The invention provides an ecological removing structure of a reinforced concrete inner support and a construction method thereof. The ecological removing structure of the reinforced concrete inner support and the construction method comprise mechanical equipment, a connecting structure, a broken column structure, a collecting structure, a transmission structure and a bottom sealing structure, wherein the broken column structure comprises a holding barrel, a hydraulic tank, an oil inlet pipe, an oil outlet pipe, an outer barrel, an extrusion rod, a buffer chamber, an oil distribution pipe, an oil inlet bin, a one-way valve, an oil return pipe and a limiting bolt; the collecting structure comprises a collecting outer barrel, a discharge opening, a discharge door, a side support plate, a topring, an outer gear, a limiting ring and a pushing plate; and the transmission structure comprises a rack, a connecting rod, a first gear and a second gear. The ecological removing structure of the reinforced concrete inner support and the construction method have the advantages that the construction noise is low, waste materials can be recycled, and steel bars and concrete can be separated.