Soil carbon sensing methodology and electrode arrangement

The electrode arrangement with a specific coating composition for squarewave voltammetry effectively detects humic and fulvic acids in soil, addressing the limitations of existing technologies by enhancing sensitivity and mechanical stability for in situ soil carbon sensing.

WO2025240995A1 Publication Date: 2025-11-27SENSORC PTY LTD
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Patent Information

Application Number
PCT/AU2025/050522
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2024-05-22
Filing Date
2025-05-17
Publication Date
2025-11-27

AI Technical Summary

Technical Problem

Existing soil carbon sensing technologies face challenges in providing cost-effective, in situ detection of humic and fulvic acids due to fouling of sensor optics and limited penetration depth of IR radiation, and electrochemical sensors lack quantitative analysis of total organic/inorganic carbon.

Method used

An electrode arrangement with a coating comprising ionic liquid, sulfonated tetrafluoroethylene-based fluoropolymer-copolymer, conductive carbon particles, polymeric adsorbent non-ionic aliphatic acrylic resin, and cross-linked hydrogel, configured for squarewave voltammetry, allows for the detection of humic and fulvic acids and water-soluble molecules with electrochemically active quinone/phenol functional groups in a soil matrix.

Benefits of technology

The electrode arrangement enables sensitive and reversible detection of humic and fulvic acids, providing insights into soil carbon content and health through squarewave voltammetry, with improved mechanical stability and sensitivity, suitable for long-term soil monitoring.

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Abstract

Provided is an electrode arrangement configured for detecting humic and fulvic acids in a soil matrix by means of squarewave voltammetry. The electrode arrangement comprises a working electrode with a coating comprising an admixture of ionic liquid 1-butyl-3- methylimidazolium tetrafluoroborate (BMIM-BF4) and sulfonated tetrafluoroethylene-based fluoropolymer-copolymer - sulfur trioxide (SO3) at a molar ratio of 1:1, sulfonated tetrafluoroethylene-based fluoropolymer-copolymer to carbon particles at a mass ratio in a range of between 1:10 and 1:15, sulfonated tetrafluoroethylene-based fluoropolymer-copolymer to polymeric adsorbent non-ionic aliphatic acrylic resin at a mass ratio in a range of between of 1:50 and 1:60, and a cross-linked hydrogel.
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