Iron-containing pseudoboehmite, sulfur recovery catalyst protected against oxygen leakage, and method of preparation

CN117427638BActive Publication Date: 2026-08-28PETROCHINA CO LTD
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Patent Information

Application Number
CN202210789846.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2022-07-06
Publication Date
2026-08-28
Estimated Expiration
2042-07-06

AI Technical Summary

Technical Problem

[0006]本发明所要解决的技术问题是:现有催化剂存在生产过程产生大量废水废液,且获得的催化剂铁利用率低等缺点,本发明提供了解决上述问题的一种含铁拟薄水铝石、抗漏氧保护硫磺回收催化剂及制备方法

Benefits of technology

[0025]1、本发明在拟薄水铝石粉体材料制备过程中添加含铁化合物和表面活性剂,使铁在拟薄水铝石粉体中高度分散,同时提高材料比表面积。制备过程中,考虑选用甲醇、甘油、甲苯等有机溶剂,同时在两亲型表面活性剂长链烷基胺的作用下,形成一种水包油的Pickering乳液反应体系。其中,表面活性剂在相界面规则排列,头部的胺基和尾部的烷基分别位于水相和油相。水热反应过程中,拟薄水铝石晶核表面的羟基与表面活性剂头部的胺基发生缩合反应,使其在相界面发生自组装反应,同时限制晶粒的进一步长大,由此合成的具有较大比表面积的含铁拟薄水铝石。然后将含铁拟薄水铝石粉体成型制备硫磺回收用抗漏氧保护催化剂,该发明有效增大了催化剂比表面积,缩短了工艺流程,提高了生产效率。其中,比表面积大小范围为200-400cm2 g-1,孔体积为0.4-0.7cm3 g-1

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Abstract

The application discloses a kind of iron-containing pseudo-boehmite, anti-leakage oxygen protective sulfur recovery catalyst and preparation method, in the preparation method for preparing pseudo-boehmite using hydrothermal method, iron-containing compound, amphiphilic surfactant and organic solvent are added;During hydrothermal reaction, the amine group of the head of amphiphilic surfactant and the alkyl of tail are located in aqueous phase and oil phase respectively, the hydroxyl on the surface of pseudo-boehmite crystal nucleus and the amine group of the head of surfactant condensation reaction occurs, and oil-in-water Pickering emulsion reaction system is formed, and iron-containing pseudo-boehmite is finally prepared by reaction.The iron-containing pseudo-boehmite is formed and used as anti-leakage oxygen protective sulfur recovery catalyst, to avoid the problems of existing impregnation method for preparing iron-containing catalyst, such as a large amount of waste water and waste liquid generated in production process, and low iron utilization rate of catalyst.
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Citation Information

Patent Citations

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    CN101189280A

  • Method for emulsifying an oily silicone phase in an aqueous phase, Anti-foaming emulsions

    WO2002062457A1