Preparation method for multiphase material

The multiphase materials are prepared by aerosolization. Taking advantage of the different melting points and insoluble materials, the low-melting point materials are melted into liquid in the smelting device to maintain the original morphology of the high-melting point materials, which solves the problems of complex and high cost of preparation of multiphase materials in the prior art, and achieves mass production.

WO2025156553A1PCT designated stage Publication Date: 2025-07-31GUANGDONG UNIV OF TECH
View PDF 6 Cites 0 Cited by

Patent Information

Application Number
PCT/CN2024/100113
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2024-01-24
Filing Date
2024-06-19
Publication Date
2025-07-31

AI Technical Summary

Technical Problem

The existing multiphase material preparation methods are complex and costly, and large-scale production cannot be achieved.

Method used

Aerosolization method is used to prepare multiphase materials, melt the low-melting point material into liquid through a smelting device, maintain the original morphology of the high-melting point material, and prepare multiphase materials by atomization method, and simplify the preparation process and achieve large-scale production using the characteristics of different melting points of the materials and insoluble in the materials.

Benefits of technology

The preparation process is simplified, time and labor costs are reduced, and the scope of application is wide, so as to achieve large-scale production of multiphase materials.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN2024100113_31072025_PF_FP_ABST
    Figure CN2024100113_31072025_PF_FP_ABST
Patent Text Reader

Abstract

A preparation method for a multiphase material, comprising: providing a first material (1), a second material (2) and / or a third material (3); loading the first material (1), the second material (2) and / or the third material (3) into a smelting apparatus (4) according to a preset ratio, and heating the first material (1), the second material (2) and / or the third material (3) by means of the smelting apparatus (4), so as to cause the first material (1) to change from a solid state to a liquid state, while the second material (2) and / or the third material (3) remain in the same state; sequentially mixing, stirring and ultrasonically treating the liquid first material (1), the second material (2) and / or the third material (3) in the smelting apparatus (4) by means of an ultrasonic stirrer (5), so as to cause the second material (2) and / or the third material (3) to be uniformly distributed in the liquid first material (1), to form a mixed liquid; atomizing and cooling the mixed liquid by means of an atomizing apparatus (6), to prepare a multiphase material in which the first material (1) encapsulates the second material (2) and / or the third material (3). The preparation method for a multiphase material has a simple process, and can achieve mass production.
Need to check novelty before this filing date? Find Prior Art

Description

A method for preparing multiphase material

[0001] CROSS-REFERENCE TO RELATED APPLICATIONS

[0002] This application claims priority to Chinese patent application number 202410105475.0, filed with the Patent Office of China on January 24, 2024, entitled "A Method for Preparing Multiphase Materials," the entire contents of which are incorporated herein by reference. Technical Field

[0003] The present invention relates to the field of polymer technology, and in particular to a method for preparing a multiphase material. Background Art

[0004] Multiphase materials refer to materials with different properties that are "compounded" together to form a material. Due to their different properties, the material has phase interfaces, mainly solid-solid, solid-liquid, liquid-liquid, gas-solid, and gas-liquid phase interfaces. The various materials complement each other in terms of performance, producing a synergistic effect, which optimizes the comprehensive performance of the material to meet various different usage requirements. Multiphase composite materials are composed of a continuous phase matrix and a phase reinforcement enclosed by the matrix. Compared with traditional single-material structures, multiphase material structures can give full play to the performance advantages of each material, such as corrosion resistance, wear resistance, and light weight, and are widely used in various fields.

[0005] However, existing multiphase materials are prepared through indirect methods. These methods rely on forming a secondary interface within a base material through multiple solid-phase, solution, or evaporation synthesis processes, resulting in a large specific surface area, enhanced thermal stability, and a typical multiphase structure with a high degree of density distribution. However, this method requires complex control of conditions, high base material costs, and high requirements for material preparation technology. Furthermore, the complex preparation process precludes mass production.

[0006] Therefore, there is an urgent need to provide a method for preparing multiphase materials to address the shortcomings of the existing technology.

[0007] Summary of the Invention

[0008] The purpose of the present invention is to provide a method for preparing a multiphase material in order to address the technical deficiencies in the prior art.

[0009] In order to achieve the purpose of the present invention, the technical solution adopted is:

[0010] The present invention provides a method for preparing a multiphase material, comprising:

[0011] S1, providing a first material, a second material, and / or a third material, wherein the first material, the second material, and / or the third material have different melting points and are mutually immiscible; the second material and / or the third material have a higher melting point than the first material; and the second material and / or the third material are in the form of powder, sheet, or wire.

[0012] S2, loading the first material, the second material, and / or the third material into a smelting device according to a preset ratio, and heating the first material, the second material, and / or the third material by the smelting device so that the first material changes from a solid state to a liquid state, while the second material and / or the third material remain in their original state;

[0013] S3, sequentially mixing, stirring, and ultrasonically treating the first material, the second material, and / or the third material in the liquid state in the smelting device using an ultrasonic stirrer, so that the second material and / or the third material are uniformly distributed in the liquid state of the first material to form a mixed liquid;

[0014] S4, atomizing and cooling the mixed liquid by an atomizing device to prepare a multiphase material in which the first material covers the second material and / or the third material.

[0015] The present invention provides a method for preparing a multiphase material, comprising:

[0016] S1a, providing a first material, a second material, and / or a third material, wherein the first material, the second material, and / or the third material have different melting points and are mutually immiscible; the second material and / or the third material have a higher melting point than the first material; and the second material and / or the third material are in the form of powder, flake, or wire;

[0017] S2a, loading the first material into a smelting device, and heating the first material by the smelting device to change the first material from a solid state to a liquid state;

[0018] S3a, controlling the first material in liquid form to flow out from the slit at the bottom of the smelting device to form a liquid metal column or a liquid metal film;

[0019] S4a, controlling the second material and / or the third material to be injected into and pass through the liquid metal column or the liquid metal film in a vertical direction through a high-pressure nozzle, cooling and collecting the second material and / or the third material and the liquid metal column or the liquid metal film ejected from the high-pressure nozzle, and obtaining a multiphase material in which the second material and / or the third material are coated by the first material.

[0020] The present invention provides a method for preparing a multiphase material, comprising:

[0021] S1b, providing a first material, a second material, and / or a third material, wherein the first material, the second material, and / or the third material have different melting points and are mutually insoluble; the second material and / or the third material have a higher melting point than the first material; the second material and / or the third material are in the form of powder, sheet, or wire, and are magnetic; the first material is non-magnetic;

[0022] S2b, loading the first material into a smelting device, and heating the first material by the smelting device to change the first material from a solid state to a liquid state;

[0023] S3b, controlling the first material in liquid form to flow out from the slit at the bottom of the smelting device to form a liquid metal column or a liquid metal film;

[0024] S4b, placing the second material and / or the third material on one side of the liquid metal column or the liquid metal film, applying a magnetic field to the second material and / or the third material to control the second material and / or the third material to move and pass through the liquid metal column or the liquid metal film; cooling and collecting the liquid metal column or the liquid metal film and the second material and / or the third material passing through the liquid metal column or the liquid metal film to obtain a multiphase material in which the second material and / or the third material are coated by the first material.

[0025] The present invention provides a method for preparing a multiphase material, comprising:

[0026] S1d, providing a first material, a second material, and / or a third material, wherein the first material, the second material, and / or the third material have different melting points and are mutually immiscible; the second material and / or the third material have a higher melting point than the first material; and the second material and / or the third material are in the form of powder, flake, or wire;

[0027] S2d, loading the first material into a smelting device, and heating the first material by the smelting device to change the first material from a solid state to a liquid state;

[0028] S3d, controlling the second material and / or the third material to be sprayed toward the liquid surface of the first liquid material at a specific angle through a high-pressure nozzle;

[0029] S4d, the second material and / or the third material are bounced off after contacting the liquid surface of the first liquid material, and the bounced second material and / or the third material are collected so that the surface of the first material contains the second material and / or the third material to form a multi-phase material.

[0030] Preferably, in S4d, the angle α between the injection speed direction of the second material and / or the third material toward the liquid surface of the first material in liquid state and the liquid surface of the first material is between 5° and 35°.

[0031] Preferably, the angle β between the plane of the second material and / or the third material and the liquid surface of the first material is 45°-α.

[0032] Preferably, the smelting device contains inert protective gas and / or reducing gas.

[0033] Preferably, the first material, the second material and / or the third material are selected from metal materials or graphene materials.

[0034] Preferably, the metal material is any one of gold, silver, copper, iron, aluminum, zinc and titanium; the graphene material is any one of original graphene material, graphene material treated with hydrogen ions and graphene material treated with oxygen ions.

[0035] Compared with the related art, the present invention provides a method for preparing a multiphase material, comprising: S1, providing a first material, a second material and / or a third material, wherein the first material, the second material and / or the third material have different melting points and are mutually insoluble; the melting point of the second material and / or the third material is higher than that of the first material; the second material and / or the third material are in the form of powder, sheet or wire; S2, charging the first material, the second material and / or the third material into a smelting device according to a preset ratio, and heating the first material, the second material and / or the third material by the smelting device to change the first material from a solid state to a liquid state, The second material and / or the third material remain in their original state; S3, the first material, the second material and / or the third material in the smelting device are sequentially mixed, stirred and ultrasonically treated so that the second material and / or the third material are evenly distributed in the first material in the liquid state to form a mixed liquid; S4, the mixed liquid is atomized and cooled by an atomizing device to form a multiphase material in which the first material covers the second material and / or the third material. The multiphase material is prepared by a gas atomization method or by driving a high-melting-point metal powder through a low-melting-point metal film / column under the action of a high-pressure nozzle / high-magnetic magnet to form a two-phase composite material, or by using the skipping stone principle to prepare a two-phase composite material. The present invention is a multiphase material prepared by a gas atomization method, which utilizes the characteristics of different melting points and incompatibility of the materials, melts the low-melting-point material into a liquid at the temperature in the smelting device provided, while maintaining the original morphology of the high-melting-point material, and prepares the multiphase material by atomization. The preparation process is simple, can be mass-produced, has a wide range of applications, and greatly reduces time and labor costs. BRIEF DESCRIPTION OF THE DRAWINGS

[0036] The present invention will be described in detail below with reference to the accompanying drawings. The above and other aspects of the present invention will become clearer and easier to understand through the detailed description made with reference to the following drawings. In the accompanying drawings:

[0037] FIG1 is a schematic flow chart of a method for preparing a multiphase material according to Example 1 of the present invention;

[0038] FIG2 is a schematic structural flow diagram of a method for preparing a multiphase material according to Example 1 of the present invention;

[0039] FIG3 is a schematic structural flow diagram of a method for preparing a multiphase material according to another embodiment of Example 1 of the present invention;

[0040] FIG4 is a schematic flow chart of a method for preparing a multiphase material according to Example 2 of the present invention;

[0041] FIG5 is a schematic structural flow diagram of a method for preparing a multiphase material according to Example 2 of the present invention;

[0042] FIG6 is a schematic flow chart of a method for preparing a multiphase material according to Example 3 of the present invention;

[0043] FIG7 is a schematic structural flow diagram of a method for preparing a multiphase material according to Example 3 of the present invention;

[0044] FIG8 is a schematic flow chart of a method for preparing a multiphase material according to Example 4 of the present invention;

[0045] FIG9 is a schematic structural flow diagram of a method for preparing a multiphase material according to Example 4 of the present invention. DETAILED DESCRIPTION

[0046] The specific embodiments and examples described herein are specific embodiments of the present invention and are intended to illustrate the concepts of the present invention. They are illustrative and exemplary only and should not be construed as limiting the embodiments and scope of the present invention. In addition to the examples described herein, those skilled in the art may also employ other obvious technical solutions based on the claims and disclosure of this application. Such solutions, including any obvious substitutions and modifications of the embodiments described herein, are within the scope of protection of the present invention.

[0047] Example 1

[0048] 1-3 , the present invention provides a method for preparing a multiphase material, characterized in that the preparation method comprises:

[0049] S1, providing a first material 1, a second material 2, and / or a third material 3, wherein the first material 1, the second material 2, and / or the third material 3 have different melting points and are mutually insoluble; the melting point of the second material 2 and / or the third material 3 is higher than the melting point of the first material 1; and the second material 2 and / or the third material 3 are in the form of powder, sheet, or wire.

[0050] S2, loading the first material 1, the second material 2 and / or the third material 3 into a smelting device 4 according to a preset ratio, and heating the first material 1, the second material 2 and / or the third material 3 by the smelting device 4, so that the first material 1 changes from a solid state to a liquid state, while the second material 2 and / or the third material 3 remain in their original state; wherein the target temperature of the smelting device 4 is set to a temperature range between the melting point of the first material 1 and the melting point of the second material 2.

[0051] S3, sequentially mixing, stirring, and ultrasonically treating the first material 1, the second material 2, and / or the third material 3 in the liquid state in the smelting device 1 using an ultrasonic stirrer 5, so that the second material 2 and / or the third material 3 are evenly distributed in the liquid state of the first material 1 to form a mixed liquid;

[0052] S4, atomizing and cooling the mixed liquid by an atomizing device 6 to prepare a multiphase material 7 in which the first material 1 covers the second material 2 and / or the third material 3.

[0053] To further illustrate this embodiment 1, the following specific examples are provided for illustration:

[0054] As shown in Figure 2, when preparing a dual-phase material, only a first material 1 and a second material 2 are required. For example, the first material 1 is 200 grams of silver, and the second material 2 is spherical copper powder with a particle size of 1 micron. The specific process is as follows: 200 grams of silver and 1 micron spherical copper powder are loaded into a smelting device 4. The target temperature of the smelting device 4 is set to 1040°C, and argon gas is introduced to heat the 200 grams of silver and 1 micron spherical copper powder in the smelting device 4, causing the 200 grams of silver to transform from a solid state to a liquid state. An ultrasonic agitator 5 is used to sequentially mix, stir, and ultrasonically treat the liquid silver and 1 micron spherical copper powder in the smelting device 4, so that the spherical copper powder is evenly distributed in the silver liquid to form a mixed liquid. The mixed liquid is then atomized and cooled by an atomizing device 6, thereby producing a silver-coated copper dual-phase composite material 71. The ultrasonic agitator 5 has an ultrasonic power of 400W, a stirring speed of 500 rpm, and an ultrasonic treatment time of 30 minutes.

[0055] As shown in Figure 3, when a three-phase material needs to be prepared, a first material 1, a second material 2 and a third material 3 are provided. For example, the first material 1 is 100 grams of silver, the second material 2 is copper powder with a particle size of 2 microns, and the third material 3 is 10 grams of graphene with a flake diameter of 10 microns. The specific process is as follows: 100 grams of silver, 2-micron copper powder and 10 grams of graphene with a flake diameter of 10 microns are loaded into a smelting device 4; the target temperature of the smelting device 4 is set to 1050°C, and nitrogen is introduced to heat the 100 grams of silver, 2-micron copper powder and 10 grams of graphene with a flake diameter of 10 microns loaded into the smelting device 4, so that the 100 grams of silver changes from solid to liquid, and the 2-micron copper powder and 10 grams of graphene with a flake diameter of 10 microns remain in their original state. The liquid silver, 2-micron copper powder, and 10 g of graphene flakes with a diameter of 10 μm in the smelting device 4 are sequentially mixed, stirred, and ultrasonically treated by an ultrasonic stirrer 5, so that the 2-micron copper powder and the 10 g of graphene flakes with a diameter of 10 μm are evenly distributed in the silver liquid to form a mixed liquid. The mixed liquid is atomized and cooled by an atomizing device 6 to obtain a three-phase composite material 72 of silver-coated copper and graphene.

[0056] Example 2

[0057] 4-5 , the present invention provides a method for preparing a multiphase material, comprising:

[0058] S1a, providing a first material 1a, a second material 2a, and / or a third material 3a, wherein the first material 1a, the second material 2a, and / or the third material 3a have different melting points and are mutually insoluble; the melting point of the second material 2a and / or the third material 3a is higher than the melting point of the first material 1a; and the second material 2a and / or the third material 3a are in the form of powder, flake, or wire.

[0059] S2a, loading the first material 1a into a smelting device 4a, and heating the first material 1a by the smelting device 4a to change the first material 1a from a solid state to a liquid state;

[0060] S3a, controlling the first material 1a in liquid form to flow out from the slit 8a at the bottom of the smelting device 4a to form a liquid metal column or liquid metal film;

[0061] S4a, controlling the second material 2a and / or the third material 3a to be injected into and pass through the liquid metal column or the liquid metal film in a vertical direction through the high-pressure nozzle 9a, cooling and collecting the second material 2a and / or the third material 3a and the liquid metal column or the liquid metal film ejected from the high-pressure nozzle 9a, and obtaining a multiphase material 7a in which the second material 2a and / or the third material 3a are coated by the first material 1a.

[0062] To further illustrate this embodiment 2, the following specific examples are provided for illustration:

[0063] As shown in FIG5 , when a dual-phase material is to be prepared, a first material 1a and a second material 2a are provided. For example, the first material 1a is 150 grams of copper, and the second material 2a is 100 grams of iron with a particle size of 10 microns. The specific process is as follows: 150 grams of copper is loaded into a smelting device 4a. The target temperature of the smelting device is set to 1200° C. Argon gas is introduced, and the 150 grams of copper loaded into the smelting device 4a is heated to convert the 150 grams of copper from a solid state to a liquid state. The molten liquid copper is controlled to flow out through the slit 8a to form a liquid metal copper film. 100 grams of iron with a particle size of 10 microns is controlled to be vertically injected into and pass through the liquid metal copper film through a high-pressure nozzle 9a. The 100 grams of iron with a particle size of 10 microns and the liquid metal copper film ejected from the high-pressure nozzle 9a are cooled and collected, thereby obtaining a copper-coated iron dual-phase composite material.

[0064] Example 3

[0065] 6-7 , the present invention provides a method for preparing a multiphase material, comprising:

[0066] S1b, providing a first material 1b, a second material 2b, and / or a third material 3b, wherein the first material 1b, the second material 2b, and / or the third material 3b have different melting points and are mutually insoluble; the melting point of the second material 2b and / or the third material 3b is higher than the melting point of the first material 1b; the second material 2b and / or the third material 3b are in the form of powder, sheet, or wire, and are magnetic; the first material 1b is non-magnetic;

[0067] S2b, loading the first material 1b into a smelting device 4b, and heating the first material 1b by the smelting device 4b to change the first material 1b from a solid state to a liquid state;

[0068] S3b, controlling the first material 1b in liquid form to flow out from the slit 8b at the bottom of the smelting device 4b to form a liquid metal column or liquid metal film;

[0069] S4b, placing the second material 2b and / or the third material 3b on one side of the liquid metal column or the liquid metal film, applying a magnetic field to the second material 2b and / or the third material 3b to control the second material 2b and / or the third material 3b to move and pass through the liquid metal column or the liquid metal film; cooling and collecting the liquid metal column or the liquid metal film and the second material 2b and / or the third material 3b passing through the liquid metal column or the liquid metal film to obtain a multiphase material 7b in which the second material 2b and / or the third material 3b are coated by the first material 1b.

[0070] To further illustrate this embodiment 3, the following specific examples are provided for illustration:

[0071] As shown in FIG4 , when a dual-phase material is to be prepared, a first material 1b and a second material 2b are provided. For example, the first material 1b is 200 grams of aluminum, and the second material 2b is 100 grams of spherical iron powder with a particle size of 5 microns. The specific process is as follows: 200 grams of aluminum are loaded into a smelting device 4b. The target temperature of the smelting device 4b is set to 700°C, and argon gas is introduced to heat the 200 grams of aluminum loaded into the smelting device 4b, so that the 200 grams of aluminum changes from solid to liquid. The molten liquid aluminum is controlled to flow out through the slit 8b to form a liquid metal aluminum film; 100 grams of spherical iron powder with a particle size of 5 microns is placed on the left side of the liquid metal aluminum film, and a magnetic field is applied to make the 100 grams of spherical iron powder with a particle size of 5 microns move to the right side of the liquid metal aluminum film and pass through the liquid metal aluminum film, and then the liquid metal aluminum film and the 100 grams of spherical iron powder with a particle size of 5 microns that pass through the liquid metal aluminum film are cooled and collected to obtain an aluminum-coated iron dual-phase composite material.

[0072] Example 4

[0073] 8-9 , the present invention provides a method for preparing a multiphase material, comprising:

[0074] S1d, providing a first material 1d, a second material 2d, and / or a third material 3d, wherein the first material 1d, the second material 2d, and / or the third material 3d have different melting points and are mutually insoluble; the melting point of the second material 2d and / or the third material 3d is higher than the melting point of the first material 1d; and the second material 2d and / or the third material 3d are in the form of powder, flake, or wire.

[0075] S2d, loading the first material 1d into a smelting device 4d, and heating the first material 1d by the smelting device 4d to change the first material 1d from a solid state to a liquid state;

[0076] S3d, controlling the second material 2d and / or the third material 3d to be sprayed toward the liquid surface of the liquid first material 1d at a specific angle through the high-pressure nozzle 8d;

[0077] S4d, the second material 2d and / or the third material 3d are bounced off after contacting the liquid surface of the first liquid material 1d, and the bounced second material 2d and / or the third material 3d are collected so that the surface of the first material 1d contains the second material 2d and / or the third material 3d to form a multi-phase material 7d.

[0078] Specifically, in S4d, the angle α between the injection velocity direction of the second material 2d and / or the third material 3d toward the liquid surface of the first material 1d and the liquid surface of the first material 1d is between 5° and 35°. The angle β between the plane of the second material 2d and / or the third material 3d and the liquid surface of the first material 1d is 45°-α.

[0079] To further illustrate this embodiment 4, the following specific examples are provided for illustration:

[0080] As shown in FIG8 , when a dual-phase material is to be prepared, a first material 1b and a second material 2b are provided. For example, the first material 1b is 200 grams of aluminum, and the second material 2b is 100 grams of flaky iron powder with a flake diameter of 50 microns and a thickness of 5 microns. The specific process is as follows: 200 grams of aluminum are placed in a smelting device 4d and heated to convert the 200 grams of aluminum from a solid state into a liquid state. 100 grams of flaky iron powder with a flake diameter of 50 microns and a thickness of 5 microns are ejected at a speed of 10 m / s toward the surface of the liquid aluminum. The angle between the velocity direction and the liquid aluminum surface is 20°, and the angle between the flaky iron powder and the liquid aluminum surface is 25°. The flaky iron powder bounces off upon contact with the liquid aluminum surface, and the ejected flaky iron powder is collected to obtain a dual-phase composite material containing aluminum on one side.

[0081] It should be noted that the smelting apparatus described in the above embodiments contains an inert protective gas and / or a reducing gas; the first material, the second material, and / or the third material are selected from metal materials or graphene materials. The metal material is any one of gold, silver, copper, iron, aluminum, zinc, and titanium; and the graphene material is any one of pristine graphene material, graphene material treated with hydrogen ions, and graphene material treated with oxygen ions.

[0082] Compared with the related art, the present invention provides a method for preparing a multiphase material, comprising: S1, providing a first material, a second material and / or a third material, wherein the first material, the second material and / or the third material have different melting points and are mutually insoluble; the melting point of the second material and / or the third material is higher than that of the first material; the second material and / or the third material are in the form of powder, sheet or wire; S2, charging the first material, the second material and / or the third material into a smelting device according to a preset ratio, and heating the first material, the second material and / or the third material by the smelting device to change the first material from a solid state to a liquid state, The second material and / or the third material remain in their original state; S3, the first material, the second material and / or the third material in the smelting device are sequentially mixed, stirred and ultrasonically treated so that the second material and / or the third material are evenly distributed in the first material in the liquid state to form a mixed liquid; S4, the mixed liquid is atomized and cooled by an atomizing device to form a multiphase material in which the first material covers the second material and / or the third material. The multiphase material is prepared by a gas atomization method or by driving a high-melting-point metal powder through a low-melting-point metal film / column under the action of a high-pressure nozzle / high-magnetic magnet to form a two-phase composite material, or by using the skipping stone principle to prepare a two-phase composite material. The present invention is a multiphase material prepared by a gas atomization method, which utilizes the characteristics of different melting points and incompatibility of the materials, melts the low-melting-point material into a liquid at the temperature in the smelting device provided, while maintaining the original morphology of the high-melting-point material, and prepares the multiphase material by atomization. The preparation process is simple, can be mass-produced, has a wide range of applications, and greatly reduces time and labor costs.

[0083] The foregoing description is merely a preferred embodiment of the present invention and is not intended to limit the present invention. Those skilled in the art will readily appreciate that the present invention is susceptible to various modifications and variations. Any modifications, equivalent substitutions, or improvements made within the spirit and principles of the present invention shall be encompassed within the scope of the claims.

Claims

1. A method for preparing a multiphase material, characterized in that, The preparation method includes: S1, providing a first material, a second material, and / or a third material, wherein the melting points of the first material, the second material, and / or the third material are different and mutually insoluble; the melting points of the second material and / or the third material are higher than the melting point of the first material; the second material and / or the third material are in the form of powder, sheet, or wire; S2, loading the first material, the second material, and / or the third material into a melting device according to a preset ratio, and heating the first material, the second material, and / or the third material through the melting device to change the first material from a solid state to a liquid state, while the second material and / or the third material remain in their original state; S3, successively performing mixing, stirring, and ultrasonic treatment on the first material, the second material, and / or the third material in a liquid state in the melting device through an ultrasonic stirrer, so that the second material and / or the third material are uniformly distributed in the first material in a liquid state to form a mixed liquid; S4, atomizing and cooling the mixed liquid through an atomizing device to produce a multiphase material in which the first material coats the second material and / or the third material.

2. A method for preparing a multiphase material, characterized in that, The preparation method includes: S1a, providing a first material, a second material, and / or a third material, wherein the melting points of the first material, the second material, and / or the third material are different and mutually insoluble; the melting points of the second material and / or the third material are higher than the melting point of the first material; the second material and / or the third material are in the form of powder, sheet, or wire; S2a, loading the first material into a melting device and heating the first material through the melting device to change the first material from a solid state to a liquid state; S3a, controlling the first material in a liquid state to flow out from the slit opening at the bottom of the melting device to form a liquid metal column or a liquid metal film; S4a, controlling the second material and / or the third material to be injected vertically and pass through the liquid metal column or the liquid metal film through a high-pressure nozzle, and cooling and collecting the second material and / or the third material ejected from the high-pressure nozzle and the liquid metal column or the liquid metal film, to obtain a multiphase material in which the first material coats the second material and / or the third material.

3. A method for preparing a multiphase material, characterized in that, The preparation method specifically includes: S1b, providing a first material, a second material, and / or a third material, wherein the melting points of the first material, the second material, and / or the third material are different and mutually insoluble; the melting points of the second material and / or the third material are higher than the melting point of the first material; the second material and / or the third material are in the form of powder, sheet, or wire, and the second material and / or the third material have magnetism; the first material has no magnetism; S2b, loading the first material into a melting device and heating the first material through the melting device to change the first material from a solid state to a liquid state; S3b. Control the first material in a liquid state to flow out from the slit opening at the bottom of the smelting device to form a liquid metal column or a liquid metal film. S4b. Place the second material and / or the third material on one side of the liquid metal column or the liquid metal film, and apply a magnetic field to the second material and / or the third material to control the movement of the second material and / or the third material and make it pass through the liquid metal column or the liquid metal film. Cool and collect the liquid metal column or the liquid metal film and the second material and / or the third material passing through the liquid metal column or the liquid metal film to obtain a multiphase material in which the first material coats the second material and / or the third material.

4. A method for preparing a multiphase material, characterized in that, The preparation method specifically includes: S1d. Provide a first material, a second material, and / or a third material, and the melting points of the first material, the second material, and / or the third material are different and mutually insoluble; the melting points of the second material and / or the third material are higher than the melting point of the first material; the shape of the second material and / or the third material is powdery, flaky, or linear. S2d. Load the first material into a smelting device, and heat the first material through the smelting device to make the first material change from a solid state to a liquid state. S3d. Control the second material and / or the third material to be sprayed onto the liquid surface of the first material in a liquid state at a specific angle through a high-pressure nozzle. S4d. The second material and / or the third material is bounced off after contacting the liquid surface of the first material in a liquid state, and the bounced-off second material and / or the third material are collected, so that the surface of the first material contains the second material and / or the third material to form a multiphase material.

5. The preparation method of a multiphase material according to claim 4, characterized in that, In S4d, the angle α between the spraying speed direction of the second material and / or the third material towards the liquid surface of the first material in a liquid state and the liquid surface of the first material is between 5° and 35°.

6. The preparation method of a multiphase material according to claim 5, wherein, The angle β between the plane of the second material and / or the third material and the liquid surface of the first material = 45° - α.

7. A method for preparing a multiphase material according to any one of claims 1 to 4, characterized in that, The smelting device is provided with an inert protective gas and / or a reducing gas.

8. A method for preparing a multiphase material according to any one of claims 1 to 4, characterized in that, The first material, the second material, and / or the third material are selected from metal materials or graphene materials.

9. A method for preparing a multiphase material according to claim 8, characterized in that, The metal material is any one of gold, silver, copper, iron, aluminum, zinc, and titanium; the graphene material is any one of an original graphene material, a graphene material treated by a hydrogen plasma, and a graphene material treated by an oxygen plasma.

Citation Information

Patent Citations

  • 3D printing composite material with SEBS wrapping metal tungsten and preparation method thereof

    CN109014174A

  • Core-shell structure powder preparation device and method

    CN111872378A

  • Water atomization preparation method of iron-based composite powder

    CN112846203A

  • Powder surface modification equipment and modification method

    CN115740472A

  • Preparation method of multiphase material

    CN117961072A