Natural protein shampoo based on APG surface activity system and preparation method thereof

Abstract

The invention provides natural protein shampoo based on an APG surface activity system and a preparation method of the natural protein shampoo, aims at solving the problems that effective microbial communities of existing shampoo are damaged, scalp barriers are damaged, and the anti-dandruff effect is not lasting, and provides a three-dimensional micro-ecological restoration framework of undecylenyl compounds, yeast zinc ZN100 and HA. The microecological friendliness is remarkably improved by targeted inhibition of malassezia proliferation and promotion of growth of scalp effective microbial communities, meanwhile, due to the synergistic effect of an APG surface activity system and undecylenoyl protein, excessive cleaning is avoided while efficient cleaning is guaranteed, a split-phase pre-dispersion and step-by-step cooling method is adopted in the preparation method, the pH value and the viscosity are accurately controlled, and the preparation method is simple and easy to implement. Different undecylenoyl protein different concentration difference formulas are provided according to different types of scalp requirements, the powerful dandruff removing and daily maintenance functions are considered, the shampoo is suitable for people of various scalp types, and the dandruff problem is fundamentally solved.

Description

Technical Field

[0001] This invention relates to the field of daily chemical product technology, specifically to a natural protein shampoo based on the APG surfactant system and its preparation method. Background Technology

[0002] Dandruff is a common scalp problem caused by a combination of factors. Normally, scalp skin cells constantly metabolize, and aged keratinocytes shed from the scalp surface—a process that is silent and difficult to detect. However, when the scalp is in an unhealthy state, such as when Malassezia proliferates excessively (Malassezia is a lipophilic fungus widely present on the scalp that breaks down sebum secreted by the scalp, converting it into free fatty acids), these free fatty acids irritate the scalp, triggering an inflammatory response. The irritated scalp accelerates the renewal of keratinocytes, resulting in incomplete keratinization and the shedding of large numbers of immature keratinocytes—the dandruff we see. Currently, common anti-dandruff shampoos on the market mainly use chemical ingredients such as zinc pyrithione (ZPT) and piroctone olamine (OCT) as anti-dandruff agents.

[0003] The invention application with publication number CN115671016A discloses a "Relaxing and Softening ZPT Anti-Dandruff and Anti-Itch Plant-Based Hair Care Shampoo," which is an aloe vera plant extract containing cationic guar gum, surfactant AES, ZPT anti-dandruff and anti-itch agent, and daily chemical fragrance. The Relaxing and Softening ZPT Anti-Dandruff and Anti-Itch Plant-Based Hair Care Shampoo is manufactured using modern scientific technology. Its effects include: after use, hair has superior softness and shine, smoothness when combing, and anti-dandruff and anti-itch capabilities. Although ZPT can effectively inhibit the growth of Malassezia, thereby reducing dandruff problems, long-term use may lead to scalp microecological imbalance, damage to the scalp barrier function, and discomfort symptoms such as dryness and itching.

[0004] To ensure better dandruff removal, patent application CN117442535A discloses an "anti-dandruff shampoo," which provides an anti-dandruff shampoo using a combination of chemical anti-dandruff agent OCT and plant-derived anti-dandruff agent. The shampoo includes the following components: sodium C14-16 olefin sulfonate, sodium methyl cocoyl taurate, sodium cocoyl methyl taurate taurate, nonionic surfactant, amphoteric surfactant, cationic conditioner, stabilizer, emollient, piroctone ketone ethanolamine salt, sophora flavescens extract, auxiliary plant extracts, preservative, fragrance, pH adjuster, thickener, deionized water, etc. While OCT has a good dandruff removal effect, it also has a certain disruptive effect on the scalp microecology and may trigger allergic reactions in some users, leading to scalp inflammation and other problems.

[0005] In summary, the existing ZPT and OCT shampoos usually have the following shortcomings: 1) Beneficial flora is damaged: ZPT and OCT anti-dandruff agents in traditional shampoos can inhibit Malassezia while also killing beneficial flora on the scalp, which under normal circumstances participates in the balance of the scalp micro-ecosystem and limits the overgrowth of potentially harmful bacteria such as Malassezia. After using ZPT and OCT shampoos, the number of beneficial flora decreases, disrupting the stability of the scalp micro-ecosystem. 2) Damage to the scalp barrier: OCT anti-dandruff agents usually have strong irritation, and some users will experience allergic reactions such as scalp itching, stinging, and erythema after use, which further damages the scalp barrier, making the scalp more susceptible to external stimuli and pathogen invasion. The cleaning system of traditional ZPT and OCT-containing shampoos is often too strong, removing the natural oil on the scalp, which can lead to impaired scalp barrier function, increased transdermal water loss, and a dry and fragile scalp. 3) Dandruff control is not long-lasting: ZPT and OCT shampoos have a short-term dandruff control effect, but the problem of dandruff tends to recur over time, and the dandruff control effect is not long-lasting. SUMMARY

[0006] The purpose of the present application is to solve the problems in the prior art and provide a natural protein shampoo based on an APG surfactant system and a preparation method thereof, which can solve the problems of damaged beneficial flora, damaged scalp barrier, and non-long-lasting dandruff control.

[0007] To achieve the above-mentioned purpose, the present application provides a natural protein shampoo based on an APG surfactant system and a preparation method thereof, which comprises the following components by weight: Phase A: C-162: 0.2-0.4 parts; Phase B: JR400: 0.2-0.4 parts; Phase C: Carbomer U20: 0.1-0.4 parts; Phase D: AES: 18-22 parts; CMT-40S: 5-8 parts; Pearl flake: 1-3 parts; Glycerol polyether 26: 0.3-0.7 parts; Glycerol oleate: 0.1-0.3 parts; Polyglyceryl-4 sunflower acid ester 0.1-0.3 parts; Phase E: Arginine: 0.4-0.6 parts; Phase F: CE7128NB: 0.5-1.5 parts; HA: 1.0-2.0 parts; PQ52: 0.1-0.3 parts; Phenoxyethanol: 0.3-0.8 parts; Ethylhexylglycerin: 0.05-0.20 parts; HFM-710: 0.5-1.5 parts; Zinc yeast ZN100: 1-2 parts; Fragrance: 0.5-1.2 parts; G phase: SM-2 pearl paste: 1-3 parts; sodium chloride: 0.5-0.9 parts; CAB35: 1-3 parts; H phase: TW-IS399S: 0.4-0.8 parts; The total weight parts of the A phase, the B phase, the C phase, the D phase, the E phase, the F phase, the G phase and the H phase are one hundred parts, and the balance is supplemented with water.

[0008] As preferred, the C-162 comprises hydroxypropyl guar hydroxypropyltrimonium chloride and water, the CE7128NB comprises dimethicone, water, poloxamer 407, laureth-23, laureth-4, polyethylene glycol-4, xanthan gum, potassium sorbate and sodium benzoate, the HA comprises lactobacillus ferment, hyaluronic acid hydroxypropyltrimonium chloride and ginger root extract, and the PQ52 comprises polyquaternium-52, laureth-16, phenoxyethanol and water.

[0009] As preferred, the AES is an anionic surfactant, the CMT-40S is an amino acid surfactant, the polyglyceryl-4 oleate is a non-ionic surfactant, the polyglyceryl-4 oleate forms a stable emulsified system with oil and fat, and the polyglyceryl-4 oleate synergizes with the CMT-40S and the AES.

[0010] As preferred, the undecylenoyl complex is composed of water, undecylenoyl hydrolyzed wheat protein potassium, phenoxyethanol and ethylhexylglycerin, and the yeast zinc ZN100 is a zinc ion-containing yeast extract; the yeast zinc ZN100 and the HA jointly construct a three-dimensional micro-ecological repair framework, the undecylenoyl complex is a basic component of the three-dimensional micro-ecological repair framework, the yeast zinc ZN100 is connected to the undecylenoyl protein, and the HA is filled between the undecylenoyl protein and the yeast zinc.

[0011] As preferred, the weight ratio of the yeast zinc ZN100, the HA and the HFM-710 in the three-dimensional micro-ecological repair framework is 1.5:1.5:1.

[0012] As preferred, the carbomer U20, the sodium chloride and the TW-IS399S are thickening agents, the weight ratio of the carbomer U20, the sodium chloride and the TW-IS399S is 0.3:0.7:0.6, and the viscosity adjustment range is 6000-8000 mPa·s.

[0013] As preferred, the carbomer U20 and water form a pH buffering matrix, the amount of the carbomer U20 in the pH buffering matrix is 0.001-0.005 parts, and the amount of water is 48-52 parts; the pH value of the pH buffering matrix ranges from 5.5 to 6.0.

[0014] To achieve the above-mentioned purpose, the application further provides a preparation method of natural protein shampoo based on APG table active system, which comprises the following steps: a) 3-5 parts of water, 0.2-0.4 parts of C-162 are used as A phase; 3-5 parts of water, 0.2-0.4 parts of JR400 are used as B phase; 45-50 parts of water, 0.1-0.4 parts of carbomer U20 are used as C phase; 18-22 parts of AES, 5-8 parts of CMT-40S, 1-3 parts of pearl flake, 0.3-0.7 parts of glycerol polyether 26, 0.1-0.3 parts of glycerol oleate and 0.1-0.3 parts of polyglyceryl-4 sunflower acid ester are used as D phase; 0.4-0.6 parts of arginine are used as E phase; CE7128NB, HA, PQ52, phenoxyethanol, ethylhexyl glycerin, HFM-710, yeast zinc ZN100 and essence are used as F phase; 0.5-1.5 parts of CE7128NB, 1.0-2.0 parts of HA, 0.1-0.3 parts of PQ52, 0.3-0.8 parts of phenoxyethanol, 0.05-0.20 parts of ethylhexyl glycerin, 0.5-1.5 parts of HFM-710, 1-2 parts of yeast zinc ZN100 and 0.5-1.2 parts of essence are used as G phase; 0.4-0.8 parts of TW-IS399S are used as H phase; b) C phase is put into a stirring pot, and the stirring pot is heated to 80-90°C until complete dissolution; c) D phase is put into the stirring pot, and stirring is performed until complete dissolution; d) A phase and B phase which are pre-dispersed are put into the stirring pot, and stirring is performed until complete dissolution; e) cooling water is opened to cool the materials in the stirring pot to 50-55°C, then arginine of E phase is put into the stirring pot, and the pH value is adjusted to 5.5-6.0; f) the materials in the stirring pot are continuously cooled to 30-45°C, then F phase and G phase are put into the stirring pot, and stirring is performed until complete uniformity; g) H phase is put into the stirring pot, and the viscosity is adjusted to 6000-8000 mPa.s; The total weight parts of A phase, B phase, C phase, D phase, E phase, F phase, G phase and H phase are one hundred parts, and the rest is supplemented with water.

[0015] Preferably, the temperature window for adjusting the pH value by arginine is 50-55ºC, the stirring speed for adjusting the pH value by arginine is 200-250rpm, and the reaction time for adjusting the pH value by arginine is 8-10min.

[0016] Advantages of the present application: 1) Improved microecological friendliness: By constructing a synergistic system of undecylenoyl complex and APG surface activity, and a three-dimensional microecological repair framework constructed by undecylenoyl complex, yeast zinc ZN100 and HA, malassezia can be effectively inhibited, the growth of scalp beneficial bacteria is promoted, the problem of scalp microecological damage caused by ZPT and OCT shampoo is solved, the malassezia inhibition rate is improved, the scalp barrier integrity is improved through percutaneous water loss test, and the stability of scalp microecology is maintained; by adding ingredients such as yeast zinc ZN100 and HA, a good growth environment is provided for scalp beneficial bacteria, the scalp microecology is more stable, and thus the dandruff problem is fundamentally solved; 2) Mild and efficient cleaning system: the synergistic effect of APG surface activity and undecylenoyl complex makes the cleaning system not only effectively remove scalp grease and dirt, but also not cause excessive cleaning and irritation to the scalp, in addition, the viscosity change of the system is small in 45℃ acceleration experiment, which ensures the stability of the shampoo during storage and use; and ingredients that can repair the scalp barrier, such as pH buffer matrix formed by carbomer U20, are added in the formula, which avoids the damage of excessive cleaning to the scalp barrier; 3) Excellent foaming performance: the synergistic effect of APG surface activity and undecylenoyl complex makes the foaming performance excellent, the foam volume measured by the roche method can reach 380ml, compared with the foam volume of general shampoo which can reach 280ml, the foam volume of the present application is increased by 100ml, which brings rich foam experience to the user and improves the cleaning effect.

[0017] The features and advantages of the present application will be described in detail in conjunction with the embodiments and the accompanying drawings. BRIEF DESCRIPTION OF DRAWINGS

[0018] Figure 1 is a comparison chart of the anti-dandruff effect of the present application and ZPT product; Figure 2 is a scalp microecological detection report after using the present application. DETAILED DESCRIPTION

[0019] The present application is a natural protein shampoo based on APG surface activity system, wherein, The present application is a preparation method of a natural protein shampoo based on APG surface activity system, which comprises the following components by weight: Phase A: C-162: 0.2-0.4 parts; Phase B: JR400: 0.2-0.4 parts; Phase C: Carbomer U20: 0.1-0.4 parts; Phase D: AES: 18-22 parts; CMT-40S: 5-8 parts; Pearl essence: 1-3 parts; Glycerin polyether 26: 0.3-0.7 parts; Glycerin oleate: 0.1-0.3 parts; Polyglyceryl-4 caprate 0.1-0.3 parts; Phase E: Arginine: 0.4-0.6 parts; Phase F: CE7128NB: 0.5-1.5 parts; HA: 1.0-2.0 parts; PQ52: 0.1-0.3 parts; Phenoxyethanol: 0.3-0.8 parts; Ethylhexylglycerin: 0.05-0.20 parts; HFM-710: 0.5-1.5 parts; Zinc yeast ZN100: 1-2 parts; Essence: 0.5-1.2 parts; Phase G: SM-2 pearl paste: 1-3 parts; Sodium chloride: 0.5-0.9 parts; CAB35: 1-3 parts; Phase H: TW-IS399S: 0.4-0.8 parts; The total weight parts of the A phase, B phase, C phase, D phase, E phase, F phase, G phase, H phase are one hundred parts, and the balance is supplemented with water.

[0020] The C-162 includes hydroxypropyl guar hydroxypropyltrimonium chloride and water, the CE7128NB includes dimethicone, water, poloxamer 407, laureth-23, laureth-4, polyethylene glycol-4, xanthan gum, potassium sorbate and sodium benzoate, the HA includes lactobacillus ferment, hydroxypropyltrimonium chloride hyaluronic acid and ginger root extract, and the PQ52 includes polyquaternium-52, laureth-16, phenoxyethanol and water.

[0021] The AES is an anionic surfactant, the CMT-40S is an amino acid type surfactant, the polyglyceryl-4 oleate is a non-ionic surfactant, the polyglyceryl-4 oleate forms a stable emulsified system with oil and fat, and the polyglyceryl-4 oleate synergizes with the CMT-40S and the AES; the undecylenoyl complex is composed of water, undecylenoyl hydrolyzed wheat protein potassium, phenoxy ethanol and ethylhexyl glycerin, the yeast zinc ZN100 is a kind of zinc ion-containing yeast extract; the yeast zinc ZN100 and the HA jointly construct a three-dimensional micro-ecological repair framework, the undecylenoyl complex serves as a basic component of the three-dimensional micro-ecological repair framework, the yeast zinc ZN100 is connected to the undecylenoyl complex, and the HA is filled between the undecylenoyl complex and the yeast zinc; the carbomer U20, sodium chloride and TW-IS399S are thickening agents, the weight ratio of the carbomer U20, sodium chloride and TW-IS399S is 0.3:0.7:0.6, and the viscosity adjustment range is 6000-8000 mPa·s; the carbomer U20 and water form a pH buffer matrix, the amount of the carbomer U20 in the pH buffer matrix is 0.001-0.005 parts, and the amount of water is 48-52 parts; the pH value of the pH buffer matrix ranges from 5.5 to 6.0.

[0022] The application also discloses a preparation method of the natural protein shampoo based on the APG surfactant system. a) water: 3-5 parts; C-162: 0.2-0.4 parts as A phase standby; water: 3-5 parts; JR400: 0.2-0.4 parts as B phase standby; water: 45-50 parts; carbomer U20: 0.1-0.4 parts as C phase standby; AES: 18-22 parts; CMT-40S: 5-8 parts; pearl flake: 1-3 parts; glycerol polyether 26: 0.3-0.7 parts; glycerol oleate: 0.1-0.3 parts; polyglyceryl-4 oleate 0.1-0.3 parts as D phase standby; arginine: 0.4-0.6 parts as E phase standby; CE7128NB; HA; PQ52; phenoxy ethanol; ethylhexyl glycerin; HFM-710; yeast zinc ZN100 and essence as F phase standby; CE7128NB: 0.5-1.5 parts; HA: 1.0-2.0 parts; PQ52: 0.1-0.3 parts; phenoxy ethanol: 0.3-0.8 parts; ethylhexyl glycerin: 0.05-0.20 parts; HFM-710: 0.5-1.5 parts; yeast zinc ZN100: 1-2 parts; essence: 0.5-1.2 parts as G phase standby; TW-IS399S: 0.4-0.8 parts as H phase standby; b) Put C phase into the stirring pot, heat the stirring pot to 80-90ºC to completely dissolve; c) Put D phase into the stirring pot, stir to completely dissolve; d) Put A phase; B phase pre-dispersed into the stirring pot, stir to completely dissolve; e) Turn on the cooling water to cool the materials in the stirring pot to 50-55ºC, then put in E phase arginine, adjust the pH value to 5.5-6.0; f) Continue to cool the materials in the stirring pot to 30-45ºC, then put in F; G phase into the stirring pot, stir to completely uniform; g) Put H phase into the stirring pot, adjust the viscosity to 6000-8000 mPa.s; The total weight parts of the A phase, B phase, C phase, D phase, E phase, F phase, G phase, H phase are one hundred parts, and the balance is made up with water.

[0023] The temperature window for adjusting the pH value of the arginine is 50-55ºC, the stirring speed for adjusting the pH value of the arginine is 200-250 rpm, and the reaction time for adjusting the pH value of the arginine is 8-10 min.

[0024] Example 1: Referring to Figure 1 and Figure 2 , in this embodiment, the formula composition is: A phase: 0.3 parts of C-162; B phase: 0.35 parts of JR400; C phase: 0.3 parts of Carbomer U20; D phase: 20 parts of AES; 7 parts of CMT-40S; 2 parts of pearl flake; 0.5 parts of glyceryl polyether 26; 0.2 parts of glyceryl oleate; 0.2 parts of polyglyceryl-4 oleate; E phase: 0.55 parts of arginine; F phase: 1 part of CE7128NB; 1.5 parts of HA; 0.2 parts of PQ52; 0.6 parts of phenoxyethanol; 0.1 parts of ethylhexylglycerin; 1 part of HFM-710; 1.5 parts of yeast zinc ZN100; 0.8 parts of fragrance; G phase: 2 parts of SM-2 pearl paste; 0.7 parts of sodium chloride; 2 parts of CAB35; H phase: 0.6 parts of TW-IS399S; The total weight parts of the A phase, B phase, C phase, D phase, E phase, F phase, G phase, H phase are one hundred parts, and the balance is made up with water, and 35 parts of undecylenoyl complex is added.

[0025] Preparation method: Prepare each component according to the above formula proportion, 4 parts of water, C-162 as A phase standby; 4 parts of water, JR400 as B phase standby; 48.6 parts of water, carbomer U20 as C phase standby; AES, CMT-40S, pearl essence, glycerol polyether 26, glyceryl oleate and polyglyceryl-4 caprate as D phase standby; arginine as E phase standby; CE7128NB, HA, PQ52, phenoxyethanol, ethylhexylglycerin, HFM-710, mother zinc ZN100 and essence as F phase standby; SM-2 pearl paste, sodium chloride and CAB35 as G phase standby; TW-IS399S as H phase standby; pour C phase into the stirring pot, heat to 85ºC to completely dissolve; pour D phase into the stirring pot to completely dissolve; pre-disperse A phase well, pre-disperse B phase well, then pour into the stirring pot to completely dissolve; open the cooling water to reduce the temperature, react for 8 min, reduce the temperature to 40ºC, pour arginine of E phase, adjust the pH value to 5.8 at the stirring speed of 220 rpm; continue to reduce the temperature of each phase material in the stirring pot to 30ºC, then pour F and G phases into the stirring pot, stir until completely uniform; adjust the viscosity to 7000 mPa.s with H phase material.

[0026] In this example, each raw material is mixed according to a specific ratio and process, and the proportion of each component is balanced. The content of undecylenoyl complex, yeast zinc ZN100 and HA in the formula is relatively high, the anti-dandruff effect is significant, and stubborn dandruff can be quickly and effectively removed; a proper amount of carbomer U20 and water form a pH buffer matrix, providing a stable environment for subsequent reactions; the APG cleaning main system composed of AES and CMT-40S plays a basic cleaning role, removing oil and dirt on the scalp surface; core active ingredients such as HFM-710 and yeast ZN100 synergize with undecylenoyl complex under appropriate temperature and pH conditions to achieve anti-dandruff and microecological repair functions; through precise temperature and pH control, the mildness and stability of the shampoo are ensured, and the irritation to the scalp is reduced. The proportion of all components in this example is relatively balanced, which can effectively remove dandruff, maintain the water-oil balance and microecological stability of the scalp, efficiently remove stubborn dandruff, and is suitable for people with severe dandruff and good scalp tolerance, such as outdoor workers and oily scalp people, etc., which can quickly solve the problem of dandruff and keep the scalp clean.

[0027] Example 2: In this example, the formula composition is: A phase: 0.2 parts of C-162; B phase: 0.3 parts of JR400; C phase: 0.25 parts of carbomer U20; Phase D: 21 parts of AES; 6 parts of CMT-40S; 3 parts of pearl flake; 0.7 parts of glyceryl polyether 26; 0.1 parts of glyceryl oleate; 0.3 parts of polyglyceryl-4 caprate; Phase E: 0.6 parts of arginine; Phase F: 1.5 parts of CE7128NB; 1.0 parts of HA; 0.3 parts of PQ52; 0.7 parts of phenoxyethanol; 0.05 parts of ethylhexylglycerin; 1.5 parts of HFM-710; 1 parts of yeast zinc ZN100; 1 parts of fragrance; Phase G: 1 parts of SM-2 pearl paste; 0.6 parts of sodium chloride; 1.5 parts of CAB35; Phase H: 0.5 parts of TW-IS399S; The total weight parts of the A phase, B phase, C phase, D phase, E phase, F phase, G phase, H phase are one hundred parts, the balance is supplemented with water, and 20 parts of undecylenoyl complex is added.

[0028] Preparation method: prepare each component according to the formula proportion, water 4.5 parts, C-162 as A phase standby; water 4.4 parts, JR400 as B phase standby; water 47 parts, carbomer U20 as C phase standby; AES, CMT-40S, pearl flake, glyceryl polyether 26, glyceryl oleate and polyglyceryl-4 caprate as D phase standby; arginine as E phase standby; CE7128NB, HA, PQ52, phenoxyethanol, ethylhexylglycerin, HFM-710, yeast zinc ZN100 and fragrance as F phase standby; SM-2 pearl paste, sodium chloride and CAB35 as G phase standby; TW-IS399S as H phase standby; put C phase into the stirring pot, heat to 88 degrees to completely dissolve; put D phase into the stirring pot to completely dissolve; pre-disperse A phase, pre-disperse B phase, then put into the stirring pot to completely dissolve; open the cooling water to reduce the temperature to 53 degrees, put in arginine of E phase, adjust the pH value to 5.6 at the stirring speed of 230 rpm, react for 8.5 min; continue to cool to 35ºC, then put F, G phase into the stirring pot, stir until completely uniform; adjust the viscosity to 6500 mPa・s with H phase raw material.

[0029] In this embodiment, the increase of the weight fraction of AES in the formula increases the proportion of anionic surfactants, improves the cleaning ability, and can more thoroughly remove oil and dirt on the scalp surface, while the abundant foam brings a good cleaning experience to the user; the increase of the pearl flake further improves the appearance and texture of the product, making the product more quality-oriented during use; the combination of glycerol, pearl paste, and sodium chloride ensures the basic moisturizing, appearance, and stability of the product, without excessively weakening the anti-dandruff and cleaning effects, so that the product can still meet the basic scalp care needs while being highly effective in anti-dandruff; by reducing the total amount of ingredients other than water, while retaining a certain anti-dandruff ability; in the preparation method, by increasing the temperature and prolonging the reaction time, the activity of the anti-dandruff ingredients is enhanced, and the anti-dandruff effect is improved; higher stirring speed and temperature help to release the potential of anti-dandruff and oil control ingredients, better regulate scalp oil secretion, and efficiently remove scalp oil and dirt, suitable for people with less dandruff, good scalp condition, and only basic anti-dandruff needs.

[0030] Example 3: In this embodiment, the formula composition is as follows: Phase A: 0.15 parts of C-162; Phase B: 0.2 parts of JR400; Phase C: 0.15 parts of Carbomer U20; Phase D: 18 parts of AES; 6 parts of CMT-40S; 3 parts of pearl flake; 0.6 parts of glycerol polyether 26; 0.15 parts of glyceryl oleate; 0.1 parts of polyglyceryl-4 guric acid ester; Phase E: 0.45 parts of arginine; Phase F: 1.3 parts of CE7128NB; 1.2 parts of HA; 0.4 parts of PQ52; 0.7 parts of phenoxyethanol; 0.1 parts of ethylhexylglycerin; 1.2 parts of HFM-710; 1.2 parts of zinc yeast ZN100; 1.3 parts of fragrance; Phase G: 1.5 parts of SM-2 pearl paste; 0.9 parts of sodium chloride; 1 parts of CAB35; Phase H: 0.7 parts of TW-IS399S; The total weight fraction of the A phase, B phase, C phase, D phase, E phase, F phase, G phase, and H phase is one hundred parts, and the balance is made up with water, and 6 parts of undecylenoyl complex are added.

[0031] Preparation method: prepare each component according to the formula proportion, 4.7 parts of water, C-162 as A phase standby; 5 parts of water, JR400 as B phase standby; 50 parts of water, carbomer U20 as C phase standby; AES, CMT-40S, pearl flake, glycerol polyether 26, glyceryl oleate and polyglyceryl-4 caprate as D phase standby; arginine as E phase standby; CE7128NB, HA, PQ52, phenoxyethanol, ethylhexylglycerin, HFM-710, zinc yeast ZN100 and essence as F phase standby; SM-2 pearl paste, sodium chloride and CAB35 as G phase standby; TW-IS399S as H phase standby; C phase is put into the stirring pot, heated to 82 degrees to completely dissolve; D phase is put into stirring to completely dissolve; A phase is pre-dispersed well, B phase is pre-dispersed well, then put into stirring to completely dissolve; open the cooling water to reduce the temperature to 50 degrees, put in arginine of E phase, adjust the pH value to 5.9 at the stirring speed of 200 rpm, react for 9.5 min; continue to cool to 30 DEG C, then F, G phase is put into the stirring pot, stirring to completely uniform; adjust the viscosity to 7500 mPa・s with H phase raw material.

[0032] In this embodiment, the reduction of the weight fraction of AES reduces the amount of anionic surfactive agent, while ensuring a certain cleaning capacity, maximally reducing the irritation to the scalp, making the shampoo more mild, suitable for sensitive scalp; the appropriate change of glycerol ingredients such as the increase of the proportion of glycerol polyether 26 and other ingredients further improves the moisturizing degree of the product, making the hair more soft and smooth after washing, reducing static electricity; in the preparation method, by reducing the temperature and adjusting the pH value, the irritation to the scalp is reduced, and the moisturizing effect is enhanced; lower stirring speed and temperature change help to reduce the risk of allergic reaction, suitable for sensitive scalp, pay attention to scalp care while dandruff removal, improve the overall health of the scalp, further reduce the proportion of ingredients, lower irritation to the scalp, more suitable for extremely sensitive and dry scalp, suitable for people who are highly sensitive to ingredients and prone to allergic reactions.

[0033] The shampoo raw materials and proportions of the embodiments 1-3 of the application are as follows:

[0034]

[0035] Table 1

[0036] The total weight fraction of the A phase, B phase, C phase, D phase, E phase, F phase, G phase, H phase is one hundred parts, and the balance is supplemented with water.

[0037] Working principle: The undecylenoyl complex can bind with specific targets on the cell membrane of Malassezia, destroy the cell wall structure of the bacteria, and cause physiological dysfunction of the bacteria, thereby inhibiting the growth and reproduction of Malassezia and achieving the purpose of removing dandruff; meanwhile, the undecylenoyl complex contains rich nutrients such as amino acids, and has the effect of repairing damaged scalp keratin layer and enhancing the barrier function of the scalp; the APG surfactant such as polyglyceryl-4 guric acid ester has excellent surface activity, can effectively remove sebum and dirt on the scalp, has little irritation to the scalp, and the APG surfactant and the undecylenoyl complex have a synergistic effect; the yeast zinc ZN100 is a yeast extract rich in zinc ions, which can regulate the secretion of sebum on the scalp and inhibit the excessive proliferation of Malassezia; the HA has strong moisturizing properties and biological activity, can nourish the scalp and promote the growth of beneficial bacteria; the undecylenoyl complex, the yeast zinc ZN100 and the HA jointly construct a three-dimensional micro-ecological repair framework, the undecylenoyl complex serves as a basic component, the yeast zinc ZN100 is connected to the undecylenoyl complex, and the HA is filled in the undecylenoyl complex and the yeast zinc ZN100, thereby providing attachment sites and nutrient substances for beneficial bacteria, being conducive to the colonization and growth of beneficial bacteria on the scalp, and maintaining the balance and stability of the scalp micro-ecology.

[0038] The above examples are illustrative of the present application and are not limiting of the present application. Any simple modification of the present application is deemed to fall within the scope of the present application.

Claims

1. A natural protein based shampoo based on APG surfactant system characterized in that: The formula comprises the following components by weight: Phase A: C-162: 0.2-0.4 parts; Phase B: JR400: 0.2-0.4 parts; Phase C: Carbomer U20: 0.1-0.4 parts; Phase D: AES: 18-22 parts; CMT-40S: 5-8 parts; Pearl flake: 1-3 parts; Glycerin polyether 26: 0.3-0.7 parts; Glycerin oleate: 0.1-0.3 parts; Polyglyceryl-4 caprate 0.1-0.3 parts; Phase E: Arginine: 0.4-0.6 parts; Phase F: CE7128NB: 0.5-1.5 parts; HA: 1.0-2.0 parts; PQ52: 0.1-0.3 parts; Phenoxyethanol: 0.3-0.8 parts; Ethylhexylglycerin: 0.05-0.20 parts; HFM-710: 0.5-1.5 parts; Yeast zinc ZN100: 1-2 parts; Essence: 0.5-1.2 parts; Phase G: SM-2 pearl paste: 1-3 parts; Sodium chloride: 0.5-0.9 parts; CAB35: 1-3 parts; Phase H: TW-IS399S: 0.4-0.8 parts; The total weight of the A phase, B phase, C phase, D phase, E phase, F phase, G phase, and H phase is 100 parts, and the balance is made up with water.

2. A natural protein based shampoo as claimed in claim 1 wherein: The C-162 comprises hydroxypropyl guar hydroxypropyltrimonium chloride and water, the CE7128NB comprises dimethicone, water, poloxamer 407, laureth-23, laureth-4, polyethylene glycol-4, xanthan gum, potassium sorbate, and sodium benzoate, the HA comprises lactobacillus ferment, hydroxypropyltrimonium chloride hyaluronic acid, and ginger root extract, and the PQ52 comprises polyquaternium-52, laureth-16, phenoxyethanol, and water.

3. A natural protein based shampoo as claimed in claim 1 wherein: The AES is an anionic surfactant, the CMT-40S is an amino acid surfactant, the polyglyceryl-4 caprate is a nonionic surfactant, the polyglyceryl-4 caprate forms a stable emulsion system with oil and fat, and the polyglyceryl-4 caprate synergizes with the CMT-40S and AES.

4. A natural protein based shampoo as claimed in claim 1 wherein: The undecylenoyl complex is composed of water, undecylenoyl hydrolyzed wheat protein potassium, phenoxyethanol, and ethylhexylglycerin, the yeast zinc ZN100 is a zinc ion-containing yeast extract, the yeast zinc ZN100 and the HA jointly construct a three-dimensional micro-ecological repair framework, the undecylenoyl complex is a basic component of the three-dimensional micro-ecological repair framework, the yeast zinc ZN100 is connected to the undecylenoyl protein, and the HA is filled between the undecylenoyl protein and the yeast zinc.

5. A natural protein based shampoo as claimed in claim 1 wherein: The weight ratio of the yeast zinc ZN100, the HA, and the HFM-710 in the three-dimensional micro-ecological repair framework is 1.5:1.5:

1.

6. A natural protein based shampoo as claimed in claim 1 wherein: The carbomer U20, sodium chloride, and TW-IS399S are thickening agents, the weight ratio of the carbomer U20, sodium chloride, and TW-IS399S is 0.3:0.7:0.6, and the viscosity adjustment range is 6000-8000 mPa·s.

7. The natural protein shampoo based on the APG surfactant system and its preparation method as described in claim 1, characterized in that: The carbomer U20 and water form a pH buffer matrix, the amount of carbomer U20 in the pH buffer matrix is 0.001-0.005 parts, and the amount of water is 48-52 parts; the pH value of the pH buffer matrix is 5.5-6.

0.

8. A process for the preparation of natural protein based shampoo based on APG surfactant system characterized by: It comprises the following steps: a) water: 3-5 parts; C-162: 0.2-0.4 parts as A phase standby; Water: 3-5 parts; JR400: 0.2-0.4 parts as B phase standby; Water: 45-50 parts; Carbomer U20: 0.1-0.4 parts as C phase standby; AES: 18-22 parts; CMT-40S: 5-8 parts; pearlescent sheet: 1-3 parts; glycerol polyether 26: 0.3-0.7 parts; glyceryl oleate: 0.1-0.3 parts; polyglyceryl-4 sunflower acid ester 0.1-0.3 parts as D phase standby; Arginine: 0.4-0.6 parts as E phase standby; CE7128NB; HA; PQ52; phenoxy ethanol; ethyl hexyl glycerol; HFM-710; zinc yeast ZN100 and essence as F phase standby; CE7128NB: 0.5-1.5 parts; HA: 1.0-2.0 parts; PQ52: 0.1-0.3 parts; phenoxy ethanol: 0.3-0.8 parts; ethyl hexyl glycerol: 0.05-0.20 parts; HFM-710: 0.5-1.5 parts; zinc yeast ZN100: 1-2 parts; Essence: 0.5-1.2 parts as G phase standby; TW-IS399S: 0.4-0.8 parts as H phase standby; b) Put C phase into the stirring pot, heat the stirring pot to 80-90ºC to completely dissolve; c) Put D phase into the stirring pot, stir until completely dissolved; d) Put A phase; B phase into the stirring pot after pre-dispersing, stir until completely dissolved; e) Turn on the cooling water to cool the materials in the stirring pot to 50-55ºC, then add E phase arginine, adjust the pH value to 5.5-6.0; f) Continue to cool the materials in the stirring pot to 30-45ºC, then add F; G phase into the stirring pot, stir until completely uniform; g) Add H phase into the stirring pot, adjust the viscosity to 6000-8000 mPa.s; The total weight of A phase, B phase, C phase, D phase, E phase, F phase, G phase and H phase is 100 parts, and the balance is made up with water.

9. A process for the preparation of natural protein based shampoo as claimed in claim 7, wherein the said process comprises the steps of: a) preparing APG surfactant b) mixing APG surfactant with other ingredients c) mixing the APG surfactant with other ingredients to get the final product. The formula includes the following components by weight: A phase: 0.3 parts C-162; B phase: 0.35 parts JR400; C phase: 0.3 parts carbomer U20; D phase: 20 parts AES; 7 parts CMT-40S; 2 parts pearlescent sheet; 0.5 parts glycerol polyether 26; 0.2 parts glyceryl oleate; 0.2 parts polyglyceryl-4 sunflower acid ester; E phase: 0.55 parts arginine; F phase: 1 part CE7128NB; 1.5 parts HA; 0.2 parts PQ52; 0.6 parts phenoxy ethanol; 0.1 parts ethyl hexyl glycerol; 1 parts HFM-710; 1.5 parts zinc yeast ZN100; 0.8 parts essence; G phase: 2 parts SM-2 pearl paste; 0.7 parts of sodium chloride; 2 parts of CAB 35; H Phase A: 0.6 parts of TW-IS 399S; The total weight parts of the A phase, the B phase, the C phase, the D phase, the E phase, the F phase, the G phase and the H phase are one hundred parts, and the balance is supplemented with water.

10. A method for preparing a natural protein shampoo based on an APG surfactant system as described in any one of claims 7 to 9, characterized in that: The temperature window of the arginine for adjusting the pH value in the step e) is 50-55ºC, the stirring speed of the arginine for adjusting the pH value is 200-250 rpm, and the reaction time of the arginine for adjusting the pH value is 8-10 min.

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