High safety solid-state lithium battery based on ion gel interfacial layer

By constructing an ion gel interface layer containing cyclic carbonate-based methacrylate compounds and phosphorus- and fluorine-containing bifunctionalized polyethers inside the electrode core, the problems of wetting and interface adhesion inside the electrode core are solved, thereby improving the stability and safety of high-safety solid-state lithium batteries.

CN122393404APending Publication Date: 2026-07-14ANHUI LIYUAN NEW ENERGY CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ANHUI LIYUAN NEW ENERGY CO LTD
Filing Date
2026-06-05
Publication Date
2026-07-14

AI Technical Summary

Technical Problem

Existing high-safety solid-state lithium batteries have difficulty simultaneously achieving deep wetting of the electrode sheet, in-situ construction of the interface, and continuous adhesion during cycling within the electrode core. This results in micro-gap residue, increased interface impedance, and contact degradation. At the same time, the migration of functional additives leads to performance degradation.

Method used

By employing a molecular-level synergistic design of methacrylate compounds containing cyclic carbonate groups and phosphorus- and fluorine-containing bifunctional polyethers, an ion gel interface layer is constructed inside the electrode core through in-situ crosslinking polymerization. This forms a three-dimensional gel network coupled with hydrogen bond networks and high-dielectric cyclic carbonate groups, achieving conformal coating and dense adhesion of the gel to the active particles.

Benefits of technology

It improves ionic conductivity and interfacial adhesion, reduces interfacial impedance, suppresses lithium dendrite nucleation and blocks thermal runaway, thereby improving the long-term stability and safety of the battery.

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Abstract

The application discloses a high-safety solid-state lithium battery based on an ionic gel interface layer and belongs to the field of solid-state lithium battery preparation, and specifically comprises a pole core, and the positive pole sheet interface, the negative pole sheet interface and the pores of each layer in the pole core are filled with the ionic gel interface layer. The application is synthesized by adding 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide to a double bond to end-capped synthesis of fluorine-containing flame-retardant bifunctional polyether crosslinking agent, and the crosslinking agent is injected into a dry battery together with a cyclic carbonate-based methacrylate compound and an electrolyte. After vacuum infiltration, in-situ thermal polymerization is initiated to build a three-dimensional crosslinking network to lock free electrolyte, form a conformal ionic gel interface layer, and significantly improve the safety performance and long-cycle performance of the solid-state lithium battery.
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