A kind of self-explosion-proof flexible glass and preparation method thereof

By using a combination of flexible glass materials and heat-absorbing core materials, self-explosion-proof flexible glass is prepared, which solves the problem of self-explosion of existing glass when the ambient temperature changes, and achieves high light transmittance, crack resistance and energy saving.

CN116001396BActive Publication Date: 2025-01-24SHANGHAI PINCHENG HLDG GRP CO LTD
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Patent Information

Application Number
CN202211646599.7
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2022-12-21
Publication Date
2025-01-24
Estimated Expiration
2042-12-21

AI Technical Summary

Technical Problem

Existing glasses are prone to thermal expansion and contraction when changing ambient temperature and humidity, resulting in self-destruction phenomena, and existing anti-destruction measures cannot effectively avoid this situation.

Method used

The combination of flexible glass materials and heat absorption core materials is used to prepare self -explosive flexible glass through steps such as vacuum dehumidification, pre -scoring, softening pinching, mold setting, cooling insulation, embryo compression, lighting, and annealing treatment.

Benefits of technology

It realizes that no cracks or burst when they are impacted, effectively avoiding the self -explosion, and at the same time improve the light transmission rate and anti -cracking performance of the glass, and have excellent energy saving effects.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention relates to the technical field of glass production, and discloses an anti-self-explosion flexible glass and a preparation method thereof, wherein the stirring and mixing mechanism comprises a mounting platform, and two stirring tanks are fixedly connected to the top of the mounting platform. The anti-self-explosion flexible glass and the preparation method thereof can absorb external infrared rays through a heat-absorbing core layer embryo, and form a nano-scale mesh structure by adding a flexible modifier internally, thereby maintaining excellent light transmittance and having excellent anti-cracking performance. When the lowest 4000J impact energy is concentrated in an area of ​​less than 20cm², the flexible glass does not produce any cracks, bursts, or falls after being impacted, and can effectively avoid cracking and spontaneous explosion. At the same time, through the cooperation of the stirring and mixing mechanism, automatic and accurate batching of explosion-proof flexible glass materials and heat-absorbing core materials is achieved, thereby greatly improving the batching efficiency of raw materials, thereby achieving the production efficiency of the anti-self-explosion flexible glass.
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Description

Technical Field

[0001] The invention relates to the technical field of glass production, and in particular to a self-explosion-proof flexible glass and a preparation method thereof. Background Art

[0002] Glass has excellent light transmittance and is widely used in the fields of construction, transportation, and automobiles. Glass is generally prepared by the float process. Due to the characteristics of current technology and process, it is inevitable that there will be defects and foreign impurities remaining. In the actual engineering use process, due to the alternating changes in ambient temperature and humidity, the glass will produce thermal expansion and contraction effects. Due to the presence of defects and foreign impurities, the glass will explode from time to time, causing the glass to shatter and fall. In addition to causing major safety accidents, it also brings about problems such as high replacement costs and difficult construction. The method of laminating in the middle can avoid injuries caused by self-explosion, but it cannot fundamentally solve the problem of self-explosion, and the laminating process is complicated, which reduces the product life.

[0003] Patent CN109572109B The present invention discloses laminated glass, including an upper ultra-white coated glass layer, an SGP film and a lower ultra-white coated glass arranged in sequence from top to bottom; The present invention also discloses a method for preparing laminated glass, including the following process steps: original sheet → slicing → edge grinding → cleaning → tempering → coating → cleaning → sheet assembly → initial pressing → vacuuming → autoclave heating and pressurization → autoclave heat preservation and pressure maintenance → autoclave cooling and pressure reduction → autoclave trimming and finishing → finished product → finished product packaging → delivery. The present invention improves the uniformity of glass heating by improving the heating method to a heating tube plus a convection fan, improves the heating efficiency of the glass, improves the visible light transmittance and strength of the SGP laminated glass, shortens the production time of the SGP laminated glass, and reduces energy consumption.

[0004] The uniformity is mainly improved by improving the heating process, but the self-explosion caused by the ambient temperature during use cannot be avoided. The production process includes 17 steps and the process is complicated.

[0005] Patent CN113863823A The present invention discloses an anti-self-explosion glass, which relates to the field of glass explosion-proof. The anti-self-explosion glass has a protective rubber pad installed on the outer surface of the reinforced glass, a protective shell installed on the outer surface of the protective rubber pad, a metal anti-collision strip fixedly installed on one side of the protective shell, and a limit groove is provided on the upper and lower sides of the fixed frame, and an assembly groove is provided on one side of the fixed frame. The other side of the fixed frame is movably connected with a fixing strip inside the limit groove and the assembly groove, and the outer surface of the connection of the four groups of fixing strips is fixedly installed with an L-shaped connecting strip by screws. The anti-self-explosion glass ensures that the frame of the reinforced glass is effectively protected, and avoids the self-explosion of the reinforced glass due to collision during use. At the same time, when the protective rubber pad is aged and hardened, it is convenient to replace the protective rubber pad.

[0006] The main method is to add a protective shell to prevent the glass from falling after self-explosion, but it cannot avoid the self-explosion caused by the ambient temperature during use. Therefore, a self-explosion-proof flexible glass and a preparation method thereof are needed. Summary of the invention

[0007] The purpose of the present invention is to provide a self-explosion-proof flexible glass and a preparation method thereof, which has explosion-proof and crack-resistant effects, and at the same time has good energy-saving effects. At the same time, the raw materials can be fully and evenly mixed, thereby improving the performance of the glass and also improving the production efficiency of the glass.

[0008] The purpose of the present invention can be achieved through the following technical solutions:

[0009] A self-explosion-proof flexible glass comprises a flexible glass material and a heat-absorbing core layer material, wherein the flexible glass material comprises the following raw material components:

[0010] Transparent organic resin: 55-95 parts

[0011] Flexibility improver: 5-40 parts

[0012] Ultraviolet absorber: 0.1-5 parts

[0013] Free radical scavenger: 0.1-0.6 parts;

[0014] The heat absorbing core layer material comprises the following raw material components:

[0015] Transparent organic resin: 55-95 parts

[0016] Flexibility improver: 5-40 parts

[0017] Carbon nanotubes: 0.1-5 parts

[0018] Infrared absorber: 0.01-2 parts

[0019] Free radical scavenger: 0.1 part to 0.6 part.

[0020] A method for preparing self-explosion-proof flexible glass comprises the following steps:

[0021] Step 1, vacuum dehumidification: put the raw materials of explosion-proof flexible glass material and heat-absorbing core material into vacuum dehumidifiers for dehumidification, and then pass them into buffer tanks after vacuum dehumidification;

[0022] Step 2, pre-dispersion: respectively introducing the raw material components of the flexible glass material and the heat absorbing core material from the buffer tank into the two stirring tanks on the stirring and mixing mechanism for heating and stirring and mixing, and at the same time introducing an inert gas into the stirring tank through the first air inlet pipe;

[0023] Step 3: Softening and kneading: the mixed raw materials in the two stirring tanks are respectively introduced into the mixing box in the kneading mechanism through the metering pump and the pipeline for softening and kneading;

[0024] Step 4: Molding: The raw materials kneaded and softened in the two mixing boxes in step 3 are respectively introduced into the flexible glass material mold and the heat absorbing core material mold through the discharge pipe for molding;

[0025] Step 5: Cooling and heat preservation: the flexible glass embryo and the heat-absorbing core layer formed in step 4 are placed in the mold for 1-2 minutes for heat preservation and standby;

[0026] Step 6, embryo body pressing: the flexible glass embryo body is divided into two parts, and taken out from the mold. At the same time, the heat-absorbing core layer embryo body is taken out from the mold and separated into continuous geometric shapes with a cross-sectional size of 1mm-5mm, and evenly arranged on the surface of the first part of the flexible glass embryo body, and then the second part of the flexible glass embryo body is flattened on the heat-absorbing core layer, and an external force of 0.3MPa-1MPa is applied on the upper surface to connect the two parts of the flexible glass embryo body again;

[0027] Step 7, calendering and shaping: the preliminarily pressed flexible glass embryo is further transferred between two calendering fixtures with a mirror effect. The surface temperature of the calendering fixture is set to 100°C to 180°C, and the temperature deviation of different parts does not exceed 0.5°C. The calendering fixture applies an external force of 0.1MPa to 1MPa to the surface of the flexible glass embryo for 0.5 minutes to 3 minutes.

[0028] Step 7: After calendering, the semi-finished flexible glass product is placed in a tempering furnace at a temperature of 70° C. to 150° C. for annealing for 30 minutes;

[0029] Step 8: After the flexible glass cools down, it enters precision cutting and packaging.

[0030] As a further solution of the present invention: the stirring and mixing mechanism includes a mounting platform, two stirring tanks are fixedly connected to the top of the mounting platform, the outer surface of the stirring tank is rotatably connected to a first gear, the outer surface of the first gear is meshingly connected to a feeding mechanism connected to the stirring tank, the outer surface of the first gear is transmission-connected to a driving mechanism, a sealing mechanism is provided in the two stirring tanks, a stirring mechanism is provided in both of the stirring tanks, one side of the stirring tank is fixedly connected to a kneading mechanism connected to the mounting platform through a pipeline, a metering pump is provided on the pipeline, and one side of the stirring tank is fixedly connected to a first air inlet pipe, and a valve is provided on the first air inlet pipe.

[0031] As a further solution of the present invention: the feeding mechanism includes a plurality of second gears with different numbers of teeth meshingly connected to the first gear, the middle of the second gear is fixedly sleeved with the first rotating shaft, the outer surface of the first rotating shaft is rotatably connected to a feeding pipe fixedly connected to a stirring tank, the top of the first rotating shaft is fixedly sleeved with a first bevel gear, the outer surface of the first bevel gear is meshingly connected with a second bevel gear, the middle of the second bevel gear is fixedly sleeved with a screw rod rotatably connected to the feeding pipe, and the top of the feeding pipe is fixedly connected to a feeding funnel fixedly connected to the stirring tank.

[0032] As a further solution of the present invention: the driving mechanism includes a first motor fixedly connected to the stirring tank, the output end of the first motor is fixedly connected to the second rotating shaft through a coupling, and the outer surface of the second rotating shaft is fixedly sleeved with a driving gear meshing with the first gear.

[0033] As a further solution of the present invention: the sealing mechanism includes a first electric telescopic rod fixedly connected to the stirring tank, the bottom end of the first electric telescopic rod is fixedly connected to a sealing plate slidably connected to the stirring tank, the bottom of the sealing plate is fixedly connected to a first rubber sealing ring, a mounting ring fixedly connected to the stirring tank is provided below the first rubber sealing ring, and the top of the mounting ring is fixedly connected to a second rubber sealing ring.

[0034] As a further scheme of the present invention: the stirring mechanism includes a first transmission shaft rotatably connected to the stirring tank, the first transmission shaft is rotatably connected to the mounting platform, the outer surface of the first transmission shaft is transmission-connected with a transmission mechanism, the bottom end of the first transmission shaft is transmission-connected with a kneading mechanism, the outer surface of the first transmission shaft is fixedly connected with a plurality of sliders, the outer surface of the slider is slidably connected with a plurality of transmission rings slidably connected to the first transmission shaft, a connecting rod is fixedly connected between the plurality of transmission rings, the top of the first transmission shaft is fixedly connected with a mounting block, the bottom of the mounting block is fixedly connected with a second electric telescopic rod, the bottom end of the second electric telescopic rod is fixedly connected to the top of one of the transmission rings, the outer surface of the transmission ring is fixedly connected with a plurality of stirring rods, the bottom of the stirring rod is fixedly connected with a flexible steel wire rope, one end of the flexible steel wire rope is fixedly connected with a hitting ball, and a plurality of first electric heating plates are fixedly connected in the stirring tank.

[0035] As a further solution of the present invention: the transmission mechanism includes a second motor fixedly connected to the mounting platform, the output end of the second motor is fixedly connected to a second transmission shaft rotatably connected to the mounting platform through a coupling, the outer surface of the second transmission shaft is fixedly sleeved with a first transmission gear, and the outer surface of the first transmission gear is meshingly connected with a second transmission gear fixedly sleeved with the first transmission shaft.

[0036] As a further scheme of the present invention: the kneading mechanism includes a mixing box fixedly connected to the mounting table, one side of the mixing box is rotatably connected to a third transmission shaft, one end of the third transmission shaft is fixedly sleeved with a third bevel gear, the outer surface of the third bevel gear is meshingly connected with a fourth bevel gear fixedly sleeved with the first transmission shaft, the outer surface of the third transmission shaft is fixedly sleeved with a third transmission gear, the outer surface of the third transmission gear is meshingly connected with two fourth transmission gears with different numbers of teeth, the middle of the fourth transmission gear is fixedly sleeved with a stirring shaft rotatably connected to the mixing box, a plurality of second electric heating plates are fixedly connected in the mixing box, a discharge pipe is fixedly connected to the bottom of the mixing box, a solenoid valve is provided on the discharge pipe, and a second air inlet pipe is fixedly connected to one side of the mixing box, and a valve is provided on the second air inlet pipe.

[0037] Beneficial effects of the present invention:

[0038] The heat-absorbing core layer can absorb external infrared rays, and by adding flexible modifiers inside, a nano-scale mesh structure is formed, which maintains excellent light transmittance and has excellent anti-cracking performance. When the minimum 4000J impact energy is concentrated on an area of ​​​​less than 20cm², the flexible glass will not produce any cracks, bursts, or falls after the impact, which can effectively avoid cracking and spontaneous explosions. At the same time, the molding temperature is much lower than the existing float glass production temperature, which has excellent energy-saving effects.

[0039] The driving mechanism on the stirring and mixing mechanism drives the first gear to rotate, and the first gear drives the feeding mechanism to operate. Through the cooperation of the feeding mechanism, the explosion-proof flexible glass material and the heat-absorbing core material can be automatically and accurately proportioned, which greatly improves the proportioning efficiency of the raw materials, thereby realizing the production efficiency of the anti-self-explosion flexible glass.

[0040] The stirring mechanism in the stirring tank is driven to operate through the transmission mechanism, and the stirring mechanism evenly and fully stirs the raw materials entering the stirring tank, thereby improving the pre-dispersion effect of the explosion-proof flexible glass material and the heat-absorbing core material, improving the mixing efficiency of the raw materials, and thus improving the performance of the raw materials.

[0041] The stirring mechanism drives the stirring shaft in the mixing box on the mounting table to rotate, so that the two stirring shafts in the mixing box rotate at a differential speed. At the same time, through the cooperation of the second electric heating plate, the raw materials in the mixing box are fully softened and kneaded, thereby improving the softening and kneading effect of the raw materials.

[0042] The feeding mechanism on the stirring tank is used to automatically and accurately feed the material into the stirring tank, and the transmission mechanism drives the stirring mechanism in the stirring tank to operate and drives the stirring shaft in the mixing box to rotate, thereby realizing the simultaneous pre-dispersion and softening and kneading of the raw materials of the explosion-proof flexible glass material and the heat-absorbing core material, which greatly improves the production efficiency of the raw materials and saves energy consumption. BRIEF DESCRIPTION OF THE DRAWINGS

[0043] The present invention will be further described below in conjunction with the accompanying drawings.

[0044] Figure 1 is a first stereogram of the external structure of the present invention;

[0045] Figure 2 is a second stereoscopic diagram of the external structure of the present invention;

[0046] Figure 3 It is a front view of the internal structure of the present invention;

[0047] Figure 4 The present invention Figure 3 A magnified view of middle;

[0048] Figure 5 The present invention Figure 4 Enlarged view of B.

[0049] In the figure: 1, mounting platform; 2, mixing tank; 3, first gear; 4, pipeline; 5, metering pump; 6, first air inlet pipe; 11, second gear; 12, first rotating shaft; 13, feeding pipe; 14, first bevel gear; 15, second bevel gear; 16, screw rod; 17, feeding funnel; 21, first motor; 22, second rotating shaft; 23, driving gear; 31, first electric telescopic rod; 32, sealing plate; 33, first rubber sealing ring; 34, mounting ring; 35, second rubber sealing ring; 41, first transmission shaft; 42, slider; 43, transmission Moving coil; 44, connecting rod; 45, mounting block; 46, second electric telescopic rod; 47, stirring rod; 48, flexible steel wire rope; 49, hitting ball; 490, first electric heating plate; 51, second motor; 52, second transmission shaft; 53, first transmission gear; 54, second transmission gear; 61, mixing box; 62, third transmission shaft; 63, third bevel gear; 64, fourth bevel gear; 65, third transmission gear; 66, fourth transmission gear; 67, stirring shaft; 68, second electric heating plate; 69, discharge pipe; 690, second air inlet pipe. DETAILED DESCRIPTION

[0050] The following will be combined with the drawings in the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention. Example

[0051] A self-explosion-proof flexible glass, comprising a flexible glass material and a heat-absorbing core layer material, wherein the flexible glass material comprises the following raw material components:

[0052] Transparent organic resin: 55 parts

[0053] Flexibility improver: 5 parts

[0054] UV absorber: 0.1 parts

[0055] Free radical scavenger: 0.1 parts;

[0056] The heat absorbing core layer material comprises the following raw material components:

[0057] Transparent organic resin: 55 parts

[0058] Flexibility improver: 5 parts

[0059] Carbon nanotubes: 0.1 parts

[0060] Infrared absorber: 0.01 parts

[0061] Free radical scavenger: 0.1 parts.

[0062] A method for preparing self-explosion-proof flexible glass comprises the following steps:

[0063] Step 1, vacuum dehumidification: put the raw materials of explosion-proof flexible glass material and heat-absorbing core material into vacuum dehumidifiers for dehumidification, and then pass them into buffer tanks after vacuum dehumidification;

[0064] Step 2, pre-dispersion: respectively introducing the raw material components of the flexible glass material and the heat absorbing core material from the buffer tank into the two stirring tanks on the stirring and mixing mechanism for heating and stirring and mixing, and at the same time introducing an inert gas into the stirring tank through the first air inlet pipe;

[0065] Step 3: Softening and kneading: the mixed raw materials in the two stirring tanks are respectively introduced into the mixing box in the kneading mechanism through the metering pump and the pipeline for softening and kneading;

[0066] Step 4: Molding: The raw materials kneaded and softened in the two mixing boxes in step 3 are respectively introduced into the flexible glass material mold and the heat absorbing core material mold through the discharge pipe for molding;

[0067] Step 5: Cooling and heat preservation: the flexible glass embryo and the heat-absorbing core layer formed in step 4 are placed in the mold for 1 minute for heat preservation;

[0068] Step 6, embryo body pressing: the flexible glass embryo body is divided into two parts, taken out from the mold, and the heat absorption core layer embryo body is taken out from the mold at the same time, and is separated into continuous geometric shapes with a cross-sectional size of 1 mm, and evenly arranged on the surface of the first part of the flexible glass embryo body, and then the second part of the flexible glass embryo body is flattened on the heat absorption core layer, and an external force of 0.3 MPa is applied on the upper surface to connect the two parts of the flexible glass embryo body again;

[0069] Step 7, calendering and shaping: the preliminarily pressed flexible glass embryo is further transferred between two calendering fixtures with a mirror effect. The surface temperature of the calendering fixture is set to 100°C, and the temperature deviation of different parts does not exceed 0.5°C. The calendering fixture applies an external force of 0.1MPa to the surface of the flexible glass embryo for 0.5 minutes.

[0070] Step 7: After calendering, the semi-finished flexible glass product is placed in a tempering furnace at a temperature of 70° C. for annealing for 30 minutes;

[0071] Step 8: After the flexible glass cools down, it enters precision cutting and packaging. Example

[0072] A self-explosion-proof flexible glass, comprising a flexible glass material and a heat-absorbing core layer material, wherein the flexible glass material comprises the following raw material components:

[0073] Transparent organic resin: 65 parts

[0074] Flexibility improver: 15 parts

[0075] UV absorber: 2 parts

[0076] Free radical scavenger: 0.3 parts;

[0077] The heat absorbing core layer material comprises the following raw material components:

[0078] Transparent organic resin: 65 parts

[0079] Flexibility improver: 15 parts

[0080] Carbon nanotubes: 2 parts

[0081] Infrared absorber: 0.1 part

[0082] Free radical scavenger: 0.3 parts.

[0083] A method for preparing self-explosion-proof flexible glass comprises the following steps:

[0084] Step 1, vacuum dehumidification: put the raw materials of explosion-proof flexible glass material and heat-absorbing core material into vacuum dehumidifiers for dehumidification, and then pass them into buffer tanks after vacuum dehumidification;

[0085] Step 2, pre-dispersion: respectively introducing the raw material components of the flexible glass material and the heat absorbing core material from the buffer tank into the two stirring tanks on the stirring and mixing mechanism for heating and stirring and mixing, and at the same time introducing an inert gas into the stirring tank through the first air inlet pipe;

[0086] Step 3: Softening and kneading: the mixed raw materials in the two stirring tanks are respectively introduced into the mixing box in the kneading mechanism through the metering pump and the pipeline for softening and kneading;

[0087] Step 4: Molding: The raw materials kneaded and softened in the two mixing boxes in step 3 are respectively introduced into the flexible glass material mold and the heat absorbing core material mold through the discharge pipe for molding;

[0088] Step 5: Cooling and heat preservation: the flexible glass embryo and the heat-absorbing core layer formed in step 4 are placed in the mold for 1.5 minutes for heat preservation and standby;

[0089] Step 6, embryo body pressing: the flexible glass embryo body is divided into two parts, taken out from the mold, and the heat absorbing core layer embryo body is taken out from the mold at the same time, and is separated into continuous geometric shapes with a cross-sectional size of 2 mm, and evenly arranged on the surface of the first part of the flexible glass embryo body, and then the second part of the flexible glass embryo body is flattened on the heat absorbing core layer, and an external force of 0.6 MPa is applied on the upper surface to connect the two parts of the flexible glass embryo body again;

[0090] Step 7, calendering and shaping: the preliminarily pressed flexible glass embryo is further transferred between two calendering fixtures with a mirror effect. The surface temperature of the calendering fixture is set to 120°C, and the temperature deviation of different parts does not exceed 0.5°C. The calendering fixture applies an external force of 0.5MPa to the surface of the flexible glass embryo for 1.5 minutes.

[0091] Step 7: After calendering, the semi-finished flexible glass product is placed in a tempering furnace at a temperature of 110° C. for annealing for 30 minutes;

[0092] Step 8: After the flexible glass cools down, it enters precision cutting and packaging. Example

[0093] A self-explosion-proof flexible glass, comprising a flexible glass material and a heat-absorbing core layer material, wherein the flexible glass material comprises the following raw material components:

[0094] Transparent organic resin: 95 parts

[0095] Flexibility improver: 40 parts

[0096] UV absorber: 5 parts

[0097] Free radical scavenger: 0.6 parts;

[0098] The heat absorbing core layer material comprises the following raw material components:

[0099] Transparent organic resin: 95 parts

[0100] Flexibility improver: 40 parts

[0101] Carbon nanotubes: 5 parts

[0102] Infrared absorber: 2 parts

[0103] Free radical scavenger: 0.6 parts.

[0104] A method for preparing self-explosion-proof flexible glass comprises the following steps:

[0105] Step 1, vacuum dehumidification: put the raw materials of explosion-proof flexible glass material and heat-absorbing core material into vacuum dehumidifiers for dehumidification, and then pass them into buffer tanks after vacuum dehumidification;

[0106] Step 2, pre-dispersion: respectively introducing the raw material components of the flexible glass material and the heat absorbing core material from the buffer tank into the two stirring tanks on the stirring and mixing mechanism for heating and stirring and mixing, and at the same time introducing an inert gas into the stirring tank through the first air inlet pipe;

[0107] Step 3: Softening and kneading: the mixed raw materials in the two stirring tanks are respectively introduced into the mixing box in the kneading mechanism through the metering pump and the pipeline for softening and kneading;

[0108] Step 4: Molding: The raw materials kneaded and softened in the two mixing boxes in step 3 are respectively introduced into the flexible glass material mold and the heat absorbing core material mold through the discharge pipe for molding;

[0109] Step 5: Cooling and heat preservation: the flexible glass embryo and the heat-absorbing core layer formed in step 4 are placed in the mold for 2 minutes for heat preservation;

[0110] Step 6, embryo body pressing: the flexible glass embryo body is divided into two parts, taken out from the mold, and the heat absorbing core layer embryo body is taken out from the mold at the same time, and is separated into continuous geometric shapes with a cross-sectional size of 5 mm, and evenly arranged on the surface of the first part of the flexible glass embryo body, and then the second part of the flexible glass embryo body is flattened on the heat absorbing core layer, and an external force of 1 MPa is applied on the upper surface to connect the two parts of the flexible glass embryo body again;

[0111] Step 7, calendering and shaping: the preliminarily pressed flexible glass embryo is further transferred between two calendering fixtures with mirror effect. The surface temperature of the calendering fixture is set to 180°C, and the temperature deviation of different parts does not exceed 0.5°C. The calendering fixture applies an external force of 1MPa to the surface of the flexible glass embryo for 3 minutes.

[0112] Step 7: After calendering, the semi-finished flexible glass product is placed in a tempering furnace at a temperature of 150° C. for annealing for 30 minutes;

[0113] Step 8: After the flexible glass cools down, it enters precision cutting and packaging.

[0114] It is mainly composed of a highly transparent flexible resin and a heat-absorbing core layer uniformly distributed inside. The materials used to prepare the flexible resin are: transparent organic resin, flexible modifier, ultraviolet absorber, and free radical scavenger. The flexible modifier is uniformly distributed in the transparent organic resin in nano form to form a nano-scale grid structure to improve the crack resistance of the resin glass; the heat-absorbing core layer is composed of transparent organic resin, flexible modifier, carbon nanotubes, infrared absorber, and free radical scavenger. Through the uniformly distributed heat-absorbing core layer, the infrared rays of the external environment are uniformly absorbed to increase its own temperature. The heat-absorbing core layer self-heats and evenly transfers heat to the surrounding medium, thereby improving the temperature uniformity of the glass surface and interior and between different parts, ensuring that different parts of the glass expand evenly, and further avoiding the possibility of self-explosion. Example

[0115] For stirring and mixing mechanisms used in the preparation process, please refer to Figure 1-Figure 5As shown, it includes a mounting platform 1, and two stirring tanks 2 are fixedly connected to the top of the mounting platform 1. The outer surface of the stirring tank 2 is rotatably connected with a first gear 3, and the outer surface of the first gear 3 is meshingly connected with a feeding mechanism connected to the stirring tank 2, and the outer surface of the first gear 3 is transmission-connected with a driving mechanism. A sealing mechanism is provided in the two stirring tanks 2, and a stirring mechanism is provided in both of the two stirring tanks 2. One side of the stirring tank 2 is fixedly connected with a kneading mechanism connected to the mounting platform 1 through a pipeline 4, and a metering pump 5 is provided on the pipeline 4. One side of the stirring tank 2 is fixedly connected with a first air inlet pipe 6, and a valve is provided on the first air inlet pipe 6. Each raw material is respectively introduced into the feeding mechanism through a buffer tank, and then the first gear 3 is driven to rotate by the driving mechanism. The first gear 3 drives the feeding mechanism to operate, and the feeding mechanism passes each raw material into the stirring tank 2 according to the moving ratio, and then seals the feeding port through the sealing mechanism, and then passes inert gas into the stirring tank 2 through the first air inlet pipe 6, and then the entering raw materials are fully and evenly mixed through the stirring mechanism, so as to realize automatic batching and feeding of explosion-proof flexible glass materials and heat-absorbing core materials, and at the same time, the raw materials are fully and evenly mixed, so as to improve the quality of glass after production, and then the stirred and mixed raw materials are passed into the kneading mechanism through the pipeline 4 and the metering pump 5 for re-engagement and softening, which improves the uniformity of the raw material mixing, thereby improving the performance of the raw materials, and at the same time, the flexible glass material and the heat-absorbing core material are fully and evenly mixed at the same time, so as to improve the production efficiency of the glass.

[0116] The feeding mechanism includes a plurality of second gears 11 of different sizes meshingly connected with the first gear 3, the middle of the second gear 11 is fixedly sleeved with a first rotating shaft 12, the outer surface of the first rotating shaft 12 is rotatably connected with a feeding pipe 13 fixedly connected with the stirring tank 2, the top of the first rotating shaft 12 is fixedly sleeved with a first bevel gear 14, the outer surface of the first bevel gear 14 is meshingly connected with a second bevel gear 15, the middle of the second bevel gear 15 is fixedly sleeved with a screw rod 16 rotatably connected with the feeding pipe 13, the top of the feeding pipe 13 is fixedly connected with a screw rod 16 fixedly connected with the stirring tank 2 The feeding funnel 17 drives the first gear 3 to rotate through the driving mechanism, and the first gear 3 drives the second gear 11 with different number of teeth to rotate. Due to the different number of teeth, the transmission ratio of the second gear 11 to the first gear 3 is different, so that the second gear 11 drives the first rotating shaft 12 to rotate at different speeds, and the first rotating shaft 12 drives the screw rod 16 to rotate at different speeds through the first bevel gear 14 and the second bevel gear 15, so that the screw rod 16 drives the feeding funnel 17 to enter the feeding pipe 13. The conveying speeds of various raw materials are different, thereby realizing accurate automatic feeding of various raw materials in proportion.

[0117] The driving mechanism includes a first motor 21 fixedly connected to the stirring tank 2, the output end of the first motor 21 is fixedly connected to the second rotating shaft 22 through a coupling, the outer surface of the second rotating shaft 22 is fixedly sleeved with a driving gear 23 meshing with the first gear 3, the second rotating shaft 22 is driven to rotate by the first motor 21, the second rotating shaft 22 drives the driving gear 23 to rotate, and the driving gear 23 drives the first gear 3 to rotate.

[0118] The sealing mechanism includes a first electric telescopic rod 31 fixedly connected to the stirring tank 2, a sealing plate 32 slidably connected to the stirring tank 2 is fixedly connected to the bottom end of the first electric telescopic rod 31, a first rubber sealing ring 33 is fixedly connected to the bottom of the sealing plate 32, a mounting ring 34 fixedly connected to the stirring tank 2 is arranged below the first rubber sealing ring 33, and a second rubber sealing ring 35 is fixedly connected to the top of the mounting ring 34. The sealing plate 32 is driven downward by the first electric telescopic rod 31, and the sealing plate 32 drives the first rubber sealing ring 33 to move downward, so that the first rubber sealing ring 33 and the second rubber sealing ring 35 on the mounting ring 34 are squeezed and sealed, thereby realizing sealing of the stirring tank 2. At the same time, the inclined design of the second rubber sealing ring 35 prevents materials from remaining on the second rubber sealing ring 35.

[0119] The stirring mechanism includes a first transmission shaft 41 rotatably connected to the stirring tank 2, the first transmission shaft 41 is rotatably connected to the mounting platform 1, the outer surface of the first transmission shaft 41 is transmission-connected with a transmission mechanism, the bottom end of the first transmission shaft 41 is transmission-connected with a kneading mechanism, the outer surface of the first transmission shaft 41 is fixedly connected with a plurality of sliders 42, the outer surface of the sliders 42 is slidably connected with a plurality of transmission rings 43 slidably connected to the first transmission shaft 41, a connecting rod 44 is fixedly connected between the plurality of transmission rings 43, the top of the first transmission shaft 41 is fixedly connected with a mounting block 45, the bottom of the mounting block 45 is fixedly connected with a second electric telescopic rod 46, the bottom end of the second electric telescopic rod 46 is fixedly connected to the top of one of the transmission rings 43, and the outer surface of the transmission ring 43 is fixedly connected with a plurality of stirring rods 47 A flexible steel wire rope 48 is fixedly connected to the bottom of the stirring rod 47, and a striking ball 49 is fixedly connected to one end of the flexible steel wire rope 48. A plurality of first electric heating plates 490 are fixedly connected in the stirring tank 2. The first transmission shaft 41 is driven to rotate by a transmission mechanism. The first transmission shaft 41 drives the transmission ring 43 to rotate through a slider 42. The transmission ring 43 drives the stirring rod 47 and the flexible steel wire rope 48 to rotate. The flexible steel wire rope 48 drives the striking ball 49 to rotate, so as to stir and mix the raw materials in the stirring tank 2. At the same time, the second electric telescopic rod 46 drives the transmission ring 43 to move up and down, thereby realizing the reciprocating movement of the stirring rod 47 and the striking ball 49 up and down. At the same time, the first electric heating plate 490 heats and melts the raw materials, thereby realizing uniform stirring and mixing of the raw materials, making the mixing effect between the raw materials better and improving the performance of the materials.

[0120] The transmission mechanism includes a second motor 51 fixedly connected to the mounting platform 1, the output end of the second motor 51 is fixedly connected to a second transmission shaft 52 rotatably connected to the mounting platform 1 through a coupling, the outer surface of the second transmission shaft 52 is fixedly sleeved with a first transmission gear 53, the outer surface of the first transmission gear 53 is meshingly connected with a second transmission gear 54 fixedly sleeved with the first transmission shaft 41, the second transmission shaft 52 is driven to rotate by the second motor 51, the second transmission shaft 52 drives the first transmission gear 53 to rotate, the first transmission gear 53 drives the second transmission gear 54 to rotate, and the second transmission gear 54 drives the first transmission shaft 41 to rotate.

[0121] The kneading mechanism includes a mixing box 61 fixedly connected to the mounting platform 1, one side of the mixing box 61 is rotatably connected to a third transmission shaft 62, one end of the third transmission shaft 62 is fixedly sleeved with a third bevel gear 63, the outer surface of the third bevel gear 63 is meshedly connected to a fourth bevel gear 64 fixedly sleeved with the first transmission shaft 41, the outer surface of the third transmission shaft 62 is fixedly sleeved with a third transmission gear 65, the outer surface of the third transmission gear 65 is meshedly connected to a fourth transmission gear 66 with two different numbers of teeth, the middle of the fourth transmission gear 66 is fixedly sleeved with a stirring shaft 67 rotatably connected to the mixing box 61, a plurality of second electric heating plates 68 are fixedly connected in the mixing box 61, a discharge pipe 69 is fixedly connected to the bottom of the mixing box 61, a solenoid valve is provided on the discharge pipe 69, and a side of the mixing box 61 is fixedly connected to the mixing box 61. A second air inlet pipe 690 is fixedly connected, and a valve is arranged on the second air inlet pipe 690. The fourth bevel gear 64 is driven to rotate by the first transmission shaft 41, and the fourth bevel gear 64 drives the third bevel gear 63 to rotate. The third bevel gear 63 drives the third transmission shaft 62 to rotate. The third transmission shaft 62 drives the third transmission gear 65 to rotate. The third transmission gear 65 drives two fourth transmission gears 66 with different numbers of teeth to rotate. The fourth transmission gear 66 drives the stirring shaft 67 to rotate. Since the numbers of teeth of the two fourth transmission gears 66 are different and the transmission ratio of the third transmission gear 65 is different, the rotation speeds of the two stirring shafts 67 are different, so that the two stirring shafts 67 are differentially stirred in the mixing box 61, thereby improving the stirring effect on the raw materials. At the same time, the second electric heating plate 68 stirs the raw materials in the mixing box 61, thereby achieving sufficient kneading and softening of the raw materials.

[0122] The working principle of the present invention is as follows: each raw material is introduced into the feeding mechanism through the buffer tank, and the second rotating shaft 22 is driven to rotate by the first motor 21, and the second rotating shaft 22 drives the driving gear 23 to rotate, and the driving gear 23 drives the first gear 3 to rotate, and the first gear 3 drives the second gear 11 with different numbers of teeth to rotate. Due to the different numbers of teeth, the transmission ratio of the second gear 11 and the first gear 3 is different, so that the second gear 11 drives the first rotating shaft 12 to rotate at different speeds, and the first rotating shaft 12 drives the screw rod 16 to rotate at different speeds through the first bevel gear 14 and the second bevel gear 15, so that the screw rod 16 drives the feeding funnel 17 to enter the feeding pipe 1 The conveying speeds of the raw materials of 3 are different, so that the raw materials can be automatically fed accurately in proportion. Then, the sealing plate 32 is driven downward by the first electric telescopic rod 31, and the sealing plate 32 drives the first rubber sealing ring 33 to move downward, so that the first rubber sealing ring 33 and the second rubber sealing ring 35 on the mounting ring 34 are squeezed and sealed, so as to seal the mixing tank 2. At the same time, the second rubber sealing ring 35 is tilted to prevent the material from remaining on the second rubber sealing ring 35. The first transmission shaft 41 is driven to rotate through the transmission mechanism, and the first transmission shaft 41 drives the transmission ring 43 to rotate through the slider 42, and the transmission ring 43 drives the stirring rod 47 The flexible steel wire rope 48 rotates, and the flexible steel wire rope 48 drives the hitting ball 49 to rotate, so as to stir and mix the raw materials in the stirring tank 2. At the same time, the second electric telescopic rod 46 drives the transmission ring 43 to move up and down, so as to realize the reciprocating movement of the stirring rod 47 and the hitting ball 49, and at the same time, the first electric heating plate 490 heats and melts the raw materials, so as to realize uniform stirring and mixing of the raw materials, so that the mixing effect between the raw materials is better, and the performance of the material is improved. The fourth bevel gear 64 is driven to rotate by the first transmission shaft 41, and the fourth bevel gear 64 drives the third bevel gear 63 to rotate, and the third bevel gear 63 drives the third transmission shaft 62 to rotate, and the third transmission shaft 62 drives The third transmission gear 65 is driven to rotate, and the third transmission gear 65 drives two fourth transmission gears 66 with different numbers of teeth to rotate, and the fourth transmission gear 66 drives the stirring shaft 67 to rotate. Since the number of teeth of the two fourth transmission gears 66 is different from the transmission ratio of the third transmission gear 65, the rotation speeds of the two stirring shafts 67 are different, so that the two stirring shafts 67 are differentially stirred in the mixing box 61, thereby improving the stirring effect of the raw materials. At the same time, the second electric heating plate 68 stirs the raw materials in the mixing box 61, so as to achieve sufficient kneading and softening of the raw materials, thereby improving the sufficient mixing of the explosion-proof flexible glass raw materials and greatly improving the performance of the flexible glass after production.

[0123] The above is a detailed description of an embodiment of the present invention, but the content is only a preferred embodiment of the present invention and cannot be considered to limit the scope of implementation of the present invention. All equivalent changes and improvements made within the scope of the present invention should still fall within the scope of the patent coverage of the present invention.

Claims

1. A method for preparing self-explosion-proof flexible glass, characterized in that: The following steps are involved: Step 1, vacuum dehumidification: the raw materials of the flexible glass material and the heat absorbing core material are respectively placed in vacuum dehumidifiers for dehumidification, and the raw materials are respectively introduced into buffer tanks after vacuum dehumidification; Step 2, pre-dispersion: respectively introducing the raw material components of the flexible glass material and the heat absorbing core material from the buffer tank into two stirring tanks (2) on the stirring and mixing mechanism for heating and stirring and mixing, and simultaneously introducing an inert gas into the stirring tank (2) through the first air inlet pipe; Step 3: Softening and kneading: the mixed raw materials in the two stirring tanks (2) are respectively introduced into the mixing box (61) in the kneading mechanism through the metering pump (5) and the pipeline (4) for softening and kneading; Step 4: Mould shaping: the raw materials kneaded and softened in the two mixing boxes in step 3 are respectively introduced into the explosion-proof flexible glass material mould and the heat-absorbing core material mould through the discharge pipe (69) for shaping; Step 5: Cooling and heat preservation: the flexible glass embryo and the heat-absorbing core layer formed in step 4 are placed in the mold for 1-2 minutes for heat preservation and standby; Step 6, embryo body pressing: the flexible glass embryo body is divided into two parts, and taken out from the mold. At the same time, the heat-absorbing core layer embryo body is taken out from the mold and separated into continuous geometric shapes with a cross-sectional size of 1mm-5mm, and evenly arranged on the surface of the first part of the flexible glass embryo body, and then the second part of the flexible glass embryo body is flattened on the heat-absorbing core layer, and an external force of 0.3MPa-1MPa is applied on the upper surface to connect the two parts of the flexible glass embryo body again; Step 7, calendering and shaping: the preliminarily pressed flexible glass embryo is further transferred between two calendering fixtures with a mirror effect. The surface temperature of the calendering fixture is set to 100°C to 180°C, and the temperature deviation of different parts does not exceed 0.5°C. The calendering fixture applies an external force of 0.1MPa to 1MPa to the surface of the flexible glass embryo for 0.5 minutes to 3 minutes. Step 7: After calendering, the semi-finished flexible glass product is placed in a tempering furnace with a temperature of 70° C. to 150° C. for annealing for 30 minutes; Step 8: After the flexible glass is cooled, it enters precision cutting and packaging; The stirring and mixing mechanism comprises a mounting platform (1), the top of the mounting platform (1) is fixedly connected to two stirring tanks (2), the outer surface of the stirring tank (2) is rotatably connected to a first gear (3), the outer surface of the first gear (3) is meshingly connected to a feeding mechanism connected to the stirring tank (2), the outer surface of the first gear (3) is drivingly connected to a driving mechanism, a sealing mechanism is provided in the two stirring tanks (2), a stirring mechanism is provided in both the two stirring tanks (2), one side of the stirring tank (2) is fixedly connected to a kneading mechanism connected to the mounting platform (1) via a pipeline (4), a metering pump (5) is provided on the pipeline (4), and one side of the stirring tank (2) is fixedly connected to a first air inlet pipe (6), and a valve is provided on the first air inlet pipe (6); The feeding mechanism comprises a plurality of second gears (11) of different sizes meshingly connected to the first gear (3); a first rotating shaft (12) is fixedly sleeved in the middle of the second gear (11); a feeding pipe (13) fixedly connected to the stirring tank (2) is rotatably connected to the outer surface of the first rotating shaft (12); a first bevel gear (14) is fixedly sleeved at the top of the first rotating shaft (12); a second bevel gear (15) is meshingly connected to the outer surface of the first bevel gear (14); a screw rod (16) rotatably connected to the feeding pipe (13) is fixedly sleeved in the middle of the second bevel gear (15); and a feeding funnel (17) fixedly connected to the stirring tank (2) is fixedly connected to the top of the feeding pipe (13); The sealing mechanism comprises a first electric telescopic rod (31) fixedly connected to the stirring tank (2); a sealing plate (32) slidably connected to the stirring tank (2) is fixedly connected to the bottom end of the first electric telescopic rod (31); a first rubber sealing ring (33) is fixedly connected to the bottom of the sealing plate (32); a mounting ring (34) fixedly connected to the stirring tank (2) is provided below the first rubber sealing ring (33); and a second rubber sealing ring (35) is fixedly connected to the top of the mounting ring (34); The stirring mechanism comprises a first transmission shaft (41) rotatably connected to the stirring tank (2); the first transmission shaft (41) is rotatably connected to the mounting platform (1); the outer surface of the first transmission shaft (41) is transmission-connected to the transmission mechanism; the bottom end of the first transmission shaft (41) is transmission-connected to the kneading mechanism; the outer surface of the first transmission shaft (41) is fixedly connected to a plurality of sliders (42); the outer surface of the sliders (42) is slidably connected to a plurality of transmission rings (43) slidably connected to the first transmission shaft (41); a connecting rod (44) is fixedly connected between the plurality of transmission rings (43); The top of the first transmission shaft (41) is fixedly connected to a mounting block (45), the bottom of the mounting block (45) is fixedly connected to a second electric telescopic rod (46), the bottom end of the second electric telescopic rod (46) is fixedly connected to the top of one of the transmission rings (43), the outer surface of the transmission ring (43) is fixedly connected to a plurality of stirring rods (47), the bottom of the stirring rod (47) is fixedly connected to a flexible steel wire rope (48), one end of the flexible steel wire rope (48) is fixedly connected to a striking ball (49), and a plurality of first electric heating plates (490) are fixedly connected inside the stirring tank (2); The kneading mechanism comprises a mixing box (61) fixedly connected to the mounting platform (1); one side of the mixing box (61) is rotatably connected to a third transmission shaft (62); one end of the third transmission shaft (62) is fixedly sleeved with a third bevel gear (63); the outer surface of the third bevel gear (63) is meshingly connected to a fourth bevel gear (64) fixedly sleeved with the first transmission shaft (41); the outer surface of the third transmission shaft (62) is fixedly sleeved with a third transmission gear (65); the outer surface of the third transmission gear (65) is meshingly connected to A fourth transmission gear (66) having two different numbers of teeth is connected, a stirring shaft (67) rotatably connected to the mixing box (61) is fixedly sleeved in the middle of the fourth transmission gear (66), a plurality of second electric heating plates (68) are fixedly connected in the mixing box (61), a discharge pipe (69) is fixedly connected to the bottom of the mixing box (61), a solenoid valve is provided on the discharge pipe (69), and a second air inlet pipe (690) is fixedly connected to one side of the mixing box (61), a valve is provided on the second air inlet pipe (690).

2. The method for preparing the self-explosion-proof flexible glass according to claim 1, characterized in that: The driving mechanism comprises a first motor (21) fixedly connected to the stirring tank (2); an output end of the first motor (21) is fixedly connected to a second rotating shaft (22) via a coupling; an outer surface of the second rotating shaft (22) is fixedly sleeved with a driving gear (23) meshingly connected to the first gear (3).

3. The method for preparing the self-explosion-proof flexible glass according to claim 1, characterized in that: The transmission mechanism comprises a second motor (51) fixedly connected to the mounting platform (1); an output end of the second motor (51) is fixedly connected to a second transmission shaft (52) rotatably connected to the mounting platform (1) via a coupling; a first transmission gear (53) is fixedly sleeved on an outer surface of the second transmission shaft (52); and a second transmission gear (54) fixedly sleeved on an outer surface of the first transmission gear (53) is meshingly connected to a second transmission gear (54) fixedly sleeved on the first transmission shaft (41).

4. A self-explosion-proof flexible glass, characterized in that: The anti-self-explosion flexible glass prepared by the method for preparing the anti-self-explosion flexible glass according to any one of claims 1 to 3 comprises a flexible glass material and a heat-absorbing core layer material, wherein the flexible glass material comprises the following raw material components: Transparent organic resin: 55-95 parts Flexibility improver: 5-40 parts Ultraviolet absorber: 0.1-5 parts Free radical scavenger: 0.1-0.6 parts; The heat absorbing core layer material comprises the following raw material components: Transparent organic resin: 55-95 parts Flexibility improver: 5-40 parts Carbon nanotubes: 0.1-5 parts Infrared absorber: 0.01-2 parts Free radical scavenger: 0.1 part to 0.6 part.

Citation Information

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