Novel carboxamide compounds
The novel carboxamide compounds address the limitations of existing pesticidally active compounds by offering enhanced biological activity, improved safety for non-target organisms, and better environmental persistence, making them effective and safer agrochemicals.
Patent Information
- Application Number
- PCT/EP2024/082067
- Authority / Receiving Office
- WO · WO
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2023-11-14
- Filing Date
- 2024-11-12
- Publication Date
- 2025-05-22
AI Technical Summary
Current pesticidally active compounds often have limitations in terms of biological activity, safety profile for non-target organisms, and environmental persistence.
Development of novel carboxamide compounds with specific structural features, which exhibit enhanced biological activity, improved safety profile for pollinators and other non-target organisms, and improved physico-chemical properties.
The novel carboxamide compounds demonstrate superior biological activity, an advantageous safety profile, and improved environmental characteristics, making them effective agrochemical active ingredients.
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Figure EP2024082067_22052025_PF_FP_ABST
Abstract
Description
[0001]82875_FF 1 NOVEL CARBOXAMIDE COMPOUNDS The present invention relates to pesticidally active, in particular insecticidally active carboxamide compounds, preferably substituted carboxamide compounds thereof, to processes for their preparation, to compositions comprising the compounds, and to their use for controlling animal pests, including arthropods and in particular insects. WO 2021 / 153720 describes certain alkoxy benzoic acid amide derivatives. There have now been found certain novel pesticidally active carboxamide compounds. The present invention accordingly relates, in a first aspect, to a compound of the formula (I) wherein: R1is selected from C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy- C1-C4-alkyl, cyano-C1-C4-alkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, C3-C6-halocycloalkyl-C1-C4- alkyl, C1-C4-alkyl-C3-C6-cycloalkyl, cyano-C3-C6-cycloalkyl, cyano-C3-C6-cycloalkyl-C1-C4-alkyl, C4-C8- bicycloalkyl, 3-, 4-, 5- or 6-membered heterocycloalkyl, phenyl, 5- or 6-membered heteroaryl, phenyl-C1-C4- alkyl or 5- or 6-membered heteroaryl-C1-C3-alkyl, wherein said 3-, 4-, 5- or 6-membered heterocycloalkyl contains 1 or 2 heteroatoms individually selected from N, O, S, S=O or SO2, with the proviso that no more than one is O, S, S=O or SO2; and wherein any of said 5- or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N or O, and wherein said 3-, 4-, 5- or 6-membered heterocycloalkyl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C3-alkyl, C1-C3- haloalkyl or C3-C6-cycloalkyl, and wherein any of said phenyl, 5- or 6-membered heteroaryl, are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, or C1-C4alkoxy; R2is selected from hydrogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C1-C4- alkylcarbonyl, or C1-C4-alkoxycarbonyl; R3is selected from halogen, cyano, or C1-C3-alkyl; R4is selected from hydrogen, or C1-C3-alkyl; R5and R6are independently selected from C1-C3-alkyl; or R5and R6together with the carbon to which they are attached represent a C3-C5 cycloalkyl group; R7is selected from C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, phenyl, or 5- or 6-membered heteroaryl; wherein said C3-C6-cycloalkyl is unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C3-alkyl, or C1-C3-haloalkyl; and wherein any of said 5- or 6-membered heteroaryl 82875_FF 2 contains 1 or 2 heteroatoms individually selected from N, S or O, with the proviso that no more than one is O or S; and wherein any of said phenyl, or said 5- or 6-membered heteroaryl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, or C1-C4-alkoxy; R8is selected from hydrogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C1-C4- alkylcarbonyl, or C1-C4-alkoxycarbonyl; or a salt or an N-oxide thereof. Surprisingly, it has been found that the novel compounds of formula (I) have, for practical purposes, advantageous levels of biological activity for protecting plants against insects or superior properties for use as agrochemical active ingredients, for example, greater biological activity, an advantageous spectrum of activity,an increased safety profile against non-target organisms above and below ground (such as fish, birds andbees), improved physico-chemical properties, or increased biodegradability. In particular, it has been surprisingly found that certain compounds of formula (I) may show an advantageous safety profile with respect to non-target arthropods, in particular pollinators such as honey bees, solitary bees, and bumble bees. Most particularly, Apis mellifera. According to a second aspect of the invention, there is provided a composition comprising a compound of formula (I) as defined in the first aspect. Such a composition may further comprise at least one additional active ingredient and / or an agrochemically-acceptable diluent or carrier. According to a third aspect of the invention, there is provided a method of combating and controlling insects, acarines, nematodes or molluscs which comprises applying to a pest, to a locus of a pest, or to a plant susceptible to attack by a pest an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound as defined in the first aspect or a composition as defined in the second aspect. According to a fourth aspect of the invention, there is provided a method for the protection of plant propagation material from the attack by insects, acarines, nematodes or molluscs, which comprises treating the propagation material or the site, where the propagation material is planted, with an effective amount of a compound of formula (I) as defined in the first aspect or a composition as defined in the second aspect. According to a fifth aspect of the invention, the present invention makes available a plant propagation material, such as a seed, comprising, or treated with or adhered thereto, a compound of formula (I) as defined in the first aspect, or a composition as defined in the second aspect. Compounds of formula (I) which have at least one basic centre can form, for example, acid addition salts, forexample with strong inorganic acids such as mineral acids, e.g., perchloric acid, sulfuric acid, nitric acid, nitrousacid, a phosphorus acid or a hydrohalic acid, with strong organic carboxylic acids, such as C1- C4alkanecarboxylic acids which are unsubstituted or substituted, for example by halogen, e.g., acetic acid, such as saturated or unsaturated dicarboxylic acids, e.g., oxalic acid, malonic acid, succinic acid, maleic acid, fumaric acid or phthalic acid, such as hydroxycarboxylic acids, e.g., ascorbic acid, lactic acid, malic acid, tartaric acid or citric acid, or such as benzoic acid, or with organic sulfonic acids, such as C1-C4alkane- or arylsulfonic 82875_FF 3 acids which are unsubstituted or substituted, for example by halogen, e.g., methane- or p-toluenesulfonic acid. Compounds of formula (I) which have at least one acidic group can form, for example, salts with bases, e.g., mineral salts such as alkali metal or alkaline earth metal salts, e.g., sodium, potassium or magnesium salts, or salts with ammonia or an organic amine, such as morpholine, piperidine, pyrrolidine, a mono-, di- or tri-lower- alkylamine, e.g., ethyl-, diethyl-, triethyl- or dimethylpropylamine, or a mono-, di- or trihydroxy-lower-alkylamine, e.g., mono-, di- or triethanolamine. In each case, the compounds of formula (I) according to the invention are in free form, in oxidized form as a N-oxide or in salt form, e.g., an agronomically usable salt form. N-oxides are oxidized forms of tertiary amines or oxidized forms of nitrogen containing heteroaromatic compounds. They are described for instance in thebook “Heterocyclic N-oxides” by A. Albini and S. Pietra, CRC Press, Boca Raton 1991. The compounds offormula (I) according to the invention also include hydrates which may be formed during the salt formation. As used herein, the term "halogen" or “halo” refers to fluorine (fluoro), chlorine (chloro), bromine (bromo) or iodine (iodo), preferably fluorine, chlorine, or bromine. This also applies, correspondingly, to halogen in combination with other meanings, such as haloalkyl, and halocycloalkyl. As used herein, cyano means a -CN group. As used herein, the term "C1-Cn-alkyl” refers to a saturated straight-chain or branched hydrocarbon radical attached via any of the carbon atoms having 1 to n carbon atoms, for example, but not limited to methyl, ethyl, n-propyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2, 2-dimethylpropyl, 1-ethylpropyl, n-hexyl, n-pentyl, 1,1- dimethylpropyl, 1,2-dimethylpropyl. As used herein, the term “C2-Cn-alkenyl” refers to a straight or branched alkenyl chain moiety having from two to n carbon atoms and one or two double bonds, for example, ethenyl, prop-1-enyl, but-2-enyl. As used herein, the term “C2-Cn-alkynyl” refers to a straight or branched alkynyl chain moiety having from two to n carbon atoms and one triple bond, for example, ethynyl, prop-2-ynyl, but-3-ynyl, As used herein, the term “C3-Cn-cycloalkyl” refers to 3 to n membered cycloalkyl radical such as cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl. As used herein, the term "C1-Cn-alkoxy" refers to a straight-chain or branched saturated alkyl radical having 1 to n carbon atoms (as mentioned above) which is attached via an oxygen atom, e.g., for example, any one of the radicals methoxy, ethoxy, n-propoxy, 1-methylethoxy, n-butoxy, 1-methylpropoxy, 2-methylpropoxy and 1,1-dimethylethoxy.As used herein, the term “C1-Cn-alkoxy-C1-Cn-alkyl” refers to an alkyl radical (as mentioned above) substitutedwith a C1-Cn-alkoxy group. Examples are methoxymethyl, methoxyethyl, ethoxymethyl and propoxymethyl. As used herein, the term “C3-Cn-cycloalkyl-C1-Cn-alkyl” refers to an alkyl radical (as mentioned above) substituted with a C3-Cn-cycloalkyl group. Examples are cyclopropylmethyl, cyclopropylethyl. Similarly, the term “C3-Cn-halocycloalkyl-C1-Cn-alkyl” refers to an alkyl radical substituted with cycloalkyl group, wherein the 82875_FF 4 cycloalkyl group is substituted by one or more of the same or different halogen atoms. Examples are 3,3- difluorobutylmethyl, and 1-chlorocyclopropylmethyl. As used herein, the term “C4-Cn-bicycloalkyl” refers to is an annulated non-aromatic bicyclic ring system comprising two rings fused together (e.g., sharing two carbon atoms), and consisting solely of carbon and hydrogen atoms. Examples are bicyclo[1.1.1]pentanyl, bicyclo[3.1.0]hexan-6-yl, bicyclo[4.1.0]heptan-7-yl, bicyclo[3.2.0]heptan-6-yl, bicyclo[3.2.0]heptan-3-yl, octahydro-2-pentalenyl, octahydro-1-pentalenyl. As used herein, the term “heterocycloalkyl” or “heterocyclyl” refers to a stable 3-, 4-, 5- or 6-membered non- aromatic monocyclic ring radical which contains 1, 2, or 3 heteroatoms / groups individually selected from N, O, S, S=O or SO2. The heterocyclyl radical may be bonded to the rest of the molecule via a carbon atom orheteroatom. The ring radical will not comprise contiguous oxygen and sulfur atoms. Examples of heterocyclylinclude, but are not limited to, epoxide, aziridinyl, pyrrolinyl, pyrrolidyl, tetrahydrofuranyl, tetrahydrothienyl, tetrahydrothiopyranyl, piperidyl, piperazinyl, tetrahydropyranyl, dioxolanyl, morpholinyl, oxazinanyl, oxetanyl, 1,1-dioxothietan-3-yl, or δ-lactamyl. The heterocycloalkyl radical may be substituted on the heteroatom and / or carbon atom. As used herein, the term “cyano-C1-Cn-alkyl” refers to C1-Cn-alkyl radical having 1 to n carbon atoms (as mentioned above), where one of the hydrogen atoms in the radical is be replaced by a cyano group: for example, cyano-methyl, 2-cyano-ethyl, 2-cyano-propyl, 3-cyano-propyl, 1-(cyano-methyl)-2-ethyl, 1-(methyl)- 2-cyano-ethyl, 4-cyanobutyl, and the like. Similarly, the term “cyano-C3-Cn-cycloalkyl” refers to a C3-Cn- cycloalkyl radical substituted with one of the hydrogen atoms by a cyano group; and the term “cyano-C3-Cn- cycloalkyl-C1-Cn-alkyl” refers to an C1-Cn-alkyl radical having a cyano-C3-Cn-cycloalkyl group. As used herein, the term "C1-Cn-haloalkyl" refers to a straight-chain or branched saturated alkyl radical attached via any of the carbon atoms having 1 to n carbon atoms (as mentioned above), where some or all of the hydrogen atoms in these radicals may be replaced by fluorine, chlorine, bromine and / or iodine, e.g., for example, bit not limited to chloromethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 2-fluoroethyl, 2-chloroethyl, 2- bromoethyl, 2-iodoethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl. Accordingly, the term “C3-Cn-halocycloalkyl” as used herein refers to a C3-Cn-cycloalkyl radical respectively substituted with one or more halo atoms which may be the same or different.As used herein, the term “C1-Cn-alkylcarbonyl” refers to a C1-Cn-alkyl group linked through the carbon atom ofa carbonyl (C=O) group. As used herein, the term “C1-Cn-alkoxycarbonyl” refers to a C1-Cn-alkoxy moiety linked through a carbon atom of a carbonyl (or C=O) group. As used herein, the term "phenyl-C1-Cn-alkyl" refers to a C1-Cn-alkyl radical substituted by a phenyl ring. Examples include benzyl. The phenyl-C1-Cn-alkyl radical may be substituted on alkyl group and / or phenyl group. 82875_FF 5 As used herein, the term “heteroaryl" refers to a 5- or 6-membered aromatic monocyclic ring radical which contains 1, 2, 3 or 4 heteroatoms individually selected from N, O or S. This ring radical will not comprise contiguous oxygen and sulfur atoms. Examples of heteroaryl include, but are not limited to, furanyl, pyrrolyl, thienyl, pyrazolyl, imidazolyl, thiazolyl, isothiazolyl, oxazolyl, isoxazolyl, triazolyl, tetrazolyl, pyrazinyl, pyridazinyl, pyrimidyl, or pyridyl. The term “heteroaryl-C1-Cn-alkyl” refers to an C1-Cn-alkyl radical respectively substituted by a heteroaryl group. The heteroaryl-C1-Cn-alkyl radical may be substituted on heteroaryl, alkyl and / or cycloalkyl group as appropriate. As used herein, the term "controlling" refers to reducing the number of pests, eliminating pests and / or preventing further pest damage such that damage to a plant or to a plant derived product is reduced.As used herein, the term "pest" refers to insects, and molluscs that are found in agriculture, horticulture,forestry, the storage of products of vegetable origin (such as fruit, grain, and timber); and those pests associated with the damage of man-made structures. The term pest encompasses all stages in the life cycle of the pest. As used herein, the term "effective amount" refers to the amount of the compound, or a salt thereof, which, upon single or multiple applications provides the desired effect. An effective amount is readily determined by the skilled person in the art, by the use of known techniques and by observing results obtained under analogous circumstances. In determining the effective amount, a number of factors are considered including, but not limited to the type of plant or derived product to be applied; the pest to be controlled and its lifecycle; the particular compound applied; the type of application; and other relevant circumstances. As used herein, the term “room temperature” or “RT” or “rt” or “ambient temperature” refer to a temperature of about 15° C to about 35° C. For example, rt can refer to a temperature of about 20° C to about 30° C. The following list provides definitions, including preferred definitions, for substituents R1, R2, R3, R4, R5, R6, R7, and R8with reference to the compounds of formula (I) of the present invention. For any one of these substituents, any of the definitions given below may be combined with any definition of any other substituent given below or elsewhere in this document. In one embodiment of the invention, R1is selected from C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C3-C6- cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C3-C6-halocycloalkyl, C3-C6- cycloalkyl-C1-C4-alkyl, C3-C6-halocycloalkyl-C1-C4-alkyl, C1-C4-alkyl-C3-C6-cycloalkyl, cyano-C3-C6-cycloalkyl,cyano-C3-C6-cycloalkyl-C1-C4-alkyl, C4-C8-bicycloalkyl, 3-, 4-, 5- or 6-membered heterocycloalkyl, phenyl, 5- or6-membered heteroaryl, phenyl-C1-C4-alkyl or 5- or 6-membered heteroaryl-C1-C3-alkyl, wherein said 3-, 4-, 5- or 6-membered heterocycloalkyl contains 1 or 2 heteroatoms individually selected from N, O, S, S=O or SO2, with the proviso that no more than one is O, S, S=O or SO2; and wherein any of said 5- or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N or O, and wherein said 3-, 4-, 5- or 6- membered heterocycloalkyl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C3-alkyl, C1-C3-haloalkyl or C3-C6-cycloalkyl, and wherein any of said phenyl, 5- or 6- 82875_FF 6 membered heteroaryl, are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, or C1-C4alkoxy. Preferably, R1is selected from C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, cyano- C1-C4-alkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, C3-C6-halocycloalkyl-C1-C4-alkyl, C1-C4-alkyl- C3-C6-cycloalkyl, cyano-C3-C6-cycloalkyl, cyano-C3-C6-cycloalkyl-C1-C4-alkyl, C4-C8-bicycloalkyl, phenyl, 5- or 6-membered heteroaryl, or phenyl-C1-C2-alkyl; wherein said 5- or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N or O; and wherein said 5- or 6-membered heteroaryl or phenyl-C1- C2-alkyl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, or C1-C4alkoxy.More preferably R1 is selected from C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl,C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, C1-C4-alkyl-C3-C6-cycloalkyl, cyano-C3-C6-cycloalkyl, C4- C8-bicycloalkyl, phenyl-C1-C2-alkyl, phenyl, or 5- or 6-membered heteroaryl; wherein said 5- or 6-membered heteroaryl contains 1 heteroatom selected from N or O; and wherein said phenyl, phenyl-C1-C2-alkyl or 5- or 6-membered heteroaryl are unsubstituted or substituted by 1, or 2 substituents independently selected from halogen, or C1-C4 alkyl. More preferably R1is ethyl, isopropyl, tert-butyl, cyclopropyl, cyclobutyl, difluoromethyl, 2,2-difluoroethyl, 2,2,2- trifluoroethyl, 2-methoxyethyl, 3,3-difluorocyclobutyl, cyclopropyl methyl, 1-cyclopropyl ethyl, 1- methylcyclopropyl, 2-methylcyclopropyl, 1-cyanocyclopropyl, 1-cyanocyclobutyl, 1-bicyclo[1.1.1]pentanyl, 2- bicyclo[1.1.1]pentanyl, 2,4-difluorophenyl, and 6-chloropyridin-3-yl. Even more preferably R1is cyclopropyl, or 1-cyanocyclopropyl. In another embodiment of the invention, R1is selected from C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C3-C6- cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C3-C6-halocycloalkyl, C3-C6- cycloalkyl-C1-C4-alkyl, C3-C6-halocycloalkyl-C1-C4-alkyl, cyano-C3-C6-cycloalkyl, cyano-C3-C6-cycloalkyl-C1- C4-alkyl, C4-C8-bicycloalkyl, 3-, 4-, 5- or 6-membered heterocycloalkyl, phenyl, 5- or 6-membered heteroaryl, phenyl-C1-C4-alkyl, or 5- or 6-membered heteroaryl-C1-C3-alkyl; wherein said 3-, 4-, 5- or 6-membered heterocycloalkyl contains 1 or 2 heteroatoms individually selected from N, O, S, S=O or SO2, with the proviso that no more than one is O, S, S=O or SO2; and wherein any of said 5- or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N or O, and wherein said 3-, 4-, 5- or 6-membered heterocycloalkyl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C3- alkyl, C1-C3-haloalkyl, or C3-C6-cycloalkyl, and wherein any of said phenyl, or 5- or 6-membered heteroaryl, are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, or C1-C4alkoxy. In another embodiment, R1is selected from C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4- alkyl, cyano-C1-C4-alkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, C3-C6-halocycloalkyl-C1-C4-alkyl, cyano-C3-C6-cycloalkyl, cyano-C3-C6-cycloalkyl-C1-C4-alkyl, C4-C8-bicycloalkyl, 5- or 6-membered heteroaryl, or phenyl-C1-C2-alkyl; wherein said 5- or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N or O; and wherein said 5- or 6-membered heteroaryl or phenyl-C1-C2-alkyl are unsubstituted 82875_FF 7 or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, or C1-C4alkoxy. Preferably R1is selected from C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C3-C6- halocycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, cyano-C3-C6-cycloalkyl, C4-C8-bicycloalkyl, phenyl-C1-C2-alkyl, or 5- or 6-membered heteroaryl; wherein said 5- or 6-membered heteroaryl contains 1 heteroatom selected from N or O; and wherein said phenyl-C1-C2-alkyl or 5- or 6-membered heteroaryl are unsubstituted or substituted by 1, or 2 substituents independently selected from halogen, or C1-C4 alkyl. More preferably R1is ethyl, isopropyl, tert-butyl, cyclopropyl, cyclobutyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-methoxyethyl, 3,3-difluorocyclobutyl, cyclopropyl methyl, 1-cyclopropyl ethyl, 1-cyanocyclopropyl, 1-bicyclo[1.1.1]pentanyl, 2-bicyclo[1.1.1]pentanyl, and 6-chloropyridin-3-yl. Even more preferably R1 iscyclopropyl, or 1-cyanocyclopropyl. In one embodiment of the invention, R2is selected from hydrogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1- C4-alkyl, cyano-C1-C4-alkyl, C1-C4-alkylcarbonyl, or C1-C4-alkoxycarbonyl. In another embodiment of the invention, R2is selected from hydrogen, C1-C3-alkyl, C1-C3-alkoxy, C1-C2-alkoxy-C1-C3-alkyl, cyano-C1-C3- alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl. Preferably R2is hydrogen, C1-C3-alkyl, C1-C2- alkylcarbonyl, or C1-C2-alkoxycarbonyl. More preferably R2is hydrogen, or methyl. Even more preferably R2is hydrogen. In one embodiment of the invention, R3is selected from halogen, cyano, or C1-C3-alkyl. Preferably R3is chlorine, bromine, fluorine, cyano, methyl, or ethyl. More preferably R3is chlorine, bromine, or methyl. Even more preferably R3is chlorine, or methyl. Still more preferably R3is chlorine. In one embodiment of the invention, R4is selected from hydrogen, or C1-C3-alkyl. Preferably R4is hydrogen, methyl, or ethyl. More preferably R4is hydrogen, or methyl. Even more preferably R4is hydrogen. In one embodiment of the invention, R5and R6are independently selected from C1-C3-alkyl; or R5and R6together with the carbon to which they are attached represent a C3-C5 cycloalkyl group. Preferably R5and R6are methyl; or R5and R6together with the carbon to which they are attached represent a cyclopropyl group. In one embodiment of the invention, R5and R6are methyl. In another embodiment of the invention, R5and R6together with the carbon to which they are attached represent a C3-C5-cycloalkyl group. Preferably R5and R6together with the carbon to which they are attached represent a cyclopropyl group.In one embodiment of the invention, R7 is selected from C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, phenyl,or 5- or 6-membered heteroaryl; wherein said C3-C6-cycloalkyl is unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C3-alkyl, or C1-C3-haloalkyl; and wherein any of said 5- or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N, S or O, with the proviso that no more than one is O or S; and wherein any of said phenyl, or said 5- or 6-membered heteroaryl 82875_FF 8 are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, or C1-C4 alkoxy. In another embodiment of the invention, R7is selected from C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, phenyl or 5- or 6-membered heteroaryl, wherein said C3-C6-cycloalkyl is unsubstituted or substituted by 1, or 2 substituents independently selected from halogen, cyano, C1-C3-alkyl or C1-C3-haloalkyl; and wherein any of said 5- or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N, S or O, with the proviso that no more than one is O or S; and wherein any of said phenyl, or said 5- or 6-membered heteroaryl are unsubstituted or substituted by 1, or 2 substituents independently selected from halogen, cyano, C1-C3 alkyl, C1-C3 haloalkyl, or C1-C3 alkoxy. Preferably R7is selected from C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, phenyl, or 5- or 6-membered heteroaryl, wherein any of said 5- or 6-membered heteroaryl contains1 heteroatom selected from N, S or O, and wherein any of said phenyl, or said 5- or 6-membered heteroaryl are unsubstituted or substituted by 1, or 2 substituents independently selected from halogen, cyano, C1-C3 alkyl, C1-C3 haloalkyl, or C1-C3 alkoxy. More preferably R7is C1-C4-haloalkyl or C3-C6-cycloalkyl. Even more preferably R7is dichloromethyl, difluoromethyl, trifluoromethyl, or cyclopropyl. Most preferably R7is trifluoromethyl. In one embodiment of the invention, R8is selected from hydrogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1- C4-alkyl, cyano-C1-C4-alkyl, C1-C4-alkylcarbonyl, or C1-C4-alkoxycarbonyl. In another embodiment of the invention, R8is selected from hydrogen, C1-C3-alkyl, C1-C3-alkoxy, C1-C3-alkoxy-C1-C3-alkyl, cyano-C1-C3- alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl. Preferably R8is hydrogen, C1-C3-alkyl, C1-C3-alkoxy-C1- C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl. More preferably R8is hydrogen, methyl, ethyl, acetyl, methylformate, methoxymethyl, or ethoxymethyl. Even more preferably R8is hydrogen, methyl, acetyl, methylformate, or methoxymethyl. Still even more preferably R8is hydrogen. The present invention, accordingly, makes available a compound of formula (I) having R1, R2, R3, R4, R5, R6, R7, and R8as defined above in all combinations / each permutation. Embodiments according to the invention are provided as set out below. In one embodiment, in a compound of formula (I) according to the present invention, R2is hydrogen, C1-C3- alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R3is chlorine, bromine, fluorine, cyano, methyl, or ethyl; R4is hydrogen, methyl, or ethyl; R5and R6are methyl; or R5and R6together with the carbon to which they are attached represent a cyclopropyl group; and R1, R7, and R8are as defined for compounds of formula (I).In another embodiment, in a compound of formula (I) according to the present invention, R2 is hydrogen, C1-C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R3is chlorine, bromine, fluorine, cyano, methyl or ethyl; R4is hydrogen, methyl, or ethyl; R5and R6are methyl; or R5and R6together with the carbon to which they are attached represent a cyclopropyl group; R8is hydrogen, C1-C3-alkyl, C1-C3-alkoxy-C1-C3-alkyl, C1-C2- alkylcarbonyl, or C1-C2-alkoxycarbonyl; and R1, and R7are as defined for compounds of formula (I). 82875_FF 9 In another embodiment, in a compound of formula (I) according to the present invention, R2is hydrogen, C1- C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R3is chlorine; R4is hydrogen, methyl, or ethyl; R5and R6are methyl; or R5and R6together with the carbon to which they are attached represent a cyclopropyl group; R8is hydrogen, C1-C3-alkyl, C1-C3-alkoxy-C1-C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; and R1and R7are as defined for compounds of formula (I). In another embodiment, in a compound of formula (I) according to the present invention, R2is hydrogen, C1- C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R3is chlorine; R4is hydrogen, methyl, or ethyl; R5and R6are methyl; or R5and R6together with the carbon to which they are attached represent a cyclopropyl group; R7is selected from C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, or 5- or 6-membered heteroaryl, wherein anyof said 5- or 6-membered heteroaryl contains 1 heteroatom selected from N, S or O, and wherein any of saidphenyl, or said 5- or 6-membered heteroaryl are unsubstituted or substituted by 1, or 2 substituents independently selected from halogen, cyano, C1-C3 alkyl, C1-C3 haloalkyl, or C1-C3 alkoxy; R8is hydrogen, C1- C3-alkyl, C1-C3-alkoxy-C1-C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; and R1is as defined for compounds of formula (I). In still another embodiment, in a compound of formula (I) according to the present invention, R2is hydrogen, C1-C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R3is chlorine; R4is hydrogen, methyl, or ethyl; R5and R6are methyl; or R5and R6together with the carbon to which they are attached represent a cyclopropyl group; R7is C1-C4-haloalkyl or C3-C6-cycloalkyl; R8is hydrogen, C1-C3-alkyl, C1-C3-alkoxy-C1-C3-alkyl, C1-C2- alkylcarbonyl, or C1-C2-alkoxycarbonyl; and R1is as defined for compounds of formula (I). In still another embodiment, in a compound of formula (I) according to the present invention, R2is hydrogen, C1-C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R3is chlorine; R4is hydrogen, methyl, or ethyl; R5and R6are methyl; or R5and R6together with the carbon to which they are attached represent a cyclopropyl group; R7is dichloromethyl, difluoromethyl, trifluoromethyl or cyclopropyl; R8is hydrogen, C1-C3-alkyl, C1-C3- alkoxy-C1-C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; and R1is as defined for compounds of formula (I). In one embodiment of the invention, the compound of formula (I) may be a compound of formula (I-a), wherein R3is chlorine, and R5and R6are methyl: for compounds of formula (I). In one embodiment, in a compound of formula (I-a) according to the present invention, R2is hydrogen, C1-C3- alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R8is hydrogen, C1-C3-alkyl, C1-C3-alkoxy-C1-C3-alkyl, C1- C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; and R1and R7are as defined for compounds of formula (I). 82875_FF 10 In another embodiment, in a compound of formula (I-a) according to the present invention, R2is hydrogen, C1- C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R7is C1-C4-haloalkyl and C3-C6-cycloalkyl; R8is hydrogen, C1-C3-alkyl, C1-C3-alkoxy-C1-C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; and R1is as defined for compounds of formula (I). In another embodiment, in a compound of formula (I-a) according to the present invention, R2is hydrogen, C1- C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R7is dichloromethyl, difluoromethyl, trifluoromethyl or cyclopropyl; R8is hydrogen, C1-C3-alkyl, C1-C3-alkoxy-C1-C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2- alkoxycarbonyl; and R1is as defined for compounds of formula (I). In another embodiment of the invention, the compound of formula (I) may be a compound of formula (I-b),wherein R3 is chlorine, and R5 and R6 together with the carbon to which they are attached represent acyclopropyl group: for compounds of formula (I). In one embodiment, in a compound of formula (I-b) according to the present invention, R2is hydrogen, C1-C3- alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R8is hydrogen, C1-C3-alkyl, C1-C3-alkoxy-C1-C3-alkyl, C1- C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; and R1and R7are as defined for compounds of formula (I). In another embodiment, in a compound of formula (I-b) according to the present invention, R2is hydrogen, C1- C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R7is C1-C4-haloalkyl and C3-C6-cycloalkyl; R8is hydrogen, C1-C3-alkyl, C1-C3-alkoxy-C1-C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; and R1is as defined for compounds of formula (I). In another embodiment, in a compound of formula (I-b) according to the present invention, R2is hydrogen, C1- C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl; R7is dichloromethyl, difluoromethyl, trifluoromethyl or cyclopropyl; R8is hydrogen, C1-C3-alkyl, C1-C3-alkoxy-C1-C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2- alkoxycarbonyl; and R1is as defined for compounds of formula (I). Preferably, the compound according to formula (I) is selected from a compound listed in Table A1, A2 or Table P (below). More preferably, the compound according to formula (I) is selected from a compound listed in Table P (below). The compounds of formula (I) according to the present invention may possess at least two chiral centres at carbon atoms marked with a star (*) as outlined below in formula (I-c). 82875_FF 11 c) of formula (I) may exist in various diastereomeric forms, e.g., -, -, -, or - configurations present at carbon atoms marked with a star (*) as in formula (I-c), respectively. In particular, each of these configurations may be evident for compounds of formula (I) in relation to the specific combinations of definitions for R1, R2, R3, R4, R5, R6, R7, and R8, for each compound described in Table A1, A2 or Table P (below). The present invention in a further aspect provides a method of controlling parasites in or on an animal in need thereof comprising administering an effective amount of a compound of the first aspect. The present invention further provides a method of controlling ectoparasites on an animal in need thereof comprising administering an effective amount of a compound of formula (I) as defined om the first aspect. The present invention furtherprovides a method for preventing and / or treating diseases transmitted by ectoparasites comprising administering an effective amount of a compound of formula (I) as defined in the first aspect, to an animal in need thereof. Compounds of formula (I) can be prepared by those skilled in the art following known methods. More specifically compounds of formula (I), and intermediates therefor can be prepared as described below in the schemes and examples. Certain stereogenic centers have been left unspecified for the clarity and are not intended to limit the teaching of the schemes in any way. The compounds of formula (I) according to the invention, wherein R1, R2, R3, R4, R5, R6, R7and R8are as defined for formula (I), can be obtained by transformation of a compound of formula (II), wherein R3, R4, R5, R6, R7and R8are as defined for formula (I) with a compound of formula (III), wherein R1and R2are as defined for formula (I), via an intermediate of formula (IV), wherein G is selected from halogen (preferably chloride), G1, G2, G3 or G4 (G1 to G4 are called activated acylating agent) as described below (scheme 1). Scheme 1 82875_FF 12 As to those skilled in the art and described for example in Tetrahedron 2005, 61 (46), 10827-10852. For example, compounds of formula (IV) where G is halogen are formed by treatment of compounds of formula (II) with for example, oxalyl chloride or thionyl chloride in the presence of catalytic quantities of dimethylformamide (DMF) in inert solvents such as dichloromethane (DCM) or tetrahydrofuran (THF) at temperatures between 25-170°C preferably 25 to 80°C. Treatment of (IV) with compounds of formula (III), optionally in the presence of a base, e.g. triethylamine or pyridine leads to compounds of formula (I). Alternatively, compounds of formula (I) can be prepared by treatment of compounds of formula (II) with dicyclohexyl carbodiimide (DCC) or 1-ethyl-3-(3- dimethylaminopropyl)carbodiimide (EDC) to give the activated species (IV), wherein G is G1 or G2, in an inert solvent, e.g., pyridine, or THF optionally in the presence of a base, e.g. triethylamine, at temperatures between rt and 180°C. In addition, an acid of the formula (II) can also be activated by reaction with a coupling reagent such as propanephosphonic acid anhydride (T3P®) or O-(7-Aza-1-benzotriazolyl)-N,N,N’,N’- tetramethyluronium-hexafluorophosphat (HATU) to provide compounds of formula (IV) wherein G is G3 and G4as described for example in Synthesis 2013, 45 (12), 1569-1601 and J. Prakt. Chem.1998, 340 (5), 581-583.Subsequent reaction with an amine of the formula (III) provides compounds of formula (I). The compounds of formula (II), wherein R3, R4, R5, R6, R7and R8are as defined for formula (I), can be obtained by transformation of a compound of formula (V), wherein R3, R4, R5, R6, R7and R8are as defined for formula (I) and R9is C1-C6-alkyl, in the presence of a base or an acid (Scheme 2). Scheme 2 As shown conditions to compounds (II) by methods known to those skilled in the art and described for example in ACS Chem. Neurosci. 2017, 2374. For example, the reaction can be performed in water or in organic solvent, such as methanol, ethanol, THF or DCM, or in mixtures; in the presence of a base, such as lithium hydroxide, sodium hydroxide or potassium hydroxide. Alternatively, the conversion of compounds (V) into compounds (II) can be performed under acidic conditions by methods known to those skilled in the art and described for example in 82875_FF 13 WO2019200246. For example, the reaction can be performed in water or in mixtures of water and an organic solvent, such as methanol, THF or dioxane; in the presence of an acid, such as trifluoroacetic acid, hydrochloric acid or sulfuric acid. The compounds of formula (Va), wherein R3, R4, R5, R6, and R7are as defined for formula (I), R9is C1-C6-alkyl, can be obtained by transformation of a compound of formula (VI), wherein R3, R4, R5, and R6are as defined for formula (I) and R9is C1-C6-alkyl, in the presence of a reagent formula (VII), wherein R7is as defined for formula (I) and G is a halogen or an activating group of formula G5 (Scheme 3). Scheme 3 As shown known to those skilled in the art and described for example in Angew. Chem. Int. Ed.2016, 5299; J. Am. Chem. Soc.2018, 5322, WO2021153720, WO2010150192. For example, the reaction can be performed in inert organic solvent, such as DCM, dioxane or THF, in the presence of a base, such as triethylamine, pyridine or 1,8- Diazabicyclo[5.4.0]undec-7-ene. Alternatively, as known to those skilled in the art, compound (VI) in a salt form (i.e. hydrochloric salt, hydrobromic salt, trifluoroacetic salt, paratoluensulfonic salt, and others known to the person skilled in the art) can be similarly used in a conversion to compound (Va). The compounds of formula (VI), R3, R4, R5, and R6are as defined for formula (I) and R9is C1-C6-alkyl, can be obtained by transformation of a compound of formula (VIII), wherein R3, R4, R5, and R6are as defined for formula (I) and R9and R10are independently C1-C6-alkyl (Scheme 4). Scheme 4 As shown in known to those skilled in the art and described for example in WO2002059117, J. Med. Chem.2003, 5238, Org. Lett.2022, 2064. For example, the reaction can be performed in organic solvent, such as DCM, dioxane or THF, in the presence of an organic or inorganic acid, such as hydrochloric acid, trifluoroacetic acid or paratoluensulfonic acid. Compounds (VI) can also be obtained and used in following transformations in their salt form (i.e. hydrochloric salt, hydrobromic salt, trifluoroacetic salt, paratoluensulfonic salt, and others known to the person skilled in the art). 82875_FF 14 The compounds of formula (VIII), wherein R3, R4, R5, and R6are as defined for formula (I) and R9and R10are independently C1-C6-alkyl, can be obtained by transformation of a compound of formula (IX), wherein R3is as defined for formula (I) and R9is C1-C6-alkyl with an alkylating agent of formula (Xa), wherein R4, R5, and R6are as defined for formula (I), R10is C1-C6-alkyl, and Q is halogen, hydroxyl or sulfonate group (Scheme 5). Scheme 5 As Q is i.e. halogen or sulfonate Q1 or Q2) to compounds (VIII) by methods known to those skilled in the art and described for example in WO2023026180, J. Med. Chem.2011, 3076, WO2022216947. For example, the reaction can be performed in organic solvent, such as DMF, acetone or acetonitrile in the presence of a base, such as cesium carbonate, sodium hydride or sodium carbonate. Alternatively, compounds (IX) can be converted by a Mitsunobu reaction with (Xa) (when Q is equal to OH) by methods known to those skilled in the art and described for example in WO2021171163, J. Chem. Pharm. Res.2014, 982. For example, the reaction can be performed in organic solvent, such as toluene, THF or DCM in the presence of an azadicarboxylate reagent,such as diethyl azadicarboxylate or diisopropyl azadicarboxylate, and a phospine reagent, such as triphenylphosphine. Alternatively, compounds (IX) can be converted by an alkylative reaction with aziridine (Xb) to compounds (VIII) by methods known to those skilled in the art and described for example in WO2009142984, WO2022165529. For example, the reaction can be performed in organic solvent, such as acetonitrile in the presence of a base, such as potassium carbonate, sodium hydride or sodium carbonate. Alternatively, compounds (IX) can be converted by an alkylative reaction with compounds (Xc) to compounds (VIII) by methods known to those skilled in the art and described for example WO2003037327 or WO2022157780. For example, the reaction can be performed in organic solvent, such as DMF, THF or acetonitrile in the presence of a base such as NaH, potassium tert-butoxide or potassium carbonate at temperatures between -40°C and 150°C, preferably at a temperature between 0 and 100°C. Compounds of formula (IX), wherein R3, is as defined for formula (I) and R9is C1-C6-alkyl, can be obtained in two steps by transformation of a compound of formula (XII), wherein R3is as defined for formula (I) and R9is C1-C6-alkyl and R11is halogen via an intermediate compound of formula (XI), wherein R3is as defined for formula (I) and R9is C1-C6-alkyl (Scheme 6). 82875_FF 15 Scheme 6 As to those skilled in the art with the name of Miyaura borylation reaction and described for example in J. Org.Chem.1995, 7508; J. Org. Chem. 2021, 103. For example, the reaction can be performed in organic solvent,such as THF or dioxane, in the presence of a base, such as potassium carbonate or potassium acetate and a palladium catalyst in combination with an appropriate ligand, such as 1,1'-bis(diphenylphosphino)ferrocene dichloropalladium. Intermediates (XI) can be converted into compounds of formula (IX) by methods known to those skilled in the art and described for example in Tetrahedron Lett.2014, 2082; Tetrahedron Lett.2017, 3323; Tetrahedron 2005, 1417. For example, the reaction can be performed in mixtures of water and an organic solvent, such as ethanol, acetonitrile or DCM, in the presence of hydrogen peroxide. Compounds of formula (I), wherein R1, R2, R3, R4, R5, R6, R7, and R8are as defined for formula (I), can be obtained by transformation of a compound of formula (Ia), wherein R1, R2, R3, R4, R5, R6, and R7are as defined for formula (I), with a compound of formula (XIII), wherein R8is as defined for formula (I) and Q is halogen or sulfonate (Scheme 7). Scheme 7As those skilledin the art and described for example in ACS Comb. Sci.2016, 569; WO202115372. For example, the reaction can be performed in organic solvent, such as DCM, DMF or acetonitrile, in the presence of a base, such as potassium carbonate or triethylamine. Alternatively, the reaction can be performed with a reagent of formula (XIIIa). In this case the reaction can be performed in organic solvent, such as DCM, DMF or acetonitrile, in the presence of a base, such as potassium carbonate or triethylamine and with the aid of a catalyst, such as 4- (dimethylamino)pyridine as described for example in WO2021178885; Org. Process Res. Dev.2014, (18), 205. 82875_FF 16 Alternatively, compounds of formula (Ia) according to the invention, wherein R1, R2, R3, R4, R5, R6, and R7are as defined for formula (I), can be obtained by transformation of a compound of formula (XIV), wherein R1, R2, R3, R4, R5, and R6are as defined for formula (I), in the presence of a sulfonylating agent of formula (VII), wherein R7is as defined for formula (I) and G is a halogen or an activating group of formula G5 (Scheme 8). Scheme 8 As shown in known to those skilled in the art and described for example in Angew. Chem. Int. Ed.2016, 5299; J. Am. Chem. Soc.2018, 5322; WO2021153720, WO2010150192. For example, the reaction can be performed in inert organic solvent, such as DCM, dioxane or THF, in the presence of a base, such as triethylamine, pyridine or 1,8- Diazabicyclo[5.4.0]undec-7-ene. Alternatively, as known to those skilled in the art, compounds (XIV) in a salt form (i.e. hydrochloric salt, hydrobromic salt, trifluoroacetic salt, paratoluensulfonic salt, and others known to the person skilled in the art) can be similarly used in a conversion to compounds (Ia). The compounds of formula (XIV), wherein R1, R2, R3, R4, R5, and R6are as defined for formula (I), can be obtained by transformation of a compound of formula (XV), wherein R1, R2, R3, R4, R5, and R6are as defined for formula (I) and R10is C1-C6-alkyl (Scheme 9). Scheme 9 As shown in known to those skilled in the art and described for example in WO2002059117, J. Med. Chem. 2003, 5238, Org. Lett. 2022,2064. For example, the reaction can be performed in organic solvent, such as DCM, dioxane or THF, in the presence of an organic or inorganic acid, such as hydrochloric acid, trifluoroacetic acid or paratoluensulfonic acid. Compounds (XIV) can also be obtained and used in following transformations in their salt form (i.e. hydrochloric salt, hydrobromic salt, trifluoroacetic salt, paratoluensulfonic salt, and others known to the person skilled in the art). The compounds of formula (XV), wherein R1, R2, R3, R4, R5, and R6are as defined for formula (I) and R10is C1-C6-alkyl, can be obtained by transformation of a compound of formula (XVI), wherein R1, R2, and R3are as 82875_FF 17 defined for formula (I) with an alkylating agent of formula (Xa), wherein R4, R5and R6are as defined for formula (I), R10is C1-C6-alkyl and Q is halogen, hydroxyl or sulfonate group (Scheme 10). Scheme 10 As shown (when Q is i.e. halogen or sulfonate Q1 or Q2) to compounds (XV) by methods known to those skilled in the art and described for example in WO2023026180, J. Med. Chem.2011, 3076, WO2022216947. For example, the reaction can be performed in organic solvent, such as DMF, acetone or acetonitrile in the presence of a base, such as cesium carbonate, sodium hydride or sodium carbonate. Alternatively, compounds (XVI) can be converted by a Mitsunobu reaction with (Xa) (when Q is equal to OH) by methods known to those skilled in the art and described for example in WO2021171163, J. Chem. Pharm. Res 2014, 982. For example, the reaction can be performed in organic solvent, such as toluene, THF or DCM in the presence of an azadicarboxylate reagent, such as diethyl azadicarboxylate or diisopropyl azadicarboxylate, and a phospine reagent, such as triphenyl phosphine. Alternatively, compounds (XVI) can be converted by an alkylative reaction with aziridine (Xb) to compounds (XV) by methods known to those skilled in the art and described for example in WO2009142984, WO2022165529. For example, the reaction can be performed in organic solvent, such as acetonitrile in the presence of a base, such as potassium carbonate, sodium hydride or sodium carbonate. The compounds of formula (XVI), wherein R1, R2, and R3are as defined for formula (I), can be obtained by transformation of a compound of formula (XVII), wherein R3is as defined for formula (I) with a compound of formula (III), wherein R1and R2are as defined for formula (I), via an intermediate of formula (XVIII), wherein G is selected from halogen (preferably chloride), G1, G2, G3or G4(G1to G4are called activated acylating agent, see scheme 1) as described below (Scheme 11). Scheme 11 As known to those skilled in the art and described for example in Tetrahedron 2005, 61 (46), 10827-10852. For example, compounds of formula (XVIII) where G is halogen are formed by treatment of compounds of formula (XVII) with 82875_FF 18 for example, oxalyl chloride or thionyl chloride in the presence of catalytic quantities of DMF in inert solvents such as DCM or THF at temperatures between 25-170°C preferably 25-80°C. Treatment of (XVIII) with compounds of formula (III), wherein R1and R2are as defined in formula (I), optionally in the presence of a base, e.g. triethylamine or pyridine, leads to compounds of formula (XVI). Alternatively, compounds of formula (XVI) can be prepared by treatment of compounds of formula (XVII) with dicyclohexyl carbodiimide (DCC) or 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) to give the activated species (XVIII), wherein G is G1 or G2, in an inert solvent, e.g., pyridine, or THF optionally in the presence of a base, e.g. triethylamine, at temperatures between rt and 180°C. In addition, an acid of the formula (XVII) can also be activated by reaction with a coupling reagent such as propanephosphonic acid anhydride (T3P®) or O-(7-Aza-1-benzotriazolyl)-N,N,N’,N’-tetramethyluronium-hexafluorophosphat (HATU) to provide compounds of formula (XVIII) wherein Gis G3 and G4 as described for example in Synthesis 2013, 45 (12), 1569-1601 and J. Prakt. Chem.1998, 340 (5), 581-583. Subsequent reaction with an amine of the formula (III) provides compounds of formula (XVI). The compounds of formula (XVII), wherein R3is as defined for formula (I), can be obtained by transformation of a compound of formula (XII), wherein R3is as defined for formula (I) and R9is C1-C6-alkyl, in the presence of a base or an acid (Scheme 12). Scheme 12 As shown in Scheme under basic conditions to compounds (XVII) by methods known to those skilled in the art and described for example in ACS Chem. Neurosci. 2017, 2374. For example, the reaction can be performed in water or in organic solvent, such as methanol, ethanol, THF or DCM, or in mixtures; in the presence of a base, such as lithium hydroxide, sodium hydroxide or potassium hydroxide. Alternatively, the conversion of compounds (XII) into compounds (XVII) can be performed under acidic conditions by methods known to those skilled in the art and described for example in WO2019200246. For example, the reaction can be performed in water or in mixtures of water and an organic solvent, such as methanol, THF or dioxane; in the presence of an acid, such as trifluoroacetic acid, hydrochloric acid or sulfuric acid. The compounds of formula (Ia) wherein R1, R2, R3, R4, R5, R6, and R7are as defined for formula (I), can be obtained by transformation of a compound of formula (XVI) wherein R1, R2, and R3are as defined for formula (I), with an alkylating agent of formula (XIXa), wherein R5, R6, R4and R7are as defined for formula (I) and Q is halogen, hydroxyl or sulfonate group (Scheme 13). 82875_FF 19 Scheme 13 As shown in (when Q is i.e. halogen or sulfonate Q1 or Q2) to compounds (Ia) by methods known to those skilled in the art anddescribed for example in Med. Chem. Res. 2015, 24 (11), 3803, Molecules 2020, 25 (22), 5459, Org. Lett.2021, 23 (13), 5102. For example, the reaction can be performed in organic solvent, such as DMF, acetone or acetonitrile in the presence of a base, such as cesium carbonate, sodium hydride or sodium carbonate. Alternatively, compounds (XVI) can be converted by a Mitsunobu reaction with (XIXIa) (when Q is equal to OH) by methods known to those skilled in the art and described for example in Bioorg. Med. Chem. Lett.2009, 19 (1), 119-122, Eur. J. Med. Chem.2017, 137, 63-75. For example, the reaction can be performed in organic solvent, such as toluene, THF or DCM in the presence of an azadicarboxylate reagent, such as diethyl azadicarboxylate or diisopropyl azadicarboxylate, and a phospine reagent, such as triphenyl phosphine. Alternatively, compounds (XVI) can be converted by an alkylative reaction with aziridine (XIXb) to compounds (Ia) by methods known to those skilled in the art and described for example in J. Chem. Res.2008, (5), 297- 300, J. Org. Chem.2014, 79 (11), 5121. For example, the reaction can be performed in organic solvent, such as acetonitrile, THF or EtOAc in the presence of a base, such as potassium carbonate, sodium hydride, pyridine, TEA, or sodium carbonate. The compounds of formula (XV), wherein R1, R2, R3, R4, R5and R6are as defined for formula (I) and R10is C1- C6-alkyl, can be obtained by transformation of a compound of formula (XX), wherein R3, R4, R5and R6are as defined for formula (I) and R10is C1-C6-alkyl with a compound of formula (III), wherein R1and R2are as defined for formula (I), via an intermediate of formula (XXI), wherein G is selected from halogen (preferably chloride), G1, G2, G3 or G4 (for G1 to G4 see scheme 1) as described below (Scheme 14). Scheme 14 G = halogen, G1G2G3G4 82875_FF 20 As shown in Scheme 14, compounds (XX) are activated to compounds of formula (XXI) by methods known to those skilled in the art and described for example in Tetrahedron 2005, 61 (46), 10827-10852. For example, compounds of formula (XXI) where G is halogen are formed by treatment of compounds of formula (XX) with for example, oxalyl chloride or thionyl chloride in the presence of catalytic quantities of DMF in inert solvents such as DCM or THF, at temperatures between 25-170°C preferably 25-80°C. Treatment of (XXI) with compounds of formula (III), wherein R1and R2are as defined in formula (I), optionally in the presence of a base, e.g. triethylamine or pyridine leads to compounds of formula (XV). Alternatively, compounds of formula (XV) can be prepared by treatment of compounds of formula (XX) with dicyclohexyl carbodiimide (DCC) or 1- ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) to give the activated species (XXI), wherein G is G1 or G2,in an inert solvent, e.g., pyridine, or THF optionally in the presence of a base, e.g., triethylamine, attemperatures between rt and 180°C. In addition, an acid of the formula (XX) can also be activated by reaction with a coupling reagent such as propanephosphonic acid anhydride (T3P®) or O-(7-Aza-1-benzotriazolyl)- N,N,N’,N’-tetramethyluronium-hexafluorophosphat (HATU) to provide compounds of formula (XXI) wherein G is G3 and G4 as described for example in Synthesis 2013, 45 (12), 1569-1601 and J. Prakt. Chem.1998, 340 (5), 581-583. Subsequent reaction with an amine of the formula (III) provides compounds of formula (XV). The compounds of formula (XX), wherein R3, R4, R5and R6are as defined for formula (I) and R10is C1-C6-alkyl can be obtained by transformation of a compound of formula (VIII), wherein R3, R4, R5and R6are as defined for formula (I) and R10and R9are independently C1-C6-alkyl, in the presence of a base or an acid (Scheme 15). Scheme 15 As shown in basic conditions to compounds (XX) to art example in ACS Chem. Neurosci.2017, 2374. For example, the reaction can be performed in water or in organic solvent, such as methanol, ethanol, THF or DCM, or in mixtures; in the presence of a base, such as lithium hydroxide, sodium hydroxide or potassium hydroxide. Alternatively, the conversion of compounds (VIII) into compounds (XX) can be performed under acidic conditions by methods known to those skilled in the art and described for example in WO2019200246. For example, the reaction can be performed in water or in mixtures of water and an organic solvent, such as methanol, THF or dioxane; in the presence of an acid, such as trifluoroacetic acid, hydrochloric acid or sulfuric acid. As shown in Scheme 16, compounds (VIII) may also directly be transformed into compounds of formula (XV), wherein R1, R2, R3, R4, R5and R6are as defined for formula (I) and R10is C1-C6-alkyl, through the aminolysis 82875_FF 21 of carboxylic esters by methods known to those skilled in the art and described for example in J. Org. Chem.2009, 9490. Treatment of (VIII), wherein R3, R4, R5 and R6 are as defined for formula (I) and R10 and R9 areindependently C1-C6-alkyl, with compounds of formula (III), wherein R1and R2are as defined in formula (I), preferably in the presence of a catalyst such as triazabicyclodecene (TBD) or 6-chloro-2-pyridone affords compounds of formula (XV). Scheme 16 For tetrahydrofuran, or or any temperatures -40°C and 150°C, preferably in the range between 0°C and 110°C. Depending on the procedure or the reaction conditions, the reactants can be reacted in the presence of a base. Examples of suitable bases are alkali metal or alkaline earth metal hydroxides, alkali metal or alkaline earth metal hydrides, alkali metal or alkaline earth metal amides, alkali metal or alkaline earth metal alkoxides, alkali metal or alkaline earth metal acetates, alkali metal or alkaline earth metal carbonates, alkali metal or alkalineearth metal dialkylamides or alkali metal or alkaline earth metal alkylsilylamides, alkylamines,alkylenediamines, free or N-alkylated saturated or unsaturated cycloalkylamines, basic heterocycles, ammonium hydroxides and carbocyclic amines. Examples which may be mentioned are sodium hydroxide, sodium hydride, sodium amide, sodium methoxide, sodium acetate, sodium carbonate, potassium tert- butoxide, potassium hydroxide, potassium carbonate, potassium hydride, lithium diisopropylamide, potassium bis(trimethylsilyl)amide, calcium hydride, triethylamine, diisopropylethylamine, triethylenediamine, cyclohexylamine, N-cyclohexyl-N,N-dimethylamine, N,N-diethylaniline, pyridine, 4-(N,N- dimethylamino)pyridine, quinuclidine, N-methylmorpholine, benzyltrimethylammonium hydroxide and 1,8- diazabicyclo[5.4.0]undec-7-ene (DBU). The reactants can be reacted with each other as such, e.g., without adding a solvent or diluent. In most cases, however, it is advantageous to add an inert solvent or diluent or a mixture of these. If the reaction is carried out in the presence of a base, bases which are employed in excess, such as triethylamine, pyridine, N- methylmorpholine or N,N-diethylaniline, may also act as solvents or diluents. The reactions are advantageously carried out in a temperature range from approximately -80°C to approximately +140°C, preferably from approximately -30°C to approximately +100°C, in many cases in the range between ambient temperature and approximately +80°C. 82875_FF 22 Depending on the choice of the reaction conditions and starting materials which are suitable in each case, it is possible, for example, in one reaction step only to replace one substituent by another substituent according to the invention, or a plurality of substituents can be replaced by other substituents according to the invention in the same reaction step. Salts of compounds of formula (I) can be prepared in a manner known per se. Thus, for example, acid addition salts of compounds of formula (I) are obtained by treatment with a suitable acid or a suitable ion exchanger reagent and salts with bases are obtained by treatment with a suitable base or with a suitable ion exchanger reagent. Salts of compounds of formula (I) can be converted in the customary manner into the free compounds I, acidaddition salts, for example, by treatment with a suitable basic compound or with a suitable ion exchangerreagent and salts with bases, for example, by treatment with a suitable acid or with a suitable ion exchanger reagent. Salts of compounds of formula (I) can be converted in a manner known per se into other salts of compounds of formula (I), acid addition salts, for example, into other acid addition salts, for example by treatment of a salt of inorganic acid such as hydrochloride with a suitable metal salt such as a sodium, barium or silver salt, of an acid, for example with silver acetate, in a suitable solvent in which an inorganic salt which forms, for example silver chloride, is insoluble and thus precipitates from the reaction mixture. Depending on the procedure or the reaction conditions, the compounds of formula (I), which have salt-forming properties can be obtained in free form or in the form of salts. The compounds of formula (I) and, where appropriate, the tautomers thereof, in each case in free form or in salt form, can be present in the form of one of the isomers which are possible or as a mixture of these, for example in the form of pure isomers, such as antipodes and / or diastereomers, or as isomer mixtures, such as enantiomer mixtures, for example racemates, diastereomer mixtures or racemate mixtures, depending on the number, absolute and relative configuration of asymmetric carbon atoms which occur in the molecule and / or depending on the configuration of non-aromatic double bonds which occur in the molecule; the invention relates to the pure isomers and also to all isomer mixtures which are possible and is to be understood in each case in this sense hereinabove and hereinbelow, even when stereochemical details are not mentioned specifically in each case. Diastereomer mixtures or racemate mixtures of compounds of formula (I), in free form or in salt form, whichcan be obtained depending on which starting materials and procedures have been chosen can be separatedin a known manner into the pure diastereomers or racemates based on the physicochemical differences of the components, for example by fractional crystallization, distillation and / or chromatography. Enantiomer mixtures, such as racemates, which can be obtained in a similar manner can be resolved into the optical antipodes by known methods, for example by recrystallization from an optically active solvent, by chromatography on chiral adsorbents, for example high-performance liquid chromatography (HPLC) on acetyl cellulose, with the aid of suitable microorganisms, by cleavage with specific, immobilized enzymes, via the 82875_FF 23 formation of inclusion compounds, for example using chiral crown ethers, where only one enantiomer is complexed, or by conversion into diastereomeric salts, for example by reacting a basic end-product racemate with an optically active acid, such as a carboxylic acid, for example camphor, tartaric or malic acid, or sulfonic acid, for example camphorsulfonic acid, and separating the diastereomer mixture which can be obtained in this manner, for example by fractional crystallization based on their differing solubilities, to give the diastereomers, from which the desired enantiomer can be set free by the action of suitable agents, for example basic agents. Pure diastereomers or enantiomers can be obtained according to the invention not only by separating suitable isomer mixtures, but also by generally known methods of diastereoselective or enantioselective synthesis, for example by carrying out the process according to the invention with starting materials of a suitable stereochemistry.N-oxides can be prepared by reacting a compound of the formula (I) with a suitable oxidizing agent, for example the H2O2 / urea adduct in the presence of an acid anhydride, e.g., trifluoroacetic anhydride. Such oxidations are known from the literature, for example from J. Med. Chem.1989, 32 (12), 2561-73, or WO 2000 / 15615. It is advantageous to isolate or synthesize in each case the biologically more effective isomer, for example enantiomer or diastereomer, or isomer mixture, for example enantiomer mixture or diastereomer mixture, if the individual components have a different biological activity. The compounds of formula (I) and, where appropriate, the tautomers thereof, in each case in free form or in salt form, can, if appropriate, also be obtained in the form of hydrates and / or include other solvents, for example those which may have been used for the crystallization of compounds which are present in solid form. The tables A1 to A2 below illustrate specific compounds of the invention. The compounds according to the following Tables A1 to A2 may be prepared according to the methods described above. The examples which follow are intended to illustrate the invention and show preferred compounds of formula (I). In any of Tables A1 to A2 below, the presence of one or more possible asymmetric carbon atoms in a compound of formula (I) according to the invention means that the compounds may occur in chiral isomeric forms, e.g., enantiomeric or diastereomeric. The compounds of formula (I) according to the following Tables A1 to A2 can be prepared according to the methods described herein. The examples which follow are intended to illustrate the invention and show preferred compounds of formula (I), in the form of a compound of formulae (I-A1) and (I-A2). Table A1 provides 176 compounds of formula (I-A1), wherein R2and R4are hydrogen, R3is chlorine, R5and R6 together with the carbon to which they are attached represent a cyclopropyl, and wherein R1, R7, and R8 areas defined as in table A1. 82875_FF 24 Table A1: Substituent definitions of R1, R7, and R8: Index R7 R8 R1 1 trifluoromethyl H ethyl 2 trifluoromethyl CH2OMe ethyl 3 trifluoromethyl CO2Me ethyl 4 trifluoromethyl acetyl ethyl 5 difluoromethyl H ethyl 6 difluoromethyl CH2OMe ethyl 7 difluoromethyl CO2Me ethyl 8 difluoromethyl acetyl ethyl 9 dichloromethyl H ethyl 10 dichloromethyl CH2OMe ethyl 11 dichloromethyl CO2Me ethyl 12 dichloromethyl acetyl ethyl 13 cyclopropyl H ethyl 14 cyclopropyl CH2OMe ethyl 15 cyclopropyl CO2Me ethyl 16 cyclopropyl acetyl ethyl 17 trifluoromethyl H isopropyl 18 trifluoromethyl CH2OMe isopropyl 19 trifluoromethyl CO2Me isopropyl 20 trifluoromethyl acetyl isopropyl 21 difluoromethyl H isopropyl 22 difluoromethyl CH2OMe isopropyl 23 difluoromethyl CO2Me isopropyl 24 difluoromethyl acetyl isopropyl 25 dichloromethyl H isopropyl 26 dichloromethyl CH2OMe isopropyl 27 dichloromethyl CO2Me isopropyl 28 dichloromethyl acetyl isopropyl 29 cyclopropyl H isopropyl 30 cyclopropyl CH2OMe isopropyl 31 cyclopropyl CO2Me isopropyl 32 cyclopropyl acetyl isopropyl 33 trifluoromethyl H tert-butyl 34 trifluoromethyl CH2OMe tert-butyl 35 trifluoromethyl CO2Me tert-butyl 36 trifluoromethyl acetyl tert-butyl 37 difluoromethyl H tert-butyl 38 difluoromethyl CH2OMe tert-butyl 39 difluoromethyl CO2Me tert-butyl 82875_FF 25 40 difluoromethyl acetyl tert-butyl 41 dichloromethyl H tert-butyl 42 dichloromethyl CH2OMe tert-butyl 43 dichloromethyl CO2Me tert-butyl 44 dichloromethyl acetyl tert-butyl 45 cyclopropyl H tert-butyl 46 cyclopropyl CH2OMe tert-butyl 47 cyclopropyl CO2Me tert-butyl 48 cyclopropyl acetyl tert-butyl 49 trifluoromethyl H 2,2,2-trifluoroethyl 50 trifluoromethyl CH2OMe 2,2,2-trifluoroethyl 51 trifluoromethyl CO2Me 2,2,2-trifluoroethyl 52 trifluoromethyl acetyl 2,2,2-trifluoroethyl 53 difluoromethyl H 2,2,2-trifluoroethyl 54 difluoromethyl CH2OMe 2,2,2-trifluoroethyl 55 difluoromethyl CO2Me 2,2,2-trifluoroethyl 56 difluoromethyl acetyl 2,2,2-trifluoroethyl 57 dichloromethyl H 2,2,2-trifluoroethyl 58 dichloromethyl CH2OMe 2,2,2-trifluoroethyl 59 dichloromethyl CO2Me 2,2,2-trifluoroethyl 60 dichloromethyl acetyl 2,2,2-trifluoroethyl 61 cyclopropyl H 2,2,2-trifluoroethyl 62 cyclopropyl CH2OMe 2,2,2-trifluoroethyl 63 cyclopropyl CO2Me 2,2,2-trifluoroethyl 64 cyclopropyl acetyl 2,2,2-trifluoroethyl 65 trifluoromethyl H cyclopropyl 66 trifluoromethyl CH2OMe cyclopropyl 67 trifluoromethyl CO2Me cyclopropyl 68 trifluoromethyl acetyl cyclopropyl 69 difluoromethyl H cyclopropyl 70 difluoromethyl CH2OMe cyclopropyl 71 difluoromethyl CO2Me cyclopropyl 72 difluoromethyl acetyl cyclopropyl 73 dichloromethyl H cyclopropyl 74 dichloromethyl CH2OMe cyclopropyl 75 dichloromethyl CO2Me cyclopropyl 76 dichloromethyl acetyl cyclopropyl 77 cyclopropyl H cyclopropyl 78 cyclopropyl CH2OMe cyclopropyl 79 cyclopropyl CO2Me cyclopropyl 80 cyclopropyl acetyl cyclopropyl 82875_FF 26 81 trifluoromethyl H 1-cyanocyclopropyl 82 trifluoromethyl CH2OMe 1-cyanocyclopropyl 83 trifluoromethyl CO2Me 1-cyanocyclopropyl 84 trifluoromethyl acetyl 1-cyanocyclopropyl 85 difluoromethyl H 1-cyanocyclopropyl 86 difluoromethyl CH2OMe 1-cyanocyclopropyl 87 difluoromethyl CO2Me 1-cyanocyclopropyl 88 difluoromethyl acetyl 1-cyanocyclopropyl 89 dichloromethyl H 1-cyanocyclopropyl 90 dichloromethyl CH2OMe 1-cyanocyclopropyl 91 dichloromethyl CO2Me 1-cyanocyclopropyl 92 dichloromethyl acetyl 1-cyanocyclopropyl 93 cyclopropyl H 1-cyanocyclopropyl 94 cyclopropyl CH2OMe 1-cyanocyclopropyl 95 cyclopropyl CO2Me 1-cyanocyclopropyl 96 cyclopropyl acetyl 1-cyanocyclopropyl 97 trifluoromethyl H 1-cyanocyclobutyl 98 trifluoromethyl CH2OMe 1-cyanocyclobutyl 99 trifluoromethyl CO2Me 1-cyanocyclobutyl 100 trifluoromethyl acetyl 1-cyanocyclobutyl 101 difluoromethyl H 1-cyanocyclobutyl 102 difluoromethyl CH2OMe 1-cyanocyclobutyl 103 difluoromethyl CO2Me 1-cyanocyclobutyl 104 difluoromethyl acetyl 1-cyanocyclobutyl 105 dichloromethyl H 1-cyanocyclobutyl 106 dichloromethyl CH2OMe 1-cyanocyclobutyl 107 dichloromethyl CO2Me 1-cyanocyclobutyl 108 dichloromethyl acetyl 1-cyanocyclobutyl 109 cyclopropyl H 1-cyanocyclobutyl 110 cyclopropyl CH2OMe 1-cyanocyclobutyl 111 cyclopropyl CO2Me 1-cyanocyclobutyl 112 cyclopropyl acetyl 1-cyanocyclobutyl 113 trifluoromethyl H 3,3-difluorocyclobutyl 114 trifluoromethyl CH2OMe 3,3-difluorocyclobutyl 115 trifluoromethyl CO2Me 3,3-difluorocyclobutyl 116 trifluoromethyl acetyl 3,3-difluorocyclobutyl 117 difluoromethyl H 3,3-difluorocyclobutyl 118 difluoromethyl CH2OMe 3,3-difluorocyclobutyl 119 difluoromethyl CO2Me 3,3-difluorocyclobutyl 120 difluoromethyl acetyl 3,3-difluorocyclobutyl 121 dichloromethyl H 3,3-difluorocyclobutyl 82875_FF 27 122 dichloromethyl CH2OMe 3,3-difluorocyclobutyl 123 dichloromethyl CO2Me 3,3-difluorocyclobutyl 124 dichloromethyl acetyl 3,3-difluorocyclobutyl 125 cyclopropyl H 3,3-difluorocyclobutyl 126 cyclopropyl CH2OMe 3,3-difluorocyclobutyl 127 cyclopropyl CO2Me 3,3-difluorocyclobutyl 128 cyclopropyl acetyl 3,3-difluorocyclobutyl 129 trifluoromethyl H 1-cyclopropyl ethyl 130 trifluoromethyl CH2OMe 1-cyclopropyl ethyl 131 trifluoromethyl CO2Me 1-cyclopropyl ethyl 132 trifluoromethyl acetyl 1-cyclopropyl ethyl 133 difluoromethyl H 1-cyclopropyl ethyl 134 difluoromethyl CH2OMe 1-cyclopropyl ethyl 135 difluoromethyl CO2Me 1-cyclopropyl ethyl 136 difluoromethyl acetyl 1-cyclopropyl ethyl 137 dichloromethyl H 1-cyclopropyl ethyl 138 dichloromethyl CH2OMe 1-cyclopropyl ethyl 139 dichloromethyl CO2Me 1-cyclopropyl ethyl 140 dichloromethyl acetyl 1-cyclopropyl ethyl 141 cyclopropyl H 1-cyclopropyl ethyl 142 cyclopropyl CH2OMe 1-cyclopropyl ethyl 143 cyclopropyl CO2Me 1-cyclopropyl ethyl 144 cyclopropyl acetyl 1-cyclopropyl ethyl 145 trifluoromethyl H 2-bicyclo[1.1.1]pentanyl 146 trifluoromethyl CH2OMe 2-bicyclo[1.1.1]pentanyl 147 trifluoromethyl CO2Me 2-bicyclo[1.1.1]pentanyl 148 trifluoromethyl acetyl 2-bicyclo[1.1.1]pentanyl 149 difluoromethyl H 2-bicyclo[1.1.1]pentanyl 150 difluoromethyl CH2OMe 2-bicyclo[1.1.1]pentanyl 151 difluoromethyl CO2Me 2-bicyclo[1.1.1]pentanyl 152 difluoromethyl acetyl 2-bicyclo[1.1.1]pentanyl 153 dichloromethyl H 2-bicyclo[1.1.1]pentanyl 154 dichloromethyl CH2OMe 2-bicyclo[1.1.1]pentanyl 155 dichloromethyl CO2Me 2-bicyclo[1.1.1]pentanyl 156 dichloromethyl acetyl 2-bicyclo[1.1.1]pentanyl 157 cyclopropyl H 2-bicyclo[1.1.1]pentanyl 158 cyclopropyl CH2OMe 2-bicyclo[1.1.1]pentanyl 159 cyclopropyl CO2Me 2-bicyclo[1.1.1]pentanyl 160 cyclopropyl acetyl 2-bicyclo[1.1.1]pentanyl 161 trifluoromethyl H 6-chloropyridin-3-yl 162 trifluoromethyl CH2OMe 6-chloropyridin-3-yl 82875_FF 28 163 trifluoromethyl CO2Me 6-chloropyridin-3-yl 164 trifluoromethyl acetyl 6-chloropyridin-3-yl 165 difluoromethyl H 6-chloropyridin-3-yl 166 difluoromethyl CH2OMe 6-chloropyridin-3-yl 167 difluoromethyl CO2Me 6-chloropyridin-3-yl 168 difluoromethyl acetyl 6-chloropyridin-3-yl 169 dichloromethyl H 6-chloropyridin-3-yl 170 dichloromethyl CH2OMe 6-chloropyridin-3-yl 171 dichloromethyl CO2Me 6-chloropyridin-3-yl 172 dichloromethyl acetyl 6-chloropyridin-3-yl 173 cyclopropyl H 6-chloropyridin-3-yl 174 cyclopropyl CH2OMe 6-chloropyridin-3-yl 175 cyclopropyl CO2Me 6-chloropyridin-3-yl 176 cyclopropyl acetyl 6-chloropyridin-3-yl Table A2 provides 88 compounds of formula (I-A2), wherein R2and R8are hydrogen, R3is chlorine, R5and R6are methyl, and wherein R1, R4, and R7are as defined as in table A2. 7 R :Index R4 R7 R1 1 H trifluoromethyl ethyl 2 H difluoromethyl ethyl 3 H dichloromethyl ethyl 4 H cyclopropyl ethyl 5 Me trifluoromethyl ethyl 6 Me difluoromethyl ethyl 7 Me dichloromethyl ethyl 8 Me cyclopropyl ethyl 9 H trifluoromethyl isopropyl 10 H difluoromethyl isopropyl 11 H dichloromethyl isopropyl 12 H cyclopropyl isopropyl 13 Me trifluoromethyl isopropyl 14 Me difluoromethyl isopropyl 15 Me dichloromethyl isopropyl 16 Me cyclopropyl isopropyl 82875_FF 29 17 H trifluoromethyl tert-butyl 18 H difluoromethyl tert-butyl 19 H dichloromethyl tert-butyl 20 H cyclopropyl tert-butyl 21 Me trifluoromethyl tert-butyl 22 Me difluoromethyl tert-butyl 23 Me dichloromethyl tert-butyl 24 Me cyclopropyl tert-butyl 25 H trifluoromethyl 2,2,2-trifluoroethyl 26 H difluoromethyl 2,2,2-trifluoroethyl 27 H dichloromethyl 2,2,2-trifluoroethyl 28 H cyclopropyl 2,2,2-trifluoroethyl 29 Me trifluoromethyl 2,2,2-trifluoroethyl 30 Me difluoromethyl 2,2,2-trifluoroethyl 31 Me dichloromethyl 2,2,2-trifluoroethyl 32 Me cyclopropyl 2,2,2-trifluoroethyl 33 H trifluoromethyl cyclopropyl 34 H difluoromethyl cyclopropyl 35 H dichloromethyl cyclopropyl 36 H cyclopropyl cyclopropyl 37 Me trifluoromethyl cyclopropyl 38 Me difluoromethyl cyclopropyl 39 Me dichloromethyl cyclopropyl 40 Me cyclopropyl cyclopropyl 41 H trifluoromethyl 1-cyanocyclopropyl 42 H difluoromethyl 1-cyanocyclopropyl 43 H dichloromethyl 1-cyanocyclopropyl 44 H cyclopropyl 1-cyanocyclopropyl 45 Me trifluoromethyl 1-cyanocyclopropyl 46 Me difluoromethyl 1-cyanocyclopropyl 47 Me dichloromethyl 1-cyanocyclopropyl 48 Me cyclopropyl 1-cyanocyclopropyl 49 H trifluoromethyl 1-cyanocyclobutyl 50 H difluoromethyl 1-cyanocyclobutyl 51 H dichloromethyl 1-cyanocyclobutyl 52 H cyclopropyl 1-cyanocyclobutyl 53 Me trifluoromethyl 1-cyanocyclobutyl 54 Me difluoromethyl 1-cyanocyclobutyl 55 Me dichloromethyl 1-cyanocyclobutyl 56 Me cyclopropyl 1-cyanocyclobutyl 57 H trifluoromethyl 3,3-difluorocyclobutyl 82875_FF 30 58 H difluoromethyl 3,3-difluorocyclobutyl 59 H dichloromethyl 3,3-difluorocyclobutyl 60 H cyclopropyl 3,3-difluorocyclobutyl 61 Me trifluoromethyl 3,3-difluorocyclobutyl 62 Me difluoromethyl 3,3-difluorocyclobutyl 63 Me dichloromethyl 3,3-difluorocyclobutyl 64 Me cyclopropyl 3,3-difluorocyclobutyl 65 H trifluoromethyl 1-cyclopropyl ethyl 66 H difluoromethyl 1-cyclopropyl ethyl 67 H dichloromethyl 1-cyclopropyl ethyl 68 H cyclopropyl 1-cyclopropyl ethyl 69 Me trifluoromethyl 1-cyclopropyl ethyl 70 Me difluoromethyl 1-cyclopropyl ethyl 71 Me dichloromethyl 1-cyclopropyl ethyl 72 Me cyclopropyl 1-cyclopropyl ethyl 73 H trifluoromethyl 2-bicyclo[1.1.1]pentanyl 74 H difluoromethyl 2-bicyclo[1.1.1]pentanyl 75 H dichloromethyl 2-bicyclo[1.1.1]pentanyl 76 H cyclopropyl 2-bicyclo[1.1.1]pentanyl 77 Me trifluoromethyl 2-bicyclo[1.1.1]pentanyl 78 Me difluoromethyl 2-bicyclo[1.1.1]pentanyl 79 Me dichloromethyl 2-bicyclo[1.1.1]pentanyl 80 Me cyclopropyl 2-bicyclo[1.1.1]pentanyl 81 H trifluoromethyl 6-chloropyridin-3-yl 82 H difluoromethyl 6-chloropyridin-3-yl 83 H dichloromethyl 6-chloropyridin-3-yl 84 H cyclopropyl 6-chloropyridin-3-yl 85 Me trifluoromethyl 6-chloropyridin-3-yl 86 Me difluoromethyl 6-chloropyridin-3-yl 87 Me dichloromethyl 6-chloropyridin-3-yl 88 Me cyclopropyl 6-chloropyridin-3-yl The compounds of formula (I) according to the invention are preventively and / or curatively valuable active ingredients in the field of pest control, even at low rates of application, which have a very favorable biocidal spectrum and are well tolerated by warm-blooded species, fish and plants. The active ingredients according to the invention act against all or individual developmental stages of normally sensitive, but also resistant, animal pests, such as insects or representatives of the order Acarina. The insecticidal or acaricidal activity of the active ingredients according to the invention can manifest itself directly, i. e. in destruction of the pests, which takes place either immediately or only after some time has elapsed, for example during ecdysis, or indirectly, for example in a reduced oviposition and / or hatching rate. 82875_FF 31 Examples of the above-mentioned animal pests are: from the order Acarina, for example: Acalitus spp., Aculus spp., Acaricalus spp., Aceria spp., Acarus siro, Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia spp., Calipitrimerus spp., Chorioptes spp., Dermanyssus gallinae, Dermatophagoides spp., Eotetranychus spp., Eriophyes spp., Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Olygonychus spp., Ornithodoros spp., Polyphagotarsone latus, Panonychus spp., Phyllocoptruta oleivora, Phytonemus spp., Polyphagotarsonemus spp., Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Steneotarsonemus spp., Tarsonemus spp. and Tetranychus spp.; from the order Anoplura, for example: Haematopinus spp., Linognathus spp., Pediculus spp., Pemphigus spp.and Phylloxera spp.;from the order Coleoptera, for example: Agriotes spp., Amphimallon majale, Anomala orientalis, Anthonomus spp., Aphodius spp., Astylus atromaculatus, Ataenius spp., Atomaria linearis, Chaetocnema tibialis, Cerotoma spp., Conoderus spp., Cosmopolites spp., Cotinis nitida, Curculio spp., Cyclocephala spp., Dermestes spp., Diabrotica spp., Diloboderus abderus, Epilachna spp., Eremnus spp., Heteronychus arator, Hypothenemus hampei, Lagria vilosa, Leptinotarsa decemlineata, Lissorhoptrus spp., Liogenys spp., Maecolaspis spp., Maladera castanea, Megascelis spp., Meligethes aeneus, Melolontha spp., Myochrous armatus, Orycaephilus spp., Otiorhynchus spp., Phyllophaga spp., Phlyctinus spp., Popillia spp., Psylliodes spp., Rhyssomatus aubtilis, Rhizopertha spp., Scarabeidae, Sitophilus spp., Sitotroga spp., Somaticus spp., Sphenophorus spp., Sternechus subsignatus, Tenebrio spp., Tribolium spp. and Trogoderma spp.; from the order Diptera, for example: Aedes spp., Anopheles spp., Antherigona soccata,Bactrocea oleae, Bibio hortulanus, Bradysia spp., Calliphora erythrocephala, Ceratitis spp., Chrysomyia spp., Culex spp., Cuterebra spp., Dacus spp., Delia spp., Drosophila melanogaster, Fannia spp., Gastrophilus spp., Geomyza tripunctata, Glossina spp., Hypoderma spp., Hyppobosca spp., Liriomyza spp., Lucilia spp., Melanagromyza spp., Musca spp., Oestrus spp., Orseolia spp., Oscinella frit, Pegomyia hyoscyami, Phorbia spp., Rhagoletis spp., Rivelia quadrifasciata, Scatella spp., Sciara spp., Stomoxys spp., Tabanus spp., Tannia spp. and Tipula spp.; from the order Hemiptera, for example: Acanthocoris scabrator, Acrosternum spp., Adelphocoris lineolatus, Aleurodes spp., Amblypelta nitida, Bathycoelia thalassina, Blissus spp., Cimex spp., Clavigralla tomentosicollis, Creontiades spp., Distantiella theobroma, Dichelops furcatus, Dysdercus spp., Edessa spp., Euchistus spp., Eurydema pulchrum, Eurygaster spp., Halyomorpha halys, Horcias nobilellus, Leptocorisaspp., Lygus spp., Margarodes spp., Murgantia histrionic, Neomegalotomus spp., Nesidiocoris tenuis, Nezaraspp., Nysius simulans, Oebalus insularis, Piesma spp., Piezodorus spp., Rhodnius spp., Sahlbergella singularis, Scaptocoris castanea, Scotinophara spp., Thyanta spp., Triatoma spp., Vatiga illudens; Acyrthosium pisum, Adalges spp., Agalliana ensigera, Agonoscena targionii, Aleurodicus spp., Aleurocanthus spp., Aleurolobus barodensis, Aleurothrixus floccosus, Aleyrodes brassicae, Amarasca biguttula, Amritodus atkinsoni, Aonidiella spp., Aphididae, Aphis spp., Aspidiotus spp., Aulacorthum solani, Bactericera cockerelli, Bemisia spp., Brachycaudus spp., Brevicoryne brassicae, Cacopsylla spp., Cavariella aegopodii Scop., 82875_FF 32 Ceroplaster spp., Chrysomphalus aonidium, Chrysomphalus dictyospermi, Cicadella spp., Cofana spectra, Cryptomyzus spp., Cicadulina spp., Coccus hesperidum, Dalbulus maidis, Dialeurodes spp., Diaphorina citri, Diuraphis noxia, Dysaphis spp., Empoasca spp., Eriosoma larigerum, Erythroneura spp., Gascardia spp., Glycaspis brimblecombei, Hyadaphis pseudobrassicae, Hyalopterus spp., Hyperomyzus pallidus, Idioscopus clypealis, Jacobiasca lybica, Laodelphax spp., Lecanium corni, Lepidosaphes spp., Lopaphis erysimi, Lyogenys maidis, Macrosiphum spp., Mahanarva spp., Metcalfa pruinosa, Metopolophium dirhodum, Myndus crudus, Myzus spp., Neotoxoptera sp, Nephotettix spp., Nilaparvata spp., Nippolachnus piri Mats, Odonaspis ruthae, Oregma lanigera Zehnter, Parabemisia myricae, Paratrioza cockerelli, Parlatoria spp., Pemphigus spp., Peregrinus maidis, Perkinsiella spp., Phorodon humuli, Phylloxera spp., Planococcus spp., Pseudaulacaspisspp., Pseudococcus spp., Pseudatomoscelis seriatus, Psylla spp., Pulvinaria aethiopica, Quadraspidiotusspp., Quesada gigas, Recilia dorsalis, Rhopalosiphum spp., Saissetia spp., Scaphoideus spp., Schizaphis spp., Sitobion spp., Sogatella furcifera, Spissistilus festinus, Tarophagus Proserpina, Toxoptera spp., Trialeurodes spp., Tridiscus sporoboli, Trionymus spp., Trioza erytreae, Unaspis citri, Zygina flammigera, Zyginidia scutellaris,; from the order Hymenoptera, for example: Acromyrmex, Arge spp., Atta spp., Cephus spp., Diprion spp., Diprionidae, Gilpinia polytoma, Hoplocampa spp., Lasius spp., Monomorium pharaonis, Neodiprion spp., Pogonomyrmex spp., Slenopsis invicta, Solenopsis spp. and Vespa spp.; from the order Isoptera, for example: Coptotermes spp., Corniternes cumulans, Incisitermes spp., Macrotermes spp., Mastotermes spp., Microtermes spp., Reticulitermes spp.; Solenopsis geminate; from the order Lepidoptera, for example: Acleris spp., Adoxophyes spp., Aegeria spp., Agrotis spp., Alabama argillaceae, Amylois spp., Anticarsia gemmatalis, Archips spp., Argyresthia spp., Argyrotaenia spp., Autographa spp., Bucculatrix thurberiella, Busseola fusca, Cadra cautella, Carposina nipponensis, Chilo spp., Choristoneura spp., Chrysoteuchia topiaria, Clysia ambiguella, Cnaphalocrocis spp., Cnephasia spp., Cochylis spp., Coleophora spp., Colias lesbia, Cosmophila flava, Crambus spp., Crocidolomia binotalis, Cryptophlebia leucotreta, Cydalima perspectalis, Cydia spp., Diaphania perspectalis, Diatraea spp., Diparopsis castanea, Earias spp., Elasmopalpus lignosellus, Eldana saccharina, Ephestia spp., Epinotia spp., Estigmene acrea, Etiella zinckinella, Eucosma spp., Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Feltia jaculiferia, Gra- pholita spp., Hedya nubiferana, Heliothis spp., Hellula undalis, Herpetogramma spp., Hyphantria cunea, Keiferia lycopersicella, Lasmopalpus lignosellus, Leucoptera scitella, Lithocollethis spp., Lobesia botrana, Loxostege bifidalis, Lymantria spp., Lyonetia spp., Malacosoma spp., Mamestra brassicae, Manduca sexta, Mythimna spp., Noctua spp., Operophtera spp., Orniodes indica, Ostrinia nubilalis, Pammene spp., Pandemis spp., Panolis flammea, Papaipema nebris, Pectinophora gossypiela, Perileucoptera coffeella, Pseudaletia unipuncta, Phthorimaea operculella, Pieris rapae, Pieris spp., Plutella xylostella, Prays spp., Pseudoplusia spp., Rachiplusia nu, Richia albicosta, Scirpophaga spp., Sesamia spp., Sparganothis spp., Spodoptera spp., Sylepta derogate, Synanthedon spp., Thaumetopoea spp., Tortrix spp., Trichoplusia ni, Tuta absoluta, and Yponomeuta spp.; from the order Mallophaga, for example. Damalinea spp. and Trichodectes spp.; 82875_FF 33 from the order Orthoptera, for example: Blatta spp., Blattella spp., Gryllotalpa spp., Leucophaea maderae, Locusta spp., Neocurtilla hexadactyla, Periplaneta spp., Scapteriscus spp., and Schistocerca spp.; from the order Psocoptera, for example: Liposcelis spp.; from the order Siphonaptera, for example: Ceratophyllus spp., Ctenocephalides spp. and Xenopsylla cheopis; from the order Thysanoptera, for example: Calliothrips phaseoli, Frankliniella spp., Heliothrips spp., Hercinothrips spp., Parthenothrips spp., Scirtothrips aurantii, Sericothrips variabilis, Taeniothrips spp., Thrips spp.; from the order Thysanura, for example, Lepisma saccharina. In a further aspect, the invention may also relate to a method of controlling damage to plant and parts thereofby plant parasitic nematodes (Endoparasitic-, Semiendoparasitic- and Ectoparasitic nematodes), especiallyplant parasitic nematodes such as root knot nematodes, Meloidogyne hapla, Meloidogyne incognita, Meloidogyne javanica, Meloidogyne arenaria and other Meloidogyne species; cyst-forming nematodes, Globodera rostochiensis and other Globodera species; Heterodera avenae, Heterodera glycines, Heterodera schachtii, Heterodera trifolii, and other Heterodera species; Seed gall nematodes, Anguina species; Stem and foliar nematodes, Aphelenchoides species; Sting nematodes, Belonolaimus longicaudatus and other Belonolaimus species; Pine nematodes, Bursaphelenchus xylophilus and other Bursaphelenchus species; Ring nematodes, Criconema species, Criconemella species, Criconemoides species, Mesocriconema species; Stem and bulb nematodes, Ditylenchus destructor, Ditylenchus dipsaci and other Ditylenchus species; Awl nematodes, Dolichodorus species; Spiral nematodes, Heliocotylenchus multicinctus and other Helicotylenchus species; Sheath and sheathoid nematodes, Hemicycliophora species and Hemicriconemoides species; Hirshmanniella species; Lance nematodes, Hoploaimus species; false rootknot nematodes, Nacobbus species; Needle nematodes, Longidorus elongatus and other Longidorus species; Pin nematodes, Pratylenchus species; Lesion nematodes, Pratylenchus neglectus, Pratylenchus penetrans, Pratylenchus curvitatus, Pratylenchus goodeyi and other Pratylenchus species; Burrowing nematodes, Radopholus similis and other Radopholus species; Reniform nematodes, Rotylenchus robustus, Rotylenchus reniformis and other Rotylenchus species; Scutellonema species; Stubby root nematodes, Trichodorus primitivus and other Trichodorus species, Paratrichodorus species; Stunt nematodes, Tylenchorhynchus claytoni, Tylenchorhynchus dubius and other Tylenchorhynchus species; Citrus nematodes, Tylenchulus species; Dagger nematodes, Xiphinema species; and other plant parasitic nematode species, such as Subanguina spp.,Hypsoperine spp., Macroposthonia spp., Melinius spp., Punctodera spp., and Quinisulcius spp..The compounds of the invention may also have activity against the molluscs. Examples of which include, for example, Ampullariidae; Arion (A. ater, A. circumscriptus, A. hortensis, A. rufus); Bradybaenidae (Bradybaena fruticum); Cepaea (C. hortensis, C. Nemoralis); ochlodina; Deroceras (D. agrestis, D. empiricorum, D. laeve, D. reticulatum); Discus (D. rotundatus); Euomphalia; Galba (G. trunculata); Helicelia (H. itala, H. obvia); Helicidae Helicigona arbustorum); Helicodiscus; Helix (H. aperta); Limax (L. cinereoniger, L. flavus, L. 82875_FF 34 marginatus, L. maximus, L. tenellus); Lymnaea; Milax (M. gagates, M. marginatus, M. sowerbyi); Opeas; Pomacea (P. canaticulata); Vallonia and Zanitoides. The active ingredients according to the invention can be used for controlling, i. e. containing or destroying, pests of the abovementioned type which occur in particular on plants, especially on useful plants and ornamentals in agriculture, in horticulture and in forests, or on organs, such as fruits, flowers, foliage, stalks, tubers or roots, of such plants, and in some cases even plant organs which are formed at a later point in time remain protected against these pests. Suitable target crops are, in particular, cereals, such as wheat, barley, rye, oats, rice, maize or sorghum; beet, such as sugar or fodder beet; fruit, for example pomaceous fruit, stone fruit or soft fruit, such as apples, pears,plums, peaches, almonds, cherries or berries, for example strawberries, raspberries or blackberries;leguminous crops, such as beans, lentils, peas or soya; oil crops, such as oilseed rape, mustard, poppies, olives, sunflowers, coconut, castor, cocoa or ground nuts; cucurbits, such as pumpkins, cucumbers or melons; fibre plants, such as cotton, flax, hemp or jute; citrus fruit, such as oranges, lemons, grapefruit or tangerines; vegetables, such as spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes or bell peppers; Lauraceae, such as avocado, Cinnamonium or camphor; and also tobacco, nuts, coffee, eggplants, sugarcane, tea, pepper, grapevines, hops, the plantain family and latex plants. In a particular embodiment, a compound of the formula (I) can control mites, rust mites and spider mites in crops, tress, and plants selected from vegetables (especially tomatoes and cucurbits), citrus, pome fruits, stone fruit, tree nuts, cotton, tropical crops, avocados, ornamentals, beans, soybean, strawberry, and grapes. The compositions and / or methods of the present invention may be also used on any ornamental and / or vegetable crops, including flowers, shrubs, broad-leaved trees and evergreens. For example the invention may be used on any of the following ornamental species: Ageratum spp., Alonsoa spp., Anemone spp., Anisodontea capsenisis, Anthemis spp., Antirrhinum spp., Aster spp., Begonia spp. (e.g., B. elatior, B. semperflorens, B. tubéreux), Bougainvillea spp., Brachycome spp., Brassica spp. (ornamental), Calceolaria spp., Capsicum annuum, Catharanthus roseus, Canna spp., Centaurea spp., Chrysanthemum spp., Cineraria spp. (C. maritime), Coreopsis spp., Crassula coccinea, Cuphea ignea, Dahlia spp., Delphinium spp., Dicentra spectabilis, Dorotheantus spp., Eustoma grandiflorum, Forsythia spp., Fuchsia spp., Geranium gnaphalium, Gerbera spp., Gomphrena globosa, Heliotropium spp., Helianthus spp., Hibiscus spp., Hortensia spp., Hydrangea spp., Hypoestes phyllostachya, Impatiens spp. (I. Walleriana), Iresines spp., Kalanchoe spp.,Lantana camara, Lavatera trimestris, Leonotis leonurus, Lilium spp., Mesembryanthemum spp., Mimulus spp.,Monarda spp., Nemesia spp., Tagetes spp., Dianthus spp. (carnation), Canna spp., Oxalis spp., Bellis spp., Pelargonium spp. (P. peltatum, P. Zonale), Viola spp. (pansy), Petunia spp., Phlox spp., Plecthranthus spp., Poinsettia spp., Parthenocissus spp. (P. quinquefolia, P. tricuspidata), Primula spp., Ranunculus spp., Rhododendron spp., Rosa spp. (rose), Rudbeckia spp., Saintpaulia spp., Salvia spp., Scaevola aemola, Schizanthus wisetonensis, Sedum spp., Solanum spp., Surfinia spp., Tagetes spp., Nicotinia spp., Verbena spp., Zinnia spp. and other bedding plants. 82875_FF 35 For example the invention may be used on any of the following vegetable species: Allium spp. (A. sativum, A. cepa, A. oschaninii, A. Porrum, A. ascalonicum, A. fistulosum), Anthriscus cerefolium, Apium graveolus, Asparagus officinalis, Beta vulgarus, Brassica spp. (B. Oleracea, B. Pekinensis, B. rapa), Capsicum annuum, Cicer arietinum, Cichorium endivia, Cichorum spp. (C. intybus, C. endivia), Citrillus lanatus, Cucumis spp. (C. sativus, C. melo), Cucurbita spp. (C. pepo, C. maxima), Cyanara spp. (C. scolymus, C. cardunculus), Daucus carota, Foeniculum vulgare, Hypericum spp., Lactuca sativa, Lycopersicon spp. (L. esculentum, L. lycopersicum), Mentha spp., Ocimum basilicum, Petroselinum crispum, Phaseolus spp. (P. vulgaris, P. coccineus), Pisum sativum, Raphanus sativus, Rheum rhaponticum, Rosemarinus spp., Salvia spp., Scorzonera hispanica, Solanum melongena, Spinacea oleracea, Valerianella spp. (V. locusta, V. eriocarpa)and Vicia faba.Preferred ornamental species include African violet, Begonia, Dahlia, Gerbera, Hydrangea, Verbena, Rosa, Kalanchoe, Poinsettia, Aster, Centaurea, Coreopsis, Delphinium, Monarda, Phlox, Rudbeckia, Sedum, Petunia, Viola, Impatiens, Geranium, Chrysanthemum, Ranunculus, Fuchsia, Salvia, Hortensia, rosemary, sage, St. Johnswort, mint, sweet pepper, tomato and cucumber. The compounds of formula (I) may be particularly suitable for control of mites, spider mites and rust mites, for example, Acarapis spp.; Acarapis woodi; Acarus siro; Acarus spp.; Aceria sheldoni; Aculops pelekassi; Aculops spp.; Aculus schlechtendali; Aculus spp.; Amblyseius fallacis; Brevipalpus spp.; Brevipalpus phoenicis; Bryobia praetiosa; Bryobia rubrioculus; Caloglyphus spp.; Cheyletiella blakei; Cheyletiella spp.; Cheyletiella yasguri; Chorioptes bovis; Chorioptes spp.; Cytodites spp.; Demodex bovis; Demodex caballi; Demodex canis; Demodex caprae; Demodex equi; Demodex ovis; Demodex spp.; Demodex suis; Dermanyssus gallinae; Dermanyssus spp.; Eotetranychus spp.; Eotetranychus willamettei; Epitrimerus pyri; Eriophyes ribis; Eriophyes spp.; Eriophyes vitis; Eutetranychus spp.; Halotydeus destructor; Hemitarsonemus spp.; Knemidocoptes spp.; Laminosioptes spp.; Listrophorus spp.; Myobia spp.; Neoschongastia xerothermobia; Neotrombicula autumnalis; Neotrombicula desaleri; Notoedres cati; Notoedres spp.; Oligonychus coffeae; Oligonychus ilicis; Oligonychus spp.; Ornithocheyletia spp.; Ornithonyssus bursa; Ornithonyssus spp.; Ornithonyssus sylviarum; Otodectes cynotis; Otodectes spp.; Panonychus citri; Panonychus spp.; Panonychus ulmi; Phyllocoptruta oleivora; Phyllocoptruta spp.; Phytoseiulus spp.; Pneumonyssoides caninum; Polyphagotarsonemus latus; Polyphagotarsonemus spp.; Psorergates ovis; Psorergates spp.; Psoroptes cuniculi; Psoroptes equi; Psoroptes ovis; Psoroptes spp.; Pterolichus spp.; Raillietia spp.; Rhizoglyphus spp.; Sarcoptes bovis; Sarcoptes canis; Sarcoptes caprae; Sarcoptes equi; Sarcoptes ovis; Sarcoptes rupicaprae; Sarcoptes spp.; Sarcoptes suis; Steneotarsonemus spinki; Steneotarsonemus spp.; Sternostoma spp.; Tarsonemus spp.; Tetranychus cinnabarinus; Tetranychus kanzawai; Tetranychus spp.; Tetranychus urticae; Trombicula akamushi; Trombicula spp.; Typhlodromus occidentalis; Tyrophagus spp.; Varroa jacobsoni; Varroa spp.; Vasates lycopersici; and Zetzellia mali. In an embodiment, a compound of formula (I) may control one or more of: Aceria sheldoni ; Aculus lycopersici; Aculus pelekassi; Aculus schlechtendali; Brevipalpus phoenicis; Brevipalpus spp.; Bryobia rubrioculus; Eotetranychus carpini; Eotetranychus spp.; Epitrimerus pyri; Eriophyes piri; Eriophyes spp.; Eriophyes vitis; 82875_FF 36 Eutetranychus africanus; Eutetranychus orientalis; Oligonychus pratensis; Panonychus citri; Panonychus ulmi; Phyllocoptes vitis; Phyllocoptruta oleivora; Polyphagotarsonemus latus; Tetranychus cinnabarinus; Tetranychus kanzawai; Tetranychus spp.; and Tetranychus urticae. In a further embodiment, a compound of formula (I) may especially be suitable for controlling one or more of: Aceria sheldoni; Aculus pelekassi; Brevipalpus phoenicis; Brevipalpus spp.; Eriophyes piri; Eriophyes vitis; Eutetranychus africanus; Eutetranychus orientalis; Oligonychus pratensis; Panonychus ulmi; Phyllocoptes vitis; Phyllocoptruta oleivora; Polyphagotarsonemus latus; Tetranychus cinnabarinus; Tetranychus kanzawai; Tetranychus spp.; and Tetranychus urticae. The term "crops" is to be understood as including also crop plants which have been so transformed by the useof recombinant DNA techniques that they are capable of synthesising one or more selectively acting toxins,such as are known, for example, from toxin-producing bacteria, especially those of the genus Bacillus. Toxins that can be expressed by such transgenic plants include, for example, insecticidal proteins, for example insecticidal proteins from Bacillus cereus or Bacillus popilliae; or insecticidal proteins from Bacillus thuringiensis, such as δ-endotoxins, e.g., Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, or vegetative insecticidal proteins (Vip), e.g., Vip1, Vip2, Vip3 or Vip3A; or insecticidal proteins of bacteria colonising nematodes, for example Photorhabdus spp. or Xenorhabdus spp., such as Photorhabdus luminescens, Xenorhabdus nematophilus; toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins and other insect-specific neurotoxins; toxins produced by fungi, such as Streptomycetes toxins, plant lectins, such as pea lectins, barley lectins or snowdrop lectins; agglutinins; proteinase inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin, papain inhibitors; ribosome-inactivating proteins (RIP), such as ricin, maize-RIP, abrin, luffin, saporin or bryodin; steroid metabolism enzymes, such as 3-hydroxysteroidoxidase, ecdysteroid-UDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors, HMG-COA-reductase, ion channel blockers, such as blockers of sodium or calcium channels, juvenile hormone esterase, diuretic hormone receptors, stilbene synthase, bibenzyl synthase, chitinases and glucanases. In the context of the present invention there are to be understood by δ-endotoxins, for example Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, or vegetative insecticidal proteins (Vip), for example Vip1, Vip2, Vip3 or Vip3A, expressly also hybrid toxins, truncated toxins and modified toxins. Hybrid toxins are produced recombinantly by a new combination of different domains of those proteins (see, for example, WO 02 / 15701). Truncated toxins, for example a truncated Cry1Ab, are known. In the case of modified toxins, one or more amino acids of the naturally occurring toxin are replaced. In such amino acid replacements, preferably non-naturally present protease recognition sequences are inserted into the toxin, such as, for example, in the case of Cry3A055, a cathepsin-G-recognition sequence is inserted into a Cry3A toxin (see WO 03 / 018810). Examples of such toxins or transgenic plants capable of synthesising such toxins are disclosed, for example, in EP-A-0374753, WO 93 / 07278, WO 95 / 34656, EP-A-0427529, EP-A-451878 and WO 03 / 052073. 82875_FF 37 The processes for the preparation of such transgenic plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above. CryI-type deoxyribonucleic acids and their preparation are known, for example, from WO95 / 34656, EP0367474, EP0401979 and WO90 / 13651. The toxin contained in the transgenic plants imparts to the plant tolerance to harmful insects. Such insects can occur in any taxonomic group of insects but are especially commonly found in the beetles (Coleoptera), two- winged insects (Diptera) and moths (Lepidoptera). Transgenic plants containing one or more genes that code for an insecticidal resistance and express one or more toxins are known and some of them are commercially available. Examples of such plants are: YieldGard ^ (maize variety that expresses a Cry1Ab toxin); YieldGard Rootworm^ (maize variety that expresses a Cry3Bb1 toxin); YieldGard Plus^ (maize variety that expresses a Cry1Ab and a Cry3Bb1 toxin); Starlink^ (maize variety that expresses a Cry9C toxin); Herculex I^ (maize variety that expresses a Cry1Fa2 toxin and the enzyme phosphinothricine N-acetyltransferase (PAT) to achieve tolerance to the herbicide glufosinate ammonium); NuCOTN 33B^ (cotton variety that expresses a Cry1Ac toxin); Bollgard I^ (cotton variety that expresses a Cry1Ac toxin); Bollgard II® (cotton variety that expresses a Cry1Ac and a Cry2Ab toxin); VipCot ^ (cotton variety that expresses a Vip3A and a Cry1Ab toxin); NewLeaf^ (potato variety that expresses aCry3A toxin); NatureGard^, Agrisure® GT Advantage (GA21 glyphosate-tolerant trait), Agrisure® CBAdvantage (Bt11 corn borer (CB) trait) and Protecta^. Further examples of such transgenic crops are: 1. Bt11 Maize from Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31790 St. Sauveur, France, registration number C / FR / 96 / 05 / 10. Genetically modified Zea mays which has been rendered resistant to attack by the European corn borer (Ostrinia nubilalis and Sesamia nonagrioides) by transgenic expression of a truncated Cry1Ab toxin. Bt11 maize also transgenically expresses the enzyme PAT to achieve tolerance to the herbicide glufosinate ammonium. 2. Bt176 Maize from Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31790 St. Sauveur, France, registration number C / FR / 96 / 05 / 10. Genetically modified Zea mays which has been rendered resistant to attack by the European corn borer (Ostrinia nubilalis and Sesamia nonagrioides) by transgenic expression of a Cry1Ab toxin. Bt176 maize also transgenically expresses the enzyme PAT to achieve tolerance to the herbicide glufosinate ammonium. 3. MIR604 Maize from Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31790 St. Sauveur, France, registration number C / FR / 96 / 05 / 10. Maize which has been rendered insect-resistant by transgenic expression of a modified Cry3A toxin. This toxin is Cry3A055 modified by insertion of a cathepsin-G-protease recognition sequence. The preparation of such transgenic maize plants is described in WO 03 / 018810. 4. MON 863 Maize from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C / DE / 02 / 9. MON 863 expresses a Cry3Bb1 toxin and has resistance to certain Coleopterainsects. 82875_FF 38 5. IPC 531 Cotton from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C / ES / 96 / 02. 6.1507 Maize from Pioneer Overseas Corporation, Avenue Tedesco, 7 B-1160 Brussels, Belgium, registration number C / NL / 00 / 10. Genetically modified maize for the expression of the protein Cry1F for achieving resistance to certain Lepidoptera insects and of the PAT protein for achieving tolerance to the herbicide glufosinate ammonium. 7. NK603 × MON 810 Maize from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C / GB / 02 / M3 / 03. Consists of conventionally bred hybrid maize varieties by crossing the genetically modified varieties NK603 and MON 810. NK603 × MON 810 Maize transgenicallyexpresses the protein CP4 EPSPS, obtained from Agrobacterium sp. strain CP4, which imparts tolerance tothe herbicide Roundup® (contains glyphosate), and also a Cry1Ab toxin obtained from Bacillus thuringiensis subsp. kurstaki which brings about tolerance to certain Lepidoptera, include the European corn borer. Transgenic crops of insect-resistant plants are also described in BATS (Zentrum für Biosicherheit und Nachhaltigkeit, Zentrum BATS, Clarastrasse 13, 4058 Basel, Switzerland) Report 2003, (http: / / bats.ch). The term "crops" is to be understood as including also crop plants which have been so transformed by the use of recombinant DNA techniques that they are capable of synthesising antipathogenic substances having a selective action, such as, for example, the so-called "pathogenesis-related proteins" (PRPs, see e.g., EP0392225). Examples of such antipathogenic substances and transgenic plants capable of synthesising such antipathogenic substances are known, for example, from EP0392225, WO95 / 33818 and EP0353191. The methods of producing such transgenic plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above. Crops may also be modified for enhanced resistance to fungal (for example Fusarium, Anthracnose, or Phytophthora), bacterial (for example Pseudomonas) or viral (for example potato leafroll virus, tomato spotted wilt virus, cucumber mosaic virus) pathogens. Crops also include those that have enhanced resistance to nematodes, such as the soybean cyst nematode. Crops that are tolerance to abiotic stress include those that have enhanced tolerance to drought, high salt, high temperature, chill, frost, or light radiation, for example through expression of NF-YB or other proteins known in the art. Antipathogenic substances which can be expressed by such transgenic plants include, for example, ionchannel blockers, such as blockers for sodium and calcium channels, for example the viral KP1, KP4 or KP6toxins; stilbene synthases; bibenzyl synthases; chitinases; glucanases; the so-called "pathogenesis-related proteins" (PRPs; see e.g., EP0392225); antipathogenic substances produced by microorganisms, for example peptide antibiotics or heterocyclic antibiotics (see e.g., WO95 / 33818) or protein or polypeptide factors involved in plant pathogen defence (so-called "plant disease resistance genes", as described in WO03 / 000906). 82875_FF 39 Further areas of use of the compositions according to the invention are the protection of stored goods and store rooms and the protection of raw materials, such as wood, textiles, floor coverings or buildings, and also in the hygiene sector, especially the protection of humans, domestic animals and productive livestock against pests of the mentioned type. The present invention provides a compound of the first aspect for use in therapy. The present invention provides a compound of the first aspect, for use in controlling parasites in or on an animal. The present invention further provides a compound of the first aspect, for use in controlling ectoparasites on an animal. The present invention further provides a compound of the first aspect, for use in preventing and / or treating diseases transmitted by ectoparasites. According to this particular aspect of the invention, the use may exclude methodsfor the treatment of the human or animal body by surgery or therapy.The present invention provides the use of a compound of the first aspect, for the manufacture of a medicament for controlling parasites in or on an animal. The present invention further provides the use of a compound of the first aspect, for the manufacture of a medicament for controlling ectoparasites on an animal. The present invention further provides the use of a compound of the first aspect, for the manufacture of a medicament for preventing and / or treating diseases transmitted by ectoparasites. The present invention provides the use of a compound of the first aspect, in controlling parasites in or on an animal. The present invention further provides the use of a compound of the first aspect, in controlling ectoparasites on an animal. The term "controlling" when used in context of parasites in or on an animal refers to reducing the number of pests or parasites, eliminating pests or parasites and / or preventing further pest or parasite infestation. The term "treating" when used in context of parasites in or on an animal refers to restraining, slowing, stopping or reversing the progression or severity of an existing symptom or disease. The term "preventing" when used in context of parasites in or on an animal refers to the avoidance of a symptom or disease developing in the animal. The term "animal" when used in context of parasites in or on an animal may refer to a mammal and a non- mammal, such as a bird or fish. In the case of a mammal, it may be a human or non-human mammal. Non- human mammals include, but are not limited to, livestock animals and companion animals. Livestock animals include, but are not limited to, cattle, camellids, pigs, sheep, goats and horses. Companion animals include, but are not limited to, dogs, cats and rabbits.The term "parasite" as used herein, refers to a pest which lives in or on the host animal and benefits by derivingnutrients at the host animal's expense. An "endoparasite" is a parasite which lives in the host animal. An "ectoparasite" is a parasite which lives on the host animal. Ectoparasites include, but are not limited to, acari, insects and crustaceans (e.g., sea lice). The Acari (or Acarina) sub-class comprises ticks and mites. Ticks include, but are not limited to, members of the following genera: Rhipicaphalus, for example, Rhipicaphalus (Boophilus) microplus and Rhipicephalus sanguineus; Amblyomrna; Dermacentor; Haemaphysalis; 82875_FF 40 Hyalomma; Ixodes; Rhipicentor; Margaropus; Argas; Otobius; and Ornithodoros. Mites include, but are not limited to, members of the following genera: Chorioptes, for example Chorioptes bovis; Psoroptes, for example Psoroptes ovis; Cheyletiella; Dermanyssus; for example, Dermanyssus gallinae; Ortnithonyssus; Demodex, e.g., Demodex canis; Sarcoptes, e.g., Sarcoptes scabiei; and Psorergates. Insects include, but are not limited to, members of the orders: Siphonaptera, Diptera, Phthiraptera, Lepidoptera, Coleoptera and Homoptera. Members of the Siphonaptera order include, but are not limited to, Ctenocephalides felis and Ctenocephatides canis. Members of the Diptera order include, but are not limited to, Musca spp.; bot fly, e.g., Gasterophilus intestinalis and Oestrus ovis; biting flies; horse flies, e.g., Haematopota spp. and Tabunus spp.; haematobia, e.g., haematobia irritans; Stomoxys; Lucilia; midges; and mosquitoes. Members of the Phthiraptera classinclude, but are not limited to, blood sucking lice and chewing lice, e.g., Bovicola Ovis and Bovicola Bovis.The term "effective amount" when used in context of parasites in or on an animal refers to the amount or dose of the compound of the invention, or a salt thereof, which, upon single or multiple dose administration to the animal, provides the desired effect in or on the animal. The effective amount can be readily determined by the attending diagnostician, as one skilled in the art, by the use of known techniques and by observing results obtained under analogous circumstances. In determining the effective amount a number of factors are considered by the attending diagnostician, including, but not limited to: the species of mammal; its size, age, and general health; the parasite to be controlled and the degree of infestation; the specific disease or disorder involved; the degree of or involvement or the severity of the disease or disorder; the response of the individual; the particular compound administered; the mode of administration; the bioavailability characteristics of the preparation administered; the dose regimen selected; the use of concomitant medication; and other relevant circumstances. The compounds of the invention may be administered to the animal by any route which has the desired effect including, but not limited to topically, orally, parenterally'and subcutaneously. Topical administration is preferred. Formulations suitable for topical administration include, for example, solutions, emulsions and suspensions and may take the form of a pour-on, spot-on, spray-on, spray race or dip. In the alternative, the compounds of the invention may be administered by means of an ear tag or collar. Salt forms of the compounds of the invention include both pharmaceutically acceptable salts and veterinary acceptable salts, which can be different to agrochemically acceptable salts. Pharmaceutically and veterinary acceptable salts and common methodology for preparing them are well known in the art. See, for example, Gould, P.L., "Salt selection for basic drugs", International Journal of Pharmaceutics, 33: 201 -217 (1986); Bastin, R.J., et al. "Salt Selection and Optimization Procedures for Pharmaceutical New Chemical Entities", Organic Process Research and Development, 4: 427-435 (2000); and Berge, S.M., et al., "Pharmaceutical Salts", Journal of Pharmaceutical Sciences, 66: 1-19, (1977). One skilled in the art of synthesis will appreciate that the compounds of the invention are readily converted to and may be isolated as a salt, such as a hydrochloride salt, using techniques and conditions well known to one of ordinary skill in the art. In addition, one skilled in the art of synthesis will appreciate that the compounds of the invention are readily converted to and may be isolated as the corresponding free base from the corresponding salt. 82875_FF 41 The present invention may also provide a method for controlling pests (such as mosquitoes and other disease vectors; see also http: / / www.who.int / malaria / vector_control / irs / en / ). In one embodiment, the method for controlling pests comprises applying the compositions of the invention to the target pests, to their locus or to a surface or substrate by brushing, rolling, spraying, spreading or dipping. By way of example, an IRS (indoor residual spraying) application of a surface such as a wall, ceiling or floor surface is contemplated by the method of the invention. In another embodiment, it is contemplated to apply such compositions to a substrate such as non-woven or a fabric material in the form of (or which can be used in the manufacture of) netting, clothing, bedding, curtains and tents. In one embodiment, the method for controlling such pests comprises applying a pesticidally effective amountof the compositions of the invention to the target pests, to their locus, or to a surface or substrate so as toprovide effective residual pesticidal activity on the surface or substrate. Such application may be made by brushing, rolling, spraying, spreading or dipping the pesticidal composition of the invention. By way of example, an IRS application of a surface such as a wall, ceiling or floor surface is contemplated by the method of the invention so as to provide effective residual pesticidal activity on the surface. In another embodiment, it is contemplated to apply such compositions for residual control of pests on a substrate such as a fabric material in the form of (or which can be used in the manufacture of) netting, clothing, bedding, curtains and tents. Substrates including non-woven, fabrics or netting to be treated may be made of natural fibres such as cotton, raffia, jute, flax, sisal, hessian, or wool, or synthetic fibres such as polyamide, polyester, polypropylene, polyacrylonitrile or the like. The polyesters are particularly suitable. The methods of textile treatment are known, e.g., WO 2008 / 151984, WO 2003 / 034823, US 5631072, WO 2005 / 64072, WO2006 / 128870, EP 1724392, WO 2005113886 or WO 2007 / 090739. Further areas of use of the compositions according to the invention may be the field of tree injection / trunk treatment for all ornamental trees as well all sort of fruit and nut trees. In the field of tree injection / trunk treatment, the compounds according to the present invention may be especially suitable against wood-boring insects from the order Lepidoptera as mentioned above and from the order Coleoptera, especially against woodborers listed in the following tables A and B: Table A. Examples of exotic woodborers of economic importance. Family Species Host or Crop Infested Buprestidae Agrilus planipennis Ash Cerambycidae Anoplura glabripennis Hardwoods Xylosandrus crassiusculus Hardwoods Scolytidae X. mutilatus Hardwoods Tomicus piniperda Conifers Table B. Examples of native woodborers of economic importance. 82875_FF 42 Family Species Host or Crop Infested Agrilus anxius Birch Agrilus politus Willow, Maple Agrilus sayi Bayberry, Sweetfern Agrilus vittaticolllis Apple, Pear, Cranberry, Serviceberry, Hawthorn Chrysobothris femorata Apple, Apricot, Beech, Boxelder, Cherry, Chestnut, Buprestidae Currant, Elm, Hawthorn, Hackberry, Hickory, Horsechestnut, Linden, Maple, Mountain-ash, Oak, Pecan, Pear, Peach, Persimmon, Plum, Poplar, Quince, Redbud, Serviceberry, Sycamore, Walnut, Willow Texania campestris Basswood, Beech, Maple, Oak, Sycamore, Willow, Yellow-poplar Goes pulverulentus Beech, Elm, Nuttall, Willow, Black oak, Cherrybark oak, Water oak, Sycamore Goes tigrinus Oak Neoclytus acuminatus Ash, Hickory, Oak, Walnut, Birch, Beech, Maple, Eastern hophornbeam, Dogwood, Persimmon, Redbud, Holly, Hackberry, Black locust, Honeylocust, Yellow-poplar, Chestnut, Osage-orange, Sassafras, Lilac, Mountain- mahogany, Pear, Cherry, Plum, Peach, Apple, Elm, Basswood, Sweetgum Cerambycidae Neoptychodes trilineatus Fig, Alder, Mulberry, Willow, Netleaf hackberry Oberea ocellata Sumac, Apple, Peach, Plum, Pear, Currant, Blackberry Oberea tripunctata Dogwood, Viburnum, Elm, Sourwood, Blueberry, Rhododendron, Azalea, Laurel, Poplar, Willow, Mulberry Oncideres cingulata Hickory, Pecan, Persimmon, Elm, Sourwood, Basswood, Honeylocust, Dogwood, Eucalyptus, Oak, Hackberry, Maple, Fruit trees Saperda calcarata Poplar Strophiona nitens Chestnut, Oak, Hickory, Walnut, Beech, Maple Corthylus columbianus Maple, Oak, Yellow-poplar, Beech, Boxelder, Sycamore, Birch, Basswood, Chestnut, Elm Dendroctonus frontalis Pine Scolytidae Dryocoetes betulae Birch, Sweetgum, Wild cherry, Beech, Pear Monarthrum fasciatum Oak, Maple, Birch, Chestnut, Sweetgum, Blackgum, Poplar, Hickory, Mimosa, Apple, Peach, Pine 82875_FF 43 Family Species Host or Crop Infested Phloeotribus liminaris Peach, Cherry, Plum, Black cherry, Elm, Mulberry, Mountain-ash Pseudopityophthorus Oak, American beech, Black cherry, Chickasaw plum, pruinosus Chestnut, Maple, Hickory, Hornbeam, Hophornbeam Paranthrene simulans Oak, American chestnut Sannina uroceriformis Persimmon Synanthedon exitiosa Peach, Plum, Nectarine, Cherry, Apricot, Almond, Black cherry Synanthedon pictipes Peach, Plum, Cherry, Beach, Black Cherry Sesiidae Synanthedon rubrofascia Tupelo Synanthedon scitula Dogwood, Pecan, Hickory, Oak, Chestnut, Beech, Birch, Black cherry, Elm, Mountain-ash, Viburnum, Willow, Apple, Loquat, Ninebark, Bayberry Vitacea polistiformis Grape The present invention may be also used to control any insect pests that may be present in turfgrass, including e.g., beetles, caterpillars, fire ants, ground pearls, millipedes, sow bugs, mites, mole crickets, scales, mealybugs, ticks, spittlebugs, southern chinch bugs and white grubs. The present invention may be used to control insect pests at various stages of their life cycle, including eggs, larvae, nymphs and adults. In particular, the present invention may be used to control insect pests that feed on the roots of turfgrass including white grubs (such as Cyclocephala spp. (e.g., masked chafer, C. lurida), Rhizotrogus spp. (e.g., European chafer, R. majalis), Cotinus spp. (e.g., Green June beetle, C. nitida), Popillia spp. (e.g., Japanese beetle, P. japonica), Phyllophaga spp. (e.g., May / June beetle), Ataenius spp. (e.g., Black turfgrass ataenius, A. spretulus), Maladera spp. (e.g., Asiatic garden beetle, M. castanea) and Tomarus spp.), ground pearls (Margarodes spp.), mole crickets (tawny, southern, and short-winged; Scapteriscus spp., Gryllotalpa africana) and leatherjackets (European crane fly, Tipula spp.). The present invention may also be used to control insect pests of turfgrass that are thatch dwelling, including armyworms (such as fall armyworm Spodoptera frugiperda, and common armyworm Pseudaletia unipuncta), cutworms, billbugs (Sphenophorus spp., such as S. venatus verstitus and S. parvulus), and sod webworms (such as Crambus spp. and the tropical sod webworm, Herpetogramma phaeopteralis). The present invention may also be used to control insect pests of turfgrass that live above the ground and feed on the turfgrass leaves, including chinch bugs (such as southern chinch bugs, Blissus insularis), Bermudagrass mite (Eriophyes cynodoniensis), rhodesgrass mealybug (Antonina graminis), two-lined spittlebug (Propsapia bicincta), leafhoppers, cutworms (Noctuidae family), and greenbugs. The present invention may also be used to control other pests of turfgrass such as red imported fire ants (Solenopsis invicta) that create ant mounds in turf. 82875_FF 44 In the hygiene sector, the compositions according to the invention may be active against ectoparasites such as hard ticks, soft ticks, mange mites, harvest mites, flies (biting and licking), parasitic fly larvae, lice, hair lice, bird lice and fleas. Examples of such parasites are: Of the order Anoplurida: Haematopinus spp., Linognathus spp., Pediculus spp. and Phtirus spp., Solenopotes spp.. Of the order Mallophagida: Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp. and Felicola spp.. Of the order Diptera and the suborders Nematocerina and Brachycerina, e.g., Aedes spp., Anopheles spp.,Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysopsspp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp. and Melophagus spp.. Of the order Siphonapterida, e.g., Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.. Of the order Heteropterida, e.g., Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.. Of the order Blattarida, e.g., Blatta orientalis, Periplaneta americana, Blattelagermanica and Supella spp.. Of the subclass Acaria (Acarida) and the orders Meta- and Meso-stigmata, e.g., Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp. and Varroa spp.. Of the orders Actinedida (Prostigmata) and Acaridida (Astigmata), e.g., Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergatesspp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp. and Laminosioptes spp.. The compositions according to the invention may also be suitable for protecting against insect infestation in the case of materials such as wood, textiles, plastics, adhesives, glues, paints, paper and card, leather, floor coverings and buildings.The compositions according to the invention can be used, for example, against the following pests: beetlessuch as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinuspecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthesrugicollis, Xyleborus spec.,Tryptodendron spec., Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon 82875_FF 45 spec. and Dinoderus minutus, and also hymenopterans such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus and Urocerus augur, and termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis and Coptotermes formosanus, and bristletails such as Lepisma saccharina. The compounds of formulae (I), (I-a), or (I-b), or one compound selected from the group consisting of the compounds as represented in Tables A1 to A2, or a compound listed in Table P (below), or salts thereof, are especially suitable for controlling one or more pests selected from the genus: Spodoptera spp., Helicoverpa spp., Heliothis spp., Leucinodes spp., Tuta spp., Plutella spp., Cydia spp., Lobesia spp., Tortrix spp., Amyeloisspp., Maruca spp., Chrysodeixis spp., Agrotis spp., Elasmopalpus spp., Dalbulus spp., Sternechus spp.,Phyllotreta spp., Popillia spp., Scirpophaga spp., Chilo spp., Cnaphalocrosis spp., Tetranychus spp., Panonychus spp., Polyphagotarsonemus spp., Phyllocoptruta spp., Aculus spp., Brevipalpus spp., Oligonychus spp., Aculops spp., Nilaparvata spp., Sogatella spp., Laodelphax spp., Nephotettix spp., Diabrotica spp., Agriotes spp., Hypnoidus spp., Limonius spp., Melanotus spp., Conoderus spp., Delia spp., Amphimallon spp., Popillia spp., Euschistus spp., Piezodorus spp., Nezara spp., Dichelops spp., Lygus spp., Leptocorisa spp., Eurygaster spp., Halymorpha spp., Thrips spp., Scirtothrips spp., Frankliniella spp., Anthonomus spp., Melingethes spp., Phyllotreta spp., Leptinotarsa spp., Bemisia spp., Trialeurodes spp., Aphis spp., and Myzus spp. In a preferred embodiment of each aspect, a compound TX (where the abbreviation “TX” means “one compound selected from the compounds of formulae (I), (I-a), or (I-b), or one compound selected from the group consisting of the compounds as represented in Tables A1 to A2, or a compound listed in Table P (below), controls one or more of pests selected from the genus: Spodoptera spp., Helicoverpa spp., Heliothis spp., Leucinodes spp., Tuta spp., Plutella spp., Cydia spp., Lobesia spp., Tortrix spp., Amyelois spp., Maruca spp., Chrysodeixis spp., Agrotis spp., Elasmopalpus spp., Dalbulus spp., Sternechus spp., Phyllotreta spp., Popillia spp., Scirpophaga spp., Chilo spp., Cnaphalocrosis spp., Tetranychus spp., Panonychus spp., Polyphagotarsonemus spp., Phyllocoptruta spp., Aculus spp., Brevipalpus spp., Oligonychus spp., Aculops spp., Nilaparvata spp., Sogatella spp., Laodelphax spp., Nephotettix spp., Diabrotica spp., Agriotes spp., Hypnoidus spp., Limonius spp., Melanotus spp., Conoderus spp., Delia spp., Amphimallon spp., Popillia spp., Euschistus spp., Piezodorus spp., Nezara spp., Dichelops spp., Lygus spp., Leptocorisa spp., Eurygaster spp., Halymorpha spp., Thrips spp., Scirtothrips spp., Frankliniella spp., Anthonomus spp., Melingethes spp., Phyllotreta spp., Leptinotarsa spp., Bemisia spp., Trialeurodes spp., Aphis spp., and Myzus spp. The compounds of formulae (I), (I-a), or (I-b), or one compound selected from the group consisting of the compounds as represented in Tables A1 to A2, or a compound listed in Table P (below), or salts thereof, are especially suitable for controlling one or more pests selected from: Spodoptera spp (for example, Spodoptera frugiperda, Spodoptera littoralis), Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix spp., Maruca vitrata, Chrysodeixis includens, Agrotis ipsilon, Elasmopalpus lignosellus, Dalbulus maidis, Phyllotreta spp., Popillia japonica, 82875_FF 46 Scirpophaga incertulas, Chilo suppressalis, Cnaphalocrosis medinalis, Tetranychus urticae, Panonychus ulmi, Polyphagotarsonemus latus, Phyllocoptruta oleivora, Brevipalpus spp., Aculops lycopersici, Nilaparvata lugens, Sogatella frucifera, Laodelphax striatellus, Nephotettix spp., Diabrotica vigifera, Agriotes spp., Hypnoidus bicolor, Limonius canus, Delia radicum, Popillia japonica, Euschistus heros, Piezodorus lituratus, Nezara viridula, Dichelops furcatus, Lygus sp., Leptocorisa acuta, Halyomorpha halys, Thrips tabaci, Scirtothrips dorsalis, Frankliniella occidentalis, Anthonomus grandis, Meligethes aeneus, Phyllotreta spp., Leptinotarsa decemlineata, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, and Myzus persicae. In a preferred embodiment of each aspect, a compound TX (where the abbreviation “TX” means “one compound selected from the compounds of formulae (I), (I-a), or (I-b), or one compound selected from thegroup consisting of the compounds as represented in Tables A1 to A2, or a compound listed in Table P(below)), controls one or more of pests selected from the genus: Spodoptera spp (for example, Spodoptera frugiperda, Spodoptera littoralis) + TX, Helicoverpa armigera + TX, Heliothis virescens + TX, Leucinodes orbonalis + TX, Tuta absoluta + TX, Plutella xylostella + TX, Cydia pomonella + TX, Lobesia spp + TX, Tortrix spp + TX, Maruca vitrata + TX, Chrysodeixis includens + TX, Agrotis ipsilon + TX, Elasmopalpus lignosellus + TX, Dalbulus maidis + TX, Phyllotreta spp + TX, Popillia japonica + TX, Scirpophaga incertulas + TX, Chilo suppressalis + TX, Cnaphalocrosis medinalis + TX, Tetranychus urticae + TX, Panonychus ulmi + TX, Polyphagotarsonemus latus + TX, Phyllocoptruta oleivora + TX Brevipalpus spp + TX, Aculops lycopersici + TX, Nilaparvata lugens + TX, Sogatella frucifera + TX, Laodelphax striatellus + TX, Nephotettix spp + TX, Diabrotica vigifera + TX, Agriotes spp + TX, Hypnoidus bicolor + TX, Limonius canus + TX, Delia radicum + TX, Popillia japonica + TX, Euschistus heros + TX, Piezodorus lituratus + TX, Nezara viridula + TX, Dichelops furcatus + TX, Lygus spp + TX, Leptocorisa acuta + TX, Halyomorpha haly + TX s, Thrips tabaci + TX, Scirtothrips dorsalis + TX, Frankliniella occidentalis + TX, Anthonomus grandis + TX, Meligethes aeneus + TX, Phyllotreta spp + TX, Leptinotarsa decemlineata + TX, Bemisia tabaci + TX, Trialeurodes vaporariorum + TX, Aphis gossypii + TX, and Myzus persicae + TX. The compounds of formulae (I), (I-a), or (I-b), or one compound selected from the group consisting of the compounds as represented in Tables A1 to A2, or a compound listed in Table P (below), or salts thereof, are especially suitable for controlling in the crops listed in the Table below the pests listed. Crop Pests leafy Spodoptera spp., Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta vegetables absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix spp., Maruca vitrata, Tetranychus urticae, Panonychus ulmi, Polyphagotarsonemus latus, Phyllocoptruta oleivora, Brevipalpus spp., Aculops lycopersici solanacea Spodoptera spp., Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix spp., Maruca vitrata, Tetranychus urticae, Panonychus ulmi, Polyphagotarsonemus latus, Phyllocoptruta oleivora, Brevipalpus spp., Aculops lycopersici 82875_FF 47 brassica Spodoptera spp., Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix spp., Maruca vitrata okra Spodoptera spp., Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix spp., Maruca vitrata pome fruits Spodoptera spp., Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix spp., Maruca vitrata, Tetranychus urticae, Panonychus ulmi, Polyphagotarsonemus latus, Phyllocoptruta oleivora, Brevipalpus spp., Aculops lycopersici vegetables Spodoptera spp., Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix spp., Maruca vitrata, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Myzus persicae grapes Spodoptera spp., Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix spp., Maruca vitrata, Thrips tabaci, Scirtothrips dorsalis, Frankliniella occidentalis nuts Spodoptera spp., Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix spp., Maruca vitrata plantation Spodoptera spp., Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix spp., Maruca vitrata, Tetranychus urticae, Panonychus ulmi, Polyphagotarsonemus latus, Phyllocoptruta oleivora, Brevipalpus spp., Aculops lycopersici eggplant Spodoptera spp., Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix spp., Maruca vitrata, Tetranychus urticae, Panonychus ulmi, Polyphagotarsonemus latus, Phyllocoptruta oleivora, Brevipalpus spp., Aculops lycopersici corn Spodoptera spp (for example, Spodoptera frugiperda, Spodoptera littoralis), Helicoverpa armigera, Heliothis virescens, Chrysodeixis includens, Agrotis ipsilon, Elasmopalpus lignosellus, Agrotis ipsilon, Dalbulus maidis, Phyllotreta sp., Popillia japonica, Tetranychus urticae, Panonychus ulmi, Polyphagotarsonemus latus, Phyllocoptruta oleivora, Brevipalpus spp., Aculops lycopersici, Diabrotica virgifera vigifera, Agriotes spp., Hypnoidus bicolor, Limonius canus, Delia radicum, Euschistus heros, Piezodorus lituratus, Nezara viridula, Dichelops furcatus, Lygus spp., Leptocorisa acuta, Halyomorpha halys, Anthonomus grandis, Meligethes aeneus, Phyllotreta spp., Leptinotarsa decemlineata soybean Spodoptera spp (for example, Spodoptera frugiperda, Spodoptera littoralis), Helicoverpa armigera, Heliothis virescens, Chrysodeixis includens, Agrotis ipsilon, Elasmopalpus lignosellus, Agrotis ipsilon, Dalbulus maidis, Phyllotreta sp., Popillia japonica, Tetranychus urticae, Panonychus ulmi, Polyphagotarsonemus latus, Phyllocoptruta oleivora, Brevipalpus spp., Aculops lycopersici, Euschistus heros, Piezodorus lituratus, 82875_FF 48 Nezara viridula, Dichelops furcatus, Lygus spp., Leptocorisa acuta, Halyomorpha halys, Thrips tabaci, Scirtothrips dorsalis, Frankliniella occidentalis, Anthonomus grandis, Meligethes aeneus, Phyllotreta spp., Leptinotarsa decemlineata cotton Spodoptera spp (for example, Spodoptera frugiperda, Spodoptera littoralis), Helicoverpa armigera, Heliothis virescens, Chrysodeixis includens, Agrotis ipsilon, Elasmopalpus lignosellus, Agrotis ipsilon, Dalbulus maidis, Phyllotreta sp., Popillia japonica, Tetranychus urticae, Panonychus ulmi, Polyphagotarsonemus latus, Phyllocoptruta oleivora, Brevipalpus spp., Aculops lycopersici, Diabrotica virgifera vigifera, Agriotes spp., Hypnoidus bicolor, Limonius canus, Delia radicum, Euschistus heros, Piezodorus lituratus, Nezara viridula, Dichelops furcatus, Lygus spp., Leptocorisa acuta, Halyomorpha halys, Thrips tabaci, Scirtothrips dorsalis, Frankliniella occidentalis, Anthonomus grandis, Meligethes aeneus, Phyllotreta spp., Leptinotarsa decemlineata, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Myzus persicae canola Spodoptera frugiperda, Elasmopalpus lignosellus, Agrotis ipsilon, Dalbulus maidis, Phyllotreta spp., Popillia japonica rice Scirpophaga incertulas, Chilo suppressalis, Cnaphalocrosis medinalis, Nilaparvata lugens, Sogatella frucifera, Laodelphax striatellus, Nephotettix spp., Euschistus heros, Piezodorus lituratus, Nezara viridula, Dichelops furcatus, Lygus spp., Leptocorisa acuta, Halyomorpha halys, Anthonomus grandis, Meligethes aeneus, Phyllotreta spp., Leptinotarsa decemlineata citrus Tetranychus urticae, Panonychus ulmi, Polyphagotarsonemus latus, Phyllocoptruta oleivora, Brevipalpus spp., Aculops lycopersici, Thrips tabaci, Scirtothrips dorsalis, Frankliniella occidentalis potato Tetranychus urticae, Panonychus ulmi, Polyphagotarsonemus latus, Phyllocoptruta oleivora, Brevipalpus spp., Aculops lycopersici, Diabrotica virgifera vigifera, Agriotes spp., Hypnoidus bicolor, Limonius canus, Delia radicum, Popillia japonica, Anthonomus grandis, Meligethes aeneus, Phyllotreta spp., Leptinotarsa decemlineata Cereal (wheat, Diabrotica virgifera vigifera, Agriotes spp., Hypnoidus bicolor, Limonius canus, Delia sorghum, radicum, Popillia japonica, Anthonomus grandis, Meligethes aeneus, Phyllotreta spp., barley) Leptinotarsa decemlineata diverse field Diabrotica virgifera vigifera, Agriotes spp., Hypnoidus bicolor, Limonius canus, Delia crops radicum, Popillia japonica fruiting Thrips tabaci, Scirtothrips dorsalis, Frankliniella occidentalis, vegetables peanut Thrips tabaci, Scirtothrips dorsalis, Frankliniella occidentalis onion Thrips tabaci, Scirtothrips dorsalis, Frankliniella occidentalis oil seed rape Anthonomus grandis, Meligethes aeneus, Phyllotreta spp., Leptinotarsa decemlineata ornamentals Thrips tabaci, Scirtothrips dorsalis, Frankliniella occidentalis 82875_FF 49 speciality Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Myzus persicae crops# # as defined in https: / / www.ams.usda.gov / services / grants / scbgp / specialty-crop In a preferred embodiment of each aspect, a compound TX (where the abbreviation “TX” means “one compound selected from the compounds of formulae (I), (I-a), or (I-b), or one compound selected from the group consisting of the compounds as represented in Tables A1 to A2, or a compound listed in Table P (below)), controls one or more of Spodoptera spp. (for example, Spodoptera frugiperda, Spodoptera littoralis), Helicoverpa armigera, Heliothis virescens, Leucinodes orbonalis, Tuta absoluta, Plutella xylostella, Cydia pomonella, Lobesia spp., Tortrix sp., Maruca vitrata, Chrysodeixis includens, Agrotis ipsilon, Elasmopalpus lignosellus, Dalbulus maidis, Phyllotreta spp., Popillia japonica, Scirpophaga incertulas, Chilo suppressalis, Cnaphalocrosis medinalis, Nilaparvata lugens, Sogatella frucifera, Laodelphax striatellus, Nephotettix spp., Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, and Myzus persicae; such as Spodoptera spp (for example, Spodoptera frugiperda, Spodoptera littoralis) + TX, Helicoverpa armigera + TX, Heliothis virescens + TX, Leucinodes orbonalis + TX, Tuta absoluta + TX, Plutella xylostella + TX, Cydia pomonella + TX, Lobesia spp + TX, Tortrix spp + TX, Maruca vitrata + TX, Chrysodeixis includens + TX, Agrotis ipsilon + TX, Elasmopalpus lignosellus + TX, Dalbulus maidis + TX, Phyllotreta spp + TX, Popillia japonica + TX, Scirpophaga incertulas + TX, Chilo suppressalis + TX, Cnaphalocrosis medinalis + TX, Nilaparvata lugens + TX, Sogatella frucifera + TX, Laodelphax striatellus + TX, Nephotettix spp + TX, Bemisia tabaci + TX, Trialeurodes vaporariorum + TX, Aphis gossypii + TX, and Myzus persicae + TX. Compounds according to the invention may possess any number of benefits including, inter alia, advantageous levels of biological activity for protecting plants against insects or superior properties for use as agrochemicalactive ingredients (for example, greater biological activity, an advantageous spectrum of activity, an increasedsafety profile (against non-target organisms above and below ground (such as fish, birds and bees), improved physico-chemical properties, or increased biodegradability). In particular, it has been surprisingly found that certain compounds of formula (I) may show an advantageous safety profile with respect to non-target arthropods, in particular pollinators such as honey bees, solitary bees, and bumble bees. Most particularly, Apis mellifera. The activity of the compositions according to the invention can be broadened considerably, and adapted to prevailing circumstances, by adding other insecticidally, acaricidally and / or fungicidally active ingredients. The mixtures of the compounds of formula (I) with other insecticidally, acaricidally and / or fungicidally active ingredients may also have further surprising advantages which can also be described, in a wider sense, as synergistic activity. For example, better tolerance by plants, reduced phytotoxicity, insects can be controlled in their different development stages or better behaviour during their production, e.g., during grinding or mixing, during their storage or during their use. Suitable additions to active ingredients here are, for example, representatives of the following classes of active ingredients: organophosphorus compounds, nitrophenol derivatives, thioureas, juvenile hormones, formamidines, benzophenone derivatives, ureas, pyrrole derivatives, carbamates, pyrethroids, chlorinated 82875_FF 50 hydrocarbons, acylureas, pyridinylmethyleneamino derivatives, macrolides, neonicotinoids and Bacillus thuringiensis preparations. The following combinations of a compound of formula (I) with another active substance are preferred (where the abbreviation “TX” means “one compound selected from the compounds of the formulae (I), (I-a), or (I-b), or one compound selected from the group consisting of the compounds as represented in Tables A1 to A2, or a compound listed in Table P (below): (7E,9Z)-dodeca-7,9-dien-1-yl acetate + TX, (9Z,11E)-tetradeca-9,11-dien-1-yl acetate + TX, (9Z,12E)- tetradeca-9,12-dien-1-yl acetate + TX, (E)-6-methylhept-2-en-4-ol + TX, (E)-dec-5-en-1-yl acetate with (E)- dec-5-en-1-ol + TX, (E)-tridec-4-en-1-yl acetate + TX, (E,Z)-tetradeca-4,10-dien-1-yl acetate + TX, (Z)-dodec-7-en-1-yl acetate + TX, (Z)-hexadec-11-en-1-yl acetate + TX, (Z)-hexadec-11-enal + TX, (Z)-hexadec-13-en-11-yn-1-yl acetate + TX, (Z)-icos-13-en-10-one + TX, (Z)-tetradec-7-en-1-al + TX, (Z)-tetradec-9-en-1-ol + TX, (Z)-tetradec-9-en-1-yl acetate + TX, 1-(4-chlorophenyl)-2-fluoro-4-methyl-5-(2,2,2-trifluoroethylsulfanyl) benzene + TX, 1,2-dibromo-3-chloropropane + TX, 1,2-dichloropropane + TX, 1,2-dichloropropane with 1,3- dichloropropene + TX, 1,3-dichloropropene + TX, 14-methyloctadec-1-ene + TX, 1-hydroxy-1H-pyridine-2- thione + TX, 2-(octylthio)ethanol + TX, 2-[5-(2-chloro-3,3,3-trifluoro-prop-1-enyl)-1-methyl-imidazol-2-yl]-5- cyclopropyl-3-ethylsulfonyl-pyridine + TX, 2-chlorophenyl N-methylcarbamate (CPMC) + TX, 3-(4- chlorophenyl)-5-methylrhodanine + TX, 3,4-dichlorotetrahydrothiophene 1,1-dioxide + TX, 4-(quinoxalin-2- ylamino)benzenesulfonamide + TX, 4-methylnonan-5-ol with 4-methylnonan-5-one + TX, 5-methyl-6-thioxo- 1,3,5-thiadiazinan-3-ylacetic acid + TX, 6-isopentenylaminopurine + TX, 8-hydroxyquinoline sulfate + TX, abamectin + TX, acequinocyl + TX, acetamiprid + TX, acetoprole + TX, acrinathrin + TX, acynonapyr + TX, Adoxophyes orana GV + TX, afidopyropen + TX, afoxolaner + TX, Agrobacterium radiobacter + TX, AKD-3088 + TX, alanycarb + TX, aldicarb + TX, aldoxycarb + TX, allethrin + TX, alpha-cypermethrin + TX, alphamethrin + TX, alpha-multistriatin + TX, Amblyseius spp. + TX, amidoflumet + TX, amino acids + TX, aminocarb + TX, Anagrapha falcifera NPV + TX, Anagrus atomus + TX, Aphelinus abdominalis + TX, Aphidius colemani + TX, Aphidoletes aphidimyza + TX, apholate + TX, Autographa californica NPV + TX, AZ 60541 + TX, azadirachtin + TX, azocyclotin + TX, Bacillus aizawai + TX, Bacillus chitinosporus AQ746 (NRRL Accession No B-21618) + TX, Bacillus firmus + TX, Bacillus kurstaki + TX, Bacillus mycoides AQ726 (NRRL Accession No. B-21664) + TX, Bacillus pumilus (NRRL Accession No B-30087) + TX, Bacillus pumilus AQ717 (NRRL Accession No. B-21662) + TX, Bacillus sp. AQ175 (ATCC Accession No.55608) + TX, Bacillus sp. AQ177 (ATCC Accession No. 55609) + TX, Bacillus sp. AQ178 (ATCC Accession No. 53522) + TX, Bacillus sphaericus Neide + TX, Bacillus subtilis AQ153 (ATCC Accession No.55614) + TX, Bacillus subtilis AQ30002 (NRRL Accession No. B-50421) + TX, Bacillus subtilis AQ30004 (NRRL Accession No. B- 50455) + TX, Bacillus subtilis AQ713 (NRRL Accession No. B-21661) + TX, Bacillus subtilis AQ743 (NRRL Accession No. B-21665) + TX, Bacillus subtilis unspecified + TX, Bacillus thuringiensis AQ52 (NRRL Accession No. B-21619) + TX, Bacillus thuringiensis BD#32 (NRRL Accession No B-21530) + TX, Bacillus thuringiensis Berliner + TX, Bacillus thuringiensis subsp. Aizawai + TX, Bacillus thuringiensis subsp. Israelensis + TX, Bacillus thuringiensis subsp. Japonensis + TX, Bacillus thuringiensis subsp. Kurstaki + TX, Bacillus thuringiensis subsp. Tenebrionis + TX, Bacillus thuringiensis subspec. kurstaki BMP 123 + TX, Beauveria bassiana + TX, Beauveria brongniartii + TX, 82875_FF 51 benclothiaz + TX, benomyl + TX, bensultap + TX, bentioflumin (CAS Number: 2566451-67-8) + TX, benzoximate + TX, benzpyrimoxan + TX, betacyfluthrin + TX, beta-cypermethrin + TX, bethoxazin + TX, bifenazate + TX, bifenthrin + TX, binapacryl + TX, bioallethrin + TX, bioresmethrin + TX, bis(tributyltin) oxide + TX, bisazir + TX, bistrifluron + TX, bisulflufen + TX, brevicomin + TX, broflanilide + TX, brofluthrinate + TX, bromoacetamide + TX, bromophos-ethyl + TX, bronopol + TX, busulfan + TX, butocarboxim + TX, butopyronoxyl + TX, butoxy(polypropylene glycol) + TX, butylpyridaben + TX, cadusafos + TX, calcium arsenate + TX, carbaryl + TX, carbofuran + TX, carbon disulfide + TX, carbosulfan + TX, cartap + TX, CAS number: 1594624-87-9 + TX, CAS number: 1922957-47-8 + TX, CAS number: 1255091-74-7 + TX, CAS number: 1365070-72-9 + TX, CAS Number: 158062-71-6 + TX, CAS number: 1594626-19-3 + TX, CASnumber: 1594637-65-6 + TX, CAS number: 1632218-00-8 + TX, CAS number: 1808115-49-2 + TX, CASnumber: 1922957-46-7 + TX, CAS number: 1922957-48-9 + TX, CAS number: 1956329-03-5 + TX, CAS number: 1990457-52-7 + TX, CAS number: 1990457-55-0 + TX, CAS number: 1990457-57-2 + TX, CAS number: 1990457-66-3 + TX, CAS number: 1990457-77-6 + TX, CAS number: 1990457-85-6 + TX, CAS number: 2032403-97-5 + TX, CAS number: 2044701-44-0 + TX, CAS number: 2095470-94-1 + TX, CAS number: 2128706-05-6 + TX, CAS number: 2133042-31-4 + TX, CAS number: 2133042-44-9 + TX, CAS number: 2171099-09-3 + TX, CAS number: 2220132-55-6 + TX, CAS number: 2396747-83-2 + TX, CAS number: 2408220-91-5 + TX, CAS number: 2408220-94-8 + TX, CAS number: 2415706-16-8 + TX, CAS Number: 2583740-14-9 + TX, CAS Number: 2583751-98-6 + TX, CAS number: 2719848-60-7 + TX, CAS Number: 2898489-71-7 + TX, CAS Number: 2922115-20-4 + TX, CAS Number: 34763-86-5 + TX, CAS number: RNA (Leptinotarsa decemlineata-specific recombinant double-stranded interfering GS2) + TX, chlorantraniliprole + TX, chlordane + TX, chlorfenapyr + TX, chloropicrin + TX, chloroprallethrin + TX, chlorpyrifos + TX, chromafenozide + TX, Chrysoperla carnea + TX, clenpirin + TX, cloethocarb + TX, clothianidin + TX, codlelure + TX, codlemone + TX, copper acetoarsenite + TX, copper dioctanoate + TX, copper hydroxide + TX, copper sulfate + TX, cresol + TX, crufomate + TX, Cryptolaemus montrouzieri + TX, cuelure + TX, cyanofenphos + TX, cyantraniliprole + TX, cybenzoxasulfyl (CAS Number: 2128706-04-5) + TX, cybutryne + TX, cyclaniliprole + TX, cyclobutrifluram + TX, cycloprothrin + TX, cycloxaprid + TX, Cydia pomonella GV + TX, cyenopyrafen + TX, cyetpyrafen + TX, cyflumetofen + TX, cyfluthrin + TX, cyhalodiamide + TX, cylohalothrin + TX, cypermethrin + TX, cyphenothrin + TX, cyproflanilide + TX, cyromazine + TX, cytokinins + TX, Dacnusa sibirica + TX, dazomet + TX, DBCP + TX, DCIP + TX, deltamethrin + TX, diafenthiuron + TX, dialifos + TX, diamidafos + TX, dibrom + TX, dibutyl adipate + TX, dibutyl phthalate + TX, dibutyl succinate + TX, dichlofenthion + TX, dichlone + TX, dichlorophen + TX, dicliphos + TX, dicloromezotiaz + TX, diethyltoluamide + TX, diflubenzuron + TX, Diglyphus isaea + TX, dimatif + TX, dimethoate + TX, dimethyl carbate + TX, dimethyl phthalate + TX, dimpropyridaz + TX, dinactin + TX, dinocap + TX, dinotefuran + TX, dioxabenzofos + TX, dipyrithione + TX, disparlure + TX, D-limonene + TX, dodec-8-en-1-yl acetate + TX, dodec-9-en-1-yl acetate + TX, dodeca-8,10-dien-1-yl acetate + TX, dodicin + TX, dominicalure + TX, doramectin + TX, emamectin + TX, emamectin benzoate + TX, empenthrin + TX, Encarsia formosa + TX, endothal + TX, endrin + TX, eprinomectin + TX, epsilon - momfluorothrin + TX, epsilon-metofluthrin + TX, Eretmocerus eremicus + TX, esfenvalerate + TX, ethion + TX, ethiprole + TX, ethoprophos + TX, ethyl 4- 82875_FF 52 methyloctanoate + TX, ethyl hexanediol + TX, ethylene dibromide + TX, etofenprox + TX, etoxazole + TX, etpyrafen + TX, eugenol + TX, Extract of seaweed and fermentation product derived from melasse + TX, Extract of seaweed and fermentation product derived from melasse comprising urea + TX, Extract of seaweed and fermented plant products + TX, Extract of seaweed and fermented plant products comprising phytohormones, vitamins, EDTA-chelated copper, zinc, and iron + TX, famphur + TX, fenaminosulf + TX, fenamiphos + TX, fenazaquin + TX, fenfluthrin + TX, fenitrothion + TX, fenmezoditiaz + TX, fenobucarb + TX, fenothiocarb + TX, fenoxycarb + TX, fenpropathrin + TX, fenpyrad + TX, fenpyroximate + TX, fensulfothion + TX, fenthion + TX, fentin + TX, fentinacetate + TX, fenvalerate + TX, ferric phosphate + TX, fipronil + TX, flometoquin + TX, flonicamid + TX, fluacrypyrim + TX, fluazaindolizine + TX, fluazuron + TX, flubendiamide +TX, flubenzimine + TX, fluchlordiniliprole + TX, flucitrinate + TX, flucycloxuron + TX, flucythrinate + TX,fluensulfone [318290-98-1] + TX, fluensulfone + TX, flufenerim + TX, flufenprox + TX, flufiprole + TX, fluhexafon + TX, flumethrin + TX, fluopyram + TX, flupentiofenox + TX, flupyradifurone + TX, flupyrimin + TX, flupyroxystrobin + TX, fluralaner + TX, fluvalinate + TX, fluxametamide + TX, formaldehyde + TX, fosthiazate + TX, fosthietan + TX, frontalin + TX, furfural + TX, galquin (CAS Number: 2644770-30-7) + TX, gamma- cyhalothrin + TX, Gossyplure® (1:1 mixture of the (Z,E) and (Z,Z) isomers of hexadeca-7,11-dien-1-yl-acetate) + TX, grandlure + TX, grandlure I + TX, grandlure II + TX, grandlure III + TX, grandlure IV + TX, Granulovirus + TX, guadipyr + TX, GY-81 + TX, halfenprox + TX, halofenozide + TX, Harpin + TX, Helicoverpa armigera Nucleopolyhedrovirus + TX, Helicoverpa zea NPV + TX, Helicoverpa zea Nucleopolyhedrovirus + TX, Heliothis punctigera Nucleopolyhedrovirus + TX, Heliothis virescens Nucleopolyhedrovirus + TX, hemel + TX, hempa + TX, heptafluthrin + TX, heterophos + TX, Heterorhabditis bacteriophora and H. megidis + TX, hexalure + TX, hexamide + TX, hexythiazox + TX, Hippodamia convergens + TX, hydramethylnon + TX, hydrargaphen + TX, hydrated lime + TX, imicyafos + TX, imidacloprid + TX, imiprothrin + TX, Indazapyroxamet + TX, indoxacarb + TX, iodomethane + TX, iprodione + TX, ipsdienol + TX, ipsenol + TX, isamidofos + TX, isazofos + TX, isocycloseram + TX, Isoflualanam (CAS number: 2892524-05-7) + TX, isothioate + TX, ivermectin + TX, japonilure + TX, kappa-bifenthrin + TX, kappa-tefluthrin + TX, kasugamycin + TX, kasugamycin hydrochloride hydrate + TX, kinetin + TX, lambda-cyhalothrin + TX, ledprona + TX, lepimectin + TX, Leptomastix dactylopii + TX, lineatin + TX, litlure + TX, looplure + TX, lotilaner + TX, lufenuron + TX, Macrolophus caliginosus + TX, Mamestra brassicae NPV + TX, mecarphon + TX, medlure + TX, megatomoic acid + TX, metaflumizone + TX, metaldehyde + TX, metam + TX, metam-potassium + TX, metam-sodium + TX, Metaphycus helvolus + TX, Metarhizium anisopliae var. acridum + TX, Metarhizium anisopliae var. anisopliae + TX, Metarhizium spp. + TX, metepa + TX, methiocarb + TX, methiotepa + TX, methomyl + TX, methoquin-butyl + TX, methoxyfenozide + TX, methyl apholate + TX, methyl bromide + TX, methyl eugenol + TX, methyl isothiocyanate + TX, methylneodecanamide + TX, metofluthrin + TX, metolcarb + TX, mexacarbate + TX, milbemectin + TX, milbemycin oxime + TX, momfluorothrin + TX, morzid + TX, moxidectin + TX, muscalure + TX, Muscodor albus 620 (NRRL Accession No. 30547) + TX, Muscodor roseus A3-5 (NRRL Accession No. 30548) + TX, Myrothecium verrucaria composition + TX, nabam + TX, NC-184 + TX, Neem tree based products + TX, Neodiprion sertifer NPV and N. lecontei NPV + TX, nickel bis(dimethyldithiocarbamate) + TX, niclosamide + TX, niclosamide-olamine + TX, nicofluprole + TX, nitenpyram + TX, nithiazine + TX, nitrapyrin + TX, octadeca- 82875_FF 53 2,13-dien-1-yl acetate + TX, octadeca-3,13-dien-1-yl acetate + TX, octhilinone + TX, omethoate + TX, orfralure + TX, Orius spp. + TX, oryctalure + TX, ostramone + TX, oxamate + TX, oxamyl + TX, oxazosulfyl + TX, oxolinic acid + TX, oxytetracycline + TX, Paecilomyces fumosoroseus + TX, Paecilomyces lilacinus + TX, parathion- ethyl + TX, Pasteuria nishizawae + TX, Pasteuria penetrans + TX, Pasteuria ramosa + TX, Pasteuria thornei + TX, Pasteuria usgae + TX, P-cymene + TX, penfluron + TX, pentachlorophenol + TX, permethrin + TX, phenothrin + TX, phorate + TX, phosphamidon + TX, phosphocarb + TX, Phytoseiulus persimilis + TX, picaridin + TX, pioxaniliprole + TX, piperazine + TX, piperflanilide (CAS number: 2615135-05-0) + TX, piperonylbutoxide + TX, pirimicarb + TX, pirimiphos-ethyl + TX, pirimiphos-methyl + TX, Plutella xylostella Granulosis virus + TX, Plutella xylostella Nucleopolyhedrovirus + TX, Polyhedrosis virus + TX, potassium and molybdenum andEDTA-chelated manganese + TX, potassium ethylxanthate + TX, potassium hydroxyquinoline sulfate + TX,prallethrin + TX, probenazole + TX, profenofos + TX, profluthrin + TX, propargite + TX, propetamphos + TX, propoxur + TX, prothiophos + TX, protrifenbute + TX, pyflubumide + TX, pymetrozine + TX, pyraclofos + TX, pyrafluprole + TX, pyrethrum + TX, pyridaben + TX, pyridalyl + TX, pyridin-4-amine + TX, pyrifluquinazon + TX, pyrimidifen + TX, pyriminostrobin + TX, pyriprole [394730-71-3] + TX, pyriprole + TX, pyriproxyfen + TX, QRD 420 (a terpenoid blend) + TX, QRD 452 (a terpenoid blend) + TX, QRD 460 (a terpenoid blend) + TX, Quillaja saponaria + TX, quinoclamine + TX, quinonamid + TX, resmethrin + TX, Rhodococcus globerulus AQ719 (NRRL Accession No B-21663) + TX, sarolaner + TX, S-bioallethrin + TX, sebufos + TX, selamectin + TX, siglure + TX, silafluofen + TX, simazine + TX, sodium pentachlorophenoxide + TX, sordidin + TX, spidoxamat + TX, spinetoram + TX, spinosad + TX, spirobudifen + TX, spirodiclofen + TX, spiromesifen + TX, spiropidion + TX, spirotetramat + TX, Spodoptera exigua multicapsid nuclear polyhedrosis virus + TX, Spodoptera frugiperda Nucleopolyhedrovirus + TX, Steinernema bibionis + TX, Steinernema carpocapsae + TX, Steinernema feltiae + TX, Steinernema glaseri + TX, Steinernema riobrave + TX, Steinernema riobravis + TX, Steinernema scapterisci + TX, Steinernema spp. + TX, Streptomyces galbus (NRRL Accession No.30232) + TX, Streptomyces sp. (NRRL Accession No. B-30145) + TX, streptomycin + TX, streptomycin sesquisulfate + TX, strychnine + TX, sulcatol + TX, sulfiflumin + TX, sulfoxaflor + TX, tazimcarb + TX, tebufenozide + TX, tebufenpyrad + TX, tebupirimiphos + TX, tecloftalam + TX, tefluthrin + TX, temephos + TX, tepa + TX, terbam + TX, terbufos + TX, terpenoid blend + TX, tetrachlorantraniliprole + TX, tetrachlorothiophene + TX, tetradec- 11-en-1-yl acetate + TX, tetradiphon + TX, tetramethrin + TX, tetramethylfluthrin + TX, tetranactin + TX, tetraniliprole + TX, theta-cypermethrin + TX, thiacloprid + TX, thiafenox + TX, thiamethoxam + TX, thiocyclam + TX, thiodicarb + TX, thiofanox + TX, thiohempa + TX, thiomersal + TX, thiometon + TX, thionazin + TX, thiophanate + TX, thiosultap + TX, thiotepa + TX, tiapyrachlor (CAS Number: 1255091-74-7) + TX, tigolaner + TX, tiorantraniliprole + TX, tioxazafen + TX, tolfenpyrad + TX, toxaphene + TX, tralomethrin + TX, transfluthrin + TX, tretamine + TX, triazamate + TX, triazophos + TX, triazuron + TX, tributyltin oxide + TX, trichlorfon + TX, trichloronate + TX, trichlorphon + TX, Trichogramma spp. + TX, trifenmorph + TX, trifluenfuronate + TX, triflumezopyrim + TX, trimedlure + TX, trimedlure A + TX, trimedlure B1 + TX, trimedlure B2 + TX, trimedlure C + TX, trimethacarb + TX, triphenyltin acetate + TX, triphenyltin hydroxide + TX, trunc-call + TX, tyclopyrazoflor + TX, Typhlodromus occidentalis + TX, uredepa + TX, Verticillium lecanii + TX, Verticillium spp. + TX, xylenols + TX, YI-5302 + TX, zeatin + TX, zeta-Cypermethrin + TX; N-[(1R)-1-benzyl-3-chloro-1-methyl- 82875_FF 54 but-3-enyl]-8-fluoro-quinoline-3-carboxamide + TX, N-[(1S)-1-benzyl-3-chloro-1-methyl-but-3-enyl]-8-fluoro- quinoline-3-carboxamide + TX, N-ethyl-N’-[5-methoxy-2-methyl-4-[(2-trifuoromethyl)tetrahydrofuran-2- yl]phenyl]-N-methyl-formamidine (these compounds may be prepared from the methods described in WO2019 / 110427) + TX, (3',4',5'-trifluoro-biphenyl-2-yl)-amide + TX, (3-methylisoxazol-5-yl)-[4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methanone (these compounds may be prepared from the methods described in WO 2017 / 220485) + TX, (4-phenoxyphenyl)methyl 2-amino-6-methyl-pyridine-3- carboxylate (this compound may be prepared from the methods described in WO 2014 / 006945) + TX, (5- methyl-2-pyridyl)-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methanone + TX, (7E,9Z)-dodeca-7,9- dien-1-yl acetate + TX, (9Z,11E)-tetradeca-9,11-dien-1-yl acetate + TX, (9Z,12E)-tetradeca-9,12-dien-1-ylacetate + TX, (E)-6-methylhept-2-en-4-ol + TX, (E)-dec-5-en-1-yl acetate with (E)-dec-5-en-1-ol + TX, (E)-tridec-4-en-1-yl acetate + TX, (E,Z)-tetradeca-4,10-dien-1-yl acetate, + TX, (R)-3-(difluoromethyl)-1-methyl-N- [1,1,3-trimethylindan-4-yl]pyrazole-4-carboxamide + TX, (Z)-dodec-7-en-1-yl acetate + TX, (Z)-hexadec-11-en- 1-yl acetate + TX, (Z)-hexadec-11-enal + TX, (Z)-hexadec-13-en-11-yn-1-yl acetate + TX, (Z)-icos-13-en-10- one + TX, (Z)-tetradec-7-en-1-al + TX, (Z)-tetradec-9-en-1-ol + TX, (Z)-tetradec-9-en-1-yl acetate + TX, (Z,2E)- 5-[1-(2,4-dichlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide (this compound may be prepared from the methods described in WO 2018 / 153707) + TX, (Z,2E)-5-[1-(4-chlorophenyl)pyrazol-3- yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide + TX, , [2-[3-[2-[1-[2-[3,5-bis(difluoromethyl)pyrazol-1- yl]acetyl]-4-piperidyl]thiazol-4-yl]-4,5-dihydroisoxazol-5-yl]-3-chloro-phenyl] methanesulfonate + TX, 1-(4,5- dimethylbenzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-isoquinoline + TX, 1-(4,5-dimethylbenzimidazol-1-yl)- 4,4-difluoro-3,3-dimethyl-isoquinoline + TX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4,5-trifluoro-3,3- dimethyl-isoquinoline + TX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4,6-trifluoro-3,3-dimethyl-isoquinoline + TX, 1-(6-chloro-7-methyl-pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-isoquinoline (these compounds may be prepared from the methods described in WO2017 / 025510) + TX, 1,1-bis(4-chlorophenyl)- 2-ethoxyethanol + TX, 1,1-dichloro-2,2-bis(4-ethylphenyl)ethane + TX, 1,2-dibromo-3-chloropropane + TX, 1,2-dichloropropane with 1,3-dichloropropene + TX, 1,3-dichloropropene + TX, 1,3-dimethoxy-1-[[4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea + TX, 1-[2-[[1-(4-chlorophenyl)pyrazol-3- yl]oxymethyl]-3-methyl-phenyl]-4-methyl-tetrazol-5-one + TX, 10-dien-1-yl acetate + TX, 14-methyloctadec-1- ene + TX, 1-bromo-2-chloroethane + TX, 1-dichloro-1-nitroethane + TX, 1-hydroxy-1H-pyridine-2-thione + TX, 1-methoxy-3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea + TX, 1-methyl-4-[3- methyl-2-[[2-methyl-4-(3,4,5-trimethylpyrazol-1-yl)phenoxy]methyl]phenyl]tetrazol-5-one + TX, 2- (difluoromethyl) - N- ((3R) - 1, 1, 3- trimethylindan- 4- yl) pyridine- 3- carboxamide + TX, 2- (difluoromethyl) - N- ((3R) - 1, 1, 3- trimethylindan- 4-yl) pyridine- 3- carboxamide + TX, 2-(1,3-dithiolan-2-yl)phenyl dimethylcarbamate + TX, 2-(2-butoxyethoxy)ethyl piperonylate + TX, 2-(2-butoxyethoxy)ethyl thiocyanate + TX, 2-(4,5-dimethyl-1,3-dioxolan-2-yl)phenyl methylcarbamate + TX, 2-(4-chloro-3,5-xylyloxy)ethanol + TX, 2- (difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide + TX, 2-(difluoromethyl)-N-[(3R)-3- ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide + TX, 2-(difluoromethyl)-N-[(3S)-3-ethyl-1,1-dimethyl- indan-4-yl]pyridine-3-carboxamide (this compound may be prepared from the methods described in WO 2014 / 095675) + TX, 2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide + TX, 2- 82875_FF 55 (octylthio)ethanol + TX, 2,2,2-trichloro-1-(3,4-dichlorophenyl)ethyl acetate + TX, 2,2-dichlorovinyl 2- ethylsulfinylethyl methyl phosphate + TX, 2,2-difluoro-N-methyl-2-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3- yl]phenyl]acetamide + TX, 2,4-dichlorophenyl benzenesulfonate + TX, 2,6-Dimethyl-1H,5H-[1,4]dithiino[2,3- c:5,6-c']dipyrrole-1,3,5,7(2H,6H)-tetrone (this compound may be prepared from the methods described in WO 2011 / 138281) + TX, 2-[2-fluoro-6-[(8-fluoro-2-methyl-3-quinolyl)oxy]phenyl]propan-2-ol + TX, 2-[6-(4- bromophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol (this compound may be prepared from the methods described in WO 2017 / 029179) + TX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)-3-pyridyl]- 1-(1,2,4-triazol-1-yl)propan-2-ol (this compound may be prepared from the methods described in WO 2017 / 029179) + TX, 2-chlorovinyl diethyl phosphate + TX, 2-fluoro-N-methyl-N-1-naphthylacetamide + TX, 2-imidazolidone + TX, 2-isovalerylindan-1,3-dione + TX, 2-methyl(prop-2-ynyl)aminophenyl methylcarbamate +TX, 2-oxo-N-propyl-2-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]acetamide (this compound may be prepared from the methods described in WO 2018 / 065414) + TX, 2-thiocyanatoethyl laurate + TX, 3-(4,4- difluoro-3,3-dimethyl-1-isoquinolyl)-7,8-dihydro-6H-cyclopenta[e]benzimidazole (these compounds may be prepared from the methods described in WO2016 / 156085) + TX, 3-(4,4-difluoro-3,4-dihydro-3,3- dimethylisoquinolin-1-yl)quinolone + TX, 3-(4-chlorophenyl)-5-methylrhodanine + TX, 3-(difluoromethyl)-1- methyl-N-[1,1,3-trimethylindan-4-yl]pyrazole-4-carboxamide + TX, 3,4-dichlorotetrahydrothiophene 1,1- dioxide + TX, 3-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxy-propyl]imidazole-4-carbonitrile (this compound may be prepared from the methods described in WO 2016 / 156290) + TX, 3-[2-(1- chlorocyclopropyl)-3-(3-chloro-2-fluoro-phenyl)-2-hydroxy-propyl]imidazole-4-carbonitrile (this compound may be prepared from the methods described in WO 2016 / 156290) + TX, 3-bromo-1-chloroprop-1-ene + TX, 3- chloro-6-methyl-5-phenyl-4-(2,4,6-trifluorophenyl)pyridazine + TX, 3-difluoromethyl-1-methyl-1H-pyrazole-4- carboxylic acid + TX, 3-ethyl-1-methoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea + TX, 3-methyl-1-phenylpyrazol-5-yl dimethylcarbamate + TX, 4- (2- bromo- 4- fluorophenyl) - N- (2- chloro- 6- fluorophenyl) - 1, 3- dimethyl- 1H- pyrazol- 5- amine + TX, 4-(2,6-difluorophenyl)-6-methyl-5-phenyl-pyridazine- 3-carbonitrile + TX, 4-(2-bromo-4-fluoro-phenyl)-N-(2-chloro-6-fluoro-phenyl)-2,5-dimethyl-pyrazol-3-amine + TX, 4-(quinoxalin-2-ylamino)benzenesulfonamide + TX, 4,4-difluoro-1-(5-fluoro-4-methyl-benzimidazol-1-yl)- 3,3-dimethyl-isoquinoline + TX, 4,4-difluoro-3,3-dimethyl-1-(6-methylpyrazolo[1,5-a]pyridin-3-yl)isoquinoline + TX, 4,4-difluoro-3,3-dimethyl-1-(7-methylpyrazolo[1,5-a]pyridin-3-yl)isoquinoline + TX, 4,4-dimethyl-2-[[4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one + TX, 4-[[6-[2-(2,4-difluorophenyl)-1,1- difluoro-2-hydroxy-3-(1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy] benzonitrile + TX, 4-[[6-[2-(2,4-difluorophenyl)- 1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy] benzonitrile + TX, 4-[[6-[2-(2,4- difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-thioxo-4H-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy] benzonitrile + TX, 4-chloro-2-(2-chloro-2-methyl-propyl)-5-[(6-iodo-3-pyridyl)methoxy]pyridazin-3-one + TX, 4-chlorophenyl phenyl sulfone + TX, 4-methyl(prop-2-ynyl)amino-3,5-xylyl methylcarbamate + TX, 4-methylnonan-5-ol with 4- methylnonan-5-one + TX, 5-(1,3-benzodioxol-5-yl)-3-hexylcyclohex-2-enone + TX, 5,5-dimethyl-2-[[4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one + TX, 5,5-dimethyl-3-oxocyclohex-1- enyl dimethylcarbamate + TX, 5-amino-1,3,4-thiadiazole-2-thiol zinc salt (2:1) + TX, 5-methyl-6-thioxo-1,3,5- thiadiazinan-3-ylacetic acid + TX, 6-chloro-3-(3-cyclopropyl-2-fluoro-phenoxy)-N-[2-(2,4-dimethylphenyl)-2,2- 82875_FF 56 difluoro-ethyl]-5-methyl-pyridazine-4-carboxamide (may be prepared from the methods described in WO 2020 / 109391) + TX, 6-chloro-3-(3-cyclopropyl-2-fluoro-phenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoro-ethyl]- 5-methyl-pyridazine-4-carboxamide (may be prepared from the methods described in WO 2020 / 109391) + TX, 6-chloro-4,4-difluoro-3,3-dimethyl-1-(4-methylbenzimidazol-1-yl)isoquinoline + TX, 6-chloro-N-[2-(2-chloro-4- methyl-phenyl)-2,2-difluoro-ethyl]-3-(3-cyclopropyl-2-fluoro-phenoxy)-5-methyl-pyridazine-4-carboxamide (may be prepared from the methods described in WO 2020 / 109391) + TX, 6-ethyl-5,7-dioxo- pyrrolo[4,5][1,4]dithiino[1,2-c]isothiazole-3-carbonitrile + TX, 6-isopentenylaminopurine + TX, 8-fluoro-N-[(1R)- 1-[(3-fluorophenyl)methyl]-1,3-dimethyl-butyl]quinoline-3-carboxamide + TX, 8-fluoro-N-[(1S)-1-[(3- fluorophenyl)methyl]-1,3-dimethyl-butyl]quinoline-3-carboxamide + TX, 8-hydroxyquinoline sulfate + TX,acethion + TX, acetoprole + TX, acibenzolar + TX, acibenzolar-S-methyl + TX, acrylonitrile + TX, Adoxophyesorana GV + TX, Agrobacterium radiobacter + TX, aldoxycarb + TX, aldrin + TX, allosamidin + TX, allyxycarb + TX, alpha-chlorohydrin + TX, alpha-ecdysone + TX, alpha-multistriatin + TX, aluminium phosphide + TX, Amblyseius spp. + TX, amectotractin + TX, ametoctradin + TX, amidithion + TX, amidothioate + TX, aminocarb + TX, aminopyrifen + TX, amisulbrom + TX, amiton + TX, amiton hydrogen oxalate + TX, amitraz + TX, anabasine + TX, Anagrapha falcifera NPV + TX, Anagrus atomus + TX, ancymidol + TX, anilazine + TX, anisiflupurin + TX, anthraquinone + TX, antu + TX, Aphelinus abdominalis + TX, Aphidius colemani + TX, Aphidoletes aphidimyza + TX, apholate + TX, aramite + TX, arsenous oxide + TX, athidathion + TX, Autographa californica NPV + TX, azaconazole + TX, azamethiphos + TX, azobenzene + TX, azothoate + TX, azoxystrobin + TX, Bacillus sphaericus Neide + TX, Bacillus thuringiensis delta endotoxins + TX, barium carbonate + TX, barium hexafluorosilicate + TX, barium polysulfide + TX, barthrin + TX, Bayer 22 / 190 + TX, Bayer 22408 + TX, Beauveria brongniartii + TX, benalaxyl + TX, benclothiaz + TX, benomyl + TX, benoxafos + TX, benthiavalicarb + TX, benzothiostrobin + TX, benzovindiflupyr + TX, benzyl benzoate + TX, beta-cyfluthrin + TX, beta- cypermethrin + TX, bethoxazin + TX, bioethanomethrin + TX, biopermethrin + TX, bis(2-chloroethyl) ether + TX, bis(tributyltin) oxide + TX, bisazir + TX, bisthiosemi + TX, bitertanol + TX, bixafen + TX, blasticidin-S + TX, borax + TX, bordeaux mixture + TX, boscalid + TX, brevicomin + TX, brodifacoum + TX, brofenvalerate + TX, bromadiolone + TX, bromethalin + TX, bromfenvinfos + TX, bromoacetamide + TX, bromocyclen + TX, bromo- DDT + TX, bromophos + TX, bromopropylate + TX, bromuconazole + TX, bronopol + TX, bufencarb + TX, bupirimate + TX, buprofezin + TX, busulfan + TX, but-3-ynyl N-[6-[[(Z)-[(1-methyltetrazol-5-yl)-phenyl- methylene]amino]oxymethyl]-2-pyridyl]carbamate + TX, butacarb + TX, butathiofos + TX, butocarboxim + TX, butonate + TX, butopyronoxyl + TX, butoxy(polypropylene glycol) + TX, butoxycarboxim + TX, butylpyridaben + TX, calcium arsenate + TX, calcium cyanide + TX, calcium polysulfide + TX, camphechlor + TX, captafol + TX, captan + TX, carbanolate + TX, carbendazim + TX, carbon disulfide + TX, carbon tetrachloride + TX, carbophenothion + TX, carboxin + TX, cartap hydrochloride + TX, CAS Number: 2454319-63-0 + TX, CAS Number: 83-46-5 + TX, cevadine + TX, chinomethionat + TX, chloralose + TX, chlorbenside + TX, chlorbicyclen + TX, chlordane + TX, chlordecone + TX, chlordimeform + TX, chlordimeform hydrochloride + TX, chlorfenethol + TX, chlorfenson + TX, chlorfensulfide + TX, chlorobenzilate + TX, chloroform + TX, chloroinconazide + TX, chloromebuform + TX, chloromethiuron + TX, chloroneb + TX, chlorophacinone + TX, chloropicrin + TX, chloropropylate + TX, chlorothalonil + TX, chlorphoxim + TX, chlorprazophos + TX, chlorthiophos + TX, 82875_FF 57 chlozolinate + TX, cholecalciferol + TX, Chrysoperla carnea + TX, cinerin I + TX, cinerin II + TX, cinerins + TX, cismethrin + TX, cis-resmethrin + TX, clocythrin + TX, closantel + TX, codlelure + TX, codlemone + TX, copper acetoarsenite + TX, copper arsenate + TX, copper dioctanoate + TX, copper hydroxide + TX, copper naphthenate + TX, copper oleate + TX, copper oxide + TX, copper oxychloride + TX, copper sulfate + TX, coumachlor + TX, coumafuryl + TX, coumaphos + TX, coumatetralyl + TX, coumethoxystrobin (jiaxiangjunzhi) + TX, coumithoate + TX, coumoxystrobin + TX, cresol + TX, crimidine + TX, crotamiton + TX, crotoxyphos + TX, crufomate + TX, cryolite + TX, Cryptolaemus montrouzieri + TX, CS 708 + TX, cuelure + TX, cufraneb + TX, cyanofenphos + TX, cyanophos + TX, cyanthoate + TX, cyazofamid + TX, cybutryne + TX, cyclethrin + TX, cyclobutrifluram + TX, Cydia pomonella GV + TX, cyflufenamid + TX, cymiazole + TX, cymoxanil + TX,cyproconazole + TX, cyprodinil + TX, cythioate + TX, cytokinins + TX, Dacnusa sibirica + TX, DAEP + TX,dazomet + TX, DCIP + TX, DCPM + TX, DDT + TX, debacarb + TX, decarbofuran + TX, demephion + TX, demephion-O + TX, demephion-S + TX, demeton-methyl + TX, demeton-O + TX, demeton-O-methyl + TX, demeton-S + TX, demeton-S-methyl + TX, demeton-S-methylsulfon + TX, diamidafos + TX, dibutyl adipate + TX, dibutyl phthalate + TX, dibutyl succinate + TX, dicapthon + TX, dichlobentiazox + TX, dichlofenthion + TX, dichlofluanid + TX, dichlone + TX, dichlorophen + TX, dichlorvos + TX, dichlozoline + TX, dicliphos + TX, diclocymet + TX, diclomezine + TX, dicloran + TX, dicresyl + TX, dicyclanil + TX, dicyclopentadiene + TX, dieldrin + TX, dienochlor + TX, diethofencarb + TX, diethyl 5-methylpyrazol-3-yl phosphate + TX, diethyltoluamide + TX, difenacoum + TX, difenoconazole + TX, difethialone + TX, diflovidazin + TX, Diglyphus isaea + TX, dilor + TX, dimatif + TX, dimefluthrin + TX, dimefox + TX, dimetan + TX, dimethirimol + TX, dimethomorph + TX, dimethrin + TX, dimethyl carbate + TX, dimethyl phthalate + TX, dimethylvinphos + TX, dimetilan + TX, dimoxystrobin + TX, dinex + TX, dinex-diclexine + TX, diniconazole + TX, dinocap-4 + TX, dinocap-6 + TX, dinocton + TX, dinopenton + TX, dinoprop + TX, dinosam + TX, dinoseb + TX, dinosulfon + TX, dinoterbon + TX, diofenolan + TX, dioxabenzofos + TX, dioxathion + TX, diphacinone + TX, diphenyl sulfone + TX, dipymetitrone + TX, dipyrithione + TX, disparlure + TX, disulfiram + TX, dithianon + TX, dithicrofos + TX, DNOC + TX, dodec-8-en-1-yl acetate + TX, dodec-9-en-1-yl acetate + TX, dodeca-8 + TX, dodemorph + TX, dodicin + TX, dodine + TX, dofenapyn + TX, dominicalure + TX, doramectin + TX, DSP + TX, d- tetramethrin + TX, ecdysterone + TX, edifenphos + TX, EI 1642 + TX, EMPC + TX, Encarsia formosa + TX, endothal + TX, endothion + TX, enestroburin + TX, enoxastrobin + TX, EPBP + TX, epoxiconazole + TX, eprinomectin + TX, Eretmocerus eremicus + TX, ergocalciferol + TX, etaphos + TX, ethaboxam + TX, ethiofencarb + TX, ethirimol + TX, ethoate-methyl + TX, ethyl 1-[[4-[(Z)-2-ethoxy-3,3,3-trifluoro-prop-1- enoxy]phenyl]methyl]pyrazole-3-carboxylate (may be prepared from the methods described in WO 2020 / 056090) + TX, ethyl 1-[[4-[[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy]phenyl]methyl]pyrazole-3- carboxylate (may be prepared from the methods described in WO 2020 / 056090) + TX, ethyl 1-[[4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrazole-4-carboxylate + TX, ethyl 1-[[5-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]-2-thienyl]methyl]pyrazole-4-carboxylate (this compound may be prepared from the methods described in WO 2018 / 158365) + TX, ethyl 4-methyloctanoate + TX, ethyl formate + TX, ethyl hexanediol + TX, ethylene dibromide + TX, ethylene dichloride + TX, ethylene oxide + TX, etridiazole + TX, etrimfos + TX, eugenol + TX, EXD + TX, famoxadone + TX, farnesol + TX, farnesol with 82875_FF 58 nerolidol + TX, fenamidone + TX, fenaminosulf + TX, fenaminstrobin + TX, fenarimol + TX, fenazaflor + TX, fenbuconazole + TX, fenbutatin oxide + TX, fenchlorphos + TX, feneptamidoquin (CAS Number: 2132414-04- 9) + TX, fenethacarb + TX, fenfuram + TX, fenhexamid + TX, fenitrothion + TX, fenopyramid (CAS Number: 2344721-61-3) + TX, fenothiocarb + TX, fenoxacrim + TX, fenoxanil + TX, fenpiclonil + TX, fenpicoxamid + TX, fenpirithrin + TX, fenpropidin + TX, fenpropimorph + TX, fenpyrad + TX, fenpyrazamine + TX, fenpyroximate + TX, fenson + TX, fensulfothion + TX, fenthion + TX, fenthion-ethyl + TX, fentin + TX, fentrifanil + TX, ferbam + TX, ferimzone + TX, ferric phosphate + TX, flocoumafen + TX, florylpicoxamid + TX, fluazinam + TX, flubeneteram + TX, flubenzimine + TX, flucofuron + TX, flucycloxuron + TX, fludioxonil + TX, fluenetil + TX, flufenoxadiazam + TX, flufenoxystrobin + TX, fluindapyr + TX, flumetylsulforim + TX, flumorph + TX, fluopicolide+ TX, fluopimomide + TX, fluopyram + TX, fluorbenside + TX, fluoroacetamide + TX, fluoroimide + TX,fluoxapiprolin + TX, fluoxastrobin + TX, fluoxytioconazole + TX, flupropadine + TX, flupropadine hydrochloride + TX, fluquinconazole + TX, flusilazole + TX, flusulfamide + TX, flutianil + TX, flutolanil + TX, flutriafol + TX, fluxapyroxad + TX, FMC 1137 + TX, folpet + TX, formaldehyde + TX, formetanate + TX, formetanate hydrochloride + TX, formparanate + TX, fosetyl-aluminium + TX, fosmethilan + TX, fospirate + TX, fosthietan + TX, frontalin + TX, fuberidazole + TX, furalaxyl + TX, furametpyr + TX, furathiocarb + TX, furethrin + TX, furfural + TX, gamma-HCH + TX, glyodin + TX, grandlure + TX, grandlure I + TX, grandlure II + TX, grandlure III + TX, grandlure IV + TX, guazatine + TX, guazatine acetates + TX, halfenprox + TX, HCH + TX, hemel + TX, hempa + TX, HEOD + TX, heptachlor + TX, heterophos + TX, Heterorhabditis bacteriophora and H. megidis + TX, hexaconazole + TX, hexadecyl cyclopropanecarboxylate + TX, hexalure + TX, hexamide + TX, HHDN + TX, Hippodamia convergens + TX, hydrargaphen + TX, hydrated lime + TX, hydrogen cyanide + TX, hymexazol + TX, hyquincarb + TX, imanin + TX, imazalil + TX, imibenconazole + TX, iminoctadine + TX, inpyrfluxam + TX, ipconazole + TX, ipfentrifluconazole + TX, ipflufenoquin + TX, iprobenphos + TX, iprodione + TX, iprovalicarb + TX, ipsdienol + TX, ipsenol + TX, IPSP + TX, isamidofos + TX, isazofos + TX, isobenzan + TX, isocarbophos + TX, isodrin + TX, isofenphos + TX, isofetamid + TX, isoflucypram + TX, isolane + TX, isoprothiolane + TX, isopyrazam + TX, isotianil + TX, isoxathion + TX, japonilure + TX, jasmolin I + TX, jasmolin II + TX, jodfenphos + TX, juvenile hormone I + TX, juvenile hormone II + TX, juvenile hormone III + TX, kadethrin + TX, kasugamycin + TX, kasugamycin hydrochloride hydrate + TX, kelevan + TX, kinetin + TX, kinoprene + TX, kresoxim-methyl + TX, lead arsenate + TX, Leptomastix dactylopii + TX, leptophos + TX, lindane + TX, lineatin + TX, lirimfos + TX, litlure + TX, looplure + TX, lvbenmixianan + TX, lythidathion + TX, Macrolophus caliginosus + TX, magnesium phosphide + TX, malonoben + TX, Mamestra brassicae NPV + TX, mancopper + TX, mancozeb + TX, mandestrobin + TX, mandipropamid + TX, maneb + TX, mazidox + TX, m- cumenyl methylcarbamate + TX, mecarbam + TX, mecarphon + TX, medlure + TX, mefentrifluconazole + TX, megatomoic acid + TX, menazon + TX, mepanipyrim + TX, meperfluthrin + TX, mephosfolan + TX, mepronil + TX, mercuric oxide + TX, mercurous chloride + TX, mesulfen + TX, mesulfenfos + TX, metalaxyl + TX, metam + TX, metam-potassium + TX, metam-sodium + TX, Metaphycus helvolus + TX, Metarhizium anisopliae var. acridum + TX, Metarhizium anisopliae var. anisopliae + TX, metarylpicoxamid + TX, metconazole + TX, metepa + TX, methacrifos + TX, methanesulfonyl fluoride + TX, methasulfocarb + TX, methiotepa + TX, methocrotophos + TX, methoprene + TX, methoquin-butyl + TX, methothrin + TX, methoxychlor + TX, methyl 82875_FF 59 (Z)-2-(5-cyclohexyl-2-methyl-phenoxy)-3-methoxy-prop-2-enoate + TX, methyl (Z)-2-(5-cyclopentyl-2-methyl- phenoxy)-3-methoxy-prop-2-enoate (these compounds may be prepared from the methods described in WO2020 / 193387) + TX, methyl (Z)-2-[5-(3-isopropylpyrazol-1-yl)-2-methyl-phenoxy]-3-methoxy-prop-2- enoate + TX, methyl (Z)-3-methoxy-2-[2-methyl-5-(3-propylpyrazol-1-yl)phenoxy]prop-2-enoate + TX, methyl (Z)-3-methoxy-2-[2-methyl-5-(4-propyltriazol-2-yl)phenoxy]prop-2-enoate + TX, methyl (Z)-3-methoxy-2-[2- methyl-5-[3-(trifluoromethyl)pyrazol-1-yl]phenoxy]prop-2-enoate (these compounds may be prepared from the methods described in WO2020 / 079111) + TX, methyl (Z)-3-methoxy-2-[2-methyl-5-[4-(trifluoromethyl)triazol- 2-yl]phenoxy]prop-2-enoate + TX, methyl apholate + TX, methyl bromide + TX, methyl eugenol + TX, methyl isothiocyanate + TX, methyl N-[[4-[1-(2,6-difluoro-4-isopropyl-phenyl)pyrazol-4-yl]-2-methyl-phenyl]methyl]carbamate (may be prepared from the methods described in WO 2020 / 097012) + TX, methyl N-[[4-[1-(4-cyclopropyl-2,6-difluoro-phenyl)pyrazol-4-yl]-2-methyl-phenyl]methyl]carbamate (may be prepared from the methods described in WO 2020 / 097012) + TX, methyl N-[[5-[4-(2,4-dimethylphenyl)triazol-2-yl]-2-methyl- phenyl]methyl]carbamate + TX, methylchloroform + TX, methylene chloride + TX, methylneodecanamide + TX, metiram + TX, metolcarb + TX, metomi-nostrobin + TX, metoxadiazone + TX, metrafenone + TX, metyltetraprole + TX, MGK 264 + TX, milbemycin oxime + TX, mipafox + TX, mirex + TX, monocrotophos + TX, morphothion + TX, morzid + TX, moxidectin + TX, muscalure + TX, myclobutanil + TX, myclozoline + TX, Myrothecium verrucaria composition + TX, N-((1R)-1-benzyl-3-chloro-1-methyl-but-3-enyl)-8-fluoro-quinoline- 3-carboxamide (these compounds may be prepared from the methods described in WO2017 / 153380) + TX, N-((1S)-1-benzyl-3-chloro-1-methyl-but-3-enyl)-8-fluoro-quinoline-3-carboxamide (these compounds may be prepared from the methods described in WO2017 / 153380) + TX, N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl- N-methyl-formamidine + TX, N'-(2-chloro-5-methyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine + TX, N,2-dimethoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide + TX, N,N-dimethyl- 1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-1,2,4-triazol-3-amine (THESE COMPOUNDS may be prepared from the methods described in WO 2017 / 055473, WO 2017 / 055469, WO 2017 / 093348 and WO 2017 / 118689) + TX, N-[(1R)-1-benzyl-1,3-dimethyl-butyl]-7,8-difluoro-quinoline-3-carboxamide + TX, N- [(1R)-1-benzyl-1,3-dimethyl-butyl]-8-fluoro-quinoline-3-carboxamide + TX, N-[(1R)-1-benzyl-3,3,3-trifluoro-1- methyl-propyl]-8-fluoro-quinoline-3-carboxamide + TX, N-[(1S)-1-benzyl-1,3-dimethyl-butyl]-7,8-difluoro- quinoline-3-carboxamide + TX, N-[(1S)-1-benzyl-1,3-dimethyl-butyl]-8-fluoro-quinoline-3-carboxamide + TX, N-[(1S)-1-benzyl-3,3,3-trifluoro-1-methyl-propyl]-8-fluoro-quinoline-3-carboxamide + TX, N-[(E)-methoxy iminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + TX, N-[(Z)-methoxyiminomethyl]-4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + TX, N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl] methyl]propanamide + TX, N-[2-[2,4-dichloro-phenoxy]phenyl]-3-(difluoromethyl)-1-methyl-pyrazole-4- carboxamide + TX, N-[2-[2-chloro-4-(trifluoromethyl)phenoxy]phenyl]-3-(difluoromethyl)-1-methyl-pyrazole-4- carboxamide + TX, N'-[2-chloro-4-(2-fluorophenoxy)-5-methyl-phenyl]-N-ethyl-N-methyl-formamidine (this compound may be prepared from the methods described in WO 2016 / 202742) + TX, N'-[4-(4,5-dichlorothiazol- 2-yl)oxy-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine + TX, N'-[5-bromo-2-methyl-6-(1-methyl-2- propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine + TX, N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy- ethoxy)-3-pyridyl]-N-isopropyl-N-methyl-formamidine (these compounds may be prepared from the methods 82875_FF 60 described in WO2015 / 155075) + TX, N'-[5-bromo-2-methyl-6-(2-propoxypropoxy)-3-pyridyl]-N-ethyl-N-methyl- formamidine (this compound may be prepared from the methods described in IPCOM000249876D) + TX, N'- [5-bromo-2-methyl-6-[(1R)-1-methyl-2-propoxy-ethoxy]-3-pyridyl]-N-ethyl-N-methyl-formamidine + TX, N'-[5- bromo-2-methyl-6-[(1S)-1-methyl-2-propoxy-ethoxy]-3-pyridyl]-N-ethyl-N-methyl-formamidine + TX, N'-[5- chloro-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine + TX, N-[N-methoxy- C-methyl-carbonimidoyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide (these compounds may be prepared from the methods described in WO 2018 / 202428) + TX, N’-[4-(1-cyclopropyl-2,2,2-trifluoro-1- hydroxy-ethyl)-5-methoxy-2-methyl-phenyl]-N-isopropyl-N-methyl-formamidine (these compounds may be prepared from the methods described in WO2018 / 228896) + TX, nabam + TX, naftalofos + TX, naled + TX,naphthalene + TX, NC-170 + TX, Neodiprion sertifer NPV and N. lecontei NPV + TX, nerolidol + TX, N-ethyl-2-methyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide + TX, N-ethyl-N’-[5- methoxy-2-methyl-4-[(2-trifluoromethyl)oxetan-2-yl]phenyl]-N-methyl-formamidine + TX, nickel bis(dimethyl dithiocarbamate) + TX, niclosamide-olamine + TX, nicotine + TX, nicotine sulfate + TX, nifluridide + TX, nikkomycins + TX, N-isopropyl-N’-[5-methoxy-2-methyl-4-(2,2,2-trifluoro-1-hydroxy-1-phenyl-ethyl)phenyl]-N- methyl-formamidine + TX, nithiazine + TX, nitrapyrin + TX, nitrilacarb + TX, nitrilacarb 1:1 zinc chloride complex + TX, nitrothal-isopropyl + TX, N-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl] cyclopropanecarboxamide + TX, N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + TX, N- methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzenecarbothioamide + TX, norbormide + TX, nuarimol + TX, O,O,O',O'-tetrapropyl dithiopyrophosphate + TX, octadeca-2,13-dien-1-yl acetate + TX, octadeca-3,13- dien-1-yl acetate + TX, octhilinone + TX, ofurace + TX, oleic acid + TX, omethoate + TX, orfralure + TX, Orius spp. + TX, oryctalure + TX, orysastrobin + TX, ostramone + TX, oxadixyl + TX, oxamate + TX, oxathiapiprolin + TX, oxine-copper + TX, oxolinic acid + TX, oxycarboxin + TX, oxydeprofos + TX, oxydisulfoton + TX, oxytetracycline + TX, paclobutrazole + TX, Paecilomyces fumosoroseus + TX, para-dichlorobenzene + TX, parathion + TX, parathion-methyl + TX, pefurazoate + TX, penconazole + TX, pencycuron + TX, penflufen + TX, penfluron + TX, pentachlorophenol + TX, pentachlorophenyl laurate + TX, penthiopyrad + TX, permethrin + TX, PH 60-38 + TX, phenamacril + TX, phenkapton + TX, phosacetim + TX, phosalone + TX, phosdiphen + TX, phosfolan + TX, phosglycin + TX, phosnichlor + TX, phosphamidon + TX, phosphine + TX, phosphorus + TX, phoxim-methyl + TX, phthalide + TX, Phytoseiulus persimilis + TX, picarbutrazox + TX, picaridin + TX, picoxystrobin + TX, pindone + TX, piperazine + TX, piperonyl butoxide + TX, piprotal + TX, pirimetaphos + TX, polychlorodicyclopentadiene isomers + TX, polychloroterpenes + TX, polynactins + TX, polyoxins + TX, potassium arsenite + TX, potassium ethylxanthate + TX, potassium hydroxyquinoline sulfate + TX, potassium thiocyanate + TX, pp'-DDT + TX, precocene I + TX, precocene II + TX, precocene III + TX, primidophos + TX, probenazole + TX, prochloraz + TX, proclonol + TX, procymidone + TX, profluthrin + TX, promacyl + TX, promecarb + TX, propamocarb + TX, propiconazole + TX, propineb + TX, propoxur + TX, propyl isomer + TX, proquinazid + TX, prothidathion + TX, prothioconazole + TX, prothiofos + TX, prothoate + TX, pydiflumetofen + TX, pyraclostrobin + TX, pyrametostrobin + TX, pyraoxystrobin + TX, pyrapropoyne + TX, pyraziflumid + TX, pyrazophos + TX, pyresmethrin + TX, pyrethrin I + TX, pyrethrin II + TX, pyrethrins + TX, pyribencarb + TX, pyridachlometyl + TX, pyridaphenthion + TX, pyridin-4-amine + TX, pyrifenox + TX, pyrimethanil + TX, 82875_FF 61 pyrimitate + TX, pyrimorph + TX, pyrinuron + TX, pyriofenone + TX, pyrisoxazole + TX, pyroquilon + TX, quassia + TX, quinalphos + TX, quinalphos-methyl + TX, quinoclamine + TX, quinofumelin + TX, quinonamid + TX, quinothion + TX, quinoxyfen + TX, quintiofos + TX, quintozene + TX, R-1492 + TX, rafoxanide + TX, resmethrin + TX, Reynoutria sachalinensis extract + TX, ribavirin + TX, R metalaxyl + TX, rotenone + TX, ryania + TX, ryanodine + TX, S421 + TX, sabadilla + TX, schradan + TX, scilliroside + TX, seboctylamine + TX, sebufos + TX, sedaxane + TX, selamectin + TX, sesamex + TX, sesasmolin + TX, SI-0009 + TX, siglure + TX, simazine + TX, simeconazole + TX, sodium arsenite + TX, sodium cyanide + TX, sodium fluoride + TX, sodium fluoroacetate + TX, sodium hexafluorosilicate + TX, sodium pentachlorophenoxide + TX, sodium selenate + TX, sodium tetrathiocarbonate + TX, sodium thiocyanate + TX, sophamide + TX, sordidin + TX,spiroxamine + TX, SSI-121 + TX, Steinernema bibionis + TX, Steinernema carpocapsae + TX, Steinernemafeltiae + TX, Steinernema glaseri + TX, Steinernema riobrave + TX, Steinernema riobravis + TX, Steinernema scapterisci + TX, Steinernema spp. + TX, streptomycin + TX, streptomycin sesquisulfate + TX, strychnine + TX, sulcatol + TX, sulcofuron + TX, sulcofuron-sodium + TX, sulfiram + TX, sulfluramid + TX, sulfotep + TX, sulfoxide + TX, sulfur + TX, sulfuryl fluoride + TX, sulprofos + TX, tar oils + TX, tau-fluvalinate + TX, tazimcarb + TX, TDE + TX, tebuconazole + TX, tebufloquin + TX, tebupirimfos + TX, tecloftalam + TX, temephos + TX, tepa + TX, TEPP + TX, terallethrin + TX, terbam + TX, tert-butyl N-[6-[[[(1-methyltetrazol-5-yl)-phenyl- methylene]amino]oxymethyl]-2-pyridyl]carbamate + TX, tetrachloroethane + TX, tetrachlorothiophene + TX, tetraconazole + TX, tetradec-11-en-1-yl acetate + TX, tetradifon + TX, tetramethylfluthrin + TX, tetrasul + TX, thallium sulfate + TX, thiabendazole + TX, thiafenox + TX, thiapronil + TX, thicrofos + TX, thifluzamide + TX, thiocarboxime + TX, thiocyclam + TX, thiocyclam hydrogen oxalate + TX, thiodiazole copper + TX, thiofanox + TX, thiohempa + TX, thiomersal + TX, thiometon + TX, thionazin + TX, thiophanate + TX, thiophanate-methyl + TX, thioquinox + TX, thiosultap + TX, thiosultap-sodium + TX, thiotepa + TX, thiram + TX, thuringiensin + TX, tiadinil + TX, tolclofos-methyl + TX, tolprocarb + TX, tolylfluanid + TX, tralomethrin + TX, transpermethrin + TX, tretamine + TX, triadimefon + TX, triadimenol + TX, triamiphos + TX, triarathene + TX, triazamate + TX, triazophos + TX, triazoxide + TX, triazuron + TX, tributyltin oxide + TX, trichlormetaphos-3 + TX, trichloronat + TX, Trichogramma spp. + TX, triclopyricarb + TX, tricyclazole + TX, tridemorph + TX, trifenmorph + TX, trifenofos + TX, trifloxystrobin + TX, triflumizole + TX, triforine + TX, trimedlure + TX, trimedlure A + TX, trimedlure B1 + TX, trimedlure B2 + TX, trimedlure C + TX, trimethacarb + TX, trinactin + TX, trinexapac + TX, triphenyltin acetate + TX, triphenyltin hydroxide + TX, triprene + TX, triticonazole + TX, trunc-call + TX, Typhlodromus occidentalis + TX, uredepa + TX, validamycin + TX, valifenalate + TX, vamidothion + TX, vaniliprole + TX, veratridine + TX, veratrine + TX, verbutin + TX, Verticillium lecanii + TX, vinclozoline + TX, warfarin + TX, XMC + TX, xylenols + TX, zeatin + TX, zetamethrin + TX, zhongshengmycin + TX, zinc naphthenate + TX, zinc phosphide + TX, zinc thiazole + TX, zineb + TX, ziram + TX, zolaprofos + TX, zoxamide + TX; Acinetobacter lwoffii + TX, Acremonium alternatum + TX, Acremonium cephalosporium + TX, Acremonium diospyri + TX, Acremonium obclavatum + TX, Adoxophyes orana granulovirus (AdoxGV) (Capex®) + TX, Agrobacterium radiobacter strain K84 (Galltrol-A®) + TX, Alternaria alternate + TX, Alternaria cassia + TX, Alternaria destruens (Smolder®) + TX, Ampelomyces quisqualis (AQ10®) + TX, Aspergillus flavus AF36 (AF36®) + TX, Aspergillus flavus NRRL 21882 (Aflaguard®) + TX, Aspergillus spp. + TX, Aureobasidium 82875_FF 62 pullulans + TX, Azospirillum (MicroAZ®, TAZO B®) + TX, Azotobacter + TX, Azotobacter chroocuccum (Azotomeal®) + TX, Azotobacter cysts (Bionatural Blooming Blossoms®) + TX, Bacillus amyloliquefaciens + TX, Bacillus cereus + TX, Bacillus chitinosporus strain AQ746 + TX, Bacillus chitinosporus strain CM-1 + TX, Bacillus circulans + TX, Bacillus firmus (BioSafe®, BioNem-WP®) in particular strain CNMC 1-1582 (e.g. VOTIVO® from BASF SE) + TX, Bacillus licheniformis strain 3086 (EcoGuard®, Green Releaf®) + TX, Bacillus licheniformis strain HB-2 (Biostart™ formerly Rhizoboost®) + TX, Bacillus macerans + TX, Bacillus marismortui + TX, Bacillus megaterium + TX, Bacillus mycoides strain AQ726 + TX, Bacillus papillae (Milky Spore Powder®) + TX, Bacillus pumilus spp. + TX, Bacillus pumilus strain AQ717 + TX, Bacillus pumilus strain GB34 (Yield Shield®) + TX, Bacillus pumilus strain QST 2808 (Sonata®, Ballad Plus®) + TX, Bacillus sphaericus(VectoLex®) + TX, Bacillus spp. + TX, Bacillus spp. strain AQ175 + TX, Bacillus spp. strain AQ177 + TX,Bacillus spp. strain AQ178 + TX, Bacillus subtilis strain AQ153 + TX, Bacillus subtilis strain AQ743 + TX, Bacillus subtilis strain QST 713 (CEASE®, Serenade®, Rhapsody®) + TX, Bacillus subtilis strain QST 714 (JAZZ®) + TX, Bacillus subtilis strain QST3002 + TX, Bacillus subtilis strain QST3004 + TX, Bacillus subtilis var. amyloliquefaciens strain FZB24 (Taegro®, Rhizopro®) + TX, Bacillus thuringiensis aizawai GC 91 (Agree®) + TX, Bacillus thuringiensis Cry 2Ae + TX, Bacillus thuringiensis Cry1Ab + TX, Bacillus thuringiensis israelensis (BMP123®, Aquabac®, VectoBac®) + TX, Bacillus thuringiensis kurstaki (Javelin®, Deliver®, CryMax®, Bonide®, Scutella WP®, Turilav WP ®, Astuto®, Dipel WP®, Biobit®, Foray®) + TX, Bacillus thuringiensis kurstaki BMP 123 (Baritone®) + TX, Bacillus thuringiensis kurstaki HD-1 (Bioprotec-CAF / 3P®) + TX, Bacillus thuringiensis strain AQ52 + TX, Bacillus thuringiensis strain BD#32 + TX, Bacillus thuringiensis tenebrionis (Novodor®, BtBooster) + TX, Bacillus thuringiensis var. aizawai (XenTari®, DiPel®) + TX, bacteria spp. (GROWMEND®, GROWSWEET®, Shootup®) + TX, bacteriophage of Clavipacter michiganensis (AgriPhage®, Bakflor®) + TX, Beauveria bassiana (Beaugenic®, Brocaril WP®) + TX, Beauveria bassiana GHA (Mycotrol ES®, Mycotrol O®, BotaniGuard®) + TX, Beauveria brongniartii (Engerlingspilz®, Schweizer Beauveria®, Melocont®) + TX, Beauveria spp. + TX, Botrytis cineria + TX, Bradyrhizobium japonicum (TerraMax®) + TX, Brevibacillus brevis + TX, Burkholderia cepacia (Deny®, Intercept®, Blue Circle®) + TX, Burkholderia gladii + TX, Burkholderia gladioli + TX, Burkholderia spp. + TX, Canadian thistle fungus (CBH Canadian Bioherbicide®) + TX, Candida butyri + TX, Candida famata + TX, Candida fructus + TX, Candida glabrata + TX, Candida guilliermondii + TX, Candida melibiosica + TX, Candida oleophila strain O + TX, Candida parapsilosis + TX, Candida pelliculosa + TX, Candida pulcherrima + TX, Candida reukaufii + TX, Candida saitoana (Bio-Coat®, Biocure®) + TX, Candida sake + TX, Candida spp. + TX, Candida tenius + TX, Cedecea davisae + TX, Cellulomonas flavigena + TX, Chaetomium cochliodes (Nova-Cide®) + TX, Chaetomium globosum (Nova-Cide®) + TX, Chromobacterium subtsugae strain PRAA4-1T (Grandevo®) + TX, Cladosporium chlorocephalum + TX, Cladosporium cladosporioides + TX, Cladosporium oxysporum + TX, Cladosporium spp. + TX, Cladosporium tenuissimum + TX, Clonostachys rosea (EndoFine®) + TX, Colletotrichum acutatum + TX, Coniothyrium minitans (Cotans WG®) + TX, Coniothyrium spp. + TX, Cryptococcus albidus (YIELDPLUS®) + TX, Cryptococcus humicola + TX, Cryptococcus infirmo-miniatus + TX, Cryptococcus laurentii + TX, Cryptophlebia leucotreta granulovirus (Cryptex®) + TX, Cupriavidus campinensis + TX, Cydia pomonella granulovirus (CYD-X®, Madex®, Madex® Plus, Madex Max, 82875_FF 63 Carpovirusine® + TX, Cylindrobasidium laeve (Stumpout®) + TX, Cylindrocladium + TX, Debaryomyces hansenii + TX, Drechslera hawaiinensis + TX, Enterobacter cloacae + TX, Enterobacteriaceae + TX, Entomophtora virulenta (Vektor®) + TX, Epicoccum nigrum + TX, Epicoccum purpurascens + TX, Epicoccum spp. + TX, Filobasidium floriforme + TX, Fusarium acuminatum + TX, Fusarium chlamydosporum + TX, Fusarium oxysporum (Fusaclean®, Biofox C®) + TX, Fusarium proliferatum + TX, Fusarium spp. + TX, Galactomyces geotrichum + TX, Gliocladium catenulatum (Primastop®, Prestop®) + TX, Gliocladium roseum + TX, Gliocladium spp. (SoilGard®) + TX, Gliocladium virens (Soilgard®) + TX, Granulovirus (Granupom®) + TX, Halobacillus halophilus + TX, Halobacillus litoralis + TX, Halobacillus trueperi + TX, Halomonas spp. + TX, Halomonas subglaciescola + TX, Halovibrio variabilis + TX, Hanseniaspora uvarum + TX, Helicoverpaarmigera nucleopolyhedrovirus (Helicovex®) + TX, Helicoverpa zea nuclear polyhedrosis virus (Gemstar®) +TX, Isaria fumosorosea (previously known as Paecilomyces fumosoroseus strain, PFR-97®, PreFeRal®) + TX, Isoflavone formononetin (Myconate®) + TX, Kloeckera apiculata + TX, Kloeckera spp. + TX, Lagenidium giganteum (Laginex®) + TX, Lecanicillium lecanii (formerly known as Verticillium lecanii (Mycotal®) conidia of strain KV01 (e.g. Vertalec® by Koppert / Arysta) + TX, Lecanicillium longisporum (Vertiblast®) + TX, Lecanicillium muscarium (Vertikil®) + TX, Lymantria Dispar nucleopolyhedrosis virus (Disparvirus®) + TX, Marinococcus halophilus + TX, Meira geulakonigii + TX, Metarhizium anisopliae (Destruxin WP®) + TX, Metarhizium anisopliae (Met52®) + TX, Metschnikowia fruticola (Shemer®) + TX, Metschnikowia pulcherrima + TX, Microdochium dimerum (Antibot®) + TX, Micromonospora coerulea + TX, Microsphaeropsis ochracea + TX, Muscodor albus 620 (Muscudor®) + TX, Muscodor roseus in particular strain A3-5 (Accession No. NRRL 30548) + TX, Mycorrhizae spp. (AMykor®, Root Maximizer®) + TX, Myrothecium verrucaria strain AARC-0255 (DiTera®, BROS PLUS®) + TX, Ophiostoma piliferum strain D97 (Sylvanex®) + TX, Paecilomyces farinosus + TX, Paecilomyces lilacinus strain 251 (MeloCon WG®) + TX, Paecilomyces linacinus (Biostat WP®) + TX, Paenibacillus polymyxa + TX, Pantoea agglomerans (BlightBan C9-1®) + TX, Pantoea spp. + TX, Pasteuria nishizawae in particular strain Pn1 (CLARIVA from Syngenta / ChemChina); + TX, Pasteuria spp. (Econem®) + TX, Penicillium aurantiogriseum + TX, Penicillium billai (Jumpstart®, TagTeam®) + TX, Penicillium brevicompactum + TX, Penicillium frequentans + TX, Penicillium griseofulvum + TX, Penicillium purpurogenum + TX, Penicillium spp. + TX, Penicillium viridicatum + TX, Phlebiopsis gigantean (Rotstop®) + TX, phosphate solubilizing bacteria (Phosphomeal®) + TX, Phytophthora cryptogea + TX, Phytophthora palmivora (Devine®) + TX, Pichia anomala + TX, Pichia guilliermondii + TX, Pichia membranaefaciens + TX, Pichia onychis + TX, Pichia stipites + TX, Pseudomonas aeruginosa + TX, Pseudomonas aureofasciens (Spot-Less Biofungicide®) + TX, Pseudomonas cepacia + TX, Pseudomonas chlororaphis (AtEze®) + TX, Pseudomonas corrugate + TX, Pseudomonas fluorescens (Zequanox®) + TX, Pseudomonas fluorescens strain A506 (BlightBan A506®) + TX, Pseudomonas putida + TX, Pseudomonas reactans + TX, Pseudomonas spp. + TX, Pseudomonas syringae (Bio-Save®) + TX, Pseudomonas viridiflava + TX, Pseudozyma flocculosa strain PF-A22 UL (Sporodex L®) + TX, Puccinia canaliculata + TX, Puccinia thlaspeos (Wood Warrior®) + TX, Pythium paroecandrum + TX, Pythium oligandrum (Polygandron®, Polyversum®) + TX, Pythium periplocum + TX, Rhanella aquatilis + TX, Rhanella spp. + TX, Rhizobia (Dormal®, Vault®) + TX, Rhizoctonia + TX, Rhodococcus globerulus strain AQ719 + TX, Rhodosporidium diobovatum + TX, Rhodosporidium toruloides + 82875_FF 64 TX, Rhodotorula glutinis + TX, Rhodotorula graminis + TX, Rhodotorula mucilagnosa + TX, Rhodotorula rubra + TX, Rhodotorula spp. + TX, Saccharomyces cerevisiae + TX, Salinococcus roseus + TX, Sclerotinia minor (SARRITOR®) + TX, Sclerotinia minor + TX, Scytalidium spp. + TX, Scytalidium uredinicola + TX, Serratia marcescens + TX, Serratia plymuthica + TX, Serratia spp. + TX, Sordaria fimicola + TX, Spodoptera exigua nuclear polyhedrosis virus (Spod-X®, Spexit®) + TX, Spodoptera littoralis nucleopolyhedrovirus (Littovir®) + TX, Sporobolomyces roseus + TX, Stenotrophomonas maltophilia + TX, Streptomyces albaduncus + TX, Streptomyces exfoliates + TX, Streptomyces galbus + TX, Streptomyces griseoplanus + TX, Streptomyces griseoviridis (Mycostop®) + TX, Streptomyces hygroscopicus + TX, Streptomyces lydicus (Actinovate®) + TX, Streptomyces lydicus WYEC-108 (ActinoGrow®) + TX, Streptomyces violaceus + TX, Tilletiopsis minor + TX,Tilletiopsis spp. + TX, Trichoderma asperellum (T34 Biocontrol®) + TX, Trichoderma atroviride (Plantmate®)+ TX, Trichoderma gamsii (Tenet®) + TX, Trichoderma hamatum TH 382 + TX, Trichoderma harzianum rifai (Mycostar®) + TX, Trichoderma harzianum T-22 (Trianum-P®, PlantShield HC®, RootShield®, Trianum-G® + TX, Trichoderma harzianum T-39 (Trichodex®) + TX, Trichoderma inhamatum + TX, Trichoderma koningii + TX, Trichoderma lignorum + TX, Trichoderma longibrachiatum + TX, Trichoderma polysporum (Binab T®) + TX, Trichoderma spp. LC 52 (Sentinel®) + TX, Trichoderma taxi + TX, Trichoderma virens (formerly Gliocladium virens GL-21) (SoilGuard®) + TX, Trichoderma virens + TX, Trichoderma viride + TX, Trichoderma viride strain ICC 080 (Remedier®) + TX, Trichosporon pullulans + TX, Trichosporon spp. + TX, Trichothecium roseum + TX, Trichothecium spp. + TX, Typhula phacorrhiza strain 94670 + TX, Typhula phacorrhiza strain 94671 + TX, Ulocladium atrum + TX, Ulocladium oudemansii (Botry-Zen®) + TX, Ustilago maydis + TX, various bacteria and supplementary micronutrients (Natural II®) + TX, various fungi (Millennium Microbes®) + TX, Verticillium chlamydosporium + TX, Vip3Aa20 (VIPtera®) + TX, Virgibaclillus marismortui + TX, Xanthomonas campestris pv. Poae (Camperico®) + TX, Xenorhabdus bovienii + TX, Xenorhabdus nematophilus + TX; AGNIQUE® MMF + TX, azadirachtin (Plasma Neem Oil®, AzaGuard®, MeemAzal®, Molt-X® e.g. AZATIN XL from Certis, US) + TX, Botanical IGR (Neemazad®, Neemix®) + TX, BugOil® + TX, canola oil (Lilly Miller Vegol®) + TX, Chenopodium ambrosioides near ambrosioides (Requiem®) + TX, Chrysanthemum extract (Crisant®) + TX, essentials oils of Labiatae (Botania®) + TX, extract of neem oil (Trilogy®) + TX, extracts of clove rosemary peppermint and thyme oil (Garden insect killer®) + TX, garlic + TX, Glycinebetaine (Greenstim®) + TX, kaolin (Screen®) + TX, lemongrass oil (GreenMatch®) + TX, Melaleuca alternifolia extract (also called tea tree oil) (Timorex Gold®) + TX, mixture of clove pepermint garlic oil and mint (Soil Shot®) + TX, mixture of clove rosemary and peppermint extract (EF 400®) + TX, mixture of rosemary sesame pepermint thyme and cinnamon extracts (EF 300®) + TX, neem oil + TX, Nepeta cataria (Catnip oil) + TX, Nepeta catarina + TX, nicotine + TX, oregano oil (MossBuster®) + TX, Pedaliaceae oil (Nematon®) + TX, pine oil (Retenol®) + TX, pyrethrum + TX, Quillaja saponaria (NemaQ®) + TX, Reynoutria sachalinensis (Regalia®, Sakalia®) + TX, rotenone (Eco Roten®) + TX, Rutaceae plant extract (Soleo®) + TX, soybean oil (Ortho ecosense®) + TX, storage glucam of brown algae (Laminarin®) + TX, thyme oil + TX; (E,Z)-7,9-Dodecadien-1-yl acetate + TX, (E,Z,Z)-3,8,11 Tetradecatrienyl acetate + TX, (Z,Z,E)-7,11,13-Hexadecatrienal + TX, 2-Methyl-1-butanol + TX, Biolure® + TX, blackheaded fireworm pheromone (3M Sprayable Blackheaded Fireworm Pheromone®) + TX, Calcium acetate + TX, Check-Mate® + TX, Codling Moth Pheromone (Paramount dispenser-(CM) / Isomate C- 82875_FF 65 Plus®) + TX, Entostat powder (extract from palm tree) (Exosex CM®) + TX, Grape Berry Moth Pheromone (3M MEC-GBM Sprayable Pheromone®) + TX, Lavandulyl senecioate + TX, Leafroller pheromone (3M MEC – LR Sprayable Pheromone®) + TX, Muscamone (Snip7 Fly Bait® + TX, Oriental Fruit Moth Pheromone (3M oriental fruit moth sprayable pheromone®) + TX, Peachtree Borer Pheromone (Isomate-P®) + TX, Scenturion® + TX, Starbar Premium Fly Bait®) + TX, Tomato Pinworm Pheromone (3M Sprayable pheromone®) + TX; Acerophagus papaya + TX, Adalia bipunctata (Adalia-System®) + TX, Adalia bipunctata (Adaline®) + TX, Adalia bipunctata (Aphidalia®) + TX, Ageniaspis citricola + TX, Ageniaspis fuscicollis + TX, Amblyseius andersoni (Anderline®, Andersoni-System®) + TX, Amblyseius californicus (Amblyline®, Spical®) + TX, Amblyseius cucumeris (Thripex®, Bugline cucumeris®) + TX, Amblyseius fallacis (Fallacis®) + TX, Amblyseiusswirskii (Bugline swirskii®, Swirskii-Mite®) + TX, Amblyseius womersleyi (WomerMite®) + TX, Amitushesperidum + TX, Anagrus atomus + TX, Anagyrus fusciventris + TX, Anagyrus kamali + TX, Anagyrus loecki + TX, Anagyrus pseudococci (Citripar®) + TX, Anicetus benefices + TX, Anisopteromalus calandrae + TX, Anthocoris nemoralis (Anthocoris-System®) + TX, Aphelinus abdominalis (Apheline®, Aphiline®), + TX, Aphelinus asychis + TX, Aphidius colemani (Aphipar®) + TX, Aphidius ervi (Aphelinus-System®) + TX, Aphidius ervi (Ervipar®) + TX, Aphidius gifuensis + TX, Aphidius matricariae (Aphipar-M®) + TX, Aphidoletes aphidimyza (Aphidend®, Aphidoline®) + TX, Aphytis lingnanensis + TX, Aphytis melinus + TX, Aprostocetus hagenowii + TX, Atheta coriaria (Staphyline®) + TX, Bombus spp. + TX, Bombus terrestris (Beeline®, Tripol®) + TX, Bombus terrestris (Natupol Beehive®) + TX, Cephalonomia stephanoderis + TX, Chilocorus nigritus + TX, Chrysoperla carnea (Chrysoline®, Chrysopa®) + TX, Chrysoperla rufilabris + TX, Cirrospilus ingenuus + TX, Cirrospilus quadristriatus + TX, Citrostichus phyllocnistoides + TX, Closterocerus chamaeleon + TX, Closterocerus spp. + TX, Coccidoxenoides perminutus (Planopar®) + TX, Coccophagus cowperi + TX, Coccophagus lycimnia + TX, Cotesia flavipes + TX, Cotesia plutellae + TX, Cryptolaemus montrouzieri (Cryptobug®, Cryptoline®) + TX, Cybocephalus nipponicus + TX, Dacnusa sibirica (Minusa®, DacDigline®, Minex®) + TX, Delphastus catalinae (Delphastus®) + TX, Delphastus pusillus + TX, Diachasmimorpha krausii + TX, Diachasmimorpha longicaudata + TX, Diaparsis jucunda + TX, Diaphorencyrtus aligarhensis + TX, Diglyphus isaea (Diminex®, Miglyphus®, Digline®) + TX, Diversinervus spp. + TX, Encarsia citrina + TX, Encarsia formosa (Encarsia max®, Encarline®, En-Strip®) + TX, Encarsia guadeloupae + TX, Encarsia haitiensis + TX, Episyrphus balteatus (Syrphidend®) + TX, Eretmoceris siphonini + TX, Eretmocerus californicus + TX, Eretmocerus eremicus (Enermix®, Ercal®, Eretline e®, Bemimix®) + TX, Eretmocerus hayati + TX, Eretmocerus mundus (Bemipar®, Eretline m®) + TX, Eretmocerus siphonini + TX, Exochomus quadripustulatus + TX, Feltiella acarisuga (Feltiline®) + TX, Feltiella acarisuga (Spidend®) + TX, Fopius arisanus + TX, Fopius ceratitivorus + TX, Formononetin (Wirless Beehome®) + TX, Franklinothrips vespiformis (Vespop®) + TX, Galendromus occidentalis + TX, Goniozus legneri + TX, Habrobracon hebetor + TX, Harmonia axyridis (HarmoBeetle®) + TX, Heterorhabditis bacteriophora (NemaShield HB®, Nemaseek®, Terranem-Nam®, Terranem®, Larvanem®, B-Green®, NemAttack ®, Nematop®) + TX, Heterorhabditis megidis (Nemasys H®, BioNem H®, Exhibitline hm®, Larvanem-M®) + TX, Heterorhabditis spp. (Lawn Patrol®) + TX, Hippodamia convergens + TX, Hypoaspis aculeifer (Aculeifer-System®, Entomite-A®) + TX, Hypoaspis miles (Hypoline m®, Entomite-M®) + TX, Lbalia leucospoides + TX, Lecanoideus floccissimus + 82875_FF 66 TX, Lemophagus errabundus + TX, Leptomastidea abnormis + TX, Leptomastix dactylopii (Leptopar®) + TX, Leptomastix epona + TX, Lindorus lophanthae + TX, Lipolexis oregmae + TX, Lucilia caesar (Natufly®) + TX, Lysiphlebus testaceipes + TX, Macrolophus caliginosus (Mirical-N®, Macroline c®, Mirical®) + TX, Mesoseiulus longipes + TX, Metaphycus flavus + TX, Metaphycus lounsburyi + TX, Micromus angulatus (Milacewing®) + TX, Microterys flavus + TX, Muscidifurax raptorellus and Spalangia cameroni (Biopar®) + TX, Neodryinus typhlocybae + TX, Neoseiulus californicus + TX, Neoseiulus cucumeris (THRYPEX®) + TX, Neoseiulus fallacis + TX, Nesideocoris tenuis (NesidioBug®, Nesibug®) + TX, Ophyra aenescens (Biofly®) + TX, Orius insidiosus (Thripor-I®, Oriline i®) + TX, Orius laevigatus (Thripor-L®, Oriline l®) + TX, Orius majusculus (Oriline m®) + TX, Orius strigicollis (Thripor-S®) + TX, Pauesia juniperorum + TX, Pediobiusfoveolatus + TX, Phasmarhabditis hermaphrodita (Nemaslug®) + TX, Phymastichus coffea + TX, Phytoseiulusmacropilus + TX, Phytoseiulus persimilis (Spidex®, Phytoline p®) + TX, Podisus maculiventris (Podisus®) + TX, Pseudacteon curvatus + TX, Pseudacteon obtusus + TX, Pseudacteon tricuspis + TX, Pseudaphycus maculipennis + TX, Pseudleptomastix mexicana + TX, Psyllaephagus pilosus + TX, Psyttalia concolor (complex) + TX, Quadrastichus spp. + TX, Rhyzobius lophanthae + TX, Rodolia cardinalis + TX, Rumina decollate + TX, Semielacher petiolatus + TX, Sitobion avenae (Ervibank®) + TX, Steinernema carpocapsae (Nematac C®, Millenium®, BioNem C®, NemAttack®, Nemastar®, Capsanem®) + TX, Steinernema feltiae (NemaShield®, Nemasys F®, BioNem F®, Steinernema-System®, NemAttack®, Nemaplus®, Exhibitline sf®, Scia-rid®, Entonem®) + TX, Steinernema kraussei (Nemasys L®, BioNem L®, Exhibitline srb®) + TX, Steinernema riobrave (BioVector®, BioVektor®) + TX, Steinernema scapterisci (Nematac S®) + TX, Steinernema spp. + TX, Steinernematid spp. (Guardian Nematodes®) + TX, Stethorus punctillum (Stethorus®) + TX, Tamarixia radiate + TX, Tetrastichus setifer + TX, Thripobius semiluteus + TX, Torymus sinensis + TX, Trichogramma brassicae (Tricholine b®) + TX, Trichogramma brassicae (Tricho-Strip®) + TX, Trichogramma evanescens + TX, Trichogramma minutum + TX, Trichogramma ostriniae + TX, Trichogramma platneri + TX, Trichogramma pretiosum + TX, Xanthopimpla stemmator + TX; abscisic acid + TX, Aminomite® + TX, BioGain® + TX, bioSea® + TX, Chondrostereum purpureum (Chontrol Paste®) + TX, Colletotrichum gloeosporioides (Collego®) + TX, Copper Octanoate (Cueva®) + TX, Delta traps (Trapline d®) + TX, Erwinia amylovora (Harpin) (ProAct®, Ni-HIBIT Gold CST®) + TX, fatty acids derived from a natural by-product of extra virgin olive oil (FLIPPER®) + TX, Ferri-phosphate (Ferramol®) + TX, Funnel traps (Trapline y®) + TX, Gallex® + TX, Grower's Secret® + TX, Homo-brassonolide + TX, Iron Phosphate (Lilly Miller Worry Free Ferramol Slug & Snail Bait®) + TX, MCP hail trap (Trapline f®) + TX, Microctonus hyperodae + TX, Mycoleptodiscus terrestris (Des-X®) + TX, Nosema locustae (Semaspore Organic Grasshopper Control®) + TX, Pheromone trap (Thripline ams®) + TX, potassium bicarbonate (MilStop®) + TX, potassium iodide + potassiumthiocyanate (Enzicur®) + TX, potassium salts of fatty acids (Sanova®) + TX, potassium silicate solution (Sil-Matrix®) + TX, Spider venom + TX, Sticky traps (Trapline YF®, Rebell Amarillo®) + TX, SuffOil-X® + TX, Traps (Takitrapline y + b®) + TX, vadescana (CAS Number: 2643947-26-4) + TX; Bacillus mojavensis strain R3B (Accession No. NCAIM (P) B001389) (WO 2013 / 034938) from Certis USA LLC + TX, Bacillus pumilus, in particular strain BU F-33, having NRRL Accession No.50185 (CARTISSA® from BASF, EPA Reg. No.71840-19) + TX, Bacillus subtilis CX-9060 from Certis USA LLC, Bacillus sp., in particular strain D747 (available as DOUBLE NICKEL® 82875_FF 67 from Kumiai Chemical Industry Co., Ltd.), having Accession No. FERM BP-8234, U.S. Patent No.7,094,592 + TX, Bacillus subtilis strain BU1814, (VELONDIS® PLUS, VELONDIS® FLEX and VELONDIS® EXTRA from BASF SE) + TX, Bacillus subtilis var. amyloliquefaciens strain FZB24 having Accession No. DSM 10271 (available from Novozymes as TAEGRO® or TAEGRO® ECO (EPA Registration No.70127-5)) + TX, Bacillus subtilis, in particular strain QST713 / AQ713 (having NRRL Accession No. B-21661 and described in U.S. Patent No. 6,060,051, available as SERENADE® OPTI or SERENADE® ASO from Bayer CropScience LP, US) + TX, Paenibacillus polymyxa, in particular strain AC-1 (e.g. TOPSEED® from Green Biotech Company Ltd.) + TX, Paenibacillus sp. strain having Accession No. NRRL B-50972 or Accession No. NRRL B-67129, WO 2016 / 154297 + TX, Pantoea agglomerans, in particular strain E325 (Accession No. NRRL B-21856) (availableas BLOOMTIME BIOLOGICAL™ FD BIOPESTICIDE from Northwest Agri Products) + TX, Pseudomonasproradix (e.g. PRORADIX® from Sourcon Padena) + TX; Aureobasidium pullulans, in particular blastospores of strain DSM14940, blastospores of strain DSM 14941 or mixtures of blastospores of strains DSM14940 and DSM14941 (e.g., BOTECTOR® and BLOSSOM PROTECT® from bio-ferm, CH) + TX, Pseudozyma aphidis (as disclosed in WO2011 / 151819 by Yissum Research Development Company of the Hebrew University of Jerusalem) + TX, Saccharomyces cerevisiae, in particular strains CNCM No. 1-3936, CNCM No. 1-3937, CNCM No. 1-3938 or CNCM No. 1-3939 (WO 2010 / 086790) from Lesaffre et Compagnie, FR + TX; Agrobacterium radiobacter strain K84 (e.g. GALLTROL-A® from AgBioChem, CA) + TX, Bacillus amyloliquefaciens isolate B246 (e.g. AVOGREEN™ from University of Pretoria) + TX, Bacillus amyloliquefaciens strain F727 (also known as strain MBI110) (NRRL Accession No. B-50768, WO 2014 / 028521) (STARGUS® from Marrone Bio Innovations) + TX, Bacillus amyloliquefaciens strain FZB42, Accession No. DSM 23117 (available as RHIZOVITAL® from ABiTEP, DE) + TX, Bacillus amyloliquefaciens, in particular strain D747 (available as Double Nickel™ from Kumiai Chemical Industry Co., Ltd., having accession number FERM BP-8234, US Patent No. 7,094,592) + TX, Bacillus licheniformis FMCH001 and Bacillus subtilis FMCH002 (QUARTZO® (WG) and PRESENCE® (WP) from FMC Corporation) + TX, Bacillus licheniformis, in particular strain SB3086, having Accession No. ATCC 55406, WO 2003 / 000051 (available as ECOGUARD® Biofungicide and GREEN RELEAF™ from Novozymes) + TX, Bacillus methylotrophicus strain BAC-9912 (from Chinese Academy of Sciences’ Institute of Applied Ecology) + TX, Bacillus mycoides, isolate, having Accession No. B-30890 (available as BMJ TGAI® or WG and LifeGard™ from Certis USA LLC) + TX, Bacillus pumilus, in particular strain GB34 (available as Yield Shield® from Bayer AG, DE) + TX, Bacillus pumilus, in particular strain QST2808 (available as SONATA® from Bayer CropScience LP, US, having Accession No. NRRL B-30087 and described in U.S. Patent No.6,245,551) + TX, Bacillus subtilis CX-9060 from Certis USA LLC + TX, Bacillus subtilis IAB / BS03 (AVIV™ from STK Bio-Ag Technologies, PORTENTO® from Idai Nature) + TX, Bacillus subtilis KTSB strain (FOLIACTIVE® from Donaghys) + TX, Bacillus subtilis strain BU1814, (available as VELONDIS® PLUS, VELONDIS® FLEX and VELONDIS® EXTRA from BASF SE) + TX, Bacillus subtilis strain GB03 (available as Kodiak® from Bayer AG, DE) + TX, Bacillus subtilis strain MBI 600 (available as SUBTILEX from BASF SE), having Accession Number NRRL B-50595, U.S. Patent No. 5,061,495 + TX, Bacillus subtilis strain Y1336 (available as BIOBAC® WP from Bion-Tech, Taiwan, registered as a biological fungicide in Taiwan under Registration Nos.4764, 5454, 5096 and 5277) + TX, Bacillus subtilis 82875_FF 68 var. amyloliquefaciens strain FZB24 having Accession No. DSM 10271 (available from Novozymes as TAEGRO® or TAEGRO® ECO (EPA Registration No.70127-5)) + TX, Bacillus subtilis Y1336 (available as BIOBAC® WP from Bion-Tech, Taiwan, registered as a biological fungicide in Taiwan under Registration Nos. 4764, 5454, 5096 and 5277) + TX, Paenibacillus epiphyticus (WO 2016 / 020371) from BASF SE + TX, Paenibacillus polymyxa ssp. plantarum (WO 2016 / 020371) from BASF SE + TX, Paenibacillus sp. strain having Accession No. NRRL B-50972 or Accession No. NRRL B-67129, WO 2016 / 154297 + TX, Pseudomonas chlororaphis strain AFS009, having Accession No. NRRL B-50897, WO 2017 / 019448 (e.g., HOWLER™ and ZIO® from AgBiome Innovations, US) + TX, Pseudomonas chlororaphis, in particular strain MA342 (e.g. CEDOMON®, CERALL®, and CEDRESS® by Bioagri and Koppert) + TX, Pseudomonas fluorescens strainA506 (e.g. BLIGHTBAN® A506 by NuFarm) + TX, Pseudomonas proradix (e.g. PRORADIX® from SourconPadena) + TX, Streptomyces griseoviridis strain K61 (also known as Streptomyces galbus strain K61) (Accession No. DSM 7206) (MYCOSTOP® from Verdera, PREFENCE® from BioWorks, cf. Crop Protection 2006, 25, 468-475) + TX, Streptomyces lydicus strain WYEC108 (also known as Streptomyces lydicus strain WYCD108US) (ACTINO-IRON® and ACTINOVATE® from Novozymes) + TX; Trichoderma atroviride strain T11 (IMI352941 / CECT20498) + TX, Ampelomyces quisqualis strain AQ10, having Accession No. CNCM 1- 807 (e.g., AQ 10® by IntrachemBio Italia) + TX, Ampelomyces quisqualis, in particular strain AQ 10 (e.g. AQ 10® by IntrachemBio Italia) + TX, Aspergillus flavus strain NRRL 21882 (products known as AFLA-GUARD® from Syngenta / ChemChina) + TX, Aureobasidium pullulans, in particular blastospores of strain DSM 14941 + TX, Aureobasidium pullulans, in particular blastospores of strain DSM14940 + TX, Aureobasidium pullulans, in particular mixtures of blastospores of strains DSM14940 and DSM 14941 (e.g. Botector® by bio-ferm, CH) + TX, Chaetomium cupreum (Accession No. CABI 353812) (e.g. BIOKUPRUM™ by AgriLife) + TX, Chaetomium globosum (available as RIVADIOM® by Rivale) + TX, Cladosporium cladosporioides, strain H39, having Accession No. CBS122244, US 2010 / 0291039 (by Stichting Dienst Landbouwkundig Onderzoek) + TX, Coniothyrium minitans, in particular strain CON / M / 91-8 (Accession No. DSM9660, e.g. Contans ® from Bayer CropScience Biologics GmbH) + TX, Cryptococcus flavescens, strain 3C (NRRL Y-50378), + TX, Dactylaria candida, Dilophosphora alopecuri (available as TWIST FUNGUS®), Fusarium oxysporum, strain Fo47 (available as FUSACLEAN® by Natural Plant Protection) + TX, Gliocladium catenulatum (Synonym: Clonostachys rosea f. catenulate) strain J1446 (e.g. Prestop ® by Lallemand) + TX, Gliocladium roseum (also known as Clonostachys rosea f rosea) strain IK726 (Jensen DF, et al. Development of a biocontrol agent for plant disease control with special emphasis on the near commercial fungal antagonist Clonostachys rosea strain ’IK726’, Australasian Plant Pathol. 2007,36(2):95-101) + TX, Gliocladium roseum (also known as Clonostachys rosea f rosea), in particular strain 321U from Adjuvants Plus, strain ACM941 as disclosed in Xue A.G. (Efficacy of Clonostachys rosea strain ACM941 and fungicide seed treatments for controlling the root tot complex of field pea, Can Jour Plant Sci 2003, 83(3): 519-524) + TX, Metschnikowia fructicola, in particular strain NRRL Y-30752 + TX, Microsphaeropsis ochracea, Penicillium steckii (DSM 27859, WO 2015 / 067800) from BASF SE + TX, mixtures of Trichoderma asperellum strain ICC 012 (also known as Trichoderma harzianum ICC012), having Accession No. CABI CC IMI 392716 and Trichoderma gamsii (formerly T. viride) strain ICC 080, having Accession No. IMI 392151 (e.g., BIO-TAM™ from Isagro USA, Inc. or BIODERMA® by 82875_FF 69 Agrobiosol de Mexico, S.A. de C.V.) + TX, Penicillium vermiculatum + TX, Phlebiopsis gigantea strain VRA 1992 (ROTSTOP® C from Danstar Ferment) + TX, Pseudozyma flocculosa, strain PF-A22 UL (available as SPORODEX® L by Plant Products Co., CA) + TX, Saccharomyces cerevisiae strain LAS117 cell walls (CEREVISANE® from Lesaffre, ROMEO® from BASF SE) + TX, Saccharomyces cerevisiae strains CNCM No.1-3936, CNCM No.1-3937, CNCM No.1-3938, CNCM No.1-3939 (WO 2010 / 086790) from Lesaffre et Compagnie, FR + TX, Saccharomyces cerevisiae, in particular strain LASO2 (from Agro-Levures et Dérivés) + TX, Simplicillium lanosoniveum + TX, strain T34 (e.g. T34 Biocontrol by Biocontrol Technologies S.L., ES) or strain ICC 012 from Isagro + TX, strain WRL-076 (NRRL Y-30842), U.S. Patent No. 7,579,183 + TX, Talaromyces flavus, strain V117b + TX, Trichoderma asperelloides JM41R (Accession No. NRRL B-50759)(TRICHO PLUS® from BASF SE) + TX, Trichoderma asperellum, in particular strain SKT-1, having AccessionNo. FERM P-16510 (e.g. ECO-HOPE® from Kumiai Chemical Industry) + TX, Trichoderma asperellum, in particular, strain kd (e.g. T-Gro from Andermatt Biocontrol) + TX, Trichoderma atroviride strain 77B (T77 from Andermatt Biocontrol) + TX, Trichoderma atroviride strain ATCC 20476 (IMI 206040) + TX, Trichoderma atroviride strain LC52 (e.g. Tenet by Agrimm Technologies Limited) + TX, Trichoderma atroviride strain LU132 (e.g. Sentinel from Agrimm Technologies Limited) + TX, Trichoderma atroviride strain NMI no. V08 / 002388 + TX, Trichoderma atroviride strain NMI no. V08 / 002389 + TX, Trichoderma atroviride strain NMI no. V08 / 002390 + TX, Trichoderma atroviride strain no. V08 / 002387 + TX, Trichoderma atroviride strain SKT-1 (FERM P- 16510), JP Patent Publication (Kokai) 11-253151 A + TX, Trichoderma atroviride strain SKT-2 (FERM P- 16511), JP Patent Publication (Kokai) 11-253151 A + TX, Trichoderma atroviride strain SKT-3 (FERM P- 17021), JP Patent Publication (Kokai) 11-253151 A + TX, Trichoderma atroviride, in particular strain SC1 (Accession No. CBS 122089, WO 2009 / 116106 and U.S. Patent No. 8,431,120 (from Bi-PA)) + TX, Trichoderma atroviride,strain CNCM 1-1237 (e.g. Esquive® WP from Agrauxine, FR) + TX, Trichoderma fertile (e.g. product TrichoPlus from BASF) + TX, Trichoderma gamsii (formerly T. viride) + TX, Trichoderma gamsii (formerly T. viride) strain ICC 080 (IMI CC 392151 CABI) (available as BIODERMA® by AGROBIOSOL DE MEXICO, S.A. DE C.V.), + TX, Trichoderma gamsii strain ICC080 (IMI CC 392151 CABI, e.g. BioDerma by AGROBIOSOL DE MEXICO, S.A. DE C.V.), + TX, Trichoderma harmatum + TX, Trichoderma harmatum, having Accession No. ATCC 28012 + TX, Trichoderma harzianum + TX, Trichoderma harzianum rifai T39 (e.g. Trichodex® from Makhteshim, US) + TX, Trichoderma harzianum strain Cepa SimbT5 (from Simbiose Agro), + TX, Trichoderma harzianum strain DB 103 (available as T-GRO® 7456 by Dagutat Biolab) + TX, Trichoderma harzianum strain ITEM 908 (e.g. Trianum-P from Koppert) + TX, Trichoderma harzianum strain T-22 (e.g. Trianum-P from Andermatt Biocontrol or Koppert) + TX, Trichoderma harzianum strain TH35 (e.g. Root-Pro by Mycontrol) + TX, Trichoderma polysporum strain IMI 206039 (e.g. Binab TF WP by BINAB Bio-Innovation AB, Sweden) + TX, Trichoderma stromaticum having Accession No. Ts3550 (e.g. Tricovab by CEPLAC, Brazil) + TX, Trichoderma virens (also known as Gliocladium virens) in particular strain GL-21 (e.g. SoilGard by Certis, US) + TX, Trichoderma virens strain G-41, formerly known as Gliocladium virens (Accession No. ATCC 20906) (e.g., ROOTSHIELD® PLUS WP and TURFSHIELD® PLUS WP from BioWorks, US) + TX, Trichoderma viride in particular strain B35 (Pietr et al., 1993, Zesz. Nauk. A R w Szczecinie 161: 125-137) + TX, Trichoderma viride strain TV1(e.g. Trianum-P by Koppert) + TX, Ulocladium oudemansii strain U3, having Accession No. 82875_FF 70 NM 99 / 06216 (e.g., BOTRY-ZEN® by Botry-Zen Ltd, New Zealand and BOTRYSTOP® from BioWorks, Inc.) + TX, Verticillium albo-atrum (formerly V. dahliae) strain WCS850 having Accession No. WCS850, deposited at the Central Bureau for Fungi Cultures (e.g., DUTCH TRIG® by Tree Care Innovations) + TX, Verticillium chlamydosporium + TX; a mixture of Azotobacter vinelandii and Clostridium pasteurianum (available as INVIGORATE® from Agrinos) + TX, a mixture of Bacillus licheniformis FMCH001 and Bacillus subtilis FMCH002 (available as QUARTZO® (WG), PRESENCE® (WP) from FMC Corporation) + TX, Azorhizobium caulinodans, in particular strain ZB-SK-5 + TX, Azospirillum brasilense (e.g., VIGOR® from KALO, Inc.) + TX, Azospirillum lipoferum (e.g., VERTEX-IF™ from TerraMax, Inc.) + TX, Azotobacter chroococcum, in particular strain H23 + TX, Azotobacter vinelandii, in particular strain ATCC 12837 + TX, Bacillus amyloliquefaciens BS27(Accession No. NRRL B-5015) + TX, Bacillus amyloliquefaciens in particular strain FZB42 (e.g. RHIZOVITAL®from ABiTEP, DE) + TX, Bacillus amyloliquefaciens in particular strain IN937a + TX, Bacillus amyloliquefaciens pm414 (LOLI-PEPTA® from Biofilm Crop Protection) + TX, Bacillus amyloliquefaciens SB3281 (ATCC # PTA- 7542, WO 2017 / 205258) + TX, Bacillus amyloliquefaciens TJ1000 (available as QUIKROOTS® from Novozymes) + TX, Bacillus cereus family member EE128 (NRRL No. B-50917) + TX, Bacillus cereus family member EE349 (NRRL No. B-50928) + TX, Bacillus cereus in particular strain BP01 (ATCC 55675, e.g. MEPICHLOR® from Arysta Lifescience, US) + TX, Bacillus mycoides BT155 (NRRL No. B-50921) + TX, Bacillus mycoides BT46-3 (NRRL No. B-50922) + TX, Bacillus mycoides EE118 (NRRL No. B-50918) + TX, Bacillus mycoides EE141 (NRRL No. B-50916) + TX, Bacillus pumilus in particular strain GB34 (e.g. YIELD SHIELD® from Bayer Crop Science, DE), + TX, Bacillus pumilus in particular strain QST2808 (Accession No. NRRL No. B-30087) + TX, Bacillus siamensis in particular strain KCTC 13613T + TX, Bacillus subtilis in particular strain AQ30002 (Accession No. NRRL No. B-50421 and described in U.S. Patent Application No. 13 / 330,576) + TX, Bacillus subtilis in particular strain AQ30004 (NRRL No. B-50455 and described in U.S. Patent Application No.13 / 330,576) + TX, Bacillus subtilis in particular strain MBI 600 (e.g. SUBTILEX® from BASF SE) + TX, Bacillus subtilis rm303 (RHIZOMAX® from Biofilm Crop Protection) + TX, Bacillus subtilis strain BU1814 (available as TEQUALIS® from BASF SE) + TX, Bacillus tequilensis in particular strain NII-0943 + TX, Bacillus thuringiensis BT013A (NRRL No. B-50924) also known as Bacillus thuringiensis 4Q7 + TX, Bradyrhizobium japonicum (e.g. OPTIMIZE® from Novozymes) + TX, Delftia acidovorans in particular strain RAY209 (e.g. BIOBOOST® from Brett Young Seeds) + TX, Lactobacillus sp. (e.g. LACTOPLANT® from LactoPAFI) + TX, Mesorhizobium cicer (e.g., NODULATOR from BASF SE) + TX, Paenibacillus polymyxa in particular strain AC-1 (e.g. TOPSEED® from Green Biotech Company Ltd.) + TX, Pseudomonas aeruginosa in particular strain PN1 + TX, Pseudomonas proradix (e.g. PRORADIX® from Sourcon Padena) + TX, Rhizobium leguminosarium biovar viciae (e.g., NODULATOR from BASF SE) + TX, Rhizobium leguminosarum in particular bv. viceae strain Z25 (Accession No. CECT 4585) + TX, Serratia marcescens in particular strain SRM (Accession No. MTCC 8708), + TX, Sinorhizobium meliloti strain NRG-185-1 (NITRAGIN® GOLD from Bayer CropScience) + TX, Thiobacillus sp. (e.g. CROPAID® from Cropaid Ltd UK) + TX; Myrothecium verrucaria strain AARC-0255 (e.g. DiTera™ from Valent Biosciences) + TX, Penicillium bilaii strain ATCC 22348 (e.g. JumpStart® from Acceleron BioAg) + TX, Penicillium bilaii strain ATCC ATCC20851 + TX, Purpureocillium lilacinum (previously known as Paecilomyces lilacinus) strain 251 (AGAL 89 / 030550, e.g. 82875_FF 71 BioAct from Bayer CropScience Biologics GmbH) + TX, Pythium oligandrum strain DV74 + TX, Pythium oligandrum strain M1 (ATCC 38472 e.g. Polyversum from Bioprepraty, CZ) + TX, Rhizopogon amylopogon (Myco-Sol from Agri-Enterprise, LLC, formerly Helena Chemical Company) + TX, Rhizopogon fulvigleba (e.g. Myco-Sol from Agri-Enterprise, LLC, formerly Helena Chemical Company) + TX, Talaromyces flavus strain V117b + TX, Trichoderma asperellum strain (Eco-T from Plant Health Products, ZA) + TX, Trichoderma asperellum strain kd (e.g. T-Gro from Andermatt Biocontrol) + TX, Trichoderma atroviride in particular strain no. V08 / 002387 + TX, Trichoderma atroviride strain CNCM 1-1237 (e.g. Esquive® WP from Agrauxine, FR) + TX, Trichoderma atroviride strain LC52 (also known as Trichoderma atroviride strain LU132, e.g. Sentinel from Agrimm Technologies Limited) + TX, Trichoderma atroviride strain no. NMI No. V08 / 002388 + TX, Trichodermaatroviride strain no. NMI No. V08 / 002389 + TX, Trichoderma atroviride strain no. NMI No. V08 / 002390 + TX,Trichoderma atroviride strain SC1 (described in WO2009 / 116106) + TX, Trichoderma harzianum strain 1295- 22 + TX, Trichoderma harzianum strain ITEM 908 + TX, Trichoderma harzianum strain T-22 (e.g. Trianum-P from Andermatt Biocontrol or Koppert) + TX, Trichoderma harzianum strain TSTh20, + TX, Trichoderma virens strain GI-3 + TX, Trichoderma virens strain GL-21 (e.g. SoilGard® from Certis, USA) + TX, Trichoderma viride strain B35 (Pietr et al., 1993, Zesz. Nauk. A R w Szczecinie 161: 125-137) + TX, Verticillium albo-atrum (formerly V. dahliae) strain WCS850 (CBS 276.92, e.g. Dutch Trig from Tree Care Innovations) + TX; Agrobacterium radiobacter strain K84 (Galltrol from AgBiochem Inc.), + TX, Bacillus amyloliquefaciens in particular strain PTS-4838 (e.g. AVEO from Valent Biosciences, US), + TX, Bacillus mycoides, isolate J. (e.g. BmJ from Certis USA LLC), + TX, Bacillus sphaericus in particular Serotype H5a5b strain 2362 (strain ABTS- 1743) (e.g. VECTOLEX® from Valent BioSciences, US), + TX, Bacillus thuringiensis israelensis strain BMP 144 (e.g. AQUABAC® by Becker Microbial Products IL) + TX, Bacillus thuringiensis subsp. aizawai strain GC- 91 + TX, Bacillus thuringiensis subsp. aizawai, in particular serotype H-7 (e.g. FLORBAC® WG from Valent BioSciences, US) + TX, Bacillus thuringiensis subsp. aizawai, in particular strain ABTS-1857 (SD-1372, e.g. XENTARI® from Valent BioSciences) + TX, Bacillus thuringiensis subsp. israelensis (serotype H-14) strain AM65-52 (Accession No. ATCC 1276) (e.g. VECTOBAC® by Valent BioSciences, US) + TX, Bacillus thuringiensis subsp. kurstaki strain ABTS 351 + TX, Bacillus thuringiensis subsp. kurstaki strain BMP 123 (from Becker Microbial Products, IL, BARITONE from Bayer CropScience) + TX, Bacillus thuringiensis subsp. kurstaki strain EG 2348 (LEPINOX from Certis, US) + TX, Bacillus thuringiensis subsp. kurstaki strain EG 7841 (CRYMAX from Certis, US) + TX, Bacillus thuringiensis subsp. kurstaki strain HD-1 (e.g. DIPEL® ES from Valent BioSciences, US) + TX, Bacillus thuringiensis subsp. kurstaki strain PB 54 + TX, Bacillus thuringiensis subsp. kurstaki strain SA 11 (JAVELIN from Certis, US) + TX, Bacillus thuringiensis subsp. kurstaki strain SA 12 (THURICIDE from Certis, US) + TX, Bacillus thuringiensis subsp. tenebrionis strain NB 176 (SD-5428, e.g. NOVODOR® FC from BioFa DE) + TX, Bacillus thuringiensis var. Colmeri (e.g. TIANBAOBTC by Changzhou Jianghai Chemical Factory) + TX, Bacillus thuringiensis var. japonensis strain Buibui + TX, Bacillus thuringiensis var. kurstaki strain EVB-113-19 (e.g., BIOPROTEC® from AEF Global) + TX, Brevibacillus laterosporus + TX, Burkholderia spp. in particular Burkholderia rinojensis strain A396 (also known as Burkholderia rinojensis strain MBI 305) (Accession No. NRRL B-50319, WO 2011 / 106491 and WO 2013 / 032693, e.g. MBI206 TGAI and ZELTO® from Marrone Bio Innovations), + TX, Chromobacterium 82875_FF 72 subtsugae in particular strain PRAA4-1T (e.g. MBI-203, e.g. GRANDEVO® from Marrone Bio Innovations) + TX, Lecanicillium muscarium Ve6 (MYCOTAL from Koppert) + TX, Paenibacillus popilliae (formerly Bacillus popilliae, e.g. MILKY SPORE POWDER™ or MILKY SPORE GRANULAR™ from St. Gabriel Laboratories) + TX, Serratia entomophila (e.g. INVADE® by Wrightson Seeds) + TX, Serratia marcescens in particular strain SRM (Accession No. MTCC 8708) + TX, Trichoderma asperellum (TRICHODERMAX from Novozymes) + TX, Wolbachia pipientis ZAP strain (e.g., ZAP MALES® from MosquitoMate) + TX; Beauveria bassiana strain ATCC 74040 (e.g. NATURALIS® from Intrachem Bio Italia) + TX, Beauveria bassiana strain ATP02 (Accession No. DSM 24665), Apopka 97 (PREFERAL from SePRO) + TX, Beauveria bassiana strain GHA (Accession No. ATCC74250, e.g. BOTANIGUARD® ES and MYCONTROL-O® from Laverlam International Corporation) +TX, Metarhizium anisopliae 3213-1 (deposited under NRRL accession number 67074 disclosed in WO2017 / 066094, Pioneer Hi-Bred International) + TX, Metarhizium robertsii 15013-1 (deposited under NRRL accession number 67073) + TX, Metarhizium robertsii 23013-3 (deposited under NRRL accession number 67075) + TX, Paecilomyces lilacinus strain 251 (MELOCON from Certis, US) + TX; Cydia pomonella (codling moth) granulosis virus (GV) + TX, Helicoverpa armigera (cotton bollworm) nuclear polyhedrosis virus (NPV) + TX, of Adoxophyes orana (summer fruit tortrix) granulosis virus (GV) + TX, Spodoptera exigua (beet armyworm) mNPV + TX, Spodoptera frugiperda (fall armyworm) mNPV + TX; Burkholderia spp. in particular Burkholderia cepacia (formerly known as Pseudomonas cepacia) + TX, Gigaspora spp. + TX, Glomus spp. + TX, Laccaria spp. + TX, LactoBacillus buchneri + TX, Paraglomus spp. + TX, Pisolithus tinctorus + TX, Pseudomonas spp. + TX, Rhizobium spp. in particular Rhizobium trifolii + TX, Rhizopogon spp. + TX, Scleroderma spp. + TX, Streptomyces spp. + TX, Suillus spp. + TX, Agrobacterium spp. + TX, Azorhizobium caulinodans + TX, Azospirillum spp. + TX, Azotobacter spp. + TX, Bradyrhizobium spp. + TX, Gigaspora monosporum + TX; Allium sativum (NEMGUARD from Eco-Spray, BRALIC from ADAMA) + TX, Armour-Zen + TX, Artemisia absinthium + TX, Biokeeper WP + TX, Brassicaceae extract in particular oilseed rape powder or mustard powder + TX, Cassia nigricans + TX, Celastrus angulatus + TX, Chenopodium anthelminticum + TX, Chenopodium quinoa saponin extract from quinoa seeds (e.g. Heads Up® (Saponins of Quinoa) from Heads Up plant Protectants, CA) + TX, Chitin + TX, Dryopteris filix-mas + TX, Equisetum arvense + TX, Fortune Aza + TX, Fungastop + TX, Melaleuca alternifolia extract (TIMOREX GOLD from STK) + TX, naturally occurring Blad polypeptide extracted from Lupin seeds (FRACTURE® from FMC) + TX, naturally occurring Blad polypeptide extracted from Lupin seeds (PROBLAD® from Certis EU) + TX, Pyrethrins + TX, Quassia amara + TX, Quercus + TX, Quillaja extract (QL AGRI 35 from BASF) + TX, REGALIA MAXX from Marrone Bio) + TX, Requiem™ Insecticide + TX, Reynoutria sachalinensis extract (REGALLIA + TX, ryania / ryanodine + TX, Symphytum officinale + TX, Tanacetum vulgare + TX, Thymol + TX, Thymol mixed with Geraniol (CEDROZ from Eden Research) + TX, Thymol mixed with Geraniol and Eugenol (MEVALONE from Eden Research) + TX, Triact 70 + TX, TriCon + TX, Tropaeulum majus + TX, Urtica dioica + TX, Veratrin + TX, Viscum album + TX; mercuric oxide + TX, octhilinone + TX, thiophanate-methyl + TX; MGK 264 + TX, 2-(2-butoxyethoxy)ethyl piperonylate + TX, 2-isovalerylindan-1,3-dione + TX, 4-(quinoxalin-2-ylamino)benzenesulfonamide + TX, 5- (1,3-benzodioxol-5-yl)-3-hexylcyclohex-2-enone + TX, acibenzolar + TX, acibenzolar-S-methyl + TX, alpha- bromadiolone + TX, alpha-chlorohydrin + TX, aluminium phosphide + TX, anthraquinone + TX, antu + TX, 82875_FF 73 arsenous oxide + TX, barium carbonate + TX, benoxacor + TX, bisthiosemi + TX, brodifacoum + TX, bromadiolone + TX, bromethalin + TX, calcium cyanide + TX, chloralose + TX, chlorophacinone + TX, cholecalciferol + TX, cloquintocet (including cloquintocet-mexyl) + TX, copper naphthenate + TX, copper oxychloride + TX, coumachlor + TX, coumafuryl + TX, coumatetralyl + TX, crimidine + TX, cyprosulfamide + TX, diazinon + TX, dichlormid + TX, dicyclopentadiene + TX, difenacoum + TX, difethialone + TX, diphacinone + TX, ergocalciferol + TX, farnesol + TX, farnesol with nerolidol + TX, fenchlorazole (including fenchlorazole- ethyl) + TX, fenclorim + TX, flocoumafen + TX, fluoroacetamide + TX, flupropadine + TX, flupropadine hydrochloride + TX, fluxofenim + TX, furilazole + TX, gamma-HCH + TX, guazatine + TX, guazatine acetates + TX, HCH + TX, hydrogen cyanide + TX, imanin + TX, iodomethane + TX, isoxadifen (including isoxadifen-ethyl) + TX, lindane + TX, magnesium phosphide + TX, MB-599 + TX, mefenpyr (including mefenpyr-diethyl)+ TX, metcamifen + TX, methiocarb + TX, methyl bromide + TX, nerolidol + TX, norbormide + TX, petroleum oils + TX, phosacetim + TX, phosphine + TX, phosphorus + TX, pindone + TX, piperonyl butoxide + TX, piprotal + TX, potassium arsenite + TX, probenazole + TX, propyl isomer + TX, pyridin-4-amine + TX, pyrinuron + TX, Reynoutria sachalinensis extract + TX, ribavirin + TX, S421 + TX, scilliroside + TX, sesamex + TX, sesasmolin + TX, sodium arsenite + TX, sodium cyanide + TX, sodium fluoroacetate + TX, strychnine + TX, sulfoxide + TX, thallium sulfate + TX, thiram + TX, trimethacarb + TX, warfarin + TX, zinc naphthenate + TX, zinc phosphide + TX, ziram + TX. The references in brackets behind the active ingredients, e.g. [3878-19-1] refer to the Chemical AbstractsRegistry number. The above described mixing partners are known. Where the active ingredients are includedin "The Pesticide Manual" [The Pesticide Manual - A World Compendium; Thirteenth Edition; Editor: C. D. S. TomLin; The British Crop Protection Council], they are described therein under the entry number given in round brackets hereinabove for the particular compound; for example, the compound "abamectin" is described under entry number (1). Where "[CCN]" is added hereinabove to the particular compound, the compound in question is included in the "Compendium of Pesticide Common Names", which is accessible on the internet [A. Wood; Compendium of Pesticide Common Names, Copyright © 1995-2004]; for example, the compound "acetoprole" is described under the internet address http: / / www.alanwood.net / pesticides / acetoprole.html. Most of the active ingredients described above are referred to hereinabove by a so-called "common name", the relevant "ISO common name" or another "common name" being used in individual cases. If the designation is not a "common name", the nature of the designation used instead is given in round brackets for the particular compound; in that case, the IUPAC name, the IUPAC / Chemical Abstracts name, a "chemical name", a "traditional name", a "compound name" or a "develoment code" is used or, if neither one of those designations nor a "common name" is used, an "alternative name" is employed. “CAS Reg. No” means the Chemical Abstracts Registry Number. The tradenames in brackets behind the active ingredient refer to the commercially available product or products comprising this active ingredient. The active ingredient mixture of the compounds of formula (I) selected from the compounds of formulae (I), (I- a), or (I-b), or one compound selected from the group consisting of the compounds as represented in Tables 82875_FF 74 A1 to A2, or a compound listed in Table P (below), with active ingredients described above comprises a compound selected from one compound of formulae (I), (I-a), or (I-b), or one compound selected from the group consisting of the compounds as represented in Tables A1 to A2, or a compound listed in Table P (below), and an active ingredient as described above preferably in a mixing ratio of from 100:1 to 1:6000, especially from 50:1 to 1:50, more especially in a ratio of from 20:1 to 1:20, even more especially from 10:1 to 1:10, very especially from 5:1 and 1:5, special preference being given to a ratio of from 2:1 to 1:2, and a ratio of from 4:1 to 2:1 being likewise preferred, above all in a ratio of 1:1, or 5:1, or 5:2, or 5:3, or 5:4, or 4:1, or 4:2, or 4:3, or 3:1, or 3:2, or 2:1, or 1:5, or 2:5, or 3:5, or 4:5, or 1:4, or 2:4, or 3:4, or 1:3, or 2:3, or 1:2, or 1:600, or 1:300, or 1:150, or 1:35, or 2:35, or 4:35, or 1:75, or 2:75, or 4:75, or 1:6000, or 1:3000, or 1:1500, or 1:350, or 2:350,or 4:350, or 1:750, or 2:750, or 4:750. Those mixing ratios are by weight.The mixtures as described above can be used in a method for controlling pests, which comprises applying a composition comprising a mixture as described above to the pests or their environment, with the exception of a method for treatment of the human or animal body by surgery or therapy and diagnostic methods practised on the human or animal body. The mixtures comprising a compound of formula (I) selected from the compounds of formulae (I), (I-a), or (I- b), or one compound selected from the group consisting of the compounds as represented in Tables A1 to A2, or a compound listed in Table P (below), and one or more active ingredients as described above can be applied, for example, in a single “ready-mix” form, in a combined spray mixture composed from separate formulations of the single active ingredient components, such as a “tank-mix”, and in a combined use of the single active ingredients when applied in a sequential manner, e.g., one after the other with a reasonably short period, such as a few hours or days. The order of applying the compounds of formula (I) and the active ingredients as described above is not essential for working the present invention. The compositions according to the invention can also comprise further solid or liquid auxiliaries, such as stabilizers, e.g., unepoxidized or epoxidized vegetable oils (e.g., epoxidized coconut oil, rapeseed oil or soya oil), antifoams, e.g., silicone oil, preservatives, viscosity regulators, binders and / or tackifiers, fertilizers or other active ingredients for achieving specific effects, e.g., bactericides, fungicides, nematocides, plant activators, molluscicides or herbicides. The compositions according to the invention are prepared in a manner known per se, in the absence of auxiliaries for example by grinding, screening and / or compressing a solid active ingredient and in the presence of at least one auxiliary for example by intimately mixing and / or grinding the active ingredient with the auxiliary (auxiliaries). These processes for the preparation of the compositions and the use of the compounds I for the preparation of these compositions are also a subject of the invention. The application methods for the compositions, that is the methods of controlling pests of the abovementioned type, such as spraying, atomizing, dusting, brushing on, dressing, scattering, or pouring - which are to be selected to suit the intended aims of the prevailing circumstances - and the use of the compositions for controlling pests of the abovementioned type are other subjects of the invention. Typical rates of concentration are between 0.1 and 1000 ppm, preferably between 0.1 and 500 ppm, of active ingredient. The rate of 82875_FF 75 application per hectare is generally 1 to 2000 g of active ingredient per hectare, in particular 10 to 1000 g / ha, preferably 10 to 600 g / ha. A preferred method of application in the field of crop protection is application to the foliage of the plants (foliar application), it being possible to select frequency and rate of application to match the danger of infestation with the pest in question. Alternatively, the active ingredient can reach the plants via the root system (systemic action), by drenching the locus of the plants with a liquid composition or by incorporating the active ingredient in solid form into the locus of the plants, for example into the soil, for example in the form of granules (soil application). In the case of paddy rice crops, such granules can be metered into the flooded paddy-field. The compounds of formula (I) of the invention and compositions thereof are to be also suitable for the protectionof plant propagation material, for example seeds, such as fruit, tubers or kernels, or nursery plants, againstpests of the abovementioned type. The propagation material can be treated with the compound prior to planting, for example seed can be treated prior to sowing. Alternatively, the compound can be applied to seed kernels (coating), either by soaking the kernels in a liquid composition or by applying a layer of a solid composition. It is also possible to apply the compositions when the propagation material is planted to the site of application, for example into the seed furrow during drilling. These treatment methods for plant propagation material and the plant propagation material thus treated are further subjects of the invention. Typical treatment rates would depend on the plant and pest / fungi to be controlled and are generally between 1 to 200 grams per 100 kg of seeds, preferably between 5 to 150 grams per 100 kg of seeds, such as between 10 to 100 grams per 100 kg of seeds. The term “seed” embraces seeds and plant propagules of all kinds including but not limited to true seeds, seed pieces, suckers, corns, bulbs, fruit, tubers, grains, rhizomes, cuttings, cut shoots and the like and means in a preferred embodiment true seeds. The present invention also comprises seeds coated or treated with or containing a compound of formula (I). The term "coated or treated with and / or containing" generally signifies that the active ingredient is for the most part on the surface of the seed at the time of application, although a greater or lesser part of the ingredient may penetrate into the seed material, depending on the method of application. When the said seed product is (re)planted, it may absorb the active ingredient. In an embodiment, the present invention makes available a plant propagation material adhered thereto with a compound of formula (I). Further, it is hereby made available, a composition comprising a plant propagation material treated with a compound of formula (I).Seed treatment comprises all suitable seed treatment techniques known in the art, such as seed dressing,seed coating, seed dusting, seed soaking and seed pelleting. The seed treatment application of the compound formula (I) can be carried out by any known methods, such as spraying or by dusting the seeds before sowing or during the sowing / planting of the seeds. The compounds of the invention can be distinguished from other similar compounds by virtue of greater efficacy at low application rates and / or different pest control, which can be verified by the person skilled in the art using the experimental procedures, using lower concentrations if necessary, e.g., 10 ppm, 5 ppm, 2 ppm, 1 ppm or 82875_FF 76 0.2 ppm; or lower application rates, such as 300, 200 or 100, mg of AI (active ingredient) per m2. The greater efficacy can be observed by an increased safety profile (against non-target organisms above and below ground (such as fish, birds, and bees), improved physico-chemical properties, or increased biodegradability). In each aspect and embodiment of the invention, "consisting essentially" and inflections thereof are a preferred embodiment of "comprising" and its inflections, and "consisting of" and inflections thereof are a preferred embodiment of "consisting essentially of” and its inflections. The disclosure in the present application makes available each and every combination of embodiments disclosed herein. It should be noted that the disclosure herein in respect of a compound of formula (I) applies equally in respectof a compound of each of formulae (I), (I-a), or (I-b), or one compound selected from the group consisting ofthe compounds as represented in Tables A1 to A2, or a compound listed in Table P (below), The compounds according to the invention can be used as pesticidal agents in unmodified form, but they are generally formulated into compositions in various ways using formulation adjuvants, such as carriers, solvents and surface-active substances. The formulations can be in various physical forms, e.g., in the form of dusting powders, gels, wettable powders, water-dispersible granules, water-dispersible tablets, effervescent pellets, emulsifiable concentrates, microemulsifiable concentrates, oil-in-water emulsions, oil-flowables, aqueous dispersions, oily dispersions, suspo-emulsions, capsule suspensions, emulsifiable granules, soluble liquids, water-soluble concentrates (with water or a water-miscible organic solvent as carrier), impregnated polymer films or in other forms known e.g., from the Manual on Development and Use of FAO and WHO Specifications for Pesticides, United Nations, First Edition, Second Revision (2010). Such formulations can either be used directly or diluted prior to use. The dilutions can be made, for example, with water, liquid fertilisers, micronutrients, biological organisms, oil, or solvents. The formulations can be prepared e.g., by mixing the active ingredient with the formulation adjuvants in order to obtain compositions in the form of finely divided solids, granules, solutions, dispersions or emulsions. The active ingredients can also be formulated with other adjuvants, such as finely divided solids, mineral oils, oils of vegetable or animal origin, modified oils of vegetable or animal origin, organic solvents, water, surface-active substances or combinations thereof. The active ingredients can also be contained in very fine microcapsules. Microcapsules contain the active ingredients in a porous carrier. This enables the active ingredients to be released into the environment incontrolled amounts (e.g., slow-release). Microcapsules usually have a diameter of from 0.1 to 500 microns.They contain active ingredients in an amount of about from 25 to 95 % by weight of the capsule weight. The active ingredients can be in the form of a monolithic solid, in the form of fine particles in solid or liquid dispersion or in the form of a suitable solution. The encapsulating membranes can comprise, for example, natural or synthetic rubbers, cellulose, styrene / butadiene copolymers, polyacrylonitrile, polyacrylate, polyesters, polyamides, polyureas, polyurethane or chemically modified polymers and starch xanthates or other polymers that are known to the person skilled in the art. Alternatively, very fine microcapsules can be formed in which 82875_FF 77 the active ingredient is contained in the form of finely divided particles in a solid matrix of base substance, but the microcapsules are not themselves encapsulated. The formulation adjuvants that are suitable for the preparation of the compositions according to the invention are known per se. As liquid carriers there may be used: water, toluene, xylene, petroleum ether, vegetable oils, acetone, methyl ethyl ketone, cyclohexanone, acid anhydrides, acetonitrile, acetophenone, amyl acetate, 2- butanone, butylene carbonate, chlorobenzene, cyclohexane, cyclohexanol, alkyl esters of acetic acid, diacetone alcohol, 1,2-dichloropropane, diethanolamine, p-diethylbenzene, diethylene glycol, diethylene glycol abietate, diethylene glycol butyl ether, diethylene glycol ethyl ether, diethylene glycol methyl ether, N,N- dimethylformamide, dimethyl sulfoxide, 1,4-dioxane, dipropylene glycol, dipropylene glycol methyl ether,dipropylene glycol dibenzoate, diproxitol, alkylpyrrolidone, ethyl acetate, 2-ethylhexanol, ethylene carbonate,1,1,1-trichloroethane, 2-heptanone, alpha-pinene, d-limonene, ethyl lactate, ethylene glycol, ethylene glycol butyl ether, ethylene glycol methyl ether, gamma-butyrolactone, glycerol, glycerol acetate, glycerol diacetate, glycerol triacetate, hexadecane, hexylene glycol, isoamyl acetate, isobornyl acetate, isooctane, isophorone, isopropylbenzene, isopropyl myristate, lactic acid, laurylamine, mesityl oxide, methoxypropanol, methyl isoamyl ketone, methyl isobutyl ketone, methyl laurate, methyl octanoate, methyl oleate, methylene chloride, m-xylene, n-hexane, n-octylamine, octadecanoic acid, octylamine acetate, oleic acid, oleylamine, o-xylene, phenol, polyethylene glycol, propionic acid, propyl lactate, propylene carbonate, propylene glycol, propylene glycol methyl ether, p-xylene, toluene, triethyl phosphate, triethylene glycol, xylenesulfonic acid, paraffin, mineral oil, trichloroethylene, perchloroethylene, ethyl acetate, amyl acetate, butyl acetate, propylene glycol methyl ether, diethylene glycol methyl ether, methanol, ethanol, isopropanol, and alcohols of higher molecular weight, such as amyl alcohol, tetrahydrofurfuryl alcohol, hexanol, octanol, ethylene glycol, propylene glycol, glycerol, N-methyl-2-pyrrolidone, and the like. Suitable solid carriers are, for example, talc, titanium dioxide, pyrophyllite clay, silica, attapulgite clay, kieselguhr, limestone, calcium carbonate, bentonite, calcium montmorillonite, cottonseed husks, wheat flour, soybean flour, pumice, wood flour, ground walnut shells, lignin, and similar substances. A large number of surface-active substances can advantageously be used in both solid and liquid formulations, especially in those formulations which can be diluted with a carrier prior to use. Surface-active substances may be anionic, cationic, non-ionic or polymeric and they can be used as emulsifiers, wetting agents or suspending agents or for other purposes. Typical surface-active substances include, for example, salts of alkyl sulfates, such as diethanolammonium lauryl sulfate; salts of alkylarylsulfonates, such as calcium dodecylbenzenesulfonate; alkylphenol / alkylene oxide addition products, such as nonylphenol ethoxylate; alcohol / alkylene oxide addition products, such as tridecylalcohol ethoxylate; soaps, such as sodium stearate; salts of alkylnaphthalenesulfonates, such as sodium dibutylnaphthalenesulfonate; dialkyl esters of sulfosuccinate salts, such as sodium di(2-ethylhexyl)sulfosuccinate; sorbitol esters, such as sorbitol oleate; quaternary amines, such as lauryltrimethylammonium chloride, polyethylene glycol esters of fatty acids, such as polyethylene glycol stearate; block copolymers of ethylene oxide and propylene oxide; and salts of 82875_FF 78 mono- and di-alkylphosphate esters; and also further substances described e.g., in McCutcheon's Detergents and Emulsifiers Annual, MC Publishing Corp., Ridgewood New Jersey (1981). Further adjuvants that can be used in pesticidal formulations include crystallisation inhibitors, viscosity modifiers, suspending agents, dyes, anti-oxidants, foaming agents, light absorbers, mixing auxiliaries, antifoams, complexing agents, neutralising or pH-modifying substances and buffers, corrosion inhibitors, fragrances, wetting agents, take-up enhancers, micronutrients, plasticisers, glidants, lubricants, dispersants, thickeners, antifreezes, microbicides, and liquid and solid fertilisers. The compositions according to the invention can include an additive comprising an oil of vegetable or animal origin, a mineral oil, alkyl esters of such oils or mixtures of such oils and oil derivatives. The amount of oiladditive in the composition according to the invention is generally from 0.01 to 10 %, based on the mixture tobe applied. For example, the oil additive can be added to a spray tank in the desired concentration after a spray mixture has been prepared. Preferred oil additives comprise mineral oils or an oil of vegetable origin, e.g., rapeseed oil, olive oil or sunflower oil, emulsified vegetable oil, alkyl esters of oils of vegetable origin, e.g., the methyl derivatives, or an oil of animal origin, such as fish oil or beef tallow. Preferred oil additives comprise alkyl esters of C8-C22 fatty acids, especially the methyl derivatives of C12-C18 fatty acids, e.g., the methyl esters of lauric acid, palmitic acid, and oleic acid (methyl laurate, methyl palmitate and methyl oleate, respectively). Many oil derivatives are known from the Compendium of Herbicide Adjuvants, 10thEdition, Southern Illinois University, 2010. The inventive compositions generally comprise from 0.1 to 99 % by weight, especially from 0.1 to 95 % by weight, of compounds of the present invention and from 1 to 99.9 % by weight of a formulation adjuvant which preferably includes from 0 to 25 % by weight of a surface-active substance. Whereas commercial products may preferably be formulated as concentrates, the end user will normally employ dilute formulations. The rates of application vary within wide limits and depend on the nature of the soil, the method of application, the crop plant, the pest to be controlled, the prevailing climatic conditions, and other factors governed by the method of application, the time of application and the target crop. As a general guideline, compounds may be applied at a rate of from 1 to 2000 l / ha, especially from 10 to 1000 l / ha. Preferred formulations can have the following compositions (weight %): Emulsifiable concentrates: active ingredient: 1 to 95 %, preferably 60 to 90 %surface-active agent: 1 to 30 %, preferably 5 to 20 %liquid carrier: 1 to 80 %, preferably 1 to 35 % Dusts: active ingredient: 0.1 to 10 %, preferably 0.1 to 5 % solid carrier: 99.9 to 90 %, preferably 99.9 to 99 % Suspension concentrates: 82875_FF 79 active ingredient: 5 to 75 %, preferably 10 to 50 % water: 94 to 24 %, preferably 88 to 30 % surface-active agent: 1 to 40 %, preferably 2 to 30 % Wettable powders: active ingredient: 0.5 to 90 %, preferably 1 to 80 % surface-active agent: 0.5 to 20 %, preferably 1 to 15 % solid carrier: 5 to 95 %, preferably 15 to 90 % Granules: active ingredient: 0.1 to 30 %, preferably 0.1 to 15 %solid carrier: 99.5 to 70 %, preferably 97 to 85 %Formulation Examples The following Examples further illustrate, but do not limit, the invention. Wettable powders a) b) c) active ingredients 25 % 50 % 75 % sodium lignosulfonate 5 % 5 % - sodium lauryl sulfate 3 % - 5 % sodium diisobutylnaphthalenesulfonate - 6 % 10 % phenol polyethylene glycol ether (7-8 mol of ethylene oxide) - 2 % - highly dispersed silicic acid 5 % 10 % 10 % Kaolin 62 % 27 % - The combination is thoroughly mixed with the adjuvants and the mixture is thoroughly ground in a suitable mill, affording wettable powders that can be diluted with water to give suspensions of the desired concentration. Powders for dry seed treatment a) b) c) active ingredients 25 % 50 % 75 % light mineral oil 5 % 5 % 5 % highly dispersed silicic acid 5 % 5 % - Kaolin 65 % 40 % - Talcum - - 20 % The combination is thoroughly mixed with the adjuvants and the mixture is thoroughly ground in a suitable mill,affording powders that can be used directly for seed treatment.Emulsifiable concentrate active ingredients 10 % octylphenol polyethylene glycol ether (4-5 mol of ethylene oxide) 3 % calcium dodecylbenzenesulfonate 3 % castor oil polyglycol ether (35 mol of ethylene oxide) 4 % 82875_FF 80 Cyclohexanone 30 % xylene mixture 50 % Emulsions of any required dilution, which can be used in plant protection, can be obtained from this concentrate by dilution with water. Dusts a) b) c) Active ingredients 5 % 6 % 4 % Talcum 95 % - - Kaolin - 94 % - mineral filler - - 96 %Ready-for-use dusts are obtained by mixing the combination with the carrier and grinding the mixture in asuitable mill. Such dusts can also be used for dry dressings for seed. Extruder granules Active ingredients 15 % sodium lignosulfonate 2 % carboxymethylcellulose 1 % Kaolin 82 % The combination is mixed and ground with the adjuvants, and the mixture is moistened with water. The mixture is extruded and then dried in a stream of air. Coated granules Active ingredients 8% polyethylene glycol (mol. wt.200) 3 % Kaolin 89 % The finely ground combination is uniformly applied, in a mixer, to the kaolin moistened with polyethylene glycol. Non-dusty coated granules are obtained in this manner. Suspension concentrate active ingredients 40 % propylene glycol 10 % nonylphenol polyethylene glycol ether (15 mol of ethylene oxide) 6 % Sodium lignosulfonate 10 %carboxymethylcellulose 1 %silicone oil (in the form of a 75 % emulsion in water) 1 % Water 32 % The finely ground combination is intimately mixed with the adjuvants, giving a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water. Using such dilutions, living 82875_FF 81 plants as well as plant propagation material can be treated and protected against infestation by microorganisms, by spraying, pouring or immersion. Flowable concentrate for seed treatment active ingredients 40 % propylene glycol 5 % copolymer butanol PO / EO 2 % Tristyrenephenole with 10-20 moles EO 2 % 1,2-benzisothiazolin-3-one (in the form of a 20% solution in water) 0.5 % monoazo-pigment calcium salt 5 %Silicone oil (in the form of a 75 % emulsion in water) 0.2 %Water 45.3 % The finely ground combination is intimately mixed with the adjuvants, giving a flowable concentrate from which solutions of any desired dilution can be obtained by dilution with water, that can be used directly for seed treatment. Using such solutions, living plants as well as plant propagation material can be treated and protected against infestation by microorganisms, by spraying, pouring or immersion. Slow Release Capsule Suspension 28 parts of the combination are mixed with 2 parts of an aromatic solvent and 7 parts of toluene diisocyanate / polymethylene-polyphenylisocyanate-mixture (8:1). This mixture is emulsified in a mixture of 1.2 parts of polyvinylalcohol, 0.05 parts of a defoamer and 51.6 parts of water until the desired particle size is achieved. To this emulsion a mixture of 2.8 parts 1,6-diaminohexane in 5.3 parts of water is added. The mixture is agitated until the polymerization reaction is completed. The obtained capsule suspension is stabilized by adding 0.25 parts of a thickener and 3 parts of a dispersing agent. The capsule suspension formulation contains 28% of the active ingredients. The medium capsule diameter is 8-15 microns. The resulting formulation is applied to seeds as an aqueous suspension in an apparatus suitable for that purpose. Formulation types include an emulsion concentrate (EC), a suspension concentrate (SC), a suspo-emulsion (SE), a capsule suspension (CS), a water dispersible granule (WG), an emulsifiable granule (EG), an emulsion, water in oil (EO), an emulsion, oil in water (EW), a micro-emulsion (ME), an oil dispersion (OD), an oil miscible flowable (OF), an oil miscible liquid (OL), a soluble concentrate (SL), an ultra-low volume suspension (SU), an ultra-low volume liquid (UL), a technical concentrate (TK), a dispersible concentrate (DC), a wettable powder (WP), a soluble granule (SG) or any technically feasible formulation in combination with agriculturally acceptable adjuvants. EXAMPLES The following Examples further illustrate, but do not limit, the invention. ABBREVIATIONS CDCl3 Deuterated chloroform 82875_FF 82 DCM dichloromethane DMF Dimethylformamide DMSO Dimethyl sulfoxide DMSO-d6 Deuterated Dimethyl sulfoxide EtOAc ethyl acetate HCl hydrochloric acid h / hrs hour / hours LC-MS Liquid Chromatography Mass Spectrometry Rt retention timeTBME methyl tert-butyl ether or tert-butyl methyl ether (or MTBE)THF tetrahydrofuran TMS tetramethylsilane PREPARATORY EXAMPLES1H NMR and19F NMR measurements were recorded on a Bruker 400MHz spectrometer, chemical shifts are given in ppm relevant to a TMS (1H) or CFCl3 (19F) standard. Spectra measured in deuterated solvents as indicated. Throughout this description, temperatures are given in degrees Celsius (°C) and “mp.” means melting point. Free radicals represent methyl groups. LC / MS means Liquid Chromatography Mass Spectrometry and the description of the apparatus, and the methods are as follows. LC-MS Method A: Spectra were recorded on a Mass Spectrometer from Waters (SQD2 or QDA Single quadrupole mass spectrometer) equipped with an electrospray source (Polarity: Positive and Negative Polarity Switch), Capillary: 0.8-3.00 kV, Cone range: 25 Source Temperature: 120-150°C, Desolvation Temperature: 500-600°C, Cone Gas Flow: 50 L / h, Desolvation Gas Flow: 1000 L / h, Mass range: 110 to 850 Da) and an Acquity UPLC from Waters: Quaternary solvent manager, heated column compartment , diode-array detector. Column: Acquity UPLC HSS T3 C18, 1.8 µm, 30 x 2.1 mm, Temp: 40°C, DAD Wavelength range (nm): 200 to 400, Solvent Gradient: A = water + 5% Acetonitrile + 0.1 % HCOOH, B= Acetonitrile + 0.05 % HCOOH: gradient: 0 min 10% B; 0.-0.2 min 10-50% B; 0.2-0.6 min 50-100% B; 0.6-1.3 min 100% B; 1.3-1.4 min 100- 10% B; 1.4-1.6 min 10% B; Flow (mL / min) 0.6. LC-MS Method B: Spectra were recorded on a Mass Spectrometer from Agilent Technologies (6410 TripleQuadrupole mass spectrometer) equipped with an electrospray source (Polarity: positive or negative ions, MS2Scan, Capillary: 4.00 kV, Fragmentor: 100 V, Desolvation Temperature: 350°C, Gas Flow: 11 L / min, Nebulizer Gas: 45 psi, Mass range: 110 to 1000 Da) and a 1200 Series HPLC from Agilent: quaternary pump, heated column compartment and VWD detector. Column: KINETEX EVO C18, 2.6 µm, 50 x 4.6 mm, Temp: 40°C, Detector VWD Wavelength: 254 nm, Solvent Gradient: A = water + 5% Acetonitrile + 0.1 % HCOOH, B= Acetonitrile + 0.1 % HCOOH: gradient: 0 min 10% B, 90%A; 0.9-1.8 min 100% B; 1.8-2.2 min 100-10% B; 2.2- 2.5 min 10%B; Flow (mL / min) 1.8. 82875_FF 83 LC-MS Method C: Spectra were recorded on a Mass Spectrometer from Waters (SQD2 or QDA Single quadrupole mass spectrometer) equipped with an electrospray source (Polarity: Positive and Negative Polarity Switch), Capillary: 0.8-3.00 kV, Cone range: 25 Source Temperature: 120-150°C, Desolvation Temperature: 500-600°C, Cone Gas Flow: 50 L / h, Desolvation Gas Flow: 1000 L / h, Mass range: 110 to 850 Da) and an Acquity UPLC from Waters: Quaternary solvent manager, heated column compartment , diode-array detector. Column: Acquity UPLC HSS T3 C18, 1.8 µm, 30 x 2.1 mm, Temp: 40°C, DAD Wavelength range (nm): 200 to 400, Solvent Gradient: A = water + 5% Acetonitrile + 0.1 % HCOOH, B= Acetonitrile + 0.05 % HCOOH: gradient: 0 min 10% B; 0.0-0.5 min 10% B; 0.5-2 min 100% B; 2-3 min 100% B; 3-3.5 min 10% B; 3.5-4 min 10% B; Flow (mL / min) 0.6.LC-MS Method D: Spectra were recorded on a Mass Spectrometer from Waters Corporation (SQD, SQDII orQDA Single quadrupole mass spectrometer) equipped with an electrospray source (Polarity: positive and negative ions), Capillary: 0.8-3.00 kV, Cone: 5-30 V, Source Temperature: 120-150°C, Desolvation Temperature: 350-600°C, Cone Gas Flow: 50-150 l / h, Desolvation Gas Flow: 650-1000 l / h, Mass range: 110 to 950 Da and an Acquity UPLC from Waters Corporation: Binary pump, heated column compartment , diode- array detector and ELSD. Column: Waters UPLC HSS T3, 1.8 µm, 30 x 2.1 mm, Temp: 60°C, DAD Wavelength range (nm): 210 to 400, Runtime: 1.5 min; Solvents: A = water + 5% MeOH + 0.05 % HCOOH, B= Acetonitrile + 0.05 % HCOOH; Flow (ml / min) 0.85, Gradient: 10% B isocratic for 0.2 min, then 10-100% B in 1.0 min, 100% B isocratic for 0.2min, 100-10% B in 0.05min, 10% B isocratic for 0.05 min. LC-MS Method E: Spectra were recorded on a ACQUITY Mass Spectrometer from Waters Corporations (SQD or SQDII Single quadrupole mass spectrometer) equipped with an electrospray source (Polarity: positive or negative ions, Capillary: 3.0 kV, Cone: 30V, Extractor: 3.00 V, Source Temperature: 150°C, Desolvation Temperature: 400°C, Cone Gas Flow: 60 L / hr, Desolvation Gas Flow: 700 L / hr, Mass range: 140 to 800 Da) and an ACQUITY UPLC from Waters Corporations with solvent degasser, binary pump, heated column compartment and diode-array detector. Column: Waters UPLC HSS T3, 1.8 µm, 30 x 2.1 mm, Temp: 60°C, DAD Wavelength range (nm): 210 to 400, Solvent Gradient: A = Water / Methanol 9:1 + 0.1% formic acid, B= Acetonitrile + 0.1% formic acid, gradient: 0-100% B in 2.5 min; Flow (ml / min) 0.75. LC-MS Method F: Mass spectra were recorded on an Agilent (Single quad mass spectrometer) equipped with an electrospray source (Multimode- Electron Spray & APCI, polarity: positive & negative ions^, capillary (kV) 4.0, corona current 4.0µA, charging Voltage, 2.00kV, nitrogen gas flow:12.0L / min, nebulizer pressure: 40psig, mass range: 100 to 1000 m / z), dry gas temperature 250°C, Vaporizer temperature 200°C, mass range: 100 to 900 Da^, mobile phase: 0.1% Formic acid in water: ACN (1:1) (%v / v). Retention times were measured via HPLC. Column used: Acquity UPLC BEH C181.7µm (2.1*50mm); flow rate 0.6 mL / min, column temperature 40°C, detection wavelength (UV) 215 nm, injection volume 0.5 μL, sample diluent water:acetonitrile 1:1 (%v / v)., runtime 10 min. Solvent system A: 0.05% TFA in water:acetonitrile 95:5 (%v / v). Solvent system B: 0.05% TFA in acetronitrile. Gradient (min / %B (%v / v) in A): 0 / 10, 1.5 / 10, 5 / 70, 7 / 95, 8.5 / 95, 8.6 / 10, 10 / 10. LC-MS Method G: Mass spectra were recorded on an Agilent (Single quad mass spectrometer) equipped with an electrospray source (Multimode- Electron Spray & APCI, polarity: positive & negative ions^, capillary (kV) 82875_FF 84 4.0, corona current 4.0µA, charging Voltage, 2.00kV, nitrogen gas flow:12.0L / min, nebulizer pressure: 40psig, mass range: 100 to 1000 m / z), dry gas temperature 250°C, Vaporizer temperature 200°C, mass range: 100 to 900 Da^, mobile phase: 0.1% Formic acid in water: ACN (1:1) (%v / v). Retention times were measured via HPLC. Column used: Eclipse Plus C18, 100x4.6 mm, 3.5 μM, flow rate 1 mL / min, column temperature 30°C, detection wavelength (UV) 215 nm, injection volume 0.5 μL, sample diluent water:acetonitrile 1:1 (%v / v)., runtime 15 min. Solvent system A: 0.05% TFA in water. Solvent system B: 0.05% TFA in acetronitrile. Gradient (min / %B (%v / v) in A): 0 / 5, 2 / 5, 10 / 98, 12 / 98, 15 / 5. Example 1: Preparation of 2-chloro-N-(1-cyanocyclopropyl)-5-[[1-(trifluoromethylsulfonylamino) cyclopropyl] methoxy]pyridine-3-carboxamide (Compound P4, Table P) (Compound P4, Table P) cyclopropyl]methyl methanesulfonate mmol) and methansulfonyl chloride (1.5 equiv., 40.1 mmol) were added dropwise to a stirred solution of tert-butyl N-[1-(hydroxymethyl)cyclopropyl]carbamate (5 g, 26.7 mmol, 1 equiv.) in dry THF (20 mL / g) at 0°C. The resulting reaction mixture was stirred at rt for 2.5h, then the reaction mixture wasdiluted with EtOAc and a cold saturated aqueous solution of sodium bicarbonate. The aqueous layer was extracted several times with EtOAc and the combined organic phases were concentrated under reduced pressure to get the desired compound as a white solid. 1H NMR (400 MHz, CDCl3) δ ppm :0.86 - 0.97 (m, 4 H) 1.42 (s, 9 H) 3.01 (s, 3 H) 4.22 (br s, 2 H) 5.16 (br s, 1 H) Step B: Preparation of methyl 5-[[1-(tert-butoxycarbonylamino)cyclopropyl]methoxy]-2-chloro-pyridine-3- carboxylate was added to a solution of methyl 2-chloro-5-hydroxy-pyridine-3- carboxylate (1 g, 5.33 mmol, 1.0 equiv.) and [1-(tert-butoxycarbonylamino)cyclopropyl]methyl methanesulfonate (1.1 equiv., 5.86 mmol) in DMF (20 mL / g) at rt under a nitrogen atmosphere. The resulting suspension was stirred at 60°C for 16h and then diluted with EtOAc and water. The aqueous layer was extracted several times with EtOAc and the combined organic phases were washed with water and brine, dried 82875_FF 85 over sodium sulfate and concentrated under reduced pressure. The desired compound was obtained by purification via column chromatography on silica gel (eluent: mixtures of cyclohexane and EtOAc). 1H NMR (400 MHz, CDCl3) δ ppm: 0.89 - 1.00 (m, 4 H) 1.42 - 1.43 (m, 9 H) 3.96 (s, 3 H) 4.05 (br s, 2 H) 5.11 (br s, 1 H) 7.68 (d, J=3.06 Hz, 1H) 8.21 (d, J=3.06 Hz, 1 H) Step C: Preparation of [1-[(6-chloro-5-methoxycarbonyl-pyridin-1-ium-3-yl)oxymethyl]cyclopropyl]ammonium dichloride in EtOAc (15 equiv., 11 mL / g) was added dropwise to a solution of methyl 5-[[1-(tert-butoxycarbonylamino)cyclopropyl]methoxy]-2-chloro-pyridine-3-carboxylate (0.520 g, 1.46 mmol, 1 equiv.) in EtOAc (4.1 mL / g) was added HCl (11 mL / g, 22.9 mmol, 4 mol / L) at 0°C. The reaction mixture was stirred at rt for 16h and concentrated under reduced pressure. The crude material was washed with TBME and dried in vacuum to get the desired compound as white solid. 1H NMR (400 MHz, DMSO-d6) δ ppm: 0.91 (br s, 2 H) 1.15 (br s, 2 H) 3.88 (br s, 3 H) 4.27 (s, 2 H) 7.86 (br s, 1 H) 8.35 (br s, 1 H) 8.92 (br s, 3 H) Step D: Preparation of methyl 2-chloro-5-[[1-(trifluoromethylsulfonylamino)cyclopropyl]methoxy]pyridine-3- carboxylate and trifluoromethanesulfonic anhydride (1.05 equiv., 1.4 mmol) were added dropwise to a solution of [1-[(6-chloro-5-methoxycarbonyl-pyridin-1-ium-3-yl)oxymethyl]cyclopropyl]ammonium dichloride (450 mg, 1.365 mmol, 1 equiv.) in DCM (20 mL / g) at 0°C. The reaction mixture was allowed to reach rt and was stirred for 16h. Next the reaction mixture was concentrated under reduced pressure and purified by column chromatography on silica gel (eluent: mixtures EtOAc and cyclohexane) to obtain the desired compound. 1H NMR (400 MHz, CD3CN) δ ppm: 1.04 - 1.08 (m, 2 H) 1.30 (s, 2 H) 3.98 (s, 3 H) 4.06 (s, 2 H) 5.99 (s, 1 H) 7.69 (d, J=3.06 Hz, 1 H) 8.22 (d, J=3.18 Hz, 1 H).19F NMR (377 MHz, CD3CN) δ ppm: -78.15 (s, 1 F) Step E: Preparation of 2-chloro-5-[[1-(trifluoromethylsulfonylamino)cyclopropyl]methoxy]pyridine-3-carboxylic acid 82875_FF 86 (3 equiv., 0.85 mmol) in water (7 mL / g) was added to a solution of methyl 2- chloro-5-[[1-(trifluoromethylsulfonylamino)cyclopropyl]methoxy]pyridine-3-carboxylate (110 mg, 0.28 mmol, 1 equiv.) in THF (20 mL / g) and methanol (3 mL / g). The resulting reaction mixture was stirred at rt for 2h, next diluted with water and washed with EtOAc. The aqueous layer was acidified with citric acid solution and extracted several times with EtOAc. The combined organic phases were concentrated under reduced pressure and dried in vacuum to get the desired compound. 1H NMR (400 MHz, DMSO-d6) δ ppm: 0.99 - 1.04 (m, 4 H) 4.11 (s, 2 H) 7.69 - 7.88 (m, 1 H) 8.18 - 8.35 (m, 1 H) 10.01 - 10.24 (m, 1 H).19F NMR (377 MHz, DMSO-d6) δ ppm: -78.19 (s, 1 F) Step F: Preparation of 2-chloro-N-(1-cyanocyclopropyl)-5-[[1-(trifluoromethylsulfonylamino) cyclopropyl] methoxy] pyridine-3-carboxamide (Compound P4, Table P) 1-aminocyclopropanecarbonitrile (1.2 equiv., 0.16 mmol) and triethylamine (5 equiv., 0.67 mmol) were added to a stirred solution of 2-chloro-5-[[1-(trifluoromethylsulfonylamino)cyclopropyl]methoxy]pyridine-3-carboxylic acid (50 mg, 0.13 mmol, 1.0 equiv.) in EtOAc (5 mL / mmol) at rt. A 1.7 M solution of 1-propanephosphonic anhydride in EtOAc (3 equiv., 0.4003 mmol, 50 mass%) was added to the solution and the reaction mixture was stirred at rt for 16 h. The reaction mixture was diluted with water and extracted with EtOAc. The combined organic phases were dried over sodium sulfate and concentrated under reduced pressure. Purification by column chromatography on silica gel (eluent: mixtures EtOAc and cyclohexane) gave the desired product. 1H NMR (400 MHz, CD3CN) δ ppm: 0.98 - 1.07 (m, 2 H) 1.12 - 1.23 (m, 2 H) 1.29 - 1.40 (m, 2 H) 1.57 - 1.63 (m, 2 H) 4.07 (s, 2 H) 7.41 - 7.48 (m, 2 H) 7.66 (br s, 1 H) 8.18 (d, J=3.18 Hz, 1 H).19F NMR (377 MHz, CD3CN)δ ppm: -79.55 (s, 1 F) Example 2: Preparation of 2-chloro-N-cyclopropyl-5-[2-methyl-2-(trifluoromethylsulfonylamino)propoxy] pyridine-3-carboxamide (Compound 25, Table P) (Compound P25, Table P) 5-[2-(tert-butoxycarbonylamino)-2-methyl-propoxy]-2-chloro-pyridine-3- carboxylate 82875_FF 87 To a stirred solution of methyl 2-chloro-5-hydroxy-pyridine-3-carboxylate (50.0 mg, 0.267 mmol) and methyl 4,4-dimethyl-2,2-dioxo-oxathiazolidine-3-carboxylate (61.3 mg, 0.293 mmol) in DMF (2.00 mL) at rt was added potassium carbonate (111 mg, 0.800 mmol). The resulting reaction mixture was stirred at 80°C for 16 hours before the reaction mixture was quenched with water. It was extracted twice with EtOAc, then the combined organic layers were washed with brine, dried over sodium sulfate and concentrated under reduced pressure. The crude was purified by flash chromatography (0 to 100% EtOAc in hexanes) to obtain methyl 5-[2-(tert- butoxycarbonylamino)-2-methyl-propoxy]-2-chloro-pyridine-3-carboxylate as colorless liquid. LCMS (method F): Rt: 3.91 min, m / z = 359.1 [M+H]+;1H NMR (400 MHz, DMSO-d6) δ ppm 8.30 (d, J = 2.8 Hz, 1H), 7.81 (d, J = 2.8 Hz, 1H), 6.66 (bs, 1H), 4.13 (s, 2H), 3.87 (s, 3H), 1.31 (s, 9H), 1.26 (s, 6H) Step B: Preparation of tert-butyl N-[2-[[6-chloro-5-(cyclopropylcarbamoyl)-3-pyridyl]oxy]-1,1-dimethyl-ethyl]carbamate -2-methyl-propoxy]-2-chloro-pyridine-3-carboxylate (30.0 mg, 0.0836 mmol) and cyclopropanamine (7.16 mg, 0.125 mmol) in THF (2.00 mL) was added 3,4,6,7,8,9-hexahydro-2H-pyrimido[1,2-a] pyrimidine (5.82 mg, 0.0418 mmol). The resulting reaction mixture was stirred at rt for 16 hours before the reaction mixture was quenched with water. It was extracted twice with EtOAc, then the combined organic layers were washed with brine, dried over sodium sulfate and concentrated under reduced pressure. The crude was purified by flash chromatography (0 to 100% EtOAc in hexanes) to obtain tert-butyl N-[2-[[6-chloro-5-(cyclopropylcarbamoyl)-3-pyridyl]oxy]-1,1-dimethyl- ethyl]carbamate as colourless liquid. LCMS (method F): Rt: 3.35 min, m / z: only fragmentation products detected 284.2 [M+H-boc]+(loss of tert- butoxycarbonyl group) and 328.1 [M+H-tBu]+(loss of tert-butyl group) 1H NMR (400 MHz, DMSO-d6) δ ppm 8.58 (d, J = 4.4 Hz, 1H), 8.15 (d, J = 3.2 Hz, 1H), 7.48 (d, J = 3.2 Hz, 1H), 6.66 (bs, 1H), 4.08 (s, 2H), 2.82 - 2.76(m, 1H), 1.34 (s, 9H), 1.26 (s, 6H), 0.72 – 0.67(m, 2H), 0.61 – 0.55 (m, 2H) Step C: Preparation of [2-[[6-chloro-5-(cyclopropylcarbamoyl)-3-pyridyl]oxy]-1,1-dimethyl-ethyl]ammonium chloride N-[2-[[6-chloro-5-(cyclopropylcarbamoyl)-3-pyridyl]oxy]-1,1-dimethyl- ethyl]carbamate (900 mg, 2.34 mmol) in 1,4-dioxane (10 mL) was added dropwise 4.0 M HCl in 1,4-dioxane(844 mg, 23.4 mmol). The resulting reaction mixture was stirred at rt for 16 hours before the solvent was 82875_FF 88 removed under reduced pressure. The crude was triturated twice with MTBE and the resulting solid was dried under vacuum to afford [2-[[6-chloro-5-(cyclopropylcarbamoyl)-3-pyridyl]oxy]-1,1-dimethyl-ethyl]ammonium chloride (500 mg, 1.76 mmol, yield: 75.2 %) as an off white solid. LCMS (method F): Rt: 5.72 min, m / z = 284.1 [M+H]+;1H NMR (400 MHz, DMSO-d6) δ ppm 8.66 (d, J = 4.0 Hz, 1H), 8.33 (bs, 3H), 8.22 (d, J = 3.2 Hz, 1H), 7.57 (d, J = 3.2 Hz, 1H), 4.09 (s, 2H), 2.84 - 2.77(m, 1H), 1.34 (s, 6H), 0.73 – 0.68 (m, 2H), 0.61 – 0.55 (m, 2H Step D: Preparation of 2-chloro-N-cyclopropyl-5-[2-methyl-2-(trifluoromethylsulfonylamino)propoxy]pyridine-3- carboxamide (Compound P25, Table P) To a solution of 5-(2-amino-2-methyl-propoxy)-2-chloro-N-cyclopropyl-pyridine-3-carboxamide (50.0 mg, 0.176mmol) in dichloromethane (4.00 mL) were added at 0°C N, N-diethylethanamine (53.5 mg, 0.529 mmol) andtrifluoromethylsulfonyl trifluoromethanesulfonate (74.6 mg, 0.264 mmol). The resulting reaction mixture was stirred at rt for 5 hours. The reaction mixture was quenched with water and extracted twice with dichloromethane. The combined organic layers were washed with brine, dried over sodium sulfate and concentrated under reduced pressure. The crude was purified by flash chromatography (0-50% EtOAc in hexanes) to give 2-chloro-N-cyclopropyl-5-[2-methyl-2-(trifluoromethylsulfonylamino)propoxy]pyridine-3- carboxamide as an off-white solid. LCMS (method F): Rt: 3.54 min, m / z = 415.9 [M+H]+;1H NMR (400 MHz, DMSO-d6) δ ppm 9.25 (s, 1H), 8.60 (d, J = 4.4 Hz, 1H), 8.17 (d, J = 3.2 Hz, 1H), 7.52 (d, J = 3.2 Hz, 1H), 4.03 (s, 2H), 2.83 - 2.77(m, 1H), 1.39 (s, 6H), 0.73 – 0.69 (m, 2H), 0.58 – 0.54 (m, 2H).19F NMR (376 MHz, DMSO-d6) δ ppm – 77.71 (s, 3 F) Example 3: Preparation 2-chloro-N-cyclopropyl-5-[2-[methoxymethyl(trifluoromethylsulfonyl)amino]-2-methyl- propoxy]pyridine-3-carboxamide (Compound P22, Table P) (Compound P22, Table P) 5-[2-methyl-2-(trifluoromethylsulfonylamino)propoxy]pyridine-3- carboxamide (100 mg, 0.240 mmol) in acetonitrile (5.00 mL) at 0° C were added N,N-diethylethanamine (73.0 mg, 0.721 mmol) and chloro(methoxy)methane (29.0 mg, 0.361 mmol). The resulting reaction mixture was stirred at rt for 5 hours before the reaction mixture was quenched with water. It was and extracted twice with EtOAc and the combined organic layers were washed with brine, dried over sodium sulfate and concentrated under reduced pressure. The crude was purified by flash chromatography (0-100% EtOAc in hexanes) to afford 2-chloro-N-cyclopropyl-5-[2-[methoxymethyl(trifluoromethylsulfonyl)amino]-2-methyl- propoxy]pyridine-3-carboxamide as a light yellow gum. LCMS (method G): Rt: 9.17 min, m / z = 460 [M+H]+;1H NMR (400 MHz, DMSO-d6) δ ppm 8.61 (d, J = 4.4 Hz, 1H), 8.18 (d, J = 3.2 Hz, 1H), 7.56 (d, J = 2.8 Hz, 1H), 4.89 (s, 2H), 4.21 (s, 2H), 3.31 (s, 3H), 2.82 - 2.76 (m, 82875_FF 89 1H), 1.58 (s, 6H), 0.73 – 0.68 (m, 2H), 0.58 – 0.54 (m, 2H).19F NMR (376 MHz, DMSO-d6) δ ppm – 75.49 (s, 3 F) Example 4: Preparation of 2-chloro-N-cyclopropyl-5-[[1-(difluoromethylsulfonylamino) cyclopropyl] methoxy]pyridine-3-carboxamide (Compound P16, Table P) (Compound P16, Table P) cyclopropyl]methyl methanesulfonate (hydroxymethyl)cyclopropyl]carbamate (2.00 g, 10.7 mmol) in THF (30 mL) was added triethylamine (2.97 mL, 21.4 mmol) followed by the addition of methanesulfonyl chloride (1836 mg, 16.0 mmol) at 0°C. The resulting reaction mixture was stirred up to rt for 16 hours before it was quenched with ice- cold water. It was extracted twice with EtOAc, and the combined organic layers were washed with brine, dried over sodium sulfate and concentrated under reduced pressure. The crude was further washed with MTBE to afford [1-(tert-butoxycarbonylamino)cyclopropyl]methyl methanesulfonate as off-white solid. 1H NMR (400 MHz, CDCl3) δ 5.10 (s,1H), 4.24 (s, 2H), 3.02 (s, 3H), 1.44 (s, 9H), 0.95 – 0.91 (m, 4H). Step B: Preparation of methyl 5-[[1-(tert-butoxycarbonylamino)cyclopropyl]methoxy]-2-chloro-pyridine-3- carboxylate pyridine-3-carboxylate (2.00 g, 10.7 mmol) in acetonitrile (40 mL) were added [1-(tert-butoxycarbonylamino)cyclopropyl]methyl methanesulfonate (5.96 g, 21.3 mmol) and cesium carbonate (10.4 g, 32.0 mmol) at rt. The resulting reaction mixture was stirred at 90°C for 16 hours in a sealed tube before it was quenched with ice-cold water and extracted twice with EtOAc. The combined organic layers were washed with brine, dried over sodium sulfate and concentrated under reduced pressure. The crude was purified by flash column chromatography (40% EtOAc in hexanes) to afford of methyl 5-[[1- (tert-butoxycarbonylamino)cyclopropyl]methoxy]-2-chloro-pyridine-3-carboxylate as an off white solid. LCMS (method F): Rt: 3.55 min, m / z = 375.0 [M+H]+;1H NMR (400 MHz, CDCl3) δ 8.22 – 8.21 (d, J = 3.2 Hz, 1H), 7.68 -7.67 (d, J = 3.2 Hz, 1H), 5.11 (br, s,1H), 4.06 (s, 2H), 3.96 (s, 3H), 1.46 (s, 9H), 0.97 – 0.90 (m, 4H) Step C: Preparation of tert-butyl N-[1-[[6-chloro-5-(cyclopropylcarbamoyl)-3-pyridyl]oxymethyl] cyclopropyl]carbamate 82875_FF 90 amino)cyclopropyl)methoxy)-2-chloronicotinate (1.40 g, 3.73 mmol) in THF (25 mL) were added cyclopropanamine (319 mg, 5.59 mmol) and 3,4,6,7,8,9-hexahydro- 2H-pyrimido[1,2-a]pyrimidine (TBD) (259 mg, 1.86 mmol. The resulting reaction mixture was stirred at rt for 16 hours before it was concentrated under reduced pressure. The crude was purified by flash chromatography (60% EtOAc in hexanes) to afford tert-butyl N-[1-[[6-chloro-5-(cyclopropylcarbamoyl)-3- pyridyl]oxymethyl]cyclopropyl]carbamate as an off-white solid. LCMS (method F): Rt: 3.03 min, m / z = 326.0 [M+H-tBu]+;1H NMR (400 MHz, CDCl3) δ 8.14 – 8.13 (d, J = 3.2 Hz, 1H), 7.65 -7.64 (d, J = 2.8 Hz, 1H), 6.67 (br, s,1H), 5.11 (br, s,1H), 4.04 s, 2H), 2.97-2.90 (m, 1H), 1.60 (s, 9H), 0.96 – 0.89 (m, 6H), 0.69-0.68 (m, 2H). Step D: Preparation of [1-[[6-chloro-5-(cyclopropylcarbamoyl)-3-pyridyl]oxymethyl]cyclopropyl]ammonium chloride 5-(cyclopropylcarbamoyl)-3 pyridyl]oxymethyl]cyclopropyl]carbamate (850 mg, 2.11 mmol) in DCM (20 mL) at 0°C was dropwise added 4N HCl in 1,4 dioxane (2.64 mL, 10.6 mmol). The resulting reaction mixture was stirred up to rt for 16 hours before it was concentrated under reduced pressure to afford [1-[[6-chloro-5-(cyclopropylcarbamoyl)-3-pyridyl]oxymethyl]cyclopropyl]ammonium chloride as a light-yellow solid.1H NMR (400 MHz, DMSO-d6) δ 8.67 – 8.66 (d, J = 4.4 Hz, 1H), 8.22 – 8.21 (d, J = 3.2 Hz, 1H), 7.55 -7.54 (d, J = 3.2 Hz, 1H), 4.57 (br, s, 2H), 4.22 (br, s, 2H), 2.84 – 2.79 (m, 1H), 1.13 – 1.10 (m, 2H), 0.93 – 9.0 (m, 2H), 0.87-0.85 (m, 2H), 0.74 – 0.70 (m, 2H). Step E: Preparation of 2-chloro-N-cyclopropyl-5-[[1-(difluoromethylsulfonylamino) cyclopropyl] methoxy]pyridine-3-carboxamide (Compound P16, Table P) To a solution of 5-[(1-aminocyclopropyl)methoxy]-2-chloro-N-cyclopropyl-pyridine-3-carboxamide (300 mg, 0.958 mmol) in DCM (10 mL) were added difluoromethanesulfonyl chloride (0.0361 g, 0.240 mmol) and 1- methyl imidazole (0.133 g, 0.958 mmol). The resulting reaction mixture was stirred at rt for 16 hours before it was quenched with saturated aqueous NaHCO3 solution. It was extracted with EtOAc, and the combined organic layers were washed with brine, dried over sodium sulfate and concentrated under reduced pressure. The crude was purified by flash column chromatography (50% EtOAc in hexanes) to afford 2-chloro-N- cyclopropyl-5-[[1-(difluoromethylsulfonylamino) cyclopropyl]methoxy]pyridine-3-carboxamide as a white solid. 82875_FF 91 LCMS (method F): Rt: 2.78 min, m / z = 396.0 [M+H]+;1H NMR (400 MHz, DMSO-d6) δ ppm 9.20 (s, 1H), 8.60 – 8.59 (d, J = 4.4 Hz, 1H), 8.18 – 8.17 (d, J = 3.2 Hz, 1H), 7.50-7.49 (d, J = 3.2 Hz, 1H), 7.01 – 6.75 (t, J = 52.8 Hz, 1H), 4.05 (s, 3H), 2.28 – 2.77 (m, 1H), 0.99 – 0.97 (m, 2H), 0.92 – 0.91 (m, 2H), 0.72 – 0.71 (m, 2H), 0.69 – 0.68 (m, 2H).19F NMR (376 MHz, DMSO-d6) δ ppm – 122.10 (s, 3 F) Example 5: Preparation of 5-[[1-[acetyl(difluoromethylsulfonyl)amino]cyclopropyl]methoxy]-2-chloro-N- cyclopropyl-pyridine-3-carboxamide (Compound P17, Table P) (Compound P17, Table P) 5-[[1-(difluoromethylsulfonylamino) cyclopropyl] methoxy]pyridine-3- carboxamide (120 mg, 0.288 mmol) in acetonitrile (10 mL) was added trithylamine (0.120 mL, 0.864 mmol) at 0°C, followed by a dropwise addition of acetyl chloride (0.0308 mL, 0.432 mmol). The resulting reaction mixture was stirred at rt for 16 hours before it was quenched with saturated aqueous NaHCO3 solution. It was extracted with EtOAc, and the combined organic layers were washed twice with brine, dried over sodium sulfate and concentrated under reduced pressure. The crude was purified by flash column chromatography (80% EtOAc in hexanes) to afford 5-[[1-[acetyl(difluoromethylsulfonyl)amino]cyclopropyl]methoxy]-2-chloro-N-cyclopropyl- pyridine-3-carboxamide as a white solid. LCMS method F : Rt: 3.22 min, m / z = 437.9 [M+H]+;1H NMR (DMSO-d6) δ 8.61 – 8.60 (d, J = 4.4 Hz, 1H), 8.17 – 8.16 (d, J = 3.2 Hz, 1H), 7.54 – 7.53 (d, J = 2.8 Hz, 1H), 7.36 – 7.09 (t, J = 53.6 Hz, 1H), 4.38 – 4.36 (d, J = 8 Hz, 1H), 3.98 – 3.95 (d, J = 12 Hz,1H), 2.81 – 2.76 (m, 1H), 2.56 (s, 3H), 1.58 (br, s, 1H),1.39-1.22 (m, 3H), 0.72 – 0.700.97 (m, 2H), 0.69 – 0.68 (m, 2H).19F NMR (376 MHz, DMSO-d6): δ -121.27 (s, 2 F) Example 6: Preparation of methyl N-[1-[[6-chloro-5-(cyclopropylcarbamoyl)-3-pyridyl]oxymethyl]cyclopropyl]-N-(difluoromethylsulfonyl)carbamate P18, Table P) (Compound P18, Table P) 5-[[1-(difluoromethylsulfonylamino)cyclopropyl]methoxy]pyridine-3- carboxamide (100 mg, 0.240 mmol) in acetonitrile (10 mL) was added triethylamine (0.100 mL, 0.720 mmol) at 0°C followed by the addition of methyl chloroformate (0.0267 mL, 0.360 mmol). The resulting reactionmixture was stirred at rt for 16 hours before it was quenched with ice-cold water. It was extracted with EtOAc and the combined organic layers were washed with brine, dried over sodium sulfate and concentrated under reduced pressure. The crude was purified by flash column chromatography (80% EtOAc in hexanes) to afford methyl N-[1-[[6-chloro-5-(cyclopropylcarbamoyl)-3-pyridyl]oxymethyl]cyclopropyl]-N-(difluoromethylsulfonyl)- carbamate as a white solid. 82875_FF 92 LCMS (method F): Rt: 3.24 min, m / z = 454.0 [M+H]+;1H NMR (400 MHz, DMSO-d6) δ 8.60 – 8.59 (d, J = 4.0 Hz, 1H), 8.19 – 8.18 (d, J = 3.2 Hz, 1H), 7.53 – 7.52 (d, J = 3.2 Hz, 1H), 7.14 – 6.87 (t, J = 52.8 Hz, 1H), 4.16 (s, 2H), 3.08 (s, 3H), 2.81 – 2.76 (m, 1H), 1.23 – 1.21 (m, 2H), 1.03 – 1.0 (m, 2H), 0.71 – 0.69 (m, 2H), 0.53 – 0.52 (m, 2H).19F NMR (376 MHz, DMSO-d6): δ -122.67. Examples of synthesized compounds of formula (I) are shown in Table P. Table P: Synthesized compounds and Spectral and Physical Chemical Data. ))dyri ]tn er dnEIUPAC name Moleculem(H+usohTM a teR[ em M ( 2-chloro-N-cyclopropyl-5-[[1- P1 (dichloromethylsulfonylamino) cyclopropyl]methoxy]pyridine-3- 0.80 428 D carboxamide 2-chloro-N-cyclopropyl-5-[[1- P2 (difluoromethylsulfonylamino) cyclopropyl]methoxy]pyridine-3- 0.77 396 D carboxamide 2-chloro-N-cyclopropyl-5-[[1- P3 (trifluoromethylsulfonylamino) cyclopropyl]methoxy]pyridine-3- 1.49 414 B carboxamide 2-chloro-N-(1-cyanocyclopropyl)-5- P4 [[1-(trifluoromethylsulfonylamino) cyclopropyl]methoxy]pyridine-3- 1.5 449 B carboxamide methyl N-[1-[[6-chloro-5- P5 (cyclopropylcarbamoyl)-3- pyridyl]oxymethyl]cyclopropyl]-N- 8.68 472 G (trifluoromethylsulfonyl)carbamate N-(1-bicyclo[1.1.1]pentanyl)-2-chloro- P6 5-[[1-(trifluoromethylsulfonylamino) cyclopropyl]methoxy]pyridine-3- 1.43 440 E carboxamide 82875_FF 93 2-chloro-N-(1-cyanocyclobutyl)-5-[[1- (trifluoromethylsulfonylamino) P7 1.30 453 E cyclopropyl]methoxy]pyridine-3- carboxamide 2-chloro-N-(2,2,2-trifluoroethyl)-5-[[1- (trifluoromethylsulfonylamino) P8 1.34 456 E cyclopropyl]methoxy]pyridine-3- carboxamide 2-chloro-N-(2-methylcyclopropyl)-5- [[1-(trifluoromethylsulfonylamino) P9 1.33 428 E cyclopropyl]methoxy]pyridine-3- carboxamide 2-chloro-N-(2,4-difluorophenyl)-5-[[1- (trifluoromethylsulfonylamino) P10 1.52 486 E cyclopropyl]methoxy]pyridine-3- carboxamide 2-chloro-N-[3-oxo-2-(2,2,2- trifluoroethyl)isoxazolidin-4-yl]-5-[[1- P11 (trifluoromethylsulfonylamino) 1.34 541 E cyclopropyl]methoxy]pyridine-3- carboxamide 2-chloro-N-ethyl-5-[[1- (trifluoromethylsulfonylamino) P12 1.18 402 E cyclopropyl]methoxy]pyridine-3- carboxamide 2-chloro-N-(1-methylcyclopropyl)-5- [[1-(trifluoromethylsulfonylamino) P13 1.31 428 E cyclopropyl]methoxy]pyridine-3- carboxamide 2-chloro-N-cyclopropyl-N-methyl-5- [[1-(trifluoromethylsulfonylamino) P14 1.34 428 E cyclopropyl]methoxy]pyridine-3- carboxamide 82875_FF 94 N-tert-butyl-2-chloro-5-[[1- (trifluoromethylsulfonylamino) P15 3.60 430 F cyclopropyl]methoxy]pyridine-3- carboxamide 2-chloro-N-[1- (difluoromethyl)cyclopropyl]-5-[[1- P16 (trifluoromethylsulfonylamino) 1.33 464 E cyclopropyl]methoxy]pyridine-3- carboxamide 5-[[1-[acetyl(difluoromethylsulfonyl) amino]cyclopropyl]methoxy] P17 3.22 438 F -2-chloro-N-cyclopropyl-pyridine-3- carboxamide methyl N-[1-[[6-chloro-5- (cyclopropylcarbamoyl)-3- P18 3.24 454 F pyridyl]oxymethyl]cyclopropyl]-N- (difluoromethylsulfonyl)carbamate 2-chloro-N-cyclopropyl-5-[[1- [difluoromethylsulfonyl P19 (methoxymethyl)amino] 3.39 440 F cyclopropyl]methoxy]pyridine-3- carboxamide 2-chloro-N-cyclopropyl-5-[[1-[(1- fluorocyclopropyl)sulfonylamino] P20 2.61 404 F cyclopropyl]methoxy]pyridine-3- carboxamide 2-chloro-N-cyclopropyl-5-[[1- [methoxymethyl(trifluoromethyl P21 8.89 458 G sulfonyl)amino]cyclopropyl] ethoxy]pyridine-3-carboxamide 2-chloro-N-cyclopropyl-5-[2- [methoxymethyl(trifluoromethyl P22 9.17 460 G sulfonyl)amino]-2-methyl- propoxy]pyridine-3-carboxamide 82875_FF 95 2-chloro-N-cyclopropyl-5-[2-[(1- fluorocyclopropyl)sulfonylamino]-2- P23 2.84 406 F methyl-propoxy]pyridine-3- carboxamide 2-chloro-N-cyclopropyl-5-[2- (difluoromethylsulfonylamino)-2- P24 3.02 398 G methyl-propoxy]pyridine-3- carboxamide 2-chloro-N-cyclopropyl-5-[2-methyl-2- P25 (trifluoromethylsulfonylamino) 3.54 416 F propoxy]pyridine-3-carboxamide 2-chloro-N-cyclobutyl-5-[[1- (trifluoromethylsulfonylamino) P26 8.85 428 G cyclopropyl]methoxy]pyridine-3- carboxamide BIOLOGICAL EXAMPLES Example B1: Bemisia tabaci (Cotton white fly) Feeding / contact activityCotton leaf discs were placed on agar in 24-well microtiter plates and sprayed with aqueous test solutionsprepared from 10'000 ppm DMSO stock solutions. After drying the leaf discs were infested with adult white flies. The samples were checked for mortality 6 days after incubation. The following compounds resulted in at least 80% mortality at an application rate of 200 ppm: P3, P4, P5, P13 Example B2: Chilo suppressalis (Striped rice stemborer) 24-well microtiter plates with artificial diet were treated with aqueous test solutions prepared from 10'000 ppm DMSO stock solutions by pipetting. After drying, the plates were infested with L2 larvae (6-8 per well). The samples were assessed for mortality, anti-feeding effect, and growth inhibition in comparison to untreated samples 6 days after infestation. Control of Chilo suppressalis by a test sample is given when at least one of the categories mortality, anti-feedant effect, and growth inhibition is higher than the untreated sample. The following compounds resulted in at least 80% control at an application rate of 200 ppm: P3 Example B3: Diabrotica balteata (Corn root worm) Maize sprouts placed onto an agar layer in 24-well microtiter plates were treated with aqueous test solutions prepared from 10'000 ppm DMSO stock solutions by spraying. After drying, the plates were infested with L2 larvae (6 to 10 per well). The samples were assessed for mortality and growth inhibition in comparison to 82875_FF 96 untreated samples 4 days after infestation. The following compounds gave an effect of at least 80% in at least one of the two categories (mortality or growth inhibition) at an application rate of 200 ppm: P3, P22 Example B4: Euschistus heros (Neotropical Brown Stink Bug) Soybean leaves on agar in 24-well microtiter plates were sprayed with aqueous test solutions prepared from 10'000 ppm DMSO stock solutions. After drying the leaves were infested with N2 nymphs. The samples were assessed for mortality and growth inhibition in comparison to untreated samples 5 days after infestation. The following compounds gave an effect of at least 80% in at least one of the two categories (mortality or growth inhibition) at an application rate of 200 ppm: P3, P5, P13, P15 Example B5: Frankliniella occidentalis (Western flower thrips) Feeding / Contact activityBean leaf discs were placed on agar in 24-well microtiter plates and sprayed with aqueous test solutionsprepared from 10'000 DMSO stock solutions. After drying the leaf discs were infested with a Frankliniella population of mixed ages. The samples were assessed for mortality 4 days after infestation. The following compounds resulted in at least 80% growth inhibition at an application rate of 200 ppm: P8 Example B6: Myzus persicae (Green peach aphid) Feeding / Contact activity Sunflower leaf discs were placed onto agar in a 24-well microtiter plate and sprayed with aqueous test solutions prepared from 10'000 ppm DMSO stock solutions. After drying, the leaf discs were infested with an aphid population of mixed ages. The samples were assessed for mortality 6 days after infestation. The following compounds resulted in at least 80% mortality at an application rate of 200 ppm: P3, P4 Example B7: Myzus persicae (Green peach aphid) Intrinsic activity Test compounds prepared from 10'000 ppm DMSO stock solutions were applied by pipette into 24-well microtiter plates and mixed with nutrient solution. The plates were closed with a stretched Parafilm. A plastic stencil with 24 holes was placed onto the plate and infested pea seedlings were placed directly on the Parafilm. The infested plate was closed with a gel blotting paper and another plastic stencil and then turned upside down. The samples were assessed for mortality 5 days after infestation. The following compounds resulted in at least 80% mortality at a test rate of 50 ppm: P1, P2, P3, P4, P5, P6, P7, P9, P12, P13, P14, P18, P18, P19, P20, P21, P22, P23, P24, P25 Example B8: Myzus persicae (Green peach aphid) Feeding / Contact activity Eggplant leaf discs were placed onto agar in a 24-well microtiter plate and sprayed with aqueous test solutions prepared from 10'000 ppm DMSO stock solutions. After drying, the leaf discs were infested with an aphidpopulation of mixed ages. The samples were assessed for mortality 6 days after infestation. The followingcompounds resulted in at least 80% growth inhibition at an application rate of 200 ppm: P3, P5, P9, P13, P16, P21, P22, P25 Example B9: Plutella xylostella (Diamond back moth) 82875_FF 97 24-well microtiter plates with artificial diet were treated with aqueous test solutions prepared from 10'000 ppm DMSO stock solutions by pipetting. After drying, Plutella eggs were pipetted through a plastic stencil onto a gel blotting paper and the plate was closed with it. The samples were assessed for mortality and growth inhibition in comparison to untreated samples 8 days after infestation. The following compounds gave an effect of at least 80% in at least one of the two categories (mortality or growth inhibition) at an application rate of 200 ppm: P2, P3, P26, P28 Example B10: Spodoptera littoralis (Egyptian cotton leaf worm) Cotton leaf discs were placed onto agar in 24-well microtiter plates and sprayed with aqueous test solutions prepared from 10'000 ppm DMSO stock solutions. After drying the leaf discs were infested with five L1 larvae.The samples were assessed for mortality, anti-feeding effect, and growth inhibition in comparison to untreatedsamples 3 days after infestation. Control of Spodoptera littoralis by a test sample is given when at least one of the categories mortality, anti-feedant effect, and growth inhibition is higher than the untreated sample. The following compounds resulted in at least 80% control at an application rate of 200 ppm: P3, P26
Claims
82875_FF 98 CLAIMS 1. A compound of the formula (I) wherein:R1 is selected from C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, C3-C6- halocycloalkyl-C1-C4-alkyl, C1-C4-alkyl-C3-C6-cycloalkyl, cyano-C3-C6-cycloalkyl, cyano-C3-C6- cycloalkyl-C1-C4-alkyl, C4-C8-bicycloalkyl, 3-, 4-, 5- or 6-membered heterocycloalkyl, phenyl, 5- or 6- membered heteroaryl, phenyl-C1-C4-alkyl or 5- or 6-membered heteroaryl-C1-C3-alkyl, wherein said 3- , 4-, 5- or 6-membered heterocycloalkyl contains 1 or 2 heteroatoms individually selected from N, O, S, S=O or SO2, with the proviso that no more than one is O, S, S=O or SO2; and wherein any of said 5- or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N or O, and wherein said 3-, 4-, 5- or 6-membered heterocycloalkyl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C3-alkyl, C1-C3-haloalkyl or C3-C6- cycloalkyl, and wherein any of said phenyl, 5- or 6-membered heteroaryl, are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, or C1-C4alkoxy; R2is selected from hydrogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C1-C4-alkylcarbonyl, or C1-C4-alkoxycarbonyl; R3is selected from halogen, cyano, or C1-C3-alkyl; R4is selected from hydrogen, or C1-C3-alkyl; R5and R6are independently selected from C1-C3-alkyl; or R5and R6together with the carbon to which they are attached represent a C3-C5 cycloalkyl group; R7is selected from C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, phenyl, or 5- or 6-membered heteroaryl; wherein said C3-C6-cycloalkyl is unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C3-alkyl, or C1-C3-haloalkyl; and wherein any of said 5- or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N, S or O, with the proviso that no more than one is O or S; and wherein any of said phenyl, or said 5- or 6-membered heteroaryl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, or C1-C4-alkoxy; R8is selected from hydrogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C1-C4-alkylcarbonyl, or C1-C4-alkoxycarbonyl;82875_FF 99 or a salt or an N-oxide thereof.
2. The compound according to claim 1, wherein R2is hydrogen, and R3is chlorine.
3. The compound according to any of claims 1 or claim 2, wherein R4is hydrogen or methyl.
4. The compound according to any of claims 1 to 3, wherein R5and R6are methyl; or R5and R6together with the carbon to which they are attached represent a cyclopropyl group.
5. The compound according to claim 4, wherein R5and R6together with the carbon to which they are attached represent a cyclopropyl group.
6. The compound according to any of claims 1 to 5, wherein R7is dichloromethyl, difluoromethyl, trifluoromethyl, or cyclopropyl.
7. The compound according to any of claims 1 to 6, wherein R8 is hydrogen, C1-C3-alkyl, C1-C3-alkoxy-C1-C3-alkyl, C1-C2-alkylcarbonyl, or C1-C2-alkoxycarbonyl.
8. The compound according to any of claims 1 to 7, wherein R8is hydrogen, methyl, acetyl, methylformate, or methoxymethyl.
9. The compound according to any of claims 1 to 8, wherein R1is selected from C1-C4-alkyl, C3-C6- cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C3-C6-halocycloalkyl, C3-C6- cycloalkyl-C1-C4-alkyl, C3-C6-halocycloalkyl-C1-C4-alkyl, cyano-C3-C6-cycloalkyl, cyano-C3-C6- cycloalkyl-C1-C4-alkyl, C4-C8-bicycloalkyl, 5- or 6-membered heteroaryl, or phenyl-C1-C4-alkyl, wherein said 5- or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N or O, and wherein said 5- or 6-membered heteroaryl or phenyl-C1-C4-alkyl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl or C1- C4alkoxy.
10. The compound according to claim 9, wherein R1is selected from C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4- haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, cyano-C3-C6- cycloalkyl, C4-C8-bicycloalkyl, phenyl-C1-C2-alkyl, or 5- or 6-membered heteroaryl, wherein said 5- or 6-membered heteroaryl contains 1 heteroatom selected from N or O, and wherein said phenyl-C1-C2- alkyl or 5- or 6-membered heteroaryl are unsubstituted or substituted by 1, or 2 substituents independently selected from halogen, and C1-C4 alkyl.
11. A composition comprising a compound as defined in any one of claims 1 to 10.82875_FF 100 12. The composition according to claim 11, further comprising at least one additional active ingredient and / or an agrochemically-acceptable diluent or carrier.
13. A method of combating and controlling insects, acarines or molluscs which comprises applying to a pest, to a locus of a pest, or to a plant susceptible to attack by a pest an insecticidally, acaricidally, or molluscicidally effective amount of a compound of formula (I) as defined in any one of claims 1 to 10 or a composition as defined in claim 11 or 12.
14. A method for the protection of plant propagation material from the attack by insects, acarines, or molluscs, which comprises treating the propagation material or the site, where the propagation material is planted, with an effective amount of a compound of formula (I) as defined in any one of claims 1 to 10 or a composition as defined in claim 11 or 12.
15. A plant propagation material, such as a seed, comprising, or treated with or adhered thereto, a compound of formula (I) as defined in any one of claims 1 to 10.
Citation Information
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