Low-temperature-resistant environment-friendly colored ribbon spray and preparation method thereof

Abstract

The invention relates to the technical field of colored ribbon spraying agents, in particular to a low-temperature-resistant environment-friendly colored ribbon spraying agent and a preparation method thereof. The invention relates to a low-temperature-resistant environment-friendly colored ribbon spray, which is prepared from 20 to 30 parts of deionized water, 0.2 to 0.4 part of preservative, 0 to 0.3 part of water-soluble pigment, 0.1 to 0.2 part of coconut oil diethanolamide, 0.1 to 0.2 part of perfluorooctyl quaternary ammonium iodide, 0.1 to 0.2 part of rhamnolipid, 0.1 to 0.2 part of sodium vinylsulfonate, 4 to 6 parts of ethanol, 15 to 25 parts of filling powder, 5 to 8 parts of acrylic resin, 5 to 7 parts of ethylene glycol monobutyl ether and 20 to 30 parts of propellant. The colored ribbon spraying agent successfully solves the problem that an existing colored ribbon spraying agent is instable in spraying under the low-temperature condition, and the excellent spraying effect is still kept in the cold environment.

Description

Technical Field

[0001] The invention relates to the technical field of ribbon sprays, in particular to a low-temperature-resistant environmentally friendly ribbon spray and a preparation method thereof. Background Art

[0002] As a convenient and fun decorative prop, ribbon spray plays an indispensable role in various celebration occasions in today's society. From weddings, birthday parties to festival celebrations, ribbon spray can be seen everywhere. Ribbon spray has become one of the key props to create a joyful atmosphere.

[0003] As people's environmental awareness continues to increase, water-based ribbon sprays have gradually replaced traditional oily ribbon sprays and become the mainstream of the market. In order to achieve a good spraying effect, most of the existing water-based ribbon sprays contain a certain proportion of resin compounds as film-forming agents. However, the solubility of resin compounds in water is originally low. In a low-temperature environment, especially when the temperature drops below freezing, the compatibility of resin compounds will be seriously affected. Specifically, as the temperature drops, the solubility between the resin compound and water decreases, and precipitation is prone to occur, and even leads to solution stratification or precipitation. This not only destroys the original uniform dispersion state, but also affects the consistency and continuity of the spray during the spraying process, thereby causing the spray to be unsmooth or even clogging the nozzle. This phenomenon greatly limits the scope of application of ribbon sprays. Once the ambient temperature drops to a lower level, especially when it is close to freezing point or lower, or when it needs to be stored in a cold environment for a long time, the existing ribbon sprays will be difficult to exert a stable spraying effect. Therefore, it is necessary to develop a water-based ribbon spray that can maintain stability in a low-temperature environment to solve the problem that the existing ribbon sprays are difficult to exert a stable spraying effect under low-temperature conditions. Summary of the invention

[0004] In order to solve the problem that existing ribbon sprays are difficult to exert a stable spraying effect under low temperature conditions, the present application provides a low-temperature resistant and environmentally friendly ribbon spray and a preparation method thereof. The ribbon spray of the present application successfully solves the problem that existing ribbon sprays are unstable in spraying under low temperature conditions, providing a broader space for the application of ribbon sprays, especially in celebrations in cold environments, the ribbon spray of the present application can still maintain excellent spraying effects and decorative performance, bringing users a more pleasant use experience.

[0005] In the first aspect, the present application provides a low temperature resistant environmentally friendly ribbon spray adopts the following technical solution: A low-temperature resistant environmentally friendly ribbon spray comprises the following raw materials in parts by mass: 20 to 30 parts of deionized water, 0.2 to 0.4 parts of preservatives, 0 to 0.3 parts of water-soluble pigments, 0.1 to 0.2 parts of coconut oil diethanolamide, 0.1 to 0.2 parts of perfluorooctyl quaternary ammonium iodide, 0.1 to 0.2 parts of rhamnolipid, 0.1 to 0.2 parts of sodium vinyl sulfonate, 4 to 6 parts of ethanol, 15 to 25 parts of filling powder, 5 to 8 parts of acrylic resin, 5 to 7 parts of ethylene glycol monobutyl ether and 20 to 30 parts of propellants.

[0006] In the above technical scheme, the present application ensures the environmental friendliness of the spray by using deionized water as a solvent; by adding a preservative, the corrosion of the ribbon spray liquid to the tank body is prevented, and the shelf life of the ribbon spray is effectively extended; by adding a water-soluble pigment, the ribbon spray is given a rich variety of colors, and the color uniformity of the ribbon is improved; by combining coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid and sodium vinyl sulfonate, the liquid dispersibility and low-temperature stability of the ribbon spray are improved, ensuring the uniformity and stability of the ribbon spray during the spraying process, especially under low temperature conditions. Continuity: The synergistic effect of coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid and sodium vinyl sulfonate improves the compatibility of acrylic resin with water, so that the ribbon spray can still smoothly spray out noodle-like ribbons with uniform color, consistent thickness and continuity under low temperature conditions, while ensuring that the ribbon spray can have a good spraying distance. Ethanol is added to the ribbon spray as a co-solvent to further improve the compatibility of raw materials such as resin with water. The synergistic effect of filling powder, acrylic resin and ethylene glycol monobutyl ether ensures that the ribbon spray can quickly form into noodle-like ribbons after spraying the liquid.

[0007] Preferably, the preservative is a combination of sodium benzoate and sodium nitrite, which comprises 0.1 to 0.2 parts of sodium benzoate and 0.1 to 0.2 parts of sodium nitrite in terms of mass fractions of the low-temperature resistant environmentally friendly ribbon spray.

[0008] In the above technical scheme, the present application selects a combination of sodium benzoate and sodium nitrite as preservatives. These two preservatives can not only effectively reduce the corrosiveness of the ribbon spray liquid to the tank body, but also can maintain a good anti-corrosion effect under low temperature conditions, and will not cause harm to the human body and the environment, and meet environmental protection requirements.

[0009] Preferably, the propellant is 1,1,1,2-tetrafluoroethane.

[0010] In the above technical scheme, 1,1,1,2-tetrafluoroethane is selected as the propellant. 1,1,1,2-tetrafluoroethane is an environmentally friendly propellant with good flame retardancy and will not damage the environment or cause harm to the human body. At the same time, in the present application, the combination of 1,1,1,2-tetrafluoroethane and water further improves the flame retardancy of the ribbon spray and further improves the safety of the ribbon spray.

[0011] Preferably, the filling powder is fluorphlogopite powder and talcum powder, which comprises 5 to 10 parts of fluorphlogopite powder and 10 to 15 parts of talcum powder in terms of mass proportion of the low-temperature resistant environmentally friendly ribbon spray.

[0012] In the above technical scheme, the present application selects fluorophlogopite powder and talcum powder as filling powders. The synergistic effect of fluorophlogopite powder and talcum powder improves the film-forming property and glossiness of the ribbon spray, making the shape of the sprayed ribbon fuller and more lustrous, further enhancing the decorative effect and aesthetics of the ribbon spray.

[0013] Preferably, the particle size of the fluorphlogopite powder is 5 μm to 20 μm, and the particle size of the talc powder is 10 μm to 30 μm.

[0014] In the above technical scheme, the present application further optimizes the spraying effect and molding performance of the ribbon spray by controlling the particle size range of the filling powder, so that the sprayed ribbons are more delicate, uniform and continuous, further improving the use experience and decorative effect of the ribbon spray.

[0015] Preferably, the mass ratio of the coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate is 0.15:0.15:0.15:0.15.

[0016] In the above technical scheme, by further optimizing the mass ratio of coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate, coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate can exert the best synergistic effect in the ribbon spray, further improving the spraying stability and continuity of the ribbon spray under low temperature conditions, while also ensuring that the ribbon after the ribbon spray is sprayed has better gloss and fineness, further improving the decorative effect and aesthetics of the ribbon spray.

[0017] In the second aspect, the present application provides a method for preparing a low-temperature resistant environmentally friendly ribbon spray using the following technical solution: A method for preparing a low-temperature resistant environmentally friendly ribbon spray comprises the following steps: Step 1: add deionized water into a stirring kettle, start stirring, add preservatives, water-soluble pigments, coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate into the stirring kettle under stirring, and stir until the mixture is uniform; Step 2: add ethanol, talcum powder, acrylic resin, and ethylene glycol monobutyl ether into the stirring kettle and stir evenly; Step 3: Fill the material obtained in step 2 into an aerosol can, and fill it with 1,1,1,2-tetrafluoroethane to obtain an aerosol.

[0018] In the above technical solution, by adopting specific preparation steps, the raw materials can be fully and evenly mixed, thereby ensuring the quality stability and spraying effect of the ribbon spray.

[0019] Preferably, in step 2, ethanol, talcum powder, acrylic resin and ethylene glycol monobutyl ether are pre-mixed and dissolved uniformly.

[0020] In the above technical scheme, the present application further improves the compatibility and dispersibility between these raw materials by pre-mixing and dissolving ethanol, talcum powder, acrylic resin, and ethylene glycol monobutyl ether evenly and then adding them into a stirring tank, thereby ensuring that the raw materials can be fully mixed during the preparation process, thereby improving the quality stability and spraying effect of the ribbon spray.

[0021] In summary, the present application includes at least one of the following beneficial technical effects: 1. The present application improves the liquid dispersibility and low-temperature stability of the ribbon spray through the synergistic effect of coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid and sodium vinyl sulfonate, so that the ribbon spray can still be smoothly sprayed under low temperature conditions to form noodle-like ribbons with uniform color, consistent thickness and continuity, while ensuring that the ribbon spray can have a good spray distance.

[0022] 2. This application further improves the film-forming property and glossiness of the ribbon spray by selecting fluorophlogopite powder and talcum powder as filling powders, making the shape of the sprayed ribbon fuller and more lustrous, further enhancing the decorative effect and aesthetics of the ribbon spray. DETAILED DESCRIPTION

[0023] In order to better illustrate the purpose, technical solutions and advantages of the present invention, the present invention will be further described below in conjunction with specific embodiments.

[0024] Example 1 A low-temperature resistant environmentally friendly ribbon spray comprises 28g of deionized water, 0.15g of sodium benzoate, 0.15g of sodium nitrite, 0.3g of water-soluble pigment, 0.15g of coconut oil diethanolamide, 0.15g of perfluorooctyl quaternary ammonium iodide, 0.15g of rhamnolipid, 0.15g of sodium vinyl sulfonate, 5g of ethanol, 8g of fluorophlogopite powder, 13g of talc, 7g of acrylic resin, 6g of ethylene glycol monobutyl ether and 25.8g of 1,1,1,2-tetrafluoroethane.

[0025] Among them, coconut oil diethanolamide was purchased from Shandong Suihua Biotechnology Co., Ltd. with the model number CDEA.

[0026] Among them, perfluorooctyl quaternary ammonium iodide was purchased from Tai'an Jiangzhou Biotechnology Co., Ltd.

[0027] Among them, rhamnolipid was purchased from Anhui Zhonghong Bioengineering Co., Ltd.

[0028] Among them, sodium vinyl sulfonate was purchased from Shandong Wanhua Environmental Protection New Materials Co., Ltd.

[0029] Among them, the fluorophlogopite powder was purchased from the Malin Mineral Products Processing Plant in Lingshou County, with a particle size of 5μm to 20μm.

[0030] Among them, talcum powder was purchased from Lingshou County Haibin Mineral Products Trading Co., Ltd. with a particle size of 10μm to 30μm.

[0031] Among them, acrylic resin was purchased from Shandong Huling New Materials Co., Ltd., model PT-2095.

[0032] Among them, ethylene glycol monobutyl ether was purchased from Shandong Xuxiang Chemical Co., Ltd.

[0033] The method for preparing the low temperature resistant environmentally friendly ribbon spray comprises the following steps: Step 1: Add deionized water into a stirring kettle, start stirring, and add preservatives, water-soluble pigments, coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate into the stirring kettle while stirring, and stir until the mixture is evenly mixed.

[0034] Step 2: pre-mix and dissolve ethanol, talcum powder, acrylic resin and ethylene glycol monobutyl ether evenly, then add them into a stirring tank, mix with the material obtained in step 1 and stir evenly.

[0035] Step 3: Fill the material obtained in step 2 into an aerosol can, and fill it with 1,1,1,2-tetrafluoroethane to obtain an aerosol.

[0036] Example 2 A low-temperature resistant environmentally friendly ribbon spray, which is different from Example 1 in that it includes 25g of deionized water, 0.2g of sodium benzoate, 0.1g of sodium nitrite, 0.3g of water-soluble pigment, 0.1g of coconut oil diethanolamide, 0.2g of perfluorooctyl quaternary ammonium iodide, 0.1g of rhamnolipid, 0.2g of sodium vinyl sulfonate, 6g of ethanol, 5g of fluorophlogopite powder, 15g of talc, 5g of acrylic resin, 7g of ethylene glycol monobutyl ether and 27.8g of 1,1,1,2-tetrafluoroethane.

[0037] The method for preparing the low temperature resistant environmentally friendly ribbon spray comprises the following steps: Step 1: Add deionized water into a stirring kettle, start stirring, and add preservatives, water-soluble pigments, coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate into the stirring kettle while stirring, and stir until the mixture is evenly mixed.

[0038] Step 2: pre-mix and dissolve ethanol, talcum powder, acrylic resin and ethylene glycol monobutyl ether evenly, then add them into a stirring tank, mix with the material obtained in step 1 and stir evenly.

[0039] Step 3: Fill the material obtained in step 2 into an aerosol can, and fill it with 1,1,1,2-tetrafluoroethane to obtain an aerosol.

[0040] Example 3 A low-temperature resistant environmentally friendly ribbon spray, which is different from Example 1 in that it includes 30g of deionized water, 0.1g of sodium benzoate, 0.2g of sodium nitrite, 0.3g of water-soluble pigment, 0.2g of coconut oil diethanolamide, 0.1g of perfluorooctyl quaternary ammonium iodide, 0.2g of rhamnolipid, 0.1g of sodium vinyl sulfonate, 4g of ethanol, 10g of fluorophlogopite powder, 10g of talc, 8g of acrylic resin, 5g of ethylene glycol monobutyl ether and 26.8g of 1,1,1,2-tetrafluoroethane.

[0041] The method for preparing the low temperature resistant environmentally friendly ribbon spray comprises the following steps: Step 1: Add deionized water into a stirring kettle, start stirring, and add preservatives, water-soluble pigments, coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate into the stirring kettle while stirring, and stir until the mixture is evenly mixed.

[0042] Step 2: pre-mix and dissolve ethanol, talcum powder, acrylic resin and ethylene glycol monobutyl ether evenly, then add them into a stirring tank, mix with the material obtained in step 1 and stir evenly.

[0043] Step 3: Fill the material obtained in step 2 into an aerosol can, and fill it with 1,1,1,2-tetrafluoroethane to obtain an aerosol.

[0044] Comparative Example 1 An environmentally friendly ribbon spray, which is different from Example 1 in that perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate are replaced by coconut oil diethanolamide in equal amounts.

[0045] Comparative Example 2 An environmentally friendly ribbon spray, which is different from Example 1 in that perfluorooctyl quaternary ammonium iodide is replaced by coconut oil diethanolamide in equal amounts.

[0046] Comparative Example 3 An environmentally friendly ribbon spray, which is different from Example 1 in that rhamnolipid is replaced by coconut oil diethanolamide in equal amounts.

[0047] Comparative Example 4 An environmentally friendly ribbon spray, which is different from Example 1 in that an equal amount of sodium vinyl sulfonate is replaced by coconut oil diethanolamide.

[0048] Performance Testing Detection 1 Test sample: the environmentally friendly ribbon spray of the above-mentioned embodiments and comparative examples.

[0049] Test method: at room temperature of 25℃, relative humidity of 65%, and no wind, leave the prepared environmentally friendly ribbon spray to stand for 8 hours at a vertical height of 1m from the ground, then spray the ribbon horizontally. After the ribbon falls naturally, the end away from the spraying point is taken as the measuring point. The horizontal spraying distance (m) of the ribbon is measured and recorded, and the state of the sprayed ribbon is observed and recorded. Ten parallel experiments are performed in each group.

[0050] Similarly, the room temperature was adjusted to 10°C and 5°C respectively, and the prepared environmentally friendly ribbon spray was left to stand at the test temperature for 8 hours, and then the above test was repeated, and the test results were recorded.

[0051] The above test results are shown in Table 1.

[0052] Table 1: Specifically combining the test results analysis of Examples 1 to 3, Comparative Examples 1 to 4 and Table 1, it can be seen that the ribbon sprays of Examples 1 to 3 all exhibit smooth spraying states, uniform color and consistent thickness of ribbon forms at 25°C, 10°C and 5°C, and the spraying distance is also far. It can be seen that the environmentally friendly ribbon spray of the present application still has good spraying performance and ribbon form under low temperature conditions, which also proves that the environmentally friendly ribbon spray of the present application has good solubility and dispersibility under low temperature conditions, and therefore can maintain good spraying performance and ribbon form.

[0053] Specifically combined with Example 1 and Comparative Examples 1 to 4, the difference between Comparative Examples 1 to 4 and Example 1 is that In 1 to 4, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate are replaced by coconut oil diethanolamide in equal or partial amounts. Combined with the test results in Table 1, Example 1 has good spraying performance and ribbon morphology under low temperature conditions. From the above comparison, it can be seen that the synergistic effect of perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate has a significant effect on improving the spraying performance and ribbon morphology of the ribbon spray under low temperature conditions.

[0054] Detection 2 Referring to the test of 4.2 flammability of sprayed mist in GB / T14449-1993 "Test Methods for Aerosol Products", the flammability of the ribbon spray was tested. The test results are shown in Table 2.

[0055] Table 2: Specifically combining the test results of Examples 1 to 3, Comparative Examples 1 to 4 and Table 2, it can be seen that the ribbon sprays of Examples 1 to 3 and Comparative Examples 1 to 4 can extinguish the candle fire source when the spray distance is 150 mm, which shows that the low-temperature resistant and environmentally friendly ribbon spray of the present application has good spray mist flammability and meets the requirements for safe use.

[0056] This specific embodiment is merely an explanation of the present application and is not a limitation of the present application. After reading this specification, those skilled in the art may make modifications to the present embodiment without any creative contribution as needed. However, as long as it is within the scope of the claims of the present application, it shall be protected by the patent law.

Claims

1. A low temperature resistant environmentally friendly ribbon spray, characterized in that: The invention comprises the following raw materials in parts by weight: 20-30 parts of deionized water, 0.2-0.4 parts of preservatives, 0-0.3 parts of water-soluble pigments, 0.1-0.2 parts of coconut oil diethanolamide, 0.1-0.2 parts of perfluorooctyl quaternary ammonium iodide, 0.1-0.2 parts of rhamnolipid, 0.1-0.2 parts of sodium vinyl sulfonate, 4-6 parts of ethanol, 15-25 parts of filling powder, 5-8 parts of acrylic resin, 5-7 parts of ethylene glycol monobutyl ether and 20-30 parts of propellants.

2. The low temperature resistant environmentally friendly ribbon spray according to claim 1, characterized in that: The preservative is a combination of sodium benzoate and sodium nitrite, and includes 0.1 to 0.2 parts of sodium benzoate and 0.1 to 0.2 parts of sodium nitrite in terms of mass fractions of the low-temperature resistant environmentally friendly ribbon spray.

3. The low temperature resistant environmentally friendly ribbon spray according to claim 1, characterized in that: The propellant is 1,1,1,2-tetrafluoroethane.

4. The low temperature resistant environmentally friendly ribbon spray according to claim 1, characterized in that: The filling powder is fluorphlogopite powder and talcum powder, and based on the mass proportion of the low-temperature resistant environmentally friendly ribbon spray, it comprises 5 to 10 parts of fluorphlogopite powder and 10 to 15 parts of talcum powder.

5. The low temperature resistant environmentally friendly ribbon spray according to claim 1, characterized in that: The particle size of the fluorphlogopite powder is 5 μm to 20 μm, and the particle size of the talc powder is 10 μm to 30 μm.

6. The low temperature resistant environmentally friendly ribbon spray according to claim 1, characterized in that: The mass ratio of the coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid and sodium vinyl sulfonate is 0.15:0.15:0.15:0.

15.

7. A method for preparing the low temperature resistant environmentally friendly ribbon spray according to any one of claims 1 to 6, characterized in that: The following steps are involved: Step 1: Add deionized water into a stirring kettle, start stirring, add preservatives, water-soluble pigments, coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate into the stirring kettle under stirring, and stir until the mixture is evenly mixed; Step 2: Add ethanol, talcum powder, acrylic resin and ethylene glycol monobutyl ether into a stirring kettle and stir evenly; Step 3: Fill the material obtained in step 2 into an aerosol can, and fill it with 1,1,1,2-tetrafluoroethane to obtain an aerosol.

8. The method for preparing a low temperature resistant environmentally friendly ribbon spray according to claim 7, characterized in that: In the step 2, ethanol, talcum powder, acrylic resin and ethylene glycol monobutyl ether are pre-mixed and dissolved uniformly.

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