High-strength medical resin

By using a high-strength medical resin composed of a specific ratio of medical-grade silicone, propylene-ethylene copolymer, isooctanoic acid, alumina, and calcium carbonate, the problem of volume shrinkage during polymerization of resin composite materials has been solved, thus improving the strength and durability of dental restorative materials.

CN113413320BActive Publication Date: 2025-11-18江苏莱美齿科有限公司
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Patent Information

Application Number
CN202110730823.X
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2021-06-30
Publication Date
2025-11-18
Estimated Expiration
2041-06-30

AI Technical Summary

Technical Problem

Existing resin composite materials experience polymerization stress due to volume shrinkage during polymerization, resulting in shrinkage gaps that can lead to dental caries and sensitive teeth.

Method used

A high-strength medical resin is formed by mixing medical-grade silicone, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite in a specific ratio, followed by heating and vacuum stirring in a twin-screw extruder.

Benefits of technology

It significantly improves the strength of medical resins, reduces shrinkage gaps, is suitable for dental restorative materials, and enhances the durability and safety of the materials.

✦ Generated by Eureka AI based on patent content.
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Abstract

The application discloses a kind of high-strength medical resin, belongs to high polymer material technical field.It includes the following components: medical silica gel, propylene-ethylene copolymer, iso-octanoic acid, aluminium oxide, calcium carbonate, potassium pyrosulfite;With weight ratio, wherein the mass ratio between medical silica gel, propylene-ethylene copolymer, iso-octanoic acid, aluminium oxide, calcium carbonate, potassium pyrosulfite is (80-100) :(120-150) :(10-25) :(2-10) :(2-6) :(2-5);Its preparation method is as follows: preparation reaction kettle is added medical silica gel, propylene-ethylene copolymer, iso-octanoic acid, aluminium oxide, calcium carbonate and potassium pyrosulfite, heated to 180 DEG C, then vacuum mixing stirring 60min after, finally send into double-screw extruder and process.It can effectively improve its strength effect, meet the demand of dental restorative material.
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Description

Technical Field

[0001] This invention belongs to the field of polymer materials technology, specifically, it relates to a high-strength medical resin. Background Technology

[0002] Resin-inorganic filler composites not only closely resemble natural teeth in terms of strength, hardness, wear resistance, polishability, and color, but also possess various functions such as fluoride release, photochromic diagnostic properties, and light transmittance and scattering properties similar to natural teeth. They are increasingly widely used in dental repair and reconstruction. It is foreseeable that, due to their comprehensive advantages in aesthetics and performance, resin composites will completely replace traditional inorganic and metallic materials. However, resin composites have a fatal weakness: volume shrinkage during polymerization and the resulting polymerization stress. If the bonding surface cannot withstand this stress, shrinkage gaps of approximately 2 to 10 μm in size will appear, leading to secondary caries and triggering sensitive teeth. Summary of the Invention

[0003] The problem to be solved

[0004] To address the problems existing in the prior art, the present invention provides a high-strength medical resin that can effectively improve its strength and meet the needs of dental restorative materials.

[0005] Technical solutions

[0006] To solve the above problems, the present invention adopts the following technical solution.

[0007] A high-strength medical resin, comprising the following components:

[0008] Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite;

[0009] By weight, the mass ratio of medical silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite is (80-100):(120-150):(10-25):(2-10):(2-6):(2-5).

[0010] The high-strength medical resin described above includes the following components:

[0011] Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite;

[0012] By weight, the mass ratio of medical silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite is (85-95):(130-140):(15-20):(2-10):(2-6):(2-5).

[0013] The high-strength medical resin described above includes the following components:

[0014] Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite;

[0015] The mass ratio of medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite is 90:135:18:6:4:5 by weight.

[0016] The high-strength medical resin mentioned above uses medical silicone purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8.

[0017] In the aforementioned high-strength medical resin, the propylene-ethylene copolymer was purchased from Dongguan Ruimate Plastics Co., Ltd., under the brand name Ruimate and model number DF-710.

[0018] In the high-strength medical resin described above, the average particle size of the alumina is 0.2 mm;

[0019] The average particle size of the calcium carbonate is 0.1 mm;

[0020] The average particle size of the potassium metabisulfite is 0.2 mm.

[0021] The isooctanoic acid in the high-strength medical resin mentioned above was purchased from Shandong Chuxin Chemical Co., Ltd.

[0022] The high-strength medical resin described above is prepared using the following method:

[0023] Prepare a reaction vessel, add medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing.

[0024] In the high-strength medical resin described above, the rotation speed of the twin-screw extruder is 300 r / min.

[0025] In the high-strength medical resin described above, the temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

[0026] Beneficial effects

[0027] Compared with the prior art, the beneficial effects of the present invention are as follows:

[0028] The addition of propylene-ethylene copolymer in this application significantly improves the strength of medical resins. The addition of isooctanoic acid also plays a crucial role, enhancing its three-dimensional network structure. Furthermore, the addition of alumina and other components also contributes to the overall strength. The weight ratio of medical-grade silicone, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite also affects these strength indicators. In summary, this method effectively improves the strength of medical resins and makes them suitable for dental restorations. Detailed Implementation

[0029] The present invention will be further described below with reference to specific embodiments.

[0030] Example 1

[0031] The high-strength medical resin of this embodiment includes the following components:

[0032] Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite;

[0033] The mass ratio of medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite is 80:(150:10:10:2:5).

[0034] The high-strength medical resin mentioned above uses medical silicone purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8.

[0035] In the aforementioned high-strength medical resin, the propylene-ethylene copolymer was purchased from Dongguan Ruimate Plastics Co., Ltd., under the brand name Ruimate and model number DF-710.

[0036] In the high-strength medical resin described above, the average particle size of the alumina is 0.2 mm;

[0037] The average particle size of the calcium carbonate is 0.1 mm;

[0038] The average particle size of the potassium metabisulfite is 0.2 mm.

[0039] The isooctanoic acid in the high-strength medical resin mentioned above was purchased from Shandong Chuxin Chemical Co., Ltd.

[0040] The high-strength medical resin described above is prepared using the following method:

[0041] Prepare a reaction vessel, add medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing.

[0042] In the high-strength medical resin described above, the rotation speed of the twin-screw extruder is 300 r / min.

[0043] In the high-strength medical resin described above, the temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

[0044] Example 2

[0045] The high-strength medical resin of this embodiment includes the following components:

[0046] Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite;

[0047] The mass ratio of medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite is 100:120:25:2:6:2 by weight.

[0048] The high-strength medical resin mentioned above uses medical silicone purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8.

[0049] In the aforementioned high-strength medical resin, the propylene-ethylene copolymer was purchased from Dongguan Ruimate Plastics Co., Ltd., under the brand name Ruimate and model number DF-710.

[0050] In the high-strength medical resin described above, the average particle size of the alumina is 0.2 mm;

[0051] The average particle size of the calcium carbonate is 0.1 mm;

[0052] The average particle size of the potassium metabisulfite is 0.2 mm.

[0053] The isooctanoic acid in the high-strength medical resin mentioned above was purchased from Shandong Chuxin Chemical Co., Ltd.

[0054] The high-strength medical resin described above is prepared using the following method:

[0055] Prepare a reaction vessel, add medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing.

[0056] In the high-strength medical resin described above, the rotation speed of the twin-screw extruder is 300 r / min.

[0057] In the high-strength medical resin described above, the temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

[0058] Example 3

[0059] The high-strength medical resin of this embodiment includes the following components:

[0060] Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite;

[0061] The mass ratio of medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite is 85:140:15:10:2:5 by weight.

[0062] The high-strength medical resin mentioned above uses medical silicone purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8.

[0063] In the aforementioned high-strength medical resin, the propylene-ethylene copolymer was purchased from Dongguan Ruimate Plastics Co., Ltd., under the brand name Ruimate and model number DF-710.

[0064] In the high-strength medical resin described above, the average particle size of the alumina is 0.2 mm;

[0065] The average particle size of the calcium carbonate is 0.1 mm;

[0066] The average particle size of the potassium metabisulfite is 0.2 mm.

[0067] The isooctanoic acid in the high-strength medical resin mentioned above was purchased from Shandong Chuxin Chemical Co., Ltd.

[0068] The high-strength medical resin described above is prepared using the following method:

[0069] Prepare a reaction vessel, add medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing.

[0070] In the high-strength medical resin described above, the rotation speed of the twin-screw extruder is 300 r / min.

[0071] In the high-strength medical resin described above, the temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

[0072] Example 4

[0073] The high-strength medical resin of this embodiment includes the following components:

[0074] Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite;

[0075] The mass ratio of medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite is 95:130:20:2:6:2 by weight.

[0076] The high-strength medical resin mentioned above uses medical silicone purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8.

[0077] In the aforementioned high-strength medical resin, the propylene-ethylene copolymer was purchased from Dongguan Ruimate Plastics Co., Ltd., under the brand name Ruimate and model number DF-710.

[0078] In the high-strength medical resin described above, the average particle size of the alumina is 0.2 mm;

[0079] The average particle size of the calcium carbonate is 0.1 mm;

[0080] The average particle size of the potassium metabisulfite is 0.2 mm.

[0081] The isooctanoic acid in the high-strength medical resin mentioned above was purchased from Shandong Chuxin Chemical Co., Ltd.

[0082] The high-strength medical resin described above is prepared using the following method:

[0083] Prepare a reaction vessel, add medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing.

[0084] In the high-strength medical resin described above, the rotation speed of the twin-screw extruder is 300 r / min.

[0085] In the high-strength medical resin described above, the temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

[0086] Example 5

[0087] The high-strength medical resin of this embodiment includes the following components:

[0088] Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite;

[0089] The mass ratio of medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite is 90:135:18:6:4:5 by weight.

[0090] The high-strength medical resin mentioned above uses medical silicone purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8.

[0091] In the aforementioned high-strength medical resin, the propylene-ethylene copolymer was purchased from Dongguan Ruimate Plastics Co., Ltd., under the brand name Ruimate and model number DF-710.

[0092] In the high-strength medical resin described above, the average particle size of the alumina is 0.2 mm;

[0093] The average particle size of the calcium carbonate is 0.1 mm;

[0094] The average particle size of the potassium metabisulfite is 0.2 mm.

[0095] The isooctanoic acid in the high-strength medical resin mentioned above was purchased from Shandong Chuxin Chemical Co., Ltd.

[0096] The high-strength medical resin described above is prepared using the following method:

[0097] Prepare a reaction vessel, add medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing.

[0098] In the high-strength medical resin described above, the rotation speed of the twin-screw extruder is 300 r / min.

[0099] In the high-strength medical resin described above, the temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

[0100] Comparative Example 1

[0101] The high-strength medical resin of this embodiment includes the following components:

[0102] Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite;

[0103] The mass ratio of medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite is 100:100:18:6:4:5 by weight.

[0104] The high-strength medical resin mentioned above uses medical silicone purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8.

[0105] In the aforementioned high-strength medical resin, the propylene-ethylene copolymer was purchased from Dongguan Ruimate Plastics Co., Ltd., under the brand name Ruimate and model number DF-710.

[0106] In the high-strength medical resin described above, the average particle size of the alumina is 0.2 mm;

[0107] The average particle size of the calcium carbonate is 0.1 mm;

[0108] The average particle size of the potassium metabisulfite is 0.2 mm.

[0109] The isooctanoic acid in the high-strength medical resin mentioned above was purchased from Shandong Chuxin Chemical Co., Ltd.

[0110] The high-strength medical resin described above is prepared using the following method:

[0111] Prepare a reaction vessel, add medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing.

[0112] In the high-strength medical resin described above, the rotation speed of the twin-screw extruder is 300 r / min.

[0113] In the high-strength medical resin described above, the temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

[0114] Comparative Example 2

[0115] The high-strength medical resin of this embodiment includes the following components:

[0116] Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite;

[0117] The mass ratio of medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite is 90:135:6:6:6:6 by weight.

[0118] The high-strength medical resin mentioned above uses medical silicone purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8.

[0119] In the aforementioned high-strength medical resin, the propylene-ethylene copolymer was purchased from Dongguan Ruimate Plastics Co., Ltd., under the brand name Ruimate and model number DF-710.

[0120] In the high-strength medical resin described above, the average particle size of the alumina is 0.2 mm;

[0121] The average particle size of the calcium carbonate is 0.1 mm;

[0122] The average particle size of the potassium metabisulfite is 0.2 mm.

[0123] The isooctanoic acid in the high-strength medical resin mentioned above was purchased from Shandong Chuxin Chemical Co., Ltd.

[0124] The high-strength medical resin described above is prepared using the following method:

[0125] Prepare a reaction vessel, add medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing.

[0126] In the high-strength medical resin described above, the rotation speed of the twin-screw extruder is 300 r / min.

[0127] In the high-strength medical resin described above, the temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

[0128] Comparative Example 3

[0129] The high-strength medical resin of this embodiment includes the following components:

[0130] Medical-grade silica gel, propylene-ethylene copolymer, alumina, calcium carbonate, potassium metabisulfite;

[0131] The mass ratio of medical-grade silicone, propylene-ethylene copolymer, alumina, calcium carbonate, and potassium metabisulfite is 90:135:6:4:5 by weight.

[0132] The high-strength medical resin mentioned above uses medical silicone purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8.

[0133] In the aforementioned high-strength medical resin, the propylene-ethylene copolymer was purchased from Dongguan Ruimate Plastics Co., Ltd., under the brand name Ruimate and model number DF-710.

[0134] In the high-strength medical resin described above, the average particle size of the alumina is 0.2 mm;

[0135] The average particle size of the calcium carbonate is 0.1 mm;

[0136] The average particle size of the potassium metabisulfite is 0.2 mm.

[0137] The high-strength medical resin described above is prepared using the following method:

[0138] Prepare a reaction vessel, add medical-grade silica gel, propylene-ethylene copolymer, alumina, calcium carbonate and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing.

[0139] In the high-strength medical resin described above, the rotation speed of the twin-screw extruder is 300 r / min.

[0140] In the high-strength medical resin described above, the temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

[0141] Comparative Example 4

[0142] The high-strength medical resin of this embodiment includes the following components:

[0143] Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, calcium carbonate, potassium metabisulfite;

[0144] The mass ratio of medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, calcium carbonate, and potassium metabisulfite is 90:135:18:4:5 by weight.

[0145] The high-strength medical resin mentioned above uses medical silicone purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8.

[0146] In the aforementioned high-strength medical resin, the propylene-ethylene copolymer was purchased from Dongguan Ruimate Plastics Co., Ltd., under the brand name Ruimate and model number DF-710.

[0147] In the high-strength medical resin described above, the average particle size of the calcium carbonate is 0.1 mm;

[0148] The average particle size of the potassium metabisulfite is 0.2 mm.

[0149] The isooctanoic acid in the high-strength medical resin mentioned above was purchased from Shandong Chuxin Chemical Co., Ltd.

[0150] The high-strength medical resin described above is prepared using the following method:

[0151] Prepare a reaction vessel, add medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, calcium carbonate and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing.

[0152] In the high-strength medical resin described above, the rotation speed of the twin-screw extruder is 300 r / min.

[0153] In the high-strength medical resin described above, the temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

[0154] Comparative Example 5

[0155] The high-strength medical resin of this embodiment includes the following components:

[0156] Medical grade silica gel, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite;

[0157] The mass ratio of medical-grade silica gel, isooctanoic acid, aluminum oxide, calcium carbonate, and potassium metabisulfite is 90:18:6:4:5 by weight.

[0158] The high-strength medical resin mentioned above uses medical silicone purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8.

[0159] In the high-strength medical resin described above, the average particle size of the alumina is 0.2 mm;

[0160] The average particle size of the calcium carbonate is 0.1 mm;

[0161] The average particle size of the potassium metabisulfite is 0.2 mm.

[0162] The isooctanoic acid in the high-strength medical resin mentioned above was purchased from Shandong Chuxin Chemical Co., Ltd.

[0163] The high-strength medical resin described above is prepared using the following method:

[0164] Prepare a reaction vessel, add medical-grade silica gel, isooctanoic acid, alumina, calcium carbonate and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing.

[0165] In the high-strength medical resin described above, the rotation speed of the twin-screw extruder is 300 r / min.

[0166] In the high-strength medical resin described above, the temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

[0167] Example 6

[0168] The medical resins prepared in Examples 1-5 and Comparative Examples 1-5 were subjected to the following tests:

[0169] It should be noted that the medical resin prepared in this application has a low applicability and is mainly used as a replacement and restorative material in dentistry. It cannot be equated with the function of light-cured resin.

[0170] Specifically, the bending strength and bending modulus were determined using the three-point bending method (YY1042-2011 "Polymer Restorative Materials in Dentistry"), as shown in Table 1.

[0171] Table 1 Test Results

[0172] Bending strength / MPa Flexural modulus / GPa Example 1 112 9.2 Example 2 114 9.2 Example 3 113 9.4 Example 4 115 9.3 Example 5 118 9.5 Comparative Example 1 107 8.8 Comparative Example 2 103 8.7 Comparative Example 3 98 7.6 Comparative Example 4 105 8.2 Comparative Example 5 65 5.1

[0173] As shown in Table 1, the addition of propylene-ethylene copolymer in this application has a significant effect on improving the strength of medical resin. The addition of isooctanoic acid also plays a crucial role, enhancing its three-dimensional network structure. Furthermore, the addition of alumina and other components also contributes to the overall strength. The weight ratio of medical silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite also affects the strength indicators. In summary, this method effectively improves the strength of medical resin and makes it suitable for dental restoration.

[0174] It will be apparent to those skilled in the art that the present invention is not limited to the details of the exemplary embodiments described above, and that the invention can be implemented in other specific forms without departing from the spirit or essential characteristics of the invention. Therefore, the embodiments should be considered in all respects as exemplary and non-limiting, and the scope of the invention is defined by the appended claims rather than the foregoing description. Thus, it is intended that all variations falling within the meaning and scope of equivalents of the claims be included within the present invention.

[0175] Furthermore, it should be understood that although this specification describes embodiments, not every embodiment contains only one independent technical solution. This narrative style is merely for clarity. Those skilled in the art should consider the specification as a whole, and the technical solutions in each embodiment can also be appropriately combined to form other embodiments that can be understood by those skilled in the art.

Claims

1. A high-strength medical resin, characterized in that: It includes the following components: Medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, aluminum oxide, calcium carbonate, potassium metabisulfite; The mass ratio of medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate, and potassium metabisulfite is 90:135:18:6:4:5 by weight. The preparation method of the high-strength medical resin is as follows: Prepare a reaction vessel, add medical-grade silica gel, propylene-ethylene copolymer, isooctanoic acid, alumina, calcium carbonate and potassium metabisulfite, heat to 180°C, then vacuum mix and stir for 60 minutes, and finally send it to a twin-screw extruder for processing. The medical silicone was purchased from Foshan Mingchengda Organosilicon Co., Ltd., whose CAS Registry Number is 112926-00-8; The propylene-ethylene copolymer was purchased from Dongguan Ruimate Plastics Co., Ltd., under the brand name Ruimate and model number DF-710. The alumina has an average particle size of 0.2 mm; The average particle size of the calcium carbonate is 0.1 mm; The average particle size of the potassium metabisulfite is 0.2 mm; The isooctanoic acid mentioned above was purchased from Shandong Chuxin Chemical Co., Ltd. The twin-screw extruder operates at a speed of 300 r / min; The temperatures of the front, middle, and rear sections of the barrel and the die head of the twin-screw extruder are 220℃, 225℃, 230℃, and 230℃, respectively.

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