Wear-resistant modified rubber cable material for new energy automobile and preparation method of wear-resistant modified rubber cable material

Abstract

The invention relates to the field of cable materials, in particular to a wear-resistant modified rubber cable material for a new energy automobile and a preparation method of the wear-resistant modified rubber cable material, and aims to solve the problems that an existing cable material for the new energy automobile is insufficient in wear resistance and mechanical strength, so that a cable is easy to crack, and potential safety hazards are caused. And the use requirements of the new energy automobile in a complex environment are difficult to meet. According to the preparation method, wear-resistant modified rubber, styrene-butadiene rubber and low-density polyethylene are used as matrixes, the comprehensive performance of the cable material is remarkably improved by integrating the advantages of the three materials, and then modified potassium titanate whiskers are added, so that the wear resistance and mechanical strength performance of the cable material are effectively improved; the cable can meet the use requirements of a new energy automobile in a severe environment, shows excellent protection performance, effectively prolongs the service life of the cable, and provides a cable transmission system which is longer in service life, safer and more reliable for the new energy automobile.

Description

Technical Field

[0001] The present invention relates to the field of cable materials, and in particular to a wear-resistant modified rubber cable material for new energy vehicles and a preparation method thereof. Background Art

[0002] New energy vehicles have developed rapidly in recent years, and the quality of their cable materials is directly related to vehicle performance, safety and service life. Although existing rubber cable materials have good insulation and flexibility, these materials are insufficient in wear resistance and mechanical strength. As a result, during the operation of new energy vehicles, the cables will be affected by various mechanical stresses, friction and environmental factors, causing the cables to crack easily, which in turn leads to safety hazards and is difficult to meet the use requirements of new energy vehicles in complex environments. This restricts its application in new energy vehicles in high-demand fields. Therefore, it is of great significance to develop a wear-resistant modified rubber cable material for new energy vehicles and a preparation method thereof. Summary of the invention

[0003] In order to overcome the above-mentioned technical problems, the purpose of the present invention is to provide a wear-resistant modified rubber cable material for new energy vehicles and a preparation method thereof, which solves the problem that the existing new energy vehicle cable materials are insufficient in wear resistance and mechanical strength, resulting in the cable being prone to cracking, which in turn leads to safety hazards and is difficult to meet the use requirements of new energy vehicles in complex environments.

[0004] The purpose of the present invention can be achieved through the following technical solutions: A wear-resistant modified rubber cable material for new energy vehicles, comprising the following components in parts by weight: Wear-resistant modified rubber 45-55 parts, styrene-butadiene rubber 5-11 parts, low-density polyethylene 17-23 parts, modified potassium titanate whisker 5.2-13.8 parts, zinc stearate 1.5-4.5 parts, sulfur 1-3 parts, rubber accelerator DM 0.8-1.6 parts, antioxidant 1024 0.6-1.4 parts and flame retardant TPP 0.3-0.7 parts; Wherein, the wear-resistant modified rubber is prepared by the following steps: Step a1: octamethylcyclotetrasiloxane and tetramethylammonium hydroxide are added to a three-necked flask equipped with a stirrer, a thermometer and an air guide tube, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 25-30° C. and a stirring rate of 300-400 r / min for 20-30 min, and then the mixture is heated to 80-85° C. and stirred for reaction for 1-2 h, and then the mixture is heated to 120-125° C. and stirred for reaction for 4-5 h. After the reaction is completed, the reaction product is cooled to room temperature to obtain an alkali-gel catalyst; Step a2: add octamethylcyclotetrasiloxane and tetramethyltetravinylcyclotetrasiloxane to a three-necked flask equipped with an agitator, a thermometer and an air guide tube, introduce nitrogen protection, stir and react for 20-30 minutes at a temperature of 25-30°C and a stirring rate of 300-400r / min, then heat to 45-50°C and continue to stir and react for 1-2 hours, then add alkali rubber catalyst, octaphenylcyclotetrasiloxane and decamethyltetrasiloxane and continue to stir and react for 1-2 hours, then heat to 110-115°C and continue to stir and react for 1.5-2 hours, then heat to 120-125°C and continue to stir and react for 30-40 minutes, then heat to 160-165°C and continue to stir and react for 30-40 minutes, then heat to 180-185°C and continue to stir and react for 2-3 hours, and after the reaction, cool the reaction product to room temperature to obtain vinylphenyl silicone rubber; Step a3: Add vinylphenyl silicone rubber and chlorobenzene to a three-necked flask equipped with a stirrer, a thermometer and an air duct, introduce nitrogen protection, stir and react for 20-30 minutes at a temperature of 25-30° C. and a stirring rate of 300-400 r / min, then heat to 55-60° C. and continue to stir and react for 1-2 hours, then add m-chloroperbenzoic acid and continue to stir and react for 20-30 hours, after the reaction is completed, cool the reaction product to room temperature, then add it to anhydrous methanol, then stand it for precipitation, then vacuum filter, wash the filter cake with distilled water 2-3 times, then place it in a vacuum drying oven, and dry it at a temperature of 55-60° C. for 3-5 hours to obtain epoxyphenyl silicone rubber; Step a4: Add epoxyphenyl silicone rubber, perfluorohexylethyl alcohol, phosphotungstic acid and chlorobenzene to a three-necked flask equipped with an agitator, a thermometer and an air duct, introduce nitrogen protection, stir the reaction for 20-30 minutes at a temperature of 25-30°C and a stirring rate of 300-400r / min, then raise the temperature to 90-95°C and continue stirring the reaction for 10-15 hours. After the reaction is completed, cool the reaction product to room temperature, add it to anhydrous methanol, let it stand to precipitate, and then vacuum filter it. Wash the filter cake with saturated sodium bicarbonate solution and saturated brine 2-3 times in turn, then place it in a vacuum drying oven, and dry it at a temperature of 55-60°C for 5-7 hours to obtain a wear-resistant modified rubber.

[0005] As a further solution of the present invention: the usage ratio of the octamethylcyclotetrasiloxane and tetramethylammonium hydroxide in step a1 is 10g:0.2-0.3g.

[0006] As a further solution of the present invention: the usage ratio of the octamethylcyclotetrasiloxane, tetramethyltetravinylcyclotetrasiloxane, alkali-gel catalyst, octaphenylcyclotetrasiloxane and decamethyltetrasiloxane in step a2 is 7.5-10.5g: 1.5-3.5g: 0.3-0.5g: 2-5g: 0.5-0.9g.

[0007] As a further solution of the present invention: the usage ratio of the alkenylphenyl silicone rubber, chlorobenzene and m-chloroperbenzoic acid in step a3 is 3-7 g: 100-120 mL: 1-4 g.

[0008] As a further solution of the present invention: the usage ratio of the epoxy phenyl silicone rubber, perfluorohexylethyl alcohol, phosphotungstic acid and chlorobenzene in step a4 is 10g:1.5-5.5g:0.5-0.9g:120-150mL.

[0009] As a further solution of the present invention: the modified potassium titanate whiskers are prepared by the following steps: Add γ-glycidyloxypropyltrimethoxysilane and ethanol solution into a three-necked flask equipped with a stirrer and a thermometer, stir and react for 20-30 minutes at a temperature of 25-30°C and a stirring rate of 300-400r / min, then add potassium titanate whiskers and continue to stir and react for 20-30 minutes, then raise the temperature to 85-90°C and continue to stir and react for 4-5 hours, after the reaction is completed, cool the reaction product to room temperature, and then vacuum filter, wash the filter cake with anhydrous ethanol for 2-3 times, and then place it in a vacuum drying oven and dry it at a temperature of 60-65°C for 2-3 hours to obtain modified potassium titanate whiskers.

[0010] As a further solution of the present invention: the usage ratio of the γ-glycidyloxypropyltrimethoxysilane, the ethanol solution and the potassium titanate whisker is 0.5-2.5g:50-55mL:5g.

[0011] As a further solution of the present invention: the volume fraction of the ethanol solution is 80-85%; the potassium titanate whiskers are potassium hexatitanate whiskers with an average diameter of 0.4 μm and an average length of 23 μm.

[0012] As a further solution of the present invention: a method for preparing a wear-resistant modified rubber cable material for new energy vehicles, comprising the following steps: Step 1: Weigh 45-55 parts of wear-resistant modified rubber, 5-11 parts of styrene-butadiene rubber, 17-23 parts of low-density polyethylene, 5.2-13.8 parts of modified potassium titanate whiskers, 1.5-4.5 parts of zinc stearate, 1-3 parts of sulfur, 0.8-1.6 parts of rubber accelerator DM, 0.6-1.4 parts of antioxidant 1024 and 0.3-0.7 parts of flame retardant TPP according to weight parts, and set aside; Step 2: adding wear-resistant modified rubber, styrene-butadiene rubber, low-density polyethylene, modified potassium titanate whisker, zinc stearate, sulfur, rubber accelerator DM, antioxidant 1024 and flame retardant TPP into a high-speed mixer, stirring evenly, then adding into an open mill, mixing at a mixing temperature of 80-100° C. for 15-20 minutes to obtain a mixed rubber material; Step 3: Place the mixed rubber material in a flat vulcanizer, vulcanize it for 20-25 minutes at a vulcanization temperature of 150-160°C and a pressure of 20-25MPa, and then cool it to obtain a wear-resistant modified rubber cable material for new energy vehicles.

[0013] Beneficial effects of the present invention: The present invention discloses a wear-resistant modified rubber cable material for new energy vehicles and a preparation method thereof. The wear-resistant modified rubber, styrene-butadiene rubber, low-density polyethylene, modified potassium titanate whisker, zinc stearate, sulfur, rubber accelerator DM, antioxidant 1024 and flame retardant TPP are added into a high-speed mixer, stirred evenly, then added into an open mill for mixing to obtain a mixed rubber material, the mixed rubber material is placed in a flat vulcanizer for vulcanization, and then cooled to obtain the wear-resistant modified rubber cable material for new energy vehicles. The preparation method uses the wear-resistant modified rubber, styrene-butadiene rubber and low-density polyethylene as a matrix, and significantly improves the comprehensive performance of the cable material by integrating the advantages of the three materials. Then, the modified potassium titanate whisker is added thereto, thereby effectively improving the wear resistance and mechanical strength of the cable material, being able to meet the use requirements of new energy vehicles in harsh environments, showing excellent protection performance, and effectively improving the service life of the cable, and ensuring that the cable can safely and reliably transmit power during the operation of the vehicle, providing a longer-life, safer and more reliable cable transmission system for new energy vehicles.

[0014] In the process of preparing wear-resistant modified rubber cable materials for new energy vehicles, a wear-resistant modified rubber is first prepared. First, octamethylcyclotetrasiloxane, tetramethyltetravinylcyclotetrasiloxane, octaphenylcyclotetrasiloxane and decamethyltetrasiloxane are used as raw materials for polymerization to form alkenylphenyl silicone rubber containing a large number of alkenyl groups and phenyl groups. Then, meta-chloroperbenzoic acid is used as an epoxidation reagent to treat the alkenylphenyl silicone rubber, so that the alkenyl groups on its molecular structure are converted into epoxy groups, and epoxyphenyl silicone rubber containing a large number of epoxy groups and phenyl groups is obtained. Finally, epoxyphenyl silicone rubber and perfluorohexylethyl alcohol are reacted, and the epoxy groups on the epoxyphenyl silicone rubber react with the hydroxyl groups on the perfluorohexylethyl alcohol, and then a large number of CF bonds are introduced into the silicone rubber to obtain a wear-resistant modified rubber; the molecular structure of the wear-resistant modified rubber contains a large number of phenyl groups, so that the rigidity and intramolecular friction of the molecular chain are enhanced, and the large number of CF bonds introduced make the molecular chain show good lubricity, so that it has a low friction coefficient, greatly improves its wear resistance, and the polarity of the molecular chain is improved after the alkenyl groups are converted into epoxy groups. , thereby enhancing the intermolecular force and improving the air tightness and adhesion of the rubber, thereby improving the mechanical properties of the rubber, and enhancing the interaction force between the rubber and other raw materials, and enhancing the reinforcement effect; in the process of preparing the wear-resistant modified rubber cable material for new energy vehicles, a modified potassium titanate whisker is also prepared, and the potassium titanate whisker is treated with γ-glycidyloxypropyltrimethoxysilane, and the siloxane on its molecular structure is hydrolyzed by γ-glycidyloxypropyltrimethoxysilane to form silanol, which is then grafted to the surface of the potassium titanate whisker to obtain the modified potassium titanate whisker; potassium titanate whisker has good high temperature resistance, heat resistance, high strength and high modulus. Adding it to the rubber material can enhance and modify it, greatly improve its mechanical properties and wear resistance, and after modification, a large amount of organic matter is introduced to its surface for wrapping, thereby greatly improving the dispersibility of the potassium titanate whisker, so that it can be evenly compatible with the rubber material, and a large number of epoxy groups will be introduced, so that it can be chemically bonded with the rubber material, thereby further improving the comprehensive performance of the rubber material. Therefore, under the synergistic effect of wear-resistant modified rubber and modified potassium titanate whiskers, the cable material is endowed with excellent mechanical strength and wear resistance, thereby improving the reliability and safety of the cable material. DETAILED DESCRIPTION

[0015] In order to enable those skilled in the art to better understand the scheme of the present invention, the technical scheme in the embodiments of the present invention will be clearly and completely described below in combination with the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

[0016] Embodiment 1: This embodiment is a method for preparing a wear-resistant modified rubber cable material for new energy vehicles, comprising the following steps: Step S1: 10 g of octamethylcyclotetrasiloxane and 0.2 g of tetramethylammonium hydroxide are added to a three-necked flask equipped with a stirrer, a thermometer and an air guide tube, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 25° C. and a stirring rate of 300 r / min for 20 min, and then the mixture is heated to 80° C. and stirred for reaction for 1 h, and then the mixture is heated to 120° C. and stirred for reaction for 4 h. After the reaction, the reaction product is cooled to room temperature to obtain an alkali-gel catalyst; Step S2: Add 7.5g of octamethylcyclotetrasiloxane and 1.5g of tetramethyltetravinylcyclotetrasiloxane to a three-necked flask equipped with an agitator, a thermometer and an air duct, introduce nitrogen protection, stir and react for 20min at a temperature of 25°C and a stirring rate of 300r / min, then heat to 45°C and continue to stir and react for 1h, then add 0.3g of alkali rubber catalyst, 2g of octaphenylcyclotetrasiloxane and 0.5g of decamethyltetrasiloxane and continue to stir and react for 1h, then heat to 110°C and continue to stir and react for 1.5h, then heat to 120°C and continue to stir and react for 30min, then heat to 160°C and continue to stir and react for 30min, then heat to 180°C and continue to stir and react for 2h, after the reaction is completed, cool the reaction product to room temperature to obtain vinylphenyl silicone rubber; Step S3: 3 g of vinylphenyl silicone rubber and 100 mL of chlorobenzene are added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred and reacted for 20 min at a temperature of 25° C. and a stirring rate of 300 r / min, and then the mixture is heated to 55° C. and the stirring reaction is continued for 1 h. Then, 1 g of m-chloroperbenzoic acid is added and the stirring reaction is continued for 20 h. After the reaction is completed, the reaction product is cooled to room temperature, and then added to anhydrous methanol, and then allowed to stand to precipitate, and then vacuum filtered. The filter cake is washed twice with distilled water, and then placed in a vacuum drying oven and dried at a temperature of 55° C. for 3 h to obtain epoxyphenyl silicone rubber; Step S4: 10 g of epoxy phenyl silicone rubber, 1.5 g of perfluorohexylethyl alcohol, 0.5 g of phosphotungstic acid and 120 mL of chlorobenzene are added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 25° C. and a stirring rate of 300 r / min for 20 min, and then the mixture is heated to 90° C. and the stirring reaction is continued for 10 h. After the reaction is completed, the reaction product is cooled to room temperature, and then added to anhydrous methanol, and then allowed to stand for precipitation, and then vacuum filtered. The filter cake is washed twice with a saturated sodium bicarbonate solution and a saturated saline solution in sequence, and then placed in a vacuum drying oven and dried at a temperature of 55° C. for 5 h to obtain a wear-resistant modified rubber; Step S5: 0.5 g of γ-glycidyloxypropyltrimethoxysilane and 50 mL of an ethanol solution with a volume fraction of 80% are added to a three-necked flask equipped with a stirrer and a thermometer, and stirred for reaction at a temperature of 25° C. and a stirring rate of 300 r / min for 20 min, then 5 g of potassium hexatitanate whiskers with an average diameter of 0.4 μm and an average length of 23 μm are added and stirred for reaction for 20 min, then the temperature is raised to 85° C. and the stirring reaction is continued for 4 h. After the reaction is completed, the reaction product is cooled to room temperature, and then vacuum filtered, the filter cake is washed twice with anhydrous ethanol, and then placed in a vacuum drying oven and dried at a temperature of 60° C. for 2 h to obtain modified potassium titanate whiskers; Step S6: weigh 45 parts of wear-resistant modified rubber, 5 parts of styrene-butadiene rubber, 17 parts of low-density polyethylene, 5.2 parts of modified potassium titanate whiskers, 1.5 parts of zinc stearate, 1 part of sulfur, 0.8 parts of rubber accelerator DM, 0.6 parts of antioxidant 1024 and 0.3 parts of flame retardant TPP according to weight parts, and set aside; Step S7: adding the wear-resistant modified rubber, styrene-butadiene rubber, low-density polyethylene, modified potassium titanate whisker, zinc stearate, sulfur, rubber accelerator DM, antioxidant 1024 and flame retardant TPP into a high-speed mixer, stirring evenly, then adding into an open mill, mixing at a mixing temperature of 80° C. for 15 minutes, to obtain a mixed rubber material; Step S8: placing the mixed rubber material in a flat vulcanizer, vulcanizing it for 20 minutes at a vulcanizing temperature of 150° C. and a pressure of 20 MPa, and then cooling it to obtain a wear-resistant modified rubber cable material for new energy vehicles.

[0017] Embodiment 2: This embodiment is a method for preparing a wear-resistant modified rubber cable material for new energy vehicles, comprising the following steps: Step S1: 10 g of octamethylcyclotetrasiloxane and 0.25 g of tetramethylammonium hydroxide were added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen was introduced for protection. The mixture was stirred for reaction at a temperature of 28° C. and a stirring rate of 350 r / min for 25 min, and then the mixture was heated to 82° C. and stirred for reaction for 1.5 h, and then the mixture was heated to 122° C. and stirred for reaction for 4.5 h. After the reaction, the reaction product was cooled to room temperature to obtain an alkali-gel catalyst; Step S2: 9 g of octamethylcyclotetrasiloxane and 2.5 g of tetramethyltetravinylcyclotetrasiloxane are added to a three-necked flask equipped with an agitator, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 28° C. and a stirring rate of 350 r / min for 25 min, and then the mixture is heated to 48° C. and the stirring reaction is continued for 1.5 h. Then, 0.4 g of alkali rubber catalyst, 3.5 g of octaphenylcyclotetrasiloxane and 0.7 g of decamethyltetrasiloxane are added and the stirring reaction is continued for 1.5 h. Then, the mixture is heated to 112° C. and the stirring reaction is continued for 1.5 h. Then, the mixture is heated to 122° C. and the stirring reaction is continued for 35 min. Then, the mixture is heated to 162° C. and the stirring reaction is continued for 35 min. Then, the mixture is heated to 182° C. and the stirring reaction is continued for 2.5 h. After the reaction is completed, the reaction product is cooled to room temperature to obtain vinylphenyl silicone rubber. Step S3: 5 g of vinylphenyl silicone rubber and 110 mL of chlorobenzene are added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 28° C. and a stirring rate of 350 r / min for 25 min, and then the mixture is heated to 58° C. and the stirring reaction is continued for 1.5 h. Then, 2.5 g of m-chloroperbenzoic acid is added and the stirring reaction is continued for 25 h. After the reaction is completed, the reaction product is cooled to room temperature, and then added to anhydrous methanol, and then allowed to stand for precipitation, and then vacuum filtered. The filter cake is washed twice with distilled water, and then placed in a vacuum drying oven and dried at a temperature of 58° C. for 4 h to obtain epoxyphenyl silicone rubber; Step S4: 10 g of epoxy phenyl silicone rubber, 3.5 g of perfluorohexylethyl alcohol, 0.7 g of phosphotungstic acid and 135 mL of chlorobenzene were added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen was introduced for protection. The mixture was stirred for reaction at a temperature of 28° C. and a stirring rate of 350 r / min for 25 min, and then the mixture was heated to 92° C. and the stirring reaction was continued for 12 h. After the reaction, the reaction product was cooled to room temperature, and then added to anhydrous methanol, and then allowed to stand for precipitation, and then vacuum filtered. The filter cake was washed twice with a saturated sodium bicarbonate solution and a saturated saline solution in sequence, and then placed in a vacuum drying oven and dried at a temperature of 58° C. for 6 h to obtain a wear-resistant modified rubber; Step S5: 1.5 g of γ-glycidyloxypropyltrimethoxysilane and 52 mL of an ethanol solution with a volume fraction of 82% are added to a three-necked flask equipped with a stirrer and a thermometer, and stirred for reaction at a temperature of 28° C. and a stirring rate of 350 r / min for 25 min, then 5 g of potassium hexatitanate whiskers with an average diameter of 0.4 μm and an average length of 23 μm are added and stirred for reaction for 25 min, then the temperature is raised to 88° C. and the stirring reaction is continued for 4.5 h. After the reaction is completed, the reaction product is cooled to room temperature, and then vacuum filtered, the filter cake is washed twice with anhydrous ethanol, and then placed in a vacuum drying oven and dried at a temperature of 62° C. for 2.5 h to obtain modified potassium titanate whiskers; Step S6: weigh 50 parts of wear-resistant modified rubber, 8 parts of styrene-butadiene rubber, 20 parts of low-density polyethylene, 9.5 parts of modified potassium titanate whiskers, 3 parts of zinc stearate, 2 parts of sulfur, 1.2 parts of rubber accelerator DM, 1 part of antioxidant 1024 and 0.5 parts of flame retardant TPP according to weight parts, and set aside; Step S7: adding the wear-resistant modified rubber, styrene-butadiene rubber, low-density polyethylene, modified potassium titanate whisker, zinc stearate, sulfur, rubber accelerator DM, antioxidant 1024 and flame retardant TPP into a high-speed mixer, stirring evenly, then adding into an open mill, mixing at a mixing temperature of 90° C. for 18 minutes, to obtain a mixed rubber material; Step S8: placing the mixed rubber material in a flat vulcanizer, vulcanizing it for 22 minutes at a vulcanizing temperature of 155° C. and a pressure of 22 MPa, and then cooling it to obtain a wear-resistant modified rubber cable material for new energy vehicles.

[0018] Embodiment 3: This embodiment is a method for preparing a wear-resistant modified rubber cable material for new energy vehicles, comprising the following steps: Step S1: 10 g of octamethylcyclotetrasiloxane and 0.3 g of tetramethylammonium hydroxide are added to a three-necked flask equipped with a stirrer, a thermometer and an air guide tube, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 85° C. and stirred for reaction for 2 h, and then the mixture is heated to 125° C. and stirred for reaction for 5 h. After the reaction, the reaction product is cooled to room temperature to obtain an alkali-gel catalyst; Step S2: 10.5 g of octamethylcyclotetrasiloxane and 3.5 g of tetramethyltetravinylcyclotetrasiloxane are added to a three-necked flask equipped with an agitator, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 50° C. and the stirring reaction is continued for 2 h. Then, 0.5 g of alkali rubber catalyst, 5 g of octaphenylcyclotetrasiloxane and 0.9 g of decamethyltetrasiloxane are added and the stirring reaction is continued for 2 h. Then, the mixture is heated to 115° C. and the stirring reaction is continued for 2 h. Then, the mixture is heated to 125° C. and the stirring reaction is continued for 40 min. Then, the mixture is heated to 165° C. and the stirring reaction is continued for 40 min. Then, the mixture is heated to 185° C. and the stirring reaction is continued for 3 h. After the reaction is completed, the reaction product is cooled to room temperature to obtain vinylphenyl silicone rubber. Step S3: 7 g of vinylphenyl silicone rubber and 120 mL of chlorobenzene are added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 60° C. and stirred for reaction for 2 h. Then 4 g of m-chloroperbenzoic acid is added and stirred for reaction for 30 h. After the reaction, the reaction product is cooled to room temperature, and then added to anhydrous methanol, and then allowed to stand for precipitation, and then vacuum filtered. The filter cake is washed with distilled water 3 times, and then placed in a vacuum drying oven and dried at a temperature of 60° C. for 5 h to obtain epoxyphenyl silicone rubber; Step S4: 10 g of epoxy phenyl silicone rubber, 5.5 g of perfluorohexylethyl alcohol, 0.9 g of phosphotungstic acid and 150 mL of chlorobenzene were added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen was introduced for protection. The mixture was stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture was heated to 95° C. and the stirring reaction was continued for 15 h. After the reaction, the reaction product was cooled to room temperature, and then added to anhydrous methanol, and then allowed to stand for precipitation, and then vacuum filtered. The filter cake was washed three times with a saturated sodium bicarbonate solution and a saturated saline solution, and then placed in a vacuum drying oven and dried at a temperature of 60° C. for 7 h to obtain a wear-resistant modified rubber; Step S5: 2.5 g of γ-glycidyloxypropyltrimethoxysilane and 55 mL of an ethanol solution with a volume fraction of 85% are added to a three-necked flask equipped with a stirrer and a thermometer, and stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, then 5 g of potassium hexatitanate whiskers with an average diameter of 0.4 μm and an average length of 23 μm are added and stirred for reaction for 30 min, then the temperature is raised to 90° C. and the stirring reaction is continued for 5 h. After the reaction is completed, the reaction product is cooled to room temperature, and then vacuum filtered. The filter cake is washed with anhydrous ethanol for 3 times, and then placed in a vacuum drying oven and dried at a temperature of 65° C. for 3 h to obtain modified potassium titanate whiskers; Step S6: weigh 55 parts of wear-resistant modified rubber, 11 parts of styrene-butadiene rubber, 23 parts of low-density polyethylene, 13.8 parts of modified potassium titanate whiskers, 4.5 parts of zinc stearate, 3 parts of sulfur, 1.6 parts of rubber accelerator DM, 1.4 parts of antioxidant 1024 and 0.7 parts of flame retardant TPP according to weight parts, and set aside; Step S7: adding the wear-resistant modified rubber, styrene-butadiene rubber, low-density polyethylene, modified potassium titanate whisker, zinc stearate, sulfur, rubber accelerator DM, antioxidant 1024 and flame retardant TPP into a high-speed mixer, stirring evenly, then adding into an open mill, mixing at a mixing temperature of 100° C. for 20 minutes, to obtain a mixed rubber material; Step S8: placing the mixed rubber material in a flat vulcanizer, vulcanizing it for 25 minutes at a vulcanizing temperature of 160° C. and a pressure of 25 MPa, and then cooling it to obtain a wear-resistant modified rubber cable material for new energy vehicles.

[0019] Comparative Example 1: This comparative example is a method for preparing a wear-resistant modified rubber cable material for new energy vehicles, comprising the following steps: Step S1: 10 g of octamethylcyclotetrasiloxane and 0.3 g of tetramethylammonium hydroxide are added to a three-necked flask equipped with a stirrer, a thermometer and an air guide tube, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 85° C. and stirred for reaction for 2 h, and then the mixture is heated to 125° C. and stirred for reaction for 5 h. After the reaction, the reaction product is cooled to room temperature to obtain an alkali-gel catalyst; Step S2: 10.5 g of octamethylcyclotetrasiloxane and 3.5 g of tetramethyltetravinylcyclotetrasiloxane are added to a three-necked flask equipped with an agitator, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 50° C. and the stirring reaction is continued for 2 h. Then, 0.5 g of alkali rubber catalyst, 5 g of octaphenylcyclotetrasiloxane and 0.9 g of decamethyltetrasiloxane are added and the stirring reaction is continued for 2 h. Then, the mixture is heated to 115° C. and the stirring reaction is continued for 2 h. Then, the mixture is heated to 125° C. and the stirring reaction is continued for 40 min. Then, the mixture is heated to 165° C. and the stirring reaction is continued for 40 min. Then, the mixture is heated to 185° C. and the stirring reaction is continued for 3 h. After the reaction is completed, the reaction product is cooled to room temperature to obtain vinylphenyl silicone rubber. Step S3: weigh 55 parts of alkenyl phenyl silicone rubber, 11 parts of styrene butadiene rubber, 23 parts of low-density polyethylene, 4.5 parts of zinc stearate, 3 parts of sulfur, 1.6 parts of rubber accelerator DM, 1.4 parts of antioxidant 1024 and 0.7 parts of flame retardant TPP according to weight parts, and set aside; Step S4: adding alkenyl phenyl silicone rubber, styrene-butadiene rubber, low-density polyethylene, zinc stearate, sulfur, rubber accelerator DM, antioxidant 1024 and flame retardant TPP into a high-speed mixer, stirring evenly, then adding into an open mill, mixing at a mixing temperature of 100° C. for 20 minutes, to obtain a mixed rubber material; Step S5: placing the mixed rubber material in a flat vulcanizer, vulcanizing it for 25 minutes at a vulcanizing temperature of 160° C. and a pressure of 25 MPa, and then cooling it to obtain a wear-resistant modified rubber cable material for new energy vehicles.

[0020] Comparative Example 2: This comparative example is a method for preparing a wear-resistant modified rubber cable material for new energy vehicles, comprising the following steps: Step S1: 10 g of octamethylcyclotetrasiloxane and 0.3 g of tetramethylammonium hydroxide are added to a three-necked flask equipped with a stirrer, a thermometer and an air guide tube, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 85° C. and stirred for reaction for 2 h, and then the mixture is heated to 125° C. and stirred for reaction for 5 h. After the reaction, the reaction product is cooled to room temperature to obtain an alkali-gel catalyst; Step S2: 10.5 g of octamethylcyclotetrasiloxane and 3.5 g of tetramethyltetravinylcyclotetrasiloxane are added to a three-necked flask equipped with an agitator, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 50° C. and the stirring reaction is continued for 2 h. Then, 0.5 g of alkali rubber catalyst, 5 g of octaphenylcyclotetrasiloxane and 0.9 g of decamethyltetrasiloxane are added and the stirring reaction is continued for 2 h. Then, the mixture is heated to 115° C. and the stirring reaction is continued for 2 h. Then, the mixture is heated to 125° C. and the stirring reaction is continued for 40 min. Then, the mixture is heated to 165° C. and the stirring reaction is continued for 40 min. Then, the mixture is heated to 185° C. and the stirring reaction is continued for 3 h. After the reaction is completed, the reaction product is cooled to room temperature to obtain vinylphenyl silicone rubber. Step S3: 7 g of vinylphenyl silicone rubber and 120 mL of chlorobenzene are added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 60° C. and stirred for reaction for 2 h. Then 4 g of m-chloroperbenzoic acid is added and stirred for reaction for 30 h. After the reaction, the reaction product is cooled to room temperature, and then added to anhydrous methanol, and then allowed to stand for precipitation, and then vacuum filtered. The filter cake is washed with distilled water 3 times, and then placed in a vacuum drying oven and dried at a temperature of 60° C. for 5 h to obtain epoxyphenyl silicone rubber; Step S4: 55 parts of epoxy phenyl silicone rubber, 11 parts of styrene-butadiene rubber, 23 parts of low-density polyethylene, 4.5 parts of zinc stearate, 3 parts of sulfur, 1.6 parts of rubber accelerator DM, 1.4 parts of antioxidant 1024 and 0.7 parts of flame retardant TPP were weighed according to weight parts and set aside; Step S5: adding epoxy phenyl silicone rubber, styrene-butadiene rubber, low-density polyethylene, zinc stearate, sulfur, rubber accelerator DM, antioxidant 1024 and flame retardant TPP into a high-speed mixer, stirring evenly, then adding into an open mill, mixing at a mixing temperature of 100° C. for 20 minutes, to obtain a mixed rubber material; Step S6: placing the mixed rubber material in a flat vulcanizer, vulcanizing it for 25 minutes at a vulcanizing temperature of 160° C. and a pressure of 25 MPa, and then cooling it to obtain a wear-resistant modified rubber cable material for new energy vehicles.

[0021] Comparative Example 3: This comparative example is a method for preparing a wear-resistant modified rubber cable material for new energy vehicles, comprising the following steps: Step S1: 10 g of octamethylcyclotetrasiloxane and 0.3 g of tetramethylammonium hydroxide are added to a three-necked flask equipped with a stirrer, a thermometer and an air guide tube, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 85° C. and stirred for reaction for 2 h, and then the mixture is heated to 125° C. and stirred for reaction for 5 h. After the reaction, the reaction product is cooled to room temperature to obtain an alkali-gel catalyst; Step S2: 10.5 g of octamethylcyclotetrasiloxane and 3.5 g of tetramethyltetravinylcyclotetrasiloxane are added to a three-necked flask equipped with an agitator, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 50° C. and the stirring reaction is continued for 2 h. Then, 0.5 g of alkali rubber catalyst, 5 g of octaphenylcyclotetrasiloxane and 0.9 g of decamethyltetrasiloxane are added and the stirring reaction is continued for 2 h. Then, the mixture is heated to 115° C. and the stirring reaction is continued for 2 h. Then, the mixture is heated to 125° C. and the stirring reaction is continued for 40 min. Then, the mixture is heated to 165° C. and the stirring reaction is continued for 40 min. Then, the mixture is heated to 185° C. and the stirring reaction is continued for 3 h. After the reaction is completed, the reaction product is cooled to room temperature to obtain vinylphenyl silicone rubber. Step S3: 7 g of vinylphenyl silicone rubber and 120 mL of chlorobenzene are added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 60° C. and stirred for reaction for 2 h. Then 4 g of m-chloroperbenzoic acid is added and stirred for reaction for 30 h. After the reaction, the reaction product is cooled to room temperature, and then added to anhydrous methanol, and then allowed to stand for precipitation, and then vacuum filtered. The filter cake is washed with distilled water 3 times, and then placed in a vacuum drying oven and dried at a temperature of 60° C. for 5 h to obtain epoxyphenyl silicone rubber; Step S4: 10 g of epoxy phenyl silicone rubber, 5.5 g of perfluorohexylethyl alcohol, 0.9 g of phosphotungstic acid and 150 mL of chlorobenzene were added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen was introduced for protection. The mixture was stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture was heated to 95° C. and the stirring reaction was continued for 15 h. After the reaction, the reaction product was cooled to room temperature, and then added to anhydrous methanol, and then allowed to stand for precipitation, and then vacuum filtered. The filter cake was washed three times with a saturated sodium bicarbonate solution and a saturated saline solution, and then placed in a vacuum drying oven and dried at a temperature of 60° C. for 7 h to obtain a wear-resistant modified rubber; Step S5: weigh 55 parts of wear-resistant modified rubber, 11 parts of styrene-butadiene rubber, 23 parts of low-density polyethylene, 4.5 parts of zinc stearate, 3 parts of sulfur, 1.6 parts of rubber accelerator DM, 1.4 parts of antioxidant 1024 and 0.7 parts of flame retardant TPP according to weight parts, and set aside; Step S6: adding the wear-resistant modified rubber, styrene-butadiene rubber, low-density polyethylene, zinc stearate, sulfur, rubber accelerator DM, antioxidant 1024 and flame retardant TPP into a high-speed mixer, stirring evenly, and then adding them into an open mill, mixing at a mixing temperature of 100° C. for 20 minutes to obtain a mixed rubber material; Step S7: placing the mixed rubber material in a flat vulcanizer, vulcanizing it for 25 minutes at a vulcanizing temperature of 160° C. and a pressure of 25 MPa, and then cooling it to obtain a wear-resistant modified rubber cable material for new energy vehicles.

[0022] Comparative Example 4: This comparative example is a method for preparing a wear-resistant modified rubber cable material for new energy vehicles, comprising the following steps: Step S1: 10 g of octamethylcyclotetrasiloxane and 0.3 g of tetramethylammonium hydroxide are added to a three-necked flask equipped with a stirrer, a thermometer and an air guide tube, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 85° C. and stirred for reaction for 2 h, and then the mixture is heated to 125° C. and stirred for reaction for 5 h. After the reaction, the reaction product is cooled to room temperature to obtain an alkali-gel catalyst; Step S2: 10.5 g of octamethylcyclotetrasiloxane and 3.5 g of tetramethyltetravinylcyclotetrasiloxane are added to a three-necked flask equipped with an agitator, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 50° C. and the stirring reaction is continued for 2 h. Then, 0.5 g of alkali rubber catalyst, 5 g of octaphenylcyclotetrasiloxane and 0.9 g of decamethyltetrasiloxane are added and the stirring reaction is continued for 2 h. Then, the mixture is heated to 115° C. and the stirring reaction is continued for 2 h. Then, the mixture is heated to 125° C. and the stirring reaction is continued for 40 min. Then, the mixture is heated to 165° C. and the stirring reaction is continued for 40 min. Then, the mixture is heated to 185° C. and the stirring reaction is continued for 3 h. After the reaction is completed, the reaction product is cooled to room temperature to obtain vinylphenyl silicone rubber. Step S3: 7 g of vinylphenyl silicone rubber and 120 mL of chlorobenzene are added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen is introduced for protection. The mixture is stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture is heated to 60° C. and stirred for reaction for 2 h. Then 4 g of m-chloroperbenzoic acid is added and stirred for reaction for 30 h. After the reaction, the reaction product is cooled to room temperature, and then added to anhydrous methanol, and then allowed to stand for precipitation, and then vacuum filtered. The filter cake is washed with distilled water 3 times, and then placed in a vacuum drying oven and dried at a temperature of 60° C. for 5 h to obtain epoxyphenyl silicone rubber; Step S4: 10 g of epoxy phenyl silicone rubber, 5.5 g of perfluorohexylethyl alcohol, 0.9 g of phosphotungstic acid and 150 mL of chlorobenzene were added to a three-necked flask equipped with a stirrer, a thermometer and an air duct, and nitrogen was introduced for protection. The mixture was stirred for reaction at a temperature of 30° C. and a stirring rate of 400 r / min for 30 min, and then the mixture was heated to 95° C. and the stirring reaction was continued for 15 h. After the reaction, the reaction product was cooled to room temperature, and then added to anhydrous methanol, and then allowed to stand for precipitation, and then vacuum filtered. The filter cake was washed three times with a saturated sodium bicarbonate solution and a saturated saline solution, and then placed in a vacuum drying oven and dried at a temperature of 60° C. for 7 h to obtain a wear-resistant modified rubber; Step S5: weigh 55 parts of wear-resistant modified rubber, 11 parts of styrene-butadiene rubber, 23 parts of low-density polyethylene, 13.8 parts of potassium hexatitanate whiskers with an average diameter of 0.4 μm and an average length of 23 μm, 4.5 parts of zinc stearate, 3 parts of sulfur, 1.6 parts of rubber accelerator DM, 1.4 parts of antioxidant 1024 and 0.7 parts of flame retardant TPP according to weight parts, and set aside; Step S6: adding the wear-resistant modified rubber, styrene-butadiene rubber, low-density polyethylene, potassium hexatitanate whisker, zinc stearate, sulfur, rubber accelerator DM, antioxidant 1024 and flame retardant TPP into a high-speed mixer, stirring evenly, then adding into an open mill, mixing at a mixing temperature of 100° C. for 20 minutes, to obtain a mixed rubber material; Step S7: placing the mixed rubber material in a flat vulcanizer, vulcanizing it for 25 minutes at a vulcanizing temperature of 160° C. and a pressure of 25 MPa, and then cooling it to obtain a wear-resistant modified rubber cable material for new energy vehicles.

[0023] The wear-resistant modified rubber cable materials for new energy vehicles of Examples 1-3 and Comparative Examples 1-4 were subjected to performance tests, and the test results are shown in the following table:

[0024] Referring to the data in the above table, based on the comparison between Examples 1-3 and Comparative Examples 1-4, it can be known that the wear-resistant modified rubber cable material for new energy vehicles of the present application has excellent mechanical properties and wear resistance.

[0025] In the description of this specification, the description with reference to the terms "one embodiment", "example", "specific example", etc. means that the specific features, structures, materials or characteristics described in conjunction with the embodiment or example are included in at least one embodiment or example of the present invention. In this specification, the schematic representation of the above terms does not necessarily refer to the same embodiment or example. Moreover, the specific features, structures, materials or characteristics described can be combined in any one or more embodiments or examples in a suitable manner.

[0026] The above contents are merely examples and explanations of the present invention. Those skilled in the art may make various modifications or additions to the specific embodiments described or replace them in a similar manner. As long as they do not deviate from the invention or exceed the scope defined in this application, they shall all fall within the protection scope of the present invention.

Claims

1. A wear-resistant modified rubber cable material for new energy vehicles, characterized in that: It comprises the following components in parts by weight: Wear-resistant modified rubber 45-55 parts, styrene-butadiene rubber 5-11 parts, low-density polyethylene 17-23 parts, modified potassium titanate whisker 5.2-13.8 parts, zinc stearate 1.5-4.5 parts, sulfur 1-3 parts, rubber accelerator DM 0.8-1.6 parts, antioxidant 1024 0.6-1.4 parts and flame retardant TPP 0.3-0.7 parts; Wherein, the wear-resistant modified rubber is prepared by the following steps: Step a1: stirring octamethylcyclotetrasiloxane and tetramethylammonium hydroxide to react, and cooling the reaction product after the reaction is completed to obtain an alkali-gel catalyst; Step a2: octamethylcyclotetrasiloxane and tetramethyltetravinylcyclotetrasiloxane are stirred for reaction, and then an alkali rubber catalyst, octaphenylcyclotetrasiloxane and decamethyltetrasiloxane are added and stirred for reaction. After the reaction is completed, the reaction product is cooled to obtain vinylphenyl silicone rubber; Step a3: stirring the alkenyl phenyl silicone rubber and chlorobenzene for reaction, then adding m-chloroperbenzoic acid and continuing stirring for reaction, cooling the reaction product after the reaction is completed, then adding it to anhydrous methanol and standing it for precipitation, then vacuum filtering, washing and drying the filter cake to obtain epoxy phenyl silicone rubber; Step a4: stirring epoxy phenyl silicone rubber, perfluorohexylethyl alcohol, phosphotungstic acid and chlorobenzene for reaction, cooling the reaction product after the reaction is completed, then adding it to anhydrous methanol and standing it for precipitation, then vacuum filtering, washing and drying the filter cake to obtain a wear-resistant modified rubber.

2. The wear-resistant modified rubber cable material for new energy vehicles according to claim 1, characterized in that: The usage ratio of the octamethylcyclotetrasiloxane and tetramethylammonium hydroxide in step a1 is 10g:0.2-0.3g.

3. The wear-resistant modified rubber cable material for new energy vehicles according to claim 1, characterized in that: The usage ratio of the octamethylcyclotetrasiloxane, tetramethyltetravinylcyclotetrasiloxane, alkali-gel catalyst, octaphenylcyclotetrasiloxane and decamethyltetrasiloxane in step a2 is 7.5-10.5g: 1.5-3.5g: 0.3-0.5g: 2-5g: 0.5-0.9g.

4. The wear-resistant modified rubber cable material for new energy vehicles according to claim 1, characterized in that: The usage ratio of the alkenylphenyl silicone rubber, chlorobenzene and m-chloroperbenzoic acid in step a3 is 3-7 g: 100-120 mL: 1-4 g.

5. The wear-resistant modified rubber cable material for new energy vehicles according to claim 1, characterized in that: The usage ratio of the epoxy phenyl silicone rubber, perfluorohexylethyl alcohol, phosphotungstic acid and chlorobenzene in step a4 is 10g:1.5-5.5g:0.5-0.9g:120-150mL.

6. The wear-resistant modified rubber cable material for new energy vehicles according to claim 1, characterized in that: The modified potassium titanate whiskers are prepared by the following steps: The γ-glycidyloxypropyltrimethoxysilane and ethanol solution are stirred for reaction, and then potassium titanate whiskers are added and the stirring reaction is continued. After the reaction is completed, the reaction product is cooled and then vacuum filtered, and the filter cake is washed and dried to obtain modified potassium titanate whiskers.

7. The wear-resistant modified rubber cable material for new energy vehicles according to claim 6, characterized in that: The usage ratio of the γ-glycidyloxypropyltrimethoxysilane, the ethanol solution and the potassium titanate whisker is 0.5-2.5 g: 50-55 mL: 5 g.

8. The wear-resistant modified rubber cable material for new energy vehicles according to claim 6, characterized in that: The volume fraction of the ethanol solution is 80-85%; the potassium titanate whiskers are potassium hexatitanate whiskers with an average diameter of 0.4 μm and an average length of 23 μm.

9. A method for preparing a wear-resistant modified rubber cable material for new energy vehicles, characterized in that: The following steps are involved: Step 1: Weigh 45-55 parts of wear-resistant modified rubber, 5-11 parts of styrene-butadiene rubber, 17-23 parts of low-density polyethylene, 5.2-13.8 parts of modified potassium titanate whiskers, 1.5-4.5 parts of zinc stearate, 1-3 parts of sulfur, 0.8-1.6 parts of rubber accelerator DM, 0.6-1.4 parts of antioxidant 1024 and 0.3-0.7 parts of flame retardant TPP according to weight parts, and set aside; Step 2: adding wear-resistant modified rubber, styrene-butadiene rubber, low-density polyethylene, modified potassium titanate whisker, zinc stearate, sulfur, rubber accelerator DM, antioxidant 1024 and flame retardant TPP into a high-speed mixer, stirring evenly, then adding into an open mill, mixing at a mixing temperature of 80-100° C. for 15-20 minutes to obtain a mixed rubber material; Step 3: Place the mixed rubber material in a flat vulcanizer, vulcanize it for 20-25 minutes at a vulcanization temperature of 150-160°C and a pressure of 20-25MPa, and then cool it to obtain a wear-resistant modified rubber cable material for new energy vehicles.

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