Aqueous personal care rinse off composition

Abstract

Aqueous personal care composition is provided, comprising: aqueous vehicle; amphoteric surfactant selected from alkyl betaine, alkyl amphoacetate, alkyl sultaine and mixtures thereof; and mixture of alkyl polyglycosides comprising: linear alkyl polyglucoside of formula A R1-O-(G)nH (A) R1=linear C6-15 alkyl; n=1-5; G=glucose; and branched alkyl polysaccharide of formula B (B) R2=C2 alkyl; R3=linear / branched C4 alkyl; g=1-5; S=monosaccharide with 5-6 carbons; with proviso R1=linear C9-15 alkyl in at least some of linear alkyl polyglucoside of formula A; with proviso mixture of alkyl polyglycosides comprises <15wt% of compound of formula I (I) R4=linear / branched C3-4 alkyl; R5=linear / branched C5-6 alkyl; G1=monosaccharide with 4-6 carbons and x=1.1-4; with proviso mixture of alkyl polyglycosides comprises 0-35wt% of compound of formula III (III) R6=-(CH2)mCH(CH3)2; R7=-(CH2)m+2CH(CH3)2; G3=monosaccharide with 4-6 carbons; z=1.1-4 and m=0-3; and with proviso mixture of alkyl polyglycosides comprises <3wt% of compound of formula IV (IV) R12=-(CH2) p CH3; R13=-(CH2) p +1CH(CH3)2; G6=monosaccharide with 4-6 carbons; wherein p=1-4; f=1.1-10.

Description

AQUEOUS PERSONAL CARE RINSE OFF COMPOSITION

[0001] The present invention relates to an aqueous personal care rinse off composition. In particular, the present invention relates to an aqueous personal care rinse off composition, comprising: (a) a dermatologically acceptable aqueous vehicle; (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof; and (c) a mixture of alkyl polyglycosides comprising: a linear alkyl polyglucoside of formula AR1-O-(G)nH (A) wherein R1is a linear Ce-is alkyl group; wherein n is an average of 1 to 5; wherein G is a monosaccharide of glucose; and a branched alkyl polysaccharide of formula Bwherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5; wherein S is a monosaccharide with 5 or 6 carbon atoms; with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl polyglucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula Iwherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IIIwherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; and with the proviso that the mixture of alkyl polyglycosides comprises < 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula TVwherein R12is -(CH2)PCH3; wherein R13is -(CH2)P+ICH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10.

[0002] There is an increasing demand for biosourced, biodegradable surfactants to replace petrochemical derived surfactants. While sugar based surfactants have been on the market for some time, they have several shortcomings that have hindered market adoption, including poor water solubility, especially in the presence of salts, and poor foaming / cleaning performance. Recent efforts have sought to overcome the poor foaming / cleaning performance by exploring sugar based surfactant with branched hydrophobes. However, such materials have lower water solubility than sugar based surfactants with linear hydrophobes, resulting in poor foaming / cleaning performance.

[0003] Conventionally, the poor foaming performance of sugar based and amphoteric surfactants is addressed through formulating with anionic primary surfactants. However, regulations around 1,4 dioxane and consumer trends in personal care products towards "sulfate-free" and more mild surfactants have driven a need to achieve high foaming performance while reducing or eliminating the use of anionic surfactants.

[0004] Accordingly, there remains a need for alternative surfactant systems that facilitate aqueous personal care rinse off formulations having acceptable foaming / cleaning performance without the incorporation of anionic surfactants.

[0005] The present invention provides an aqueous personal care rinse off composition, comprising: (a) a dermatologically acceptable aqueous vehicle; (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof; and (c) a mixture of alkyl polyglycosides comprising: a linear alkyl polyglucoside of formula AR1-O-(G)nH (A)wherein R1is a linear Ce-is alkyl group; wherein n is an average of 1 to 5; wherein G is a monosaccharide of glucose; and a branched alkyl polysaccharide of formula Bwherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5; wherein S is a monosaccharide with 5 or 6 carbon atoms; with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl polyglucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula Iwherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IIIwherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; and with the proviso that the mixture of alkyl polyglycosides comprises < 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IVwherein R12is -(CH2)pCH3; wherein R13is -(CH2)P+ICH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10.

[0006] The present invention provides an aqueous personal care rinse off composition, comprising: (a) a dermatologically acceptable aqueous vehicle; (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof; and (c) a mixture of alkyl polyglycosides comprising: 65 to 99 wt%, based on weight of the mixture of alkyl polyglycosides, of a linear alkyl polyglucoside of formula A; wherein R1is a linear Ce-is alkyl group; wherein n is an average of 1 to 5; wherein G is a monosaccharide of glucose; and 1 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a branched alkyl polysaccharide of formula B; wherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5; wherein S is a monosaccharide with 5 or 6 carbon atoms; with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl polyglucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula I; wherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula III; wherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; and with the proviso that the mixture of alkyl polyglycosides comprises < 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IV; wherein R12is -(CH2)PCH3; wherein R13is -(CFh^iCHCCHs^; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / 'is 1.1 to 10.

[0007] The present invention provides an aqueous personal care rinse off composition, comprising: (a) a dermatologically acceptable aqueous vehicle; (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof; and (c) a mixture of alkyl polyglycosides comprising: 65 to 99 wt%, based on weight of the mixture of alkyl polyglycosides, of a linear alkyl polyglucoside of formula A; wherein R1is a linear Ce-is alkyl group; wherein n is an average of 1 to 5; wherein G is a monosaccharide of glucose; and 1 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a branched alkylpolysaccharide of formula B; wherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5; wherein S is a monosaccharide with 5 or 6 carbon atoms; with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl poly glucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt%, based on weight of the mixture of alkyl poly glycosides, of a compound of formula I; wherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1 .1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula ID; wherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; with the proviso that the mixture of alkyl polyglycosides comprises < 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IV; wherein R12is -(CH2)pCH3; wherein R13is -(CH2)p+iCH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10; and wherein the linear alkyl polyglucoside of formula A and the branched alkyl polysaccharide of formula B comprise 95 to 100 wt% of all alkyl polyglycosides in the aqueous personal care rinse off composition.

[0008] The present invention provides an aqueous personal care rinse off composition, comprising: (a) a dermatologically acceptable aqueous vehicle; (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof; and (c) a mixture of alkyl polyglycosides comprising: 65 to 99 wt%, based on weight of the mixture of alkyl polyglycosides, of a linear alkyl polyglucoside of formula A; wherein R1is a linear C6-15 alkyl group; wherein n is an average of 1 to 5; wherein G is a monosaccharide of glucose; and 1 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a branched alkyl polysaccharide of formula B; wherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5; wherein S is a monosaccharide with 5 or 6 carbon atoms; with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl poly glucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula I; wherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbonatoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula III; wherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; with the proviso that the mixture of alkyl polyglycosides comprises< 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IV; wherein R12is -(CH2)PCH3; wherein R13is -(CH2)p+iCH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10; wherein the linear alkyl polyglucoside of formula A and the branched alkyl polysaccharide of formula B comprise 95 to 100 wt% of all alkyl polyglycosides in the aqueous personal care rinse off composition; and wherein the aqueous personal care rinse off composition comprises < 1 wt%, based on weight of the personal care rinse off composition, of an anionic surfactant.

[0009] The present invention provides an aqueous personal care rinse off composition, comprising: (a) a dermatologically acceptable aqueous vehicle; (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof; and (c) a mixture of alkyl polyglycosides comprising: 65 to 99 wt%, based on weight of the mixture of alkyl polyglycosides, of a linear alkyl polyglucoside of formula A; wherein R1is a linear Ce-is alkyl group; wherein n is an average of 1 to 5; wherein G is a monosaccharide of glucose; and 1 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a branched alkyl polysaccharide of formula B; wherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5; wherein S is a monosaccharide with 5 or 6 carbon atoms; with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl polyglucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula I; wherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula III; wherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; with the proviso that the mixture of alkyl polyglycosides comprises< 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formulaIV; wherein R12is -(CH2)pCHa; wherein R13is -(CH2)P+ICH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10; wherein the linear alkyl polyglucoside of formula A and the branched alkyl polysaccharide of formula B comprise 95 to 100 wt% of all alkyl poly glycosides in the aqueous personal care rinse off composition; wherein the aqueous personal care rinse off composition comprises < 1 wt%, based on weight of the personal care rinse off composition, of an anionic surfactant; wherein the aqueous personal care rinse off composition comprises < 0.05 wt%, based on weight of the mixture of alkyl polyglycosides, of a fatty acid alkyl ester alkoxylate of formula VR14CO2-(AO)h-R15(V) wherein R14is a linear or branched, saturated or unsaturated, alkyl group containing 5 to 21 carbon atoms; wherein AO is a C2-4 alkylene oxide unit; wherein h is 1 to 30 and wherein R15is a linear or branched alkyl group containing 1 to 6 carbon atoms; and wherein the aqueous personal care rinse off composition comprises < 0.01 wt%, based on weight of the aqueous personal care rinse off composition, of a fatty acid ester of an alkyl glycoside having a fatty acid residue selected from the group consisting of R17(O)O- and / or R18(O)O-, wherein R17is a C12 or higher hydrocarbon and R18is a Ce-io hydrocarbon.

[0010] The present invention provides an aqueous personal care rinse off composition, comprising: (a) a dermatologically acceptable aqueous vehicle; (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof; and (c) a mixture of alkyl polyglycosides comprising: 65 to 99 wt%, based on weight of the mixture of alkyl polyglycosides, of a linear alkyl polyglucoside of formula A; wherein R1is a linear Ce-is alkyl group; wherein n is an average of 1 to 5; wherein G is a monosaccharide of glucose; and 1 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a branched alkyl polysaccharide of formula B; wherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5; wherein S is a monosaccharide with 5 or 6 carbon atoms; with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl polyglucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula I; wherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of acompound of formula ID; wherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; with the proviso that the mixture of alkyl polyglycosides comprises < 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IV; wherein R12is -(CH2)PCH3; wherein R13is -(CH2)P+ICH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10; wherein the linear alkyl polyglucoside of formula A and the branched alkyl polysaccharide of formula B comprise 95 to 100 wt% of all alkyl poly glycosides in the aqueous personal care rinse off composition; wherein the aqueous personal care rinse off composition comprises < 0.01 wt%, based on weight of the personal care rinse off composition, of an anionic surfactant; wherein the aqueous personal care rinse off composition comprises < 0.05 wt%, based on weight of the mixture of alkyl polyglycosides, of a fatty acid alkyl ester alkoxylate of formula V; wherein R14is a linear or branched, saturated or unsaturated, alkyl group containing 5 to 21 carbon atoms; wherein AO is a C2-4 alkylene oxide unit; wherein h is 1 to 30 and wherein R15is a linear or branched alkyl group containing 1 to 6 carbon atoms; and wherein the aqueous personal care rinse off composition comprises < 0.01 wt%, based on weight of the aqueous personal care rinse off composition, of a fatty acid ester of an alkyl glycoside having a fatty acid residue selected from the group consisting of R17(O)O- and / or R18(O)O-, wherein R17is a C12 or higher hydrocarbon and R18is a Ce-io hydrocarbon.

[0011] The present invention provides an aqueous personal care rinse off composition, comprising: (a) a dermatologically acceptable aqueous vehicle; (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof; and (c) a mixture of alkyl polyglycosides comprising: 65 to 99 wt%, based on weight of the mixture of alkyl polyglycosides, of a linear alkyl polyglucoside of formula A; wherein R1is a linear Ce-is alkyl group; wherein n is an average of 1 to 5; wherein G is a monosaccharide of glucose; and 1 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a branched alkyl polysaccharide of formula B; wherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5; wherein S is a monosaccharide with 5 or 6 carbon atoms; with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl poly glucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt%, based on weight of the mixture of alkyl poly glycosides, of a compound of formula I; wherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula III; wherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; with the proviso that the mixture of alkyl polyglycosides comprises < 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IV; wherein R12is -(CHz^CHs; wherein R13is -(CH2)P+ICH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10; wherein the linear alkyl polyglucoside of formula A and the branched alkyl polysaccharide of formula B comprise 95 to 100 wt% of all alkyl poly glycosides in the aqueous personal care rinse off composition; wherein the aqueous personal care rinse off composition comprises < 0.01 wt%, based on weight of the personal care rinse off composition, of an anionic surfactant; wherein the aqueous personal care rinse off composition comprises < 0.05 wt%, based on weight of the mixture of alkyl polyglycosides, of a fatty acid alkyl ester alkoxylate of formula V; wherein R14is a linear or branched, saturated or unsaturated, alkyl group containing 5 to 21 carbon atoms; wherein AO is a C2-4 alkylene oxide unit; wherein h is 1 to 30 and wherein R15is a linear or branched alkyl group containing 1 to 6 carbon atoms; wherein the aqueous personal care rinse off composition comprises < 0.01 wt%, based on weight of the aqueous personal care rinse off composition, of a fatty acid ester of an alkyl glycoside having a fatty acid residue selected from the group consisting of R17(O)O- and / or R18(O)O-, wherein R17is a C12 or higher hydrocarbon and R18is a Ce-io hydrocarbon; and wherein at least 5 wt% of the linear alkyl polyglucoside of formula A is a linear C10 alkyl polyglucoside.

[0012] The present invention provides an aqueous personal care rinse off composition, comprising: (a) a dermatologically acceptable aqueous vehicle; (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof; and (c) a mixture of alkyl polyglycosides comprising: 65 to 99 wt%, based on weight of the mixture of alkyl polyglycosides, of a linear alkyl polyglucoside of formula A; wherein R1is a linear C6-15 alkyl group; wherein n is an average of 1 to 5; wherein G is a monosaccharide of glucose; and 1 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a branched alkyl polysaccharide of formula B; wherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5; wherein S is a monosaccharidewith 5 or 6 carbon atoms; with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl polyglucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula I; wherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula III; wherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; with the proviso that the mixture of alkyl polyglycosides comprises < 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IV; wherein R12is -(CH2 / >CH3; wherein R13is -(CH2)p+iCH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10; wherein the linear alkyl polyglucoside of formula A and the branched alkyl polysaccharide of formula B comprise 95 to 100 wt% of all alkyl polyglycosides in the aqueous personal care rinse off composition; wherein the aqueous personal care rinse off composition comprises < 0.01 wt%, based on weight of the personal care rinse off composition, of an anionic surfactant; wherein the aqueous personal care rinse off composition comprises < 0.05 wt%, based on weight of the mixture of alkyl polyglycosides, of a fatty acid alkyl ester alkoxylate of formula V; wherein R14is a linear or branched, saturated or unsaturated, alkyl group containing 5 to 21 carbon atoms; wherein AO is a C2-4 alkylene oxide unit; wherein h is 1 to 30 and wherein R15is a linear or branched alkyl group containing 1 to 6 carbon atoms; wherein the aqueous personal care rinse off composition comprises < 0.01 wt%, based on weight of the aqueous personal care rinse off composition, of a fatty acid ester of an alkyl glycoside having a fatty acid residue selected from the group consisting of R17(O)O- and / or R18(O)O-, wherein R17is a C12 or higher hydrocarbon and R18is a Ce-io hydrocarbon; and wherein the linear alkyl polyglucoside of formula A is a blend comprising 10 to 90 wt%, based on weight of the blend, of a linear Cs alkyl polyglucoside and 10 to 90 wt%, based on weight of the blend, of a linear C10 alkyl poly glucoside.

[0013] The present invention provides a method of cleaning at least one of mammalian skin and hair, comprising: applying an aqueous personal care rinse off composition of the present invention to the skin or hair of a mammal; and rinsing the aqueous personal care rinse off composition from the skin or hair with a rinse water.DETAILED DESCRIPTION

[0014] We have found that aqueous personal care rinse off compositions comprising a combination of an amphoteric surfactant (e.g., cocamidopropyl betaine) with a mixture of alkyl polyglycosides comprising a linear alkyl polyglucoside of formula AR1-O-(G)nH (A) wherein R1is a linear C6-15 alkyl group; wherein n is an average of 1 to 5; wherein G is a monosaccharide of glucose; and a branched alkyl polysaccharide of formula Bwherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5; wherein S is a monosaccharide with 5 or 6 carbon atoms; provide surprising boost in foaming performance.

[0015] Unless otherwise indicated, ratios, percentages, parts, and the like are by weight.

[0016] As used herein, unless otherwise indicated, the phrase "molecular weight" or MW refers to the weight average molecular weight as measured in a conventional manner with gel permeation chromatography (GPC) and conventional standards, such as polystyrene molecular weight standards. GPC techniques are discussed in detail in Modem Size Exclusion Liquid Chromatography - Practice of Gel Permeation and Gel Filtration Chromatography, Second Edition, A.M. Striegel, W. W. Yau, J. J. Kirkland, D. D. Bly; John Wiley & Sons, Inc. 2009. Molecular weights are reported herein in units of Daltons, or equivalently, g / mol.

[0017] The term "dermatologically acceptable" as used herein and in the appended refers to ingredients that are typically used for topical application to the skin, and is intended to underscore that materials that are toxic when present in the amounts typically found in skin care compositions are not contemplated as part of the present invention.

[0018] Preferably, the aqueous personal care rinse off composition of the present invention is selected from the group consisting of a shampoo, a conditioning shampoo, a body wash, an exfoliating body wash, a facial wash, an exfoliating facial wash, a Equid hand soap and a hand dish wash. More preferably, the aqueous personal care rinse off composition of the present invention is selected from the group consisting of a shampoo, a conditioning shampoo, body wash and a facial wash. Most preferably, the aqueous personal care rinse offcomposition of the present invention is selected from the group consisting of a shampoo and a body wash.

[0019] Preferably, the aqueous personal care rinse off composition of the present invention, comprises: (a) a dermatologically acceptable aqueous vehicle (preferably, 45 to 99.91 wt% (more preferably, 60 to 98 wt%; still more preferably, 70 to 94 wt%; most preferably, 80 to 92 wt%), based on weight of the aqueous personal care rinse off composition, of the dermatologically acceptable aqueous vehicle); (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof (preferably, 0.04 to 25 wt% (more preferably, 1 to 20 wt%; still more preferably, 4 to 15 wt%; most preferably, 5 to 10 wt%), based on weight of the aqueous personal care rinse off composition of, the dermatologically acceptable amphoteric cleaning surfactant) (preferably, wherein the dermatologically acceptable amphoteric cleaning surfactant is selected from the group consisting of an alkyl betaine, an alkyl sultaine and mixtures thereof; more preferably, wherein the dermatologically acceptable amphoteric cleaning surfactant is selected from the group consisting of cocamidopropyl betaine, cocamidopropyl hydroxysultaine and mixtures thereof; still more preferably, wherein the dermatologically acceptable amphoteric cleaning surfactant includes cocamidopropyl betaine; most preferably, wherein the dermatologically acceptable cleaning surfactant is cocamidopropyl betaine); and (c) a mixture of alkyl polyglycosides (preferably, 0.05 to 30 wt% (more preferably, 1 to 20 wt%; still more preferably, 2 to 15 wt%; most preferably, 3 to 10 wt%), based on weight of the aqueous personal care rinse off composition, of the mixture of alkyl polyglycosides) comprising: a linear alkyl polyglucoside of formula A (preferably, 65 to 99 wt% (more preferably, 70 to 95 wt%; still more preferably, 75 to 92.5 wt%; most preferably, 80 to 90 wt%), based on weight of the mixture of alkyl polyglycosides, of the linear alkyl polyglucoside of formula A)R1-O-(G)nH (A) wherein R1is a linear Ce-is alkyl group (preferably, a linear Cs-i4 alkyl group; more preferably, a linear Cs-io alkyl group; still more preferably, at least one of a linear Cs alkyl group and a linear Cio alkyl group; most preferably, a blend of a linear Cs alkyl group and a linear Cio alkyl group); wherein n is an average of 1 to 5 (preferably, 1 to 3; more preferably, 1 to 2; most preferably, 1.1 to 2); wherein G is a monosaccharide of glucose; and a branched alkyl polysaccharide of formula B (preferably, 1 to 35 wt% (more preferably, 5 to 30 wt%;still more preferably, 7.5 to 25 wt%; most preferably, 10 to 20 wt%), based on weight of the mixture of alkyl poly glycosides, of the branched alkyl polysaccharide of formula B)wherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5 (preferably, 1 to 3; more preferably, 1 to 2; most preferably, 1.1 to 2); wherein S is a monosaccharide with 5 or 6 carbon atoms (preferably, ribulose, xylulose, ribose, arabinose, xylose, lyxose, galactose, mannose, glucose and mixtures thereof; more preferably, arabinose, xylose, glucose and mixtures thereof; still more preferably, xylose, glucose and mixtures thereof; most preferably, xylose); with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl polyglucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt% (preferably, 1 to 14 wt%; more preferably, 2 to 12.5 wt%; still more preferably, 5 to 12 wt%; most preferably, 8 to 11 wt%), based on weight of the mixture of alkyl polyglycosides, of a compound of formula Iwherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt% (preferably, 0 to 30 wt%; more preferably, 0 to 25 wt%; still more preferably, 0 to 20 wt%; yet more preferably, 0 to 15 wt%; still yet more preferably, 0 to 10 wt%; most preferably, less than the detectable limit), based on weight of the mixture of alkyl polyglycosides, of a compound of formula inwherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; and with the proviso that the mixture of alkyl polyglycosides comprises < 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IVwherein R12is -(CH2)PCH3; wherein R13is -(CH2)p+iCH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10.

[0020] More preferably, the aqueous personal care rinse off composition of the present invention, comprises: (a) a dermatologically acceptable aqueous vehicle (preferably, 45 to 99.91 wt% (more preferably, 60 to 98 wt%; still more preferably, 70 to 94 wt%; most preferably, 80 to 92 wt%), based on weight of the aqueous personal care rinse off composition, of the dermatologically acceptable aqueous vehicle); (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof (preferably, 0.04 to 25 wt% (more preferably, 1 to 20 wt%; still more preferably, 4 to 15 wt%; most preferably, 5 to 10 wt%), based on weight of the aqueous personal care rinse off composition of, the dermatologically acceptable amphoteric cleaning surfactant) (preferably, wherein the dermatologically acceptable amphoteric cleaning surfactant is selected from the group consisting of an alkyl betaine, an alkyl sultaine and mixtures thereof; more preferably, wherein the dermatologically acceptable amphoteric cleaning surfactant is selected from the group consisting of cocamidopropyl betaine, cocamidopropyl hydroxysultaine and mixtures thereof; still more preferably, wherein the dermatologically acceptable amphoteric cleaning surfactant includes cocamidopropyl betaine; most preferably, wherein the dermatologically acceptable cleaning surfactant is cocamidopropyl betaine); and (c) a mixture of alkyl polyglycosides (preferably, 0.05 to 30 wt% (more preferably, 1 to 20 wt%; still morepreferably, 2 to 15 wt%; most preferably, 3 to 10 wt%), based on weight of the aqueous personal care rinse off composition, of the mixture of alkyl polyglycosides) comprising: a linear alkyl poly glucoside of formula A (preferably, 65 to 99 wt% (more preferably, 70 to 95 wt%; still more preferably, 75 to 92.5 wt%; most preferably, 80 to 90 wt%), based on weight of the mixture of alkyl polyglycosides, of the linear alkyl polyglucoside of formula A); wherein R1is a linear C6-15 alkyl group (preferably, a linear Cs-i4 alkyl group; more preferably, a linear Cs-io alkyl group; still more preferably, at least one of a linear C8 alkyl group and a linear C10 alkyl group; most preferably, a blend of a linear Cs alkyl group and a linear C10 alkyl group); wherein n is an average of 1 to 5 (preferably, 1 to 3; more preferably,I to 2; most preferably, 1.1 to 2); wherein G is a monosaccharide of glucose; and a branched alkyl polysaccharide of formula B (preferably, 1 to 35 wt% (more preferably, 5 to 30 wt%; still more preferably, 7.5 to 25 wt%; most preferably, 10 to 20 wt%), based on weight of the mixture of alkyl polyglycosides, of the branched alkyl polysaccharide of formula B); wherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5 (preferably, 1 to 3; more preferably, 1 to 2; most preferably, 1.1 to 2); wherein S is a monosaccharide with 5 or 6 carbon atoms (preferably, ribulose, xylulose, ribose, arabinose, xylose, lyxose, galactose, mannose, glucose and mixtures thereof; more preferably, arabinose, xylose, glucose and mixtures thereof; still more preferably, xylose, glucose and mixtures thereof; most preferably, xylose); with the proviso that R1is a linear C9- 15 alkyl group in at least some of the linear alkyl polyglucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt% (preferably, 1 to 14 wt%; more preferably, 2 to 12.5 wt%; still more preferably, 5 to 12 wt%; most preferably, 8 toI I wt%), based on weight of the mixture of alkyl polyglycosides, of a compound of formula I; wherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt% (preferably, 0 to 30 wt%; more preferably, 0 to 25 wt%; still more preferably, 0 to 20 wt%; yet more preferably, 0 to 15 wt%; still yet more preferably, 0 to 10 wt%; most preferably, less than the detectable limit), based on weight of the mixture of alkyl polyglycosides, of a compound of formula III; wherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; with the proviso that the mixture of alkyl polyglycosides comprises < 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formulaIV; wherein R12is -(CH2)pCHa; wherein R13is -(CH2)P+ICH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10; and with any one or more of the following additional mixture of alkyl polyglycoside provisos (i)-(ix) (each mixture proviso taken individually, all possible combinations of two or more mixture provisos and combinations of mixture proviso(s) with additional composition proviso(s) discussed subsequently are contemplated):(i) with the proviso that the mixture of alkyl polyglycosides comprises < 1 wt% (preferably, < 0.5 wt%; more preferably, < 0.1 wt%; still more preferably, < 0.01 wt%; yet more preferably, < 0.001 wt%; still yet more preferably, < 0.0001 wt%; most preferably, less than detectable Emit), based on weight of the mixture of alkyl polyglycosides, of an alkyl oligoglucoside of formula nR16-O-(G2)y (D) wherein R16is a branched C9-11 alkyl group; wherein G2is a glucose unit and wherein y is 1.4 to 2.0;(ii) with the proviso that at least 5 wt% (preferably, at least 10 wt%; more preferably, at least 25 wt%; still more preferably, at least 40 wt%; most preferably, at least 45 wt%), based on weight of the linear alkyl polyglucoside of formula A, is a linear C10 alkyl polyglucoside;(iii) with the proviso that the linear alkyl polyglucoside of formula A is a blend comprising a linear Cs alkyl poly glucoside (preferably, 5 to 95 wt% (more preferably, 10 to 90 wt%; still more preferably, 25 to 75 wt%; yet more preferably, 40 to 60 wt%; most preferably, 45 to 55 wt%), based on weight of the blend, of the linear Cs alkyl polyglucoside) and a linear C10 alkyl polyglucoside (preferably, 5 to 95 wt% (more preferably, 10 to 90 wt%; still more preferably, 25 to 75 wt%; yet more preferably, 40 to 60 wt%; most preferably, 45 to 55 wt%), based on weight of the blend, of the linear C10 alkyl poly glucoside);(iv) with the proviso that the mixture of alkyl polyglycosides comprises < 0.2 wt% (preferably, < 0.1 wt%; more preferably, < 0.05 wt%; still more preferably, < 0.01 wt%; yet more preferably, < 0.005 wt%; still yet more preferably, < 0.001 wt%; yet still more preferably, < 0.0001 wt%; most preferably, less than detectable limit), based on weight of the mixture of alkyl poly glycosides, of the compound of formula IV;(v) with the proviso that the mixture of alkyl polyglycosides comprises < 0.05 wt% (preferably, < 0.01 ; more preferably, < 0.005; still more preferably, < 0.001; yet more preferably, < 0.0005; still yet more preferably, < 0.0001 wt%; most preferably, less thandetectable limit), based on weight of the mixture of alkyl polyglycosides, of a fatty acid alkyl ester alkoxylate of formula VR14CO2-(AO)h-R15(V) wherein R14is a linear or branched, saturated or unsaturated, alkyl group containing 5 to 21 carbon atoms; wherein AO is a C2-4 alkylene oxide unit; wherein h is 1 to 30 and wherein R15is a linear or branched alkyl group containing 1 to 6 carbon atoms;(vi) with the proviso that the mixture of alkyl polyglycosides comprises < 0.05 wt% (preferably, < 0.01 wt%; more preferably, < 0.005 wt%; still more preferably, < 0.001 wt%; yet more preferably, < 0.0005 wt%; still yet more preferably, < 0.0001 wt%; most preferably, less than detectable Emit), based on weight of the mixture of alkyl polyglycosides, of the compound of formula III;(vii) with the proviso that the mixture of alkyl polyglucosides comprises < 0.1 wt% (preferably, < 0.05 wt%; more preferably, < 0.01 wt%; still more preferably, < 0.001 wt%; yet more preferably, < 0.0001 wt%; still yet more preferably, < 0.00001 wt%; most preferably, less than detectable Emit), based on weight of the mixture of alkyl polyglucosides, of a compound of formula VIRI9-O-(G7)jtH (VI) wherein R19is a Enear C1-8 alkyl group; wherein G7is a monosaccharide with 5 or 6 carbon atoms and wherein k is an average of 1 to 10;(viii) with the proviso that the mixture of alkyl polyglycosides comprises < 0.1 wt% (preferably, < 0.05 wt%; more preferably, < 0.01 wt%; stiU more preferably, < 0.001 wt%; yet more preferably, < 0.0001 wt%; stiU yet more preferably, < 0.00001 wt%; most preferably, less than detectable limit), based on weight of the mixture of alkyl polyglucosides, of a compound of formula VIIwherein R20is a Enear or branched C2-5 alkyl group; wherein R21is a linear or branched C4-7 alkyl group; wherein the sum of the carbon atoms of R20and R21is 7 to 11; wherein G8is a monosaccharide residue; and wherein r is 1 to 4; and(ix) with the proviso that a 5 wt% concentration of the mixture of alkyl polyglycosides in water has a turbidity of 0 to < 15 Nephelometic Turbidity Units (NTU) measured using a turbidity meter at 20 °C.

[0021] Preferably, the aqueous personal care rinse off composition of the present invention, comprises 45 to 99.91 wt% (preferably, 60 to 98 wt%; more preferably, 70 to 94 wt%; most preferably, 80 to 92 wt%), based on weight of the aqueous personal care rinse off composition, of a dermatologically acceptable aqueous vehicle. More preferably, the aqueous personal care rinse off composition of the present invention, comprises: 45 to 99.91 wt% (preferably, 60 to 98 wt%; more preferably, 70 to 94 wt%; most preferably, 80 to 92 wt%), based on weight of the aqueous personal care rinse off composition, of a dermatologically acceptable aqueous vehicle; wherein the dermatologically acceptable aqueous vehicle comprises water. Still more preferably, the aqueous personal care rinse off composition of the present invention, comprises: 45 to 99.91 wt% (preferably, 60 to 98 wt%; more preferably, 70 to 94 wt%; most preferably, 80 to 92 wt%), based on weight of the aqueous personal care rinse off composition, of a dermatologically acceptable aqueous vehicle; wherein the dermatologically acceptable aqueous vehicle is selected from the group consisting of water and an aqueous Ci-4 alcohol mixture. Most preferably, the aqueous personal care rinse off composition of the present invention, comprises: 45 to 99.91 wt% (preferably, 60 to 98 wt%; more preferably, 70 to 94 wt%; most preferably, 80 to 92 wt%), based on weight of the aqueous personal care rinse off composition, of a dermatologically acceptable aqueous vehicle, wherein the dermatologically acceptable aqueous vehicle is water.

[0022] Preferably, the water used in the aqueous personal care rinse off composition of the present invention is at least one of distilled water and deionized water. More preferably, the water used in the aqueous personal care rinse off composition of the present invention is distilled and deionized.

[0023] Preferably, the aqueous personal care rinse off composition of the present invention, comprises 0.04 to 25 wt% (preferably, 1 to 20 wt%; more preferably, 4 to 15 wt%; most preferably, 5 to 10 wt%), based on weight of the aqueous personal care rinse off composition, of a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof. More preferably, the aqueous personal care rinse off composition of the present invention, comprises 0.04 to 25 wt% (preferably, 1 to 20 wt%; more preferably, 4 to 15 wt%; mostpreferably, 5 to 10 wt%), based on weight of the aqueous personal care rinse off composition, of a dermatologically acceptable amphoteric cleaning surfactant; wherein the dermatologically acceptable amphoteric cleaning surfactant is selected from the group consisting of an alkyl betaine, an alkyl sultaine and mixtures thereof (more preferably, wherein the dermatologically acceptable amphoteric cleaning surfactant is selected from the group consisting of cocamidopropyl betaine, cocamidopropyl hydroxysultaine and mixtures thereof; still more preferably, wherein the dermatologically acceptable amphoteric cleaning surfactant includes cocamidopropyl betaine; most preferably, wherein the dermatologically acceptable cleaning surfactant is cocamidopropyl betaine).

[0024] Preferably, the aqueous personal care rinse off composition of the present invention, comprises 0.05 to 30 wt% (preferably, 1 to 20 wt%; more preferably, 2 to 15 wt%; most preferably, 3 to 10 wt%), based on weight of the aqueous personal care rinse off composition, of a mixture of alkyl polyglycosides comprising: 65 to 99 wt% (preferably, 70 to 95 wt%; still more preferably, 75 to 92.5 wt%; most preferably, 80 to 90 wt%), based on weight of the mixture of alkyl polyglycosides, of a linear alkyl polyglucoside of formula A; wherein R1is a linear Ce-is alkyl group (preferably, a linear Cs-i4 alkyl group; more preferably, a linear Cs-io alkyl group; still more preferably, at least one of a linear Cg alkyl group and a linear Cio alkyl group; most preferably, a blend of a linear Cs alkyl group and a linear Cio alkyl group); wherein n is an average of 1 to 5 (preferably, 1 to 3; more preferably, 1 to 2; most preferably, 1.1 to 2); and wherein G is a monosaccharide of glucose; and 1 to 35 wt% (preferably, 5 to 30 wt%; more preferably, 7.5 to 25 wt%; most preferably, 10 to 20 wt%), based on weight of the mixture of alkyl poly glycosides, of a branched alkyl polysaccharide of formula B; wherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5 (preferably, 1 to 3; more preferably, 1 to 2; most preferably, 1.1 to 2); wherein S is a monosaccharide with 5 or 6 carbon atoms (preferably, ribulose, xylulose, ribose, arabinose, xylose, lyxose, galactose, mannose, glucose and mixtures thereof; more preferably, arabinose, xylose, glucose and mixtures thereof; still more preferably, xylose, glucose and mixtures thereof; most preferably, xylose).

[0025] Preferably, the aqueous personal care rinse off composition of the present invention, further comprises at least one ingredient selected from the group consisting of an absorbent; an aesthetic enhancer (e.g., starch); an alpha hydroxy acid; an antiaging agent; an antidandruff agent; an antifungal; an antimicrobial agent; an antioxidant (e.g., butylated hydroxytoluene); an antiseptic; an antistatic agent; a bioactive agent; a bleaching agent;additional cleaning surfactant; a chelating agent; a colorant; a conditioning agent (e.g., silicone, polyquatemium, cationic guar); a dye; an emollient; an emulsifying agent; a film former (e.g., water proofing agent); a fixative polymer; a foaming agent; a fragrance; a hard particle; a humectant (e.g., glycerin, sorbitol, monoglycerides, lecithins, glycolipids, fatty alcohols, fatty acids, polysaccharides, sorbitan esters, polysorbates (e.g., Polysorbate 20, Polysorbate 40, Polysorbate 60, and Polysorbate 80), diols (e.g., propylene glycol), diol analogs, triols, triol analogs, cationic polymeric polyols); a lubricating agent; an opacifier; a pearlizing agent; a penetrant; a pH adjusting agent; a pigment; a plant extract; a preservative (e.g., benzoic acid, sorbic acid, phenoxyethanol); a protein / amino acid; a rheology modifier; a salt (e.g., NaCl); a sensory modifier; a slip agent; a soap; a soft particle; a solvent (e.g., glycol ethers); a sunscreen additive; a suspending agent; a UV light inhibitor; a vitamin and mixtures thereof.

[0026] Preferably, the aqueous personal care rinse off composition of the present invention comprises 0 to 25 wt% (preferably, 0.5 to 20 wt%; more preferably, 1 to 15 wt%; most preferably, 2 to 10 wt%), based on weight of the aqueous personal care rinse off composition, of an additional cleaning surfactant. Preferably, the aqueous personal care rinse off composition of the present invention comprises 0 to 25 wt% (preferably, 0.5 to 20 wt%; more preferably, 1 to 15 wt%; most preferably, 2 to 10 wt%), based on weight of the aqueous personal care rinse off composition, of an additional cleaning surfactant; wherein the additional cleaning surfactant is selected from the group consisting of cationic surfactants and nonionic surfactants.

[0027] Preferably, the aqueous personal care rinse off composition of the present invention, further comprises 0 to 10 wt% (preferably, 0 to 3 wt%), based on weight of the aqueous personal care rinse off composition, of a salt (e.g., NaCl).

[0028] Preferably, the aqueous personal care rinse off composition of the present invention, further comprises an antimicrobial agent. More preferably, the aqueous personal care rinse off composition of the present invention, further comprises an antimicrobial agent; wherein the antimicrobial agent is selected from the group consisting of phenoxyethanol, benzoic acid, benzyl alcohol, sodium benzoate, DMDM hydantoin, 2-ethylhexyl glyceryl ether and isothiazolinone (e.g., methylchloroisothiazolinone, methylisothiazolinone). Still more preferably, the aqueous personal care rinse off composition of the present invention, further comprises an antimicrobial agent; wherein the antimicrobial agent is an isothiazolinone (more preferably, wherein the antimicrobial is selected from the group consisting ofmethylisothiazolinone, methylchloroisothiazolinone and mixtures thereof; most preferably, wherein the biocide is methylisothiazolinone).

[0029] Preferably, the aqueous personal care rinse off composition of the present invention, further comprises a pH adjusting agent. More preferably, the aqueous personal care rinse off composition of the present invention, further comprises a pH adjusting agent; wherein the aqueous personal care rinse off composition has a pH of 4.5 to 9 (preferably, 5 to 8; most preferably, 5 to 7).

[0030] Preferably, the pH adjusting agent is selected from the group consisting of at least one of citric acid, lactic acid, hydrochloric acid, aminoethyl propanediol, triethanolamine, monoethanolamine, sodium hydroxide, potassium hydroxide, amino-2-methyl-l -propanol. More preferably, the pH adjusting agent is selected from the group consisting of at least one of citric acid, lactic acid, sodium hydroxide, potassium hydroxide, triethanolamine, amino-2-methyl-l -propanol. Still more preferably, the pH adjusting agent includes is triethanolamine. Most preferably, the pH adjusting agent is triethanolamine.

[0031] Preferably, the aqueous personal care rinse off composition of the present invention, comprises: (a) a dermatologically acceptable aqueous vehicle (preferably, 45 to 99.91 wt% (more preferably, 60 to 98 wt%; still more preferably, 70 to 94 wt%; most preferably, 80 to 92 wt%), based on weight of the aqueous personal care rinse off composition, of the dermatologically acceptable aqueous vehicle); (b) a dermatologically acceptable amphoteric cleaning surfactant selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof (preferably, 0.04 to 25 wt% (more preferably, 1 to 20 wt%; still more preferably, 4 to 15 wt%; most preferably, 5 to 10 wt%), based on weight of the aqueous personal care rinse off composition of, the dermatologically acceptable amphoteric cleaning surfactant) (preferably, wherein the dermatologically acceptable amphoteric cleaning surfactant is selected from the group consisting of an alkyl betaine, an alkyl sultaine and mixtures thereof; more preferably, wherein the dermatologically acceptable amphoteric cleaning surfactant is selected from the group consisting of cocamidopropyl betaine, cocamidopropyl hydroxysultaine and mixtures thereof; still more preferably, wherein the dermatologically acceptable amphoteric cleaning surfactant includes cocamidopropyl betaine; most preferably, wherein the dermatologically acceptable cleaning surfactant is cocamidopropyl betaine); and (c) a mixture of alkyl polyglycosides (preferably, 0.05 to 30 wt% (more preferably, 1 to 20 wt%; still more preferably, 2 to 15 wt%; most preferably, 3 to 10 wt%), based on weight of the aqueous personal care rinse off composition,of the mixture of alkyl polyglycosides) comprising: a linear alkyl polyglucoside of formula A (preferably, 65 to 99 wt% (more preferably, 70 to 95 wt%; still more preferably, 75 to 92.5 wt%; most preferably, 80 to 90 wt%), based on weight of the mixture of alkyl polyglycosides, of the linear alkyl polyglucoside of formula A); wherein R1is a linear Ce 15 alkyl group (preferably, a linear Cs-i4 alkyl group; more preferably, a linear Cs-io alkyl group; still more preferably, at least one of a linear Cg alkyl group and a linear C10 alkyl group; most preferably, a blend of a linear Cg alkyl group and a linear C10 alkyl group); wherein n is an average of 1 to 5 (preferably, 1 to 3; more preferably, 1 to 2; most preferably, 1 .1 to 2); wherein G is a monosaccharide of glucose; and a branched alkyl polysaccharide of formula B (preferably, 1 to 35 wt% (more preferably, 5 to 30 wt%; still more preferably, 7.5 to 25 wt%; most preferably, 10 to 20 wt%), based on weight of the mixture of alkyl polyglycosides, of the branched alkyl polysaccharide of formula B); wherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5 (preferably, 1 to 3; more preferably, 1 to 2; most preferably, 1.1 to 2); wherein S is a monosaccharide with 5 or 6 carbon atoms (preferably, ribulose, xylulose, ribose, arabinose, xylose, lyxose, galactose, mannose, glucose and mixtures thereof; more preferably, arabinose, xylose, glucose and mixtures thereof; still more preferably, xylose, glucose and mixtures thereof; most preferably, xylose); with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl polyglucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt% (preferably, 1 to 14 wt%; more preferably, 2 to 12.5 wt%; still more preferably, 5 to 12 wt%; most preferably, 8 to 11 wt%), based on weight of the mixture of alkyl polyglycosides, of a compound of formula I; wherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt% (preferably, 0 to 30 wt%; more preferably, 0 to 25 wt%; still more preferably, 0 to 20 wt%; yet more preferably, 0 to 15 wt%; still yet more preferably, 0 to 10 wt%; most preferably, less than the detectable limit), based on weight of the mixture of alkyl polyglycosides, of a compound of formula III; wherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; with the proviso that the mixture of alkyl polyglycosides comprises < 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IV; wherein R12is -(CFDpCHs; wherein R13is -(CH2)^ICH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10; and with any one or more of the following additional composition provisos (i)-(ix) (each composition proviso taken individually, all possible combinations of two or more composition provisos and combinations of composition proviso(s) with additional mixture proviso(s) discussed previously are contemplated):(i) with the proviso that the aqueous personal care rinse off composition comprises < 100 wt%, based on weight of the aqueous personal care rinse off composition, of (a)+(b)+(c);(ii) with proviso that the aqueous personal care rinse off composition comprises < 1 wt% (preferably, < 0.5 wt%; more preferably, < 0.1 wt%; still more preferably, < 0.01 wt%; yet more preferably, < 0.001 wt%; still yet more preferably, < 0.0001 wt%; most preferably, less than detectable Emit), based on weight of the personal care rinse off composition, of anionic surfactant (e.g., alkyl ether sulfates, alkyl benzene sulfonates, alkyl sulfates, olefin sulfonates, paraffin sulfonates and soap (carboxylate));(iii) with the proviso that the aqueous personal care rinse off composition comprises < 0.01 wt% (preferably, < 0.001 wt%; more preferably, < 0.0001 wt%; most preferably, less than detectable limit) , based on weight of the aqueous personal care rinse off composition, of an anionic surfactant;(iv) with the proviso that the aqueous personal care rinse off composition comprises < 0.05 wt% (preferably, < 0.01; more preferably, < 0.005; still more preferably, < 0.001; yet more preferably, < 0.0005; still yet more preferably, < 0.0001 wt%; most preferably, less than detectable limit), based on weight of the mixture of alkyl polyglycosides, of a fatty acid alkyl ester alkoxylate of formula VR14CO2-(AO)h-R15(V) wherein R14is a linear or branched, saturated or unsaturated, alkyl group containing 5 to 21 carbon atoms; wherein AO is a C2-4 alkylene oxide unit; wherein h is 1 to 30 and wherein R15is a linear or branched alkyl group containing 1 to 6 carbon atoms;(v) with the proviso that the aqueous personal care rinse off composition comprises < 0.01 wt% (preferably, < 0.005 wt%; more preferably, < 0.001 wt%; still more preferably, < 0.0001 wt%; yet more preferably, < 0.0001 wt%; still yet more preferably, < 0.00001 wt%; most preferably, less than detectable limit), based on weight of the aqueous personal care rinse off composition, of a fatty acid ester of an alkyl glycoside having a fatty acid residueselected from the group consisting of R17(O)O- and / or R18(O)O-, wherein R17is a C12 or higher hydrocarbon and R18is a Ce-io hydrocarbon;(vi) with the proviso that the linear alkyl polyglucoside of formula A comprises 80 to 100 wt% (preferably, 90 to 100 wt%; more preferably, 95 to 100 wt%; still more preferably, 98 to 100 wt%; yet more preferably, 99 to 100 wt%; still yet more preferably, 99.9 to 100 wt% most preferably, 100 wt%) of all linear alkyl polyglycoside in the aqueous personal care rinse off composition;(vii) with the proviso that the linear alkyl polyglucoside of formula A and the branched alkyl polysaccharide of formula B comprise 95 to 100 wt% (preferably, 97 to 100 wt%; more preferably, 98 to 100 wt%; still more preferably, 99 to 100 wt%; yet more preferably, 99.5 to 100 wt%; still yet more preferably, 99.9 to 100 wt%; yet still more preferably, 99.99 to 100 wt%; most preferably, 100 wt%) of all alkyl polyglycoside in the aqueous personal care rinse off composition;(viii) with the proviso that the aqueous personal care rinse off composition comprises < 0.1 wt% (preferably, < 0.05 wt%; more preferably, < 0.01 wt%; still more preferably, < 0.001 wt%; yet more preferably, < 0.0001 wt%; still yet more preferably, < 0.00001 wt%; most preferably, less than detectable limit), based on weight of the aqueous personal care rinse off composition, of a compound of formula VIR19-O-(G7)*H (VI) wherein R19is a linear Ci-s alkyl group; wherein G7is a monosaccharide with 5 or 6 carbon atoms and wherein k is an average of 1 to 10; and(ix) with the proviso that the aqueous personal care rinse off composition comprises < 0.1 wt% (preferably, < 0.05 wt%; more preferably, < 0.01 wt%; still more preferably, < 0.001 wt%; yet more preferably, < 0.0001 wt%; still yet more preferably, < 0.00001 wt%; most preferably, less than detectable limit), based on weight of the aqueous personal care rinse off composition, of a compound of formula VIIwherein R20is a linear or branched C2-5 alkyl group; wherein R21is a linear or branched C4-7 alkyl group; wherein the sum of the carbon atoms of R20and R21is 7 to 11; wherein G8is a monosaccharide residue; and wherein r is 1 to 4.

[0032] Preferably, the aqueous personal care rinse off composition has a viscosity > 1,500 cP at 21 °C (preferably, 2,000 to 50,000 cP at 21 °C; more preferably, 2,500 to 30,000 cP at 21 °C; still more preferably, 3,000 to 25,000 cP at 21 °C; yet more preferably, 4,000 to 20,000 cP at 21 °C; most preferably, 5,000 to 15,000 cP at 21 °C) (preferably, measured after 24 hours in a temperature-controlled room (21+3° C.), using a Brookfield Viscosimeter Model DV-II+ at 30 RPM, with a RV spindle 31. The viscosity value can be taken after a stabilization time of 1 min).

[0033] Preferably, the method of cleaning at least one of mammalian skin and hair (preferably, at least one of human skin and hair) of the present invention, comprises: applying an aqueous personal care rinse off composition of the present invention to the skin or hair of a mammal (preferably, skin or hair of a human); and rinsing the aqueous personal care rinse off composition from the skin or hair with a rinse water.

[0034] Some embodiments of the present invention will now be described in detail in the following Examples.Syntheses S1-S3: Alkyl polyglycosides

[0035] A round-bottomed reactor was placed in an aluminum heating block and fitted with a 25 mL Dean-Stark trap (containing 15 mL hexanes) and a magnetic stir bar. To the reactor was added Sugar and n-butanol as noted in TABLE 1. The reactor contents were then stirred vigorously under a nitrogen blanket (bubbler). To the stirring reactor contents was added para-toluenesulfonic acid monohydrate (1 mol%) and the aluminum heating block set at temperature T1(noted in TABLE 1) and maintained at that temperature until the rate of increase in water volume slowed to zero, for ~2-3 hours. The reactor contents were then allowed to cool to ambient temperature with continued stirring. Then Alcohol B (B molar equivalents) was added to the reactor contents as noted in TABLE 1. The Dean-Stark trap was then replated with a still head and a condenser flask. The reactor contents were then vacuum distilled with the aluminum heating block set at temperature T2(noted in TABLE 1) and the condenser flask set in an ice-cooled bath. The vacuum was periodically adjusted to a flow rate of 1-2 drops / second. The vacuum was maintained for 2 to 4 hours. The distillation was then stopped. The distillation apparatus was placed back under a nitrogen atmosphere and the stirred contents of the reactor were allowed to cool to ambient temperature. A solution of sodium hydroxide was added to the stirring reactor contents as noted in TABLE 1. After vigorous stirring, the pH was measured (pH paper) to ensure the reactor contents were basic. A sample of the reactor contents was diluted with hexanes and purified via automated column chromatography. The alcohol eluted at a mobile phase concentration of 100% hexanes to 20 / 80 ethyl acetate / hexanes. The solvent mixture was then ramped over 2 column volumes to 100% ethyl acetate. The solvent system was then changed to ethyl acetate-methanol, and the solvent ratio was ramped over 1-6 column volumes to 60-100% methanol - during which time the product eluted as a mixture of mono- and polysaccharides. The solvent was removed under reduced pressure to give the final product.TABLE 1Comparative Examples CF1-CF15 and Example Fl: Aqueous Compositions

[0036] Aqueous compositions were prepared in Comparative Examples CF1-CF15 and Example Fl having a mixture of surfactants in water as noted in TABLE 2. The formulations were prepared by adding the surfactants noted in TABLE 2 to deionized water and vortex mixing for 30 seconds at a speed of 3,000 rpm. Following mixing, the samples were allowed to incubate in an oven set at 60 °C for ~12 hours. The samples were then allowed to cool to room temperature before futher evaluation.Turbidity

[0037] The turbidity of aqueous compositions having a 1 wt% surfactant concentration in water prepared according to Comparative Examples CF1, CF3-CF10 and Example Fl; and of aqueous compositions having a 5 wt% surfactant concentration in water prepared according to Comparative Examples CF11-CF15 was measured using a turbidity meter at 20 °C. The meter was calibrated according to instructions included with the machine. The results of the turbidity measurements are provided in TABLE 2. The aqueous compositions having a measured turbidity of < 15 Nephelometric Turbidity Units (NTU) are marked as clear and those with a turbidity of > 15 NTU are marked as turbid.Foaming Performance

[0038] The foaming performance of aqueous compositions having a 0.1 wt% surfactant concentration prepared according to Comparative Examples CF1-CF10 and Example Fl was determined using the following procedure. Foam height and bubble size measurements were performed using a Kruss Dynamic Foam Analyzer. A 50 mL sample of each of the aqueous compositions was transferred to a CY4572 measuring column with 55 mm camera height. Foam structure settings were adjusted to detect a minimum bubble area of 500 pm2and a maximum bubble area of 70 mm2. Foam was generated using a set stirring speed of 6,000 rpm with a 5 second oscillation and 10 second total stir time. After foam generation, data was collected for 5 minutes. The initial foam height (measured 10 seconds after mixing stopped) and the final foam height (measured 300 seconds after mixing stopped) are reported in TABLE 2.

Claims

We claim:

1. An aqueous personal care rinse off composition, comprising:(a) a dermatologically acceptable aqueous vehicle;(b) a dermatologically acceptable amphoteric cleaning surfactant; wherein the dermatologically acceptable amphoteric cleaning surfactant is selected from the group consisting of an alkyl betaine, an alkyl amphoacetate, an alkyl sultaine and mixtures thereof; and(c) a mixture of alkyl polyglycosides comprising: a linear alkyl polyglucoside of formula AR1-O-(G)„H (A) wherein R1is a linear C6-15 alkyl group; wherein n is an average of 1 to 5; wherein G is a monosaccharide of glucose; and a branched alkyl polysaccharide of formula Bwherein R2is a C2 alkyl group; wherein R3is a linear or branched C4 alkyl group; wherein g is an average of 1 to 5; wherein S is a monosaccharide with 5 or 6 carbon atoms; with the proviso that R1is a linear C9-15 alkyl group in at least some of the linear alkyl polyglucoside of formula A; with the proviso that the mixture of alkyl polyglycosides comprises < 15 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula Iwherein R4is a linear or branched C3-4 alkyl group; wherein R5is a linear or branched C5-6 alkyl group; wherein G1is a monosaccharide with 4 to 6 carbon atoms and wherein x is 1.1 to 4; with the proviso that the mixture of alkyl polyglycosides comprises 0 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IIIwherein R6is -(CH2)mCH(CH3)2; wherein R7is -(CH2)m+2CH(CH3)2; G3is a monosaccharide with 4 to 6 carbon atoms; wherein z is 1.1 to 4 and wherein m is 0 to 3; and with the proviso that the mixture of alkyl polyglycosides comprises < 3 wt%, based on weight of the mixture of alkyl polyglycosides, of a compound of formula IVwherein R12is -(CH2)PCH3; wherein R13is -(CH2)p+iCH(CH3)2; wherein G6is a monosaccharide with 4 to 6 carbon atoms; wherein p is 1 to 4; wherein / is 1.1 to 10.

2. The aqueous personal care rinse off composition of claim 1, wherein the mixture of alkyl polyglycosides comprises 65 to 99 wt%, based on weight of the mixture of alkyl polyglycosides, of the linear alkyl polyglucoside of formula A; and 1 to 35 wt%, based on weight of the mixture of alkyl polyglycosides, of the branched alkyl polysaccharide of formula B.

3. The aqueous personal care rinse off composition of claim 2, wherein the linear alkyl polyglucoside of formula A and the branched alkyl polysaccharide of formula B comprise 95 to 100 wt% of all alkyl polyglycosides in the aqueous personal care rinse off composition.

4. The aqueous personal care rinse off composition of claim 3, wherein the aqueous personal care rinse off composition comprises < 1 wt%, based on weight of the personal care rinse off composition, of an anionic surfactant.

5. The aqueous personal care rinse off composition of claim 4, wherein the aqueous personal care rinse off composition comprises < 0.05 wt%, based on weight of the mixture of alkyl polyglycosides, of a fatty acid alkyl ester alkoxylate of formula VR14CO2-(AO)h-R15(V) wherein R14is a linear or branched, saturated or unsaturated, alkyl group containing 5 to 21 carbon atoms; wherein AO is a C2-4 alkylene oxide unit; wherein h is 1 to 30 and wherein R15is a linear or branched alkyl group containing 1 to 6 carbon atoms; and wherein the aqueous personal care rinse off composition comprises < 0.01 wt%, based on weight of the aqueous personal care rinse off composition, of a fatty acid ester of an alkyl glycoside having a fatty acid residue selected from the group consisting of R17(O)O- and / or R18(O)O-, wherein R17is a C12 or higher hydrocarbon and R18is a Ce-io hydrocarbon.

6. The aqueous personal care rinse off composition of claim 5, wherein the aqueous personal care rinse off composition comprises < 0.01 wt%, based on weight of the aqueous personal care rinse off composition, of the anionic surfactant.

7. The aqueous personal care rinse off composition of claim 6, wherein at least 5 wt% of the linear alkyl polyglucoside of formula A is a linear Cio alkyl polyglucoside.

8. The aqueous personal care rinse off composition of claim 6, wherein the linear alkyl polyglucoside of formula A is a blend comprising 10 to 90 wt%, based on weight of the blend, of a linear Cs alkyl polyglucoside and 10 to 90 wt%, based on weight of the blend, of a linear Cio alkyl poly glucoside.

9. The aqueous personal care rinse off composition of claim 8, further comprising an ingredient selected from the group consisting of an absorbent, an aesthetic enhancer, an alpha hydroxy acid, an antiaging agent, an antidandruff agent, an antifungal, an antimicrobial agent, an antioxidant, an antiseptic, an antistatic agent, a bioactive agent, a bleaching agent, a chelating agent, a colorant, a conditioning agent, a dye, an emollient, an emulsifying agent, a film former, a fixative polymer, a foaming agent, a fragrance, a hard particle, a humectant, a lubricating agent, an opacifier, a pearlizing agent, a penetrant, a pH adjusting agent, a pigment, a plant extract, a preservative, a protein / amino acid, a rheology modifier, a salt, a sensory modifier, a slip agent, a soft particle, a sunscreen additive, a suspending agent, a UV light inhibitor, a vitamin and mixtures thereof.

10. A method of cleaning at least one of mammalian skin and hair, comprising: applying an aqueous personal care rinse off composition according to claim 1 to the skin or hair of a mammal; and rinsing the aqueous personal care rinse off composition from the skin or hair with a rinse water.

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