Apparatus and method for manufacturing laminated electrode body
By using a multi-layer drum and cutting component manufacturing device, the positive electrode, separator and negative electrode in the lithium-ion secondary battery are efficiently stacked, solving the problems of low production efficiency and poor performance in the prior art, and achieving high-speed and continuous Laminated electrode body manufacture.
Patent Information
- Application Number
- CN202411441831.2
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Priority Date
- 2019-03-29
- Filing Date
- 2020-03-11
- Publication Date
- 2025-02-18
AI Technical Summary
It is difficult to efficiently manufacture a stacked electrode body with alternately stacked positive electrodes, separators, and negative electrodes, especially when meeting the high requirements for capacity, internal resistance and heat dissipation performance of vehicle-mounted lithium-ion secondary batteries.
Using a manufacturing device including a first laminated drum and a second laminated drum, the cut laminated body is laminated on different tables, and the diaphragm veneer is cut at a predetermined width by cutting members to form a desired electrode plate and a diaphragm veneer. Then stack the components in turn.
The stacked electrode body is manufactured at a high speed and continuously, which improves production efficiency and meets the demands of lithium-ion secondary batteries for high capacity, low internal resistance and high heat dissipation performance.
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Figure CN119481206A_ABST
Abstract
Description
[0001] This application is a divisional application of an application with an international application date of March 11, 2020 (date of entering the Chinese national phase: September 26, 2021), an international application number of PCT / JP2020 / 010497 (national application number: 202080024626.X), and an invention name of “Device and method for manufacturing a stacked electrode body”. Technical Field
[0002] The present disclosure relates to a manufacturing device and a manufacturing method for a stacked electrode body. Background Art
[0003] For example, in lithium-ion secondary batteries for vehicles, since a larger capacity, lower internal resistance, and higher heat dissipation performance are required, a laminated battery that can meet these requirements has been developed. The battery is in the form of alternately stacking positive electrodes, separators, and negative electrodes, connecting each electrode to a metal terminal called a tab and placing it in a container made of an aluminum laminate film, injecting an electrolyte, and sealing it.
[0004] Patent document 1 describes a structure comprising: an electrode support portion for receiving an electrode supplied by a conveying device and supporting the electrode; a circulation member in the shape of a ring extending in the up-down direction and having an electrode support portion mounted on the outer peripheral surface; a stacking unit arranged on the side opposite to the conveying device across the circulation member and having a multi-layer stacking portion for stacking electrodes; a pushing portion for simultaneously pushing a plurality of electrodes supported by the electrode support portion toward the multi-layer stacking portion; and a control portion for controlling the circulation and lifting of the circulation member and the movement of the pushing portion, the control portion controlling the movement of the pushing portion so that the pushing portion pushes the electrode toward the stacking portion at a speed slower than the conveying speed of the electrode conveyed by the conveying device.
[0005] Patent document 2 describes a device for manufacturing a stacked electrode body in which positive electrodes and negative electrodes are alternately stacked with a separator between them, the device comprising: a winding roller having an outer peripheral surface capable of winding up a continuously unwound separator sheet; and an electrode supply unit for supplying electrodes in sequence at intervals to a valley in a manner capable of switching between positive and negative electrodes, the valley being formed between a separator sheet SS that has been wound up on the outer peripheral surface and a separator sheet to be wound up on the outer peripheral surface.
[0006] Patent document 3 describes the following structure: comprising: a winding component of a roughly cylindrical shape, which is used to wind a continuous battery material, wherein the continuous battery material is a continuous positive electrode material, a continuous negative electrode material and a continuous separator material which are continuously formed with fracture lines which are easily used to cut the positive electrode, the negative electrode and the separator respectively as raw materials, and each raw material is formed in the order of continuous separator material, continuous positive electrode material, continuous separator material and continuous negative electrode material or in the order of continuous separator material, continuous negative electrode material, continuous separator material and continuous positive electrode material so that their respective fracture lines overlap in a consistent manner; a pressing component, which is used to press the wound continuous battery material against the side circumferential surface of the winding component; and a cutting component, which cuts the continuous battery material at each fracture line after the continuous battery material is wound on the winding component for the required number of stacking layers, and the cutting component is formed by partially protruding in the radial direction from the circumferential direction of the side circumferential surface of the winding component.
[0007] Prior art literature
[0008] Patent Literature
[0009] Patent Document 1: International Publication No. 2017 / 131027
[0010] Patent Document 2: Japanese Patent Application Publication No. 2012-199211
[0011] Patent Document 3: Japanese Patent Application Publication No. 2011-86508 Summary of the invention
[0012] In order to efficiently manufacture a stacked electrode body consisting of alternately stacked positive electrodes, separators, and negative electrodes, it is necessary to supply a strip-shaped positive electrode body and a strip-shaped negative electrode body to a roller, cut these strip-shaped positive electrode bodies and negative electrode bodies into desired sizes to obtain positive electrode plates and negative electrode plates, respectively, and stack these positive electrode plates and negative electrode plates in sequence at desired positions.
[0013] An object of the present disclosure is to provide a technology capable of manufacturing a stacked electrode body formed by stacking a separator single plate and electrodes at a high speed.
[0014] In one technical solution disclosed in the present invention, it includes: a first stacking roller, which is used to stack a stack on a first stacking table, wherein the stack is formed by cutting the diaphragm single plate of a stack formed by stacking diaphragm single plates and electrodes into a specified width; and a second stacking roller, which is different from the first stacking roller and is used to stack the stack cut out by the cutting on a second stacking table different from the first stacking table.
[0015] In another aspect of the present disclosure, the first stacking roller and the second stacking roller are arranged so as to rotate in the same direction with respect to a conveyance direction of the stacked body cut out by the cutting.
[0016] In still another aspect of the present disclosure, the first stacking roller and the second stacking roller are arranged so as to rotate in directions different from each other.
[0017] In still another aspect of the present disclosure, the stacked body cut out by the cutting is fed to the second stacking roller via the first stacking roller.
[0018] In another technical solution of the present disclosure, it also includes a cutting component, which is used to cut the diaphragm single plate of the stacked body into a specified width. The stacked body is a four-layer stacked body formed by configuring the first electrode plate on the first diaphragm single plate, configuring the second diaphragm single plate on the first electrode plate, and configuring the second electrode plate on the second diaphragm single plate. The cutting component cuts the first diaphragm single plate and the second diaphragm single plate of the four-layer stacked body into a specified width.
[0019] In another technical solution of the present disclosure, it also includes a cutting component, which is used to cut the diaphragm single plate of the stacked body into a specified width. The stacked body is a three-layer stacked body formed by configuring a first electrode plate on a first diaphragm single plate and configuring a second diaphragm single plate on the first electrode plate. The cutting component cuts the first diaphragm single plate and the second diaphragm single plate of the three-layer stacked body into a specified width.
[0020] In another technical solution of the present disclosure, it also includes a cutting component, which is used to cut the diaphragm single plate of the stack into a specified width. The stack is a 4-layer stack and a 3-layer stack. The 4-layer stack is formed by configuring the first electrode plate on the first diaphragm single plate, configuring the second diaphragm single plate on the first electrode plate, and configuring the second electrode plate on the second diaphragm single plate. The 3-layer stack is formed by configuring the first electrode plate on the first diaphragm single plate, and configuring the second diaphragm single plate on the first electrode plate. The cutting component is used to cut the first diaphragm single plate and the second diaphragm single plate of each of the 4-layer stack and the 3-layer stack into a specified width.
[0021] In another technical solution of the present disclosure, the first stacking roller stacks one of the three-layer stacking bodies on the first stacking table and stacks a specified number of the four-layer stacking bodies on the first stacking table, and the second stacking roller stacks one of the three-layer stacking bodies on the second stacking table and stacks the specified number of the four-layer stacking bodies on the second stacking table.
[0022] In another technical solution of the present disclosure, when the three-layer stack is supplied from the cutting part before one of the three-layer stack is stacked on the first stacking table and the specified number of the four-layer stack is stacked on the first stacking table, the first stacking roller does not stack the supplied three-layer stack on the first stacking table, and the second stacking roller stacks the supplied three-layer stack on the second stacking table.
[0023] In another technical solution disclosed in the present invention, the first stacking roller has a plurality of first stacking heads on its outer circumferential surface for holding the stacked body, and the plurality of first stacking heads rotate along the circumferential direction of the roller and stack the stacked body on the first stacking table, and the second stacking roller has a plurality of second stacking heads on its outer circumferential surface for holding the stacked body, and the plurality of second stacking heads rotate along the circumferential direction of the roller and stack the stacked body on the second stacking table.
[0024] In another technical scheme of the present disclosure, the following steps are included: conveying a stacked body to a first stacking roller or a second stacking roller, wherein the stacked body is formed by cutting the diaphragm single plate of a stacked body formed by stacking diaphragm single plates and electrode plates into a specified width; stacking the cut stacked body on a first stacking table using the first stacking roller; and stacking the cut stacked body on a second stacking table different from the first stacking table using the second stacking roller different from the first stacking roller.
[0025] In still another aspect of the present disclosure, the first stacking roller and the second stacking roller rotate in the same direction to perform stacking.
[0026] In still another aspect of the present disclosure, the first stacking roller and the second stacking roller rotate in directions different from each other to perform stacking.
[0027] According to one aspect of the present disclosure, a stacked electrode body formed by stacking a separator single plate and electrodes can be manufactured at high speed. BRIEF DESCRIPTION OF THE DRAWINGS
[0028] Figure 1 It is a conceptual structural diagram of a manufacturing apparatus according to an embodiment.
[0029] Figure 2 It is a structural perspective view of the manufacturing apparatus according to the embodiment.
[0030] Figure 3 It is an explanatory diagram showing a method for producing a four-layer laminate according to an embodiment.
[0031] Figure 4 This is a structural diagram of a four-layer laminate according to an embodiment.
[0032] Figure 5 It is an explanatory diagram showing a method for producing a three-layer laminate according to an embodiment.
[0033] Figure 6 This is a structural diagram of a three-layered laminate according to an embodiment.
[0034] Figure 7 It is a lamination explanatory diagram of a three-layer laminate and a four-layer laminate according to an embodiment.
[0035] Figure 8 It is a cut-away explanatory diagram of the separator according to the embodiment.
[0036] Fig. 9 It is a diagram for explaining the production procedure of a three-layer stacked body and a four-layer stacked body according to the embodiment.
[0037] Fig.10 It is a structural diagram of a stacked electrode body according to an embodiment.
[0038] Fig.11 It is a structural perspective view of a positive electrode cutting head according to an embodiment.
[0039] Fig.12 It is an explanatory diagram of a cut portion of a positive electrode single plate of a comparative example.
[0040] Fig.13 This is a cut-away explanatory diagram of a positive electrode single plate according to an embodiment (part 1).
[0041] Fig.14 This is a cut-away explanatory diagram of a positive electrode single plate according to an embodiment (part 2).
[0042] Fig.15 It is an explanatory diagram of the reciprocating movement of the circular blade according to the embodiment.
[0043] Fig.16 The diagrams are a top view and a side view of a positive electrode plate according to the embodiment.
[0044] Fig.17 It is an explanatory diagram of a cross section of a positive electrode single plate according to an embodiment.
[0045] Fig.18 It is an explanatory diagram of a cross section of a positive electrode single plate of a comparative example.
[0046] Fig.19 It is an explanatory diagram showing other blade shapes according to the embodiment.
[0047] Fig. 20 It is an explanatory diagram of the reciprocating movement of another blade according to the embodiment.
[0048] Fig.21 It is a diagram for explaining supply of a positive electrode plate according to the embodiment.
[0049] Fig. 22 yes Fig.21 A partial enlarged view of .
[0050] Fig.23A It is an explanatory diagram of the negative electrode heating roller and the bonding roller according to the embodiment.
[0051] Fig. 23B It is a perspective view of the pressing force adjustment mechanism according to the embodiment.
[0052] Fig.23C It is a rear view of the pressing force adjustment mechanism according to the embodiment.
[0053] Fig.24 It is an explanatory diagram of bonding of a negative electrode plate of a comparative example.
[0054] Fig.25 It is an explanatory diagram of bonding of the negative electrode plate according to the embodiment.
[0055] Fig.26 It is a diagram for explaining the pressurization range during bonding of negative electrode plates according to the embodiment.
[0056] Fig. 27 It is a diagram for explaining the pressurization range when the separator S2 according to the embodiment is bonded.
[0057] Fig.28 It is a diagram for explaining the pressurization range during bonding of the positive electrode plates according to the embodiment.
[0058] Fig.29 It is a structural perspective view of the laminating roller according to the embodiment.
[0059] Fig.30 This is an operation explanation diagram of the stacking roller according to the embodiment (part 1).
[0060] Fig.31 This is an operation explanation diagram of the stacking roller according to the embodiment (part 2).
[0061] Fig.32 This is an operation explanation diagram of the stacking roller according to the embodiment (part 3).
[0062] Fig.33 This is an operation explanation diagram of the stacking roller according to the embodiment (4).
[0063] Fig.34 It is a structural perspective view of a lamination head according to an embodiment.
[0064] Fig.35 Graph showing the position change of the lamination head according to the embodiment.
[0065] Fig.36 It is a structural perspective view of the stacking stage according to the embodiment.
[0066] Fig.37It is a diagram showing the arrangement of claws of the laminating table according to the embodiment.
[0067] Fig.38 It is an explanatory diagram of the claw operation of the laminating table according to the embodiment.
[0068] Fig.39 It is a plan view showing another arrangement of claws of the laminating stage according to the embodiment.
[0069] Fig.40 This is a diagram for explaining the interlocking action between the laminating head and the claws according to the embodiment (part 1).
[0070] Fig.41 This is a diagram (part 2) for explaining the interlocking action of the laminating head and the claws according to the embodiment.
[0071] Fig.42 This is a diagram (part 3) for explaining the interlocking action of the laminating head and the claws according to the embodiment.
[0072] Fig.43 This is a diagram (4) for explaining the interlocking action of the laminating head and the claws according to the embodiment.
[0073] Fig.44 This is a diagram (part 5) for explaining the interlocking action of the laminating head and the claws according to the embodiment.
[0074] Fig.45 This is a conceptual structure diagram of Modification Example 1.
[0075] Fig.46 This is a diagram for explaining stacking of Modification Example 1.
[0076] Fig.47 This is another stacking explanation diagram of Modification Example 1.
[0077] Fig.48 This is a conceptual structure diagram of variant example 2.
[0078] Fig.49 This is another conceptual structure diagram of Modification Example 2.
[0079] Fig.50 This is a conceptual structure diagram of variant example 3.
[0080] Fig.51 This is a conceptual structure diagram of variant example 4.
[0081] Description of Reference Numerals
[0082] 10. Negative electrode cutting roller; 12. Negative electrode heating roller; 14. Positive electrode cutting roller; 16. Positive electrode heating roller; 18. Bonding roller; 20. Diaphragm cutting roller; 22. Laminating roller; 24. Laminating table; N, negative electrode single plate; P, positive electrode single plate; NP, negative electrode plate; PP, positive electrode plate. DETAILED DESCRIPTION
[0083] Hereinafter, a manufacturing apparatus and a manufacturing method of a laminated electrode body according to one aspect of the present disclosure will be described. However, the embodiment described below is an example, and the present disclosure is not limited thereto.
[0084] Figure 1 A conceptual diagram of a manufacturing apparatus for a stacked electrode body according to the present embodiment is shown. The manufacturing apparatus according to the embodiment is a continuous roller type manufacturing apparatus in which a plurality of rollers are combined, and includes a negative electrode cutting roller 10, a negative electrode heating roller 12, a positive electrode cutting roller 14, a positive electrode heating roller 16, a bonding roller 18, a separator cutting roller 20, and a stacking roller 22.
[0085] The negative electrode cutting drum 10 is a first electrode cutting drum having a first radius and rotating at a first angular velocity around a central axis. A strip-shaped negative electrode single plate N is supplied to the negative electrode cutting drum 10 as a first electrode single plate. The negative electrode single plate N is a negative electrode. The negative electrode single plate N is composed of a negative electrode collector and a negative electrode active material layer formed on the negative electrode collector. The negative electrode active material layer can be formed on one surface of the negative electrode collector or on both surfaces. In the following description, the negative electrode active material layer is formed on both surfaces of the negative electrode collector. The negative electrode active material layer contains a negative electrode active material and a binding material.
[0086] Well-known materials can be used for both the negative electrode current collector and the negative electrode active material layer, and an example of a lithium ion secondary battery is shown below.
[0087] As the negative electrode collector, a foil of a metal that is stable within the potential range of the negative electrode and a film having the metal disposed on the surface can be used. As the negative electrode collector, a porous body such as a mesh, a punched sheet, or an expanded alloy of the metal can also be used. As the material of the negative electrode collector, copper, copper alloy, aluminum, aluminum alloy, stainless steel, nickel, etc. can be used. From the viewpoint of current collection, mechanical strength, etc., the thickness of the negative electrode collector is preferably, for example, greater than 3 μm and less than 50 μm. For example, by applying a negative electrode composite material slurry containing a negative electrode active material, a binder, and a dispersion medium on the negative electrode collector and then drying the coating, a negative electrode active material layer is formed on one or both sides of the negative electrode collector, thereby making it possible to produce a negative electrode single plate N. As needed, the negative electrode active material layer may also contain any component such as a conductive agent. There is no particular limitation on the thickness of the negative electrode active material layer, for example, greater than 10 μm and less than 100 μm.
[0088] In the case of lithium-ion secondary batteries, there are no particular restrictions on the negative electrode active material as long as it is a material that can absorb and release lithium ions. The material constituting the negative electrode active material may be a non-carbon material, a carbon material, or a combination thereof. As non-carbon materials, lithium metal, alloys containing lithium elements, and metal compounds such as metal oxides, metal sulfides, and metal nitrides containing lithium can be listed. As alloys containing lithium elements, for example, lithium aluminum alloys, lithium tin alloys, lithium lead alloys, and lithium silicon alloys can be listed. As metal oxides containing lithium, for example, metal oxides containing lithium and titanium, tantalum, or niobium can be listed, but lithium titanate (Li4Ti5O 12 Etc.). As carbon materials used as negative electrode active materials, for example, graphite and hard carbon can be listed. Among them, graphite is preferred because it has high capacity and small irreversible capacity. Graphite is a general term for carbon materials with a graphite structure, including natural graphite, artificial graphite, expanded graphite, graphitized mesophase carbon particles, etc. In the case of using graphite as the negative electrode active material, in order to reduce the activity of reduction and decomposition of aqueous electrolytes, it is preferred to coat the surface of the negative electrode active material layer with a coating. These negative electrode active materials can be used alone or in combination of two or more. As the binding material contained in the negative electrode active material layer, fluorine-based polymers, rubber-based polymers, etc., styrene-butadiene copolymers (SBR) or modified forms thereof can be used.
[0089] The negative electrode cutting drum 10 has a plurality of electrode cutting heads arranged along the circumferential direction of the drum. The plurality of electrode cutting heads include a cutting component and an outer peripheral surface for adsorbing and holding the negative electrode single plate N. The cutting component is, for example, a blade that moves in a direction substantially orthogonal to the circumferential direction of the outer peripheral surface. The supplied negative electrode single plate N is adsorbed and held on the outer peripheral surface and rotates. The electrode cutting head adsorbs and holds the negative electrode single plate N, so it is also called a holding head. A gap is formed between the plurality of electrode cutting heads, and in the gap, the blade mounted on the electrode cutting head moves in a direction substantially orthogonal to the circumferential direction, so that the negative electrode single plate N adsorbed and held on the outer peripheral surface is cut into a specified width (first width) by the blade.
[0090] A plurality of electrode cutting heads rotate around the common center axis of the negative electrode cutting drum 10, respectively, and each electrode cutting head is independently driven by a motor along the circumferential direction of the drum relative to other electrode cutting heads. For example, when two electrode cutting heads adjacent in the circumferential direction are set as electrode cutting head a and electrode cutting head b, electrode cutting head a and electrode cutting head b rotate around the common center axis of the drum at a constant speed, and change the relative speed to each other in each specified interval on the circumference of the negative electrode cutting drum 10. For example, at a certain time point, electrode cutting head a and electrode cutting head b both rotate at a constant speed, and the relative speed is 0, but at another time point, electrode cutting head a accelerates in a direction away from the subsequent electrode cutting head b, and becomes a limited relative speed. By independently driving the electrode cutting head in this way, the cutting position of the negative electrode single plate N can be adjusted by using a blade mounted on the electrode cutting head, and the position adjustment of the negative electrode plate generated by cutting can be performed. The moving speed of the electrode cutting head can be achieved by using a motor corresponding to each electrode cutting head.
[0091] The negative electrode cutting drum 10 may also be equipped with various cameras, which can be used to monitor the position of the negative electrode single plate N before cutting and the positions of the plurality of negative electrode plates generated by cutting. The negative electrode cutting drum 10 sucks and holds the supplied negative electrode single plate N and rotates and transports the negative electrode single plate N. Figure 1 The negative electrode single plate N is cut at the position 11 in the middle to generate a negative electrode plate. The electrode cutting head that absorbs and holds the negative electrode single plate N and rotates to the position 11 while absorbing and holding the negative electrode single plate N, and cuts the negative electrode single plate N with the blade mounted thereon when reaching the position 11. The negative electrode plates of the first width generated by cutting are rotated and transported while being absorbed and held on the outer peripheral surfaces of the respective electrode cutting heads.
[0092] The negative electrode heating roller 12 is a first electrode heating roller, and is arranged adjacent to the negative electrode cutting roller 10 in a manner close to the negative electrode cutting roller 10. The negative electrode heating roller 12 has a second radius, and rotates around the central axis at a second angular velocity. The second radius of the negative electrode heating roller 12 may be the same as the first radius of the negative electrode cutting roller 10, or may be different from the first radius of the negative electrode cutting roller 10. The second angular velocity of the negative electrode heating roller 12 is different from the first angular velocity of the negative electrode cutting roller 10. Specifically, the second angular velocity of the negative electrode heating roller 12 is set so that its linear velocity is substantially the same as the linear velocity of the bonding roller 18 described later. As an example, the second radius is set to be the same as the first radius, and the second angular velocity>the first angular velocity. In this case, the linear velocity of the negative electrode cutting roller 10 is different from the linear velocity of the negative electrode heating roller 12, and the linear velocity of the negative electrode heating roller 12>the linear velocity of the negative electrode cutting roller 10. Therefore, the electrode cutting head of the negative electrode cutting drum 10 is temporarily accelerated to be substantially the same as the linear speed of the negative electrode heating drum 12 before the position adjacent to the negative electrode heating drum 12, so that the relative speed with the negative electrode heating drum 12 is approximately zero. The electrode cutting head of the negative electrode cutting drum 10 discharges the adsorbed and held negative electrode plate to the negative electrode heating drum 12 side at the time point when the relative speed is approximately zero. After discharging the adsorbed and held negative electrode plate, the electrode cutting head of the negative electrode cutting drum 10 switches to the speed before acceleration.
[0093] The negative electrode heating roller 12 absorbs and holds the negative electrode plate discharged from the negative electrode cutting roller 10, and heats (preheats) the negative electrode plate using a built-in heater. The figure shows the situation where the negative electrode plate is heated at position 13. This heating (preheating) process is to thermally bond the separator and the negative electrode plate in the subsequent bonding process. The place heated by the negative electrode heating roller 12 is not limited to a specific position (such as position 13). The negative electrode heating roller 12 can also be in a heated state all the time during the rotation of the roller.
[0094] The positive electrode cutting drum 14 is a second pole cutting drum having a third radius and rotating at a third angular velocity around a central axis. A strip-shaped positive electrode single plate P is supplied to the positive electrode cutting drum 14 as a second pole single plate. The positive electrode single plate P is a rectangular electrode body. The positive electrode single plate P is composed of a positive electrode collector and a positive electrode active material layer formed on the positive electrode collector. The positive electrode active material layer can be formed on one surface of the positive electrode collector or on both surfaces. In the following description, the positive electrode active material layer is formed on both surfaces of the positive electrode collector. The positive electrode active material layer contains a positive electrode active material and a binding material.
[0095] Well-known materials can be used for both the positive electrode current collector and the positive electrode active material layer, and examples thereof are as follows.
[0096] As the positive electrode current collector, a foil of a metal that is stable within the potential range of the positive electrode and a film having the metal disposed on the surface can be used. As the positive electrode current collector, a porous body such as a mesh, a punched sheet, or an expanded alloy of the metal can also be used. As the material of the positive electrode current collector, stainless steel, aluminum, an aluminum alloy, titanium, etc. can be used. From the viewpoint of current collection, mechanical strength, etc., the thickness of the positive electrode current collector is preferably, for example, greater than 3 μm and less than 50 μm. For example, by applying a positive electrode composite material slurry containing a positive electrode active material, a conductive material, a binding material, etc. on the positive electrode current collector and drying it, a positive electrode active material layer is formed on the positive electrode current collector, and the positive electrode active material layer is rolled, thereby obtaining a positive electrode single plate. There is no particular limitation on the thickness of the positive electrode active material layer, for example, greater than 10 μm and less than 100 μm.
[0097] The positive electrode active material is a lithium transition metal oxide containing transition metal elements such as lithium (Li) and cobalt (Co), manganese (Mn) and nickel (Ni). As the conductive material contained in the positive electrode active material layer, for example, carbon black, acetylene black, Ketjen black, graphite and other carbon powders can be listed. For these materials, one can be used alone, or two or more can be used in combination. As the binding material contained in the positive electrode active material layer, for example, fluorine-based polymers, rubber-based polymers, etc. can be listed. As fluorine-based polymers, for example, polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF) or their modified bodies can be listed, and as rubber-based polymers, for example, ethylene-propylene-isoprene copolymers, ethylene-propylene-butadiene copolymers, etc. can be listed. For these materials, one can be used alone, or two or more can be used in combination.
[0098] The positive electrode cutting drum 14 has a plurality of electrode cutting heads arranged along the circumferential direction of the drum. The electrode cutting head includes a cutting component and an outer peripheral surface for adsorbing and holding the positive electrode single plate P. The cutting component is, for example, a blade that moves in a direction substantially orthogonal to the circumferential direction of the outer peripheral surface. The supplied positive electrode single plate P is adsorbed and held on the outer peripheral surface and rotates. The electrode cutting head adsorbs and holds the positive electrode single plate P, so it is also called a holding head. A gap is formed along the circumferential direction between the plurality of electrode cutting heads, and in this gap, the blade mounted on the electrode cutting head moves in a direction substantially orthogonal to the circumferential direction, so that the positive electrode single plate P adsorbed and held on the outer peripheral surface is cut into a specified width (the second width) by the blade. The plurality of electrode cutting heads, like the electrode cutting heads of the negative electrode cutting drum 10, respectively rotate around the common central axis of the positive electrode cutting drum 14, and each electrode cutting head is independently driven by a motor along the circumferential direction of the drum relative to other electrode cutting heads. For example, when two electrode cutting heads adjacent to each other in the circumferential direction are set as electrode cutting head a and electrode cutting head b, electrode cutting head a and electrode cutting head b rotate at a constant speed around the common central axis of the drum, and change the relative speed to each other in each specified interval on the circumference of the positive electrode cutting drum 14. For example, at a certain time point, electrode cutting head a and electrode cutting head b both rotate at a constant speed, and the relative speed is 0, but at another time point, electrode cutting head a accelerates in a direction away from the subsequent electrode cutting head b, and becomes a limited relative speed. By independently driving the electrode cutting head in this way, the cutting position of the positive electrode single plate P can be adjusted by using a circular blade mounted on the electrode cutting head, and the position adjustment of the negative electrode plate generated by cutting can be performed. The moving speed of the electrode cutting head can be achieved by using a motor corresponding to each electrode cutting head.
[0099] The positive electrode cutting drum 14 may also be equipped with various cameras, which can be used to monitor the position of the positive electrode single plate P before cutting and the positions of the plurality of positive electrode plates generated by cutting. The positive electrode cutting drum 14 absorbs and holds the supplied positive electrode single plate P and rotates and transports the positive electrode single plate P. Figure 1 The positive electrode plate is produced by cutting the positive electrode single plate P at position 15 in the electrode cutting head. The electrode cutting head that absorbs and holds the positive electrode single plate P and rotates to position 15 while absorbing and holding the positive electrode single plate P, and cuts the positive electrode single plate P with the blade mounted thereon when reaching position 15. The positive electrode plate produced by cutting is rotated and transported while being absorbed and held on the outer peripheral surface of each electrode cutting head.
[0100] The positive electrode heating roller 16 is a second electrode heating roller, and is arranged adjacent to the positive electrode cutting roller 14 in a manner close to the positive electrode cutting roller 14. The positive electrode heating roller 16 has a fourth radius, and rotates around the central axis at a fourth angular velocity. The fourth radius of the positive electrode heating roller 16 may be the same as the third radius of the positive electrode cutting roller 14, or may be different from the third radius of the positive electrode cutting roller 14. The fourth angular velocity of the positive electrode heating roller 16 is different from the third angular velocity of the positive electrode cutting roller 14. Specifically, the fourth angular velocity of the positive electrode heating roller 16 is set so that its linear velocity is substantially the same as the linear velocity of the bonding roller 18 described later. As an example, the fourth radius is set to be the same as the third radius, and the fourth angular velocity>the third angular velocity. In this case, the linear velocity of the positive electrode cutting roller 14 is different from the linear velocity of the positive electrode heating roller 16, and the linear velocity of the positive electrode heating roller 16>the linear velocity of the positive electrode cutting roller 14. Therefore, the electrode cutting head of the positive electrode cutting drum 14 is temporarily accelerated to be substantially the same as the linear velocity of the positive electrode heating drum 16 before the position adjacent to the positive electrode heating drum 16, so that the relative velocity with the positive electrode heating drum 16 is approximately zero. The electrode cutting head of the positive electrode cutting drum 14 discharges the adsorbed and held positive electrode plate to the positive electrode heating drum 16 side at the time point when the relative velocity is approximately zero. After discharging the adsorbed and held positive electrode plate, the electrode cutting head of the positive electrode cutting drum 14 switches to the rotation speed before acceleration.
[0101] The positive electrode heating roller 16 absorbs and holds the positive electrode plate discharged from the positive electrode cutting roller 14, and heats (preheats) the positive electrode plate using a built-in heater. The figure shows the situation where the positive electrode plate is heated at position 17. This heating (preheating) process is to thermally bond the separator and the positive electrode plate in the subsequent bonding process. The place heated by the positive electrode heating roller 16 is not limited to a specific position (such as position 17). The positive electrode heating roller 16 can also be in a heated state all the time during the rotation of the roller.
[0102] The bonding roller 18 is disposed between the negative heating roller 12 and the positive heating roller 16 in a manner adjacent to both the negative heating roller 12 and the positive heating roller 16. The bonding roller 18 has a fifth radius and rotates at a fifth angular velocity around the central axis. A strip-shaped separator S1 is supplied to the bonding roller 18 as a first separator single plate, and a strip-shaped separator S2 is supplied as a second separator single plate. Furthermore, a negative electrode plate heated by the negative heating roller 12 is supplied to the bonding roller 18, and a positive electrode plate heated by the positive heating roller 16 is supplied.
[0103] As for the negative electrode plate, the linear speed of the negative electrode heating roller 12 is substantially the same as the linear speed of the bonding roller 18, and the heated negative electrode plate adsorbed and held by the negative electrode heating roller 12 is discharged to the bonding roller 18 side at a position close to the bonding roller 18. In addition, as for the positive electrode plate, the linear speed of the positive electrode heating roller 16 is substantially the same as the linear speed of the bonding roller 18, and the heated positive electrode plate adsorbed and held by the positive electrode heating roller 16 is discharged to the bonding roller 18 side at a position close to the bonding roller 18.
[0104] In addition, since the linear speed of the negative electrode heating drum 12 is substantially the same as the linear speed of the bonding drum 18, the linear speed of the electrode cutting head of the negative electrode cutting drum 10 before the position adjacent to the negative electrode heating drum 12 is substantially the same as the linear speed of the bonding drum 18. In addition, since the linear speed of the positive electrode heating drum 16 is substantially the same as the linear speed of the bonding drum 18, the linear speed of the electrode cutting head of the positive electrode cutting drum 14 before the position adjacent to the positive electrode heating drum 16 is substantially the same as the linear speed of the bonding drum 18. Therefore, the electrode cutting head discharges the negative electrode plate or the positive electrode plate held by adsorption at a time point substantially the same as the linear speed of the bonding drum 1.
[0105] The strip-shaped separator S1 is adsorbed and held at a specified position of the bonding roller 18. Afterwards, the heated negative electrode plate discharged from the negative heating roller 12 is arranged on the separator S1 at a position adjacent to the negative heating roller 12 located on the downstream side in the rotation direction. Afterwards, the strip-shaped separator S2 is arranged on the negative electrode plate at a specified position further downstream in the rotation direction. Afterwards, the separator S1, the negative electrode plate and the separator S2 are bonded by applying pressure using a hot pressing roller 19, and the heated positive electrode plate discharged from the positive heating roller 16 is arranged in the separator S2 at a position adjacent to the positive heating roller 16 located on the further downstream side in the rotation direction, and the positive electrode plates are bonded using the pressing force of the positive heating roller 16. A thermal bonding layer is formed on the surface of the separator S1 and the separator S2, and the thermal bonding layer does not exhibit bonding properties at room temperature, but exhibits bonding properties when heated. The thermal adhesive layer is, for example, a thermoplastic layer containing a thermoplastic polymer, and the strip separator S1 and the negative electrode plate, the negative electrode plate and the strip separator S2, and the strip separator S2 and the positive electrode plate are bonded together by utilizing the plastic deformation of the thermoplastic polymer caused by heating. In this way, a four-layer laminate of the strip separator S1 / negative electrode plate / strip separator S2 / positive electrode plate is generated on the bonding drum 18. The four-layer laminate is conveyed from the bonding drum 18 to the separator cutting drum 20.
[0106] On the other hand, the positive electrode plate is not supplied from the positive electrode cutting drum 14 for every constant number of plates, and the positive electrode plate is not supplied from the positive electrode heating drum 16. Therefore, the positive electrode plate is not supplied to the bonding drum 18 for every constant number of plates, and a three-layer laminate of the strip separator S1 / negative electrode plate / strip separator S2 is generated on the bonding drum 18. The three-layer laminate is conveyed from the bonding drum 18 to the separator cutting drum 20 in the same manner as the four-layer laminate.
[0107] The diaphragm cutting drum 20 has a sixth radius and rotates around the central axis at a sixth angular velocity. The diaphragm cutting drum 20 has a plurality of diaphragm cutting heads arranged along the circumferential direction of the drum. The diaphragm cutting head includes a cutting component and an outer peripheral surface for adsorbing and holding a 4-layer stack and a 3-layer stack. The cutting component is, for example, a blade that moves in a direction approximately orthogonal to the circumferential direction of the outer peripheral surface. The transported 4-layer stack and 3-layer stack are adsorbed and held on the outer peripheral surface and rotate. The diaphragm cutting head adsorbs and holds the 4-layer stack and the 3-layer stack, and is therefore also called a holding head. A gap is formed along the circumferential direction between the plurality of diaphragm cutting heads, and in the gap, the blade mounted on the diaphragm cutting head moves in a direction approximately orthogonal to the circumferential direction, so that the 4-layer stack and the 3-layer stack adsorbed and held on the outer peripheral surface are cut into a specified width (the third width) by the blade. Specifically, the strip separator S1 and the strip separator S2 are cut between adjacent negative plates arranged at a predetermined interval in a four-layer stack of strip separator S1 / negative plate / strip separator S2 / positive plate, or between adjacent negative plates arranged at a predetermined interval in a three-layer stack of strip separator S1 / negative plate / strip separator S2, or between adjacent negative plates arranged at a predetermined interval in a four-layer stack and a three-layer stack. The figure shows a case where the cutting is performed at position 21.
[0108] The stacking drum 22 has a 7th radius and rotates around the central axis at a 7th angular velocity. The linear velocity of the stacking drum is adjusted to be substantially the same as the linear velocity of the diaphragm cutting drum 20. The stacking drum 22 has a plurality of stacking heads arranged along the circumferential direction of the drum. The stacking head has an outer peripheral surface for adsorbing and holding the cut 4-layer stacked bodies and 3-layer stacked bodies. The plurality of stacking heads rotate around the common central axis of the stacking drum 22, respectively, and each stacking head is independently driven by a cam along the circumferential direction of the drum relative to the other stacking heads. For example, when two stacking heads adjacent in the circumferential direction are set as stacking head a and stacking head b, stacking head a and stacking head b rotate around the common central axis of the drum at a constant speed, and the relative speeds of each other are changed in each specified interval on the circumference of the stacking drum 22. For example, at a certain time point, both stacking head a and stacking head b rotate at a constant speed, so the relative speed is 0, but at another time point, stacking head a accelerates in a direction away from the subsequent stacking head b, and becomes a finite relative speed. By independently driving the stacking heads in this way, the stacking roller 22 can be kept rotating at a constant angular velocity as a whole, and a specific stacking head can be stopped at the stacking position. In this stopped state, the cut 4-layer stack and 3-layer stack held by adsorption on the outer peripheral surface can be discharged and arranged on the stacking table 24.
[0109] The stacking table 24 is arranged directly below the stacking roller 22. The 4-layer stack and the 3-layer stack discharged from the stacking roller 22 are stacked in sequence on the stacking table 24 to form a stacked electrode body. The stacking table 24 can be driven along two axes (X axis and Y axis) orthogonal to each other, and can adjust the inclination angle (θ) on the X-Y plane, thereby adjusting the position (XY position) and inclination angle (θ) of the 4-layer stack and the 3-layer stack discharged from the stacking roller 22 to align, and stack the 4-layer stack and the 3-layer stack in sequence to manufacture a stacked electrode body. The stacking table 24 has claws at the four corners, and these claws are used to press and fix the stacked 4-layer stack and the 3-layer stack. The stacked 3-layer stack and the 4-layer stack are pressurized and / or heated to bond to each other.
[0110] The outline of the manufacturing process of the stacked electrode body is summarized as follows.
[0111] (1) Cutting the negative electrode single plate on a roller to produce a negative electrode plate
[0112] (2) Heating the negative plate on a roller
[0113] (3) Cutting the positive electrode single plate on the roller to produce the positive electrode plate
[0114] (4) Heating the positive plate on a roller
[0115] (5) Bonding the strip-shaped separator and the negative electrode plate to a roller, bonding the strip-shaped separator to the roller, and bonding the positive electrode plate to the roller.
[0116] (6) Cutting the strip-shaped separator on a roller to produce a three-layer laminate and a four-layer laminate
[0117] (7) Laminating a 3-layer laminate and a 4-layer laminate on a drum
[0118] (8) In order to bond the stacked three-layer laminate and the four-layer laminate to each other, pressurization and / or heating are performed.
[0119] By performing the cutting, heating, bonding, and laminating steps on the drum in this manner, the processing can be performed continuously at high speed.
[0120] Figure 2 A perspective view showing a specific structure of the manufacturing apparatus according to the embodiment.
[0121] From the left side of the figure, the negative electrode cutting drum 10, the negative electrode heating drum 12, the bonding drum 18, the positive electrode heating drum 16, and the positive electrode cutting drum 14 are arranged adjacent to each other in order. The negative electrode cutting drum 10 is arranged adjacent to the negative electrode heating drum 12, the negative electrode heating drum 12 is arranged adjacent to the bonding drum 18, the positive electrode cutting drum 14 is arranged adjacent to the positive electrode heating drum 16, and the positive electrode heating drum 16 is arranged adjacent to the bonding drum 18. The negative electrode cutting drum 10, the negative electrode heating drum 12, the bonding drum 18, the positive electrode heating drum 16, and the positive electrode cutting drum 14 rotate around their central axes respectively, and these central axes are substantially parallel to each other.
[0122] The negative electrode single plate N in a strip shape with tension adjusted by a tension roller is supplied to the negative electrode cutting drum 10. The negative electrode cutting drum 10 includes a plurality of cutting heads rotating around a central axis, for example, 12 electrode cutting heads arranged in a circumferential direction, and the negative electrode single plate N in a strip shape is held by adsorption on the outer peripheral surface of the electrode cutting head and rotates together with the electrode cutting head.
[0123] A plurality of electrode cutting heads are respectively provided with blades that move in a direction substantially orthogonal to the circumferential direction, i.e., in the width direction of the negative electrode cutting drum, and the blades move in the width direction of the drum within a certain range in the rotation direction to cut the negative electrode single plate N. After cutting the negative electrode single plate N, the electrode cutting head moves independently in the circumferential direction relative to the other electrode cutting heads, adjusts the interval between the negative electrode plates, and makes the relative speed approximately 0 at a position adjacent to the negative electrode heating drum 12.
[0124] The negative electrode plate adsorbed and held by the electrode cutting head of the negative electrode cutting roller 10 is supplied to the negative electrode heating roller 12 at a position adjacent to the negative electrode heating roller 12. Specifically, an adsorption hole for adsorbing and holding the negative electrode plate is formed on the outer peripheral surface of the electrode cutting head (holding head), and a groove extending in the circumferential direction is formed. With respect to the groove formed in the holding head, a supply component is arranged between the holding head and the roller of the next stage, and the supply component is engaged with the groove to detach the negative electrode plate as an electrode body from the adsorption surface of the holding head and supply it to the roller of the next stage. As a supply component, for example, a belt conveyor is inserted into the groove at a position adjacent to the negative electrode heating roller 12, so that the negative electrode plate adsorbed and held by the electrode cutting head climbs onto the belt conveyor, and the negative electrode plate is supplied to the negative electrode heating roller 12 side by means of the belt conveyor. The belt conveyor will be further described later. The negative electrode cutting roller 10 rotates and conveys the negative electrode plate at a specified interval.
[0125] The negative electrode plates cut out by the negative electrode cutting drum 10 are sequentially supplied to the negative electrode heating drum 12. The negative electrode heating drum 12 rotates at substantially the same linear speed as the bonding drum 18 to heat the negative electrode plates and rotates and conveys the heated negative electrode plates to a position adjacent to the bonding drum 18.
[0126] In addition, a strip-shaped positive electrode single plate P whose tension is adjusted by a plurality of tension rollers is supplied to the positive electrode cutting drum 14. The positive electrode cutting drum 14 includes a plurality of cutting heads rotating around a central axis, for example, 12 electrode cutting heads arranged in a circumferential direction, and the strip-shaped positive electrode single plate P is adsorbed and held on the outer peripheral surface of the electrode cutting head and rotates together with the electrode cutting head.
[0127] A plurality of electrode cutting heads are respectively provided with blades that move in a direction substantially orthogonal to the circumferential direction, i.e., in the width direction of the positive electrode cutting drum, and the blades move in the width direction of the drum within a certain range in the rotation direction to cut the positive electrode single plate P. After cutting the positive electrode single plate P, the electrode cutting head moves independently in the circumferential direction relative to the other electrode cutting heads, adjusts the interval between the positive electrode plates, and makes the relative speed approximately 0 at a position adjacent to the positive electrode heating drum 16.
[0128] The positive electrode plate adsorbed and held by the electrode cutting head of the positive electrode cutting roller 14 is supplied to the positive electrode heating roller 16 at a position adjacent to the positive electrode heating roller 16. Specifically, adsorption holes for adsorbing and holding the positive electrode plate are formed on the outer peripheral surface of the electrode cutting head (holding head), and a groove extending in the circumferential direction is formed. With respect to the groove formed in the holding head, a supply component is arranged between the holding head and the roller of the next stage, and the supply component is engaged with the groove to detach the positive electrode plate as an electrode body from the adsorption surface of the holding head and supply it to the roller of the next stage. As a supply component, for example, a belt conveyor is inserted into the groove at a position adjacent to the positive electrode heating roller 16, so that the positive electrode plate adsorbed and held by the electrode cutting head climbs onto the belt conveyor, and the positive electrode plate is supplied to the positive electrode heating roller 16 side by means of the belt conveyor.
[0129] The positive electrode cutting drum 14 rotates and conveys the positive electrode plates at predetermined intervals.
[0130] The positive plates cut by the positive cutting drum 14 are sequentially supplied to the positive heating drum 16. The positive heating drum 16 rotates at substantially the same linear speed as the bonding drum 18 to heat the positive plates and rotates and conveys the heated positive plates to a position adjacent to the bonding drum 18.
[0131] The strip-shaped separators S1 and S2 whose tensions are adjusted by a plurality of tension rollers are supplied to the bonding roller 18. In addition, the heated negative electrode plate is supplied to the bonding roller 18 at a position where the bonding roller 18 is adjacent to the negative electrode heating roller 12, and the heated positive electrode plate is supplied to the bonding roller 18 at a position where the bonding roller 18 is adjacent to the positive electrode heating roller 16. The bonding roller 18 rotates in a direction that is the same as the linear speed of the negative electrode heating roller 12 and the linear speed of the positive electrode heating roller 16. The supply position of the separator S1, the supply position of the negative electrode plate, the supply position of the separator S2, and the supply position of the positive electrode plate are sequentially arranged from the upstream side to the downstream side in the rotation direction of the bonding roller 18. A hot pressing roller 19 is arranged between the supply position of the separator S2 and the supply position of the positive electrode plate.
[0132] The bonding roller 18 holds the strip-shaped separator S1 on its outer peripheral surface and rotates to transport the separator S1. Then, the negative electrode plate that has been heated at a position adjacent to the negative electrode heating roller 12 is arranged on the separator S1 at a predetermined interval and pressurized by the pressure between the rollers. The bonding roller 18 holds the negative electrode plate arranged on the separator S1 at a predetermined interval and rotates to transport the negative electrode plate. The strip-shaped separator S2 is arranged on the negative electrode plate at the supply position of the separator S2, and the three-layer stack of the separator S1 / negative electrode plate / separator S2 is pressed by the pressing force of the hot pressing roller 19.
[0133] The three-layer stack that has been heat-pressed by the hot pressing roller 19 is then rotated and transported to a position adjacent to the positive heating roller 16, where the positive plate is arranged on the diaphragm S2 at a specified interval and pressurized by the pressure between the rollers. The positive plate is hot-pressed to the diaphragm S2 by the pressure between the rollers. In addition, the rotation of the positive cutting roller 14 and the positive heating roller 16 is stopped at a constant number of times, so that the supply of the positive plate from the positive heating roller 16 to the bonding roller 18 is stopped. As a result, the positive plate is not arranged on the diaphragm S2, and the state of the three-layer stack is maintained. The three-layer stack consisting of the strip-shaped diaphragm S1 / negative plate / strip-shaped diaphragm S2 and the four-layer stack consisting of the strip-shaped diaphragm S1 / negative plate / strip-shaped diaphragm S2 / positive plate are transported to the diaphragm cutting roller 20 by means of multiple tension rollers. In addition, instead of stopping the rotation of the positive electrode cutting drum 14 and the positive electrode heating drum 16 at the time of obtaining the three-layer stack, the three-layer stack can be prepared by separately manufacturing and introduced through a path different from the introduction path of the four-layer stack.
[0134] The three-layer laminate and the four-layer laminate are heat-pressed by the pressure between the rollers of the negative electrode heating roller 12 and the bonding roller 18, the pressure between the rollers of the positive electrode heating roller 16 and the bonding roller 18, and the pressing force of the heat-pressing roller 19. However, when the ends of the negative electrode plate cut by the negative electrode cutting roller 10 and the ends of the positive electrode plate cut by the positive electrode cutting roller 14 are pressed by rollers or rolls, damage may occur at the ends of the negative electrode plate and the ends of the positive electrode plate. Therefore, damage is prevented by temporarily relaxing the pressure between the rollers and the pressing by the heat-pressing roller 19 at the ends of the negative electrode plate cut by the negative electrode cutting roller 10 and the ends of the positive electrode plate cut by the positive electrode cutting roller 14. By relaxing the pressing not only at the ends of the negative electrode plate cut by the negative electrode cutting roller 10 and the ends of the positive electrode plate cut by the positive electrode cutting roller 14, but also at the ends of the four sides of the negative electrode plate and the ends of the four sides of the positive electrode plate, damage to the negative electrode plate and the positive electrode plate can be suppressed. That is, in terms of suppressing damage to the negative electrode plate and the positive electrode plate, it is more preferable that only the inside of the negative electrode plate and the inside of the positive electrode plate are bonded to the separator.
[0135] The separator cutting drum 20 may be disposed separately from the set of drums including the negative electrode cutting drum 10 , the negative electrode heating drum 12 , the bonding drum 18 , the positive electrode heating drum 16 , and the positive electrode cutting drum 14 .
[0136] The diaphragm cutting drum 20 holds the 3-layer laminate and the 4-layer laminate supplied by the tension roller on the outer peripheral surface, and cuts the strip-shaped diaphragms S1 and S2 of the 3-layer laminate and the 4-layer laminate using the same diaphragm cutting head structure as the negative electrode cutting drum 10. The cut 3-layer laminate and the 4-layer laminate are rotated and transported to a position adjacent to the stacking drum 22 while being held by the diaphragm cutting head. The outer peripheral surface of the diaphragm cutting head is formed with adsorption holes for adsorbing and holding the 3-layer laminate and the 4-layer laminate.
[0137] The membrane cutting drum 20 rotates and conveys the three-layered laminate or the four-layered laminate at predetermined intervals.
[0138] The stacking drum 22 is arranged adjacent to the diaphragm cutting drum 20, and rotates at a linear speed substantially the same as that of the diaphragm cutting drum 20. The stacking drum 22 includes a plurality of stacking heads that rotate around the center of rotation of the drum. The longitudinal section of the stacking head is substantially in the shape of the letter T, and adsorption holes for adsorbing and holding the three-layer stack and the four-layer stack are formed on the outer peripheral surface of the stacking head, and a vacuum pad is provided inside the adsorption hole. The three-layer stack and the four-layer stack adsorbed and held on the diaphragm cutting drum 20 are adsorbed on the stacking head with the aid of a vacuum pad. The plurality of stacking heads rotate around the common central axis of the stacking drum 22, respectively, and each stacking head is independently driven in the circumferential direction of the drum relative to the other stacking heads, and then driven in the radial direction of the drum. That is, the stacking head rotates and transports the three-layer stack and the four-layer stack to a position adjacent to the stacking table 24 while adsorbing and holding them. When the stacking head reaches a position close to the stacking table 24, the relative speed of the drum in the circumferential direction relative to the stacking table 24 becomes 0, and the stacking head moves in the radial direction of the drum toward the stacking table 24. The stacking head makes the three-layer or four-layer stack held by suction abut against the stacking table 24, or makes the three-layer or four-layer stack held by suction abut against the stacking table 24 if there are already three-layer or four-layer stacks stacked on the stacking table 24, releases the suction holding force, and stacks the three-layer or four-layer stack held by suction. After that, the stacking head moves again in the radial direction of the drum away from the stacking table 24, and starts rotating again.
[0139] The above is an overall description.
[0140] In addition, regarding the handover of the three-layer laminate and the four-layer laminate from the diaphragm cutting drum 20 to the laminating drum 22, a method using a vacuum pad provided on the laminating head of the laminating drum 22 has been described, but the present invention is not limited thereto. The same method as that of the positive electrode cutting drum and the negative electrode cutting drum may be adopted, that is, a groove is provided on the diaphragm cutting drum and the three-layer laminate and the four-layer laminate are handed over to the laminating drum 22 by a belt conveyor.
[0141] In addition, when transferring the positive electrode plate and the negative electrode plate from the positive electrode cutting drum and the negative electrode cutting drum to the heating drum and the bonding drum, a vacuum pad may be used instead of a belt conveyor. In addition, the roller that supplies the electrode body or laminate such as the positive electrode plate and the negative electrode plate to the adsorption pad is called the first roller, and the roller equipped with the adsorption pad is also called the second roller.
[0142] Next, the details of the production process of the three-layer laminate and the four-layer laminate will be described.
[0143] Figure 3 and Figure 4 The basic manufacturing process of a four-layer laminate is schematically shown.
[0144] Figure 3 (a) shows the cutting of the negative electrode by the negative electrode cutting drum 10. A pole tab Nt is formed at a constant interval on a negative electrode single plate N including a negative electrode collector and a negative electrode active material layer. The pole tab Nt is formed integrally with the negative electrode collector and protrudes from one edge of the negative electrode collector (protrudes in a direction orthogonal to the extension direction of the strip-shaped negative electrode single plate N). The negative electrode cutting drum 10 cuts the negative electrode single plate N at a constant interval to generate a negative electrode plate NP of a first width. A pole tab Nt is formed on one edge of the negative electrode plate NP.
[0145] Figure 3 (b) shows the cutting of the positive electrode by the positive electrode cutting drum 14. Pole tabs Pt are formed at constant intervals on the positive electrode single plate P including the positive electrode collector and the positive electrode active material layer. The pole tabs Pt are formed integrally with the positive electrode collector and protrude from one edge of the positive electrode collector (protrude in a direction orthogonal to the extension direction of the strip-shaped positive electrode single plate P). The positive electrode cutting drum 14 cuts the positive electrode single plate P at constant intervals to generate a positive electrode plate PP of the second width. Pole tabs Pt are formed on one edge of the positive electrode plate PP. The size of the positive electrode plate PP is smaller than that of the negative electrode plate NP. In addition, the interval (pitch) between the pole tabs Pt of the positive electrode plate PP is smaller than the interval (pitch) between the pole tabs Nt of the negative electrode plate NP.
[0146] Figure 3 (c) shows the bonding by the bonding roller 18. The negative electrode plates NP are arranged and bonded at a constant interval on the strip-shaped separator S1, the strip-shaped separator S2 is arranged and bonded on the negative electrode plate NP, and the positive electrode plates PP are arranged and bonded at a constant interval in a manner overlapping on the negative electrode plate NP. The positive electrode plate PP is arranged inside the region where the negative electrode plate NP exists. The negative electrode plates NP and the positive electrode plates PP are separated from each other, but since the strip-shaped separators S1 and S2 have not been cut and remain in a strip-shaped state, the whole is a strip-shaped 4-layer stack.
[0147] Figure 3(d) shows the cutting by the separator cutting drum 20. The separator cutting drum 20 cuts the strip-shaped four-layer laminate at a constant interval, that is, between adjacent negative electrode plates NP, to produce a four-layer laminate 40 with a third width in which the separators S1 and S2 are cut.
[0148] Figure 4 The structure of the four-layer stacked body 40 is shown. A separator S1 is arranged at the bottom layer, a negative electrode plate NP is stacked on the separator S1, a separator S2 is stacked on the negative electrode plate NP, and a positive electrode plate PP is stacked on the separator S2.
[0149] Figure 5 and Figure 6 The production process of the three-layer laminate is schematically shown.
[0150] Figure 5 (a) shows the bonding by the bonding roller 18. The negative electrode plates NP are arranged and bonded at a constant interval on the strip-shaped separator S1, and the strip-shaped separator S2 is arranged and bonded on the negative electrode plates NP. Regarding the positive electrode plates PP, the positive electrode plates PP are not arranged every constant number. The negative electrode plates NP are separated from each other, but since the strip-shaped separators S1 and S2 have not been cut and remain in a strip-shaped state, the whole is a strip-shaped three-layer stack.
[0151] Figure 5 (b) shows the cutting process using the separator cutting drum 20. The separator cutting drum 20 cuts the strip-shaped three-layer laminate at a constant interval, that is, between adjacent negative plates NP, to generate a three-layer laminate 30 with a third width in which the separators S1 and S2 are cut. The three-layer laminate 30 is generated at a constant number of intervals. That is, like a four-layer laminate 40, a four-layer laminate 40, a three-layer laminate 30, a four-layer laminate, ...
[0152] Figure 6 The structure of the three-layer stacked body 30 is shown. A separator S1 is arranged at the bottom layer, a negative electrode plate NP is stacked on the separator S1, and a separator S2 is stacked on the negative electrode plate NP.
[0153] As described above, the three-layered laminate 30 and the four-layered laminate 40 are produced and supplied from the membrane cutting drum 20 to the laminating drum 22 .
[0154] Figure 7 The laminating process of the laminating drum 22 is schematically shown.
[0155] When the stacking drum 22 receives the rectangular 3-layer stack 30 and 4-layer stack 40 from the separator cutting drum 20, it sequentially arranges and stacks them on the stacking table 24. That is, when the 3-layer stack 30 of separator S1 / negative electrode plate NP / separator S2 is received, it is turned upside down and arranged on the stacking table 24 in the form of separator S2 / negative electrode plate NP / separator S1.
[0156] Next, when the stacking drum 22 receives the four-layer stack 40 of the separator S1 / negative electrode plate NP / separator S2 / positive electrode plate PP, it turns it upside down and arranges it in the form of positive electrode plate PP / separator S2 / negative electrode plate NP / separator S1 and stacks it on the three-layer stack 30 of the stacking table 24. As a result, the separator S2 / negative electrode plate NP / separator S1 / positive electrode plate PP / separator S2 / negative electrode plate NP / separator S1 are stacked on the stacking table 24. Next, the stacking drum 22 also receives the four-layer stack 40, arranges it upside down and stacks it on the four-layer stack 40 of the stacking table 24. Thus, separator S2 / negative electrode plate NP / separator S1 / positive electrode plate PP / separator S2 / negative electrode plate NP / separator S1 / positive electrode plate PP / separator S2 / negative electrode plate NP / separator S1 / … / positive electrode plate PP / separator S2 / negative electrode plate NP / separator S1 are stacked. The stacking roller 22 stacks one three-layer stack 30 and a predetermined number of four-layer stacks 40 on the stacking table 24 in sequence to manufacture a stacked electrode body. By stacking the three-layer stack 30 and the four-layer stack 40 in combination, a stacked electrode body in a rectangular shape in which the electrodes at both ends are always the negative electrode plates NP can be obtained.
[0157] The structure of stacking in reverse is just an example, and other stacking methods are also possible, of course. For example, first, a 4-layer stack may be stacked without being reversed, and finally, a 3-layer stack may be stacked without being reversed.
[0158] Figure 8 to Figure 10 The lamination process of the three-layer laminate 30 and the four-layer laminate 40 is shown more specifically.
[0159] Figure 8 The separator cutting process using the separator cutting roller 20 is shown. The strip-shaped three-layer laminate 30 and the four-layer laminate 40 bonded by the bonding roller 18 are cut and separated at approximately the middle position between the adjacent negative electrode plates NP. Similarly, the strip-shaped four-layer laminate 40 is also cut and separated at approximately the middle position between the adjacent negative electrode plates NP.
[0160] Fig. 9The cut 3-layer stack 30 and 4-layer stack 40 are shown. For example, when a vacancy of a positive electrode plate PP is generated in every 38 positive electrode plates PP, 37 4-layer stacks 40 are continuously generated after one 3-layer stack 30, and then one 3-layer stack 30 is generated again, and then 37 4-layer stacks 40 are generated. When N is set as a statistical variable, when N=1, it is a 3-layer stack 30, when N=2, it is a 4-layer stack 40, when N=3, it is a 4-layer stack 40, ..., when N=38, it is a 4-layer stack 40, when N=39, it is a 3-layer stack 30, and when N=40, it is a 4-layer stack 40.
[0161] Fig.10 The structure of the stacked electrode body is shown in which a three-layer stack 30 is first arranged on a stacking table 24 and then a four-layer stack 40 is sequentially stacked on the three-layer stack 30. The structure is a stack of one three-layer stack 30 and thirty-seven four-layer stacks 40. The electrodes at both ends of the stacked electrode body are negative plates NP.
[0162] Next, the specific structure of the electrode cutting head will be described in more detail.
[0163] Fig.11 A structural stereogram of the electrode cutting heads constituting the positive electrode cutting drum 14 is shown. A plurality of electrode cutting heads are arranged in a circumferential direction around the center of the rotation axis of the positive electrode cutting drum 14. The electrode cutting heads are driven independently of other electrode cutting heads in a circumferential direction (direction a in the figure) by a motor 14v provided for each electrode cutting head. Here, a linear motor, a planetary gear, a toothed belt, etc. may be used instead of the motor 14v to independently drive.
[0164] An adsorption hole 14g is formed on the outer peripheral surface 14p of the electrode cutting head, and the adsorption hole 14g is used to adsorb and hold the positive electrode single plate P and the (cut) positive electrode plate PP. A groove 14r is formed along the circumferential direction in the approximate center of the direction (b direction in the figure) perpendicular to the circumferential direction of the outer peripheral surface 14p, and no adsorption hole 14g is formed in the groove 14r. In addition, a cutting mechanism module 14t with circular blades 50a and 50b is provided in the electrode cutting head. The circular blades 50a and 50b are a pair of blades. The circular blades 50a and 50b are a set of upper and lower rotating blades, which cut the positive electrode single plate as a rectangular electrode body by reciprocating in the direction b in the figure while rotating. That is, the circular blades 50a and 50b cut the positive electrode single plate by moving back and forth in the direction b in the figure from the initial position retreated from the outer peripheral surface 14p, and then return to the initial position again by returning in the direction b in the figure. The cutting mechanism module 14t is provided with a cam 14u engaged with a cam groove formed on a fixed shaft of the positive electrode cutting drum 14. The cutting mechanism module 14t allows the cam 14u to move along the cam groove as the electrode cutting head rotates, thereby reciprocating the circular blades 50a and 50b along the track in a direction orthogonal to the circumferential direction (direction b in the figure) in the gap between adjacent electrode cutting heads by means of a rack and pinion mechanism. The reciprocating speed of the circular blades 50a and 50b in the direction b in the figure can be appropriately adjusted by setting the gear ratio of the rack and pinion mechanism.
[0165] Furthermore, the cutting mechanism module 14t is connected to the cam 14w. After the circular blades 50a and 50b move forward in the direction b in the figure to cut the positive electrode single plate, the cutting head that attracts and holds the positive electrode plate moves in a direction away from the cutting head that holds the positive electrode single plate, and then the cam 14w rotates, so that the rotating shaft 14x of the cutting mechanism module 14t rotates. Then, as the rotating shaft 14x rotates, the cutting mechanism module 14t and the circular blades 50a and 50b move in a direction away from the cut surface of the positive electrode single plate. After that, the circular blades 50a and 50b move back in the direction b in the figure.
[0166] Fig.12The figure shows a case where the upper and lower circular blades 50a and 50b are arranged to overlap each other in the thickness direction of the positive electrode single plate P and cut. The positive electrode single plate P is composed of a positive electrode collector P1 and a positive electrode active material layer P2, and the upper circular blade 50a is arranged to penetrate the upper positive electrode active material layer P2 and the positive electrode collector P1 to a certain depth. In addition, the lower circular blade 50b is arranged to penetrate the lower positive electrode active material layer P2 and the positive electrode collector P1 to a certain depth. The depth of the circular blade 50a and the circular blade 50b overlap in the thickness direction of the positive electrode single plate P. The positive electrode single plate P can also be cut according to the arrangement position of the circular blades 50a and 50b, but the inventors of the present application have confirmed that in the case of the arrangement of the circular blades 50a and 50b, useless protrusions, i.e., burrs, are sometimes generated on the cut surface of the positive electrode single plate P, which may cause the deterioration of the stacked electrode body.
[0167] on the other hand, Fig.13 The upper and lower circular blades 50a and 50b are arranged in a non-overlapping manner in the thickness direction of the positive electrode single plate P to cut. The upper circular blade 50a is arranged to penetrate the upper positive electrode active material layer P2, but not to penetrate the positive electrode collector P1. In addition, the lower circular blade 50b is arranged to penetrate the lower positive electrode active material layer P2, but also not to penetrate the positive electrode collector P1. The upper and lower circular blades 50a and 50b are arranged at a limited distance from each other in the thickness direction. In such a configuration, the upper and lower positive electrode active material layers P2 of the positive electrode single plate P are cut by the circular blades 50a and 50b, but the positive electrode collector P1 is not cut, and although a notch is generated in a part thereof, it maintains a strip-shaped state. However, the positive electrode single plate P is adsorbed and held on the outer peripheral surface of a plurality of electrode cutting heads, and the electrode cutting heads move independently in the circumferential direction to adjust the interval between the positive electrode plates PP, and move in a manner where the relative linear velocity with the positive electrode heating roller 16 is approximately 0. When the electrode cutting head moves independently in the circumferential direction, pulling forces in opposite directions act on the cut portion of the positive electrode single plate P. Under the action of this pulling force, the positive electrode collector P1 breaks with the notch as the base point, resulting in cutting. The inventors of this application have confirmed that according to Fig.13 The arrangement of the circular blades 50 a and 50 b shown above does not cause burrs to be generated on the cut surface of the positive electrode single plate P, or burrs are unlikely to be generated.
[0168] In addition, Fig.13In the figure, the upper and lower circular blades 50a and 50b are arranged so as not to overlap in the thickness direction of the positive electrode single plate P, but the upper and lower circular blades 50a and 50b may be arranged so that the distance in the thickness direction of the positive electrode single plate P is 0. In short, when the distance in the thickness direction of the positive electrode single plate P between the blade tips of the upper and lower circular blades 50a and the blade tips of the circular blade 50b is set to L, and the thickness of the positive electrode collector P1 is set to d, it is sufficient to arrange d>L≥0. Here, L<0 means that the upper and lower circular blades 50a and 50b overlap each other, which means that the upper and lower circular blades 50a and 50b cut the upper and lower positive electrode active material layers P2 and the positive electrode collector P1. d>L≥0 can be said that the upper positive electrode active material layer P2 is cut by the upper circular blade 50a, and the lower positive electrode active material layer P2 is cut by the lower circular blade 50b, and the positive electrode collector P1 is not cut but is broken by the action of the pulling force.
[0169] Fig.14 Examples of use Fig.13 The electrode cutting head 14a and the electrode cutting head 14b cut the positive electrode single plate P.
[0170] like Fig.14 As shown in (a), the electrode cutting head 14a and the electrode cutting head 14b rotate around the center of the rotating axis of the drum while adsorbing and holding the positive electrode single plate P on the outer peripheral surface. The positive electrode single plate P is composed of a positive electrode collector P1 and a positive electrode active material layer P2 formed on both surfaces of the positive electrode collector P1. When the rotation moves to a predetermined position, the cutting mechanism 14t provided in the electrode cutting head 14a is used to move the circular blades 50a and 50b back and forth to cut the positive electrode active material layer P2 of the positive electrode single plate P.
[0171] Fig.14 (b) shows the state where the positive electrode active material layer P2 is cut by the circular blades 50a and 50b. At this time, the positive electrode current collector P1 is not cut yet, but is still held in a strip shape by the outer peripheral surfaces of the electrode cutting heads 14a and 14b.
[0172] Afterwards, if Fig.14 As shown in (c), the electrode cutting head 14a moves independently and at an accelerated speed along the circumferential direction of the drum relative to the electrode cutting head 14b. Through this movement, a pulling force is applied to the positive electrode collector P1 to cut the strip-shaped positive electrode collector P1. Afterwards, the circular blades 50a and 50b are moved back by the cutting mechanism 14t provided in the electrode cutting head 14a. In this sense, in the present embodiment, the cutting of the positive electrode single plate P can be said to be performed by a combination of the movement of the circular blades 50a and 50b and the movement of the electrode cutting head. In addition, after that, Fig.15 The detailed process of the reciprocating movement of the circular blades 50a and 50b will be further described.
[0173] In this embodiment, the positive current collector P1 of the positive electrode single plate P is cut by pulling force, and the positive active material layer P2 is cut by the circular blades 50a and 50b. Therefore, the cut surface of the positive current collector P1 and the cut surface of the positive active material layer P2 have different cut shapes.
[0174] Fig.16 A plan view and a side view of the cut positive electrode plate PP are shown. Fig.16 (a) is a top view, in which a positive electrode active material layer P2 exists on the surface and a tab Pt extends from an end portion. Fig.16 (b) is a side view, and Fig.14 Likewise, positive electrode active material layers P2 exist on the upper and lower parts of positive electrode current collector P1. Here, reference symbol c in the figure indicates a cut surface obtained by cutting with an electrode cutting head.
[0175] Fig.17 Show Fig.16 The cross section of the cutting surface c in (b). Fig.17 Shown by Fig.13 The cross section of the cut surface c of the positive electrode single plate P after being cut by the electrode cutting head 14a and the electrode cutting head 14b. Fig.17 500a and 500b are shown in the figure. Since the range where the circular blades 50a and 50b touch the positive electrode collector P1 is relatively small, the burrs extending from the end face of the positive electrode collector P1 due to the positive electrode collector P1 being touched by the circular blades 50a and 50b are suppressed. In addition, as described later, by making the circular blades 50a and 50b leave the cut surface after cutting, the circular blades 50a and 50b will not touch the cut surface when returning, which also suppresses the damage of the cut surface.
[0176] on the other hand, Fig.18 Schematically showing Fig.12 The cut surface c is shown for comparison when the circular blades 50a and 50b are arranged in a manner overlapping each other in the thickness direction of the positive electrode single plate P. The reciprocating range 500a of the circular blade 50a overlaps with the reciprocating range 500b of the circular blade 50b. As the circular blades 50a and 50b rub against the positive electrode collector P1, the end surface of the positive electrode collector P1 stretches and generates burrs. Fig.17 and Fig.18 By comparison, the effect of the arrangement of the circular blades of this embodiment can be clearly seen.
[0177] In addition, as described above, the positive electrode single plate P is cut by reciprocating the circular blades 50a and 50b. Fig.15The circular blades 50a and 50b are schematically shown to reciprocate. The circular blades 50a and 50b are moved back and forth from the initial position in a direction perpendicular to the circumferential direction of the drum by the cutting mechanism module 14t to cut the positive electrode active material layer P2. The circular blades 50a and 50b move back and forth along the moving plane 52.
[0178] Next, the circular blades 50a and 50b return to their initial positions by returning. First, after the electrode cutting head 14a holding the positive electrode plate PP by suction moves away from the electrode cutting head 14b holding the positive electrode single plate P, Fig.11 The cam 14w shown rotates to rotate the rotating shaft 14x. As the rotating shaft 14x rotates, the cutting mechanism module 14t and the circular blades 50a and 50b move in a direction away from the positive single plate P. After that, the circular blades 50a and 50b move back in a direction orthogonal to the circumferential direction of the drum. After the forward movement, the cutting mechanism module 14t and the circular blades 50a and 50b are moved to the initial position again by rotating the cam 14w in the opposite direction. The forward movement track and the return movement track of the circular blades 50a and 50b are different from each other. When returning, the circular blades 50a and 50b do not abut against the cut surface of the positive single plate P and the cut surface of the positive single plate PP, so the damage to the cut surface can be effectively suppressed.
[0179] In the present embodiment, circular blades 50a and 50b are exemplified as the blades of the electrode cutting head, but the shape of the blades is not limited thereto. In addition, in the present embodiment, the damage of the cut surface is suppressed by making the orbits of the reciprocating circular blades 50a and 50b of the electrode cutting head different, but as a structure for suppressing the damage of the cut surface, it is not limited thereto.
[0180] Fig.19 Other blade shapes of the electrode cutting head are shown. The upper and lower blades 50a and 50b are circular blades as a whole, but partially have flat portions. Focusing on the blade 50a, it is composed of an arc portion 50a1 and a flat portion 50a2, with a blade formed on the arc portion 50a1 and no blade formed on the flat portion 50a2. The same is true for the blade 50b. The blade 50b is composed of an arc portion 50b1 and a flat portion 50b2, with a blade formed on the arc portion 50b1 and no blade formed on the flat portion 50b2. The blades 50a and 50b both rotate around the rotation axis and cut the positive electrode single plate P at the arc portions 50a1 and 50b1 where the blades are formed.
[0181] Fig. 20 Shown by Fig.19The rotation of the blades 50a and 50b shown in FIG. 5 cuts the positive electrode single plate P. In the initial position, the arc portion 50a1 of the blade 50a is opposite to the arc portion 50b1 of the blade 50b. When moving to the positive electrode single plate P, the blades 50a and 50b rotate from the initial position, so that Fig. 20 (a) Fig. 20 As shown in (b), the arc portion 50a1 and the arc portion 50b1 are used to cut the positive electrode single plate P. When the blades 50a and 50b are further rotated, Fig. 20 When the positive electrode single plate P is rotated to a position where the flat portion 50a2 and the flat portion 50b2 are opposite to each other as in (c), the cutting of the positive electrode single plate P is completed and the forward movement is completed. During the return movement, the blades 50a and 50b are moved to the initial position while maintaining the flat portion 50a2 and the flat portion 50b2 relative to each other. Since the interaxial distance between the blades 50a and 50b is constant, a gap is generated between the blades 50a and 50b when the flat portion 50a2 and the flat portion 50b2 are opposite to each other. By performing the return movement while maintaining the gap, the blades 50a and 50b will not come into contact with the cut surface, thereby suppressing damage to the cut surface. In this case, there is no need to Fig.15 The rotation of the cam 14w shown causes the cutting mechanism module 14t to move (tilt).
[0182] As described above, the positive electrode single plate P is cut by the positive electrode cutting drum 14 to produce positive electrode plates PP, which are supplied to the positive electrode heating drum 16. For example, the positive electrode plates PP can be supplied from the positive electrode cutting drum 14 to the positive electrode heating drum 16 by a belt conveyor or the like.
[0183] Fig.21 The supply of the positive electrode plate PP from the positive electrode cutting drum 14 to the positive electrode heating drum 16 is schematically shown. Fig. 22 Show Fig.21 A partial enlarged view of the positive electrode cutting drum 14 and the positive electrode heating drum 16, that is, an enlarged view of the abutment portion.
[0184] The belt conveyor 140 is arranged near the contact portion between the positive electrode cutting drum 14 and the positive electrode heating drum 16, and one end of the belt conveyor 140 is inserted into the groove 14r of the positive electrode cutting drum 14 (see Fig.11 ). The width of the pulley on one end side of the belt conveyor 140 inserted into the groove 14r is substantially the same as the width of the groove 14r. The pulley on the other end side of the belt conveyor 140 is arranged near the positive electrode heating drum 16. The belt of the belt conveyor 140 extends from the groove 14r of the positive electrode cutting drum 14 to the vicinity of the positive electrode heating drum 16, and turns back at the pulley on the other end side of the belt conveyor 140 and returns to the groove 14r of the positive electrode cutting drum 14 again.
[0185] The positive electrode single plate PP is cut by the positive electrode cutting drum 14, and is held by suction on the outer peripheral surface of the positive electrode cutting drum 14 and is rotated and conveyed. When the positive electrode plate PP is rotated and conveyed and abuts against the belt conveyor 140 with one end inserted into the groove 14r, the positive electrode plate PP climbs onto the belt conveyor 140, leaves the surface of the positive electrode cutting drum 14, and rides on the belt conveyor 140. The positive electrode plate PP riding on the belt conveyor 140 is transported to the positive electrode heating drum 16 by the belt conveyor 140, is attracted by the suction holes formed on the outer peripheral surface of the positive electrode heating drum 16, moves from the belt conveyor 140 to the outer peripheral surface of the positive electrode heating drum 16, and is held by suction. In the above description, the portion of the belt conveyor 140 inserted into the groove 14r is held by the pulley on one end side, but a blade may be inserted into the groove 14r instead of the pulley, and the portion of the belt conveyor 140 inserted into the groove 14r may be held by the blade.
[0186] The above description describes the cutting of the positive electrode single plate P by the positive electrode cutting drum 14 and the supply of the positive electrode plate PP from the positive electrode cutting drum 14 to the positive electrode heating drum 16, but the same is true for the cutting of the negative electrode single plate N by the negative electrode cutting drum 10 and the supply of the negative electrode plate NP from the negative electrode cutting drum 10 to the negative electrode heating drum 12. In addition, with regard to the cutting of the strip separator by the separator cutting drum 20, damage to the cut surface can also be suppressed by returning the blades 50a and 50b without contacting the cut surface.
[0187] Next, the process of supplying the negative electrode plate NP or the positive electrode plate PP from the negative electrode heating drum 12 or the positive electrode heating drum 16 to the bonding drum 18 will be described in detail.
[0188] Fig.23A The negative electrode heating drum 12 and the bonding drum 18 are shown. The negative electrode heating drum 12 receives the negative electrode plate NP cut out by the negative electrode cutting drum 10, and heats the negative electrode plate NP while adsorbing and holding the negative electrode plate NP on the outer peripheral surface and rotating and conveying the negative electrode plate NP. In addition, the heated negative electrode plate NP is sequentially bonded to the strip-shaped separator S1 at a constant interval at a position adjacent to the bonding drum 18, and the separator S1 is adsorbed and held on the outer peripheral surface of the bonding drum 18 and is rotating and conveying.
[0189] The negative electrode heating drum 12 is supported by an axis so as to be able to swing freely around the drum rotation fulcrum 122, and is swung around the drum rotation fulcrum 122 by a motor 124. In addition, a coil spring 120 is provided on the negative electrode heating drum 12 so as to face the drum rotation fulcrum 122. When the negative electrode heating drum 12 swings around the rotation fulcrum 122, the deflection amount of the coil spring 120 changes, thereby adjusting the pressure of the pressure point which is the contact point between the negative electrode heating drum 12 and the bonding drum 18.
[0190] The negative electrode heating roller 12 uses the pressure of the pressure point to press the heated negative electrode plate NP against the strip-shaped separator S1 on the bonding roller 18 to bond the negative electrode plate NP to the separator S1, but the negative electrode heating roller 12 has a limited eccentricity, and the bonding roller 18 also has a limited eccentricity. If there is an eccentricity, the deflection amount of the coil spring 120 changes, so it is impossible to press the negative electrode plate NP with a constant pressure to bond it.
[0191] Therefore, the eccentricity of the negative electrode heating roller 12 and the bonding roller 18 are synthesized, and the synthesized value is used to coordinate with the rotation of the rollers, so that the motor 124 is always rotated, and the negative electrode heating roller 12 is swung around the rotation fulcrum 122 as the center, thereby offsetting the change in the pressure at the pressurizing point, and pressurizing the negative electrode plate NP with a substantially constant pressure to bond it to the strip-shaped separator S1.
[0192] The eccentricity of the negative electrode heating roller 12 and the bonding roller 18 is measured in advance and stored in the memory of the control device as a table. A drive signal based on a cancellation waveform such as a composite waveform that cancels the eccentricity of the two rollers is supplied to the motor 124 to suppress the deflection of the coil spring 120 caused by the eccentricity, thereby suppressing the change of the pressure.
[0193] The control device drives the motor 124 using the cancellation waveform as a drive signal waveform, thereby canceling the respective eccentricities and pressing the negative electrode heating drum 12 against the bonding drum 18 at a constant pressure at all times.
[0194] However, if the negative electrode heating roller 12 is pressed against the bonding roller 18 with a constant pressure to bond the negative electrode plate NP to the strip-shaped separator S1, the negative electrode plate NP may be damaged by the pressure, especially at the ends of the negative electrode plate NP, i.e., at the ends of the roller in the circumferential direction. Therefore, the pressure between the negative electrode heating roller 12 and the bonding roller 18 is reduced or the pressure is interrupted (the pressure is set to 0) at both ends of the negative electrode plate NP in the circumferential direction, rather than bonding the negative electrode plate NP to the separator S1 with a constant pressure, to prevent damage to both ends of the negative electrode plate NP.
[0195] Fig.24 The negative electrode plate NP is bonded to the strip-shaped separator S1 with a constant pressure. Fig.24 The negative electrode plate NP is bonded to the separator S1 without reducing the pressure between the negative electrode heating roller 12 and the bonding roller 18 or interrupting the pressure. Fig.24 In the figure, the separator S1 is shown in a straight line, but in fact, it is adsorbed and held on the bonding roller 18 and is in an arc-shaped state along the arc-shaped outer shape of the bonding roller 18. Fig.24In the embodiment, one negative electrode plate NP is heated by the negative electrode heating drum 12 , but a plurality of negative electrode plates NP may be heated.
[0196] exist Fig.24 In (a), the negative electrode heating roller 12 directly contacts the separator S1 in the area where the negative electrode plate NP does not exist, and presses the separator S1 with a constant pressure. Fig.24 As shown in (b), the first thing to do is to climb onto the circumferential front end of the negative electrode plate NP and press the circumferential front end against the separator S1 with a constant pressure. At this time, the front end of the negative electrode plate NP is flattened and deformed by the pressure.
[0197] After that, the negative electrode heating roller 12 also continues to press the negative electrode plate NP against the separator S1 with a constant pressure, so that the negative electrode plate NP is bonded to the separator S1. Fig.24 As shown in (c), since the rear end portion of the negative electrode plate NP in the circumferential direction is also pressed against the separator S1 with a constant pressure, the rear end portion is also compressed and deformed by the pressure like the front end portion.
[0198] When the negative electrode heating roller 12 is pressed against the bonding roller 18 with a constant pressure, the separator S1 is pressed even in the portion where the negative electrode plate NP is not present, so the separator S1 may be damaged, and the circumferential front end and circumferential rear end of the negative electrode plate NP may also be pressed and damaged. Fig.24 In (c), the flattening of the circumferential front end portion and the circumferential rear end portion is schematically shown as an inclined surface shape.
[0199] on the other hand, Fig.25 The present embodiment shows a state where the negative electrode plate NP is bonded to the separator S1. Fig.25 The negative electrode plate NP is bonded to the separator S1 at a time point when the pressure between the negative electrode heating roller 12 and the bonding roller 18 is reduced or the pressure is interrupted. Fig.25 In the figure, the separator S1 is shown in a straight line, but in fact, it is adsorbed and held on the bonding roller 18 and is in an arc-shaped state along the arc-shaped outer shape of the bonding roller 18. Fig.25 In the embodiment, one negative electrode plate NP is heated on the negative electrode heating drum 12, but a plurality of negative electrode plates NP may be heated.
[0200] exist Fig.25In (a), the negative electrode heating roller 12 limits the pressure at the pressure point in the area where the negative electrode plate NP does not exist, and does not press the negative electrode heating roller 12 against the bonding roller 18. In this state, the negative electrode plate NP is rotated and conveyed, and even if the circumferential front end of the negative electrode plate NP abuts against the separator S1, the constant pressure limit is maintained intact. Therefore, the circumferential front end of the negative electrode plate NP is not pressed.
[0201] exist Fig.25 In (b), when the negative electrode plate NP is further rotated and conveyed and the center portion excluding the circumferential front end portion contacts the separator S1, the negative electrode heating drum 12 is pressed against the bonding drum 18 with a constant pressure. Thus, the negative electrode plate NP is bonded to the separator S1.
[0202] exist Fig.25 In (c), when the negative electrode plate NP is further rotated and conveyed and the circumferential rear end portion contacts the separator S1, the pressure is limited and the negative electrode heating drum 12 is not pressed against the bonding drum 18. Therefore, the circumferential rear end portion of the negative electrode plate NP is not pressed.
[0203] By constituting as above that only the central portion of the negative electrode plate NP is pressed with a constant pressure, the constant pressure is limited to the two ends of the negative electrode plate NP, i.e., the front end in the circumferential direction and the rear end in the circumferential direction without pressing the two ends, thereby preventing damage to the two ends of the negative electrode plate NP. In addition, the constant pressure is also limited in the area where the negative electrode plate NP does not exist, thereby also preventing damage to the separator S1.
[0204] In addition to eliminating the eccentricity between the negative electrode heating roller 12 and the bonding roller 18, the control device also reduces the pressure between the negative electrode heating roller 12 and the bonding roller 18 at both ends of the negative electrode plate NP or stops the pressure. Fig. 23B , Fig.23C The mechanism for reducing the pressure between the negative electrode heating roller 12 and the bonding roller 18 or interrupting the pressure application will be described.
[0205] Fig. 23B , Fig.23CIt is a stereoscopic view and a rear view of the pressure adjustment mechanism, in which a cam mechanism 80 is provided on the support α of the bonding roller 18. A swing arm 82 is installed on the support β of the negative heating roller 12 as an arm engaged with the cam mechanism 80, and the swing arm 82 axis supports the roller 84. The surface of the cam mechanism 80 is in contact with the roller 84. The surface shape of the cam mechanism 80 has a polygon or has protrusions at a predetermined interval. The cam mechanism 80 operates in a manner that the corner part or protrusion of the polygon reduces the pressure between the negative heating roller 12 and the bonding roller 18 or interrupts the pressure. The cam mechanism 80 is driven by a motor independent of the drive of the motor 124. By operating the cam mechanism 80, the distance between the negative heating roller 12 and the bonding roller 18 can be controlled, and the pressure applied to the negative plate NP can be reduced or the pressure can be interrupted.
[0206] In addition, the pressure between the negative electrode heating roller 12 and the bonding roller 18 is kept constant by driving the motor 124, but the distance between the support β to which the negative electrode heating roller 12 is mounted and the support α to which the bonding roller 18 is mounted changes. As the distance changes, the distance between the cam mechanism 80 and the roller 84 changes, and there is a possibility that the pressure between the negative electrode heating roller 12 and the bonding roller 18 cannot be reduced at a predetermined time or the pressure is interrupted.
[0207] In order to keep the distance between the cam mechanism 80 and the roller 84 constant, the roller 86 is provided on the swing arm 82, and the inclined member 88, the roller 90 and the cam mechanism 92 which can be driven independently with respect to the support β of the negative electrode heating drum 12 are provided on the support β side. The roller 86 contacts the inclined surface of the inclined member 88. The roller 90 is attached to the inclined member 88 and contacts the cam mechanism 92. By using the cam mechanism 92 driven by the motor to move the inclined member 88 up and down, the swing arm 82 is swung by the roller 86 contacting the inclined surface of the inclined member 88.
[0208] The motor 124 is driven according to the canceling waveform, so that the support β and the inclined member 88 move left and right, but the motor (not shown) that moves the cam mechanism 92 up and down is also driven according to the canceling waveform, so that the inclined surface of the inclined member 88 also moves up and down, thereby suppressing the change in the position of the roller 86. By suppressing the change in the position of the roller 86, the change in the distance between the roller 84 and the cam mechanism 80 can be suppressed.
[0209] In addition, the above description describes a method in which the negative electrode plate NP is bonded to the strip-shaped separator S1 with a constant pressure by driving the motor 124, and damage to the two ends of the negative electrode plate NP is suppressed by driving the cam mechanism 80. However, by driving the motor 124, it is also possible to suppress damage to the two ends of the negative electrode plate NP on the basis of bonding the negative electrode plate NP to the strip-shaped separator S1 with a constant pressure.
[0210] For example, the position of the negative electrode plate NP on the negative electrode heating drum 12 and the interval between the negative electrode plates NP can be detected by using a camera disposed near the negative electrode heating drum 12. The control device that monitors and controls the entire manufacturing device can also receive the position data and interval data of the negative electrode plate NP detected by the camera, and control the permission / limitation of the constant pressure (or the turning on / off of the constant pressure) using the received position data and interval data.
[0211] The relationship between the positive electrode heating roller 16 and the bonding roller 18 is the same. The control device uses the driving signal waveform for eliminating the eccentricity between the positive electrode heating roller 16 and the bonding roller 18 and pressing the positive electrode heating roller 16 against the bonding roller 18 with a constant pressure as a reference, and superimposes a driving signal waveform for limiting the constant pressure at the two ends of the positive plate PP and the area where the positive plate PP does not exist on the driving signal waveform to drive the roller.
[0212] Furthermore, the hot pressing roller 19 is a roller used to press the strip-shaped separator S1 / negative electrode plate NP / strip-shaped separator S2 for hot pressing, and the control device can also drive the roller with a driving signal waveform for limiting a constant pressure at both ends of the negative electrode plate NP and in an area where the negative electrode plate NP does not exist.
[0213] In addition, Fig.23A In the description of FIG. 1 , the roller rotation fulcrum 122, the motor 124 and the coil spring 120 are provided on the negative electrode heating roller 12, but these components may also be provided on the bonding roller 18 side. Fig.23A , the negative electrode heating roller 12 is shown in contact with the bonding roller 18, but there is a case where the roller supplying the positive electrode plate also contacts the bonding roller 18. In such a case, it is preferred that the roller rotation fulcrum, the motor and the coil spring are provided on the roller supplying the positive electrode plate and the roller supplying the negative electrode plate.
[0214] Figure 26 to Figure 28 The pressure ranges of the negative electrode heating drum 12 , the heat pressure bonding roller 19 , and the positive electrode heating drum 16 are shown.
[0215] Fig.26The single-dotted line shows the range of pressure applied when the strip-shaped separator S1 and the negative electrode plate NP are bonded using the negative electrode heating roller 12 and the bonding roller 18. The two ends of the strip-shaped separator S1 in the negative electrode plate NP in the longitudinal direction are not pressurized, and the other areas are pressurized and pressed. In other words, the two opposite sides of the four sides of the rectangular negative electrode plate NP, that is, the two opposite sides in the longitudinal direction of the strip-shaped separator S1, are not pressurized, and the two opposite sides in the direction orthogonal to the longitudinal direction are pressurized. The pressurized parts of the two pressurized sides of the four sides of the rectangular negative electrode plate NP are bonded to the separator S1, and the two sides that are not pressurized are not bonded to the separator S1.
[0216] Fig. 27 The dot-dash line shows the pressure range when the strip-shaped separator S1, the negative electrode plate NP, and the strip-shaped separator S2 are bonded together by the heat-pressing roller 19 and the bonding roller 18. Fig.26 In the same situation, the two ends of the strip-shaped separators S1 and S2 in the length direction of the negative plate NP are not pressurized, and the other areas are pressurized and pressed. In other words, the two opposite sides of the four sides of the rectangular negative plate NP, that is, the two opposite sides in the length direction of the strip-shaped separators S1 and S2 are not pressurized, and the two opposite sides in the direction orthogonal to the length direction are pressurized. The pressurized parts of the two pressurized sides of the four sides of the rectangular negative plate NP are bonded to the separator S2, and the two non-pressurized sides are not bonded to the separator S1.
[0217] Fig.28 The single-dot chain line shows the range of pressure applied when the strip-shaped separator S1, the negative electrode plate NP, the strip-shaped separator S2 and the positive electrode plate PP are bonded using the positive electrode heating roller 16 and the bonding roller 18. The two ends of the strip-shaped separators S1 and S2 in the length direction of the positive electrode plate PP are not pressurized, and the other areas are pressurized and pressed. In other words, the two opposite sides of the four sides of the rectangular positive electrode plate PP, that is, the two opposite sides in the length direction of the strip-shaped separators S1 and S2 are not pressurized, and the two opposite sides in the direction orthogonal to the length direction are pressurized. The pressurized parts of the two pressurized sides of the four sides of the rectangular positive electrode plate PP are bonded to the separators S1 and S2, and the two sides that are not pressurized are not bonded to the separators S1 and S2.
[0218] Since the size of the positive plate PP is smaller than that of the negative plate NP, Fig.28 The pressure range is less than Fig.26 As described above, the three-layer laminate 30 and the four-layer laminate 40 are manufactured while controlling the pressurization range.
[0219] Next, the lamination process performed by the lamination drum 22 and the lamination stage 24 will be described in more detail.
[0220] Fig.29 The structure stereogram of the stacking drum 22 is shown. The stacking drum 22 is arranged adjacent to the diaphragm cutting drum 20 and rotates at substantially the same linear speed as the diaphragm cutting drum 20. The stacking drum 22 includes a plurality of stacking heads that rotate around the center of rotation of the drum. The number of stacking heads is arbitrary, and for example, 12 stacking heads 22a, 22b, 22c, 22d, 22e, 22f, 22g, 22h, 22i, 22j, 22k, and 22m are included. Each stacking head includes an arm (spoke) connected to the central axis (center) of the drum at one end and a retaining portion connected to the other end of the spoke. The longitudinal cross-sectional shape of each stacking head is substantially T-shaped due to the arm and the retaining portion, and an adsorption hole is formed on the outer peripheral surface of the retaining portion, which is used to adsorb and retain the three-layer stack 30 and the four-layer stack 40 generated by cutting the diaphragm cutting drum 20. The retaining portion is connected to the arm in a manner that it can swing freely in the circumferential direction relative to the arm.
[0221] The plurality of stacking heads 22a to 22m rotate around the central axis of the stacking drum 22, and each stacking head is driven independently in the circumferential direction of the drum relative to the other stacking heads, and then driven in the radial direction of the drum. That is, each stacking head rotates and transports the three-layer stack 30 and the four-layer stack 40 to a position adjacent to the stacking stage 24 while adsorbing and holding them. When each stacking head reaches a position adjacent to the stacking stage 24, the relative speed of the stacking head in the circumferential direction of the drum relative to the stacking stage 24 becomes 0, and the stacking head moves in the radial direction of the drum toward the stacking stage 24. Each stacking head close to the stacking table 24 brings the three-layer stack 30 or four-layer stack 40 held by suction into contact with the stacking table 24, or brings the three-layer stack 30 or four-layer stack 40 held by suction into contact with the stacking table 24 if the three-layer stack 30 or four-layer stack 40 is already stacked on the stacking table 24, releases the suction holding force, and stacks the three-layer stack 30 or four-layer stack 40 held by suction. After that, each stacking head moves in the direction away from the stacking table 24 in the radial direction of the drum.
[0222] Figure 30 to Figure 33 Hereinafter, in the description of the operation of each laminating head, the "radial direction of the drum" and the "radial direction of the laminating drum 22" will be appropriately referred to as the "radial direction".
[0223] like Fig.30As shown, the stacking heads 22a to 22m rotate at a constant angular velocity around the rotation center axis of the stacking drum 22, but when reaching a predetermined position, they accelerate in the circumferential direction independently of the other stacking heads. For example, focusing on the stacking head 22a, when reaching a predetermined position in the circumferential direction, the stacking head 22a accelerates and approaches the adjacent stacking head 22m on the upstream side in the rotation direction, and moves away from the adjacent stacking head 22b on the downstream side in the rotation direction.
[0224] After acceleration Fig.31 When the stacking head 22a reaches a position adjacent to the stacking table 24, the relative speed of the stacking head 22a in the circumferential direction of the roller relative to the stacking table 24 becomes 0. The stacking head 22a stacks the three-layer stack 30 or the four-layer stack 40 held by suction on the outer circumference on the stacking table 24 at this adjacent position. More specifically, when the stacking head 22a approaches the position adjacent to the stacking table 24, it swings to an angle such that the outer circumferential surface of the holding portion is substantially parallel to the table surface of the stacking table 24, and while maintaining the outer circumferential surface of the holding portion substantially parallel to the table surface of the stacking table 24, the stacking head 22a moves in the direction of the stacking table 24 by moving the arm in the radial direction, so that the outer circumferential surface of the holding portion approaches the table surface of the stacking table 24, and the three-layer stack 30 or the four-layer stack 40 held by suction on the outer circumferential surface is stacked on the stacking table 24.
[0225] Fig.32 and Fig.33 The state after stacking the three-layer stack 30 or the four-layer stack 40 on the stacking table 24 is shown. The adjacent stacking head 22b on the downstream side of the stacking head 22a in the rotation direction accelerates due to reaching the specified position and approaches the stacking head 22a. After stacking the three-layer stack 30 or the four-layer stack 40 on the stacking table 24, the stacking head 22a rotates in the circumferential direction and retreats from the position adjacent to the stacking table 24. More specifically, the stacking head 22a moves in the radial direction by the arm and moves in the direction of the outer peripheral surface away from the adjacent position adjacent to the table surface of the stacking table 24. In order not to interfere with the stacking head 22b, the stacking head 22a moves in the rotation direction and retreats. After retreating from the adjacent position, the outer peripheral surface of the holding portion swings in the opposite direction and recovers.
[0226] Fig.34 A specific configuration example of the lamination head 22a is shown. The same applies to the other lamination heads 22b to 22m.
[0227] The stacking head 22a includes a holding portion 22a3 and two arms 22a1 and 22a2. The arms 22a1 and 22a2 extend in parallel along the radial direction of the stacking drum 22, and the arms 22a1 and 22a2 are integrally driven to rotate along the circumferential direction of the drum by a cam mechanism 22a4, and the arms 22a1 and 22a2 are driven to swing along the circumferential direction by a cam mechanism 22a5. An outer peripheral surface 22a3 that can swing freely is provided at the radial ends of the arms 22a1 and 22a2. The outer peripheral surface 22a3 rotates while the arms 22a1 and 22a2 rotate in the circumferential direction, and swings and moves while the arms 22a1 and 22a2 swing and move in the radial direction. In addition, the outer peripheral surface 22a3 swings relative to the arms 22a1 and 22a2 by a cam mechanism 22a6.
[0228] Fig.35 The time change of the position of the laminating head 22a is shown. In the figure, the horizontal axis represents time, and the vertical axis represents the position (angle) in the circumferential direction of the drum.
[0229] The laminating head 22 a rotates at a constant angular velocity from a certain reference position to the position θ1 . The outer peripheral surface 22 a 3 rotates while holding the three-layer laminate 30 or the four-layer laminate 40 by suction.
[0230] Next, when the predetermined position θ1 is reached, the stacking head 22a is accelerated in the circumferential direction, and the outer peripheral surface 22a3 is also accelerated. During this period, the adjacent stacking head 22b in the downstream direction of rotation continues to rotate at a constant angular velocity, so the distance between the stacking head 22a and the stacking head 22b increases. Through this acceleration, it can be said that the stacking head 22a generates and ensures the stop time at a position adjacent to the stacking table 24, that is, the stacking time of the three-layer stack 30 or the four-layer stack 40 stacked on the stacking table 24. In addition, during this acceleration, the outer peripheral surface 22a3 swings relative to the arms 22a1 and 22a2, and is tilted in a manner that the surface that adsorbs and holds the three-layer stack 30 or the four-layer stack 40 is roughly parallel to the table surface of the stacking table 24.
[0231] Next, when the stacking head 22a reaches the position θ2 adjacent to the stacking table 24, it stops at the position (of course, deceleration control is performed before stopping, but it is omitted for the sake of convenience), and the arms 22a1 and 22a2 are moved in the radial direction so that the outer peripheral surface approaches the table surface of the stacking table 24, and the suction force of the outer peripheral surface is released, and the three-layer stacked body 30 or the four-layer stacked body 40 is stacked on the stacking table 24. At this time, the corners of the three-layer stacked body 30 or the four-layer stacked body 40 supplied from the stacking table 22a are pressed and held by the claws provided on the stacking table 24. The operation of the claws of the stacking table 24 in conjunction with the operation of the stacking head 22a will be further described later.
[0232] After stacking three or four layers of stacked bodies 30 or 40, the stacking head 22a rotates at an accelerated speed to retreat to a predetermined position θ3. During the retreat, the outer peripheral surface 22a3 swings relative to the arms 22a1 and 22a2, so that the surface that attracts and holds the three or four layers of stacked bodies 30 or 40 is tilted and restored to the initial angle.
[0233] Then, when reaching the predetermined position θ3, the stacking head 22a rotates again at a constant angular velocity until reaching the predetermined position θ1 again. During this period, the stacking head 22a receives a new three-layer stack 30 or four-layer stack 40 from the diaphragm cutting drum 20 and holds them by suction on the outer peripheral surface 22a3 before reaching the predetermined position θ1.
[0234] Next, the operation of the laminating stage 24 will be described in more detail.
[0235] Fig.36 The stacking table 24 is a perspective view of the structure. The stacking table 24 is arranged directly below the stacking roller 22. The stacking table 24 includes a table 24g on which the three-layer stacked bodies 30 and the four-layer stacked bodies 40 are stacked, and claws 24a to 24d for pressing and holding the three-layer stacked bodies 30 and the four-layer stacked bodies 40 stacked on the table 24g from above.
[0236] The table 24g is formed into a rectangular shape corresponding to the rectangular shape of the three-layer stack 30 and the four-layer stack 40, and is arranged in a substantially horizontal plane. The three-layer stack 30 or the four-layer stack 40 adsorbed and held on the outer peripheral surface of the stacking heads 22a to 22m of the stacking roller 22 is positioned and arranged on the rectangular table 24g and stacked. Specifically, when the two orthogonal axes in the horizontal plane are set as the X-axis and the Y-axis, and the rotation direction of the X-axis based on a certain direction in the horizontal plane is set as the θ direction, the table 24g is driven along the X-axis and the Y-axis directions, and driven along the θ direction, that is, the movement drive and rotation drive in the horizontal plane are performed, so as to be positioned to match the adsorption and holding posture of the three-layer stack 30 or the four-layer stack 40 adsorbed and held on the outer peripheral surface of the stacking heads 22a to 22m of the stacking roller 22. The stacking order is, for example, first placing the three-layer stack 30 on the table 24g, then stacking the four-layer stack 40 on the three-layer stack 30, and then stacking the new four-layer stack 40 on the already stacked four-layer stack 40.
[0237] The claws 24a to 24d are respectively arranged at the four corners of the rectangular table 24g. The planar shapes of the claws 24a to 24d are respectively substantially L-shaped, and the claws 24a to 24d are supported to swing freely in the θ direction with the axis as the center, and are supported to move freely in the vertical direction (hereinafter appropriately referred to as the vertically above or the vertically below). The driving source of the claws 24a to 24d can also be mounted on the stacking table 24 in the same manner as the driving source for driving and positioning the table 24g in the XY direction and the θ direction, but in order to seek lightweight stacking table 24, it can also be mounted outside the stacking table 24. In the case where the driving source of the claws 24a to 24d is mounted outside the stacking table 24, the external driving source and the claws 24a to 24d are connected by a cam mechanism using a metal wire 24e, and the driving force from the external driving source is transmitted by the metal wire 24e to swing and drive the claws 24a to 24d up and down. The claws 24a to 24d are pressed vertically downward by the spring 24f, and the three-layer stacked body 30 and the four-layer stacked body 40 on the table 24g are pressed and held by the pressing force.
[0238] Fig.37 The planar arrangement of the table 24g and the claws 24a to 24d of the stacking table 24 is shown. When the table 24g is set to a rectangular shape, the claws 24a to 24d are arranged at the four corners of the rectangular shape. The claws 24a and 24c are arranged on the diagonal line of the table 24g, and the claws 24b and 24d are arranged on the other diagonal line of the table 24g. The claws 24a and 24c form a pair, which is the first claw pair, and the claws 24b and 24d form a pair, which is the second claw pair. The claws 24a to 24d can swing freely (rotate freely) clockwise and counterclockwise around the rotation axis. Focusing on the claw 24d, it is arranged at the upper left corner of the table 24g, and its axis is located in the area defined by the extension lines of the two opposite long sides of the table 24g. The claw 24d retreats to the outside of the existence area of the table 24g (retreat position) at the initial position, and by swinging clockwise, it is partially located in the existence area of the table 24g, and presses the stacked body (3-layer stacked body 30 and 4-layer stacked body 40) stacked on the table 24g at the pressing position. In addition, focusing on the claw 24a, it is arranged at the upper right corner of the table 24g, and its axis is located in the area defined by the extension lines of the two opposite long sides of the table 24g. The claw 24a retreats to the outside of the existence area of the table 24g (retreat position) at the initial position, and by swinging counterclockwise, it is partially located in the existence area of the table 24g, and presses and holds the stacked body stacked on the table 24g. The claw 24b performs the same action as the claw 24d, and the claw 24c performs the same action as the claw 24a.
[0239] When pressing and holding the stacked body, the claws 24a and 24c and the claws 24b and 24d located on the diagonal line of the table 24g swing as a group in the horizontal plane and move up and down. That is, the first claw pair of the claws 24a and 24c swings to press and hold the stacked body, but at this time, the second claw pair of the claws 24b and 24d presses and holds the stacked body, so the newly stacked body is not held. In addition, when a new stacked body is stacked next, the second claw pair of the claws 24b and 24d swings and retreats from the table 24g, moves upward, and swings again to press and hold the newly stacked body.
[0240] Fig.38 The operation of pressing and holding the laminated body by the claws 24a to 24d is shown.
[0241] Fig.38 (a) shows a state where the three-layer stack 30-1 stacked on the table 24g is pressed and held. When the three-layer stack 30-1 is initially stacked on the table 24g, the claws 24a and 24c swing counterclockwise and are arranged on the three-layer stack 30-1, and the three-layer stack 30-1 is pressed vertically downward from above by the pressure of the spring 24f to hold the three-layer stack 30-1.
[0242] Fig.38 (b) shows that Fig.38 The state (a) is a state where a 4-layer laminate 40-2 is newly laminated on the 3-layer laminate 30-1. The 4-layer laminate 40-2 is laminated from above the claws 24a and 24c that press and hold the 3-layer laminate 30-1, so that the 4-layer laminate 40-2 is laminated in a manner that covers parts of the claws 24a and 24c.
[0243] Fig.38 (c) shows the state of pressing and holding the four-layer stack 40-2. In the state of pressing and holding the three-layer stack 30-1 by the claws 24a and 24c, the claws 24b and 24d move vertically upward, and then swing in the clockwise direction to be arranged on the four-layer stack 40-2. The claws 24b and 24d press and hold the four-layer stack 40-2 from the top to the vertical bottom by the pressure of the spring 24f.
[0244] Fig.38 (d) shows that Fig.38The state (c) of the claws 24a and 24c is a state in which the claws 24a and 24c are retracted. After the four-layer stack 40-2 is pressed and held by the claws 24b and 24d, the claws 24a and 24c no longer need to press and hold the three-layer stack 30-1, and in order not to become an obstacle to the next newly stacked stack, they need to retreat from the table 24g. Therefore, the claws 24a and 24c are moved vertically upward and swung clockwise to retreat from the table 24g. At this time, the three-layer stack 30-1 and the four-layer stack 40-2 are pressed and held by the claws 24b and 24d, so that their stacking positions will not be misaligned due to the swing of the claws 24a and 24c.
[0245] Fig.38 (e) shows that Fig.38 The state (d) is a state where the next stack 40-3 is newly stacked on the 4-layer stack 40-2. The 4-layer stack 40-3 is stacked from above the claws 24b and 24d that press and hold the 4-layer stack 40-2, so the 4-layer stack 40-3 is stacked in a manner that covers parts of the claws 24b and 24d.
[0246] Fig.38 (f) shows the state of pressing and holding the 4-layer stack 40-3. While the 4-layer stack 40-2 is pressed and held by the claws 24b and 24d, the claws 24a and 24c move vertically upward, and then swing in the counterclockwise direction to be arranged on the 4-layer stack 40-3. The claws 24a and 24c press and hold the 4-layer stack 40-3 from the top to the vertical bottom by the pressure of the spring 24f. By repeating the above actions, the 4-layer stacks 40-2, 40-3, ... are sequentially stacked on the 3-layer stack 30-1.
[0247] The claws 24a to 24d of this embodiment and their respective shafts are as follows: Fig.37 Although shown as being arranged in the area defined by the extension lines of the two opposite long sides of the table top 24g, it is not necessarily limited thereto and may be arranged outside the area defined by the extension lines of the two opposite long sides of the table top 24g. The area defined by the extension lines of the two opposite long sides of the table top 24g is an area that also includes the table top 24g. The area outside the area defined by the extension lines of the two opposite long sides of the table top 24g is an area that does not include the table top 24g.
[0248] Fig.39 The top view shows a case where the axes of the claws 24a to 24d are arranged outside the area defined by the extension lines of the two opposing long sides of the table 24g. Focusing on the claw 24d, it is arranged at the upper left corner of the table 24g, and its axis is located outside the area defined by the extension lines of the two opposing long sides of the table 24g. Note that Fig.37 The position of the claw 24d in Fig.39The same is true for the other claws 24a to 24c. Fig.39 In the embodiment, the axes of the claws 24a to 24d are located outside the region defined by the extension lines of the two opposing short sides of the table 24g. The region outside the region defined by the extension lines of the two opposing short sides of the table 24g is a region that does not include the table 24g.
[0249] If the axes of the claws 24a to 24d are arranged outside the area defined by the extension lines of the two opposing long sides of the table 24g, when the laminated body held by suction on the outer peripheral surface of the laminating heads 22a to 22m of the laminating roller 22 is laminated on the table 24g, the laminated body is not inserted from directly above the table 24g, but is inserted from obliquely above the table 24g by the outer peripheral surface moving along the circumference. When the radius of the laminating roller 22 is relatively large enough compared to the size of the table 24g, the situation is roughly equivalent to the situation where the laminated body is inserted from the lateral direction of the table 24g.
[0250] exist Fig.39 Schematically shows the situation where such a stacked body enters from the lateral direction of the table 24g. A 4-layer stacked body 40-2 is stacked on the table 24g, and the 4-layer stacked body 40-2 is pressed and held by claws 24a and 24c. When a new 4-layer stacked body 40-3 is stacked, the 4-layer stacked body 40-3 adsorbed and held on the outer peripheral surface of the stacking roller 22 enters from the lateral direction of the table 24g (from the bottom in the figure). The axes of the claws 24b and 24d are arranged outside the area defined by the extension lines of the two opposite long sides of the table 24g. Even if the claws 24b and 24d move vertically upward, swing, and are located on the table 24g, they will not collide with the next 4-layer stacked body 40-3 entering from the lateral direction. The claws 24b and 24d will not become obstacles for the 4-layer stacked body 40-3. Therefore, when stacking the four-layer stack 40-3, it is not necessary to retreat the claws 24b and 24d to the outside of the existence area of the table 24g (retreat position). The claws 24b and 24d are positioned on the table 24g (standby position) and standby. After the four-layer stack 40-3 is stacked on the four-layer stack 40-2, the claws 24b and 24d can quickly press and hold the four-layer stack 40-3 using the pressure of the spring 24f.
[0251] Figure 40 to Figure 44 The operation of the claws 24a to 24d of the laminating stage 24 in conjunction with the operation of the laminating heads 22a to 22m is shown in more detail. The operation of the laminating head 22a is shown in the figure as an example, but the operation of the other laminating heads 22b to 22m is also the same.
[0252] Fig.40The side view is shown in the case where the three-layer stack 30-1 and the four-layer stack 40-2 are already stacked on the table 24g of the stacking table 24 and the four-layer stack 40-3 is newly stacked by the stacking head 22a. In the figure, 24c and 24d are shown as claws, but the claw 24a operates in the same way as the claw 24c, and the claw 24b operates in the same way as the claw 24d.
[0253] The claw 24c uses the pressure of the spring 24f to press and hold the three-layer stack 30-1 and the four-layer stack 40-2 on the table 24g. On the other hand, the claw 24d moves vertically upward and swings around the axis, and is in a standby state in a manner in which its part is located above the table 24g (retreat position). The stacking head 22a absorbs and holds the four-layer stack 40-3 on its outer peripheral surface and rotates, and accelerates and approaches the position adjacent to the table 24g when reaching a specific position. When the stacking head 22a approaches the position adjacent to the table 24g, the holding portion 22a3 swings relative to the arms 22a1 and 22a2, and makes the outer peripheral surface roughly parallel to the table 24g while avoiding collision with the table 24g.
[0254] Fig.41 This is the case where the lamination head 22a reaches a position close to the mesa 24g.
[0255] The arms 22a1 and 22a2 of the stacking head 22a move along the radial direction of the stacking roller 22, and the holding portion 22a3 also moves vertically downward, so that the outer peripheral surface of the holding portion 22a3 is closer to the table 24g. At this time, the claw 24d is in a standby state above the table 24g (retreat position), and the claw 24c maintains the state of pressing and holding the three-layer stack 30-1 and the four-layer stack 40-2. Afterwards, in this state, Fig.42 As shown, the stacking head 22a stacks the 4-layer stack 40-3 on the 3-layer stack 30-1 and the 4-layer stack 40-2 on the table 24g, and releases the adsorption force of the holding part 22a3. In addition, the holding part 22a3 may be temporarily stopped from moving vertically downward until the 4-layer stack 40-3 is stacked on the 3-layer stack 30-1 and the 4-layer stack 40-2 on the table 24g. By temporarily stopping, the impact when the 4-layer stack 40-3 is stacked on the 3-layer stack 30-1 and the 4-layer stack 40-2 on the table 24g can be alleviated.
[0256] Fig.43The state where the 4-layer stack 40-3 is stacked on the 3-layer stack 30-1 and the 4-layer stack 40-2 is shown. Since the claw 24c (and the claw 24a) press and hold the 3-layer stack 30-1 and the 4-layer stack 40-2, the 4-layer stack 40-3 is stacked on the claw 24c (and the claw 24a). In addition, the claw 24d (and the claw 24b) is in a standby state above the table 24g. When the 4-layer stack 40-3 is stacked, the claw 24d (and the claw 24b) quickly moves vertically downward to press and hold the newly stacked 4-layer stack 40-3. When the 4-layer stack 40-3 is pressed and held by claw 24d (and claw 24b), claw 24c (and claw 24a) no longer needs to press and hold the 3-layer stack 30-1 and the 4-layer stack 40-2, so it moves vertically upward, then swings around the axis and retreats from the table 24g, and waits above the table 24g (retreat position).
[0257] Fig.44 The state where the stacking of the four-layer stack 40-3 is completed is shown. The three-layer stack 30-1, the four-layer stack 40-2, and the four-layer stack 4-3 are pressed and held by the claw 24d (and the claw 24b). In addition, the claw 24c (and the claw 24a) are located above the table 24g (retreat position) and are in a standby state to prepare for the stacking of the four-layer stack to be newly stacked next, that is, the four-layer stack held by suction on the outer peripheral surface of the stacking head 22b.
[0258] Thus, according to Fig.39 The configuration of the claws 24a to 24d shown is that the two claws other than the claw for pressing and holding the stack do not need to retreat in order to avoid becoming an obstacle when the next stack enters, and can wait on the table 24g (retreat position). Therefore, after the stack is stacked, the stack can be quickly pressed and held to shorten the total stacking time.
[0259] In addition, the outer peripheral surface (holding portion 22a3) of the stacking head 22a may also be a structure in which the cross section observed from the circumferential direction of the stacking roller 22 is not flat but curved into a concave shape or a convex shape, and the three-layer stack or the four-layer stack is sucked and held on the concave or convex surface. The purpose is to suppress the swaying of the part of the three-layer stack or the four-layer stack extending from the end of the stacking head 22a even when the size of the outer peripheral surface of the stacking head 22a is made smaller than the size of the three-layer stack or the four-layer stack. In the case where the holding portion 22a3 of the stacking head 22a is curved into a convex shape, the position of the stacking head 22a adjacent to the table 24g refers to the position where the distance between the most protruding part of the holding portion 22a3 and the table 24g is the shortest. When the outer peripheral surface of the lamination head 22a is curved in a concave shape, the position where the lamination head 22a is adjacent to the terrace 24g is the position where the distance between the outermost portion of the lamination head 22a and the terrace 24g is the shortest.
[0260] Although the embodiments of the present disclosure have been described above, the present disclosure is not limited to these embodiments, and various modifications are possible. Modifications will be described below.
[0261] <Variation 1>
[0262] In the present embodiment, one set of the stacking roller 22 and the stacking stage 24 is disposed, but a plurality of sets of the stacking roller 22 and the stacking stage 24 may be disposed.
[0263] Fig.45 The configuration diagram is shown in the case where the stacking drum 23 and the stacking stage 25 are arranged in addition to the stacking drum 22 and the stacking stage 24 .
[0264] The three-layer stack 30 and the four-layer stack 40 generated by cutting by the diaphragm cutting drum 20 are supplied to the stacking drum 22 or the stacking drum 23. The three-layer stack 30 and the four-layer stack 40 supplied to the stacking drum 22 are sequentially stacked on the stacking table 24 arranged adjacent to the stacking drum 22. In addition, the three-layer stack 30 and the four-layer stack 40 supplied to the stacking drum 23 are sequentially stacked on the stacking table 25 arranged adjacent to the stacking drum 23.
[0265] The stacking roller 22 and the stacking roller 23 are respectively in contact with the membrane cutting roller 20, and rotate in the same direction relative to the rotation direction of the membrane cutting roller 20. Such a configuration in which the plurality of stacking rollers 22 and 23 rotate in the same direction relative to the conveying direction of the three-layer stacked body 30 and the four-layer stacked body 40 conveyed from the membrane cutting roller 20 is called a parallel configuration. In the parallel configuration, the structures of the stacked bodies stacked on the stacking tables 24 and 25 are the same.
[0266] Fig.46 The following shows a state of stacking using a set of a stacking roller 22 and a stacking stage 24 and a set of a stacking roller 23 and a stacking stage 25 .
[0267] The control device for controlling the entire manufacturing device selectively supplies the three-layer stack 30 and the four-layer stack 40 generated by cutting by the diaphragm cutting drum 20 to either the stacking drum 22 or the stacking drum 23. For example, when a stacked electrode body is first stacked on the stacking table 24 and then stacked on the stacking table 25 to manufacture a stacked electrode body, the control device first supplies the three-layer stack 30 and the four-layer stack 40 from the diaphragm cutting drum 20 to the stacking drum 22.
[0268] The stacking drum 22 receives the three-layer stack 30 supplied from the membrane cutting drum 20 and stacks it on the stacking table 24. Then, a stacked electrode body is manufactured by stacking, for example, a total of 37 four-layer stacks 40 on the three-layer stack 30. When the last 37th four-layer stack 40 is supplied to the stacking drum 22, the control device switches the output destination of the membrane cutting drum 20 from the stacking drum 22 to the stacking drum 23.
[0269] The stacking drum 23 receives the three-layer stack 30 supplied from the membrane cutting drum 20 and stacks it on the stacking table 25. Then, another stacked electrode body is manufactured by stacking, for example, 37 four-layer stacks 40 in total on the three-layer stack 30. When the last 37th four-layer stack 40 is supplied to the stacking drum 23, the control device switches the output destination of the membrane cutting drum 20 from the stacking drum 23 to the stacking drum 22 again.
[0270] In addition, if the three-layer laminate 30, the four-layer laminate 40, the four-layer laminate 40, ..., the three-layer laminate 30, the four-layer laminate 40, ... are normally supplied from the separator cutting drum 20, there is no problem, but there may be a case where an abnormality occurs in at least any one of the negative electrode cutting drum 10, the negative electrode heating drum 12, the positive electrode cutting drum 14, the positive electrode heating drum 16, the bonding drum 18, and the separator cutting drum 20, and the normal three-layer laminate 30 and the four-layer laminate 40 cannot be generated. In such a case, when the abnormality is detected by the detection sensor provided in each drum, the three-layer laminate 30 or the four-layer laminate 40 is excluded as a defect before being supplied to the stacking drums 22 and 23, and the normal stacking of laminates such as stacking 37 four-layer laminates 40 continuously after one three-layer laminate 30 cannot be maintained. For example, when the 37th 4-layer stack 40 is produced, the bonding of the positive electrode plate PP is poor in the bonding drum 18. Therefore, when the 37th 4-layer stack 40 is judged as defective and excluded in the inspection process of the bonding drum 18, the next 3-layer stack 30 is supplied from the separator cutting drum 20 instead of the 37th 4-layer stack 40. If the 3-layer stack 30 is stacked on the stacking stage 24 from the stacking drum 22, a normal stacked electrode body cannot be manufactured.
[0271] Therefore, in such a case, the three-layer stack 30 supplied instead of the 37th four-layer stack 40 may be supplied to the stacking drum 23 instead of the stacking drum 22, and the stacking drum 23 stacks the three-layer stack 30 on the stacking table 25. By supplying the four-layer stack 40 supplied from the diaphragm cutting drum 20 after the three-layer stack to the stacking drum 22 and stacking it on the stacking table 24, a stack in which 37 four-layer stacks 40 are stacked on the three-layer stack 30 is formed on the stacking table 24.
[0272] Furthermore, a predetermined number of stacked bodies, each of which is a stacked body of the three-layer stacked body 30 and a stacked body of the four-layer stacked body 40 , are pressed and / or heated to be bonded to each other, thereby forming a stacked electrode body.
[0273] Fig.47 The stacking method in this case is schematically shown.
[0274] The control device monitors the stacked bodies cut by the membrane cutting drum 20, identifies whether it is a three-layer stacked body 30 or a four-layer stacked body 40, and counts the number of stacked bodies in sequence. When the 37th four-layer stacked body 40 is abnormal and is excluded as defective, the 37th is not a four-layer stacked body 40 but a three-layer stacked body 30.
[0275] For the control device, if the 37th stack is a 4-layer stack 40, it is supplied to the stacking drum 22. However, when it is detected that the 37th stack is not a 4-layer stack 40 but a 3-layer stack 30, the output destination of the diaphragm cutting drum 20 is changed from the stacking drum 22 to the stacking drum 23, and the 3-layer stack 30 is stacked on the stacking stage 25 instead of the stacking stage 24. In the figure, the × mark attached to the 3-layer stack 30 indicates that it is not stacked on the stacking stage 24 but stacked on the stacking stage 25. After that, since the 4-layer stack 40 is supplied in sequence, the control device maintains the output destination of the diaphragm cutting drum 20 as the stacking drum 23, and stacks 37 4-layer stacks 40 in sequence on the stacking stage 25. As for the stacking stage 24, the stacking of the electrode body can be completed by stacking one 4-layer stack 40 that is insufficient at an appropriate time point.
[0276] As described above, by arranging a plurality of sets of stacking rollers and stacking tables and appropriately distributing the stacked bodies, it is possible to efficiently manufacture stacked electrode bodies without stopping the manufacturing process even if a defect occurs in the stacked bodies.
[0277] In addition, defects in the stack can be detected by any roller, but in particular, in order to detect defects in the negative electrode plate NP and the positive electrode plate PP, detection sensors such as cameras can be arranged on the negative electrode heating roller 12 and the positive electrode heating roller 16 to discharge the defects detected by these rollers. In this case, the negative electrode heating roller 12 has a function of heating the negative electrode plate NP and also has a function of determining whether the plate is normal or not and a function of eliminating defects. The positive electrode heating roller 16 also has a function of heating the positive electrode plate PP and also has a function of determining whether the plate is normal or not and a function of eliminating defects.
[0278] When a defect is detected on the negative electrode cutting drum 10 and the positive electrode cutting drum 14, after the negative electrode single plate or the positive electrode single plate is cut, the normal / defective judgment function and the defect elimination function are provided. Alternatively, the negative electrode cutting drum 10 and the positive electrode cutting drum 14 may have a normal / defective judgment function, and the negative electrode heating drum 12 and the positive electrode heating drum 16 may have a defect elimination function.
[0279] When a defect is detected on the membrane cutting drum 20, the normal / defective judgment function and the defect elimination function are provided after the membrane is cut and before the cut laminated body is supplied to the laminating drum. In other words, the membrane cutting drum 20 has the normal / defective judgment function and the defect elimination function while having the function of cutting the membrane.
[0280] <Variation 2>
[0281] exist Fig.45 In the embodiment, the stacking rollers 22 and 23 are arranged in parallel, but the stacking rollers 22 and 23 may be arranged in series with respect to the diaphragm cutting roller 20.
[0282] Fig.48 The structure in this case is shown. The three-layer stack 30 and the four-layer stack 40 generated by cutting by the diaphragm cutting drum 20 are supplied to the stacking drum 22. The stacking drum 23 is arranged to abut against the stacking drum 22 instead of the diaphragm cutting drum 20. The three-layer stack 30 and the four-layer stack 40 are supplied to the stacking drum 23 via the stacking drum 22. The three-layer stack 30 and the four-layer stack 40 supplied to the stacking drum 22 are sequentially stacked on the stacking table 24 arranged adjacent to the stacking drum 22. In addition, the three-layer stack 30 and the four-layer stack 40 supplied to the stacking drum 23 are sequentially stacked on the stacking table 25 arranged adjacent to the stacking drum 23.
[0283] The stacking roller 22 and the stacking roller 23 rotate in different directions. The configuration in which the stacking roller 22 and the stacking roller 23 that are in contact with each other rotate in different directions is called a series configuration. Rotating in different directions means that one roller rotates clockwise while the other roller rotates counterclockwise. In the series configuration, the structures of the stacked bodies stacked on the stacking stages 24 and 25 may be different.
[0284] That is, the stacking roller 23 is supplied with the three-layer stack 30 and the four-layer stack 40 via the stacking roller 22 abutting against it, but the rotation direction of the stacking roller 23 is the opposite direction to the rotation direction of the stacking roller 22. The three-layer stack 30 and the four-layer stack 40 supplied from the stacking roller 23 to the stacking stage 25 are reversed with respect to the arrangement of the three-layer stack 30 and the four-layer stack 40 supplied from the stacking roller 22 to the stacking stage 24. Thus, for example, stacking starts with the three-layer stack on the stacking stage 24 and the four-layer stack is sequentially stacked on the three-layer stack, whereas the four-layer stack is sequentially stacked on the stacking stage 25 and the three-layer stack is stacked on the four-layer stack. Therefore, in the series arrangement, the structures of the stacks stacked on the stacking stages 24 and 25 may be different.
[0285] In addition, if Fig.49 As shown, when the stacking roller 23 is set not to abut against the stacking roller 22 but to be separated from the stacking roller 22 by an intermediate roller 27, and the stacking roller 23 abuts against the intermediate roller 27, the stacking roller 22 and the stacking roller 23 rotate in the same direction relative to the diaphragm cutting roller 20, and thus are arranged in parallel.
[0286] <Variation 3>
[0287] In the present embodiment, the structure comprises a negative electrode cutting drum 10, a negative electrode heating drum 12, a positive electrode cutting drum 14, a positive electrode heating drum 16, a bonding drum 18, a diaphragm cutting drum 20, and a stacking drum 22. However, the negative electrode heating drum 12 may be omitted and the negative electrode cutting drum 10 and the bonding drum 18 may be arranged adjacent to each other, and the positive electrode heating drum 16 may be omitted and the positive electrode cutting drum 14 and the bonding drum 18 may be arranged adjacent to each other.
[0288] Fig.50 The structure in this case is shown. Figure 1 In contrast, there is no negative electrode heating drum 12 and positive electrode heating drum 16 , the negative electrode cutting drum 10 is adjacent to the bonding drum 18 , and the positive electrode cutting drum 14 is adjacent to the bonding drum 18 .
[0289] The negative electrode cutting drum 10 cuts the strip-shaped negative electrode single plate N to produce negative electrode plates NP, and after heating the negative electrode plates NP, supplies them to the bonding drum 18. It can be said that the negative electrode cutting drum 10 has both Figure 1 The function of the negative electrode heating roller 12 is as follows.
[0290] The positive electrode cutting drum 14 cuts the strip-shaped positive electrode single plate P to produce a positive electrode plate PP, and supplies the positive electrode plate PP to the bonding drum 18 after heating the positive electrode plate PP. Figure 1 The function of the positive electrode heating roller 16 is as follows.
[0291] exist Fig.50 In the embodiment, the negative electrode cutting drum 10 is adjacent to the bonding drum 18, but the negative electrode cutting drum 10 and the bonding drum 18 may be separated, and the heated negative electrode plate NP from the negative electrode cutting drum 10 may be conveyed to the bonding drum 18 by a conveying mechanism such as a belt conveyor. Similarly, the positive electrode cutting drum 14 and the bonding drum 18 may be separated, and the heated positive electrode plate PP from the positive electrode cutting drum 14 may be conveyed to the bonding drum 18 by a conveying mechanism such as a belt conveyor.
[0292] <Variation 4>
[0293] In the present embodiment, the strip-shaped separators S1 and S2 are cut by the separator cutting drum 20 . However, the separator cutting drum 20 may be omitted and the strip-shaped separators S1 and S2 may be cut by the bonding drum 18 .
[0294] Fig.51 The structure in this case is shown. Figure 1 In contrast, there is no separator cutting drum 20 , and the three-layer laminate 30 and the four-layer laminate 40 produced by cutting by the bonding drum 18 are supplied to the laminating drum 22 by a conveying mechanism.
[0295] The bonding drum 18 includes a bonding head having a circular blade, and cuts the strip-shaped separators S1 and S2 at a predetermined cutting position 28. The bonding head may have, for example, a circular blade and a cutting function.
[0296] <Variant 5>
[0297] In the present embodiment, a three-layer laminate and a four-layer laminate are made, but the present invention is not necessarily limited thereto, and a two-layer laminate or a laminate having more than four layers may also be made. Figure 1 The positive electrode cutting drum 14 and the positive electrode heating drum 16 are deleted or stopped, and the negative electrode plate NP is supplied to the separator S1 and bonded to the bonding drum 18, and they are supplied to the separator cutting drum 20 as a two-layer stack. The separator S2 may be supplied to the negative electrode plate NP and bonded to the bonding drum 18, and they are supplied to the separator cutting drum 20 as a two-layer stack. The separator S2 may be supplied to the negative electrode plate NP and bonded to the bonding drum 18, and the positive electrode plate PP may be supplied to the separator S2 and bonded to the bonding drum 18, and they are supplied to the separator cutting drum 20 as a three-layer stack. Alternatively, the bonding on the bonding drum 18 may be repeated to form a stack with four or more layers and supply it to the separator cutting drum 20.
[0298] <Variant 6>
[0299] The separator cutting drum 20 and the stacking drum 22 do not need to be arranged adjacent to the bonding drum 18. It is also possible to stack the strip-shaped separator, the positive electrode and the negative electrode to form a laminated body by a method and an apparatus other than the bonding drum 18, cut the strip-shaped separator, and stack them on the stacking drum 22. On the other hand, it is also possible to form a laminated body by stacking the strip-shaped separator, the positive electrode and the negative electrode on the bonding drum 18, and to form a laminated electrode body by a method and an apparatus other than the separator cutting drum 20 and the stacking drum 22.
Claims
1. A device for manufacturing a laminated electrode body, wherein: The manufacturing device comprises: a first laminating roller for laminating a laminated body on a first laminating stage, wherein the laminated body is formed by cutting the diaphragm single plate of the laminated body formed by laminating diaphragm single plates and electrodes into a predetermined width by a cutting member; and a second stacking roller different from the first stacking roller and used to stack the stacked body cut out by the cutting on a second stacking stage different from the first stacking stage; The stacked body is a four-layer stacked body in which a plurality of first electrode plates are separately arranged on a first diaphragm single plate, a second diaphragm single plate is arranged on the first electrode plate, and a plurality of second electrode plates are separately arranged on the second diaphragm single plate. The cutting member cuts the first diaphragm single plate and the second diaphragm single plate of the four-layer stack into a predetermined width.
2. The manufacturing apparatus of a laminated electrode body according to claim 1, wherein: The first stacking roller and the second stacking roller are arranged so as to rotate in the same direction with respect to a conveyance direction of the stacked body cut out by the cutting.
3. The manufacturing apparatus of a laminated electrode body according to claim 1, wherein: The first stacking roller and the second stacking roller are arranged so as to rotate in directions different from each other.
4. The manufacturing apparatus of a laminated electrode body according to claim 3, wherein: The stacked body cut out by the cutting is fed to the second stacking roller via the first stacking roller.
5. The manufacturing apparatus for a laminated electrode assembly according to any one of claims 1 to 3, wherein: The first stacking roller has a plurality of first stacking heads on its outer circumferential surface for holding the stacked body, and the plurality of first stacking heads rotate along the circumferential direction of the roller and stack the stacked body on the first stacking table. The second stacking roller has a plurality of second stacking heads on its outer circumferential surface for holding the stacked body, and the plurality of second stacking heads rotate along the circumferential direction of the roller and stack the stacked body on the second stacking table.
6. A device for manufacturing a laminated electrode body, wherein: The manufacturing device comprises: a first laminating roller for laminating a laminated body on a first laminating stage, wherein the laminated body is formed by cutting the diaphragm single plate of the laminated body formed by laminating diaphragm single plates and electrodes into a predetermined width by a cutting member; and a second stacking roller different from the first stacking roller and used to stack the stacked body cut out by the cutting on a second stacking stage different from the first stacking stage; The stacked body is a three-layer stacked body in which a plurality of first electrode plates are separately arranged on a first separator single plate, and a second separator single plate is arranged on the first electrode plate. The cutting member cuts the first diaphragm single plate and the second diaphragm single plate of the three-layer stack into a predetermined width.
7. The manufacturing apparatus of a laminated electrode body according to claim 6, wherein: The first stacking roller and the second stacking roller are arranged so as to rotate in the same direction with respect to a conveyance direction of the stacked body cut out by the cutting.
8. The manufacturing apparatus of a laminated electrode body according to claim 6, wherein: The first stacking roller and the second stacking roller are arranged so as to rotate in directions different from each other.
9. The manufacturing apparatus for a laminated electrode body according to claim 8, wherein: The stacked body cut out by the cutting is fed to the second stacking roller via the first stacking roller.
10. The manufacturing apparatus for a laminated electrode body according to any one of claims 6 to 8, wherein: The first stacking roller has a plurality of first stacking heads on its outer circumferential surface for holding the stacked body, and the plurality of first stacking heads rotate along the circumferential direction of the roller and stack the stacked body on the first stacking table. The second stacking roller has a plurality of second stacking heads on its outer circumferential surface for holding the stacked body, and the plurality of second stacking heads rotate along the circumferential direction of the roller and stack the stacked body on the second stacking table.
11. A method for manufacturing a laminated electrode body, wherein: The manufacturing method comprises the following steps: The stack is conveyed to the first stacking roller or the second stacking roller, wherein the stack is formed by cutting the diaphragm single plate of the stack formed by stacking the diaphragm single plate and the electrode plate into a predetermined width by a cutting member; stacking the cut stacked body on the first stacking stage using the first stacking roller; and The cut stack is stacked on a second stacking stage different from the first stacking stage by using the second stacking roller different from the first stacking roller, The stacked body is a four-layer stacked body in which a plurality of first electrode plates are separately arranged on a first diaphragm single plate, a second diaphragm single plate is arranged on the first electrode plate, and a plurality of second electrode plates are separately arranged on the second diaphragm single plate. The cutting member cuts the first diaphragm single plate and the second diaphragm single plate of the four-layer stack into a predetermined width.
12. The method for producing a laminated electrode body according to claim 11, wherein: The first stacking roller and the second stacking roller rotate in the same direction to perform stacking.
13. The method for producing a laminated electrode body according to claim 11, wherein: The first stacking roller and the second stacking roller rotate in directions different from each other to perform stacking.
14. A method for manufacturing a laminated electrode body, wherein: The manufacturing method comprises the following steps: The stack is conveyed to the first stacking roller or the second stacking roller, wherein the stack is formed by cutting the diaphragm single plate of the stack formed by stacking the diaphragm single plate and the electrode plate into a predetermined width by a cutting member; stacking the cut stacked body on the first stacking stage using the first stacking roller; and The cut stack is stacked on a second stacking stage different from the first stacking stage by using the second stacking roller different from the first stacking roller, The stacked body is a three-layer stacked body in which a plurality of first electrode plates are separately arranged on a first separator single plate, and a second separator single plate is arranged on the first electrode plate. The cutting member cuts the first diaphragm single plate and the second diaphragm single plate of the three-layer stack into a predetermined width.
15. The method for producing a laminated electrode body according to claim 14, wherein: The first stacking roller and the second stacking roller rotate in the same direction to perform stacking.
16. The method for manufacturing a laminated electrode body according to claim 14, wherein: The first stacking roller and the second stacking roller rotate in directions different from each other to perform stacking.
Citation Information
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