二维纳米成炭发泡剂及其阻燃复合材料和制备方法

By preparing a two-dimensional nano-carbonizing foaming agent with a nanosheet structure and compounding it with ammonium polyphosphate, the problems of long synthesis time, high solvent consumption and insufficient thermal stability of triazine-based carbonizing agents were solved, achieving efficient and environmentally friendly flame retardant effect and improved mechanical properties of polymers.

CN116903928BActive Publication Date: 2026-07-17BEIJING INST OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BEIJING INST OF TECH
Filing Date
2023-06-20
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing triazine-based charring agents suffer from problems such as long synthesis time, high solvent consumption, insufficient thermal stability, low nitrogen content, low char yield, and poor flame retardant effect, which affect the flame retardant and mechanical properties of polymer materials.

Method used

A two-dimensional nano-carbonizing foaming agent with a nanosheet structure was prepared by reacting carbon-containing organic acids with melamine and metal ion aqueous solution. This agent was then compounded with ammonium polyphosphate to form an intumescent flame retardant system, which was then used to blend with polymers to form flame retardant composite materials.

Benefits of technology

It achieves flame retardant effects with high nitrogen content, rapid foaming into char, good compatibility, and low cost, improves the flame retardant and mechanical properties of polymers, and the preparation process is environmentally friendly and simple.

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Abstract

本发明公开了一种二维纳米成炭发泡剂,具有纳米片层结构,通过含碳有机酸水溶液与三聚氰胺、金属离子水溶液反应得到。本发明的二维纳米成炭发泡剂不仅低氯残留、成炭量高、发泡效果好、热稳定性高、不易水解,而且对聚合物基体的力学性能损伤小或无损伤,同时制备方法简单快捷,制备成本低,安全环保。与聚磷酸铵复配制成膨胀型阻燃体系,可以较低的添加量达到优异的阻燃性能。添加到工程聚合物产品中制成阻燃复合材料,既可提高聚合物的阻燃性能,又能使聚合物保持良好的力学性能。
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