Aqueous oxidizing compositions containing amino acids

Abstract

The present invention relates to aqueous oxidizing compositions containing amino acids that reduce hair damage during chemical service. It has been found that the effectiveness of reducing hair damage is further improved by adding polycarboxylic acids to bleaching powder compositions, oxidative dye compositions, and permanent wave compositions.

Description

[Technical Field]

[0001] The present invention relates to an aqueous oxidizing composition containing an amino acid, which is useful as a second composition. Additionally, a two-part bleaching and oxidative dyeing composition and method is disclosed, wherein the first composition further comprises a polycarboxylic acid. A kit of parts containing the composition of the present invention is also disclosed. [Background technology]

[0002] Aqueous compositions containing hydrogen peroxide are well known in the art. These compositions are essential components in many industrial and technical processes. For example, bleaching or dyeing solid substrates requires the presence of an oxidizing composition. In particular, the paper, wool, and cosmetic industries rely on the performance of these compositions.

[0003] However, because application of oxidizing compositions to biological materials results in chemical damage, there is a growing trend to reduce the amount of damage caused to the materials.

[0004] A series of patent applications (US Pat. Nos. 5,629,139, 5,629,140, ​​5,629,150) disclose methods claiming the benefits of the combined use of bismaleate-based binders in chemical hair treatments, such as oxidative hair dyeing, permanent shaping, and bleaching, for improving hair structure, but these publications do not address the core of the present invention.

[0005] Furthermore, the application of polycarboxylic acids and amino acids in bleaching powders is known from US Pat. No. 5,623,999. In any case, the document does not address the core of the present invention. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] US Patent Application Publication No. 2015 / 0034119 [Patent Document 2] US Patent Application Publication No. 2015 / 0037270 [Patent Document 3] International Publication No. 2015 / 017768 [Patent Document 4] International Publication No. 2018 / 085478 Summary of the Invention

[0007] Therefore, the first object of the present invention is to a) hydrogen peroxide; b) one or more amino acids with a molar mass of less than or equal to 120 g / mol and / or their salts and / or mixtures thereof, and aqueous oxidizing composition B having a pH in the range of 1 to 6, comprising:

[0008] The second object of the present invention is to - the below described: c) one or more persalts and / or peroxy salts; d) one or more alkalizing agents; e) one or more polycarboxylic acids and / or salts thereof a first bleaching powder composition A comprising: - a second aqueous oxidizing composition B as defined above, A two-part bleaching composition comprising:

[0009] The third object of the present invention is to - a dyeing composition C having a pH ranging from 7 to 12 and comprising one or more oxidation dye precursors and / or oxidation dye couplers, and one or more alkalizing agents; - a second aqueous oxidizing composition B as defined above, A two-component oxidation dye composition comprising:

[0010] A fourth object of the present invention is to provide an aqueous oxidizing composition B as defined above, a bleaching powder composition A as defined above, an oxidation dye composition C having a pH ranging from 7 to 12 and comprising one or more oxidation dye precursors and / or oxidation dye couplers, and one or more alkalizing agents, - an aqueous permanent wave composition D having a pH in the range of 7 to 12 and comprising one or more reducing agents and one or more alkalizing agents; and another composition selected from It is a kit of parts including:

[0011] A fifth object of the present invention is a method for bleaching and / or oxidative dyeing keratinous fibers, preferably human keratinous fibers, more preferably human hair, comprising: i) providing a bleaching powder composition A as defined above and a second aqueous oxidizing composition B as defined above; ii) optionally providing an oxidative dye composition C as defined above; iii) mixing the two compositions of step i) optionally together with a third oxidation dyeing composition C to produce a ready-to-use composition having a pH in the range of 7 to 12; iv) applying the ready-to-use mixture to the keratin fibers and leaving it for 1 minute to 60 minutes; v) rinsing the keratinous fibers and optionally shampooing the keratinous fibers; The method includes:

[0012] A sixth object of the present invention is a method for oxidative dyeing of keratinous fibers, preferably human keratinous fibers, more preferably human hair, comprising: vi) providing an oxidation dye composition C as defined above and a second aqueous oxidizing composition B as defined above; vii) mixing the two compositions of step vi) to produce a ready-to-use composition having a pH in the range of 7 to 12; viii) applying the ready-to-use mixture to the keratin fibers and leaving it for 1 minute to 60 minutes; ix) rinsing the keratinous fibers and optionally shampooing the keratinous fibers; The method includes:

[0013] A seventh object of the present invention is a method for permanently shaping keratinous fibers, preferably human keratinous fibers, more preferably human hair, comprising: x) optionally washing the keratin fibers with shampoo; xi) placing the keratin fibers under mechanical tension; xii) applying an aqueous permanent wave composition D as defined above to the keratinous fibers and leaving the composition for a period ranging from 1 minute to 60 minutes; xiii) optionally rinsing the composition; xiv) preparing an aqueous oxidizing composition B as defined above, applying it to the keratin fibers and leaving it for a period ranging from 1 minute to 30 minutes; xv) releasing the mechanical tension from the keratin fibers; xvi) rinsing the keratin fibers and optionally shampooing the keratin fibers; Including, provided that steps xi) and xii) and steps xv) and xvi) may be performed in any order. Detailed Description of the Invention

[0014] The inventors of the present invention have unexpectedly discovered that adding amino acids to aqueous oxidizing compositions reduces damage to keratin fibers. Thus, the cosmetic properties of keratin fibers, such as feel, texture, gloss, and color uniformity, as well as bleaching power, are improved. It has also been found that the effect can be improved by adding polycarboxylic acids to secondary compositions, such as bleaching powders, oxidation dye compositions, and perm compositions.

[0015] [Aqueous oxidizing composition] The present invention provides a) hydrogen peroxide; b) one or more amino acids with a molar mass of less than or equal to 120 g / mol and / or their salts and / or mixtures thereof, and an aqueous oxidizing composition B having a pH in the range of 1 to 6, comprising:

[0016] The total concentration of the compounds a) is preferably 1% by weight or more, more preferably 2% by weight or more, and even more preferably 3% by weight or more, calculated relative to the total weight of the aqueous oxidizing composition B, in terms of bleaching / dyeing / perming performance after mixing with the first composition. The total concentration of the compounds a) is preferably 20% by weight or less, more preferably 15% by weight or less, and even more preferably 12% by weight or less, calculated based on the total weight of the aqueous oxidizing composition B, from the viewpoints of bleaching / dyeing / perming performance after mixing with the first composition and cosmetic safety. To achieve the above-mentioned effects, the total concentration of the compounds a) is preferably in the range of 1% by weight to 20% by weight, more preferably in the range of 2% by weight to 15% by weight, and even more preferably in the range of 3% by weight to 12% by weight, calculated relative to the total weight of the aqueous oxidizing composition B.

[0017] From the viewpoint of cosmetic safety, the one or more amino acids as the compound b) are preferably selected from alanine, glycine, arginine, histidine, lysine, aspartic acid, glutamic acid, serine, threonine, proline, valine, isoleucine, leucine, phenylalanine, tyrosine, tryptophan, and / or salts thereof, and / or mixtures thereof.

[0018] The one or more compounds of b) preferably have a molar mass of less than or equal to 120 g / mol, from the viewpoint of hair penetration, and preferably the compounds are selected from alanine and / or glycine, and / or salts thereof, and / or mixtures thereof.

[0019] From the viewpoint of hair damage, the total concentration of the compounds in b) is preferably 0.01% by weight or more, more preferably 0.03% by weight or more, and even more preferably 0.05% by weight or more, calculated relative to the total weight of composition B. The total concentration of the compounds in b) is preferably 0.7% by weight or less, more preferably 0.5% by weight or less, and even more preferably 0.5% by weight or less, calculated relative to the total weight of composition B, from the viewpoint of hair damage and economical reasons. To achieve the above-mentioned effects, the total concentration of the compound b) is preferably in the range of 0.01% by weight to 0.7% by weight, more preferably in the range of 0.03% by weight to 0.5% by weight, and even more preferably in the range of 0.05% by weight to 0.3% by weight, calculated relative to the total weight of composition B.

[0020] The aqueous oxidizing composition has a pH in the range of 1-6. From the viewpoints of storage stability and cosmetic safety, the pH of the composition is preferably 1.5 or higher, more preferably 2 or higher, and even more preferably 2.5 or higher. From the viewpoint of storage stability, the pH of the composition is preferably 5 or less, more preferably 4.5 or less, and even more preferably 4 or less. In order to obtain the above-mentioned effects, the pH of the composition is preferably in the range of 1.5 to 5, more preferably in the range of 2 to 4.5, and even more preferably in the range of 2.5 to 4.

[0021] [Form of aqueous oxidizing composition] The aqueous oxidizing composition B of the present invention is preferably an emulsion, a thickened gel, or a combination thereof, from the viewpoints of cosmetic safety and user friendliness.

[0022] [Lipophilic compound as compound f)] When the compositions of the invention are formulated as emulsions and / or thickened emulsions, the compositions preferably comprise one or more lipophilic compounds as compound(s) f).

[0023] Preferably, the compound f) is C 12 ~C 22 Fatty alcohols, C3-C 22 Alcohol and C 12 ~C 22 Esters with fatty acids, C8-C 22 They are selected from fatty acids, vegetable oils, and / or silicones, and / or hydrocarbon-based products, and / or mixtures thereof.

[0024] Appropriate C 12~C 22 The fatty alcohols are myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, and cetearyl alcohol. Appropriate C3~C 22 Alcohol and C 12 ~C 22 Esters with fatty acids are isopropyl myristate, isopropyl palmitate, and myristyl myristate. Suitable for C8~C 22 The fatty acids are oleic acid, linoleic acid, and palmitic acid. Suitable vegetable oils are olive oil, almond oil, sunflower oil, and argan oil. Suitable silicones are non-aminated and aminated silicones, the latter commonly known as amodimethicone.

[0025] The total concentration of the compound f) is preferably 1% by weight or more, more preferably 2% by weight or more, and even more preferably 3% by weight or more, calculated based on the total weight of composition B, from the viewpoint of forming a stable composition and the safety of users. The total concentration of the compounds f) is preferably 20% by weight or less, more preferably 15% by weight or less, and even more preferably 12% by weight or less, calculated relative to the total weight of composition B, in order to form a stable composition. To achieve the above-mentioned effects, the total concentration of the compound f) is preferably in the range of 1% by weight to 20% by weight, more preferably in the range of 2% by weight to 15% by weight, and even more preferably in the range of 3% by weight to 12% by weight, calculated relative to the total weight of composition B.

[0026] [Surfactant as compound g)] Composition B of the present invention may further comprise, as compound g), one or more surfactants, preferably selected from nonionic surfactants, anionic surfactants, cationic surfactants, and / or amphoteric / zwitterionic surfactants, and / or mixtures thereof, more preferably selected from anionic surfactants, in order to stabilize the composition and improve wetting and mixing properties.

[0027] Preferably, the anionic surfactant may be selected from ethoxylated or non-ethoxylated alkyl ether sulfate surfactants, alkyl sulfates, ethoxylated and / or non-ethoxylated alkyl carboxylates, ethoxylated or non-ethoxylated amino acid surfactants, and / or mixtures thereof and / or salts thereof. A good example is C 10 ~C 22 and a degree of ethoxylation of 1 to 50, or a mixture thereof, and / or a salt thereof.

[0028] Suitable nonionic surfactants may be selected from alkyl polyglycosides, ethoxylated triglycerides, ethoxylated fatty alcohols, ethoxylated fatty acid esters, and / or mixtures thereof.

[0029] Suitable cationic surfactants include C 12 ~C 22 or a quaternary ammonium surfactant having a carbon chain length in the range of C 12 ~C 22 and alkylamidoalkylamine surfactants and / or salts thereof, having at least one alkyl chain with a carbon chain length in the range of 1 to 4. Suitable examples are cetrimonium chloride and behentrimonium chloride.

[0030] Suitable amphoteric / zwitterionic surfactants are betaine type. Suitable compounds can be selected from alkyl betaines and / or alkyl amide betaines. A preferred compound selected from alkyl betaines is lauryl betaine. A preferred compound selected from alkyl amide betaines is cocamidopropyl betaine. The present disclosure also relates to salts of the compounds.

[0031] The appropriate concentration range of the surfactant is in the range of 0.1% by weight to 10% by weight calculated based on the total weight of composition B, from the viewpoint of improving the wettability of keratin fibers, physical stability, and miscibility with other compositions.

[0032] [Thickening polymer] From the viewpoint of cosmetic safety, it is further preferred that composition B of the present invention contains one or more thickening polymers. Composition B of the present invention comprises one or more thickening polymers chosen from nonionic and / or anionic thickening polymers, and / or mixtures thereof. Preferably, the thickening polymer is selected from polymers that result in aqueous solutions and / or dispersions at a pH of 1 to 6 with a viscosity of at least 1,000 mPa·s, measured at a polymer concentration of 1% by weight in water at 25°C, calculated relative to the total weight of the composition, and determined by a Brookfield viscometer, e.g., at 25°C using a suitable spindle at 10 rpm for 1 minute.

[0033] Suitable nonionic thickening polymers are cellulose-based polymers. Suitable examples of cellulose-based polymers are methylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxyethyl-methylcellulose, and alkylated hydroxylcelluloses, such as (C2-C8)-alkylcelluloses or cetyl hydroxyethylcellulose.

[0034] Suitable anionic thickening polymers are selected from natural-based anionic polymers and / or synthetic anionic polymers. Suitable natural anionic polymers may be selected from xanthan gum, dehydroxanthan gum, hydroxypropyl xanthan gum, carboxymethylcellulose, and starch-based polymers such as vegetable starches and / or their synthetically processed derivatives, such as hydroxypropyl starch phosphate. Equally suitable are alginic acid, sodium alginate, ammonium alginate, calcium alginate, gum arabic, and guar gum. Suitable synthetic anionic polymers are associative thickening polymers, for example, acrylates / steareth-30 methacrylate copolymer.

[0035] Preferred thickening polymers for the compositions of the present invention are natural anionic polymers, more preferably xanthan gum and / or dehydroxanthan gum, in view of their biodegradability and low environmental impact.

[0036] Preferably, the total concentration of the thickening polymers of the present invention is 0.1% by weight or more, more preferably 0.25% by weight or more, and even more preferably 0.5% by weight or more, calculated relative to the total weight of Composition B, in order to provide the composition with sufficient viscosity. Preferably, the total concentration of the thickening polymers of the present invention is 15% by weight or less, more preferably 12% by weight or less, and even more preferably 10% by weight or less, calculated relative to the total weight of Composition B, from the viewpoint of providing sufficient viscosity to the composition and from the viewpoint of cost of goods. To achieve the above-mentioned effects, the total concentration of the thickening polymer in Composition B of the present invention is in the range of 0.1% by weight to 15% by weight, preferably in the range of 0.25% by weight to 12% by weight, and more preferably in the range of 0.5% by weight to 10% by weight, calculated based on the total weight of Composition B.

[0037] The compositions of the present invention have a viscosity in the range of 1,000 to 25,000 mPa·s, preferably 2,000 to 20,000 mPa·s, and more preferably 2,500 to 17,500 mPa·s, as determined by a cone and plate viscometer at 25° C. under atmospheric conditions. A suitable viscometer is a Brookfield viscometer with a #4 spindle.

[0038] [Two-component bleaching composition] The present invention provides - the below described: c) one or more persalts and / or peroxy salts; d) one or more alkalizing agents; e) one or more polycarboxylic acids and / or salts thereof a first bleaching powder composition A comprising: - a second aqueous oxidizing composition B as defined above, Also covered is a two-part bleaching composition comprising:

[0039] Bleaching powder composition A comprises one or more persalts and / or peroxy salts. Suitable persalts and / or peroxy salts are sodium persulfate, potassium persulfate, ammonium persulfate, alkaline earth peroxides such as magnesium peroxide, maleimide peroxide or urea peroxide, or phthalimidoperoxyhexanoic acid. In terms of bleaching power, preferred persalts are sodium, potassium and ammonium persulfate.

[0040] From the viewpoints of bleaching power and cosmetic safety, the total concentration of the persalt and / or peroxy salt in the bleaching powder composition is preferably in the range of 10% by weight to 80% by weight, more preferably in the range of 15% by weight to 70% by weight, even more preferably in the range of 20% by weight to 60% by weight, and even more preferably in the range of 25% by weight to 60% by weight, calculated relative to the total weight of bleaching powder composition A.

[0041] The bleaching powder composition A comprises one or more alkalizing agents as compounds d). When Composition A is a bleaching powder composition, in order to provide sufficient alkalinity, it contains one or more alkalizing agents at a total concentration of preferably 0.25% by weight to 30% by weight, more preferably 0.5% by weight to 25% by weight, and even more preferably 1% by weight to 20% by weight, calculated based on the total weight of the bleaching powder composition A.

[0042] A suitable alkalizing agent is metasilicate, particularly sodium metasilicate. The concentration of metasilicate in bleaching powder composition A is preferably in the range of 1% to 20% by weight, more preferably 5% to 15% by weight, calculated based on the total weight of bleaching powder composition A, in terms of alkalinity.

[0043] Other suitable alkalizing agents include alkali carbonate and bicarbonate salts, such as sodium, potassium, and ammonium salts. From the viewpoint of buffering capacity, preferred salts are bicarbonates, and particularly preferred is ammonium bicarbonate. The appropriate concentration of carbonate in bleaching powder composition A, calculated based on the total weight of bleaching powder composition A, from the viewpoints of buffering capacity and low hair damage, is in the range of 0.25% to 10% by weight, preferably in the range of 0.5% to 7.5% by weight, more preferably in the range of 0.75% to 5% by weight, and even more preferably in the range of 1% to 4% by weight.

[0044] The bleaching powder composition A contains one or more polycarboxylic acids and / or salts thereof as the compound e). The preferred polycarboxylic acid and / or salt thereof as the compound e) has two or more carboxyl groups from the viewpoint of reducing hair damage, and is more preferably selected from malic acid, oxalic acid, malonic acid, succinic acid, fumaric acid, adipic acid, maleic acid, glutaric acid, ethylene diaminotetraacetic acid, pyromellitic acid, and / or salts thereof, and / or mixtures thereof. From the viewpoints of reducing hair damage, commercial availability, and cosmetic safety, it is even more preferable that the one or more polycarboxylic acids as compound e) have two carboxyl groups, and are more preferably selected from malic acid, oxalic acid, malonic acid, succinic acid, fumaric acid, adipic acid, maleic acid, glutaric acid, and / or salts thereof, and / or mixtures thereof. The most preferred compound of e) is malic acid and / or a salt thereof from the viewpoint of reducing hair damage.

[0045] From the viewpoint of reducing hair damage, the total concentration of the compound e) in the bleaching powder composition A is preferably 0.01% by weight or more, more preferably 0.05% by weight or more, and even more preferably 0.1% by weight or more, calculated based on the total weight of the bleaching powder composition A. From the viewpoint of reducing hair damage, the total concentration of the compound e) in the bleaching powder composition A is preferably 5% by weight or less, more preferably 2.5% by weight or less, and even more preferably 1% by weight or less, calculated based on the total weight of the bleaching powder composition A. To achieve the above-mentioned effects, the total concentration of the compound e) in the first bleaching powder composition A is preferably in the range of 0.01% by weight to 5% by weight, more preferably 0.05% by weight to 2.5% by weight, and even more preferably 0.1% by weight to 1% by weight, calculated based on the total weight of the bleaching powder composition A.

[0046] [Two-component oxidation dyeing composition] The present invention provides - a dyeing composition C having a pH ranging from 7 to 12 and comprising one or more oxidation dye precursors and / or oxidation dye couplers, and one or more alkalizing agents; - a second aqueous oxidizing composition B as defined above, The present invention also covers a two-component oxidation dye composition comprising:

[0047] Composition C preferably contains one or more compounds e) defined above and / or their salts and / or mixtures thereof from the viewpoint of reducing hair damage. The same concentrations and conditions as those disclosed in Composition A apply.

[0048] The oxidation dye composition C has a pH in the range of 7 to 12 and contains one or more oxidation dye precursors and / or oxidation dye couplers, and one or more alkalizing agents. The pH of the oxidation dye composition C is preferably 7.5 or higher, more preferably 8.0 or higher, and even more preferably 8.5 or higher, from the viewpoint of dyeing performance. The pH of the dye composition C is preferably 11 or less, more preferably 10.5 or less, and even more preferably 10.0 or less, from the viewpoints of cosmetic safety and dyeing performance. In order to obtain the above-mentioned effects, the pH of the oxidation dye composition C is preferably in the range of 7.5 to 11, more preferably 8.0 to 10.5, and even more preferably 8.5 to 10.0.

[0049] The oxidation dye composition C comprises one or more oxidation dye precursors and / or oxidation dye couplers.

[0050] Suitable oxidation dye precursors are, for example, p-phenylenediamine and / or its derivatives, p-aminophenol and / or its derivatives, and heterocyclic compounds, such as diaminopyrazoles and substituted pyrimidines, and / or their derivatives.

[0051] Exemplary oxidation dye precursors are p-phenylenediamine, p-aminophenol, 2,5-diamino-toluene, 2-n-propyl or 2-ethyl-p-phenylenediamine, 2,6-di-methyl-p-phenylene-diamine, 2-(2,5-diaminophenyl)ethanol, 1-amino-4-bis-(2'-hydroxy-ethyl)amino-benzene, 2-(2-hydroxyethylamino)-5-aminotoluene, 4,4'-diaminodiphenylamine, 4-aminodiphenylamine, 2-amino-5-N,N-diethylaminotoluene, 4-amino -N-Ethyl-N-isopropylaniline, 2-chloro-p-phenylenediamine, 1-β-hydroxyethyl-2,5-diamino-4-chlorobenzene, 1-β-hydroxyethyl-2,5-diamino-4-methylbenzene, 2-methoxy-p-phenylenediamine, N,N-diethyl-p-phenylenediamine, 1-amino-4-β-methoxyethylaminobenzene, 1-dimethyl-amino-4-aminobenzene, 1-hydroxy-2,5-diamino-4-methylbenzene, 1-hydroxymethyl-2,5-diaminobenzene, 1,3-dimethyl- 2,5-diaminobenzene, 1,4-diaminoisopropylbenzene and / or 1-amino-4-β-hydroxypropylaminobenzene, 1-hydroxyethyl-4,5-diaminopyrazole, 3,4-diamino-5-hydroxypyrazole, 3,5-diaminopyrazole, 3,5-diaminopyrazole-1-carboxamide, 3-amino-5-hydroxypyrazole, 1-phenyl-2-methylpyrazole, 1-phenyl-3-methylpyrazole-5-one, 3,5-dimethylpyrazole, 3,5-dimethylpyrazole-1-methanol, 3, 5-Diamino-1,2,4-triazole, 4-aminophenol and its derivatives, such as 4-amino-3-methylphenol, 2-chloro-4-aminophenol, 2,6-dichloro-4-aminophenol, 2,4-diamino-phenol, 2,6-dibromo-4-aminophenol, tetraaminopyrimidine, triaminohydroxypyrimidine, diaminomono- and -dihydroxypyrimidine, aminotriazine, 5-aminosalicylic acid and / or 1,2,4-triaminobenzene, 2,5-diaminopyridine, 2,3-diaminopyridine, 2,6-diaminopyridine, 3-amino-2-methylamino-6-methoxypyridine, 2-dimethyl-5-aminopyridine, 2-dimethylaminoethyl-3-hydroxypyridine, 2-amino-4,6-dimethylpyridine, 2-amino-3-hydroxypyridine, 3-amino-2(β-hydroxyethylamino)-6-methoxypyridine, 2,6-dimethylamino-5-aminopyridine, 2-di(hydroxyethyl)amino-5-aminopyridine, 2-hydroxyethylamino-5-aminopyridine, 4-hydroxy-2,5,6-triaminopyrimidine, and / or water-soluble salts thereof, and / or mixtures thereof.

[0052] Suitable oxidation dye couplers are resorcinol and / or its derivatives, m-aminophenol and / or its derivatives, m-phenylenediamine and / or its derivatives, pyridine and / or its derivatives, and naphthol and / or its derivatives.

[0053] Examples of oxidation dye couplers are 5-amino-2-methylphenol, 2-methyl-5-hydroxyethylaminophenol, 2,4-diaminophenoxyethanol, 2-amino-4-hydroxyethylaminoanisole, 2-methyl-5-amino-6-chlorophenol, 1,3-bis(2,4-diaminophenoxy)propane, 2-bis(2-hydroxyethyl)aminotoluene, 2-amino-5-methylphenol, resorcinol, 2-methyl-resorcinol, 4-chlororesorcinol, 2-amino-4-chlorophenol, 5-amino-4-methoxy-2-methylphenol, 2-aminophenol, 3-aminophenol, 1-methyl-2-hydroxy-4-aminobenzene, 3-N,N-dimethylaminophenol, 2,6-dihydroxy-3,5-dimethoxypyridine, 5-amino-3-methylphenol , 6-amino-3-methylphenol, 1,3-diamino-benzene, 1-amino-3-(2'-hydroxyethylamino)benzene, 1-amino-3-[bis(2'-hydroxyethyl)amino]benzene, α-naphthol, 4,6-dichlororesorcinol, 1,3-diamino-toluene, 4-hydroxy-1,2-methylenedioxybenzene, 1,5-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 1-hydroxy-2-methylnaphthalene, 4-hydroxy-1,2-methyldioxybenzene, 2,4-diamino-3-chlorophenol, 5-amino-2-methoxyphenol and / or 1-methoxy-2-amino-4-(2'-hydroxyethylamino)-benzene, or water-soluble salts thereof, and mixtures thereof.

[0054] A suitable total concentration of the oxidation dye precursors and / or oxidation dye couplers is in the range of 0.001% to 5% by weight, preferably 0.01% to 4% by weight, more preferably 0.05% to 3% by weight, and even more preferably 0.1% to 2% by weight, calculated relative to the total weight of the oxidation dye composition C.

[0055] The oxidation dyeing composition C comprises one or more alkalizing agents. Preferably, the one or more alkalizing agents are selected from the viewpoints of cosmetic safety and dyeing performance, such as ammonia, a compound having the general structure:

[0056] [ka]

[0057] wherein R1, R2, and R3 are the same or different from H, and are preferably selected from C1-C4 alkyl, C3-C4 unsaturated alkyl, C3-C4 branched chain alkyl, C1-C4 hydroxyl alkyl, C3-C4 unsaturated hydroxyl alkyl, C3-C4 branched chain hydroxyl alkyl, with the proviso that at least one of R1, R2, or R3 is different from H.

[0058] The alkalizing agent is selected from ammonia and / or a salt thereof, monoethanolamine and / or a salt thereof, and / or 2-aminomethylpropanol, and / or a mixture thereof, from the viewpoint of dyeing strength.

[0059] The concentration of the alkalizing agent in the oxidation dyeing composition A before mixing is preferably in the range of 0.25% by weight to 15% by weight, more preferably 0.5% by weight to 12.5% ​​by weight, even more preferably 0.75% by weight to 10% by weight, and even more preferably 1% by weight to 7.5% by weight, calculated relative to the total weight of the oxidation dyeing composition C before mixing, from the viewpoint of sufficient alkalinity and dyeing strength.

[0060] The oxidation dye composition may be in the form of a thickened gel, an emulsion, or a thickened emulsion.

[0061] To form the emulsion, the oxidation dye composition C may contain f) one or more lipophilic compounds, as disclosed in detail in the aqueous oxidation composition.

[0062] To form a thickened gel and / or a thickened emulsion, the oxidation dyeing composition C may further comprise a thickening polymer, as disclosed in the aqueous oxidation composition.

[0063] Furthermore, in terms of wettability and formulation stability, the oxidation dyeing composition C may further comprise one or more surfactants as compounds g), as disclosed in the aqueous oxidation compositions.

[0064] [Ready-to-use mixtures and bleaching / oxidation dyeing methods] The present invention relates to a method for bleaching and / or oxidative dyeing keratinous fibers, preferably human keratinous fibers, more preferably human hair, comprising the steps of: i) providing a bleaching powder composition A as defined above and a second aqueous oxidizing composition B as defined above; ii) optionally providing an oxidative dye composition C as defined above; iii) mixing the two compositions of step i) optionally together with a third oxidation dyeing composition C to produce a ready-to-use composition having a pH in the range of 7 to 12; iv) applying the ready-to-use mixture to the keratin fibers and leaving it for 1 minute to 60 minutes; v) rinsing the keratinous fibers and optionally shampooing the keratinous fibers; The present invention also covers methods including the following.

[0065] Bleaching powder composition A is mixed with aqueous oxidizing composition B to form a ready-to-use composition. A suitable mixing weight ratio is 5:1 to 1:5 (bleaching powder composition A:aqueous oxidizing composition B). Conventionally, suitable mixing ratios are 1:1, 1:2, and 1:3 (bleaching powder composition A:aqueous oxidizing composition B) by weight.

[0066] The oxidation dyeing composition C may be mixed with the aqueous oxidizing composition B and the bleaching powder composition A to form a ready-to-use composition. A suitable mixing weight ratio is 5:1:0.1 to 1:5:3 (oxidation dyeing composition C: aqueous oxidizing composition B: bleaching powder composition A). Conventionally, suitable mixing ratios are 1:1:2, 1:2:2, and 1:3:1 (oxidation dyeing composition C: aqueous oxidizing composition B: bleaching powder composition A) by weight.

[0067] Suitably, the pH of the ready-to-use composition is in the range of 7 to 12. From the viewpoint of accelerating dyeing, the pH of the ready-to-use composition is preferably in the range of 7.5 to 11, more preferably 8.0 to 10.5.

[0068] The ready-to-use composition is then applied to the keratin fibers as defined in step ii) and left for 1 to 60 minutes. The preferred time range for step ii) is 5 to 45 minutes, more preferably 10 to 35 minutes, in order to dye the keratin fibers thoroughly.

[0069] During step ii) and after applying the ready-to-use composition, heat may be applied in order to accelerate the oxidation dyeing. A suitable temperature range is 30°C to 50°C in terms of the oxidation dyeing speed and cosmetic safety.

[0070] The ready-to-use composition is then rinsed from the keratinous fibers, which are optionally washed with shampoo and optionally blow-dried with a hairdryer.

[0071] Ready-to-use mixtures and methods of oxidation dyeing The present invention relates to a method for oxidative dyeing of keratinous fibers, preferably human keratinous fibers, more preferably human hair, comprising the steps of: vi) providing an oxidation dye composition C as defined above and a second aqueous oxidizing composition B as defined above; vii) mixing the two compositions of step vi) to produce a ready-to-use composition having a pH in the range of 7 to 12; viii) applying the ready-to-use mixture to the keratin fibers and leaving it for 1 minute to 60 minutes; ix) rinsing the keratinous fibers and optionally shampooing the keratinous fibers; The present invention also covers methods including the following.

[0072] The oxidation dyeing composition C is mixed with the aqueous oxidation composition B to form a ready-to-use composition. A suitable mixing weight ratio is 5:1 to 1:5 (oxidation dyeing composition C:aqueous oxidation composition B). Conventionally, suitable mixing ratios are 1:1, 1:2, and 1:3 (oxidation dyeing composition C:aqueous oxidation composition B) by weight.

[0073] Suitably, the pH of the ready-to-use composition is in the range of 7 to 12. From the viewpoint of accelerating dyeing, the pH of the ready-to-use composition is preferably in the range of 7.5 to 11, more preferably 8.0 to 10.5.

[0074] The ready-to-use composition is then applied to the keratinous fibers as defined in step viii) and left for 1 minute to 60 minutes. A preferred time range for step viii) is 5 minutes to 45 minutes, more preferably 10 minutes to 35 minutes, in order to dye the keratinous fibers thoroughly.

[0075] In step viii), after applying the ready-to-use composition, heat may be applied in order to accelerate the oxidation dyeing. A suitable temperature range is 30°C to 50°C in terms of the oxidation dyeing speed and cosmetic safety.

[0076] The ready-to-use composition is then rinsed from the keratinous fibers, which are optionally washed with shampoo and optionally dried with a hair dryer.

[0077] [Permanent wave method] The present invention relates to a method for permanently shaping keratinous fibers, preferably human keratinous fibers, more preferably human hair, comprising the steps of: x) optionally washing the keratin fibers with shampoo; xi) placing the keratin fibers under mechanical tension; xii) applying an aqueous permanent wave composition D as defined below to the keratinous fibers and leaving the composition for a period ranging from 1 minute to 60 minutes; xiii) optionally rinsing the composition; xiv) preparing an aqueous oxidizing composition as defined above, applying it to the keratin fibers and leaving it for a period ranging from 1 minute to 30 minutes; xv) releasing the mechanical tension from the keratin fibers; xvi) rinsing the keratinous fibers and optionally shampooing the keratinous fibers, However, this also covers the method with the proviso that steps xi) and xii), and steps xv) and xvi) may be performed in any order. With the exception of steps xi) and xii), and steps xv) and xvi), the other steps listed above are preferably performed in the order listed.

[0078] Composition D preferably contains one or more compounds e) defined above and / or their salts and / or mixtures thereof from the viewpoint of reducing hair damage. The same concentrations and conditions as those disclosed in composition A apply.

[0079] The term "permanent shaping" should be understood to refer to permanent curling and permanent straightening.

[0080] Thus, the mechanical tension defined in step xi) is provided, for example, by placing the keratin fibers on curlers or by straightening the fibers with a comb or brush.

[0081] The composition defined in step xii) comprises one or more reducing agents. In principle, any inorganic or organic reducing agent and / or mixtures thereof are suitable for the purposes of the present invention.

[0082] Suitable inorganic reducing agents are sulfites and / or hydrogen sulfites, such as sodium, potassium, and ammonium salts. Suitable organic reducing agents are thioglycolic acid and / or its salts, cysteamine and / or its salts, thioglycerin and / or its salts, glycerin esters of thioglycolic acid and / or its salts, thiolactic acid and / or its salts, cysteine ​​or its derivatives and / or salts, and / or mixtures thereof. From the viewpoint of cosmetic safety, preferred reducing agents are thioglycolic acid and / or its salts, thiolactic acid and / or its salts, cysteine ​​or its derivatives and / or salts, sodium sulfite, potassium sulfite, ammonium sulfite, and mixtures thereof. From the viewpoint of cosmetic safety, the most preferred reducing agents are thioglycolic acid and / or its salts, sodium sulfite, potassium sulfite, ammonium sulfite, and / or mixtures thereof.

[0083] The concentration of the reducing agent in the composition of step xvii) is preferably in the range of 0.5% to 20% by weight, more preferably 1% to 15% by weight, even more preferably 2% to 12% by weight, and even more preferably 3% to 10% by weight, calculated relative to the total weight of the composition of step xvii).

[0084] The pH of the composition may be acidic or alkaline, ranging from 3 to 12, preferably from 4 to 11, and is most preferably alkaline in terms of reducing power, ranging from 7.5 to 10.5. The pH can be adjusted with known organic and / or inorganic acids and alkalizing agents (see above for dyeing and bleaching).

[0085] The composition of step xii) is left on the hair at ambient temperature for 1 to 60 minutes, preferably 2 to 45 minutes, more preferably 5 to 30 minutes, even more preferably 5 to 20 minutes, optionally with the application of heat.

[0086] Next, in step xiv), the aqueous oxidizing composition of the present invention is applied to the hair and left for 1 to 30 minutes. The composition is preferably left on the keratin fibers for 2 to 25 minutes, more preferably 3 to 20 minutes, and even more preferably 5 to 15 minutes, optionally with the application of heat and / or using a heating device, in view of hair damage and oxidation performance.

[0087] [Kit of Parts] The present invention relates to an aqueous oxidizing composition as defined above, a bleaching powder composition A as defined above, - an oxidation dye composition C as defined above, having a pH ranging from 7 to 12 and comprising one or more oxidation dye precursors and / or oxidation dye couplers, and one or more alkalizing agents, - an aqueous permanent wave composition D as defined above, having a pH ranging from 7 to 12 and comprising one or more reducing agents and one or more alkalizing agents; and one or more compositions selected from This also applies to kits of parts, including:

[0088] It is preferred from the standpoint of customer friendliness that the above compositions are packaged separately.

[0089] Compositions C and / or D preferably contain one or more compounds e) defined above, and / or salts thereof, and / or mixtures thereof, from the viewpoint of reducing hair damage.

[0090] The following examples are illustrative of the present invention but are not intended to limit it. [Example]

[0091] Example 1 The following aqueous oxidizing composition was prepared by dissolving alanine as compound b) in an aqueous composition of hydrogen peroxide under constant stirring.

[0092] [Table 1]

[0093] The following bleaching powder composition A was prepared, containing malic acid as compound e). weight% Hydroxyethylcellulose 3 Tetrasodium EDTA 2 Malic acid 0.5 Sodium carbonate 1 Ammonium persulfate 11 Potassium persulfate 36 Sodium metasilicate 10 Mineral oil 8 Diatomaceous earth (amount to make 100)

[0094] The above aqueous oxidizing composition was mixed with bleaching powder composition A in a weight ratio of 1:2 (bleaching powder composition A:aqueous oxidizing composition) to obtain a ready-to-use composition having a pH of approximately 10.0. 2 g of the composition was applied to human hair streaks (2 g per streak, 21 cm long) and left for 30 minutes at 40° C. The streaks were then rinsed with lukewarm water, washed with shampoo and dried with a hair dryer. The hair strands were then touched by five independent experts, who were asked which hair strand they preferred in terms of feel. All experts preferred the hair strands bleached with the composition of the present invention.

[0095] Example 2 The following aqueous oxidizing compositions were prepared by dissolving an amino acid as compound b) in an aqueous composition of hydrogen peroxide under constant stirring.

[0096] [Table 2]

[0097] The above composition was then mixed with the bleaching powder of Example 1 and human hair was treated as described below. The hair flows were then felt by five independent experts who were asked which hair flow they preferred in terms of feel and were asked to assign a ranking of 1 to 3, with higher numbers representing optimal results. The experts were blinded to the treatment groups.

[0098] [Table 3]

[0099] As a result, experts preferred hair styles treated with the compositions of the present invention.

[0100] Example 3 weight% Glycine 0.05 Cetearyl Alcohol 4.0 Sodium lauryl sulfate 0.8 Phosphoric acid, enough to make pH 1.5 Tetrasodium EDTA 0.05 Hydrogen peroxide 6.0 Water up to 100.0 The concentration of glycine as compound b) can also be adjusted to 0.05%, 0.1% or 0.5%, or any value therebetween, to achieve the same technical effect. The concentration of hydrogen peroxide can be adjusted to 9%, 12%, 15% or 20% by weight, or any value therebetween.

[0101] Example 4 weight% Alanine 0.01 Cetearyl Alcohol 4.0 Sodium lauryl sulfate 0.8 Phosphoric acid, enough to make the pH 2.5 Tetrasodium EDTA 0.05 Hydrogen peroxide 6.0 Water up to 100.0 The concentration of alanine as compound b) can also be adjusted to 0.05%, 0.1% or 0.5%, or any value therebetween, to achieve the same technical effect. The concentration of hydrogen peroxide can be adjusted to 9%, 12%, 15% or 20% by weight, or any value therebetween.

[0102] Example 5 weight% Glycine 0.1 Alanine 0.1 Proline 0.1 Cetearyl Alcohol 4.0 Sodium lauryl sulfate 0.8 Phosphoric acid, enough to make pH 3.0 Tetrasodium EDTA 0.05 Hydrogen peroxide 6.0 Water up to 100.0 The concentration of hydrogen peroxide can be adjusted to 9%, 12%, 15% or 20% by weight, or any value therebetween.

[0103] Example 6 The following oxidation dye compositions were prepared: weight% Cetearyl Alcohol 12 Sodium Cetearyl Sulfate 2 Cocamide MEA 5 Oleic Acid 2 Malic acid 1 Tetrasodium EDTA 1 Sodium sulfite 1 Ammonium hydroxide 5 Ammonium chloride 1 Toluene-2,5-diamine sulfate 0.75 Resorcinol 0.10 4-chlororesorcinol 0.25 m-aminophenol 0.05 4-amino-2-hydroxytoluene 0.05 Fragrance 0.5 Water up to 100 The above composition had a pH of 9.5.

[0104] The oxidation dye composition was then mixed with the stored Inventive Composition 1 and Comparative Composition 1 of Example 1 in a 1:1 weight ratio to produce a ready-to-use composition, which had a pH of approximately 9.5. The ready-to-use compositions were applied to human hair and left at room temperature for 30 minutes, after which the compositions were rinsed off with water and the hair was washed with shampoo and dried with a hair dryer. The hair was colored an intense reddish-brown, had a smooth cosmetic feel, and better shine with Inventive Composition 1, whereas the hair treated with Comparative Composition 1 had poor feel and less shine.

[0105] Example 7 The following permanent shape compositions were prepared: weight% Ammonium thioglycolate (60%) 21.3 Ammonium bicarbonate 5.0 1,3-butylene glycol 3.0 Malic acid 1.0 Amodimethicone 0.2 PEG-40 hydrogenated castor oil 0.7 Fragrance 0.4 Ammonia (25% active) up to pH 8.0 Water up to 100.0

[0106] Human hair was washed with shampoo and placed under mechanical tension with curlers. The above composition was then applied to the hair and left for 15 minutes at 40° C. The composition was then rinsed off with water. Next, the inventive composition 1 and the comparative composition 1 of Example 1 were applied to the hair and left to stand at room temperature for 15 minutes. The hair was then released from tension and the curlers were removed. The hair was then rinsed, washed with shampoo, and dried with a hair dryer. The hair was strongly curled with inventive composition 1 and had a good cosmetic feel, whereas the hair treated with comparative composition 1 had poor hair feel and low curl strength.

Claims

1. a) Hydrogen peroxide b) alanine and / or glycine, and / or salts thereof, and / or mixtures thereof Including, the total concentration of the compounds of a) ranges from 1% to 20% by weight, calculated relative to the total weight of the composition; the total concentration of the compounds of b) ranges from 0.01% to 0.5% by weight, calculated relative to the total weight of the composition; having a pH in the range of 1 to 6; Aqueous oxidizing composition B for keratin fibers.

2. 10. The composition of claim 1, wherein the pH of the composition is in the range of 1.5 to 5.

3. C 12 ~C 22 Fatty alcohols, C 3 ~C 22 Alcohol and C 12 ~C 22 Esters with fatty acids, C 8 ~C 22 3. Composition according to claim 1 or 2, characterized in that it comprises one or more lipophilic compounds f) chosen from fatty acids, vegetable oils, and / or silicones, and / or hydrocarbon-based products, and / or mixtures thereof.

4. 4. The composition according to claim 3, characterized in that the total concentration of the one or more compounds of f) ranges from 1% to 20% by weight, calculated relative to the total weight of the aqueous oxidizing composition B.

5. 5. The composition according to claim 1, comprising as compound g) one or more surfactants selected from nonionic surfactants, anionic surfactants, cationic surfactants and / or amphoteric / zwitterionic surfactants, and / or mixtures thereof.

6. 6. A composition according to claim 1, characterized in that it comprises one or more thickening polymers.

7. - the below described: c) one or more persalts and / or peroxy salts; d) one or more alkalizing agents; e) one or more polycarboxylic acids and / or salts thereof a first bleaching powder composition A comprising: a second aqueous oxidizing composition B according to any one of claims 1 to 6, A two-part bleaching composition comprising:

8. 8. The composition according to claim 7, wherein the one or more polycarboxylic acids as compounds e) have two or more carboxyl groups.

9. 9. Composition according to claim 7 or 8, characterized in that the one or more polycarboxylic acids as compound(s) e) are selected from malic acid, oxalic acid, malonic acid, succinic acid, fumaric acid, adipic acid, maleic acid, glutaric acid, ethylenediaminetetraacetic acid, pyromellitic acid, and / or their salts, and / or mixtures thereof.

10. 10. A composition according to any one of claims 7 to 9, characterized in that the total concentration of compounds e) in the first bleaching powder composition A is between 0.01% and 5% by weight, calculated relative to the total weight of the first bleaching powder composition A.

11. 11. Composition according to any one of claims 7 to 10, characterized in that the first bleaching powder composition A comprises as compound c) one or more persalts and / or peroxy salts in a total concentration ranging from 10% to 80% by weight, calculated relative to the total weight of the first bleaching powder composition A.

12. 12. A composition according to any one of claims 7 to 11, characterized in that the first bleaching powder composition A comprises as compound d) one or more alkalizing agents in a total concentration ranging from 0.25% to 30% by weight, calculated relative to the total weight of the first bleaching powder composition A.

13. a dyeing composition C having a pH ranging from 7 to 12 and comprising one or more oxidation dye precursors and / or oxidation dye couplers, and one or more alkalizing agents, a second aqueous oxidizing composition B according to any one of claims 1 to 6, A two-component oxidation dye composition comprising:

14. an aqueous oxidizing composition B according to any one of claims 1 to 6; a bleaching powder composition A according to any one of claims 7 to 12, an oxidation dye composition C having a pH ranging from 7 to 12 and comprising one or more oxidation dye precursors and / or oxidation dye couplers, and one or more alkalizing agents; - an aqueous permanent wave composition D having a pH in the range of 7 to 12 and comprising one or more reducing agents and one or more alkalizing agents; and another composition selected from Kit of parts, including:

15. 15. The kit according to claim 14, characterized in that composition C and / or D comprises one or more compounds of e) according to any one of claims 7 to 12, and / or salts thereof, and / or mixtures thereof.

16. 1. A method for bleaching and / or oxidative dyeing keratin fibers, comprising: i) providing a bleaching powder composition A according to any one of claims 7 to 12 and a second aqueous oxidizing composition B according to any one of claims 7 to 12 or 1 to 6; ii) optionally providing an oxidative dyeing composition C according to any one of claims 13 to 15; iii) mixing the two compositions of step i) optionally together with a third oxidation dyeing composition C to produce a ready-to-use composition having a pH in the range of 7 to 12; iv) applying the ready-to-use mixture to the keratin fibers and leaving it for 1 minute to 60 minutes; v) rinsing the keratinous fibers and optionally shampooing the keratinous fibers; A method comprising:

17. 1. A method for oxidative dyeing of keratin fibers, comprising: vi) providing an oxidation dyeing composition C according to any one of claims 13 to 15 and a second aqueous oxidizing composition B according to any one of claims 1 to 6; vii) mixing the two compositions of step vi) to produce a ready-to-use composition having a pH in the range of 7 to 12; viii) applying the ready-to-use mixture to the keratin fibers and leaving it for 1 minute to 60 minutes; ix) rinsing the keratinous fibers and optionally shampooing the keratinous fibers; A method comprising:

18. 1. A method for permanently shaping keratinous fibers, comprising: x) optionally washing the keratin fibers with shampoo; xi) subjecting the keratin fibers to mechanical tension; xii) applying the aqueous permanent wave composition D according to claim 14 or 15 to keratinous fibers and leaving the composition for a period ranging from 1 minute to 60 minutes; xiii) optionally rinsing the composition; xiv) preparing an aqueous oxidizing composition B according to any one of claims 1 to 6, applying it to keratinous fibers and leaving it for a period ranging from 1 minute to 30 minutes; xv) releasing the mechanical tension from the keratin fibers; xvi) rinsing the keratin fibers and optionally shampooing the keratin fibers; Including, With the proviso that steps xi) and xii) and steps xv) and xvi) may be performed in any order.

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