Process for the preparation of a ruthenium-based catalyst and use thereof
By using an Al2O3-supported Ru-based catalyst in the partial hydrogenation of benzene to cyclohexene, the pore structure and Ru particle size of the catalyst were controlled, thus solving the cost problem caused by high Ru content and achieving efficient cyclohexene production.
CN119680534BActive Publication Date: 2025-12-09HUBEI XINGFA CHEM GRP CO LTD
Patent Information
- Application Number
- CN202411771997.0
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-12-04
- Publication Date
- 2025-12-09
- Estimated Expiration
- 2044-12-04
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Figure SMS_1
Abstract
The application provides a preparation method of a novel ruthenium-based catalyst and application of the catalyst in a reaction of partial hydrogenation of benzene to cyclohexene. Thanks to a large amount of mesopores with a size of less than 50 nm in the alumina carrier, the catalyst involved in the application can obtain a catalytic performance of 50-80 (i.e. a conversion rate of 50% and a cyclohexene selectivity of 80%) under low ruthenium, which is much higher than 50-60 of a comparative sample. This can greatly reduce the production cost of catalysis and improve the production efficiency of cyclohexene, thereby providing a certain possibility for subsequent industrial application.
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Citation Information
Patent Citations
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