A novel method and automated device for intelligent color / shape changeable molecular printing, with multifunctional integrated mechanisms, on various textile-based surfaces

Abstract

In the claimed invention, the design and implementation of an advanced intelligent combined multicomponent multisectoral printer have been disclosed by utilizing a set of combined techniques comprising at least one option among various 2D printing mechanisms, by focusing on 3 preferred printing mechanisms of the heat transfer printing, the planographic printmaking, and the digital printing, in combination, integration, and synchronization with at least one molecular printing technique, from molecular printing techniques based on direct materials / molecules' delivery mechanism such as soft lithography, drop-on-demand (DOD) inkjet printing, nanoimprint lithography (NIL), soft lithography and dip-pen / polymer-pen nanolithography (DPN), in a series of embodiments. These embodiments include the process of designing a technically advanced laser printer system, a technically improved calendar dye-sublimation printing machine, and a special type of offset printer, as the 2D printing unit, along with implementing a novel advanced molecular printer system as the 3D printing unit, with the purpose of conducting innovative simultaneous hybrid 2D-3D printing procedures, by various external stimuli and with relying on applying a wide range of sensitive metastable molecular and macromolecular derivatives possessing various color-changing inherent effects of Adsorchromism, Mechanochromism, Thermochromism, Vapochromism, Photochromism, Electrochromism, Piezochromism, and Solvatochromism.

Description

A novel method and automated device for intelligent color / shape changeable molecular printing, with multifunctional integrated mechanisms, on various textile-based surfaces

[0001] A wide range of printing devices and systems have been established during the past decade with the ability to perform the 2D printing process of designs, images, paintings, schematics, and different design styles on various silk-based, woolen, fabric, polymeric, paper-based, or any other textile-based surfaces and substrates, based on various mechanisms; despite that, there are a series of technical limitations exist among those mentioned devices and systems including the technical restrictions on applying or establishing desired changes or secondary manipulations on designs, styles, images and 2D schematics printed on various surfaces, the lack of changeability, and the lack of modifiability.

[0002] In this claimed invention, several embodiments for the fabrication and implementation of an advanced multi-purpose multicomponent multisectoral printer, which possesses a series of unique hybrid 2D-3D printing techniques, and consists of a set of units, devices, and operating systems, along with a set of mechanical and electromechanical parts and equipment, has been disclosed, with the possession of multitasking characteristics and the capability of performing a complex synchronized and simultaneous 2D-3D printing procedures, by relying on the existence of various mechanical and electromechanical systems, devices and equipment including a unit of technically improved 2D printing, a unit of technically advanced 3D printing device and system, with the ability to execute and implement at least one molecular printing technique, a set of rollers, cylinders, and drums embedded in different points, sections, and compartments of the claimed combined multicomponent multisectoral printer device, with various structural and technical roles and functions, a collection of nano / micro syringes, nano / micronozzles, and complex multicomponent molecular injection systems, a set of mobile plates and substrates, along with a series of several different types of mobile and fixed surface-mounted electromechanical systems, containing a set of technical capabilities and capabilities and capable of performing several different functions and operational roles.

[0003] The technical background of the claimed invention is in the field of designing a printing system, with a special combination printing mechanism to implement the process of printing different designs on different surfaces, focusing on the fields of textile printing and inkjet printing, by relying on various technical advancement and improvement of various methods that can be used in the claimed fields, especially by designing a comprehensive multi-purpose multifunctional approach for conducting advanced hybrid 2D-3D printing techniques; techniques that comprise from a combination of several conventional 2D or 3D printing procedures benefiting from applying multiple technical improvement and efficiency enhancement aspects on several targeted printing techniques, preferably the heat transfer printing, the screen printing, the digital laser printing, the continuous inkjet printing (CIJ), the dye-sublimation printing, as well as various planographic printmaking techniques, i.e. the offset printing (offset lithography), the flexographic printing, drop-on-demand (DOD) inkjet printing, nanoimprint lithography (NIL), dip-pen nanolithography (DPN), and soft lithography.

[0004] The technical background of the claimed invention, can be searched and checked through A61K9 / 5138, B05B12 / 12, B05D1 / 00, B22F12 / 53, B29B2009 / 125, B29C64 / 112, B29C71 / 04, B29C2035 / 0827, B29C67 / 0011, B29K2105 / 0085, B29K2105 / 162, B32B5 / 02, B41C1 / 10, B41C2201 / 00, B41C2210 / 20, B41F1 / 18, B41F7 / 02, B41F7 / 265, B41F7 / 30, B41F11 / 02, B41F16 / 02, B41J2 / 005, B41J2 / 0057, B41J2 / 04, B41J2 / 0458, B41J2 / 04588, B41J2 / 04593, B41J2 / 14, B41J2 / 14233, B41J2 / 155, B41J2 / 1714, B41J2 / 175, B41J2 / 2107, B41J2 / 211, B41J2 / 2114, B41J2 / 2135, B41J2 / 442, B41J2 / 45, B41J2 / 4753, B41J2 / 525, B41J3 / 546, B41J11 / 42, B41J2002 / 012, B41J2002 / 041, B41J2 / 47, B41J3 / 4078, B41J11 / 00, B41J13 / 106, B41M1 / 00, B41M1 / 14, B41M1 / 18, B41M2205 / 02, B41M2205 / 34, B41M2205 / 40, B41M3 / 008, B41M3 / 144, B41M5 / 0011, B41M5 / 0023, B41M5 / 0047, B41M5 / 0058, B41M5 / 0064, B41M5 / 007, B41M5 / 0076, B41M5 / 0256, B41M5 / 286, B41M5 / 333, B41M5 / 38207, B41M5 / 385, B41M5 / 40, B41M5 / 50, B41M5 / 5209, B41M5 / 52, B41M5 / 5218, B41M5 / 5254, B41M7 / 0081, B41N1 / 22, B41M7 / 0045, B41P2200 / 13, B41P2217 / 50, C08F2 / 48, C08J2335 / 02, C08K5 / 315, C08K5 / 3437, C08K5 / 41, C08K5 / 56, C08L83 / 00, C09B23 / 0066, C09B23 / 086, C09B23 / 164, C09B47 / 045, C09B67 / 0016, C09B67 / 0026, C09B11 / 24, C09B23 / 0008, C09B23 / 0016, C09B23 / 00, C09D11 / 03, C09D11 / 10, C09D11 / 30, C09D11 / 40, C09D11 / 54, C09D167 / 00, C09K9 / 02, D06B19 / 0076, D06B23 / 30, D06C15 / 06, D06P1 / 00, D06P1 / 16, D06P1 / 54, D06P3 / 00, D06P5 / 004, D06P5 / 005, D06P5 / 006, D06P5 / 007, D06P5 / 2005, D06P5 / 2011, D06P5 / 22, D06P5 / 30, D06P1 / 5221, D06P1 / 65118, D06P1 / 65143, D06Q1 / 00, D06Q1 / 08, F26B13 / 18, G06F3 / 1204, G03F7 / 00, G03F7 / 0045, G03F7 / 027, G03F7 / 029, G03F7 / 033, G03F7 / 035, G03F7 / 038, G03F7 / 0388, G03F7 / 004 G03F7 / 0755, G03F7 / 0757, G03F7 / 105, G03F7 / 11, G03F7 / 16, G03F7 / 168, G03F7 / 2004, G03F7 / 2006, G03F7 / 2014, G03F7 / 26, G03F7 / 3035, G03G5 / 0696, G03G5 / 06, G03G15 / 04, G03G15 / 757, G03G21 / 1642, G03G21 / 1671, G03G2215 / 00523, G03H1 / 24, G03H2001 / 2263, G03H2001 / 2273, G03H2210 / 22, G03H2222 / 22, G03H2222 / 33, G06K15 / 102, G06K15 / 1247, G06K15 / 1878, G06K15 / 188, G06K2215 / 0094, H01S5 / 18355, H01S5 / 3202, H04N1 / 504, H04N1 / 6027, H05H1 / 2425, H10K71 / 135, Y10T29 / 49401, Y10T428 / 24802 and Y10T428 / 2982 codes of the international patent codes (IPC) and the cooperative patent classification (CPC), in various online databases and international patent search engines.

[0005] By searching keywords such as "Combined Printer", "Combined Molecular Printer", "Nanolithography", "Dye-Sublimation printer with Nanolithography", "Digital Printer with Nanolithography", and " Dip-pen Nanolithography" in international patent databases such as Google Patent, Patent Scope, Lenz, USPTO Patent Center, Espacenat and other similar patent documents and declarations were obtained as follows.

[0006] In the patent No. CN101888929B, under the title of "Rotary flat-bed printing machine ", which was registered on 2009-01-28, a rotary flat-bed printing machine (rotary lithographic printing machine) has been claimed to be designed which has an inking unit with a plurality of inking rolls and a dampening unit with a plurality of dampening rolls, wherein one of the dampening rolls has a porous surface from which the dampening agent exits. In the dampening agent flow, between the dampening roll having the porous surface and the plate cylinder, at least two further rolls are arranged. Moreover, the claimed rotary lithographic printing machine, comprising a plate cylinder, an inking unit having a plurality of inking unit rollers for supplying an ink flow to said plate cylinder, a dampening unit having a plurality of dampening unit rollers for supplying a dampening solution flow to said plate cylinder, one of said dampening unit rollers having a porous surface from which dampening solution emerges and at least two further rollers disposed in the dampening solution flow between said dampening unit roller having said porous surface and said plate cylinder.

[0007] In the patent No. US11512418B2, under the title of "Dye sublimation calender", which was registered on 2021-07-13, A fixation / transfer device for control of dye waste in a dye sublimation process has been taken into consideration. The device comprises a textile inlet, a textile outlet, a heat press or calender, an endless belt for driving the textile from the textile inlet to the textile outlet through the heat press, the heat press being held at a temperature sufficient to cause sublimation of the printing dye, and a cleaning station for cleaning the endless belt, the cleaning station being located downstream of the textile outlet and upstream of the textile outlet. The feed belt may be heated at the cleaning station so that sublimation may assist cleaning. Moreover, the claimed endless belt configured to drive said textile from said textile inlet to said textile outlet through said heat press to fix an image formed from a dye suitable for textiles, the image for fixing being carried on the textile, said heat press being held at a temperature sufficient to cause sublimation of said dye suitable for use with textiles thereby to fix said image, the heated rotary textile-pressing drum being configured to rotate with said textile; also, the alleged cleaning station configured to clean said endless belt to remove traces of said dye suitable for textiles, said cleaning station being located downstream of said textile outlet and upstream of said textile inlet, a path of said textile from said textile inlet to said textile outlet not passing said cleaning station.

[0008] In the patent No. AU2013289853B2, under the title of "An apparatus and process", which was registered on 2012-07-10, an apparatus for printing different images onto a substrate has been discussed, composes of multiple sections which includes: a first cylinder having multiple printing plates, the printing plates having a first inked region that receive ink from an ink source; and a second cylinder having a second inked region and a second non-inked region, wherein the first and second cylinders are operable so that the second inked region of the second cylinder receives ink from the first inked region of the first cylinder, and the second non-inked region of the second cylinder at least partially registers with the first inked region of the first cylinder, yet the second non-inked region is adapted to prevent ink from transferring from the first inked region to the second non-inked region, wherein the second cylinder includes multiple transfer plates, and two or more of the transfer plates of the second cylinder have different second non-inked regions, and different inked regions to print images having some different content and some common content, the second non-inked region of the transfer plates is recessed from the second inked region of the transfer plate, and the images printed by at least two of the transfer plates have different content; wherein the image printed is determined by the parts of the first inked region and the second inked region that register, such that the different content in the images is background (negative) printing formed by the non-inked region of the transfer plates.

[0009] In the patent No. MX2013012016A, under the title of "System and method for printing high definition images with innovative patterns and designs in bed cloth, preferably sheets", which was registered on 2013-10-15, a system and method has been disclosed which was specialized for implementing high resolution images’ printing in textile materials, preferably bed cloth such as sheets and pillow cases, using an improved technique of sublimation, where an arrangement of color profiles is generated in printers, for carrying out the pre-sublimation printing and the sublimation process so as to have the possibility of choosing affordable inks and transfer paper of better quality and pressure that will offer excellent results of sublimation, and where the equipment intended to improve the sublimation consists in a calender with a heat emitting cylinder heated by recirculating hot oil for generating high, constant and uniform temperatures in the whole surface of the cylinder; consequently, the combination of this innovation along with the application of high temperatures enables the solid ink to be transformed into gaseous state in a better way, also obtaining brighter colors that highlight the quality of the images, achieving high definition images of 720 dpi to 1440 dpi in the textile material.

[0010] In the patent No. US8236393B2, under the title of " Inkjet recording material", which was registered on 2009-07-09, an inkjet recording material has been claimed that comprises a supporting substrate, a first bottom base coat applied to at least one surface of said substrate, and a second topcoat layer applied over the claimed base coat. In asserted inkjet recording material, the base coat includes a combination of at least three pigments and the topcoat layer comprises pigments selected from the group consisting of fumed silica, silica gel, precipitated silica, colloidal silica, fumed alumina, boehmite, pseudo-boehmite or a mixture thereof. It has also been noted that the claimed topcoat layer applied over aforementioned base coat, consisting of pigments selected from the group consisting of fumed silica, silica gel, precipitated silica, colloidal silica, fumed alumina, boehmite, pseudo-boehmite, or a mixture thereof.

[0011] In the patent No. US9898231B2, under the title of "System and method of mobile printing using near field communication", which was registered on 2016-09-30, a method of mobile printing using near field communication (NFC) has been taken into consideration which includes executing a mobile printing application installed in a mobile device; setting a wireless connection for data transmission between the mobile device and an image forming apparatus by performing NFC tagging on the image forming apparatus with the mobile device; and automatically performing a function corresponding to a status of the mobile printing application when NFC tagging is performed.

[0012] In the patent No. EP3351602B1, under the title of "Lithographic printing ink, varnish for lithographic inks, and method for producing printed matter using said ink", which was registered on 2016-09-20, a lithographic printing ink has been disclosed which has a highly sensitive curability for active energy beam simultaneously with a high washability with water, and which also has excellent resistance to surface staining in the printing and high water resistance of the cured film. Furthermore, this invention comprises (a) a pigment and (b) a resin possessing an ethylenically unsaturated group as well as a hydrophilic group, further comprising (g) a pigment dispersant, wherein the content of the pigment dispersant (g) is 5 to 50 mass % in relation to 100 mass % of the pigment (a), and wherein the pigment dispersant (g) contains an acidic group, which relates to varnish for such lithographic ink and a method for producing printed material.

[0013] In the patent No. US10921712B2, under the title of "Color developing composition, lithographic printing plate precursor, a method for producing lithographic printing plate, and color developing compound", which was registered on 2018-08-17, a color developing composition has been taken into consideration containing a compound represented by a specific formula, a lithographic printing plate precursor including support and an image-recording layer containing the color developing composition, a method for producing a lithographic printing plate including: exposing the lithographic printing plate precursor in an image pattern; and removing a non-exposed portion in the image-recording layer using at least one of printing ink or dampening water on a printer, and a color developing compound represented by the alleged chemical formula.

[0014] In the patent No. US9643400B2, under the title of "Treatment of release layer", which was registered on 2013-03-05, a method for treating a hydrophobic release layer of an intermediate transfer member for use in a printing process has been provided in which a negatively charged aqueous inkjet ink including a polymeric resin and a colorant is jetted onto the alleged layer, the claimed method comprising contacting the release layer, before jetting the ink, with an aqueous solution or dispersion of a positively charged polymeric chemical agent reducing the tendency of a jetted ink droplet to bead up on the intermediate transfer member. This claimed printing process comprising jetting an aqueous inkjet ink containing a negatively charged polymeric resin and a colorant onto a hydrophobic release layer of an intermediate transfer member, further comprising, prior to said jetting, contacting the hydrophobic release layer with an aqueous solution or dispersion of a polymeric chemical agent having a positive charge density of at least 3 meq / g of polymeric chemical agent and an average molecular weight of at least 1,000, provided that if the positive charge density of the polymeric chemical agent is less than 6 meq / g of polymeric chemical agent then the average molecular weight of the polymeric chemical agent is at least 5,000, wherein the polymeric chemical a ent is selected from the group consisting of linear polyethylene imine, branched polyethylene imine, modified polyethylene imine, poly(diallyldimethylammonium chloride), poly(4-vinylpyridine), polyallylamine, a vinyl pyrrolidone-dimethylaminopropyl methacrylamide co-polymer, a vinyl caprolactam-dimethylaminopropyl methacrylamide hydroxyethyl methacrylate terpolymer, a quaternized copolymer of vinyl pyrrolidone and dimethylaminoethyl methacrylate with diethyl sulfate, a guar hydroxypropyltrimonium chloride, a hydroxypropyl guar hydroxypropyltrimonium chloride, and combinations thereof, and further comprising, after said jetting, transferring the ink to a substrate.

[0015] In the patent No. US10991548B2, under the title of "Modular print head assembly for plasma jet printing , which was registered on 2020-07-07, An apparatus for printing has been claimed comprising: a plasma module for generating a plasma discharge, wherein the plasma module comprises a dielectric tube, a first electrode having a first surface area, and a second electrode having a second surface area, wherein the first electrode and the second electrode are configured to move along the length of the dielectric tube; and (ii) a detachable fluid assembly comprising a dielectric spacer and a cartridge, wherein a proximal end of the dielectric spacer is configured to be attached to or detached from a distal end of the plasma module, and a distal end of the dielectric spacer is coupled to a proximal end of the cartridge, wherein the cartridge comprises an ink inlet, an ink outlet, an ink reservoir, a piezo atomizer, a perforated plate, a lip, or a combination thereof, and wherein the dielectric spacer of the fluid assembly has a length that is greater than a distance between respective centers of the first electrode and the second electrode in the plasma module, and between 5 millimeters (mm) to 216 mm.

[0016] In the patent No. US20110011289A1, under the title of "Rotary lithographic printing machine", which was registered on 2010-07-27, a rotary lithographic printing machine has been disclosed comprising an inking unit having a plurality of inking unit rollers, and a dampening roller having a porous surface from which dampening solution emerges. This claimed rotary lithographic printing machine, comprised: a plate cylinder; an inking unit having a plurality of inking unit rollers for supplying an ink flow to said plate cylinder; a dampening unit having a plurality of dampening unit rollers for supplying a dampening solution flow to said plate cylinder; one of said dampening unit rollers having a porous surface from which dampening solution emerges; and at least two further rollers disposed of in the dampening solution flow between said dampening unit roller having said porous surface and said plate cylinder.

[0017] In the patent No. US11098214B2, under the title of "Dye-sublimation inkjet printing for textile", which was registered on 2017-10-30, a process of direct inkjet printing of an image on an absorbent substrate by using an inkjet dye-sublimation ink composition has been taken into consideration that is formulated to interact with an immobilizing composition such that the ink composition solidifies on the surface of an absorbent substrate, thereby substantially limiting soaking of the ink composition into the substrate. Also provided are a printing process and a printing machine, wherein the ink composition is directly printed on the substrate concomitantly with the immobilizing composition, and thereafter undergoes heat-pressing to afford a dye-sublimation transfer of the dye to the substrate, thereby forming an image that is characterized by sharp and well-defined edges of the dyed fields.

[0018] In the patent No. US11512418B2, under the title of "Sublimation printing processes and fabric pretreatment compositions for ink jet printing onto arbitrary fabrics", which was registered on 2010-08-27, an ink jet printing process for sublimation printing of arbitrary textile fiber substrates has been disclosed which the claimed fiber materials are pretreated with an aqueous coating composition, enabling ink jet printing of natural and regenerated cellulosic fibers and blends thereof with synthetic fibers, by direct sublimation or sublimation transfer printing, applying to said fibers a textile coating or fabric pretreatment composition, wherein said textile coating or fabric pretreatment comprises: an aqueous dispersion of fluoropolymer particles and a non-fluoropolymer binder, wherein said aqueous fluoropolymer dispersion comprises particles of PTFE micro-powder, claimed micro-powder being either a granular-based PTFE micro-powder or a coagulated dispersion-based fine powder PTFE micro-powder, in which the term “micro-powder,” as used herein, refers to very finely divided low molecular weight polytetrafluoroethylene (PTFE) powder, in which the fluoropolymer component composing the dispersed fluoropolymer particles is non-melt-processable PTFE or non-melt-processable modified PTFE, so-called because the PTFE homopolymer is modified by copolymerization with a co-polymerizable ethylenically unsaturated comonomer in a very small amount, typically less than 1% by weight of the copolymer. These powders are either granular-based (suspension polymerized) or (fine powder) coagulated dispersion-based (emulsion or dispersion polymerized) powders. Their molecular weight ranges from a few ten thousand to a few hundred thousand compared to several million for the high molecular weight as-polymerized PTFE granular molding resins and CD-based fine powder extrusion resins.

[0019] In the patent No. JP2003328282A, under the title of "Dry transfer method for ink-jet printing, transfer paper and ink", which was registered on 2002-05-02, a transfer method, with a sublimating dye printed layer and the printed layer is transferred to a polyester fiber fabric by heat has been provided. In fact, the dry transfer method for ink-jet printing is a method with which dry transfer paper for ink-jet printing obtained by providing one side of the paper, etc., with a receiving layer containing sublimating dye-containing ink printed by inkjet and the printed surface is transferred to the fabric by heat and comprises using the dye ink with 160-280°C sublimation point and having 2-20% dye residual ratio after the transfer and the transfer paper for the ink-jet printing is obtained by using the dye ink having a 160-280°C sublimation point and wholly has a 2-20% dye residual ratio after the transfer. The ink for the dry transfer for the ink-jet printing is the dye ink having 160-280°C sublimation point and has 2-20% dye residual ratio after the transfer.

[0020] In the patent No. US11512418B2, under the title of "Dye sublimation calender", which was registered on 2021-07-13, a calender apparatus for the fixation / transfer of images on textile, has been disclosed which operating by dye sublimation procedure, and the dye is suitable for use with textiles, the apparatus consisting of: a dyed textile inlet for input of a textile; a textile outlet for output of said textile; a heat press comprising a calender, the calender comprising a heated rotary textile-pressing drum; an endless belt configured to drive said textile from said textile inlet to said textile outlet through said heat press to fix an image formed from a dye suitable for textiles, the image for fixing being carried on the textile, said heat press being held at a temperature sufficient to cause sublimation of said dye suitable for use with textiles thereby to fix said image, the heated rotary textile-pressing drum being configured to rotate with said textile; and a cleaning station configured to clean said endless belt to remove traces of said dye suitable for textiles, said cleaning station being located downstream of said textile outlet and upstream of said textile inlet, a path of mentioned textile from, mentioned textile inlet to referred textile outlet not passing claimed cleaning station.

[0021] In the patent No. MX2013012016A, under the title of "System and method for printing high definition images with innovative patterns and designs in bed cloth, preferably sheets", which was registered on 2013-10-15, a system and method for printing high resolution images in textile materials has been taken into consideration, preferably bed cloth such as sheets and pillow cases, using an improved technique of sublimation, where an arrangement of color profiles is generated in printers, for carrying out the pre-sublimation printing and the sublimation process so as to have the possibility of choosing affordable inks and transfer paper of better quality and pressure that will offer excellent results of sublimation, and where the equipment intended to improve the sublimation consists in a calender with a heat emitting cylinder heated by recirculating hot oil for generating high, constant and uniform temperatures in the whole surface of the cylinder; consequently, the combination of this innovation along with the use of high temperatures enables the solid ink to be transformed into gaseous state in a better way, also obtaining brighter colors that highlight the quality of the images, achieving high definition images of 720 dpi to 1440 dpi in the textile material.

[0022] In the patent No. US8236393B2, under the title of "Dye sublimation calender", which was registered on 2009-07-09, an inkjet recording material has been claimed, comprising: a supporting substrate; a bottom base coat applied to at least one surface of said substrate, said base coat including a combination of at least three types of pigments; and a topcoat layer applied over said base coat, said topcoat layer comprising pigments selected from the group consisting of fumed silica, silica gel, precipitated silica, colloidal silica, fumed alumina, boehmite, pseudo-boehmite, or a mixture thereof. Furthermore, a fabricating approach of an inkjet recording material has been provided comprising the steps of: preparing an aqueous base coat composition comprising a combination of at least three types of pigments and a topcoat layer composition comprising pigments selected from the group consisting of fumed silica, silica gel, precipitated silica, colloidal silica, fumed alumina, boehmite, pseudo-boehmite or a mixture thereof; applying the base coat composition to at least one side of a supporting substrate to form a bottom base coat layer; applying the topcoat layer composition over said base coat; and drying and calendering the coated substrate.

[0023] In the patent No. US20100053239A1, under the title of "Liquid application apparatus and method, and inkjet recording apparatus", which was registered on 2009-08-28, a liquid application apparatus has been alleged which includes: a drum which holds a sheet-shaped recording medium on a circumferential surface thereof and rotationally conveys the recording medium; a belt which is wrapped about at least a pair of rollers and makes contact with the recording medium held on the circumferential surface of the drum and rotationally conveyed; a belt travel device which causes the belt to travel; and an application liquid supply device which supplies an application liquid to a circumferential surface of the belt, which the application liquid supplied to the circumferential surface of the belt is applied to the recording medium through the belt.

[0024] In the patent No. JPWO2018235395A1, under the title of "Transfer printing method", which was registered on 2018-04-09, a transfer printing method has been provided which satisfying versatility, simplicity, fixability, color developability and fineness. The claimed problems are a step (1) of preparing a transfer sheet, a step (2) of forming a pattern on the transfer sheet by using a pigment ink to obtain a transfer sheet, a step of bringing the transfer sheet into close contact with a printing medium, and heating and applying. The method includes a step (3) of applying pressure, a step (4) of heat-treating the transfer paper and the medium to be printed without being pressed in a contact state, and a step (5) of removing the transfer paper from the medium to be printed. The step (3), the step (4), and the step (5) are achieved by the transfer printing method having this order.

[0025] In the patent No. US10189245B2, under the title of "Method and an assembly for sublimation transfer printing", which was registered on 2016-07-08, a method for sublimation transfer printing has been taken into consideration which comprises multiple continuous and sequential steps of: feeding a web of carrier from a feed mechanism in a machine direction to a carrier transport unit of a sublimation transfer printer provided with multiple digital printing stations, synchronizing the speed of carrier with the movement of said transport unit; positioning carrier on said transport unit; depositing sublimation ink or inks onto carrier whilst synchronizing the speed of carrier with the deposition of the sublimation ink or inks; removing carrier from transport unit and passing carrier with deposited sublimation ink or inks together with a web of substrate material to be printed from a feed mechanism through a heat press at sublimation conditions, transferring the sublimation ink or inks onto the substrate material, and collecting the printed substrate material and used carrier from outlet, wherein the digital printing stations extend transversally to the machine direction and cover the width of carrier.

[0026] In the patent No. JP2003313786A, under the title of "Dry type transfer paper for inkjet textile printing", which was registered on 2021-07-13,

[0027] In the patent No. US11512418B2, under the title of "Dye sublimation calender", which was registered on 2002-04-23, for providing transfer paper homogeneously transcribed in the longitudinal direction in case when transcribed on a polyester fiber fabric by continuous lengthy printing by applying a sublimating dye-printing layer on the transfer paper and heat transcribing it to the polyester fiber fabric, a dry transfer paper for ink-jet printing has been disclosed comprising a receiving surface of an ink-jet printer ink containing a sublimable dye provided on one surface of a flexible support such as paper. Has a total thickness of 50 μm to 150 μm and a width of 25 cm and a length of 1 m or more and an ink-jet printer ink containing a sublimable dye having a sublimation point of 180 ° C. to 280 ° C., and printing at 1440 dpi on the transfer paper ink-receiving layer by an ink-jet printer. Is in contact with a polyester cloth, and the residual ratio (%) of the dye remaining on the print surface after heat transfer at 190 ° C. for 30 seconds is defined as SDR, and the standard deviation of SDR is 2.0 (%) or less.

[0028] In the patent No. EP2471655B1, under the title of "Lithographic printing plate precursor and lithographic printing method", which was registered on 2011-12-28, a lithographic printing plate precursor has been taken into consideration comprising: a support; and an image-recording layer containing a binder, a radical polymerizable compound and a radical polymerization initiator, wherein the binder comprises a polymer compound having a nucleus being derived from a multifunctional thiol having from 6 to 10 thiol groups and polymer chains connected to the nucleus through sulfide bonds derived from these thiol groups and the polymer chains have a polymerizable group. Furthermore, this claimed lithographic printing method facilitating the process of mounting the exposed lithographic printing plate precursor on a printing machine and supplying printing ink and dampening water to remove an unexposed area of the image-recording layer, to conduct printing after image exposure of the lithographic printing plate precursor with laser.

[0029] In the patent No. US11117364B2, under the title of "Color developing composition, lithographic printing plate precursor, method for producing lithographic printing plate, and compound", which was registered on 2019-02-25, acolor developing composition by possessing excellent color developability has been disclosed to provide a lithographic printing plate precursor which is excellent in terms of the plate inspection property by color development and a method for producing a lithographic printing plate in which the lithographic printing plate precursor is used. In addition, another object intends to achieve in this claimed inventios is to provide a new compound that can be preferably used as a color developer.

[0030] In the patent No. US11294279B2, under the title of "Lithographic printing plate precursor, and method for producing lithographic printing plate", which was registered on 2019-10-11, a lithographic printing plate precursor including an image recording layer on a hydrophilic support as well as an approach of preparing a lithographic printing plate has been alleged, which consisting of imagewise exposing a lithographic printing plate precursor, thereby forming an exposed portion and an unexposed portion, and feeding at least one of printing ink or dampening water, thereby removing the unexposed portion, wherein the lithographic printing plate precursor comprises an image recording layer on a hydrophilic support, the image recording layer comprises a polymerization initiator, an infrared absorbent, a polymerizable compound, a polymer particle, and an acid color former, as well as the infrared absorbent which and the difference between the highest occupied molecular orbital (HOMO) of the compound represented by Formula 1 and the highest occupied molecular orbital of the polymerization initiator is 0.57 eV or less.

[0031] In the patent No. AU2020200938A1, under the title of "Ink film constructions", which was registered on 2020-02-10, an ink film construction has been provided comprising: (a) a first printing substrate selected from the group consisting of an uncoated fibrous printing substrate and a commodity coated fibrous printing substrate; and (b) an ink film having an ink dot set contained within a square geometric projection projecting on said first printing substrate, said ink dot set containing at least 10 distinct ink dots, fixedly adhered to a surface of said first printing substrate, all said ink dots within said square geometric projection being counted as individual members of said set, each of said ink dots containing at least one colorant dispersed in an organic polymeric resin, each of said dots having a diameter of 5 to 300 micrometers; each ink dot of said ink dots having a generally convex shape in which a deviation from convexity, (DCdot), is defined by: DCdot = 1 - AA / CSA, AA being a calculated projected area of said dot, said area disposed generally parallel to said first fibrous printing substrate; and CSA being a surface area of a convex shape that minimally bounds a contour of said projected area.

[0032] In the patent No. JP4887173B2, under the title of "Preparation method of lithographic printing plate", which was registered on 2007-02-16, a preparation method of lithographic printing plate precursor has been provided which possessing a photosensitive layer containing (A) an initiator compound, (B) a polymerizable compound and (C) a binder on a support, and having a pH of 2 to 10 after imagewise exposure. Moreover, the claimed photosensitive layer further contains (D) an infrared absorber and (E) a sensitizing dye having a maximum absorption in a wavelength region of 350 to 450 nm. Also, an undercoat layer is provided between the support and the photosensitive layer.

[0033] In the patent No. US10363733B2, under the title of "Photosensitive resin composition, planographic printing plate precursor, method for producing planographic printing plate, and polymer compound", which was registered on 2017-03-02, a positive type lithographic printing plate precursor has been taken into consideration which consisting of: a recording layer which contains a photosensitive resin composition on a support having a hydrophilic surface, wherein the photosensitive resin composition comprises: a polymer compound which has an amine bond or a quaternary ammonium salt bond in the main chain, and at least one bond selected from the group consisting of a urea bond, a urethane bond, and a carbonate bond in the main chain and has a sulfonamide group or a phenolic hydroxyl group in the main chain and / or the side chain; and an infrared absorbing material.

[0034] In the patent No. EP2735444B1, under the title of "Lithographic printing plate precursor for newspaper printing and method for producing the same, and plate making method of lithographic printing plate", which was registered on 2013-11-26, a lithographic printing plate precursor has been disclosed for newspaper printing comprising on a support, an image-recording layer which contains an infrared absorbing dye, a radical polymerization initiator, a radical polymerizable compound, a polymer compound having a polyoxyalkylene chain in a side chain of the polymer compound and an anionic or nonionic surfactant and is capable of being developed with at least one of printing ink and dampening water on a cylinder of a printing machine, characterized in that the lithographic printing plate precursor has a shear droop in which a shear droop amount (X) is from 35 to 150 µm and a shear droop width (Y) is from 50 to 300 µm at an edge of the image-recording layer side, and a region within 1 cm from an edge surface (1c) of the lithographic printing plate precursor including the shear droop has been treated with a treating solution containing an anionic or nonionic surfactant, in which the shear droop amount (X) is a distance from an upper end of the edge surface (1c) of the lithographic printing plate precursor to an extended line of a top surface of the lithographic printing plate precursor, and the shear droop width (Y) is a distance from a point where the top surface of the lithographic printing plate precursor begins to droop to an extended line of the edge surface (1c), wherein the thickness of a layer of the treating solution coated in the region is from 0.1 µm to 50 µm, after drying the treating solution.

[0035] In the patent No. US7901863B2, under the title of "Photosensitive resin composition for laser engravable printing substrate", which was registered on 2005-01-26, a photosensitive resin composition for a laser engravable printing substrate has been provided which comprising a resin (a) having a polymerizable unsaturated group whose number average molecular weight is in the range of 1000 to 20×104, organic compound (b) having a polymerizable unsaturated group whose number average molecular weight is <1000 and organosilicon compound (c) having at least one Si—O bond in each molecule and having no polymerizable unsaturated group in molecules, wherein the content of organosilicon compound (c) is in the range of 0.1 to 10 wt. % based on the whole of photosensitive resin composition.

[0036] In the patent No. JP5014462B2, under the title of "Printing apparatus and sheet processing apparatus", which was registered on 2010-05-11, a printing apparatus has been disclosed which is capable of duplex printing and composed form several assemblies including: a sheet supply unit for holding and supplying continuous sheets; a transport mechanism that transports a sheet having a roller provided with a driving force; a printing unit including a line-type print head for printing on a sheet conveyed by the conveyance mechanism; a reversing unit for reversing the front and back of the sheet printed on the first surface in the printing unit and supplying the same to the printing unit again; a first acquisition unit for acquiring rotation information of the roller; a second acquisition unit that acquires information on the movement state of the sheet by measuring the sheet surface; a control unit including a memory that stores information acquired by the first acquisition unit and information acquired by the second acquisition unit in association with each other and stored as correction data for at least one rotation of the roller, and sequentially prints a plurality of images on the first surface by the printing unit on the sheet supplied from the sheet supply unit, and reverses the front and back of the sheet printed on the first surface by the reversing unit. Supplying to the printing unit, and controlling the printing unit to sequentially print a plurality of images on the second surface on the back side of the first surface, cut and discharge each image, and the claimed control unit can read out the correction data corresponding to the rotation information acquired by the first acquisition unit during printing from the memory, and further corrects at least one of the drive control of the print head and the drive control of the roller. In addition, the printing apparatus controls to make the correction data used for correction different when printing on the first surface and when printing on the second surface.

[0037] In the patent No. US8496326B2, under the title of "Apparatus and methods for controlling application of a substance to a substrate", which was registered on 2012-01-11, Apparatus and methods for controlling application of a substance to a substrate has been provided which involve the use of a functional agent that blocks the substance from or attracts the principal substance to the substrate. The apparatus and methods may utilize ink jet technology to apply the functional agent directly to the substrate or to an intermediate surface. The principal substance may be an ink, a dye, a marking substance other than an ink, or a carrier for any other type of substance. Furthermore, An apparatus for printing has been taken into consideration which comprising; a substrate; means for jetting a gating agent in a layer having a first pattern; means for applying a principal substance in a layer; and means for transferring the principal substance from the substrate to a print medium in a second pattern, wherein the layer of gating agent is disposed atop one of the substrate and the principal substance on the substrate; wherein the gating agent and the principal substance are applied to the same side of the substrate; and wherein the first pattern and the second pattern are the same when the layer of gating agent is intermediate the substrate and the layer of principal substance, and the first pattern and the second pattern are different when the layer of principal substance is intermediate the substrate and the layer of gating agent.

[0038] In the patent No. US5909227A, under the title of "Photograph processing and copying system using coincident force drop-on-demand ink jet printing", which was registered on 1996-04-10, a digital color photograph printer (mini-lab) and a photograph copier has been provided which utilizes a drop on concurrent drop selection and drop separation demand printing mechanism. The system consists of a color continuous tone scanner, a scanner signal conditioning unit, a digital halftoning unit, a data phasing unit, and a printing mechanism using liquid ink. When copying, continuous tone image information from the image scanner is digitally color corrected, digitally halftoned in real-time and printed by the printing head. The system may be operated by a human operator, or may be fully automatic, producing a copy of a photograph after sensing payment by coin, banknote, credit card, or other means.

[0039] In the patent No. US7263752B2, under the title of "Method for manufacturing an ink-jet head", which was registered on 2005-03-31, a method for manufacturing an actuator unit including a piezoelectric sheet has been disclosed which the actuator unit is designed to be laminated on a passage unit having a plurality of pressure chambers formed therein, the claimed method comprising: preparing a member containing the piezoelectric sheet on which a common electrode is supported, the member having a first face to be fixed to the passage unit and a second face facing a direction opposite to the first face, the common electrode being provided to be common to pressure chambers and exposing from a side face of the member that connects the first face and the second face; forming a surface electrode that covers the second face and the side face and contacts the common electrode on the side face of the member; and partially removing the surface electrode on the second face to form individual electrodes at positions corresponding to the respective pressure chambers.

[0040] In the patent No. US8707898B2, under the title of "Apparatus for fanfolding media", which was registered on 2008-03-19, an apparatus for fanfolding media has been provided which having a first and a second side, and the claimed apparatus comprising: a first sensor associated with a first print tower; said first sensor adapted to identify whether the media includes a friable coating on the first side thereof; and said first print tower comprising an anilox roller, a plate cylinder having a relief surface, and an impression roller, the first print tower being adapted to apply an overcoat to a portion of the friable coating on the first side of the media in response to said friable coating being identified thereon by the first sensor; wherein a thermally sensitive coating is the friable coating; and said first print tower is configured to apply said overcoat with sufficiently low thermal resistivity on said first media side to permit heat applied by a thermal printer to image the thermally sensitive coating therethrough.

[0041] In the patent No. US8833893B2, under the title of "Method of printing and printing apparatus", which was registered on 2012-01-27, a method of printing has been provided which initiating by the implementation of printing procedure of a first image on a sheet being conveyed; forming a reference mark for cutting the sheet in a non-image region between the first image and a second image following the first image; printing the second image on the sheet being conveyed; detecting the reference mark; and finally performing the cutting process of the sheet to cut off the non-image region by using a first cutter and a second cutter provided downstream of the first cutter based on the detected reference mark, wherein the reference mark is formed with a length in a conveying direction of the sheet in accordance with a length of the first image in the conveying direction, and the second image is printed to set a length of the non-image region in the conveying direction in accordance with the length of the first image in the conveying direction, and when cutting off the non-image region, the first cutter first cuts off a downstream side of the second image, and then the second cutter cuts off an upstream side of the first image after conveying a cut sheet portion including the first image and the non-image region for a distance determined according to a length of the non-image region.

[0042] In the patent No. US11833840B2, under the title of "Printing using color changeable material", which was registered on 2019-04-04, multiple systems and methods for printing data on a substrate have been taken into consideration which include a color-changeable material. The claimed methods of printing data on a substrate using a printing device, and which the substrate is related to a color-changeable material, comprising: data representative of an image comprising one or more colors to be printed on the substrate with the color-changeable material; and controlling, using the input data, one or more laser diodes to illuminate the color-changeable material to print the image on the substrate, wherein controlling the one or more laser diodes comprises controlling a parameter of light emitted by the one or more laser diodes to cause a portion of the color-changeable material to change to a color of the one or more colors, wherein the color-changeable material is sensitive to the light illuminating the color-changeable material and one component of the color-changeable material changes to a particular color of a plurality of colors based on the parameter of the light illuminating the color-changeable material, wherein all chemical components of the color-changeable material are of a fixed chemical composition and a first area of the one component causes the color-changeable material to change to the particular color of the plurality of colors based on a first value of the parameter of the light illuminating the first area of the one component and a second area of the one component causes the color-changeable material to change to a second color of the plurality of colors based on a second value of the parameter of the light illuminating the second area of the one component; wherein the color-changeable material of the first area is a same material as the color-changeable material of the second area.

[0043] In the patent No. US6796556B2, under the title of "Multi-function media eject system in an ink jet printer", which was registered on 2003-04-25, a media eject system for a printer having an output tray has been provided which comprising: an edge wing for supporting an edge of media exiting the printer, said edge wing movable between support and non-support positions; a kicker for engaging a trailing edge of media and moving the media into the tray, said kicker movable between a retracted position and an extended position and operable to move the media into the tray by movement of said kicker from said retracted position to said extended position; and a controller for determining a print condition including at least one of a media type and a print format, and for adjusting a position of said wing dependent upon asserted print condition.

[0044] In the patent No. US8734037B2, under the title of "Printing apparatus", which was registered on 2010-11-18, an printing apparatus has been provided comprising: a sheet feeding unit configured to feed a sheet that is a continuous sheet; a reverse unit configured to reverse the sheet for duplex printing, wherein, in the duplex printing, a printing unit performs printing a plurality of images on a first surface of the sheet fed from the sheet feeding unit, the printed sheet is reversed by the reverse unit to feed the reversed sheet to the printing unit again, and the printing unit performs printing a plurality of images on a second surface, which is a back of the first surface, of the sheet fed from the reverse unit; the printing unit, wherein the printing unit is configured to print on the sheet and convey the sheet as a conveyed sheet, wherein the printing unit includes: a print head, a first roller pair configured to nip the sheet at an upstream side of the print head to convey the sheet, a second roller pair configured to nip the sheet at a downstream side of the print head to convey the sheet, a third roller pair configured to nip the sheet at an upstream side of the first roller pair to convey the sheet, a direct sensor configured to measure a surface of the conveyed sheet at a measurement position between a nip position of the first roller pair and a nip position of the third roller pair to obtain information relating to a movement speed of the conveyed sheet, and a mark reader configured to read marks, formed on a first surface of the sheet fed from the sheet feeding unit by the print head with a plurality of images, at a reading position between the nip position of the first roller pair and the nip position of the third roller pair when printing on a second surface of the sheet fed from the reverse unit; a humidifying unit having a duct leading to a discharge opening located at an upstream side of the nip position of the third roller pair to introduce a humidifying gas from the humidifying unit in a way that causes the introduced humidifying gas to flow through around the measuring position of the direct sensor, then flow through a gap between the print head and the sheet; and a control unit configured to control to correct at least one of driving control of the print head and conveying control of the sheet based on the information obtained by the direct sensor, and to adjust print positions of each image on the second surface of the continuous sheet to each image on the first surface of the continuous sheet based on read timings by the mark reader.

[0045] In the patent No. US9718972B2, under the title of "Functional inks based on layered materials and printed layered materials", which was registered on 2013-10-22, an ink formulation has been disclosed herein which comprises a carrier liquid with a dispersion of flakes derived from a layered material. The thickness of each flake depends on the number of layers of the layered material in the flake. The thickness distribution of the flakes includes: at least 20% by number of single layer flakes; at least 40% by number cumulatively of single, double and triple layer flakes; or not more than 40% by number of flakes having ten or more layers. The layered material is selected from one or more of elemental materials such as graphene (typically derived from pristine graphite), metals (e.g., NiTe2, VSe2), semi-metals (e.g., WTa2, TcS2), semiconductors (e.g., WS2, WSe2, MoS2, MoTe2, TaS2, RhTe2, PdTe2), insulators (e.g., h-BN, HfS2), superconductors (e.g., NbS2, NbSe2, NbTe2, TaSe2) and topological insulators and thermo-electrics (e.g., Bi2Se3, Bi2Te3). Also disclosed are methods of manufacturing suitable inks and uses of the inks.

[0046] In the patent No. JP2013163380A, under the title of "Image processing method and image processing device", which was registered on 2013-03-25, an image processing method has been provided comprising at least one of: recording an image on a thermoreversible recording medium by heating the thermoreversible recording medium by application of laser beams thereon, the image being formed of a plurality of laser beam lines; and erasing an image from a thermoreversible recording medium by heating the thermoreversible recording medium by application of laser beams, the image being formed of a plurality of laser beam lines, wherein during laser scanning where the laser beams are swept over the medium in parallel at a predetermined distance, the laser beams are sequentially applied in alternating directions, some part of the laser scanning involves a period where laser application is discontinued, and the period where laser application is discontinued involves no laser beam application from a first laser scanning end point to a second laser scanning point, the first laser scanning end point corresponding to the end point of laser scanning started at a first laser scanning starting point, and wherein the thermoreversible recording medium offers temperature-dependent reversible changes in transparency or color tone.

[0047] In the patent No. JP5464263B2, under the title of "Image processing method and image processing apparatus", which was registered on 2012-12-21, An image recording step for recording an image on the thermoreversible recording medium has been taken into consideration which by irradiating and heating a laser beam to a thermoreversible recording medium in which either transparency or color tone reversibly changes depending on temperature, and Including at least one of an image erasing step of erasing an image recorded on the thermoreversible recording medium by irradiating and heating the thermoreversible recording medium with a laser beam; In at least one of the image recording step and the image erasing step, the laser light is parallel light, and the laser output of the peripheral portion with respect to the laser optical axis central portion changes the laser output itself to change the laser optical axis center.

[0048] In the patent No. US8673431B2, under the title of "Ink set for forming multilayer, ink jet recording method, and printed material", which was registered on 2012-08-28, an ink set for forming a multilayer has been claimed which includes a group of coloring ink compositions which include a yellow, a magenta, a cyan and a black ink composition, and a clear ink composition, wherein each of the coloring ink compositions contain a (component A) radical polymerizable compound, a (component B) radical polymerization initiator and a (component D) coloring agent, and the component A contains a (component A-1) N-vinyl compound and a (component A-2) specific ethylenic unsaturated compound (CTFA), the clear ink composition contains a (component A) radical polymerizable compound, a (component B) acylphosphine oxide-based photo-initiator and a (component C) surfactant, and the relation of 0.1≦(Y / X)<1 is satisfied when the content of the radical polymerization initiator in the clear ink composition is X, the content of the radical polymerization initiator in the magenta ink composition is Y.

[0049] In the patent No. US8546301B2, under the title of "On-demand printable construct", which was registered on 2011-06-11, an on-demand printable construct has been provided which consisting of the first and second substrates straddling a thermally printable medium, a bonding agent that secures the substrates together enclosing the thermally printable medium between the two substrates, the thermally printable medium including an area designated within the construct for thermal printing through the first substrate, and the bonding agent being excluded from overlapping with the designated area of the thermally printable medium arranged within the construct for thermal printing.

[0050] In the patent No. US20080050517A1, under the title of "Pulse Heating Methods and Apparatus for Printing and Dyeing", which was registered on 2007-08-23, an apparatus, systems and methods have been disclosed in which one or more dyes are placed on first and second donors, the donors are positioned on the opposite side of a receiver, and a burst of pulse energy is applied to the first donor at a temperature of at least 260° F and a heat energy is applied to the receiver at a lower temperature. Also, it has been claimed that the pulse energy allows for more uniformed application of high energy dyes onto the receiver.

[0051] In the patent No. JP2008246967A, under the title of "Manufacturing process of inkjet recording medium for sublimation ink transfer", which was registered on 2007-03-30, a method for producing an ink jet recording medium has been provided for sublimation ink transfer using a paper support mainly composed of wood pulp, the paper support is composed of two or more paper layers, and 10 g of a layer composed of thermoplastic fine particles is provided between the paper layers. Also, this claimed method of producing an ink jet recording medium for sublimation ink transfer, comprising heating and pressurizing with a calender and smoothing and fusing thermoplastic fine particles between layers to form a layer, the utilized thermoplastic fine particles are polyethylene resin powder and the calendering conditions have been claimed to be adjusted in a roll surface temperature of 80 °C or higher and lower than 200 °C.

[0052] In the patent No. US8995015B2, under the title of "Method of printing", which was registered on 2013-01-10, a method for printing on a substrate has been provided wherein the substrate is printed with a plate-based printing process, particularly with an offset printing process, and with a plateless printing process, particularly with an inkjet printing process, in line with the plate-based printing process, characterized in that a printing resolution of the plateless printing process is determined, by a processor of a plateless printer, depending on a printing speed of the plate-based printing process.

[0053] In the patent No. US8402891B2, under the title of "Methods for printing a print medium, on a web, or a printed sheet output", which was registered on 2011-05-11, a method for variable printing has been taken into consideration composing the steps of: providing a printing cylinder carrying a printing plate having a first area for a variable information to be printed, the entire first area being ink receptive, and a second area containing some ink receptive areas corresponding to a static information to be printed; applying ink to the first area and the second area of the plate; applying an aqueous solution to portions of a particular area of a substrate on a controllable point by point basis to define the variable information; and transferring the ink from the first area of the plate to other portions of the particular area of the substrate that are free of aqueous solution to print the variable information on the substrate and transferring the ink from the second area of the plate to the substrate to print the static information on the substrate; wherein the applied aqueous solution inhibits transfer of the ink to the substrate. Furthermore, a method of printing has been claimed simultaneously, comprising the steps of: utilizing an ink jet head to apply an aqueous solution on a controllable point by point basis to portions of a first particular area of a substrate; applying lithographic ink onto a first portion and a second portion of a cylinder of a lithographic printing press; contacting the first portion of the cylinder with the substrate to print a fixed content at a first area of the substrate and contacting the first particular area with the second portion of the cylinder to transfer lithographic ink from the second portion of the cylinder onto other portions of the first particular area of the substrate that are free of aqueous solution; using the ink jet head to apply aqueous solution on a controllable point by point basis to portions of a second particular area of the substrate different from the first particular area; applying lithographic ink onto the first portion and the second portion of the cylinder; and contacting the first portion of the cylinder with the substrate to print said fixed content at a second area of the substrate and contacting the second particular area of the substrate with the second portion of the cylinder to transfer lithographic ink onto other portions of the second particular area of the substrate that are free of aqueous solution.

[0054] In the patent No. JPS60127154A, under the title of "Sheet-fed offset press", which was registered on 1983-12-15, a sheet-fed offset printing machine has been disclosed which it is characterized in that it is equipped with a printing section having a printing section, and is capable of overprinting images of the same plate multiple times on the same substrate during one rotation of a cylinder without causing any misalignment. It has also been asserted that when there are two printing units, the printed material that has been overprinted with the same image on the front side in the first printing unit is sent to the second printing unit via the delivery cylinder / or the delivery cylinder and the reversing cylinder, or without passing through them.

[0055] In the patent No. US8529049B2, under the title of "Inkjet printing methods and inkjet ink sets", which was registered on 2012-02-16, an inkjet ink set has been claimed which coupled to an inkjet printer, and comprising: at least two or more pigmented non-aqueous color inkjet inks of the same color and color density; wherein the at least two or more pigmented non-aqueous color inkjet inks have a different composition; and the at least two or more non-aqueous color inkjet inks contain the same colorant or colorants.

[0056] In the patent No. US8814337B2, under the title of "Inkjet ink sets for high speed printing on plain papers and glossy media", which was registered on 2007-12-27, an inkjet ink set has been provided which includes a cyan ink, a magenta ink and a yellow ink, wherein each of said cyan, magenta and yellow inks individually comprises at least 65% water, between 1% and 5% by weight of a dispersed pigment colorant, a surfactant that reduces static surface tension, a dynamic surface tension reducing agent distinct from the surfactant, and at least one humectant distinct from the surfactant and the dynamic surface tension reducing agent; and wherein each of said cyan, magenta and yellow inks is characterized by exhibiting a viscosity normalized dynamic surface tension at surface refresh ages of 0.01 s of less than 23.0 mN / (m*cP); and wherein the average viscosity normalized dynamic surface tension at a surface refresh age of 0.01 s for said cyan, magenta and yellow inks taken together is less than 22.0 mN / (m*cP).

[0057] In the patent No. US8337001B2, under the title of "Compact printer with static page width printhead", which was registered on 2010-12-19, a type of printer has been disclosed comprising: an elongate support case defining a docking bay and having a personal computer interface connector protruding from a first end thereof; a print media cartridge configured to dock in the docking bay in a releasable manner; a page-width printhead assembly mounted across a second end of the support case opposite the first end, the page-width printhead assembly including a static ink ejection printhead for ejecting ink upon print media supplied from the print media cartridge; and a series of ink channel reservoirs including one reservoir for each color printed by the ink ejection printhead, the reservoirs being formed around the ink ejection printhead with feed channels progressively reducing in size to feed the printhead.

[0058] In the patent No. US11780154B2, under the title of "Extrusion printing of liquid crystal elastomers", which was registered on 2021-04-23, a method of ink-extrusion printing an object has been discussed which includes the process of providing a mixture including liquid crystal monomers and photo-catalyzing or heating the mixture to produce a liquid crystal ink. Furthermore, the claimed liquid crystal ink for ink-extrusion printing, composing of: a mixture including liquid crystal diacrylate monomers and a chain extending monomer selected from the group consisting of a primary amine chain extending monomer, 2,2′-(ethylenedioxy)diethanethiol, glycol di(3-mercaptopropionate), 1,3-propanedithiol, nonanedithiol, ethanedithiol, hexanedithiol, and combinations thereof, wherein at least some of the liquid crystal diacrylate monomers are part of liquid crystal oligomers of the ink, wherein the chain extending monomer is incorporated between some or all of the liquid crystal diacrylate monomers and terminates the liquid crystal oligomers, and wherein the mixture when at a target printing temperature is in a nematic phase.

[0059] In the patent No. US9714344B2, under the title of "Ultraviolet-ray-curable organopolysiloxane composition, and method for producing printing material", which was registered on 2014-08-19, an ultraviolet-ray-curable organopolysiloxane composition has been asserted which containing: (A) (A-1) a straight-chain organopolysiloxane containing an alkenyl group, and (A-2) a three-dimensional-network-shaped organopolysiloxane resin containing an R12R2SiO1 / 2unit, an R13SiO1 / 2unit, an SiO2unit, and an alkenyl group; (B) an organohydrogenpolysiloxane; (C) a photoactive platinum complex curing catalyst; and (D) an organopolysiloxane oligomer containing an R12R2SiO1 / 2unit or the R12R2SiO1 / 2unit and an R13R2SiO1 / 2unit, also containing an R1SiO3 / 2unit, not containing an SiO2unit, and also containing an alkenyl group. Also, it has been alleged that the ultraviolet-ray-curable organopolysiloxane composition have been eventually retained high strength and have done extremely well suppressing heat-induced expansion or contraction; hence, have made it possible to transfer a pattern and print with high dimensional accuracy.

[0060] In the patent No. EP3002321B1, under the title of "Undercoat composition, composition set, inkjet recording method, and printed material", which was registered on 2015-09-11, an undercoat composition has been disclosed comprising: an isocyanate group-containing compound as Component A, a radically polymerizable monomer containing at least b1 or b3 below as Component B, a photopolymerization initiator as Component C, and a surfactant in a content of 0.001 to 2 mass% relative to the entire mass of the undercoat composition; wherein the total content of b1 and b2 is 50 to 90 mass% relative to the total solids content mass of the undercoat composition, and the total content of b1 and b3 is 5 to 90 mass% relative to the total solids content mass of the undercoat composition, b1: a polyfunctional radically polymerizable monomer having a Log P value of no greater than 2.0, b2: a polyfunctional radically polymerizable monomer having a Log P value of greater than 2.0, and b3: a monofunctional radically polymerizable monomer having a Log P value of no greater than 2.0.

[0061] In the patent No. US9404000B2, under the title of "Flexographic printing process with wet on wet capability", which was registered on 2014-02-27, a flexographic printing process has been referred with wet on wet capability based on controlled polymer or polymer segment precipitation that leads to gel formation of ink compounds by controlling the solubility parameter of the ink system. The mechanism to obtain a desirable wet on wet color trapping is the formation and / or presence of a gel in the applied ink film due to a controlled physicochemical mechanism of resin precipitation. This is accomplished either by controlling a change in the Hansen Solubility Parameter of the liquid in the ink through evaporation of some or all of a non-reactive and volatile solvent, or alternatively by use of a polymer comprised of two distinct and separate segments one of which is soluble in the monomer / oligomer mix and the other of which is not. The insoluble segments form a reversible gel that is broken to a liquid by shear in the application process, allowing application of a liquid ink, and is reestablished in the applied ink film in such a manner and with such strength as to allow overprinting in the wet on wet flexographic printing process.

[0062] In the patent No. US8069782B2, under the title of "Stamps with micrometer- and nanometer-scale features and methods of fabrication thereof ", which was registered on 2005-12-19, a stamp has been disclosed which adapted for imprinting at least one pharmaceutical composition, and comprising a stamp surface, wherein the surface comprises at least two identification regions each having at least one identification feature, the feature having at least one lateral dimension of 10 microns or less, and wherein the size of the stamp is one mm square or less, and wherein the identification regions each have an area of about 10,000 micron squared or less.

[0063] In the patent No. US7491422B2, under the title of "Direct-write nanolithography method of transporting ink with an elastomeric polymer coated nanoscopic tip to form a structure having internal hollows on a substrate", which was registered on 2005-02-14, a method of direct-write nanolithography has been provided which consisting of: transporting an ink from a polymer-coated nanoscopic tip to a substrate to form a structure on the substrate, wherein the ink comprises solvent and the structure comprises internal hollows from direct transfer of the solvent to the substrate, wherein polymer adheres to the tip and is not transported to the substrate, and wherein the polymer is a hydrophobic elastomeric polymer having a glass transition temperature of about 25°C or less. Moreover, this claimed method of transporting ink to a substrate, has been claimed to be implemented through dip-pen nano-lithographic (DPN) stamp tips coated with polymer (e.g., polydimethylsiloxane (PDMS), etc.). It has also been noted this kind of tip adsorbs chemicals (“inks”) easily and is used to generate DPN nanopatterns that are imaged with the same tip after a DPN process and builds a bridge between micro-contact printing (μCP) and DPN, making it possible for one to easily generate smaller structures of any molecules that have been patterned by the μCP technique. The easy tip-coating and writing process enriches the state-of-the-art DPN technique. The sub-100 nm DPN resolution obtained by using this kind of novel tip is comparable to that with a conventional Si3N4probe tip. Importantly, the unique stamp tip was able to transfer solvent (e.g., liquid “ink”) onto a substrate, resulting in fabrication of hollow nanostructures with only one DPN holding / writing step. Inks comprising metals and sol-gel materials are noted, as well as applications in photomask repair, enhancement, and fabrication.

[0064] In the patent No. US20210380829A1, under the title of "Dye-sublimation inkjet printing for textile", which was registered on 2021-08-23, a dye-sublimation ink composition has been claimed which comprising a sublimable dye, a property-sensitive agent and an aqueous carrier, wherein: the composition is substantially devoid of a film-forming agent; and referred property-sensitive agent is characterized by causing congelation of the composition upon contacting a property-adjusting agent.

[0065] In the patent No. US7810538B2, under the title of "Method and apparatus for forming dye sublimation images in solid plastic", which was registered on 2008-08-15, an apparatus for forming a dye sublimation image in a substrate has been provided with a dye carrier which possessing an image formed thereon of a sublimatic dyestuff, the apparatus comprising: a platen, for disposing thereon the substrate, the substrate having further disposed thereon the dye carrier such that the sublimatic dyestuff is in contact with the substrate; a membrane for covering the substrate, the dye carrier, and at least a portion of the platen; a clamping system for applying, with the membrane, a uniform clamping pressure to the substrate and the dye carrier, which clamps the substrate and dye carrier to the platen; a heating device for heating the substrate and the dye carrier from their ambient temperature to a first temperature and for a period of time requisite to form the image in the substrate; and a cooling device for cooling the substrate and the dye carrier to a second temperature following the heating thereof, wherein the clamping system is able to provide the uniform clamping pressure to the substrate and dye carrier as the substrate and dye carrier is in the heating device and the cooling device and therebetween, wherein the platen comprises a vacuum orifice, and wherein the membrane covers the vacuum orifice, and wherein the clamping system comprises a vacuum system for applying a vacuum to the vacuum orifice to create a vacuum between the platen and the membrane.

[0066] In the patent No. US8475905B2, under the title of "Sublimation dye printed textile", which was registered on 2008-02-14, an unstitched design has been taken into consideration by having the appearance of being stitched or embroidered. A stitched design is digitally imaged, and the digital image used to control dye sublimation printing of a representation of the image onto a desired surface. In one configuration, the surface is a woven textile.

[0067] In the patent No. US8485657B2, under the title of "Sublimation printing processes and fabric pretreatment compositions for ink jet printing onto arbitrary fabrics", which was registered on 2010-08-27, an ink jet printing process for sublimation printing of arbitrary textile fiber substrates has been provided, wherein the fiber materials are pretreated with an aqueous coating composition, enabling ink jet printing of natural and regenerated cellulosic fibers and blends thereof with synthetic fibers, by direct sublimation or sublimation transfer printing, applying to said fibers a novel textile coating or fabric pretreatment composition, wherein said textile coating or fabric pretreatment includes: an aqueous dispersion of fluoropolymer particles and a non-fluoropolymer binder.

[0068] In the patent No. US11530330B2, under the title of "Inkjet printing on dyed synthetic fabrics", which was registered on 2018-01-23, an ink-set and a process for direct inkjet printing color images on dyed synthetic fabrics have been disclosed herewith, based on forming an image on the fabric in the form of a well-adhered crosslinked film, using an acid-immobilized ink composition, while avoiding dye migration from the fabric to the image in the process of curing the film, using a low-temperature curing crosslinking agent and curing the image at a temperature lower than 120±5° C.

[0069] In the patent No. US9340694B2, under the title of "Sublimable dye ink for ink jet and dyeing method", which was registered on 2014-02-07, a sublimation transfer dyeing method has been referred which includes: inkjet printing the ink on a sheet recording medium; and superposing a printed surface of the recording medium on an object to be dyed, then heating to sublimate-transfer the sublimating dye to the object to be dyed. Thereby, the present invention provides a sublimating dye ink for ink jets containing a sublimating dye, which has high-quality and stable recording performance, maintains the ink storage stability, and at the same time, the ink has a high print density on a surface of a recording medium, and reduces environmental pollution during a dyeing process.

[0070] In the patent No. US8889338B2, under the title of "Flexographic printing forme precursor for laser engraving", which was registered on 2012-03-27, a method of making a flexographic printing form precursor for laser engraving have taken into consideration which includes the steps of (i) providing at least one layer of a curable composition on a substrate; (ii) curing the at least one layer; wherein the curable composition defining an outermost layer includes at least 0.5% by weight relative to the total weight of the composition of an organo-silicon compound including at least one polymerizable group; and a urethane (meth)acrylate oligomer having three or less polymerizable groups.

[0071] In the patent No. CN101186146A, under the title of "Photochromism printing method, system and device", which was registered on 2006-11-15, a photochromic printing equipment has been claimed for being utilized to be printed on recording medium, and described photochromic printing equipment comprises: Photochromic ink; Inkjet mechanism has spray orifice, and wherein said photochromic ink is injected on the described recording medium through described spray orifice by described inkjet mechanism is inner; and Light source, emission light changes the chemical characteristic of described photochromic ink thus to described photochromic ink.

[0072] In the patent No. JP2542187B2, under the title of "Image-receiving sheet for thermal transfer recording", which was registered on 1986-03-12, an image-receiving sheet for thermal transfer recording, and particularly to a sublimation type or vaporization type thermal transfer recording has been provided which possessing excellent gradation expression and resolution in sublimation vaporization thermal transfer recording. It has been claimed that when used in combination with an ink transfer sheet having an ink containing a sublimable or vaporizable dye as a transfer layer, it receives the dye sublimated or vaporized by each heat of the ink transfer sheet.

[0073] In the patent No. US10279582B2, under the title of "Combined printing press", which was registered on 2015-08-25, a combined printing press has been claimed for the production of security documents, in particular banknotes, comprising a screen printing group, and an intaglio printing group adapted to process substrates in the form of individual sheets or successive portions of a continuous web, wherein the screen printing group is located upstream of the intaglio printing group and comprises at least one screen printing unit designed to print a pattern of optically-variable ink onto one side of the substrates, which optically-variable ink contains flakes that are orientable by means of a magnetic field, wherein the screen printing group further comprises a magnetic unit located downstream of the screen printing unit, which magnetic unit is designed to magnetically induce an optically-variable effect in the pattern of optically-variable ink applied by the screen printing unit, wherein the screen printing group further comprises at least one drying / curing unit designed to dry / cure the pattern of optically-variable ink in which the optically-variable effect has been induced by the magnetic unit prior to transfer of the substrates to the intaglio printing group, wherein the screen printing group comprises a drying / curing assembly located downstream of the magnetic unit and designed to subject the substrates to a drying / curing operation prior to transfer of the substrates to the intaglio printing group, which drying / curing assembly includes a drying / curing cylinder and one or more drying / curing units positioned about part of the circumference of the drying / curing cylinder, and wherein the screen printing group comprises a first drying / curing unit cooperating directly with the magnetic unit.

[0074] In the patent No. US11142013B2, under the title of "Method for smoother tonal response in flexographic printing", which was registered on 2017-05-26, a process for creating a flexographic plate or a mask for producing a flexographic plate has been taken into consideration which includes providing a screen having a resolution defined by a base pattern of equally sized screen spots, each screen spot comprising a smallest exposed discrete element represented on the screen. In at least a non-solid tonal portion of the plate or mask, the size of physical spots are selectively modulated such that each set of four neighboring physical spots in the base pattern has an unexposed area centered therebetween. Each screen spot in the base pattern may be an exposed pixel surrounded by 8 unexposed pixels, each physical spot corresponding to the resolution of a laser beam for exposing the spots on the mask, in which the imaging step includes boosting power of the laser beam for isolated pixels relative to non-isolated pixels. Mask and plates, and imaging systems for creating them, are also disclosed.

[0075] In the patent No. JP2020185684A, under the title of "Image formation device", which was registered on 2019-05-13, an image formation device has been disclosed which includes a print head and a perforation head which are fitted to a carriage and perform scanning. Furthermore, the image formation device performs perforation and printing on a paper surface of a sheet in this order for providing an image formation device that prevents ink smear at perforation with such a configuration as integrating a perforation head with a print head.

[0076] In the patent No. US7525562B2, under the title of "Graphic-arts laser imaging with reduced-length laser cavities and improved performance", which was registered on 2005-05-03, an apparatus for imaging a laser-responsive recording medium has been discussed which composing of several compartments including: a source emitting a beam of radiation; an optical barrier element with an aperture defined therethrough, the optical barrier element blocking an outer portion of the beam whereby the aperture enables transmission of only an inner portion of the beam therethrough, the transmitted inner portion exhibiting a reduced divergence and a reduced beam quality factor (M2) relative to the beam incident on the optical barrier element; a crystal for receiving radiation exiting the aperture, the crystal forming a single-mode radiation beam having an effective aperture based at least in part on the size of the aperture and on a doping level of the crystal; an output coupler for receiving the single-mode light beam formed by the crystal and forming a resonator cavity therewith; and a second optical barrier element with a second aperture defined therethrough, the second aperture being positioned within the resonator cavity to reduce modal power disturbances and configured to pass the fundamental mode of the light beam while blocking higher-order modes.

[0077] In the patent No. JP3086146B2, under the title of "Ink jet recording head, method of manufacturing the same, laser processing apparatus, and ink jet recording apparatus", which was registered on 1995-03-01, a laser processing apparatus for processing a groove, by irradiating a workpiece with a laser beam, an ink jet recording head having a groove processed by the laser processing apparatus, and an ink jet recording apparatus having the ink jet recording head. This claimed apparatus possesses a concave portion for forming an ink passage communicating with a discharge port for discharging ink by laser processing, which possessing the capability of forming into a plate, and forming a filter on the path at once with the formation, and a step of forming the passage by joining the recess is formed a side of the substrate to another substrate. Furthermore, the alleged passage composed form a flow path communicating with the discharge port and a common liquid chamber connected to a plurality of the flow paths.

[0078] In the patent No. JP6527899B2, under the title of "Ink-jet ink for textile printing, ink cartridge, and ink-jet textile printing method", which was registered on 2017-03-15, an inkjet ink for textile printing has been provided which comprising a pigment, wherein the pigment is dispersed and composed form various components including the water, multiple aqueous organic solvents, water-insoluble dyes, dispersing agents, fat, resins and a crosslinking agent, wherein the water-insoluble dyes and the resins are dispersed.

[0079] In the patent No. JP6433568B2, under the title of "Inkjet ink composition for building material printing, inkjet ink set for building material printing, inkjet recording method, and decorative building material", which was registered on 2015-01-30, an inkjet ink composition has been disclosed for printing building materials, which has been claimed to have excellent curability, inkjet discharge properties, weather-resistance of cured ink composition, adhesion of cured ink composition, and ink storage stability; an inkjet ink set for printing building materials; and an inkjet recording method. Also provided are decorative building materials having outstanding weather-resistance.　This inkjet ink composition for printing building materials is characterized by containing: as component A, a specific radical polymerizable compound; as component B, a radical polymerization initiator; as component C, a coloring pigment; and as component D, a pigment dispersant.

[0080] In the patent No. US10029451B2, under the title of "Non-contact transfer printing", which was registered on 2016-12-09, a transfer printing process that exploits the mismatch in mechanical or thermo-mechanical response at the interface of a printable micro- or nano-device and a transfer stamp, has been provided for driving the release of the device from the stamp and its non-contact transfer to a receiving substrate are provided. The resulting facile, pick-and-place process is demonstrated with the assembling of 3-D microdevices and the printing of GAN light-emitting diodes onto silicon and glass substrates. High speed photography is used to provide experimental evidence of thermo-mechanically driven release. This claimed method of transferring ink from a donor substrate to a receiving substrate, comprises several steps including: providing a non-ablative transfer device having a transfer surface; providing the claimed donor substrate having a donor surface, and said donor surface having ink thereon, wherein said ink is a micro-sized or nano-sized prefabricated electronic, optical, or electro-optical device or device component thereof; contacting at least a portion of said transfer surface with at least a portion of said ink; separating said transfer surface from said donor surface, wherein said ink is transferred from said donor surface to said transfer surface; positioning said transfer surface having said ink disposed thereon into alignment with a receiving surface of said receiving substrate; and actuating referred transfer device, claimed ink, or both of discussed transfer device and said ink by generating a non-ablative force that releases at least a portion of said ink from said transfer surface, thereby transferring said ink to said receiving surface, wherein said step of actuating comprises mechanically stressing an interface between said transfer surface and said ink so as to cause delamination, thereby resulting in release of said ink.

[0081] In the patent No. US9937734B2, under the title of "Method for the indirect application of printing liquid onto a printing material", which was registered on 2016-02-18, an approach for the indirect application of printing liquid onto a printing material has been taken into consideration which the claimed method comprising the following steps: providing an intermediate carrier having an outer layer with a relatively low thermal conductivity; applying a printing liquid on the intermediate carrier only at printing points corresponding to a printing image in an inkjet method; heating the printing liquid; transferring the printing liquid or its evaporated remaining ink layer in a press nip from the intermediate carrier onto the printing material; heating the intermediate carrier locally at the points at which the printing image is to be subsequently applied or has already been applied before the application of the printing liquid; and applying a conditioning medium after the heating step and before the step of applying the printing liquid.

[0082] In the patent No. US11168940B2, under the title of "Adjustable interlacing of drying rollers in a print system", which was registered on 2020-06-23, multiple systems and methods have been taken into consideration for adjustable interlacing of drying rollers in a print system. One system is an apparatus that includes first rollers that conduct heat from a heat source, and dry a web of print media as the web travels over a front side of the first rollers in a first direction. A last roller of the first rollers turns the web in a second direction. The apparatus also includes second rollers disposed a distance above the first rollers and that transport the web in the second direction. The apparatus further includes a movement mechanism that reduces the distance between the second rollers and the first rollers to cause the second rollers to occupy spaces between the first rollers so that the web traveling in the second direction contacts a back side of the first rollers to further dry the web.

[0083] In the patent No. US9789699B1, under the title of "Apparatus and method for thermal transfer printing", which was registered on 2017-03-24, methods, systems, and apparatus, including medium-encoded computer program products have been disclosed for the purpose of thermal transfer printing include, in at least one aspect, a printing apparatus includes: a band capable of holding hot melt ink thereon; rollers configured and arranged to hold and transport the band with respect to a substrate; a printhead configured and arranged to thermally transfer a portion of the ink from the band to the substrate to print on the substrate; and a heating device configured and arranged to heat the band to cause ink on the band to re-melt, flow and replace at least some of the portion of the ink transferred to the substrate previously before arriving at the printhead again for a next print.

[0084] In the patent No. US10302508B2, under the title of "Co-topo polymeric compositions, devices and systems for controlling threshold and delay activation sensitivities", which was registered on 2018-01-02, a method of detecting the occurrence of a stimulus has been claimed which consisting of: the process of applying a stimulus to a co-topo-polymeric indicator composition comprising a copolymer of a co-crystallized first alkyl ester diacetylenic acid monomer and a second alkyl ester diacetylenic acid monomer that is distinct from the first alkyl ester diacetylenic acid monomer; and the process of assessing said co-topo-polymeric indicator composition for the occurrence of a color change.

[0085] In the patent No. US8866861B2, under the title of "Systems and methods for automatic print alignment", which was registered on 2013-03-14, a technical approach for print alignment by a continuous feed printer has been disclosed which comprising the procedures of: detecting, by a sensor of a printer, a first line of a pattern on a non-printing side of a printing medium, the pattern comprising two non-parallel lines separated by a predetermined distance at a predetermined position of the printing medium; advancing, by the printer, the printing medium a first distance; detecting, by the sensor, a second line of the pattern; advancing, by the printer, the printing medium a second distance; detecting, by the sensor, a third line of the pattern; identifying a difference between the first distance and the second distance; and identifying, by the printer, a horizontal offset of the printing medium from an expected location of the predetermined position proportional to the difference between the first distance and the predetermined distance, and proportional to the difference between the first distance and the second distance.

[0086] In the patent No. US11370862B2, under the title of "Radiation-sensitive composition, planographic printing plate precursor, and plate-making method for planographic printing plate", which was registered on 2019-05-12, a planographic printing plate precursor has been disclosed which includes: a support; and an image recording layer which includes a radical initiator, a radical polymerizable component, and a radiation absorption compound, and in which the image recording layer shows two or more peaks of a radical generation amount in a radical generation amount-versus-time curve after exposure to image forming radiation, in which the radical initiator includes an electron-donating radical initiator and an electron-accepting radical initiator, and the radiation absorption compound with possessing especial chemical substitutes and certain chemical backbone.

[0087] In the patent No. US8267506B2, under the title of "Ink jet printer device and humidification method of ejection portion", which was registered on 2009-09-23, an inkjet printer device has been provided which composed of: an ejection portion that ejects an ink droplet onto a recording medium; a humidification portion that is provided upstream of the ejection portion in a transportation direction of the recording medium and ejects a wetting liquid droplet onto the recording medium; and a control portion that makes the ink droplet be ejected onto the recording medium from the ejection portion and the wetting liquid droplet be ejected onto the recording medium from the humidification portion, wherein the ejection portion is humidified during printing by letting the wetting liquid droplet ejected onto the recording medium evaporate from the recording medium.

[0088] In the patent No. US5305018A, under the title of "Excimer laser-ablated components for inkjet printhead", which was registered on 1992-03-09, a newly designed inkjet printhead has been taken into consideration which includes a nozzle plate formed of a polymer material that has been photo ablated or photo-etched to form inkjet nozzles. The polymer material preferably is a plastic such as Teflon, polyimide, polymethylmethacrylate, polyethyleneterephthalate or mixtures thereof. The nozzle plate also has formed in it a plurality of vaporization chambers. The inkjet nozzles are preferably formed in a flexible strip of polymer film by masked laser radiation, where the mask is physically spaced from the polymer film. Heater resistors may be formed on the nozzle plate within each of the vaporization chambers.

[0089] In the patent No. US6527357B2, under the title of "Assisted drop-on-demand inkjet printe", which was registered on 2001-07-23, a droplet generator has been disclosed that is particularly adapted for generating micro droplets of ink on demand in an inkjet printhead having a plurality of nozzles. The claimed droplet generator includes a droplet separator formed from the combination of a droplet assistor and a droplet initiator. The mentioned droplet assistor is coupled to ink in each of the nozzles and functions to lower the amount of energy necessary for an ink droplet to form and separate from an ink meniscus extending across the nozzle outlet. The droplet assistor may be, for example, a heater or surfactant supply mechanism for lowering the surface tension of the ink meniscus. Alternatively, the droplet assistor may be a mechanical oscillator such as a piezoelectric transducer that generates oscillations in the ink sufficient to periodically form convex ink meniscus across the nozzle outlets, but insufficient to cause ink droplets to separate from the outlets. The droplet initiator cooperates with the droplet assistor and selectively causes an ink droplet to form and separate from the ink meniscus. The droplet initiator may be, for example, a thermally-actuated paddle. The droplet separator increases the speed and accuracy of ink micro droplets expelled from the printhead nozzles.

[0090] In the patent No. US10722947B2, under the title of "Micro-selective sintering laser systems and methods thereof", which was registered on 2017-03-31, a microscale selective laser sintering (μ-SLS) has been discussed that enhanced the minimum feature-size resolution of metal additively manufactured parts by up to two orders of magnitude, while still maintaining the throughput of traditional additive manufacturing processes. The microscale selective laser sintering includes, in some embodiments, ultra-fast lasers, a micro-mirror based optical system, nanoscale powders, and a precision spreader mechanism. The micro-SLS system is capable of achieving build rates of at least 1 cm3 / hr while achieving a feature-size resolution of approximately 1 μm. Furthermore it has been noted that the exemplified systems and methods facilitate a direct write, microscale selective laser sintering μ-SLS system that is configured to write 3D metal structures having features sizes down to approximately 1 μm scale on rigid or flexible substrates. The exemplified systems and methods may operate on a variety of material including, for example, polymers, dielectrics, semiconductors, and metals.

[0091] In the patent No. US11579561B2, under the title of "Cartridge and drum unit for electrophotographic image forming apparatus", which was registered on 2022-09-23, a technically improved cartridge has been asserted which includes a photosensitive drum, a developing roller, and a casing rotatably supporting the photosensitive drum and the developing roller. The casing includes a groove open to outside of the casing. The casing also includes first and second projected parts that project from the first end portion of the casing in the direction of a rotational axis of the photosensitive drum and away from the photosensitive drum. As seen in the direction of the rotational axis of the photosensitive drum, the rotational axis of the photosensitive drum and the groove are positioned along a line in the extended direction, with the first projected part being positioned on one side of the line and the second projected part being positioned on the other side of the line. A first end of the groove and a second end of the groove are open such that the groove forms a channel in the casing along the extended direction.

[0092] In the patent No. US9176417B2, under the title of "Surface-emitting laser device, surface-emitting laser array, optical scanner, image forming apparatus, and method for manufacturing surface-emitting laser device", which was registered on 2014-04-04, a surface-emitting laser device has been disclosed which composing a transparent dielectric layer situated in an emitting region and configured to cause a reflectance at a peripheral part to be different from a reflectance at a central part in the emitting region. In the surface-emitting laser device, the thickness of a contact layer is different between a region having a relatively high reflectance and a region having a relatively low reflectance in the emitting region. The contact layer is provided on the high refractive index layer of an upper multilayer film reflecting mirror, and the total optical thickness of the high refractive index layer and the contact layer in the region having the relatively low reflectance is deviated from an odd number multiple of a one quarter oscillation wavelength of laser light emitted from the emitting region.

[0093] In the patent No. US10241400B2, under the title of "Color developing composition, lithographic printing plate precursor, plate making method for lithographic printing plate, and color developer", which was registered on 2017-01-17, a color developing composition has been disclosed which has been claimed to develops colors in a high density and does not significantly discolor when aged, a lithographic printing plate precursor which has excellent plate-inspecting properties by means of color development and is capable of maintaining strong color development even when aged after color development, a plate making method for a lithographic printing plate in which the lithographic printing plate precursor is used, and a new compound that can be preferably used as a color developer.

[0094] In the patent No. US7633599B2, under the title of "Apparatuses and methods for changing an intensity distribution of light within an illumination field without distorting the telecentricity of the light", which was registered on 2006-09-20, an apparatus for altering an intensity distribution of a light within an illumination field has been provided which includes several sections including: a structure configured to be positioned within the illumination field so that a first portion of the light within the illumination field impinges upon the structure, the first portion of the light having a first area defined by a first value, wherein the structure is one of translucent to a wavelength of the light and opaque to the wavelength; and an actuator configured to cause a movement of a first portion of the structure so that a second portion of the light within the illumination field impinges upon the structure, the first portion of the structure being a flap coupled to a second portion of the structure, the second portion of the light having a second area defined by a second value, the second value different from the first value; wherein the light within the illumination field is produced by a source configured so that a pupil fill of a beam of the light is uncontrolled, but the beam of the light downstream of the structure is substantially telecentric before and after the movement of the first portion of the structure.

[0095] In the patent No. US9700908B2, under the title of " Techniques for arrayed printing of a permanent layer with improved speed and accuracy ", which was registered on 2015-06-30, a repeatable manufacturing process has been disclosed which is utilized a printer to deposits liquid for each product carried by a substrate to form respective thin films. In this claimed process, the liquid is dried, cured or otherwise processed to form from the liquid a permanent layer of each respective product. To perform printing, each newly-introduced substrate is roughly mechanically aligned, with an optical system detecting sub-millimeter misalignment, and with software correcting for misalignment. Rendering of adjusted data is performed such that nozzles are variously assigned dependent on misalignment to deposit droplets in a regulated manner, to ensure precise deposition of liquid for each given area of the substrate. For example, applied to the manufacture of flat panel displays, software ensures that exactly the right amount of liquid is deposited for each “pixel” of the display, to minimize likelihood of visible discrepancies in the resultant display.

[0096] In the patent No. US9902818B2, under the title of "Isolated and fixed micro and nano structures and methods thereof", which was registered on 2015-05-05, a delivery device for discrete micro and nanoscale particles has been taken into consideration which consisting of: a dissolvable substrate of a first material, wherein the dissolvable substrate is dissolvable in biological fluids; and a plurality of substantially monodisperse particles configured from a second material; wherein, each particle of the plurality has (i) an engineered shape bounded by six substantially planar surfaces that each span respective entire sides of the particle and (ii) a maximum cross-sectional dimension of less than about 10 micrometers; wherein the plurality of substantially monodisperse particles are coupled with the dissolvable substrate in a substantially predetermined orientation; and wherein the second material comprises a therapeutically or pharmaceutically active agent dispersed throughout the entire particle.

[0097] In the patent No. US10095135B2, under the title of "Phthalocyanine crystal, and electrophotographic photoreceptor, electrophotographic photoreceptor cartridge and image-forming device using the same", which was registered on 2017-08-07, an excellent phthalocyanine crystal having high sensitivity and little fluctuation in sensitivity for a humidity change in a use environment and applicable to the martial for solar battery, electronic paper, electrophotographic photoreceptor, etc. Namely, phthalocyanine crystal obtained by bringing a phthalocyanine crystal precursor into contact with an aromatic aldehyde compound to convert the crystal form. Also, an electrophotographic photoreceptor has been provided that not only exhibits high sensitivity but also has little fluctuation in sensitivity for a humidity change in a use environment. Further, provided is an electrophotographic photoreceptor cartridge and an image-forming device, both of which can produce a stable quality images for a humidity change in a use environment by using the electrophotographic photoreceptor.

[0098] In the patent No. US10991548B2, under the title of "Modular print head assembly for plasma jet printing", which was registered on 2020-07-07, an apparatus for performing plasma jet printing has been disclosed which comprises: (i) a plasma module for generating a plasma discharge, wherein the plasma module comprises a dielectric tube, a first electrode having a first surface area, and a second electrode having a second surface area, wherein the first electrode and the second electrode are configured to move along the length of the dielectric tube; and (ii) a detachable fluid assembly comprising a dielectric spacer and a cartridge, wherein a proximal end of the dielectric spacer is configured to be attached to or detached from a distal end of the plasma module, and a distal end of the dielectric spacer is coupled to a proximal end of the cartridge, wherein the cartridge comprises an ink inlet, an ink outlet, an ink reservoir, a piezo atomizer, a perforated plate, a lip, or a combination thereof, and wherein the dielectric spacer of the fluid assembly has a length that is (i) greater than a distance between respective centers of the first electrode and the second electrode in the plasma module, and (ii) between 5 millimeters (mm) to 216 mm.

[0099] In the patent No. US11155676B2, under the title of "Polymer composition for selective sintering", which was registered on 2017-04-06, a polymer powder composition has been discussed for the production of shaped objects via selective laser sintering includes a thermoplastic material, which is a polyester, wherein the powder has specific particles size distribution. The thermoplastic material has: has a crystallization half time of >30 s and <12 min at a supercooling of 50° C. below the peak melt temperature; a glass transition temperature Tg of >50° C.; a peak melt temperature Tp,m of >200° C.; an extrapolated first heating run melt onset temperature Tei,m of >5° C. above the extrapolated first cooling run crystallization end temperature Tef,c; and a degree of crystallinity of >10.0%. The polymer composition has a continuous use temperature of >100° C., and a low change of molecular weight during exposure to selective laser sintering processing temperatures.

[0100] In the patent No. US9994020B2, under the title of "High viscosity jetting method", which was registered on 2015-09-21, a method for jetting a liquid has been claimed which includes the steps of: providing a piezoelectric printhead including a nozzle having a shape including an outer edge within a minimum covering circle, a maximum distance from the outer edge to a center of the minimum covering circle being greater than or equal to a minimum distance from the outer edge to the center of the minimum covering circle times 1.2; jetting the liquid through the nozzle at a viscosity of 25 mPa·s to 1000 mPa·s; and recirculating the liquid through the piezoelectric printhead.

[0101] In the patent No. US7548360B2, under the title of "Holographic printer", which was registered on 2008-03-11, a dual mode holographic printer has been provided which being operable in a first mode of operation for directly writing a 1-step white-light viewable hologram and in a second mode of operation for writing a master hologram (H1) that is used thereafter to produce a white-light viewable hologram (H2), said holographic printer comprising: a pulsed laser source arranged to produce a laser beam at a first wavelength, said laser beam being split into an object beam and a reference beam which is mutually coherent with said object beam; an aperture arranged in the path of said reference beam and a reference beam lens arranged downstream of said aperture; a reference beam telescope arranged to control the size of said reference beam; a spatial light modulator wherein, in use, said object beam illuminates said spatial light modulator; a first lens system for writing a holographic pixel of said hologram on to a photosensitive medium, said first lens system being arranged downstream of said spatial light modulator and being arranged to focus said object beam to a minimum beam waist at a Fourier plane defined by said first lens system; and positioning means for positioning said photosensitive medium at said Fourier plane in said first mode of operation and at a position downstream of said Fourier plane in said second mode of operation; wherein said reference beam lens arranged downstream of said aperture produces an approximate image of said aperture at the surface of said photosensitive medium.

[0102] In the patent No. US7636166B2, under the title of "Interferometer system for monitoring an object", which was registered on 2007-01-23, a interferometric-based system has been claimed comprising: a first object mounted relative to a second object, the first object being moveable with respect to the second object; a plurality of interferometers each configured to derive a first wavefront and a second wavefront from input radiation and to combine the first and second wavefronts to provide output radiation comprising information about an optical path length difference between the paths of the first and second wavefronts, each interferometer comprising a reflective element positioned in the path of the first wavefront and mounted on the first object, where the reflective element for each interferometer is mounted at a different location on the first object relative to the reflective elements for the other interferometers; a plurality of fiber waveguides, each fiber waveguide being configured to deliver the input radiation to a corresponding interferometer and direct the output radiation from the corresponding interferometer to a corresponding detector; and an electronic controller coupled to the corresponding detectors and programmed to monitor, for each interferometer, a corresponding degree of freedom of the first object relative to the second object based on the information from at least one of the interferometers, wherein the degree of freedom for each interferometer is an absolute displacement between the first and second objects.

[0103] A diverse array of printing devices and systems has emerged over the past decade, capable of executing the 2D printing process for designs, images, paintings, schematics, and various design styles on a multitude of surfaces and substrates, including silk, wool, fabric, polymers, and paper. These advancements are based on different mechanisms; however, several technical limitations persist among these devices and systems. These limitations include restrictions on implementing or making desired alterations or secondary modifications to the printed designs, styles, images, and 2D schematics on various surfaces, as well as a lack of adaptability and modifiability.

[0104] In this claimed invention, the design and implementation of an technically enhanced intelligent combined multicomponent multisectoral printer, has been taken into consideration by benefiting form a set of combined techniques comprising at least one option among the 3 preferred aforementioned 2D printing mechanisms including the heat transfer printing, the planographic printing, and the digital printing, in combination, integration, and along with at least one molecular printing technique, from molecular printing techniques based on direct materials / molecules' delivery mechanism such as soft lithography, dip-pen nanolithography, polymer-pen lithography techniques and as well as other molecular printing techniques based on the direct energy delivery mechanism, such as nanografting, nanoshaving, anodic oxidation, and millipede techniques, which enable the creation of a set of molecular layers with improved capabilities on different printing surfaces and substrates.

[0105] As mentioned previously, various printing devices and systems have been established with the ability to apply the 2D printing process of designs, images, paintings, schematics, and different design styles on various silk-based, woolen, fabric, polymeric, paper-based, or any other textile-based surfaces and substrates, based on various mechanisms and techniques including the intaglio printing techniques to implement printing processes on incised surfaces, including engraving (Rotogravure), etching, drypoint, aquatint and mezzotint printing processes, the relief printing techniques in order to apply printing processes on raised surfaces such as woodcut, anastatic printing (relief etching), linocut and metal cut printing processes, the planographic printing techniques, for the process of implementation and application of printing procedures on various flat surfaces, such as flexography, lithography and offset lithography printing techniques as well as a set of digital printing techniques, for applying color printing procedures and techniques (inkjet printing) of digital images on different types of paper, cloth, silk, wool, fabric, and polymer surfaces, such as dye-sublimation, laser printer and other types of inkjet printers such as drop-on-demand inkjet printers.

[0106] Despite the existing technical differences and the use of various mechanisms in applying printing processes, several common technical limitations exist among those mentioned devices and systems, and in this claimed invention, by applying a series of structural changes and additions, an attempt has been made to overcome those limitations and improve the efficiency and expand the ability to apply combined printing for them. The first limitation that can be mentioned is the inability to apply the printing process several times on the targeted surfaces or substrates. In fact, the 2D printing process of various images and schematics based on the mentioned mechanisms is one-time and fixed, and after the process of printing designs, schematics, images, or any other design styles, based on each of the considered 5 mechanisms of heat transfer printing, intaglio printing, relief printing, planographic printing and digital printing, preferably the 3 of those 2D printing mechanisms i.e. the heat transfer printing, planographic printing, and digital printing techniques as the main focus in this invention, on various textile-based substrates and surfaces, it will not be possible to impose any alteration or manipulation that printed design, style and schematic or to replace that design with another style, schematic or image.

[0107] This issue leads to the fact that the discussed utilized substrates and printed surfaces are disposable and the possibility of using or reusing the produced substrate or printed surfaces is possible only if recycling processes are applied and the technical limitations on applying or establishing these types of desired changes and manipulations on designs, styles, images and 2D schematics printed on different surfaces, will eventually impose multiple technical drawbacks such as the reduction in the efficiency and effectiveness of these printing procedures, which subsequently results in the escalation of the amount of waste and scraps produced, caused by these technical errors in the application of the printing process.

[0108] The second limitation that exists in these common mechanisms and techniques for 2D printing of designs for different surfaces of paper-based, silk-based, woolen, polymeric, and fabric, or any other type of textile, is the stability of the printed design and the lack of changeability, in line with various tastes or intentions. In fact, after the printing process, based on the claimed multiple printing mechanisms and techniques, a design with a general schematic and a fixed and specific color spectrum is printed on the mentioned surfaces in a fixed form.

[0109] In this claimed invention, a process of design and implementation of an improved intelligent combined multicomponent multisectoral printer, has been taken into consideration by utilizing a set of combined techniques comprising at least one option among the 3 preferred aforementioned 2D printing mechanisms including the heat transfer printing, the planographic printing, and the digital printing, in combination, integration, and along with at least one molecular printing technique, from molecular printing techniques based on direct materials / molecules' delivery mechanism such as soft lithography, dip-pen nanolithography, polymer-pen lithography techniques and as well as other molecular printing techniques based on the direct energy delivery mechanism, such as nanografting, nanoshaving, anodic oxidation, and millipede techniques, which enable the creation of a set of molecular layers with improved capabilities on different printing surfaces and substrates. It is worth noting that in this intelligent combined multicomponent multisectoral printer designed as claimed, by combining molecular printing techniques, especially molecular 3D printing techniques, based on the direct materials / molecules' delivery mechanism, it is possible to create a set of molecular layers with the claimed enhanced capabilities.

[0110] Among these claimed advanced capabilities, it can be pointed out that having molecular capabilities to adopt configurations, various electronic-molecular states, and different color and structural patterns, by external factors and stimuli such as molecular capabilities of Vapochromism, Mechanochromism, and Thermochromism and from among the compounds used with the claimed characteristics in this claimed designed intelligent combined multicomponent multisectoral printer, various chemical derivatives of organometallic compounds, molecular machines, various polymeric and copolymeric structures, nanoclusters, nanostructures, and various nano / micro crystals can be mentioned, which has the possibility of applying targeted manipulations on a molecular scale.

[0111] With the help of external stimulating factors such as laser light beams, electric pulses, thermal pulses and molecular vibrations, using the preferred piezoelectric approach and technique based on the targeted induction of molecular switches and the induction of controlled changes in configuration patterns, different electron levels and molecular structures.

[0112] As mentioned, in this claimed invention, the design, and implementation of an improved intelligent combined multicomponent multisectoral printer with combined performance, based on a set of combined approaches and techniques, has been considered by consisting of utilizing at least one of 5 general 2D printing mechanisms, e.g. heat transfer printing, intaglio printing, relief printing, planographic printing, and digital printing, by preferring 3 of those 2D printing mechanisms i.e. the heat transfer printing, planographic printing, and digital printing techniques as the main focus in this invention, in combination with and along with using at least one molecular printing technique, from molecular printing techniques based on direct materials / molecules' delivery mechanism, such as soft lithography, dip-pen nanolithography, and polymer-pen lithography techniques, as well as other molecular printing techniques based on direct energy delivery mechanism, such as nanografting, nanoshaving, anodic oxidation, and millipede techniques, which has made possible the process of implementing a complex and targeted process of printing a set of diverse molecular layers, followed by the improved technical ability necessary to align molecular printing techniques, especially 3D molecular printing techniques, based on direct materials / molecules' delivery mechanism and it has the ability to apply targeted structural changes and manipulations in order to create various electronic-molecular states, different color and structural configurations and patterns, based on the existence of inherent molecular capabilities such as Vapochromism, Mechanochromism, and Thermochromism, by various external factors and stimuli including laser light beams, electric pulses, thermal pulses, and various techniques in creating molecular vibrations, especially, from the preferred piezoelectric approach and technique.

[0113] In this regard, in order to investigate step by step how to implement this system and the upgraded hybrid multicomponent intelligent printing device, the general steps and initiatives are considered, evaluated and investigated in a logical process and with a technical approach.

[0114] - In the first step, a dedicated system equipped with the necessary facilities, parts, and equipment to implement the molecular printing process has been designed and implemented. In this exclusive molecular printing system, the process of 3D printing various molecular compounds and structures, which possess inherent molecular capabilities such as Vapochromism, Mechanochromism, and Thermochromism, is established in layers and on different surfaces and substrates of silk, wool, fabric, polymer, paper, fabric or any other type of printed substrate containing images, schematics, and various design styles.

[0115] - The second step is relied on the procedure of connecting and synchronizing the operation of a common printing device, which has a functional capacity based on at least one of the 3 preferred mentioned mechanisms of 2D printing comprising, heat transfer printing, planographic printing, and digital printing, with a special molecular printing system.

[0116] - In the last step, the targeted implementation of the most appropriate technique and process from the set of molecular printing processes and techniques based on the direct materials / molecules' delivery mechanism, such as soft lithography, dip-pen nanolithography, and polymer-pen lithography or any other molecular printing techniques based on the direct energy delivery mechanism, such as nanografting, nanoshaving, anodic oxidation and millipede techniques, according to the type, materials and ingredients of the substrate or printed surface, the type of design and color spectrum used, and the type of chemical compounds used, for the purpose of printing the design, the schematic or style is implemented on the surface.

[0117] As it is clarified from the previous description, the process of implementing the claimed multicomponent multisectoral smart printing device and system is based on a technical dimension to design and implement devices, constituents, equipment, and electromechanical systems related to various components and parts of this invention and also, on the basis of a molecular dimension, based on the manipulations and application of targeted optimization processes in the chemical and molecular properties of the compounds and macromolecules used and with the aim of achieving the desired printing goals. In this regard, we will first examine the technical dimension in the implementation process of this upgraded multi-part multi-sectoral intelligent printing machine.

[0118] In the first step, the alleged exclusive and dedicated system has been fabricated with the aim of implementing the molecular printing processes. In this exclusive molecular printing system (1), a plate and a metal / polymer mobile substrate of compact polymer structures are utilized, which serves as a placement and embedding area of various paper-based, woolen, silk-based, polymeric, fabric, and any other textile-based printing substrates and the referred plate is mechanically connected to a set of mobile and rotating rollers and cylinders (9 and 20) equipped with a set of electromotive systems.

[0119] Furthermore, a special transparent railed plate and substrate (2) equipped with an array of nano / micronozzles and complex multimolecular injection systems (5), with improved design, in the upper area of the plate and the mobile metal / polymer substrate of the type of compact polymer structures claimed, is embedded and situated.

[0120] The existence of this special transparent plate and substrate with rails (2) equipped with a set of claimed nano / micro nozzles and complex multicomponent molecular injection systems (5), has created the possibility of applying different processes and processes of injecting clear, fluid, colloidal or suspension solutions of compounds, macromolecules and specific chemical derivatives used in this claimed invention, on a molecular / macromolecular scale and in the nanometer / micrometer dimension range which eventually, the existence of this discussed complex multicomponent molecular injection system has provided the possibility of implementing and applying the molecular 3D printing process, from the preferred molecular 3D printing techniques of soft lithography, dip-pen nanolithography and polymer-pen lithography, on various substrates and printing surfaces of various compounds.

[0121] In this regard, to comprehend the technical details more precisely and how to apply the molecular 3D printing process, from the preferred types of soft lithography and dip-pen nanolithography techniques, the stepwise investigation for implementing the procedure will be taken into consideration.

[0122] As mentioned prior, the main part of this exclusive claimed molecular printing system (2), which is a functional area where the 3D molecular printing process is performed, comprises 2 aligned plates and substrates, including the claimed specific transparent railed plate and substrate (2), which is equipped with a set of nano / micro nozzles and complex multicomponent molecular injection systems (5), as well as the alleged mobile metallic / polymeric plate and substrate, which is serving as the embedding location of various printing substrates of paper, wool, silk, polymer, fabric, and other types of textile and has been located in the lower area of the mentioned technically specific transparent railed-equipped plated and substrate and has been installed in the vicinity of the nano / micro syringes and nano / micro nozzles of the claimed molecular injection system (5), that these two claimed aligned plates and substrates are mutually related to each other, with the help of a set of moving rollers and cylinders.

[0123] This claimed set of rollers and movable cylinders includes a set of movable sectional railed cylinders (9) and several sets of end-to-end rollers with different dimensions (20 and 21). On the outer surface of this set of claimed rail-moving cylinders, a set of mobile surface-mounted smart electromechanical systems, which possesses at least one enhanced laser radiation source and an optical sensor (3), with multiple capabilities in inducing and creating various electronic-molecular excitations, along with the ability to be digitally linked to various systems and devices, as well as a set of surface-fixed electromechanical systems, which composes several electro-optic parts and constituents such as beam splitters, polarizers, and dichroic mirrors / prisms and with the ability to be linked to different systems and parts in digital form (4), can be embedded and placed.

[0124] The existence of these 2 different types of electromechanical systems has made it possible to create and induce targeted molecular excitations, based on utilizing the interferometry technique and the radiation and reflection of certain wavelengths of polarized electromagnetic waves and rays in a wide frequency range, preferably the laser light waves, in molecular / macromolecular compounds during the process of injecting clear, colloidal or suspension solutions of various chemical derivatives that can be used in this claimed invention, such as organometallic compounds, molecular machines, various polymeric and copolymeric structures, nanoclusters, nanostructures, and various nano / micro crystals.

[0125] In this regard, following the movement and passage of different textile print substrates mentioned in the path embedded on the alleged metal / polymer moving substrate and plate, the asserted molecular 3D printing process is initially performed by injecting a small volume of the solution containing utilized chemical and macromolecular compounds, in the preferred range of 0.1 to 2.5 microliters, through nano / micro syringes and nano / micronozzles of the claimed molecular injection system.

[0126] In the next step, following by injecting the solution carrying chemical and macromolecular substituents and covering the surface molecules of the discussed targeted printing substrates with these alleged chemical and macromolecular compounds, the claimed coated substrates will be eventually subjected to and irradiated by the targeted radiation of a specific spectrum of polarized electromagnetic waves, of the preferred type of laser electromagnetic waves and rays, in different and specific directions, by two sets of claimed electromechanical systems, including a set of the mobile intelligent electromechanical system positioned on the surface, containing at least one enhanced laser radiation source and an optical sensor and a set of surface-fixed electromechanical systems, possessing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms.

[0127] The above-mentioned procedure, will eventually lead to purposeful alterations in the type and the energy level differentiations of the intramolecular interactions of these mentioned macromolecules and chemical derivatives with their internal substitutions and changes in the 3-dimensional configuration, followed by the creation of various excitations in the electronic, vibrational, and molecular levels of chemical derivatives and injected macromolecules; Moreover, that procedure will cause targeted variation in the type and amount of energy of intermolecular interactions of these macromolecules and chemical derivatives injected with the structures and molecules on the outer surface of the printed substrate.

[0128] These electronic and vibrational excitations, in line with the claimed purposeful changes imposed in the type of intramolecular and intermolecular interactions, with the intermediary of creating molecular excitations and changes in the type of configuration and molecular 3D structure, are leading to the creation and establishment of the chemical connections and molecular bonds, of the preferred type of covalent and ionic bonds, among the injected macromolecules and chemical derivatives used for coating and covering the surface externality of the printed substrate, with other chemical and molecular structures on the outer surface of the target printed substrate or with chemical compounds and molecular structures used during the 2D printing process of various heat transfer printing, intaglio printing, relief printing, planographic printing and digital printing techniques, such as color compounds and it will subsequently enable imposing the molecular 3D printing process on various printing surfaces and substrates.

[0129] As mentioned earlier, in the technical approach of examining the steps and general initiatives considered in the design of this system and the technically improved hybrid multisectoral intelligent printing machine, along with the process of designing and implementing the claimed exclusive molecular printing system, a set of printing systems and devices has been utilized to apply 2D heat transfer printing, intaglio printing, relief printing, planographic printing and digital printing processes of different designs, images, images and design styles, on different silk, wool, fabric, polymer, paper, fabric or any other textile surfaces, in a synchronized manner with the implemented exclusive molecular printing system.

[0130] In fact, by synchronizing the performance of conventional printing devices and systems with a proprietary molecular printing system, various textile-based printing substrates and surfaces discussed in this claimed invention, are able to be subjected initially to the 2D printing process of designs, schematics, images, and different design styles by means of printing systems and 2D printing devices and subsequently, the claimed 3D molecular printing process is performed by the exclusive molecular printing system (1).

[0131] In this claimed invention, it is possible to synchronize the performance of various 2D printing printers, based on different printing mechanisms and techniques, with the claimed exclusive molecular printing system which among these common printing mechanisms and techniques, the intaglio printing mechanisms and techniques for apply printing processes on incised surfaces, including engraving (Rotogravure), etching, drypoint, aquatint and mezzotint printing processes, the relief printing techniques, with the aim of imposing printing processes on raised surfaces such as woodcut, anastatic printing (relief etching), linocut and metal cut, the planographic printing techniques of applying printing processes on flat surfaces, such as flexography, lithography and offset lithography printing techniques and as well as a set of digital printing techniques, with the purpose of implementing color printing processes (inkjet printing) of digital images on various paper-based, silk-based, woolen, fabric, and polymeric surfaces, such as dye-sublimation printing, laser printing and any other types of inkjet printing mechanisms like drop-on-demand inkjet printing, can be noted.

[0132] In this claimed invention, among these discussed 2D printing techniques, devices, and systems, the digital printing technique used in two dye-sublimation and laser printers and the planographic printing technique which is the fundamental mechanism used in the flexographic and the offset lithography printers, have been considered preferentially and with improved technical designing points of view, for the implementation of the overall assembly of the claimed advanced multicomponent multisectoral intelligent printing device.

[0133] To have a deeper and more detailed understanding of the electromechanical technical techniques and molecular mechanisms used, to implement, align, and conduct the combined process of the primary 2D printing process with the secondary molecular 3D printing process in the set of embodiments designed and implemented in this invention, the technical principles and implementation process of each used 2D or 3D molecular printing device and system have been investigated.

[0134] The first 2D printing device and system considered to have an improved technical design is the laser printer, which performs based on the digital printing technique. The claimed advanced laser printer system (10) consists of a set of rollers equipped with a set of bobbins and electromotor systems (26 and 29) which this claimed set of bobbins and electromotor system includes at least one developer roller unit (17), at least one electrostatic roller unit (28) and a set of transfer rollers and pressure rollers (16), at least one toner / ink hopper unit (14), at least one photoreceptor drum assembled unit (15), at least one clearing unit (28) connected to the photoreceptor drum assembled unit part, at least one Fuser unit (25), and at least one Corona wire unit (52).

[0135] As shown in the implemented advanced laser printing system, in the lower area and compartment, the paper tray unit (19) is installed and placed in the transfer pathway by a set of transfer rollers and pressure rollers (16) equipped with a set of bobbins and electromotor systems (26 and 29). Subsequently, by transferring the target surface with the aim of applying 2D printing process in the path of assembled sets of photoreceptor drum units (15), holding units (18), the Corona wire sections (52), and the Fuser units (25), the 2D printing procedure is carried out in the vicinity of the photoreceptor drum assembly unit, followed by the radiation of a certain frequency range of laser electromagnetic waves to the surface of the photoreceptor drum assembly and the stimulation of the corresponding surface, to apply the printing process and fixate the colored compounds and dye inks transferred from the toner / ink hopper unit (14) and with the help of the developer roller unit (17), on the external surface of the photoreceptor drum assembly (15).

[0136] In laser printers with a traditional design, the process of radiating electromagnetic waves and laser-type radiation rays is done through the laser scanning unit; however, in this embodiment of the claimed invention, an advanced hybrid electromechanical system, based on two separate specific electromechanical systems has been utilized which consisting of at least one unit of electromechanical system fixed on the surface, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be linked to different systems and parts, in digital form (8), with at least one unit of the electromechanical system fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms, and with the ability to be linked to different systems and parts, in digital form (7).

[0137] Subsequently, by using this combined electromechanical system, in addition to possessing improved technical ability in producing and irradiating a specific frequency and wavelength spectrum of laser electromagnetic waves, the capability of being linked and continuously transmitting digital information, among the sets used from these two units and the separate electromechanical system constituting the claimed combined electromechanical system, will also be possible in an encrypted and targeted manner, based on the physical mechanism of interferometry and in the form of laser telecommunication. In fact, the nature and technical approaches used in the implementation of this system and the advanced hybrid multi-component smart printing device in this claimed invention, have made it possible to combine and simultaneously implement the claimed 2D printing and 3D molecular printing methods and techniques and by implementing these two mentioned technical features, it will make it possible to create smart digital communication between different electromechanical parts.

[0138] Furthermore, benefiting from the interferometry mechanism and laser telecommunication technique has made it possible to establish and create digital communication among various units of the utilized electromechanical systems that make up the claimed hybrid electromechanical system in the designed advanced laser printing device (10), with other electromechanical systems which have been used in the internal functional area or compartment of other utilized equipment and outside the laser printing device and system, especially with the electromechanical units and systems used in the implemented improved molecular printer system claimed (1), which consists of at least two sets of main electromechanical units and systems and includes a set of intelligent electromechanical systems movable on the surface, containing at least one upgraded laser radiation source and an optical sensor and with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be linked to various systems and parts, in digital form, in addition to a set of electromechanical systems fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the ability to be digitally linked to different systems and parts.

[0139] The second redesigned and renovated 2D printing device and system that is considered is the calendar dye-sublimation printing device and system, which consists of a set of rollers, drums, and cylinders equipped with a set of bobbins and electromotor systems that this claimed bobbins and electromotor systems' set includes a set of units and rollers supplying different polymeric, fabric, and paper-based substrates (Feeder), a set of collector roller / cylinders or rewind roller / cylinders and a set of intermediate cylinders, along with at least one thermal unit including a drum and a thermal head, at least one conveyor unit and a set of at least 3 inputs of printing substrate with different materials, including at least one layer of tissue paper and at least one layer of fabric, next to the main printing substrate of various types of paper, wool, silk, polymer, or any other compatible type of textile.

[0140] In the aforementioned redesigned 2D dye-sublimation calendar printing device and system in this embodiment of the claimed invention, at least 3 inputs and 3 outputs of the printing substrate with different materials and types of structure, including at least one input unit of the printing substrate of fabric type, with the title of fabric feeding roller (61), at least one input unit of the paper-type printing bed, with the title of paper feeding roller (72), at least one input unit for entering the sectional print bed made of paper, called issue paper feeding roller (upper 68), at least one output unit to receive and aggregate the print substrate produced from fabric, called fabric rewind roller (69), at least one output unit to receive and aggregate the printed substrate produced from paper, named paper rewind roller (62), and at least one output unit for receiving and gathering the cross-sectional printed substrate used in the heat transfer dye sublimation printing process, named the issue paper rewind roller (68 lower), has been installed and used that each of these 3 inputs and 3 claimed outputs, coupled and through a set of transmission levels, including at least one open transferring pathway for transferring fabric-based printable substrates and pieces (24), at least one closed transferring pathway for transferring tissue paper-based substrates and layers (45) and at least one open transferring pathway for the transfer of the original printed substrate and for the transfer of paper-based printable substrates (44), have been mechanically linked to each other which facilitates the transfer of utilized print substrates within the compartments and different print paths used.

[0141] In the lower area of the redesigned and implemented dye sublimation calendar printing system (38), a conveyor (41) has been used to transfer the prepared printing substrate to the output area of the machine. Also, regarding the inherent and conventional nature of the claimed dye-sublimation calendar printing device and system, in order to apply the heat flow transfer process with the aim of triggering the eventual evaporation and stabilization procedure of the utilized heat-sensitive colors, an oil drum (43) equipped with a set of bobbins and electromotor systems (70) was used to create rotation in the oil drum unit and homogenize the heating process.

[0142] In this redesigned printing device and system, a set of rollers, drums, and cylinders are used, each of which is independently equipped with a set of bobbins and electromotor systems (64, 66, and 70), which, leads to the optimization of the performance and improvement of the heat transfer process used in this claimed system and printing device, following the application of this adopted technical approach. Moreover, a specific approach has been used to modify the existing intermolecular interactions between dye colors used with traditional water-based solvent systems, in order to improve the efficiency and performance of the printing process and to stabilize the colors used on the target printing substrate.

[0143] In fact, the operating temperature range of the device and traditional printing systems based on the dye-sublimation mechanism is between 180 and 230 degrees Celsius, which hinders the possibility of implementing the mentioned printing technique on many surfaces and printing substrates, especially temperature-sensitive printing substrates. Furthermore, another technical problem in this printing technique and method relates to the existence of multiple technical issues and aspects regarding the uniform and homogeneous distribution of color on the surface and the target printing substrate and the prevention of non-uniformities in the distribution and accumulation and undesired stabilization of the used colors in the unwanted areas of the target printing substrate.

[0144] In this embodiment of the claimed invention, by using an engineered alternative fluid and solvent system, based on the use of a specific range of perfluorocarbons and perfluorinated compounds, the heat transfer process can be carried out in a modulated and moderated manner. In this method, an engineered fluid and solvent system based on two different approaches has been used. In the first approach, only a solution based on perfluorocarbons and only consisting of mixing at least two different perfluorocarbons, at least one compound with a preferred weight range between 150 and 250 daltons and at least one compound with a preferred weight range between 250 and 400 daltons will be used.

[0145] In the second approach, along with the use of perfluorinated compounds, other polar solvents will be used, preferably over non-protonated solvents such as etheric compounds such as THF, which will form the major part of the fluid used, perfluorocarbon compound or compounds. It is worth noting that following the application of the claimed engineered fluid and solvent system, which is based on perfluorocarbon compounds, the performance of the dye sublimation calendar printing device and system implemented in this embodiment of the invention will be operational in a lower temperature range and this temperature range, in the condition that the first approach, which is based on the use of perfluorochemical compounds and derivatives, would be taken into consideration for the preparation and engineering of the alleged solvent system, the operational temperature range of the claimed system and printing device has faced a significant temperature adjustment and modulation, and in the operating range of 70 to 125 degrees Celsius, it would be able to perform printing operations.

[0146] Also, in case of using the second approach, which is based on using a set of several types of solvents, with different physicochemical properties and consisting of at least one perfluorocarbon-based solvent with at least one other protonated or non-protonated polar solvent, the temperature range of the dye sublimation printing process will be optimally in the operating range of 140 to 180 degrees Celsius. By taking the procedure of conducting this technique and engineered approach for the design of the alternative fluid and solvent system into consideration, which eventually leads to a significant reduction in the operating temperature range of the device and the claimed printing system, it will be possible to use printing substrates and surfaces sensitive to humidity and heat, such as silk surfaces and surfaces composed of a wide range of polymeric compounds sensitive to the solvolysis process.

[0147] Moreover, the process of evaporation and stabilization of the dye inks used in the process is more easily possible and minimizes the errors of the printing process. It is worth noting that by reducing the operating temperature range, it will be possible to adjust and monitor the process of printing and stabilization of dye inks in different areas of the target substrate and printed surface in a controlled and targeted manner, which this issue will minimize the possibility of creating errors in the printing process and will provide the possibility of revising or applying any instant structural changes or secondary alterations in the pattern being printed.

[0148] It is worth noting that the perfluorinated compounds that can be used in this embodiment of the invention, include a set of light-weight perfluorocarbon derivatives preferably the liquid perfluorocarbons including perfluoro (3-pentanone), perfluoro(2-methyl-3-pentanone), perfluoro(2,4-dimethyl-3-pentanone), perfluoro(methyl cyclohexanone), perfluoro(dimethyl cyclohexanone) and perfluoro(2,4-dimethyl cyclopentanone) and a series of heavy-weight perfluorocarbon derivatives consisting of dozen compounds such as 1,1,1,2,2,4,4,5,5,5-decafluoropentan-3-one, 1,1,1,2,4,5,5, 5-octafluoro-2,4-bis(trifluoromethyl)pentan-3-one, 1,1,1,2,2,6,6,7,7,7-decafluoro-4,4-bis(trifluoromethyl)heptane-3,5-dione, 2,3,5,6-tetrafluoro-2,3,5,6-tetrakis(trifluoromethyl)cyclohexane-1,4-dione, 2,3,3,5,5,6-hexafluoro-2,4,4,6-tetrakis(trifluoromethyl)cyclohexan-1-one, 4,5-difluoro-2,2-bis(perfluoroethyl)-4,5-bis(trifluoromethyl)-1,3-dioxolane, 2,3,4,5-tetrafluoro-2,3,4,5-tetrakis(trifluoromethyl)cyclopentan-1-one, 2,3,6,9,10,12,14-heptafluoro-2,3,6,9, 10,12,14-heptakis(trifluoromethyl)-1,4,8,11-tetraoxadispiro[4.1.47.35]tetradecan-13-one and 1,3,4,5,6,7,8,9-octafluoro-1,3,4,5,6,7,8,9-octakis(trifluoromethyl)-1,3,4,5,6,7,8,9-octahydro-2H-cyclopenta[e]-as-indacen-2-one and generally, along with a wide range of various perfluorocarbons and perfluorinated derivatives, which possessed any of these perfluorocarbon-based chemical bases including 1,3,4,5,6,7-hexafluoro-1,3-bis(trifluoromethyl)-1,3-dihydro-2H-inden-2-one, 1,1,1,5,5,5-hexafluoropentan-3-one, 1,1,1,2,7-pentafluoro-4,4-bis(trifluoromethyl)heptane-3,5-dione, 2,3,5,6-tetrakis(trifluoromethyl)cyclohexane-1,4-dione, 2,4,4,6-tetrakis(trifluoromethyl)cyclohexan-1-one, 2,2-bis(perfluoroethyl)-4,5-bis(trifluoromethyl)-1,3-dioxolane, 2,5-bis(trifluoromethyl)cyclopentan-1-one, 2,14-bis(trifluoromethyl)-1,4,8,11-tetraoxadispiro[4.1.47.35]tetradecan-13- one, 1,9-bis(trifluoromethyl)-1,3,4,5,6,7,8,9-octahydro-2H-cyclopenta[e]-as-indacen-2-one and 1,3-bis( trifluoromethyl)-1,3-dihydro-2H-inden-2-one.

[0149] The third and last 2D printing device and system used is a toner / ink-based roll-to-roll / rotary printing mechanism and a special type of offset printer (30). The implemented offset printing system and device, consisting of a set of different rollers and cylinders, including a set of ink / toner rollers (33), a set of wetting-out rollers (58), a set of pressure cylinders (32), at least one unit of plate cylinders (55), at least one unit of blanket (offset) cylinder (37), and a set of guide rollers (56, 144, 145, and 146) that the possibility of situating and embedding units of Anilox roller and Doctor blade, if the flexographic printing technique is used instead of the offset printing technique, along with a set of ink / toner fountain / trays (57), and set of solvent placement units and trays (wetting out / solvent fountain / tray) (34), in addition to at least one transfer path for different structural types of specific printing substrates and surfaces (24), including various paper-based, leather-based, woolen, silk-based, polymeric, fabric, and other textile types.

[0150] This device and printing system based on toner / ink-based roll-to-roll / rotary printing mechanism is specially designed and implemented which has smoothed the possibility of synchronizing the performance of this 2D printing machine with the designed 3D molecular printing system, with the purpose of making the technical process of implementing and assembling the advanced combined multicomponent multisectoral printer alleged in this embodiment of the claimed invention possible and eventually, by carrying out the 2D printing process, the technical procedure of carrying out various 3D molecular printing processes and techniques, in the claimed 3D molecular printing device, has been provided in line with the transfer of the substrate and the printed surface produced into the referred 3D molecular printing device.

[0151] As discussed earlier, the type of process and molecular approach adopted to apply the molecular 3D printing process will be determined according to the type of substrate and the type of toners, inks, and other colored and non-colored compounds used. Now, in this section, the implementation and evaluation of the molecular 3D printing process on various printing surfaces and substrates that have been exposed to 2D printing processes, with a comprehensive and detail-oriented approach, has been discussed. As mentioned earlier, various chemical compounds and derivatives such as organometallic compounds, molecular machines, various polymeric and copolymer structures, nanoclusters, nanostructures, nano / micro crystals, and various macromolecules have been utilized to carry out the process of molecular 3D printing, in the various mentioned embodiments of this invention.

[0152] In fact, the fundament for electing and determining the type of claimed derivatives and chemical and macromolecular structures is dependent on a set of parameters and influencing factors, which can be classified into two general parameters. The first claimed general parameter is the structural material of the surface and the printed substrate, as well as the physicochemical and rheological properties of the utilized surface and the printed substrate, which in accordance with the printing purpose considered for the implementation of the molecular 3D printing process, the existence of the most optimal molecular-optical-chemical properties will be the basis for selecting and determining the type of derivatives and chemical and macromolecular structures claimed to be used in the 3D printing process and can include a wide variety of textile-based structures and paper-based, fabric, woolen, silk-based, and polymeric types.

[0153] The second general influential parameter considered is the type and intensity of the considered external stimulus factors, to apply and create electronic and molecular excitations in the derivatives and chemical and macromolecular compounds used in the claimed molecular 3D printing process. As discussed earlier, these electronic and vibrational excitations, in line with these purposeful alterations created in the type of intramolecular and intermolecular interactions claimed, by inducing and imposing molecular excitations and alterations in the type of configuration and molecular 3D structure, will lead to the establishment of possible intramolecular or intermolecular connections and bonds, of the preferred type of covalent and ionic bonds, among the constituents of these compounds and macromolecular chemical derivatives used on the surface and printing substrate, with the components of the chemical and molecular structures existing on the outer surface of the target printing substrate or with the chemical compounds and molecular structures used during the application of various 2D printing processes, it enables the molecular 3D printing process on different printing surfaces and substrates.

[0154] This issue demonstrates the importance and effectiveness of the parameters of the external stimulation factors used, such as laser light beams, electric pulses, thermal pulses, and molecular vibrations, using the preferred piezoelectric approach and technique, in line with inducing targeted manipulations on a molecular scale and in selecting and determining the structure and chemical derivatives with optimal molecular-optical-chemical properties. Eventually, based on the molecular effect exerted by the type of external stimulus used in the implementation of molecular 3D printing, the process of targeted induction of molecular switches and controlled changes in different levels of electronic, vibrational, and rotational energy and in various configuration patterns of the utilized macromolecular chemical compounds and derivatives, has been provided according to the type of considered demand and purpose.

[0155] In this regard, a careful examination of the preferred macromolecular chemical compounds and derivatives and the preferred type and conditions of each of the considered usable external stimuli has been carried out, in accordance with the physicochemical, rheological, and structural properties of the substrates and different printing surfaces used and the approach adopted for the implementation and assembly of the claimed advanced multicomponent multisectoral intelligent printing system and device.

[0156] Firstly, a series of inherent or induced chemical effects and properties in a series of compounds, derivatives, and chemical macromolecules that can be used in this claimed invention have been reviewed, which enables the purposeful engineering and manipulation of these properties, in order to lead to and achieve a set of controlled changes in electronic, molecular, and conformational energy levels, which subsequently leads to further purposeful changes and obtains the desired macroscopic properties, especially in the type of secondary color. After that, the effect of each of the claimed external stimulating methods and factors in the process of creating molecular excitations and targeted changes in different electronic, vibrational, rotational, and molecular energy levels has been investigated and evaluated.

[0157] Among these effects and chemical properties that can be inherent or be induced by the claimed external stimulating factors, which are playing the cornerstone role in the way of applying the molecular 3D printing process in this claimed invention, multiple molecular effects and properties related to the chemical effect of chromism, which this chromism effect is also related to various provoking and stimulating factors in applying the process of color change in various chemical compounds and structures, can be pointed out including Adsorchromism, Mechanochromism, Thermochromism, Vapochromism, Photochromism, Electrochromism, Piezoceramics and Solvatochromism.

[0158] In fact, the process of 3D molecular printing on various printing surfaces and substrates would be conducted by injecting a specific volume range of various types of clear, colloidal, or suspension solutions containing these alleged chemical and macromolecular compounds, which have the inherent properties of the above-mentioned chromism effect, including the Adsorchromism, the Mechanochromism, the Thermochromism, the Vapochromism, the Photochromism, the Electrochromism, the Piezochromism, and the Solvatochromism, in the optimal preferred range of 0.1 to 2.5 microliters and through a set of nano / micro syringes and nano / micronozzles of the claimed molecular injection system (5) which are embedded on the surface of specially designed transparent railed substrate and plate.

[0159] Furthermore, as discussed earlier, the claimed improved hybrid multi-component intelligent printing system and device, possesses the ability to perform and implement the simultaneous process of 2D printing and targeted molecular 3D printing on various types of textile-based printing surfaces and substrates, such as any paper-based, fabric, silk-based, woolen, and polymeric surfaces or substrates, which illustrates the capability and compatibility of the claimed multicomponent multisectoral printing system and device in performing molecular 3D printing process on different chemical structures.

[0160] Moreover, considering the ability of the claimed multicomponent multisectoral system and device to apply the molecular 3D printing process on different printing surfaces and substrates that have been exposed to different color combinations by different 2D printing techniques, the application of chemical and macromolecular species and derivatives containing various molecular properties in accordance with the chromism effect, based on 3 effective factors that include the type of substrate and printed surface used, the type of color compounds and chemical additives used in 2D printing techniques applied before the implementation of molecular 3D printing approach, and the type of external stimulus and induction agent used to apply stimulation and create different electronic-molecular excitations is in different physicochemical and rheological states and conditions, would be justified.

[0161] In this regard, the type of species and chemical derivatives and preferred macromolecular compounds and the type and preferred physicochemical and rheological conditions of the carrier used, regarding the type of surface and the desired printing substrate, the type of color combinations and factors used in the process of applying 2D printing techniques and the type of external stimuli used will be evaluated and investigated.

[0162] The first intrinsic property and effect discussed is the Adsorbchromism effect. The Adsorbchromism effect is a special type of general effect of color change due to the influence of external factors and stimuli (the chromism effect), and it is based on the induction of changes in the electronic states of molecules and colored chemical compounds, following the occurrence of their surface absorption process on different surfaces. In fact, the process of carrying out the surface absorption process of colored molecules and chemical compounds, of the preferred type of dye molecules, will be based on various general molecular mechanisms such as protonation, aggregation, electronic interaction, intramolecular structural changes, intramolecular and intermolecular conformational alterations, electrostatic interactions and internal mobility decrease.

[0163] To achieve and implement the various mentioned techniques and mechanisms, based on the Adsorchromism effect, various compounds will be used and in this invention, in general, a set of different molecular approaches have been used as preferred compounds that can be used in techniques and mechanisms based on the Adsorbchromism effect claimed, which will be in line with the use of a set of chemical processes and trends for the production and synthesis of complex macromolecular compounds and based on the molecular mechanisms of protonation, electronic interaction, intramolecular structural changes, and intramolecular and intermolecular conformational alterations.

[0164] This set of claimed processes includes a range of molecular processes which include:

[0165] - The first process consists of the process of using the stable salts of part of the metals of the transition elements of the first row and the first 4 elements of the group of alkaline and alkaline earth metals, as the centers and cores of coordination compounds, and a wide range of ligands and macromolecular compounds.

[0166] In this mentioned process, a series of ligands and macromolecular compounds have been used, which have the ability to be affected by external factors and stimuli in order to create and establish a change or a set of alterations in the type of one structural isomer to another type of structural isomer, or to create a change in a specific type of configuration of a structural isomer, to a specific type of a specific configuration or spatial configuration. In this process, a set of chemical and structural changes that are reversible have been considered. It is worth noting that the intercalation process and molecular mechanism can be considered as a subset of this molecular process.

[0167] - The second process relies on the process of applying a wide range of stable salts belonging to a category of metals of the transition elements of the first row and the first 4 elements of the group of alkaline and alkaline earth metals, as centers and nuclei for the formation of coordination compounds along with a wide range of ligands and macromolecular compounds.

[0168] In this aforementioned process, a series of ligands and macromolecular compounds have been utilized which possess the capability of being affected by external factors and stimuli, with the aim of establishing a specific alteration or a set of structural changes, in the type of a certain structural isomer to another type of structural isomer, or to impose a specific structural or spatial alteration in a specific type of configuration of a structural isomer, to a specific type of a specific configuration or spatial configuration. In this process, the set of chemical and structural changes performed on each ligand or macromolecular structural isomer is considered reversible.

[0169] - The third process is related to the performance of a diverse range of semi-stable or unstable metal salts belonging to the 3 periods of the 4th, 5th, and 6th transition metals of the periodic table and especially, metals belonging to groups 5 to 9 transition elements, as the centers and cores of coordinating compounds, in addition with the utilization of a wide range of ligands or specific macromolecular compounds.

[0170] In this process, metals that have multiple oxidation numbers and exhibit high oxidation properties have been used, which according to this high oxidizing property, the possibility of creating an oxidation process on organic chemical derivatives and macromolecular compounds used as ligands have been emerged, in the way of formation of coordination compounds and based on electron transfer (charge transfer) mechanisms, they have different mechanisms such as ligand-to-metal charge transfer (LMCT), metal-to-ligand charge transfer (MLCT) and metal-to-metal charge transfer (MMCT). In this process, the set of chemical and structural changes performed on each ligand or macromolecular structural isomer is considered irreversible.

[0171] - The fourth process is based on the use of a diverse and wide range of a set of several different types of macromolecules, with different dimensions, surface charge density, and electrostatic and electrochemical properties. In this process and method, a specific macromolecule, with a significant molecular size and containing a variety of chemical substitutions and different functional groups, has been used as the central part of the process, which leads to a dispersion in the surface charge density distribution in the chains and different molecular regions of the claimed macromolecule.

[0172] Besides, a set of macromolecules and other chemical derivatives, which have smaller molecular dimensions and molecular radii and less solvated by the solvent molecules, have been used as groups and side chains. which possess the capability of creating and establishing various intramolecular and intermolecular interactions with chains, chemical substitutions and functional groups in the central macromolecule. In this process, the set of chemical and structural changes performed on each macromolecular structural isomer is considered reversible.

[0173] - The fifth process is based on using a diverse and wide range of a set of several different types of macromolecules, with different dimensions, surface charge density, and electrostatic and electrochemical properties. In this process and method, a certain macromolecule, with a significant molecular size and containing a variety of chemical substitutions and various functional groups, that these functional groups lead to dispersion in the surface charge density distribution, in the chains and different points of that claimed macromolecule, has been used as the central part of the process.

[0174] Furthermore, a set of macromolecules and other chemical derivatives, that have smaller molecular dimensions and molecular radii and are less solvated by the solvent molecules, have been utilized as chemical groups and side chains and they can create various intramolecular and intermolecular interactions with chains, chemical substitutions and functional groups in the central macromolecule. In this process, the set of chemical and structural changes performed on each macromolecular structural isomer is considered irreversible.

[0175] - The sixth process is based on the general technique of molecular imprinting, in which macromolecular derivatives such as organic polymer derivatives with thixotropic and viscoelastic preferred physicochemical properties are used. This process relies on the procedure of creation and formation of template-based cavities in the polymer matrix, by using various synthetic techniques for the synthesis of crosslinked copolymeric derivatives, including the free-radical polymerization and sol-gel polymerization as the preferable synthetic mechanisms by biological species and macromolecules, with enzymatic properties, due to the nature of the process, the created holes and positions are formed in a predetermined manner with very high selectivity and affinity. It is also worth mentioning that in this process, the set of chemical and structural changes performed on each macromolecular and polymer structural isomer will be possible in both reversible and irreversible ways.

[0176] - The seventh process relies on the utilization of the enzymatic degradation process or any destructive chemical reaction, based on a chemical and biochemical component or structure with enzymatic properties, along with a set of derivatives and different chemical compounds, of all molecular and macromolecular types and with monomeric, dimeric, oligomeric and polymeric chemical and structural sequences, which contain at least one chain or substitution sensitive to enzyme activity.

[0177] The second intrinsic property and effect discussed is the Electrochromism effect. The Electrochromism effect is a special type of general effect of color change due to the influence of external factors and stimuli (the chromism effect), based on at least one chemical reaction, such as oxidation and reduction, and is reversible, which subsequently by using an inherent potential difference, one or a set of several oxidation and reduction reactions are carried out and with the possibility of the electric current exchange process, between the oxidizing species / species and the reducing species / species present in the reaction, It would lead to eventual alterations in the state of the molecular electron levels and the distribution of electrons in the molecular orbitals of the used species, and with the change in electron absorption and emission levels, it causes a shift in the π-π*excitations.

[0178] The third inherent property and effect discussed is the Photochromism effect. The effect of Photochromism, like Electrochromism, is a special type of the general effect of color change due to the influence of external factors and stimuli (the chromism effect) and is reversible, which relies on carrying out a chemical reaction or transformation process, between two or a set of several stereoisomers or structural isomers and by the external factor of light radiation and based on the general mechanism of photoirradiation. The intrinsic property and effect of Photochromism depends on a set of molecular techniques and mechanisms such as photo-induced proton transfer, trans-cis photoisomerization, homolytic cleavage, and photocyclization, with the purpose of benefiting from this inherent property and effect discussed, in this claimed invention, a set of different molecular techniques and approaches have been used, which will include a range of molecular processes, as follows.

[0179] - In the first process, a set of organic macromolecular compounds, which have a range of substitutions and chemical chains containing a set of conjugated double bonds, are used and the Photochromism process is carried out with the help of a source of polarized electromagnetic waves with the capability for emitting and irradiating a certain wavelength range of electromagnetic waves. It is worth noting that the wavelength spectrum used for irradiating organic macromolecular compounds will be determined in accordance with the type of substitution and the chain containing a set of conjugated double bonds and is proportional to the functional groups and other effective substitutions placed in the chemical structure of the used compound and derivative, which are located in the vicinity of the indicated chain of double bonds. Moreover, from a technical point of view, the claimed process will be based on the technique and molecular mechanism of trans-cis photoisomerization.

[0180] - In the second process, metal salts of intermediary elements and coordination compounds, with centrality of quasi-stable or unstable metallic elements belonging to the 3 rows of the 4th, 5th and 6th transition metals of the periodic table and especially, metals belonging to groups 5 to 9 transition elements have been taken into consideration as the centers and the cores of these mentioned coordination compounds. In this process, after irradiating the used sample of these alleged metal compounds and salts with the help of polarized electromagnetic waves, the process of charge transfer and electron excitement will be carried out among atomic and molecular electron orbitals and layers, in a reversible manner and based on the photo-induce electron transfer technique.

[0181] - In the third process, which is based on the technique and molecular mechanism of photocyclization, aromatic, pseudo-aromatic, and non-aromatic cyclic or non-cyclic macromolecular compounds and derivatives containing a set of conjugated double bonds and especially chemical compounds containing at least one non-cyclic substitution of conjugated double bond with an aromatic ring have been utilized. In this process, by irradiating and exposing the chemical structure used by a spectrum of electromagnetic waves, by imposing and inducing an electronic excitation in the molecular orbitals of the chemical compound used, a molecular process and chemical reaction relies on two general molecular mechanisms of hydrogen shift and carbon shift, will be carried out in the direction of cyclization or cyclization of the corresponding molecule.

[0182] In fact, following the photocyclization process, the primary molecule will be reversibly converted to one of its structural isomers that has more rings. Among the most important mechanisms for carrying out the claimed ring-forming reactions, several sigmatropic reactions and rearrangements can be referred to such as Claisen rearrangement of [3,3] sigmatropic reaction, Diels-Alder reaction of [4,2] sigmatropic reaction, Cope rearrangement of [1,5] sigmatropic reaction, Woodward Hoffmann rearrangement of [1,7] sigmatropic reaction, Wagner-Meerwein rearrangement of [1,2] sigmatropic reaction, and other processes such as [2,3] sigmatropic reaction. It is worth noting that in this process, it would be possible to simultaneously utilize some chemical derivatives and stable metal salts of some alkaline elements, alkaline earth elements, and transition elements of the first series, in the role of photocyclization process catalyst.

[0183] - In the fourth process, which is based on the technique and molecular mechanism of homolytic cleavage, a set of light-sensitive compounds containing at least one weak and radiation-sensitive bond has been used. In this way, with the creation of free radicals, various chemical processes take place in order to change the chemical nature of the compounds and chemical derivatives used. Notably, the most pivotal molecular mechanism and approach that is considered, based on this method and molecular process, is the radical photopolymerization and the preferred type is living radical polymerization, which will be carried out in the bed of rigid polymer matrices.

[0184] The fourth characteristic and intrinsic effect that is discussed, is the Thermochromism effect. In terms of the nature and the way it works, the Thermochromism effect is similar to the Photochromism effect In fact, this claimed inherent property and effect is another special type of the general effect of color change due to the influence of external factors and stimuli (the chromism effect) and is reversible, which is relies on carrying out a chemical reaction or transformation process between two or a set of several stereoisomers or structural isomers and by the external factor of heat and temperature changes.

[0185] Furthermore, it is worth noting that similar to the Photochromism effect, the inherent property and effect of Thermochromism is based on a set of molecular techniques and mechanisms such as thermo-induced proton transfer, trans-cis thermoisomerization, homolytic cleavage and thermocyclization, with the aim of taking advantage of this inherent property and effect discussed, in this claimed invention, a set of different molecular techniques and approaches have been used, which include a range of molecular processes, similar to the effect and inherent property of Photochromism, as follows.

[0186] - Similar to the first process related to the inherent effect and property of Photochromism, in the first process related to the inherent property and effect of Thermochromism, a set of organic macromolecular compounds, which have a range of substitutions and chemical chains containing a set of conjugated double bonds, have been used and the Thermochromism process is conducted with the help of a heat source and with the ability to apply heat and temperature changes in a wide range. It is worth noting that the temperature range used for applying heat in organic macromolecular compounds will be determined based on the type of substitution and the chain containing a set of conjugated double bonds and proportional to the functional groups and other effective substitutions placed in the chemical structure which are adjacent to the chain of double bonds mentioned. Furthermore, from a technical point of view, the claimed process will be based on the technique and molecular mechanism of trans-cis thermoisomerization.

[0187] - Similar to the second process related to the effect and inherent property of Photochromism, in the second process related to the inherent property and effect of thermochromism, metal salts of transition elements and coordination compounds, with the centrality of quasi-stable or unstable metallic elements belonging to the 3 periods of the 4th, 5th, and 6th periods of transitional metals of the periodic table and especially, metals belonging to groups 5 to 9 of transitional elements are used, which play the role of the centers and cores of these coordination compounds and in this process, following by transmitting heat energy and applying targeted temperature alterations in the used sample of these alleged metal compounds and salts, the process of charge transfer and electron transfer among layers and atomic and molecular electron orbitals will be performed in a reversible manner and based on the thermo-induce electron transfer technique.

[0188] - Similar to the third process related to the effect and inherent property of Photochromism, in the third process which is related to the effect and inherent property of Thermochromism and is based on the technique and molecular mechanism of photocyclization, various aromatic, pseudo-aromatic, and non-aromatic cyclic or non-cyclic macromolecular compounds and derivatives containing a set of conjugated double bonds and especially chemical compounds containing at least one non-cyclic substitution of conjugated double bond with an aromatic ring have been utilized. In this procedure, following the process of inducing heat and embedding the utilized chemical structure in the proximity to a heat source and with the establishment of a certain excitation in the molecular orbitals or vibrational and rotational levels of the used chemical compound, based on two general hydrogen shift and carbon shift mechanisms, a molecular process and chemical reaction, will be carried out in the direction of cyclization or cyclization of the corresponding molecule.

[0189] In fact, following the photocyclization process, the primary molecule will be reversibly converted to one of its structural isomers that possess several extra rings. Among the most important mechanisms for carrying out the claimed ring-forming reactions, we can mention sigmatropic reactions and rearrangements, including the Claisen rearrangement of [3,3] sigmatropic reaction, the Diels-Alder reaction of [4,2] sigmatropic reaction, the Cope rearrangement of [1,5] sigmatropic reaction, the Woodward Hoffmann rearrangement of [1,7] sigmatropic reaction, the Wagner-Meerwein rearrangement of [1,2] sigmatropic reaction and other molecular rearrangements or chemical processes with a [2,3] sigmatropic reaction mechanism. It is worth noting that in this process, the possibility of simultaneously using several derivatives and stable metal salts of some alkaline elements, alkaline earth elements, and transition elements of the first series, with the thermocyclization process catalyst role, has been provided.

[0190] - Similar to the fourth process related to the effect and intrinsic property of Photochromism, in the fourth process related to the Thermochromism effect, which is based on the technique and molecular mechanism of homolytic cleavage, a set of light-sensitive compounds is utilized, which contain at least one weak and radiation-sensitive bond. In this way, with the creation of free radicals, various chemical processes take place in order to change the chemical nature of the compounds and chemical derivatives used. It is worth mentioning that the most important molecular mechanism and approach considered, based on this method and molecular process, is radical Thermochromism with the preferred type of living radical polymerization, which will be conducted in the bed of rigid polymer matrices.

[0191] Prior dealing with the fifth effect and inherent property investigated in this embodiment of the claimed invention, another molecular process and approach will be investigated, which despite having a set of fundamental differences with the previous four processes, can be considered as a subset of possible molecular processes and approaches for both the effects and inherent properties of Photochromism and Thermochromism. In this process, which can be related to any effect and inherent property of Photochromism and Thermochromism, manipulating the enzymatic activity of a wide range of natural or biologically engineered enzymes with the help of external heating or irradiation with a certain frequency range of electromagnetic waves has been considered.

[0192] In the process of implementing and implementing this method and process, at least one enzyme matrix has been used along with a set of compounds and derivatives sensitive to enzyme activity, which possess the capability of creating and producing degraded compounds and secondary derivatives after undergoing a chemical reaction in the presence of the utilized enzyme matrix and the enzyme matrix carrier solution. In fact, in this method, by utilizing an external thermal or radiation triggering factor such as a temperature shock, a significant change in the temperature of the matrix and the enzyme solution has been used, or exposing the sample and the enzyme matrix to the radiation of a spectrum of electromagnetic waves with the ability to excite, undergo the process of enzymatic activity switching, in two types, on-off or reduced-enhanced, and in both reversible or irreversible ways, and will eventually lead to a chain of chemical reactions.

[0193] The fifth intrinsic property and effect discussed is Mechanochromism or Piezochromism. In terms of molecular and chemical nature, the Mechanochromism or Piezochromism effect is a special type of general effect of color change due to the impact of external factors and stimuli (the chromism effect), which is triggered and be activated by an external mechanical factor and force, such as pressure, and based on changes in the band gap (band gab) in the crystalline form of polymeric compounds, zwitterionic derivatives, and especially compounds with semiconducting properties.

[0194] Notably, the process and molecular approach of Piezochromism can occur in both irreversible and reversible manners and in various temperature ranges. Also, according to the type of chemical nature of the discussed process, the main focus in carrying out the process of Mechanochromism or Piezochromism is the existence of a type of chemiluminescent property such as fluorescence or phosphorescence, and the possibility of conducting this process will be provided in a wide range of chromogenic polymers, semiconducting derivatives centered at least one of the metals and intermediary elements of the fifth and sixth periods, diverse ranges of compounds and derivatives of oxide, peroxide, halide, nitrite, nitrate, sulfide, sulfite, sulfate, and carbonate pseudo-metallic compounds of the periodic table, multinuclear coordination compounds centered on at least one cationic species of transition metal elements of periods and periods of the fourth, fifth and sixth periods of the periodic table, and in general, any other chemical compound that possesses a set of fluorescence or phosphorescence properties.

[0195] The sixth and last inherent property and effect considered in this invention is the inherent property and effect of Solvatochromism, consisting of several different sub-branches such as hydrochromism and ionochromism, which represents the effect of the solvent on the energy levels and electron levels of the compound. In this situation, following the application of the chemical structure and molecular composition considered in a diverse range of solvents, due to the type of solvent coating and new intermolecular interactions between the solvent molecules with different components, substitutions and functional groups in the relevant chemical composition, a change in the levels of bonding, non-bonding, and anti-bonding molecular orbitals has emerged, which is proportional to the change in the energy levels induced by these intermolecular interactions, the range of absorption and emission wavelengths of the chemical structure of the covered solvent will change and subsequently, the mentioned process will cause an alteration in the color of the solution and the final matrix of the utilized chemical structure and solvent.

[0196] To achieve the Solvatochromism process, It would be possible to use a wide range of polar conjugated aromatic molecular and macromolecular compounds. Especially hydrazone derivatives, benzothiazole, phenylacrylonitrile, phenylimidazole, phenyltriazole, nitropyridine, cyanopyridine, cationic derivatives such as pyridinium phenolate and styrylpyridinium, combined pyridine derivatives conjugated with various substitutions such as aniline, acrylonitrile, imidazole and triazole, cyanine derivatives and in general, any conjugated aromatic chemical structure and compound that has at least two aromatic rings and one conjugated linker.

[0197] Finally, it is worth noting that other intrinsic or induced effects and properties will exist to create the secondary chromism effect in the claimed embodiments of this invention, which would create the possibility to use these approaches and molecular mechanisms, in a lateral and complementary manner. Considering these approaches and molecular mechanisms, as complementary innate and induced effects and properties, relies on the need for an external chemical stimulating agent and the application of a series of specific technical restrictions to control the environmental conditions and exchange of airflow, within the compartments and different components, it is related to the application of the 3D printing process.

[0198] The most important inherent and induced property and effect considered, in this embodiment of the claimed invention, will be the effect of Vapochromism, which with the purpose of benefiting from this special type of chromism effect in creating color changes in the targeted direction, a specific range of volatile organic compounds (VOCs) will be used in order to create steam and produce the gaseous phase of organic chemical compounds, as external chemical stimuli used in the application of the discussed approach and molecular mechanism.

[0199] In this method and the complementary method that can be used in this embodiment of the claimed invention, different crystalline forms of organometallic compounds, various matrices of cross-linked polymers, preferably matrices, and systems with rheological properties of gel and hydrogel, and besides that, various coordination compounds will be used with the centrality of intermediate elements of the fourth, fifth and sixth periods of the periodic table and with various macromolecular chelating ligands, such as pillar[5]arene-based derivatives, phenanthroline-based derivatives, bipyridine-based derivatives, diphenylphosphino-based derivatives, porphyrin-based derivatives, corrole-based derivatives, biphenol-based derivatives, BINAO-based derivatives, terpyridine-based derivatives, regular and S-oxide derivatives based on sulfur-bridged dimine ligand and pyrazole-based derivatives that were functionalized with various electron-donating functional groups, preferably hydroxy, phenyl ether, amine, and imine functional groups, along with a set of different electron-withdrawing substitutions, especially with substitutions such as nitro substitute, cyano substitute, acrylonitrile, sulfate, carbonate, sulfonic acid, phosphonic acid, and in total, any substitution with other electron-withdrawing properties.

[0200] In the previous sections, the technical details and how to implement various embodiments of this claimed invention, including the design and implementation of units of 2D printer devices and systems, were discussed. Moreover, the preferred macromolecular chemical compounds and derivatives and the preferred type and conditions of each of the considered usable external stimuli were carefully examined, in accordance with the physicochemical, rheological, and structural properties of the substrates and different printing surfaces used and the approach adopted for the implementation and assembly of the claimed advanced intelligent multicomponent multisectoral printing system and device. In this section, the technical details and methods used to implement the improved molecular printer device and system will be reviewed, which possesses the ability to implement a set of molecular functions and processes, based on the general mechanism and technique of 3D molecular printing, and is considered the main embodiment of this claimed invention.

[0201] As discussed earlier, the improved intelligent combined multicomponent multisectoral printer implemented in this invention possesses a set of several combined technical capabilities and functions, with the aim of achieving the implementation of a synchronized print combined process, which consists of implementing at least one 2D printing process, along with at least one 3D printing process, based on the application of at least one molecular process and approach from a set of different molecular processes and approaches claimed. The technical and chemical details of these processes and chemical approaches have already been mentioned in detail.

[0202] In fact, all the considered embodiments of this intelligent combined multicomponent multisectoral printer are claimed to be designed and implemented in such a way that the process of synchronizing the 2D printing process with molecular printing processes is possible. As a result, along with considering a set of specific technical and chemical parameters, such as the physicochemical, rheological, and structural properties of the printed substrate or surface used, the type of 2D printing technique and process used, and the colored and non-colored derivatives and compounds used in the 2D printing process, the printed outputs obtained and resulted from these claimed 2D printing processes and techniques would possess the ability to be compatible with the claimed advanced molecular printer system (1).

[0203] As mentioned in the previous sections, inside the functional compartment of this advanced molecular printer system discussed (6), an assembly of 2 general types of intelligent electromechanical systems, including an assembly of intelligent electromechanical systems moving on a surface, containing at least one laser-enhanced radiation source and an optical sensor (3), together with a set of electromechanical systems fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms (4), can be witnessed.

[0204] Furthermore, in addition to these 2 types of sets of claimed intelligent electromechanical systems, from two different moving plates and substrates, including a metallic / polymeric mobile plate and substrate of the type of compressed polymer structures, which is the place of situating and embedding various printing substrates of paper, wool, silk, polymer, fabric, fabric and other types of textile, it is also used with a special transparent plate and substrate with rails (2) which is equipped with a set of nano / micro nozzles and complex multi-component molecular injection systems (5) and these two plates are connected mutually through a set of 4 cylinders with a special design (9), which is suitable for placing and embedding a set of several units of claimed electromechanical systems, and a set of 2 end-to-end rollers (20).

[0205] During the molecular 3D printing process, the substrate or printed surface (24) is inserted through at least one unit of the set of guide rollers (21) into the main compartment and operational section of the claimed advanced molecular printer system. The main operating part of the designed advanced molecular printer system will include 2 plates and a designed moving plate and substrate, along with a set of operating units of 2 types of electromechanical systems, which are mounted on the inner upper surface of each of the claimed 4 moving railed-equipped cylinders (9).

[0206] As previously claimed in connection with the molecular processes and approaches employed in this embodiment of the invention, with the aim to conduct and implement the 3D molecular printing technique, based on the targeted manipulation of physicochemical, electrostatic, and electrodynamic properties of suitable and usable molecular and macromolecular compounds and derivatives, which benefit from the inherent properties and molecular properties of Adsorbchromism, Mechanochromism, Thermochromism, Vapochromism, Photochromism, Electrochromism, Piezochromism or Solvatochromism, the necessity to enable the essential technical conditions to benefit from a variety of pre-determined specific external stimuli, with the preference of enabling the technical condition of performing 4 basic external stimuli, including a laser stimulus based on the irradiation of light photons and polarized electromagnetic waves, an electric stimulus based on the application of electrical pulses, a temperature stimulus based on the application of thermal pulses, and also mechanical stress stimuli, which these alleged mechanical stress stimuli rely on the procedure of applying various mechanical and pressure stimuli to create targeted molecular vibrations and based on the piezoelectric effect, would be pivotal.

[0207] As a result, in order to induce various excitations in the electronic and vibrational levels of molecular and macromolecular compounds and their derivatives, the technical possibility of inducing and carrying out a set of reversible or irreversible chemical processes and reactions, based on diverse molecular mechanisms, including the process of changing and manipulating the oxidation number, applying chemical isomerization reactions, applying various molecular switches, and inducing targeted and controlled alterations or manipulations in the configuration patterns of the utilized compounds, has been smoothed. In order to achieve the stated goal and to access the necessary technical capabilities in the application and use of the claimed external stimuli, the main components of the operational part of the claimed improved molecular printer system have been equipped with a set of special technical capabilities, which, in accordance with the targeted approach, provides the possibility of using each of these 4 stimuli or several external stimuli simultaneously.

[0208] The cornerstone of the claimed operational part is two mobile plates and substrates, and two different types of electromechanical systems are used. On the upper metallic / polymeric surface of the mobile plate and substrate of the type of compressed polymer structures, which is the location of placement and embedding of various paper, wool, silk, polymer, fabric, fabric, and other types of textile printing substrates, a series of different ceramic, ionic, and polymeric compounds have been utilized, which are in crystalline and semicrystalline form and have piezoelectricity characteristics.

[0209] Notably, among these various claimed ceramic, ionic, and polymeric compounds, the preferred types of chalcogenide derivatives, quasi-metallic and metallic elements of the fifth group of the periodic table, and transition elements of the fourth and fifth periods, as the network-forming groups, have been taken into consideration, along with the elements belonging to the sixth main group of the periodic table (chalcogen) such as sulfur, selenide, and tellurium, semisynthetic natural semicrystalline polymer derivatives, preferably using chitosan and cellulose derivatives as well as synthetic polymer derivatives with semicrystalline form such as polyvinylidene fluoride (PVDF), poly-L-lactic acid (PLLA), polyhydroxybutyrate (PHB) and polyamide derivatives with other compounds and their copolymer derivatives.

[0210] In addition to this capability considered for the design and implementation of the upper surface of the plate and the claimed movable substrate, it will be possible to use semiconductor surfaces based on chemical compounds with the characteristics of straightening the electric current, which this matter will provide the possibility of performing the electric pulse technique, as a specific example of external factors and stimuli that can be used, in a situation where there is a desire to use molecular and macromolecular compounds and derivatives with the inherent nature and effect of Electrochromism.

[0211] The most pivotal element of the main operating part of the alleged molecular printer system is the 2 different types of specially designed electromechanical systems, which consist of an intelligent electromechanical system movable on the surface, containing at least one enhanced laser radiation source and an optical sensor (3) and an electromechanical system fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms (4).

[0212] A surface-mounted intelligent electromechanical system containing at least one laser-enhanced radiation source and an optical sensor (3), consisting of an array of electronic and electromechanical components and systems, which has provided the possibility of this electromechanical system for being digitally linked to other electromechanical systems or different electromechanical-based parts, in the form of laser telecommunication, which is based on the radiation of polarized laser electromagnetic waves and in the form of encrypted and decrypted information transmission. This claimed electromechanical system, contains a special planetary gearbox with an improved design, that the claimed planetary gearbox consists of at least 3 planetary gears (86), at least one epicyclic gear (90), and one ring gear (85), on the upper surface of the outer body of this special planetary gearbox (106), a quasi-spherical movable base (102) is embedded.

[0213] The purpose of using this set and this planetary gearbox with the claimed improved design is to enable the necessary conditions to apply horizontal and vertical angular rotation, respectively, with an effective range in a range of 180 degrees and a range of 60 degrees. As depicted in various embodiments of the claimed movable electromechanical system, on the upper surface and area of the claimed quasi-spherical movable base (102), a set of equipment comprising at least one laser light beam emitter unit (96), at least one optical sensor unit (photoreceiver), of different types of photocell, photodiode or phototransistor (100) and also a set of electrical connectors (87) are installed.

[0214] The main purpose of using the laser beam emitting unit (96) is to enable the necessary conditions for the radiation of a specific frequency spectrum of polarized laser electromagnetic waves, as the most important and the first external stimulus used. In fact, with the presence of this part and the laser beam emitting unit, the necessary conditions for the exposure of the screen and the utilized metal / polymer mobile substrate of the type of compact polymer structures, which is the place of placement and embedding of various textile-based printing substrates, would be provided with a specific frequency and wavelength spectrum of polarized laser electromagnetic waves and the mentioned issue will eventually cause the possibility of creating and inducing various excitation in different energy levels of electronic, vibrational and rotational orbitals of chemical compounds and molecular and macromolecular derivatives that have at least one of the inherent properties and natures of Adsorchromism, Mechanochromism, Thermochromism, Vapochromism, Photochromism, Electrochromism, Piezochromism and Solvatochromism.

[0215] In the set of different molecular approaches and processes used in the implementation of the general technique of 3D molecular printing (3D molecular printing) the role of laser light rays produced and radiated by the alleged laser light ray emitting unit (96) is classified into two primary and secondary categories.

[0216] In case of consideration of chemical approaches and processes that are based on the application of the effect and inherent nature of Photochromism, Thermochromism and Adsorchromism, light rays and laser electromagnetic waves are considered as the primary external stimuli which will provide the possibility of inducing different excitations in the energy levels of electronic, vibrational and rotational molecular orbitals of derivatives and different molecular and macromolecular compounds, including the organometallic derivatives and compounds, molecular machines, various polymeric and copolymeric structures, nanoclusters, nanostructures and various nano / micro crystals claimed in various embodiments of this invention, directly, which through a set of nano / micro nozzles and complex multi-component molecular injection systems (5), with an improved design that embedded on the lower surface of the plate and a special transparent substrate with rails (2), the process of applying and injecting a clear, fluid, colloidal or suspension carrier solution of these derivatives and compounds would be carried out.

[0217] Furthermore, it should be mentioned that to benefit from each of the two effects and the two inherent properties of Photochromism and Thermochromism, the nature of the technical model will be similar in using the laser light beam emitter, and the only distinguishing aspect of these two issues will be the optimal frequency range for the laser electromagnetic waves produced and radiated, for benefiting from the inherent effect and property of Photochromism, the range of electromagnetic waves in the visible region of violet color to ultraviolet and preferably the wavelength range between 25 nm and 430 nm will be used. Notably, in order to optimistically benefit from the effect and inherent property of the Thermochromism effect, the range of electromagnetic waves in the visible region of red color to infrared (infrared) and preferably the wavelength range between 430 nm and 900 nm would be applied.

[0218] In contrast to the described criteria and classification, for the purpose of benefiting from compounds with the inherent effects and properties of Mechanochromism, Electrochromism, and Piezochromism, the produced and radiated light rays and electromagnetic waves toward the target substrate and printed surfaces will act as a secondary external stimulus.

[0219] Furthermore, it is worth noting that in addition to the main considered goal to apply targeted manipulations at the electronic levels and in the chemical structure or the configuration of various conformers of the utilized molecules and macromolecules, by a subsequent induction of various excitations at different molecular, electronic, vibrational, and rotational levels, another complementary goal has been targeted in line with the implementation of the mentioned mobile electromechanical system in the application of the considered technical approaches.

[0220] This alleged complementary goal relies on establishing the capability and technical ability to continuously exchange digital information and laser telecommunication type, among a compilation of several units and sets of this specific type of claimed movable electromechanical systems, with other electromechanical systems used, in various embodiments and compartments designed from other devices and printing systems used in this invention, which enables the process of transmitting, receiving and exchanging pulsed or continuous polarized laser electromagnetic waves, with the aim of establishing a compilation of digital communications by facilitating the process of continuous exchange of encrypted and decrypted information, among different mobile or fixed smart electromechanical sets used on different surfaces, which have the ability to be linked to different objects and parts, through the presence of enhanced laser radiation sources.

[0221] This will provide a unique continuous digital telecommunication connection, both among the various operational components in the claimed enhanced molecular printer system, and between the claimed enhanced molecular printer system and the target 2D printing devices and systems. This issue will provide and smooth the process of synchronizing the performance of various 2D printing devices and systems, that were applied in various embodiments of the claimed invention, with the mentioned molecular printer system, along with the process of self-regulation and optimization of factors and parameters effective in the process of implementing the combined 2D-3D printing process, in an optimized manner.

[0222] In the previous section, the technical details used in the design and implementation of a mobile smart electromechanical system on the surface, containing at least one enhanced laser radiation source and an optical sensor (3) were discussed. Similarly to the claimed mobile intelligent electromechanical system, the alleged surface-fixed electromechanical system contains electro-optic parts such as beam splitters, polarizers and dichroic mirrors / prisms (4), also consisting of a set of electronic and electromechanical parts and systems, which has provided the technical possibility for this electromechanical system to be linked to other electromechanical systems and different parts, in a digital form and of the laser telecommunication type, which relies on the procedure of polarized laser electromagnetic waves radiation and in the form of encrypted and decrypted information transmission.

[0223] Similar to the approach used in the design of the central part and the main and operating compartment of the intelligent electromechanical system movable on the surface, containing at least one laser-enhanced radiation source and a claimed optical sensor, a special planetary gearbox is used in the central part of this electromechanical system which comprises at least 3 planetary gears (126), at least one sun gear (epicyclic gear) (129), and one ring gear (125), and on top of that, a quasi-spherical movable base (132) is installed to create a range of 180 degrees in the effective range of horizontal angular rotation and a range of 60 degrees in the effective range of vertical angular rotation, relative to the axis perpendicular to the surface of the movable quasi-spherical base (132).

[0224] Besides, the rest of the utilized parts and equipment in the implementation of this claimed fixable electromechanical system, possess a functional and technical nature with the parts and components used in the central compartment of the mobile surface-mounted intelligent electromechanical system, containing at least one enhanced laser radiation source and a pointed optical sensor, and the only technical difference applied in this section relies on the replacement of a set of laser light beam emitting units (96) with at least one electro-optical unit or piece from among the usable electro-optic parts such as beam splitters, polarizers and dichroic mirrors / prisms (123) that the type of this utilized electro-optical element in the claimed advanced molecular printer system will preferably be polyhedral and often in the form of hexagons, heptagons, and tetrahedrons. The existence of different side faces (124), flat top (134), and small top (135) has provided the possibility to cause eventual refraction and deviation in the rays radiated from polarized laser electromagnetic waves in a targeted manner, which has enabled the process of targeted radiation with an adjusted intensity, in a 120-degree coverage area and in line with 2 plates and the moving substrate.

[0225] Furthermore, the asserted surface-fixable electromechanical system used in the mentioned improved molecular printer system (4) possesses at least one unit of the main brushless motor, including a set of coils and central brushless magnets (127), which is installed on the upper surface of the fixed metal base (131) and the lower surface of the claimed metal base (131) is installed on the inner upper surface of the set of mobile cylinders with uneven thickness (9) and the existence of this set of coils and central brushless magnets claimed (127), to create purposeful and intelligent rotational movement in the whole assembly and by relying on the capability of establishing weak cross-sectional connections and interactions, on various levels and according to the type and nature of the encrypted information exchanged, among different units and sets of electromechanical systems in different compartments and devices.

[0226] In the previous sections, it was mentioned to evaluate and examine the details and technical approaches used in the design of various embodiments and the implementation of various devices, systems, and compartments that make up the intelligent combined multicomponent multisectoral printer. Due to the existence of a set of several independent and dependent systems, in the operationalization of the claimed multi-part and multi-part printing system and device, the numerous advantages of the various embodiments of the claimed invention have been evaluated and investigated separately.

[0227] As claimed, the improved intelligent combined multicomponent multisectoral printer designed and implemented in this invention possesses a set of several combined technical capabilities and functions, which include the procedure of implementation of at least one 2D printing process, along with at least one 3D printing process, based on the use of at least one molecular process and approach from a set of various claimed molecular processes and approaches, with the aim of achieving the implementation of a synchronized printing process.

[0228] In fact, all the considered embodiments of this intelligent combined multicomponent multisectoral printer are claimed to be designed and implemented in such a way that the process of synchronizing the 2D printing process with molecular printing processes is possible. As a result, along with taking a set of specific technical and chemical parameters, such as the physicochemical, rheological, and structural properties of the utilized printed substrate or surface, the type of 2D printing technique and process used, and the colored and non-colored derivatives and compounds used during the 2D printing process into consideration, the printed outputs obtained from these claimed 2D printing processes and techniques will have the ability to be compatible with the claimed advanced molecular printer system.

[0229] The claimed intelligent combined multicomponent multisectoral printer possesses a combined functionality, by relying on a set of combined approaches and techniques, consisting of using at least one of 3 main preferred 2D printing mechanisms, e.g. heat transfer printing, planographic printing, and digital printing, in combination with and along with the application of at least one molecular printing technique, from various sources of molecular printing techniques and approaches relying on the direct materials / molecules' delivery mechanism, such as soft lithography, dip-pen nanolithography and polymer-pen lithography techniques and also, other molecular printing techniques are based on the direct energy delivery mechanism, such as nanografting, nanoshaving, anodic oxidation and millipede techniques.

[0230] Following the presence and existence of such combined printing functionality in the claimed advanced multicomponent multisectoral printing system and device, the process of implementing a complex and targeted process of hybrid 2D-3D printing mechanisms, in accordance with a set of several diverse molecular layers, would be provided.

[0231] Furthermore, regarding the existence of the above-mentioned improved technical ability necessary to align various molecular printing techniques, especially molecular printing 3D printing techniques based on direct materials / molecules' delivery mechanism, this advance hybrid 2D-3D multitasking printer would possess the ability to apply targeted structural alterations or manipulations, with the aim of creating different excitations in electronic and vibrational levels and subsequently, establishing various electronic-molecular states, configurations, and different color and structural patterns, with the help and intermediary role of various external factors and stimuli including laser light beams, electric pulses, thermal pulses and any related techniques in inducing molecular vibrations, especially from the preferred piezoelectric-based approaches or techniques, by relying on the existence of various inherent molecular capabilities and effects including Adsorchromism, Mechanochromism, Thermochromism, Vapochromism, Photochromism, Electrochromism, Piezochromism, and Solvatochromism.

[0232] In laser printers with a conventional design, the process of radiating electromagnetic waves and laser-type radiation rays is done through the laser scanning unit; However, in this embodiment of the claimed invention, an improved hybrid electromechanical system is used, based on two separate special electromechanical systems and consisting of at least one unit of the electromechanical system fixed on the surface, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be linked to different systems and parts, in digital form, with at least one unit of the electromechanical system fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms, and with the ability to be digitally linked to various systems and parts.

[0233] Subsequently, by using this combined electromechanical system, in addition to possessing improved technical ability in producing and irradiating a specific frequency and wavelength spectrum of laser electromagnetic waves, it would enable the technical conditions to link and transmit digital information continuously among the sets used from these two units and the separate electromechanical system constituting the alleged combined electromechanical system, encrypted and targeted, based on the physical mechanism of interferometry and in the form of laser telecommunication.

[0234] With respect to the nature and technical approaches considered in the implementation of this system and the improved multitasking multisectoral intelligent printing device in this claimed invention, which has provided the possibility of combining and simultaneously implementing the claimed 2D printing and 3D molecular printing methods and techniques; the implementation of these two mentioned technical features will make it possible to establish smart digital communication among various electromechanical parts or systems utilized in different invention's embodiments.

[0235] Moreover, by benefiting from the application of both interferometry mechanism and laser telecommunication technique, the possibility of establishing digital communication among the electromechanical systems constituting the claimed hybrid electromechanical system in the designed advanced laser printing device with the electromechanical systems used in other equipment that positioned in the external area and outside the claimed laser printing system and device, particularly with the electromechanical units and systems employed in the claimed implemented enhanced molecular printer system, comprising at least two compilations of main electromechanical units and systems and including a set of advanced electromechanical systems movable on the surface, containing at least one enhanced laser radiation source and an optical sensor and with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally linked to diverse electromechanical and any other receiver-possessed surface-mounted systems and parts, in digital form, along with a set of surface-fixed electromechanical systems, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms with the ability to be digitally connected to different systems or devices, is provided.

[0236] Furthermore, in the redesigned and considered second 2D printing device and system, which is the calendar dye sublimation printing device and system, a specific and innovative approach has been used in the redesign of the device and the implemented dye-sublimation calendar printing system, which relies on the significant optimization and reduction of the operating temperature range of the redesigned device and printing system, compared to the operating temperature range available in the conventional and previous designs of this type of device and printing system based on the dye sublimation printing mechanism.

[0237] In fact, the operating temperature range of the device and traditional printing systems based on the dye-sublimation mechanism is between 180 and 230 degrees Celsius, which makes it impossible to implement the mentioned printing technique on many surfaces and printing substrates, especially temperature-sensitive printing substrates. Moreover, another technical problem in this printing technique and method, is related to the existence of many problems regarding the uniform and homogeneous distribution of color on the surface and the target printing substrate and the prevention of non-uniformities in the distribution and accumulation and undesired stabilization of the used colors in the unwanted areas of the target printing substrate.

[0238] In this embodiment of the claimed invention, by using an engineered alternative fluid and solvent system, based on the use of a specific range of perfluorocarbons, the heat transfer process can be carried out in a moderated manner. As referred earlier, in this method, an engineered fluid and solvent system based on two different approaches has been utilized. In the first approach, only a solution based on perfluorinated compounds, exclusively comprising a mixture of at least two different perfluorocarbons, by accounting for at least one compound with a preferred weight range, between 150 and 250 daltons alongside at least one compound with a preferred weight range of between 250 and 400 daltons is used. In the second approach, along with the use of perfluorocarbons derivatives, other polar solvents have been used, preferably over non-protonated solvents such as etheric compounds such as THF, which constitutes the major part of the fluid used, perfluorinated compound or compounds.

[0239] Subsequently, by using the engineered fluid and solvent system based on the main base of perfluorinated compounds, the implemented dye sublimation calendar printing device and system has operational capability in a lower temperature range than previous designs and systems. As a result, by using this technique and engineered approach in the design of alternative fluid and solvent systems, a significant reduction in the operating temperature range of the device and claimed printing system can be obtained, and eventually, the possibility of using specific printed substrates and surfaces sensitive to humidity and heat, such as silk-based or woolen surfaces or substrates composed of a wide range of polymeric compounds sensitive to the solvolysis process, is provided.

[0240] Furthermore, the process of evaporation and stabilization of the dye inks used in the process is more easily possible and minimizes the errors of the printing process.

[0241] It is worth noting that reducing the operating temperature range, leads to the establishment of the possibility of setting and monitoring the process of printing and fixing dye inks in different areas of the target substrate and printed surface in a controlled and targeted manner, which eventually has minimized the possibility of emerging errors in the printing path and has made it possible to revise or apply instant secondary changes in the pattern being printed.

[0242] : Representing a schematic representation of the completely assembled advanced intelligent combined multicomponent multisectoral printer, compose of an advanced laser printer system. Referred components include the advanced molecular 3D printing system (1), a special transparent railed plate and substrate (2), the mobile surface-mounted smart electromechanical systems, which possesses at least one enhanced laser radiation source and an optical sensor (3), the surface-fixed electromechanical systems, which composes several electro-optic parts and constituents such as beam splitters, polarizers, and dichroic mirrors / prisms (4), the complex multi-purpose multicomponent molecular injection systems comprising of a series of nano / micronozzles and nano / micro syringes (5), the advanced molecular printer system’s internal area of the functional compartment (6), the surface-fixed electromechanical system, which contains electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and is installed in the inner compartment of the advanced molecular printer system (7), the electro-optic-equipped surface-fixed electromechanical system, which is embedded in the inner compartment of advanced laser printer system (8), the whole unit of the advanced laser printer system (10), and the internal compartment of the claimed advanced laser printer system (11).

[0243] : Illustrating all the constituents and a fully assembled 2D schematic of the improved intelligent combined multicomponent multisectoral printer, including at least one advanced molecular printer system, at least one advanced laser printer system. Referred components include the central holder and support axis (12), the external area of the main protective compartment (13), the toner / ink hopper unit (14), the photoreceptor drum assembled unit (15), the set of transfer rollers and pressure rollers (16), the developer / toner roller unit (17), the holding units (18), the paper tray unit (19), the Fuser units (25), and a set of bobbins and electromotoric systems embedded on transfer / pressure rollers (26)

[0244] : Depicting a fully assembled 3D schematic of the claimed improved smart combined multicomponent multisectoral printer, relies on using at least one advanced laser printer unit, and all its constituents. Referred components the movable sectional railed-equipped cylinder with special design (9), the set of guide rollers (21), the front frame (22), the back frame (23), and the paper or textile-driven printable substrates and pieces (24)

[0245] : Demonstrating schematics of the complete assembled set of parts and systems that make up the intelligent combined multicomponent multisectoral printer, containing at least one advanced offset printing or flexographic system, along with the advanced molecular 3D printer.

[0246] : Showing schematic representations of complete assembly of the considered intelligent combined multicomponent multisectoral printer, operating based on a dual printing mechanisms of color printing mechanism (inkjet printing), along with the molecular printing mechanism, from different points of view.

[0247] : Illustrating 2 different 2D schematic of the inkjet-molecular 3D printing dual-action combined multicomponent multisectoral printer, in hidden lines visible forms. Referred components include the electrostatic roller unit (28), and a set of bobbins and electromotoric systems embedded on the developer / toner roller (29)

[0248] : Representing 2 different hidden lines visible schematics of the considered intelligent combined multicomponent multisectoral printer, containing at least one advanced offset printing or flexographic system, along with the advanced molecular 3D printer. Referred components include a unit of the advanced offset printing or flexographic system (30), the reel (31), the ink / toner fountain / tray (57), and the wetting-out roller (58)

[0249] : Depicting several schematic representations of the toner / ink-based roll-to-roll / rotary-molecular 3D printing dual-function advanced combined multicomponent multisectoral printer, from various perspectives. Referred components include the external hole and housing area of the claimed mobile sectional railed-equipped cylinder unit’s support axis (35), and the external compartment of the advanced offset printing or flexographic system (36)

[0250] : Illustrating a 2D schematic of the claimed advanced combined multicomponent multisectoral printer, which possesses a dual hybrid operation based on the combination of two different printing mechanisms, including the toner / ink-based roll-to-roll / rotary printing mechanism, with the molecular printing mechanism.

[0251] : Demonstrating multiple 3D schematics of the alleged toner / ink-based roll-to-roll / rotary-molecular 3D printing dual-function advanced combined multicomponent multisectoral printer, in various isometric, dimetric and trimetric shapes.

[0252] : Representing several hidden lines visible and hidden lines removed of the claimed improved smart combined multicomponent multisectoral printer, relies on utilizing at least one advanced offset printing or flexographic system, from various points of view. Referred components include a unit of the blanket (offset) cylinder (37)

[0253] : Showing a schematic representation of the completely assembled set and all the constituents of the advanced intelligent complex multicomponent multisectoral printer, which operates based on the combination of two different printing mechanisms, including the dye-sublimation printing mechanism, preferably calendar, with the molecular printing mechanism. Referred components include the dye sublimation calendar printing system (38), the external compartment and housing area of the dye sublimation calendar printer (39), a series of supportive and fixable ducts (40), the conveyor (41), and the temperature modulator and monitor unit (42)

[0254] : Demonstrating 3D schematic representations of a complete assembled set of devices and systems that make up the intelligent combined multicomponent multisectoral printer, containing at least one unit of technically upgraded calendar sublimation machine, along with the advanced molecular 3D printer. Referred components include the oil drum unit (43), the open transferring pathway for the transfer of the original printed substrate and for the transfer of paper-based printable substrates (44), the closed transferring pathway for transferring tissue paper-based substrates and layers (45), and the adjustable compression circulative closed pathway (47)

[0255] : Illustrating 2 different 3D schematics of alleged heat transfer dye-sublimation-molecular 3D printing dual-function advanced combined multicomponent multisectoral printer, in hidden lines visible form.

[0256] : Depicting several 3D schematic representations of a complete assembled set of parts and systems that composes the intelligent combined multicomponent multisectoral printer, containing at least one unit of technically upgraded calendar sublimation machine along with the advanced molecular 3D printer, from various visual angles.

[0257] : Representing 2 2D schematics of a section of the improved molecular printer system, as a comprising device of the alleged advanced intelligent complex multicomponent multisectoral printer, in hidden lines visible forms.

[0258] : Showing 2 different 2D schematic representations of a section of the advanced molecular printer system, as a part of the improved intelligent combined multicomponent multisectoral printer, by focusing on representing the constituting mobile surface-mounted set of electromechanical systems.

[0259] : Demonstrating several 2D schematics of the complete assembly and all the components of the body compartment of the claimed improved molecular printer system. Referred components include the railed-based intersecting area (48), the support axis for holding mobile sectional railed-equipped cylinder unit (49)

[0260] : Illustrating 2 distinguishable 2D schematic representations of the complete assembly and all the components of the multisectoral body compartment of the advanced molecular printer system, as part of the improved intelligent combined multicomponent multisectoral printer.

[0261] : Depicting 3 different 2D schematic of the complete assembly and all the components of the multisectoral body compartment of the advanced molecular printer system, as part of the improved intelligent combined multicomponent multisectoral printer, in hidden lines visible forms.

[0262] : Showing several isometrical and diametrical shapes and representations of the complete assembled set and all the components of the body and the placement of the mechanical and electromotor systems of the claimed advanced molecular printer system.

[0263] : Illustrating several 3D schematics of the complete assembly of the body compartment and the housing of the placement of the mechanical and electromotor systems of the claimed advanced molecular printer system.

[0264] : Showing two 2D schematics of the fully assembled and the placement of the various units and electromotoric systems that compose the advanced laser printer system. Referred components include the holding and fixating base (27) the complex of lower pressure roller and upper heated hollow roller with a radiant light source inside (50), the fuser unit rollers’ connector (51), and the Corona wire unit (52)

[0265] : Representing several 2D and 3D schematics of the compartment assembly and the placement of each unit and electromotoric system inside the referred compartment of the technically upgraded laser printer system, as part of the technically advanced intelligent complex multicomponent multisectoral printer.

[0266] : Depicting a hidden lines visible form of a complete assembled set and all components, systems, and constituents that compose the claimed advanced laser printer system, as part of the upgraded intelligent combined multicomponent multisectoral printer.

[0267] : Demonstrating several 2D schematic representations of the complete assembled set and all the constituents, and systems that creates the advanced laser printer system, as a section of the claimed technically advanced intelligent combined multicomponent multisectoral printer.

[0268] : Illustrating several 2D schematics of the complete assembled of the advanced laser printer system, and all its constituents, components, parts and systems, in both hidden lines visible and hidden lines removed. Referred components include the pentagon prismatic electro-optic unit

[0269] : Showing several 3D schematic representations of all the components, parts and constituent systems and the complete assembly of the upgraded laser printer system, as a part of the upgraded intelligent combined multicomponent multisectoral printer, in both isometric and dimetric shapes and from various perspectives.

[0270] : Representing a 2D schematics of fully complete assembled assembly of the considered advanced offset printing or flexographic printing system, containing various functional and structural rollers, cylinders and units. Referred components include a unit of the pressure cylinder (32), a unit of the ink / toner roller (33), the solvent placement unit and tray (wetting out / solvent fountain / tray) (34), a unit of the plate cylinder (55), the equal-size direct guide rollers (56), a singular guide roller (144), the unequal-size guide rollers (145), a series of diverting and pressurizing guide rollers (146)

[0271] : Showing multiple representations of all the constituents and components of the complete assembly of an advanced offset printing or flexographic printing system, as a part of the intelligent combined multicomponent multisectoral printer, from different points of view.

[0272] : Demonstrating both wireframed and hidden lines visible schematic representations of an advanced offset or flexographic printing system, as a section of the technically improved intelligent combined multicomponent multisectoral printer, both isometrically and dimetrically. Referred components include the external compartment of the claimed offset printing or flexographic printing unit (59)

[0273] : Showing several 3D schematic representations of the fully assembled advanced offset printing or flexographic printing system with a printing function based on 2 toner / ink-based roll-to-roll / rotary printing mechanisms.

[0274] : Displaying 3 different asymptotic schematics of the fully assembled set and all the constituents and components of an improved offset printing or flexographic printing system, as part of the upgraded intelligent combined multicomponent multisectoral printer, in various isometric, dimetric and trimetric shapes.

[0275] : Representing a fully assembled schematic of the technically upgraded calendar dye-sublimation printer system. Referred components include the small-scale intermediary roller’s series (60), the fabric feeding roller (61), the paper rewind roller (62), tissue paper mobile roller equipped with a series of bobbins / electromotors (63), a series of bobbins / electromotors installed on the tissue paper mobile roller (64), the large-scale bobbin-equipped rotatable cylinder, embedded in the adjustable compression circulative closed pathway area, (66), the set of bobbins and electromotors embedded on the claimed large-scale bobbin-equipped rotatable cylinder (67), the tissue paper feeding / rewind roller (68), the fabric rewind roller (69), the set of bobbins and electromotor systems installed on the oil drum unit (70), printing substrates’ sheet location adjusting (71), the paper feeding roller (72), the mobile 180-degree rotatable cylinder (73), the motorized 180-degree rotatable cylinder (76), the set of bobbins and electromotors embedded on the motorized 180-degree-rotatable cylinder’s exterior (77), and the large-scale intermediary roller (79)

[0276] : Depicting two 2D schematic representations of the complete assembly and of the claimed upgraded calendar dye-sublimation printer system and all its constituents, as a part of the technically upgraded intelligent complex multicomponent multisectoral printers. Referred components include fabric pieces’ transferring pathway (46), the primary motorized ultrasmall-scale transferring roller (74), the temperature detector unit (75), the printable substrates’ sheet holder (78), and the printing substrate adjusting unit (80)

[0277] : Demonstrating 2 lateral and asymptotic 3D representations of a fully assembled unit of the claimed technically upgraded calendar dye-sublimation printer.

[0278] : Illustrating 2 different upper visual angle’s schematics of the claimed mobile surface-mounted intelligent electromechanical system, containing at least one laser-enhanced radiation source and an optical sensor. Referred components include the outlet terminal (81), the connector port of the outlet terminal (82), the electric wires (83), the assembly plate (84), the ring gear (85), a unit of the triple planetary gears (86), electrical connectors (87), the series of bobbins of the complementary brushless electromotor (88), the central (main) brushless magnets (89), the epicyclic gear (90), the laser radiation source / optical sensor base-plate interface (91), and the connector port for the laser radiation source / optical sensor unit (92)

[0279] : Showing a singular complete representation of the claimed movable surface-mounted intelligent electromechanical system and all its electromechanical components, that possesses multiple capabilities for inducing and generating various electron-molecular excitations; along with the ability to be digitally linked to various objects, parts and devices. Referred components include the spiral angle altering unit (93), the magnetic turntable (94), and the lower exterior surface to install electromotors and complementary motor’s bobbins (95)

[0280] : Representing several schematics of the fully assembled assembly and all constituting components of the alleged smart surface-movable electromechanical system, form different perspectives and in hidden lines visible forms. Referred components include the laser light beam emitter unit (96), the laser output lens (97), the semi-sphere holder of the altering direction nut unit (98) the cables connecting the radiator to the connector (99), the photoreceiver unit including photocell, photodiode or phototransistor (100), the laser light inlet channel (101), the quasi-spherical movable base for adjusting the entire photocell / laser assembly (102), and the laser radiation source / optical sensor adjustable base (103)

[0281] : Showing several 3D schematics of the complete assembly and all the structural and electromechanical components of the smart electromechanical system movable on the surface, containing at least one enhanced laser radiation source and an optical sensor, in both isometric and dimetric shapes. Referred components include the upper exterior surface of the adjustable base (104), and the metallic base for establishing fixed connections (105)

[0282] : Depicting multiple 2D schematic representations of the mobile surface-mounted smart electromechanical system, with multiple abilities of inducing and generating various electron-molecular excitations; along with the ability to be digitally linked to different objects and parts.

[0283] : Demonstrating several representations and 3D schematics of the discussed mobile surface-mounted intelligent electromechanical system, containing at least one technically improved laser radiation source, at least one optical sensor (photoreceiver) such as photocell / phototransistor / photodiode, from various points of view. Referred components include the external compartment of the planetary gearbox (106)

[0284] : Illustrating 2 different 2D schematic representations of the considered surface-fixed electromechanical system, from upper viewing angles. Referred components include the connector port for the laser radiation source / optical sensor unit (107), the cables connecting the radiator to the connector (108), the ring gear (109), the set of electrical connectors (110), the main brushless magnets (111), a unit of the triple planetary gears (112), and the sun gear of the planetary gearbox (113)

[0285] : Representing multiple 2D schematic representations of the fully assembled assembly and all the constituting structural and electromechanical components of the surface-fixed electromechanical system, containing at least one laser-enhanced radiation source and an optical sensor. Referred components include the laser light beam emitter unit (114), the laser output lens (115), the optical sensor unit (photoreceiver), of different types of photocell, photodiode or phototransistor (116), the laser light inlet channel (117), the metallic base for establishing fixed connections (118), the interior laser radiation source / optical sensor adjustable spiral base (119), the quasi-spherical movable base for adjusting the entire photocell / laser assembly (120), and the exterior laser radiation source / optical sensor adjustable spiral base (122)

[0286] : Displaying a series of 3D schematics of a completely assembled assembly and all components and constituents of the claimed laser-enhanced radiation source-and-optical sensor-equipped fixed surface-mounted electromechanical system. Referred components include the outer body (external compartment) of the planetary gearbox (121)

[0287] : Showing multiple isometrically shaped schematics of completely assembled assembly of the surface-fixed electromechanical system and all its constituents, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally linked to various systems and devices.

[0288] : Depicting 2 different 2D schematics of the fully assembled set of the fixed surface-mounted electro-optic-equipped electromechanical system, which contains at least three beam splitters and dichroic mirrors / prisms units as its electro-optic part and be embedded in the internal area of the alleged advanced molecular 3D printer. Referred components include the electro-optical unit such as beam splitters, polarizers and dichroic mirrors / prisms (123), the various lateral polygonal faces of the polygonal prismatic electro-optic unit (124), the ring gear (125), the series of coils and central (main) brushless magnets (127), and the electro-optic unit-plate interface (130)

[0289] : Illustrating multiple 2D and 3D representations of the alleged electromechanical system fixed on the surface with all its constituting components, which contains electro-optic components such as beam splitters, polarizers, and dichroic mirrors / prisms. Referred components include the metallic base for establishing fixed connections (131), the quasi-spherical movable base for adjusting the polygonal prismatic electro-optic unit (132), and the external compartment of the planetary gearbox (133)

[0290] : Representing various perspectives and several 3D schematics of a complete assembly of the claimed fixed surface-mounted electro-optic-equipped electromechanical system, which contains at least three beam splitters and dichroic prisms units as its electro-optic part and be installed in the internal compartment of the advanced molecular 3D printer, in both hidden lines visible and hidden lines removed. Referred components include the flat top (134), and the small top (135) surface of the claimed polygonal prismatic electro-optic unit

[0291] : Demonstrating several wireframed and hidden lines visible forms and schematics of the complete assembled assembly and all constituting components of another type of surface-fixed electromechanical system, containing at least one electro-optic part, which will be embedded in the internal compartment of the advanced laser printer system. Referred components include the quasi-spherical movable base for adjusting the pentagon prismatic electro-optic unit (136), the ring gear (137), a specific unit of the triple planetary gears (138), a series of the brushless magnets (139), the magnetic turntable (140), the sun gear of the planetary gearbox (141)

[0292] : Showing 3 different schematics of the fully assembled set and all constituting components of the referred electro-optic-equipped surface-fixed electromechanical system, which is embedded in the internal compartment of the advanced laser printer system, in various isometric, dimetric and trimetric shapes.

[0293] : Depicting several 3D schematic representations of the complete assembled assembly of a type of electro-optic-equipped surface-fixed electromechanical system, which is embedded in the internal area of the considered technically improved laser printer system.

[0294] : Illustrating a singular 2D schematic of the part related to the railed-equipped transparent plate and substrate of the body and the housing area of the mechanical and electromotor systems of the claimed advanced molecular printer system, from frontal visual angle

[0295] : Representing a series of 2D and 3D schematics of the fully assembled unit of transparent railed plate and substrate equipped with a set of nano / micro inkjet nozzles, as a constituent of the body and housing area of the mechanical and electromotoric systems of the claimed advanced molecular printer system, from different perspectives. Referred components include the railed area of the claimed railed special transparent plate and substrate (142), and the housing area and placement of the complex injection system’s nano / micro syringes or nano / micronozzles (143)

[0296] : Displaying several 3D representations of the considered transparent railed plate and substrate, and the referred advanced multi-purpose injection system embedded on it, in various isometric, dimetric and trimetric shapes.

[0297] : It shows a schematic representation of all the components and the complete assembled set of the upgraded intelligently combined multicomponent multisectoral printer, whose operation is based on the combination of two different printing mechanisms, including the color printing technique (inkjet printing), a special type of laser printing, with the molecular printing technique, preferably nanolithography and consisting of a set of parts and systems, including at least one advanced molecular printer system, at least one advanced laser printer system, a set of mobile surface-mounted smart electromechanical systems, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be linked to different systems and parts, in digital form, a set of electromechanical systems fixed on the surface, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be linked to different systems and parts digitally, a set of electromechanical systems fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form, a set of nano / micro inkjet nozzles and injection systems with an improved design and the ability to combine and inject a set of several molecular / macromolecular compounds, for applying the nanolithography technique and sets of special drums, rollers and cylinders, consisting of a range of photosensitive compounds, from the direct viewing angle, in the direction of the x and z axes of the coordinate system, and in the form of hidden lines visible. The scale of the drawn figures is 1 to 20 real scale and the dimensions shown are in centimeters.

[0298] : It demonstrates the general schematic and the complete assembly of the improved intelligent combined multicomponent multisectoral printer, which is based on the combination of two different printing mechanisms, including the color printing mechanism (inkjet printing), a special type of laser printing, with the molecular printing mechanism, preferably nanolithography and has the ability to print a range of compounds, molecules and macromolecules photosensitive, tenebrescent, photo-induced fluorescent and photo-induced phosphorescent and comprising a set of parts and systems, including at least one advanced molecular printer system, at least one advanced laser printer system, a set of intelligent electromechanical systems movable on the surface, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations and the ability to be linked to various systems and parts digitally, a set of electromechanical systems fixed on the surface, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally connected to various systems and parts, a set of electromechanical systems fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the power of being linked digitally to different systems and parts, a set of nano / micro inkjet nozzles and injection systems with an improved design and the ability to combine and inject a set of several molecular / macromolecular compounds, for applying the nanolithography technique and sets of special drums, rollers and cylinders, consisting of a range of photosensitive compounds, from the lower viewing angle, in line with the x and z axes of the coordinate system, and in the form of hidden lines visible. The scale of the drawn figures is 1 to 20 real scale and the dimensions shown are in centimeters.

[0299] : It represents a fully assembled schematic of the improved smart combined multicomponent multisectoral printer, whose technical operation is based on the combination of two different printing mechanisms, including inkjet printing, a special type of laser printing, with a molecular printing mechanism, preferably nanolithography, which possesses the ability to print a range of photosensitive, tenebrescent, photo-induced fluorescent and photo-induced phosphorescent compounds, molecules and macromolecules with multiple printing capabilities, on a specific printing substrate with various composition of paper, leather, wool, silk, polymer, fabric, or any other types of textile, from a lateral viewing angle, along the 3 coordinate axes, in a dimetric shape and in the form of hidden lines visible. The scale of the drawn figures is 1 to 20 real scale and the dimensions shown are in centimeters.

[0300] : It illustrates 2D schematics of the complete assembled set of parts and systems that make up the intelligent combined multicomponent multisectoral printer, by possessing an operational mechanism based on a combination of two different printing mechanisms, including inkjet printing, a special type of laser printing, with molecular printing technique, preferably nanolithography and comprising a set of sections and systems, including at least one advanced molecular printer system, at least one advanced laser printer system, a set of intelligent electromechanical systems movable on the surface, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be linked to different systems and parts, in digital form, a set of surface-mounted electromechanical systems fixed on the surface, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be linked digitally to various systems and parts, a set of electromechanical systems fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form, a set of nano / micro inkjet nozzles and injection systems with an improved design and the ability to combine and inject a set of several molecular / macromolecular compounds, for applying the nanolithography technique and sets of special drums, rollers and cylinders, consisting of a range of photosensitive compounds, from the lateral visual angles, in line with x and z axes of the coordinate system and in the forms of hidden lines visible and wireframed. The scale of the drawn shapes is 1 to 32 real scale and the dimensions shown are in centimeters.

[0301] : It depicts two 3D schematics of the complete assembly of the intelligent combined multicomponent multisectoral printer, which operates based on the combination of two different printing mechanisms, including the color printing mechanism (inkjet printing), a special type of laser printing, with the molecular printing mechanism, preferably nanolithography and empowered by the capability of printing a range of compounds, molecules and macromolecules photosensitive, tenebrescent, photo-induced fluorescent and photo-induced phosphorescent and includes a set of parts and systems, including at least one advanced molecular printer system, at least one advanced laser printer system, a set of mobile surface-mounted intelligent electromechanical systems, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be linked to various systems and parts, in digital form, a set of electromechanical systems fixed on the surface, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally connected to diverse systems and devices, a set of electromechanical systems fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form, a set of nano / micro inkjet nozzles and injection systems with an improved design and the ability to combine and inject a set of several molecular / macromolecular compounds, for applying the nanolithography technique and several sets of technically renovated drums, rollers and cylinders, which possessing a range of photosensitive compounds, from various lateral and asymptotic points of view, along the 3 axes of the coordinate system, and in isometric and dimetric shapes, and in the form of hidden lines visible. The scale of the drawn shapes is 1 to 32 real scale and the dimensions shown are in centimeters.

[0302] : It shows a general schematic and the complete assembly of a technically upgraded intelligent combined multicomponent multisectoral printer, which functions based on the combination of two different printing mechanisms, including inkjet printing, a special type of laser printing, and molecular printing, preferably nanolithography and the ability to print a range of photosensitive, tenebrescent, photo-induced fluorescent and photo-induced phosphorescent compounds, molecules and macromolecules with multiple printing capabilities, on a specific printing substrate composing various types of paper, leather, wool, silk, polymer, fabric and other types of textile, from 2 different viewing angles, along the y and z axes of the coordinate system and in the form of hidden lines visible. The scale of the drawn shapes is 1 to 32 real scale and the dimensions shown are in centimeters.

[0303] : It illustrates 2D schematics of all components and the complete assembly of a technically advanced intelligent combined multicomponent multisectoral printer, which operates based on the combination of two different printing mechanisms, including the toner / ink-based roll-to-roll / rotary printing mechanism, from flexography or offset printing, with the molecular printing mechanism, preferably nanolithography and comprising a set of parts and systems, including at least one advanced molecular printer system, at least one advanced offset printing or flexographic system, a set of mobile surface-mounted intelligent electromechanical systems, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally linked to diverse systems and devices, a set of surface-fixed electromechanical systems, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be linked to different systems and parts, in digital form, a set of fixed surface-mounted electromechanical systems, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the capability of being digitally connected to different systems and devices, a set of nano / micro inkjet nozzles and injection systems, with an advanced design and with the ability to combine and inject a set of several molecular / macromolecular compounds and apply the nanolithography technique, and multiple sets of technically renovated drums, rollers, and cylinders, composed of a range of photosensitive compounds, from the front and lower perspectives, in line with the x and z axes of the coordinate system and in the form of hidden lines visible. The scale of the drawn shapes is 1 to 28 real scale and the dimensions shown are in centimeters.

[0304] : It demonstrates the schematics of all the components and the complete assembly of the improved intelligent combined multicomponent multisectoral printer, which possesses an operation based on the combination of two different printing mechanisms, including the toner / ink-based roll-to-roll / rotary printing mechanism, from flexography or offset printing, with the molecular printing mechanism, preferably nanolithography, which can operate printing a range of photosensitive, tenebrescent, photo-induced fluorescent and photo-induced phosphorescent compounds, molecules and macromolecules with multiple printing capabilities, on a specific printing substrate with the composition of various paper, leather, wool, silk, polymer, fabric, and other types of textile types, and consisting of a set of parts and systems, including at least one advanced molecular printer system, at least one advanced offset printing or flexographic system, a set of intelligent electromechanical systems movable on the surface, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations and the ability to be linked to different systems and parts, in digital form, a set of electromechanical systems fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form a set of nano / micro inkjet nozzles and injection systems, with improved design and the ability to mix and inject a set of several molecular / macromolecular compounds and apply the nanolithography technique. and also, several sets of specific drums, rollers, and cylinders which are made of a range of photosensitive compounds, from various lateral and asymptotic points of view, along the 3 axes of the coordinate system, in isometric and dimetric shapes and in both forms of hidden lines visible and hidden lines removed. The scale of the drawn shapes is 1 to 40 real scale and the dimensions shown are in centimeters.

[0305] : It represents a schematic representation of all the components and the complete assembled set of the upgraded intelligent combined multicomponent multisectoral printer, which operates based on the combination of two different printing mechanisms, including the toner / ink-based roll-to-roll / rotary printing mechanism, one of the preferred mechanisms of flexography or offset printing, with the molecular printing mechanism, preferably nanolithography and the ability to print a range of photosensitive, tenebrescent, photo-induced fluorescent and photo-induced phosphorescent compounds, molecules and macromolecules with multiple printing capabilities, on a specific type of paper-based, leather-based, woolen, silk-based, polymeric, fabric-based, or any other type of textile-based printing substrate, from the lateral visual angle, along the x and z axes of the coordinate system and in the form of hidden lines visible. The scale of the drawn figures is 1 to 20 real scale and the dimensions shown are in centimeters.

[0306] : It depicts a schematic representation of the complete assembled set and all components and components of an advanced intelligent combined multicomponent multisectoral printer, which possesses a combined printing mechanism, resulting from the combination of two different printing mechanisms, including the toner / ink-based roll-to-roll / rotary printing mechanism, one of the preferred mechanisms of flexography or offset printing, with the molecular printing mechanism, preferably nanolithography and the capability of printing a wide range of photosensitive, tenebrescent, photo-induced fluorescent and photo-induced phosphorescent compounds, molecules and macromolecules with enhanced multiple printing capabilities, on a specific printing substrate composing of paper, leather, wool, silk, polymer, fabric, and other types of textiles, from different asymptotic visual angles, along the 3 axes of the coordinate system, in isometric, dimetric and trimetric shapes and in the form of hidden lines visible. The scale of the drawn shapes is 1 to 36 real scale and the dimensions shown are in centimeters.

[0307] : It shows schematics of the complete assembled set and all the components and parts that make up the upgraded intelligent combined multicomponent multisectoral printer, which operates based on the combination of two different printing mechanisms, including the toner / ink-based roll-to-roll / rotary printing mechanism, from flexography or offset printing, with the molecular printing mechanism, preferably nanolithography and the ability to print a range of photosensitive, tenebrescent, photo-induced fluorescent and photo-induced phosphorescent compounds, molecules and macromolecules with enhanced multiple printing capabilities, on various types of paper-based, leather-based, woolen, silk-based, polymeric, fabric-based, or any other textile-based printing substrates and consisting of a set of parts and systems, including at least one advanced molecular printer system, at least one advanced offset printing or flexographic system, a set of mobile surface-mounted intelligent electromechanical systems, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally linked to various systems and devices, a set of surface-fixed electromechanical systems, containing electro-optic parts such as beam splitters, polarizers and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form, a set of nano / micro inkjet nozzles and injection systems, with improved design and the capability of mixing and injecting a set of several molecular / macromolecular compounds and applying the nanolithography technique and multiple sets of dedicated drums, rollers, and cylinders which are composed of a range of photosensitive compounds, from different upper, lower, and lateral visual angles, in line with the 3 dimensions of the coordinate system, in different isometric and trimetric shapes and in 2 forms of hidden lines visible and hidden lines removed. The scale of the drawn shapes is 1 to 40 real scale and the dimensions shown are in centimeters.

[0308] : It illustrates a schematic representation of the fully assembled set and all the components and parts of the advanced intelligent complex multicomponent multisectoral printer, which operates based on the combination of two different printing mechanisms, including the dye-sublimation printing mechanism, preferably calendar, with the molecular printing mechanism, preferably nanolithography and the ability to print a range of photosensitive, tenebrescent, photo-induced fluorescent, and photo-induced phosphorescent compounds, molecules, and macromolecules with enhanced multiple printing capabilities, on a specific printing substrate composed of various types of paper, leather, wool, silk, polymer, fabric, and other types of textile and consisting of a set of devices and systems, including at least one technically upgraded molecular printer unit, at least a technically improved calendar sublimation machine unit, a set of intelligent mobile surface-mounted electromechanical systems, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally linked to different systems and parts, a set of fixed surface-mounted electromechanical systems, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form, a set of nano / micro inkjet nozzles and injection systems, with an improved design and with the ability to combine and inject a set of several molecular / macromolecular compounds and apply the nanolithography technique, a set of bobbins and electromotors, a set of substrates and thermal tanks, a set of printable sheets and layers, as well as sets of special drums, rollers, and cylinders, consisting of a range of photosensitive compounds, from the direct visual angle, in the direction of the x and z axes of the coordinate system and in the form of hidden lines visible. The scale of the drawn figures is 1 to 20 real scale and the dimensions shown are in centimeters.

[0309] : It demonstrates the schematics of all the comprising components and a fully assembled advanced intelligent combined multicomponent multisectoral printer, which functions based on the combination of two different printing mechanisms, including the dye-sublimation printing mechanism, preferably calendar, with the molecular printing mechanism, preferably nanolithography and the ability to print a range of photosensitive, tenebrescent, photo-induced fluorescent and photo-induced phosphorescent compounds, molecules and macromolecules with enhanced multiple printing capabilities, on various specific paper-based, leather-based, woolen, silk-based, polymeric, fabric-based, or any other textile-based printing substrates, and comprises a set of sections and systems, including at least one upgraded molecular printer system, at least one unit of upgraded calendar sublimation machine, a set of intelligent electromechanical systems movable on the surface, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally connected to various devices and systems, a set of surface-fixed electromechanical systems containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form, a set of nano / micro inkjet nozzles and injection systems, with an improved design and with the ability to combine and inject a set of several molecular / macromolecular compounds and to apply the nanolithography technique, a set of bobbins and electromotors, a set of substrates and thermal tanks, a set of printable sheets and layers, as well as multiple sets of technically renovated drums, rollers, and cylinders, made up of a range of photosensitive compounds, from different lateral perspectives, in line with the 3 dimensions of the coordinate system, in 2 isometric and dimetric shapes, and in the form of hidden lines visible. The scale of the drawn shapes is 1 to 32 real scale and the dimensions shown are in centimeters.

[0310] : It displays 2-dimensional schematics of all comprising components and the complete assembly of the technically advanced intelligent combined multicomponent multisectoral printer, which is based on the combination of two different printing mechanisms, including the dye-sublimation printing mechanism, preferably calendar, with the molecular printing mechanism, preferably nanolithography and the ability to print a range of photosensitive, tenebrescent, photo-induced fluorescent, and photo-induced phosphorescent compounds, molecules, and macromolecules with enhanced multiple printing capabilities on specific various paper-based, leather-based, woolen, silk-based, polymeric, fabric-based, and any other types of textile printing substrates, from the direct viewing angle, in the direction of the y and z axes of the coordinate system, it is visible in the form of hidden lines. The scale of the drawn shapes is 1 to 30 real scale and the dimensions shown are in centimeters.

[0311] : It depicts multiple schematic representations of all the components and the complete assembly of the upgraded intelligent combined multicomponent multisectoral printer, which operates based on the simultaneous alignment of two different printing mechanisms, including the dye-sublimation printing mechanism, preferably calendar, with the molecular printing mechanism, preferably nanolithography and the capability of printing a range of photosensitive, tenebrescent, photo-induced fluorescent and photo-induced phosphorescent compounds, molecules and macromolecules with enhanced multiple printing capabilities, on a specific printing substrate of different types of paper, leather, wool, silk, polymer, fabric and other types of textile, from various upper, lower, lateral and asymptotic visual angles, in line with the 3 axes of the coordinate system and in the form of hidden lines visible and hidden lines removed. The scale of the drawn shapes is 1 to 40 real scale and the dimensions shown are in centimeters.

[0312] : It Illustrates two 2D schematics of a section of the improved molecular printer system, as part of the improved intelligent complex multicomponent multisectoral printer, which consists of a set of intelligently movable surface-mounted electromechanical systems, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally linked to different systems and parts, a set of fixed surface-mounted electromechanical systems, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the ability to be digitally connected to various systems and devices, a set of nano / micro inkjet nozzles and injection systems, with an improved design and with the ability to combine and inject a set of several molecular / macromolecular compounds, based on the nanolithography technique and a railed transparent substrate, from the direct visual angles, in line with the x and z axes of the coordinate system, and in the forms of hidden lines visible and wireframed. The scale of the drawn shapes is 1 to 16 real scale and the dimensions shown are in centimeters.

[0313] : It shows two 2D schematics of a section of the improved molecular printer system, as part of the improved intelligent combined multicomponent multisectoral printer, which consists of a set of electromechanical systems movable on the surface, containing at least one enhanced laser radiation source and an optical sensor, fixed surface-mounted a set of electromechanical systems, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms are a set of nano / micro inkjet nozzles and injection systems, with an improved design based on nanolithography technique and at least one railed transparent substrate, from direct and frontal visual angles, in line with the axes x and z of the coordinate system, in both hidden lines visible and wireframed forms, and by focusing on representing a cross-section of the claimed railed transparent substrate, a cross-section of inkjet nano / micro nozzles and injection systems embedded on the designed railed transparent substrate as well as a section of drums and rollers equipped with mentioned electromechanical systems. The scale of the drawn shapes is 1 to 20 real scale and the dimensions shown are in centimeters.

[0314] : It represents several 2D schematics of the complete assembly and all the components of the body compartment of the claimed improved molecular printer system, as part of the improved intelligent combined multicomponent multisectoral printer, which consists of a set of nano / micro inkjet nozzles and injection systems, with improved design and the ability to combine and inject a set of several molecular / macromolecular compounds, based on the nanolithography technique, at least one railed transparent substrate for embedding a set of claimed nano / micro inkjet nozzles, and injection systems, and several mobile rollers and cylinders, which a set of mobile surface-mounted intelligent electromechanical systems, containing at least one enhanced laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally linked to various systems and devices, and a set of electromechanical systems fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form, can be embedded and installed on the external surface of these mobile rollers and cylinders, from different lateral visual angles, in line with sets of 2 x and z axes and 2 y and z axes of the coordinate system and in the forms of hidden lines visible and wireframed. The scale of the drawn figures is 1 to 20 real scale and the dimensions shown are in centimeters.

[0315] : It demonstrates 2 2D representations of the constituent parts and fully assembled assemblies of the body scaffold and compartment of the mechanical and electromotor systems of the claimed advanced molecular printer system, which is part of the upgraded intelligent combined multicomponent multisectoral printer and comprises a set of nano / micro inkjet nozzles and injection systems, with technically advanced design and the capability of mixing and injecting a set of several molecular / macromolecular compounds, based on the nanolithography technique, at least one railed transparent substrate for embedding the set of claimed nano / micro inkjet nozzles and injection systems, a set of drums and rollers with improved mechanical designs and equipped with rail sections and electric motors that create rotational movement and rotation and at least one specific type of printing substrate composing of various types of paper, leather, wool, silk, polymer, fabric, or any other types of textile, from 2 lateral points of view, along the x and z axes as well as y and z axes of the coordinate system, and in the form of hidden lines visible. The scale of the drawn figures is 1 to 20 real scale and the dimensions shown are in centimeters.

[0316] : It demonstrates several 3D schematic representations of the complete assembly and all the components of the multisectoral body compartment of the advanced molecular printer system, as part of the improved intelligent combined multicomponent multisectoral printer, which comprises a set of nano / micro inkjet nozzles and injection systems, with improved design and the ability to combine and inject a set of several molecular / macromolecular compounds, based on the nanolithography technique, at least one railed transparent substrate for embedding a set of the alleged nano / micro inkjet nozzles and injection systems, and several mobile rollers and cylinders, that a set of surface-movable advanced electromechanical systems, containing at least one enhanced laser radiation source and an optical sensor, and a set of surface-fixed electromechanical systems, containing electro-optic parts such as beam splitters, polarizers and dichroic mirrors / prisms, can be situated and embedded on the upper surface of these rollers and cylinders, from various lateral and asymptotic viewing angles, along the 3 axes of the coordinate system, in three isometric, dimetric, and trimetric shapes and in the form of hidden lines visible. The scale of the drawn shapes is 1 to 27 real scale and the dimensions shown are in centimeters.

[0317] : It depicts 3D schematics of the complete assembled set and all the components of the body and the placement of the mechanical and electromotor systems of the claimed advanced molecular printer system, which plays a role as a part of the intelligent combined multicomponent multisectoral printer and consists of a set of nano / micro inkjet nozzles and injection systems, with technically improved design and the ability to mix and inject a set of several molecular / macromolecular compounds, based on the nanolithography technique. at least one railed transparent substrate for embedding the alleged set of nano / micro inkjet nozzles and injection systems, a set of drums and rollers with improved mechanical designs and equipped with rail sections and electric motors that create rotational movement and rotation, and at least one paper-based, leather-based, woolen, silk-based, polymeric, fabric-based or any other textile-based printing substrate, from different lateral perspectives and points of view, along the 3 axes of the coordinate system, in both isometric and dimetric shapes and in the hidden lines visible form. The scale of the drawn shapes is 1 to 27 real scale and the dimensions shown are in centimeters.

[0318] : It shows multiple 3D schematics of the complete assembly of the body and the housing of the placement of the mechanical and electromotor systems of the claimed advanced molecular printer system, which is part of the intelligent combined multicomponent multisectoral printer and consists of a set of nano / micro inkjet nozzles and injection systems, with an improved design and by possessing the capability of mixing and injecting several molecular / macromolecular compounds' sets, based on the nanolithography technique, at least one railed transparent substrate for embedding the discussed set of nano / micro inkjet nozzles and injection systems, a set of drums and rollers with improved mechanical designs and equipped with rail sections and electric motors that create rotational movement and rotation and at least one specific type of printing substrate composing of various paper-based, leather-based, woolen, silk-based, polymeric, fabric-based and any other types of textile, from different lateral and asymptotic viewing angles, along the 3 axes of the coordinate system, shaped isometrically and in both hidden lines visible and wireframed forms. The scale of the drawn shapes is 1 to 32 real scale and the dimensions shown are in centimeters.

[0319] : It illustrates two 2D schematic representations of the body assembly and the placement of the electromotor systems and various units that make up the upgraded laser printer system, as a part of the upgraded intelligent combined multicomponent multisectoral printer which comprises a set of rollers equipped with a set of bobbins and electromotor systems including at least one developer roller unit, at least an electrostatic roller unit and a set of transfer rollers and pressure rollers, at least one toner / ink hopper unit, at least one assembled drum unit, at least one clearing unit connected to the assembled drum unit, and at least one fuser unit, from 2 visual angles, along the x and z axes of the coordinate system, and in the forms of hidden lines visible and wireframed. The scale of the drawn figures is 1 to 20 real scale and the dimensions shown are in centimeters.

[0320] : It represents the schematics of the body assembly and the placement of the electromotor systems and various units that make up the upgraded laser printer system, as part of the technically advanced intelligent complex multicomponent multisectoral printer, with a function based on 2 color printing mechanisms (inkjet printing), of a special subtype of laser printing, and a molecular printing mechanism, which consists of a set of rollers equipped with a set of bobbins and electromotor systems, at least one toner / ink hopper unit, at least one assembled unit of drum type, at least one cleaning unit (clearing unit) mechanically connected to the assembled unit of the drum type, and at least one fuser unit, from various front, top, lateral and asymptotic perspectives, in line with the 3 axes of the coordinate system, in isometric shapes and in 2 different forms of hidden lines visible and hidden lines removed. The scale of the drawn shapes is 1 to 30 real scale and the dimensions shown are in centimeters.

[0321] : It illustrates a general schematic representation of a 2D schematic representation of the complete assembled set and all components, parts, and systems that make up the upgraded laser printer system, as part of the upgraded intelligent combined multicomponent multisectoral printer, with a function based on 2 color printing mechanisms (inkjet printing), specifically the laser printing, and molecular printing mechanism, which consists of a set of electromechanical systems fixed on the surface, containing at least one upgraded laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be linked to different systems and parts, in digital form, a set of electromechanical systems fixed on the surface, containing electro-optic parts such as beam splitters, polarizers and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form, a set of rollers equipped with a set of bobbins and electromotor systems including at least one developer roller unit, at least one electrostatic roller unit, at least a set of transfer rollers and pressure rollers, at least one toner / ink hopper unit, at least one assembled unit of drum type, at least one cleaning unit (clearing unit) connected to the assembled unit of drum type and at least one fuser unit, from the direct viewing angle, in the direction of y and z axes of the coordinate system and in the form of hidden lines visible. The scale of the drawn shapes is 1 to 12 real scale and the dimensions shown are in centimeters.

[0322] : It shows the 2D schematics of the complete assembled set and all the components, parts, and systems that creates the advanced laser printer system, as a section of the claimed technically advanced intelligent combined multicomponent multisectoral printer, with an operation based on 2 color printing mechanisms (inkjet printing), of a special type of laser printing, and molecular printing mechanism, which comprises a set of fixed surface-mounted electromechanical systems, containing at least one upgraded laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally connected to different systems and devices, a set of electromechanical systems fixed on the surface, containing electro-optic parts such as beam splitters, polarizers and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form, a set of rollers equipped with a set of bobbins and electromotive systems including at least one developer roller unit, at least one electrostatic roller unit as well as a set of transfer rollers and pressure rollers, at least one toner / ink hopper unit, at least one assembled drum type unit, at least one cleaning unit (clearing unit) is connected to the assembled part of the drum-type unit and at least one fuser unit, from the front and side viewing angles, along the x and z axes of the coordinate system and in the form of hidden lines visible. The scale of the drawn shapes is 1 to 22 real scale and the dimensions shown are in centimeters.

[0323] It depicts several 2D schematics of the complete assembled set and all the constituents, components, parts and systems that make up the technically enhanced laser printer system, as a part of the considered technically improved intelligent combined multicomponent multisectoral printer, with a function based on 2 color printing mechanisms (inkjet printing), of a special type of laser printing, and molecular printing mechanism, which consists of a set of electromechanical systems fixed on the surface, containing at least one upgraded laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be digitally connected to various systems and devices, a set of surface-fixed electromechanical systems, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form, a set of rollers equipped with a set of bobbins and electromotive systems, at least one toner / ink hopper unit, at least one assembled drum type unit, at least one cleaning unit (clearing unit) which is mechanically connected to the assembled part of the drum-type unit and at least one fuser unit, from different angles and lateral perspectives , along the 2 x and z axes of the coordinate system and in 2 different forms; the hidden lines visible and the hidden lines removed. The scale of the drawn shapes is 1 to 16 real scale and the dimensions shown are in centimeters.

[0324] : It represents several 3D schematic representations of all the components, parts and constituent systems and the complete assembly of the upgraded laser printer system, as a part of the upgraded intelligent combined multicomponent multisectoral printer, with a function based on 2 color printing mechanisms (inkjet printing), of a special type of laser printing, and molecular printing mechanism, which consists of a set of electromechanical systems fixed on the surface, containing at least one upgraded laser radiation source and an optical sensor, with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the ability to be linked to different systems and devices, in digital form, a set of electromechanical systems fixed on the surface, containing electro-optic parts such as beam splitters, polarizers and dichroic mirrors / prisms and with the ability to be linked to different systems and parts, in digital form, a set of rollers equipped with a set of bobbins and electromotor systems including at least one Developer roller unit, at least one Electrostatic roller unit and a set of Transfer rollers and Pressure rollers, at least one toner / ink hopper unit, at least one assembled drum unit, at least one clearing unit connected to the assembled drum unit, and at least one fuser unit, from different lateral and asymptotic viewing angles, in line with the 3 axes of the coordinate system, and in isometric and dimetric shapes, and in 2 different hidden lines visible and hidden lines removed. The scale of the drawn shapes is 1 to 34 real scale and the dimensions shown are in centimeters.

[0325] : It demonstrates a 2D schematic representation of all the constituents and components and the complete assembled assembly of an advanced offset printing or flexographic printing system, as part of an advanced intelligent combined multicomponent multisectoral printer, with a combined function based on 2 toner / ink-based roll-to-roll / rotary printing mechanisms, from the preferred types of flexography or offset printing and molecular printing mechanism, which consists of a set of rollers and cylinders including a set of ink / toner rollers, a set of wetting out rollers, pressure cylinders, at least one unit of plate cylinders, at least one unit of blanket (offset) cylinder and a set of guide rollers, where it is possible to place units of Anilox roller and Doctor blade if flexographic printing technique is used instead of offset printing technique, along with a set of color placement units and substrates (ink / toner fountain / tray) and a set of units and substrates for solvent placement (wetting out / solvent fountain / tray), in addition to at least one specific type of printing substrate of different types of paper, leather, wool, silk, polymer, fabric or any other types of textile, from the frontal viewing angle, in line with the y and z axes of the coordinate system and in a wireframed form. The scale of the drawn shapes is 1 to 8 real scale and the dimensions shown are in centimeters.

[0326] : It illustrates the schematics of all the parts and components and the complete assembly of an advanced offset printing or flexographic printing system, as a part of the intelligent combined multicomponent multisectoral printer, with a combined operation based on 2 toner / ink-based roll-to-roll / rotary printing mechanisms, from the preferred types of flexography or offset printing and molecular printing mechanism, which consists of a set of rollers and cylinders including a set of ink / toner rollers, a set of wetting out rollers, pressure cylinders, at least one unit of plate cylinders, at least one unit of blanket (offset) cylinder and a set of guide rollers that can accommodate units of Anilox roller and Doctor blade if flexographic printing technique is used instead of offset printing technique, along with a set of color placement units and substrates (ink / toner fountain / tray) and a set of solvent placement units and substrates (wetting out / solvent fountain / tray), in addition to at least one specific type of printing substrate, which can be composed of different types of paper, leather, wool, silk, polymer, fabric, or any other types of textile, from different viewing angles from the front and lateral perspectives, along the y and z axes of the coordinate system and in the form of hidden lines. The scale of the drawn shapes is 1 to 14 real scale and the dimensions shown are in centimeters.

[0327] : It shows schematics of all the parts and components and the complete assembly of an advanced offset or flexographic printing system, as a section of the technically improved intelligent combined multicomponent multisectoral printer with a combined function based on 2 toner / ink-based roll-to-roll / rotary printing mechanisms, from the preferred types of flexography or offset printing and molecular printing mechanism, which consists of a set of rollers and cylinders, including a set of ink / toner rollers, a set of wetting out rollers, of pressure cylinders, at least one unit of plate cylinders, at least one unit of a blanket (offset) cylinder and a set of guide rollers that allow the placement of units Anilox roller and Doctor blade are also available if flexographic printing technique is used instead of offset printing technique, along with a set of color placement units and substrates (ink / toner fountain / tray) and a set of solvent placement units and substrates (wetting out / solvent fountain / tray), along with at least one specific type of printing substrate, from different lateral and asymptotic points of view, along the 3 axes of the coordinate system, in an isometric shape and in 2 different hidden lines visible and wireframed forms. The scale of the drawn shapes is 1 to 22 real scale and the dimensions shown are in centimeters.

[0328] : It illustrates 3D schematic representations of all the constituents and the fully assembled advanced offset printing or flexographic printing system, as a part of the technically innovative intelligent combined multicomponent multisectoral printer with a combined function based on 2 toner / ink-based roll-to-roll / rotary printing mechanisms, from the preferred types of flexography or offset printing and molecular printing mechanism, which consists of a set of rollers and cylinders including a set of ink / toner rollers, a set of wetting out rollers, pressure cylinders, at least one unit of plate cylinders, at least one unit of blanket (offset) cylinder, and a set of guide rollers, along with a set of color placement units and substrates (ink / toner fountain / tray) and a set of solvent placement units and substrates (wetting out / solvent fountain / tray), in addition to at least one specific type of printing substrate, with different types of paper, leather, wool, silk, polymer, fabric, and any other types of textiles, from different viewing angles, upper, lower, side, and asymptotic, in line with the 3 axes of the coordinate system, in both isometric and dimetric shapes, and in both hidden lines visible and hidden lines removed forms. The scale of the drawn shapes is 1 to 30 real scale and the dimensions shown are in centimeters.

[0329] : It depicts 3 various representations of the 3D schematic of the fully assembled set and all the constituents and components of an improved offset printing or flexographic printing system, as part of the upgraded intelligent combined multicomponent multisectoral printer, with a combined function based on 2 toner / ink-based roll-to-roll / rotary printing mechanisms, from the preferred types of flexography or offset printing and molecular printing mechanism, which comprises a set of rollers and cylinders, including a set of ink / toner rollers, a set of wetting out rollers, of pressure cylinders, at least one unit of plate cylinders, at least one unit of blanket (offset) cylinder and a set of guide rollers that allow the placement of units Anilox roller and Doctor blade are also available if flexographic printing technique is used instead of offset printing technique, along with a set of color placement units and substrates (ink / toner fountain / tray) and a set of solvent placement units and substrates (wetting out / solvent fountain / tray), in addition to at least one specific type of printing substrate, with different paper-based, leather-based, woolen, silk-based, polymeric and fabric-based type, or any other types of textiles, from various lateral visual angles, in line with the 3 axes of the coordinate system, in various isometric, dimetric, and trimetric shapes, and in both forms of hidden lines visible and wireframed. The scale of the drawn shapes is 1 to 20 real scale and the dimensions shown are in centimeters.

[0330] : It displays a schematic representation of the complete assembled assembly and all the various components, devices, and sections that make up an improved calendar dye-sublimation printer system, as a part of the technically enhanced intelligent complex multicomponent multisectoral printer with a combined function based on 2 different printing mechanisms including dye-sublimation printing mechanism, of the preferred calendar type and molecular printing mechanism, which includes a set of rollers, drums, and cylinders equipped with a set of bobbins and electromotor systems, including a set of units and rollers which supplying various polymeric, fabric, and paper-based substrates (Feeder), a set of collector roller / cylinders or rewind roller / cylinders and a set of intermediate cylinders, along with at least one thermal unit including a drum and a thermal head, at least one conveyor unit and a set of at least 3 different types of printing substrate inputs, at least one layer of tissue paper and at least one layer of fabric, in addition to the main printing substrate, which composed of various paper-based, woolen, silk-based, polymeric, and any other compatible types of textiles, from the direct viewing angle, in line with the 2 x and z axes of the coordinate system and in a wireframed form. The scale of the drawn shapes is 1 to 10 real scale and the dimensions shown are in centimeters.

[0331] : It depicts two 2D schematics of the complete assembled assembly and all the various parts, pieces, and parts that make up an upgraded calendar dye-sublimation printer system, as a part of the technically upgraded intelligent complex multicomponent multisectoral printers with a combined function based on 2 different printing mechanisms including the dye-sublimation printing mechanism, of the preferred calendar type and molecular printing mechanism, which comprises a set of rollers, drums, and cylinders equipped with a set of bobbins and electromotor systems, including a set of various polymeric, fabric, and paper-based substrates supplying units and rollers (Feeder), a set of collector roller / cylinders or rewind roller / cylinders and a set of intermediate cylinders, along with at least one thermal unit including a drum and a thermal head, at least one conveyor unit, and a set of at least 3 different types of printing substrate inputs, at least one layer of tissue paper and at least one layer of fabric, in addition to the main printing substrate of paper, wool, silk, polymer, and any other compatible types of textiles, from direct and frontal visual angles, along the x and z axes ...

Claims

The design and implementation of an advanced multicomponent multisectoral printer, which consists of a set of units, devices, and operating systems, along with a set of mechanical and electromechanical parts and equipment, has been claimed, with the possession of multitasking characteristics and multiple hybrid 2D-3D printing mechanisms. The set of claimed devices and operating systems consists of units as follows:- At least one unit of 2D printing device and system with changed and improved technical design- At least one unit of 3D printing device and system, with the ability to execute and implement at least one molecular printing technique.Furthermore, the claimed intelligent combined multicomponent multisectoral printer consists of a set of mechanical and electromechanical parts and equipment as follows:- A set of rollers, cylinders, and drums embedded in different points, sections, and compartments of the claimed combined multicomponent multisectoral printer device, with various structural and technical roles and functions.- A collection of nano / micro syringes, nano / micronozzles, and complex multicomponent molecular injection systems- A set of mobile plates and substrates- A set of several different types of mobile or fixed surface-mounted electromechanical systems, containing a set of technical capabilities and capabilities and capable of performing several different functions and operational roles.According to claim 1, the first component of the designed intelligent combined multicomponent multisectoral printer is related to the use of at least one unit of the 2D printing device and system with a modified and improved technical design, which possesses the ability to implement and execute several 2D printing techniques based on at least one mechanism from a preferable triple set of 2D printing mechanisms that can be used in this invention, including heat transfer printing, planographic printing and digital printing.According to claim 2, the preferred printing devices or units that are considered to be utilized for the implementation of the 2D printing technique in this invention, are focused into 3 different printing systems, which comprise an technically upgraded laser printer system, an upgraded calendar dye-sublimation printing machine, and a special toner / ink-based roll-to-roll / rotary printing mechanism-based offset printer.Claim 4) According to claim 3, the claimed advanced laser printer system consists of a set of parts, equipment, and special systems as follows:- A set of rollers equipped with a set of bobbins and electromotor systems- At least one unit of the complex advanced electromechanical combined systemAccording to claim 4, the set of rollers equipped with a set of claimed bobbins and electromotor systems, comprises at least one Developer roller unit, at least one Electrostatic roller unit, and a set of Transfer rollers and Pressure rollers, at least one toner / ink hopper unit, at least one assembled photoreceptor drum unit, at least one clearing unit connected to the assembled photoreceptor drum unit, at least one fuser unit, and at least one corona wire unit.According to claim 4, the claimed hybrid advanced electromechanical system complex is composed of 2 different types of electromechanical systems, and possesses a combined hybrid function based on aligning and synchronizing the function of these two claimed types of special electromechanical systems, which comprises at least one unit of the surface-fixed electromechanical system, containing at least one enhanced laser radiation source and an optical sensor with multiple capabilities in inducing and creating different electronic-molecular excitations, along with the capability of being linked digitally to certain systems or devices, with at least one fixated surface-mounted unit of the electromechanical system, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms, that can be digitally linked to various systems and electromechanical components positioned in different areas of the alleged printing device.According to claims 4 and 6, following the subsequent utilization of the claimed advanced electro-mechanical system complex, in addition to establishing an improved technical capability in producing, transmitting, and irradiating various specific frequency and wavelength spectra of polarized laser electromagnetic waves, the ability to link and continuously transmit digital information, among the comprising sets and units of these two separate electromechanical systems that constituting the claimed combined electromechanical system, has been provided in an encrypted and targeted manner, by relying on the physical mechanism of interferometry and in the form of laser telecommunication.Claim 8) According to claim 3, the claimed improved calendar dye-sublimation printing machine consists of a set of specific parts, equipment and systems as follows:- A set of rollers, drums and cylinders equipped with a set of bobbins and electromotor systems- At least 3 inputs and 3 outputs of the printed substrate with different materials and structural typesAccording to claim 8, the claimed set of rollers, drums, and cylinders equipped with a set of bobbins and electromotor systems, comprises at least a set of units and rollers supplying different polymeric, fabric, and paper substrates (Feeder), at least a set of collector roller / cylinders or rewind roller / cylinders, and at least a set of intermediate cylinders, at least one thermal unit including a drum and a thermal head and at least one conveyor unit.According to claim 8, the part related to at least 3 inputs and 3 outputs of the printed substrate with a different material and structural type claimed, includes at least one layer of tissue paper and at least one layer of fabric, next to the main printing substrate of different types of paper, wool, silk, polymer or any other specific compatible textile.According to claim 10, each of the claimed 3 inputs and 3 outputs, coupled and through a set of transmission levels, comprising at least one open transferring pathway for transferring fabric-based printable substrates and pieces, at least one closed transferring pathway for transferring tissue paper-based substrates and layers and at least one open transferring pathway for transferring the original printed substrate and for transferring paper-based printable substrates, are mutually connected, which have facilitated the possibility of transferring the used printing substrates within the utilized compartments and different printing paths.According to claim 9, the claimed thermal unit, which consists of at least one drum, at least one thermal head, and at least one conveyor unit, is applied in the manner and design of an oil drum equipped with a set of bobbins and electromotive systems for the purpose of evaporating and stabilizing heat-sensitive colors, and it is used to rotate the oil drum unit and homogenize the heating process. Furthermore, in addition to utilizing an oil drum equipped with a set of bobbins and electromotoric systems, a set of rollers, drums, and cylinders that are each independently equipped with a set of bobbins and electromotoric systems have been used.It can be claimed that in the claimed invention, a specific molecular approach has been used in the engineering, design, and composition of alternative fluid and solvent systems to modify the existing intermolecular interactions between dye colors used with conventional water-based single-component or multicomponent solvent systems.According to claims 8 and 13, this claimed specific molecular approach has been used in the engineering, design, and composition of the alternative fluid and solvent system in the claimed advanced dye-sublimation calendar printing device.According to claim 14, the specific molecular approach claimed in the design of the composition of the engineered alternative fluid and solvent system relies on the application of a specific range of compounds and chemical derivatives, with a perfluorocarbon or perfluorochemical base, which in this method, an engineered fluid and solvent system based on two various approaches has been used.According to claim 15, in the first approach considered in the design and implementation of the composition of the engineered alternative fluid and solvent system, exclusively a solution based on perfluorocarbons and only consisting of mixing at least two different perfluorocarbon derivatives, at least one compound with a preferred weight range between 150 and 250 daltons, and at least one compound with a preferred weight range between 250 and 400 daltons has been used. Moreover, in the second approach considered for the design and implementation of the composition of the claimed engineered alternative fluid and solvent system, in addition to the use of perfluorocarbons or perfluorochemicals, other polar solvents will be used, preferably over non-protonated solvents such as etheric compounds, e.g. THF, which perfluorinated compounds will compose the major proportion of the claimed utilized engineered fluid.According to claim 16, following the application of the claimed engineered fluid and solvent system, the operating temperature range of the device and the dye sublimation calendar printing system implemented in this claimed invention, will be determined according to the type of approach adopted in the design and engineering of the constituent components of the fluid and solvent system. It is worth mentioning that in the circumstances where the first approach, which is based on the use of perfluorocarbons and perfluorochemical derivatives, is used for the preparation and engineering of the claimed replacement fluid and solvent system, the operating temperature range of the claimed system and printing device is in the optimal operating temperature range between 70 and 125 degrees Celsius and in the case of applying the second approach, which relies on utilizing a set of several types of solvents, with various physicochemical properties and consists of at least one perfluorinated solvent with at least one other protonated or non-protonated polar solvent. The temperature range of the utilized dye sublimation printing process will be in the operating range of 140 to 180 degrees Celsius optimally.According to claim 15, applicable perfluorinated compounds and perfluorochemicals for designed the engineered fluid system and the claimed alternative solvent, includes a series of lightweight perfluorocarbons with preference over liquid compounds perfluoro (3-pentanone), perfluoro(2-methyl-3-pentanone), perfluoro(2,4-dimethyl-3-pentanone), perfluoro(methyl cyclohexanone), perfluoro (dimethyl cyclohexanone) and perfluoro(2,4-dimethyl cyclopentanone) and a series of heavy-weight perfluorocarbon derivatives consisting of compounds such as 1,1,1,2,2,4,4,5,5,5-decafluoropentan-3-one, 1,1,1,2,4,5,5,5-octafluoro-2,4-bis(trifluoromethyl)pentan-3-one, 1,1,1,2,2,6,6,7,7,7-decafluoro-4,4-bis(trifluoromethyl)heptane- 3,5-dione, 2,3,5,6-tetrafluoro-2,3,5,6-tetrakis(trifluoromethyl)cyclohexane-1,4-dione, 2,3,3,5,5,6-hexafluoro-2,4,4,6-tetrakis(trifluoromethyl)cyclohexan-1-one, 4,5-difluoro-2,2-bis(perfluoroethyl)-4,5-bis(trifluoromethyl)-1,3-dioxolane, 2,3,4,5-tetrafluoro-2,3,4,5-tetrakis(trifluoromethyl)cyclopentan-1-one, 2,3,6,9,10,12,14-heptafluoro-2,3,6,9,10,12,14-heptakis(trifluoromethyl)-1,4,8,11-tetraoxadispiro[4.1.47.35]tetradecan-13-one and 1,3,4,5,6,7,8,9-octafluoro-1,3,4,5,6,7,8,9-octakis(trifluoromethyl)-1,3,4,5,6,7,8,9-octahydro-2H-cyclopenta[e]-as-indacen-2-one and includes a wide range of diverse perfluorochemicals and perfluorocarbon derivatives, based on 1,3,4,5,6,7-hexafluoro-1,3-bis(trifluoromethyl)-1,3-dihydro-2H-inden-2-one, 1,1,1,5,5,5-hexafluoropentan-3-one, 1,1,1,2,7-pentafluoro-4,4-bis(trifluoromethyl)heptane-3,5-dione, 2,3,5,6-tetrakis(trifluoromethyl)cyclohexane-1,4-dione, 2,4,4,6-tetrakis(trifluoromethyl)cyclohexan-1-one, 2,2-bis(perfluoroethyl)-4,5-bis(trifluoromethyl)-1,3-dioxolane, 2,5-bis(trifluoromethyl)cyclopentan-1-one, 2,14-bis(trifluoromethyl)-1,4,8,11-tetraoxadispiro[4.1.47.35]tetradecan-13-one, 1,9-bis(trifluoromethyl)-1,3,4,5,6,7,8,9-octahydro-2H-cyclopenta[e]-as-indacen-2-one and 1,3-bis( trifluoromethyl)-1,3-dihydro-2H-inden-2-one structures.According to claim 3, the claimed advanced laser printer system consists of a set of parts, equipment and special systems as follows:- A collection of different rollers and cylinders- A set of platforms and holding units- At least one transfer path for various structural types of specific printing substrates and surfaces, including different types of paper-based, leather-based, woolen, silk-based, polymeric, fabric and any other special structural type of different textile types.According to claim 19, the set of claimed rollers and cylinders, includes a set of ink / toner rollers, a set of wetting out rollers, a set of pressure cylinders, at least one unit of plate cylinders, at least one unit of blanket (offset) cylinder, and a set of guide rollers. Furthermore, it is possible to place units of an Anilox roller type roller and a special type of Doctor blade type in the case of using the flexographic printing technique, as an alternative to the offset printing technique used.According to claim 19, the collection of substrates and holding units claimed, comprises a set of color placement units and substrates (ink / toner fountain / tray) and a set of solvent placement units and substrates (wetting out / solvent fountain / tray).According to claim 1, the second constituent element of the designed intelligent combined multicomponent multisectoral printer is the improved molecular printer system, which plays a role as a representative of the unit related to the 3D printing device and system and with the ability to execute and implement at least one molecular printing technique.According to claim 22, the improved molecular printer system is equipped with a set of parts, equipment, and various mechanical and electromechanical systems as follows:- A set of rollers, cylinders and drums- A set of 2 screens and a moving platform, with a special and improved design- A set of nano / micronozzles and complex multi-component molecular injection systems- A set of two different types of electromechanical systemsAccording to claim 23, the set of 2 claimed movable plates and substrates, with a special and improved design, includes a plate and a metal / polymer movable bed of the type of compressed polymer structures, which is embedded in the upper area and is the place for placing and embedding various paper, wool, silk, polymer, fabric, fabric, and other types of textile printing substrates, along with a special transparent rail-embedded plate and substrate, which is installed in the lower area and in line with the referred mobile plate and substrate embedded in the upper level, and is equipped with dozens of different units of nano / micronozzles and alleged complex multicomponent molecular injection systems.According to claim 24, the set of two types of claimed electromechanical systems, consists of a type of intelligent electromechanical system movable on the surface, containing at least one upgraded laser radiation source and an optical sensor, and an electromechanical system fixed on the surface, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms.According to claim 25, the mobile surface-mounted smart electromechanical system, containing at least one enhanced laser radiation source and a claimed optical sensor, consists of a set of electronic and electromechanical components and systems, which has provided the linkability of this electromechanical system to other electromechanical systems and parts, in a digital form and of the type of the laser telecommunication, which is based on the radiation of polarized laser electromagnetic waves, in the encrypted and decrypted information transmission manner.According to claim 26, this mobile surface-mounted intelligent electromechanical system, contains a special planetary gearbox with an improved design and consists of at least 3 planetary gears, at least one epicyclic gear, and one ring gear, which has enabled the necessary conditions to apply horizontal and vertical angular rotation, respectively with an effective range in a range of 180 degrees and a range of 60 degrees.According to claim 26, this mobile surface-mounted intelligent electromechanical system contains a special planetary gearbox with an improved design and consists of at least 3 planetary gears, at least one epicyclic gear, and one ring gear, which has enabled the necessary conditions to apply horizontal and vertical angular rotation, respectively with an effective range in a range of 180 degrees and a range of 60 degrees.According to claim 28, by using the laser beam emitting unit, the necessary conditions for radiating a certain frequency spectrum of polarized laser electromagnetic waves have been provided. In fact, with the presence of this part and the laser beam emitting unit, the necessary conditions for exposing the plate and the metal / polymer mobile substrate of the type of compact polymer structures have been used, which is the place of placement and embedding of various textile-based printing substrates, which is provided with a specific frequency and wavelength spectrum of polarized laser electromagnetic waves.According to claims 25, 26, and 27, the alleged surface-fixed electromechanical system, containing electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms, composed of a set of electronic and electromechanical parts and systems, which has provided the capability of digitally link this electromechanical system to other electromechanical systems and parts, mutually and in the laser telecommunication type, which relies on the radiation of polarized laser electromagnetic waves and in the form of encrypted and decrypted information transmission. Moreover, similar to the approach used in the design of the central part and the main and operational compartment of the advanced mobile surface-mounted electromechanical system, comprising at least one laser-enhanced radiation source and a claimed optical sensor, in the central section of the claimed implemented surface-fixed electromechanical system, which contains a set of electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms, a special planetary gearbox is used, which consists of at least 3 planetary gears, at least one epicyclic gear, a ring gear, and a quasi-spherical movable base is embedded, with the aim of establishing a range of 180 degrees in the effective range of horizontal angular rotation and a range of 60 degrees in the effective range of vertical angular rotation, relative to the axis perpendicular to the surface of the claimed quasi-spherical movable base.According to claims 23 and 31, in the referred fixed surface-mounted electromechanical system, consisting electro-optic parts such as beam splitters, polarizers, and dichroic mirrors / prisms, the type of this utilized electro-optical element in the claimed advanced molecular printer system is preferably polyhedral and often in the shape of hexagons, heptagons and tetrahedrons, and the existence of different side faces, flat top, and small top, has made it possible to cause refraction and deviation in the laser light beams and rays radiated from polarized laser electromagnetic waves in a purposeful and targeted manner, which has facilitated the process of radiation with a adjusted and regulated intensity, in a coverage range of 120 degrees and in line with the 2 alleged movable plates and substrates.It can be claimed that in this claimed invention, a set of molecular and macromolecular chemical compounds and derivatives such as organometallic compounds, molecular machines, various polymeric and copolymeric structures, nanoclusters, and nanostructures, in addition to nano / micro crystalline and semicrystalline structural forms, which have inherent chromism-related properties and effects, preferably the Adsorchromism, Mechanochromism, Thermochromism, Vapochromism, Photochromism, Electrochromism, Piezochromism and the Solvatochromism effect, has been used to implement and carry out the molecular 3D printing process.It can be claimed that in the claimed invention, the necessary technical conditions for benefiting from a variety of external stimuli, with a preference for enabling the use of 4 basic external stimuli, including a laser stimulus, based on the irradiation of a specific frequency spectrum of light photons and polarized laser electromagnetic wave beams, an electrical stimulus that relies on the application of electrical pulses, a temperature stimulus that relies on the application of thermal pulses, and also a mechanical stress stimulus, which is based on the application of mechanical and pressure stimuli and has the ability to impose and induce targeted molecular vibrations based on the piezoelectric effect, is providedAccording to claim 33, the possibility of inducing and carrying out a set of reversible or irreversible chemical processes and reactions, based on various molecular mechanisms and processes, e.g. altering and manipulating the oxidation number, applying a wide spectrum of chemical isomerization reactions, applying various molecular switches and inducing wide controlled changes and manipulations in the configuration patterns of the utilized compounds, has become provided.According to claims 23, 24, and 32, the process of implementing the molecular 3D printing process on different printing surfaces and substrates, is conducted with the help of injecting a specific volume range of clear, colloidal, fluidic, or suspension solutions containing these chemical compounds and claimed molecular and macromolecular compounds, which have claimed inherent properties and effects including Adsorchromism, Mechanochromism, Thermochromism, Vapochromism, Photochromism, Electrochromism, Piezochromism or Solvatochromism, and n the general preferred range of 0.1 to 2.5 microliters and with the help of a set of nano / micro syringes and nano / micronozzles of the multicomponent molecular injection system designed and embedded on the surface of the claimed transparent railed-equipped substrate and plate.According to claims 32 and 33, to implement the molecular 3D printing process, based on the Adsorchromism effect, a set of different molecular approaches have been used as preferred compounds that can be used in the claimed Adsorchromism based techniques and mechanisms, these discussed molecular approaches have the ability to be initiated and activated with the help of all 4 types of external stimuli claimed, which will be in line with the use of a set of specific chemical processes and trends for the production and synthesis of complex macromolecular compounds and based on the molecular mechanisms of protonation, electronic interaction, intramolecular structural changes, and intramolecular and intermolecular conformational alterations.According to claim 36, the first claimed molecular approach and chemical process, based on the Adsorchromism effect, relies on the process of using stable salts of a part of transition elements or metals of the first row, as well as the first 4 elements of alkaline and alkaline earth metals' group of the periodic table, as the centers and nuclei of coordination compounds, and a wide range of ligands and macromolecular compounds, in this mentioned process, a set of ligands and macromolecular compounds that have the ability to be affected by external factors and stimuli, to induce a specific alteration or a series of molecular alterations, in the type of one structural isomer to another type of structural isomer, or to impose a change in a specific type of configuration of a structural isomer, to a specific type of a specific configuration or spatial configuration, has been used. In this process, a set of chemical and structural changes that are done in a reversible manner is considered, and the molecular intercalation mechanism is used as a subset of this alleged molecular process.According to claim 36, the second claimed molecular approach and chemical process, based on the Adsorchromism effect, relies on a series of chemical processes, which includes the use of a wide range of stable salts belonging to a series of transition metals or elements of the first row and the first 4 elements of alkaline and alkaline earth metals’ group, as the centers and nuclei for the formation of coordination compounds, and a wide range of ligands and macromolecular compounds. In this mentioned process, a set of ligands and macromolecular compounds have been applied, that possess the ability to be affected by external factors and stimuli, in order to impose an alteration or a set of alterations, in the type of one structural isomer to another type of structural isomer, or to induce a change in a specific type of configuration of a structural isomer, to a specific type of a specific configuration or spatial configuration. In this process, the set of chemical and structural changes performed on each ligand or macromolecular structural isomer is considered reversible.According to claim 36, a third claimed molecular approach and chemical process, based on the Adsorchromism effect, is based on the application of a variety of semi-stable or unstable metal salts belonging to the 3 periods of the 4th, 5th, and 6th transition metals of the periodic table and especially, the metals belonging to groups 5 to 9 of the transition elements, as the centers and cores of coordination compounds, along with a wide range of specific macromolecular ligands or compounds. In this process, metals that have multiple oxidation numbers and exhibit high oxidation properties have been used, and regarding this high oxidation property, the possibility of establishing an oxidation process on organic chemical derivatives and macromolecular compounds used as ligands, in the way of forming coordination compounds based on various charge transfer mechanisms, e.g. ligand to metal charge transfer (LMCT), metal to ligand charge transfer (MLCT) and metal to metal charge transfer (MMCT), has been provided. In this process, the set of chemical and structural changes performed on each ligand or macromolecular structural isomer is considered irreversible.According to claim 36, a fourth claimed molecular approach and chemical process, based on the Adsorchromism effect, relates to the use of a diverse and wide range of a set of several types of macromolecules, with various dimensions, surface-charge density, and electrostatic and electrochemical properties. In this process and method, a certain macromolecule, with a significant molecular size and containing a variety of chemical substitutions and different functional groups, which causes dispersion in the surface charge density distribution, in the chains and different substitutes of that claimed macromolecule, has been utilized as the central part of the process. Furthermore, a set of macromolecules and other chemical derivatives, which have smaller molecular dimensions, and smaller molecular and solvated radii, have been used as side chains and possess the capability of establishing various intramolecular and intermolecular interactions with other chains, chemical substitutions, and functional groups in the central macromolecule. In this process, the set of chemical and structural changes performed on each macromolecular structural isomer is considered reversible.According to claim 36, the fifth claimed molecular approach and chemical process, based on the Adsorchromism effect, is based on the use of a diverse and wide range of a set of several different types of macromolecules, with different dimensions, surface charge density, and electrostatic and electrochemical properties. In this process and method, a specific macromolecule, with a significant molecular size range and containing a variety of chemical substitutions and various functional groups leads to a dispersion in the surface charge density distribution, in the chains and various points of the claimed macromolecule, has been used as the central part of the process. Moreover, a set of macromolecules and other chemical derivatives, which have smaller molecular dimensions and low-level molecular solvated radii, have been applied as groups and side chains and with the ability to create various intramolecular and intermolecular interactions with chains, chemical substitutions, and functional groups in the central macromolecule. In this process, the set of chemical and structural changes performed on each macromolecular structural isomer is considered irreversible.According to claim 36, the sixth claimed molecular approach and chemical process, based on the Adsorchromism effect, relies on the general technique of molecular imprinting, in which macromolecular derivatives, such as organic polymer derivatives, with thixotropic and viscoelastic preferred physicochemical properties are utilized. This process is based on the creation and formation of template-based cavities in the polymer matrix and using diverse synthetic techniques for the synthesis of crosslinked copolymeric derivatives, including both free-radical polymerization and sol-gel polymerization's synthetic techniques, as preferred synthetic mechanisms and by biological species and macromolecules, with enzymatic properties, in which due to the nature of the process, the created holes and positions are formed in a predetermined manner with very high selectivity and affinity. In this process, the set of chemical and structural changes performed on each macromolecular and polymer structural isomer will be possible in both reversible and irreversible manners.According to claim 36, the seventh claimed molecular approach and chemical process, based on the Adsorchromism effect, relies on the utilization of the enzymatic degradation procedure or any destructive chemical reaction, based on a chemical and biochemical component or structure with enzymatic properties, along with a set of derivatives and different chemical compounds, of all molecular and macromolecular types and with monomeric, dimeric, oligomeric and polymeric chemical and structural sequences, which contain at least one chain or substitution sensitive to enzyme function.According to claim 32, the implementation of the molecular 3D printing process, based on the electrochromism effect, is based on using and performing at least one chemical reaction, of the type of oxidation and reduction, in a reversible manner, which is subsequently performed by using an inherent potential difference, one or a set of several oxidation and reduction reactions and with the possibility of the electric current exchange process between the oxidizing species / species and the reducing species / species present in the reaction, it imposes various alterations in the state of the molecular electron levels and the distribution of electrons in the molecular orbitals of the used species, and with a switch in electron absorption and emission levels, it will be followed by a shift inexcitations.According to claims 32 and 33, the implementation of the molecular 3D printing process, based on the photochromism effect, consisting of a set of molecular approaches and different chemical processes relying on using and carrying out at least one chemical reaction or transformation process between two or a set of several stereoisomers or structural isomers and by external laser agent and based on the general mechanism of photo-irritation, and the inherent property and effect of the alleged photochromism is based on a set of techniques and molecular mechanisms such as photo-induced proton transfer, trans-cis photoisomerization, homolytic cleavage and photocyclization.According to claim 45, the first claimed molecular approach and chemical process, based on the photochromism effect, relies on the use of a set of organic macromolecular compounds, which have a range of substitutions and chemical chains containing a set of conjugated double bonds, that the claimed photochromism process is performed with the help of a polarized electromagnetic wave radiation source and capable of radiating a specific wavelength range of electromagnetic waves. Notably, the wavelength spectrum used in order to irradiate organic macromolecular compounds will be determined, in accordance with the type of substitution and the chain containing the set of conjugated double bonds, as well as regarding the functional groups and other effective substitutions placed in the chemical structure of the compound and derivative used, which are located in the vicinity of the mentioned double bond chain; besides, from a technical point of view, the claimed process will be based on the technique and molecular mechanism of trans-cis photoisomerization.According to claim 45, the second claimed molecular approach and chemical process, based on the photochromism effect, relates to the application of a set of metal salts of transition elements and the coordination compounds with the centrality of semi-stable or unstable metal elements belonging to the 3 rows of 4th, 5th, and 6th transition metals of the periodic table and especially, metals belonging to groups 5 to 9 of transition elements, as the centers and cores of these coordination compounds that in this process, following by irradiating the applied sample of these alleged metal compounds and salts with the help of polarized electromagnetic waves. The process of charge transfer and electron transfer between layers and atomic and molecular electron orbitals will be carried out reversibly and based on the photo-induced electron transfer technique.According to claim 45, a third claimed molecular approach and chemical process, based on the photochromism effect, relies on the technique and molecular mechanism of photocyclization and a set of aromatic, semi-aromatic, and non-aromatic cyclic or non-cyclic macromolecular compounds and derivatives, containing a set of conjugated double bonds, especially chemical compounds that contain at least one non-cyclic substitution of a conjugated double bond with an aromatic ring, have been used.According to claim 48, in the claimed molecular approach and chemical process, based on the photochromism effect, by irradiating and exposing the employed chemical structure to a specific frequency spectrum of laser-polarized electromagnetic waves, and creating an excitation in the molecular orbitals of the chemical compound used, a molecular process and chemical reaction based on two general mechanisms of hydrogen shift and carbon shift will be carried out in the direction of cyclization or cyclization of the corresponding molecule. In fact, following the photocyclization process, the primary molecule will be reversibly converted to one of its structural isomers that has more rings. The most pivotal mechanisms for carrying out the claimed cyclization reactions in this claimed invention would be the sigmatropic reactions and rearrangements, preferably the Claisen rearrangement of the [3,3] sigmatropic reaction type, the Diels-Alder reaction of the [4,2] sigmatropic reaction type, the Cope rearrangement of the [1,5] sigmatropic reaction type, the Woodward Hoffmann rearrangement of the [1,7] sigmatropic type reaction, the Wagner-Meerwein rearrangement type [1,2] sigmatropic reaction and other processes such as [2,3] sigmatropic reaction. It can be pointed out that it will be possible to simultaneously use multiple derivatives and stable metal salts of some alkaline elements, alkaline earth, and transition elements of the first series, in the role of photocyclization process catalyst.According to claim 45, the fourth claimed molecular approach and chemical process is based on the effect of photochromism, based on the technique and molecular mechanism of homolytic cleavage, and a set of light-sensitive compounds containing at least one weak and radiation-sensitive bond has been used. In this way, following the creation of free radicals, various chemical processes take place in order to alter the chemical nature of the compounds and chemical derivatives used. The most important molecular mechanism and approach considered, based on this method and molecular process, is radical photopolymerization and the preferred type is living radical polymerization, which will be performed on the rigid polymer matrix bed.According to claims 32 and 33, the implementation of the molecular 3D printing process, based on the Mechanochromism or Piezochromism effect, is initiated and activated by an external mechanical factor and force, such as pressure, and is based on changes in the band gap (bandgap) in the crystalline form of polymeric compounds, zwitterionic derivatives, and especially various compounds with semiconducting properties. The process and molecular approach of Piezochromism used in this claimed invention can occur in both irreversible and reversible manners and in a diverse temperature range. Besides that, according to the chemical nature of the discussed process, the main focus in carrying out the Mechanochromism or Piezochromism process is the presence of a type of chemiluminescent property such as fluorescence or phosphorescence, and the possibility of carrying out this process, will be existed in a wide range of chromogenic polymers, semiconducting derivatives with at least one of the metals and transition elements of the fifth and sixth periodicity, a diverse range of compounds and derivatives of oxide, peroxide, halide, nitrite, nitrate, sulfide, sulfite, sulfate, and carbonate pseudo metallic compounds of the periodic table, multinuclear coordination compounds centered on at least one cationic species of transition metal elements of the fourth, fifth, and sixth periods of the periodic table and, in general, any other chemical compound that possess a series of fluorescence or phosphorescence properties.According to claims 32 and 33, the implementation of the molecular 3D printing process, based on the Solvatochromism effect, which itself consists of several sub-branches such as hydrochromism and ionochromism, relies on the effect of the solvent on the electronic levels and the induction of energy changes in the electronic levels of various compounds and subsequently by using the chemical structure and molecular composition considered in an engineered solvent system, consisting of a diverse range of solvents, due to the type of solvent coating and new intermolecular interactions between solvent molecules with different components, substitutions and functional groups in the relevant chemical composition, an alteration in the energy levels of bonding, non-bonding, and anti-bonding molecular orbitals of the utilized molecular or macromolecular compound would be created, which is proportional to the change in the energy levels created by these intermolecular interactions, the range of absorption and emission wavelengths of the chemical structure of the covered solvent will change and subsequently, the mentioned process will cause a change in the color of the solution and the final matrix of the utilized chemical structure and solvent.According to claim 52, in order to achieve molecular processes and approaches based on the Solvatochromism effect, in line with the application and implementation of a set of molecular 3D printing processes, a wide range of polar conjugated aromatic molecular and macromolecular compounds have been used, especially hydrazone derivatives, benzothiazole, phenylacrylonitrile, phenylimidazole, phenyltriazole, nitropyridine, cyanopyridine, cationic derivatives such as pyridinium phenolate and styrylpyridinium, hybrid conjugated derivatives of pyridine with various substitutions such as aniline, acrylonitrile, imidazole and triazole, cyanine derivatives, and in general, any conjugated aromatic chemical structure and compound that possesses at least two aromatic rings and a conjugated linker.According to claims 32 and 33, in addition to using printing techniques based on the claimed inherent effects of Adsorchromism, Mechanochromism, Thermochromism, Vapochromism, Photochromism, Electrochromism, Piezochromism, and Solvatochromism, the pivotal technical conditions for the use of a molecular-macromolecular biological process and approach, related to both effects and inherent properties of photochromism and thermochromism is provided based on manipulation and adjusted switches in the level of enzymatic activity of a wide range of natural or biologically engineered enzymes by 2 external laser and temperature stimuli, by applying heating or irradiating a specific frequency range of polarized electromagnetic waves, that in the process of implementing and implementing this claimed method and process, at least one enzyme matrix has been used along with a set of compounds and derivatives sensitive to enzyme activity, which possesses the capability of producing degraded compounds and secondary derivatives after undergoing a chemical reaction in the presence of the enzyme matrix and the enzyme matrix carrier solution used.According to claim 54, in this biological molecular-macromolecular approach, by using an external thermal or radiation factor such as a temperature shock, a significant switch in the temperature of the matrix and the utilized enzyme solution will emerge, or by exposing the sample and matrix of the claimed enzyme to the radiation of a specific frequency range of electromagnetic waves with the ability to excite, the applied enzyme undergoes the process of enzymatic activity switching, in two various types: on-off or reduced-enhanced, which both referred types can either be performed reversibly or irreversibly and causes a chain of chemical reactions to take place.According to claims 22, 23, 24, 32 and 33, the cornerstone in the conduction and implementation of the molecular 3D printing technique in the claimed advanced molecular printer system is the general set of 2 plates and the mentioned movable substrate, that includes the moving metal / polymer substrate composed of compressed polymer structures embedded in the upper area, in the vicinity to the advanced railed-equipped transparent plate and substrate embedded in the lower area, along with 2 different types of electromechanical system used, that comprises an intelligent mobile surface-mounted electromechanical system, containing at least one enhanced laser radiation source and an optical sensor, along with the referred surface-fixed electromechanical system, containing electro-optic parts such as beam splitters, polarizers and dichroic mirrors / prisms, which is the possibility of inducing and carrying out a set of reversible or irreversible chemical processes and reactions, based on various molecular mechanisms like changing and manipulating the oxidation number, applying chemical isomerization reactions, applying molecular switches, and inducing controlled changes and manipulations in a wide-range of various configuration patterns of the used molecular and macromolecular compounds and derivatives, by eventually carrying out the process of inducing various types of excitations in the electronic, vibrational, and rotational levels of the molecular and macromolecular compounds and derivatives used, has been facilitated.According to claim 56, on the upper metallic / polymeric surface of the mobile substrate and plate of the type of compressed polymer structures, which is the place of placement and embedding of various paper, wool, silk, polymer, fabric, fabric and other types of textile printing substrates, a series of different ceramic, ionic and polymeric compounds, which are in crystalline and semicrystalline form and have piezoelectricity properties, have been used.According to claim 57, these various ceramic, ionic, and polymeric compounds that are claimed to be used, are related to the preferred types of chalcogenide derivatives and comprise semi metallic and metallic elements of the fifth group of the periodic table and transition elements of the fourth and fifth periods, as network forming group, along with elements belonging to the sixth main group of the periodic table (chalcogen) such as sulfur, selenide and tellurium, semisynthetic natural semicrystalline polymer derivatives, preferably using chitosan and cellulose derivatives as well as synthetic polymer derivatives with semicrystalline form, e.g. polyvinylidene fluoride (PVDF), poly-L-lactic acid (PLLA), polyhydroxybutyrate (PHB) and polyamide derivatives with other compounds and their copolymer derivatives. Besides that, it will be possible to perform semi-conducting surfaces based on chemical compounds with characteristics of straightening electric current, which accordingly will provide the possibility of applying the electric pulse technique as a specific example of usable external factors and stimuli, In preferable conditions where a desire to use molecular and macromolecular compounds and derivatives with the inherent nature and effect of electrochromism exists.According to claims 7 and 29, in addition to the claimed communication role for laser light beams and polarized electromagnetic waves produced and transmitted, which has enabled the ability to link and continuously transmit digital information, based on the laser telecommunication technique, between electromechanical systems and devices and operational systems, used in the claimed invention, in an encrypted and targeted manner and based on the physical mechanism of interferometry, laser light beams, and polarized electromagnetic waves are claimed to play a role as the main external stimuli.According to claim 59, the alleged stimulating role for the laser light rays produced and radiated by the indicated laser light beam emitting unit is classified into two primary and secondary categories. In case of considering chemical approaches and processes that are rely on the application of the effect and inherent nature of Photochromism, Thermochromism and Adsorchromism, light beams and laser electromagnetic waves are considered as the primary external stimuli. On the other hand, if aiming to implement a molecular 3D printing mechanism, based on benefiting from compounds with inherent effects and properties of Mechanochromism, Electrochromism and Piezochromism, the light beams and electromagnetic waves generated and radiated towards the target printed substrate and surfaces will act as a secondary external stimulus.According to claim 60, in order to benefit from the inherent effect and property of Photochromism, with the help of the claimed laser stimulus, the optimal frequency range for polarized laser electromagnetic waves produced and radiated, would be in the visible region of the violet to ultraviolet and preferably the preferable utilized wavelength range would be between 25 nm and 430 nm, and to benefit from the effect and inherent property of Thermochromism, the range of electromagnetic waves, would be in the visible region of red to infrared and preferably would be in the wavelength range between 430 nm and 900 nm.

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