GH4151 alloy bar and preparation method therefor and use thereof

Abstract

The present application relates to the field of metal material manufacturing, and in particular to a GH4151 alloy bar and a preparation method therefor and a use thereof. The method comprises the following steps: (1) carrying out homogenization heat treatment on a GH4151 alloy cast ingot to obtain a heat treated bar; (2) forging the heat treated bar to obtain a forged bar; (3) carrying out hot rolling treatment on the forged bar to obtain a hot rolled bar; (4) carrying out solution treatment on the hot rolled bar to obtain a solid solution bar; (5) carrying out cold drawing treatment on the solid solution bar to obtain a cold drawn bar; and (6) carrying out aging treatment on the cold drawn bar to obtain a GH4151 alloy bar. According to the GH4151 alloy bar prepared in the present application, grains can be effectively refined, the surface dimensional precision is improved, and the tensile strength of the prepared GH4151 alloy bar is improved, so that the GH4151 alloy bar has excellent mechanical properties.

Description

GH4151 alloy bar and its preparation method and application Technical Field

[0001] The present invention relates to the field of metal material manufacturing, and specifically relates to a GH4151 alloy bar and its preparation method and application. Background Art

[0002] GH4151 alloy is a newly developed, difficult-to-deform nickel-based high-temperature alloy. With a service temperature of up to 800°C, GH4151 alloy can be used in various fasteners for aircraft engines and ground-based gas turbines. Currently, only patents exist for the smelting and forging of large-scale GH4151 alloy bars for forgings. Patents are lacking regarding the composition, processing, and performance of small-scale GH4151 alloy bars (diameters Φ5-Φ40mm) for fasteners.

[0003] Existing methods for producing small-sized GH4151 fastener bars often involve homogenization, annealing, and post-forging heat treatment. However, the resulting grain size and mechanical properties of these small-sized GH4151 alloy bars do not meet the requirements of practical applications. Therefore, a method is needed to effectively homogenize the grain size and improve the mechanical properties of small-sized GH4151 alloy bars (diameters Φ5-Φ40 mm). Summary of the Invention

[0004] The purpose of this application is to overcome the problems in the prior art that the grain size and mechanical properties of small-sized GH4151 bars at high service temperatures cannot meet the requirements, and to provide a GH4151 alloy bar and its preparation method and application. The prepared GH4151 alloy bar has uniform fine grain structure, high tensile strength and excellent mechanical properties.

[0005] In order to achieve the above-mentioned object, the first aspect of the present application provides a method for preparing a GH4151 alloy bar, wherein the method comprises the following steps:

[0006] (1) homogenizing heat treatment of GH4151 alloy ingot to obtain heat-treated rods;

[0007] (2) forging the heat-treated bar to obtain a forged bar;

[0008] (3) hot rolling the forged bar to obtain a hot-rolled bar;

[0009] (4) subjecting the hot-rolled bar to a solid solution treatment to obtain a solid solution bar;

[0010] (5) cold drawing the solid solution rod to obtain a cold drawn rod;

[0011] (6) The cold drawn bar is subjected to aging treatment to obtain a GH4151 alloy bar.

[0012] Preferably, the temperature of the hot rolling treatment is 1100-1200°C, preferably 1130-1180°C.

[0013] Preferably, the hot rolling deformation is 20-50%, preferably 30-40%.

[0014] Preferably, the cold drawing treatment is performed under the following conditions: the solid solution rod is cold drawn at a drawing speed of 5-20 mm / s, preferably 10-15 mm / s.

[0015] Preferably, the cold drawing deformation is 10-50%, preferably 20-40%.

[0016] The second aspect of the present application provides a GH4151 alloy bar obtained by the preparation method described in the first aspect;

[0017] Preferably, the GH4151 alloy bar has a grain size of not less than grade 8, a room temperature tensile strength higher than 1810 MPa, a 800°C tensile strength higher than 1020 MPa, and an 800°C / 500 MPa endurance life greater than 28 hours.

[0018] The third aspect of the present application provides the use of the GH4151 alloy rod described in the second aspect in fasteners for aircraft engines and / or ground gas turbines.

[0019] Through the above technical solution, the beneficial effects achieved by this application are as follows:

[0020] The GH4151 alloy rods produced in this application can effectively refine the grains, improve the surface dimensional accuracy, and improve the tensile strength of the produced GH4151 alloy rods through special processing methods, so that they have excellent mechanical properties and can meet the production and development needs of fasteners for aircraft engines and ground gas turbines. BRIEF DESCRIPTION OF THE DRAWINGS

[0021] FIG1 is a high-magnification metallographic photograph of the GH4151 alloy rod prepared in Example 1 of the present application. DETAILED DESCRIPTION

[0022] The endpoints of the ranges and any values ​​disclosed herein are not limited to the precise ranges or values, and these ranges or values ​​should be understood to include values ​​close to these ranges or values. For numerical ranges, the endpoints of each range, the endpoints of each range and individual point values, and the individual point values ​​can be combined with each other to obtain one or more new numerical ranges, which should be considered to be specifically disclosed herein.

[0023] A first aspect of the present application provides a method for preparing a GH4151 alloy bar, wherein the method comprises the following steps:

[0024] (1) homogenizing heat treatment of GH4151 alloy ingot to obtain heat-treated rods;

[0025] (2) forging the heat-treated bar to obtain a forged bar;

[0026] (3) hot rolling the forged bar to obtain a hot-rolled bar;

[0027] (4) subjecting the hot-rolled bar to a solid solution treatment to obtain a solid solution bar;

[0028] (5) cold drawing the solid solution rod to obtain a cold drawn rod;

[0029] (6) The cold drawn bar is subjected to aging treatment to obtain a GH4151 alloy bar.

[0030] The GH4151 alloy rods prepared in this application have a rod diameter range of Φ5-Φ40mm. Through the above-mentioned special treatment method, the grains can be effectively refined, the surface dimensional accuracy can be improved, and the tensile strength of the prepared GH4151 alloy rods can be improved, so that they have excellent mechanical properties.

[0031] In this application, the term "small-sized GH4151 alloy bar" has the conventional meaning in the art, referring to GH4151 alloy bar with a diameter range of Φ5-Φ40mm. Compared to large-sized GH4151 alloy bar (diameter greater than 60mm), the small-sized GH4151 alloy bar referred to in this application is primarily used in the fastener manufacturing field. The bar preparation process includes a cold drawing step, resulting in higher dimensional accuracy and surface quality. The resulting GH4151 alloy bar has a room temperature tensile strength exceeding 1810MPa, preferably exceeding 2000MPa, a tensile strength at 800°C exceeding 1020MPa, and a rupture life of greater than 20h at 800°C / 500MPa.

[0032] The preparation method of the GH4151 alloy ingot is not particularly limited in the present application. The GH4151 alloy ingot can be obtained by conventional methods in the field. For example, the GH4151 alloy ingot is prepared by a two-step smelting method of vacuum induction melting + vacuum consumable remelting to prepare a Φ406 mm ingot, or by a three-step smelting method of vacuum induction melting + protective atmosphere electroslag remelting + vacuum consumable remelting to prepare a Φ508 mm ingot.

[0033] In the present application, there is no particular limitation on the shape of the GH4151 alloy ingot, as long as it can meet the requirements of the preparation method. For example, the GH4151 alloy ingot is cylindrical or rectangular; preferably, the GH4151 alloy ingot is cylindrical.

[0034] In this application, the preparation method processes small-sized GH4151 alloy bars. Compared with conventional large-sized GH4151 alloy bars, it has technical difficulties such as high strength requirements, difficult surface quality control, and difficult dimensional accuracy control, and puts forward higher requirements on the control of hot rolling and cold drawing process parameters.

[0035] According to the present application, preferably, the homogenization heat treatment process includes:

[0036] (1-1) casting the GH4151 alloy ingot at 1120-1140° C. for 30-50 hours;

[0037] (1-2) Raise the temperature to 1150-1170°C at a rate of 6-10°C / min and keep at this temperature for 20-40 hours;

[0038] (1-3) Raise the temperature to 1180-1210℃ at a rate of 6-10℃ / min, keep it at that temperature for 20-40h, and then cool it down to below 500℃ at a rate of 2-5℃ / min.

[0039] In the present application, the equipment for the homogenization heat treatment is not particularly limited, and those skilled in the art can adaptably select it according to their needs. Preferably, the homogenization heat treatment is performed in an air furnace. Preferably, in step (1-1), the GH4151 alloy ingot is heated from 2-40°C to 1120-1140°C at a heating rate of 6-10°C / min.

[0040] In this application, the heat-treated rods are preferably cooled using furnace cooling. Furnace cooling refers to the cooling of the rods within the furnace as the furnace temperature decreases. More preferably, after exiting the furnace, the heat-treated rods are covered with asbestos and air-cooled. Air cooling refers to cooling the rods in the atmosphere.

[0041] In the present application, preferably, homogenization heat treatment is performed under the above conditions, which can eliminate segregation and make the distribution of components in the alloy ingot more uniform. At the same time, it can eliminate the low melting point phase and improve the mechanical properties of the alloy.

[0042] According to the present application, preferably, the forging conditions include:

[0043] (2-1) performing an upsetting treatment on the heat-treated bar to obtain an upsetting ingot;

[0044] (2-2) The upset ingot is stretched and opened to obtain a stretched ingot.

[0045] According to the present application, preferably, the upsetting treatment includes the following steps: heating the heat-treated bar from 2-40°C to 1150-1180°C at a heating rate of 5-10°C / min, and keeping the temperature for 10-20h.

[0046] More preferably, the heat-treated bar is heated from 20-30°C to 1150-1180°C at a heating rate of 6-8°C / min and kept warm for 15-20 hours.

[0047] According to the present application, preferably, the pressing speed of the upsetting treatment is 10-40 mm / min, preferably 20-40 mm / min, and the upsetting deformation amount is 30-60% to obtain an upsetting ingot.

[0048] The deformation amount referred to in this application refers to the change in the size of the blank along the deformation direction before and after processing and deformation, and will not be repeated hereafter.

[0049] In the present application, preferably, upsetting treatment is performed under the above conditions, which can break up dendrites, promote the formation of equiaxed crystals, and refine the grain structure.

[0050] According to the present application, preferably, the stretching and blanking process includes the following steps:

[0051] The upsetting ingot is kept at 1150-1180°C for 20-30 hours, preferably 25-30 hours, the pressing speed of the drawing and blanking is 20-50 mm / min, preferably 30-40 mm / min, and the drawing deformation is 30-60% to obtain a drawn ingot.

[0052] In the present application, preferably, stretching and blanking are carried out under the above conditions, which can further promote equiaxed grain refinement, optimize grain structure, and improve mechanical properties.

[0053] According to the present application, preferably, the final forging temperature of the forging process is not lower than 1050°C.

[0054] According to the present application, preferably, the forging process is performed 8-12 times to obtain the forged bar.

[0055] In the present application, the equipment for the forging process is not particularly limited, and those skilled in the art can make an adaptive selection according to needs. Preferably, the forging process is carried out on a 4500-8000t fast forging machine to obtain a forged bar of Φ120-Φ150mm.

[0056] According to the present application, preferably, the temperature of the hot rolling treatment is 1100-1200°C, preferably 1130-1180°C.

[0057] According to the present application, preferably, the hot rolling deformation is 20-50%, preferably 30-40%.

[0058] According to the present application, preferably, the hot rolling process is performed for 5-8 passes.

[0059] In the present application, the equipment for the hot rolling treatment is not particularly limited, and those skilled in the art can make an adaptive selection according to needs. Preferably, the hot rolling treatment is carried out in a hot rolling mill to prepare Φ16-Φ40 mm hot-rolled bars.

[0060] In the present application, preferably, the final rolling temperature of the hot rolling treatment is not lower than 1000° C., and the surface of the rod is coated with asbestos to reduce the temperature drop.

[0061] In the present application, hot rolling treatment under the above conditions can refine the grains and improve the surface dimensional accuracy of the bar.

[0062] According to the present application, preferably, the solution treatment comprises the following steps: heating the hot-rolled bar from 300-500°C to 1080-1180°C at a heating rate of 5-10°C / min, keeping the temperature for 2-8h and then cooling to room temperature.

[0063] In the present application, the cooling method for the solution treatment is not particularly limited, and those skilled in the art can make an adaptive selection according to needs. Preferably, air cooling or oil cooling is adopted.

[0064] In the present application, solution treatment is performed under the above conditions, which can improve the tensile strength of the finally obtained GH4151 alloy bar.

[0065] According to the present application, preferably, the cold drawing treatment condition is: cold drawing the solid solution rod at a drawing speed of 5-20 mm / s, preferably, the cold drawing speed is 10-15 mm / s.

[0066] According to the present application, preferably, the cold drawing deformation is 10-50%, preferably 20-40%.

[0067] According to the present application, preferably, the cold drawing process is performed 5-8 times.

[0068] In the present application, the equipment for the cold drawing treatment is not particularly limited, and those skilled in the art can make an adaptive selection according to needs. Preferably, the cold drawing treatment is carried out on a 15t-60t single-chain or double-chain drawing machine to obtain a Φ5-Φ40mm cold-drawn bar, and the cold drawing treatment is carried out at room temperature.

[0069] In the present application, preferably, during the cold drawing process, a lubricant is applied to the surface of the rod. The lubricant may be a conventional lubricant in the art, such as lithium sulfate-based grease.

[0070] In the present application, cold drawing treatment under the above conditions can improve the tensile strength of the GH4151 alloy bar, so that the room temperature tensile strength of the bar is higher than 1810 MPa, preferably higher than 2000 MPa, the tensile strength at 800°C is higher than 1020 MPa, and the 800°C / 500 MPa endurance life is greater than 20 hours.

[0071] According to the present application, preferably, the aging treatment includes the following steps:

[0072] (6-1) heating the cold drawn bar from 100-300° C. to 770-870° C. at a heating rate of 2-5° C. / min, holding the temperature for 8-16 hours, and then cooling to room temperature to obtain a first aging treated bar;

[0073] (6-2) The first aging treatment bar is heated from 100-300°C to 620-760°C at a heating rate of 2-5°C / min, kept at this temperature for 8-16 hours, and then cooled to room temperature.

[0074] In the present application, preferably, aging treatment is performed under the above conditions, which can effectively control the size of the γ′ phase in the alloy rod to be 2-10 microns, the shape to be spherical and / or ellipsoidal, and to be dispersedly distributed, thereby improving the high-temperature mechanical properties of the alloy.

[0075] According to the present application, preferably, based on the total mass of the GH4151 alloy ingot, the GH4151 alloy ingot contains the following elements:

[0076] 10.5-11.5wt% Cr, 14.5-15.5wt% Co, 2.5-3wt% Ti, 3-4wt% Al, 2.5-3.5wt% Nb, not more than 1wt% Fe, 4-5wt% Mo, 2.5-3wt% W, 0.002-0.02wt% Mg, 0.025-0.04wt% Zr, 0.05-2wt% Ta, 0.03-0.3wt% Si, 0.01-0.035wt% C, not more than 0.01wt% B, and 0.01-0.1wt% Hf and 50-60wt% Ni.

[0077] In the present application, the alloy ingot having the above composition is used to help improve the mechanical properties of the prepared GH4151 alloy bar.

[0078] According to a preferred embodiment of the present application, the method for preparing the GH4151 alloy bar comprises the following steps:

[0079] (A) subjecting a GH4151 alloy ingot to homogenization heat treatment, wherein the homogenization heat treatment process comprises:

[0080] (A-1) casting the GH4151 alloy ingot at 1120-1140° C. for 30-50 hours;

[0081] (A-2) heating to 1150-1170°C at a rate of 6-10°C / min and holding for 20-40 hours;

[0082] (A-3) heating to 1180-1210°C at a rate of 6-10°C / min, holding for 20-40 hours, and then cooling to below 500°C at a rate of 2-5°C / min;

[0083] (B) subjecting the heat-treated bar to a forging process, wherein the forging process conditions include:

[0084] (B-1) performing an upsetting treatment on the heat-treated bar, wherein the upsetting treatment comprises the following steps:

[0085] The heat-treated bar is heated from 2-40°C to 1150-1180°C at a heating rate of 5-10°C / min and kept at this temperature for 10-20 hours;

[0086] The pressing speed of the upsetting treatment is 10-40 mm / min, and the upsetting deformation is 30-60%, thereby obtaining an upsetting ingot;

[0087] (B-2) stretching and blanking the upset ingot, the stretching and blanking comprising the following steps: keeping the upset ingot at 1150-1180° C. for 20-30 hours, with a downward pressing speed of 20-50 mm / min and a stretching deformation of 30-60%, to obtain a stretched ingot;

[0088] (B-3) performing the forging process 8 to 12 times to obtain the forged bar;

[0089] (C) hot rolling the forged bar, wherein the hot rolling temperature is 1130-1180° C. and the hot rolling deformation is 30-40%;

[0090] The hot rolling process is performed for 5 to 8 times to obtain a hot-rolled bar;

[0091] (D) subjecting the hot-rolled bar to a solution treatment, the solution treatment comprising the following steps: heating the hot-rolled bar from 300-500° C. to 1080-1180° C. at a heating rate of 5-10° C. / min, holding the temperature for 2-8 hours, and then cooling the bar to room temperature to obtain a solution bar;

[0092] (E) cold drawing the solid solution rod, wherein the cold drawing process comprises cold drawing the solid solution rod at a drawing speed of 5-20 mm / s and a cold drawing deformation of 10-50%;

[0093] The cold drawing process is performed 5-8 times to obtain a cold drawn bar;

[0094] (F) subjecting the cold-drawn bar to an aging treatment, wherein the aging treatment comprises the following steps:

[0095] (F-1) heating the cold-drawn bar from 100-300° C. to 770-870° C. at a heating rate of 2-5° C. / min, holding the temperature for 8-16 hours, and then cooling to room temperature to obtain a first aging-treated bar;

[0096] (F-2) heating the first aging treated rod from 100-300° C. to 620-760° C. at a heating rate of 2-5° C. / min, keeping the temperature for 8-16 hours, and then cooling to room temperature to obtain a GH4151 alloy rod.

[0097] The second aspect of the present application provides a GH4151 alloy rod obtained by the preparation method described in the first aspect.

[0098] According to the present application, preferably, the GH4151 alloy bar has a grain size of not less than grade 8, a room temperature tensile strength higher than 1810 MPa, a 800°C tensile strength higher than 1020 MPa, and an 800°C / 500 MPa endurance life greater than 28 hours.

[0099] The third aspect of the present application provides the use of the GH4151 alloy rod described in the second aspect in fasteners for aircraft engines and / or ground gas turbines.

[0100] The present application will be described in detail below through examples and comparative examples. In the following examples and comparative examples, unless otherwise specified, all raw materials used can be obtained from commercial channels;

[0101] (1) Room temperature tensile strength: GB / T 228.1 Metallic materials tensile tests Part 1: Room temperature test method.

[0102] (2) Tensile strength at 800℃: GB / T 228.2 Tensile tests on metallic materials - Part 2: High temperature test methods.

[0103] (3) 800℃ / 500MPa endurance life: GB / T 2039 Metal materials uniaxial tensile creep and endurance test method.

[0104] (4) Grain size: GB / T 6394 Method for determination of average grain size of metals.

[0105] Example 1

[0106] A GH4151 alloy ingot (ingot Φ508±20 mm) was obtained by triple smelting, with the following composition: 11 wt% Cr, 15 wt% Co, 2.8 wt% Ti, 3.5 wt% Al, 3.2 wt% Nb, 0.8 wt% Fe, 4.5 wt% Mo, 2.8 wt% W, 0.01 wt% Mg, 0.03 wt% Zr, 1.0 wt% Ta, 0.05 wt% Si, 0.02 wt% C, 0.005 wt% B, 0.05 wt% Hf and 55.235 wt% Ni.

[0107] The GH4151 alloy ingot was processed as follows:

[0108] (A) subjecting a GH4151 alloy ingot to homogenization heat treatment, wherein the homogenization heat treatment process comprises:

[0109] (A-1) keeping the GH4151 alloy ingot at 1140° C. for 50 hours;

[0110] (A-2) heating to 1170°C at a rate of 8°C / min and holding for 40 h;

[0111] (A-3) Raise the temperature to 1200°C at a rate of 8°C / min, keep at this temperature for 40 hours, then lower the temperature at a rate of 5°C / min, cool down to below 500°C, remove from the furnace, cover with asbestos and cool in air;

[0112] (B) subjecting the heat-treated bar to a forging process, wherein the forging process conditions include:

[0113] (B-1) performing an upsetting treatment on the heat-treated bar, wherein the upsetting treatment comprises the following steps:

[0114] The heat-treated bar is heated from 20°C to 1180°C at a heating rate of 8°C / min and kept at this temperature for 20 hours;

[0115] The pressing speed of the upsetting treatment is 40 mm / min, the upsetting deformation is 40%, and an upsetting ingot is obtained;

[0116] (B-2) stretching and blanking the upset ingot, the stretching and blanking comprising the following steps: holding the upset ingot at 1180° C. for 30 hours, with a downward pressing speed of 40 mm / min and a stretching deformation of 50%, to obtain a stretched ingot;

[0117] (B-3) The forging process is performed 10 times with a final forging temperature of 1100° C. to obtain a forged bar with a diameter of 120 mm;

[0118] (C) hot rolling the forged bar, wherein the hot rolling temperature is 1160° C. and the hot rolling deformation is 30%;

[0119] The hot rolling process is performed for 6 times, with the final rolling temperature being 1050° C., to obtain a Φ35 mm hot-rolled bar;

[0120] (D) subjecting the hot-rolled bar to a solution treatment, the solution treatment comprising the following steps: placing the hot-rolled bar into a furnace at 300° C., heating the bar to 1100° C. at a heating rate of 10° C. / min, holding the temperature for 8 hours, and then air-cooling the bar to room temperature to obtain a solution bar;

[0121] (E) cold drawing the solid solution rod, wherein the cold drawing conditions are as follows: cold drawing the solid solution rod at a drawing speed of 10 mm / s, applying lithium sulfate-based grease on the surface of the rod, and the cold drawing deformation is 30%;

[0122] The cold drawing process is performed 6 times to obtain a Φ25 mm cold drawn bar;

[0123] (F) subjecting the cold-drawn bar to an aging treatment, wherein the aging treatment comprises the following steps:

[0124] (F-1) heating the cold-drawn bar from 100° C. to 800° C. at a heating rate of 5° C. / min, holding the temperature for 12 hours, and then air-cooling the bar to room temperature to obtain a first aging treatment bar;

[0125] (F-2) The first aging treated rod was heated from 100° C. to 700° C. at a heating rate of 5° C. / min, kept at this temperature for 12 h, and then air-cooled to room temperature to obtain a GH4151 alloy rod.

[0126] Example 2

[0127] The GH4151 alloy ingot is the same as that in Example 1, and the GH4151 alloy ingot is processed in the following manner:

[0128] (A) subjecting a GH4151 alloy ingot to homogenization heat treatment, wherein the homogenization heat treatment process comprises:

[0129] (A-1) keeping the GH4151 alloy ingot at 1140° C. for 50 hours;

[0130] (A-2) heating to 1160°C at a rate of 8°C / min and holding for 40 h;

[0131] (A-3) Raise the temperature to 1200°C at a rate of 8°C / min, keep at this temperature for 40 hours, then lower the temperature at a rate of 5°C / min, cool down to below 500°C, remove from the furnace, cover with asbestos and cool in air;

[0132] (B) subjecting the heat-treated bar to a forging process, wherein the forging process conditions include:

[0133] (B-1) performing an upsetting treatment on the heat-treated bar, wherein the upsetting treatment comprises the following steps:

[0134] The heat-treated bar is heated from 20°C to 1160°C at a heating rate of 8°C / min and kept at this temperature for 20 hours;

[0135] The pressing speed of the upsetting treatment is 40 mm / min, the upsetting deformation is 30%, and an upsetting ingot is obtained;

[0136] (B-2) stretching and blanking the upset ingot, the stretching and blanking comprising the following steps: holding the upset ingot at 1160° C. for 30 hours, with a downward pressing speed of 40 mm / min and a stretching deformation of 40%, to obtain a stretched ingot;

[0137] (B-3) The forging process is performed 10 times with a final forging temperature of 1100° C. to obtain a forged bar with a diameter of 120 mm;

[0138] (C) hot rolling the forged bar, wherein the hot rolling temperature is 1140° C. and the hot rolling deformation is 30%;

[0139] The hot rolling process is performed for 6 times, with the final rolling temperature being 1050° C., to obtain a Φ35 mm hot-rolled bar;

[0140] (D) subjecting the hot-rolled bar to a solution treatment, the solution treatment comprising the following steps: placing the hot-rolled bar into a furnace at 300° C., heating the bar to 1100° C. at a heating rate of 10° C. / min, holding the temperature for 8 hours, and then air-cooling the bar to room temperature to obtain a solution bar;

[0141] (E) cold drawing the solid solution rod, wherein the cold drawing conditions are as follows: cold drawing the solid solution rod at a drawing speed of 10 mm / s, applying lithium sulfate-based grease on the surface of the rod, and the cold drawing deformation is 30%;

[0142] The cold drawing process is performed 6 times to obtain a Φ25 mm cold drawn bar;

[0143] (F) subjecting the cold-drawn bar to an aging treatment, wherein the aging treatment comprises the following steps:

[0144] (F-1) heating the cold-drawn bar from 100° C. to 820° C. at a heating rate of 5° C. / min, holding the temperature for 16 hours, and then air-cooling the bar to room temperature to obtain a first aging-treated bar;

[0145] (F-2) The first aging treated rod was heated from 100° C. to 720° C. at a heating rate of 5° C. / min, kept at this temperature for 10 h, and then air-cooled to room temperature to obtain a GH4151 alloy rod.

[0146] Example 3

[0147] The GH4151 alloy ingot is the same as that in Example 1, and the GH4151 alloy ingot is processed in the following manner:

[0148] (A) subjecting a GH4151 alloy ingot to homogenization heat treatment, wherein the homogenization heat treatment process comprises:

[0149] (A-1) keeping the GH4151 alloy ingot at 1120° C. for 50 hours;

[0150] (A-2) heating to 1170°C at a rate of 10°C / min and holding for 40 h;

[0151] (A-3) Raise the temperature to 1200°C at a rate of 10°C / min, keep at this temperature for 40 hours, then lower the temperature at a rate of 5°C / min, cool down to below 500°C, remove from the furnace, cover with asbestos and cool in air;

[0152] (B) subjecting the heat-treated bar to a forging process, wherein the forging process conditions include:

[0153] (B-1) performing an upsetting treatment on the heat-treated bar, wherein the upsetting treatment comprises the following steps:

[0154] The heat-treated bar is heated from 20°C to 1150°C at a heating rate of 10°C / min and kept at this temperature for 20 hours;

[0155] The pressing speed of the upsetting treatment is 40 mm / min, the upsetting deformation is 50%, and an upsetting ingot is obtained;

[0156] (B-2) stretching and blanking the upset ingot, the stretching and blanking comprising the following steps: holding the upset ingot at 1150° C. for 20 hours, with a downward pressing speed of 30 mm / min and a stretching deformation of 30%, to obtain a stretched ingot;

[0157] (B-3) The forging process is performed 8 times with a final forging temperature of 1050° C. to obtain a forged bar with a diameter of 150 mm;

[0158] (C) hot rolling the forged bar, wherein the hot rolling temperature is 1130° C. and the hot rolling deformation is 30%;

[0159] The hot rolling process is performed for 5 times, with the final rolling temperature being 1050° C., to obtain a Φ40 mm hot-rolled bar;

[0160] (D) subjecting the hot-rolled bar to a solution treatment, the solution treatment comprising the following steps: placing the hot-rolled bar into a furnace at 300° C., heating it to 1080° C. at a heating rate of 5° C. / min, holding the temperature for 8 hours, and then air-cooling it to room temperature to obtain a solution-treated bar;

[0161] (E) cold drawing the solid solution rod, wherein the cold drawing conditions are as follows: cold drawing the solid solution rod at a drawing speed of 5 mm / s, applying lithium sulfate-based grease on the surface of the rod, and the cold drawing deformation is 20%;

[0162] The cold drawing process is performed 8 times to obtain a Φ35 mm cold drawn bar;

[0163] (F) subjecting the cold-drawn bar to an aging treatment, wherein the aging treatment comprises the following steps:

[0164] (F-1) heating the cold-drawn bar from 100° C. to 870° C. at a heating rate of 5° C. / min, holding the temperature for 16 hours, and then air-cooling the bar to room temperature to obtain a first aging-treated bar;

[0165] (F-2) The first aging treated rod was heated from 100° C. to 760° C. at a heating rate of 5° C. / min, kept at this temperature for 16 h, and then air-cooled to room temperature to obtain a GH4151 alloy rod.

[0166] Example 4

[0167] The GH4151 alloy ingot was the same as that in Example 1, and the GH4151 alloy rod was prepared according to the method of Example 1, except that the hot rolling treatment temperature in step (C) was 1190°C.

[0168] Comparative Example 1

[0169] The GH4151 alloy ingot was the same as in Example 1. The GH4151 alloy ingot was processed as follows:

[0170] (A) subjecting a GH4151 alloy ingot to homogenization heat treatment, wherein the homogenization heat treatment process comprises:

[0171] (A-1) keeping the GH4151 alloy ingot at 1120° C. for 50 hours;

[0172] (A-2) heating to 1170°C at a rate of 10°C / min and holding for 40 h;

[0173] (A-3) Raise the temperature to 1200°C at a rate of 10°C / min, keep at this temperature for 40 hours, then lower the temperature at a rate of 5°C / min, cool down to below 500°C, remove from the furnace, cover with asbestos and cool in air;

[0174] (B) hot rolling the heat-treated bar, wherein the hot rolling temperature is 1130° C. and the hot rolling deformation is 30%;

[0175] The hot rolling process is performed for 5 times, with the final rolling temperature being 1050° C., to obtain a Φ40 mm hot-rolled bar;

[0176] (C) subjecting the hot-rolled bar to a solution treatment, the solution treatment comprising the following steps: placing the hot-rolled bar into a furnace at 300° C., heating it to 1080° C. at a heating rate of 5° C. / min, holding the temperature for 8 hours, and then air-cooling it to room temperature to obtain a solution-treated bar;

[0177] (D) cold drawing the solid solution rod, wherein the cold drawing conditions are as follows: cold drawing the solid solution rod at a drawing speed of 5 mm / s, applying lithium sulfate-based grease on the surface of the rod, and the cold drawing deformation is 20%;

[0178] The cold drawing process is performed 8 times to obtain a Φ35 mm cold drawn bar;

[0179] (E) subjecting the cold-drawn bar to an aging treatment, wherein the aging treatment comprises the following steps:

[0180] (E-1) heating the cold-drawn bar from 100° C. to 870° C. at a heating rate of 5° C. / min, holding the temperature for 16 hours, and then air-cooling the bar to room temperature to obtain a first aging-treated bar;

[0181] (E-2) The first aging treated rod was heated from 100° C. to 760° C. at a heating rate of 5° C. / min, kept at this temperature for 16 h, and then air-cooled to room temperature to obtain a GH4151 alloy rod.

[0182] Comparative Example 2

[0183] The GH4151 alloy ingot was the same as that in Example 1, and the GH4151 alloy bar was prepared according to the method of Example 1, except that no hot rolling treatment was performed.

[0184] Comparative Example 3

[0185] The GH4151 alloy ingot was the same as that in Example 1, and the GH4151 alloy bar was prepared according to the method of Example 1, except that no cold drawing treatment was performed.

[0186] Test Example 1

[0187] The obtained GH4151 alloy bars were tested, and the test results are shown in Table 1.

[0188] FIG1 is a high-magnification metallographic microstructure photograph of the GH4151 alloy rod prepared in Example 1. It can be observed from FIG1 that the precipitated phase is evenly distributed and the rod microstructure meets the requirements of uniform fine grains.

[0189] Table 1

[0190] From the results in Table 1, it can be seen that the GH4151 alloy rod prepared by the preparation method of the present application has a grain size of not less than grade 8, a room temperature tensile strength higher than 1810 MPa, a 800°C tensile strength higher than 1020 MPa, and an 800°C / 500 MPa endurance life greater than 28 h, with finer grains and better mechanical properties.

[0191] The preferred embodiments of the present application are described in detail above, but the present application is not limited thereto. Within the technical concept of the present application, various simple modifications can be made to the technical solution of the present application, including combining the various technical features in any other appropriate manner. These simple modifications and combinations should also be regarded as the contents disclosed in the present application and fall within the scope of protection of the present application.

Claims

1. A method for preparing GH4151 alloy bars, characterized in that: The method comprises the following steps: (1) homogenizing heat treatment of GH4151 alloy ingot to obtain heat-treated rods; (2) forging the heat-treated bar to obtain a forged bar; (3) hot rolling the forged bar to obtain a hot-rolled bar; (4) subjecting the hot-rolled bar to a solid solution treatment to obtain a solid solution bar; (5) cold drawing the solid solution rod to obtain a cold drawn rod; (6) The cold drawn bar is subjected to aging treatment to obtain a GH4151 alloy bar.

2. The preparation method according to claim 1, wherein The process of the homogenization heat treatment comprises: (1-1) casting the GH4151 alloy ingot at 1120-1140° C. for 30-50 hours; (1-2) Raise the temperature to 1150-1170°C at a rate of 6-10°C / min and keep at this temperature for 20-40 hours; (1-3) Raise the temperature to 1180-1210℃ at a rate of 6-10℃ / min, keep it at that temperature for 20-40h, and then cool it down to below 500℃ at a rate of 2-5℃ / min.

3. The preparation method according to claim 1, wherein The forging conditions include: (2-1) performing an upsetting treatment on the heat-treated bar to obtain an upsetting ingot; (2-2) stretching and blanking the upset ingot to obtain a stretched ingot; Preferably, the final forging temperature of the forging process is not less than 1050°C; Preferably, the forging process is performed 8-12 times to obtain the forged bar.

4. The preparation method according to claim 3, wherein The upsetting process comprises the following steps: The heat-treated bar is heated from 2-40°C to 1150-1180°C at a heating rate of 5-10°C / min and kept at this temperature for 10-20 hours; Preferably, the pressing speed of the upsetting treatment is 10-40 mm / min, and the upsetting deformation amount is 30-60%, thereby obtaining an upsetting ingot.

5. The preparation method according to claim 3, wherein The drawing and blanking process comprises the following steps: The upsetting ingot is kept at 1150-1180° C. for 20-30 hours, the pressing speed of the drawing and blanking is 20-50 mm / min, and the drawing deformation amount is 30-60% to obtain the drawn ingot.

6. The preparation method according to claim 1, wherein The temperature of the hot rolling treatment is 1100-1200°C, preferably 1130-1180°C; Preferably, the hot rolling deformation is 20-50%, preferably 30-40%; Preferably, the hot rolling process is performed for 5-8 passes.

7. The preparation method according to claim 1, wherein The solution treatment comprises the following steps: The hot-rolled bar is heated from 300-500° C. to 1080-1180° C. at a heating rate of 5-10° C. / min, kept at this temperature for 2-8 hours, and then cooled to room temperature.

8. The preparation method according to claim 1, wherein The conditions of the cold drawing treatment are: Cold drawing the solid solution rod at a drawing speed of 5-20 mm / s, preferably 10-15 mm / s; Preferably, the cold drawing deformation is 10-50%, preferably 20-40%; And / or, the cold drawing process is performed 5-8 times.

9. The preparation method according to claim 1, wherein The aging treatment comprises the following steps: (6-1) heating the cold drawn bar from 100-300° C. to 770-870° C. at a heating rate of 2-5° C. / min, holding the temperature for 8-16 hours, and then cooling to room temperature to obtain a first aging treated bar; (6-2) The first aging treatment bar is heated from 100-300°C to 620-760°C at a heating rate of 2-5°C / min, kept at this temperature for 8-16 hours, and then cooled to room temperature.

10. The preparation method according to claim 1, wherein Based on the total mass of the GH4151 alloy ingot, the GH4151 alloy ingot contains the following elements: 10.5-11.5wt% Cr, 14.5-15.5wt% Co, 2.5-3wt% Ti, 3-4wt% Al, 2.5-3.5wt% Nb, not more than 1wt% Fe, 4-5wt% Mo, 2.5-3wt% W, 0.002-0.02wt% Mg, 0.025-0.04wt% Zr, 0.05-2wt% Ta, 0.03-0.3wt% Si, 0.01-0.035wt% C, not more than 0.01wt% B, 0.01-0.1wt% Hf and 50-60wt% Ni.

11. GH4151 alloy rod obtained by the preparation method according to any one of claims 1 to 10; Preferably, the GH4151 alloy bar has a grain size of not less than grade 8, a grain size difference between the core and the edge of the bar is less than 2 grades, a room temperature tensile strength higher than 1810 MPa, a 800°C tensile strength higher than 1020 MPa, and an 800°C / 500 MPa endurance life greater than 28 hours.

12. Use of the GH4151 alloy bar according to claim 11 in fasteners for aircraft engines and / or ground gas turbines.

Images