Pesticidal composition comprising a compound containing a 1, 2, 4-triazolyl and a 4-oxothiazolyl and another pesticidal agent

Abstract

The present disclosure relates to the field of molecules having pesticidal utility on pests in Phyla Arthropoda, Mollusca and Nematoda, methods of producing such molecules, intermediates used in such methods, and methods of using such pesticidal compositions against such pests. These pesticidal compositions can be used, for example, as acaricides, insecticides, acaricides, molluscicides, and nematicides.

Description

BACKGROUND OF THE INVENTION

[0001] The present disclosure relates to the field of: molecules having pesticidal utility against pests in the phyla Arthropoda, Mollusca, and Nematoda, methods for producing such molecules, intermediates used in such methods, and methods of using such pesticidal compositions against such pests. Such pesticidal compositions can be used, for example, as acaricides, insecticides, acaricides, molluscicides, and nematicides.

[0002] Each year, insects, plant pathogens, and weeds destroy more than 40% of all food produced. This loss occurs despite the application of pesticides and the use of a variety of non-chemical control measures (such as crop rotation) and biological control measures. If only a portion of this food could be saved, it could be used to feed more than three billion malnourished people in the world (Pimental, D., Pest Control in World Agriculture, Agricultural Sciences - Volume II, 2009).

[0003] Plant-parasitic nematodes are one of the most common pests and are often one of the most insidious and costly pests. It is estimated that losses attributable to nematodes range from about 9% in developed countries to about 15% in underdeveloped countries. However, a survey of various crops in 35 states of the United States showed losses due to nematodes as high as 25% (Nicol et al., Current Nematode Threats to World Agriculture, Genomic and Molecular Genetics of Plant-Nematode Interactions pages 21-43, 2011).

[0004] It should be noted that gastropods (slugs and snails) are pests of lower economic importance than other arthropods or nematodes, but in some places, they can significantly reduce yields, seriously affect the quality of harvested products, and spread diseases to humans, animals, and plants. Although only a few dozen gastropod species are serious regional pests, and a few species are important pests globally. In particular, gastropods affect a wide variety of agricultural and horticultural crops, such as arable land, pastoral, and fiber crops; vegetables; bush and tree fruits; herbs; and ornamental plants (Speiser, B., Molluscicides, Encyclopedia of Pest Management, Chapter 219, pp. 506 - 508, 2002).

[0005] Termites cause damage to all types of private and public structures as well as agricultural and forestry resources. In 2005, it was estimated that termites caused more than $50 billion in damage globally each year (Korb, J., Termites, Current Biology, Vol. 17, No. 23, 2007).

[0006] Therefore, for many reasons (including those mentioned above), the need for new pesticidal agents, which are expensive (estimated at approximately $286 million per pesticidal agent in 2014), time - consuming (an average of approximately 11.3 years per pesticidal agent), and difficult to develop, persists (Phillips McDougall, The Cost of New Agrochemical Product Discovery, Development and Registration in 1995, 2000, 2005 - 8 and 2010 - 2014. R&D expenditure in 2014 and expectations for 2019, 2016).

[0007] Definitions

[0008] The examples provided herein are not exhaustive and should not be construed as restrictive. It is understood that substituents should comply with chemical bonding rules and steric compatibility constraints with respect to the specific molecule to which they are attached. These definitions are for the purposes of this disclosure only.

[0009] The term "active substance" or "active ingredient" means the following group of pesticidal agents, each of which is considered an "active substance" or "active ingredient" - selected from the group AIGA-1, AIGA-2, or AI-1 or AI-2. These common names can be found in multiple locations, such as the "Compendium of Pesticide Common Names" of the British Crop Production Council, available at https: / / pesticidecompendium.bcpc.org / . For a variety of reasons, these active ingredients can be used in combination with the molecules disclosed below.

[0010] The term "AIGA-1" refers to the following preferred group of mixing combinations to form a mixture with multiple agricultural functions, and the mixing combinations are selected from the group consisting of: abamectin, acephate, acequinocyl, acetamiprid, acrinathrin, acynonapyr, afidopyropen, alanycarb, aldicarb, allethrin, alpha-cypermethrin, aminopyralid, amitraz, azadirachtin, azamethiphos, azinphos-ethyl, azinphos-methyl, azocyclotin, azoxystrobin, bendiocarb, benfuracarb, bensultap, benzoximate, benzpyrimoxan, beta-cyfluthrin, beta-cypermethrin, bifenazate, bifenthrin, bioallethrin, biresmethrin, bistrifluron, broflanilide, bromopropylate, buprofezin, butocarboxim, butoxycarboxim, cadusafos, carbaryl, carbofuran, carbosulfan, carboxin, cartap hydrochloride, chinomethionat, chlorantraniliprole, chlordane, chlorethoxyfos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormephos,Chlorpyrifos, Chlorpyrifos-methyl, Chromafenozide, Clofentezine, Clopyralid, Cloquintocet, Clothianidin, Copper Hydroxide, Coumaphos, Cyanophos, Cyantraniliprole, Cyclaniliprole, Cyclobutrifluram, Cycloprothrin, Cycloxaprid, Cyenopyrafen, Cyflumetofen, Cyfluthrin, Cyhalothrin, Cyhexatin, Cymoxanil, Cypermethrin, Cyphenothrin, Cyproflanilide, Cyromazine, d-cis-trans Allethrin, DDVP, Deltamethrin, Demeton-S-methyl, Diafenthiuron, Diazinon, Dichlorvos, Dicofol, Dicrotophos, Difenoconazole, Diflovidazin, Diflubenzuron, Dimethoate, Dimethylvinphos, Dimpropyridaz, Dinotefuran, Disulfoton, DNOC, d-trans Allethrin, Emamectin, Emamectin Benzoate, Empenthrin, Endosulfan, EPN, Esfenvalerate, Ethaboxam, Ethiofencarb, Ethion, Ethiprole, Ethoprophos, Etofenprox,famoxadone, famphur, fenamiphos, fenazaquin, fenbuconazole, fenbutatin oxide, fenitrothion, fenmezoditiaz, fenobucarb, fenoxycarb, fenpropathrin, fenpyroximate, fenthion, fenvalerate, fipronil, flazasulfuron, flonicamid, florasulam, fluacrypyrim, fluazaindolizine, flubendiamide, flucycloxuron, flucythrinate, fludioxonil, fluensulfone, flufenoxuron, flumethrin, flumioxazin, fluopyram, fluoxapiprolin, fluoxastrobin, flupyradifurone, flupyrimin, fluroxypyr, fluxametamide, fluxapyroxad, formetanate, fosthiazate, furathiocarb, gamma-cyhalothrin, glyphosate, halauxifen, halfenprox, halofenozide, heptenophos, hexaflumuron, hexythiazox, hydramethylnon, hydroprene, imazamox, imazapyr, imicyafos, imidacloprid, imiprothrinindazapyroxamet, indoxacarb, inpyrfluxam, ipconazole, isocycloseram, isofenphos, isoflucypram, isoprocarb, isoxathion, kadethrin, kinoprene, lambda-cyhalothrin, lepimectin, lufenuron, malathion, mancozeb, MCPA, mecarbam, mefenoxam, metaflumizone, metalaxyl, metconazole, methamidophos, methenamine, methidathion, methiocarb, methomyl, methoprene, methoxychlor, methoxyfenozide, metolcarb, metsulfuron, mevinphos, milbemectin, monocrotophos, myclobutanil, naled, nicosulfuron, nitrapyrin, novaluron, noviflumuron, omethoate, oxamyl, oxathiapiprolin, oxazosulfyl, oxydemeton-methyl, parathion, parathion-methyl, penflufen, penthiopyrad, permethrin, phenothrin, phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, picarbutrazoxPicloram, Picoxystrobin, Pinoxaden, Pirimicarb, Pirimiphos-methyl, Prallethrin, Profenofos, Propargite, Propetamphos, Propiconazole, Propoxur, Propyzamide, Prothioconazole, Prothiofos, Spiflumetofen, Pyflubumide, Pymetrozine, Pyraclofos, Pyraclostrobin, Pyrethrum, Pyridaben, Pyridalyl, Pyridaphenthion, Pyrifluquinazon, Pyrimidifen, Pyriproxyfen, Pyroxasulfone, Quinalphos, Resmethrin, Rimsulfuron, Rotenone, Sedaxane, Silafluofen, Spidoxamat, Spinetoram, Spinosad, Spirobudifen, Spirodiclofen, Spiromesifen, Spiropidion, Spirotetramat, Sulfluramid, Sulfotep, Sulfoxaflor, Tau-fluvalinate, Tebuconazole, Tebufenozide, Tebufenpyrad, Tebupirimfos, Teflubenzuron, Tefluthrin, Temefos, Terbufos, Tetrachlorvinphos, Tetradifontetramethrin, tetraniliprole, theta-cypermethrin, thiabendazole, thiamethoxam, thiocyclam, thiodicarb, thiofanox, thiometon, thiosultap-sodium, thiram, tiorantraniliprole, tioxazafen, tolfenpyrad, tralkoxydim, tralomethrin, transfluthrin, triazamate, triazophos, trichlorfon, triclopyr, trifloxystrobin, triflumezopyrim, triflumuron, trimethacarb, vamidothion, XMC, xylylcarb, zeta-cypermethrin, and 2,4-D. For the avoidance of doubt, each of these biocides is an active ingredient.

[0011] The term "AIGA-2" means the following preferred group of blends for use in forming extended pesticidal compositions and having multiple agricultural functions: abamectin, acetamiprid, bixafen, bifenthrin, chlorantraniliprole, chlorfenapyr, cyantraniliprole, cyclaniliprole, flubendiamide, fipronil, flonicamid, fluopyram, flupyradifurone, flufiprole, flutriafol, imidacloprid, indoxacarb, isoxazolin-3-carboxamide, lambda-cyhalothrin, methoxyfenozide, metazachlor, pyriproxyfen, spirodiclofen, spinetoram, spinosad, tebufenozide, spirotetramat, flonicamid, thiamethoxam, and triflumezopyrim.

[0012] The molecule named N-(4-chloro-2-(pyridin-3-yl)thiazol-5-yl)-N-ethyl-3-(methylsulfonyl)propanamide is an active ingredient and, for the purposes of this disclosure, is defined as "AI-1"

[0013]

[0014] The molecule named N-(3-chloro-(pyridin-3-yl)-1H-pyrazol-4-yl)-2-(methylsulfonyl)propanamide is the active ingredient and, for the purposes of this disclosure, is defined as "AI-2".

[0015]

[0016] The term "site" means a habitat, breeding ground, plant, seed, soil, material, or environment where pests are growing, may grow, or may pass through. For example, a site can be: where crops, trees, fruits, grains, forage species, vines, turf, and / or ornamental plants are growing; where livestock are housed; the interior or exterior surfaces of a building (such as where grains are stored); building materials used in a building (such as impregnated wood); and the soil around a building.

[0017] The term "pest" means an organism harmful to humans or human concerns (such as crops, food, livestock, etc.), where the organism is from the phylum Arthropoda, Mollusca, or Nematoda. Specific examples are ants, aphids, bed bugs, beetles, borers, caterpillars, cockroaches, crickets, earwigs, fleas, flies, grasshoppers, maggots, wasps, jassids, leafhoppers, lice, locusts, maggots, mealybugs, mites, moths, nematodes, plant bugs, planthoppers, psyllids, sawflies, scales, termites, slugs, snails, spiders, springtails, stink bugs, Symphyla, termites, thrips, ticks, wasps, whiteflies, and horsehair worms.

[0018] Additional examples are pests among the following

[0019] (1) Chelicerata, Myriapoda, and Hexapoda.

[0020] (2) Arachnida, Symphyla, and Insecta.

[0021] (3) Order Anoplura. A non-exhaustive list of specific genera includes, but is not limited to: Haematopinus spp., Hoplopleura spp., Linognathus spp., Pediculus spp., Polyplax spp., Solenopotes spp., and Neohaematopinis spp. A non-exhaustive list of specific species includes, but is not limited to: Haematopinus asini, Haematopinus suis, Linognathus setosus, Linognathus ovillus, Pediculus humanus capitis, Pediculus humanus humanus, and Pthirus pubis.

[0022] (4) Order Coleoptera. A non-exhaustive list of specific genera includes, but is not limited to: Acanthoscelides spp., Agriotes spp., Anthonomus spp., Apion spp., Apogonia spp., Araecerus spp., Aulacophora spp., Bruchus spp., Cerosterna spp., Cerotoma spp., Ceutorhynchus spp., Chaetocnema spp., Colaspis spp., Ctenicera spp., Curculio spp., Cyclocephala spp., Diabrotica spp., Dinoderus spp., Gnathocerus spp., Hemicoelus spp., Heterobostruchus spp., Hypera spp., Ips spp., Lyctus spp., Megascelis spp., Meligethes spp., Mezium spp., Niptus spp., Otiorhynchus spp., Pantomorus spp., Phyllophaga spp., Phyllotreta spp., Ptinus spp., Rhizotrogus spp., Rhynchites spp., Rhynchophorus spp., Scolytus spp., Sphenophorus spp., Sitophilus spp., Tenebrio spp., and Tribolium spp. A non-exhaustive list of specific species includes, but is not limited to: Acanthoscelides obtectusObtectus), Agrilus planipennis, Ahasverus advena, Alphitobius diaperinus, Anoplophora glabripennis, Anthonomus grandis, Anthrenus verbasci, Anthrenus falvipes, Ataenius spretulus, Atomaria linearis, Attagenus unicolor, Bothynoderes punctiventris, Bruchus pisorum, Callosobruchus maculatus, Carpophilus hemipterus, Cassida vittata, Cathartus quadricollis, Cerotoma trifurcata, Ceutorhynchus assimilis, Ceutorhynchus napi, Conoderus scalaris, Conoderus stigmosus, Conotrachelus nenuphar, Cotinis nitida, Crioceris asparagi, Cryptolestes ferrugineus, Cryptolestes pusillus, Cryptolestes turcicus, Cylindrocopturus adspersus, Deporaus marginatus, Dermestes lardarius, Dermestes maculatus, Epilachna varivestis, Euvrilletta peltata, Faustinus cubae, Hylobius pales, Hylotrupes bajulus, Hyperapostica), coffee berry borer (Hypothenemus hampei), cigarette beetle (Lasioderma serricorne), Colorado potato beetle (Leptinotarsa decemlineata), grey-headed click beetle (Limonius canus), Liogenys fuscus, Liogenys suturalis, rice water weevil (Lissorhoptrus oryzophilus), Lophocateres pusillus, Lyctus planicollis, Maecolaspis joliveti, Melanotus communis, Meligethes aeneus, Melolontha melolontha, Necrobia rufipes, Oberea brevis, Oberea linearis, coconut rhinoceros beetle (Oryctes rhinoceros), Oryzaephilus mercator, Oryzaephilus surinamensis, black-horned flea beetle (Oulema melanopus), rice flea beetle (Oulema oryzae), Phyllophaga cuyabana, Polycaon stoutti, Japanese beetle (Popillia japonica), Prostephanus truncatus, Rhyzopertha dominica, Sitona lineatus, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum, Tenebroides mauritanicus, Tribolium castaneum, Tribolium confusum, Trogoderma granarium, Trogoderma variabile, Xestobium rufovillosum, and Zabrus tenebrioides.

[0023] (5) Order Dermaptera. A non-exhaustive list of specific species includes, but is not limited to: Forficula auricularia.

[0024] (6) Order Blattaria. A non-exhaustive list of specific species includes, but is not limited to: Blattella germanica, Blattella asahinai, Blatta orientalis, Blatta lateralis, Parcoblatta pennsylvanica, Periplaneta americana, Periplaneta australasiae, Periplaneta brunnea, Periplaneta fuliginosa, Pycnoscelus surinamensis, and Supella longipalpa.

[0025] (7) Order Diptera. A non-exhaustive list of specific genera includes, but is not limited to: Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Bactrocera spp., Ceratitis spp., Chrysops spp., Cochliomyia spp., Contarinia spp., Culex spp., Culicoides spp., Dasineura spp., Delia spp., Drosophila spp., Fannia spp., Hylemya spp., Liriomyza spp., Musca spp., Phorbia spp., Pollenia spp., Psychoda spp., Simulium spp., Tabanus spp., and Tipula spp.A non-exhaustive list of specific species includes, but is not limited to: Agromyza frontella, Anastrepha suspensa, Anastrepha ludens, Anastrepha obliqua, Bactrocera cucurbitae, Bactrocera dorsalis, Bactrocera invadens, Bactrocera zonata, Ceratitis capitata, Dasineura brassicae, Delia platura, Fannia canicularis, Fannia scalaris, Gasterophilus intestinalis, Gracillia perseae, Haematobia irritans, Hypoderma lineatum, Liriomyza brassicae, Liriomyza sativa, Melophagus ovinus, Musca autumnalis, Musca domestica, Oestrus ovis, Oscinella frit, Pegomya betae, Piophila casei, Psila rosae, Rhagoletis cerasi, Rhagoletis pomonella, Rhagoletis mendax, Sitodiplosis mosellana, and Stomoxys calcitrans.

[0026] (8) Order Hemiptera. A non-exhaustive list of specific genera includes, but is not limited to: Adelges spp., Aulacaspis spp., Aphrophora spp., Aphis spp., Bemisia spp., Ceroplastes spp., Chionaspis spp., Chrysomphalus spp., Coccus spp., Empoasca spp., Euschistus spp., Lepidosaphes spp., Lagynotomus spp., Lygus spp., Macrosiphum spp., Nephotettix spp., Nezara spp., Nilaparvata spp., Philaenus spp., Phytocoris spp., Piezodorus spp., Planococcus spp., Pseudococcus spp., Rhopalosiphum spp., Saissetia spp., Therioaphis spp., Toumeyella spp., Toxoptera spp., Trialeurodes spp., Triatoma spp, and Unaspis spp.A non-exhaustive list of specific species includes, but is not limited to: Acrosternum hilare, Acyrthosiphon pisum, Aleyrodes proletella, Aleurodicus dispersus, Aleurothrixus floccosus, Amrasca biguttula biguttula, Aonidiella aurantii, Aphis fabae, Aphis gossypii, Aphis glycines, Aphis pomi, Aulacorthum solani, Bactericera cockerelli, Bagrada hilaris, Bemisia argentifolii, Bemisia tabaci, Blissus leucopterus, Boisea trivittata, Brachycorynella asparagi, Brevennia rehi, Brevicoryne brassicae, and Psylla pyrisuga.

[0027] (Cacopsylla pyri), Psylla pyricola, Calocoris norvegicus, Ceroplastes rubens, Cimex hemipterus, Cimex lectularius, Coccus pseudomagnoliarum, Dagbertus fasciatus, Dichelops furcatus, Diuraphis noxia, Diaphorina citri, Dysaphis plantaginea, Dysdercus suturellus, Edessa meditabunda, Empoasca vitis, Eriosoma lanigerum, Erythroneura elegantula, Eusarcoris ventralis

[0028] (Eurygaster maura), Euschistus conspersus, Euschistus heros

[0029] (Euschistus heros), Brown stink bug (Euschistus servus), Tea-winged stink bug (Halyomorpha halys), Cashew plant bug (Helopeltis antonii), Green peach aphid (Hyalopterus pruni), Cashew plant bug (Helopeltis antonii), Tea horned plant bug (Helopeltis theivora), Cottony cushion scale (Icerya purchasi), Mango leafhopper (Idioscopus nitidulus), Small green leafhopper (Jacobiasca formosana), Small brown planthopper (Laodelphax striatellus), European fruit lecanium (Lecanium corni), Large rice bug (Leptocorisa oratorius), Variable rice bug (Leptocorisa varicornis), Western tarnished plant bug (Lygus hesperus), Cotton mealybug (Maconellicoccus hirsutus), Spotted alfalfa aphid (Macrosiphum euphorbiae), English grain aphid (Macrosiphum granarium), Rose-grain aphid (Macrosiphum rosae), Four-lined leafhopper (Macrosteles quadrilineatus), Raspberry froghopper (Mahanarva fimbriolata), Bean bug (Megacopta cribraria), Rose-grain aphid (Metopolophium dirhodum), Longhorned coreid bug (Mictis longicornis), Green peach aphid (Myzus persicae), Lettuce aphid (Nasonovia ribisnigri), Green rice leafhopper (Nephotettix cincticeps), Long-nosed plant bug (Neurocolpus longirostris), Green stink bug (Nezara viridula), Brown planthopper (Nilaparvata lugens), Papaya mealybug (Paracoccus marginatus), Potato psyllid (Paratriozacockerelli), Citrus flatid scale (Parlatoria pergandii), Purple scale (Parlatoria ziziphi), Corn planthopper (Peregrinus maidis), Grape phylloxera (Phylloxera vitifoliae), Physokermes sp. (Physokermes piceae), California plant bug (Phytocoriscalifornicus), Phytocoris relativus, Piezodorus guildinii, Planococcus citri, Planococcus ficus, Poecilocapsus lineatus, Psallus vaccinicola, Pseudacysta perseae, Pseudococcus brevipes, Quadraspidiotus perniciosus, Rhopalosiphum maidis, Rhopalosiphum padi, Saissetia oleae, Scaptocoris castanea, Schizaphis graminum, Sitobion avenae, Sogatella furcifera, Trialeurodes vaporariorum, Trialeurodes abutiloneus, Unaspis yanonensis, and Zulia entrerriana.

[0030] (9) Order Hymenoptera. A non-exhaustive list of specific genera includes, but is not limited to: Acromyrmex spp., Atta spp., Camponotus spp., Diprion spp., Dolichovespula spp., Formica spp., Monommorium spp., Neodiprion spp., Paratrechina spp., Pheidole spp., Pogonomyrmex spp., Polistes spp., Solenopsis spp., Technomyrmex spp., Tetramorium spp., Vespula spp., Vespa spp., and Xylocopa spp. A non-exhaustive list of specific species includes, but is not limited to: Athalia rosae, Atta texana, Caliroa cerasi, Cimbex americana, Iridomyrmex humilis, Linepithema humile, Mellifera Scutellata, Monommorium minimum, Monommorium pharaonis, Neodiprion sertifer, Solenopsis invicta, Solenopsis geminata, Solenopsis molesta, Solenopsis richteri, Solenopsis xyloni, Tapinoma sessile, and Wasmannia auropunctata.

[0031] (10) Order Isoptera. A non-exhaustive list of specific genera includes, but is not limited to: Coptotermes spp., Cornitermes spp., Cryptotermes spp., Heterotermes spp., Kalotermes spp., Incisitermes spp., Macrotermes spp., Marginitermes spp., Microcerotermes spp., Procornitermes spp., Reticulitermes spp., Schedorhinotermes spp., and Zootermopsis spp. A non-exhaustive list of specific species includes, but is not limited to: Coptotermes acinaciformis, Coptotermes curvignathus, Coptotermes frenchi, Coptotermes formosanus, Coptotermes gestroi, Cryptotermes brevis, Heterotermes aureus, Heterotermes tenuis, Incisitermes minor, Incisitermes snyderi, Microtermes obesi, Cornitermes angularis

[0032] (Cryptotermes brevis), Heterotermes aureus, Heterotermes tenuis

[0033] (Heterotermes tenuis), Incisitermes minor, Incisitermes snyderi

[0034] (Incisitermes snyderi), Microtermes obesi, Cornitermes angularis

[0035] (Nasutitermes corniger), Odontotermes formosanus, Odontotermes obesus, Reticulitermes banyulensis, Reticulitermes grassei, Reticulitermes flavipes, Reticulitermes hageni, Reticulitermes hesperus, Reticulitermes santonensis, Reticulitermes speratus, Reticulitermes tibialis, and Reticulitermes virginicus.

[0036] (11) Order Lepidoptera. A non-exhaustive list of specific genera includes, but is not limited to: Adoxophyes spp., Agrotis spp., Argyrotaenia spp., Cacoecia spp., Caloptilia spp., Chilo spp.,

[0037] (Chrysodeixis spp.), Colias spp., Crambus spp., Diaphania spp., Diatraea spp., Earias spp., Ephestia spp., Epimecis spp., Feltia spp., Gortyna spp., Helicoverpa spp., Heliothis spp., Indarbela spp., Lithocolletis spp., Loxagrotis spp., Malacosoma spp., Nemapogon spp., Peridroma spp., Phyllonorycter spp., Pseudaletia spp., Plutella spp., Sesamia spp., Spodoptera spp., Synanthedon spp., and Yponomeuta spp. A non-exhaustive list of specific species includes, but is not limited to: Achaea janata, Adoxophyes orana, Agrotis ipsilon, Alabama argillacea, Amorbia cuneana, Amyelois transitella, Anacamptodes defectaria, Anarsia lineatella, Anomis sabulifera, Anticarsia gemmatalis, Archips argyrospila, Archips rosana, Argyrotaenia citrana, Autographa gamma, Bonagota cranaodes, Borbo cinnara, Bucculatrixthurberiella), Capua reticulana, Carposina niponensis, Chlumetia transversa, Choristoneura rosaceana, Cnaphalocrocis medinalis, Conopomorpha cramerella, Corcyra cephalonica, Cossus cossus, Cydia caryana, Cydia funebrana, Cydia molesta, Cydia nigricana, Cydia pomonella, Darna diducta, Diaphania nitidalis, Diatraea saccharalis, Diatraea grandiosella, Earias insulana, Earias vittella, Ecdytolopha aurantianum, Elasmopalpus lignosellus, Ephestia cautella, Ephestia elutella, Ephestia kuehniella, Epinotia aporema, Epiphyas postvittana, Erionota thrax, Estigmene acrea, Eupoecilia ambiguella, Euxoa auxiliaris, Galleria mellonella, Grapholita molesta, Hedylepta indicata, Helicoverpa armigera, Helicoverpa zea, Heliothis virescens, Hellula undalis, Keiferia lycopersicella, Leucinodesorbonalis), coffee leafminer (Leucoptera coffeella), apple leafminer (Leucoptera malifoliella), grape berry moth (Lobesia botrana), bean cutworm (Loxagrotis albicosta), gypsy moth (Lymantria dispar), peach leafminer (Lyonetia clerkella), oil palm caterpillar (Mahasena corbetti), cabbage moth (Mamestra brassicae), tobacco hornworm (Manduca sexta), bean pod borer (Maruca testulalis), bagworm (Metisa plana), armyworm (Mythimna unipuncta), tomato borer (Neoleucinodes elegantalis), rice leafroller (Nymphula depunctalis), winter moth (Operophtera brumata), European corn borer (Ostrinia nubilalis), Vesuvian moth (Oxydia vesulia), grape leafroller (Pandemis cerasana), apple leafroller (Pandemis heparana), African swallowtail (Papilio demodocus), pink bollworm (Pectinophora gossypiella), beet armyworm (Peridroma saucia), coffee leafminer (Perileucoptera coffeella), potato tuber moth (Phthorimaea operculella), citrus leafminer (Phyllocnistis citrella), apple blotch leafminer (Phyllonorycter blancardella), small white (Pieris rapae), green cloverworm (Plathypena scabra), apple fruit moth (Platynota idaeusalis), Indian meal moth (Plodia interpunctella), diamondback moth (Plutella xylostella), grape berry moth (Polychrosis viteana), citrus fruit borer (Prays endocarpa), olive fruit borer (Pray s oleae), armyworm (Pseudaletia unipuncta), soybean looper (Pseudoplusia includens), mint moth (Rachiplusia nu), yellow rice borer (Scirpophagaincertulas), Sesamia inferens, Sesamia nonagrioides, Setora nitens, Sitotroga cerealella, Sparganothis pilleriana, Spodoptera exigua, Spodoptera frugiperda, Spodoptera eridania, Thecla basilides, Tinea pellionella, Tineola bisselliella, Trichoplusia ni, Tuta absoluta, Zeuzera coffeae, and Zeuzera pyrina.

[0038] (12) Order Mallophaga. A non-exhaustive list of specific genera includes, but is not limited to: Anaticola spp., Bovicola spp., Chelopistes spp., Goniodes spp., Menacanthus spp., and Trichodectes spp. A non-exhaustive list of specific species includes, but is not limited to: Bovicola bovis, Bovicola caprae, Bovicola ovis, Chelopistes meleagridis, Goniodes dissimilis, Goniodes gigas, Menacanthus stramineus, Menopon gallinea, and Trichodectes canis.

[0039] (13) Order Orthoptera. A non-exhaustive list of specific genera includes, but is not limited to: Melanoplus spp. and Pterophylla spp. A non-exhaustive list of specific species includes, but is not limited to: Acheta domesticus, Anabrus simplex, Gryllotalpa africana, Gryllotalpa australis, Gryllotalpa brachyptera, Gryllotalpa hexadactyla, Locusta migratoria, Microcentrum retinerve, Schistocerca gregaria, and Scudderia furcata.

[0040] (14) Order Psocoptera. A non-exhaustive list of specific species includes, but is not limited to: Liposcelis decolor, Liposcelis entomophila, Lachesilla quercus, and Trogium pulsatorium.

[0041] (15) Order Siphonaptera. A non-exhaustive list of specific species includes, but is not limited to: Ceratophyllus gallinae, Ceratophyllus niger, Ctenocephalides canis, Ctenocephalides felis, and Pulex irritans.

[0042] (16) Thysanoptera. A non-exhaustive list of specific genera includes, but is not limited to: Caliothrips spp., Frankliniella spp., Scirtothrips spp., and Thrips spp. A non-exhaustive list of specific species includes, but is not limited to: Caliothrips phaseoli, Frankliniella bispinosa, Frankliniella fusca, Frankliniella occidentalis, Frankliniella schultzei, Frankliniella tritici, Frankliniella williamsi, Heliothrips haemorrhoidalis, Rhipiphorothrips cruentatus, Scirtothrips citri, Scirtothrips dorsalis, Taeniothrips rhopalantennalis, Thrips hawaiiensis, Thrips nigropilosus, Thrips orientalis, Thrips palmi, and Thrips tabaci.

[0043] (17) Thysanura. A non-exhaustive list of specific genera includes, but is not limited to: Lepisma spp. and Thermobia spp.

[0044] (18) Order Acarina. A non-exhaustive list of specific genera includes, but is not limited to: Acarus spp., Aculops spp., Argus spp., Boophilus spp., Demodex spp., Dermacentor spp., Epitrimerus spp., Eriophyes spp., Ixodes spp., Oligonychus spp., Panonychus spp., Rhizoglyphus spp., and Tetranychus spp.A non-exhaustive list of specific species includes, but is not limited to, Acarapis woodi, Acarus siro, Aceria mangiferae, Aculops lycopersici, Aculus pelekassi, Aculus schlechtendali, Amblyomma americanum, Brevipalpus obovatus, Brevipalpus phoenicis, Dermacentor variabilis, Dermatophagoides pteronyssinus, Eotetranychus carpini, Liponyssoides sanguineus, Notoedres cati, Oligonychus coffeae, Oligonychus ilicis, Ornithonyssus bacoti, Panonychus citri, Panonychus ulmi, Phyllocoptruta oleivora, Polyphagotarsonemus latus, Rhipicephalus sanguineus, Sarcoptes scabiei, Tegolophus perseaflorae, Tetranychus urticae, Tyrophagus longior, and Varroa destructor.

[0045] (19) Order Araneae. A non-exhaustive list of specific genera includes, but is not limited to: Loxosceles spp., Latrodectus spp., and Atrax spp. A non-exhaustive list of specific species includes, but is not limited to, Loxosceles reclusa, Latrodectus mactans, and Atrax robustus.

[0046] (20) Class Symphyla. A non-exhaustive list of specific species includes but is not limited to: Scutigerella immaculata.

[0047] (21) Subclass Collembola. A non-exhaustive list of specific species includes but is not limited to: Bourletiella hortensis, Onychiurus armatus, Onychiurus fimetarius, and Sminthurus viridis.

[0048] (22) Phylum Nematoda. A non-exhaustive list of specific genera includes but is not limited to: Aphelenchoides spp., Belonolaimus spp., Criconemella spp., Ditylenchus spp., Globodera spp., Heterodera spp., Hirschmanniella spp., Hoplolaimus spp., Meloidogyne spp., Pratylenchus spp., and Radopholus spp. A non-exhaustive list of specific species includes but is not limited to: Dirofilaria immitis, Globodera pallida, Heterodera glycines, Heterodera zeae, Meloidogyne incognita, Meloidogyne javanica, Onchocerca volvulus, Pratylenchus penetrans, Radopholus similis, and Rotylenchulus reniformis.

[0049] (23) Phylum Mollusca. A non-exhaustive list of specific species includes, but is not limited to: Cornu aspersum, Deroceras reticulatum, Limax flavus, Milax gagates, and Pomacea canaliculata.

[0050] In one aspect, the group of pests to be controlled is sap-feeding pests. Sap-feeding pests typically have piercing and / or sucking mouthparts and feed on the sap and internal plant tissues of plants. Examples of sap-feeding pests of particular agricultural concern include, but are not limited to: aphids, leafhoppers, moths, scale insects, thrips, psyllids, mealybugs, stink bugs, and whiteflies. Specific examples of orders with sap-feeding pests of agricultural concern include, but are not limited to, Phthiraptera and Hemiptera. Specific examples of Hemiptera of agricultural concern include, but are not limited to: species of Aulacaspis, species of Cercopis, species of Aphis, species of Bemisia, species of Coccus, species of Euschistus, species of Lygus, species of Macrosiphum, species of Nezara, and species of Rhopalosiphum.

[0051] In another aspect, the group of pests to be controlled is chewing pests. Chewing pests typically have mouthparts that allow them to chew on plant tissues including roots, stems, leaves, buds, and reproductive tissues (including, but not limited to, flowers, fruits, and seeds). Examples of chewing pests of particular agricultural concern include, but are not limited to: caterpillars, beetles, grasshoppers, and locusts. Specific examples of orders with chewing pests of agricultural concern include, but are not limited to, Coleoptera and Lepidoptera. Specific examples of Coleoptera of agricultural concern include, but are not limited to: species of Anthonomus, species of Colaspis, species of Chaetocnema, species of Chrysomela, species of Cybocephalus, species of Donacia, species of Hypera, species of Melolontha, species of Phyllotreta, species of Rhynchophorus, and species of Sitophilus.

[0052] The phrase "pesticidally effective amount" means the amount of a pesticidal agent required to achieve an observable effect on a pest, such as necrosis, death, retardation, prevention, elimination, destruction, or otherwise reduction in the presence and / or activity of the pest in a locus. Such an effect can occur when a pest population is expelled from a locus, the pest is incapacitated in or around a locus, and / or the pest is eradicated in or around a locus. Of course, combinations of these effects can occur. Generally, the pest population, activity, or both are desirably reduced by more than fifty percent, preferably by more than 90 percent, and most preferably by more than 99 percent. Generally, the pesticidally effective amount for agricultural purposes is from about 0.0001 grams per hectare to about 5000 grams per hectare, preferably from about 0.0001 grams per hectare to about 500 grams per hectare, and even more preferably from about 0.0001 grams per hectare to about 50 grams per hectare.

[0053] All references cited herein (including publications, patent applications, and patents) are incorporated herein by reference to the extent as if each reference was individually and specifically indicated to be incorporated by reference and set forth in its entirety herein.

[0054] Unless otherwise indicated in the text or clearly contradicted by the context, the terms "a", "an", "the", "at least one", and similar designators in the context of the present disclosure (especially in the context of the following claims) shall be construed to include both the singular and the plural. Unless otherwise indicated in the text or clearly contradicted by the context, the term "at least one" followed by a list of one or more items (e.g., "at least one of A and B") shall be construed to mean either one item selected from the listed items (A or B) or any combination of two or more of the listed items (A and B). Unless otherwise indicated, the terms "comprising", "having", "including", and "containing" shall be construed as open-ended terms (i.e., meaning "including but not limited to"). Unless otherwise indicated herein, the recitation of a range of values herein is merely intended to be a shorthand method of referring individually to each separate value falling within the range, and each separate value is incorporated into the specification as if it were individually recited herein. Unless otherwise indicated in the text or otherwise clearly contradicted by the context, all methods described herein can be performed in any suitable order. Unless otherwise stated, the use of any and all examples or exemplary language (e.g., "such as") provided herein is merely intended to better illustrate the present disclosure and is not intended to limit the scope of the present disclosure. No language in the specification should be construed as indicating any non-claimed element as essential to the practice of any embodiment of the present disclosure. In the present disclosure, the terms "molecule" and "compound" are used interchangeably. Detailed Description

[0055] This document discloses a pest control composition, which comprises:

[0056] (A) A molecule having a structure according to Formula I

[0057]

[0058] Wherein:

[0059] R 1 is CF3, CHF2, CF2CF3, OCF3, OCF2CF3, SF5, or SO2CF3;

[0060] R 2 is H, F, or CH3;

[0061] R 3 is CH3 or OCH3; and

[0062] R 4 is CH2OCH2CH3, CH2OCH2CF3, or CH2OCH2CH2F;

[0063] And (B) a mixing compatibility agent, which is

[0064] (1) A member of AIGA-1;

[0065] (2) A member of AIGA-2;

[0066] (3) AI-1; or

[0067] (4) AI-2.

[0068] Examples of molecules having Formula I are shown in Table 1.

[0069]

[0070]

[0071]

[0072]

[0073]

[0074] The molecules in part (A) having Formula I, and specifically, molecules F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, and F16 can be prepared by those skilled in the art. For example, see WO 2021 / 011722A1, WO 2014 / 160031, and WO 2013 / 009791.

[0075] The pesticidal composition can be mixed with active ingredients and other compatible mixtures to enhance the usefulness of the composition. Such active ingredients can have, for example, acaricidal, insecticidal, fungicidal, nematicidal activity, which broadens the scope of pest control as well as other materials, compounds, and compositions. The procedures for preparing such compositional mixtures are known in the art.

[0076] In addition, the following details are provided according to the above.

[0077] 1d. A pesticidal composition, comprising:

[0078] (A) A molecule having a structure according to Formula I

[0079]

[0080] Wherein:

[0081] R 1 is CF3, CHF2, CF2CF3, OCF3, OCF2CF3, SF5, or SO2CF3;

[0082] R 2 is H, F, or CH3;

[0083] R 3 is CH3 or OCH3; and

[0084] R 4 is CH2OCH2CH3, CH2OCH2CF3, or CH2OCH2CH2F;

[0085] And

[0086] (B) A compatible mixture, which is

[0087] (1) A member of AIGA;

[0088] (2) A member of AIGA-1;

[0089] (3) A member of AIGA-2;

[0090] (3) AI-1; or

[0091] (4) AI-2.

[0092] 2d. The pesticidal composition according to Detail 1d, wherein the molecule having a structure according to Formula I is F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, or F16.

[0093] 3d. The composition according to 2d, wherein the molecule is F1

[0094] 4d. The composition according to 2d, wherein the molecule is F2.

[0095] 5d. The composition according to 2d, wherein the molecule is F3.

[0096] 6d. The composition according to 2d, wherein the molecule is F4.

[0097] 7d. The composition according to 2d, wherein the molecule is F5.

[0098] 8d. The composition according to 2d, wherein the molecule is F6.

[0099] 9d. The composition according to 2d, wherein the molecule is F7.

[0100] 10d. The composition according to 2d, wherein the molecule is F8.

[0101] 11d. The composition according to 2d, wherein the molecule is F9.

[0102] 12d. The composition according to 2d, wherein the molecule is F10.

[0103] 13d. The composition according to 2d, wherein the molecule is F11.

[0104] 14d. The composition according to 2d, wherein the molecule is F12.

[0105] 15d. The composition according to 2d, wherein the molecule is F13.

[0106] 16d. The composition according to 2d, wherein the molecule is F14.

[0107] 17d. The composition according to 2d, wherein the molecule is F15.

[0108] 18d. The composition according to 2d, wherein the molecule is F16.

[0109] 19d. The composition according to 2d, wherein the molecule is a stereoisomer of F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, or F16.

[0110] 20d. The composition according to details 1d to 19d, wherein the admixture is one selected from AIGA.

[0111] 21d. The composition according to details 1d to 19d, wherein the admixture is one selected from AIGA-1.

[0112] 22d. The composition according to details 1d to 21d, wherein the admixture is abamectin.

[0113] 23d. The composition according to details 1d to 21d, wherein the admixture is acephate.

[0114] 24d. The composition according to details 1d to 21d, wherein the admixture is acequinocyl.

[0115] 25d. The composition according to details 1d to 21d, wherein the admixture is acetamiprid.

[0116] 26d. The composition according to details 1d to 21d, wherein the admixture is allethrin.

[0117] 27d. The composition according to details 1d to 21d, wherein the admixture is acynonapyr.

[0118] 28d. The composition according to details 1d to 21d, wherein the admixture is afidopyropen.

[0119] 29d. The composition according to details 1d to 21d, wherein the admixture is alanycarb.

[0120] 30d. The composition according to details 1d to 21d, wherein the admixture is aldicarb.

[0121] 31d. The composition according to details 1d to 21d, wherein the admixture is allethrin.

[0122] 32d. The composition according to details 1d to 21d, wherein the admixture is alpha-cypermethrin.

[0123] 33d. The composition according to details 1d to 21d, wherein the admixture is aminopyralid.

[0124] 34d. The composition according to details 1d to 21d, wherein the admixture is amitraz.

[0125] 35d. The composition according to details 1d to 21d, wherein the admixture is azadirachtin.

[0126] 36d. The composition according to details 1d to 21d, wherein the mixing combination is pirimiphos-methyl.

[0127] 37d. The composition according to details 1d to 21d, wherein the mixing combination is azinphos-ethyl.

[0128] 38d. The composition according to details 1d to 21d, wherein the mixing combination is azinphos-methyl.

[0129] 39d. The composition according to details 1d to 21d, wherein the mixing combination is cyhexatin.

[0130] 40d. The composition according to details 1d to 21d, wherein the mixing combination is azoxystrobin.

[0131] 41d. The composition according to details 1d to 21d, wherein the mixing combination is bendiocarb.

[0132] 42d. The composition according to details 1d to 21d, wherein the mixing combination is benfuracarb.

[0133] 43d. The composition according to details 1d to 21d, wherein the mixing combination is bensultap.

[0134] 44d. The composition according to details 1d to 21d, wherein the mixing combination is benzoximate.

[0135] 45d. The composition according to details 1d to 21d, wherein the mixing combination is bixafen.

[0136] 46d. The composition according to details 1d to 21d, wherein the mixing combination is beta-cyfluthrin.

[0137] 47d. The composition according to details 1d to 21d, wherein the mixing combination is beta-cypermethrin.

[0138] 48d. The composition according to details 1d to 21d, wherein the mixing combination is bifenazate.

[0139] 49d. The composition according to details 1d to 21d, wherein the mixing combination is bifenthrin.

[0140] 50d. The composition according to details 1d to 21d, wherein the mixing combination is allethrin.

[0141] 51d. The composition according to details 1d to 21d, wherein the mixing combination is bioallethrin.

[0142] 52d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is bistrifluron.

[0143] 53d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is broflanilide.

[0144] 54d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is bromopropylate.

[0145] 55d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is buprofezin.

[0146] 56d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is butocarboxim.

[0147] 57d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is butoxycarboxim.

[0148] 58d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is cadusafos.

[0149] 59d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is carbaryl.

[0150] 60d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is carbofuran.

[0151] 61d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is carbosulfan.

[0152] 62d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is carboxin.

[0153] 63d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is cartap hydrochloride.

[0154] 64d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is chinomethionat.

[0155] 65d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is chlorantraniliprole.

[0156] 66d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is chlordane.

[0157] 67d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is chlorfenvinphos.

[0158] 68d. The composition according to details 1d to 21d, wherein the mixing combination is chlorfenapyr.

[0159] 69d. The composition according to details 1d to 21d, wherein the mixing combination is dichlorvos.

[0160] 70d. The composition according to details 1d to 21d, wherein the mixing combination is chlorfluazuron.

[0161] 71d. The composition according to details 1d to 21d, wherein the mixing combination is chlormephos.

[0162] 72d. The composition according to details 1d to 21d, wherein the mixing combination is chlorpyrifos.

[0163] 73d. The composition according to details 1d to 21d, wherein the mixing combination is chlorpyrifos-methyl.

[0164] 74d. The composition according to details 1d to 21d, wherein the mixing combination is chromafenozide.

[0165] 75d. The composition according to details 1d to 21d, wherein the mixing combination is clofentezine.

[0166] 76d. The composition according to details 1d to 21d, wherein the mixing combination is clopyralid.

[0167] 77d. The composition according to details 1d to 21d, wherein the mixing combination is cloquintocet-mexyl.

[0168] 78d. The composition according to details 1d to 21d, wherein the mixing combination is clothianidin.

[0169] 79d. The composition according to details 1d to 21d, wherein the mixing combination is copper hydroxide.

[0170] 80d. The composition according to details 1d to 21d, wherein the mixing combination is coumaphos.

[0171] 81d. The composition according to details 1d to 21d, wherein the mixing combination is cyanophos.

[0172] 82d. The composition according to details 1d to 21d, wherein the mixing combination is cyantraniliprole.

[0173] 83d. The composition according to details 1d to 21d, wherein the mixing combination is cyclaniliprole.

[0174] 84d. The composition according to details 1d to 21d, wherein the admixture is cyphenothrin.

[0175] 85d. The composition according to details 1d to 21d, wherein the admixture is cycloprothrin.

[0176] 86d. The composition according to details 1d to 21d, wherein the admixture is epoxiconazole.

[0177] 87d. The composition according to details 1d to 21d, wherein the admixture is pyridaben.

[0178] 88d. The composition according to details 1d to 21d, wherein the admixture is cyflumetofen.

[0179] 89d. The composition according to details 1d to 21d, wherein the admixture is cyhalothrin.

[0180] 90d. The composition according to details 1d to 21d, wherein the admixture is lambda-cyhalothrin.

[0181] 91d. The composition according to details 1d to 21d, wherein the admixture is cyhexatin.

[0182] 92d. The composition according to details 1d to 21d, wherein the admixture is cymoxanil.

[0183] 93d. The composition according to details 1d to 21d, wherein the admixture is deltamethrin.

[0184] 94d. The composition according to details 1d to 21d, wherein the admixture is phenothrin.

[0185] 95d. The composition according to details 1d to 21d, wherein the admixture is cyproflanilide.

[0186] 96d. The composition according to details 1d to 21d, wherein the admixture is cyromazine.

[0187] 97d. The composition according to details 1d to 21d, wherein the admixture is d-cis-trans allethrin.

[0188] 98d. The composition according to details 1d to 21d, wherein the admixture is dichlorvos.

[0189] 99d. The composition according to details 1d to 21d, wherein the admixture is deltamethrin.

[0190] 100d. The composition according to details 1d to 21d, wherein the mixing combination is demeton-S-methyl.

[0191] 101d. The composition according to details 1d to 21d, wherein the mixing combination is diafenthiuron.

[0192] 102d. The composition according to details 1d to 21d, wherein the mixing combination is diazinon.

[0193] 103d. The composition according to details 1d to 21d, wherein the mixing combination is dichlorvos.

[0194] 104d. The composition according to details 1d to 21d, wherein the mixing combination is dicofol.

[0195] 105d. The composition according to details 1d to 21d, wherein the mixing combination is dimefox.

[0196] 106d. The composition according to details 1d to 21d, wherein the mixing combination is difenoconazole.

[0197] 107d. The composition according to details 1d to 21d, wherein the mixing combination is flufenzine.

[0198] 108d. The composition according to details 1d to 21d, wherein the mixing combination is diflubenzuron.

[0199] 109d. The composition according to details 1d to 21d, wherein the mixing combination is dimethoate.

[0200] 110d. The composition according to details 1d to 21d, wherein the mixing combination is dimethylvinphos.

[0201] 111d. The composition according to details 1d to 21d, wherein the mixing combination is flubendiamide.

[0202] 112d. The composition according to details 1d to 21d, wherein the mixing combination is dinotefuran.

[0203] 113d. The composition according to details 1d to 21d, wherein the mixing combination is disulfoton.

[0204] 114d. The composition according to details 1d to 21d, wherein the mixing combination is DNOC.

[0205] 115d. The composition according to details 1d to 21d, wherein the mixing combination is d-trans allethrin.

[0206] 116d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is emamectin benzoate.

[0207] 117d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is emamectin benzoate.

[0208] 118d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is empenthrin.

[0209] 119d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is endosulfan.

[0210] 120d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is EPN.

[0211] 121d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is esfenvalerate.

[0212] 122d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is ethaboxam.

[0213] 123d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is ethiofencarb.

[0214] 124d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is ethion.

[0215] 125d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is ethiprole.

[0216] 126d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fenamiphos.

[0217] 127d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is ethofenprox.

[0218] 128d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is oxfendazole.

[0219] 129d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is amiton.

[0220] 130d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fenamiphos.

[0221] 131d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fenazaquin.

[0222] 132d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fenbuconazole.

[0223] 133d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fenbutatin oxide.

[0224] 134d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fenitrothion.

[0225] 135d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is furmecyclox.

[0226] 136d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fenobucarb.

[0227] 137d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is phenoxycarb.

[0228] 138d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fenpropathrin.

[0229] 139d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flubenzimine.

[0230] 140d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fenthion.

[0231] 141d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fenvalerate.

[0232] 142d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fipronil.

[0233] 143d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flazasulfuron.

[0234] 144d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flonicamid.

[0235] 145d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is florasulam.

[0236] 146d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flufenerim.

[0237] 147d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flutianil.

[0238] 148d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flubendiamide.

[0239] 149d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flucycloxuron.

[0240] 150d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is cyhalothrin.

[0241] 151d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fludioxonil.

[0242] 152d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flupyradifurone.

[0243] 153d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flufenoxuron.

[0244] 154d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flumethrin.

[0245] 155d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flumioxazin.

[0246] 156d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fluxapyroxad.

[0247] 157d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fluxametamide.

[0248] 158d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fluoxastrobin.

[0249] 159d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flupyradifurone.

[0250] 160d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flufenerim.

[0251] 161d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fluroxypyr.

[0252] 162d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fluxametamide.

[0253] 163d. The composition according to details 1d to 21d, wherein the mixing combination is fluxapyroxad.

[0254] 164d. The composition according to details 1d to 21d, wherein the mixing combination is chlordimeform.

[0255] 165d. The composition according to details 1d to 21d, wherein the mixing combination is fosthiazate.

[0256] 166d. The composition according to details 1d to 21d, wherein the mixing combination is furathiocarb.

[0257] 167d. The composition according to details 1d to 21d, wherein the mixing combination is lambda-cyhalothrin.

[0258] 168d. The composition according to details 1d to 21d, wherein the mixing combination is glyphosate.

[0259] 169d. The composition according to details 1d to 21d, wherein the mixing combination is fluroxypyr.

[0260] 170d. The composition according to details 1d to 21d, wherein the mixing combination is pyridaben.

[0261] 171d. The composition according to details 1d to 21d, wherein the mixing combination is tebufenozide.

[0262] 172d. The composition according to details 1d to 21d, wherein the mixing combination is heptenophos.

[0263] 173d. The composition according to details 1d to 21d, wherein the mixing combination is hexaflumuron.

[0264] 174d. The composition according to details 1d to 21d, wherein the mixing combination is hexythiazox.

[0265] 175d. The composition according to details 1d to 21d, wherein the mixing combination is hydramethylnon.

[0266] 176d. The composition according to details 1d to 21d, wherein the mixing combination is hydroprene.

[0267] 177d. The composition according to details 1d to 21d, wherein the mixing combination is imazamox.

[0268] 178d. The composition according to details 1d to 21d, wherein the mixing combination is imazapyr.

[0269] 179d. The composition according to details 1d to 21d, wherein the mixing compatibility is imidocyclophosphamide.

[0270] 180d. The composition according to details 1d to 21d, wherein the mixing compatibility is imidacloprid.

[0271] 181d. The composition according to details 1d to 21d, wherein the mixing compatibility is imiprothrin.

[0272] 182d. The composition according to details 1d to 21d, wherein the mixing compatibility is indazapyroxamet.

[0273] 183d. The composition according to details 1d to 21d, wherein the mixing compatibility is indoxacarb.

[0274] 184d. The composition according to details 1d to 21d, wherein the mixing compatibility is ipconazole.

[0275] 185d. The composition according to details 1d to 21d, wherein the mixing compatibility is prothioconazole.

[0276] 186d. The composition according to details 1d to 21d, wherein the mixing compatibility is isoxazolinon.

[0277] 187d. The composition according to details 1d to 21d, wherein the mixing compatibility is isofenphos.

[0278] 188d. The composition according to details 1d to 21d, wherein the mixing compatibility is isotianil.

[0279] 189d. The composition according to details 1d to 21d, wherein the mixing compatibility is isoprocarb.

[0280] 190d. The composition according to details 1d to 21d, wherein the mixing compatibility is isoxathion.

[0281] 191d. The composition according to details 1d to 21d, wherein the mixing compatibility is tetramethrin.

[0282] 192d. The composition according to details 1d to 21d, wherein the mixing compatibility is kinoprene.

[0283] 193d. The composition according to details 1d to 21d, wherein the mixing compatibility is lambda-cyhalothrin.

[0284] 194d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is ravuconazole.

[0285] 195d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is lufenuron.

[0286] 196d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is malathion.

[0287] 197d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is mancozeb.

[0288] 198d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is MCPA.

[0289] 199d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is mecarbam.

[0290] 200d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is metalaxyl-M.

[0291] 201d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is metaflumizone.

[0292] 202d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is metalaxyl.

[0293] 203d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is metconazole.

[0294] 204d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is methamidophos.

[0295] 205d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is hexamine.

[0296] 206d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is methidathion.

[0297] 207d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is methiocarb.

[0298] 208d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is methomyl.

[0299] 209d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is methoprene.

[0300] 210d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is methoxychlor.

[0301] 211d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is tebufenozide.

[0302] 212d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is metolcarb.

[0303] 213d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is metsulfuron-methyl.

[0304] 214d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is mevinphos.

[0305] 215d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is milbemycin.

[0306] 216d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is monocrotophos.

[0307] 217d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is myclobutanil.

[0308] 218d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is naled.

[0309] 219d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is nicosulfuron.

[0310] 220d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is chlorpyrifos.

[0311] 221d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flucycloxuron.

[0312] 222d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is lufenuron.

[0313] 223d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is omethoate.

[0314] 224d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is oxamyl.

[0315] 225d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flutriafol.

[0316] 226d. The composition according to details 1d to 21d, wherein the mixing compatibility is oxazosulfone.

[0317] 227d. The composition according to details 1d to 21d, wherein the mixing compatibility is sulfotep.

[0318] 228d. The composition according to details 1d to 21d, wherein the mixing compatibility is parathion.

[0319] 229d. The composition according to details 1d to 21d, wherein the mixing compatibility is methyl parathion.

[0320] 230d. The composition according to details 1d to 21d, wherein the mixing compatibility is fenpyrazamine.

[0321] 231d. The composition according to details 1d to 21d, wherein the mixing compatibility is pythiathion.

[0322] 232d. The composition according to details 1d to 21d, wherein the mixing compatibility is permethrin.

[0323] 233d. The composition according to details 1d to 21d, wherein the mixing compatibility is phenothrin.

[0324] 234d. The composition according to details 1d to 21d, wherein the mixing compatibility is phenthoate.

[0325] 235d. The composition according to details 1d to 21d, wherein the mixing compatibility is phorate.

[0326] 236d. The composition according to details 1d to 21d, wherein the mixing compatibility is phosalone.

[0327] 237d. The composition according to details 1d to 21d, wherein the mixing compatibility is phosmet.

[0328] 238d. The composition according to details 1d to 21d, wherein the mixing compatibility is phosphamidon.

[0329] 239d. The composition according to details 1d to 21d, wherein the mixing compatibility is phoxim.

[0330] 240d. The composition according to details 1d to 21d, wherein the mixing compatibility is picafentrazone.

[0331] 241d. The composition according to details 1d to 21d, wherein the mixing compatibility is picloram.

[0332] 242d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is picoxystrobin.

[0333] 243d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pinoxaden.

[0334] 244d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pirimicarb.

[0335] 245d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pirimiphos-methyl.

[0336] 246d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is d-phenothrin.

[0337] 247d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is profenofos.

[0338] 248d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is clofentezine.

[0339] 249d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is propaphos.

[0340] 250d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is propiconazole.

[0341] 251d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is baygon.

[0342] 252d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is penthiopyrad.

[0343] 253d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is prothioconazole.

[0344] 254d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is profenofos.

[0345] 255d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fluxapyroxad.

[0346] 256d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flutolanil.

[0347] 257d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is prometryn.

[0348] 258d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pyraclofos.

[0349] 259d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pyraoxystrobin.

[0350] 260d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pyrethrum.

[0351] 261d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pyridaben.

[0352] 262d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pyridalyl.

[0353] 263d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pyridaphenthion.

[0354] 264d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pyrafluprole.

[0355] 265d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pyrimidifen.

[0356] 266d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is pyriproxyfen.

[0357] 267d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is thiazopyr.

[0358] 268d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is quinalphos.

[0359] 269d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is resmethrin.

[0360] 270d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is sulfometuron methyl.

[0361] 271d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is rotenone.

[0362] 272d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is fluxapyroxad.

[0363] 273d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is silafluofen.

[0364] 274d. The composition according to details 1d to 21d, wherein the mixing combination is spirodiclofen.

[0365] 275d. The composition according to details 1d to 21d, wherein the mixing combination is spinetoram.

[0366] 276d. The composition according to details 1d to 21d, wherein the mixing combination is spinosad.

[0367] 277d. The composition according to details 1d to 21d, wherein the mixing combination is spirodiclofen.

[0368] 278d. The composition according to details 1d to 21d, wherein the mixing combination is spirotetramat.

[0369] 279d. The composition according to details 1d to 21d, wherein the mixing combination is spiromesifen.

[0370] 280d. The composition according to details 1d to 21d, wherein the mixing combination is methoprene.

[0371] 281d. The composition according to details 1d to 21d, wherein the mixing combination is spirotetramat.

[0372] 282d. The composition according to details 1d to 21d, wherein the mixing combination is sulfluramid.

[0373] 283d. The composition according to details 1d to 21d, wherein the mixing combination is sulfotep.

[0374] 284d. The composition according to details 1d to 21d, wherein the mixing combination is sulfoxaflor.

[0375] 285d. The composition according to details 1d to 21d, wherein the mixing combination is tau-fluvalinate.

[0376] 286d. The composition according to details 1d to 21d, wherein the mixing combination is tebuconazole.

[0377] 287d. The composition according to details 1d to 21d, wherein the mixing combination is tebufenozide.

[0378] 288d. The composition according to details 1d to 21d, wherein the mixing combination is pyridaben.

[0379] 289d. The composition according to details 1d to 21d, wherein the mixing combination is butathiofos.

[0380] 290d. The composition according to details 1d to 21d, wherein the admixture is chlorfluazuron.

[0381] 291d. The composition according to details 1d to 21d, wherein the admixture is tefluthrin.

[0382] 292d. The composition according to details 1d to 21d, wherein the admixture is temephos.

[0383] 293d. The composition according to details 1d to 21d, wherein the admixture is terbufos.

[0384] 294d. The composition according to details 1d to 21d, wherein the admixture is tetrachlorvinphos.

[0385] 295d. The composition according to details 1d to 21d, wherein the admixture is tetradifon.

[0386] 296d. The composition according to details 1d to 21d, wherein the admixture is tetramethrin.

[0387] 297d. The composition according to details 1d to 21d, wherein the admixture is flubendiamide.

[0388] 298d. The composition according to details 1d to 21d, wherein the admixture is theta-cypermethrin.

[0389] 299d. The composition according to details 1d to 21d, wherein the admixture is thiabendazole.

[0390] 300d. The composition according to details 1d to 21d, wherein the admixture is thiamethoxam.

[0391] 301d. The composition according to details 1d to 21d, wherein the admixture is thiocyclam.

[0392] 302d. The composition according to details 1d to 21d, wherein the admixture is thiodicarb.

[0393] 303d. The composition according to details 1d to 21d, wherein the admixture is thiofanox.

[0394] 304d. The composition according to details 1d to 21d, wherein the admixture is malathion-methyl.

[0395] 305d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is bisultap.

[0396] 306d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is thiram.

[0397] 307d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is flubendiamide.

[0398] 308d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is thiazosulfone.

[0399] 309d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is tolfenpyrad.

[0400] 310d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is tralkoxydim.

[0401] 311d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is tetramethrin.

[0402] 312d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is transfluthrin.

[0403] 313d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is triazamate.

[0404] 314d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is triazophos.

[0405] 315d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is trichlorfon.

[0406] 316d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is picloram.

[0407] 317d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is trifloxystrobin.

[0408] 318d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is triflumezopyrim.

[0409] 319d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is triflumuron.

[0410] 320d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is dimephenthoate.

[0411] 321d. The composition according to details 1d to 21d, wherein the mixing combination is formetanate.

[0412] 322d. The composition according to details 1d to 21d, wherein the mixing combination is XMC.

[0413] 323d. The composition according to details 1d to 21d, wherein the mixing combination is carbaryl.

[0414] 324d. The composition according to details 1d to 21d, wherein the mixing combination is lambda-cyhalothrin.

[0415] 325d. The composition according to details 1d to 21d, wherein the mixing combination is 2,4-D.

[0416] 326d. The composition according to any one of the foregoing details 1d to 21d, wherein the mixing combination is acetamiprid.

[0417] 327d. The composition according to any one of the foregoing details 1d to 21d, wherein the mixing combination is N-(4-chloro-2-(pyridin-3-yl)thiazol-5-yl)-N-ethyl-3-(methylsulfonyl)propanamide (AI-1)

[0418]

[0419] 328d. The composition according to any one of the foregoing details 1d to 21d, wherein the mixing combination is N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-2-(methylsulfonyl)propanamide (AI-2)

[0420]

[0421] 329d. The composition according to any one of the foregoing details 1d to 328d, wherein the weight ratio of the molecule to the mixing combination is from about 50000:1 to about 1:50000.

[0422] 330d. The composition according to any one of the foregoing details 1d to 328d, wherein the weight ratio of the molecule to the mixing combination is from about 40000:1 to about 1:40000.

[0423] 331d. The composition according to any one of the foregoing details 1d to 328d, wherein the weight ratio of the molecule to the mixing combination is from about 10256:1 to about 1:10256.

[0424] 332d. A composition according to any one of the foregoing details 1d to 328d, wherein the weight ratio of the molecule to the mixed formulation is from about 10,000:1 to about 1:10,000.

[0425] 333d. A composition according to any one of the foregoing details 1d to 328d, wherein the weight ratio of the molecule to the mixed formulation is from about 2564:1 to about 1:2564.

[0426] 334d. A composition according to any one of the foregoing details 1d to 328d, wherein the weight ratio of the molecule to the mixed formulation is 1000:1 to about 1:1000.

[0427] 335d. A composition according to any one of the foregoing details 1d to 328d, wherein the weight ratio of the molecule to the mixed formulation is from about 640:1 to about 1:640.

[0428] 336d. A composition according to any one of the foregoing details 1d to 238d, wherein the weight ratio of the molecule to the mixed formulation is 500:1 to about 1:500.

[0429] 337d. A composition according to any one of the foregoing details 1d to 238d, wherein the weight ratio of the molecule to the mixed formulation is 100:1 to about 1:100.

[0430] 338d. A composition according to any one of the foregoing details 1d to 238d, wherein the weight ratio of the molecule to the mixed formulation is 50:1 to about 1:50.

[0431] 339d. A composition according to any one of the foregoing details 1d to 238d, wherein the weight ratio of the molecule to the mixed formulation is 20:1 to about 1:20.

[0432] 340d. A composition according to any one of the foregoing details 1d to 328d, wherein the weight ratio of the molecule to the mixed formulation is from about 16:1 to about 1:16.

[0433] 341d. A composition according to any one of the foregoing details 1d to 238d, wherein the weight ratio of the molecule to the mixed formulation is 10:1 to about 1:10.

[0434] 342d. A composition according to any one of the foregoing details 1d to 238d, wherein the weight ratio of the molecule to the mixed formulation is 5:1 to about 1:5.

[0435] 343d. A composition according to any one of the foregoing details 1d to 238d, wherein the weight ratio of the molecule to the mixed formulation is from 3:1 to about 1:3.

[0436] 344d. A composition according to any one of the foregoing details 1d to 238d, wherein the weight ratio of the molecule to the mixed formulation is from 2:1 to about 1:2.

[0437] 345d. A composition according to any one of the foregoing details 1d to 238d, wherein the weight ratio of the molecule to the mixed formulation is 1:1.

[0438] 346d. A method for controlling pests in a site by using a pesticidal composition according to any one of the foregoing details 1d to 345d in a pesticidal effective amount.

[0439] 347d. The method according to detail 346d, wherein the pests are from the phylum Arthropoda, Mollusca, and / or Nematoda.

[0440] 348d. The method according to detail 346d, wherein the pests are ants, aphids, bed bugs, beetles, borers, caterpillars, cockroaches, crickets, earwigs, fleas, flies, grasshoppers, maggots, wasps, leafhoppers, springtails, lice, locusts, grubs, mealybugs, mites, moths, nematodes, mirids, planthoppers, psyllids, sawflies, scale insects, woodworms, slugs, snails, spiders, springtails, stink bugs, symphylans, termites, thrips, ticks, wasps, whiteflies, and / or horsehair worms.

[0441] 349d. The method according to detail 346d, wherein the pests are aphids, springtails, moths, scale insects, thrips, psyllids, mealybugs, stink bugs, and / or whiteflies.

[0442] 350d. The method according to detail 346d, wherein the pests are caterpillars, beetles, grasshoppers, and / or locusts.

[0443] 351d. The composition according to detail 3d, wherein the mixed formulation is one selected from AIGA.

[0444] 352d. The composition according to detail 3d, wherein the mixed formulation is one selected from AIGA-1.

[0445] 353d. The composition according to detail 3d, wherein the mixed formulation is abamectin.

[0446] 354d. The composition according to detail 3d, wherein the mixed formulation is mevinphos.

[0447] 355d. The composition according to detail 3d, wherein the mixing combination is acequinocyl.

[0448] 356d. The composition according to detail 3d, wherein the mixing combination is acetamiprid.

[0449] 357d. The composition according to detail 3d, wherein the mixing combination is allethrin.

[0450] 358d. The composition according to detail 3d, wherein the mixing combination is acynonapyr.

[0451] 359d. The composition according to detail 3d, wherein the mixing combination is acetoprole.

[0452] 360d. The composition according to detail 3d, wherein the mixing combination is alanycarb.

[0453] 361d. The composition according to detail 3d, wherein the mixing combination is aldicarb.

[0454] 362d. The composition according to detail 3d, wherein the mixing combination is allethrin.

[0455] 363d. The composition according to detail 3d, wherein the mixing combination is alpha-cypermethrin.

[0456] 364d. The composition according to detail 3d, wherein the mixing combination is aminopyralid.

[0457] 365d. The composition according to detail 3d, wherein the mixing combination is amitraz.

[0458] 366d. The composition according to detail 3d, wherein the mixing combination is azadirachtin.

[0459] 367d. The composition according to detail 3d, wherein the mixing combination is azamethiphos.

[0460] 368d. The composition according to detail 3d, wherein the mixing combination is azinphos-ethyl.

[0461] 369d. The composition according to detail 3d, wherein the mixing combination is azinphos-methyl.

[0462] 370d. The composition according to detail 3d, wherein the mixing combination is azocyclotin.

[0463] 371d. The composition according to detail 3d, wherein the mixing combination is azoxystrobin.

[0464] 372d. The composition according to detail 3d, wherein the admixture is bendiocarb.

[0465] 373d. The composition according to detail 3d, wherein the admixture is benfuracarb.

[0466] 374d. The composition according to detail 3d, wherein the admixture is bensultap.

[0467] 375d. The composition according to detail 3d, wherein the admixture is bixafen.

[0468] 376d. The composition according to detail 3d, wherein the admixture is beta-cyfluthrin.

[0469] 377d. The composition according to detail 3d, wherein the admixture is beta-cypermethrin.

[0470] 378d. The composition according to detail 3d, wherein the admixture is bifenazate.

[0471] 379d. The composition according to detail 3d, wherein the admixture is bifenthrin.

[0472] 380d. The composition according to detail 3d, wherein the admixture is allethrin.

[0473] 381d. The composition according to detail 3d, wherein the admixture is bioallethrin.

[0474] 382d. The composition according to detail 3d, wherein the admixture is bistrifluron.

[0475] 383d. The composition according to detail 3d, wherein the admixture is broflanilide.

[0476] 384d. The composition according to detail 3d, wherein the admixture is bromopropylate.

[0477] 385d. The composition according to detail 3d, wherein the admixture is buprofezin.

[0478] 386d. The composition according to detail 3d, wherein the admixture is butacarb.

[0479] 387d. The composition according to detail 3d, wherein the admixture is butoxycarboxim.

[0480] 388d. The composition according to detail 3d, wherein the admixture is cadusafos.

[0481] 389d. The composition according to detail 3d, wherein the mixing compatibility agent is carbaryl.

[0482] 390d. The composition according to detail 3d, wherein the mixing compatibility agent is carbofuran.

[0483] 391d. The composition according to details 1d to 21d, wherein the mixing compatibility agent is carbosulfan.

[0484] 392d. The composition according to detail 3d, wherein the mixing compatibility agent is carboxin.

[0485] 393d. The composition according to detail 3d, wherein the mixing compatibility agent is cartap hydrochloride.

[0486] 394d. The composition according to detail 3d, wherein the mixing compatibility agent is chinomethionat.

[0487] 395d. The composition according to detail 3d, wherein the mixing compatibility agent is chlorantraniliprole.

[0488] 396d. The composition according to detail 3d, wherein the mixing compatibility agent is chlordane.

[0489] 398. The composition according to detail 3d, wherein the mixing compatibility agent is chlorfenapyr.

[0490] 399d. The composition according to detail 3d, wherein the mixing compatibility agent is chlorfenvinphos.

[0491] 400d. The composition according to detail 3d, wherein the mixing compatibility agent is chlorfluazuron.

[0492] 401d. The composition according to detail 3d, wherein the mixing compatibility agent is chloromethon.

[0493] 402d. The composition according to detail 3d, wherein the mixing compatibility agent is chlorpyrifos.

[0494] 403d. The composition according to detail 3d, wherein the mixing compatibility agent is chlorpyrifos-methyl.

[0495] 404d. The composition according to detail 3d, wherein the mixing compatibility agent is chromafenozide.

[0496] 405d. The composition according to detail 3d, wherein the mixing compatibility agent is clopyralid.

[0497] 406d. The composition according to detail 3d, wherein the mixing compatibility agent is cloquintocet-mexyl.

[0498] 407d. The composition according to detail 3d, wherein the mixing combination is clothianidin.

[0499] 408d. The composition according to detail 3d, wherein the mixing combination is copper hydroxide.

[0500] 409d. The composition according to detail 3d, wherein the mixing combination is coumaphos.

[0501] 410d. The composition according to detail 3d, wherein the mixing combination is cyanophos.

[0502] 411d. The composition according to detail 3d, wherein the mixing combination is cyantraniliprole.

[0503] 412d. The composition according to detail 3d, wherein the mixing combination is cyclaniliprole.

[0504] 413d. The composition according to detail 3d, wherein the mixing combination is cyflumetofen.

[0505] 414d. The composition according to detail 3d, wherein the mixing combination is cycloprothrin.

[0506] 415d. The composition according to detail 3d, wherein the mixing combination is epoxiconazole.

[0507] 416d. The composition according to detail 3d, wherein the mixing combination is pyridaben.

[0508] 417d. The composition according to detail 3d, wherein the mixing combination is cyflumetofen.

[0509] 418d. The composition according to detail 3d, wherein the mixing combination is cyhalothrin.

[0510] 419d. The composition according to detail 3d, wherein the mixing combination is lambda-cyhalothrin.

[0511] 420d. The composition according to detail 3d, wherein the mixing combination is cyhexatin.

[0512] 421d. The composition according to detail 3d, wherein the mixing combination is cymoxanil.

[0513] 422d. The composition according to detail 3d, wherein the mixing combination is cypermethrin.

[0514] 423d. The composition according to detail 3d, wherein the mixing combination is cyphenothrin.

[0515] 424d. The composition according to detail 3d, wherein the admixture is cyflumetofen.

[0516] 425d. The composition according to detail 3d, wherein the admixture is cyromazine.

[0517] 426d. The composition according to detail 3d, wherein the admixture is d-cis-trans allethrin.

[0518] 427d. The composition according to detail 3d, wherein the admixture is DDVP.

[0519] 428d. The composition according to detail 3d, wherein the admixture is deltamethrin.

[0520] 429d. The composition according to detail 3d, wherein the admixture is demeton-S-methyl.

[0521] 430d. The composition according to detail 3d, wherein the admixture is diafenthiuron.

[0522] 431d. The composition according to detail 3d, wherein the admixture is diazinon.

[0523] 432d. The composition according to detail 3d, wherein the admixture is dichlorvos.

[0524] 433d. The composition according to detail 3d, wherein the admixture is dicofol.

[0525] 434d. The composition according to detail 3d, wherein the admixture is dimefox.

[0526] 435d. The composition according to detail 3d, wherein the admixture is difenoconazole.

[0527] 436d. The composition according to detail 3d, wherein the admixture is fluacrypyrim.

[0528] 437d. The composition according to detail 3d, wherein the admixture is diflubenzuron.

[0529] 438d. The composition according to detail 3d, wherein the admixture is dimethoate.

[0530] 439d. The composition according to detail 3d, wherein the admixture is methacrifos.

[0531] 440d. The composition according to detail 3d, wherein the mixing compatibility agent is clothianidin.

[0532] 441d. The composition according to detail 3d, wherein the mixing compatibility agent is dinotefuran.

[0533] 442d. The composition according to detail 3d, wherein the mixing compatibility agent is disulfoton.

[0534] 443d. The composition according to detail 3d, wherein the mixing compatibility agent is DNOC.

[0535] 444d. The composition according to detail 3d, wherein the mixing compatibility agent is d-trans allethrin.

[0536] 445d. The composition according to detail 3d, wherein the mixing compatibility agent is emamectin.

[0537] 446d. The composition according to detail 3d, wherein the mixing compatibility agent is emamectin benzoate.

[0538] 447d. The composition according to detail 3d, wherein the mixing compatibility agent is empenthrin.

[0539] 448d. The composition according to detail 3d, wherein the mixing compatibility agent is endosulfan.

[0540] 449d. The composition according to detail 3d, wherein the mixing compatibility agent is EPN.

[0541] 450d. The composition according to detail 3d, wherein the mixing compatibility agent is esfenvalerate.

[0542] 451d. The composition according to detail 3d, wherein the mixing compatibility agent is ethaboxam.

[0543] 452d. The composition according to detail 3d, wherein the mixing compatibility agent is ethiofencarb.

[0544] 453d. The composition according to detail 3d, wherein the mixing compatibility agent is ethion.

[0545] 454d. The composition according to detail 3d, wherein the mixing compatibility agent is ethiprole.

[0546] 455d. The composition according to detail 3d, wherein the mixing compatibility agent is ethoprophos.

[0547] 456d. The composition according to detail 3d, wherein the mixing compatibility agent is etofenprox.

[0548] 457d. The composition according to detail 3d, wherein the mixing combination is famoxadone.

[0549] 458d. The composition according to detail 3d, wherein the mixing combination is amiton.

[0550] 459d. The composition according to detail 3d, wherein the mixing combination is fenamiphos.

[0551] 460d. The composition according to detail 3d, wherein the mixing combination is fenazaquin.

[0552] 461d. The composition according to detail 3d, wherein the mixing combination is fenbuconazole.

[0553] 462d. The composition according to detail 3d, wherein the mixing combination is fenbutatin oxide.

[0554] 463d. The composition according to detail 3d, wherein the mixing combination is fenitrothion.

[0555] 464d. The composition according to detail 3d, wherein the mixing combination is fenthion.

[0556] 465d. The composition according to detail 3d, wherein the mixing combination is fenobucarb.

[0557] 466d. The composition according to detail 3d, wherein the mixing combination is fenoxycarb.

[0558] 467d. The composition according to detail 3d, wherein the mixing combination is fenpropathrin.

[0559] 468d. The composition according to detail 3d, wherein the mixing combination is fenpyroximate.

[0560] 469d. The composition according to detail 3d, wherein the mixing combination is fenthion.

[0561] 470d. The composition according to detail 3d, wherein the mixing combination is fenvalerate.

[0562] 471d. The composition according to detail 3d, wherein the mixing combination is fipronil.

[0563] 472d. The composition according to detail 3d, wherein the mixing combination is flazasulfuron.

[0564] 473d. The composition according to detail 3d, wherein the mixing combination is flonicamid.

[0565] 474d. The composition according to detail 3d, wherein the mixing combination is florasulam.

[0566] 475d. The composition according to detail 3d, wherein the mixing combination is pyridaben.

[0567] 476d. The composition according to detail 3d, wherein the mixing combination is fluazinam.

[0568] 477d. The composition according to detail 3d, wherein the mixing combination is flubendiamide.

[0569] 478d. The composition according to detail 3d, wherein the mixing combination is flucycloxuron.

[0570] 479d. The composition according to detail 3d, wherein the mixing combination is cyhalothrin.

[0571] 480d. The composition according to detail 3d, wherein the mixing combination is fludioxonil.

[0572] 481d. The composition according to detail 3d, wherein the mixing combination is flupyradifurone.

[0573] 482d. The composition according to detail 3d, wherein the mixing combination is flufenoxuron.

[0574] 483d. The composition according to detail 3d, wherein the mixing combination is flumethrin.

[0575] 484d. The composition according to detail 3d, wherein the mixing combination is flumioxazin.

[0576] 485d. The composition according to detail 3d, wherein the mixing combination is fluopyram.

[0577] 486d. The composition according to detail 3d, wherein the mixing combination is fluxapyroxad.

[0578] 487d. The composition according to detail 3d, wherein the mixing combination is fluoxastrobin.

[0579] 488d. The composition according to detail 3d, wherein the mixing combination is flupyrimin.

[0580] 489d. The composition according to detail 3d, wherein the mixing combination is flufenerim.

[0581] 490d. The composition according to detail 3d, wherein the mixing combination is fluroxypyr.

[0582] 491d. The composition according to detail 3d, wherein the mixing combination is fluxametamide.

[0583] 492d. The composition according to detail 3d, wherein the mixing combination is fluxazolamide.

[0584] 493d. The composition according to detail 3d, wherein the mixing combination is chlordimeform.

[0585] 494d. The composition according to detail 3d, wherein the mixing combination is fosthiazate.

[0586] 495d. The composition according to detail 3d, wherein the mixing combination is furathiocarb.

[0587] 496d. The composition according to detail 3d, wherein the mixing combination is lambda-cyhalothrin.

[0588] 497d. The composition according to detail 3d, wherein the mixing combination is glyphosate.

[0589] 498d. The composition according to detail 3d, wherein the mixing combination is halauxifen-methyl.

[0590] 499d. The composition according to detail 3d, wherein the mixing combination is hexythiazox.

[0591] 500d. The composition according to detail 3d, wherein the mixing combination is tebufenozide.

[0592] 501d. The composition according to detail 3d, wherein the mixing combination is heptenophos.

[0593] 502d. The composition according to detail 3d, wherein the mixing combination is hexaflumuron.

[0594] 503d. The composition according to detail 3d, wherein the mixing combination is hexythiazox.

[0595] 504d. The composition according to detail 3d, wherein the mixing combination is hydramethylnon.

[0596] 505d. The composition according to detail 3d, wherein the mixing combination is hydroprene.

[0597] 506d. The composition according to detail 3d, wherein the mixing combination is imazamox.

[0598] 507d. The composition according to detail 3d, wherein the mixing combination is imazapyr.

[0599] 508d. The composition according to detail 3d, wherein the mixing compatibility agent is imidocyclophosphamide.

[0600] 509d. The composition according to detail 3d, wherein the mixing compatibility agent is imidacloprid.

[0601] 510d. The composition according to detail 3d, wherein the mixing compatibility agent is imiprothrin.

[0602] 511d. The composition according to detail 3d, wherein the mixing compatibility agent is indazapyroxamet.

[0603] 512d. The composition according to detail 3d, wherein the mixing compatibility agent is indoxacarb.

[0604] 513d. The composition according to detail 3d, wherein the mixing compatibility agent is ipconazole.

[0605] 514d. The composition according to detail 3d, wherein the mixing compatibility agent is prothioconazole.

[0606] 515d. The composition according to detail 3d, wherein the mixing compatibility agent is isoxazamid.

[0607] 516d. The composition according to detail 3d, wherein the mixing compatibility agent is isofenphos.

[0608] 517d. The composition according to detail 3d, wherein the mixing compatibility agent is isoflucypram.

[0609] 518d. The composition according to detail 3d, wherein the mixing compatibility agent is isoprocarb.

[0610] 519d. The composition according to detail 3d, wherein the mixing compatibility agent is isoxathion.

[0611] 520d. The composition according to detail 3d, wherein the mixing compatibility agent is tetramethrin.

[0612] 521d. The composition according to detail 3d, wherein the mixing compatibility agent is kinoprene.

[0613] 522d. The composition according to detail 3d, wherein the mixing compatibility agent is lambda-cyhalothrin.

[0614] 523d. The composition according to detail 3d, wherein the mixing compatibility agent is lepimectin.

[0615] 524d. The composition according to detail 3d, wherein the mixing combination is lufenuron.

[0616] 525d. The composition according to detail 3d, wherein the mixing combination is malathion.

[0617] 526d. The composition according to detail 3d, wherein the mixing combination is mancozeb.

[0618] 527d. The composition according to detail 3d, wherein the mixing combination is MCPA.

[0619] 528d. The composition according to detail 3d, wherein the mixing combination is mecarbam.

[0620] 529d. The composition according to detail 3d, wherein the mixing combination is metalaxyl - M.

[0621] 530d. The composition according to detail 3d, wherein the mixing combination is metaflumizone.

[0622] 531d. The composition according to detail 3d, wherein the mixing combination is metalaxyl.

[0623] 532d. The composition according to detail 3d, wherein the mixing combination is metconazole.

[0624] 533d. The composition according to detail 3d, wherein the mixing combination is methamidophos.

[0625] 534d. The composition according to detail 3d, wherein the mixing combination is hexamine.

[0626] 535d. The composition according to detail 3d, wherein the mixing combination is methidathion.

[0627] 536d. The composition according to detail 3d, wherein the mixing combination is methiocarb.

[0628] 537d. The composition according to detail 3d, wherein the mixing combination is methomyl.

[0629] 538d. The composition according to detail 3d, wherein the mixing combination is methoprene.

[0630] 539d. The composition according to detail 3d, wherein the mixing combination is methoxychlor.

[0631] 540d. The composition according to detail 3d, wherein the mixing combination is methoxyfenozide.

[0632] 541d. The composition according to detail 3d, wherein the mixing compatibility agent is XMC.

[0633] 542d. The composition according to detail 3d, wherein the mixing compatibility agent is metsulfuron-methyl.

[0634] 543d. The composition according to detail 3d, wherein the mixing compatibility agent is mevinphos.

[0635] 544d. The composition according to detail 3d, wherein the mixing compatibility agent is milbemycin.

[0636] 545d. The composition according to detail 3d, wherein the mixing compatibility agent is monocrotophos.

[0637] 546d. The composition according to detail 3d, wherein the mixing compatibility agent is myclobutanil.

[0638] 547d. The composition according to detail 3d, wherein the mixing compatibility agent is naled.

[0639] 548d. The composition according to detail 3d, wherein the mixing compatibility agent is nicosulfuron.

[0640] 549d. The composition according to detail 3d, wherein the mixing compatibility agent is nitrapyrin.

[0641] 550d. The composition according to detail 3d, wherein the mixing compatibility agent is noviflumuron.

[0642] 551d. The composition according to detail 3d, wherein the mixing compatibility agent is novaluron.

[0643] 552d. The composition according to detail 3d, wherein the mixing compatibility agent is omethoate.

[0644] 553d. The composition according to detail 3d, wherein the mixing compatibility agent is oxamyl.

[0645] 554d. The composition according to detail 3d, wherein the mixing compatibility agent is fluopyram.

[0646] 555d. The composition according to detail 3d, wherein the mixing compatibility agent is oxasulfuron.

[0647] 556d. The composition according to detail 3d, wherein the mixing compatibility agent is sulfotep.

[0648] 557d. The composition according to detail 3d, wherein the mixing compatibility agent is parathion.

[0649] 558d. The composition according to detail 3d, wherein the mixing combination is parathion-methyl.

[0650] 559d. The composition according to detail 3d, wherein the mixing combination is fenpyrazamine.

[0651] 560d. The composition according to detail 3d, wherein the mixing combination is pythiathion.

[0652] 561d. The composition according to detail 3d, wherein the mixing combination is permethrin.

[0653] 562d. The composition according to detail 3d, wherein the mixing combination is phenothrin.

[0654] 563d. The composition according to detail 3d, wherein the mixing combination is phenthoate.

[0655] 564d. The composition according to detail 3d, wherein the mixing combination is phorate.

[0656] 565d. The composition according to detail 3d, wherein the mixing combination is phosalone.

[0657] 566d. The composition according to detail 3d, wherein the mixing combination is phosmet.

[0658] 567d. The composition according to detail 3d, wherein the mixing combination is phosphamidon.

[0659] 568d. The composition according to detail 3d, wherein the mixing combination is phoxim.

[0660] 569d. The composition according to detail 3d, wherein the mixing combination is pipercarbazole.

[0661] 570d. The composition according to detail 3d, wherein the mixing combination is picloram.

[0662] 571d. The composition according to detail 3d, wherein the mixing combination is picoxystrobin.

[0663] 572d. The composition according to detail 3d, wherein the mixing combination is pinoxaden.

[0664] 573d. The composition according to detail 3d, wherein the mixing combination is pirimicarb.

[0665] 574d. The composition according to detail 3d, wherein the mixing combination is pirimiphos-methyl.

[0666] 575d. The composition according to detail 3d, wherein the admixture is d - allethrin.

[0667] 576d. The composition according to detail 3d, wherein the admixture is profenofos.

[0668] 577d. The composition according to detail 3d, wherein the admixture is propargite.

[0669] 578d. The composition according to detail 3d, wherein the admixture is propaphos.

[0670] 579d. The composition according to detail 3d, wherein the admixture is propiconazole.

[0671] 580d. The composition according to detail 3d, wherein the admixture is propoxur.

[0672] 581d. The composition according to detail 3d, wherein the admixture is propyzamide.

[0673] 582d. The composition according to detail 3d, wherein the admixture is prothioconazole.

[0674] 584d. The composition according to detail 3d, wherein the admixture is fluxapyroxad.

[0675] 585d. The composition according to detail 3d, wherein the admixture is piflufenzide.

[0676] 586d. The composition according to detail 3d, wherein the admixture is prometryn.

[0677] 587d. The composition according to detail 3d, wherein the admixture is pyraclofos.

[0678] 588d. The composition according to detail 3d, wherein the admixture is pyraclostrobin.

[0679] 589d. The composition according to detail 3d, wherein the admixture is pyrethrum.

[0680] 590d. The composition according to detail 3d, wherein the admixture is pyridaben.

[0681] 591d. The composition according to detail 3d, wherein the admixture is pyridalyl.

[0682] 592d. The composition according to detail 3d, wherein the admixture is pyridaphenthion.

[0683] 593d. The composition according to detail 3d, wherein the mixing combination is pyrafluprole.

[0684] 594d. The composition according to detail 3d, wherein the mixing combination is pyrimidifen.

[0685] 595d. The composition according to detail 3d, wherein the mixing combination is pyriproxyfen.

[0686] 596d. The composition according to detail 3d, wherein the mixing combination is flucarbazone-sodium.

[0687] 597d. The composition according to detail 3d, wherein the mixing combination is quinalphos.

[0688] 598d. The composition according to detail 3d, wherein the mixing combination is pyrethrum.

[0689] 599d. The composition according to detail 3d, wherein the mixing combination is sulfosulfuron.

[0690] 600d. The composition according to detail 3d, wherein the mixing combination is rotenone.

[0691] 601d. The composition according to detail 3d, wherein the mixing combination is fluxapyroxad.

[0692] 602d. The composition according to detail 3d, wherein the mixing combination is silafluofen.

[0693] 603d. The composition according to detail 3d, wherein the mixing combination is spirodiclofen.

[0694] 604d. The composition according to detail 3d, wherein the mixing combination is spinetoram.

[0695] 605d. The composition according to detail 3d, wherein the mixing combination is spinosad.

[0696] 606d. The composition according to detail 3d, wherein the mixing combination is spirodiclofen.

[0697] 607d. The composition according to detail 3d, wherein the mixing combination is spirotetramat.

[0698] 608d. The composition according to detail 3d, wherein the mixing combination is spiromesifen.

[0699] 609d. The composition according to detail 3d, wherein the mixing combination is mepiquat chloride.

[0700] 610d. The composition according to detail 3d, wherein the co-formulant is spirotetramat.

[0701] 611d. The composition according to detail 3d, wherein the co-formulant is sulfluramid.

[0702] 612d. The composition according to detail 3d, wherein the co-formulant is sulfotep.

[0703] 613d. The composition according to detail 3d, wherein the co-formulant is sulfoxaflor.

[0704] 614d. The composition according to detail 3d, wherein the co-formulant is tau-fluvalinate.

[0705] 615d. The composition according to detail 3d, wherein the co-formulant is tebuconazole.

[0706] 618d. The composition according to detail 3d, wherein the co-formulant is butathiofos.

[0707] 619d. The composition according to detail 3d, wherein the co-formulant is chlorfluazuron.

[0708] 620d. The composition according to detail 3d, wherein the co-formulant is heptafluthrin.

[0709] 621d. The composition according to detail 3d, wherein the co-formulant is temephos.

[0710] 622d. The composition according to detail 3d, wherein the co-formulant is terbufos.

[0711] 623d. The composition according to detail 3d, wherein the co-formulant is tetrachlorvinphos.

[0712] 624d. The composition according to detail 3d, wherein the co-formulant is tetradifon.

[0713] 625d. The composition according to detail 3d, wherein the co-formulant is tetramethrin.

[0714] 626d. The composition according to detail 3d, wherein the co-formulant is flubendiamide.

[0715] 627d. The composition according to detail 3d, wherein the co-formulant is theta-cypermethrin.

[0716] 628d. The composition according to detail 3d, wherein the co-formulant is thiabendazole.

[0717] 629d. The composition according to detail 3d, wherein the mixing combination is thiamethoxam.

[0718] 630d. The composition according to detail 3d, wherein the mixing combination is thiocyclam.

[0719] 631d. The composition according to detail 3d, wherein the mixing combination is thiodicarb.

[0720] 632d. The composition according to detail 3d, wherein the mixing combination is monocrotophos.

[0721] 633d. The composition according to detail 3d, wherein the mixing combination is disulfoton-methyl.

[0722] 634d. The composition according to detail 3d, wherein the mixing combination is bisultap.

[0723] 635d. The composition according to detail 3d, wherein the mixing combination is thiram.

[0724] 636d. The composition according to detail 3d, wherein the mixing combination is flubendiamide.

[0725] 637d. The composition according to detail 3d, wherein the mixing combination is thiazosulfone.

[0726] 638d. The composition according to detail 3d, wherein the mixing combination is tolfenpyrad.

[0727] 639d. The composition according to detail 3d, wherein the mixing combination is tralkoxydim.

[0728] 640d. The composition according to detail 3d, wherein the mixing combination is tetramethrin.

[0729] 641d. The composition according to detail 3d, wherein the mixing combination is transfluthrin.

[0730] 642d. The composition according to detail 3d, wherein the mixing combination is triazamate.

[0731] 643d. The composition according to detail 3d, wherein the mixing combination is triazophos.

[0732] 644d. The composition according to detail 3d, wherein the mixing combination is trichlorfon.

[0733] 645d. The composition according to detail 3d, wherein the mixing combination is picloram.

[0734] 646d. The composition according to detail 3d, wherein the mixing combination is trifloxystrobin.

[0735] 647d. The composition according to detail 3d, wherein the mixing combination is triflumezopyrim.

[0736] 648d. The composition according to detail 3d, wherein the mixing combination is tralomethrin.

[0737] 649d. The composition according to detail 3d, wherein the mixing combination is BPMC.

[0738] 650d. The composition according to detail 3d, wherein the mixing combination is triticonazole.

[0739] 651d. The composition according to detail 3d, wherein the mixing combination is formetanate.

[0740] 652d. The composition according to detail 3d, wherein the mixing combination is XMC.

[0741] 653d. The composition according to detail 3d, wherein the mixing combination is methiocarb.

[0742] 654d. The composition according to detail 3d, wherein the mixing combination is zeta-cypermethrin.

[0743] 655d. The composition according to detail 3d, wherein the mixing combination is 2,4-D.

[0744] 656d. The composition according to detail 3d, wherein the mixing combination is nitenpyram.

[0745] 657d. The composition according to detail 3d, wherein the mixing combination is N-(4-chloro-2-(pyridin-3-yl)thiazol-5-yl)-N-ethyl-3-(methylsulfonyl)propanamide (AI-1)

[0746]

[0747] 658d. The composition according to detail 3d, wherein the mixing combination is N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-2-(methylsulfonyl)propanamide (AI-2)

[0748]

[0749] 659d. The composition according to detail 3d, wherein the mixing combination is heat-inactivated Burkholderia spp.

[0750] 660d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from about 40000:1 to about 1:40000.

[0751] 661d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from about 10256:1 to about 1:10256.

[0752] 662d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from about 10000:1 to about 1:10000.

[0753] 663d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from about 2564:1 to about 1:2564.

[0754] 664d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is 1000:1 to about 1:1000.

[0755] 665d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from about 640:1 to about 1:640.

[0756] 666d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is 500:1 to about 1:500.

[0757] 667d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is 100:1 to about 1:100.

[0758] 668d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is 50:1 to about 1:50.

[0759] 669d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is 20:1 to about 1:20.

[0760] 670d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from about 16:1 to about 1:16.

[0761] 671d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 10:1 to about 1:10.

[0762] 672d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 5:1 to about 1:5.

[0763] 673d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 3:1 to about 1:3.

[0764] 674d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 2:1 to about 1:2.

[0765] 675d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is 1:1.

[0766] 676d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 1:20,000 to 20,000:1.

[0767] 677d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 1:2,000 to 2,000:1.

[0768] 678d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 1:160,000 to 160,000:1.

[0769] 679d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 1:80,000 to 80,000:1.

[0770] 680d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 1:16,000 to 16,000:1.

[0771] 681d. The composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 1:8,000 to 8,000:1.

[0772] 682d. A composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 1:250 to 250:1.

[0773] 683d. A composition according to any one of the foregoing details 351d to 659d, wherein the weight ratio of F1 to the mixed formulation is from 1:25 to 25:1.

[0774] 684d. A method for controlling pests in a location by using a pesticidally effective amount of a pesticidal composition according to any one of the foregoing details 351d to 683d.

[0775] 685d. The method according to detail 684d, wherein the pests are from the phylum Arthropoda, Mollusca, and / or Nematoda.

[0776] 686d. The method according to detail 684d, wherein the pests are ants, aphids, bed bugs, beetles, borers, caterpillars, cockroaches, crickets, earwigs, fleas, flies, grasshoppers, maggots, wasps, leafhoppers, springtails, lice, locusts, grubs, mealybugs, mites, moths, nematodes, mirids, planthoppers, psyllids, sawflies, scale insects, woodworms, slugs, snails, spiders, springtails, stink bugs, symphylans, termites, thrips, ticks, wasps, whiteflies, and horsehair worms.

[0777] 687d. The method according to detail 684d, wherein the pests are aphids, springtails, moths, scale insects, thrips, psyllids, mealybugs, stink bugs, and / or whiteflies.

[0778] 688d. The method according to detail 684d, wherein the pests are caterpillars, beetles, grasshoppers, and / or locusts.

[0779] In some aspects of the pesticidal compositions disclosed herein, the molecule having the structure of Formula I is F1. In some aspects, the pesticidal compositions disclosed herein comprise F1 and at least one active ingredient selected from AIGA-1. In some other aspects, the pesticidal compositions disclosed herein comprise F1 and at least two active ingredients selected from AIGA-1. In some other aspects, the pesticidal compositions disclosed herein comprise F1 and at least three active ingredients selected from AIGA-1. In certain other aspects, the pesticidal compositions disclosed herein comprise F1 and at least four active ingredients selected from AIGA-1. In some aspects, the pesticidal compositions disclosed herein comprise F1 and AI-2. In some other aspects, the pesticidal compositions disclosed herein comprise F1 and AI-1.

[0780] In some aspects, the pesticidal composition disclosed herein comprises F1 and another active ingredient selected from the group consisting of cyflumetofen, isoxazamip, spirodiclofen, ethiprole, tolfenpyrad, and fenpyrazamine. The ratio of F1 to any one of these ingredients is a ratio of 1:100 to 100:1.

[0781] In some aspects, the pesticidal composition disclosed herein comprises F1 and cyflumetofen. The ratio of F1 to cyflumetofen is 1:200 to 200:1. When F1 and cyflumetofen are mixed at a certain ratio within this range, enhanced efficacy can be expected. "Enhanced efficacy" in this context means an efficacy greater than the expected efficacy calculated by the Colby equation.

[0782] In some aspects, the pesticidal composition disclosed herein comprises F1 and isoxazamip. The ratio of F1 to isoxazamip is 1:200 to 200:1. When F1 and isoxazamip are mixed at a certain ratio within this range, enhanced efficacy can be expected. "Enhanced efficacy" in this context means an efficacy greater than the expected efficacy calculated by the Colby equation.

[0783] In some aspects, the pesticidal composition disclosed herein comprises F1 and spirodiclofen. The ratio of F1 to spirodiclofen is 1:200 to 200:1. When F1 and spirodiclofen are mixed at a certain ratio within this range, enhanced efficacy can be expected. "Enhanced efficacy" in this context means an efficacy greater than the expected efficacy calculated by the Colby equation.

[0784] In some aspects, the pesticidal composition disclosed herein comprises F1 and ethiprole. The ratio of F1 to ethiprole is 1:200 to 200:1. When F1 and ethiprole are mixed at a certain ratio within this range, enhanced efficacy can be expected. "Enhanced efficacy" in this context means an efficacy greater than the expected efficacy calculated by the Colby equation.

[0785] In some aspects, the pesticidal composition disclosed herein comprises F1 and tolfenpyrad. The ratio of F1 to tolfenpyrad is 1:200 to 200:1. When F1 and tolfenpyrad are mixed at a certain ratio within this range, enhanced efficacy can be expected. "Enhanced efficacy" in this context means an efficacy greater than the expected efficacy calculated by the Colby equation.

[0786] In some aspects, the pesticidal composition disclosed herein comprises F1 and fenamidiaz. The ratio of F1 to fenamidiaz is from 1:200 to 200:1. When F1 and fenamidiaz are mixed in a certain proportion within this range, enhanced efficacy can be expected. "Enhanced efficacy" in this context means an efficacy greater than the expected efficacy calculated by the Colby equation.

[0787] In some aspects, the pesticidal composition disclosed herein comprises F1 and at least one active ingredient selected from AIGA-2. In some other aspects, the pesticidal composition disclosed herein comprises F1 and at least two active ingredients selected from AIGA-2. In some other aspects, the pesticidal composition disclosed herein comprises F1 and at least three active ingredients selected from AIGA-2. In certain other aspects, the pesticidal composition disclosed herein comprises F1 and at least four active ingredients selected from AIGA-2.

[0788] In certain aspects, the combination of F1 with at least one other active substance can be used for any one of foliar, seed, soil or furrow treatment. In some preferred aspects, the combination of F1 with at least one other active substance can be used for seed treatment. In some aspects, such seed treatment mixtures can comprise F1 and at least two active substances. In some other aspects, such seed treatment mixtures can comprise F1 and at least three active substances. In certain other aspects, such seed treatment mixtures can comprise F1 and at least four active substances.

[0789] In some aspects, the combination of F1 with other active substances can be any one of the following:

[0790] 1. F1, imidacloprid, metalaxyl, picoxystrobin, ethaboxam, ipconazole, fluxapyroxad

[0791] 2. F1, metalaxyl, picoxystrobin, ethaboxam, ipconazole, fluxapyroxad

[0792] 3. F1, metalaxyl-M, picoxystrobin, ethaboxam, ipconazole, fluxapyroxad

[0793] 4. F1, fluxametamide, fluxapyroxad

[0794] 5. F1, imidacloprid, isoxazam, picoxystrobin, ethaboxam, ipconazole, fluxapyroxad

[0795] 6. F1, isoxazam, picoxystrobin, ethaboxam, ipconazole, fluxapyroxad

[0796] 7. F1, cyflufenamid, picoxystrobin, ethaboxam, ipconazole, fluxapyroxad

[0797] 8. F1, Fludioxonil, Metalaxyl - M, thiabendazole, azoxystrobin

[0798] 9. F1, Zoxamide, Ethaboxam, Metalaxyl

[0799] 10. F1, Prothioconazole, Fluoxastrobin, Metalaxyl

[0800] 11. F1, Fludioxonil, thiabendazole, azoxystrobin, Metalaxyl - M, Fluxapyroxad

[0801] 12. F1, Fenpyrazamine, Prothioconazole, Metalaxyl

[0802] 13. F1, Difenoconazole, Zoxamide, Iprovalicarb, Metalaxyl - M

[0803] Aspect A:

[0804] One aspect of the pesticidal composition disclosed herein is a pesticidal composition comprising:

[0805] (A) F1;

[0806]

[0807] B) Mixed formulations, which are selected from the group consisting of: abamectin, azinphos-methyl, chinomethionat, acetamiprid, fluproxyfen, acynonapyr, pyridalyl, alanycarb, aldicarb, allethrin, alpha-cypermethrin, clopyralid, amitraz, azadirachtin, pirimiphos-methyl,azinphos-ethyl,azinphos-methyl, cyhexatin, azoxystrobin, bendiocarb, propoxur, bensultap, benzoximate, benclothiazox, beta-cyfluthrin, beta-cypermethrin, bifenazate, bifenthrin, bioallethrin, bioresmethrin, bistrifluron, broflanilide, bromopropylate, buprofezin, butocarboxim, butoxycarboxim, cadusafos, carbaryl, carbofuran, carbosulfan, carboxin, cartap hydrochloride, chinomethionat, chlorantraniliprole, chlordane, chlorfenvinphos, chlorfenapyr, chlorpyrifos-methyl, chlorpyrifos, cyromazine, clofentezine, clopyralid, cloquintocet-mexyl, clothianidin, copper hydroxide, coumaphos, cyanophos, cyantraniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliprole, cyclaniliproleMilbemycin, monocrotophos, myclobutanil, naled, nicosulfuron, chlorantraniliprole, flucycloxuron, noviflumuron, omethoate, methiocarb, flutriafol, oxasulfuron, sulfoxaflor, parathion, methyl parathion, fenpyrazamine, pythiathion, permethrin, phenothrin, phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, pipercarbazole, picloram, picoxystrobin, pinoxaden, pirimicarb, pirimiphos-methyl, d - propargite, profenofos, clofentezine, prothoate, propiconazole, propoxur, propyzamide, prothioconazole, prothiofos, spiflumetofen, flufenpyr-ethyl, prometryn, pyraclofos, pyraoxystrobin, pyrethrum, pyridaben, pyridalyl, pyridaphenthion, pyflubumide, pyrimidifen, pyriproxyfen, pyroxasulfone, quinalphos, resmethrin, rimsulfuron, rotenone, fluxapyroxad, silafluofen, spirodiclofen, spirotetramat, spiromesifen, spiromesifene, methoprene, spirotetramat, flonicamid, sulfotep, flonicamid, tau - fluvalinate, tebuconazole, tebufenozide, pyrimidifen, chlorfluazuron, heptafluthrin, temephos, terbufos, tetrachlorvinphos, tetradifon, tetramethrin, cyhalodiamide, theta - cypermethrin, thiabendazole, thiamethoxam, thiosultap - sodium, thiodicarb, thiofanox, methyldisulfoton, bisultap, thiram, thiodicarb, thiazosulfone, tolfenpyrad, tralkoxydim, tralomethrin, transfluthrin, triazamate, triazophos, trichlorfon, triclopyr, trifloxystrobin, triflumezopyrim, novaluron, dimethomorp, formetanate, XMC, methomyl, xi - cypermethrin, AI - 1, AI - 2, and 2,4 - D.

[0808] Aspect B

[0809] Another aspect is a pesticidal composition comprising F1 and a mixed formulation, wherein the mixed formulation is selected from the group consisting of: abamectin, acetamiprid, bixafen, bifenthrin, chlorantraniliprole, chlorfenapyr, cyantraniliprole, cyclaniliprole, cyazypyr, fipronil, flonicamid, fluopyram, flupyradifurone, flufenerim, flutriafol, imidacloprid, indoxacarb, isoxazoline, lambda - cyhalothrin, methoxyfenozide, prometryn, pyriproxyfen, spirodiclofen, spinetoram, spinosad, spiromesifene, spirotetramat, flonicamid, thiamethoxam, and triflumezopyrim.

[0810] Aspect C

[0811] On the other hand, there is a pest-killing composition comprising F1 and a mixed formulation, wherein the mixed formulation is selected from the group consisting of: azoxystrobin, copper hydroxide, difenoconazole, tiadinil, fludioxonil, fluxapyroxad, fluoxastrobin, fluxametamide, ipconazole, prothioconazole, isoflucypram, metalaxyl-M, cyproconazole, flutriafol, picoxystrobin, propiconazole, prothioconazole, fluxametamide, pyraclostrobin, fluxapyroxad, tebuconazole, thiabendazole, thiram, triadimenol, tricyclazole, orysastrobin, abamectin, acetamiprid, chlorantraniliprole, AI-1, AI-2, benpyrimoxan, bifenthrin, broflanilide, chlorantraniliprole, chlorfenapyr, clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, flutriafol, flufiprole, heat-inactivated Burkholderia species strain A 396, imidacloprid, indoxacarb, lambda-cyhalothrin, methoxyfenozide, methomyl, pyriproxyfen, spinosad, spinetoram, spirodiclofen, spirotetramat, flonicamid, cyhalofop-butyl, thiamethoxam, and triflumezopyrim.

[0812] Aspect D

[0813] On the other hand, there is a pest-killing composition comprising F1 and a mixed formulation, wherein the mixed formulation is selected from the group consisting of: azoxystrobin, copper hydroxide, difenoconazole, tiadinil, fludioxonil, fluxapyroxad, fluoxastrobin, fluxametamide, ipconazole, prothioconazole, isoflucypram, metalaxyl-M, cyproconazole, flutriafol, picoxystrobin, propiconazole, prothioconazole, fluxametamide, pyraclostrobin, fluxapyroxad, tebuconazole, thiabendazole, thiram, triadimenol, tricyclazole, orysastrobin.

[0814] Aspect E

[0815] On the other hand, there is a pest-killing composition comprising F1 and a mixed formulation, wherein the mixed formulation is selected from the group consisting of: abamectin, acetamiprid, chlorantraniliprole, AI-1, AI-2, benpyrimoxan, bifenthrin, broflanilide, chlorantraniliprole, chlorfenapyr, clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, flutriafol, flufiprole, heat-inactivated Burkholderia species strain A 396, imidacloprid, indoxacarb, lambda-cyhalothrin, methoxyfenozide, methomyl, pyriproxyfen, spinosad, spinetoram, spirodiclofen, spirotetramat, flonicamid, cyhalofop-butyl, thiamethoxam, and triflumezopyrim.

[0816] In any of the pesticidal compositions according to aspects A - E, the ratio of F1 to admixture B) is selected from 1:160,000 to 160,000:1, 1:80,000 to 80,000:1, 1:40,000 to 40,000:1, 1:20,000 to 20,000:1, 1:10,000 to 10,000:1, 1:8000 to 8000:1, 1:5000 to 5000:1, 1:2000 to 2000:1, 1:1000 to 1000:1, 1:500 to 500:1, 1:250 to 250:1, 1:100 to 100:1, 1:50 to 50:1, 1:25 to 25:1, 1:10 to 10:1, 1:5 to 5:1, and 1:1.

[0817] The present disclosure also provides a method for controlling pests attacking plants, plant propagation parts, and plant habitats, the method comprising the step of contacting the plants, plant propagation parts, plant habitats with the compositions of aspects A - E.

[0818] The present disclosure also provides a method for controlling pests attacking plants, plant propagation parts, plant habitats, the method comprising the step of contacting the pests or their habitats, food supplies, breeding sites, their places with the compositions of aspects A - E.

[0819] The present disclosure provides a method for treating seeds, the method comprising the step of contacting the seeds with the compositions of aspects A - E.

[0820] The present disclosure also provides seeds treated with the compositions of aspects A - E.

[0821] These combinations containing more than two active substances can be mixed in appropriate ratios such that all the active substances together with F1 can exhibit an enhanced activity effect compared to when they are used alone. For example, when calculated using the Colby equation or any other method, a specific mixture of F1 with more than two active substances, such as F1, iprrobenfos, ethaboxam, and metalaxyl, may show enhanced activity compared to the activity of any individual active substance (i.e., calculating the expected efficacy using the Colby equation and comparing it with the observed efficacy; if the observed efficacy is greater than the expected efficacy calculated using the Colby equation, the composition shows enhanced efficacy). In addition to providing enhanced activity, these combinations can provide additional unexpected advantageous properties. For example, desirable degradable properties; improved toxicological and / or ecotoxicological characteristics; improved useful plant properties, including emergence, crop yield, more developed root systems, increased tillering, increased plant height, increased greenness, larger leaves, fewer dead basal leaves, stronger tillering, earlier flowering, earlier grain maturity, increased shoot growth, improved essential nutrient content, improved plant vigor, and early germination.

[0822] Although the enhanced activity of the compositions disclosed herein is unexpected and surprising, this activity also extends the scope of action of F1 alone or any individual active substance in two ways: the application rate of F1 and any other active substance is reduced while the activity remains good or better, where the mixture still achieves a high level of pest control even when the two individual components have themselves become ineffective within such a low application rate range. Additionally, the use of such mixtures can significantly broaden the pest spectrum that can be controlled.

[0823] Bioassay

[0824] The following bioassays were conducted against the green peach aphid (Myzus persicae), sweet potato whitefly (Bemisia tabaci), western flower thrip (Frankliniella occidentalis), brown planthopper (Nilaparvata lugens), neotropical brown stink bug (Euschistus heros), corn earworm (Helicoverpa zea), fall armyworm (Spodoptera frugiperda), and soybean looper (Chrysodeixis includens), which are good indicator species for a wide range of agricultural pests. The results for these indicator species show the broad utility of various pesticidal agents (also known as active ingredients) in combination with molecules of formula I in controlling insect pests.

[0825] Bioassay 1: Green peach aphid (Myzus persicae, MYZUPE, "GPA").

[0826] The green peach aphid is the most important aphid pest of peach trees, causing reduced growth, leaf wilting, and death of various tissues. The green peach aphid is also dangerous because it serves as a vector for transmitting plant viruses such as potato virus Y and potato leafroll virus to members of the nightshade / potato family Solanaceae and various mosaic viruses to many other food crops. GPA attacks plants such as broccoli, burdock, cabbage, carrot, cauliflower, daikon radish, eggplant, green bean, lettuce, macadamia nut, papaya, pepper, sweet potato, tomato, watercress, and zucchini. GPA also attacks many ornamental crops such as carnation, chrysanthemum, flowering white cabbage, poinsettia, and rose. GPA has developed resistance to many pesticidal agents. Currently, it is the third most reported pest in terms of the number of insect resistance cases (Sparks et al.). Therefore, due to the above factors, controlling this pest is important. In addition, molecules that control GPA, a sap-feeding pest, can be used to control other pests that feed on plant sap.

[0827] Prepare stock solutions of F1 and various active ingredients initially at concentrations of 4 milligrams per milliliter (mg / mL) (for F1) and 0.1 mg / mL (for the active ingredient) using a 1:1 mixture of acetone:methanol as the diluent. Prepare stock solutions with F1 and each active ingredient separately. Prepare test solutions from the stock solutions. Prepare test solutions containing F1, the active ingredient separately, and mixtures of F1 with each active ingredient. The test solutions of F1 and the active ingredient separately are prepared by adding 750 microliters (μL) of the stock solution to a 25 mL glass vial, then adding 750 μL of the 1:1 acetone:methanol solvent, and subsequently adding 13.5 mL of water containing 0.025% 20 to produce a 0.0005% (weight / volume (w / v)) solution. The test solutions containing mixtures of F1 and the active ingredient separately are prepared by adding 750 μL of the active ingredient stock solution to a 25 mL glass vial, subsequently adding 750 μL of the F1 stock solution, and then adding 13.5 mL of water containing 0.025% 20 to produce a test solution containing 0.0005% (w / v) F1 and 0.0005% (w / v) active ingredient. Continuously dilute each test solution to produce test solutions at the desired doses (0.0005% (w / v), 0.000125% (w / v), 0.00003125% (w / v), 0.0000078% (w / v), 0.00000195% (w / v), and 0.0000005% (w / v)). In the test solutions containing mixtures of F1 and the active ingredient, the active ingredient is diluted as described above, but the concentration of F1 remains constant (0.04% (w / v)).

[0828] Test the test solutions against GPA using the following procedure: Use cabbage seedlings with 2 - 3 small (3 - 5 centimeters (cm)) true leaves grown in 3 - inch pots as the test substrate. One day before chemical application, infest the seedlings with 20 - 50 GPA (wingless adults and nymph stages). Use four pots with separate seedlings for each treatment. Using a handheld aspirator - type sprayer, spray the solution onto both sides of the cabbage leaves until runoff occurs. Spray reference plants (solvent check) with only the diluent (0.025% 20 in water and 10% acetone:methanol (1:1)). Before grading, keep the treated plants in a storage room at approximately 25 °C and ambient relative humidity (RH approximately 20% to approximately 45%) for three days. Evaluate by counting the number of live aphids per plant under a microscope three days after treatment. Use the following Abbott correction formula (W.S. Abbott, J. Econ. Entomol. [Journal of Economic Entomology] 18 (1925), pp. 265 - 267) to measure the percentage of control:

[0829] Corrected % control = (1 - (Y / X)) * 100

[0830] Where X = the number of live aphids on the solvent - checked plants, and Y = the number of live aphids on the treated plants. In Table B1, "expected % control" was calculated using the method described by Colby S.R., Weeds, 1967, 15, 20 - 22. The results are shown in Table 1 in the tabular section.

[0831] Bioassay 2: Sweet potato whitefly (Bemisia tabaci, BEMITA, "SPW").

[0832] The sweet potato whitefly is a major destructive pest of cotton. It is also a serious pest of many vegetable crops (such as cucurbits, brassica crops, tomatoes, and head lettuce) and ornamental plants. SPW causes damage both by direct feeding damage and virus transmission. SPW is a sap - feeding insect, and its feeding removes plant nutrients. This can lead to stunted growth, defoliation, reduced yield, and boll abscission in cotton. SPW produces large amounts of honeydew, which supports the growth of sooty mold on plant leaves. SPW is also a vector of viruses such as cotton leaf crumple virus and tomato yellow leaf curl virus.

[0833] Using acetone as a diluent, stock solutions of F1 and one or more active ingredients were prepared at a concentration of 0.2 mg / mL. Stock solutions were prepared with F1 and each active ingredient separately. Test solutions were prepared from the stock solutions. Test solutions containing F1, the active ingredient alone, and mixtures of F1 and each active ingredient were prepared. The test solutions of F1 and the active ingredient alone were prepared by adding 500 μL of the stock solution to a 25 - mL glass vial, then adding 500 μL of acetone, and subsequently adding 9 mL of water containing 0.025% 20 to produce a 0.001% (w / v) solution. The test solutions containing mixtures of F1 and the active ingredient were prepared by adding 500 μL of the active ingredient stock solution to a 25 - mL glass vial, subsequently adding 500 μL of the F1 stock solution, and then adding 9 mL of water containing 0.025% 20 to produce a test solution containing 0.001% (w / v) F1 and 0.001% (w / v) active ingredient. Each test solution was serially diluted to produce test solutions of the desired doses (0.001% (w / v), 0.0001% (w / v), 0.00001% (w / v), 0.000001% (w / v), 0.0000001% (w / v), and 0.00000001% (w / v)).

[0834] The test solution was tested against SPW using the following procedure: Cotton seedlings grown in 3-inch pots, pruned to leave only one true leaf, were used as the test substrate. Adult whiteflies (B. tabaci) were allowed to colonize and lay eggs on the cotton plants for 24 hours, after which all adults were removed from the plants using compressed air. The development of the eggs on the plants was monitored, and when crawler emergence was in progress (based on visual inspection using a microscope, >25% emergence), the test solution and method described above for green peach aphid (GPA) were used to spray the plants. The treated plants were kept in a holding chamber at approximately 25 °C and ambient relative humidity (RH) before grading. Evaluation was carried out by counting the number of 2nd-3rd instar nymphs developed per plant under a microscope 7 - 9 days after treatment. The Abbott's correction formula (W.S. Abbott, J. Econ. Entomol. [Journal of Economic Entomology] 18 (1925), pp. 265 - 267) was used as follows to measure the percentage control:

[0835] Corrected % control = (1 - (Y / X)) * 100

[0836] where X = the number of live nymphs on the solvent check plants, and Y = the number of live nymphs on the treated plants. In Table B2, the "expected % control" was calculated using the method described by Colby S.R., Weeds, 1967, 15, 20 - 22. The results are shown in Table 2 in the tabular section.

[0837] Bioassay 3: Western flower thrips (Frankliniella occidentalis, "WFT").

[0838] Western flower thrips is a major destructive pest of a wide range of commercially relevant plant species (over 500 recorded host plants), including many fruits, vegetables, and ornamental plants. WFT is a sap-feeding insect that feeds on various plant parts, damaging plant cells as it feeds. It is also known that WFT acts as a vector for plant diseases and is one of the major vectors of tomato spotted wilt virus.

[0839] Stock solutions of F1 and the various active ingredients were initially prepared at a concentration of 0.1 mg / mL using acetone as the diluent. Stock solutions were prepared with F1 and each active ingredient individually. Test solutions were prepared from the stock solutions. Test solutions containing F1, the individual active ingredients, and mixtures of F1 with each active ingredient were prepared. The test solutions of F1 and the individual active ingredients were prepared by adding 500 μL of the stock solution to a 25 mL glass vial, then adding 500 μL of acetone, and subsequently adding 9 mL containing 0.025% Prepared with water at 20 to produce a 0.0005% (w / v) solution. The test solution containing the mixture of F1 and the individual active ingredient was prepared by adding 500 μL of the active ingredient stock solution to a 25 mL glass vial, followed by adding 500 μL of the F1 stock solution, and then adding 9 mL containing 0.025% Prepared with water at 20 to produce a test solution containing 0.0005% (w / v) F1 and 0.0005% (w / v) active ingredient. Each test solution was serially diluted to produce test solutions at the desired doses (0.0005% (w / v), 0.000125% (w / v), 0.00003125% (w / v), 0.0000078% (w / v), and 0.00000195% (w / v)).

[0840] The following procedure was used to test the test solutions against WFT: Leaf discs (2.7 cm in diameter) were cut from the true leaves of cotton plants. The leaf discs were immersed in the test solution and shaken to ensure complete coverage, and then placed in PetriSlides containing filter paper discs. The treated leaf discs were air-dried for approximately 1 hour. Each leaf disc was infested by placing 5 WFT (9 - 10 day-old nymphs) on each leaf disc, and the PetriSlides were covered to prevent escape. Each treatment was repeated three times, and the test treatments were maintained at approximately 26 °C and ambient relative humidity (RH) before grading. Reference leaf discs were treated with diluent only (solvent check). Evaluation was carried out by counting the number of live WFT under magnification 3 days after treatment. The percentage control was measured using the following Abbott's correction formula (W.S. Abbott, J. Econ. Entomol. [Journal of Economic Entomology] 18 (1925), pp. 265 - 267):

[0841] Corrected % control = (1 - (Y / X)) * 100

[0842] where X = the number of live nymphs on the solvent check leaf discs, and Y = the number of live nymphs on the treated leaf discs. In Table B3, the "expected % control" was calculated using the method described in Colby S.R., Weeds, 1967, 15, 20 - 22. The results are shown in Table 3 in the tabular section.

[0843] Bioassay 4: Helicoverpa armigera (Helicoverpa zea, "CEW"), Spodoptera frugiperda (Fall Armyworm, "FAW"), and Pseudoplusia includens (Soybean Looper, "SBL").

[0844] The cotton bollworm is one of the most costly crop pests in North America, typically attacking the harvested parts of many valuable crops. In addition to corn and tomatoes, CEW larvae also attack artichokes, asparagus, cabbage, cantaloupe, kale, cowpeas, cucumbers, eggplant, lettuce, lima beans, melons, okra, peas, peppers, potatoes, pumpkins, snap beans, spinach, squash, sweet potatoes, and watermelons. Other crops damaged by the cotton bollworm include alfalfa, clover, cotton, flax, oats, millet, rice, sorghum, soybeans, sugarcane, sunflowers, tobacco, vetch, and wheat. The fall armyworm is a global pest of many agriculturally important plant species, including alfalfa, barley, buckwheat, cotton, clover, corn, oats, millet, peanuts, rice, ryegrass, sorghum, sugar beets, soybeans, sugarcane, timothy, tobacco, wheat, and so on. The larvae of the FAW damage plants by feeding on leaves and fruits, resulting in reduced yields or even death of the host plants. Similarly, the soybean looper is a common and destructive pest of soybeans, but it also feeds on other agricultural crops (such as peanuts, cotton, and corn) as well as vegetable crops (including peas, crucifers, sweet potatoes, tomatoes, sweet peppers, snap beans, cucumbers, and watermelons). CEW, FAW, and SBL are good representatives of destructive larval Lepidoptera pests.

[0845] Prepare stock solutions of F1 and one or more active ingredients at concentrations of 0.4 mg / mL (for F1) and 4 mg / mL (for the active ingredient) using a 9:1 mixture of acetone:water as the diluent. Prepare stock solutions with F1 and each active ingredient separately. Prepare test solutions from the stock solutions. Prepare test solutions containing F1, the active ingredient separately, and mixtures of F1 with each active ingredient. The test solution of F1 is prepared by adding 500 μL of the stock solution to a 25 mL glass vial and then adding 500 μL of the 9:1 mixture of acetone:water. The active ingredient separately is prepared by adding 500 μL of the stock solution to a 25 mL glass vial and then adding 500 μL of the 9:1 mixture of acetone:water. The test solution containing a mixture of F1 and the active ingredient separately is prepared by adding 500 μL of the stock solution of the active ingredient to a 25 mL glass vial, followed by adding 500 μL of the stock solution of F1, resulting in a test solution containing 0.04% (w / v) F1 and 0.4% (w / v) active ingredient. Continuously dilute each test solution to produce test solutions at the desired doses (0.04% (w / v), 0.004% (w / v), 0.0004% (w / v), 0.00004% (w / v), 0.000004% (w / v), and 0.0000004% (w / v) for F1, and 0.4% (w / v), 0.04% (w / v), 0.004% (w / v), 0.0004% (w / v), 0.00004% (w / v), and 0.000004% (w / v) for the active ingredient).

[0846] Test the test solutions against CEW, FAW, and SBL using the following procedure: Distribute artificial lepidopteran diet (Multi-Species Lepidopteran Diet, Southland Products) in 128-cell bioassay trays (Frontier Agricultural Sciences TM ). Pipette 50 μL of the test solution into the cells of the bioassay tray. (The test solution doses of 0.04% (w / v), 0.004% (w / v), 0.0004% (w / v), 0.00004% (w / v), 0.000004% (w / v), and 0.0000004% (w / v) in the diet are converted to 5, 0.5, 0.05, 0.005, 0.0005, and 0.00005 μg / cm 2Concentration.) Only the reference treatment (solvent check) was treated with the diluent. Each treatment was replicated 8 times for each species. Second-instar CEW, FAW, or SBL larvae were placed on top of the diet in each cell and covered with a transparent perforated sticky lid. The test trays were kept at approximately 26 °C and ambient relative humidity (RH) until grading. After 5 days, the number of live larvae in each cell was recorded and the percent control was measured using the following Abbott's correction formula (W.S. Abbott, J. Econ. Entomol. [Journal of Economic Entomology] 18 (1925), pp. 265-267):

[0847] Corrected % control = (1 - (Y / X)) * 100

[0848] where X = the number of live larvae on the solvent check, and Y = the number of live larvae on the treated diet. In Table B4, the "expected % control" was calculated using the method described in Colby S.R., Weeds, 1967, 15, 20-22. The results are shown in Table 4 in the tabular section.

[0849] Bioassay 5: Neotropical brown stink bug (Euschistus heros, "BSB").

[0850] The Neotropical brown stink bug is a major pest of soybeans, cotton, sunflowers, and other economically important crops. The BSB is a sap-feeding insect that damages plant cells and seeds during feeding. Feeding on plant seeds can reduce seed viability and lower yields.

[0851] Using dimethyl sulfoxide (DMSO) as a solvent, a stock solution of F1 and one or more active ingredients was prepared at a concentration of 0.2 mg / mL. Stock solutions were prepared with F1 and each active ingredient individually. Test solutions were prepared from the stock solutions. Test solutions containing F1, the individual active ingredients, and mixtures of F1 with each active ingredient were prepared. The test solutions of F1 and the individual active ingredients were prepared by adding 30 μL of the stock solution to a single well of a 96-well plate, then adding 30 μL of DMSO, and subsequently adding 140 μL of a 2:1 mixture of acetone:water as a diluent to produce a 0.03% (w / v) solution. The test solutions containing mixtures of F1 and the individual active ingredients were prepared by adding 30 μL of the F1 stock solution to a single well of a 96-well plate, subsequently adding 30 μL of the individual active ingredient stock solution to the same well, and then adding 140 μL of a 2:1 mixture of acetone:water as a diluent to produce a test solution containing 0.03% (w / v) F1 and 0.03% (w / v) active ingredient. Each test solution was serially diluted to produce test solutions at the desired doses (0.03% (w / v), 0.0075% (w / v), 0.001875% (w / v), 0.000469% (w / v), 0.000117% (w / v), and 0.000029% (w / v)).

[0852] The following procedure was used to test the test solutions against BSB: Artificial agar diet (2% agar, 12% sucrose) was dispensed in 48-well plastic plates (Fisher Scientific TM ). 25 μL of the test solution was pipetted into the wells of a bioassay tray. (The test solution doses of 0.03% (w / v), 0.0075% (w / v), 0.001875% (w / v), 0.000469% (w / v), 0.000117% (w / v), and 0.000029% (w / v) in the diet were converted to concentrations of 36, 9, 2.25, 0.5625, 0.140625, and 0.035156 μg / cm 2 .) The reference treatment (solvent check) was treated with only the diluent. Each treatment was replicated three times, and the test treatments were held at approximately 26 °C and ambient relative humidity (RH) before grading. Three to five BSB nymphs were added to each well and covered with a transparent perforated sticky lid. The total number of live BSB nymphs was recorded four days after application. Scoring was based on the total number of live nymphs in all three replicates. The percentage control was measured using the following Abbott's correction formula (W.S. Abbott, J. Econ. Entomol. [Journal of Economic Entomology] 18 (1925), pp. 265 - 267):

[0853] Corrected % control = (1 - (Y / X)) * 100

[0854] where X = the number of live nymphs on the solvent check, and Y = the number of live nymphs on the treated bean segments. In Table B5, "expected % control" was calculated using the method described by Colby S.R., Weeds, 1967, 15, 20 - 22. The results are shown in Table 5 in the tabular section.

[0855] Bioassay 6: Brown Planthopper (Nilaparvata lugens, NILALU, "BPH").

[0856] The Brown Planthopper is a highly destructive rice pest present in the Asia - Pacific region. The BPH is a sap - feeding insect that can mechanically damage rice enough to kill the plant and act as a vector for viral pathogens that reduce rice yield. Additionally, the BPH has developed resistance to many insecticides that have been used to control outbreaks. Due to these factors, management of the BPH is important, and it is equally important to develop new technologies to control this major pest species.

[0857] F1 and one or more active ingredients were tested at 50, 12.5, 3.125, and 0.78 grams of active ingredient per hectare (g / ha). At these rates, F1 and the individual active ingredients were tested at a 1:1 ratio. Since triflumezopyrim has high potency against BPH, this chemical was tested at lower rates of 0.78, 0.19, 0.049, and 0.012 g / ha. F1 and triflumezopyrim were tested at a 16:1 ratio. Test solutions containing F1, the individual active ingredients, and mixtures of F1 with each active ingredient were prepared. Test solutions were prepared by weighing 5 mg of each test chemical (either alone or in combination according to the treatment) into 25 mL glass vials. Then, 1 mL of acetone was added to each vial to dissolve the test chemical, followed by 19 mL of water containing 0.125% Tween 20 adjuvant. This test solution represented the 50 g / ha treatment and was then serially diluted four - fold to produce three lower rates: 12.5, 3.125, and 0.78 g / ha. Triflumezopyrim was prepared in a similar manner, but with two additional serial dilutions to produce solutions representing 6 rates of 12.5, 3.125, 0.78, 0.19, 0.049, and 0.012 g / ha. The two higher doses were discarded, and the four lower doses were used for testing. Each rate was replicated four times, and a solvent blank was used as a control treatment.

[0858] Five (5) rice seedlings (10 - 12 days old) planted in 3-inch pots were used as test plants. The rice seedlings were grown in soil and the soil was covered with a 2% agar solution. The test solution was applied to the test plants using a Devries Laboratory Research Sprayer that was set to spray at 200 liters per hectare (L / ha) using a TeeJet hollow cone nozzle. After application, the rice seedlings were dried for 1 hour and then a single clear plastic tube (2 inches in diameter x 12 inches in height) was placed over the seedlings in each pot. The tube was pushed down into the agar to create a sealed test chamber. The agar prevented insects from hiding in the soil and made the collection and grading of adult insects easier. Ten to fifteen (10 - 15) 5th instar BPH nymphs were transferred to each test chamber using a vacuum aspirator. Immediately after BPH infestation, each test chamber was covered with a piece of 90-grade cheesecloth and secured with a rubber band to seal the test chamber. The test chambers were kept at 25°C for 6 days and then the total number of live insects in each test chamber was counted. The percentage control was measured using the following Abbott's correction formula (W.S. Abbott, J. Econ. Entomol. [Journal of Economic Entomology] 18 (1925), pp. 265 - 267):

[0859] Percent control corrected = (1 - (Y / X)) * 100

[0860] where X = the number of live insects on the solvent check and Y = the number of live insects in the treated chamber. In Table B6, the "expected percent control" was calculated using the method described in Colby S.R., Weeds, 1967, 15, 20 - 22. The results are shown in Table 6 in the tabular section.

[0861] Bioassay 7: Cotton bollworm (Helicoverpa zea, HELIZE, "CEW"), fall armyworm (Spodoptera frugiperda, LAPHFR, "FAW"), beet armyworm (Spodoptera exigua, LAPHEG, "BAW"), and soybean looper (Pseudoplusia includens, PSEPIN, "SBL").

[0862] The test solution was tested against CEW, FAW, BAW, and SBL using the following procedure: Artificial lepidopteran diet (Multi-Species Lepidopteran Diet, Southern States) was dispensed into 96-well plates. Twenty microliters of the test solution was pipetted into the wells of the bioassay plate. The doses of the test solution in the diet were 5, 0.5, 0.05, 0.005, 0.0005, and 0.00005 mg / cm2. (Doses of 0.04% (w / v), 0.004% (w / v), 0.0004% (w / v), 0.00004% (w / v), 0.000004% (w / v), and 0.0000004% (w / v) of the test solution in the diet were converted to concentrations of 5, 0.5, 0.05, 0.005, 0.0005, and 0.00005 mg / cm2, respectively.) The reference treatment (solvent check) was treated with diluent only. Each treatment was replicated five times for each species. Approximately five first-instar CEW, FAW, BAW, or SBL larvae were placed on top of the diet in each well and covered with a clear perforated sticky lid. The test trays were maintained at approximately 25 °C and ambient relative humidity until grading. Five days later, the number of wells in which all larvae had died was recorded as 100% and averaged across all replicates; then the percentage control was measured using the following Abbott's correction formula (W.S. Abbott, J. Econ. Entomol. [Journal of Economic Entomology] 18 (1925), pp. 265 - 267):

[0863] Corrected % control = (1 - (Y / X)) * 100

[0864] where X = the number of live larvae on the solvent check and Y = the number of live larvae on the treated diet.

[0865] In Table 7, the "expected % control" was calculated using the method described by Colby S.R., Weeds, 1967, 15, 20 - 22. The results are shown in Table 7.

[0866] Bioassay 8: Western Corn Rootworm (Diabrotica virgifera, DIABVI, "WCR")

[0867] The Western Corn Rootworm is one of the most destructive beetle (Coleoptera) pests that attacks the roots of corn plants in North America and Europe every year. The larval stage feeds on corn roots early in the season, which prevents normal plant growth and damages the structural integrity of the plant. This reduces yield and causes plant lodging. The WCR is a good representative of soil pests that feed on plant roots and seeds.

[0868] Corn seeds were planted in greenhouse pots filled with steam-pasteurized soil. Western corn rootworm eggs supplied by Corteva Agriscience, Johnston, IA, US were suspended in a 0.08% agar solution added to the soil. A 1:1 solution of acetone:water was used as a diluent, and stock solutions of F1 and the active ingredient were prepared at a concentration of 250 or 500 ug ai / 10 mL at ratios of (F1∶AI) 1:0.004, 1:0.01, 1:0.02, 1:0.04, 1:0.08, 1:0.1, 1:0.15, 1:0.2, 1:0.4, 1:2, or 1:4. The soil application solution was applied to the soil at 10 mL of infusion. The plants were grown in the greenhouse at 25°C for 13 days, then the roots were removed from the soil, washed, and measured to determine the length of the middle nodal roots. The measured lengths were compared to infested and uninfested untreated checks to determine the average percent control providing protection to the corn roots. The results are shown in Table 8.

[0869] Agriculturally acceptable acid addition salts, salt derivatives, solvates, ester derivatives, polymorphs, isotopomers, and radionuclides

[0870] The molecule having Formula I can be formulated into agriculturally acceptable acid addition salts. As non-limiting examples, amine functional groups can form salts with hydrochloric acid, hydrobromic acid, sulfuric acid, phosphoric acid, acetic acid, benzoic acid, citric acid, malonic acid, salicylic acid, malic acid, fumaric acid, oxalic acid, succinic acid, tartaric acid, lactic acid, gluconic acid, ascorbic acid, maleic acid, aspartic acid, benzenesulfonic acid, methanesulfonic acid, ethanesulfonic acid, hydroxymethanesulfonic acid, and hydroxyethanesulfonic acid. Additionally, as non-limiting examples, acid functional groups can form salts including salts derived from alkali metals or alkaline earth metals and salts derived from ammonia and amines. Examples of preferred cations include sodium, potassium, and magnesium.

[0871] The molecule having Formula I can be formulated into salt derivatives. As non-limiting examples, salt derivatives can be prepared by contacting the free base with a sufficient amount of the desired acid to produce the salt. The free base can be regenerated by treating the salt with a suitable dilute aqueous base such as dilute sodium hydroxide, potassium carbonate, ammonia, and aqueous sodium bicarbonate. For example, in many cases, a pesticidal agent such as 2,4-D is made more water-soluble by converting it to its dimethylamine salt.

[0872] The molecule of Formula I can be formulated with a solvent into a stable complex such that the complex remains intact after removal of the non-complexed solvent. These complexes are often referred to as "solvates". However, it is particularly desirable to use water as the solvent to form stable hydrates.

[0873] Molecules of Formula I containing acid functional groups can be made into ester derivatives. These ester derivatives can then be applied in the same manner as the molecules disclosed in this document.

[0874] Molecules of Formula I can be made into a variety of polymorphs. Polymorphism is important in agrochemical development because different crystal polymorphs or structures of the same molecule can have significantly different physical and biological properties.

[0875] Molecules of Formula I can be made with different isotopes. Of particular importance are molecules having 2 H (also known as deuterium) or 3 H (also known as tritium) in place of 1 H. Molecules of Formula I can be made with different radionuclides. Of particular importance are molecules having 14 C (also known as radiocarbon). Molecules of Formula I having deuterium, tritium, or 14 C can be used in biological studies, half-life studies, and mode of action studies that allow tracking in chemical and physiological processes.

[0876] Formulations

[0877] Pesticides may not be suitable for application in their pure form. It is usually necessary to add other substances so that the pesticide can be used at the desired concentration and in a suitable form, allowing for easy application, handling, transportation, storage, and maximum pesticidal activity. Thus, pesticides are formulated, for example, as baits, concentrated emulsions, dusts, emulsifiable concentrates, fumigants, gels, granules, microcapsules, seed treatments, suspension concentrates, suspoemulsions, tablets, water-soluble liquids, water-dispersible granules, dry flowables, wettable powders, or ultra-low volume solutions.

[0878] Pesticides are most often applied in the form of aqueous suspensions or emulsions prepared from concentrated formulations of such pesticides. Such water-soluble, water-suspendable, or emulsifiable formulations are liquids that are commonly referred to as solids (wettable powders, water-dispersible granules), liquids that are commonly referred to as emulsifiable concentrates or aqueous suspensions. Wettable powders that can be compacted to form water-dispersible granules contain a tight mixture of the pesticide, a carrier, and a surfactant. The concentration of the pesticide is usually from about 10% to about 90% by weight. Carriers are usually selected from attapulgite clay, montmorillonite clay, diatomaceous earth, or purified silicates. Effective surfactants, making up from about 0.5% to about 10% of the wettable powder, are found in sulfonated lignin, condensed naphthalenesulfonates, naphthalenesulfonates, alkylbenzene sulfonates, alkyl sulfates, and nonionic surfactants such as ethylene oxide adducts of alkyl phenols.

[0879] The emulsifiable concentrate of the biocide contains a biocide (such as from about 50 to about 500 grams per liter of liquid) dissolved in a carrier, and the carrier is a mixture of a water-miscible solvent or a water-immiscible organic solvent and an emulsifier. Available organic solvents include aromatic compounds (especially xylene) and petroleum fractions (especially the high-boiling naphthalene and olefin parts of petroleum, such as heavy aromatic naphtha). Other organic solvents can also be used, such as terpene solvents including rosin derivatives, aliphatic ketones such as cyclohexanone, and complex alcohols such as 2-ethoxyethanol. Suitable emulsifiers for the emulsifiable concentrate are selected from conventional anionic surfactants and nonionic surfactants.

[0880] The aqueous suspension includes a water-insoluble biocide dispersed in an aqueous carrier at a concentration ranging from about 5% by weight to about 50% by weight. The suspension is prepared by finely grinding the biocide and vigorously mixing it into a carrier composed of water and a surfactant. Components such as inorganic salts and synthetic or natural gums can also be added to increase the density and viscosity of the aqueous carrier. It is usually most effective to grind and mix the biocide simultaneously by preparing an aqueous mixture in an apparatus such as a sand mill, a ball mill, or a piston-type homogenizer and homogenizing it. The biocide in the form of a suspension can be microencapsulated in a plastic polymer.

[0881] The oil dispersion (OD) includes an organic-solvent-insoluble biocide finely dispersed in a mixture of an organic solvent and an emulsifier at a concentration in the range of from about 2% to about 50% by weight. One or more biocides can be dissolved in the organic solvent. Available organic solvents include aromatic compounds (especially xylene) and petroleum fractions (especially the high-boiling naphthalene and olefin parts of petroleum, such as heavy aromatic naphtha). Other solvents can include vegetable oils, seed oils, and esters of vegetable oils and seed oils. Suitable emulsifiers for the oil dispersion are selected from conventional anionic surfactants and nonionic surfactants. A thickening agent or a gelling agent is added in the formulation of the oil dispersion to change the rheological or flow properties of the liquid and prevent the separation and sedimentation of the dispersed particles or droplets.

[0882] Pesticides can also be applied in the form of granular compositions, which are particularly useful for application to soil. Granular compositions generally contain from about 0.5% to about 10% by weight of the pesticide, which is dispersed in a carrier comprising clay or a similar substance. Such compositions are typically prepared by dissolving the pesticide in a suitable solvent and applying it to a pre-formed granular carrier having an appropriate particle size of from about 0.5 mm to about 3 mm. Such compositions can also be formulated by making agglomerates or pastes of the carrier and the molecules and then extruding and drying to obtain the desired particle size. Another form of granules is water-emulsifiable granules (EG). It is a formulation consisting of granules to be applied in the form of a conventional oil-in-water emulsion in which one or more active ingredients are dissolved or diluted in an organic solvent after disintegration and dissolution in water. Water-emulsifiable granules contain one or several active ingredients dissolved or diluted in a suitable organic solvent, which are absorbed in a water-soluble polymer shell or some other type of soluble or insoluble matrix.

[0883] Dusts containing pesticides are prepared by intimately mixing the pesticide in powder form with a suitable dusty agricultural carrier such as kaolin, ground volcanic rock, etc. Dusts can suitably contain from about 1% to about 10% of the pesticide. Dusts can be applied in the form of seed dressing or foliar application using a dusting machine.

[0884] It is also practical to apply pesticides in the form of a solution in a suitable organic solvent, usually petroleum, such as spray oils widely used in agrochemistry.

[0885] Pesticides can also be applied in the form of aerosol compositions. In such compositions, the pesticide is dissolved or dispersed in a carrier which is a pressure-generating propellant mixture. The aerosol composition is packaged in a container which dispenses the mixture through an atomizing valve.

[0886] When a pesticide is mixed with a food or an attractant or both, a pesticide bait is formed. When pests consume the bait, they also consume the pesticide. The bait can be in the form of granules, gels, flowable powders, liquids, or solids. The bait can be used in pest shelters.

[0887] A fumigant is a pesticidal agent that has a relatively high vapor pressure and can thus exist in the form of a gas at a sufficient concentration to kill pests in soil or enclosed spaces. The toxicity of a fumigant is proportional to its concentration and exposure time. They are characterized by good diffusibility and act by penetrating the respiratory system of pests or being absorbed through the epidermis of pests. Fumigants are applied to control stored product pests under airtight sheets, in sealed chambers or buildings, or in specific compartments.

[0888] A pesticidal agent can be microencapsulated by suspending pesticidal agent particles or droplets in various types of plastic polymers. By changing the chemical properties of the polymer or by changing factors in processing, microcapsules can be formed with various sizes, solubilities, wall thicknesses, and degrees of permeability. These factors control the rate of release of the active ingredient inside, which in turn affects the residual properties, action rate, and odor of the product. Microcapsules can be formulated as suspension concentrates or water-dispersible granules.

[0889] An oil solution concentrate is manufactured by dissolving a pesticidal agent in a solvent that will keep the pesticidal agent in solution. The oil solution of the pesticidal agent usually knocks down and kills pests faster than other formulations because the solvent itself has pesticidal action and the dissolution of the waxy outer covering increases the rate of pesticidal agent uptake. Other advantages of the oil solution include better storage stability, better crack permeability, and better adhesion to greasy surfaces.

[0890] Another embodiment is an oil-in-water emulsion, wherein the emulsion comprises oily beads each having a lamellar liquid crystal coating and dispersed in an aqueous phase, wherein each oily bead contains at least one agriculturally active molecule and is individually coated with a monolayer or multilayered layer comprising: (1) at least one nonionic lipophilic surfactant, (2) at least one nonionic hydrophilic surfactant, and (3) at least one ionic surfactant, wherein the average particle size of the beads is less than 800 nanometers.

[0891] Other formulation components

[0892] Generally, when the molecules disclosed in Formula I are used in a formulation, such formulations can also contain other components. These components include but are not limited to (this is a non-exhaustive and non-mutually exclusive list) wetting agents, spreading agents, adhesives, penetrants, buffers, chelating agents, anti-bleaching agents, compatibilizers, defoamers, cleaning agents, and emulsifying agents. Several components are described next.

[0893] A wetting agent is a substance that, when added to a liquid, increases the spreading or penetrating ability of the liquid by reducing the surface tension between the liquid and the surface on which it spreads. Wetting agents are used in agrochemical formulations for two main functions: during processing and manufacturing, to increase the rate of wetting of powders in water to produce soluble liquids or suspension concentrates; and during mixing of the product with water in the spray tank, to reduce the wetting time of wettable powders and improve the penetration of water into water-dispersible granulates. Examples of wetting agents used in wettable powder, suspension concentrate, and water-dispersible granulate formulations are: sodium lauryl sulfate, sodium dioctyl sulfosuccinate, alkylphenol ethoxylates, and aliphatic alcohol ethoxylates.

[0894] A dispersant is a substance that adsorbs onto the surface of particles, helps to keep the particles in a dispersed state, and prevents their re-aggregation. Dispersants are added to agrochemical formulations to facilitate dispersion and suspension during manufacturing and to ensure that the particles redisperse in the water in the spray tank. They are widely used in wettable powders, suspension concentrates, and water-dispersible granulates. Surfactants used as dispersants have the ability to strongly adsorb onto the particle surface and provide a charged or steric barrier against particle re-aggregation. The most commonly used surfactants are anionic surfactants, nonionic surfactants, or mixtures of the two types. For wettable powder formulations, the most common dispersant is sodium lignosulfonate. For suspension concentrates, polyelectrolytes (such as naphthalene sulfonate formaldehyde condensates) are used to obtain very good adsorption and stability. Triphenylvinylphenol ethoxylate phosphate is also used. Nonionic surfactants such as alkylaryl ethylene oxide condensates and EO-PO block copolymers are sometimes combined with anionic surfactants as dispersants for suspension concentrates. In recent years, new types of very high molecular weight polymer surfactants have been developed as dispersants. They have very long hydrophobic "backbones" and a large number of ethylene oxide chains, forming the "teeth" of a "comb-type" surfactant. These high molecular weight polymers can impart very good long-term stability to suspension concentrates because the hydrophobic backbone has many anchor points on the particle surface. Examples of dispersants used in agrochemical formulations are: sodium lignosulfonate, naphthalene sulfonate formaldehyde condensates, triphenylvinylphenol ethoxylate phosphate, aliphatic alcohol ethoxylates, alkyl ethoxylates, EO-PO block copolymers, and graft copolymers.

[0895] An emulsifier is a substance that stabilizes a suspension of droplets of one liquid phase in another liquid phase. In the absence of an emulsifier, the two liquids would separate into two immiscible liquid phases. The most commonly used emulsifier blends contain alkylphenols or aliphatic alcohols having twelve or more ethylene oxide units and the oil-soluble calcium salt of dodecylbenzenesulfonic acid. A range of hydrophilic-lipophilic balance (“HLB”) values from about 8 to about 18 will normally provide a well-stabilized emulsion. Emulsion stability can sometimes be improved by the addition of small amounts of EO-PO block copolymer surfactants.

[0896] A solubilizer is a surfactant that forms micelles in water at concentrations above the critical micelle concentration. These micelles are then able to dissolve or solubilize water-insoluble materials within the hydrophobic portion of the micelle. The types of surfactants commonly used for solubilization are nonionic surfactants, sorbitan monooleate, sorbitan monooleate ethoxylate, and methyl oleate.

[0897] Surfactants are sometimes used alone or in combination with other additives (such as mineral oil or vegetable oil) as adjuvants for spray tank mixing to improve the biological performance of the pesticide against the target. The types of surfactants used for bioenhancement usually depend on the nature and mode of action of the pesticide. However, they are generally nonionic surfactants such as: alkyl ethoxylates, linear aliphatic alcohol ethoxylates, and aliphatic amine ethoxylates.

[0898] Carriers or diluents in agricultural formulations are materials added to pesticides to give the product the desired strength. Carriers are usually materials with high absorption capacity, while diluents are usually materials with low absorption capacity. Carriers and diluents are used in the formulation of dusts, wettable powders, granules, and water-dispersible granules.

[0899] Organic solvents are mainly used in the formulation of emulsifiable concentrates, oil-in-water emulsions, suspoemulsions, oil dispersions, and ultra-low volume formulations, and to a lesser extent in the formulation of granular formulations. Mixtures of solvents are sometimes used. The first main group of solvents is aliphatic paraffin oils such as kerosene or refined paraffin. The second main group (and the most commonly used) of solvents includes aromatic solvents such as xylene and higher molecular weight C9 and C10 aromatic solvent fractions. Chlorinated hydrocarbons can be used as co-solvents to prevent the crystallization of pesticides when the formulation is emulsified in water. Alcohols are sometimes used as co-solvents to increase the solubilizing capacity. Other solvents can include vegetable oils, seed oils, and esters of vegetable and seed oils.

[0900] Thickeners or gelling agents are mainly used in formulating suspension concentrates, oil dispersions, emulsions, and suspoemulsions to modify the rheological or flow characteristics of liquids and prevent the separation and sedimentation of dispersed particles or droplets. Thickeners, gelling agents, and antisettling agents are generally divided into two categories, namely water-insoluble particles and water-soluble polymers. Clays and silica can be used to produce suspension concentrate and oil dispersion formulations. Examples of these types of materials include, but are not limited to, montmorillonite, bentonite, magnesium aluminum silicate, and palygorskite. Water-soluble polysaccharides in water-based suspension concentrates have been used as thickening-gelling agents for many years. The most commonly used types of polysaccharides are natural extracts of seeds and seaweeds or synthetic derivatives of cellulose. Examples of these types of materials include, but are not limited to, guar gum, locust bean gum, carrageenan, alginate, methylcellulose, sodium carboxymethylcellulose (SCMC), and hydroxyethylcellulose (HEC). Other types of antisettling agents are based on modified starches, polyacrylates, polyvinyl alcohol, and polyethylene oxide. Another good antisettling agent is xanthan gum.

[0901] Microorganisms can cause spoilage of formulated products. Therefore, preservatives are used to eliminate or mitigate their effects. Examples of such agents include, but are not limited to: propionic acid and its sodium salts, sorbic acid and its sodium or potassium salts, benzoic acid and its sodium salts, sodium p-hydroxybenzoate, methyl p-hydroxybenzoate, and 1,2-benzisothiazolin-3-one (BIT).

[0902] The presence of surfactants usually causes foaming of water-based formulations during production and mixing operations during application through spray tanks. To reduce the tendency to foam, antifoaming agents are usually added during the production stage or before filling into bottles. Generally, there are two types of antifoaming agents, namely silicone and non-silicone. Silicone is usually an aqueous emulsion of dimethylpolysiloxane, and non-silicone antifoaming agents are water-insoluble oils (such as octanol and nonanol) or silica. In both cases, the function of the antifoaming agent is to displace the surfactant from the air-water interface.

[0903] "Green" agents (such as adjuvants, surfactants, solvents) can reduce the overall environmental footprint of crop protection formulations. Green agents are biodegradable and generally derived from natural and / or sustainable sources, such as plant and animal sources. Specific examples are: vegetable oils, seed oils, and their esters, as well as alkoxylated alkyl polyglucosides.

[0904] Application

[0905] The molecules of Formula I and their combinations disclosed herein can be applied to any location. Specific locations where such molecules are applied include alfalfa, almond, apple, barley, beans, canola, corn, cotton, cruciferous plants, flowers, forage species (ryegrass, sudan grass, tall fescue, kentucky bluegrass, and clover), fruits, lettuce, oats, oilseed crops, citrus, peanut, pear, pepper, potato, rice, sorghum, soybean, strawberry, sugarcane, sugar beet, sunflower, tobacco, tomato, wheat (e.g., hard red winter wheat, soft red winter wheat, white winter wheat, hard red spring wheat, and durum spring wheat), and other valuable crops or locations where seeds thereof are to be planted.

[0906] The molecules of Formula I and their combinations disclosed herein can also be applied to locations where plants (such as crops) grow and where there are few (or even practically none) pests that can commercially damage such plants. Applying such molecules at such locations will be beneficial for plant growth at such locations. Such beneficial effects can include, but are not limited to: helping plants grow better roots; helping plants better withstand stress growth conditions; improving plant health; improving plant yield (e.g., increased biomass and / or increased content of valuable components); improving plant vigor (e.g., improved plant growth and / or greener leaves); improving plant quality (e.g., improving the content or composition of certain components); and improving plant tolerance to abiotic and / or biotic stresses.

[0907] When growing multiple plants, the molecules of Formula I and their combinations disclosed herein can be applied together with ammonium sulfate, as this can provide additional benefits.

[0908] The molecules of Formula I and their combinations disclosed herein can be applied on, in, or around the following plants: plants genetically modified to express specific traits (such as Bacillus thuringiensis (e.g., Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry3Bb, Cry34Ab1 / Cry35Ab1)), other insecticidal toxin-expressing plants, or plants expressing herbicide tolerance, or plants having "stacked" exogenous genes expressing insecticidal toxins, herbicide tolerance, nutritional enhancement, or any other beneficial trait.

[0909] The molecules of formula (I) and their combinations disclosed herein can be applied to the foliage and / or fruiting parts of plants to control pests. Such molecules will come into direct contact with the pests, or the pests will consume such molecules when feeding on the plants or when extracting the sap or other nutrients of the plants.

[0910] The molecules of formula (I) and their combinations disclosed herein can also be applied to the soil, and when applied in this way, pests feeding on roots and stems can be controlled. The roots can absorb such molecules and thereby transport them upwards to the leaf parts of the plants to control chewing pests and sap-sucking pests above ground.

[0911] The systemic movement of the pesticidal agents in plants can be utilized to control pests on one part of a plant by applying the molecules of formula (I) (e.g., by spraying sites) to different parts of the plant. For example, the control of foliage-feeding insects can be achieved by drip irrigation or furrow application, by treating the soil with, for example, a pre-planting or post-planting soil drench, or by treating the plant seeds before planting.

[0912] The molecules of formula (I) and their combinations disclosed herein can be used in conjunction with baits. Generally for baits, the bait is placed on the ground where, for example, termites can come into contact with and / or be attracted to the bait. The bait can also be applied to the surfaces (horizontal, vertical or inclined surfaces) of buildings where, for example, ants, termites, cockroaches and flies can come into contact with and / or be attracted to the bait.

[0913] The molecules of formula (I) and their combinations disclosed herein can be encapsulated inside capsules or placed on the surface of capsules. The size of the capsules can range from nano-size (about 100 - 900 nanometers in diameter) to micro-size (about 10 - 900 micrometers in diameter).

[0914] The molecules of formula (I) and their combinations disclosed herein can be applied to the eggs of pests. Due to the unique ability of the eggs of some pests to resist certain pesticidal agents, it may be desirable to repeat the application of such molecules to control newly emerged larvae.

[0915] The molecules of formula I and their combinations disclosed herein can be applied as seed treatment agents. The seed treatment agents can be applied to all types of seeds, including seeds from which plants that have been genetically modified to express a particular trait will germinate. Representative examples include those that express a protein toxic to invertebrate pests such as Bacillus thuringiensis, or other insecticidal toxins, those that express herbicide tolerance such as "Roundup Ready" seeds, or those that have "stacked" foreign genes that express insecticidal toxins, herbicide tolerance, enhanced nutrition, drought resistance, or any other beneficial trait. In addition, such seed treatment agents of the molecules of formula I can further enhance the ability of plants to better withstand stress growth conditions. This results in healthier and more vigorous plants, which can lead to higher yields at harvest time. Generally, an amount of about 1 gram to about 500 grams of such molecules / 100,000 seeds is expected to provide good benefits, an amount of about 10 grams to about 100 grams / 100,000 seeds is expected to provide better benefits, and an amount of about 25 grams to about 75 grams / 100,000 seeds is expected to provide even better benefits.

[0916] Component A (the molecule of formula I) is present in the formulation for seed treatment in a pesticidal effective amount, for example, in an amount of 1% to about 60% by weight based on the total weight of the seed treatment mixture. Each compound of component B is present in a pesticidal effective amount of from about 1% to about 60% by weight based on the total weight of the seed treatment mixture. Component A and B can be applied to the seeds sequentially or simultaneously.

[0917] The seed treatment agent can contain more than one active compound as component B, such as compounds having additional fungicidal, insecticidal, acaricidal, and / or nematicidal properties. As used herein, the term "seed" means any dormant stage of a plant that is physically detached from the plant state of the plant, and / or can be stored long-term and / or can be used to regenerate another plant of the same species. The term "dormant" refers to a state in which a plant remains viable within reasonable limits despite the absence of light, water, and / or nutrients that are necessary for the plant (i.e., non-seed) state. In a particular embodiment, the term refers to true seeds.

[0918] The molecules of formula I and their combinations disclosed herein can be applied together with one or more active ingredients in a soil conditioner.

[0919] The molecules of formula I and their combinations disclosed herein can be used in the veterinary field or in the field of non-human animal husbandry for the control of endoparasites and ectoparasites. Such molecules can be administered in the following ways: orally in the form of, for example, tablets, capsules, beverages, granules, percutaneously by, for example, dipping, spraying, pouring, spotting, and dusting, and parenterally in the form of, for example, injection solutions.

[0920] The molecules of formula I and their combinations disclosed herein can also be advantageously used in livestock farming, such as for cattle, chickens, geese, goats, pigs, sheep, and turkeys. They can also be advantageously used for pets, such as horses, dogs, and cats. The specific pests to be controlled can be flies, fleas, and ticks that are annoying to such animals. Suitable formulations are administered orally to the animals together with drinking water or food. Suitable dosages and formulations depend on the species.

[0921] The molecules of formula I and their combinations disclosed herein can also be used to control parasites (especially in the intestine) in the animals listed above.

[0922] The molecules of formula I and their combinations disclosed herein can also be used in therapeutic methods for human healthcare. Such methods include, but are not limited to, oral administration in the form of, for example, tablets, capsules, beverages, granules, and transdermal application.

[0923] The molecules of formula I and their combinations disclosed herein can also be applied to invasive pests. Pests worldwide have migrated to new environments (for such pests) and have thereafter become new invasive species in such new environments. Such molecules can also be used for such new invasive species to control them in such new environments.

[0924] The table part is as follows

[0925] Calculate the % increase above expectation in the following table according to the following equation:

[0926] ((Observed % control of the mixture - Expected % control) / Expected % control) x 100

[0927] Thus, in some cases, * indicates that the % increase above expectation is too large to be calculated using the above equation (e.g., when the Expected % control = 0).

[0928]

[0929]

[0930]

[0931]

[0932]

[0933]

[0934]

[0935]

[0936]

[0937]

[0938]

[0939]

[0940]

[0941]

[0942]

[0943]

[0944]

[0945]

[0946]

[0947]

[0948]

[0949]

Claims

1. A pesticidal composition, comprising: (A) A molecule having a structure according to Formula I Wherein: R 1 is CF3, CHF2, CF2CF3, OCF3, OCF2CF3, SF5, or SO2CF3; R 2 is H, F, or CH3; R 3 is CH3 or OCH3; and R 4 is -CH2OCH2CH3, -CH2OCH2CF3, or -CH2OCH2CH2F; and B) a mixed formulation, which is (1) a member of AIGA; (2) a member of AIGA-1; (3) a member of AIGA-2; (3) AI-1; or (4) AI-2.

2. The pesticidal composition according to claim 1, wherein, Molecules having the structure according to Formula I are F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, or F16.

3. The composition according to claim 2, wherein, The molecule is F1.

4. The composition according to claim 3, comprising: (A) F1; B) A mixture composition selected from the group consisting of: abamectin, azinphos-methyl, chinomethionat, acetamiprid, fluprothrin, acynonapyr, pyridalyl, alanycarb, aldicarb, allethrin, alpha-cypermethrin, clopyralid, amitraz, azadirachtin, pirimiphos-methyl,azinphos-ethyl, azinphos-methyl, cyhexatin, azoxystrobin, bendiocarb, benfuracarb, bensultap, benzoximate, bixafen, beta-cyfluthrin, beta-cypermethrin, bifenazate, bifenthrin, bioallethrin, bioresmethrin, bistrifluron, broflanilide, bromopropylate, buprofezin, butocarboxim, butoxycarboxim, cadusafos, carbaryl, carbofuran, carbosulfan, carboxin, cartap hydrochloride, chinomethionat, chlorantraniliprole, chlordane, chlorfenvinphos, chlorfenapyr, chlorpyrifos-methyl, chlorpyrifos, chlorethoxyfos, chlorpropham, chlorthiophos, clethodim, clothianidin, copper hydroxide, coumaphos, cyanophos, cyantraniliprole, cyclaniliprole, cycloxaprid, cyphenothrin, DDVP, deltamethrin, demeton-S-methyl, diafenthiuron, diazinon, dichlorvos, dicofol, dimefox, difenoconazole, fluacrypyrim, dimethoate, dimethylvinphos, dinotefuran, disulfoton, DNOC, d-trans-allethrin, emamectin, emamectin benzoate, empenthrin, endosulfan, EPN, esfenvalerate, febantel, ethiofencarb, ethion, ethiprole, ethoprophos, etofenprox, fenamidone, fenamiphos, fenazaquin, fenbuconazole, fenbutatin oxide, fenitrothion, fenpyrazamine, fenpropathrin, fenpyroximate, fenthion, fenvalerate, fipronil, flazasulfuron, flonicamid, florasulam, flufenerim, fluopyram, flurochloridone, flupyradifurone, flutolanil, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flutriafol, flMilbemycin, monocrotophos, myclobutanil, bromophos, nicosulfuron, chlorpyrifos, flucycloxuron, lufenuron, omethoate, methiocarb, flutriafol, oxasulfuron, sulfotep, parathion, methyl parathion, fenpyrazamine, isopyrazam, permethrin, phenothrin, phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, pipercarb, picloram, picoxystrobin, pinoxaden, pirimicarb, pirimiphos-methyl, d - trans - allethrin, profenofos, propargite, propaphos, propiconazole, propoxur, propyzamide, prothioconazole, prothiofos, spiflumetofen, flufenoxuron, prometryn, pyraclofos, pyraoxystrobin, pyrethrum, pyridaben, pyridalyl, pyridaphenthion, pyflubumide, pyrimidifen, pyriproxyfen, pyroxasulfone, quinalphos, resmethrin, sulfosulfuron, rotenone, fluxapyroxad, silafluofen, dispirotetramat, spinetoram, spinosad, spirodiclofen, spirotetramat, spiromesifen, methoprene, spirotetramat, flonicamid, sulfotep, flonicamid, tau - fluvalinate, tebuconazole, tebufenozide, pyrimidifen, chlorfluazuron, heptafluthrin, temephos, terbufos, tetrachlorvinphos, binapacryl, tetramethrin, cyhalofop - butyl, thiabendazole, thiamethoxam, thiosultap - sodium, thiodicarb, methomyl, phorate, dimethoate, bisultap, thiram, thiaramide, thiazosulfone, tolfenpyrad, tralkoxydim, tralomethrin, transfluthrin, triazophos, trichlorfon, triclopyr, trifloxystrobin, triflumezopyrim, novaluron, methomyl, formetanate, XMC, xylylcarb, zeta - cypermethrin, AI - 1, AI - 2, and 2,4 - D.

5. The pesticidal composition according to claim 1, wherein, The mixed formulation is selected from the group consisting of: abamectin, acetamiprid, bixafen, bifenthrin, chlorantraniliprole, chlorfenapyr, cyantraniliprole, cyclaniliprole, flupyradifurone, flubendiamide, flufenoxuron, flonicamid, flubendazole, fipronil, flutriafol, indoxacarb, isoxazolinyl, lambda-cyhalothrin, methoxyfenozide, metoprene, pyriproxyfen, spirotetramat, spinosad, spinetoram, sulfoxaflor, thiamethoxam, and triflumezopyrim.

6. The pesticidal composition according to claim 4, wherein, The mixed formulation is selected from the group consisting of: azoxystrobin, copper hydroxide, difenoconazole, isothiazolinone, fludioxonil, fluxapyroxad, fluoxastrobin, fluxametamide, indoxacarb, prothioconazole, isopyrazam, metalaxyl-M, cyflufenamid, picoxystrobin, propiconazole, prothioconazole, fluxametamide, boscalid, penflufen, tebuconazole, thiabendazole, thiram, triadimenol, tricyclazole, azoxystrobin, abamectin, acetamiprid, acetoprole, AI-1, AI-2, bixafen, bifenthrin, broflanilide, chlorantraniliprole, chlorfenapyr, clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, fluazaindolizine, flupyradifurone, flubendiamide, heat-inactivated Burkholderia species strain A 396, imidacloprid, indoxacarb, lambda-cyhalothrin, methoxyfenozide, methomyl, pyriproxyfen, spinosad, spinetoram, spirodiclofen, spirotetramat, sulfoxaflor, cyhalofop-butyl, thiamethoxam, and triflumezopyrim.

7. The pesticidal composition according to claim 5, wherein, The mixed formulation is selected from the group consisting of: azoxystrobin, copper hydroxide, difenoconazole, isothiazolinone, fludioxonil, fluxapyroxad, fluoxastrobin, fluxametamide, indoxacarb, prothioconazole, isopyrazam, metalaxyl-M, cyflufenamid, picoxystrobin, propiconazole, prothioconazole, fluxametamide, boscalid, penflufen, tebuconazole, thiabendazole, thiram, triadimenol, tricyclazole, and azoxystrobin.

8. The pesticidal composition according to claim 5, wherein, The mixed formulation is selected from the group consisting of: abamectin, acetamiprid, chlorantraniliprole-acetamiprid, AI-1, AI-2, bixafen, bifenthrin, broflanilide, chlorantraniliprole, chlorfenapyr, clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, flutriafol, flupyradifurone, flufiprole, fluxametamide, heat-inactivated Burkholderia sp. strain A 396, imidacloprid, indoxacarb, lambda-cyhalothrin, methoxyfenozide, methomyl, pyriproxyfen, spinosad, spinetoram, spirodiclofen, spirotetramat, sulfoxaflor, cyhalofamid, thiamethoxam, and triflumezopyrim.

9. The pesticidal composition according to claims 1 - 8, wherein, The ratio of F1 to the mixed formulation B) is selected from 1:160,000 to 160,000:1, 1:80,000 to 80,000:1, 1:40,000 to 40,000:1, 1:20,000 to 20,000:1, 1:10,000 to 10,000:1, 1:8000 to 8000:1, 1:5000 to 5000:1, 1:2000 to 2000:1, 1:1000 to 1000:1, 1:500 to 500:1, 1:250 to 250:1, 1:100 to 100:1, 1:50 to 50:1, 1:25 to 25:1, 1:10 to 10:1, 1:5 to 5:1, and 1:

1.

10. A method for controlling pests attacking plants, plant propagation parts, and plant habitats, the method comprising the step of bringing the plants, plant propagation parts, plant habitats into contact with the composition according to claims 1 - 8.

11. A method for controlling pests attacking plants, plant propagation parts, and plant habitats, the method comprising the step of bringing the pests or their habitats, food supplies, breeding grounds, their places into contact with the composition according to claims 1 - 8.

12. A method of treating seeds, the method comprising the step of contacting the seeds with a composition according to claims 1-5.

13. A seed treated with a composition according to claims 1-8.

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