Curable compositions for the manufacture of electrodes of lithium-ion batteries

Abstract

A composition in the form of a slurry comprises an electrode particulate material; a (meth)acrylate oligomer; a solvent; an adhesion promoter comprising a (meth)acrylated phosphate ester; and optionally a (meth)acrylate monomer and / or a free radical photoinitiator. This composition is suitable for use in the fabrication of electrodes of lithium-ion batteries. In particular, the composition may be applied to a current collector, then cured to form a cathode or an anode. It has been found that this composition provides electrodes having an homogeneous surface which is deprived of cracks and also enhanced adhesion of the electrode particulate material to current collectors used in lithium-ion batteries.

Description

[0001] CURABLE COMPOSITIONS FOR THE MANUFACTURE OF ELECTRODES

[0002] OF LITHIUM-ION BATTERIES

[0003] TECHNICAL FIELD

[0004] The present invention relates to curable compositions suitable for curing, including curing by electron beam, and useful as cathodes or anodes of lithium-ion batteries. The invention also relates to methods for making electrodes of lithium-ion batteries.

[0005] BACKGROUND OF THE INVENTION

[0006] Lithium-ion batteries are currently used in power supplies, in particular for portable devices such as tools, phones and computers, and for electric vehicles. They include an electrochemical cell comprising two electrodes, namely an anode (negative electrode) and a cathode (positive electrode) that are separated by a separator and ionically connected by an electrolyte. Each of these electrodes comprises a metal sheet, known as the current collector, which is coated with a particulate electrode material. A polymeric binder is typically used to hold the particles together and to the current collector and to provide flexibility to the electrode. This binder is usually mixed with the particulate material and with a solvent to obtain a paste having the required viscosity, which is then applied onto the current collector and dried.

[0007] Water has been preferred over organic solvents in the manufacture of electrodes due to environmental and health concerns. The polymeric binder may be a styrene-butadiene rubber (SBR) latex, which may be used in combination with a thickener such as carboxymethylcellulose (CMC), or an acrylic latex. Thus, US 2024 / 0204193 discloses a polymeric binder for the negative electrode of a lithium-ion battery, which is obtained from acrylic monomers, including a phosphate ester of polypropylene glycol methacrylate (Sipomer® PAM 600 from SYENSQO). The polymeric binder is in the form of an aqueous dispersion and is mixed with an electrode particulate material and optionally with a crosslinker to obtain a slurry. This slurry is said to remain stable due to the presence of the phosphate monomer.

[0008] Instead of a binder, it has been suggested to mix the electrode material with radiation- curable binder precursors. For instance, U.S. Patent No. 11,043,336 discloses mixing specific polymer precursors with electrode solid particles to form an aqueous mixture, applying the mixture to an electrode current collector, followed by the application of actinic or electron beam radiation to the current collector for curing the polymer, thereby binding the electrode binder to the current collector. According to the '336 patent, the polymer precursors include (meth)acrylate-functionalized monomers and / or oligomers, in addition to a photoinitiator and optionally a coupling agent such as Silquest® A-187 (Momentive Performance Materials). Aqueous mixtures in the context of electrode fabrication can pose several drawbacks. The primary issue is the potential for water to interfere with the curing process, particularly when using (meth)acrylate-functionalized monomers and oligomers. Water may slow down or inhibit the polymerization process, leading to incomplete curing or lower cross-linking density, which can compromise the mechanical strength and adhesion of the electrode material to the current collector. Additionally, the presence of water can cause swelling or delamination of the electrode coating during drying, negatively impacting the uniformity and integrity of the final product. Moreover, managing water removal and ensuring complete drying can add complexity to the manufacturing process, increasing energy consumption and potentially affecting the overall efficiency of the electrode production.

[0009] U.S. Patent No. 9,543,565 also discloses a curable electrode binder suitable for lithium-ion batteries. The ‘565 patent discloses the use of functionalized rubber polymers that are electron beam and / or actinic radiation curable and may be utilized in the preparation of binders for electrodes to replace epoxy acrylate oligomers and thus improve metal adhesion. The rubber polymers are functionalized to include reactive groups, such carboxylated, acrylated, vinyl, vinyl ether, or epoxy functionalized polyisoprene and / or polybutadiene rubbers. The rubber polymers are intended to react with a reactive diluent, such as isorbomyl acrylate or PEG-200 diacrylate, or with a reactive crosslinking agent, which may also be a (meth)acrylate monomer.

[0010] The inventors have shown that polymer binders based on (meth)acrylate- functionalized oligomers can have suitable adhesion to current collectors and thus enhance the performance of electrodes when they are formulated in the presence of specific adhesion promoters. This invention thus provides an alternative solution to that disclosed in the prior art.

[0011] These adhesion promoters comprise a (meth)acrylated phosphate ester, which has been used in similar polymer binders as an agent to prevent volatilization of the material during thermal curing, in the manufacture of electronic parts (W02016 / 140204). SUMMARY OF THE INVENTION

[0012] This invention pertains to a composition in the form of a slurry comprising:

[0013] (A) an electrode particulate material in an amount of at least 50 wt % by weight, based on the weight of the composition;

[0014] (B) a (meth)acrylate-functionalized oligomer;

[0015] (C) a solvent;

[0016] (D) an adhesion promoter comprising a (meth)acrylated phosphate ester;

[0017] (E) optionally, a (meth)acrylate-functionalized monomer; and

[0018] (F) optionally, a free radical photoinitiator.

[0019] It is also directed to a method of forming an electrode comprising the steps of:

[0020] (a) applying the above composition to a current collector to form a layer;

[0021] (b) optionally, heating the layer,

[0022] (c) curing the layer by exposing it to radiation; and

[0023] (d) optionally consolidating the electrode by thermomechanical treatment.

[0024] Another object of the invention is an electrode comprising a current collector and a layer obtained by using the above composition.

[0025] Yet another object of the invention is lithium-ion battery comprising a cathode, an anode and a separator, characterized in that the cathode and / or the anode is an electrode according to the invention or an electrode made according to the above method.

[0026] DETAILED DESCRIPTION OF THE INVENTION

[0027] In the context of this description, when ranges are given they should be understood as encompassing their lower and upper limits.

[0028] In addition, unless otherwise indicated, all percentages are to be understood as weight percents.

[0029] Moreover, the reference to "a" particulate material, "an" adhesion promoter, "an" oligomer, "a" solvent and so on encompasses both one and at least one of these compounds, including any mixture of two or more of these compounds.

[0030] As used herein, the term “slurry” means a free-flowing or flowable and / or pumpable suspension (at room temperature) including solid materials in a suitable solvent. Electrode composition

[0031] The invention relates to an electrode composition for a lithium-ion battery.

[0032] The composition is in the form a slurry. This slurry may have a viscosity of about 100 to about 5,000 cPs, preferably from about 500 to about 3,000 cPs, and most preferably from about 1,000 to about 2,500 at 25°C, as measured using a Brookfield viscometer, model DV-II, using a 27 spindle (with the spindle speed varying typically between 20 and 200 rpm, depending on viscosity).

[0033] The composition comprises: (A) an electrode particulate material in an amount of at least 50 wt % by weight, based on the weight of the composition; (B) a (meth)acrylate- functionalized oligomer; (C) a solvent; and (D) an adhesion promoter comprising a (meth)acrylated phosphate ester. Optionally, this composition may further comprise (E) a (meth)acrylate-functionalized monomer and / or (F) a free radical photoinitiator. These constituents will now be described in detail.

[0034] Electrode particulate material

[0035] Component (A) in the composition of this invention consists of one or more electrode particulate materials.

[0036] The electrode particulate material may be selected from cathode particulate materials and anode particulate materials. Preferably, the electrode particulate material is a cathode particulate material.

[0037] The electrode particulate material typically includes an active material and optionally a conductive additive. The active material is a material that can reversibly absorb and release or host (intercalate) lithium ions to create reaction sites for lithium-ion electrochemical reactions (battery charging / discharging). The conductive additive is an additive used to improve the conductivity of the electrode.

[0038] The electrode particulate material of the negative electrode (anode) for lithium-ion batteries typically includes an active material that can reversibly absorb and release or host (intercalate) lithium ions to create reaction sites for lithium-ion electrochemical reactions (battery charging / discharging) and a conductive additive typically used to improve the conductivity of the negative electrode, which reduces the battery's internal resistance, and consequently boosts power output of the battery. Some compounds are capable of performing both functions (active material and conductive additive). In embodiments of the invention, the anode particulate material is selected from carbon materials such as carbon nanotubes (CNTs), graphite, hard carbon, activated carbon, carbon black, graphene, mesoporous carbon; silicon materials such as amorphous silicon, semi -crystalline silicon, silicon oxides and silicon nanowires; tin and tin oxides; germanium; lithium titanate; mixtures or composites of the aforementioned materials, and / or other materials known in the art as suitable for use as the anode in a lithium ion battery. In embodiments of the invention, the anode particulate material comprises an active material selected from carbon materials such as graphite, hard carbon, activated carbon, graphene and mesoporous carbon; silicon materials such as amorphous silicon, semi-crystalline silicon, silicon alloys, silicon oxides and silicon nanowires; metals such as tin, aluminum, antimony and alloys thereof; metal oxides such as tin oxides; germanium; lithium metal; a lithium alloy; lithium titanate (Li^isOn); mixtures or composites of the aforementioned materials, and / or other materials known in the art as suitable for use as the anode in a lithium-ion battery. The anode particulate material may further comprise a conductive additive selected from carbon-based additives such as graphite, graphene, carbon black, carbon fibers or carbon nanotubes (CNTs); metal powders such as silver, nickel, copper or aluminum powder; and mixtures thereof.

[0039] In embodiments of the invention, the cathode particulate material is selected from the group consisting of lithium metal oxides wherein the metal is selected from cobalt, manganese, nickel and / or vanadium, including lithium nickel manganese cobalt oxide, lithium nickel cobalt aluminum oxide, lithium manganese oxide, lithium nickel oxide and lithium cobalt oxide; lithium iron phosphate; mixtures thereof; and combinations thereof with carbon particles. Preferably the cathode particulate material is lithium iron phosphate. In particular, the cathode particulate material may comprise an active material selected from the group consisting of LiCoCh; Li(Ni, Co, A1)O2; Li(i+X)NiaMnbCoc(where x represents a real number of 0 or more, a = 0.9, 0.8, 0.6, 0.5, or 1 / 3, b = 0.05, 0.1, 0.2, 0.3, or 1 / 3, c = 0.05, 0.1, 0.2, or 1 / 3); LiNiCh; LiM^CU; LiCoMnC ; LisNiMmCL; Li3Fe2(PO4)3; Li3V2(PO4)3; a spinel Li Mn substituted by a different element having a composition represented by Lii+zMn2-z-yMyO4, M representing at least one metal chosen from Al, Mg, Co, Fe, Ni, and Zn, y and z independently representing a real number between 0 and 2; a lithium metal phosphate having a composition represented by LiM’PCU, with M’ representing Fe, Mn, Co, or Ni or a lithium bimetal phosphate LiM1uM2u-xPO4 (LMFP) with M1and M2are different and independently selected from Fe, Mn, Co, or Ni and 0<u<l; and mixtures thereof. The cathode particulate material may further comprise a conductive additive selected from graphite, graphene, carbon-based additives such as carbon black, carbon fibers or carbon nanotubes (CNTs); metal powders such as silver, nickel, copper or aluminum powder; and mixtures thereof.

[0040] In addition, the surface of each of the above-described materials may be coated. The coating material is not particularly limited as long as it has lithium-ion conductivity and contains a material capable of being maintained in the form of a coating layer on the surface of the active material. Examples of the coating material include LiNbCE, Li^isOn, and LisPCU.

[0041] Preferably, component (A) is free of silver particles surface-treated with stearic acid. More preferably, component (A) is free of conductive particles surface-treated with stearic acid. Even more preferably, component (A) is free of silver particles (surface-treated or nonsurface-treated).

[0042] Component (A) is present in an amount of at least 50 wt% relative to the weight of the composition. Preferably, component (A) is present in an amount of 50 to 70 wt%, more preferably 55 to 65 wt%, relative to the weight of the composition.

[0043] Component (A) may be present in an amount of 50 to 98 wt.%, preferably 60 to 98 wt.%, more preferably 70 to 97 wt.%, still preferably 80 to 96 wt.%, such as 85 to 95 wt.% or 90 to 95 wt.%, relative to the weight of components (A), (B), (D) and, if present, (E) and (F).

[0044] (Meth)acrylate-functionalized oligomer

[0045] Component (B) in the composition of this invention consists of one or more (meth)acrylate-functionalized oligomers. Component (B) is distinct from components (A), (C), (D), (E) and (F).

[0046] The term "oligomer" refers to molecules with a distribution of molecular weights and typically having one or more polymerizable functional groups. An oligomer may be the reaction product of two or more monomers. An oligomer may have a number averaged molecular weight greater than 500 g / mol, preferably 500 g / mol to 60,000 g / mol, in particular 800 to 20,000 g / mol and more preferably 1,000 g / mol to 8,000 g / mol. As is recognized, commercial products of a particular oligomer may contain impurities or other chemical species. The term “(meth)acrylate-functionalized oligomer” means an oligomer comprising a (meth)acrylate group. The term “(meth)acrylate group” encompasses acrylate groups (-0- CO-CH=CH2) and methacrylate groups (-O-CO-C(CH3)=CH2).

[0047] Moreover, component (B) preferably comprises or consists of at least one (meth)acrylate-functionalized oligomer having 1 to 10 (meth)acrylate groups, in particular 2 to 6 (meth)acrylate groups, more particularly 2 (meth)acrylate groups.

[0048] In particular, component (B) may comprise or consist of (meth)acrylate- functionalized oligomers selected from (meth)acrylate-functionalized urethane oligomers (sometimes also referred to as “urethane (meth)acrylate oligomers,” “polyurethane (meth)acrylate oligomers” or “carbamate (meth)acrylate oligomers”), (meth)acrylate- functionalized epoxy oligomers (sometimes also referred to as “epoxy (meth)acrylate oligomers”), (meth)acrylate-functionalized polyether oligomers (sometimes also referred to as “polyether (meth)acrylate oligomers”), (meth)acrylate-functionalized polydiene oligomers (sometimes also referred to as “polydiene (meth)acrylate oligomers”), (meth)acrylate-functionalized polycarbonate oligomers (sometimes also referred to as “polycarbonate (meth)acrylate oligomers”), (meth)acrylate-functionalized polyester oligomers (sometimes also referred to as “polyester (meth)acrylate oligomers”), (meth)acrylate-functionalized (meth)acrylic oligomers (sometimes also referred to as “(meth)acrylic (meth)acrylate oligomers” and mixtures thereof.

[0049] The urethane (meth)acrylate oligomers may be prepared by reacting at least one diisocyanate (such as at least one aliphatic and / or aromatic diisocyanate) with at least one polyol which may be selected from polyester polyols (including aromatic, aliphatic and mixed aliphatic / aromatic polyester polyols), polyether polyols, polycarbonate polyols, polycaprolactone polyols, polyorganosiloxane polyols (e.g., polydimethylsiloxane polyols), or polydiene polyols (e.g., polybutadiene polyols), or combinations thereof, and with at least one hydroxy-functionalized (meth)acrylate such as hydroxyethyl acrylate or hydroxyethyl methacrylate. Any order of addition may be practiced to prepare the urethane (meth)acrylate, as is known in the art. For example, the at least one hydroxyl-functionalized (meth)acrylate may first be reacted with at least one diisocyanate to obtain an isocyanate-functionalized (meth)acrylate, which may then be reacted with the at least one polyol. In another embodiment, at least one diisocyanate may first be reacted with at least one polyol to obtain an isocyanate-functionalized prepolymer, which is thereafter reacted with at least one hydroxyl-functionalized (meth)acrylate. Alternatively, all the components may be combined and reacted at the same time.

[0050] The urethane (meth)acrylate oligomers may contain two, three, four or more (meth)acrylate functional groups per molecule. Advantageously, the urethane (meth)acrylate oligomer comprises an aliphatic urethane (meth)acrylate oligomer having two (meth)acrylate groups.

[0051] Suitable polyether (meth)acrylate oligomers include, but are not limited to, the condensation reaction products of at least one (meth)acrylating agent (such as acrylic or methacrylic acid or synthetic equivalents or mixtures thereof) with at least one polyether polyol (such as polyethylene glycol, polypropylene glycol or polytetramethylene glycol). Suitable polyether polyols can be linear or branched substances containing ether bonds and terminal hydroxyl groups. Polyether polyols can be prepared by ring opening polymerization of cyclic ethers such as tetrahydrofuran or alkylene oxides (e.g., ethylene oxide and / or propylene oxide) with a starter molecule. Suitable starter molecules include water, polyhydroxyl functional materials, polyester polyols and amines.

[0052] Exemplary polyester (meth)acrylate oligomers include the reaction products of at least one (meth)acrylating agent (such as acrylic or methacrylic acid or mixtures or synthetic equivalents thereof) with at least one hydroxyl group-terminated polyester polyol. The reaction process may be conducted such that all or essentially all of the hydroxyl groups of the polyester polyol have been (meth)acrylated, particularly in cases where the polyester polyol is difunctional. The polyester polyols can be made by polycondensation reactions of at least one polyol (in particular, at least one diol) and at least one polycarboxylic acid functional compound (in particular at least one dicarboxylic acid and / or anhydride). The polyol and polycarboxylic acid functional compounds can each have linear, branched, cycloaliphatic or aromatic structures and can be used individually or as mixtures.

[0053] Examples of suitable epoxy (meth)acrylates include the reaction products of acrylic or methacrylic acid or mixtures thereof with an epoxy resin (in particular a polyglycidyl ether or ester). The epoxy resin may, in particular, be selected from 3,4- epoxy cy cl ohexylmethyl-3',4'-epoxy cyclohexanecarboxylate, 2-(3,4-epoxycyclohexyl-5,5- spiro-3,4-epoxy) cy cl ohexane-l,4-di oxane, bis(3,4-epoxycyclohexylmethyl)adipate, bis(3,4-epoxy-6-m ethylcyclohexyl methyl)adipate, 3,4-epoxy-6-methylcyclohexyl-3',4'- epoxy-6'-methylcyclo-hexane carboxylate, dicyclopentadiene diepoxide, a bisphenol diglycidyl ether, 1,4-butanediol diglycidyl ether, 1,6-hexanediol diglycidyl ether, glycerol triglycidyl ether, trimethylolpropane triglycidyl ether, polyethylene glycol diglycidyl ether, polypropylene glycol diglycidyl ether, polyglycidyl ethers of a polyether polyol obtained by the addition of one or more alkylene oxides to an aliphatic polyhydric alcohol such as ethylene glycol, propylene glycol and glycerol, diglycidyl esters of aliphatic C6-C22 dibasic acids, glycidyl esters of C30-36 dimers of fatty acids, an epoxidized vegetable oil (such as epoxidized soybean oil and epoxidized linseed oil), epoxidized polybutadiene, and the like.

[0054] Suitable (meth)acrylic (meth)acrylate oligomers include oligomers which may be described as substances having an oligomeric (meth)acrylic backbone which is functionalized with one or more (meth)acrylate groups (which may be at a terminus of the oligomer or pendant to the acrylic backbone). The (meth)acrylic backbone may be a homopolymer, random copolymer or block copolymer comprised of repeating units of (meth)acrylic monomers. The (meth)acrylic monomers may be any monomeric (meth)acrylate such as C1-C6 alkyl (meth)acrylates as well as functionalized (meth)acrylates such as (meth)acrylates bearing hydroxyl, carboxylic acid and / or epoxy groups. (Meth)acrylic (meth)acrylate oligomers may be prepared using any procedures known in the art, such as by oligomerizing monomers, at least a portion of which are functionalized with hydroxyl, carboxylic acid and / or epoxy groups (e.g., hydroxyalkyl(meth)acrylates, (meth)acrylic acid, glycidyl (meth)acrylate) to obtain a functionalized oligomer intermediate, which is then reacted with one or more (meth)acrylate-containing reactants to introduce the desired (meth)acrylate functional groups.

[0055] In embodiments of the invention, the (meth)acrylate-functionalized oligomer is selected from the group consisting of urethane (meth)acrylate oligomers, polyester (meth)acrylate oligomers and polyether (meth)acrylate oligomers. Preferably, component (B) comprises or consists of a polyether urethane (meth)acrylate or a polyester urethane (meth)acrylate, such as an aliphatic polyester-based urethane di- or tetra-acrylate oligomer, an aliphatic polyether-based urethane di- or tetra-acrylate oligomer or an aliphatic polyester / polyether-based urethane di- or tetra-acrylate oligomer. More preferably, component (B) comprises or consists of a polyether urethane acrylate, still preferably component (B) comprises or consists of an aliphatic polyether-based urethane diacrylate oligomer. In an embodiment, this oligomer may comprise residues of hydroxy ethyl acrylate, isophorone diisocyanate, and a poly ether polyol.

[0056] Commercially available oligomers suitable for use as the (meth)acrylate oligomer herein include CN9018, CN9021, and CN996, commercially available from Sartomer.

[0057] Component (B) may be present in an amount of 0.5 to 20 wt%, preferably from 1 to 15 wt%, more preferably from 2 to 12 wt% relative to the weight of the composition.

[0058] Component (B) may be present in an amount of about 2 to about 20 wt%, preferably about 4 to about 15 wt%, and most preferably about 6 to about 12 wt% based on the weight of components (A), (B), (D) and, if present, (E) and (F).

[0059] Adhesion promoter

[0060] Component (D) in the composition of this invention consists of one or more adhesion promoters. Component (D) is distinct from components (A), (B), (C), (E) and (F).

[0061] Component (D) comprises or consists of one or more (meth)acrylated phosphate esters.

[0062] It has been found that compositions employing adhesion promoters comprising a (meth)acrylated phosphate ester form after curing electrodes having a homogeneous surface which is deprived of cracks and also enhanced adhesion of the electrode particulate material to current collectors used in lithium-ion batteries.

[0063] The adhesion promoter may comprise or consist of a mono(meth)acrylated phosphate ester, a di(meth)acrylated phosphate ester or a mixture thereof. In a preferred embodiment, the (meth)acrylated phosphate ester comprises or consists of a mixture of a mono(meth)acrylated phosphate ester and a di(meth)acrylated phosphate ester, for instance in a weight ratio of 30:70 to 70:30, preferably from 40:60 to 60:40 and still preferably of about 50:50.

[0064] In an embodiment, the mono(meth)acrylated phosphate ester and the di(meth)acrylated phosphate ester are monomers having formulas (I) and (II), respectively: wherein in Formula (1) and Formula (2): each Ri is independently H or Ci-Ce alkyl; each R2 is independently H or Ci-Ce alkyl; each R3 is independently H or Ci-Ce alkyl; each X is independently Ci-Ce alkylene, where a N, O or S atom may be inserted between any two carbon atoms present in the alkylene chain and wherein carbon atoms in the alkylene chain may be substituted with a C1-C3 alkyl group; each R4 is independently H or a cation; each R5 is independently H or a cation; each n is independently 4 to 7; and each m is independently 0 to 25.

[0065] It is preferred that the mono(meth)acrylated phosphate ester and / or the di(meth)acrylated phosphate ester is such that at least one, and preferably all, the following conditions are met:

[0066] • Ri = R2=R4=Rs=H

[0067] • R3= H or CH3

[0068] • X = -CH2-CH2-.

[0069] In an embodiment, m is 0.

[0070] In a preferred embodiment, m ranges from 1 to 25, preferably 2 to 18, and more preferably 3 to 12 and n is 5.

[0071] Component (D) may be present in an amount of 0.1 to 10 wt%, preferably from 0.2 to 8 wt%, more preferably from 0.5 to 5 wt% relative to the weight of the composition.

[0072] Component (D) may be present in an amount of about 0.1 to about 10 wt%, preferably from about 0.2 to 8 wt%, more preferably about 0.3 to about 5 wt%, even more preferably about 0.4 to about 2 wt%, and most preferably about 0.5 to about 1.5 wt% based on the weight of components (A), (B), (D) and, if present, (E) and (F).

[0073] The composition may comprise from 3.0 to 120 parts by weight, preferably from 5.2 to 115 parts by weight, more preferably from 6.0 to 110 parts by weight, of component (D) based on 100 parts by weight of components (B) and (E), if present. In one embodiment, the composition may comprise from 20 to 120 parts by weight, preferably from 25 to 115 parts by weight, more preferably from 30 to 110 parts by weight, of component (D) based on 100 parts by weight of components (B) and (E), if present. In another embodiment, the composition may comprise from 3.0 to 20 parts by weight, preferably from 5.2 to 15 parts by weight, more preferably from 6.0 to 12 parts by weight, of component (D) based on 100 parts by weight of components (B) and (E), if present.

[0074] Solvent

[0075] Component (C) in the composition of this invention consists of one or more solvents. Component (C) is distinct from components (A), (B), (D), (E) and (F).

[0076] The solvent is useful to disperse the distinct components of the compositions which ensures homogeneity of the mixture and a uniform distribution when the composition is applied on the current collector to make an electrode. The solvent is particularly useful to control the viscosity of the composition and facilitate its application on the current collector. The solvent is intended to be evaporated (by heating and / or vacuum) after application on the current collector and it no longer present in the final electrode.

[0077] The solvent may be an organic compound which is liquid at 0°C and which has a boiling point, measured at 101.325 kPa, of less than 250°C. The solvent may be an organic solvent, i.e. a solvent having carbon atoms. The solvent may be a non-reactive solvent, i.e. it is non-reactive with respect to the components of the composition of the invention, in particular it is devoid of polymerizable ethylenic unsaturations such as (meth)acrylate groups, vinyl group, allyl groups.

[0078] In embodiments of the invention, component (C) comprises or consists of a polar organic solvent. In particular, component (C) comprises or consists of a polar organic solvent selected from N-methylpyrrolidone (NMP), dimethylsulfoxide (DMSO), N,N- dimethylformamide (DMF), triethylphosphite, triethylphosphate, acetone, cyclopentanone, tetrahydrofuran, methyl ethyl ketone (MEK), methyl isobutyl ketone (MiBK), ethyl acetate (EA), butyl acetate (BA), methyl propionate, ethyl propionate, methyl butyrate, isopropanol, ethanol, methanol, acetonitrile, ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC), butylene carbonate, gamma-butyrolactone, N-butylpyrrolidone, and mixtures thereof. More particularly, component (C) comprises or consists of a polar organic solvent selected from acetone, butyl acetate, isopropanol, methyl ethyl ketone (MEK), ethanol, methanol, acetonitrile, propylene carbonate, ethyl acetate and mixtures thereof, and preferably comprises or consists of isopropanol.

[0079] Component (C) may be present in an amount of about 30 to about 80 wt%, preferably about 35 to about 70 wt%, and most preferably about 45 to about 70 wt% based on the weight of the composition.

[0080] In an embodiment of the invention, the composition is anhydrous. By this expression, it is means that the composition comprises less than 5% of water, preferably less than 2% of water, more preferably less than 1% of water, based on the total weight of the composition.

[0081] Moreover, in an embodiment of the invention, the composition does not comprise n- methyl-2-pyrrolidone.

[0082] (Meth)acrylate-functionalized monomer

[0083] Component (E) as optionally used in the composition of this invention consists of one or more (meth)acrylate-functionalized monomers. Component (E) is distinct from components (A), (B), (C), (D) and (F).

[0084] As used herein, the term “(meth)acrylate-functionalized monomer” means a monomer comprising a (meth)acrylate group. The term “(meth)acrylate group” encompasses acrylate groups (-O-CO-CH=CH2) and methacrylate groups (-O-CO-C(CH3)=CH2).

[0085] The (meth)acrylate-functionalized monomer may have a molecular weight of less than 600 g / mol, in particular from 100 to 550 g / mol, more particularly 200 to 500 g / mol.

[0086] The (meth)acrylate-functionalized monomer may have 1 to 6 (meth)acrylate groups, in particular 1 to 3 (meth)acrylate groups.

[0087] Component (E) may comprise a mixture of (meth)acrylate-functionalized monomers having different functionalities. For example, component (E) may comprise a mixture of a (meth)acrylate-functionalized monomer containing a single acrylate or methacrylate group per molecule (referred to herein as “mono(meth)acrylate-functionalized compounds”) and a (meth)acrylate-functionalized monomer containing 2 or more, preferably 2 to 6, acrylate and / or methacrylate groups per molecule (referred to herein as “poly(meth)acrylate- functionalized monomer”). In one embodiment, component (E) comprises or consists of a mono(meth)acrylate- functionalized monomer.

[0088] Examples of suitable mono(meth)acrylate-functionalized monomers include, but are not limited to, mono-(meth)acrylate esters of aliphatic alcohols (wherein the aliphatic alcohol may be straight chain, branched or alicyclic and may be a mono-alcohol, a di-alcohol or a polyalcohol, provided only one hydroxyl group is esterified with (meth)acrylic acid); mono-(meth)acrylate esters of aromatic alcohols (such as phenols, including alkylated phenols); mono-(meth)acrylate esters of alkylaryl alcohols (such as benzyl alcohol); mono- (meth)acrylate esters of oligomeric and polymeric glycols such as diethylene glycol, triethylene glycol, dipropylene glycol, tripropylene glycol, polyethylene glycol, and polypropylene glycol); mono-(meth)acrylate esters of monoalkyl ethers of glycols and oligoglycols; mono-(meth)acrylate esters of alkoxylated (e.g., ethoxylated and / or propoxylated) aliphatic alcohols (wherein the aliphatic alcohol may be straight chain, branched or alicyclic and may be a mono-alcohol, a di-alcohol or a polyalcohol, provided only one hydroxyl group of the alkoxylated aliphatic alcohol is esterified with (meth)acrylic acid); mono-(meth)acrylate esters of alkoxylated (e.g., ethoxylated and / or propoxylated) aromatic alcohols (such as alkoxylated phenols); caprolactone mono(meth)acrylates; and mixtures thereof.

[0089] The following compounds are specific examples of mono(meth)acrylate- functionalized monomers suitable for use in component (E): methyl (meth)acrylate; ethyl (meth)acrylate; n-propyl (meth)acrylate; n-butyl (meth)acrylate; isobutyl (meth)acrylate; n- hexyl (meth)acrylate; 2-ethylhexyl (meth)acrylate; n-octyl (meth)acrylate; isooctyl (meth)acrylate; n-decyl (meth)acrylate; n-dodecyl (meth)acrylate; tridecyl (meth)acrylate; tetradecyl (meth)acrylate; hexadecyl (meth)acrylate; 2-hydroxyethyl (meth)acrylate; 2- and 3-hydroxypropyl (meth)acrylate; 2-methoxy ethyl (meth)acrylate; 2-ethoxy ethyl (meth)acrylate; 2- and 3-ethoxypropyl (meth)acrylate; tetrahydrofurfuryl (meth)acrylate; alkoxylated tetrahydrofurfuryl (meth)acrylate; 2-(2-ethoxyethoxy)ethyl (meth)acrylate; cyclohexyl (meth)acrylate; glycidyl (meth)acrylate; isodecyl (meth)acrylate; lauryl (meth)acrylate; 2-phenoxyethyl (meth)acrylate; alkoxylated phenol (meth)acrylates; alkoxylated nonylphenol (meth)acrylates; benzyl (meth)acrylate, cyclic trimethylolpropane formal (meth)acrylate; (2,2-dimethyl-l,3-dioxolan-4-yl)methyl (meth)acrylate; (2-ethyl-2- methyl- 1,3 -di oxolan-4-yl)m ethyl (meth)acrylate; glycerol formal methacrylate; isobomyl (meth)acrylate; tricyclodecanemethanol (meth)acrylate; tert-butylcyclohexanol (meth)acrylate; trimethylcyclohexanol (meth)acrylate; diethylene glycol monomethyl ether (meth)acrylate; diethylene glycol monoethyl ether (meth)acrylate; diethylene glycol monobutyl ether (meth)acrylate; triethylene glycol monoethyl ether (meth)acrylate; ethoxylated lauryl (meth)acrylate; methoxy polyethylene glycol (meth)acrylates; hydroxyl ethyl-butyl urethane (meth)acrylates; 3-(2-hydroxyalkyl)oxazolidinone (meth)acrylates; a caprolactone mono(meth)acrylate; and combinations thereof.

[0090] In another embodiment, component (E) may comprise or consist of a poly(meth)acrylate-functionalized monomer.

[0091] Examples of suitable poly(meth)acrylate-functionalized monomers include acrylate and methacrylate esters of polyols selected from ethylene glycol, di-, tri- or tetraethylene glycol, 1,2- or 1,3-propylene glycol, di-, tri- or tetra(l,2-propylene glycol), di-, tri- or tetra( 1,3 -propylene glycol), 1,2-, 1,3- or 1,4-butylene glycol, di-, tri- or tetra(l,4-butylene glycol), 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, 1,8-octanediol, 1,9-nonanediol, 1,10-decanediol, 1,12-dodecanediol, 2-methyl-l,3-propanediol, 2,2-dimethyl-l,3- propanediol, 2,2-diethyl-l,3-propanediol, 2-methyl-2-ethyl-l,3-propanediol, 3-methyl-l,5- pentanediol, 3,3-dimethyl-l,5-pentanediol, 2, 4-di ethyl- 1,5-pentanediol, 3 -butyl -3 -ethyl - 1,5-pentane diol, 2,2,4-trimethyl 1,5-pentanediol, cyclohexanediol, cyclohexane- 1,4- dimethanol, norbomene dimethanol, norbornane dimethanol, tricyclodecanediol, tricyclodecane dimethanol, hydrogenated bisphenol A, B, F or S, a dianhydrohexitol (i.e. isosorbide, isomannide, isoidide), as well as the alkoxylated (i.e. ethoxylated and / or propoxylated) derivatives thereof; and mixtures thereof. Such polyols may be fully or partially esterified (with (meth)acrylic acid, (meth)acrylic anhydride, (meth)acryloyl chloride or the like), provided they contain at least two (meth)acrylate functional groups per molecule.

[0092] Exemplary poly(meth)acrylate-functionalized monomers may include bisphenol A di(meth)acrylate; hydrogenated bisphenol A di(meth)acrylate; ethylene glycol di(meth)acrylate; diethylene glycol di(meth)acrylate; triethylene glycol di(meth)acrylate; tetraethylene glycol di(meth)acrylate; polyethylene glycol di(meth)acrylate; propylene glycol di(meth)acrylate; dipropylene glycol di(meth)acrylate; tripropylene glycol di(meth)acrylate; tetrapropylene glycol di(meth)acrylate; polypropylene glycol di(meth)acrylate; polytetramethylene glycol di(meth)acrylate; 1,2-butanediol di(meth)acrylate; 2,3-butanediol di(meth)acrylate; 1,3 -butanediol di(meth)acrylate; 1,4- butanediol di(meth)acrylate; 1,5-pentanediol di(meth)acrylate; 1,6-hexanediol di(meth)acrylate; 1,8 -octanediol di(meth)acrylate; 1,9-nonanediol di(meth)acrylate; 1,10- nonanediol di(meth)acrylate; 1,12-dodecanediol di(meth)acrylate; neopentyl glycol di(meth)acrylate; 2-methyl-2,4-pentanediol di(meth)acrylate; polybutadiene di(meth)acrylate; cyclohexane-l,4-dimethanol di(meth)acrylate; tri cyclodecane dimethanol di(meth)acrylate; glyceryl di(meth)acrylate; glyceryl tri(meth)acrylate; trimethylolethane tri(meth)acrylate; trimethylolethane di(meth)acrylate; trimethylolpropane tri(meth)acrylate; ethoxylated trimethylolpropane tri(meth)acrylate; trimethylolpropane di(meth)acrylate; pentaerythritol di(meth)acrylate; pentaerythritol tri(meth)acrylate; pentaerythritol tetra(meth)acrylate, di(trimethylolpropane) diacrylate; di(trimethylolpropane) triacrylate; di(trimethylolpropane) tetraacrylate, sorbitol penta(meth)acrylate; di(pentaerythritol) tetraacrylate; di(pentaerythritol) pentaacrylate; di(pentaerythritol) hexa(meth)acrylate; tris (2 -hydroxy ethyl) isocyanurate tri(meth)acrylate; and mixtures thereof.

[0093] In embodiments of the invention, the (meth)acrylate monomer is selected from the group consisting of aliphatic monofunctional (meth)acrylate monomers, preferably cyclic aliphatic monofunctional (meth)acrylate monomers such as tetrahydrofurfuryl acrylate, isobornyl acrylate, trimethylolpropane formal acrylate and combinations thereof; aliphatic difunctional (meth)acrylate monomers, preferably acyclic aliphatic difunctional (meth)acrylate monomers such as 1,4-butanediol di(meth)acrylate, 1,6-hexanediol diacrylate, and combinations thereof; and mixtures thereof.

[0094] Component (E) may be present in an amount of 0.5 to 20 wt%, preferably from 1 to 15 wt%, more preferably from 2 to 10 wt% relative to the weight of the composition. Alternatively, the composition may be devoid of component (E).

[0095] Component (E) may represent from 1 to 10 wt.%, preferably from 2 to 8 wt.%, more preferably from 3 to 6 wt.% based on the weight of components (A), (B), (D), (E) and if present, (F).

[0096] Free radical photoinitiator

[0097] Component (F) as optionally used in the composition of this invention consists of one or more free radical photoinitiators. Component (F) is distinct from components (A), (B), (C), (D) and (E). Free radical photoinitiators are compounds that can generate free radicals upon exposure to light of an appropriate wavelength and / or intensity. Such photoinitiators can adopt two different modes of action, and are classified by mode of action as Norrish Type I and Norrish Type II photoinitiators. As used herein, the term “activity” with reference to Norrish Type I and Norrish Type II activity is intended to relate to Norrish photoinitiation and analogous reactions. For instance, a free radical photoinitiator having Norrish Type I activity within the scope of this invention would be a photoinitiator characterized by a cleavage reaction into two radical fragments of the original photoinitiator on exposure to light. For a free radical photoinitiator having Norrish Type II activity, exposure to light causes the abstraction of an atom, such as hydrogen, to generate the radical. When present, the free radical photoinitiator (F) may be a free radical photoinitiator having Norrish type I activity and / or Norrish type II activity, more particularly a free radical photoinitiator having Norrish type II activity.

[0098] Non-limiting types of free radical photoinitiators suitable for use in the composition of the invention include, for example, benzoins, benzoin ethers, acetophenones, a-hydroxy acetophenones, benzil, benzil ketals, anthraquinones, phosphine oxides, acylphosphine oxides, a-hydroxyketones, phenylglyoxylates, a-aminoketones, benzophenones, thioxanthones, xanthones, acridine derivatives, phenazine derivatives, quinoxaline derivatives, triazine compounds, benzoyl formates, aromatic oximes, metallocenes, acylsilyl or acylgermanyl compounds, camphorquinones, polymeric derivatives thereof, and mixtures thereof.

[0099] Examples of specific free radical photoinitiators include, but are not limited to, 2- methylanthraquinone, 2-ethylanthraquinone, 2-chloroanthraquinone, 2-benzyanthra- quinone, 2-t-butylanthraquinone, l,2-benzo-9,10-anthraquinone, benzoin ethers, benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, alpha-methylbenzoin, alpha-phenylbenzoin, Mi chi er’ s ketone, acetophenones such as 2,2-dialkoxybenzophenones and 1 -hydroxyphenyl ketones, benzophenone, 4,4’ -bis-(di ethylamino) benzophenone, acetophenone, 2,2-diethyloxyacetophenone, , 2-isopropylthioxanthone, thioxanthone, diethyl thioxanthone, 1,5-acenaphthylene, benzil, a-hydroxyketone, 2,4,6- trimethylbenzoyldiphenyl phosphine oxide, , 2,2-dimethoxy-l,2-diphenylethanone, 1- hydroxycyclohexyl phenyl ketone, 2-methyl-l-[4-(methylthio) phenyl]-2- morpholinopropanone, 2-hydroxy-2-methyl-l-phenyl-propanone, oligomeric a-hydroxy ketone, benzoyl phosphine oxides, phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide, ethyl(2,4,6-trimethylbenzoyl)phenyl phosphinate, anisoin, anthraquinone, anthraquinone-2- sulfonic acid sodium salt monohydrate, (benzene) tricarbonylchromium, , benzoin isobutyl ether, benzophenone / 1 -hydroxy cyclohexyl phenyl ketone 50 / 50 blend, 3, 3', 4, d'benzophenonetetracarboxylic dianhydride, 4-benzoylbiphenyl, 2-benzyl-2-(dimethyl- amino)-4'-morpholinobutyrophenone, 4,4'-bis(diethylamino)benzophenone, 4,4'- bis(dimethylamino)benzophenone, camphorquinone, 2-chlorothioxanthen-9-one, dibenzosuberenone, 4,4'-dihydroxybenzophenone, , 4-(dimethylamino)benzophenone, 4, 'dimethylbenzil, 2,5-dimethylbenzophenone, 3,4-dimethylbenzophenone, diphenyl(2,4,6- trimethylbenzoyl)phosphine oxide / 2-hydroxy-2 -methylpropiophenone 50 / 50 blend, d'ethoxyacetophenone, 2,4,6-trimethylbenzoyldiphenylphosphine oxide, 3'-hydroxyaceto- phenone, 4'-hydroxyacetophenone, 3 -hydroxybenzophenone, 4-hydroxybenzophenone, 2- m ethylbenzophenone, 3 -methylbenzophenone, methybenzoylformate, phenanthrenequinone, 4'-phenoxyacetophenone, (cumene)cyclopentadienyl iron(ii) hexafluorophosphate, 9, 10-di ethoxy and 9, 10-dibutoxyanthracene, 2-ethyl-9,10-dimethoxy anthracene, and combinations thereof.

[0100] In particular, the free radical photoinitiator may comprise a free radical photoinitiator selected from a benzophenone such as SpeedCure® BP (benzophenone), SpeedCure® 7005 (polymeric benzophenone), SpeedCure® 7006 (polymeric benzophenone), SpeedCure® EMK (4,4’-bis(diethylamino)benzophenone) or SpeedCure® BMS (4-benzoyl-4’- methyldiphenyl sulphide); a thioxanthone such as SpeedCure® 7010 (polymeric thioxanthone), SpeedCure® ITX (isopropyl thioxanthone), SpeedCure® DETX (2,4- diethylthi oxanthone) or SpeedCure® CPTX (1 -chi oro-4-propoxythi oxanthone); an a- hydroxy acetophenone; an acylphosphine oxide such as SpeedCure® BPO (phenyl bis(2,4,6- trimethylbenzoyl)-phosphine oxide), SpeedCure® TPO (2,4,6- trimethylbenzoyldiphenylphosphine oxide) or SpeedCure® TPO-L (ethyl (2,4,6- trimethylbenzoyl)phenyl phosphinate); a phenylglyoxylate such as SpeedCure® MBF (methylbenzoylformate); and mixtures thereof.

[0101] Component (F) may be present in the composition in an amount of from 0.1 to 5% based on the weight of components (A), (B), (D), (F) and if present, (E). Alternatively, the composition may be devoid of component (F).

[0102] Other components

[0103] The composition is preferably free of an organic peroxide having the following structure: wherein each R1is independently a hydrocarbon group.

[0104] More preferably, the composition is free of an organic peroxide. Even more preferably, the composition is free of a peroxide.

[0105] Methods

[0106] The composition of this invention may be prepared by mixing the component (D), component (B) and optional components (E) and (F) with the component (C) to obtain a binder or resin composition which is then mixed with component (A) to form a slurry. This slurry may have a viscosity of about 100 to about 5,000 cPs, preferably from about 500 to about 3,000 cPs, and most preferably from about 1,000 to about 2,500 at 25°C, as measured using a Brookfield viscometer, model DV-II, using a 27 spindle (with the spindle speed varying typically between 20 and 200 rpm, depending on viscosity).

[0107] This composition may be used in the manufacture of an electrode, preferably of a cathode, according to a process comprising the steps of:

[0108] (a) applying a composition as defined above to a current collector to form a layer;

[0109] (b) optionally, heating the layer;

[0110] (c) curing the layer by exposing it to radiation; and

[0111] (d) optionally consolidating the electrode by thermomechanical treatment.

[0112] Specifically, the composition may be applied to one or both sides of a current collector, preferably as a thin film, then allowed to dry (possibly under vacuum and / or with heat) so as to remove the solvent and then cured. The current collector may be in the form of a foil, a mesh, a foam, a rod or any other shape. The current collector may be made of aluminum, stainless steel, titanium, copper or nickel. The composition may be applied by any method known in the art such as spraying, rolling, draw bar application, bird bar application, gravure, slot coating or other coil coating methods. It may then be dried, for instance at 40-80°C in an oven in order to remove at least part of the solvent. The composition may then be cured by exposing it to actinic (UV or visible) or electron beam (EB) radiation. This allows forming the polymeric binder, encapsulating the electrode particulate material within the polymer network and also firmly binding the electrode thus obtained to the current collector. Optionally, the electrode may be consolidated using a calendaring process. This process consists of applying pressure to the electrode using two rollers, possibly heated.

[0113] In an embodiment, the composition comprises component (F) and the radiation is actinic radiation. In another embodiment, the composition does not comprise component (F) and the radiation is electron beam radiation.

[0114] The thickness of the layer may be from about 1 pm to about 500 pm, preferably about 25 pm to about 400 pm, more preferably about 50 pm to about 150 pm.

[0115] Electrode and batter

[0116] The invention also relates to an electrode comprising a current collector and a layer obtained by using the composition as defined above.

[0117] The layer may comprise or consist of component (A) embedded in a polymeric binder obtained by curing components (B), (D) and optionally (E).

[0118] The electrode may be made according to the method described above. Components (A), (B), (D) and (E) may be as defined above.

[0119] Preferably, the electrode is a cathode.

[0120] The invention also relates to a lithium-ion battery comprising a cathode, an anode and a separator, wherein the cathode and / or the anode is an electrode according to the present invention or an electrode made according to the method of the present invention. Preferably, the lithium-ion battery comprises a cathode according to the present invention or a cathode made according to the method of the present invention.

[0121] Preferably, the lithium-ion battery further comprises a lithium salt, preferably a lithium salt selected from the group consisting of LiCF3SO3, LiPFe, LiClO4, LiBF4, LiB(C2O4)2, LiN(SO2F)2, LiN(SO2CF3)2, LiN(SO2C2F3)2, LiN(SO2C2F5)2, LiN(SO2F)(SO2CF3), LiN(SO2F)(SO2C2F5), LiN(SO2CF3)(SO2C2F5), LiAsF6, LiBF2C2O4, LiNO3, LiPF3(CF2CF3)3, LiBETI, LiTDI, and mixtures thereof.

[0122] Preferably, the lithium-ion battery further comprises a non-aqueous organic solvent. Said solvent may be used to solubilize the lithium salt. As examples of the non-aqueous organic solvent, mention may be made of non-protic organic solvents, such as N- methylpyrrolidone (NMP), N-butylpyrrolidone, ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC), butylene carbonate, gamma-butyro lactone, 1,2-dimethoxy ethane, tetrahydrofuran, 2-methyl tetrahydrofuran, dimethylsulfoxide (DMSO), 1,3 -di oxolane, formamide, N,N-dimethylformamide (DMF), dioxolane, acetonitrile, nitromethane, methyl formate, methyl acetate, ethyl acetate (EA), butyl acetate (BA), methyl propionate, ethyl propionate, methyl butyrate, phosphoric acid triester, trimethoxy methane, dioxolane derivatives, sulfolane, methyl sulfolane, l,3-dimethyl-2-imidazolidinone, propylene carbonate derivatives, tetrahydrofuran derivatives, and mixtures thereof.

[0123] Although the invention is illustrated and described herein with reference to specific embodiments, the invention is not intended to be limited to the details shown. Rather, various modifications may be made in the details within the scope and range of equivalents of the claims and without departing from the invention.

[0124] EXAMPLES

[0125] Example 1: Preparation of cathode samples

[0126] Slurries comprising lithium iron phosphate (LFP) (80% / 85% / 90%) and a resin system (20% / l 5% / 10%) were prepared and introduced into a Flacktek® polypropylene high-speed mixer cup. The mixture was blended for 4 minutes at 2000 rpm. Isopropanol (35% / 40% / 50%) was added for dispersion purposes. The resin system consisted of adhesion promoters, oligomers, and optionally acrylate monomers.

[0127] Subsequently, the slurries were cast onto an aluminum collector that had been cleaned with acetone prior to casting, with thicknesses ranging between 50 to 100 pm. The casted slurries underwent E-beam curing with a surface dose of 50 kGy, a speed of 6 m / min, and a voltage of 200 kV, utilizing 2 passes. The samples were dried in an oven at 60°C for 5 minutes before curing.

[0128] Provided below in Tables 1A-1D are the constituents used and their amounts in parts by weight. Table 1A

[0129] Table IB Table 1C

[0130] Table ID LFP is lithium iron phosphate (LiFePC ).

[0131] CN9021 is an aliphatic urethane diacrylate oligomer available from Sartomer.

[0132] Silane A- 187 was used as a control and is an adhesion promoter commercially available from Momentive Performance Materials of Niskayuna, New York.

[0133] IP A is isopropanol.

[0134] SR9053 is a blend of a diacrylate phosphate diester and monoacrylate phosphate monoester in 50% SR502 having the formula: wherein SR502 is ethoxylated (9) trimethylolpropane triacrylate

[0135] SR531 is cyclic trimethylolpropane formal acrylate

[0136] SR9054 is a 50 / 50 blend of a dimethacrylate phosphate diester and monomethacrylate phosphate monoester having the formula:

[0137] SR499 is ethoxylated (6) trimethylolpropane triacrylate

[0138] NTX14724 was made as follows. Toluene was used as process solvent to disperse P2O5 and the caprolactone modified 2-hydroxyethyl (meth)acrylate was then metered into the P2Os / toluene mixture. Toluene was then stripped off to obtain phosphate esters.

[0139] NTX153 19 was made as follows. SR833S was used to disperse P2O5. With no process solvent required, the step to remove the process solvent could be omitted. The caprolactone modified 2-hydroxyethyl (meth)acrylate was metered into the P2O5 / SR833S mixture to obtain a phosphate esters monomer blend. Final product was filtered through 0.5 micron bag to remove unreacted P2O5. wherein SR833S is a diacrylate monomer having the following structure:

[0140] Example 2: Visual assessment of the samples

[0141] The electrodes prepared in Example 1 were tested to evaluate their aspect and their adherence to the current collector.

[0142] The results of these experiments are reported in the following Tables 2A-2D.

[0143] Table 2A Table 2B

[0144] Table 2C

[0145] Table 2D

[0146] All formulations containing the adhesion promoters of this invention allowed preparing electrodes comprising lower than 85% of electrode particulate material, which did not have cracks and adhered well to the current collector (see Samples 6, 9, 12, 15 and 18). This was not the case of samples which contained either no adhesion promoter or a silane compound as an adhesion promoter (see Samples 1 and 3-5). These samples exhibited consistent issues with poor wetting and the presence of cracks, resulting in poor adherence during and after folding.

[0147] In formulations comprising at least 85% of electrode particulate material, the use of modified caprolactone-4HEA and 10HEA (NTX15319 and NTX14724) as adhesion promoters enhanced adhesion when compared to unmodified adhesion promoters of this invention (SR9053 and SR9054) (see Samples 13-14 and 16-17 vs. Samples 7-8 and 10-11). These samples consistently showed excellent wetting, uniform coating, and a complete absence of cracks, resulting in strong adherence after folding and ensuring that the coating remained intact without peeling off.

[0148] Although Samples 7, 8, 10, and 11 still had issues with poor wetting and / or the presence of cracks at higher particulate loadings, they performed better than the control samples overall, indicating a step up in quality.

[0149] Moreover, incorporating (meth)acrylate-functionalized monomers such as SR499 and SR531 into the formulations (Samples 18-20) was shown to increase the crosslinking density, which improved mechanical properties like adhesion and resistance to cracking. It was thus possible to lower the amount of adhesion promoter.

[0150] These monomers also optimize wetting and flow, leading to a more uniform, defect-free coating, and allow for fine-tuning of curing kinetics, making the formulation more robust and durable.

[0151] It should be understood that any two quantitative values assigned to a property may constitute a range of that property, and all combinations of ranges formed from all stated quantitative values of a given property are contemplated in this disclosure. The subject matter disclosed herein has been described in detail and by reference to specific embodiments. It should be understood that any detailed description of a component or feature of an embodiment does not necessarily imply that the component or feature is essential to the particular embodiment or to any other embodiment.

Claims

CLAIMS1. A composition in the form of a slurry comprising:(A) an electrode particulate material in an amount of at least 50 wt % by weight, based on the weight of the composition;(B) a (meth)acrylate-functionalized oligomer;(C) a solvent;(D) an adhesion promoter comprising a (meth)acrylated phosphate ester;(E) optionally, a (meth)acrylate-functionalized monomer; and(F) optionally, a free radical photoinitiator.

2. The composition of claim 1, wherein the (meth)acrylated phosphate ester of component (D) is selected from the group consisting of: a mono(meth)acrylated phosphate ester, a di(meth)acrylated phosphate ester or a mixture thereof, preferably the (meth)acrylated phosphate ester comprises a mixture of a mono(meth)acrylated phosphate ester and a di(meth)acrylated phosphate ester, for instance in a weight ratio of 30:70 to 70:30, preferably from 40:60 to 60:40 and still preferably of about 50:50.

3. The composition of claim 2, wherein the mono(meth)acrylated phosphate ester and the di(meth)acrylated phosphate ester are monomers having formulas (I) and (II), respectively:wherein in Formula (1) and Formula (2): each Ri is independently H or Ci-Ce alkyl; each R2 is independently H or Ci-Ce alkyl; each R3 is independently H or Ci-Ce alkyl; each X is independently Ci-Ce alkylene, where a N, O or S atom may be inserted between any two carbon atoms present in the alkylene chain and wherein carbon atoms in the alkylene chain may be substituted with a C1-C3 alkyl group; each R4 is independently H or a cation; each R5 is independently H or a cation; each n is independently 4 to 7; and each m is independently 0 to 25.

4. The composition of claim 3, wherein the mono(meth)acrylated phosphate ester and / or the di(meth)acrylated phosphate ester is such that at least one, and preferably all, the following conditions are met:• Ri = R2=R4=Rs=H• R3= H or CH3• X = -CH2-CH2-.

5. The composition of claim 3 or 4, wherein the mono(meth)acrylated phosphate ester and / or the di(meth)acrylated phosphate ester is such that m is 0.

6. The composition of claim 3 or 4, wherein the mono(meth)acrylated phosphate ester and / or the di(meth)acrylated phosphate ester is such that m ranges from 1 to 25, preferably 2 to 18, and more preferably 3 to 12 and n is 5.

7. The composition of any one of claims 1-6, wherein component (D) is present in an amount of about 0.3 to about 5 wt%, preferably about 0.4 to about 2 wt%, and most preferably about 0.5 to about 1.5 wt% based on the weight of components (A), (B), (D) and, if present, (E) and (F).

8. The composition of any one of claims 1-7, wherein the composition comprises from 3.0 to 120 parts by weight, preferably from 5.2 to 115 parts by weight, more preferably from 6.0 to 110 parts by weight, of component (D) based on 100 parts by weight of components (B) and (E), if present.

9. The composition of any one of claims 1-8, wherein the electrode particulate material is a cathode particulate material and is selected from the group consisting of lithium metal oxides wherein the metal is selected from cobalt, manganese, nickel and / or vanadium, including lithium nickel manganese cobalt oxide, lithium nickel cobalt aluminum oxide, lithium manganese oxide, lithium nickel oxide and lithium cobalt oxide; lithium iron phosphate; mixtures thereof; and combinations thereof with carbon particles, preferably the cathode particulate material is lithium iron phosphate.

10. The composition of any one of claims 1-8, wherein component (A) comprises a cathode particulate material comprising an active material selected from the group consisting of LiCoCh; Li(Ni, Co, A1)O2; Li(i+X)NiaMnbCoc(where x represents a real number of 0 or more, a = 0.9, 0.8, 0.6, 0.5, or 1 / 3, b = 0.05, 0.1, 0.2, 0.3, or 1 / 3, c = 0.05, 0.1, 0.2, or 1 / 3); LiNiO2; LiMn2O4; LiCoMnCU; LisNiMmCE; Li3Fe2(PO4)3; Li3V2(PO4)3; a spinel Li Mn substituted by a different element having a composition represented by Lii+zMn2-z-yMyO4, M representing at least one metal chosen from Al, Mg, Co, Fe, Ni, and Zn, y and z independently representing a real number between 0 and 2; a lithium metal phosphate having a composition represented by LiM’PCU, with M’ representing Fe, Mn, Co, or Ni or a lithium bimetal phosphateLiM1uM2i-uPO4 (LMFP) with M1and M2are different and independently selected from Fe, Mn, Co, or Ni and 0<u<l; and mixtures thereof.

11. The composition of claim 10, wherein the cathode particulate material comprises lithium iron phosphate (LiFePCE).

12. The composition of claim 10 or 11, wherein the cathode particulate material further comprises a conductive additive selected from carbon-based additives such as graphite, graphene, carbon black, carbon fibers or carbon nanotubes (CNTs); metal powders such as silver, nickel, copper or aluminum powder; and mixtures thereof.

13. The composition of any one of claims 1-12, wherein component (A) is present in an amount of 50 to 98 wt.%, preferably 60 to 98 wt.%, more preferably 70 to 97 wt.%, still preferably 80 to 96 wt.%, such as 85 to 95 wt.% or 90 to 95 wt.%, relative to the weight of components (A), (B), (D) and, if present, (E) and (F).

14. The composition of any one of claims 1-13, wherein component (B) comprises or consists of at least one (meth)acrylate-functionalized oligomer selected from the group consisting of urethane (meth)acrylate oligomers, epoxy (meth)acrylate oligomers, polyether (meth)acrylate oligomers, polydiene (meth)acrylate oligomers, polycarbonate (meth)acrylate oligomers, polyester (meth)acrylate oligomers, (meth)acrylic (meth)acrylate oligomers and mixtures thereof, preferably from the group consisting of urethane (meth)acrylate oligomers, polyester (meth)acrylate oligomers and polyether (meth)acrylate oligomers, more preferably component (B) comprises or consists of a polyether urethane (meth)acrylate or a polyester urethane (meth)acrylate, still preferably component (B) comprises or consists of an aliphatic polyether-based urethane diacrylate oligomer.

15. The composition of any one of claims 1-14, wherein component (B) is present in an amount of about 2 to about 20 wt%, preferably about 4 to about 15 wt%, and most preferably about 6 to about 12 wt% based on the weight of components (A), (B), (D) and, if present, (E) and (F).

16. The composition of any one of claims claim 1-15, wherein component (E) is present and comprises or consists of a (meth)acrylate monomer selected from the group consisting of aliphatic monofunctional (meth)acrylate monomers, preferably cyclic aliphatic monofunctional (meth)acrylate monomers such as tetrahydrofurfuryl acrylate, isobomyl acrylate, trimethylolpropane formal acrylate and combinations thereof; aliphatic difunctional (meth)acrylate monomers, preferably acyclic aliphatic difunctional (meth)acrylate monomers such as 1,4-butanediol di(meth)acrylate, 1,6 -hexanediol diacrylate, and combinations thereof; and mixtures thereof.

17. The composition of any one of claims 1-16, wherein component (C) comprises or consists of a polar organic solvent selected from N-methylpyrrolidone (NMP), dimethylsulfoxide (DMSO), N,N-dimethylformamide (DMF), triethylphosphite, triethylphosphate, acetone, cyclopentanone, tetrahydrofuran, methyl ethyl ketone (MEK), methyl isobutyl ketone (MiBK), ethyl acetate (EA), butyl acetate (BA), methyl propionate, ethyl propionate, methyl butyrate, isopropanol, ethanol, methanol, acetonitrile, ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC), butylene carbonate, gamma-butyrolactone, N- butylpyrrolidone, and mixtures thereof.

18. The composition of any one of claims 1-17, wherein component (C) is present in an amount of about 30 to about 80 wt%, preferably about 35 to about 70 wt%, and most preferably about 45 to about 70 wt% based on the weight of the composition.

19. The composition of any one of claims 1-18, which is anhydrous.

20. An electrode comprising a current collector and a layer obtained by using the composition according to any one of claims 1-19.

21. A method of forming an electrode comprising the steps of:(a) applying a composition of any of claims 1-19 to a current collector to form a layer;(b) optionally, heating the layer;(c) curing the layer by exposing it to radiation; and(d) optionally consolidating the electrode by thermomechanical treatment.

22. The method of claim 21, wherein the composition does not comprise component (E) and the radiation is electron beam radiation.

23. The method of claim 21, wherein the composition comprises component (E) and the radiation is actinic radiation.

24. A lithium-ion battery comprising a cathode, an anode and a separator, characterized in that the cathode and / or the anode is an electrode according to claim 20 or an electrode made according to the method of any one of claims 21-23.

25. A lithium-ion battery according to claim 24, wherein the cathode is an electrode according to claim 20 or an electrode made according to the method of any one of claims 21- 23.

26. The lithium-ion battery according to claim 24 or 25, wherein said battery further comprises a lithium salt, preferably a lithium salt selected from the group consisting of LiCF3SO3, LiPF6, LiC104, LiBF4, LiB(C2O4)2, LiN(SO2F)2, LiN(SO2CF3)2, LiN(SO2C2F3)2, LiN(SO2C2F5)2, LiN(SO2F)(SO2CF3), LiN(SO2F)(SO2C2F5), LiN(SO2CF3)(SO2C2F5), LiAsF6, LiBF2C2O4, LiNO3, LiPF3(CF2CF3)3, LiBETI, LiTDI, and mixtures thereof.

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