Component and manufacturing process for it

Abstract

Procedure, comprehensive: Formation of a metal gate (60, 62) in a first interlayer dielectric (46); Performing a treatment on the metal gate (60, 62) and the first interlayer dielectric (46) such that selectively a hard mask (66) is grown on the metal gate (60, 62) without growing the hard mask (66) from the first interlayer dielectric (46); Deposition of a second interlayer dielectric (68) over the hard mask (66) and the first interlayer dielectric (46); Planarizing the second interlayer dielectric (68) and the hard mask (66); and Forming a gate contact plug (88) that penetrates the hard mask (66) for electrical coupling to the metal gate (60, 62).

Description

STATE OF THE ART

[0001] When forming metal gates and their corresponding gate plugs for fin field-effect transistors (FinFETs), the metal gates are often recessed, and hard masks are filled into the recesses created by the metal gate recesses. Some portions of the hard masks are then removed to form contact openings through which the metal gates are exposed. The gate plugs are formed for connection to the metal gates.

[0002] Recessing the metal gates results in metal gate loss, requiring the metal gates to be formed higher than their final heights to compensate for the lost height. The increased height of the metal gates causes difficulties in filling the gaps for forming the metal gates. Furthermore, the formation of the hard masks experiences a pattern loading effect during etching of the hard masks, and this pattern loading effect causes some sections of the metal gates to be recessed more than others.

[0003] Methods in which recesses are formed in metal gates are disclosed in US 2013 / 0175619 A1. Further prior art relating to the subject matter of the invention can be found, for example, in US 2013 / 0 320 411 A1, US 2014 / 0 264 478 A1, US 2009 / 0 321 856 A1, US 2013 / 0 277 764 A1, and US 2008 / 0 128 763 A1.

[0004] The invention provides a method according to claim 1, a further method according to claim 8, and a component according to claim 16. Embodiments are specified in the dependent claims. BRIEF DESCRIPTION OF THE DRAWINGS

[0005] Aspects of the present disclosure are best understood from the following detailed description, in conjunction with the accompanying figures. It should be noted that, in accordance with standard industry practice, various features are not drawn to scale. Indeed, the dimensions of various features may be arbitrarily exaggerated or reduced for clarity of discussion. Fig. 1 to 17 are perspective and cross-sectional views of intermediate stages in the formation of a transistor according to some embodiments. Fig. 18 illustrates a process flow for forming a transistor and contact plugs according to some embodiments. DETAILED DESCRIPTION

[0006] The following disclosure provides numerous different embodiments or examples for implementing various features of the invention. Specific examples of components and arrangements are described below to simplify the present disclosure.

[0007] The transistor and methods of forming the same are provided according to various embodiments. The intermediate stages for forming the transistors are illustrated according to some embodiments. Some variations of some embodiments are discussed. Throughout the various views and illustrative embodiments, like reference numerals are used to refer to like elements. In the illustrated exemplary embodiments, the formation of fin field-effect transistors (FinFETs) is used as an example to explain the concept of the present disclosure. Planar transistors may also adopt the concept of the present disclosure.

[0008] Fig. 1 to 17 illustrate the cross-sectional views and perspective views of intermediate stages in the formation of FinFETs according to some embodiments of the present disclosure. The steps described in Fig. 1 to 16 are also shown schematically in the process flow 200 as shown in Fig. 18 shown, reproduced.

[0009] Fig. 1 illustrates a perspective view of an initial structure. The initial structure includes a wafer 10 further including a substrate 20. The substrate 20 may be a semiconductor substrate, which may be a silicon substrate, a silicon germanium substrate, or a substrate formed from other semiconductor materials. The substrate 20 may be doped with an n-type or p-type impurity. Isolation regions 22, such as shallow trench isolation (STI) regions, may be formed extending from a top surface of the substrate 20 into the substrate 20. The portions of the substrate 20 between adjacent STI regions 22 are referred to as semiconductor stripes 24. The top surfaces of the semiconductor stripes 24 and the top surfaces of the STI regions 22 may be substantially flush with each other, according to some example embodiments.According to some embodiments of the present disclosure, the semiconductor stripes 24 are parts of the original substrate 20, and therefore, the material of the semiconductor stripes 24 is the same as that of the substrate 20. According to alternative embodiments of the present disclosure, the semiconductor stripes 24 are replacement stripes formed by etching the portions of the substrate 20 between STI regions 22 to form recesses and performing epitaxy to regrow additional semiconductor material in the recesses. Accordingly, the semiconductor stripes 24 are formed from a semiconductor material that is different from that of the substrate 20. According to some exemplary embodiments, the semiconductor stripes 24 are formed from silicon germanium, silicon carbon, or a III-V compound semiconductor material.

[0010] The STI regions 22 may include a liner oxide (not shown), which may be a thermal oxide formed by thermal oxidation of a surface layer of the substrate 20. The liner oxide may also be a deposited silicon oxide layer formed using, for example, atomic layer deposition (ALD), high-density plasma chemical vapor deposition (HDPCVD), or chemical vapor deposition (CVD). The STI regions 22 may also include a dielectric material over the liner oxide, where the dielectric material may be formed using flowable chemical vapor deposition (FCVD), spin-on coating, or the like.

[0011] With reference to Fig. 2, the STI regions 22 are recessed so that the upper portions of the semiconductor stripes 24 protrude higher than the upper surfaces 22A of the remaining portions of the STI regions 22 to form protruding ridges 24'. The corresponding step is illustrated as step 202 in the process flow 200, as shown in Fig. 18. The etching may be performed using a dry etching process, using HF3 and NH3 as the etching gases. Plasma may be generated during the etching process. Argon may also be included. According to alternative embodiments of the present disclosure, the recessing of the STI regions 22 is performed using a wet etching process. The etching chemical may include, for example, HF.

[0012] With reference to Fig. 3, a dummy gate stack 30 is formed on the top surfaces and sidewalls of the (protruding) fins 24'. The corresponding step is shown as step 204 in the process flow 200, as shown in Fig. 18. The dummy gate stacks 30 may include dummy gate dielectrics 32 and dummy gate electrodes 34 over the dummy gate dielectrics 32. The dummy gate electrodes 34 may be formed using polysilicon, for example, and other materials may also be used. Each of the dummy gate stacks 30 may also include one (or more) hard mask layers 36 over the dummy gate electrodes 34. The hard mask layers 36 may be formed of silicon nitride, silicon oxide, silicon carbonitride, or multiple layers thereof. The dummy gate stacks 30 may traverse a single or multiple raised fins 24' and / or STI regions 22. The dummy gate stacks 30 also have longitudinal directions that are perpendicular to the longitudinal directions of the protruding ridges 24'.

[0013] Next, gate spacers 38 are formed on the sidewalls of the dummy gate stacks 30. According to some embodiments of the present disclosure, the gate spacers 38 are formed from a dielectric material, such as silicon nitride, silicon carbonitride, or the like, and may have a single-layer structure or a multi-layer structure with multiple dielectric layers. According to some embodiments of the present disclosure, the gate spacers 38 are free of oxygen atoms therein.

[0014] An etching step (hereinafter referred to as source / drain recessing) is then performed to etch the portions of the protruding fins 24' that are not covered by the dummy gate stack 30 and the gate spacers 38, resulting in the structure shown in Fig. 4. The recessing may be anisotropic, and therefore the portions of the fins 24' directly beneath the dummy gate stacks 30 and gate spacers 38 are protected and not etched. The upper surfaces of the recessed semiconductor strips 24 may, according to some embodiments, be lower than the upper surfaces 22A of the STI regions 22. Recesses 40 are accordingly formed between the STI regions 22. The recesses 40 are located on opposite sides of the dummy gate stacks 30.

[0015] Next, epitaxial regions (source / drain regions) 42 are formed by selectively growing a semiconductor material in the recesses 40, which forms the structure in Fig. 5A. The corresponding step is shown as step 206 in process flow 200, as shown in Fig. 18. According to some example embodiments, the epitaxial regions 42 contain silicon germanium or silicon. Depending on whether the resulting FinFET is an n-type FinFET or a p-type FinFET, a p-type or n-type impurity may be doped in situ during epitaxy. For example, if the resulting FinFET is a p-type FinFET, silicon germanium boron (SiGeB) may be grown. Conversely, if the resulting FinFET is an n-type FinFET, silicon phosphorus(III) (SiP) or silicon carbon phosphorus(III) (SiCP) may be grown. According to alternative embodiments of the present disclosure, the epitaxial regions 42 are formed from a III-V compound semiconductor, such as GaAs, InP, GaN, InGaAs, InAlAs, GaSb, AlSb, AlAs, AlP, GaP, combinations thereof, or multilayers thereof.After the epitaxial regions 42 have completely filled the recesses 40, the epitaxial regions 42 begin to expand horizontally and facets can be formed.

[0016] After the epitaxial growth step, the epitaxial regions 42 may be further implanted with an n-type or p-type impurity to form source and drain regions, also designated using reference numeral 42. According to alternative embodiments of the present disclosure, the implantation step is skipped if the epitaxial regions 42 are doped in situ with the p-type or n-type impurity during epitaxial growth to form the source / drain regions. The epitaxial source / drain regions 42 include lower portions formed within the STI regions 22 and upper portions formed over the upper surfaces of the STI regions 22.

[0017] Fig. 5B illustrates the formation of the source / drain regions 42 according to alternative embodiments of the present disclosure. According to these embodiments, the protruding fins 24', as shown in Fig. 3, and epitaxial regions 41 are grown on the protruding ridges 24'. The material of the epitaxial regions 41 may be similar to the material of the epitaxial semiconductor material 42, as shown in Fig. 5A, depending on whether the resulting FinFET is a p-type FinFET or an n-type FinFET. Accordingly, the source / drains 42 include protruding fins 24' and the epitaxial region 41. An implantation may be performed to implant an n-type impurity or a p-type impurity.

[0018] Fig. 6 illustrates a perspective view of the structure after the formation of a contact etch stop layer (CESL) 47 and an inter-layer dielectric (ILD) 46. The corresponding step is illustrated as step 208 in the process flow 200, as shown in Fig. 18. The CESL 47 may be omitted according to some embodiments, and when formed, it may be formed from silicon nitride, silicon carbonitride, or the like. According to some embodiments of the present disclosure, the CESL 47 is free of oxygen therein. The CESL 47 may be formed using a conformal deposition process, such as, for example, ALD or CVD. The ILD 46 may include a dielectric material formed using, for example, FCVD, spin-on coating, CVD, or another deposition process. The ILD 46 may also be formed from an oxygen-containing dielectric material, which may be silicon-based, such as tetraethyl orthosilicate (TEOS) oxide, plasma-enhanced CVD (PECVD) oxide (SiO2), phosphosilicate glass (PSG), borosilicate glass (BSG), boron-doped phosphosilicate glass (BPSG), or the like.A planarization step, such as chemical mechanical polishing (CMP) or mechanical grinding, may be performed to align the top surfaces of the ILD 46, the dummy gate stack 30, and the gate spacers 38.

[0019] A cross-sectional view of the structure shown in Fig. 6 is shown in Fig. 7, where the cross-sectional view is obtained from the vertical plane which is the line AA in Fig. 6 contains.

[0020] Next, the dummy gate stacks 30 containing the hard mask layers 36, the dummy gate electrodes 34, and the dummy gate dielectrics 32 are replaced by replacement gate stacks containing metal gates and replacement gate dielectrics, as shown in Fig. 8 and Fig. 9. The cross-sectional views shown in Fig. 8 and Fig. 9, and the subsequent cross-sectional views are taken from the same vertical plane, which is the line AA in Fig. 6. In the cross-sectional view, the heights of the upper surfaces 22A of the STI regions 22 are shown, and the semiconductor fins 24' are above the upper surfaces 22A.

[0021] When forming the replacement gate stacks, the hard mask layers 36, the dummy gate electrodes 34 and the dummy gate dielectrics 32 are formed as shown in Fig. 7, first removed in one or more etching steps, resulting in trenches / openings 48, as shown in Fig. 8 which are to be formed. The corresponding step is shown as step 210 in the process flow 200, as shown in Fig. 18. The upper surfaces and side surfaces of the protruding semiconductor fins 24' are exposed to the trenches 48.

[0022] Next, with reference to Fig. 9, (exchange) gate dielectric layers 52 are formed, which are inserted into the trenches 48 ( Fig. 8). According to some embodiments of the present disclosure, the gate dielectric layer 52 includes an interfacial layer (IL) 54 as its lower portion. The IL 54 is formed on the exposed surfaces of the protruding fins 24'. The IL 54 may include an oxide layer, such as a silicon oxide layer formed by the thermal oxidation of the protruding fins 24', a chemical oxidation process, or a deposition process. The gate dielectric layer 52 may further include a high-k dielectric layer 56 formed over the IL 54. The high-k dielectric layer 56 includes a high-k dielectric material, such as hafnium oxide, lanthanum oxide, aluminum oxide, zirconium oxide, silicon nitride, or the like. The dielectric constant (k value) of the high-k dielectric material is higher than 3.9 and may be higher than approximately 7.0.The high-k dielectric layer 56 may contain oxygen if it is very thin, or it may also be oxygen-free. The high-k dielectric layer 56 overlies and may contact the IL 54. The high-k dielectric layer 56 is formed as a conformal layer and extends on the sidewalls of the protruding fins 24' and the sidewalls of the gate spacers 38. According to some embodiments of the present disclosure, the high-k dielectric layer 56 is formed using ALD or CVD.

[0023] With further reference to Fig. 9, stacked layers 58 are deposited. The sublayers in the stacked layers 58 are not shown separately, while the sublayers are in fact distinguishable from one another. The deposition can be carried out using a conformal deposition process, such as ALD or CVD, such that the thickness of the vertical sections and the thickness of the horizontal sections of the stacked layers 58 (and each of the sublayers) are substantially equal to one another. The deposited gate dielectric layers 52 and stacked layers 58 extend into the trenches 48 ( Fig. 8) and contain some sections above ILD 46.

[0024] The stacked layers 58 may include a diffusion barrier layer and one (or more) work function layers above the diffusion barrier layer. The diffusion barrier layer may be formed of titanium nitride (TiN), which may or may not be doped with silicon. The work function layer determines the work function of the gate and includes at least one or more layers formed of different materials. The material of the work function layer is selected depending on whether the particular FinFET is an n-type FinFET or a p-type FinFET. For example, if the FinFET is an n-type FinFET, the work function layer may include a TaN layer and a titanium aluminum (TiAl) layer above the TaN layer. If the FinFET is a p-type FinFET, the work function layer may include a TaN layer, a TiN layer above the TaN layer, and a TiAl layer above the TiN layer.After the deposition of the work function layer(s), a barrier layer, which can be another TiN layer, is formed.

[0025] Next, a metal material 60 is deposited, which may be formed of tungsten or cobalt, for example. The metal material 60 fills the remaining trenches 48 ( Fig. 8) completely. In a subsequent step, as in Fig. As shown in Figure 9, a planarization step, such as CMP or mechanical grinding, is performed so that the portions of layers 56, 58, and 60 above the ILD 46 are removed. As a result, metal gate electrodes 62 are formed that include the remaining portions of layers 58 and 60. The remaining portion of layers 52, 58, and 60 are referred to below as replacement gate stack 64. As shown in Fig. 9, the top surfaces of the metal gates 62, gate spacers 38, CESL 47, and ILD 46 may be substantially coplanar at this time.

[0026] Fig. 10 to 12A illustrate the formation of self-aligned hard masks according to some embodiments. The material of the ILD 46 differs from that of the CESL 47, gate spacers 38, and gate electrodes 68. For example, the ILD 46 may be an oxygen-containing dielectric, such as an oxide, while the CESL 47, gate spacers 38, and gate electrodes 62 are oxygen-free. Accordingly, in Fig. 10 to 12A, the surfaces of the ILD 46, the CESL 47, gate spacers 38 and gate electrodes 62 are treated to enable the subsequent selective deposition of the hard masks.

[0027] With reference to Fig. 10, a pretreatment is carried out, for example using an acid, which may be a dilute hydrofluoride (HF) solution. The corresponding step is shown as step 212 in process flow 200, as shown in Fig. 18. The pretreatment is schematically illustrated using arrows 65. The pretreatment can also be carried out using a mixed gas of NH3 (ammonia) and HF3.

[0028] According to some embodiments, the pretreatment includes an etching action that causes the recessing of the ILD 46. The recess depth D1 may range between approximately 10 nm and approximately 50 nm. Accordingly, the sidewalls of the CESL 47 (or, if no CESL is formed, the sidewalls of the gate spacers 38) are exposed.

[0029] Next, the wafer 10 is further processed, and the connections created (during pretreatment) on the surface of the ILD 46 are completed to create an inhibitor film 63, as shown in Fig. 11. The corresponding step is shown as step 214 in the process flow 200, as shown in Fig. 18. For example, the treatment to generate some hydrophobic compounds with the oxygen atoms may be performed in the ILD 46. The compounds that attach to the oxygen atoms may include Si(CH3)3 according to some embodiments. The respective process for attaching the compounds may include a silylation process, wherein a respective process gas may include bis(trimethylsilyl)amine, hexamethyldisilazane (HMDS), tetramethyldisilazane (TMDS), trimethylchlorosilane (TMCS), dimethyldichlorosilane (DMDCS), methyltrichlorosilane (MTCS), or the like. According to other embodiments, because the material of the ILD 46 differs from that of the CESL 47, the gate spacers 38, and the gate electrodes 62, a thin organic film (also shown as thin film 63) may be selectively deposited on the ILD 46, but not on the exposed surfaces of the ILD 46, the gate spacers 38, and the gate electrodes 62.Accordingly, either by completing interconnections or by selective deposition, the property of the surface of the ILD 46 is changed to be different from that of the CESL 47, the gate spacers 38 and the gate electrodes 62.

[0030] Next, as in Fig. 12A, self-aligned hard masks 66 are selectively deposited on the replacement gate stacks 64. The corresponding step is shown as step 216 in the process flow 200, as shown in Fig. 18. The hard masks 66 are referred to as self-aligned hard masks because they are self-aligned to the positions of the CESL 47, the gate spacers 38, and the gate electrodes 62. The hard masks 66 are formed of a dielectric material such as silicon nitride, silicon carbonitride, or the like. During deposition, since the surface of the ILD 46 has been changed, it is difficult for nucleation to occur, and therefore the hard masks 66 are not formed starting from the ILD 46. Instead, the hard masks 66 are deposited on the surfaces of the CESL 47, the gate spacers 38, and the gate electrodes 62. The portions of the hard masks 66 directly above the gate electrodes 62 are grown primarily upward, and the portions of the hard masks 66 grown from the sidewalls of the CESL 47 (or the gate spacers 38 if the CESL 47 is not formed) are grown primarily horizontally.

[0031] In embodiments where the gate dielectrics 56 contain oxygen, the hard masks 66 may or may not grow from the top surfaces of the gate dielectrics 56, depending on the composition of the gate dielectrics 56. However, because the gate dielectrics 56 are thin and the exposed surfaces of the gate dielectrics 56 are narrow, even if the hard masks 66 cannot be grown well starting from the gate dielectrics 56, the portions of the hard masks 66 grown from the gate spacers 38 and the gate electrodes 62 merge into one another to form bulk hard masks 66.According to some embodiments, defects (not shown) may (or may not) be formed in regions 67A and / or 67B due to weak growth in these regions, and the defects may, according to some example embodiments, cause the hard masks 66 to be slightly physically separated from the ILD 46 and / or the gate dielectrics 56.

[0032] Fig. 12B shows a perspective view of the wafer 10 as shown in Fig. 12A. Fig. Figure 12B illustrates that the hard masks 66 form long stripes covering the gate electrodes 62, the gate spacers 38, and the CESL 47. As shown in Fig. 12A, the hard masks 66 extend laterally beyond the outer edges of the CESL 47, and therefore, the hard masks 66 may have a width W2 that is greater than the distance W1 between the outer edges of the adjacent vertical sections of the CESL 47. The hard masks 66 further have rounded (curved) sidewalls and top surfaces. According to some embodiments of the present disclosure, the thickness T1 of the hard masks 66 is greater than about 10 nm, and the thickness T1 may range between about 10 nm and about 199 nm.

[0033] After the formation of the hard mask 66, a post-treatment is performed to improve the film quality of the hard masks 66. According to some exemplary embodiments, the post-treatment is performed by rapid thermal annealing (RTA) at a temperature between approximately 800°C and approximately 1200°C. According to alternative embodiments, the post-treatment is performed by plasma treatment, wherein the process gas includes, for example, N2, H2, Ar, He, and / or the like. The post-treatment removes the dangling bonds of the hard masks 66, making them less porous and more resistant to subsequent cleaning processes.

[0034] Depending on the post-treatment method and the composition of the inhibitor film 63, the post-treatment may or may not result in the removal of the inhibitor film 63. If the inhibitor film 63 is not removed as a result of the post-treatment, an additional process to remove the inhibitor film 63 is performed after the formation of the hard masks 66 and before or after the post-treatment to enable the deposition of the overlying ILD. According to some embodiments, the inhibitor film 63 is removed in an etching gas or etching solution, depending on the type of inhibitor film. According to alternative embodiments, the inhibitor film 63 is removed using plasma, which may have a low bombardment effect.

[0035] Next, as in Fig. 13, the ILD 68 is formed. The corresponding step is shown as step 218 in the process flow 200, as shown in Fig. 18. The ILD 68 may be formed using a material selected from the same group of candidate materials as the ILD 46, and the material of the ILD 68 may be the same as or different from the material of the ILD 46. The ILD 68 has a top surface that is higher than the top surfaces of the hard masks 66 so that the hard masks 66 are recessed into the ILD 68. There may or may not be a visible interface between the ILD 46 and the ILD 68.

[0036] Fig. 14A and Fig. 14B illustrate a cross-sectional view and a perspective view, respectively, of the wafer 10 after a planarization step, which may be performed using CMP or mechanical grinding. Fig. Figure 14B illustrates a perspective view of the wafer 10 as shown in Fig. 14A. The corresponding step is shown as step 220 in the process flow 200, as shown in Fig. 18. As a result of the planarization step, the top surfaces of the hard masks 66 are planarized and coplanar with the top surfaces of the ILD 68. The remaining hard masks 66 still have curved sidewalls in contact with the ILD 68.

[0037] After planarization, an additional post-treatment may be performed to further improve the film quality of the hard masks 66. The additional post-treatment has the same function as the previous post-treatment performed before the formation of the ILD 68 and can remove the newly exposed dangling bonds of the hard masks 66 that were exposed as a result of planarization, and further makes the hard masks 66 less porous and more resistant to subsequent cleaning processes. The additional post-treatment may be performed using a method selected from the same group of candidate materials and methods as the previous treatment.

[0038] Fig. 15 to 17 illustrate the formation of gate / source contact plugs and gate contact plugs. In the illustrative example embodiments, three source / drain regions 42 are shown, and the illustrated process shows the formation of one source / drain contact plug connected to the leftmost source / drain region 42. In the actual process, source / drain contact plugs are also formed for connecting to the middle and rightmost source / drain regions 42. However, these source / drain contact plugs are formed at different levels than illustrated and are therefore not shown in the illustrated plane. Likewise, although a gate contact plug is shown as being formed directly above the replacement gate stack 64 on the right side of the figures, a gate contact plug may also be formed directly above the left gate stack 64, which is in a different plane than illustrated and is therefore not shown.

[0039] Fig. 15 illustrates the formation of a source / drain silicide region 70, metal layer 72, conductive barrier layer 74, and metal region 76. The corresponding step is illustrated as step 222 in process flow 200, as shown in Fig. 18. According to some embodiments, the metal layer 72 (e.g., a titanium layer) is deposited as a cap layer, followed by a nitriding process on the upper portion of the metal layer 72 to form a metal nitride layer (74, for example). The lower portion of the metal layer 72 is not nitrided. Next, annealing (which may be accelerated thermal annealing) is performed to react the metal layer 72 with the upper portion of the source / drain regions 42 to form the silicide region 70. The portions of the metal layer 72 on the sidewalls of the ILD 46 are not reacted.Next, either the previously formed metal nitride layer 74 is left as the illustrated conductive barrier 74, or the previously formed metal nitride layer 74 is removed, followed by the deposition of a new metal nitride layer (such as titanium nitride, also illustrated by reference numeral 74) that is thinner than the removed metal nitride layer. The metal region 76 is then formed, for example, by filling with tungsten, cobalt, or the like, followed by a panning process to remove excess materials, resulting in the lower source / drain contact plug 78.

[0040] With reference to Fig. 16, an etch stop layer 80 is formed according to some embodiments of the present disclosure. According to some embodiments, the etch stop layer 80 is formed from SiN, SiCN, SiC, SiOCN, or another dielectric material. The thickness of the etch stop layer 80 may range between approximately 2 nm and approximately 4 nm. The formation method may include PECVD, ALD, CVD, or the like. Next, an ILD 82 is formed over the etch stop layer 80. The material of the ILD 82 may be selected from the same candidate materials (and methods) for forming the ILD 46 and ILD 58, and the ILDs 46, 68, and 82 may be formed from the same or different dielectric materials. According to some embodiments, the ILD 82 is formed using PECVD, FCVD, spin-on coating, or the like and may include silicon oxide (SiO2).The strength of the ILD 82 can range between approximately 700 Å and approximately 800 Å.

[0041] The ILD 82 and the etch stop layer 82 are etched to form openings 83 and 84. The etching can be carried out, for example, using reactive ion etching (RIE). In a subsequent step, as shown in Fig. 17, connectors / vias 86 and 88 are formed. The corresponding step is shown as step 224 in the process flow 200, as shown in Fig.18. According to some embodiments of the present disclosure, plugs / vias 86 and 88 include barrier layers 90 and metal-containing material 92 over the barrier layers. According to some embodiments of the present disclosure, forming plugs / vias 86 and 88 includes forming a cap barrier layer 90 and a metal-containing material 92 over the cap barrier layer and performing planarization to remove excess portions of the cap barrier layer and metal-containing material. Barrier layer 90 may be formed from a metal nitride, such as titanium nitride or tantalum nitride. Metal-containing material 92 may be formed from tungsten, cobalt, copper, or the like.

[0042] In the final FinFET 100, the gate contact plug 88 penetrates the respective hard mask 66, with the remaining hard mask 66 having portions opposite the gate contact plug 88. The hard masks 66 extend laterally beyond the respective replacement gates 64 and CESL 47 and have curved sidewalls (which may be rounded) in contact with the ILD 68.

[0043] The embodiments of the present disclosure have several advantageous features. By forming the hard mask using selective deposition on the metal gates, rather than recessing the metal gates and then forming the hard mask in the recesses, the metal gates do not have to consider the height loss during recessing and can be formed at a lower height. Gap filling during metal gate formation is therefore easier. The pattern loading effect during metal gate recessing, which causes the final metal gates to have different heights, is also eliminated.

Claims

[1] Method comprising: Forming a metal gate (60, 62) in a first interlayer dielectric (46); Applying a treatment to the metal gate (60, 62) and the first interlayer dielectric (46) such that selectively growing a hard mask (66) on the metal gate (60, 62) without growing the hard mask (66) from the first interlayer dielectric (46); depositing a second interlayer dielectric (68) over the hard mask (66) and the first interlayer dielectric (46); Planarizing the second interlayer dielectric (68) and the hard mask (66); and Forming a gate contact plug (88) penetrating the hard mask (66) for electrical coupling to the metal gate (60, 62). [2] The method of claim 1, wherein a gate spacer (38) is present on a sidewall of the metal gate (60, 62) and a vertical portion of a contact etch stop layer (47) is present on a sidewall of the gate spacer (38), and wherein the hard mask (66) is further grown from a sidewall of the vertical portion of the contact etch stop layer (47). [3] The method of claim 1 or 2, wherein the hard mask (66) is grown to have a curved sidewall and a curved top surface. [4] A method according to any one of the preceding claims, wherein the treatment comprises: Pretreating the metal gate (60, 62) and the first interlayer dielectric (46) with an acid; and Forming an inhibitor film (63) on an exposed surface of the first interlayer dielectric (46) without forming the inhibitor film (63) on the metal gate (60, 62). [5] The method of any preceding claim, further comprising, after selectively growing the hard mask (66), performing a post-treatment on the hard mask (66). [6] The method of claim 5, wherein the post-treatment comprises thermal annealing. [7] The method of any preceding claim, further comprising, after the second interlayer dielectric (68) and the hard mask (66) have been planarized, performing an additional post-treatment on the hard mask (66). [8] Method comprising: Forming a metal gate (60, 62) in a first interlayer dielectric (46); recessing the first interlayer dielectric (46) such that a top surface of the first interlayer dielectric (46) is lower than a top surface of the metal gate (60, 62); selectively growing a hard mask (66) on the metal gate (60, 62), the hard mask (66) including a top portion grown upward and a sidewall portion grown horizontally, without growing the hard mask (66) from the first interlayer dielectric (46); depositing a second interlayer dielectric (68) over the hard mask (66) and the first interlayer dielectric (46); Planarizing the hard mask (66), leaving a bottom portion of the hard mask (66) to cover the metal gate (60, 62); and Forming a gate contact plug (88) penetrating the second interlayer dielectric (68) for electrical coupling to the metal gate (60, 62). [9] The method of claim 8, wherein the gate contact plug (88) further penetrates the hard mask (66), the hard mask (66) including a portion remaining on one side of the gate contact plug (88). [10] The method of claim 8 or 9, wherein a gate spacer (38) is located on a sidewall of the metal gate (60, 62), and wherein the sidewall portion of the hard mask (66) is grown from a sidewall of the gate spacer (38). [11] The method of any one of claims 8 to 10, wherein the hard mask (66) is grown to have a curved sidewall and a curved top surface. [12] A method according to any one of claims 8 to 11, further comprising: Pretreating the metal gate (60, 62) and the first interlayer dielectric (46) with an acid; and Forming an inhibitor film (63) on the first interlayer dielectric (46) without forming the inhibitor film (63) on the metal gate (60, 62). [13] The method of any one of the preceding claims 8 to 12, further comprising, after selectively growing the hard mask (66), performing a post-treatment on the hard mask (66). [14] The method of claim 13, wherein the post-treatment comprises thermal annealing. [15] A method according to any one of claims 13 or 14, wherein the post-treatment comprises a plasma treatment. [16] A component manufactured by a method according to any one of the preceding claims, comprising: a first interlayer dielectric (46); a gate stack (64) comprising a metal gate (60, 62) in the first interlayer dielectric (46); a hard mask (66) comprising a first portion covering the gate stack (64) and a second portion covering a first portion of the first interlayer dielectric (46), wherein a top surface of the first interlayer dielectric (46) is lower than a top surface of the gate stack (64), and wherein the second portion of the hard mask (66) is lower than the top surface of the gate stack (64); a second interlayer dielectric (68) having a sidewall contacting a sidewall of the hard mask (66), the second interlayer dielectric (68) covering a second portion of the first interlayer dielectric (46); and a gate contact plug (88) penetrating the hard mask (66) to contact the gate stack (64). [17] The device of claim 16, wherein the side wall of the hard mask (66) is curved. [18] The device of claim 16 or 17, wherein the gate stack (64) comprises a gate dielectric (52) having a vertical portion, and the device further comprises a defect (67A) at a top surface of the vertical portion of the gate dielectric (52). [19] The device of any one of claims 16 to 18, further comprising a contact etch stop layer (47) having a bottom portion covered by the first interlayer dielectric (46) and a vertical portion having a sidewall contacting the first interlayer dielectric (46), wherein the second portion of the hard mask (66) further contacts the sidewall of the vertical portion of the contact etch stop layer (47).

Images