig. 9A. In particular, the protective clothing 1 can comprise a headgear and / or hood, in particular a hood or a balaclava.
[0454] In this context, the connecting region 5, in particular with the third layer 4, can define or delimit a field of vision opening, in particular for sealingly receiving a respiratory mask 10 (cf. in particular Fig. 9B and Fig. 9C).
[0455] The protective clothing according to the invention or the corresponding connecting area 5 has overall excellent protective properties against harmful or toxic substances:
[0456] Thus, the protective clothing 1, in particular also in the connection area 5, preferably the seam area 6, can have a barrier effect against harmful and / or toxic substances, in particular chemical warfare agents, in particular bis[2-chloroethyl] sulfide (mustard gas, HD), determined according to method 2.2 of CRDEC-SP-84010, of at most 4 pg / cm 2 per 24 hours, in particular not more than 3.5 pg / cm 2 per 24 hours, preferably not more than 3.0 pg / cm 2 per 24 hours, preferably not more than 2.5 pg / cm 2 per 24 hours, particularly preferably not more than 2.25 pg / cm 2 per 24 hours, most preferably not more than 2 pg / cm 2 per 24 hours, more preferably not more than 1.75 pg / cm 2 per 24 hours.
[0457] In addition, the protective clothing 1, in particular also in the connection area 5, preferably the seam area 6, can have a barrier effect against harmful and / or toxic substances, in particular chemical warfare agents, in particular bis[2-chloroethyl]sulfide (mustard gas, HD), determined according to the Laid Drop Diffusive Flow Test of at most 4 pg / cm 2 per 24 hours, in particular not more than 3.5 pg / cm 2 per 24 hours, preferably not more than 3.0 pg / cm 2 per 24 hours, preferably not more than 2.5 pg / cm 2 per 24 hours, particularly preferably not more than 2.25 pg / cm 2 per 24 hours, most preferably not more than 2 pg / cm 2 per 24 hours, more preferably not more than 1.75 pg / cm 2per 24 h, in particular measured as cumulative breakthrough by gas chromatography (GC / FPD) after exposure to mustard gas for 24 h at a temperature of 23 °C and a relative humidity of not more than 5 % RH, in particular with a material sample area of 10 cm 2, a material exposure to 8 mustard gas drops (each drop volume = 1 pl), a test execution in a test cell above a PE membrane (10 pm), a flow under the material of 100 ml / min, a flow above the material of 0.5 m / s and a flow through the material of 0 cm / s. Within the framework of the aforementioned diffusion flow test, the procedure can be such that the air flow under the material sample is drawn through a wash bottle, for example, and the cumulative breakthrough is then measured using gas chromatography, as previously described. The diffusion flow test simulates the diffusion of liquid warfare agent through the underlying protective material without convection and thereby simulates the flat contact of the protective clothing on the skin, the latter being simulated by the PE membrane.
[0458] In addition, the following embodiments of the protective clothing according to the invention are also the subject of the present aspect:
[0459] Thus, the present invention also relates to protective clothing 1 with a protective function against chemical and / or biological and / or radioactive pollutants and / or poisons (warfare agents) ("ABC or CBRN protective function"), in particular ABC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, wherein the protective clothing 1
[0460] (a) a first, in particular flat and / or two-dimensional, layer 2 in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer 2a and a textile carrier layer 2b ("adsorption layer carrier"),
[0461] (b) a second, in particular flat and / or two-dimensional, layer 3 in the form of a textile air-permeable covering material ("top layer", "outer fabric") and
[0462] (c) a third, in particular flat and / or two-dimensional, layer 4 in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers 2, 3, 4 are arranged and / or positioned overlapping one another in a connecting region 5 and are connected, in particular sewn, to one another in the connecting region 5 with a common seam 7 forming a seam region 6 ("layer connecting seam"), wherein at least in the seam region 6 an additional multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped or band-shaped, adsorption filter material 8,in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area 6 and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area 6, wherein the additional adsorption filter material 8 is connected, in particular sewn, to the layers 2, 3, 4 by means of the seam 7 (the same seam 7), wherein the additional adsorption filter material 8 has an adsorption layer 8a and a textile carrier layer 8b, in particular wherein the adsorption layer 8a is arranged on the carrier layer 8b and / or firmly connected (attached, fixed) to the carrier layer 8b, preferably by means of lamination, preferably by means of a first adhesive layer, and wherein the additional adsorption filter material 8 is flat and / or two-dimensional,in particular in the form of a strip (band) and / or strip-shaped (band-shaped).
[0463] According to the present aspect, the present invention also relates to protective clothing 1 with a protective function against chemical and / or biological and / or radioactive pollutants and / or poisons (warfare agents) ("ABC or CBRN protective function"), in particular ABC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, in particular a protective clothing 1 as defined above, wherein the protective clothing 1
[0464] (a) a first, in particular flat and / or two-dimensional, layer 2 in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer 2a and a textile carrier layer 2b ("adsorption layer carrier"),
[0465] (b) a second, in particular flat and / or two-dimensional, layer 3 in the form of a textile air-permeable covering material ("top layer", "outer fabric") and
[0466] (c) a third, in particular flat and / or two-dimensional, layer 4 in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers 2, 3, 4 are arranged and / or positioned overlapping one another in a connecting region 5 and are connected, in particular sewn, to one another in the connecting region 5 with a common seam 7 forming a seam region 6 ("layer connecting seam"), wherein at least in the seam region 6 an additional multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped or band-shaped, adsorption filter material 8,in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area 6 and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area 6, is arranged and / or provided and / or is present, wherein the additional adsorption filter material 8 is connected, in particular sewn, to the layers 2, 3, 4 by means of the seam 7 (the same seam 7), wherein in the connecting area 5, in particular in the seam area 6, the third layer 4 with the additional adsorption filter material 8 is arranged and / or positioned between the first layer 2 and the second layer 3, and wherein in the connecting area 5, in particular in the seam area 6, the additional adsorption filter material 8 is arranged and / or positioned between the third layer 4 and the first layer 2,wherein the additional adsorption filter material 8 comprises an adsorption layer 8a and a textile carrier layer 8b, in particular wherein the adsorption layer 8a is arranged on the carrier layer 8b and / or is firmly connected (attached, fixed) to the carrier layer 8b, preferably by means of lamination, preferably by means of a first adhesive layer, and wherein the additional adsorption filter material 8 is flat and / or two-dimensional, in particular in the form of a strip (band) and / or strip-shaped (band-shaped).
[0467] In addition, according to the present aspect, the present invention also relates to protective clothing 1 with a protective function against chemical and / or biological and / or radioactive pollutants and / or poisons (warfare agents) ("ABC or CBRN protective function"), in particular ABC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, wherein the protective clothing 1
[0468] (a) a first, in particular flat and / or two-dimensional, layer 2 in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer 2a and a textile carrier layer 2b ("adsorption layer carrier"),
[0469] (b) a second, in particular flat and / or two-dimensional, layer 3 in the form of a textile, air-permeable covering material ("top layer", "outer fabric") and (c) a third, in particular flat and / or two-dimensional, layer 4 in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers 2, 3, 4 are arranged and / or positioned overlapping one another in a connecting region 5 and are connected, in particular sewn, to one another in the connecting region 5 with a common seam 7 forming a seam region 6 ("layer connecting seam"), wherein at least in the seam region 6 an additional multi-layer, in particular at least two-layer, textile, air-permeable, preferably strip-shaped or band-shaped, adsorption filter material 8,in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area 6 and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area 6, is arranged and / or provided and / or is present, wherein the additional adsorption filter material 8 is connected, in particular sewn, to the layers 2, 3, 4 by means of the seam 7 (the same seam 7), wherein in the connecting area 5, in particular in the seam area 6, the third layer 4 with the additional adsorption filter material 8 is arranged and / or positioned between the first layer 2 and the second layer 3 and wherein in the connecting area 5, in particular in the seam area 6, the additional adsorption filter material 8 is arranged and / or positioned between the third layer 4 and the first layer 2 and / or wherein in the connecting area 5,in particular in the seam area 6, the layers 2, 3, 4 and the additional adsorption filter material 8 are arranged and / or positioned in the following sequence: (i) first layer 2, (ii) additional adsorption filter material 8, (iii) third layer 4; (iv) second layer 3, wherein the first layer 2 and / or the second layer 3, in particular the first layer 2 and the second layer 3, are each folded and / or folded over in the connection area 5 in the direction of the third layer 4 and / or the additional adsorption filter material 8, in particular folded over and / or folded over at the edges, wherein the additional adsorption filter material 8 has an adsorption layer 8a and a textile carrier layer 8b, in particular wherein the adsorption layer 8a is arranged on the carrier layer 8b and / or is firmly connected (attached, fixed) to the carrier layer 8b, preferably by means of lamination, preferably by means of a first adhesive layer,and wherein the additional adsorption filter material 8 is flat and / or two-dimensional, in particular in the form of a strip (band) and / or strip-shaped (band-shaped).
[0470] Furthermore, according to the underlying aspect, the present invention also relates to protective clothing 1 with a protective function against chemical and / or biological and / or radioactive pollutants and / or poisons (warfare agents) ("ABC or CBRN protective function"), in particular ABC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, wherein the protective clothing 1
[0471] (a) a first, in particular flat and / or two-dimensional, layer 2 in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer 2a and a textile carrier layer 2b ("adsorption layer carrier"),
[0472] (b) a second, in particular flat and / or two-dimensional, layer 3 in the form of a textile air-permeable covering material ("top layer", "outer fabric") and
[0473] (c) a third, in particular flat and / or two-dimensional, layer 4 in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers 2, 3, 4 are arranged and / or positioned overlapping one another in a connecting region 5 and are connected, in particular sewn, to one another in the connecting region 5 with a common seam 7 forming a seam region 6 ("layer connecting seam"), wherein at least in the seam region 6 an additional multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped or band-shaped, adsorption filter material 8,in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area 6 and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area 6, is arranged and / or provided and / or is present, wherein the additional adsorption filter material 8 is connected, in particular sewn, to the layers 2, 3, 4 by means of the seam 7 (the same seam 7), wherein in the connecting area 5, in particular in the seam area 6, the third layer 4 with the additional adsorption filter material 8 is arranged and / or positioned between the first layer 2 and the second layer 3 and wherein in the connecting area 5, in particular in the seam area 6, the additional adsorption filter material 8 is arranged and / or positioned between the third layer 4 and the first layer 2 and / or wherein in the connecting area 5,in particular in the seam area 6, the layers 2, 3, 4 and the additional adsorption filter material 8 are arranged and / or positioned in the following sequence: (i) first layer 2, (ii) additional adsorption filter material 8, (iii) third layer 4; (iv) second layer 3, wherein the first layer 2 and / or the second layer 3, in particular the first layer 2 and the second layer 3, are each folded and / or turned over in the connection region 5 in the direction of the third layer 4 and / or the further adsorption filter material 8, in particular folded and / or turned over at the edges, wherein the seam 7, with respect to the first layer 2 and the second layer 3, only the folded and / or turned over regions of the first layer 2 and the second layer 3, in particular the folded and / or turned over regions of the first layer 2 and the second layer 3 that are in direct contact with the third layer 4 or the additional adsorption filter material 8,and connects it to the third layer 4 and the additional adsorption filter material 8; and / or wherein the additional adsorption filter material 8 comprises an adsorption layer 8a and a textile carrier layer 8b, in particular wherein the adsorption layer 8a is arranged on the carrier layer 8b and / or is firmly connected (attached, fixed) to the carrier layer 8b, preferably by means of lamination, preferably by means of a first adhesive layer, and wherein the additional adsorption filter material 8 is flat and / or two-dimensional, in particular in the form of a strip (band) and / or strip-shaped (band-shaped).
[0474] With regard to the present aspect, reference can also be made to the statements regarding the further aspects of the present invention, which apply accordingly in this case. Furthermore, according to a further aspect of the present invention, the present invention relates to the protective material 1 according to the invention with a protective function against chemical and / or biological and / or radioactive pollutants and / or toxic substances (warfare agents) ("NBC or CBRN protective function"), in particular for NBC protective clothing ("CBRN protective clothing"), preferably for civilian or military purposes, wherein the protective material 1
[0475] (a) a first, in particular flat and / or two-dimensional, layer 2 in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer 2a and a textile carrier layer 2b ("adsorption layer carrier"),
[0476] (b) a second, in particular flat and / or two-dimensional, layer 3 in the form of a textile air-permeable covering material ("top layer", "outer fabric") and
[0477] (c) has a third, in particular flat and / or two-dimensional, layer 4 in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers 2, 3, 4 are arranged and / or positioned overlapping one another in a connecting region 5 and are connected, in particular sewn, to one another in the connecting region 5 with a common seam 7 forming a seam region 6 ("layer connecting seam"), wherein at least in the seam region 6 an additional multi-layered, in particular at least two-layered, textile air-permeable, preferably strip-shaped orband-shaped adsorption filter material 8, in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam region 6 and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam region 6, is arranged and / or provided and / or is present, wherein the additional adsorption filter material 8 is connected, in particular sewn, to the layers 2, 3, 4 by means of the seam 7 (the same seam 7). With regard to the present aspect, reference can also be made in addition to the statements on the further aspects of the present invention, which apply accordingly in the present case.
[0478] The present invention also relates - according to yet another aspect of the present invention - to protective equipment or protective articles of all kinds, in particular for the civilian or military sector, in particular protective clothing, such as protective suits, protective gloves, protective footwear, protective socks, head protection clothing and the like, as well as protective covers, preferably all of the aforementioned protective equipment and / or protective articles for NBC use and / or with a protective function against chemical and / or biological and / or radioactive pollutants and / or toxic substances, manufactured using a protective material as defined above and / or comprising a protective material as defined above.
[0479] According to the present aspect, the present invention also relates to filters and filter materials of all kinds, in particular for the removal of chemical and / or biological and / or radioactive pollutants and / or toxins, in particular from air and / or gas streams, such as protective mask filters, odor filters, surface filters, air filters, in particular filters for room air purification, adsorptive support structures and filters for the medical sector, produced using a protective material as defined above and / or comprising a protective material as defined above.
[0480] With regard to the present aspect, reference can also be made to the statements relating to the further aspects of the present invention, which apply accordingly in this case.
[0481] In addition, the present invention - according to yet another aspect of the present invention - also relates to the inventive use of a protective material as defined above for the production of protective equipment and / or protective articles of all kinds, in particular protective clothing, in particular for the civil or military sector, such as protective suits, protective gloves, protective footwear, protective socks, head protection clothing and the like, and protective coverings of all kinds, preferably all of the aforementioned protective materials for NBC use and / or with a protective function against chemical and / or biological and / or radioactive pollutants and / or toxic substances.In this context, the present invention according to the present aspect also relates to the use of a protective material as defined above for the production of filters and filter materials of all kinds, in particular for the removal of chemical and / or biological and / or radioactive pollutants and / or toxins, in particular from air and / or gas streams, such as ABC protective mask filters, odor filters, surface filters, air filters, in particular filters for room air purification, adsorptive support structures and filters for the medical sector.
[0482] With regard to the present aspect, reference can also be made to the statements relating to the further aspects of the present invention, which apply accordingly in this case.
[0483] The present invention further relates - according to yet another aspect of the present invention - to the method according to the invention for sealing a connecting region 5 of a plurality of layers 2, 3, 4, in particular a textile air-permeable first layer 2, a textile air-permeable second layer 3 and a non-textile air-impermeable third layer 4, of a protective clothing 1 and / or a protective material 1 against chemical and / or biological and / or radioactive pollutants and / or toxic substances, wherein the layers 2, 3, 4 are arranged and / or positioned overlapping one another in the connecting region 5 and are connected, in particular sewn, to one another in the connecting region 5 with a common seam 7 forming a seam region 6 ("layer connecting seam"), wherein at least in the seam region 6 an additional multi-layer, in particular at least two-layered, textile air-permeable,Preferably, an adsorption filter material 8, preferably in strip-shaped or band-shaped form, is arranged and / or provided, in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam region 6 and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam region 6, wherein the additional adsorption filter material 8 is connected, in particular sewn, to the layers 2, 3, 4 by means of the seam 7 (the same seam 7). With regard to the present aspect, reference can also be made to the statements regarding the further aspects of the present invention, which apply accordingly in this case.
[0484] Furthermore, the present invention - according to a further aspect of the present invention - also relates to the inventive use of an (additional) adsorption filter material 8, in particular an (additional) multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped or band-shaped adsorption filter material 8, in a connecting region 5, in particular seam region 6, of a protective clothing 1 and / or a protective material 1 for forming and / or providing a sealing connection against chemical and / or biological and / or radioactive pollutants and / or toxins of layers 2, 3, 4 arranged and / or positioned overlapping one another in the connecting region 5, in particular a textile air-permeable first layer 2, a textile air-permeable second layer 3 and a non-textile air-impermeable third layer 4, wherein the layers 2, 3,4 are connected, in particular sewn, to one another in the connecting region 5 with a common seam 7 forming a seam region 6 ("layer connecting seam"), and wherein the additional adsorption filter material 8 is arranged and / or provided at least in the seam region 6, wherein the additional adsorption filter material 8 is connected, in particular sewn, to the layers 2, 3, 4 by means of the seam 7 (the same seam 7), in particular for the purpose of adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam region 6 by the additional adsorption filter material 8 and / or in particular for the purpose of preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam region 6 through the additional adsorption filter material 8.
[0485] According to the present aspect, the present invention also relates to the inventive use of an (additional) adsorption filter material 8, in particular an (additional) multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped or.band-shaped adsorption filter material 8, in a connecting region 5, in particular seam region 6, of a protective clothing 1 and / or a protective material 1 for forming and / or providing a sealing connection against chemical and / or biological and / or radioactive pollutants and / or poisons of layers 2, 3, 4, namely at least one textile air-permeable layer 2, 3 on the one hand and a non-textile air-impermeable layer 4 on the other hand, which are arranged and / or positioned overlapping one another in the connecting region 5 and are connected, in particular sewn, to one another in the connecting region 5 with a common seam 7 ("layer connecting seam") forming the seam region 6.
[0486] In this regard, it can be provided according to the invention that the additional adsorption filter material 8 is arranged and / or provided at least in the seam region 6, wherein the additional adsorption filter material 8 is connected, in particular sewn, to the layers 2, 3, 4 by means of the seam 7 (the same seam 7).
[0487] With regard to the present aspect, reference can also be made to the statements relating to the further aspects of the present invention, which apply accordingly in this case.
[0488] As regards the above-described method according to the invention or the uses according to the invention according to the preceding aspects, it is particularly provided that (a) the first, in particular flat and / or two-dimensional, layer 2 is in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer 2a and a textile carrier layer 2b ("adsorption layer carrier"), that (b) the second, in particular flat and / or two-dimensional, layer 3 is in the form of a textile air-permeable cover material ("top layer", "outer fabric") and that (c) the third,in particular flat and / or two-dimensionally formed, layer 4 is present and / or formed in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material.,
[0489] Further embodiments, modifications, variations, modifications, special features, and advantages of the present invention will be readily apparent and achievable to those skilled in the art upon reading the description, without departing from the scope of the present invention. The present invention is illustrated by the following exemplary embodiments, which, however, are not intended to limit the present invention in any way.
[0490] EXAMPLES OF IMPLEMENTATION:
[0491] Versions A: Materials
[0492] Different protective materials according to the invention or related protective clothing are produced, namely protective materials or clothing according to the invention (material A1, A2, A3 and B1, B2 and B3) on the one hand and comparison protective materials or clothing (material C1, D1 and E1) on the other hand.
[0493] For the materials A1, A2, and A3 according to the invention, a textile sheet material in the form of a laminate is used for the first layer, which comprises a textile carrier layer, an adsorption layer with activated carbon particles applied thereto, a particle or aerosol filter layer applied to the adsorption layer, and a cover or spacer or intermediate layer applied to this layer. The carrier layer is in the form of a knitted fabric based on a cotton / elastane blend with antibacterial treatment and has a basis weight of approximately 115 g / m² 2For the adsorption layer, adsorbent particles in the form of particulate activated carbon in spherical form (activated carbon particles in spherical form) are used. The activated carbon used has a total pore volume according to Gurvich of approximately 0.8 cm 3 / g, a specific BET surface area of about 1,900 m 2 / g and an average pore diameter of approximately 25 nm. Furthermore, the spherical activated carbon used has an average particle diameter D50 of approximately 0.25 mm. The particle or aerosol filter layer is also in the form of a polyurethane fleece and has a surface weight of approximately 30 g / m 2 A polyamide-based knit fabric is used as the cover, spacer, or intermediate layer. This layer has a surface weight of approximately 54 g / m 2 on.
[0494] For the inventive materials B1, B2, and B3, as well as the comparative materials C1, D1, and E1, a corresponding textile adsorption filter material is used for the first layer therein, but with the proviso that the relevant material, in contrast to the first layer of materials A1, A2, and A3, does not comprise a particle or aerosol filter layer. The first layer for materials B1, B2, B3, as well as C1, D1, and E1, is thus based on a laminate, which in turn is formed from a textile carrier layer, as previously mentioned, an adsorption layer, as previously mentioned, and a cover, spacer, or intermediate layer, as previously mentioned (and thus does not have a particle or aerosol filter layer). Furthermore, for all materials A1, A2, A3 or B1, B2 and B3 as well as C1, D1 and E1, a second layer in the form of a textile, air-permeable covering material based on para-aramid (Nomex®) is used.The second layer is thus flame-retardant and / or flame-retardant and / or fire-resistant and / or flame-resistant. Furthermore, the material of the second layer exhibits oleophobic or hydrophobic properties through an impregnation or coating based on a fluorinated polymer.
[0495] For all materials A1, A2 and A3 as well as B1, B2 and B3 as well as C1, D1 and E1, the third layer is formed in the form of a non-textile polymer-based or plastic-based and air-impermeable surface material based on butyl rubber.
[0496] Furthermore, with regard to the additional adsorption filter material used for materials A1, A2, and A3, as well as B1, B2, and B3, this is formed or cut in a band- or strip-shaped manner, wherein the additional adsorption filter material is made of the same material as the textile sheet material used for the first layer of materials A1, A2, and A3. The additional adsorption filter material thus equally comprises a textile carrier layer, an adsorption layer with activated carbon particles applied thereto, a particle or aerosol filter layer applied to the adsorption layer, and a cover, spacer, or intermediate layer applied to this layer, as previously defined for materials A1, A2, and A3 with respect to the first layer.
[0497] In the case of materials A1 and B1, the connecting region is further designed such that the third layer is arranged on the surface or side of the second layer facing away from the first layer and after which the additional adsorption filter material is positioned on the surface or side of the third layer facing away from the second layer and thus on the outside on or above the third layer (layer sequence in the connecting region: first layer, second layer, additional adsorption filter material, third layer), wherein the first, second and third layers as well as the additional adsorption filter material are connected in the connecting region with a common seam (see also embodiment according to Fig. 3).A comparable structure is realized for material C1, but with the proviso that material C1 does not have any additional adsorption filter material (layer sequence in the connection area: first layer, second layer, third layer); in the connection area, these layers are similarly connected with a common seam.
[0498] For material D1, a similar structure is implemented in the joining area; the first layer, second layer, and third layer are joined with a common seam. Furthermore, for material D1, instead of the additional adsorption filter material, a non-textile, polymer-based, air- and water-impermeable sealing tape is applied to the outside of the joining area (i.e., on the side or surface of the third layer facing away from the second layer) using an adhesive or pressure-sensitive adhesive applied over the entire area, covering the outside of the seam or seam area (layer sequence in the joining area: first layer, second layer, third layer, non-textile sealing tape).
[0499] For materials A2 and B2, the third layer with the additional adsorption filter material is arranged between the first layer and the second layer, with the additional adsorption filter material being positioned between the third layer and the first layer and thus, so to speak, on the inside of or below the third layer (layer sequence in the connecting area: first layer, additional adsorption filter material, third layer, second layer); moreover, the first, second, and third layers are connected in the connecting area with the additional adsorption filter material with a common seam (see Fig. 1).
[0500] In the case of materials A3 and B3, the third layer with the additional adsorption filter material is arranged equally between the first layer and the second layer, with the additional adsorption filter material being positioned between the third layer and the first layer and thus, so to speak, on the inside of or below the third layer; furthermore, the first layer and the second layer are each folded over in the direction of the third layer in the connecting region; moreover, the common seam which connects the first, second and third layers as well as the additional adsorption filter material to one another is designed in such a way that it only covers the folded over area or section of the first layer or the second layer which is (directly) in contact with the third layer or the additional adsorption filter material, and the first orsecond layer with the third layer and the additional adsorption filter material, so that the non-folded area of the first layer or the second layer in the connection area is not covered by the common seam and the seam is, so to speak, additionally covered by these areas - layer sequence in the connection area: first layer with non-folded area (not covered by the seam) and folded area (covered by the seam), additional adsorption filter material, third layer, second layer with non-folded area (not covered by the seam) and folded area (covered by the seam) (cf. Fig. 6A).
[0501] Material E1 corresponds to material A3 with the proviso that instead of the additional adsorption filter material, a textile surface material (reinforcement layer or ply) without adsorption material and with hydrophilic and oleophilic properties is used, based on a nonwoven material made of a mixture of polyamide and polyester (70 : 30) with a basis weight of 60 g / m 2 , based on WO 2019 / 129656 A1 or EP 3 731 939 A1.
[0502] Explanation B: Investigations
[0503] For all of the aforementioned protective materials A to C, the protective function against harmful or toxic substances (here specifically: mustard gas, HD) is examined:
[0504] The protective function against chemical warfare agents (mustard gas, HD) is determined on the basis of the so-called standardized diffusion flow test with applied drops ("Laid Drop Diffusive Flow Test"). For this purpose, the respective previously described materials A1, A2, A3 or B1, B2 and B3 as well as C1, D1 and E1 (sample area: 10 cm each) are 2) in a test cell over a PE membrane (10 pm), which simulates human skin. Furthermore, chemical warfare agent drops (8 drops of mustard gas per material, each with a volume of 1 pl) are applied to defined areas of the materials to be tested using a cannula (primarily in the connection area on the side of the material where the second layer is positioned). Test conditions: relative humidity of maximum 5% RH, temperature of 23 °C, mustard gas exposure for 24 h (test duration), flow under the material: 100 ml / min, flow above the material: 0.5 m / s, flow through the material: 0 cm / s. The air flow under the sample is drawn through a wash bottle. As part of the tests, the cumulative breakthrough is determined in pg / m using gas chromatography (GC / FPD). 2These tests simulate the diffusion of liquid warfare agent through the textile protective material without convection and thereby simulate the flat contact of the protective clothing with the skin, the latter being simulated by the PE membrane. Version C: Results
[0505] Using the previously described test method, the following values (cumulative breakthrough values) can be determined within the framework of the Laid Drop Diffusive Flow Test for the materials A1, A2, A3 or B1, B2 and B3 as well as C1, D1 and E1, which were also described previously:
[0506] 1. Materials A1, A2, A3 (first layer with particle or aerosol filter layer): 2. Materials B1, B2, B3 (first layer without particle or aerosol filter layer):
[0507] 3. Materials C1, D1, E1 (first layer without particle or aerosol filter layer): 4. Further tests were conducted on materials B1 and D1 with regard to the resistance and stability of the respective materials, taking into account washing and drying processes (wash cycles). Materials B1 and D1 were subjected to all defined washing and drying processes based on the DIN ISO 6330 4M standard (drying F). After 10 wash cycles, the invention material B1 exhibited a cumulative breakthrough value of 0.57 in the Laid Drop Diffusive Flow Test, while material D1 achieved a value of > 5.9. In particular, material D1 exhibited material damage with delamination of the non-textile sealing tape.
[0508] Overall, the tests demonstrate the excellent protective properties of the inventive materials A1, A2 and A3 or B1, B2 and B3 compared to the comparison materials. For the comparison material C1, relatively poor protective properties were observed, in particular there is a penetration of toxic substances along the connecting seam. The material D1 with the non-textile sealing tape also only has reduced mechanical resistance and wash resistance, accompanied by a reduction in protective performance after corresponding washing treatment. The material E1 with the hydrophilic and oleophilic reinforcement tape also has poorer protective properties than the inventive materials. In particular, the hydrophilic or oleophilic reinforcement tape does not have sufficient properties that could lead to a sustained absorption of toxic substances. Rather, there is a transfer of toxic substances.
[0509] With regard to the materials according to the invention, a further improvement in protective performance can be observed through the additional use of a particle or aerosol filter layer for the first layer, since only a smaller portion of the toxic substance can penetrate the first layer. In particular, the particle or aerosol filter layer also further relieves the load on the adsorption layer of the first layer. Furthermore, improved protective performance is observed for an arrangement of the third layer with the additional adsorption filter material between the first layer on the one hand and the second layer on the other, with the additional adsorption filter material being arranged, so to speak, below the third layer (cf. materials A2 and B2). The protective performance can be further improved with appropriate folding of the first and second layers and the special seam design (cf. materials A3 and B3).Overall, the above statements demonstrate the excellent protective properties of the materials according to the invention. In particular, the present invention provides an effective technical solution for sealing the transition area between textile layers or components on the one hand and a non-textile component or layer on the other.
[0510] List of reference symbols
[0511] 1 Protective clothing or protective material
[0512] 2 first layer
[0513] 2a Adsorption layer of the first layer
[0514] 2b textile carrier layer of the first layer
[0515] 2c Adsorbent particles of the first layer
[0516] 2d spacer or intermediate layer of the first layer
[0517] 2nd particle or aerosol filter layer of the first layer
[0518] 3 second layer
[0519] 4 third layer
[0520] 5 Connection area
[0521] 6 Seam area
[0522] 7 Seam or layer connecting seam
[0523] 8 additional adsorption filter material
[0524] 8a Adsorption layer of the additional adsorption filter material
[0525] 8b textile carrier layer of the additional adsorption filter material
[0526] 8c Adsorbent particles of the additional adsorption filter material
[0527] 8d Spacer or intermediate layer of the additional adsorption filter material
[0528] 8e Particle or aerosol filter layer of the additional adsorption filter material
[0529] 9, 9' hem or edge reinforcement or securing
[0530] 10 respirator mask
[0531] 11 Securing or stabilizing suture
Claims
Patent claims:
1. Protective clothing (1) with a protective function against chemical and / or biological and / or radioactive pollutants and / or toxic substances (warfare agents) ("NBC or CBRN protective function"), in particular NBC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, wherein the protective clothing (1) (a) a first, in particular flat and / or two-dimensional, layer (2) in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer (2a) and a textile carrier layer (2b) ("adsorption layer carrier"), (b) a second, in particular flat and / or two-dimensional, layer (3) in the form of a textile air-permeable covering material ("top layer", "outer fabric") and (c) a third, in particular flat and / or two-dimensional, layer (4) in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers (2, 3, 4) are arranged and / or positioned overlapping one another in a connecting region (5) and are connected, in particular sewn, to one another in the connecting region (5) with a common seam (7) forming a seam region (6) ("layer connecting seam"), wherein at least in the seam region (6) an additional multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped orband-shaped adsorption filter material (8), in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area (6) and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area (6), is arranged and / or provided and / or is present, wherein the additional adsorption filter material (8) is connected, in particular sewn, to the layers (2, 3, 4) by means of the seam (7) (the same seam (7)).
2. Protective clothing according to claim 1, wherein the seam (7) is produced and / or formed by sewing, in particular using at least one yarn and / or thread; and / or wherein the seam (7) is produced and / or formed by repeatedly guiding at least one yarn and / or thread through the layers (2, 3, 4) and the additional adsorption filter material (8); and / or wherein the yarn and / or thread of the seam (7) comprises or consists of a material, in particular textile fiber material, from the group of natural materials and synthetic materials, preferably selected from the group of cotton; wool; linen; polyesters; polyolefins, polyvinyl chlorides; polyvinylidene chlorides; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; polyacrylics; polyamides; polyvinyl alcohols; polyurethanes; polyvinyl esters; viscoses; and mixtures or combinations thereof;and / or wherein the yarn and / or the thread of the seam (7) is formed as a monofilament yarn or as a multifilament yarn; and / or wherein the seam (7) is not formed as an adhesive seam and / or at least substantially comprises no adhesive and / or is not formed by gluing the layers (2, 3, 4) and the additional adsorption filter material (8); and / or wherein the seam (7) is not formed as a welded seam and / or is not formed by welding the layers (2, 3, 4) and the additional adsorption filter material (8); 3. Protective clothing according to claim 1 or 2, wherein the additional adsorption filter material (8) has an adsorption layer (8a) and a textile carrier layer (8b), in particular wherein the adsorption layer (8a) is arranged on the carrier layer (8b) and / or is firmly connected (attached, fixed) to the carrier layer (8b), preferably by means of lamination, preferably by means of a first adhesive layer.
4. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) is flat and / or two-dimensional, in particular in the form of a strip (band) and / or strip-shaped (band-shaped); and / or wherein the additional adsorption filter material (8) has a width (b) in the range from 2 mm to 50 mm, in particular in the range from 4 mm to 35 mm, preferably in the range from 6 mm to 30 mm, more preferably in the range from 8 mm to 25 mm, particularly preferably in the range from 10 mm to 20 mm.
5. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) is in the form of a strip (band) and / or strip-shaped (band-shaped) and is arranged along the seam (7), in particular along the seam course of the seam (7).
6. Protective clothing according to one of the preceding claims, wherein the seam (7) is arranged and / or designed such that the seam (7) engages, in particular penetrates and / or passes through, the additional adsorption filter material (8).
7. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) is arranged and / or positioned at least substantially completely along the seam (7), in particular along the seam path of the seam (7), and / or extends at least substantially completely along the seam (7), in particular along the seam path of the seam (7); and / or wherein the seam (7) is connected to the additional adsorption filter material (8) along at least substantially its entire seam path and / or encompasses the additional adsorption filter material (8).
8. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) extends on both sides along the seam (7), in particular on both sides of the seam (7); and / or wherein the opposing and along the seam (7), in particular along the seam (7), extending and / or arranged Edges of the additional adsorption filter material (8), in particular independently of one another, are each spaced from the seam (7).
9. Protective clothing according to one of the preceding claims, wherein the opposite edges of the additional adsorption filter material (8) running and / or arranged along the seam (7), in particular along the seam path of the seam (7), in particular independently of one another, each have a distance from the seam (7), preferably perpendicular to the seam path of the seam (7), of at least 1 mm, in particular at least 2 mm, preferably at least 3 mm, preferably at least 4 mm, particularly preferably at least 5 mm;and / or wherein the opposite edges of the additional adsorption filter material (8) running and / or arranged along the seam (7), in particular along the seam profile of the seam (7), in particular independently of one another, each have a distance from the seam (7), preferably perpendicular to the seam profile of the seam (7), in the range from 1 mm to 20 mm, in particular in the range from 2 mm to 17.5 mm, preferably in the range from 3 mm to 15 mm, preferably in the range from 4 mm to 12.5 mm, particularly preferably in the range from 5 mm to 10 mm; 10. Protective clothing according to one of the preceding claims, wherein the opposite edges of the additional adsorption filter material (8) running and / or arranged along the seam (7), in particular along the seam path of the seam (7), preferably perpendicular to the seam path of the seam (7), have at least substantially an identical distance from the seam (7); and / or wherein the seam (7) runs along the longitudinal path of the additional adsorption filter material (8) through the additional adsorption filter material (8) and / or is arranged and / or positioned at least substantially centrally to the additional adsorption filter material (8).
11. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) is arranged and / or provided in the seam region (6) and also in the connecting region (5) and / or wherein the additional adsorption filter material (8) also extends into the connecting region (5); and / or wherein the additional adsorption filter material (8) covers the connecting region (5) at least partially and / or in sections, preferably at least substantially completely.
12. Protective clothing according to claim 11, wherein the additional adsorption filter material (8) also extends, in particular at least on one side or on both sides, beyond the connecting region (5).
13. Protective clothing according to one of the preceding claims, wherein in the connecting region (5), in particular in the seam region (6), the layers (2, 3, 4) and the additional adsorption filter material (8) are arranged and / or positioned in a stacked manner.
14. Protective clothing according to one of the preceding claims, wherein in the connecting region (5), in particular in the seam region (6), the layers (2, 3, 4) are arranged and / or positioned overlapping one another.
15. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) in the connecting region (5), in particular in the seam region (6), is in direct contact with the third layer (4) and / or directly abuts and / or rests on the third layer (4); and / or wherein the seam (7) directly connects the additional adsorption filter material (8) to the third layer (4).
16. Protective clothing according to one of the preceding claims, wherein in the connecting region (5), in particular in the seam region (6), the additional adsorption filter material (8) is arranged and / or positioned in the wearing and / or use state of the protective clothing (1) on the side facing the wearer and / or user of the protective clothing (1) or the side facing away from it, preferably on the side of the third layer (4) facing the wearer and / or user of the protective clothing (1); and / or wherein in the connecting region (5), in particular in the seam region (6), the additional adsorption filter material (8) is arranged and / or positioned in the wearing and / or use state of the protective clothing (1) on the side facing away from a source of harmful and / or toxic substances or on the side facing towards a source of harmful and / or toxic substances, preferably on the side facing away from a source of harmful and / or toxic substances, of the third layer (4).
17. Protective clothing according to one of claims 1 to 16, wherein in the connecting region (5), in particular in the seam region (6), the additional adsorption filter material (8), in particular with its surface and / or side facing away from the third layer (4), is in direct contact with the first layer (2) and / or directly abuts and / or rests on the first layer (2); and / or wherein the seam (7) directly connects the additional adsorption filter material (8) to the first layer (2).
18. Protective clothing according to claim 17, wherein in the connecting region (5), in particular in the seam region (6), the second layer (3) on the surface and / or side of the third layer (4) facing away from the additional adsorption filter material (8) is in direct contact with the third layer (4) and / or directly abuts and / or rests on the third layer (4); and / or wherein the seam (7) directly connects the second layer (3) to the third layer (4).
19. Protective clothing according to one of claims 17 or 18, wherein in the connecting region (5), in particular in the seam region (6), the third layer (4) with the additional adsorption filter material (8) is arranged and / or positioned between the first layer (2) and the second layer (3).
20. Protective clothing according to one of claims 17 to 19, wherein in the connecting region (5), in particular in the seam region (6), the first layer (2) in the wearing and / or use state of the protective clothing (1) on the wearer and / or user of the protective clothing (1) is arranged and / or positioned ("inside of the protective clothing (1)"); and / or wherein in the connecting region (5), in particular in the seam region (6), the second layer (3) is arranged and / or positioned in the wearing and / or use state of the protective clothing (1) on the side of the protective clothing (1) facing away from the wearer and / or user of the protective clothing (1) ("outside of the protective clothing (1)").
21. Protective clothing according to one of claims 17 to 20, wherein in the connecting region (5), in particular in the seam region (6), the first layer (2) is arranged and / or positioned on the side of the protective clothing (1) facing away from a source of harmful and / or toxic substances in the wearing and / or use state of the protective clothing (1); and / or wherein in the connecting region (5), in particular in the seam region (6), the second layer (3) is arranged and / or positioned on the side of the protective clothing (1) facing towards a source of harmful and / or toxic substances in the wearing and / or use state of the protective clothing (1).
22. Protective clothing according to one of claims 17 to 21, wherein in the connecting region (5), in particular in the seam region (6), the additional adsorption filter material (8) is arranged and / or positioned between the third layer (4) and the first layer (2); in particular wherein the additional adsorption filter material (8) is in direct contact with the third layer (4), in particular directly abuts and / or rests on the third layer (4); and / or in particular wherein the additional adsorption filter material (8) is in direct contact with the third layer (4) and, in particular opposite the third layer (4), with the first layer (2), in particular directly abuts and / or rests on the third layer (4) and, in particular opposite the third layer (4), on the first layer (2).
23. Protective clothing according to one of claims 17 to 22, wherein in the connecting region (5), in particular in the seam region (6), the second layer (3) is arranged and / or positioned on the surface and / or side of the third layer (4) opposite the additional adsorption filter material (8); and / or wherein in the connecting region (5), in particular in the seam region (6), the second layer (3) is in direct contact with the third layer (4), preferably directly against and / or rests on the third layer (4), in particular on the surface and / or side of the third layer (4) opposite the additional adsorption filter material (8).
24. Protective clothing according to one of claims 17 to 23, wherein in the connecting region (5), in particular in the seam region (6), the layers (2, 3, 4) and the additional adsorption filter material (8) in the subsequent removal or removal.The following are arranged and / or positioned in the following order: (i) first layer (2), (ii) additional adsorption filter material (8), (iii) third layer (4); (iv) second layer (3); in particular, wherein the additional adsorption filter material (8) is arranged and / or positioned on the side of the third layer (4) facing a wearer and / or user of the protective clothing (1) when the protective clothing (1) is in the worn and / or used state; and / or in particular, wherein the first layer (2) is arranged and / or positioned on the side (inside) of the protective clothing (1) facing a wearer and / or user of the protective clothing (1) when the protective clothing (1) is in the worn and / or used state; and / or in particular, wherein the second layer (3) is arranged and / or positioned on the side (outside) of the protective clothing (1) facing away from a wearer and / or user of the protective clothing (1) when the protective clothing (1) is in the worn and / or used state.
25. Protective clothing according to one of claims 1 to 16, wherein in the connecting region (5), in particular in the seam region (6), the additional adsorption filter material (8), in particular with its surface and / or side facing away from the third layer (4), is in direct contact with the second layer (3) and / or directly abuts and / or rests on the second layer (3); and / or wherein the seam (7) directly connects the additional adsorption filter material (8) to the second layer (3).
26. Protective clothing according to claim 25, wherein in the connecting region (5), in particular in the seam region (6), the second layer (3) with the surface and / or side of the second layer (3) facing away from the additional adsorption filter material (8) is in direct contact with the first layer (2) and / or directly abuts and / or rests on the first layer (2); and / or wherein the seam (7) directly connects the second layer (3) to the first layer (2).
27. Protective clothing according to claim 25 or 26, wherein in the connecting region (5), in particular in the seam region (6), the third layer (4) with the additional adsorption filter material (8) is arranged and / or positioned on the second layer (3), in particular wherein the additional adsorption filter material (8) is arranged and / or positioned between the third layer (4) and the second layer (3).
28. Protective clothing according to one of claims 25 to 27, wherein in the connecting region (5), in particular in the seam region (6), the first layer (2) is arranged and / or positioned in the wearing and / or use state of the protective clothing (1) on the side of the protective clothing (1) facing the wearer and / or user of the protective clothing (1) ("inside of the protective clothing (1)"); and / or wherein in the connecting region (5), in particular in the seam region (6), the third layer (4) is arranged and / or positioned in the wearing and / or use state of the protective clothing (1) on the side of the protective clothing (1) facing away from the wearer and / or user of the protective clothing (1) ("outside of the protective clothing (1)"), in particular wherein the additional adsorption filter material (8) is arranged and / or positioned between the third layer (4) and the second layer (3) ("intermediate layer").
29. Protective clothing according to one of claims 25 to 28, wherein in the connecting region (5), in particular in the seam region (6), the first layer (2) is arranged and / or positioned in the worn and / or used state of the protective clothing (1) on the side of the protective clothing (1) facing away from a source of harmful and / or toxic substances in the protective clothing (1); and / or wherein in the connecting region (5), in particular in the seam region (6), the third layer (4) is arranged and / or positioned in the worn and / or used state of the protective clothing (1) on the side of the protective clothing (1) facing away from a source of harmful and / or toxic substances in the protective clothing (1).
30. Protective clothing according to one of claims 25 to 29, wherein in the connecting region (5), in particular in the seam region (6), the additional adsorption filter material (8) is arranged between the third layer (4) and the second layer (3); in particular wherein the additional adsorption filter material (8) is in direct contact with the third layer (4), in particular directly abuts and / or rests on the third layer (4); and / or in particular wherein the additional adsorption filter material (8) is in direct contact with the third layer (4) and, in particular opposite the third layer (4), with the second layer (3), in particular directly abuts and / or rests on the third layer (4) and, in particular opposite the third layer (4), on the second layer (3).
31. Protective clothing according to one of claims 25 to 30, wherein in the connecting region (5), in particular in the seam region (6), the first layer (2) is arranged and / or positioned on the surface and / or side of the second layer (3) opposite the additional adsorption filter material (8); and / or wherein in the connecting region (5), in particular in the seam region (6), the first layer (2) is in direct contact with the second layer (3), preferably directly against and / or rests on the second layer (3), in particular on the surface and / or side of the second layer (3) opposite the additional adsorption filter material (8).
32. Protective clothing according to one of claims 25 to 31, wherein in the connecting region (5), in particular in the seam region (6), the layers (2, 3, 4) and the additional adsorption filter material (8) in the subsequent removal or removal.The following are arranged and / or positioned in the following order: (i) first layer (2), (ii) second layer (3), (iii) additional adsorption filter material (8), (iv) third layer (4); in particular, wherein the additional adsorption filter material (8) is arranged and / or positioned on the surface and / or side of the third layer (4) facing a wearer and / or user of the protective clothing (1) when the protective clothing (1) is in the worn and / or used state; and / or in particular, wherein the first layer (2) is arranged and / or positioned on the side (inside) of the protective clothing (1) facing a wearer and / or user of the protective clothing (1) when the protective clothing (1) is in the worn and / or used state; and / or in particular, wherein the third layer (4) is arranged and / or positioned on the side (outside) of the protective clothing (1) facing away from a wearer and / or user of the protective clothing (1) when the protective clothing (1) is in the worn and / or used state.
33. Protective clothing according to one of claims 1 to 16, wherein in the connecting region (5), in particular in the seam region (6), the additional adsorption filter material (8) is not connected to a further layer on its surface and / or side facing away from the third layer (4) and / or is not in contact with a further layer; and / or wherein the surface and / or side of the additional adsorption filter material (8) facing away from the third layer (4) is free and / or uncovered; and / or wherein the seam (7) directly connects the additional adsorption filter material (8) to the second layer (3).
34. Protective clothing according to claim 33, wherein in the connecting region (5), in particular in the seam region (6), the third layer (4) with its surface and / or side facing away from the additional adsorption filter material (8) is in direct contact with the second layer (3) and / or directly abuts and / or rests on the second layer (3); and / or wherein the seam (7) directly connects the third layer (4) to the second layer (3).
35. Protective clothing according to claim 33 or 34, wherein in the connecting region (5), in particular in the seam region (6), the third layer (4) with the additional adsorption filter material (8) is arranged and / or positioned on the second layer (3), in particular wherein the additional adsorption filter material (8) is arranged and / or positioned on the surface and / or side of the third layer (4) facing away from the second layer (3).
36. Protective clothing according to one of claims 33 to 35, wherein in the connecting region (5), in particular in the seam region (6), the first layer (2) faces the wearer and / or user of the protective clothing (1) in the worn and / or used state of the protective clothing (1) ("inner side of the protective clothing (1)"); and / or wherein in the connecting region (5), in particular in the seam region (6), the third layer (4) faces away from the wearer and / or user of the protective clothing (1) in the worn and / or used state of the protective clothing (1) ("outer side of the protective clothing (1)"), in particular wherein the additional adsorption filter material (8) is arranged and / or positioned on the surface and / or side of the third layer (4) facing away from the second layer (3) ("outermost layer").
37. Protective clothing according to one of claims 33 to 36, wherein in the connecting region (5), in particular in the seam region (6), the first layer (2) is arranged and / or positioned on the side of the protective clothing (1) facing away from a source of harmful and / or toxic substances in the protective clothing (1) when the protective clothing (1) is in the wearing and / or using state; and / or wherein in the connecting region (5), in particular in the seam region (6), the additional adsorption layer (8) is arranged and / or positioned on the side of the protective clothing (1) facing towards a source of harmful and / or toxic substances in the protective clothing (1) when the protective clothing (1) is in the wearing and / or using state.
38. Protective clothing according to one of claims 33 to 37, wherein in the connecting region (5), in particular in the seam region (6), the additional adsorption filter material (8) is arranged and / or positioned on the third layer (4); and / or wherein in the connecting region (5), in particular in the seam region (6), the third layer (4) is arranged / or positioned between the additional adsorption filter material (8) and the second layer (3); in particular wherein the additional adsorption filter material (8) is in direct contact with the third layer (4), in particular directly abuts and / or rests on the third layer (4);and / or in particular wherein the third layer (4) is in direct contact with the additional adsorption filter material (8) and, in particular opposite the additional adsorption filter material (8), with the second layer (3), in particular directly contacting and / or resting on the third layer (4) and, in particular opposite the third layer (4), on the second layer (3); 39. Protective clothing according to one of claims 33 to 38, wherein in the connecting region (5), in particular in the seam region (6), the first layer (2) is arranged and / or positioned on the surface and / or side of the second layer (3) opposite the third layer (4); and / or wherein in the connecting region (5), in particular in the seam region (6), the first layer (2) is in direct contact with the second layer (3), preferably directly against and / or rests on the second layer (3), in particular on the surface and / or side of the second layer (3) opposite the third layer (4).
40. Protective clothing according to one of claims 33 to 39, wherein in the connecting region (5), in particular in the seam region (6), the layers (2, 3, 4) and the additional adsorption filter material (8) are arranged and / or positioned in the following sequence: (i) first layer (2), (ii) second layer (3), (iii) third layer (4), (iv) additional adsorption filter material (8); in particular wherein the additional adsorption filter material (8) is arranged and / or positioned on the surface and / or side of the third layer (4) facing away from a wearer and / or user of the protective clothing (1) when the protective clothing (1) is worn and / or in use; and / or in particular wherein the first layer (2) is arranged and / or positioned on the side (inside) of the protective clothing (1) facing towards a wearer and / or user of the protective clothing (1) when the protective clothing (1) is worn and / or in use; and / or in particular wherein the additional adsorption filter material (8) is arranged and / or positioned on the side (outside) of the protective clothing (1) facing away from a wearer and / or user of the protective clothing (1) when the protective clothing (1) is worn and / or in use.
41. Protective clothing according to one of the preceding claims, wherein the first layer (2) and the second layer (3) are turned over in the connecting region (5), in particular are turned over together, preferably by means of the seam (7), preferably including and / or co-covering the third layer (4) and the additional adsorption filter material (8).
42. Protective clothing according to one of the preceding claims, wherein the first layer (2) and / or the second layer (3) are hemmed, independently of one another, in the connecting region (5).
43. Protective clothing according to one of the preceding claims, wherein the first layer (2) and / or the second layer (3), independently of one another, are folded over and / or turned over in the connecting region (5), in particular folded over and / or turned over at the edges.
44. Protective clothing according to one of claims 1 to 43, wherein the first layer (2) and / or the second layer (3), in particular the first layer (2) and the second layer (3), are folded and / or folded over in the connecting region (5) in the direction of the third layer (4) and / or the further adsorption filter material (8), in particular folded and / or folded over at the edges, in particular wherein the third layer (4) with the additional adsorption filter material (8) is arranged and / or positioned between the first layer (2) and the second layer (3), preferably as defined in claim 24.
45. Protective clothing according to claim 42 or 43, wherein the seam (7), with respect to the first layer (2) and the second layer (3), only engages the turned-over and / or folded-over regions of the first layer (2) and the second layer (3), in particular the turned-over and / or folded-over regions of the first layer (2) and the second layer (3) that are in direct contact with the third layer (4) or the additional adsorption filter material (8), and connects them to the third layer (4) and the additional adsorption filter material (8); and / or wherein the seam (7) does not (also) engage the non-turned-over and / or non-folded region of the first layer (2) and / or the non-turned-over and / or non-folded region of the second layer (3), in particular the non-turned-over and / or non-folded region of the first layer (2).
46. Protective clothing according to one of claims 1 to 43, wherein the first layer (2) and / or the second layer (3), in particular the first layer (2) and the second layer (3), are each folded over and / or folded over in the connecting region (5) so as to point away from and / or lead away from the third layer (4) and / or the further adsorption filter material (8), in particular folded over and / or folded over at the edges, in particular wherein in the connecting region (5), in particular the seam region (6), the second layer (3) is arranged and / or positioned on the first layer (2) relative to the non-folded and / or non-folded region of the first layer (2) and / or the second layer (3), and wherein the third layer (4) with the additional adsorption filter material (8) is arranged and / or positioned on the surface and / or side of the second layer (3) facing away from the first layer (2), preferably as defined in claim 32 or 40.
47. Protective clothing according to one of the preceding claims, wherein the first layer (2) and the second layer (3), on the one hand, and the third layer (4), on the other hand, extend from the connecting region (5) in different directions, in particular in at least substantially opposite directions; and / or wherein the first layer (2), the second layer (3), the third layer (4), and the additional adsorption filter material (8) are arranged and / or positioned overlapping one another only in the connecting region (5), in particular including the seam region (6).
48. Protective clothing according to one of the preceding claims, wherein the first layer (2) and the second layer (3), in particular far away from and / or outside the connecting region (5), define and / or form a covering and / or covering region (covering and / or covering section), preferably for covering at least one body section, in particular body part, of a wearer and / or user of the protective clothing (1) in a manner that protects it against the effects of harmful and / or toxic substances.
49. Protective clothing according to one of the preceding claims, wherein the first layer (2), in particular remote from and / or outside the connection area (5), is arranged and / or positioned on the side of the protective clothing (1) facing the wearer and / or user of the protective clothing (1) in the worn and / or used state ("inside of the protective clothing (1)"); and / or wherein the first layer (2), in particular remote from and / or outside the connection area (5), is arranged and / or positioned on the side of the protective clothing (1) facing away from a source of harmful and / or toxic substances in the worn and / or used state of the protective clothing (1) ("inside of the protective clothing (1)").
50. Protective clothing according to one of the preceding claims, wherein the first layer (2) is and / or is designed to be gas-permeable, in particular air-permeable; and / or wherein the first layer (2) is and / or is designed to be a gas-permeable, in particular air-permeable, textile fabric.
51. Protective clothing according to one of the preceding claims, wherein the textile carrier layer (2b) is present and / or formed as a preferably gas-permeable, in particular air-permeable, textile fabric; and / or wherein the textile carrier layer (2b) is formed as a knitwear, in particular as a warp-knitted fabric (knitted fabric) or a weft-knitted fabric (knitted fabric), woven fabric, scrim, or textile composite material, in particular as a weft-knitted fabric.
52. Protective clothing according to one of the preceding claims, wherein the textile carrier layer (2b) comprises or is formed from natural fibers and / or synthetic fibers (chemical fibers), preferably natural fibers, particularly preferably cotton fibers; and / or wherein the textile carrier layer (2b) comprises or is formed from natural fibers, particularly preferably cotton fibers, optionally in combination with synthetic fibers (chemical fibers); and / or wherein the textile carrier layer (2b) comprises a material, in particular textile fiber material, preferably textile fibers, in particular as a yarn and / or thread, selected from the group of natural materials and synthetic materials, in particular selected from the group of cotton (CO); wool; linen; polyesters; polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; aramids, in particular meta- and / or para-amides;optionally modified and / or regenerated celluloses; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof, preferably selected from the group of modified and / or regenerated celluloses, in particular viscose; aramids, in particular meta- and / or para-amides; polyamide and mixtures or combinations thereof, or consists of these; and / or wherein the textile carrier layer (2b) is made of a material, in particular textile fiber material, preferably textile fibers, in particular as a yarn and / or thread, in the form of a mixture of cotton and polyester (CO / PES); or a mixture of polyamide and polyester (PA / PES); or a mixture of cotton and elastane (CO / EL); or a mixture of polyester and elastane (PES / EL); or a mixture of polyamide and elastane; (PA / EL), preferably a mixture of cotton and elastane (CO / EL); and / or wherein the textile carrier layer (2b) is elastically and / or reversibly stretchable, in particular wherein the textile carrier layer (2b) comprises elastane, in particular elastane fibers, preferably in an amount of at most 20% by weight, preferably at most 15% by weight, based on the textile carrier layer (2b); and / or wherein the textile carrier layer (2b) is made of a material, in particular textile fiber material, preferably textile fibers, in particular as yarn and / or thread, in the form of cotton (CO) or polyester (PES); and / or wherein the textile carrier layer (2b) has an antimicrobial, in particular antibacterial, finish.
53. Protective clothing according to one of the preceding claims, o wherein the textile carrier layer (2b) has a basis weight in the range of 10 g / m 2 2 2 to 350 g / m , in particular in the range from 20 g / m to 300 g / m , 2 2 preferably in the range from 30 g / m to 250 g / m , particularly preferably in the range from 50 g / m to 175 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%.
54. Protective clothing according to one of the preceding claims, wherein the textile carrier layer (2b), in particular remote from and / or outside the connection region (5), is arranged and / or positioned on the surface and / or side of the first layer (2) facing the wearer and / or user of the protective clothing (1) ("inner side of the first layer (2)"); and / or wherein the textile carrier layer (2b), in particular remote from and / or outside the connection region (5), is arranged and / or positioned on the surface and / or side of the first layer (2) facing away from a source of harmful and / or toxic substances ("inner side of the first layer (2)") when the protective clothing (1) is worn and / or used.
55. Protective clothing according to one of the preceding claims, wherein the adsorption layer (2a) is discontinuous; and / or wherein the adsorption layer (2a) is gas-permeable, preferably air-permeable.
56. Protective clothing according to one of the preceding claims, wherein the adsorption layer (2a) comprises or is formed from adsorbent particles (2c), in particular a plurality of individual and / or discrete adsorbent particles (2c).
57. Protective clothing according to claim 56, wherein the adsorbent particles (2c) of the adsorption layer (2a) are selected from the group of (i) in particular particulate activated carbon and / or activated carbon particles, preferably in the form of activated carbon particles in granular form ("granular carbon") or activated carbon particles in spherical form ("spherical carbon"); (ii) zeolites, in particular natural and / or synthetic zeolites; (iii) molecular sieves, in particular zeolitic molecular sieves, synthetic molecular sieves and / or in particular synthetic molecular sieves based on carbon, oxides and / or glasses; (iv) metal oxide and / or metal particles; (v) ion exchange resins, in particular polydisperse and / or monodisperse cation and / or anion exchangers, in particular of the gel type and / or macroporous type; (vi) inorganic oxides, in particular silicon dioxides, silica gels and / or aluminum oxides; (vii) porous organic polymers and / or porous organic-inorganic hybrid polymers and / or metal-organic framework materials, in particular MOFs (metal organic framework), COFs (covalent organic framework), ZI Fs (zeolite imidazolate framework), POMs (polymer organic material) and / or OFCs; (viii) mineral granules; (ix) clathrates; and (x) mixtures and / or combinations thereof; with (i) being particularly preferred.
58. Protective clothing according to claim 56 or 57, wherein the adsorber particles (2c) of the adsorption layer (2a) are activated carbon particles, preferably in the form of granular activated carbon particles ("granular carbon") or spherical activated carbon particles ("spherical carbon"), preferably in the form of spherical activated carbon particles; and / or wherein the adsorber particles (2c) of the adsorption layer (2a) are activated carbon fibers and / or activated carbon filaments, in particular in the form of an activated carbon fiber sheet.
59. Protective and / or filter material according to any one of claims 56 to 58, wherein the adsorber particles (2c) of the adsorption layer (2a) are activated carbon particles, preferably in the form of activated carbon particles in granular form ("granular carbon") or activated carbon particles in spherical form ("spherical carbon"), preferably activated carbon particles in spherical form; in particular wherein the activated carbon has a total pore volume, in particular a total pore volume according to Gurvich, in the range of 0.3 cm 3 / g up to 3.8 cm 3 / g, especially in the range of 0.4 cm 3 / g up to 3.5 cm 3 / g, preferably in the range of 0.5 cm 3 / g up to 3 cm 3 / g, particularly preferably in the range of 0.6 cm 3 / g up to 2.5 cm 3 / g, most preferably in the range of 0.5 cm 3 / g to 1.5 cm 3 / g, and / or in particular wherein at least 65%, in particular at least 70%, preferably at least 75%, preferably at least 80%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon is formed by pores with pore diameters of at most 50 nm, in particular by micropores and / or mesopores; and / or in particular wherein 50% to 95%, in particular 60% to 90%, preferably 70% to 85%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon is formed by pores with pore diameters of at most 50 nm, in particular by micropores and / or mesopores; and / or in particular wherein 1% to 60%, in particular 5% to 50%, preferably 10% to 40%, preferably 15% to 35%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon is formed by pores with pore diameters of more than 2 nm, in particular by mesopores and / or macropores; and / or。 in particular wherein the activated carbon has a pore volume formed by pores with pore diameters of at most 2 nm (ie < 2 nm), in particular micropore volume according to carbon black, in the range of 0.05 cm 3 / g to 2.5 cm 3 / g, especially 0.15 cm 3 / g up to 2 cm 3 / g, preferably 0.3 cm 3 / g to 1.5 cm 3 / g, in particular wherein 15% to 98%, in particular 25% to 95%, preferably 35% to 90%, of the total pore volume of the activated carbon is formed by pores with pore diameters of at most 2 nm, in particular by micropores; and / or in particular wherein the activated carbon has a specific BET surface area in the range of 600 m 2 / g up to 4,000 m 2 / g, especially 800 m 2 / g up to 3,500 m 2 / g, preferably 1,000 m 2 / g up to 3,000 m 2 / g, particularly preferably 1,200 m 2 / g up to 2,750 m 2 / g, most preferably 1,300 m 2 / g up to 2,500 m 2 / g, and / or in particular wherein the activated carbon has a surface formed by pores with pore diameters of at most 2 nm, in particular by micropores, in the range of 400 to 3,500 m 2 / g, especially 500 to 3,000 m 2 / g, preferably 600 to 2,500 m 2 / g, preferably 700 to 2,000 m 2 / g, and / or in particular wherein the activated carbon has a surface formed by pores with pore diameters in the range of 2 nm to 50 nm, in particular by mesopores, in the range of 200 to 2,000 m 2 / g, in particular 300 to 1,900 m / g, preferably 400 to 1,800 m / g, more preferably 500 to 1,700 m / g; and / or in particular wherein the activated carbon has an average pore diameter in the range from 0.1 nm to 55 nm, in particular 0.2 nm to 50 nm, preferably 0.5 nm to 45 nm, more preferably 1 nm to 40 nm.
60. Protective and / or filter material according to one of claims 56 to 59, wherein the adsorbent particles (2c) of the adsorption layer (2a), in particular the activated carbon particles, have a particle size, in particular a particle diameter, in the range from 0.05 mm to 2 mm, in particular in the range from 0.075 mm to 1 mm, preferably in the range from 0.1 mm to 0.5 mm, preferably in the range from 0.125 mm to 0.4 mm, particularly preferably in the range from 0.15 mm to 0.35 mm, in particular determined according to ASTM D2862; in particular wherein at least 80 wt.%, in particular at least 90 wt.%, preferably at least 95 wt.%, more preferably at least 99 wt.%, of the adsorbent particles (2c), in particular the activated carbon particles, have particle sizes, in particular particle diameters, in the aforementioned ranges; and / or wherein the adsorbent particles (2c) of the adsorption layer (2a), in particular the activated carbon particles, have an average particle size (D50), in particular an average particle diameter (D50), in the range from 0.05 mm to 1.5 mm, in particular in the range from 0.08 mm to 1 mm, preferably in the range from 0.1 mm to 0.75 mm, preferably in the range from 0.12 mm to 0.5 mm, particularly preferably in the range from 0.15 mm to 0.3 mm, in particular determined according to ASTM D2862.
61. Protective and / or filter material according to one of claims 56 to 59, wherein the adsorbent particles (2c) of the adsorption layer (2a), in particular the activated carbon particles, are present in an amount in the range of 5 g / m 2up to 500 g / m 2 , especially 10 g / m 2 up to 300 g / m 2 , preferably 30 g / m 2 up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2 , are used; and / or wherein the first layer (2), in particular the adsorption layer (2a), the adsorbent particles (2c), in particular the activated carbon particles, in an amount in the range of 5 g / m 2 up to 500 g / m 2 , especially 10 g / m 2 up to 300 g / m 2 , preferably 30 g / m 2 up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2 , and / or wherein the adsorption layer (2a) has a basis weight, in particular determined as dry weight, in the range of 5 g / m 2 up to 500 g / m 2 , especially 10 g / m 2 up to 300 g / m 2 , preferably 30 g / m 2 up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2, in particular determined according to DIN EN 12127, preferably after drying for 1 hour at 105 °C.
62. Protective clothing according to one of the preceding claims, wherein the first layer (2) has a textile spacer and / or intermediate layer (2d), in particular wherein the textile spacer and / or intermediate layer (2d) is arranged in particular on the surface and / or side of the adsorption layer (2a) opposite the carrier layer (2b).
63. Protective clothing according to claim 62, wherein the textile spacer and / or intermediate layer (2d) is present and / or formed as a preferably gas-permeable, in particular air-permeable, textile fabric; and / or in particular wherein the textile spacer and / or intermediate layer (2d) is formed as an air-permeable textile fabric, in particular as a knitwear, woven fabric, scrim or textile composite material, preferably nonwoven, particularly preferably as a nonwoven; and / or wherein the textile spacer and / or intermediate layer (2d) comprises or is formed from natural fibers and / or synthetic fibers (chemical fibers), preferably synthetic fibers;and / or in particular wherein the textile spacer and / or intermediate layer (2d) comprises or consists of a material, in particular textile fiber material, preferably textile fibers, in particular as a yarn and / or thread, selected from the group of synthetic materials, in particular selected from the group of polyesters; polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates; aramids, in particular meta- and / or para-amides; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof; preferably polyesters; and / or wherein the textile spacer and / or intermediate layer (2d) has a basis weight in 2 2 2; Range from 5 g / m to 150 g / m , especially in the range from 10 g / m to 2 2 2 125 g / m , preferably in the range from 15 g / m to 100 g / m , particularly preferably in the range from 20 g / m to 75 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%.
64. Protective clothing according to one of the preceding claims, wherein the first layer (2) has a particle and / or aerosol filter layer (2e), preferably a particle and aerosol filter layer (2e); in particular wherein the particle and / or aerosol filter layer (2e) is present and / or formed as a gas-permeable textile fabric which comprises or is formed from a plurality of individual textile fibers; and / or in particular wherein the particle and / or aerosol filter layer (2e) has or consists of at least one functional layer with particle and / or aerosol filter properties, in particular with particle and aerosol filter properties, and / or in particular wherein the particle and / or aerosol filter layer (2e) is designed to be gas-permeable, in particular air-permeable, and / or water vapor-permeable, preferably gas-permeable, in particular air-permeable, and water vapor-permeable, preferably air-permeable and water vapor-permeable.
65. Protective clothing according to claim 64, wherein the particle and / or aerosol filter layer (2e) has a (total) 2 2 Basis weight in the range from 5 g / m to 200 g / m , in particular in the range from 10 g / m to 150 g / m , preferably in the range from 15 g / m to 120 g / m , preferably in the range from 20 g / m to 100 g / m , particularly preferably in the range from 25 g / m to 80 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%; and / or wherein the particle and / or aerosol filter layer (2e) has a thickness, in particular total cross-sectional thickness, in the range from 0.01 mm to 5 mm, in particular in the range from 0.03 mm to 3 mm, preferably in the range from 0.05 mm to 2 mm, more preferably in the range from 0.07 mm to 1 mm, particularly preferably in the range from 0.09 mm to 0.75 mm, further preferably in the range from 0.1 mm to 0.5 mm, in particular determined according to DIN EN ISO 9073-2.
66. Protective clothing according to claim 64 or 65, wherein the particle and / or aerosol filter layer (2e), in particular the functional layer, has a separation efficiency (separation efficiency), in particular fractional separation efficiency, of at least 80%, in particular of at least 85%, preferably of at least 90%, preferably of at least 95%, determined according to DIN EN 1822 at a pressure difference of 15 Pascal with potassium chloride (KCl) as test substance (in particular 1%) as minimum efficiency (MPPS, in particular MPPS = 0.1 pm to 0.3 pm); and / or wherein the particle and / or aerosol filter layer (2e) is designed as a HEPA filter (High Efficiency Penetration or Particulate Air) or ULPA filter (Ultra Low Penetration or Particulate Air).
67. Protective clothing according to one of claims 64 to 66, wherein the particle and / or aerosol filter layer (2e), in particular the functional layer, comprises and / or is formed from at least one textile fiber (functional layer textile fiber), preferably a plurality of textile fibers; and / or wherein the particle and / or aerosol filter layer (2e), in particular the functional layer, comprises and / or is formed from a plurality of individual textile fibers (functional layer textile fibers); in particular wherein the textile fibers of the particle and / or aerosol filter layer (2e), in particular the functional layer, have a fiber diameter in the range from 10 nm to 1,500 nm, in particular in the range from 50 nm to 1,000 nm, preferably in the range from 100 nm to 800 nm, more preferably in the range from 150 nm to 600 nm, particularly preferably in the range from 200 nm to 400 nm, in particular determined according to DIN 53 811;and / or in particular wherein the textile fibers of the particle and / or aerosol filter layer (2e), in particular of the functional layer, are synthetic fibers (chemical fibers); and / or wherein the textile fibers of the functional layer are a material from the group of polyurethanes (PU); polyesters (PES); polyolefins (PO), such as polyethylene (PE), polypropylene (PP), polyoxyethylene and polyoxypropylene; polyvinyl chlorides (CLF); polyvinylidene chlorides (CLF); acetates (CA); triacetates (CTA); polyacrylic (PAN), in particular polyacrylonitriles; polyamides (PA); polyvinyl alcohol (PVAL); polyvinyl esters; poly(meth)acrylates; polyvinylidene fluorides (PVDF); and mixtures and combinations thereof, preferably from the group of polyurethanes; polyesters, polyolefins, polyamides, polyacrylonitriles, poly(meth)acrylates and polyvinylidene fluorides; their copolymers and their mixtures and combinations, preferably from the group of polyurethanes, polyesters, polyolefins and polyamides;their copolymers and mixtures and combinations thereof, most preferably polyurethanes; and / or; wherein the textile fibers of the particle and / or aerosol filter layer (2e), in particular the functional layer, are polyurethane fibers; and / or wherein the particle and / or aerosol filter layer (2e), in particular the functional layer, comprises or consists of polyurethane fibers.
68. Protective clothing according to one of claims 64 to 67, wherein the particle and / or aerosol filter layer (2e), in particular the functional layer, has an average pore size or average mesh size, in particular average pore size, in the range from 0.05 pm to 100 pm, in particular in the range from 0.1 pm to 50 pm, preferably in the range from 0.2 pm to 20 pm, more preferably in the range from 0.3 pm to 10 pm, particularly preferably in the range from 0.4 pm to 5 pm, further preferably in the range from 0.5 pm to 3 pm, in particular determined according to ASTM F316-86.
69. Protective clothing according to one of claims 64 to 68, wherein the particle and / or aerosol filter layer (2e) is designed in multiple layers, in particular in three layers, wherein the particle and / or aerosol filter layer (2e) has at least one outer carrier layer and at least one functional layer arranged between the outer carrier layers, in particular connected to the outer carrier layers, with particle and / or aerosol filter properties, in particular with particle and aerosol filter properties, in particular wherein the particle and / or aerosol filter layer (2e) is designed as a gas-permeable, in particular air-permeable, composite, preferably a laminate.
70. Protective clothing according to one of claims 64 to 69, wherein the particle and / or aerosol filter layer (2e), in particular the functional layer, is produced by electrospinning, spunbonding, meltblow or a combination of these processes, preferably by a combination of electrospinning and meltblow processes, or by electrospinning, preferably by electrospinning; and / or wherein the particle and / or aerosol filter layer (2e), in particular the functional layer, is formed as a scrim or textile composite, in particular nonwoven, particularly preferably as a nonwoven; and / or wherein the particle and / or aerosol filter layer (2e), in particular the functional layer, is formed and / or present as a scrim or textile composite material, in particular nonwoven, particularly preferably as a nonwoven, based on and / or made of polyurethane fibers.
71. Protective clothing according to one of the preceding claims, wherein the particle and / or aerosol filter layer (2e) is arranged directly on the adsorption layer (2a) or on the spacer and / or intermediate layer (2d) and / or is connected thereto; or wherein the particle and / or aerosol filter layer (2e) is arranged on the spacer and / or intermediate layer (2d) and / or is connected thereto, wherein the spacer and / or intermediate layer (2d) is arranged on the surface and / or side facing away from the particle and / or aerosol filter layer (2e) on the adsorption layer (2a) and / or is connected thereto; or wherein the particle and / or aerosol filter layer (2e) is arranged between the adsorption layer (2a) and the spacer and / or intermediate layer (2d) and / or is connected thereto;wherein the spacer and / or intermediate layer (2d) is arranged between the adsorption layer (2a) and the particle and / or aerosol filter layer (2e) and / or is firmly connected (attached, fixed) to the adsorption layer (2a) and / or the particle and / or aerosol filter layer (2e), in particular (only) to the adsorption layer (2a), in particular by means of a preferably discontinuously, preferably punctually, applied adhesive and / or by means of lamination; 72. Protective clothing according to one of the preceding claims, wherein the first layer (2) has a textile cover layer (cover layer of the first layer (2)); in particular wherein the textile cover layer is arranged on the side of the adsorption layer (2a) opposite the carrier layer (2b); and / or in particular wherein the textile cover layer is designed as a gas-permeable, in particular air-permeable, textile fabric, in particular as a textile knitwear, preferably as a warp-knitted fabric (knitted fabric) or a warp-knitted fabric (knitted fabric), or in particular as a woven fabric, scrim, nonwoven fabric or textile composite material; and / or in particular wherein the textile covering layer comprises natural textile fibers and / or synthetic textile fibers (chemical fibers), preferably synthetic textile fibers, or is formed therefrom; and / or in particular wherein the textile covering layer comprises synthetic fibers (chemical fibers), optionally in combination with natural fibers, preferably cotton fibers, or is formed therefrom; and / or in particular wherein the textile covering layer comprises elastane (EL), in particular elastane fibers; and / or in particular wherein the textile covering layer has a basis weight in the range 2 2 2 2 from 5 g / m to 400 g / m , in particular in the range from 10 g / m to 300 g / m , 2 2 preferably in the range from 20 g / m to 250 g / m , particularly preferably in the range from 30 g / m to 175 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%; and / or in particular wherein the textile cover layer has a thickness, in particular cross-sectional thickness, in the range from 0.001 mm to 10 mm, in particular in the range from 0.01 mm to 8 mm, preferably in the range from 0.05 mm to 4 mm, preferably in the range from 0.075 mm to 2 mm, particularly preferably in the range from 0.1 mm to 2 mm, further preferably in the range from 0.15 mm to 1 mm, in particular determined according to DIN EN ISO 5084; and / or in particular wherein the textile covering layer comprises a material, in particular textile fibre material, preferably textile fibres, selected from the group of natural materials and synthetic materials, in particular selected from the group of cotton (CO); wool; linen; polyesters;Polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; aramids, in particular meta- and / or para-amides; optionally modified and / or regenerated celluloses; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof, preferably selected from the group of modified and / or regenerated celluloses, in particular viscose; aramids, in particular meta- and / or para-amides; polyamide and mixtures or combinations thereof.
73. Protective clothing according to one of the preceding claims, wherein the textile cover layer is arranged directly on the adsorption layer (2a) or on the particle and / or aerosol filter layer (2e) and / or is connected thereto; and / or wherein the particle and / or aerosol filter layer (2e) is arranged between the textile cover layer on the one hand and the adsorption layer (2a) or the spacer and / or intermediate layer (2d) on the other hand and / or is connected thereto.
74. Protective clothing according to one of the preceding claims, wherein the adsorption layer (2a) is fixed to the textile carrier layer (2b) in particular by means of a preferably discontinuously, preferably punctiformly, applied adhesive; and / or wherein the spacer and / or intermediate layer (2d) is fixed to the adsorption layer (2a) in particular by means of a preferably discontinuously, preferably punctiformly applied adhesive; and / or wherein the textile cover layer is fixed to the adsorption layer (2a) or to the particle and / or aerosol filter layer (2e) in particular by means of a preferably discontinuously, preferably punctiformly applied adhesive or by lamination.
75. Protective clothing according to one of the preceding claims, wherein the first layer (2) has a basis weight in the range of 10 g / m 2 up to 600 g / m 2 , especially in the range of 50 g / m 2 up to 500 g / m 2, preferably in the range of 100 g / m 2 up to 450 g / m 2 , particularly preferably in the range of 150 g / m 2 up to 410 g / m 2 , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%; and / or wherein the first layer (2) has a thickness, in particular total cross-sectional thickness, in the range from 0.01 mm to 10 mm, in particular in the range from 0.05 mm to 5 mm, preferably in the range from 0.1 mm to 3 mm, preferably in the range from 0.2 mm to 2 mm, particularly preferably in the range from 0.5 mm to 2 mm, in particular determined according to DIN EN ISO 5084; and / or wherein the first layer (2) and / or the protective material (1) has a gas permeability, in particular air permeability, of at least 1 mm / s, in particular at least 2 mm / s, preferably at least 5 mm / s, preferably at least 7 mm / s, particularly preferably at least 10 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal; and / or wherein the first layer (2) and / or the protective material (1) have a gas permeability, in particular air permeability, in the range from 1 mm / s to 500 mm / s, in particular in the range from 2 mm / s to 400 mm / s, preferably in the range from 5 mm / s to 200 mm / s, more preferably in the range from 7 mm / s to 150 mm / s, particularly preferably in the range from 10 mm / s to 100 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal.
76. Protective clothing according to one of the preceding claims, wherein the first layer (2) and / or the protective material (1) has a bursting pressure, in particular determined according to DIN EN ISO 13938-2, of at least 50 kPa (kilopascals), in particular of at least 75 kPa, preferably of at least 90 kPa, particularly preferably of at least 100 kPa; and / or wherein the first layer (2) and / or the protective material (1) has a bursting pressure, in particular determined according to DIN EN ISO 13938-2, in the range from 50 kPa (kilopascals) to 1.000 kPa, in particular in the range from 75 kPa to 800 kPa, preferably in the range from 90 kPa to 600 kPa, particularly preferably in the range from 100 kPa to 500 kPa; and / or wherein the first layer (2) and / or the protective material (1) has a tensile stress and / or extensibility (elongation) in at least one direction, in particular in the longitudinal or transverse direction, determined according to DIN 53835-14 at 20 Newtons, of at least 2.5%, preferably of at least 5%, preferably of at least 7%; and / or wherein the first layer (2) and / or the protective material (1) has a shrinkage in at least one direction, in particular in the longitudinal or transverse direction, determined according to DIN EN 5077, of at most 12%, preferably of at most 10%, preferably of at most 6%.
77. Protective clothing according to one of the preceding claims, wherein the second layer (3) is three-layered and in particular formed as a composite and / or laminate; in particular wherein the second layer (3) comprises or consists of (i) a textile carrier layer (2b) (textile carrier layer of the second layer (3)), in particular as defined in one of claims 51 to 54; (ii) an adsorption layer (2a) (adsorption layer of the second layer (3)), in particular as defined in one of claims 55 to 61; and (iii) a textile cover layer (cover layer of the second layer (3)), in particular as defined in claim 72 or 73, or a textile spacer and / or intermediate layer (2d) (textile spacer and / or intermediate layer of the second layer (3)), in particular as defined in claim 62 or 63; and / or in particular wherein the second layer (3) comprises the aforementioned layers (i) to (iv) in the order and / or sequence (i), (ii), (iii), (iv);or wherein the second layer (3) is in particular four-layered and in particular formed as a composite and / or laminate; in particular wherein the second layer (3) (i) comprises a textile carrier layer (2b) (textile carrier layer of the second layer (3)), in particular as defined in one of claims 51 to 54; (ii) an adsorption layer (2a) (adsorption layer of the second layer (3)), in particular as defined in one of claims 55 to 61; (iii) a particle and / or aerosol filter layer (2e) (particle and / or aerosol filter layer of the second layer (3)), in particular as defined in one of claims 64 to 71; and (iv) comprises or consists of a textile cover layer (cover layer of the second layer (3)), in particular as defined in claim 72 or 73, or a textile spacer and / or intermediate layer (2d) (textile spacer and / or intermediate layer of the second layer (3)), in particular as defined in claim 62 or 63;and / or in particular wherein the second layer (3) comprises the aforementioned layers (i) to (iv) in the order and / or sequence (i), (ii), (iii), (iv); 78. Protective clothing according to one of the preceding claims, wherein the second layer (3), in particular remote from and / or outside the connection region (5), is arranged and / or positioned on the side of the protective clothing (1) facing away from the wearer and / or user of the protective clothing (1) in the worn and / or used state ("outside of the protective clothing (1)"); and / or wherein the second layer (3), in particular remote from and / or outside the connection region (5), is arranged and / or positioned on the side of the protective clothing (1) facing a source of harmful and / or toxic substances in the worn and / or used state of the protective clothing (1) ("outside of the protective clothing (1)").
79. Protective clothing according to one of the preceding claims, wherein the second layer (3) is and / or is designed to be gas-permeable, in particular air-permeable; and / or wherein the second layer (3) is and / or is designed to be a gas-permeable, in particular air-permeable, textile fabric.
80. Protective clothing according to one of the preceding claims, wherein the second layer (3) is designed as a textile knitwear, preferably as a warp-knitted fabric (knitted fabric) or a woven fabric (knitted fabric), or in particular as a woven fabric, scrim, nonwoven or textile composite material; and / or wherein the second layer (3) comprises or is formed from natural textile fibers and / or synthetic textile fibers (chemical fibers), preferably synthetic textile fibers, in particular as a yarn and / or thread; and / or wherein the second layer (3) comprises or is formed from synthetic fibers (chemical fibers), optionally in combination with natural fibers, preferably cotton fibers, in particular as a yarn and / or thread; and / or wherein the second layer (3) is a material, in particular textile fiber material, preferably textile fibers, in particular as a yarn and / or thread, selected from the group of natural materials and synthetic materials, in particular selected from the group of cotton (CO); wool; linen; polyesters;Polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; aramids, in particular meta- and / or para-amides; optionally modified and / or regenerated celluloses; polyacrylic; polyamide; polyvinyl alcohol; Polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof, preferably selected from the group of modified and / or regenerated celluloses, in particular viscose; aramids, in particular meta- and / or para-amides; polyamide and mixtures or combinations thereof; and / or wherein the second layer (3) is elastically and / or reversibly stretchable; in particular wherein the second layer (3) comprises elastane, in particular elastane fibers, in particular as yarn and / or thread, in particular in an amount of at most 10 wt.%, preferably at most 5 wt.%, based on the second layer (3).
81. Protective clothing according to one of the preceding claims, wherein the second layer (3) has a basis weight in the range of 5 g / m 2 up to 400 g / m 2 , especially in the range of 10 g / m 2 up to 300 g / m 2, preferably in the range of 20 g / m 2 up to 250 g / m 2 , particularly preferably in the range of 30 g / m 2 up to 175 g / m 2 , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%; and / or wherein the second layer (3) has a thickness, in particular cross-sectional thickness, in the range from 0.001 mm to 10 mm, in particular in the range from 0.01 mm to 8 mm, preferably in the range from 0.05 mm to 4 mm, preferably in the range from 0.075 mm to 2 mm, particularly preferably in the range from 0.1 mm to 2 mm, further preferably in the range from 0.15 mm to 1 mm, in particular determined according to DIN EN ISO 5084.
82. Protective clothing according to one of the preceding claims, wherein the second layer (3) is flame-retardant and / or flame-retardant and / or fire-resistant and / or flame-resistant and / or wherein the second layer (3) comprises at least one flame-retardant and / or flame-retardant and / or fire-resistant and / or flame-resistant material, in particular in the form of or as a component of a yarn and / or thread; in particular wherein the fire-resistant and / or flame-resistant material is at least one aramid, in particular meta-aramid and / or para-aramid, and / or a modified and / or regenerated cellulose; and / or in particular wherein the second layer (3) comprises the flame-retardant and / or flame-retardant and / or fire-resistant and / or flame-resistant material in an amount in the range from 1 wt.% to 100 wt.%, in particular 2 wt.% to 95 wt.%, preferably 5 wt.% to 90 wt.%, based on the second layer (3).
83. Protective clothing according to one of the preceding claims, wherein the second layer (3) is antistatic; in particular wherein the second layer (3) comprises at least one antistatic material, in particular in the form of or as a component of a yarn and / or twisted yarn and / or thread; and / or in particular wherein the second layer (3) comprises the antistatic material in an amount in the range from 0.1 wt.% to 10 wt.%, in particular 0.2 wt.% to 5 wt.%, preferably 0.5 wt.% to 3 wt.%, based on the second layer (3).
84. Protective clothing according to one of the preceding claims, wherein the second layer (3) has an oleophobic and / or hydrophobic finish; in particular wherein the finish is in the form of an impregnation or coating, in particular by means of at least one fluorocarbon and / or at least one fluorohydrocarbon, in particular a fluorinated polymer.
85. Protective clothing according to one of claims 1 to 84, wherein the second layer (3), in particular far away from and / or outside the connecting region (5), is only firmly connected (attached or fixed) to the first layer (2) in sections, in particular linearly and / or at the edges, in particular by means of sewing, welding, tacking, gluing or the like, and is otherwise arranged loosely and / or unconnected to the first layer (2), in particular resting thereon.
86. Protective clothing according to one of claims 1 to 84, wherein the second layer (3), in particular far away and / or outside the connecting region (5), and the first layer (2) are firmly connected (attached, fixed) to one another at their contact surfaces and / or are made to adhere, in particular are firmly connected (attached, fixed) and / or adhered, in particular laminated, at least substantially over the entire surface and / or at least substantially over the entire side, preferably are firmly connected (attached, fixed) and / or adhered, in particular laminated, at least substantially over the entire surface.
87. Protective clothing according to one of the preceding claims, wherein the second layer (3) has a basis weight in the range of 10 g / m 2 up to 600 g / m 2 , especially in the range of 50 g / m 2 up to 500 g / m 2 , preferably in the range of 100 g / m 2 up to 450 g / m 2 , particularly preferably in the range of 150 g / m 2 up to 410 g / m 2, in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%; and / or wherein the second layer (3) has a thickness, in particular total cross-sectional thickness, in the range from 0.01 mm to 10 mm, in particular in the range from 0.05 mm to 5 mm, preferably in the range from 0.1 mm to 3 mm, preferably in the range from 0.2 mm to 2 mm, particularly preferably in the range from 0.5 mm to 2 mm, in particular determined according to DIN EN ISO 5084; and / or wherein the second layer (3) has a gas permeability, in particular air permeability, of at least 2 mm / s, in particular at least 3 mm / s, preferably at least 7 mm / s, preferably at least 9 mm / s, particularly preferably at least 12 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal;and / or wherein the second layer (3) has a gas permeability, in particular air permeability, in the range from 2 mm / s to 600 mm / s, in particular in the range from 3 mm / s to 500 mm / s, preferably in the range from 7 mm / s to 300 mm / s, preferably in the range from 9 mm / s to 200 mm / s, particularly preferably in the range from 12 mm / s to 150 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal.; 88. Protective clothing according to one of the preceding claims, wherein the third layer (4), in particular far away from and / or outside the connecting region (5), defines and / or forms a transition region (transition section), in particular opening region (opening section), and / or a sealing region, preferably for the in particular sealing reception (sealing contact) and / or passage of a body section, in particular body part, of a wearer and / or user of the protective clothing (1) and / or preferably for the in particular sealing reception (sealing contact) and / or connection to further protective equipment, such as a respiratory mask (10), preferably an ABC respiratory mask, or the like; in particular wherein the third layer (4) is designed as a sealing element.
89. Protective clothing according to one of the preceding claims, wherein the third layer (4), in particular far away from and / or outside the connecting region (5), defines and / or forms a field of vision opening, head opening, neck opening, abdominal and / or pelvic opening, arm and / or hand opening or a foot and / or leg opening, in particular a field of vision opening.
90. Protective clothing according to one of the preceding claims, wherein the third layer (4) is in the form of a band, in particular a flat band; and / or wherein the third layer (4) is in the form of a flat band with two opposite flat sides.
91. Protective clothing according to one of the preceding claims, wherein the third layer (4) is formed as a single piece and / or in one piece, in particular as a single piece and / or open piece, preferably with two ends; or wherein the third layer (4) is formed as a single piece and / or closed piece and / or continuous piece.
92. Protective clothing according to one of the preceding claims, wherein the third layer (4), in particular far away from and / or outside the connecting region (5), defines and / or forms a field of vision opening for, in particular, sealingly receiving (sealing fit) and / or edge-side covering a respiratory mask (10); in particular wherein the third layer (4) with the connecting region (5) is a component of a hood; (head) cap and / or balaclava (of the protective clothing (1)); and / or in particular wherein the third layer (4) with the connecting region (5) is arranged in a hood; (head) cap and / or balaclava (of the protective clothing (1)).
93. Protective clothing according to one of the preceding claims, wherein the third layer (4) is designed as a preferably elastic and / or reversibly stretchable sealing element for preferably sealing contact with a respiratory mask (10) and / or wherein the third layer (4) is designed in the form of a band, in particular a flat band; and / or wherein the third layer (4) is designed in the form of a flat band with two opposite flat sides; in particular wherein the third layer (4) is arranged and / or provided circumferentially in the edge region of a field of vision opening of the protective clothing (1); and / or in particular the third layer (4) delimits the protective clothing (1) circumferentially at the edge to the field of vision opening;and / or in particular wherein the third layer (4), in particular the surface (sealing surface) of the third layer (4) which lies against the respiratory mask (10) in the worn and / or used state, is at least substantially flat, in particular band-shaped or strip-shaped; and / or in particular wherein the third layer (4), in particular the surface (sealing surface) of the third layer (4) which lies against the respiratory mask (10) in the worn and / or used state, is at least substantially flat, in particular band-shaped or strip-shaped, which lies against the respiratory mask (10) or is designed to lie against it; and / or; in particular, wherein the third layer (4) in the worn and / or used state rests with one of its flat sides, in particular at the edge, against the respiratory mask (10) and / or is positioned and / or arranged with one of its flat sides relative to the respiratory mask (10); and / or in particular, wherein the third layer (4) in the worn and / or used state faces the respiratory mask (10) with one of its flat sides.
94. Protective clothing according to one of the preceding claims, wherein the third layer (4) is designed as a preferably elastic and / or reversibly stretchable sealing element for preferably sealingly contacting a body section, in particular a body part, of a wearer and / or user of the protective clothing (1); in particular wherein the third layer (4) is arranged and / or provided circumferentially in the edge region of an opening in the protective clothing (1) and / or wherein the third layer (4) delimits the protective clothing (1) circumferentially at the edge side from the opening; and / or in particular wherein the third layer (4), in particular the surface (sealing surface) of the third layer (4) which bears against the body section, in particular a body part, in the worn and / or used state, is designed to be at least substantially flat, in particular band-shaped or strip-shaped;and / or in particular wherein, in the wearing and / or use state, the third layer (4), in particular the surface (sealing surface) of the third layer (4) lying against the body section, in particular body part, is at least substantially flat, in particular band-shaped or strip-shaped, lying against the body section, in particular body part, or is designed to lie against it.; 95. Protective clothing according to one of the preceding claims, wherein the third layer (4), in particular the flat side(s) of the third layer (4), is / are at least substantially bead-free and / or has / have at least substantially no elevations and / or at least substantially no projections and / or substantially no thickenings.
96. Protective clothing according to one of the preceding claims, wherein the third layer (4) has a width in the range from 1 mm to 70 mm, in particular in the range from 5 mm to 50 mm, preferably in the range from 10 mm to 40 mm, preferably in the range from 15 mm to 35 mm, particularly preferably in the range from 20 mm to 30 mm; and / or wherein the third layer (4) has a height (thickness) in the range from 0.1 mm to 10 mm, in particular in the range from 0.2 mm to 8 mm, preferably in the range from 0.5 mm to 5 mm, preferably in the range from 0.75 mm to 4 mm, particularly preferably in the range from 1 mm to 3 mm; and / or wherein the third layer (4) has a basis weight in the range of 10 g / m 2 up to 1,000 g / m 2 , especially in the range of 50 g / m 2 up to 800 g / m 2 , preferably in the range of 100 g / m 2 up to 600 g / m 2 , particularly preferably in the range of 150 g / m 2 up to 500 g / m 2, in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%; and / or wherein the third layer (4) is water-impermeable and / or water vapor-impermeable and / or wherein the third layer (4) is air-impermeable and water-impermeable and / or water vapor-impermeable.
97. Protective clothing according to one of the preceding claims, wherein the third layer (4) is elastically and / or reversibly stretchable; and / or wherein the third layer (4) comprises or consists of at least one particularly elastic and / or particularly reversibly stretchable material, in particular wherein the particularly elastic and / or particularly reversibly stretchable material comprises or consists of at least one elastomer, in particular a naturally based and / or synthetically based elastomer; and / or in particular wherein the particularly elastic and / or particularly reversibly stretchable material of the third layer (4) is a rubber and / or caoutchouc material, in particular silicone rubber and / or butyl rubber, preferably butyl rubber; and / or in particular, wherein the particularly elastic and / or particularly reversibly stretchable material of the third layer (4) is a polyisoprene material; and / or in particular, wherein the particularly elastic and / or particularly reversibly stretchable material of the third layer (4) is a synthetic polymer, preferably based on a block copolymer with the components polyurethane and polyethylene glycol.
98. Protective clothing according to one of the preceding claims, wherein the third layer (4) is formed as a multifilament yarn with a plurality of individual filaments made of the elastic and / or reversibly stretchable material of the third layer (4) and / or comprises such a multifilament yarn, in particular wherein the third layer (4) additionally contains a textile component.
99. Protective clothing according to one of the preceding claims, wherein the third layer (4) has a coating, preferably for the purposes of (supplementary) sealing, (supplementary) adhesion and / or (supplementary) non-slipping of the sealing element (4), in particular with respect to accommodated body portions of the wearer and / or user of the protective clothing (1) and / or with respect to the respiratory mask (10), in particular wherein the coating is arranged and / or applied on the side, in particular the flat side, of the third layer (4) facing the respiratory mask (3) and / or the wearer and / or user of the protective clothing (1) when worn and / or in use; and / or in particular wherein the coating comprises or consists of a silicone and / or a silicone rubber.
100. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) is and / or designed to be gas-permeable, in particular air-permeable; and / or wherein the additional adsorption filter material (8) is and / or designed to be a gas-permeable, in particular air-permeable, textile fabric.
101. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) has a textile carrier layer (8b) (textile carrier layer of the additional adsorption filter material (8)), in particular wherein the textile carrier layer (8b) is present and / or formed as a preferably gas-permeable, in particular air-permeable, textile sheet structure; and / or in particular wherein the textile carrier layer (8b) is formed as a knitwear, in particular as a warp-knitted fabric (knitted fabric) or weft-knitted fabric (knitted fabric), woven fabric, scrim, or textile composite material, in particular as a knitwear.
102. Protective clothing according to claim 101, wherein the textile carrier layer (8b) comprises or is formed from natural fibers and / or synthetic fibers (chemical fibers), preferably natural fibers, particularly preferably cotton fibers; and / or wherein the textile carrier layer (8b) comprises or is formed from natural fibers, particularly preferably cotton fibers, optionally in combination with synthetic fibers (chemical fibers); and / or wherein the textile carrier layer (8b) is a material, in particular textile fiber material, preferably textile fibers, in particular as a yarn and / or thread, selected from the group of natural materials and synthetic materials, in particular selected from the group of cotton (CO); wool; linen; polyesters; polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; aramids, in particular meta- and / or para-amides; optionally modified and / or regenerated celluloses;Polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof, preferably selected from the group of modified and / or regenerated celluloses, in particular viscose; aramids, in particular meta- and / or para-amides; polyamide and mixtures or combinations thereof, or consists of these; and / or; wherein the textile carrier layer (8b) consists of a material, in particular textile fiber material, preferably textile fibers, in particular as yarn and / or thread, in the form of a mixture of cotton and polyester (CO / PES); or a mixture of polyamide and polyester (PA / PES); or a mixture of cotton and elastane (CO / EL); or a mixture of polyester and elastane (PES / EL); or a mixture of polyamide and elastane (PA / EL), preferably a mixture of cotton and elastane (CO / EL); and / or wherein the textile carrier layer (8b) is elastically and / or reversibly stretchable, in particular wherein the textile carrier layer (2b) comprises elastane, in particular elastane fibers, preferably in an amount of at most 20 wt.%, preferably at most 15 wt.-%, based on the textile carrier layer (8b); and / or wherein the textile carrier layer (8b) consists of a material, in particular textile fiber material, preferably textile fibers, in particular as yarn and / or thread, in the form of cotton (CO) or polyester (PES); and / or wherein the textile carrier layer (8b) has an antimicrobial, in particular antibacterial, finish.
103. Protective clothing according to claim 101 or 102, o wherein the textile carrier layer (8b) has a basis weight in the range of 10 g / m 2 2 2 to 350 g / m , in particular in the range from 20 g / m to 300 g / m , 2 2 preferably in the range from 30 g / m to 250 g / m , particularly preferably in the range from 50 g / m to 175 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%.
104. Protective clothing according to one of claims 101 to 103, wherein the textile carrier layer (8b) in the wearing and / or use state of the protective clothing (1) is arranged and / or positioned on the surface and / or side of the additional adsorption filter material (8) facing the wearer and / or user of the protective clothing (1) ("inner side of the additional adsorption filter material (8)"); and / or wherein the textile carrier layer (2b) in the wearing and / or use state of the protective clothing (1) is arranged and / or positioned on the surface and / or side of the additional Adsorption filter material (8) is arranged and / or positioned ("inside of the additional adsorption filter material (8)").
105. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) has an adsorption layer (8a) (adsorption layer of the additional adsorption filter material (8)), in particular wherein the adsorption layer (8a) is discontinuous; and / or in particular wherein the adsorption layer (8a) is gas-permeable, preferably air-permeable.
106. Protective clothing according to claim 105, wherein the adsorption layer (8a) comprises or is formed from adsorber particles (8c) (adsorber particles of the additional adsorption filter material (8)), in particular a plurality of individual and / or discrete adsorber particles (8c).
107. Protective clothing according to claim 106, wherein the adsorbent particles (8c) of the adsorption layer (8a) are selected from the group of (i) in particular particulate activated carbon and / or activated carbon particles, preferably in the form of activated carbon particles in granular form ("granular carbon") or activated carbon particles in spherical form ("spherical carbon"); (ii) zeolites, in particular natural and / or synthetic zeolites; (iii) molecular sieves, in particular zeolitic molecular sieves, synthetic molecular sieves and / or in particular synthetic molecular sieves based on carbon, oxides and / or glasses; (iv) metal oxide and / or metal particles; (v) ion exchange resins, in particular polydisperse and / or monodisperse cation and / or anion exchangers, in particular of the gel type and / or macroporous type; (vi) inorganic oxides, in particular silicon dioxides, silica gels and / or aluminum oxides; (vii) porous organic polymers and / or porous organic-inorganic hybrid polymers and / or metal-organic frameworks materials, in particular MOFs (Metal Organic Framework), COFs (Covalent Organic Framework), ZIFs (Zeolite Imidazolate Framework), POMs (Polymer Organic Material) and / or OFCs; (viii) mineral granules; (ix) clathrates; and (x) mixtures and / or combinations thereof; with (i) being particularly preferred.
108. Protective clothing according to claim 106 or 107, wherein the adsorber particles (8c) of the adsorption layer (8a) are activated carbon particles, preferably in the form of granular activated carbon particles ("granular carbon") or spherical activated carbon particles ("spherical carbon"), preferably in the form of spherical activated carbon particles; and / or wherein the adsorber particles (8c) of the adsorption layer (8a) are activated carbon fibers and / or activated carbon filaments, in particular in the form of an activated carbon fiber sheet.
109. Protective and / or filter material according to any one of claims 106 to 108, wherein the adsorber particles (8c) of the adsorption layer (8a) are activated carbon particles, preferably in the form of activated carbon particles in granular form ("granular carbon") or activated carbon particles in spherical form ("spherical carbon"), preferably activated carbon particles in spherical form; in particular wherein the activated carbon has a total pore volume, in particular a total pore volume according to Gurvich, in the range of 0.3 cm 3 / g up to 3.8 cm 3 / g, especially in the range of 0.4 cm 3 / g up to 3.5 cm 3 / g, preferably in the range of 0.5 cm 3 / g up to 3 cm 3 / g, particularly preferably in the range of 0.6 cm 3 / g up to 2.5 cm 3 / g, most preferably in the range of 0.5 cm 3 / g to 1.5 cm 3 / g; and / or in particular wherein at least 65%, in particular at least 70%, preferably at least 75%, preferably at least 80%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon is formed by pores with pore diameters of at most 50 nm, in particular by micropores and / or mesopores; and / or in particular wherein 50% to 95%, in particular 60% to 90%, preferably 70% to 85%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon is formed by pores with pore diameters of at most 50 nm, in particular by micropores and / or mesopores; and / or in particular wherein 1% to 60%, in particular 5% to 50%, preferably 10% to 40%, preferably 15% to 35%, of the total pore volume, in particular the total pore volume according to Gurvich, of the activated carbon is formed by pores with pore diameters of more than 2 nm, in particular by mesopores and / or macropores; and / or in particular wherein the activated carbon has a pore volume formed by pores with pore diameters of at most 2 nm (ie < 2 nm), in particular micropore volume according to Carbon Black, in the range of 0.05 cm 3 / g to 2.5 cm 3 / g, especially 0.15 cm 3 / g up to 2 cm 3 / g, preferably 0.3 cm 3 / g to 1.5 cm 3 / g, in particular wherein 15% to 98%, in particular 25% to 95%, preferably 35% to 90%, of the total pore volume of the activated carbon is formed by pores with pore diameters of at most 2 nm, in particular by micropores; and / or in particular wherein the activated carbon has a specific BET surface area in the range of 600 m 2 / g up to 4,000 m 2 / g, especially 800 m 2 / g up to 3,500 m 2 / g, preferably 1,000 m 2 / g up to 3,000 m 2 / g, particularly preferably 1,200 m 2 / g up to 2,750 m 2 / g, most preferably 1,300 m 2 / g up to 2,500 m 2 / g, and / or in particular wherein the activated carbon has a surface formed by pores with pore diameters of at most 2 nm, in particular by micropores, in the range of 400 to 3,500 m 2 / g, especially 500 to 3,000 m 2 / g, preferably 600 to 2,500 m 2 / g, preferably 700 to 2,000 m 2 / g, and / or in particular wherein the activated carbon has a surface formed by pores with pore diameters in the range of 2 nm to 50 nm, in particular by mesopores, in the range of 200 to 2,000 m 2 / g, in particular 300 to 1,900 m / g, preferably 400 to 1,800 m / g, more preferably 500 to 1,700 m / g; and / or in particular wherein the activated carbon has an average pore diameter in the range from 0.1 nm to 55 nm, in particular 0.2 nm to 50 nm, preferably 0.5 nm to 45 nm, more preferably 1 nm to 40 nm.
110. Protective and / or filter material according to one of claims 106 to 109, wherein the adsorbent particles (8c) of the adsorption layer (8a), in particular the activated carbon particles, have a particle size, in particular a particle diameter, in the range from 0.05 mm to 2 mm, in particular in the range from 0.075 mm to 1 mm, preferably in the range from 0.1 mm to 0.5 mm, more preferably in the range from 0.125 mm to 0.4 mm, particularly preferably in the range from 0.15 mm to 0.35 mm, in particular determined according to ASTM D2862; in particular wherein at least 80 wt.%, in particular at least 90 wt.%, preferably at least 95 wt.%, preferably at least 99 wt.-%, of the adsorbent particles (8c), in particular the activated carbon particles, have particle sizes, in particular particle diameters, in the aforementioned ranges; and / or wherein the adsorbent particles (8c) of the adsorption layer (8a), in particular the activated carbon particles, have an average particle size (D50), in particular an average particle diameter (D50), in the range from 0.05 mm to 1.5 mm, in particular in the range from 0.08 mm to 1 mm, preferably in the range from 0.1 mm to 0.75 mm, more preferably in the range from 0.12 mm to 0.5 mm, particularly preferably in the range from 0.15 mm to 0.3 mm, in particular determined according to ASTM D2862.
111. Protective and / or filter material according to one of claims 106 to 109, wherein the adsorber particles (8c) of the additional adsorption filter material (8), in particular the activated carbon particles, are present in an amount in the range of 5 g / m 2 up to 500 g / m 2 , especially 10 g / m 2 up to 300 g / m 2 , preferably 30 g / m 2up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2 , are used; and / or wherein the additional adsorption filter material (8), in particular the adsorption layer (8a), the adsorber particles (8c), in particular the activated carbon particles, in an amount in the range of 5 g / m 2 up to 500 g / m 2 , especially 10 g / m 2 up to 300 g / m 2 , preferably 30 g / m 2 up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2 , and / or wherein the adsorption layer (8a) has a basis weight, in particular determined as dry weight, in the range of 5 g / m 2 up to 500 g / m 2 , especially 10 g / m 2 up to 300 g / m 2 , preferably 30 g / m 2 up to 200 g / m 2 , preferably 40 g / m 2 up to 150 g / m 2 , in particular determined according to DIN EN 12127, preferably after drying for 1 hour at 105 °C.
112. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) has a textile spacer and / or intermediate layer (8d) (textile spacer and / or intermediate layer of the additional adsorption filter material (8)), in particular wherein the textile spacer and / or intermediate layer (8d) is arranged in particular on the surface and / or side of the adsorption layer (8a) opposite the carrier layer (8b).
113. Protective clothing according to claim 112, wherein the textile spacer and / or intermediate layer (8d) is present and / or formed as a preferably gas-permeable, in particular air-permeable, textile fabric; and / or in particular wherein the textile spacer and / or intermediate layer (8d) is formed as an air-permeable textile fabric, in particular as a knitwear, woven fabric, scrim, or textile composite, preferably nonwoven, particularly preferably as a nonwoven; and / or wherein the textile spacer and / or intermediate layer (8d) comprises or is formed from natural fibers and / or synthetic fibers (chemical fibers), preferably synthetic fibers;and / or in particular wherein the textile spacer and / or intermediate layer (8d) comprises or consists of a material, in particular textile fiber material, preferably textile fibers, in particular as a yarn and / or thread, selected from the group of synthetic materials, in particular selected from the group of polyesters; polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates; aramids, in particular meta- and / or para-amides; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof; preferably polyesters; and / or wherein the textile spacer and / or intermediate layer (8d) has a basis weight in 2 2 2; Range from 5 g / m to 150 g / m , especially in the range from 10 g / m to 2 2 2 125 g / m , preferably in the range from 15 g / m to 100 g / m , particularly preferably in the range from 20 g / m to 75 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%.
114. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) has a particle and / or aerosol filter layer (8e) (particle and / or aerosol filter layer of the additional adsorption filter material (8)), preferably a particle and aerosol filter layer (8e); in particular, wherein the particle and / or aerosol filter layer (8e) is present and / or formed as a gas-permeable textile fabric which comprises or is formed from a plurality of individual textile fibers;and / or in particular wherein the particle and / or aerosol filter layer (8e) has or consists of at least one functional layer with particle and / or aerosol filter properties, in particular with particle and aerosol filter properties, and / or in particular wherein the particle and / or aerosol filter layer (8e) is designed to be gas-permeable, in particular air-permeable, and / or water vapor-permeable, preferably gas-permeable, in particular air-permeable, and water vapor-permeable, preferably air-permeable and water vapor-permeable.; 115. Protective clothing according to claim 114, wherein the particle and / or aerosol filter layer (8e) has a (total) 2 2 Basis weight in the range from 5 g / m to 200 g / m , in particular in the range from 10 g / m to 150 g / m , preferably in the range from 15 g / m to 120 g / m , preferably in the range from 20 g / m to 100 g / m , particularly preferably in the range from 25 g / m to 80 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%; and / or wherein the particle and / or aerosol filter layer (8e) has a thickness, in particular total cross-sectional thickness, in the range from 0.01 mm to 5 mm, in particular in the range from 0.03 mm to 3 mm, preferably in the range from 0.05 mm to 2 mm, more preferably in the range from 0.07 mm to 1 mm, particularly preferably in the range from 0.09 mm to 0.75 mm, further preferably in the range from 0.1 mm to 0.5 mm, in particular determined according to DIN EN ISO 9073-2.
116. Protective clothing according to claim 114 or 115, wherein the particle and / or aerosol filter layer (8e), in particular the functional layer, has a separation efficiency, in particular fractional separation efficiency, of at least 80%, in particular of at least 85%, preferably of at least 90%, preferably of at least 95%, determined according to DIN EN 1822 at a pressure difference of 15 Pascal with potassium chloride (KCl) as the test substance (in particular 1%) as the minimum efficiency (MPPS, in particular MPPS = 0.1 pm to 0.3 pm); and / or wherein the particle and / or aerosol filter layer (8e) is designed as a HEPA filter (High Efficiency Penetration or Particulate Air) or ULPA filter (Ultra Low Penetration or Particulate Air).
117. Protective clothing according to one of claims 114 to 116, wherein the particle and / or aerosol filter layer (8e), in particular the functional layer, comprises and / or is formed from at least one textile fiber (functional layer textile fiber), preferably a plurality of textile fibers; and / or wherein the particle and / or aerosol filter layer (2e), in particular the functional layer, comprises and / or is formed from a plurality of individual textile fibers (functional layer textile fibers); in particular wherein the textile fibers of the particle and / or aerosol filter layer (8e), in particular the functional layer, have a fiber diameter in the range from 10 nm to 1,500 nm, in particular in the range from 50 nm to 1.000 nm, preferably in the range from 100 nm to 800 nm, more preferably in the range from 150 nm to 600 nm, particularly preferably in the range from 200 nm to 400 nm, in particular determined according to DIN 53 811; and / or in particular wherein the textile fibers of the particle and / or aerosol filter layer (8e), in particular of the functional layer, are synthetic fibers (chemical fibers); and / or wherein the textile fibers of the functional layer are a material from the group of polyurethanes (PU); polyesters (PES); polyolefins (PO), such as polyethylene (PE), polypropylene (PP), polyoxyethylene and polyoxypropylene; polyvinyl chlorides (CLF); polyvinylidene chlorides (CLF); acetates (CA); triacetates (CTA); polyacrylic (PAN), in particular polyacrylonitriles; polyamides (PA); polyvinyl alcohol (PVAL); polyvinyl esters; poly(meth)acrylates; Polyvinylidene fluorides (PVDF); as well as mixtures and combinations thereof, preferably from the group of polyurethanes; polyesters,. Polyolefins, polyamides, polyacrylonitriles, poly(meth)acrylates and polyvinylidene fluorides; their copolymers and their mixtures and combinations, preferably from the group of polyurethanes; polyesters, polyolefins and polyamides; their copolymers and their mixtures and combinations, very particularly preferably polyurethanes; and / or wherein the textile fibers of the particle and / or aerosol filter layer (8e), in particular of the functional layer, are polyurethane fibers; and / or wherein the particle and / or aerosol filter layer (8e), in particular the functional layer, comprises or consists of polyurethane fibers.
118. Protective clothing according to one of claims 114 to 117, wherein the particle and / or aerosol filter layer (8e), in particular the functional layer, has an average pore size or average mesh size, in particular average pore size, in the range from 0.05 pm to 100 pm, in particular in the range from 0.1 pm to 50 pm, preferably in the range from 0.2 pm to 20 pm, more preferably in the range from 0.3 pm to 10 pm, particularly preferably in the range from 0.4 pm to 5 pm, further preferably in the range from 0.5 pm to 3 pm, in particular determined according to ASTM F316-86.
119. Protective clothing according to one of claims 114 to 118, wherein the particle and / or aerosol filter layer (8e) is designed in multiple layers, in particular in three layers, wherein the particle and / or aerosol filter layer (8e) has at least one outer carrier layer and at least one functional layer arranged between the outer carrier layers, in particular connected to the outer carrier layers, with particle and / or aerosol filter properties, in particular with particle and aerosol filter properties, in particular wherein the particle and / or aerosol filter layer (8e) is designed as a gas-permeable, in particular air-permeable, composite, preferably a laminate.
120. Protective clothing according to one of claims 114 to 119, wherein the particle and / or aerosol filter layer (8e), in particular the functional layer, is produced by electrospinning, spunbonding processes, meltblow processes or a combination of these processes, preferably by a combination of electrospinning and meltblow processes, or by electrospinning, preferably by electrospinning; and / or wherein the particle and / or aerosol filter layer (8e), in particular the functional layer, is formed as a scrim or textile composite material, in particular a nonwoven, particularly preferably as a nonwoven; and / or wherein the particle and / or aerosol filter layer (8e), in particular the functional layer, is formed as a scrim or textile composite material, in particular a nonwoven, particularly preferably as a nonwoven, based on and / or made of polyurethane fibers.
121. Protective clothing according to one of the preceding claims, wherein the particle and / or aerosol filter layer (8e) is arranged directly on the adsorption layer (8a) or on the spacer and / or intermediate layer (8d) and / or is connected thereto; or wherein the particle and / or aerosol filter layer (8e) is arranged on the spacer and / or intermediate layer (8d) and / or is connected thereto, wherein the spacer and / or intermediate layer (8d) is arranged on the surface and / or side facing away from the particle and / or aerosol filter layer (8e) on the adsorption layer (8a) and / or is connected thereto; or wherein the particle and / or aerosol filter layer (8e) is arranged between the adsorption layer (8a) and the spacer and / or intermediate layer (8d) and / or is connected thereto;wherein the spacer and / or intermediate layer (8d) is arranged between the adsorption layer (8a) and the particle and / or aerosol filter layer (8e) and / or is firmly connected (attached, fixed) to the adsorption layer (8a) and / or the particle and / or aerosol filter layer (8e), in particular (only) to the adsorption layer (8a), in particular by means of a preferably discontinuously, preferably punctually, applied adhesive and / or by means of lamination; 122. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) has a textile cover layer (cover layer of the additional adsorption filter material (8)); in particular wherein the textile cover layer is arranged on the side of the adsorption layer (2a) opposite the carrier layer (2b); and / or in particular wherein the textile covering layer is designed as a gas-permeable, in particular air-permeable, textile fabric, in particular as a textile knitwear, preferably as a warp-knitted fabric (knitted fabric) or a weft-knitted fabric (knitted fabric), or in particular as a woven fabric, scrim, nonwoven or textile composite material; and / or in particular wherein the textile covering layer comprises natural textile fibers and / or synthetic textile fibers (chemical fibers), preferably synthetic textile fibers, or is formed therefrom; and / or in particular wherein the textile covering layer comprises synthetic fibers (chemical fibers), optionally in combination with natural fibers, preferably cotton fibers, or is formed therefrom; and / or in particular wherein the textile covering layer comprises elastane (EL), in particular elastane fibers; and / or in particular wherein the textile covering layer has a basis weight in the range 2 2 2 2 from 5 g / m to 400 g / m , in particular in the range from 10 g / m to 300 g / m , 2 2 preferably in the range from 20 g / m to 250 g / m , particularly preferably in the range from 30 g / m to 175 g / m , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%; and / or in particular wherein the textile cover layer has a thickness, in particular cross-sectional thickness, in the range from 0.001 mm to 10 mm, in particular in the range from 0.01 mm to 8 mm, preferably in the range from 0.05 mm to 4 mm, preferably in the range from 0.075 mm to 2 mm, particularly preferably in the range from 0.1 mm to 2 mm, further preferably in the range from 0.15 mm to 1 mm, in particular determined according to DIN EN ISO 5084; and / or in particular wherein the textile covering layer comprises a material, in particular textile fibre material, preferably textile fibres, selected from the group of natural materials and synthetic materials, in particular selected from the group of cotton (CO); wool; linen; polyesters;Polyolefins, polyvinyl chloride; polyvinylidene chloride; acetates, in particular cellulose acetates; triacetates, in particular cellulose triacetates; aramids, in particular meta- and / or para-amides; optionally modified and / or regenerated celluloses; polyacrylic; polyamide; polyvinyl alcohol; polyurethanes; polyvinyl esters; modified and / or regenerated celluloses, in particular viscose; and mixtures or combinations thereof, preferably selected from the group of modified and / or regenerated celluloses, in particular; Viscose; aramids, in particular meta- and / or para-amides; polyamide and mixtures or combinations thereof.
123. Protective clothing according to claim 122, wherein the textile cover layer is arranged directly on the adsorption layer (8a) or on the particle and / or aerosol filter layer (8e) and / or is connected thereto; and / or wherein the particle and / or aerosol filter layer (8e) is arranged between the textile cover layer on the one hand and the adsorption layer (8a) or the spacer and / or intermediate layer (8d) on the other hand and / or is connected thereto.
124. Protective clothing according to one of the preceding claims, wherein the adsorption layer (8a) is fixed to the textile carrier layer (8b) in particular by means of a preferably discontinuously, preferably punctiformly, applied adhesive; and / or wherein the spacer and / or intermediate layer (8d) is fixed to the adsorption layer (8a) in particular by means of a preferably discontinuously, preferably punctiformly applied adhesive; and / or wherein the textile cover layer is fixed to the adsorption layer (8a) or to the particle and / or aerosol filter layer (8e) in particular by means of a preferably discontinuously, preferably punctiformly applied adhesive or by lamination.
125. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) has a basis weight in the range of 10 g / m 2 up to 600 g / m 2 , especially in the range of 50 g / m 2 up to 500 g / m2 , preferably in the range of 100 g / m 2 up to 450 g / m 2 , particularly preferably in the range of 150 g / m 2 up to 410 g / m 2 , in particular determined according to DIN EN 12127, preferably after 24 hours of conditioning at a temperature of 20 °C and a relative humidity of 65%; and / or wherein the additional adsorption filter material (8) has a thickness, in particular total cross-sectional thickness, in the range from 0.01 mm to 10 mm, in particular in the range from 0.05 mm to 5 mm, preferably in the range from 0.1 mm to 3 mm, preferably in the range from 0.2 mm to 2 mm, particularly preferably in the Range from 0.5 mm to 2 mm, in particular determined according to DIN EN ISO 5084; and / or wherein the additional adsorption filter material (8) has a gas permeability, in particular air permeability, of at least 1 mm / s, in particular at least 2 mm / s, preferably at least 5 mm / s, more preferably at least 7 mm / s, particularly preferably at least 10 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal;and / or wherein the additional adsorption filter material (8) has a gas permeability, in particular air permeability, in the range from 1 mm / s to 500 mm / s, in particular in the range from 2 mm / s to 400 mm / s, preferably in the range from 5 mm / s to 200 mm / s, preferably in the range from 7 mm / s to 150 mm / s, particularly preferably in the range from 10 mm / s to 100 mm / s, in particular determined according to DIN EN ISO 9237 and / or in particular determined at a differential pressure (flow resistance) of 100 Pascal.; 126. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) has a bursting pressure, in particular determined according to DIN EN ISO 13938-2, of at least 50 kPa (kilopascals), in particular of at least 75 kPa, preferably of at least 90 kPa, particularly preferably of at least 100 kPa; and / or wherein the additional adsorption filter material (8) has a bursting pressure, in particular determined according to DIN EN ISO 13938-2, in the range from 50 kPa (kilopascals) to 1.000 kPa, in particular in the range from 75 kPa to 800 kPa, preferably in the range from 90 kPa to 600 kPa, particularly preferably in the range from 100 kPa to 500 kPa; and / or wherein the additional adsorption filter material (8) has a tensile stress and / or extensibility (elongation) in at least one direction, in particular in the longitudinal or transverse direction, determined according to DIN 53835-14 at 20 Newtons, of at least 2.5%, preferably of at least 5%, preferably of at least 7%; and / or wherein the additional adsorption filter material (8) has a shrinkage in at least one direction, in particular in the longitudinal or transverse direction, determined according to DIN EN 5077, of at most 12%, preferably of at most 10%, preferably of at most 6%.
127. Protective clothing according to one of the preceding claims, wherein the additional adsorption filter material (8) is three-layered and in particular formed as a composite and / or laminate; in particular wherein the additional adsorption filter material (8) comprises or consists of (i) a textile carrier layer (8b) (textile carrier layer of the additional adsorption filter material (8)), in particular as defined in one of claims 101 to 104; (ii) an adsorption layer (8a) (adsorption layer of the additional adsorption filter material (8)), in particular as defined in one of claims 105 to 111; and (iii) a textile cover layer (cover layer of the additional adsorption filter material (8)), in particular as defined in claim 122 or 123, or a textile spacer and / or intermediate layer (8d) (textile spacer and / or intermediate layer of the additional adsorption filter material (8)), in particular as defined in claim 112 or 113;and / or in particular wherein the additional adsorption filter material (8) has the aforementioned layers (i) to (iv) in the series and / or sequence (i), (ii), (iii), (iv); or wherein the additional adsorption filter material (8) is four-layered and in particular designed as a composite and / or laminate; in particular wherein the additional adsorption filter material (8) (i) has a textile carrier layer (8b) (textile carrier layer of the additional adsorption filter material (8)), in particular as defined in one of claims 101 to 104; (ii) an adsorption layer (8a) (adsorption layer of the additional adsorption filter material (8)), in particular as defined in one of claims 105 to 111; (iii) a particle and / or aerosol filter layer (8e) (particle and / or aerosol filter layer of the additional adsorption filter material (8)), in particular as defined in one of claims 114 to 121;and (iv) comprises or consists of a textile cover layer (cover layer of the additional adsorption filter material (8)), in particular as defined in claim 122 or 123, or a textile spacer and / or intermediate layer (8d) (textile spacer and / or intermediate layer of the additional adsorption filter material (8)), in particular as defined in claim 112 or 113; and / or; in particular wherein the additional adsorption filter material (8) has the aforementioned layers (i) to (iv) in the series and / or sequence (i), (ii), (iii), (iv).
128. Protective clothing according to one of the preceding claims, wherein at least one of the opposing edges and / or edges extending and / or arranged along the seam (7), in particular along the seam path of the seam (7), of the additional adsorption filter material (8), in particular the edge of the additional adsorption filter material (8) oriented toward the main extension of the third layer (4) and / or in particular the edge of the additional adsorption filter material (8) oriented toward the main extension of the first layer (2) and / or the second layer (3), preferably the edge of the additional adsorption filter material (8) oriented toward the main extension of the third layer (4), is hemmed and / or is provided and / or equipped with at least one hem and / or edge reinforcement and / or securing means (9, 9'), in particular in the form of a closing and / or closure seam, preferably a finishing seam;and / or wherein the edge of the additional adsorption filter material (8) oriented toward the main extension of the third layer (4) is hemmed and / or provided and / or equipped with at least one hem and / or edge reinforcement and / or securing feature (9), in particular in the form of a closing and / or closure seam, preferably a finishing seam; and / or wherein the edge of the additional adsorption filter material (8) oriented toward the main extension of the first layer (2) and / or the second layer (3) is hemmed and / or provided and / or equipped with at least one hem and / or edge reinforcement and / or securing feature (9'), in particular in the form of a closing and / or closure seam, preferably a finishing seam.; 129. Protective clothing according to one of the preceding claims, wherein the protective clothing (1) has a securing and / or stabilizing seam (11), in particular a topstitching seam, arranged in the connecting region (5); and / or wherein the connecting region (5) has a securing seam (11), in particular a topstitching seam; in particular wherein the securing and / or stabilizing seam (11) runs at least substantially parallel to the seam (7); and / or in particular wherein the securing and / or stabilizing seam (11) is arranged on the side of the seam (4) facing away from the direction of extension of the third layer (4); and / or in particular wherein the securing and / or stabilizing seam (11) is arranged on the side of the seam (4) facing the direction of extension of the first layer (2) and / or the second layer (3); and / or in particular wherein the securing and / or stabilizing seam (11) encompasses the first layer (2), the second layer (3), the third layer (4) and the additional adsorption filter material (8), in particular penetrating or respectivelypasses through; and / or in particular wherein the securing and / or stabilising seam (11) in the event of the first layer (2) and / or the second layer (3), in particular the first layer (2) and the second layer (3), being turned over and / or folded over, in particular as defined in one of claims 43 to 46, encompasses, in particular penetrates or passes through, both the turned over and / or folded over area and the non-turned over and / or non-folded area of the first layer (2) and / or the second layer (3), in particular the first layer (2) and the second layer (3).
130. Protective clothing according to one of the preceding claims, wherein the protective clothing (1) is designed in the form of a headgear and / or a hood, in particular in the form of a hood or a balaclava; and / or wherein the protective clothing (1) comprises a headgear and / or a hood, in particular a hood or a balaclava; in particular wherein the connecting region (5), in particular with the third layer (4), defines and / or delimits a field of vision opening, in particular for sealingly receiving a respiratory mask (10).
131. Protective clothing according to one of the preceding claims, wherein the protective clothing (1), in particular also in the connecting area (5), preferably the seam area (6), has a barrier effect against harmful and / or toxic substances, in particular chemical warfare agents, in particular bis[2-chloroethyl]sulphide (mustard gas, HD), determined according to Method 2.2 of CRDEC-SP-84010, of not more than 4 pg / cm 2per 24 hours, in particular not more than 3.5 pg / cm 2 per 24 hours, preferably not more than 3.0 pg / cm 2 per 24 hours, preferably not more than 2.5 pg / cm 2 per 24 hours, particularly preferably not more than 2.25 pg / cm 2 per 24 hours, most preferably not more than 2 pg / cm 2 per 24 hours, more preferably not more than 1.75 pg / cm 2 per 24 hours.
132. Protective clothing according to one of the preceding claims, wherein the protective clothing (1), in particular also in the connecting area (5), preferably the seam area (6), has a barrier effect against harmful and / or toxic substances, in particular chemical warfare agents, in particular bis[2-chloroethyl] sulfide (mustard gas, HD), determined according to the Laid Drop Diffusive Flow Test of at most 4 pg / cm 2 per 24 hours, in particular not more than 3.5 pg / cm 2 per 24 hours, preferably not more than 3.0 pg / cm 2 per 24 hours, preferably not more than 2.5 pg / cm 2per 24 hours, particularly preferably not more than 2.25 pg / cm 2 per 24 hours, most preferably not more than 2 pg / cm 2 per 24 hours, more preferably not more than 1.75 pg / cm 2 per 24 h, in particular measured as cumulative breakthrough by gas chromatography (GC / FPD) after a mustard gas exposure of 24 h at a temperature of 23 °C and a relative humidity of not more than 5 % RH, in particular with a material sample area of 10 cm 2 , a material exposure to 8 mustard gas drops (each drop volume = 1 pl), a test procedure in a test cell above a PE membrane (10 pm), a flow under the material of 100 ml / min, a flow above the material of 0.5 m / s and a flow through the material of 0 cm / s.
133. Protective clothing (1) with a protective function against chemical and / or biological and / or radioactive pollutants and / or poisons (warfare agents) ("NBC or CBRN protective function"), in particular NBC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, in particular protective clothing (1) according to one of the preceding claims, wherein the protective clothing (1) (a) a first, in particular flat and / or two-dimensional, layer (2) in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer (2a) and a textile carrier layer (2b) ("adsorption layer carrier"), (b) a second, in particular flat and / or two-dimensional, layer (3) in the form of a textile air-permeable covering material ("top layer", "outer fabric") and (c) a third, in particular flat and / or two-dimensional, layer (4) in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers (2, 3, 4) are arranged and / or positioned overlapping one another in a connecting region (5) and are connected, in particular sewn, to one another in the connecting region (5) with a common seam (7) forming a seam region (6) ("layer connecting seam"), wherein at least in the seam region (6) an additional multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped orband-shaped adsorption filter material (8), in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxic substances occurring in the seam region (6) and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxic substances in the seam region (6), wherein the additional adsorption filter material (8) is connected, in particular sewn, to the layers (2, 3, 4) by means of the seam (7) (the same seam (7)), wherein the additional adsorption filter material (8) has an adsorption layer (8a) and a textile carrier layer (8b), in particular wherein the adsorption layer (8a) is arranged on the carrier layer (8b) and / or is firmly connected (attached, fixed) to the carrier layer (8b), preferably by means of lamination, preferably by means of a first adhesive layer, and. wherein the additional adsorption filter material (8) is flat and / or two-dimensional, in particular in the form of a strip (band) and / or strip-shaped (band-shaped).
134. Protective clothing (1) with a protective function against chemical and / or biological and / or radioactive pollutants and / or poisons (warfare agents) ("NBC or CBRN protective function"), in particular NBC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, in particular protective clothing (1) according to one of the preceding claims, wherein the protective clothing (1) (a) a first, in particular flat and / or two-dimensional, layer (2) in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer (2a) and a textile carrier layer (2b) ("adsorption layer carrier"), (b) a second, in particular flat and / or two-dimensional, layer (3) in the form of a textile air-permeable covering material ("top layer", "outer fabric") and (c) a third, in particular flat and / or two-dimensional, layer (4) in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers (2, 3, 4) are arranged and / or positioned overlapping one another in a connecting region (5) and are connected, in particular sewn, to one another in the connecting region (5) with a common seam (7) forming a seam region (6) ("layer connecting seam"), wherein at least in the seam region (6) there is an additional multi-layer, in particular at least two-layer, textile, air-permeable, preferably strip-shaped or band-shaped, adsorption filter material (8), in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxic substances occurring in the seam region (6) and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area (6), is arranged and / or provided and / or present, wherein the additional adsorption filter material (8) is connected, in particular sewn, to the layers (2, 3, 4) by means of the seam (7) (the same seam (7)), wherein in the connecting area (5), in particular in the seam area (6), the third layer (4) with the additional adsorption filter material (8) is arranged and / or positioned between the first layer (2) and the second layer (3), and wherein in the connecting area (5), in particular in the seam area (6), the additional adsorption filter material (8) is arranged and / or positioned between the third layer (4) and the first layer (2), wherein the additional adsorption filter material (8) has an adsorption layer (8a) and a textile carrier layer (8b),in particular wherein the adsorption layer (8a) is arranged on the carrier layer (8b) and / or firmly connected (attached, fixed) to the carrier layer (8b), preferably by means of lamination, preferably by means of a first adhesive layer, and wherein the additional adsorption filter material (8) is flat and / or two-dimensional, in particular in the form of a strip (band) and / or strip-shaped (band-shaped).
135. Protective clothing (1) with a protective function against chemical and / or biological and / or radioactive pollutants and / or poisons (warfare agents) ("NBC or CBRN protective function"), in particular NBC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, in particular protective clothing (1) according to one of the preceding claims, wherein the protective clothing (1) (a) a first, in particular flat and / or two-dimensional, layer (2) in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer (2a) and a textile carrier layer (2b) ("adsorption layer carrier"), (b) a second, in particular flat and / or two-dimensional, layer (3) in the form of a textile air-permeable covering material ("top layer", "outer fabric") and (c) a third, in particular flat and / or two-dimensional, layer (4) in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers (2, 3, 4) are arranged and / or positioned overlapping one another in a connecting region (5) and are connected, in particular sewn, to one another in the connecting region (5) with a common seam (7) forming a seam region (6) ("layer connecting seam"), wherein at least in the seam region (6) an additional multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped or band-shaped, adsorption filter material (8),in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area (6) and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area (6), is arranged and / or provided and / or is present, wherein the additional adsorption filter material (8) is connected, in particular sewn, to the layers (2, 3, 4) by means of the seam (7) (the same seam (7)), wherein in the connecting area (5), in particular in the seam area (6), the third layer (4) with the additional adsorption filter material (8) is arranged and / or positioned between the first layer (2) and the second layer (3), and wherein in the connecting area (5), in particular in the seam area (6),the additional adsorption filter material (8) is arranged and / or positioned between the third layer (4) and the first layer (2) and / or wherein in the connecting region (5), in particular in the seam region (6), the layers (2, 3, 4) and the additional adsorption filter material (8) are arranged and / or positioned in the following sequence: (i) first layer (2), (ii) additional adsorption filter material (8), (iii) third layer (4); (iv) second layer (3), wherein the first layer (2) and / or the second layer (3), in particular the first layer (2) and the second layer (3), in the connecting region (5) each in the direction of the third layer (4) and / or the further adsorption filter material, (8) are folded over and / or folded over, in particular folded over and / or folded over at the edges, wherein the additional adsorption filter material (8) has an adsorption layer (8a) and a textile carrier layer (8b), in particular wherein the adsorption layer (8a) is arranged on the carrier layer (8b) and / or is firmly connected (attached, fixed) to the carrier layer (8b), preferably by means of lamination, preferably by means of a first adhesive layer, and wherein the additional adsorption filter material (8) is flat and / or two-dimensional, in particular in the form of a strip (band) and / or strip-shaped (band-shaped).
136. Protective clothing (1) with a protective function against chemical and / or biological and / or radioactive pollutants and / or poisons (warfare agents) ("NBC or CBRN protective function"), in particular NBC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, in particular protective clothing (1) according to one of the preceding claims, wherein the protective clothing (1) (a) a first, in particular flat and / or two-dimensional, layer (2) in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer (2a) and a textile carrier layer (2b) ("adsorption layer carrier"), (b) a second, in particular flat and / or two-dimensional, layer (3) in the form of a textile air-permeable covering material ("top layer", "outer fabric") and (c) a third, in particular flat and / or two-dimensionally formed, layer (4) in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers (2, 3, 4) are arranged and / or positioned overlapping one another in a connecting region (5) and are connected in the connecting region (5) to a common, a seam region (6) forming a seam (7) ("layer connecting seam"), in particular sewn together, wherein at least in the seam area (6) an additional multi-layer, in particular at least two-layer, textile, air-permeable, preferably strip-shaped or band-shaped, adsorption filter material (8), in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area (6) and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area (6), is arranged and / or provided and / or present, wherein the additional adsorption filter material (8) is connected, in particular sewn, to the layers (2, 3, 4) by means of the seam (7) (the same seam (7)), wherein in the connecting area (5), in particular in the seam area (6),the third layer (4) with the additional adsorption filter material (8) is arranged and / or positioned between the first layer (2) and the second layer (3), and wherein in the connecting region (5), in particular in the seam region (6), the additional adsorption filter material (8) is arranged and / or positioned between the third layer (4) and the first layer (2), and / or wherein in the connecting region (5), in particular in the seam region (6), the layers (2, 3, 4) and the additional adsorption filter material (8) are arranged and / or positioned in the following sequence: (i) first layer (2), (ii) additional adsorption filter material (8), (iii) third layer (4); (iv) second layer (3), wherein the first layer (2) and / or the second layer (3), in particular the first layer (2) and the second layer (3), are each folded and / or turned over in the connecting region (5) in the direction of the third layer (4) and / or the further adsorption filter material (8),in particular folded and / or folded over at the edges, wherein the seam (7), with respect to the first layer (2) and the second layer (3), only covers the folded and / or folded over areas of the first layer (2) and the second layer (3), in particular the folded and / or folded over areas of the first layer (2) and the second layer (3) that are in direct contact with the third layer (4) or the additional adsorption filter material (8), and connects them to the third layer (4) and the additional adsorption filter material (8); and / or, wherein the additional adsorption filter material (8) has an adsorption layer (8a) and a textile carrier layer (8b), in particular wherein the adsorption layer (8a) is arranged on the carrier layer (8b) and / or is firmly connected (attached, fixed) to the carrier layer (8b), preferably by means of lamination, preferably by means of a first adhesive layer, and wherein the additional adsorption filter material (8) is flat and / or two-dimensional, in particular in the form of a strip (band) and / or strip-shaped (band-shaped).
137. Protective material (1) with a protective function against chemical and / or biological and / or radioactive pollutants and / or toxic substances (warfare agents) ("NBC or CBRN protective function"), in particular for NBC protective clothing ("CBRN protective clothing"), preferably for civil or military purposes, wherein the protective material (1) (a) a first, in particular flat and / or two-dimensional, layer (2) in the form of a multi-layer, in particular at least two-layer, textile air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for the adsorption of chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material has an adsorption layer (2a) and a textile carrier layer (2b) ("adsorption layer carrier"), (b) a second, in particular flat and / or two-dimensional, layer (3) in the form of a textile air-permeable covering material ("top layer", "outer fabric") and (c) a third, in particular flat and / or two-dimensional, layer (4) in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material, wherein the layers (2, 3, 4) are arranged and / or positioned overlapping one another in a connecting region (5) and are connected, in particular sewn, to one another in the connecting region (5) with a common seam (7) forming a seam region (6) ("layer connecting seam"), wherein at least in the seam area (6) an additional multi-layer, in particular at least two-layer, textile, air-permeable, preferably strip-shaped or band-shaped, adsorption filter material (8), in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area (6) and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area (6), is arranged and / or provided and / or present, wherein the additional adsorption filter material (8) is connected, in particular sewn, to the layers (2, 3, 4) by means of the seam (7) (the same seam (7)).
138. Protective material according to claim 137, characterized by one or more of the features of claims 1 to 136.
139. Protective equipment and / or protective articles of all kinds, in particular for the civil or military sector, in particular protective clothing, such as protective suits, protective gloves, protective footwear, protective socks, head protection clothing and the like, as well as protective covers, preferably all of the aforementioned protective equipment and / or protective articles for NBC use and / or with a protective function against chemical and / or biological and / or radioactive pollutants and / or toxic substances, manufactured using a protective material as defined in claim 136 or 137 and / or comprising a protective material as defined in claim 136 or 137.
140. Filters and filter materials of all kinds, in particular for the removal of chemical and / or biological and / or radioactive pollutants and / or toxic substances, in particular from air and / or gas streams, such as Protective mask filters, odor filters, surface filters, air filters, in particular filters for room air purification, adsorptive support structures and filters for the medical sector, produced using a protective material as defined in claim 136 or 137 and / or comprising a protective material as defined in claim 136 or 137.
141. Use of a protective material (1 ) as defined in claim 136 or 137 for the production of protective equipment and / or protective articles of all kinds, in particular protective clothing, in particular for the civil or military sector, such as protective suits, protective gloves, protective footwear, protective socks, head protection clothing and the like, and protective coverings of all kinds, preferably all the aforementioned protective materials for NBC use and / or with a protective function against chemical and / or biological and / or radioactive pollutants and / or toxic substances.
142. Use of a protective material (1 ) as defined in claim 136 or 137 for the production of filters and filter materials of all kinds, in particular for the removal of chemical and / or biological and / or radioactive pollutants and / or toxins, in particular from air and / or gas streams, such as ABC protective mask filters, odor filters, surface filters, air filters, in particular filters for room air purification, adsorptive support structures and filters for the medical sector.
143. Method for sealing a connecting region (5) of a plurality of layers (2, 3, 4), in particular a textile air-permeable first layer (2), a textile air-permeable second layer (3) and a non-textile air-impermeable third layer (4), of protective clothing (1) and / or a protective material (1) against chemical and / or biological and / or radioactive pollutants and / or toxic substances, wherein the layers (2, 3, 4) are arranged and / or positioned overlapping one another in the connecting region (5) and are connected, in particular sewn, to one another in the connecting region (5) with a common seam (7) forming a seam region (6) ("layer connecting seam"), wherein at least in the seam region (6) an additional multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped orband-shaped adsorption filter material (8), in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area (6) and / or in particular for preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area (6), is arranged and / or provided, wherein the additional adsorption filter material (8) is connected by means of the seam (7). (the same seam (7)) is connected, in particular sewn, to the layers (2, 3, 4).
144. Use of an (additional) adsorption filter material (8), in particular an (additional) multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped or band-shaped adsorption filter material (8), in a Connection area (5), in particular seam area (6), a Protective clothing (1) and / or a protective material (1) for forming and / or providing a sealing connection against chemical and / or biological and / or radioactive pollutants and / or toxins from layers (2, 3, 4) arranged and / or positioned in the connecting region (5) in an overlapping manner, in particular a textile air-permeable first layer (2), a textile air-permeable second layer (3) and a non-textile air-impermeable third layer (4), wherein the layers (2, 3, 4) are connected, in particular sewn, to one another in the connecting region (5) with a common seam (7) forming a seam region (6) ("layer connecting seam"), and wherein the additional adsorption filter material (8) is arranged and / or provided at least in the seam region (6), wherein the additional adsorption filter material (8) is connected to the layers (2, 3, 4) is connected, in particular sewn,in particular for the purpose of adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins occurring in the seam area (6) by the additional adsorption filter material (8) and / or in particular for the purpose of preventing breakthroughs of chemical and / or biological and / or radioactive pollutants and / or toxins in the seam area (6) by the additional adsorption filter material (8).
145. Use of an (additional) adsorption filter material (8), in particular an (additional) multi-layer, in particular at least two-layer, textile air-permeable, preferably strip-shaped or band-shaped adsorption filter material (8), in a Connection area (5), in particular seam area (6), a Protective clothing (1 ) and / or a protective material (1 ) for forming and / or providing a sealing connection against chemical and / or biological and / or radioactive pollutants and / or poisons of overlapping in the connection area (5) arranged and / or positioned and connected, in particular sewn, layers (2, 3, 4) to one another in the connecting region (5) with a common seam (7) ("layer connecting seam") forming the seam region (6), namely at least one textile air-permeable layer (2, 3) on the one hand and a non-textile air-impermeable layer (4) on the other hand.
146. Use according to claim 145, wherein the additional adsorption filter material (8) is arranged and / or provided at least in the seam region (6), wherein the additional adsorption filter material (8) is connected, in particular sewn, to the layers (2, 3, 4) by means of the seam (7) (the same seam (7)).
147. The method according to claim 143, the use according to claim 144, or the use according to claim 145 or 146, wherein (a) the first, in particular flat and / or two-dimensional, layer (2) is in the form of a multi-layer, in particular at least two-layer, textile, air-permeable adsorption filter material ("inner layer", "inner fabric", "inner lining"), in particular for adsorbing chemical and / or biological and / or radioactive pollutants and / or toxins, wherein the adsorption filter material comprises an adsorption layer (2a) and a textile carrier layer (2b) ("adsorption layer carrier"); wherein (b) the second, in particular flat and / or two-dimensional, layer (3) is in the form of a textile, air-permeable cover material ("top layer", "outer fabric").and wherein (c) the third, in particular flat and / or two-dimensional, layer (4) is present and / or formed in the form of a non-textile, in particular polymer-based and / or plastic-based, air-impermeable sheet material; 148. Method according to claim 143 or 147, use according to claim 144 or 147 or use according to any one of claims 145 to 147, characterized by one or more of the features of claims 1 to 138.
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