Mosquito-proof antibacterial fabric and jacket

Abstract

The application relates to the technical field of textiles, and particularly discloses an anti-mosquito and antibacterial fabric and a hunting jacket. The anti-mosquito and antibacterial fabric comprises a base cloth layer, an anti-mosquito and antibacterial layer arranged on one side of the base cloth layer, and an inner layer arranged on the side, away from the base cloth layer, of the anti-mosquito and antibacterial layer. The base cloth layer comprises 240-380 parts of base fibers and 30-50 parts of functional components by weight; the anti-mosquito and antibacterial layer comprises 150-250 parts of antibacterial fibers and 100-150 parts of anti-mosquito fibers; and the inner layer comprises 100-200 parts of warm-keeping carbon fibers, 50-100 parts of ramie fibers and 20-50 parts of ceramic powder fibers. The anti-mosquito fabric has excellent and long-lasting anti-mosquito and antibacterial effects. In addition, the hunting jacket is made of the anti-mosquito and antibacterial fabric, has excellent anti-mosquito and antibacterial performance, and has long-lasting anti-mosquito and antibacterial effects.

Description

TECHNICAL FIELD

[0001] The application relates to the technical field of textiles, and particularly discloses an anti-mosquito and antibacterial fabric and a jacket. BACKGROUND

[0002] The jacket is an important equipment for outdoor activities, and becomes the first choice of people for outdoor activities because of good air permeability, windproofness and waterproofness. With the rapid development of outdoor hiking and mountaineering, people have put forward new requirements for the comfort and functionality of outdoor clothes in order to resist the harm of outdoor harsh environment to the human body. In summer, there are many mosquitoes and bacteria outside, and how to prevent mosquito bites and bacterial growth becomes the focus of people. People need the jacket to not only quickly absorb moisture, but also have good anti-mosquito and antibacterial effects. Therefore, the development of the anti-mosquito and antibacterial fabric as the preparation fabric of the jacket can better meet the consumer demand and improve the market competitiveness of the product.

[0003] For the related technologies in the above, the inventors find that the anti-mosquito and antibacterial fabric used by the clothes with anti-mosquito and antibacterial effects on the market adopts a chemical dipping or coating method to fix the anti-mosquito and antibacterial agent on the fabric. Although this method can achieve certain anti-mosquito and antibacterial effects, the anti-mosquito and antibacterial agent is prone to falling off and unstable, resulting in poor anti-mosquito and antibacterial effects and durability of the fabric. SUMMARY

[0004] In order to improve the durability of the anti-mosquito and antibacterial effects of the fabric and improve the anti-mosquito and antibacterial performance of the fabric, the application provides an anti-mosquito and antibacterial fabric and a jacket.

[0005] In a first aspect, the application provides an anti-mosquito and antibacterial fabric, which adopts the following technical solution:

[0006] The anti-mosquito and antibacterial fabric comprises a base cloth layer, an anti-mosquito and antibacterial layer arranged on one side of the base cloth layer, and an inner layer arranged on the side of the anti-mosquito and antibacterial layer away from the base cloth layer. The base cloth layer comprises 240-380 parts by weight of base fibers and 30-50 parts by weight of functional components. The anti-mosquito and antibacterial layer comprises 150-250 parts by weight of antibacterial fibers and 100-150 parts by weight of anti-mosquito fibers. The inner layer comprises 100-200 parts by weight of warm-keeping carbon fibers, 50-100 parts by weight of ramie fibers and 20-50 parts by weight of ceramic powder fibers.

[0007] Through the above technical solution, the base fibers of the base cloth layer make the fabric have good wear resistance and washing resistance, and the addition of the functional components endows the base cloth layer of the fabric with more comprehensive performance. The inner layer mainly improves the warmth and comfort of the fabric. The warm-keeping carbon fibers and the ceramic powder fibers can lock heat and improve the warmth-keeping effect of the fabric. The ramie fibers have excellent air permeability and moisture absorption, can keep the skin dry and comfortable, and reduce bacterial growth and odor generation.

[0008] The mosquito-repellent and antibacterial fibers in the mosquito-repellent and antibacterial layer are functional fibers that are directly woven into the fabric through fiber integration, rather than achieving mosquito-repellent and antibacterial properties through surface coating or impregnation. This integration method makes the mosquito-repellent and antibacterial properties an integral part of the fabric itself, ensuring the stability and durability of these functional fibers in the fabric. It has stronger water resistance and will not easily fall off or shift even after repeated washing and mechanical friction, so it can continue to play its mosquito-repellent and antibacterial functions, significantly enhancing the durability of the fabric's mosquito-repellent and antibacterial effects.

[0009] Optionally, the antibacterial fiber comprises, by weight, 12-18 parts graphene, 20-30 parts polyethyleneimine, 2-6 parts silver nitrate and 30-40 parts polyethylene.

[0010] By adopting the above technical solution, compared with traditional antibacterial materials, graphene has the advantages of high surface activity, high reactivity and high biocompatibility. Its antibacterial principle is mainly through mechanical cutting. When bacteria adhere to the graphene fabric, the graphene physically destroys the bacteria through its sharp boundaries, thereby inhibiting the growth and reproduction of bacteria. This antibacterial mechanism is not only effective but also broad-spectrum, and can inhibit the growth of a variety of bacteria.

[0011] Silver nitrate provides silver ions to the antibacterial fibers. Silver ions are known for their broad-spectrum antibacterial effects. When graphene combines with silver ions, its antibacterial properties are significantly enhanced, which can more effectively inhibit and kill bacteria, fungi and other microorganisms, thus improving the antibacterial properties of the fabric. Graphene contains oxygen atoms, which can easily form hydrogen bonds, covalent bonds and other bonds, and can also form a stable composite structure through electrostatic adsorption. It has high chemical stability, and the silver ions in the graphene-silver composite material can be continuously released, making the antibacterial effect durable. After multiple washes and uses, the fabric can still maintain excellent antibacterial properties, significantly improving the fabric's washability and the durability of the antibacterial effect.

[0012] Optionally, the method for preparing the antibacterial fiber includes the following steps:

[0013] After dispersing graphene in water and sonicating for 30-40 minutes, polyethyleneimine was added, and sonication was continued. The pH was adjusted to 7-8 to obtain the dispersion.

[0014] Silver nitrate was added to the dispersion, and ammonia was added until the precipitate disappeared. The mixture was then microwaved at 100-120℃, cooled, and freeze-dried to obtain a graphene-silver blend.

[0015] The graphene-silver blend and polyethylene were mixed and added to water, and the mixture was heated and stirred at 40-60℃ for 6-8 hours to obtain the spinning solution. Antibacterial fibers were then prepared by electrospinning.

[0016] By adopting the above technical solution, the addition of silver ions enhances the antibacterial activity of graphene in antibacterial fibers. The graphene-silver composite material is used to prepare antibacterial fibers through electrospinning, so that the antibacterial fibers combine the long-lasting and stable antibacterial properties of graphene and silver ions. Even after multiple washes and uses, the antibacterial fibers can still maintain their stable antibacterial effect.

[0017] Optionally, by weight, the mosquito-repellent fiber comprises 20-25 parts bamboo fiber, 20-30 parts polyethylene, 8-12 parts mosquito-repellent microcapsules, and 30-40 parts polyester fiber; the mosquito-repellent microcapsules comprise permethrin, melamine resin, and tetrachlorpyrifos in a mass ratio of (2-8):(3-7):1.

[0018] By adopting the above technical solutions, both permethrin and tetrafluoroethylene have highly efficient, low-toxicity and long-lasting mosquito-repellent effects. Tetrafluoroethylene has excellent knockdown properties against mosquitoes, while permethrin has a lethal effect. The combination of the two as the core material of mosquito-repellent microcapsules can significantly enhance the efficacy and improve the dispersibility and stability of permethrin and tetrafluoroethylene in the microcapsules. This helps the two to be better and more evenly dispersed in the microcapsules, preventing precipitation or aggregation, thereby effectively prolonging the mosquito-repellent activity and durability of the mosquito-repellent fiber.

[0019] Optionally, the method for preparing the mosquito-repellent fiber includes the following steps:

[0020] Mosquito-repellent microcapsules were prepared by in-situ polymerization using permethrin and tetrachlorpyrifos as core materials and melamine resin as wall material. Mosquito-repellent fibers were prepared by mixing bamboo fiber and polypropylene as core material and mixing mosquito-repellent microcapsules and polyester fiber as skin material through core-skin composite spinning.

[0021] By adopting the above technical solution, mosquito-repellent fibers are prepared by core-sheath composite spinning. Polyester fiber, as the core layer, provides mechanical strength to the mosquito-repellent fiber. Microcapsule technology can form a physical barrier between the core material and the wall material, allowing the core material to slowly release through the wall material and exert its effect. Polyester fiber with added mosquito-repellent microcapsules as the core layer can stably and slowly release the effective ingredients in the mosquito-repellent microcapsules, thereby achieving a long-lasting mosquito-repellent effect. Bamboo fiber and polypropylene composite as the sheath layer further increases the spinnability, strength and durability of the mosquito-repellent fiber.

[0022] In addition, bamboo fiber has natural antibacterial properties, which can effectively inhibit the growth of bacteria and enhance the antibacterial properties of mosquito-repellent fibers. On the other hand, bamboo fiber has a special microporous structure inside, which, as the outer layer of mosquito-repellent fibers, can ensure that the active ingredients in mosquito-repellent microcapsules can be slowly released through the outer layer to achieve the mosquito-repellent effect.

[0023] Optionally, by weight, the functional components include 50-70 parts phenolic resin, 60-80 parts graphene dispersion slurry, 20-30 parts tea tree oil, 15-20 parts chitosan, 40-50 parts polar solution, 0.3-0.8 parts leveling agent, 1-4 parts waterproofing agent and 6-13 parts curing agent.

[0024] By adopting the above technical solution, phenolic resin has good heat resistance, corrosion resistance and mechanical strength, which can effectively improve the wear resistance and heat resistance of the base fabric layer.

[0025] Graphene not only has excellent antibacterial properties, but also good electrical conductivity, thermal conductivity, and UV resistance. As a functional component, it can be adsorbed onto the outermost base layer of a fabric to enhance its mosquito-repellent and antibacterial properties, as well as give it antistatic, warm, and UV-resistant properties. In addition, graphene is an ultra-thin and strong material that can form a physical barrier that prevents mosquitoes from penetrating the base layer, effectively preventing mosquito bites.

[0026] Tea tree oil and chitosan are both natural antibacterial agents with strong antibacterial, anti-inflammatory and insect-repellent effects. The combination of the two can further enhance the antibacterial and mosquito-repellent properties of the base fabric layer.

[0027] Optionally, by weight, the matrix fibers include 100-150 parts polyamide fiber, 50-80 parts acrylic fiber, 100-120 parts polyester fiber and 30-70 parts asbestos fiber.

[0028] By adopting the above technical solutions, the base fabric layer prepared from polyamide fiber, acrylic fiber, polyester fiber and asbestos fiber can form the first mosquito-proof and antibacterial barrier of the fabric. These fibers have high strength and abrasion resistance, which makes the base fabric layer less prone to damage during use and improves the durability of the fabric.

[0029] Optionally, the preparation method of antibacterial mosquito-repellent fabric includes the following steps:

[0030] The base fabric yarn is prepared by blending the base fibers, and then woven to obtain a pre-treated base fabric layer. The base fabric yarn is then woven to obtain a pre-treated base fabric layer. The pre-treated base fabric layer is then immersed in functional components for padding, drying and curing to obtain the base fabric layer. Antibacterial fibers and mosquito-repellent fibers are blended to prepare antibacterial and mosquito-repellent yarn, and then woven to obtain a mosquito-repellent and antibacterial layer. Inner layer yarn is blended with heat-insulating carbon fiber, ramie fiber and ceramic powder fiber, and then woven to obtain the inner layer. The woven base fabric layer, mosquito-repellent and antibacterial layer and inner layer are then stacked in sequence, and adjacent fabric layers are sewn together with metal wires and then glued.

[0031] By adopting the above technical solutions, the fabric successfully achieves multiple functions such as antibacterial, mosquito repellent, warmth retention, and breathability and moisture wicking through the blending of different fiber materials in the base fiber. Immersing the pre-treated base fabric layer in the functional components and then rolling and drying it significantly enhances the antistatic, antibacterial, mosquito repellent, and UV-resistant properties of the outer base fabric layer. After weaving, the three-layer fabric structure is sewn together with metal filaments and then glued to form a fabric, which further enhances the stability and durability of the fabric.

[0032] Secondly, this application provides a windproof jacket made from a mosquito-repellent and antibacterial fabric of this application.

[0033] By adopting the above technical solution, the down jacket of this application has excellent and long-lasting mosquito repellent and antibacterial effects.

[0034] In summary, this application has the following beneficial effects:

[0035] 1. The fabric of this application includes a base fabric layer, a mosquito-repellent and antibacterial layer, and an inner layer. The inner layer gives the fabric better warmth retention, breathability, moisture wicking, and comfort. The base fabric layer gives the fabric good comprehensive properties such as waterproofing, UV protection, breathability, and moisture wicking. By integrating mosquito-repellent and antibacterial fibers into the fabric, a mosquito-repellent and antibacterial layer is formed, making the mosquito-repellent and antibacterial properties an integral part of the fabric itself. This significantly enhances the durability of the fabric's mosquito-repellent and antibacterial properties and improves the fabric's mosquito-repellent and antibacterial characteristics.

[0036] 2. In the mosquito-repellent fiber of this application, mosquito-repellent microcapsules are incorporated into the mosquito-repellent fiber through core-sheath composite spinning. The core material of the mosquito-repellent microcapsule, permethrin and tetrachlorpyrifos, are combined as effective ingredients, which significantly improves the mosquito-repellent and insect-repellent properties of the mosquito-repellent fiber. At the same time, the core material can be slowly released outward through the wall material of the mosquito-repellent microcapsule and exert its effect, which significantly enhances the effectiveness and durability of the fabric's mosquito-repellent performance.

[0037] 3. The antibacterial fiber of this application contains graphene and silver ions to form a graphene-silver composite material, which significantly improves the antibacterial properties of the antibacterial fiber; the graphene in the functional components of the base fabric layer of this application further enhances the antibacterial, antistatic, and UV protection properties of the fabric, while tea tree oil and chitosan further enhance the antibacterial and insect-repellent effects of the fabric. Detailed Implementation

[0038] The present application will be further described in detail below with reference to preparation examples, embodiments and comparative examples.

[0039] Material source

[0040] Unless otherwise specified, the raw materials used in the preparation examples, embodiments, and comparative examples in this application are all commercially available products, specifically:

[0041] Graphene is a nanoscale powder with a thickness of 0.55-3.74 nm and a specific surface area of ​​420-550 m². 2 / g, number of layers < 3 layers, D50 < 10μm;

[0042] Graphene dispersion slurry, with an effective component of 80%;

[0043] Permethrin, tetrachlorfon, tea tree oil, and chitosan are all industrial grade.

[0044] Melamine resin, selected from Weng Kaier Technology Co., Ltd., CYMEL385;

[0045] The phenolic resin was selected from Foshan Jieke New Materials Co., Ltd., T365FA;

[0046] The leveling agent was selected from Shanghai Guangbai New Materials Co., Ltd., BYK333;

[0047] The waterproofing agent was selected from Guangzhou Qiantai Chemical Co., Ltd., and the waterproofing agent is C8.

[0048] The curing agent was selected from Shandong Pinshang New Materials Co., Ltd., specifically 3650 polyamide curing agent.

[0049] Examples of matrix fiber preparation: 1.1-1.3

[0050] Preparation Example 1.1

[0051] The matrix fiber, raw materials and dosages are shown in Table 1.

[0052] Table 1

[0053]

[0054] The preparation method of the above-mentioned matrix fibers is as follows:

[0055] The product is obtained by mixing polyamide fiber, acrylic fiber, polyester fiber and asbestos fiber in a certain proportion.

[0056] Preparation Examples 1.2-1.3

[0057] The preparation method of the matrix fiber differs from that of Preparation Example 1.1 in that the raw materials and their amounts are shown in Table 1, while the other steps are the same as those in Preparation Example 1.1.

[0058] Examples of preparation of functional components 2.1-2.7

[0059] Preparation Example 2.1

[0060] The functional components, raw materials and dosages are shown in Table 2. The polar solution used is ethanol.

[0061] Table 2

[0062]

[0063]

[0064] The preparation method of the above-mentioned functional components includes the following steps:

[0065] Phenolic resin, graphene dispersion slurry, tea tree oil, chitosan, leveling agent, ethanol, and waterproofing agent are mixed and stirred until the viscosity is controlled at 1000 CPS-1300 CPS. Then, a curing agent is added and stirring is continued for 5 minutes. The mixture is then filtered through a 200-mesh nylon filter to obtain the final product.

[0066] Preparation Examples 2.2-2.3

[0067] The preparation method of the functional components differs from that of Preparation Example 2.1 in that the raw materials and their amounts are shown in Table 2, while the other steps are the same as those in Preparation Example 2.1.

[0068] Preparation Example 2.4

[0069] The preparation method of the functional component differs from that of Preparation Example 2.1 in that no graphene dispersion slurry was added, while all other steps are the same as in Preparation Example 2.1.

[0070] Preparation Example 2.5

[0071] The preparation method of the functional component differs from that of Preparation Example 2.1 in that tea tree oil and chitosan were not added, while the other steps are the same as those in Preparation Example 2.1.

[0072] Preparation Example 2.6

[0073] The preparation method of the functional component differs from that of Preparation Example 2.1 in that chitosan was not added, while all other steps are the same as in Preparation Example 2.1.

[0074] Preparation Example 2.7

[0075] The preparation method of the functional component differs from that of Preparation Example 2.1 in that tea tree oil was not added, while all other steps are the same as in Preparation Example 2.1.

[0076] Examples of antibacterial fiber preparation: 3.1-3.4

[0077] Preparation Example 3.1

[0078] The raw materials and dosages of the antibacterial fiber are shown in Table 3.

[0079] Table 3

[0080]

[0081] The method for preparing the above-mentioned antibacterial fiber includes the following steps:

[0082] S1. After dispersing graphene in water and sonicating for 30 minutes, add polyethyleneimine and continue sonicating for 10 minutes. Adjust the pH to 8 to obtain dispersion A.

[0083] S2. Add silver nitrate to dispersion A, and simultaneously add ammonia until the precipitate disappears to obtain dispersion B;

[0084] S3. Transfer dispersion B to a microwave synthesizer, heat to 100℃ and microwave for 5 minutes, cool, and freeze dry in a vacuum freeze dryer to obtain graphene-silver blend.

[0085] S4. The graphene-silver blend and polyethylene are mixed and added to water, and heated and stirred at 40°C for 8 hours to obtain the spinning solution. Antibacterial fibers are then prepared by electrospinning.

[0086] Preparation Example 3.2

[0087] The antibacterial fiber, with its raw materials and dosages as shown in Table 3, is prepared using the following steps:

[0088] S1. After dispersing graphene in water and sonicating for 40 minutes, add polyethyleneimine and continue sonicating for 10 minutes. Adjust the pH to 7 to obtain dispersion A.

[0089] S2. Add silver nitrate to dispersion A, and simultaneously add ammonia until the precipitate disappears to obtain dispersion B;

[0090] S3. Transfer dispersion B to a microwave synthesizer, heat to 120℃ and microwave for 5 minutes, cool, and freeze dry in a vacuum freeze dryer to obtain graphene-silver blend;

[0091] S4. The graphene-silver blend and polyethylene are mixed and added to water, heated and stirred at 60°C for 6 hours to obtain the spinning solution, and antibacterial fibers are prepared by electrospinning.

[0092] Preparation Example 3.3

[0093] The antibacterial fiber, with its raw materials and dosages as shown in Table 3, is prepared using the following steps:

[0094] S1. After dispersing graphene in water and sonicating for 30 minutes, add polyethyleneimine and continue sonicating for 10 minutes. Adjust the pH to 8 to obtain dispersion A.

[0095] S2. Add silver nitrate to dispersion A, and simultaneously add ammonia until the precipitate disappears to obtain dispersion B;

[0096] S3. Transfer dispersion B to a microwave synthesizer, heat to 110℃ and microwave for 5 minutes, cool, and freeze dry in a vacuum freeze dryer to obtain graphene-silver blend;

[0097] S4. The graphene-silver blend and polyethylene are mixed and added to water, heated and stirred at 50°C for 7 hours to obtain the spinning solution, and antibacterial fibers are prepared by electrospinning.

[0098] Preparation Example 3.4

[0099] The antibacterial fiber differs from that in Preparation Example 3.1 in that its preparation method includes the following steps:

[0100] S1. After dispersing graphene in water and sonicating for 30 minutes, add polyethyleneimine and continue sonicating for 10 minutes. Adjust the pH to 8 to obtain the dispersion.

[0101] S2. The dispersion was transferred to a microwave synthesizer, heated to 100°C and microwaved for 5 minutes, then cooled and freeze-dried in a vacuum freeze dryer to obtain the graphene blend.

[0102] S3. The graphene blend and polyethylene are mixed and added to water, and heated and stirred at 40°C for 8 hours to obtain the spinning solution. Antibacterial fibers are then prepared by electrospinning.

[0103] Examples of mosquito-repellent fiber preparation: 4.1-4.4

[0104] Preparation Example 4.1

[0105] The mosquito-repellent fiber, with its raw materials and dosages as shown in Table 4, includes mosquito-repellent microcapsules containing permethrin, melamine resin, and tetrachlorpyrifos in a mass ratio of 2:3:1.

[0106] Table 4

[0107]

[0108] The preparation method of the above-mentioned mosquito-repellent fiber includes the following steps:

[0109] S1. Mosquito-repellent microcapsules are prepared by in-situ polymerization using permethrin and tetrachlorpyrifos as core materials and melamine resin as wall material; S2. Mosquito-repellent fibers are prepared by mixing bamboo fiber and polypropylene as core material and mixing mosquito-repellent microcapsules and polyester fiber as skin material through core-skin composite spinning.

[0110] Preparation Example 4.2

[0111] The preparation method of the mosquito-repellent fiber differs from that of Preparation Example 4.1 in that the raw materials and their amounts are shown in Table 4. The mosquito-repellent microcapsules include permethrin, melamine resin and tetrachlorpyrifos in a mass ratio of 5:5:1. All other steps are the same as those in Preparation Example 4.1.

[0112] Preparation Example 4.3

[0113] The preparation method of the mosquito-repellent fiber differs from that of Preparation Example 4.1 in that the raw materials and their amounts are shown in Table 4. The mosquito-repellent microcapsules include permethrin, melamine resin and tetrachlorpyrifos in a mass ratio of 8:7:1. All other steps are the same as those in Preparation Example 4.1.

[0114] Preparation Example 4.4

[0115] The preparation method of the mosquito-repellent fiber differs from that of Preparation Example 4.1 in that the tetrachlorpyrifos in the mosquito-repellent microcapsules is replaced with an equal mass of permethrin, while the other steps are the same as those in Preparation Example 4.1.

[0116] Example

[0117] Example 1

[0118] A mosquito-repellent and antibacterial fabric, the components and amounts of each raw material are shown in Table 5, wherein the matrix fiber is prepared by Preparation Example 1.1, the functional component is prepared by Preparation Example 2.1, the antibacterial fiber is prepared by Preparation Example 3.1, and the mosquito-repellent fiber is prepared by Preparation Example 4.1.

[0119] Table 5

[0120]

[0121] The preparation method of the above-mentioned mosquito-repellent and antibacterial fabric includes the following steps:

[0122] S1. The base fabric yarn is prepared by blending the matrix fibers, and a pretreated base fabric layer is prepared by weaving. The pretreated base fabric layer is immersed in the functional components for padding, drying and curing to obtain the base fabric layer.

[0123] S2. Antibacterial and mosquito-repellent fibers are blended to produce antibacterial and mosquito-repellent yarn, which is then woven to produce a mosquito-repellent and antibacterial layer.

[0124] S3. The inner layer yarn is obtained by blending thermal insulation carbon fiber, ramie fiber and ceramic powder fiber, and then woven to obtain the inner layer.

[0125] S4. Stack the woven base fabric layer, mosquito-proof and antibacterial layer and inner layer in sequence, sew the adjacent fabric layers together with metal wires and then perform a heat sealing treatment.

[0126] Examples 2-6

[0127] A mosquito-repellent and antibacterial fabric differs from Example 1 in that the components and amounts of each raw material are shown in Table 5, and the sources of the matrix fiber, functional components, antibacterial fiber, and mosquito-repellent fiber are shown in Table 6. All other steps are the same as in Example 1.

[0128] Table 6

[0129]

[0130] Example 7

[0131] A mosquito-repellent and antibacterial fabric, which differs from Example 1 in that the antibacterial fiber is prepared by Preparation Example 3.4, while the other steps are the same as in Example 1.

[0132] Example 8

[0133] A mosquito-repellent and antibacterial fabric, which differs from Example 1 in that the mosquito-repellent fiber is prepared by Preparation Example 4.4, while the other steps are the same as in Example 1.

[0134] Example 9

[0135] A mosquito-repellent and antibacterial fabric, which differs from Example 1 in that the functional components are prepared according to Preparation Example 2.4, while the other steps are the same as in Example 1.

[0136] Example 10

[0137] A mosquito-repellent and antibacterial fabric, which differs from Example 1 in that the functional components are prepared by Preparation Example 2.5, while the other steps are the same as in Example 1.

[0138] Example 11

[0139] A mosquito-repellent and antibacterial fabric, which differs from Example 1 in that the functional components are prepared according to Preparation Example 2.6, while the other steps are the same as in Example 1.

[0140] Example 12

[0141] A mosquito-repellent and antibacterial fabric, which differs from Example 1 in that the functional components are prepared according to Preparation Example 2.7, while the other steps are the same as in Example 1.

[0142] Comparative Example

[0143] Comparative Example 1

[0144] A mosquito-repellent and antibacterial fabric, which differs from Example 1 in that step S1 specifically involves: blending the base fibers to obtain the base fabric yarn, and then weaving it to obtain the base fabric layer. All other steps are the same as in Example 1.

[0145] Comparative Example 2

[0146] A mosquito-repellent and antibacterial fabric differs from Example 1 in that the antibacterial fiber used is a composite fiber of equal mass, comprising bamboo fiber and polyester fiber in a mass ratio of 3:1. All other steps are the same as in Example 1.

[0147] Comparative Example 3

[0148] A mosquito-repellent and antibacterial fabric, which differs from Example 1 in that the mosquito-repellent fiber used is a composite fiber of equal mass, the composite fiber including polyester fiber and acrylic fiber in a mass ratio of 1:1, and the other steps are the same as in Example 1.

[0149] Comparative Example 4

[0150] A mosquito-repellent and antibacterial fabric differs from Example 1 in that the antibacterial fiber used is composite fiber A of equal mass, and the mosquito-repellent fiber used is composite fiber B of equal mass. Composite fiber A includes bamboo fiber and polyester fiber in a mass ratio of 3:1, and composite fiber B includes polyester fiber and acrylic fiber in a mass ratio of 1:1. All other steps are the same as in Example 1.

[0151] Performance testing

[0152] The mosquito-repellent and antibacterial fabrics of Examples 1-12 and Comparative Examples 1-4 were tested for mosquito-repellent and antibacterial properties, as well as the mosquito-repellent and antibacterial fabrics after 50 washes. Each test was performed 3 times, and the average value was recorded in Table 7.

[0153] Mosquito repellency performance testing: The mosquito repellency performance of the fabric was tested by placing it in a repulsion tester in accordance with GB / T30126-2013 "Test and evaluation of mosquito repellency performance of textiles".

[0154] Antibacterial performance testing: The antibacterial performance of the fabric was tested according to GB / T20944.3-2008 "Evaluation of antibacterial properties of textiles - Part 3: Vibration method".

[0155] Table 7

[0156]

[0157]

[0158] As shown in Table 7, the performance test data indicates that the mosquito-repellent and antibacterial fabric of this application has a mosquito repellency rate of ≥81.2%, demonstrating its strong mosquito-repellent and insect-repellent effect. The fabric also exhibits an inhibition rate of 97.2-99.2% against Staphylococcus aureus, 94.3-95.6% against Escherichia coli, and 90.3-91.2% against Candida albicans, demonstrating its effective antibacterial properties. Furthermore, the fabric maintains high mosquito-repellent and insect-repellent effects and antibacterial properties even after 50 washes, indicating its long-lasting mosquito-repellent and antibacterial performance.

[0159] According to the performance test data of Examples 1-6 and Comparative Examples 1-4, it can be seen that the fabric uses a blend of mosquito-repellent and antibacterial fibers to prepare a mosquito-repellent and antibacterial layer as part of the fabric. Through fiber integration, the mosquito-repellent and antibacterial properties become part of the fabric itself, which significantly enhances the mosquito-repellent and antibacterial properties of the fabric. Even after multiple washes, it still has a significant mosquito-repellent and antibacterial effect, effectively improving the durability of the fabric's mosquito-repellent and antibacterial effect. The use of functional components further enhances the mosquito-repellent and antibacterial properties of the fabric.

[0160] According to the performance test data of Examples 1-6 and Example 7, the addition of silver ions gives the antibacterial fiber stronger antibacterial properties. Compared with the fabric made of antibacterial fiber with only graphene added as an effective antibacterial component, the graphene-silver composite component effectively enhances the antibacterial properties of the fabric made of antibacterial fiber and can maintain a stable antibacterial effect after multiple washes.

[0161] According to the performance test data of Examples 1-6 and Example 8, both permethrin and tetrachlorpyrifos have highly efficient, low-toxicity and long-lasting mosquito repellent effects. The fabric made of mosquito repellent fibers prepared by combining permethrin and tetrachlorpyrifos with mosquito repellent microcapsules has a stronger mosquito repellent and insect-repelling effect than the fabric made of mosquito repellent fibers prepared by mosquito repellent microcapsules containing only permethrin.

[0162] According to the performance test data of Examples 1-6 and Examples 9-12, the graphene in the functional components further enhances the antibacterial properties of the fabric, and the addition of tea tree oil and chitosan can effectively improve the mosquito and insect repellent effect of the fabric. Moreover, the mosquito and insect repellent effect is better when tea tree oil and chitosan are used in combination.

[0163] This specific embodiment is merely an explanation of this application and is not intended to limit it. After reading this specification, those skilled in the art can make modifications to this embodiment without contributing any inventive step, but such modifications are protected by patent law as long as they fall within the scope of the claims of this application.

Claims

1. A mosquito-repellent and antibacterial fabric, characterized in that, It includes a base fabric layer, a mosquito-proof and antibacterial layer disposed on one side of the base fabric layer, and an inner layer disposed on the side of the mosquito-proof and antibacterial layer away from the base fabric layer; By weight, the base fabric layer comprises 240-380 parts of matrix fibers and 30-50 parts of functional components. The matrix fibers comprise 100-150 parts of polyamide fibers, 50-80 parts of acrylic fibers, 100-120 parts of polyester fibers, and 30-70 parts of asbestos fibers. The functional components comprise 50-70 parts of phenolic resin, 60-80 parts of graphene dispersion slurry, 20-30 parts of tea tree oil, 15-20 parts of chitosan, 40-50 parts of polar solution, 0.3-0.8 parts of leveling agent, 1-4 parts of waterproofing agent, and 6-13 parts of curing agent. The mosquito-repellent and antibacterial layer comprises 150-250 parts of antibacterial fiber and 100-150 parts of mosquito-repellent fiber. The antibacterial fiber comprises 12-18 parts of graphene, 20-30 parts of polyethyleneimine, 2-6 parts of silver nitrate, and 30-40 parts of polyethylene. The mosquito-repellent fiber comprises 20-25 parts of bamboo fiber, 20-30 parts of polyethylene, 8-12 parts of mosquito-repellent microcapsules, and 30-40 parts of polyester fiber. The mosquito-repellent microcapsules comprise permethrin, melamine resin, and tetrachlorpyrifos in a mass ratio of (2-8):(3-7):

1. The inner layer comprises 100-200 parts of thermal insulation carbon fiber, 50-100 parts of ramie fiber, and 20-50 parts of ceramic powder fiber.

2. The mosquito-repellent and antibacterial fabric according to claim 1, characterized in that, The method for preparing the antibacterial fiber includes the following steps: After dispersing graphene in water and sonicating for 30-40 minutes, polyethyleneimine was added, and sonication was continued. The pH was adjusted to 7-8 to obtain the dispersion. Silver nitrate was added to the dispersion, and ammonia was added until the precipitate disappeared. The mixture was then microwave-heated, cooled, and freeze-dried at 100-120°C to obtain a graphene-silver blend. The graphene-silver blend and polyethylene were mixed and added to water, and the mixture was heated and stirred at 40-60℃ for 6-8 hours to obtain the spinning solution. Antibacterial fibers were then prepared by electrospinning.

3. The mosquito-repellent and antibacterial fabric according to claim 1, characterized in that, The method for preparing the mosquito-repellent fiber includes the following steps: Mosquito-repellent microcapsules were prepared by in-situ polymerization using permethrin and tetrachlorpyrifos as core materials and melamine resin as wall material. Mosquito-repellent fibers are prepared by mixing bamboo fiber and polypropylene as the core material, and mixing mosquito-repellent microcapsules and polyester fiber as the outer layer material through core-sheath composite spinning.

4. The mosquito-repellent and antibacterial fabric according to claim 1, characterized in that, Its preparation method includes the following steps: The base fabric yarn is prepared by blending the matrix fibers, and the pretreated base fabric layer is prepared by weaving. The pretreated base fabric layer is immersed in the functional components and then subjected to padding, drying and curing to obtain the base fabric layer. Antibacterial and mosquito-repellent fibers are blended to produce antibacterial and mosquito-repellent yarn, which is then woven to produce a mosquito-repellent and antibacterial layer. The inner layer yarn is obtained by blending thermal insulation carbon fiber, ramie fiber and ceramic powder fiber, and then woven to form the inner layer. The woven base fabric layer, mosquito-proof and antibacterial layer, and inner layer are stacked in sequence, and the adjacent fabric layers are sewn together with fine metal wires and then glued together.

5. A mosquito-repellent and antibacterial windbreaker, made of a mosquito-repellent and antibacterial fabric as described in any one of claims 1-4.

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