Modified polyolefin / polyester plate and manufacturing method therefor

By employing continuous mixing and plasticizing processes and two-stage extrusion, along with grafting modification, blending modification, coupling/crosslinking modification, and fiber reinforcement modification, the problem of low calcium carbonate addition was solved, thereby improving the performance and production efficiency of modified polyolefin/polyester boards.

WO2025245970A1PCT designated stage Publication Date: 2025-12-04TAIZHOU HUALI PLASTIC

Patent Information

Application Number
PCT/CN2024/104843
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2024-05-29
Filing Date
2024-07-11
Publication Date
2025-12-04

AI Technical Summary

Technical Problem

In the existing technology, due to the small intermolecular contact area and the low compatibility between polymers and calcium carbonate, the amount of calcium carbonate added in polyolefins and polyesters is relatively low, resulting in decreased product performance and calcium carbonate precipitation on the surface, which affects the product appearance.

Method used

By employing a continuous mixing and plasticizing process and a two-stage extrusion process, the calcium carbonate filling amount is increased through grafting modification, blending modification, coupling/crosslinking modification, and fiber reinforcement modification. This enhances intermolecular interactions, forms a dense molecular network structure, and improves material properties.

Benefits of technology

It has enabled efficient production, improved the product's flexural modulus, hardness, toughness and fatigue resistance, reduced production costs, avoided product surface defects, and improved product quality and production efficiency.

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Abstract

A modified polyolefin / polyester plate and a manufacturing method therefor. The modified polyolefin / polyester plate comprises a polyester / polyolefin substrate plate and a composite layer laminated on one side or two sides of the polyester / polyolefin substrate plate, wherein the substrate plate is obtained by performing continuous-process mixing, plasticizing and two-stage extrusion, and is a solid layer or a foamed layer. By means of a process of mixing / plasticizing / two-stage extrusion continuous production and synchronous composite molding, shutdown is not required for transition between the working procedures; therefore, 24-hour uninterrupted production can be achieved, thereby obtaining high production efficiency. By means of continuous production, accurate control and online monitoring can be achieved, the stability and consistency of product quality are ensured, the fluidity of materials is better, and a better venting effect is obtained.
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Description

Modified polyolefin / polyester board and its manufacturing method Technical Field

[0001] This invention relates to the field of polymer sheet technology, and in particular to a modified polyolefin / polyester sheet and its manufacturing method. Background Technology

[0002] Sustainable development of resources refers to a development model that ensures future generations can continue to utilize resources while meeting current human needs. The treatment and reuse of waste materials is an effective way to achieve sustainable development. The treatment and reuse of waste polymer materials has received widespread attention in the industry, as it not only reduces environmental damage and material waste but also offers significant economic benefits.

[0003] Products such as wind turbine blades and plastic bottles, which are made of polymer composite materials such as polyolefins / polyesters, will be subject to large-scale disposal in the present or near future. Some of these products are difficult to recycle due to the presence of other composite materials. The current disposal method is to send them to landfills, which cannot achieve sustainable resource utilization.

[0004] Manufacturing sheets is one way to reuse polymer composites such as polyolefins and polyesters. To improve the flexural modulus, hardness, toughness, fatigue resistance, and glass transition temperature of the sheets, calcium carbonate is added to the polyolefins and polyesters. Furthermore, increasing the amount of calcium carbonate added reduces the manufacturing cost of the sheets. In existing technologies, due to the small intermolecular contact area and low compatibility between polymers and calcium carbonate, the amount of calcium carbonate added to polyolefins and polyesters is relatively low. Generally, the amount of calcium carbonate added per 100g of polyolefin or polyester does not exceed 250g; otherwise, the product performance will drop sharply, calcium carbonate will precipitate on the product surface, resulting in numerous small pits and severely affecting the product's appearance. Summary of the Invention

[0005] To address the shortcomings of existing technologies, this invention provides a modified polyolefin / polyester board with excellent performance and its manufacturing method.

[0006] The technical solution adopted by the present invention to solve the above-mentioned technical problems is as follows:

[0007] A modified polyolefin / polyester board includes a polyester / polyolefin substrate and a composite layer laminated on one or both sides of the polyester / polyolefin substrate. The polyester / polyolefin substrate is obtained by continuous mixing and plasticizing and two-stage extrusion. The polyester / polyolefin substrate is a solid layer or a foamed layer.

[0008] Furthermore, the composite layer includes a UV coating, a wear-resistant layer, a patterned film layer, and a sound-absorbing pad layer. The modified polyolefin / polyester board is formed by roll-pressing a wear-resistant layer, a patterned film layer, and a sound-absorbing pad onto a polyester / polyolefin substrate board, followed by roll-coating with UV paint and photocuring to form a UV coating. The board is then cut, grooved, and packaged. The surface of the modified polyolefin / polyester board body contains simulated three-dimensional textures.

[0009] Furthermore, the composite layer includes melamine patterned wear-resistant paper, melamine balance paper, adhesive, and a sound-absorbing pad layer. The modified polyolefin / polyester board is formed by simultaneously hot-pressing melamine patterned wear-resistant paper and melamine balance paper onto the upper and lower surfaces of a polyester / polyolefin substrate, and then rolling-coating the adhesive to adhere the sound-absorbing pad layer. The surface of the modified polyolefin / polyester board body contains simulated three-dimensional textures.

[0010] Furthermore, the foamed layer is formed by adding 0.5-3 parts of chemical foaming agent to the solid layer components and extruding and foaming, or by physically foaming by introducing a certain amount of carbon dioxide or nitrogen gas during the extrusion of the solid layer components.

[0011] Furthermore, the solid layer is modified using one or more of the following methods: grafting modification, blending modification, coupling / crosslinking modification, and fiber reinforcement modification.

[0012] Furthermore, the solid layer is grafted and modified, and the specific components and weight parts are as follows:

[0013] 100 parts of polyolefin / polyester

[0014] 1-10 parts of maleic anhydride

[0015] Calcium carbonate 50-500 parts

[0016] The solid layer is modified by blending, and the specific components and weight parts are as follows:

[0017] 100 parts of polyolefin / polyester

[0018] 5-20 parts of rubber or elastomer

[0019] Calcium carbonate 50-500 parts

[0020] 10-20 parts flame retardant

[0021] The solid layer employs coupling modification, and the specific components and weight parts are as follows:

[0022] 100 parts of polyolefin / polyester

[0023] 5-10 parts of silane coupling agent

[0024] Calcium carbonate 50-500 parts

[0025] The solid layer is modified with fiber reinforcement, and the specific components and weight parts are as follows:

[0026] 100 parts of polyolefin / polyester

[0027] 20-80 parts fiber

[0028] Calcium carbonate 50-500 parts

[0029] The solid layer employs various modifications, the specific components and weight parts are as follows:

[0030] 100 parts of polyolefin / polyester

[0031] 1-10 parts of maleic anhydride

[0032] 5-10 parts of silane coupling agent

[0033] 20-80 parts fiber

[0034] 5-20 parts of rubber or elastomer

[0035] Calcium carbonate 50-500 parts

[0036] 10-20 parts flame retardant.

[0037] Furthermore, the polyolefin / polyester is one or more of PE, PP, PB, PET, and PETG, and is either recycled or virgin material; the rubber or elastomer is one or more of SBS, TPE, TPU, EPDM, NBR, and EVA; and the fiber is one or more of plant fiber, inorganic fiber, and chemical fiber.

[0038] Furthermore, the two-stage extrusion involves using two extruders in succession for extrusion. The materials are mixed according to their mass components and then extruded in a first-stage reactive extruder, followed by extrusion in a second-stage twin-screw extruder.

[0039] Furthermore, the sound-absorbing pad layer is formed by rolling and bonding a sound-absorbing pad under a polyester / polyolefin substrate.

[0040] A method for manufacturing a modified polyolefin / polyester board, wherein the substrate board is a solid layer or a foamed layer, and single or multiple modifications are selected, comprising the following steps: weighing and mixing the required raw materials and adding them to a mixing unit for mixing and plasticizing; the mixing unit first hot-mixing to 120℃-140℃, then discharging the material into a cold-mixing unit for cooling and mixing to 50℃, and then adding it to a two-stage extrusion unit; the first-stage reactive extruder first reacts and modifies the material at 180℃-240℃, and the second-stage extruder extrudes the material into a die at 160℃-220℃, and then the material enters a roll forming machine at 160℃-200℃, where it first rolls and presses a composite patterned film layer and a wear-resistant layer, and then rolls and presses a composite sound-absorbing pad at 80℃-100℃; cooling, shaping, and cutting to form a large polyolefin / polyester board; the wear-resistant layer of the large polyolefin / polyester board is coated with a UV coating and cured to form a UV coating; and the board is then cut, grooved, and packaged to form the polyolefin / polyester board.

[0041] A method for manufacturing a modified polyolefin / polyester board, wherein the substrate board is a solid layer or a foamed layer, and single or multiple modifications are selected, comprising the following steps: weighing and mixing the required raw materials and adding them to a mixing unit for mixing and plasticizing; the mixing unit first hot-mixing to 120℃-140℃, then discharging the material into a cold-mixing unit for cooling and mixing to 50℃, and then adding it to a two-stage extrusion unit; the first-stage reactive extruder first reacts and modifies the material at 180℃-240℃, and the second-stage extruder at 160℃-220℃. After being extruded and formed under certain conditions, the material enters a roll forming machine and is rolled to a certain thickness at 160℃-200℃. After cooling and cutting, a polyolefin / polyester substrate board is formed. Under the conditions of pressure 3-18Mpa, temperature 150-220℃, and time 30-600s, melamine patterned wear-resistant paper and melamine balance paper are simultaneously hot-pressed onto the upper and lower parts of the polyolefin / polyester substrate board. Adhesive is then applied to the board to bond a sound-absorbing pad. The board is then cut, grooved, and packaged to form the polyolefin / polyester board.

[0042] The mixed plasticizing two-stage extrusion method used in this application involves connecting a high-low temperature mixing unit to a two-stage extruder. First, the high-low temperature mixing unit performs the mixing and plasticizing, followed by two-stage extrusion, forming a continuous manufacturing method. This method, by separating the extrusion process, allows the pre-extrusion and main extrusion stages to be performed simultaneously, thus significantly shortening the production cycle. Furthermore, the pretreatment process can be automated, reducing the workload of operators and improving production efficiency. Continuous mixed plasticizing is used to achieve the mixed pre-plasticization of graft-modified, blend-modified, coupling / crosslinked modified, and fiber-reinforced modified materials for further modification. Two-stage extrusion and roller pressing are used to link graft modification, blend modification, coupling / crosslinked modification, and fiber-reinforced modification. Two-stage extrusion allows for multiple modifications to be performed simultaneously.

[0043] Among these methods, grafting modification involves the following steps: Grafting modification: Under the action of an initiator, the macromolecular chains of polyolefins and polyesters undergo chain breakage during bi-stage extrusion shearing, resulting in a decrease in molecular weight and a wider molecular distribution. Simultaneously, maleic anhydride is grafted onto the polyolefin and polyester molecular chains, improving the material's polarity, enhancing intermolecular interactions, better encapsulating calcium carbonate, increasing calcium carbonate filler content, and reducing costs. Blending modification: Through mixing, dispersion, and bi-stage extrusion shearing, multiple materials undergo continuous molecular cross-linking and interpenetration, forming a denser molecular network. This combines the advantages of multiple materials, overcoming the disadvantages of a single material, and leveraging the properties of multiple materials to improve the product's impact strength, rigidity, and toughness, while increasing calcium carbonate filler content and reducing costs. Coupling / crosslinking modification: Under the action of coupling or crosslinking agents, through mixing, dispersion, and bi-stage extrusion shearing plasticizing, the molecular chains react and form a three-dimensional network structure through chemical bonds. This results in a larger contact area between molecules, improving compatibility with calcium carbonate, increasing calcium carbonate filler content, and reducing costs. Coupling and crosslinking also improve the product's flexural modulus, hardness, and glass transition temperature. Fiber reinforcement modification: The fiber surface has a layer of functional groups such as oxides, hydroxyl groups or amino groups. Through mixing, dispersion and two-stage extrusion shear plasticizing, it can combine with the active functional groups in polyester and polyolefin to form strong chemical bonds, thereby improving its strength and stiffness. The fiber can inhibit the fracture of polyolefin and polyester materials. When external force is applied, the fiber can absorb and disperse stress, hinder the propagation of cracks, and improve toughness and fatigue resistance.

[0044] Compared with existing technologies, the advantages of this invention are as follows: The manufacturing process of this invention is a continuous, synchronous composite molding process involving mixed plasticizing and two-stage extrusion. No downtime is required between each step, thus enabling 24-hour uninterrupted production with high efficiency. Continuous production allows for precise control and online monitoring, ensuring product quality stability and consistency; it also reduces waste of raw materials and energy, lowering production costs. The material flowability is better, and the venting effect is improved; this helps avoid problems such as bubbles and product surface defects, improving product quality and reducing the defect rate. Detailed Implementation

[0045] The technical solution of the present invention will be further described below with reference to specific embodiments.

[0046] Example 1: A method for manufacturing a modified polyolefin / polyester board, wherein the substrate board is a solid layer, which is modified by a single method, and the solid layer is modified by grafting. The specific components and weight parts are: 100 parts of polyolefin / polyester, 5 parts of maleic anhydride, and 500 parts of calcium carbonate. The polyolefin / polyester is PE and PET, which are recycled materials. The manufacturing method includes the following steps: weighing and mixing the required raw materials and adding them to a mixing unit for mixing and plasticizing. The mixing unit first heat-mixes to 130°C, then discharges the material into a cold mixing unit to cool and mix to 50°C, and then adds it to a two-stage extruder unit. The first-stage reactive extruder first reacts and modifies the material at 210°C, and the second-stage extruder extrudes the material into a die at 190°C. After forming, the material enters a roll forming machine at 180°C, where it is first roll-pressed to form a composite patterned film layer and a wear-resistant layer. Then, at 90°C, it is roll-pressed to form a composite sound-absorbing pad. After cooling and forming, it is cut to form a polyolefin / polyester sheet. The wear-resistant layer of the polyolefin / polyester sheet is coated with a UV coating and cured to form a UV coating. Finally, the sheet is cut, grooved, and packaged to form the polyolefin / polyester sheet.

[0047] Example 2: A method for manufacturing a modified polyolefin / polyester board, wherein the substrate board is a solid layer, using a single modification method, and the solid layer uses a coupling modification method. The specific components and weight parts are: 100 parts polyolefin / polyester, 6 parts silane coupling agent, and 50 parts calcium carbonate. The polyolefin / polyester is a composite of PE, PP, PB, PET, and PETG, all of which are recycled materials. The specific manufacturing method is the same as in Example 1.

[0048] Example 3: A method for manufacturing a modified polyolefin / polyester board, wherein the substrate board is a foamed layer, employing various modifications. The specific components and their weight parts are: 100 parts polyolefin / polyester, 5 parts maleic anhydride, 7 parts silane coupling agent, 50 parts fiber, 10 parts rubber or elastomer, 250 parts calcium carbonate, 15 parts flame retardant, and 2 parts chemical foaming agent. The polyolefin / polyester is a composite of PP, PB, and PET, all of which are recycled materials. The rubber or elastomer is a composite of SBS, EPDM, and NBR. The fiber is a composite of plant fiber and inorganic fiber. The specific manufacturing method is the same as in Example 1.

[0049] Example 4: A method for manufacturing a modified polyolefin / polyester board, wherein the substrate board is a solid layer, which is modified by a single process, and the solid layer is modified by a blend process. The specific components and parts by weight are: 100 parts of polyolefin / polyester, 10 parts of rubber or elastomer, 500 parts of calcium carbonate, and 15 parts of flame retardant. The polyolefin / polyester is PE and PB, which are recycled materials; the rubber or elastomer is TPU and EVA. The manufacturing method includes the following steps: weighing and mixing the required raw materials and adding them to a mixing unit for mixing and plasticizing. The mixing unit first heat-mixes to 130°C, then discharges the material into a cold mixing unit to cool and mix to 50°C, and then adds it to a two-stage extrusion unit. The first-stage reactive extruder first reacts and modifies the material at 200°C, and the second-stage extruder extrudes the material into a die at 180°C. After the material enters a roll forming machine, it is rolled to a fixed thickness at 180°C, cooled, and cut to form a polyolefin / polyester substrate board. Under the conditions of 10 MPa pressure, 190°C temperature, and 200 s time, melamine patterned wear-resistant paper and melamine balance paper are simultaneously hot-pressed onto the top and bottom of the polyolefin / polyester substrate board, respectively. Adhesive is applied by roller to bond the sound-absorbing pad, and the board is then cut, grooved, and packaged to form the polyolefin / polyester board.

[0050] Example 5: A method for manufacturing a modified polyolefin / polyester board, wherein the substrate board is a foamed layer, which is modified using a single method. The foamed layer is fiber-reinforced and modified with the following specific components and weight parts: 100 parts polyolefin / polyester, 20 parts fiber, 50 parts calcium carbonate, and 0.8 parts chemical foaming agent. The polyolefin / polyester is PB, which is a recycled material; the fiber is a chemical fiber. The specific manufacturing method is the same as in Example 4.

[0051] Example 6: A method for manufacturing a modified polyolefin / polyester board, wherein the substrate board is a foamed layer, employing various modifications. The specific components and their weight parts are: 100 parts polyolefin / polyester, 3 parts maleic anhydride, 8 parts silane coupling agent, 30 parts fiber, 18 parts rubber or elastomer, 300 parts calcium carbonate, 12 parts flame retardant, and 2 parts chemical foaming agent. The polyolefin / polyester is a composite of PE, PP, PB, PET, and PETG, all of which are recycled materials. The rubber or elastomer is a composite of SBS and NBR, and the fiber is an inorganic fiber. The specific manufacturing method is the same as in Example 4.

[0052] Comparative Example 1: A method for manufacturing a modified polyolefin / polyester board, wherein the substrate board is a solid layer, using single modification, and the solid layer is grafted modified. The specific components and weight parts are: 100 parts polyolefin / polyester, 5 parts maleic anhydride, and 500 parts calcium carbonate. The polyolefin / polyester is PE and PET, which are recycled materials. The manufacturing method includes the following steps: weighing and mixing the required raw materials and adding them to a two-stage extrusion unit; the first-stage reactive extruder first reacts and modifies the material at 210°C; the second-stage extruder extrudes the material into a die at 190°C, and then the material enters a roll forming machine at 180°C to roll-press a composite patterned film layer and a wear-resistant layer, and then roll-presses a composite sound-absorbing pad at 90°C; cooling and shaping are then performed to form a large polyolefin / polyester board; a UV coating is applied to the wear-resistant layer of the large polyolefin / polyester board and cured by UV light; the board is then cut, grooved, and packaged to form the polyolefin / polyester board.

[0053] Comparative Example 2: A method for manufacturing a modified polyolefin / polyester board, wherein the substrate board is a solid layer, using single modification, and the solid layer is grafted modified. The specific components and weight parts are: 100 parts polyolefin / polyester, 5 parts maleic anhydride, and 500 parts calcium carbonate. The polyolefin / polyester is PE and PET, which are recycled materials. The manufacturing method includes the following steps: weighing and mixing the required raw materials and adding them to a mixing unit for mixing and plasticizing. The mixing unit first hot mixes to 130°C, then discharges the material into a cold mixing unit to cool and mix to 50°C, and then adds it to an extruder. Under 210°C, the material is first extruded and molded, and then enters a roll forming machine. Under 180°C, the roll forming unit first rolls and presses a composite patterned film layer and a wear-resistant layer, and then rolls and presses a composite sound-absorbing pad under 90°C. After cooling and molding, it is cut to form a large polyolefin / polyester board. The wear-resistant layer of the large polyolefin / polyester board is coated with a UV coating and cured to form a UV coating. The board is then cut, grooved, and packaged to form the polyolefin / polyester board.

[0054] Performance tests were performed on the above embodiments and comparative examples:

[0055] The maximum force test, i.e., the strength (rigidity) test, was conducted according to the standard ASTM D1037. All samples were 4mm thick with a 1.0mm sound-absorbing pad, 25mm wide, and 152mm long. The test speed was 3mm / min, and the distance between the center points of the two supports was 72mm. The floor interlocking section strength test was performed using a universal tensile testing machine. All samples were 4mm thick with a 1.0mm sound-absorbing pad, and the universal tensile testing machine's test speed was 50mm / min.

[0056] The above description is only for explanation of the present invention and is not intended to limit the invention. The scope of the present invention is defined by the claims. Within the scope of protection of the present invention, any form of modification may be made.

Claims

1. A modified polyolefin / polyester plate, comprising a polyester / polyolefin base plate obtained by mixing plasticizing, double-stage extrusion in a continuous method, and a composite layer compounded on one side or both sides of the polyester / polyolefin base plate, wherein the polyester / polyolefin base plate is a solid layer or a foamed layer.

2. The modified polyolefin / polyester sheet according to claim 1, characterized in that: The composite layer comprises a UV coating layer, a wear-resistant layer, a pattern film layer and a soundproof pad layer, and the modified polyolefin / polyester plate is formed by roll pressing the wear-resistant layer, the pattern film layer and the soundproof pad on the polyester / polyolefin base plate, roll coating UV paint and photocuring to form the UV coating layer, and cutting, grooving and packaging, wherein the surface of the modified polyolefin / polyester plate contains simulated three-dimensional texture.

3. The modified polyolefin / polyester sheet according to claim 1, characterized in that: The composite layer comprises melamine pattern wear-resistant paper, melamine balance paper, an adhesive and a soundproof pad layer, and the modified polyolefin / polyester plate is formed by synchronously hot pressing the melamine pattern wear-resistant paper and the melamine balance paper on the polyester / polyolefin base plate, respectively, roll coating the adhesive and attaching the soundproof pad layer, wherein the surface of the modified polyolefin / polyester plate contains simulated three-dimensional texture.

4. The modified polyolefin / polyester sheet according to any one of claims 1 to 3, characterized in that: The foamed layer is obtained by adding 0.5-3 parts of a chemical foaming agent to the components of the solid layer and extruding and foaming, or by physically foaming by introducing a certain amount of carbon dioxide or nitrogen gas when the solid layer is extruded.

5. The modified polyolefin / polyester sheet according to any one of claims 1 to 3, characterized in that: The solid layer is modified by grafting, blending, coupling / crosslinking or fiber reinforcement.

6. The modified polyolefin / polyester sheet according to claim 5, characterized in that: The solid layer is modified by grafting, and the specific components and weight parts are as follows: Polyolefin / polyester 100 parts Maleic anhydride 1-10 parts Calcium carbonate 50-500 parts The solid layer is modified by blending, and the specific components and weight parts are as follows: Polyolefin / polyester 100 parts Rubber or elastomer 5-20 parts Calcium carbonate 50-500 parts Flame retardant 10-20 parts The solid layer is modified by coupling, and the specific components and weight parts are as follows: Polyolefin / polyester 100 parts Silane coupling agent 5-10 parts Calcium carbonate 50-500 parts The solid layer is modified by fiber reinforcement, and the specific components and weight parts are as follows: Polyolefin / polyester 100 parts ​ ​ ​ ​ ​ ​ ​ Fiber 20-80 parts Calcium carbonate 50-500 parts The solid layer is modified in multiple ways, and the specific components and parts by weight are as follows: Polyolefin / polyester 100 parts Maleic anhydride 1-10 parts Silane coupling agent 5-10 parts Fiber 20-80 parts Rubber or elastomer 5-20 parts Calcium carbonate 50-500 parts Flame retardant 10-20 parts.

7. The modified polyolefin / polyester sheet according to claim 6, characterized in that: The polyolefin / polyester is one or several of PE, PP, PB, PET, and PETG, which is recycled or new material, the rubber or elastomer is one or several of SBS, TPE, TPU, EPDM, NBR, and EVA, and the fiber is one or several of plant fiber, inorganic fiber, and chemical fiber.

8. The modified polyolefin / polyester sheet according to claim 7, characterized in that: The double-stage extrusion is a combination of two extruders, the material is mixed by mass fraction and then added to the first reaction-type extruder for extrusion, and then added to the second double-screw extruder for extrusion.

9. The modified polyolefin / polyester sheet according to claim 8, characterized in that: The soundproof pad layer is a composite soundproof pad rolled on the lower surface of the polyester / polyolefin base plate.

10. A method of manufacturing the modified polyolefin / polyester sheet according to any one of claims 2, 4 to 9, characterized by: The base plate is a solid layer or a foamed layer, which is modified in single or multiple ways, including the following steps: weighing and mixing the required raw materials and adding them to a mixing unit for mixing and plasticizing, the mixing unit is heated and mixed to 120-140°C, the discharged material is cooled and mixed to 50°C, then added to a double-stage extruder, the first reaction-type extruder is used to modify the material at 180-240°C, the second extruder is used to extrude the material into a mold at 160-220°C, then added to a roller forming machine, the roller forming machine is used to roll and composite the pattern film layer and the wear-resistant layer at 160-200°C, then roll and composite the soundproof pad at 80-100°C, and finally cooled, formed, and cut to form a polyolefin / polyester large plate, the wear-resistant layer of the polyolefin / polyester large plate is coated with UV paint and photocured to form a UV coating, and then cut, grooved, and packaged to form the polyolefin / polyester plate.

11. A method for producing the modified polyolefin / polyester sheet according to any one of claims 3 to 9, characterized by: The base plate is a solid layer or a foamed layer, and is modified by single modification or multiple modifications, including the following steps: weighing and mixing the required raw materials, adding them into a mixing unit for plasticizing and mixing, the mixing unit is first heated and mixed to 120-140 DEG C, the material is discharged into a cold mixing and cooling unit for mixing and cooling to 50 DEG C, then a double-stage extruder is added, the first-stage reaction-type extruder is used to modify the material at 180-240 DEG C, the second-stage extruder is used to form a mold at 160-220 DEG C, then a roller forming machine is added, the material is rolled to a certain thickness at 160-200 DEG C, and then cooled, cut and formed into a polyolefin / polyester base plate, melamine pattern wear-resistant paper and melamine balance paper are synchronously hot-pressed on the upper and lower surfaces of the polyolefin / polyester base plate at a pressure of 3-18 Mpa, a temperature of 150-220 DEG C and a time of 30-600 s, a roller is used to coat an adhesive to adhere a silent pad, and then the polyolefin / polyester base plate is cut, grooved and packaged to form the polyolefin / polyester plate.

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