Sulfonamide compound and noxious arthropod control composition containing same

Abstract

In formula (I) (in the formula, Q (# represents a bonding site with a sulfur atom and a bonding site with Het) represents a group represented by formula Q1 or the like, R2a and R2b are the same or different from each other and represent C1-C6 alkyl groups which may be substituted with one or more halogen atoms or the like, R3a, R3b and R3d are the same or different from each other and represent hydrogen atoms or the like, Het represents a group represented by formula Het1 or the like, A2 represents a nitrogen atom or CR4a, A3 represents a nitrogen atom or CR4b, and R7 represents a hydrogen atom or the like. (In the formula, R1 represents an oxygen atom or a sulfur atom, W1 represents an oxygen atom or a sulfur atom, R4a and R4b are the same or different from each other and represent a C1-C6 chain hydrocarbon group or the like, R6 represents a C1-C6 chain hydrocarbon group or the like, and T represents a C1-C10 chain hydrocarbon group {the C1-C10 chain hydrocarbon group has one or more substituents selected from the group consisting of cyano groups and halogen atoms} or the like. ) The compound has an excellent control effect on harmful arthropods. # imgabs0 #

Description

Technical Field

[0001] This patent application claims priority and benefits under the Paris Convention based on Japanese Patent Application No. 2022-155034 (filed on September 28, 2022), and all the contents described in the above application are incorporated into this specification by reference.

[0002] The present invention relates to a sulfonamide compound and a harmful arthropod control composition containing the sulfonamide compound. Background Art

[0003] Various compounds have been studied for the purpose of controlling harmful arthropods. For example, Patent Document 1 describes that a certain compound has a pest control effect.

[0004] Prior art literature

[0005] Patent Literature

[0006] Patent Document 1: International Publication No. 2018 / 008727 Summary of the Invention

[0007] Problems to be solved by the invention

[0008] An object of the present invention is to provide a compound having excellent control effect on harmful arthropods.

[0009] Means for solving problems

[0010] The present invention is as follows.

[0011] [1] A compound represented by formula (I) (hereinafter referred to as Compound N of the present invention) or an N-oxide thereof (hereinafter referred to as Compound (I) or an N-oxide thereof as Compound of the present invention).

[0012] [Chemical Formula 1]

[0013]

[0014] 〔where,

[0015] Q shown in the following formula represents a group represented by formula Q1, a group represented by formula Q2, a group represented by formula Q3, a group represented by formula Q4, a group represented by formula Q5, a group represented by formula Q6, or a group represented by formula Q7 (# represents a bonding site to a sulfur atom, ● represents a bonding site to Het),

[0016] [Chemical Formula 2]

[0017]

[0018] [Chemical Formula 3]

[0019]

[0020] A 1 Indicates NR 5 , oxygen atoms or sulfur atoms,

[0021] G 1 , G 2 , G 3 and G 4 The combination of:

[0022] G 1 is a nitrogen atom or CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c combination of;

[0023] G 1 CR 3a , G 2 is a nitrogen atom, G 3 CR 3d , G 4 CR 3c combination of;

[0024] G 1 CR 3a , G 2 CR 3b , G 3 is a nitrogen atom, G 4 CR 3c or

[0025] G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 is a combination of nitrogen atoms,

[0026] R 2a and R 2b are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom,

[0027] R 2a and R 2b Together with the nitrogen atom to which they are bound, they may form an aziridinyl, azetidinyl, pyrrolidinyl or piperidinyl group,

[0028] R3a 、R 3b 、R 3c 、R 3d 、R 3f 、R 3g 、R 3i and R 3k are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group B, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group E, a phenyl group which may be substituted by one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group H, or 12 NR 11 R 12 NR 11a R 12a NR 24 NR 11 R 12 NR 24 OR 11 NR 11 C(O)R 13 NR 24 NR 11 C(O)R 13 NR 11 C(O)OR 14 NR 24 NR 11 C(O)OR 14 NR 11 C(O)NR 31 R 32 NR 24 NR 11 C(O)NR 31 R 32 、N=CHNR 31 R 32 、N=S(O) p R 15 R 16 、C(O)R 13 、C(O)OR 17 、C(O)NR 31 R 32 、C(O)NR 11 S(O)2R 23 , CR 30 =NOR 17 NR 11 CR 24 =NOR 17 、S(O) q R 23 , cyano group, nitro group, hydrogen atom or halogen atom,

[0029] R 3e and R 3h are the same or different from each other and represent a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from Group H,

[0030] When Q is a group represented by formula Q1, R 3a 、R 3b and R 3d The two adjacent substituents in the group may form, together with the two carbon atoms to which they are bonded, a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, or a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring may be substituted with one or more substituents selected from Group H}, or a triazole ring which may be substituted with one or more substituents selected from Group I,

[0031] p represents 0 or 1,

[0032] q represents 0, 1, or 2,

[0033] R 30 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a halogen atom, or an OR 35 NR 36 R 37 , or hydrogen atoms,

[0034] R 17 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from Group D, or a hydrogen atom,

[0035] R 12 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group J, a C3-C7 cycloalkenyl group which may be substituted by one or more substituents selected from Group J, a phenyl group which may be substituted by one or more substituents selected from Group D, a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, a hydrogen atom, or S(O)2R 23 ,

[0036] R 23 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from Group D,

[0037] R 11a and R12a Together with the nitrogen atom to which they are bonded, they represent a 3- to 7-membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from Group E,

[0038] R 13 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from Group D, or a hydrogen atom,

[0039] R 14 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group D},

[0040] R 15 and R 16 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms,

[0041] R 31 represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom,

[0042] R 32 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group J, or a hydrogen atom,

[0043] Het represents a group represented by formula Het1, a group represented by formula Het2, a group represented by formula Het3, a group represented by formula Het4, a group represented by formula Het5, a group represented by formula Het6, or a group represented by formula Het7,

[0044] [Chemical Formula 4]

[0045]

[0046] A 2 Represents nitrogen atom or CR 4a ,

[0047] A 3 Represents nitrogen atom or CR 4b ,

[0048] A 4 Represents nitrogen atom or CR4c ,

[0049] W 1 represents an oxygen atom or a sulfur atom,

[0050] When Het is a group represented by the formula Het5 or Het6,

[0051] A 2 and A 3 The combination of:

[0052] A 2 CR 4a , A 3 is a nitrogen atom or CR 4b or,

[0053] A 2 is a nitrogen atom, A 3 CR 4b combination of

[0054] B 1 、B 2 and B 3 The combination of:

[0055] B 1 CR 6e , B 2 is a nitrogen atom or CR 6b , B 3 is a nitrogen atom or CR 6c combination of;

[0056] B 1 is a nitrogen atom or CR 6a , B 2 CR 6e , B 3 is a nitrogen atom or CR 6c or

[0057] B 1 is a nitrogen atom or CR 6a , B 2 is a nitrogen atom or CR 6b , B 3 CR 6e combination of

[0058] When Het is a group represented by the formula Het7,

[0059] A 2 and A 3 The combination of:

[0060] A 2 CR 4a , A 3is a nitrogen atom or CR 4b or,

[0061] A 2 is a nitrogen atom, A 3 is a nitrogen atom or CR 4b combination of

[0062] B 1 、B 2 、B 3 and B 4 The combination of:

[0063] B 1 is a nitrogen atom or CR 6a , B 2 CR 6e , B 3 is a nitrogen atom or CR 6c , B 4 is a nitrogen atom or CR 6d combination of;

[0064] B 1 is a nitrogen atom or CR 6a , B 2 is a nitrogen atom or CR 6b , B 3 CR 6e , B 4 is a nitrogen atom or CR 6d combination of;

[0065] B 1 is a nitrogen atom or CR 6a , B 2 is a nitrogen atom or CR 6b , B 3 CR 6c , B 4 CR 6e combination of;

[0066] B 1 is a nitrogen atom or CR 6a , B 2 CR 6b , B 3 is a nitrogen atom, B 4 CR 6e or

[0067] B 1 CR 6a , B 2 is a nitrogen atom, B 3 is a nitrogen atom, B 4 CR 6e combination of

[0068] R4a 、R 4b 、R 4c 、R 6a 、R 6b 、R 6c 、R 6d The same or different, representing a C1-C6 chain hydrocarbon group, nitro group, OR 18 NR 18 R 19 , cyano group, amino group, halogen atom or hydrogen atom,

[0069] R 6e represents a C1-C6 chain hydrocarbon group substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C4 cycloalkyl group which may be substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 , OR 7 , halogen atoms or OS(O)2R 7 ,

[0070] R 6 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C6 cycloalkyl group which may be substituted by one or more substituents selected from Group J, a phenyl group which may be substituted by one or more substituents selected from Group H, or a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group H,

[0071] T represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C3-C5 alkenyloxy)C2-C5 alkyl group, a (C3-C5 alkynyloxy)C2-C5 alkyl group, or a (C1-C5 alkyl)-S(O) group. w -(C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) w -(C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) w -(C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O) w -(C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) w -(C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) w-(C2-C5 alkyl) group, and the (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms}, (C3-C7 cycloalkyl)C1-C3 alkyl substituted with one or more substituents selected from Group G, C3-C7 cycloalkyl substituted with one or more substituents selected from Group G, OR 1 、S(O) v R 1 、OS(O)2R 1 、CH2OR 1 NR 1 R 29 、C(O)R 1 、C(O)NR 1 R 29 NR 29 C(O)R 1 、N=CR 1 R 30 , a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12,

[0072] [Chemical Formula 5]

[0073]

[0074] [Chemical Formula 6]

[0075]

[0076] [Chemical Formula 7]

[0077]

[0078] X 1 Represents nitrogen atom or CR 1a ,

[0079] X 2 Represents nitrogen atom or CR 1b ,

[0080] X 3 Represents nitrogen atom or CR 1c ,

[0081] X 4 Represents nitrogen atom or CR 1d ,

[0082] X 5 Represents nitrogen atom or CR1e ,

[0083] R 1x represents a C1-C5 chain hydrocarbon group substituted by one or more halogen atoms, OR 7 、OS(O)2R 7 、S(O) m R 7 NR 8 S(O)2R 7 or halogen atoms,

[0084] R 1a 、R 1b 、R 1c 、R 1d and R 1e are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom,

[0085] Y 1 Indicates NR 25 , oxygen atoms or sulfur atoms,

[0086] Y 2 Represents nitrogen atom or CR 26 ,

[0087] Y 3 Represents nitrogen atom or CR 27 ,

[0088] Y 4 Represents nitrogen atom or CR 28 ,

[0089] R 5 and R 25 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom,

[0090] R 26 、R 27 and R 28 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom,

[0091] R 1y represents a C1-C5 chain hydrocarbon group substituted by one or more halogen atoms, OR 7 、OS(O)2R 7、S(O) m R 7 NR 8 S(O)2R 7 , cyano or halogen atoms,

[0092] R 1ay and R 7 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group substituted by one or more halogen atoms,

[0093] m and v are the same or different and represent 0, 1 or 2.

[0094] w and t are the same or different from each other and represent 0, 1 or 2,

[0095] R 1 represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C3-C5 alkenyloxy)C2-C5 alkyl group, a (C3-C5 alkynyloxy)C2-C5 alkyl group, or a (C1-C5 alkyl)-S(O) group. t -(C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) t -(C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) t -(C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O) t -(C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) t -(C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) t -(C2-C5 alkyl) group, and said (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms, (C3-C7 cycloalkyl)C1-C3 alkyl substituted with one or more substituents selected from Group G, or C3-C7 cycloalkyl substituted with one or more substituents selected from Group G,

[0096] R 18 and R 35 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms,

[0097] R 8 、R 11 、R 19 、R 24 、R29 、R 36 and R 37 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a hydrogen atom.

[0098] Group B: The group consisting of C1-C6 alkoxy groups which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfanyl groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfinyl groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfonyl groups which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl groups which may be substituted by one or more halogen atoms, cyano groups, hydroxyl groups and halogen atoms.

[0099] Group C: A group consisting of a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, and a halogen atom.

[0100] Group D: C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, hydroxyl group, C1-C6 alkoxy group which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, sulfanyl group, C1-C6 alkylsulfanyl group which may be substituted by one or more halogen atoms, C1-C6 alkylsulfinyl group which may be substituted by one or more halogen atoms, C1-C6 alkylsulfonyl group which may be substituted by one or more halogen atoms, amino group, NHR group 21 NR 21 R 22 、C(O)R 21 、OC(O)R 21 、C(O)OR 21 , cyano, nitro and halogen atoms.

[0101] R 21 and R 22 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted with one or more halogen atoms.

[0102] Group E: The group consisting of a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, a halogen atom, an oxo group, a hydroxyl group, a cyano group and a nitro group.

[0103] Group F: C1-C6 alkoxy group which may be substituted with one or more halogen atoms, phenyl group which may be substituted with one or more substituents selected from Group D, 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from Group D, C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, 3-7-membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from Group C, amino group, NHR group 21 NR 21 R 22 , a group consisting of halogen atoms and cyano groups.

[0104] Group G: a group consisting of a halogen atom, a C1-C6 haloalkyl group, and a cyano group.

[0105] Group H: C1-C6 alkyl which may be substituted with one or more halogen atoms, OR 10 NR 9 R 10 、C(O)R 10 、C(O)NR 9 R 10 、OC(O)R 9 、OC(O)OR 9 NR 10 C(O)R 9 NR 10 C(O)OR 9 、C(O)OR 10 , a halogen atom, a nitro group, a cyano group, an amino group and a 5- or 6-membered aromatic heterocyclic group.

[0106] R 9 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms,

[0107] R 10 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom.

[0108] Group I: The group consisting of a C2-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, a C2-C6 alkylcarbonyl group which may be substituted by one or more halogen atoms, a C2-C6 alkoxycarbonyl group which may be substituted by one or more halogen atoms, an aminocarbonyl group, a (C1-C6 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms, a methyl group, and a di(C1-C4 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms.

[0109] Group J: A group consisting of a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a halogen atom, and a cyano group.

[0110] [2] The compound according to [1] or its N-oxide, wherein Q is a group represented by formula Q1 or a group represented by formula Q5.

[0111] [3] The compound according to [1] or its N-oxide, wherein Q is a group represented by the formula Q5.

[0112] [4] The compound or N-oxide thereof as described in [3], wherein G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c .

[0113] [5] The compound or N-oxide thereof according to any one of [1] to [4], wherein Het is a group represented by the formula Het1, and A 2 CR 4a , A 3 CR 4b or nitrogen atoms.

[0114] [6] The compound or N-oxide thereof according to any one of [1] to [4], wherein Het is a group represented by the formula Het5, and A 2 CR 4a , A 3 CR 4b , B 1 CR 6a , B 2 CR 6e , B 3 A nitrogen atom.

[0115] [7] The compound or N-oxide thereof according to any one of [1] to [4], wherein Het is a group represented by the formula Het7, and A 2 CR 4a , A 3 is a nitrogen atom, B 1 CR 6a , B 2 CR 6e , B 3 CR 6c , B 4 CR 6d .

[0116] [8] A harmful arthropod control composition comprising an inactive carrier and the compound or N-oxide thereof according to any one of [1] to [7].

[0117] [9] A composition comprising one or more components selected from the group consisting of group (a), group (b), group (c), and group (d), and the compound or N-oxide thereof according to any one of [1] to [7],

[0118] Group (a): a group consisting of insecticidal active ingredients, acaricidal active ingredients and nematicidal active ingredients;

[0119] Group (b): bactericidal active ingredients;

[0120] Group (c): plant growth regulating ingredients;

[0121] Group (d): repellent ingredients.

[0122]

[10] A method for controlling harmful arthropods, comprising applying an effective amount of the compound or N-oxide thereof according to any one of [1] to [7] or an effective amount of the composition according to [9] to the harmful arthropods or to a habitat of the harmful arthropods.

[0123]

[11] A seed or a vegetative propagation organ containing an effective amount of the compound or N-oxide thereof according to any one of [1] to [7] or an effective amount of the composition according to [9].

[0124] Effects of the Invention

[0125] According to the present invention, harmful arthropods can be controlled. DETAILED DESCRIPTION

[0126] The substituents in the present invention are explained.

[0127] The halogen atom refers to a fluorine atom, a chlorine atom, a bromine atom or an iodine atom.

[0128] When the substituent is substituted with two or more halogen atoms or substituents, these halogen atoms or substituents may be the same or different.

[0129] In this specification, the expression "CX-CY" means that the number of carbon atoms is X to Y. For example, the expression "C1-C6" means that the number of carbon atoms is 1 to 6.

[0130] The chain hydrocarbon group refers to an alkyl group, an alkenyl group or an alkynyl group.

[0131] Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a 1,1-dimethylpropyl group, a 1,2-dimethylpropyl group, a 1-ethylpropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, and a hexyl group.

[0132] The haloalkyl group refers to an alkyl group substituted with one or more halogen atoms.

[0133] Examples of the alkenyl group include ethenyl, 1-propenyl, 2-propenyl, 1-methyl-1-propenyl, 1-methyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1-ethyl-2-propenyl, 3-butenyl, 4-pentenyl, and 5-hexenyl.

[0134] Examples of the alkynyl group include ethynyl, 1-propynyl, 2-propynyl, 1-methyl-2-propynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 2-butynyl, 4-pentynyl, and 5-hexynyl.

[0135] Examples of the alkoxy group include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, a tert-butoxy group, a pentyloxy group, and a hexyloxy group.

[0136] Examples of the alkenyloxy group include a 2-propenyloxy group, a 2-butenyloxy group, and a 5-hexenyloxy group.

[0137] Examples of the alkynyloxy group include a 2-propynyloxy group, a 2-butynyloxy group, and a 5-hexynyloxy group.

[0138] Examples of the cycloalkyl group include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a cycloheptyl group.

[0139] Examples of the cycloalkenyl group include a cyclopropenyl group, a cyclobutenyl group, a cyclopentenyl group, a cyclohexenyl group, and a cycloheptenyl group.

[0140] Examples of the 3- to 7-membered non-aromatic heterocyclic group include aziridinyl, oxirane, thiirane, azetidinyl, oxetanyl, thietanyl, pyrrolidinyl, tetrahydrofuranyl, tetrahydrothiophenyl, piperidinyl, pyranyl, dihydropyranyl, tetrahydropyranyl, tetrahydrothiopyranyl, azepanyl, oxepanyl, thiepanyl, pyrazolinyl, pyrazolidinyl, imidazolinyl, imidazolidinyl, oxazolinyl, thiazolinyl, oxazolidinyl, thiazolidinyl, isoxazolinyl, isoxazolidinyl, isothiazolinyl, isothiazolidinyl, dioxolyl, dioxane, morpholinyl, thiomorpholinyl, and piperazinyl.

[0141] Examples of the 5- or 6-membered aromatic heterocyclic group include pyrrolyl, furyl, thienyl, pyrazolyl, imidazolyl, triazolyl, tetrazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridyl, pyridazinyl, pyrimidinyl, pyrazinyl, triazinyl and tetrazinyl.

[0142] Examples of the 6-membered aromatic heterocyclic group include a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, and a tetrazinyl group.

[0143] Examples of the (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms include cyclopropylmethyl, (2-fluorocyclopropyl)methyl, cyclopropyl(fluoro)methyl, and (2-fluorocyclopropyl)(fluoro)methyl.

[0144] Examples of the (C1-C5 alkoxy)C2-C5 alkyl group include 2-methoxyethyl, 3-methoxypropyl and 3-ethoxypropyl.

[0145] The so-called (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted with one or more halogen atoms means a group in which (C3-C7 cycloalkyl) and / or (C1-C6 alkyl) may be substituted with one or more halogen atoms, and examples thereof include (2,2-difluorocyclopropyl)methyl, 2-cyclopropyl-1,1,2,2-tetrafluoroethyl, 2-(2,2-difluorocyclopropyl)-1,1,2,2-tetrafluoroethyl, (2,2-difluorocyclopropyl)propyl, (2,2-difluorocyclopropyl)butyl, (2,2-difluorocyclopropyl)pentyl, and (2,2-difluorocyclopropyl)hexyl.

[0146] The (C3-C7 cycloalkyl)C1-C3 alkyl group substituted with one or more substituents selected from group G refers to a group in which (C3-C7 cycloalkyl) and / or (C1-C3 alkyl) are substituted with one or more substituents selected from group G, and examples thereof include (2,2-difluorocyclopropyl)methyl, [1-(trifluoromethyl)cyclopropyl]methyl, [2-(trifluoromethyl)cyclopropyl]methyl, 2-cyclopropyl-1,1,2,2-tetrafluoroethyl, 2-cyclopropyl-3,3,3-trifluoropropyl, and 1,1,2,2-tetrafluoro-2-[2-(trifluoromethyl)cyclopropyl]ethyl.

[0147] Examples of the phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted by one or more substituents selected from group M} include benzyl, 2-fluorobenzyl, 4-chlorobenzyl, 4-(trifluoromethyl)benzyl, and 2-[4-(trifluoromethyl)phenyl]ethyl.

[0148] Examples of the alkylsulfanyl group include a methylsulfanyl group, an ethylsulfanyl group, a propylsulfanyl group, and an isopropylsulfanyl group.

[0149] Examples of the alkylsulfinyl group include a methylsulfinyl group, an ethylsulfinyl group, a propylsulfinyl group, and an isopropylsulfinyl group.

[0150] Examples of the alkylsulfonyl group include a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, and an isopropylsulfonyl group.

[0151] Examples of the alkylcarbonyl group include an acetyl group, a propionyl group, a 2-methylpropionyl group, and a hexanoyl group.

[0152] Examples of the alkoxycarbonyl group include a methoxycarbonyl group, an ethoxycarbonyl group, an isopropoxycarbonyl group, and a pentyloxycarbonyl group.

[0153] Examples of the N-oxide of the compound represented by formula (I) include compounds represented by the following formula.

[0154] [Chemical Formula 8]

[0155]

[0156] [In the formula, the symbols have the same meanings as above.]

[0157] The compounds of the present invention may exist in one or more stereoisomers. Examples of stereoisomers include enantiomers, diastereomers, and geometric isomers. The compounds of the present invention include individual stereoisomers and mixtures of stereoisomers in any ratio.

[0158] The compounds of the present invention may form acid addition salts. Examples of acids that form acid addition salts include inorganic acids such as hydrogen chloride, phosphoric acid, and sulfuric acid, and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid. Acid addition salts can be obtained by mixing the compounds of the present invention with an acid.

[0159] As an embodiment of the compound N of the present invention, the following compounds can be mentioned.

[0160] [Embodiment 1] In the compound N of the present invention, Q is a group represented by the formula Q1 or a group represented by the formula Q5.

[0161] [Method 2] In method 1, G 1 is a nitrogen atom or CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c ,

[0162] R 3a 、R 3b 、R 3c and R 3d The same or different groups are C1-C6 chain hydrocarbon groups which may be substituted by one or more substituents selected from Group B, C3-C7 cycloalkyl groups which may be substituted by one or more substituents selected from Group E, phenyl groups which may be substituted by one or more substituents selected from Group H, 5- or 6-membered aromatic heterocyclic groups which may be substituted by one or more substituents selected from Group H, OR 12 , CR30 =NOR 17 , hydrogen atoms or halogen atoms,

[0163] R 17 and R 30 are the same or different from each other, and are C1-C6 chain hydrocarbon groups which may be substituted by one or more halogen atoms,

[0164] R 12 A compound which is a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group J, or a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D.

[0165] [Method 3] In Method 2, R 3a and R 3c is a hydrogen atom,

[0166] R 3b and R 3d the same or different from each other, and are C1-C6 chain hydrocarbon groups which may be substituted by one or more halogen atoms, C3-C7 cycloalkyl groups which may be substituted by one or more halogen atoms, phenyl groups which may be substituted by one or more halogen atoms, 5- or 6-membered aromatic heterocyclic groups which may be substituted by one or more halogen atoms, OR 12 , hydrogen atoms or halogen atoms,

[0167] R 12 A compound containing a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms.

[0168] [Method 4] In Method 3, R 3b and R 3d Compounds which are the same or different and are C1-C6 chain hydrocarbon groups, hydrogen atoms or halogen atoms which may be substituted with one or more halogen atoms.

[0169] [Embodiment 5] In the compound N of the present invention, Q is a group represented by the formula Q1.

[0170] [Method 6] In method 5, R 3a 、R 3b and R 3d The same or different groups are C1-C6 chain hydrocarbon groups which may be substituted by one or more substituents selected from Group B, C3-C7 cycloalkyl groups which may be substituted by one or more substituents selected from Group E, phenyl groups which may be substituted by one or more substituents selected from Group H, 5- or 6-membered aromatic heterocyclic groups which may be substituted by one or more substituents selected from Group H, OR 12 , CR 30 =NOR 17 , hydrogen atoms or halogen atoms,

[0171] R 17 and R 30 are the same or different from each other, and are C1-C6 chain hydrocarbon groups which may be substituted by one or more halogen atoms,

[0172] R 12 A compound which is a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group J, or a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D.

[0173] [Method 7] In Method 6, R 3a is a hydrogen atom,

[0174] R 3b and R 3d the same or different from each other, and are C1-C6 chain hydrocarbon groups which may be substituted by one or more halogen atoms, C3-C7 cycloalkyl groups which may be substituted by one or more halogen atoms, phenyl groups which may be substituted by one or more halogen atoms, 5- or 6-membered aromatic heterocyclic groups which may be substituted by one or more halogen atoms, OR 12 , hydrogen atoms or halogen atoms,

[0175] R 12 A compound containing a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms.

[0176] [Method 8] In Method 7, R 3b and R 3d Compounds which are the same or different and are C1-C6 chain hydrocarbon groups, hydrogen atoms or halogen atoms which may be substituted with one or more halogen atoms.

[0177] [Embodiment 9] In the compound N of the present invention, Q is a group represented by the formula Q5.

[0178] [Method 10] In method 9, G 1 is a nitrogen atom or CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c ,

[0179] R 3a 、R 3b 、R 3c and R 3dThe same or different groups are C1-C6 chain hydrocarbon groups which may be substituted by one or more substituents selected from Group B, C3-C7 cycloalkyl groups which may be substituted by one or more substituents selected from Group E, phenyl groups which may be substituted by one or more substituents selected from Group H, 5- or 6-membered aromatic heterocyclic groups which may be substituted by one or more substituents selected from Group H, OR 12 , CR 30 =NOR 17 , hydrogen atoms or halogen atoms,

[0180] R 17 and R 30 are the same or different from each other, and are C1-C6 chain hydrocarbon groups which may be substituted by one or more halogen atoms,

[0181] R 12 A compound which is a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group J, or a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D.

[0182] [Method 11] In Method 10, R 3a and R 3c is a hydrogen atom,

[0183] R 3b and R 3d the same or different from each other, and are C1-C6 chain hydrocarbon groups which may be substituted by one or more halogen atoms, C3-C7 cycloalkyl groups which may be substituted by one or more halogen atoms, phenyl groups which may be substituted by one or more halogen atoms, 5- or 6-membered aromatic heterocyclic groups which may be substituted by one or more halogen atoms, OR 12 , hydrogen atoms or halogen atoms,

[0184] R 12 A compound containing a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms.

[0185] [Method 12] In Method 11, R 3b and R 3d Compounds which are the same or different and are C1-C6 chain hydrocarbon groups, hydrogen atoms or halogen atoms which may be substituted with one or more halogen atoms.

[0186] [Embodiment 13] In the compound N of the present invention, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0187] [Embodiment 14] In the compound N of the present invention, R 2a and R 2bCompounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0188] [Method 15] In Method 1, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0189] [Method 16] In Method 1, R 2a and R 2b Compounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0190] [Method 17] In Method 2, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0191] [Method 18] In Method 2, R 2a and R 2b Compounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0192] [Method 19] In Method 3, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0193] [Method 20] In Method 3, R 2a and R 2b Compounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0194] [Method 21] In Method 4, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0195] [Method 22] In Method 4, R 2a and R 2b Compounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0196] [Method 23] In Method 5, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0197] [Method 24] In method 5, R 2a and R 2bCompounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0198] [Method 25] In Method 6, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0199] [Method 26] In Method 6, R 2a and R 2b Compounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0200] [Method 27] In Method 7, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0201] [Method 28] In Method 7, R 2a and R 2b Compounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0202] [Method 29] In method 8, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0203] [Method 30] In method 8, R 2a and R 2b Compounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0204] [Method 31] In Method 9, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0205] [Method 32] In method 9, R 2a and R 2b Compounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0206] [Method 33] In method 10, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0207] [Method 34] In method 10, R 2a and R 2bCompounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0208] [Method 35] In method 11, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0209] [Method 36] In method 11, R 2a and R 2b Compounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0210] [Method 37] In method 12, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0211] [Method 38] In method 12, R 2a and R 2b Compounds which are the same or different from each other and are methyl, ethyl, cyclopropyl or hydrogen atoms.

[0212] [Embodiment 39] In any of Embodiments 1 to 14 or Compound N of the present invention, a compound wherein Het is a group represented by formula Het1, a group represented by formula Het3, a group represented by formula Het5, or a group represented by formula Het7.

[0213] [Embodiment 40] In any of Embodiments 1 to 14 or Compound N of the present invention, a compound wherein Het is a group represented by the formula Het1 or a group represented by the formula Het3.

[0214] [Embodiment 41] In any of Embodiments 1 to 14 or Compound N of the present invention, a compound wherein Het is a group represented by Formula Het5 or a group represented by Formula Het7.

[0215] [Embodiment 42] In any of Embodiments 1 to 14 or Compound N of the present invention, a compound wherein Het is a group represented by the formula Het1.

[0216] [Embodiment 43] In any of Embodiments 1 to 14 or Compound N of the present invention, a compound wherein Het is a group represented by the formula Het3.

[0217] [Embodiment 44] In any of Embodiments 1 to 14 or Compound N of the present invention, a compound wherein Het is a group represented by the formula Het5.

[0218] [Embodiment 45] In any of Embodiments 1 to 14 or Compound N of the present invention, a compound wherein Het is a group represented by the formula Het7.

[0219] [Method 46] In method 39, A 2 CR 4a , A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , B 1 CR 6a , B 2 CR 6e , B 3 is a nitrogen atom or CR 6c , B 4 CR 6d ,

[0220] R 4a 、R 4b 、R 4c 、R 6a 、R 6c 、R 6d are the same or different from each other and are C1-C6 chain hydrocarbon groups, halogen atoms or hydrogen atoms which may be substituted by one or more halogen atoms,

[0221] R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or halogen atoms,

[0222] R 6 is a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms,

[0223] T is OR 1 ,

[0224] R 1 It is a compound of a C1-C10 chain hydrocarbon group having one or more substituents selected from the group consisting of a cyano group and a halogen atom, or a C3-C7 cycloalkyl group having one or more substituents selected from Group G.

[0225] [Method 47] In method 39, A 2 CR 4a , A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , B 1 CR 6a , B 2 CR 6b , B 3 is a nitrogen atom or CR 6e , B 4 CR 6d ,

[0226] R 4a 、R 4b 、R 4c 、R 6a 、R 6b and R 6d are the same or different from each other and are C1-C6 chain hydrocarbon groups, halogen atoms or hydrogen atoms which may be substituted by one or more halogen atoms,

[0227] R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or halogen atoms,

[0228] R 6 is a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms,

[0229] T is OR 1 ,

[0230] R 1 A compound which is a C1-C10 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, or a C3-C7 cycloalkyl group substituted with one or more substituents selected from Group G.

[0231] [Method 48] In method 42, A 2 CR 4a , A 3 is a nitrogen atom or CR 4b ,

[0232] R 4a and R 4b are the same or different from each other and are C1-C6 chain hydrocarbon groups, halogen atoms or hydrogen atoms which may be substituted by one or more halogen atoms,

[0233] R 6 is a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms,

[0234] T is OR 1 ,

[0235] R 1 A compound which is a C1-C10 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, or a C3-C7 cycloalkyl group substituted with one or more substituents selected from Group G.

[0236] [Method 49] In method 43, A 2 CR 4a , A 3 is a nitrogen atom or CR 4b , A4 CR 4c ,

[0237] R 4a 、R 4b and R 4c are the same or different from each other and are C1-C6 chain hydrocarbon groups, halogen atoms or hydrogen atoms which may be substituted by one or more halogen atoms,

[0238] T is OR 1 ,

[0239] R 1 A compound which is a C1-C10 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, or a C3-C7 cycloalkyl group substituted with one or more substituents selected from Group G.

[0240] [Method 50] In method 44, A 2 CR 4a , A 3 CR 4b , B 1 CR 6a , B 2 CR 6e , B 3 is a nitrogen atom or CR 6c ,

[0241] R 4a 、R 4b 、R 6a and R 6c are the same or different from each other and are C1-C6 chain hydrocarbon groups, halogen atoms or hydrogen atoms which may be substituted by one or more halogen atoms,

[0242] R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or halogen atoms.

[0243] [Method 51] In method 45, A 2 CR 4a , A 3 CR 4b , B 1 CR 6a , B 2 CR 6e , B 3 CR 6c , B 4 CR 6d ,

[0244] R 4a 、R 4b 、R6a 、R 6c and R 6d are the same or different from each other and are C1-C6 chain hydrocarbon groups, halogen atoms or hydrogen atoms which may be substituted by one or more halogen atoms,

[0245] R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or halogen atoms.

[0246] [Method 52] In method 46, A 2 CR 4a , A 3 CR 4b , B 1 CR 6a , B 2 CR 6e , B 3 CR 6c , B 4 CR 6d ,

[0247] R 4a 、R 4b 、R 6a 、R 6c and R 6d are the same or different from each other and are C1-C6 chain hydrocarbon groups, halogen atoms or hydrogen atoms which may be substituted by one or more halogen atoms,

[0248] R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or halogen atoms.

[0249] [Method 53] In method 47, A 2 CR 4a , A 3 CR 4b , B 1 CR 6a , B 2 CR 6b , B 3 CR 6e , B 4 CR 6d ,

[0250] R 4a 、R 4b 、R 6a 、R 6b and R 6dare the same or different from each other and are C1-C6 chain hydrocarbon groups, halogen atoms or hydrogen atoms which may be substituted by one or more halogen atoms,

[0251] R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or halogen atoms.

[0252] [Method 54] In method 48, R 4a and R 4b is a hydrogen atom, R 6 A compound containing methyl.

[0253] [Method 55] In method 49, R 4a 、R 4b and R 4c A compound containing hydrogen atoms.

[0254] [Method 56] In method 50, B 3 is a nitrogen atom, R 4a 、R 4b and R 6a A compound containing hydrogen atoms.

[0255] [Method 57] In method 51, R 4a 、R 4b 、R 6a 、R 6c and R 6d A compound containing hydrogen atoms.

[0256] [Method 58] In method 52, R 4a 、R 4b 、R 6a 、R 6c and R 6d A compound containing hydrogen atoms.

[0257] [Method 59] In method 53, R 4a 、R 4b 、R 6a 、R 6b and R 6d A compound containing hydrogen atoms.

[0258] [Embodiment 60] In any one of Embodiments 1 to 38 or the compound N of the present invention, W 1 A compound containing oxygen atoms.

[0259] [Method 61] In method 39, W 1 A compound containing oxygen atoms.

[0260] [Method 62] In method 40, W 1 A compound containing oxygen atoms.

[0261] [Method 63] In method 41, W 1 A compound containing oxygen atoms.

[0262] [Method 64] In method 42, W 1 A compound containing oxygen atoms.

[0263] [Method 65] In method 43, W 1 A compound containing oxygen atoms.

[0264] [Method 66] In method 44, W 1 A compound containing oxygen atoms.

[0265] [Method 67] In method 45, W 1 A compound containing oxygen atoms.

[0266] [Method 68] In method 46, W 1 A compound containing oxygen atoms.

[0267] [Method 69] In method 47, W 1 A compound containing oxygen atoms.

[0268] [Method 70] In method 48, W 1 A compound containing oxygen atoms.

[0269] [Method 71] In method 49, W 1 A compound containing oxygen atoms.

[0270] [Method 72] In method 50, W 1 A compound containing oxygen atoms.

[0271] [Method 73] In method 51, W 1 A compound containing oxygen atoms.

[0272] [Method 74] In method 52, W 1 A compound containing oxygen atoms.

[0273] [Method 75] In method 53, W 1 A compound containing oxygen atoms.

[0274] [Method 76] In method 54, W 1 A compound containing oxygen atoms.

[0275] [Method 77] In method 55, W 1 A compound containing oxygen atoms.

[0276] [Method 78] In method 56, W 1 A compound containing oxygen atoms.

[0277] [Method 79] In method 57, W 1 A compound containing oxygen atoms.

[0278] [Method 80] In method 58, W 1 A compound containing oxygen atoms.

[0279] [Method 81] In method 59, W 1 A compound containing oxygen atoms.

[0280] Next, the method for producing the compound of the present invention will be described.

[0281] Manufacturing method 1

[0282] The compound represented by formula (I) (compound N of the present invention) can be produced by reacting a compound represented by formula (M-1) (hereinafter referred to as compound (M-1)) with a compound represented by formula (M-2) (hereinafter referred to as compound (M-2)).

[0283] [Chemical Formula 9]

[0284]

[0285] [In the formula, the symbols have the same meanings as above.]

[0286] The reaction is usually carried out in a solvent. Examples of the solvent include ethers (hereinafter referred to as ethers) such as tetrahydrofuran (hereinafter referred to as THF), 1,4-dioxane, 1,2-dimethoxyethane (hereinafter referred to as DME), methyl tert-butyl ether (hereinafter referred to as MTBE), and diethyl ether; halogenated hydrocarbons (hereinafter referred to as halogenated hydrocarbons) such as dichloromethane and chloroform; aromatic hydrocarbons (hereinafter referred to as aromatic hydrocarbons) such as toluene and xylene; nitriles (hereinafter referred to as nitriles) such as acetonitrile; water; and mixtures of two or more thereof.

[0287] In the reaction, the compound (M-2) is usually used in a ratio of 0.8 to 10 mol based on 1 mol of the compound (M-1).

[0288] The reaction can be carried out by mixing compound (M-1) and compound (M-2). The reaction can also be carried out in the presence of a base as needed. Examples of the base include alkali metal carbonates such as sodium carbonate and potassium carbonate (hereinafter referred to as alkali metal carbonates); tertiary amines such as triethylamine (hereinafter referred to as tertiary amines); and nitrogen-containing aromatic compounds such as pyridine (hereinafter referred to as nitrogen-containing aromatic compounds). When a base is used in the reaction, the base is usually used in a ratio of 1 to 3 moles relative to 1 mole of compound (M-1).

[0289] The reaction temperature is usually within the range of -20 to 200° C. The reaction time is usually within the range of 0.1 to 24 hours.

[0290] After the reaction is completed, water may be poured into the reaction mixture, followed by extraction with an organic solvent, and post-treatment operations such as drying and concentration of the organic layer may be performed to obtain Compound (I).

[0291] Compound (M-2) is a commercially available compound or can be produced by a known method.

[0292] Manufacturing method 2

[0293] The compound represented by formula (Ia) (hereinafter referred to as compound (Ia)) can be produced by reacting a compound represented by formula (M-3) (hereinafter referred to as compound (M-3)) with a compound represented by formula (M-4) (hereinafter referred to as compound (M-4)) in the presence of a base.

[0294] [Chemical Formula 10]

[0295]

[0296] [In the formula, Het A represents Het3, Het5, Het6 or Het7, and other symbols have the same meanings as above.

[0297] The reaction is usually carried out in a solvent. Examples of the solvent include ethers; aromatic hydrocarbons; nitriles; aprotic polar solvents (hereinafter referred to as aprotic polar solvents) such as dimethylformamide (hereinafter referred to as DMF), N-methylpyrrolidone (hereinafter referred to as NMP), and dimethyl sulfoxide (hereinafter referred to as DMSO); water; and mixtures of two or more thereof.

[0298] Examples of the base include alkali metal carbonates and alkali metal hydrides such as sodium hydride (hereinafter referred to as alkali metal hydrides).

[0299] In the reaction, compound (M-4) is usually used in a ratio of 0.8 to 1.2 mol, and the base is usually used in a ratio of 1 to 3 mol, based on 1 mol of compound (M-3).

[0300] The reaction temperature is usually within a range of -20 to 200° C. The reaction time is usually within a range of 0.5 to 24 hours.

[0301] After the reaction, water is added to the reaction mixture, followed by extraction with an organic solvent, and the obtained organic layer is subjected to post-treatment operations such as drying and concentration to obtain compound (Ia).

[0302] Compound (M-3) is known or can be produced according to the method described in, for example, International Publication No. 2018 / 008727, International Publication No. 2019 / 131575, or International Publication No. 2019 / 131587.

[0303] Manufacturing method 3

[0304] Compound (Ia) can be produced by reacting compound (M-3) with a compound represented by formula (M-5) (hereinafter referred to as compound (M-5)) in the presence of a metal catalyst.

[0305] [Chemical Formula 11]

[0306]

[0307] 〔where X a represents a chlorine atom, a bromine atom or an iodine atom, and other symbols have the same meanings as above.

[0308] The reaction is usually carried out in a solvent. Examples of the solvent include ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more thereof.

[0309] In the reaction, a base may be used as needed. Examples of the base include organic bases such as tertiary amines and nitrogen-containing aromatic compounds (hereinafter referred to as organic bases); alkali metal carbonates; and alkali metal hydrides.

[0310] In the reaction, compound (M-5) is usually used in a ratio of 0.8 to 1.2 mol, and the base is usually used in a ratio of 1 to 3 mol, based on 1 mol of compound (M-3).

[0311] Examples of the metal catalyst include copper catalysts such as copper (I) iodide, copper (I) bromide, copper (I) chloride, copper (I) oxide, copper (I) trifluoromethanesulfonate benzene complex, tetrakis(acetonitrile)copper (I) hexafluorophosphate, and copper (I) 2-thiophenecarboxylate; nickel catalysts such as bis(cyclooctadiene)nickel (0) and nickel (II) chloride; and palladium catalysts such as palladium (II) acetate, tetrakis(triphenylphosphine)palladium (0), and tris(dibenzylideneacetone)dipalladium (II). When a metal catalyst is used in the reaction, it is usually used in a ratio of 0.01 to 0.5 mol per 1 mol of compound (M-1).

[0312] A ligand may be used in the reaction as needed. Examples of the ligand include triphenylphosphine, 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (hereinafter referred to as Xantphos), 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine. When a ligand is used in the reaction, the ligand is usually used in a ratio of 0.01 to 0.5 mol based on 1 mol of compound (M-1).

[0313] The reaction temperature is usually in the range of -20°C to 150°C. The reaction time is usually in the range of 0.5 to 24 hours.

[0314] After the reaction, water is added to the reaction mixture, followed by extraction with an organic solvent, and post-treatment operations such as drying and concentration of the organic layer can be performed to obtain compound (Ia).

[0315] Manufacturing Method 4

[0316] Compound (Ib) can be produced by reacting a compound represented by formula (M-6) (hereinafter referred to as compound (M-6)) with compound (M-5) in the presence of a metal catalyst.

[0317] [Chemical Formula 12]

[0318]

[0319] [In the formula, Het B represents Het1, Het2 or Het4, M represents 9-borabicyclo[3.3.1]nonane-9-yl, dihydroxyboronyl, 4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl, tributylstannyl or ZnCl, and other symbols have the same meanings as above.

[0320] The reaction is usually carried out in a solvent. Examples of the solvent include ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures of two or more thereof.

[0321] Examples of the metal catalyst used in the reaction include palladium catalysts such as tetrakis(triphenylphosphine)palladium(0), 1,1'-bis(diphenylphosphino)ferrocenepalladium(II) dichloride, tris(dibenzylideneacetone)dipalladium(0), and palladium(II) acetate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; iron catalysts such as iron(III) chloride and iron(III) acetylacetonate; and copper catalysts such as copper(I) iodide and copper(I) chloride.

[0322] A ligand, a base and / or an inorganic halide may be added to the reaction as needed.

[0323] Examples of the ligand used in the reaction include triphenylphosphine, Xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline.

[0324] Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases.

[0325] Examples of the inorganic halide used in the reaction include alkali metal fluorides such as potassium fluoride and sodium fluoride; and alkali metal chlorides such as lithium chloride and sodium chloride.

[0326] In the reaction, compound (M-5) is usually used in a ratio of 1 to 10 moles, the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles, the ligand is usually used in a ratio of 0.01 to 1 mole, the base is usually used in a ratio of 0.1 to 5 moles, and the inorganic halide is usually used in a ratio of 0.1 to 5 moles, relative to 1 mole of compound (M-6).

[0327] The reaction temperature is usually within a range of -20°C to 200°C. The reaction time is usually within a range of 0.1 to 24 hours.

[0328] After the reaction, water is added to the reaction mixture, followed by extraction with an organic solvent, and post-treatment operations such as drying and concentration of the organic layer can be performed to obtain compound (Ib).

[0329] Compound (M-6) is known or can be produced according to the method described in, for example, International Publication No. 2018 / 221720.

[0330] Reference manufacturing method 1

[0331] Compound (M-1) can be produced by reacting a compound represented by formula (M-7) (hereinafter referred to as compound (M-7)) with a chlorinating agent in the presence of chlorosulfonic acid.

[0332] [Chemical Formula 13]

[0333]

[0334] [In the formula, the symbols have the same meanings as above.]

[0335] The reaction can be carried out in a solvent as needed. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aromatic hydrocarbons, and mixtures of two or more thereof.

[0336] Examples of the chlorinating agent used in the reaction include phosphorus oxychloride and thionyl chloride.

[0337] In the reaction, chlorosulfonic acid is usually used in a ratio of 1 to 10 mol, and the chlorinating agent is usually used in a ratio of 1 to 10 mol, based on 1 mol of compound (M-7).

[0338] The reaction temperature is usually within a range of -20°C to 200°C. The reaction time is usually within a range of 0.1 to 24 hours.

[0339] After the reaction is completed, water is added to the reaction mixture, extraction is carried out with an organic solvent, and post-treatment operations such as drying and concentration of the organic layer can be performed to obtain compound (M-1).

[0340] Compound (M-7) is known or can be produced according to the method described in, for example, International Publication No. 2018 / 008727, International Publication No. 2018 / 221720, International Publication No. 2019 / 131575 or International Publication No. 2019 / 131587.

[0341] Reference Manufacturing Method 2

[0342] The compound represented by formula (M-9) (hereinafter referred to as compound (M-9)) can be produced by reacting the compound represented by formula (M-8) (hereinafter referred to as compound (M-8)) with a chlorinating agent in the presence of chlorosulfonic acid.

[0343] [Chemical Formula 14]

[0344]

[0345] [In the formula, the symbols have the same meanings as above.]

[0346] The reaction can be carried out according to the method described in Reference Production Method 1, using Compound (M-8) instead of Compound (M-7).

[0347] Compound (M-8) is a commercially available compound or can be produced by a known method.

[0348] Reference Manufacturing Method 3

[0349] Compound (M-5) can be produced by reacting compound (M-9) with compound (M-2).

[0350] [Chemical Formula 15]

[0351]

[0352] [In the formula, the symbols have the same meanings as above.]

[0353] The reaction can be carried out according to the method described in Production Method 1, using Compound (M-9) instead of Compound (M-1).

[0354] Reference Manufacturing Method 4

[0355] Compound (M-4) can be produced by reacting compound (M-5) with a fluorinating agent.

[0356] [Chemical Formula 16]

[0357]

[0358] [In the formula, the symbols have the same meanings as above.]

[0359] The reaction is usually carried out in a solvent. Examples of the solvent include aromatic hydrocarbons, aprotic polar solvents, and mixtures of two or more thereof.

[0360] Examples of the fluorinating agent used in the reaction include cesium fluoride and potassium fluoride.

[0361] In the reaction, the fluorinating agent is usually used in a ratio of 1 to 10 mol based on 1 mol of compound (M-7).

[0362] The reaction temperature is usually in the range of 20° C. to 300° C. The reaction time is usually in the range of 0.1 to 24 hours.

[0363] After the reaction is completed, water is added to the reaction mixture, extraction is performed with an organic solvent, and post-treatment operations such as drying and concentration of the organic layer can be performed to obtain compound (M-4).

[0364] The compound of the present invention may be mixed or used in combination with one or more components (hereinafter referred to as present components) selected from the following group consisting of Group (a), Group (b), Group (c) and Group (d).

[0365] The aforementioned mixed use or combined use means that the compound of the present invention and the present component are used simultaneously, separately, or with a time interval therebetween.

[0366] When the compound of the present invention and the present component are used simultaneously, the compound of the present invention and the present component may be contained in separate preparations or in the same preparation.

[0367] One aspect of the present invention is a composition (hereinafter referred to as composition A) comprising one or more components selected from the group consisting of group (a), group (b), group (c), and group (d) (i.e., the present component) and the compound of the present invention.

[0368] Group (a) is composed of acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphate insecticides), GABA-gated chloride channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamate-gated chloride channel allosteric modulators (e.g., macrolide insecticides), juvenile hormone mimics, multisite inhibitors, chord organ TRPV channel modulators, mite growth inhibitors, and insect midgut lining disruption agents derived from microorganisms. The present invention relates to a group consisting of: a group consisting of: inhibitors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin-based insecticides), chitin biosynthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, inhibitors of mitochondrial electron transport chain complexes I, II, III, and IV, voltage-dependent sodium channel blockers, acetyl-CoA carboxylase inhibitors, ranolidine receptor modulators (e.g., diamide-based insecticides), chord organ modulators, microbial insecticides, and other insecticidal active ingredients, acaricidal active ingredients, and nematicidal active ingredients. These ingredients are described according to the classification based on the IRAC mechanism of action.

[0369] Group (b) includes nucleic acid synthesis inhibitors (e.g., phenylamide-based fungicides, acylamino acid-based fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiration inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid synthesis and protein synthesis inhibitors (e.g., anilinopyridine-based fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., triazole-based DMI fungicides), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multi-site contact-active fungicides, microbial fungicides, and other fungicidal active ingredients. These ingredients are described according to the FRAC-based mechanism of action.

[0370] Group (c) is a group of plant growth regulating ingredients (including mycorrhizal fungi and rhizobia).

[0371] Group (d) is a group of repellent ingredients.

[0372] Examples of combinations of this component and the compound of the present invention are described below. For example, alanycarb+SX refers to a combination of alanycarb and SX.

[0373] It should be noted that the abbreviation SX refers to any one compound of the present invention selected from the compound group SX1 to SX964. In addition, the ingredients described below are all known ingredients and can be obtained from commercially available preparations or manufactured by known methods. If the ingredient is a microorganism, it can also be obtained from a bacterial collection institution. It should be noted that the numbers in parentheses represent CAS RN (registered trademark).

[0374] Combination of the present component of the above group (a) with the compound of the present invention:

[0375] Abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acetoprole + SX, acrinathrin + SX, acynonapyr + SX, afidopyropen + SX, afoxolaner + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha-endosulfan + SX, aluminum phosphide + SX, amitraz + SX, azadirachtin + SX, azamethiphos + SX, azinphos + SX, Hos-ethyl + SX, azinphos-methyl + SX, azocyclotin + SX, bark of Celastrus angulatus + SX, bendiocarb + SX, benfluthrin + SX, benfuracarb + SX, bensultap + SX, benzoximate + SX, benzpyrimoxan + SX, beta-cyfluthrin + SX, beta-cypermethrin + SX, bifenazate + SX, bifenthrin + SX, bioallethrin + SX, bioresmethrin + SX, bistrifluron + SX, borax rax)+SX, boric acid+SX, broflanilide+SX, bromopropylate+SX, buprofezin+SX, butocarboxim+SX, butoxycarboxim+SX, cadusafos+SX, calcium phosphideSX, carbaryl + SX, carbofuran + SX, carbosulfan + SX, cartap hydrochloride + SX, cartap + SX, chinomethionat + SX, chlorantranilip role + SX, chlordane + SX, chlorethoxyfos + SX, chlorfenapyr + SX, chlorfenvinphos + SX, chlorfluazuron + SX, chlormephos + SX, chloropicrin + SX, chlorpyrifos + SX, chlorpyrifos s-methyl + SX, chromafenozide + SX, clofentetracycline zine + SX, clothianidin + SX, concanamycin A + SX, coumaphos + SX, cryolite + SX, cyanophos + SX, cyantraniliprole + SX, cy claniliprole + SX, cyclobutrifluram + SX, cycloprothrin + SX, cycloxaprid + SX, cyenopyrafen + SX, cyetpyrafen + SX, cyflumetofen + SX, cyfluthrin + SX, cyhalodiam ide)+SX, cyhalothrin+SX, cyhexatin+SX, cypermethrin+SX, cyphenothrin+SX, cyproflanilide+SX, cyromazine+SX, dazomet+SX, deltamethrin+SX, demeton-S-methyl+SX, diafenthiuron+SX, diazinonnon)+SX, dichlorvos+SX, dichlorvos+SX, dichloromezotiaz+SX, dicofol+SX, dicrotophos+SX, diflovidazin+SX, diflubenzuron+SX, dimefluthrin+SX, dimethoate+SX, di methylvinphos+SX, dimpropyridaz+SX, dinotefuran+SX, disodium octaborate+SX, disulfoton+SX, DNOC(2-methyl-4,6-dinitrophenol)+SX, doramectin+SX, dried leaves of Dryopteris filix-mas) + SX, emamectin-benzoate + SX, empenthrin + SX, endosulfan + SX, EPN (O-ethyl O-(4-nitrophenyl)phen ylphosphonothioate) + SX, epsilon-metofluthrin + SX, epsilon-momfluorothrin + SX, esfenvalerate + SX, ethiofencarb + SX, ethion + SX, ethiprole + SX, ethoprophos + SX, etofenprox + SX, etoxazole + SX, extract of Artemisia absinthium m)+SX, Azadirachta indica extract+SX, Cassia nigricans extract+SX, Clittoria ternatea extract+SX, Symphytum officinale extract+SX, Chenopodium ambrosum extract+SXsioides + SX, extract of Tanacetum vulgare + SX, extract of Urtica dioica + SX, mistletoe extract of Viscum album + SX, famphur + SX, fenamiphos + SX, fenazaquin + SX, fenbutatin ox ide + SX, fenitrothion + SX, fenmezoditiaz + SX, fenobucarb + SX, fenoxycarb + SX, fenpropathrin + SX, fenpyroximate + SX, fenthion + SX, fenvalerate + SX, fipronil + SX, flomet Fluoxetine + SX, flonicamid + SX, fluacrypyrim + SX, fluazaindolizine + SX, fluazuron + SX, flubendiamide + SX, fluchlordiniliprole + SX, flucycloxuron + SX, flucythrinate + SX, fluensulfone + SX, flufenoprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin + SX, flupentiofenox + SX, flupyradifurone + SX, flupyrimin + SX, flupypyrimid + SX, flupy upyroxystrobin + SX, fluralaner + SX, flu valinate + SX, fluxametamide + SX, formetanate + SX, fosthiazate + SX, furamethrin + SX, furathiocarb + SX, gamma-cyhalothrin + SX, GS-omega / kappaHXTX-Hv1a peptide (GS-omega / kappa HXTX-Hv1a peptide) + SX, halfenprox + SX, halofen ozide + SX, heptafluthrin + SX, heptenophos + SX, hexaflumuron + SX, hexythiazox + SX, potassium salt of hop beta acid acid)+SX, hydramethylnon+SX, hydroprene+SX, imicyafos+SX, imidacloprid+SX, imidaclothiz+SX, imiprothrin+SX, indazapyroxamet+SX, indoxacarb+SX, isocycloseram+SX, isofenphos+SX, isoprocarb+SX, O-(methoxyaminothiophosphoryl) salicylic acid isopropyl-O-(methoxyaminothiophosphoryl)salicylate+SX, isoxathion+SX, ivermectin+SX, kadethrin+SX, kappa-tefluthrin+SX, kappa-bifenthrin+SX, kinoprene+SX, lambda-cyhalothrin+SX, ledprona+SX, leno remycin + SX, lepimectin + SX, lime sulfur + SX, lotilaner + SX, lufenuron + SX, machine oil + SX, malathion + SX, mecarbam + SX, meperfluthrin + SX, metaflumizone + SX, metam + SX, methamidophos + SX, methidathion + SX, methiocarb + SX, methomylyl)+SX, methoprene+SX, methoxychlor+SX, methoxyfenozide+SX, methyl bromide+SX, metofluthrin+SX, metolcarb+SX, metoxadiazone+SX, mevinphos+SX, milbemectin+SX, milbemycin oxime+SX, mivorilaner+SX, modoflaner+SX, momfluorothrin+SX, monocrotophos+SX, moxidectin+SX, naled+SX, nicofluprole+SX, nicotine+SX, nicotine sulfate SX, nitenpyram+SX, novaluron+SX, noviflumuron+SX, Chenopodium anthelminticum seed oil+SX, omethoate+SX, oxamyl+SX, oxazosulfyl+SX, oxydemeton-methyl+SX, parathion+SX, parathion-methyl+SX, permethrin+SX, phenothrin+SX, phenthoate+SX, phorate+SX, phosalone+SX, phosmet+SX, phosphamide amidon)+SX, phosphine+SX, phoxim+SX, pirimicarb+SX, pirimiphos-methyl+SX, prallethrin+SX, profenofos+SX, pr ofluthrin+SX, propargite+SX, propetamphos+SX, propoxur+SX, propylene glycol alginateglycol alg inate+SX, prothiofos+SX, pyflubumide+SX, pymetrozine+SX, pyraclofos+SX, pyrethrins+SX, pyridaben+SX, pyridalyl+SX, pyridaphenthion+SX, pyrifluquinazone+SX, pyrimidifen+SX, pyriminostrobin+SX, pyriprole+SX, pyriproxyfen+SX, quinalph os + SX, resmethrin + SX, rotenone + SX, ryanodine + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate + SX, sodium metaborate + SX, spidoxamat + SX, spinetoram + SX, spinosad + SX, spirobudifen + SX, spirodiclofen + SX, spiromesifen + SX, spiropidion + SX, spirotetramat + SX, sulfiflum in)+SX, sulfluramid+SX, sulfotep+SX, sulfoxaflor+SX, sulfur+SX, sulfuryl fluoride+SX, tartaremetic+SX, tau-fluvalinate+SX, tebufenozide+SX, tebufenpyrad+SX, tebupirimfos+SX, teflubenzuron+SX, tefluthrin+SX, temephos+SX, terbufosrbufos)+SX, terpene constituents of the extract of chenopodium ambrosioides nearambrosioides+SX, tetrachlorantraniliprole+SX, tetrachlorvinpho s+SX, tetradifon+SX, tetramethrin+SX, tetramethylfluthrin+SX, tetraniliprol e)+SX, theta-cypermethrin+SX, thiacloprid+SX, thiamethoxam+SX, thiocyclam+SX, thiodicarb+SX, thiofanox+SX, thiometon+SX, thiosultap-disodium+SX, thiosultap-monosodium+SX, tigolaner+SX, tiorantr aniliprole) + SX, tioxazafen + SX, tolfenpyrad + SX, tralomethrin + SX, transfluthrin + SX, triazamate + SX, triazophos + SX, trichlorfon + SX, trifluenfuronate + SX, trifl umezopyrim + SX, triflumuron + SX, trimethacar b + SX, tyclopyrazoflor + SX, umifoxolaner + SX, vamidothion + SX, wood extract of Quassia amara + SX, XMC (3,5-dimethylphenyl N-methylcarbamate, 3,5-dimethylphenyl N-methylcarbamate) thylcarbamate)+SX, xylylcarb+SX, zeta-cypermethrinpermethrin) + SX, zinc phosphide + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietane-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propanamide (1118626-57-5) + SX, N-{4-chloro-3-[(1-cyanocyclopentyl)phenyl]-2-methyl-N-(1-oxothietane-3-yl)benzamide 1-methyl-4-(methylsulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methylsulfonyl)propionamide (2396747-83-2) + SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-(methylsulfonyl)propionamide + SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazole alkane-3,5-dione (2171099-09-3) + SX, 2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX, 7-fluoro-N-[1-(methylsulfanyl)-2-methylpropane-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfanyl)-2-methylpropane-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-Fluoro-N-[1-(methylsulfonyl)-2-methylpropane-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide+SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide+SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one (2607927-97-7)+SX,

[0376] BT crop protein Cry1Ab(BT crop protein Cry1Ab)+SX、BT crop protein Cry1Ac(BT crop protein Cry1Ac)+SX、BT crop protein Cry1Fa(BT crop protein Cry1Fa)+SX、BT crop protein Cry1A.105(BT crop protein Cry1A.105)+SX、BT crop protein Cry2Ab(BTcrop protein Cry2Ab)+SX、BT crop protein Vip3A(BT crop protein Vip3A)+SX、BT crop protein mCry3A(BT crop protein mCry3A)+SX、BT crop protein Cry3Ab(BT crop protein Cry3Ab)+SX、BT crop protein Cry3Bb(BT crop protein Cry3Bb)+SX、BT crop protein Cry34Ab1 / Cry35Ab1(BT crop protein Cry34Ab1 / Cry35Ab1)+SX, Adoxophyes orana GV (granulovirus) strain BV-0001+SX, Anticarsia gemmatalis MNPV (multiple nucleocapsidnucleopolyhedrovirus)+SX, Autographa californica MNPV+SX, Cydia pomonella GV strain V15+SX, Cydia pomonella GV strain V22+SX, Cryptophlebia leucotreta GV+SX, Dendrolimus cytoplasmic polyhedrosis virus punctatuscypovirus)+SX, Helicoverpa armigera NPV (nucleopolyhedrovirus) strain BV-0003)+SX, Helicoverpa zeaNPV+SX, Lymantria disparSX, Mamestra brassicae NPV+SX, Mamestra configurata NPV+SX, Neodiprion abietis NPV+SX, Neodiprion lecontei NPV+SX, Neodiprion sertifer NPV+SX, Nosema locustae+SX, Orgyia pseudotsugata NPV+SX, Pieris rapae GV+SX, Plodia interpunctella GV+SX, Spodoptera exigua NPV+SX, MNPV)+SX, Spodoptera littoralis MNPV+SX, Spodoptera litura NPV+SX, Arthrobotrys dactyloides+SX, Bacillus firmus strain GB-126+SX, Bacillus firmus strain I-1582+SX, Bacillus firmus strain NCIM2637+SX, Bacillus megaterium+SX, Bacillus sp. strain AQ175+SX, Bacillus sp. strain AQ177+SX, sp. strain AQ177) + SX, Bacillus sp. strain AQ178 + SX, Bacillus sphaericus strain 2362 serotype H5a5b + SX, Bacillus sphaericus strain ABTS1743 + SX, Bacillus thuringiensis strain AQ52 + SX,AQ52)+SX, Bacillus thuringiensis strain BD#32+SX, Bacillus thuringiensis strain CR-371+SX, Bacillus thuringiensis subsp. Aizawai strain ABTS-1857+SX, Bacillus thuringiensis subsp. Aizawai strain AM65-52+SX, Bacillus thuringiensis subsp. Aizawai strain GC-91+SX, Bacillus thuringiensis subsp. Aizawai strain GC-91+SX, Bacillus thuringiensis subsp. Aizawai NB200+SX, strainNB200)+SX, Bacillus thuringiensis subsp.Aizawai Serotype strain H-7+SX, Bacillus thuringiensis subsp.Kurstaki strain ABTS351+SX, Bacillus thuringiensis subsp.Kurstaki strain BMP123+SX, Bacillus thuringiensis subsp.Kurstaki strain CCT1306+SX, Bacillus thuringiensis subsp.Kurstaki strain EG2348+SX, Bacillus thuringiensis subsp.Kurstaki strain EG2348)+SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841 (Bacillus thuringiensis subsp. Kurstaki strain EG7841)+SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19 (Bacillus thuringiensis subsp. Kurstakistrain EVB113-19)+SX, Bacillus thuringiensis subsp. Kurstaki strain F810+SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1+SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1+SX, Bacillus thuringiensis subsp. Kurstaki strain PB54+SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11+SX, Bacillus thuringiensis subsp. Kurstaki strain SA-12+SX, Bacillus thuringiensis subsp. Kurstaki strain SA-12+SX, Bacillus thuringiensis Tenebriosis NB176+SX thuringiensis subsp. Tenebriosis strain NB176)+SX, Bacillus thuringiensis subsp. Thuringiensis strain MPPL002+SX, Bacillus thuringiensis subsp. morrisoni+SX, Bacillus thuringiensis var. colmeri+SX, Bacillus thuringiensis var. darmstadiensis strain 24-91+SX, Bacillus thuringiensis var. dendrolimus+SX, Bacillus thuringiensis wax moth variant+SX. var. galleriae)+SX, Bacillus thuringiensis var. israelensis strain BMP144)+SX, Bacillus thuringiensis var. israelensis serotype H-14serotype strain H-14)+SX, Bacillus thuringiensis var.japonensis strainbuibui)+SX, Bacillus thuringiensis var.sandiego strain M-7+SX, Bacillus thuringiensis var.7216+SX, Bacillus thuringiensis var.aegypti+SX, Bacillus thuringiensis var.T36+SX, Beauveria bassiana ANT-03+SX, Beauveria bassiana ATCC74040+SX. strain ATCC74040)+SX, Beauveria bassiana strain GHA+SX, Beauveria brongniartii+SX, new heat-killed bacteria A396 strain (Burkholderia rinojensis strain A396)+SX, active purple bacteria PRAA4-1T strain (Chromobacterium subtsugae strain PRAA4-1T)+SX, Dactyllela ellipsospora+SX, Dectylaria thaumasia+SX, Hirsutella minnesotensis+SX, Hirsutella rhossiliensis+SX, Hirsutella thompsonii+SX, Lagenidium giganteum+SX, Lecanicillium lecanii strain KV01 KV01)+SX, conidia of Lecanicillium lecanii strain DAOM198499+SX, conidia of Lecanicillium lecanii strain DAOM216596DAOM216596)+SX, Lecanicillium muscarium strain Ve6+SX, Metarhizium anisopliae strain F52+SX, Metarhizium anisopliae var. acridum+SX, Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52+SX, Metarhizium flavoviride+SX, Monacrosporium phymatopagum+SX, Paecilomyces fumosoroseus Apopka strain 97+SX, Paecilomyces lilacinus strain 251)+SX, Paecilomyces tenuipes strain T1+SX, Paenibacillus popilliae+SX, Pasteuria nishizawaestrain Pn1+SX, Pasteuria penetrans+SX, Pasteuria usgae+SX, Pasteuria thornei+SX, Serratia entomophila+SX, Verticillium chlamydosporium+SX, Verticillium lecani strain NCIM1312+SX, Wolbachia pipientis+SX.

[0377] Combination of the present component of the above group (b) with the compound of the present invention:

[0378] acibenzolar-S-methyl + SX, ald imorph + SX, ametoctradin + SX, aminopyrifen + SX, amisulbrom + SX, anilazine + SX, azaconazole + SX, azoxystrobin + SX, basic copper sulfate sulfate + SX, benalaxyl + SX, benalaxyl-M + SX, benodanil + SX, benomyl + SX, benthiavalicarb + SX, benthiavalicarb-isopropyl + SX, benzovindiflupyr + SX, binapacryl + SX, biphenyl + SX, bitertanol + SX, bixafen + SX, blasticidin-S + SX, Bordeaux mixture + SX, boscalid + SX, bromothalonil + SX, bromuconazole + SX, bupirimat e)+SX, captafol+SX, captan+SX, carbendazim+SX, carboxin+SX, carpropamide+SX, chinomethionat+SX, chitin+SX, chloroinconazide+SX, chloroneb+SX, chlorothalonil+SX, chlozolinate+SX, colletochlorin B+SX, copper(II) acetate+SX, copper(II) hydroxide+SX, copperoxychloride+SX, copper(II) sulfate+SX, coumoxysporintrobin + SX, cyazofamid + SX, cyflufenamid + SX, cymoxanil + SX, cyproconazole + SX, cyprodinil + SX, dichlobentiazox + SX, dichlofluanid + SX, diclocymet + SX, diclomezine + SX, dicloran + SX, diethofencarb + SX, difenoconazole + SX, diflumetorim + SX, dimet hachlone + SX, dimethirimol + SX, dimethomo rph)+SX, dimoxystrobin+SX, diniconazole+SX, diniconazole-M+SX, dinocap+SX, dipotassium hydrogenphosphite+SX, dipymetitrone+SX, dithianon+SX, dodecylbenzenesulphonic acid bisethylenediamine copper(II) salt+SX, dodemorph+SX, dodine+SX, edifenphos+SX, enoxastrobin+SX, epoxiconazole iconazole + SX, etaconazole + SX, ethaboxam + SX, ethirimol + SX, etridiazole + SX, garlic extract + SX, extract of thecotyledons of lupine plantlets ("BLAD") + SX, extract of Equisetum arvense + SX, extract of Melaleuca alternifolia + SX, extract of Reynoutria cuspidatum + SX,sachalinensis + SX, extract of Tropaeolummajus + SX, famoxadone + SX, fenamidone + SX, fenaminstrobin + SX, fenarimol + SX, fenbuconazole + SX, fenfuram + SX, fenhexamid + SX, fenoxanil + SX, fenpiclonil + SX, fenpicoxamid + SX, fenpropidin + SX, fenpropimorph + SX, fenpyrazamine + SX, fentin acetate + SX, fentin chloride + SX, and fentin hydroxide. hydroxide)+SX, ferbam+SX, ferimzone+SX, florylpicoxamid+SX, fluazinam+SX, flubeneteram+SX, fludioxonil+SX, flufen oxadiazam+SX, flufenoxystrobin+SX, flu indapyr)+SX, flumetylsulforim+SX, flumorph+SX, fluopicolide+SX, fluopyram+SX, fluopimomide+SX, fluoroimide+SX, fluoxapiprolin+SX, fluoxastrobin+SX, fluoxytioconazole+SX, fluquinconazole+SX, flusilazole+SX, flusulfamide+SX, flutianil+SX, fluto lanil+SX, flutriafol+SX, fluxapyroxad+SX, folpet+SX, fosetyl+SX, fosetyl-aluminumuminium) + SX, furidazole + SX, furalaxyl + SX, furametpyr + SX, guazatine + SX, hexaconazole + SX, hymexazole + SX, imazalil + SX, imibenconazole + SX, iminoctadine + SX, iminoctadine triacetate + SX, inpyrf luxam + SX, iodocarb + SX, ipc onazole)+SX, ipfentrifluconazole+SX, ipflufenoquin+SX, iprobenfos+SX, iprodione+SX, iprovalicarb+SX, isofetamid+SX, isofluxuram+SX, isoprothiolane+SX, isopyrazam+SX, isotianil+SX,

[0379] Kasugamycin + SX, kresoxim-methyl + SX, laminarin + SX, leaves and bark of oak Quercus+SX, mancozeb+SX, mandestrobin+SX, mandipropamid+SX, maneb+SX, mefentrifluconazole+SX, mepanipyrim+SX, mepronil+SX, meptyldinocap+SX, metalaxyl+SX, metalaxyl-M+SX, metaylpicoxamid+SX, metconazole+SX, methasulfocarb+SX, metiram+SX, metominostrobin+SX, metrafenone+SX, metyltetraprole+SX, myclobutanil+SX, naftifine ine+SX, nuarimol+SX, octhilinone+SX, ofurace+SX, orysastrobin+SX, oxadixyl+SX, oxathiapiprolin+SX, oxine-copper+SX, oxolinic acid+SX, oxpoconazole+SX, oxpoconazole fumarate+SX, oxycarboxin+SX, oxytetracycline+SX, pefurazolin ate)+SX, penconazole+SX, pencycuron+SX, penflufen+SX, penthiopyrad+SX, phenamacril+SX, phosphorous acid+SX, phthalide+SX, picarbutrazox+SX, picoxystrobinstrobin + SX, piperalin + SX, polyoxins + SX, potassium hydrogencarbonate + SX, potassium dihydrogenphosphite + SX, probenazole + SX, prochloraz + SX, procymidone + SX, propamidine + SX, propamocarb + SX, propiconazole + SX, ole+SX, propineb+SX, proquinazid+SX, prothiocarb+SX, prothioconazole+SX, pydiflumetofen+SX, pyraclostrobin+SX, pyrametostrobin+SX, pyraoxystrobin+SX, pyrapropoyne+SX, pyraziflumid+SX, pyrazophos+SX, pyribencarb+SX, pyributicarb+SX, pyridachlometyl+SX, pyrifenox+SX, pyrim ethanil+SX, pyrimorph+SX, pyriofenon e)+SX, pyrisoxazole+SX, pyroquilon+SX, Quillaja extract+SX, quinconazole+SX, quinofumelin+SX, quinoxyfen+SX, quintozene+SX, Saponins of ChenopodiumSX, sedaxane + SX, silthiofam + SX, simeconazole + SX, sodium hydrogen carbonate + SX, spiroxamine + SX, streptomycin + SX, sulfur + SX, tebuconazole + SX, tebufloquin + SX, teclofthalam + SX, tecnazene + SX, terbinafine + SX, tetraconazole + SX, thiabendazole + SX, thifluzamide + SX, thiophanate + SX, thiophanate-methyl hyl)+SX, thiram+SX, thymol+SX, tiadinil+SX, tolclofos-methyl+SX, tolfenpyrad+SX, tolprocarb+SX, tolylfluanid+SX, triadimefon+SX, triadimenol+SX, triazoxide+SX, triclopyricarb+SX, tricyclazole+SX, tridemorph+SX, trifloxystrobin+SX bin)+SX, triflumizole+SX, triforine+SX, triticonazole+SX, validamycin+SX, valifenalate+SX, vinclozolin+SX, yellow mustard powder+SX, zinc thiazole+SX, zineb+SX, ziram+SX, zoxamide+SX,

[0380] N'-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylformamidine (1202781-91-6) + SX, N'-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylformamidine (929908-57-6) + SX, N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylformamidine (1052688-31-9) + SX, N'-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N- Methylformamidine (2055589-28-9) + SX, N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylformamidine (2055756-21-1) + SX, N'-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylformamidine (2062599-39-5) + SX, N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl]-N-isopropyl-N-methylformamidine (2101814-55-3) + SX, N'-[5-bromo-6-(1-methyl-2-propoxyethoxy)-2

[0381] -methylpyridin-3-yl]-N-ethyl-N-methylformamidine (1817828-69-5) + SX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine (1362477

[0382] -26-6) + SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) + SX, (2Z)-3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) + SX, (1R, 2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol(1801930-06-2)+SX, (1S,2R,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol(1801930-07-3)+SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol(1394057-13-6)+SX, (1R,2 S,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-08-4) + SX, (1S,2R,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5) + SX, methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (1791398-02-1) + SX, 1- (2,4-Difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol(2019215-86-0)+SX、1-(2,4-Difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6-difluorophenoxy)cyclopropyl]ethanol(2019215-84-8)+SX、1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile(2018316-13-5)+SX、1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018317-25-2) + SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082661-43-4) + SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) + SX, methyl ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879- 98-8) + SX, 2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-21-4) + SX, 2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9) + SX, 2-(difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2) + SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyphenyl)-1H-pyrazol-3-yl]oxy}-1H-pyrazol-4-yl 4-(2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methylpyrimidine (1605340-92-8) + SX, N-(1-benzyl-1,3-dimethylbutyl)-8-fluoroquinoline-3-carboxamide (2132414-04-9) + SX, N-(1-benzyl-3,3,3-trifluoro-1-methylpropyl)- 8-Fluoroquinoline-3-carboxamide (2132414-00-5) + SX, 4,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolin-3-one (2098918-25-1) + SX, 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolin-3-one (2098918-26-2) + SX, N-ethyl-2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide + SX, N,2-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide4-oxadiazol-3-yl]phenyl}methyl)propionamide+SX, N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide+SX, N-methoxy-N'-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, N'-ethyl-N-methoxy-N-({4-[5 -(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, N,N'-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, N-acetyl-2-(ethylsulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoromethyl)benzamide (2043675-2 8-9) + SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(4-bromo-7-fluoroindol-1-yl)butan-2-yl ester + SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(7-bromoindol-1-yl)butan-2-yl ester + SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(7-bromo-4-fluoroindol-1-yl)butan-2-yl ester + SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(3,5-dichloropyridin-2-yl)butan-2-yl ester + SX, N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alanine 3-(3,5-dichloropyridin-2-yl)butan-2-yl ester + SX,

[0383] N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-aceto 1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate) + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)acetamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide + SX, 3,3,3-trifluoro-N-({2-fluoro-4-[5-( 3,3,3-trifluoro-N-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide+SX, 3,3,3-trifluoro-N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide+SX, ) propionamide + SX, N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)butanamide + SX, N-methoxy-N-methyl-N'-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N-diethyl-N'-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, N-methyl-N'-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one+SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one+SX, 4-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)morpholin-3-one+SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolin-3-one ketone + SX, 3,3-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azepan-2-one + SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 5-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol- 3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxylic acid ethyl ester + SX, N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-propyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy 4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide+SX, N,N-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-1,2,4-triazol-3-amine+SX, N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide+SX, methyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propanoate+SX, 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propanoate+SX,4-triazol-1-yl) propionic acid ethyl ester + SX, 2-[2-(trifluoromethyl)-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl) propionic acid methyl ester + SX, 1-(2,3-dimethylpyridin-5-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-[2-(difluoromethyl)-3-methylpyridin-5-yl]-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 2,2-difluoro-N-[6-({[1-(1-methyl-1H-tetrazol-5-yl)benzimidazol-2-yl]oxy}methyl)pyridin-2-yl]-2-phenoxyacetamide + SX , 1-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile + SX, 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylic acid ethyl ester + SX, 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylic acid ethyl ester + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-3 -(3-cyclopropyl-2-fluorophenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3.4]octan-1-yl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2 ,6-difluoropyridin-4-yl)amino]-N-hexyl-5-methylthiazole-4-carboxamide+SX, 2-[acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide+SX, 2-[(2-methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide+SX, 2-[(2-methylpropanoyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide+SX, 2-[(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide+SX,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxetane-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxetane-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX,

[0384] 2-{[(oxan-4-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl) -1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine+SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-3-yl)ethyl]pyrimidin-2-amine+SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine+SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[ 1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine+SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidin-2-amine+SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidine+SX, 3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-difluorophenyl)cyclopropyl] methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, (5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, 3

[0385] -[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, N-((2S)-1

[0386] -{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide+SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide+SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide+SX, yl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide+SX, N-((2S)-1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide+SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide+SX, 1-(2H)-pyridin-1(2H)-yl}propan-2-yl)-2-methylpropanamide+SX, ({5-[1-(2,6-difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate+SX, ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate+SX, ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate+SX, ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate+SX, (Z)-2-(5-cyclopentyl-2-methylphenoxy)-3-methoxy-2-propenoic acid methyl ester+SX, (Z)-2-(5-cyclohexyl-2 -methylphenoxy)-3-methoxy-2-propenoic acid methyl ester + SX, (Z)-2-[(3-isopropyl-1H-pyrazol-1-yl)-2-methylphenoxy]-3-methoxy-2-propenoic acid methyl ester + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-6-fluoro-3,3-dimethylisoquinolin-4(3H)-one+SX, (2Z)-3-methoxy-2-[(4-methyl[1,1'-biphenyl]-3-yl)oxy]-2-propenoic acid methyl ester+SX,

[0387] Agrobacterium radiobactor strain K1026 + SX, Agrobacterium radiobactor strain K84 + SX, Bacillus amyloliquefaciens strain PTA-4838 (Aveo (trademark) EZ Nematicide) + SX, Bacillus amyloliquefaciens strain AT332 + SX, Bacillus amyloliquefaciens strain B3 + SX, Bacillus amyloliquefaciens strain D747 + SX, Bacillus amyloliquefaciens strain DB101 + SX, Bacillus amyloliquefaciens strain DB101)+SX, Bacillus amyloliquefaciens strain DB102+SX, Bacillus amyloliquefaciens strain GB03+SX, Bacillus amyloliquefaciens strain FZB24+SX, Bacillus amyloliquefaciens strain FZB42+SX, Bacillus amyloliquefaciens strain IN937a+SX, Bacillus amyloliquefaciens strain MBI600+SX, Bacillus amyloliquefaciens strain QST713+SX QST713)+SX, Bacillus amyloliquefaciens isolate strain B246+SX, Bacillus amyloliquefaciens F727 strainF727)+SX, Bacillus amyloliquefaciens subsp. plantarum strain D747+SX, Bacillus licheniformis strain HB-2+SX, Bacillus licheniformis strain SB3086+SX, Bacillus pumilus strain AQ717+SX, Bacillus pumilus strain BUF-33+SX, Bacillus pumilus strain GB34+SX, Bacillus pumilus strain QST2808+SX, Bacillus simplex CGF2856+SX, Bacillus pumilus strain BUF-33+SX, Bacillus pumilus strain GB34+SX, Bacillus pumilus strain QST2808+SX, Bacillus simplex CGF2856+SX, Bacillus pumilus strain BUF-33+SX, Bacillus pumilus strain GB34+SX, Bacillus pumilus strain QST2808+SX, Bacillus simplex CGF2856+SX, Bacillus pumilus strain BUF-33+SX, Bacillus pumilus strain GB34+SX, Bacillus pumilus strain QST2808+SX, Bacillus simplex CGF2856+SX, Bacillus pumilus strain BUF-33+SX, Bacillus pumilus strain GB34+SX, Bacillus pumilus strain QST2808+SX, Bacillus simplex CGF2856+SX, Bacillus pumilus strain BUF-33+SX, Bacillus pumilus strain simplexstrain CGF2856)+SX, Bacillus subtilis AQ153 strain+SX, Bacillus subtilis AQ743 strain+SX, Bacillus subtilis BU1814 strain+SX, Bacillus subtilis D747 strain+SX, Bacillus subtilis DB101 strain+SX, Bacillus subtilis FZB24 strain+SX, Bacillus subtilis GB03 strain+SX, Bacillus subtilis HAI0404 strain+SX, Bacillus subtilis strain HAI0404)+SX, Bacillus subtilis strain IAB / BS03+SX, Bacillus subtilis strain MBI600+SX, Bacillus subtilis QST30002 / AQ30002+SX, Bacillus subtilis strainQST30002 / AQ30002)+SX, Bacillus subtilis QST30004 / AQ30004 strain (Bacillus subtilis strain QST30004 / AQ30004)+SX, Bacillus subtilis QST713 strain (Bacillus subtilis strain QST713)+SX, Bacillus subtilis QST714 strain (Bacillus subtilis strain QST714)+SX, Bacillus subtilis var. Amyloliquefaciens strain FZB24 (Bacillus subtilis var. Amyloliquefaciens strain FZB24)+SX, Bacillus subtilis strain Y1336+SX, Burkholderia cepacia+SX, Burkholderia cepacia type Wisconsin strain J82 (Burkholderia cepacia type Wisconsin strain J82)+SX, Burkholderia cepacia type Wisconsin M54+SX, Candida oleophila strain O+SX, Candida saitoana+SX, Chaetomium cupreum+SX, Clonostachys rosea+SX, Coniothyrium minitans strain CGMCC8325+SX, Coniothyrium minitans strain CON / M / 91-8+SX, Cryptococcus albidus+SX, Erwinia carotovora subsp. carotovora strain CGE234M403+SX CGE234M403)+SX, Fusarium oxysporum strain Fo47+SX, Gliocladium catenulatum strain J1446+SX, Paenibacillus polymyxa strain AC-1+SXAC-1)+SX, Paenibacillus polymyxa strain BS-0105+SX, Pantoea agglomerans strain E325+SX, Phlebiopsis gigantea strain VRA1992+SX, Pseudomonas aureofaciens strain TX-1+SX, Pseudomonas chlororaphis strain 63-28+SX, Pseudomonas chlororaphis strain AFS009+SX, Pseudomonas chlororaphis MA342+SX, strain MA342)+SX, Pseudomonas fluorescens strain 1629RS+SX, Pseudomonas fluorescens strain A506+SX, Pseudomonas fluorescens strain CL145A+SX, Pseudomonas fluorescens strain G7090+SX, Pseudomonas sp. strain CAB-02+SX, Pseudomonas syringae strain 742RS+SX, Pseudomonas syringae strain MA-4+SX, Pseudomonas flocculatus PF-A22UL strain + SX, Pseudomonas rhodesia strain HAI-0804 + SX, Pythium oligandrum strain DV74 + SX, Pythium oligandrum strain M1 + SX, Streptomyces griseoviridis strain K61 + SX,K61)+SX, Streptomyces lydicus strain WYCD108US+SX, Streptomyces lydicus strain WYCD108US+SX, Streptomyces lydicus strain WYEC108+SX, Talaromyces flavus strain SAY-Y-94-01+SX, Talaromyces flavus strain V117b+SX, Trichoderma asperellum strain ICC012+SX, Trichoderma asperellum SKT-1+SX, Trichoderma asperellum strain T25+SX, Trichoderma asperellum strain T34+SX, T34)+SX, Trichoderma asperellum strain TV1+SX, Trichoderma atroviride strain CNCM 1-1237+SX, Trichoderma atroviridestrain LC52+SX, Trichoderma atroviridestrain IMI 206040+SX, Trichoderma atroviride strain SC1+SX, Trichoderma atroviride strain SKT-1+SX, Trichoderma atroviride strain T11+SX, Trichoderma gamsii endophyte ICC080+SX strain ICC080)+SX, Trichoderma harzianum strain 21+SX, Trichoderma harzianum strain DB104+SX, Trichoderma harzianum strain DSM 14944+SX14944)+SX, Trichoderma harzianum strain ESALQ-1303+SX, Trichoderma harzianum strain ESALQ-1306+SX, Trichoderma harzianum strain IIHR-Th-2+SX, Trichoderma harzianum strain ITEM908+SX, Trichoderma harzianum kd+SX, Trichoderma harzianum strain MO1+SX, Trichoderma harzianum strain SF+SX, Trichoderma harzianum strain T22+SX, T22)+SX, Trichoderma harzianum strain T39+SX, Trichoderma harzianum strain T78+SX, Trichoderma harzianum strain TH35+SX, Trichoderma polysporum strain IMI206039+SX, Trichoderma astromaticum+SX, Trichoderma virens strain G-41+SX, Trichoderma virens strain GL-21+SX, Trichoderma viride+SX, Variovorax paradoxus strain CGF4526+SX, Harpinprotein+SX.

[0388] Combination of the present component of the above group (c) with the compound of the present invention:

[0389] 1-Methylcyclopropene+SX, 1,3-diphenylurea+SX, 2,3,5-triiodobenzoic acid+SX, IAA((1H-indol-3-yl)acetic acid)+SX, IBA(4-(1H-indol-3-yl)butyric acid)+SX, MCPA(2-(4-chloro-2-methylphenoxy)acetic acid)+SX, MCPB(4-(4-chloro-2-methylphenoxy)butyric acid)+SX, 4-CPA(4-chlorophenoxyacetic acid) acid + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat-chloride + SX, chlorpropham + SX, choline chloridechloride + SX, cloprop + SX, cyanamide + SX, cyclanilide + SX, daminozide + SX, decan-1-ol + SX, dichlorprop + SX, dikegulac + SX, dimethipin + SX, diquat + SX, ethephon + SX, ethychlozate + SX, flumetralin + SX, flurprimidol + SX, forchlorfenuron + SX, formononetin + SX, Gibberellin A A) + SX, Gibberellin A3 + SX, inabenfide + SX, Kinetin + SX, lipochitooligosaccharide SP104 + SX, maleic hydrazide + SX, mefluidide + SX, mepiquat-chloride + SX, oxidized glutathione + SX, paclobutrazol + SX, pendimethalin + SX, prohexadione-calcium + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, sintofen + SX, sodium 1-naphthaleneacetate + SX, sodium cyanate cyanate) + SX, thidiazuron + SX, triapenthenol + SX, tribufos + SX, trinexapac-ethyl + SX, uniconazole-P + SX, 2-(naphthalen-1-yl)acetamide + SX, [4-oxo-4-(2-phenylethyl)amino]butyric acid + SX, 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylic acid methyl ester + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]propan-1-ol + SX, Claroideoglomusetunicatum + SX, Claroideoglomus claroideum + SX, Funneliformis mosseae + SX, Gigaspora margarita + SX, Gigaspora rosea + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus monosporum + SX, Paraglomus brasillianum + SX, Rhizophagus clarus + SX, Rhizophagus intraradices RTI-801 + SX, Rhizophagus irregularis DAOM 197198 strain + SX, Azorhizobium caulinodans + SX, Azospirillum amazonense + SX, Azospirillum brasilense XOH strain + SX, Azospirillum brasilense Ab-V5 strain + SX, Azospirillum brasilense Ab-V6 strain + SX, Azospirillum caulinodans + SX, Azospirillumhalopraeferens + SX, Azospirillum irakense + SX, Azospirillum lipoferum + SX, Bradyrhizobium elkanii SEMIA 587 strain + SX, Bradyrhizobium elkanii SEMIA 5019 strain + SX, Bradyrhizobium japonicum TA-11 strain + SX, Bradyrhizobium USDA 110 strain + SX, Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Delftia acidovorans RAY209 strain + SX, Mesorhizobium ciceri + SX, Mesorhizobium huaguihuakii)+SX, Mesorhizobium loti+SX, Rhizobium etli+SX, Rhizobium galegae+SX, Rhizobium leguminosarum bv.Phaseoli+SX, Rhizobium leguminosarum bv.Trifolii+SX, Rhizobium leguminosarum bv.Viciae+SX, Rhizobium trifolii+SX, Rhizobium tropici+SX, Sinorhizobium fredii+SX, Sinorhizobium truncatula meliloti)+SX, Zucchini Yellow Mosaik Virus weak strain+SX.

[0390] Combination of the present component of the above group (d) with the compound of the present invention:

[0391] Anthraquinone + SX, DEET + SX, Icaridin + SX.

[0392] The ratio of the compound of the present invention to the present component is not particularly limited, and examples thereof include 1000:1 to 1:1000, 500:1 to 1:500, 100:1 to 1:100, 50:1, 20:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, and 1:50 in terms of weight ratio (compound of the present invention:present component).

[0393] The compound of the present invention is effective against harmful arthropods such as harmful insects and harmful mites, harmful nematodes, and harmful mollusks. Examples of harmful arthropods, harmful nematodes, and harmful mollusks include the following.

[0394] Hemiptera: Laodelphax striatellus, Nilaparvatalugens, Sogatella furcifera, Peregrinus maidis, Javesella pellucida, Perkinsiella saccharicida, Tagosodesorizicolus, Stenocranus pacificus, etc. Delphacidae; Nephotettix cincticeps, Nephotettix virescens, Nephotettix nigropictus, Recilia dorsalis, Empoasca onukii, Empoasca fabae, Dalbulus spp. maidis), white-winged brown-veined leafhopper (Cofanaspectra), two-spotted green leafhopper (Amrasca biguttula biguttula), etc.; Aphrophoridae (Aphrophoridae) (Philaenus spumarius), etc.; Cercopidae (Mahanarvaposticata), sugarcane leafhopper (Mahanarva fimbriolata), etc.;Beet aphid (Aphisfabae), soybean aphid (Aphis glycines), cotton aphid (Aphis gossypii), apple aphid (Aphis pomi), spiraea aphid (Aphis spiraecola), peach aphid (Myzus persicae), plum short-tailed aphid (Brachycaudus helichrysi), cabbage aphid (Brevicoryne brassicae), rose apple aphid (Dysaphis plantaginea), cabbage stalked aphid (Lipaphis erysimi), potato long-tailed aphid (Macrosiphum euphorbiae), eggplant ditch aphid (Aulacorthum solani), lettuce aphid (Nasonovia ribisnigri), cereal stalked aphid (Rhopalosiphumpadi), corn aphid (Rhopalosiphum maidis), citrus aphid (Toxoptera citricida), peach pink aphid (Hyalopterus pruni), sorghum aphid (Melanaphis sacchari), Tetraneuranigriabdominalis, Ceratovacuna lanigera, Eriosomalanigerum, Sitobion avenae, and other Aphididae; Daktulosphaira vitifoliae, Phylloxera devastatrix, Phylloxera notabilis, Phylloxera russelae, and other Phylloxeridae; Adelgidae, Adelges tsugae, Adelges piceae, and Aphrastasia pectinatae;Pentatomidae, including the black rice stink bug (Scotinophara lurida), the Malayan black rice stink bug (Scotinophara coarctata), the black-bearded rice stink bug (Nezara antennata), the northern two-star stink bug (Eysarcoris aeneus), the large-spined white-star stink bug (Eysarcoris lewisi), the broad two-star stink bug (Eysarcoris ventralis), the pseudo two-star stink bug (Eysarcoris annamita), the brown-winged stink bug (Halyomorpha halys), the green rice stink bug (Nezara viridula), the brown stink bug (Euschistus heros), the red-banded stink bug (Piezodorus guildinii), the rice stink bug (Oebalus pugnax), the stink bug (Dichelops melacanthus), the wall stink bug (Piezodorus hybneri); the digging brown stink bug (Scaptocoris castanea) and other Cydnidae; Alydidae such as Riptortus clavatus, Leptocorisa chinensis, and Leptocorisa acuta; Coreidae such as Cletus punctiger and Leptoglossus australis; Lygaeidae such as Cavelerius saccharivorus, Togohemipterus, and Blissus leucopterus; Trigonotylus caelestialium, Stenotus rubrovittatus, and Stenodema calcarata), American meadow bug (Lygus lineolaris), and other Miridae; Trialeurodes vaporariorum (Househouse whitefly), Bemisia tabaci (Bemisia tabaci), Dialeurodes citri (Citrus whitefly), Aleurocanthus spiniferus (Blackthorn whitefly), Aleurocanthus camelliae (Camellia whitefly), and Pealius euryae (Whitefly);Tea long round scale (Abgrallaspis cyanophylli), red round scale (Aonidiella aurantii), pear round scale (Diaspidiotusperniciosus), mulberry white scale (Pseudaulacaspis pentagona), arrow-pointed shield scale (Unaspis yanonensis), citrus sharp shield scale (Unaspis citri) and other shield scale families (Diaspididae); red wax scale (Ceroplastes rubens) and other scale families (Coccidae); blowing cotton scale (Icerya purchasi), silver-haired blowing cotton scale (Icerya seychellarum) and other cotton scale families (Margarodidae); Lycoris mealybug (Phenacoccus solani), hibiscus mealybug (Phenacoccussolenopsis), Japanese hip-striped mealybug (Planococcus Pseudococcidae, including Pseudococcus kraunhiae, Pseudococcus comstocki, Planococcus citri, Pseudococcus calceolariae, Pseudococcus longispinus, and Brevennia rehi; Psyllidae, including Diaphorina citri, Trioza erytreae, Cacopsylla pyrisuga, Cacopsylla chinensis, Bactericera cockerelli, and Cacopsylla pyricola; and Corythucha ciliata, Corythucha chrysanthemum. marmorata), Stephanitis nashi, and Stephanitis pyrioides, among others; Cimicidae, including Cimex lectularius and Cimex hemipterus; and Cicadidae, including Quesada gigas.Triatoma infestans, Triatoma rubrofasciata, Triatoma dimidiata, Rhodonius prolixus, and other members of the Reduviidae family.

[0395] Lepidoptera: Chilo suppressalis, Chilopolychrysus, Scirpophaga innotata, Scirpophaga incertulas, Rupela albina, Cnaphalocrocis medinalis, Marasmia patnalis, Marasmia exigua, Notarcha derogata, Ostrinia furnacalis, Ostrinia nubilalis, Hellulaundalis, Herpetogramma luctuosale, Parapedia siateterrellus, Nymphula depun ctalis), sugarcane borer (Diatraea saccharalis), eggplant yellow moth (Leucinodes orb onalis), and other grass borers (Crambidae); small corn borer (Elasmopalpus lignosellus), Indian grain moth (Plodia interpunctella), leather dark moth (Euzophera batangensis), powdery moth (Cadra cautella), and other moths (Pyralidae);Spodoptera litura, Spodoptera exigua, Mythimna separata, Mamestra brassicae, Sesamia inferens, Spodoptera mauritia, Nara nga aenescens, Spodoptera frugiperda, Spodoptera exempta, Spodoptera cosmioides, Spodoptera eridania, Agrotis ipsilon, Agrotis segetum, Autographanigrisigna, Plusia festucae, Chrysodeixis includens, Trichoplusia spp., Heliothis spp. virescens, Heliothis spp., Helicoverpa armigera, Helicoverpa zea, Anticarsia gemmatalis, Alabamaargillacea, Hydraecia immanis, and other Noctuidae species; and Pieridae such as Pieris rapae.Pear borer (Grapholita molesta), sand apple borer (Grapholita dimorpha), soybean borer (Leguminivora glycinivorella), Japanese bean moth (Matsumuraeses azukivora), apple leaf roller (Adoxophyesorana fasciata), tea leaf roller (Adoxophyes honmai), tea long leaf roller (Homona magnanima), apple yellow leaf roller (Archips fuscocupreanus), apple leaf roller (Cydia pomonella), yellow stem borer (Tetramoera schistaceana), bean shot borer (Epinotia aporema), citrus fruit fly (Citripestis sagittiferella), grape flower winged leaf roller (Lobesia botrana), etc. (Tortricidae); tea leaf roller (Caloptilia theivora), golden leaf roller (Phyllonorycter ringoniella, etc.; Carposinidae, etc.; Lyonetiidae, etc., such as Leucopteracoffeella, Lyonetia clerkella, and Lyonetia prunifoliella; Lymantriidae, etc., such as Lymantria spp., such as Lymantria dispar, and Euproctis spp., such as Euproctis pseudoconspersa; Plutellidae, etc., such as Plutella xylostella; Anarsialineatella, Helcystogramma triannulella), red bell moth (Pectinophoragossypiella), potato moth (Phthorimaea opercule lla), tomato moth (Tutaabsoluta) and other moths of the family Gelechiidae; American white moth (Hyphantria cunea) and other moths of the family Arctiidae;Castniidae, such as the sugarcane borer (Telchin licus); Cossidae, such as the aromatic wood borer (Cossus insularis); Geomet ridae, such as the bridge-building moth (Ascotis selenaria); Limacodidae, such as the beautiful green moth (Parasalepida); Stathmopodidae, such as the persimmon moth (Stathmopoda masinissa); Sphingidae, such as the ghost-faced hawkmoth (Acherontia lachesis); Sesiidae, such as the Nokonaferalis, apple clearwing moth (Synanthedon hector), and jade clearwing moth (Synanthedon tenuis); Hesperiidae, such as the straight-striped rice butterfly (Parnara guttata); clothes moth (Tinea translucens), Tineola bisselliell a, etc.

[0396] Thysanoptera: Thripidae, including Frankliniella occidentalis, Thrips palmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, Sten chaetothrips biformis, Echinothrips americanus, and Scirtothrips perseae; and Phlaeothripidae, including Haplothrips aculeatus.

[0397] Diptera: Anthomyiidae, such as Delia platura, Del ia antiqua, and Pegomya cunicularia; Ulidiidae, such as Tetanops myopaeformis; Agromyzidae, such as Agromyza oryzae, Liriomyza sativae, Liriomyza trifolii, and Chromatomyia horti cola; Chloropidae, such as Chlorops oryzae; Bactrocera cucurbitae, Bactrocera dorsalis, Bactrocera latifrons, and Bactrocera serrata. oleae), Bactroceratryoni, Ceratitis capitata, Rhagoletis pomonella, Rhacochlaena japonica, etc.; Ephydridae, Hydrellia philippina, Hydrelliasasakii, etc.; Drosophilidae, Drosophila suzukii, Drosophila melanogaster, etc.; Phoridae, Megaseliaspiracularis, etc.; Psychodidae, Clogmia albipunctata, etc.; Bradysia sutchusii, etc. difformis), Bradysia odoriphaga, and other Sciaridae; Mayetiola destructor, Orseolia oryzae, and other Cecidomyiidae; Diopsidae, Diopsis macrophthalma, and other Protrusive-eye Flies;Glossinidae, including the Central African tsetse fly (Glossina palpalis) and the stinging tsetse fly (Glossina morsitans); Simuliidae, including the Japanese gnat (Simulium japonicum) and the hate gnat (Simulium damnosum); Phlebotominae; Tipulidae, including the rice crane fly (Tipula aino), the common crane fly (Tipula oleracea), and the European crane fly (Tipula paludosa); Culex pallens, Culex tritaeniorhynchus, Culex pipiens f. molestus, Culex quinquefasciatus, Culex pipiens pipiens, Culex vishnui, and Aedes albopictus. albopictus), Aedes aegypti, Anopheles sinensis, Anopheles gambiae, Anopheles stephensi, Anopheles coluzzii, Anopheles albiimanus, Anopheles sundaicus, Anopheles arabiensis, Anopheles funestus, Anopheles darlingi, Anopheles farauti, Anopheles minimus, etc.; Simulidae, such as Prosimulium yezoensis and Simulium ornatum; Tabanidae, such as Tabanus trigonus; Housefly, such as Musca domestica. domestica), Muscina stabulans, Stomoxyscalcitrans, Haema tobia irritans, etc., Muscidae; Calliphoridae; Sarcophagidae;Chironomus plumosus, Chironomus yoshimatsui, Glyptotendipes tokuna gai, etc., belonging to the Chironomidae family; Fannidae family.

[0398] Coleoptera: Diabrotica spp. (e.g., Diabrotica virgifera virgifera, Diabrotica undecimpunctata howardi, Diabrotica barberi, Diabrotica virgiferazeae, Diabrotica balteata, Diabrotica specios a), Cerotoma trifurcata, Oulema melanopus, Aulacophora femoralis, Phyllotreta striolata, Phyllotreta cruciferae, Phyllotreta pusilla, Psylliodes rapa chrysocephala), Psylliodes punctulata, Leptinotarsa ​​decemlineata, Oulema oryzae, Colaspis brunnea, Chaetocnema pulicaria, Chaetocnema confinis, Epitrix cucumeris, Dicladispa armige ra, Myochrous denticollis, Lacc optera quadrimaculata, Epitrix hirtipennis, Phaedon brassicae, Medythianigrobilineata, etc.; Seedcorn beetle (Stenolophus stenolophus) lecontei), corn seed beetle (Clivina impressifrons), etc. Carabidae;Scarabaeidae species such as the bronze beetle (Anomala cuprea), the multicolored beetle (Anomala rufocuprea), the small bronze beetle (Anomala albopilosa), the Japanese beetle (Popillia japonica), the bean beetle (Heptophylla picea), the European beetle (Rhizotrogus majalis), the black beetle (Tomarus gibbosus), the tooth-clawed beetle (Holotrichia spp.), the June beetle (Phyllophaga crinita), the Argentine beetle (Diloboderus abderus), the Argentine beetle (Diloboderus spp.), and other Argentine beetles (Diloboderus spp.); the long-horned beetle (Anthriibidae) such as the coffee bee weevil (Araecerus coffeae); the Aponidae such as the sweet potato ant weevil (Cylas formicarius); the Brazilian bean weevil (Zabrotes subfasciatus) and other Bruchidae; Scolytidae, including Tomicus piniperda and Hypothenemus hampei;West Indian sweet potato weevil (Euscepes postfasciatus), alfalfa leaf weevil (Hyperapostica), corn weevil (Sitophilus zeamais), rice weevil (Sitophilus oryzae), corn weevil (Si tophilus granarius), rice weevil (Echinocnemus squameus), rice water weevil (Li ssorhoptrus oryzophilus), palm weevil (Rhabdoscelus lineaticollis), cotton boll weevil (Anthonomus grandis), parasitic corn weevil (Sphenophorus venatus), southern corn long-beak weevil (Sphenophorus callosus), soybean stem weevil (Sternechus subsignatus), sugarcane weevil (Sphenophorus levis), cucurbit rust weevil (Scepticus griseus), Scepticus uniformis, Aracanthus mourei, etc. Aracanthus spp., cotton root borer (Eutinobothrus brasiliensis; Tenebrionidae, such as Tribolium castaneum, Tribolium confusum, and Alphitobius diaperinus; Coccinellidae, such as Epilachna vigintioctopunctata; Bostrychidae, such as Lyctus brunneus and Rhizo pertha dominica; Ptinidae; Cerambycidae, such as Anoplophora malasiaca, Migdolus fryanus, and Aromia bungii;Elateridae, including Melanotus okinawensis, Agriotes fuscicollis, Melanotus legatus, Anchastus spp., Conoderus spp., Ctenicera spp., Limonius spp., and Aeolus spp.; Staphylinidae, including Paederus fuscipes; Dermestidae, including Anthrenus verbasci, Dermestes maculates, and Trogodermagranarium; and Lasioderma serricorne), Stegobium paniceum, and other Anobiidae; Cryptolestes ferrugineus and other Lae mophloeidae; Oryzaephilus surinamensis and other Suriname saw-toothed beetles; Brassicogethes aeneus and other Nitidulidae.

[0399] Orthoptera: Migratory locust (Locusta migratoria), Moroccan halberd locust (Dociostaurus maroccanus), Australian plague locust (Chortoicetes termin ifera), Red-winged locust (Nomadacris septemfasciata), Brown migratory locust (Locustana pardalina), Tree locust (Anacridium melanorhodon), Italian locust (Calliptamus italicus), Long-fronted locust (Melanoplus differentialis), Two-banded grasshopper (Melanoplus bivittatus), Migrant grasshopper (Melanoplus sanguinipes), Red-legged grasshopper (Melanoplus femurrubrum), Clear-winged earth locust (Camnula pellucida), Desert locust (Schistocerca gregaria), Yellow-winged locust (Gastrimargus musicus), Spur-throated locust (Austracris guttulosa), Small-winged rice grasshopper (Oxya The following are some of the family members of the Acrididae family: the Japanese rice locust (Oxya japonica), the Indian yellow-backed locust (Patanga succincta), the African mole cricket (Gryllota lpa orientalis), the Gryllidae family: the house cricket (Acheta domesti ca), the yellow-faced oil gourd (Teleogryllusemma), and the Tettigoniidae family: the Mormon cricket (Anabrus simplex).

[0400] Hymenoptera: Tenthredinidae, including Athalia rosae and Athalia japonica; Solenopsis spp., including Solenopsis invicta and Solenopsis geminata; Atta spp., including Brown leaf-cutting ants (Attacapiguara); Acromyrmex spp.; Paraponera clavata; Ochetellus glaber; Monomoriumpharaonis; Linepithema humile; Formica japonica; Pristomyrmex punctutus; Pheidole spp. noda), Pheidolemegacephala, Camponotus japonicus, Camponotus obscuripes, Pogonomyrmex spp., Pogonomyrmex ex occidentalis, Wasmania spp., Ano plolepis gracilipes, and other species of Formicidae; Vespidae, including the Asian giant hornet (Vespa mandarinia), Vespa simillima, Vespa analis, Vespavelutina, and Polistes jokahamae; Urocerus occidentalis, Pogonomyrmex spp., Wasmania spp., and other species of the same family; gigas) and other tree wasps (Siricidae); Bethylidae.

[0401] Blattodea: German cockroach (Blattella germanica), Ectobiidae; Black-breasted cockroach (Periplaneta fuliginosa), American cockroach (Periplaneta americana), Australian cockroach (Periplaneta australasiae), Brown-spotted cockroach (Periplaneta brunnea), Oriental cockroach (Blattaorientalis), Blattidae; Northern termite (Reticulitermes speratus), Taiwanese white-spotted termite (Coptotermes formosanus), Small termite (Incisitermes minor), Cut-headed sand termite (Cryptotermes domesticus), Black-winged soil termite (Odontotermes formosanus), Hengchun new termite (Neotermes koshunensis), Red tree termite (Glyptoter mes Termites include the Termitidae, such as the white-necked termite (Glyptotermes satsumensis), the Nakajima termite (Glyptotermes nakajimai), the black tree termite (Glyptotermes fuscus), the forest termite (Hodotermopsis sjostedti), the Guangdong termite (Coptotermes guangzhouensis), the yellow-limbed reticulite (Reticulite rmes amamianus), the Amami termite (Reticulitermes miyatakei), the closed-door reticulite (Reticulitermes kanmonensis), the high mountain elephant termite (Nasutitermes tak asagoensis), the Nitobe near-twisted termite (Pericapritermes nitobei), the Taiwan termite (Sinocapritermes mushae), and the corner termite (Cornitermes cumulans).

[0402] Order Siphonaptera: Pulex irritans, Ctenocephalides felis, Ctenocephalides canis, Xenopsylla cheopis, Echidnophaga gallinacea, etc., including the human flea family (Pulicidae); Tunga penetrans, etc., including the Hectopsyllidae; Nosopsyllus fasciatus, etc., including the European rat flea family (Ceratophyllidae).

[0403] Psocodae: Pediculidae such as human head louse (Pediculus humanus capitis); Pthiridae such as pubic louse (Pthirus pubis); Haematopinus usurysternus and Haematopinus suis; Linognathidae such as calf jaw louse (Linognathus vituli), sheep jaw louse (Linognathus ovillus), and buffalo blind louse (Solenopotescapillatus); Bovicoliidae such as cattle hair louse (Bovicola bovis), sheep louse (Bovico laovis), Bovicola breviceps, Damalinia forficula, and Werneckiella spp.; Trichod ectes canis), cat louse (Felicola subrostratus), etc.; Menoponidae, such as Menopon gallinae, Menacanthus stram ineus, and duck louse (Trinoton spp.); Trimenoponidae, such as Cummingsia spp.; Trogiidae, such as Trogium pulsatorium; Liposcel idae or Liposcelididae, such as Lipos celis corrodens, Liposcelis bostrychophila, Liposcelis pearmani, and Liposcelisentomophila.

[0404] Thysanura: Lepismatidae such as Ctenolepisma villosa and Lepismasaccharina.

[0405] Acari: Tetranychus urticae, Tetranychus kanzawai, Tetranychus evansi, Panonychus citri, Panonychus ulmi, Oligonychus spp., etc. Tetranychidae; Aculops pelekassi, Phyllocoptruta citri, Aculops lycopersici, Calacarus carinatus, Acaphylla theavagrans, Eriophyes chibaensis, Aculus schlechtendali, Aceria diospyri), Aceria tosichella, Shevtchenkella sp., etc.; Tarsonemidae, such as Polyphagotarsonemus latu s; Tenuipalpidae, such as Brevipalpus phoenicis; Tuckerellidae;Haemaphysalis longicornis, Haemaphysalis flav a, Haemaphysalis japonica, Haemaphysalis campanulata, Dermacentor variabilis, Dermacentor taiwanensis, Dermacentor andersoni, Dermacentor reticulatus, Ixodes ovatus, Ixodes persulcatus, Ixodes scapularis, Ixodes pacificus, Ixodes holocyclus, Ixodes ricinus, Amblyomma americanum, Amblyomma maculatum, Rhipicephalus micus The main species of ticks include Ixodidae, such as Rhipicephalus annulatus, Rhipicephalus sanguineus, Rhipicephalus appendiculatus, and Rhipicephalus decoloratus; Argasidae, such as Argas persicus, Ornithodoros hermsi, and Ornithodoros turicata; Acaridae, such as Tyrophagus putrescentiae and Tyrophagus similis; Pyroglyphidae, such as Dermatophagoides farinae and Dermatophagoides pteronyssinus; Cheyletus eruditus and Cheyletus turicata; malaccensis), Chelacaropsis moorei, Cheyletiella yasguri, and other carnivorous mites (Cheyletidae);Psoroptes ovis, Psoroptes equi, Knemidocoptes mutans, Otodectes cynotis, Chori-optes spp., etc. of the Psoroptidae family; Notoedres cati, Notoedres muris, Sarcoptes scabiei, etc. of the Sarcoptidae family; Listrophorus gibbus, etc. of the Rabbit family; Dermanyssidae, Dermanyssus gallinae, etc. of the Dermanyssidae family; Ornithonyssus sylviarum, Ornith onyssus bacoti) and other Macronyssidae; Varroidae, such as Varroa jac obsoni; Demodicidae, such as Demodex canis and Demodex cati; Trombiculidae, such as Leptotrombidium akamushi, Leptotrombidium pallidum, and Leptotrombidium scutellare.

[0406] Araneae: Eutichuridae, including the Japanese red-clawed spider (Cheiracanthium japonicum); Theridiidae, including the red-backed spider (Latrodectus hasseltii).

[0407] Polydesmida: Oxidus gracilis, Nedyopus tambanus, etc. Paradoxosomatidae.

[0408] Isopoda: Common beetle (Armadillidium vulgare), etc. Armadillidiidae.

[0409] Class Chilopoda: Scutigeridae, including Thereuonema hilgendorfi; Scolopendridae, including Scolopendra subspinipes; and Ethopolyidae, including Bothropolys rugosus.

[0410] Gastropoda: Limacidae, such as Limax marginatus and Limaxflavus; Philomycidae, such as Meghimatium bilineatum; Ampullariidae, such as Poma cea canaliculata; Lymnaeidae, such as Austropeplea ollula.

[0411] Nematodes: Aphelenchoididae, including the rice stem-tipped nematode Aphelenchoides besseyi; Pratylenchus coffeae, Pratylenchus brachyurus, Pratylenchus neglectus, and Radopholus similis, including the Pratylenchidae; Meloidogyne javanica, Meloidogyne incognita, guava root-knot nematodes Meloidogyne enterolobii, Meloidogyne hapla, soybean cyst nematode Heterodera glycines, and potato golden nematode Globodera spp. rostochiensis), Globodera pallida, and Meloidogyne chitwoodi; Hoplolaim idae, such as Rotylenchulus reniformis; Anguinidae, such as Nothotylenchus acris and Ditylenchus dipsaci; Tylenchulidae, such as Tylenchulus se mipenetrans; Longidoridae, such as Xiphinema ind ex; Trichodoridae; and Parasitaphelenchi dae, such as Bursaphelenchus xylophilus.

[0412] Harmful insects, harmful mites, and other harmful arthropods, harmful mollusks, and harmful nematodes may be those whose sensitivity to insecticides, acaricides, molluscicides, or nematodes is reduced, or those that are highly resistant to them.

[0413] The method for controlling harmful arthropods of the present invention can be implemented by directly applying an effective amount of the compound of the present invention or composition A to harmful arthropods and / or applying it to the habitats of harmful arthropods (plants, soil, houses, animals, etc.). Examples of the method for controlling harmful arthropods of the present invention include foliage treatment, soil treatment, root treatment, spraying treatment, fumigation treatment, water surface treatment, and seed treatment.

[0414] For the compound or composition A of the present invention, an inactive carrier such as a solid carrier, a liquid carrier, a gaseous carrier and a surfactant are usually mixed, and formulation adjuvants such as a binder, a dispersant, and a stabilizer are added as needed. The formulation is prepared into an aqueous suspension preparation, an oily suspension preparation, an oil preparation, an emulsion, an emulsion preparation, a microemulsion preparation, a microcapsule preparation, a wettable powder, a water-dispersible granule, a powder, a granule, a tablet, an aerosol preparation, a resin preparation, etc. for use. The present invention is not limited to these preparations and can be formulated into the dosage forms described in Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers-271-276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications (Manual on development and use of pesticide standards of the Food and Agriculture Organization of the United Nations and the World Health Organization, FAO Plant Production and Protection Papers-271-276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications), 2016, ISSN: 0259-2517 for use.

[0415] These preparations usually contain 0.0001 to 99% of the compound or composition A of the present invention by weight.

[0416] Examples of the solid support include clay (pyrophyllite clay, kaolin clay, etc.), talc, calcium carbonate, diatomaceous earth, zeolite, bentonite, acid clay, attapulgite, white carbon, ammonium sulfate, vermiculite, perlite, pumice, silica sand, fine powders and granules of chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.), and resins (polyethylene, polypropylene, polyester, polyurethane, polyamide, polyvinyl chloride, etc.).

[0417] Examples of the liquid carrier include water, alcohols (ethanol, cyclohexanol, benzyl alcohol, propylene glycol, polyethylene glycol, etc.), ketones (acetone, cyclohexanone, etc.), aromatic hydrocarbons (xylene, phenylxylylethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, methyl oleate, propylene carbonate, etc.), nitriles (acetonitrile, etc.), ethers (ethylene glycol dimethyl ether, etc.), amides (N,N-dimethylformamide, N,N-dimethyloctanamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), lactams (N-methylpyrrolidone, N-octylpyrrolidone, etc.), fatty acids (oleic acid, etc.), and vegetable oils (soybean oil, etc.).

[0418] Examples of the gaseous support include fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide.

[0419] Examples of the surfactant include nonionic surfactants (polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyethylene glycol fatty acid ester, etc.) and anionic surfactants (alkyl sulfonates, alkyl aryl sulfonates, alkyl sulfates, etc.).

[0420] Other formulation adjuvants include binders, dispersants, colorants, stabilizers, and the like. Specifically, they include polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, synthetic water-soluble polymers (polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylic acids, etc.), acidic isopropyl phosphate, and butylated hydroxytoluene.

[0421] In addition, adjuvants can be used as components that enhance or assist the efficacy of the compounds of the present invention. Specific examples include Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol (registered trademark), Silwet L-77 (registered trademark), BreakThru (registered trademark), Sundance II (registered trademark), Induce (registered trademark), Penetrator (registered trademark), AgriDex (registered trademark), Lutensol A8 (registered trademark), NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITON X 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark), ARPON (registered trademark), EnSpray N (registered trademark), and BANOLE (registered trademark).

[0422] In the present invention, examples of the plant include the whole plant, stems and leaves, flowers, ears, fruits, trunks, branches, crowns, seeds, vegetative propagation organs, and seedlings.

[0423] Vegetative propagation organ refers to: among the root, stem, leaf etc. of plant, the position with the ability of growing when this position is cut off from main body and is arranged in soil.As vegetative propagation organ, can enumerate for example tuberous root (tuberous root), creeping root (creeping root), bulb (bulb), corm (corm or solid bulb), tuber (tuber), rhizome (rhizome), stolon (stolon), rhizophore (rhizophore), stem cuttings (cane cuttings), propagation bud (propagule) and vine cuttings (vine cutting).It should be noted that stolon is sometimes also referred to as runner (runner), and propagation bud is also referred to as bulbil, is divided into fleshy bud (broad bud), bulbil (bulbil).Vine cuttings refer to the slender (general term of leaf and stem, rootless seedling (shoot)) of sweet potato, Japanese yam etc. The term "bulb" also refers to bulbs, corms, tubers, rhizomes, stem cuttings, root tubers, or tubers. Tuber cultivation begins by planting tubers in the soil, but the tubers used are usually called seed potatoes.

[0424] As a method for controlling harmful arthropods by applying an effective amount of the compound or composition A of the present invention to the soil, for example, a method of applying an effective amount of the compound or composition A of the present invention to the soil before or after transplanting plants. More specifically, for example, hole treatment (hole spreading, hole treatment soil mixing), root treatment (root spreading, root soil mixing, root irrigation, root treatment in the late seedling stage), furrow treatment (furrow spreading, furrow soil mixing), furrow treatment (furrow spreading, furrow soil mixing, furrow spreading during the growing period), furrow treatment at sowing (furrow spreading at sowing, furrow soil mixing at sowing), comprehensive treatment (whole soil spreading, whole soil mixing), ridge side treatment, water surface treatment (water surface application, water surface application after water storage), other soil spreading treatments (leaf spreading of granules during the growing period, spreading under the canopy or around the trunk, soil surface spreading, soil surface mixing, hole spreading, ridge ground surface scattering, inter-plant scattering), other irrigation treatments (soil irrigation, irrigation during the seedling period, liquid injection treatment, irrigation at the base of the plant, liquid drip irrigation, chemical solution irrigation), seedling box treatment (seedling box scattering, seedling box irrigation, seedling box liquid accumulation), seedling tray treatment (seedling tray scattering, seedling tray irrigation, seedling tray liquid accumulation), seedling bed treatment (seedling bed scattering, seedling bed irrigation, nursery bed scattering, seedling soaking), bed soil mixing treatment (bed soil mixing, bed soil mixing before sowing, scattering before covering soil at sowing, scattering after covering soil at sowing, covering soil mixing), and other treatments (cultivated soil mixing, turning in, topsoil mixing, rainwater drip soil mixing, planting position treatment, granular calyx scattering, paste fertilizer mixing).

[0425] Examples of seed treatment include treatments of seeds or vegetative propagation organs with the compound or composition A of the present invention. Specifically, examples include: spraying treatments in which a suspension of the compound or composition A of the present invention is atomized and sprayed onto the surface of seeds or vegetative propagation organs; coating treatments in which the compound or composition A of the present invention is applied to seeds or vegetative propagation organs; immersion treatments in which seeds or vegetative propagation organs are immersed in a solution of the compound or composition A of the present invention for a predetermined period of time; and methods in which seeds or vegetative propagation organs are coated with a carrier containing the compound or composition A (coating treatments, pellet coating treatments, etc.). Examples of the vegetative propagation organs include seed potatoes.

[0426] When treating seeds or vegetative propagation organs with composition A, composition A may be prepared as a single formulation for treating the seeds or vegetative propagation organs, or composition A may be prepared as multiple different formulations for treating the seeds or vegetative propagation organs in multiple batches. Examples of methods for treating the seeds or vegetative propagation organs with multiple different formulations include: treating the seeds or vegetative propagation organs with a formulation containing only the compound of the present invention as an active ingredient, allowing the seeds or vegetative propagation organs to air-dry, and then treating the seeds or vegetative propagation organs with a formulation containing the present ingredient; and treating the seeds or vegetative propagation organs with a formulation containing the compound of the present invention and the present ingredient as active ingredients, allowing the seeds or vegetative propagation organs to air-dry, and then treating the seeds or vegetative propagation organs with a formulation containing the present ingredient other than the treated present ingredient.

[0427] The seeds or vegetative propagation organs retaining the compound or composition A of the present invention in the present invention refer to seeds or vegetative propagation organs in a state where the compound or composition A of the present invention is attached to the surface of the seeds or vegetative propagation organs. For the seeds or vegetative propagation organs retaining the compound or composition A of the present invention, materials other than the compound or composition A of the present invention may be attached before or after the compound or composition A of the present invention is attached to the seeds or vegetative propagation organs.

[0428] In addition, when composition A forms a layer on the surface of a seed or a vegetative propagation organ and adheres to it, the layer is formed by one layer or multiple layers. In addition, when formed by multiple layers, each layer is a layer containing one or more active ingredients, or is formed by a layer containing one or more active ingredients and a layer not containing an active ingredient.

[0429] Seeds or vegetative propagation organs containing the compound or composition A of the present invention can be obtained, for example, by applying a formulation containing the compound or composition A of the present invention to seeds or vegetative propagation organs using the aforementioned seed treatment method.

[0430] When the compound or composition A of the present invention is used for controlling harmful arthropods in agricultural fields, the application rate is: 2 The amount of the compound of the present invention is usually 1 to 10,000 g. When treating seeds or vegetative propagation organs, the amount of the compound of the present invention is usually applied in the range of 0.001 to 100 g per kg of seeds or vegetative propagation organs. When the compound of the present invention or composition A is formulated into an emulsion, wettable powder, suspension, etc., it is usually diluted with water to a concentration of 0.01 to 10,000 ppm of the active ingredient and applied. Granules, powders, etc. are usually applied directly.

[0431] Alternatively, the compound or composition A of the present invention can be treated by winding a resin preparation processed into a sheet or string around crops, stretching it near crops, or laying it on the soil around the roots.

[0432] When the compound or composition A of the present invention is used to control harmful arthropods that inhabit houses, the application rate is, when treating on the surface, 1m 2 The amount of the compound of the present invention per treatment area is usually 0.01 to 1000 mg. When the treatment is carried out in space, the amount is per 1 m 3 The amount of the compound of the present invention applied to the treated space is generally 0.01 to 500 mg. When the compound of the present invention or composition A is formulated into an emulsion, wettable powder, suspension, or the like, it is usually diluted with water to a concentration of 0.1 to 10,000 ppm of the active ingredient and applied directly. Alternatively, an oil formulation, aerosol formulation, fumigant, or poison bait formulation may be used.

[0433] The compounds of this invention or composition A are used to prevent and treat external parasites of small animals such as cattle, horses, pigs, sheep, goats, chickens, dogs, cats, rats, mice, etc., and can be used for animals by methods known in veterinary medicine. As a specific method of use, in the case of systemic suppression for the purpose, by, for example, tablets, feeds mixed in, suppositories, injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.) to apply, in the case of non-systemic suppression for the purpose, by, for example, oils or aqueous liquids are sprayed, poured or sprayed, shampoo formulations are used to wash animals, or resin formulations are made into collars, ear tags and animals are worn. The amount of the compounds of this invention or composition A when applied to animals is generally in the range of 0.1 to 1000 mg relative to the body weight 1 kg of the animal.

[0434] The compound or composition A of the present invention can be used as an agent for controlling harmful arthropods in agricultural lands such as dry fields, paddy fields, lawns, and orchards. Examples of plants include the following.

[0435] Corn (dent, hard, soft, popping, glutinous, sweet, and non-sweet corn), rice (long-grain, short-grain, medium-grain, Japonica, tropical Japonica, Indica, Javanese, upland rice, floating rice, direct-seeded, transplanted, and glutinous rice), wheat (bread wheat (hard, soft, medium, red, and white), durum wheat, spelt, and club wheat, as well as various winter and spring wheat types), barley (two-row barley (= malting barley), six-row barley, naked barley, and various sticky barley types), (winter barley type, spring barley type), rye (winter rye type, spring rye type), triticale (winter triticale type, spring triticale type), oats (winter oat type, spring oat type), sorghum, cotton (upland type, Pima type), soybeans (mature seed harvest varieties, branch bean varieties, green cutting varieties, each indeterminate growth type, determinate growth type, semi-determinate growth type), peanuts, buckwheat, sugar beets (for sugar production, feed, root vegetables, leafy vegetables, fuel), rapeseed (winter rapeseed type, spring rapeseed type), Canadian rapeseed (winter Canadian rapeseed type, spring Canadian rapeseed type), sunflower (for oil extraction, food Vegetables for ornamental purposes (e.g., eggplant, tomato, green pepper, hot pepper, potato), cucurbitaceae vegetables (cucumber, pumpkin, zucchini, watermelon, melon), cruciferous vegetables (radish, turnip, horseradish, kohlrabi, cabbage, cabbage, mustard, broccoli, cauliflower), Asteraceae vegetables (burdock, chamomile, artichoke, lettuce), Liliaceae vegetables (scallion, onion, garlic, asparagus), Umbelliferae vegetables (carrot, parsley, celery, parsnip), Chenopodiaceae vegetables (spinach, pachyderm), Lamiaceae vegetables (perilla, mint), , basil, etc.), strawberry, sweet potato, Japanese yam, taro, pome fruit (apple, pear, Japanese pear, white pear, papaya crabapple, quince, etc.), stone fruit (peach, plum, nectarine, greengage, cherry, apricot, prune, etc.), citrus (Wenzhou mandarin orange, orange, lemon, lime, grapefruit, etc.), nuts (chestnut, walnut, hazelnut, almond, pistachio, cashew, macadamia, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, persimmon, fig, olive, loquat, banana, coffee, date, coconut, ornamental plants, forest plants, lawn grass, forage grass.

[0436] The above-mentioned plants are not particularly limited as long as they are commonly cultivated varieties. The above-mentioned plants also include plants that can be made by natural mating, plants that can be produced by mutation, F1 hybrid plants and genetically modified crops. As genetically modified crops, for example, plants that are endowed with resistance to herbicides such as HPPD (4-hydroxyphenylpyruvate dioxygenase) inhibitors such as isoxaflutole, ALS (acetolactate synthase) inhibitors such as imazethapyr, thifensulfuron, EPSP (5-enolpyruvylshikimate-3-phosphate synthase) inhibitors, glutamine synthetase inhibitors, PPO (protoporphyrinogen oxidase) inhibitors, bromoxynil or dicamba; plants that can synthesize selective toxins known in Bacillus thuringiensis such as Bacillus thuringiensis; plants that can be endowed with specific insecticidal activity by synthesizing gene fragments that are partially identical to endogenous genes from harmful insects and inducing gene silencing (RNAi; RNA interference) in the target harmful insects.

[0437] Example

[0438] Hereinafter, the present invention will be described in more detail using production examples, formulation examples, test examples, and the like, but the present invention is not limited to these examples.

[0439] In this specification, Me represents a methyl group, Et represents an ethyl group, Pr represents a propyl group, i-Pr represents an isopropyl group, t-Bu represents a tert-butyl group, C2F5 represents a perfluoroethyl group, c-Pr represents a cyclopropyl group, Ph represents a phenyl group, Py2 represents a 2-pyridyl group, Py3 represents a 3-pyridyl group, and Py4 represents a 4-pyridyl group. When c-Pr, Ph, Py2, Py3, and Py4 are substituted with a substituent, the position of substitution is indicated before the substituent symbol. For example, 1-CN-c-Pr represents 1-cyanocyclopropyl, 3,4-F2-Ph represents 3,4-difluorophenyl, 2-C2F5-Ph represents 2-(perfluoroethyl)phenyl, 4-SO2CF3-Ph represents 4-(trifluoromethanesulfonyl)phenyl, 3,4-(OCF3)2-Ph represents 3,4-bis(trifluoromethoxy)phenyl, 3-SCF3-4-OCF3-Ph represents 3-[(trifluoromethyl)thio]-4-(trifluoromethoxy)phenyl, and 4-CF3-Py2 represents 4-(trifluoromethyl)-2-pyridyl.

[0440] First, production examples of the compound of the present invention and its production intermediates are shown.

[0441] Reference Production Example 1

[0442] To a mixture of 2.2 g of 3-(2-bromoacetyl)-1-methyl-6-(2,2,3,3,3-pentafluoropropoxy)-2(1H)-pyridone and 30 mL of ethanol produced by the method described in International Publication No. 2019 / 124548 was added 1.04 g of 5-(trifluoromethyl)-2-aminopyridine at room temperature, and the mixture was stirred under reflux for 9 hours. After the obtained mixture was cooled to room temperature, it was concentrated under reduced pressure. Water was added to the obtained residue, and extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel column chromatography to obtain 2.10 g of intermediate 1 represented by the following formula.

[0443] [Chemical Formula 17]

[0444]

[0445] Intermediate 1: 1 H-NMR(CDCl3)δ:8.70(1H,s),8.50(2H,dt),7.64(1H,d),7.31(1H,dd),5.78(1H,d),4.55(2H,t),3.62(3H,s).

[0446] Reference Production Example 2

[0447] The compounds produced according to Reference Production Example 1 and their physical properties are shown below.

[0448] In the compound represented by formula (A-1), T, A 3 、R 3b and R 3d The combination is any combination of compounds described in [Table A1].

[0449] [Chemical Formula 18]

[0450]

[0451] [Table 1]

[0452] [Table A1]

[0453] intermediates T <![CDATA[A 3 ]]> <![CDATA[R 3b ]]> <![CDATA[R 3d ]]> 2 <![CDATA[OCH2CF2CF3]]> CH Br H 3 <![CDATA[OCH2CF2CF3]]> CH I H 4 <![CDATA[OCH2CF2CF3]]> N Br H 5 <![CDATA[OCH2CF2CF3]]> N I H 6 <![CDATA[OCH2CF2CF3]]> N H <![CDATA[CF3]]> 16 <![CDATA[OCH2CF2CF3]]> N <![CDATA[CF3]]> H 17 <![CDATA[OCH2CF2CF3]]> N H I

[0454] Intermediate 2: 1 H-NMR(CDCl3)δ:3.47(3H,s),5.12(2H,t),6.24(1H,d),7.50(1H,d),7.58(1H,d),8.39(1H,d),8.66(1H,s),9.04(1H,s).

[0455] Intermediate 3: 1H-NMR(CDCl3)δ:3.61(3H,s),4.54(2H,t),5.77(1H,d),7.33-7.41(2H,m),8.38(1H,s),8.50-8.55(2H,m).

[0456] Intermediate 4: 1 H-NMR(CDCl3)δ:3.55(3H,s),4.93(2H,t),7.21(1H,d),7.45(1H,d),8.25(1H,s),8.44(1H,s),8.71(1H,s).

[0457] Intermediate 5: 1 H-NMR(CDCl3)δ:3.57(3H,s),4.94(2H,t),7.34-7.38(2H,m),8.38(1H,s),8.43(1H,s),8.73(1H,s).

[0458] Intermediate 6: 1 H-NMR(CDCl3)δ:3.58(3H,s),4.96(2H,t),6.94(1H,d),7.89(1H,s),8.23(1H,d),8.60(1H,s),8.77(1H,s).

[0459] Intermediate 16: 1 H-NMR(CDCl3)δ:3.58(3H,s),4.95(2H,t),7.32(1H,d),7.66(1H,d),8.49(1H,d),8.59(1H,s),8.76(1H,s).

[0460] Intermediate 17: 1 H-NMR(CDCl3)δ:3.57(3H,s),4.94(2H,t),7.00(1H,d),7.87(1H,d),8.00(1H,d),8.45(1H,s),8.72(1H,s).

[0461] Reference Production Example 3

[0462] Under ice-cooling conditions, a mixture of 1.52 g of triphosgene and 15 mL of THF was added dropwise to a mixture of 3.00 g of 4-(trifluoromethyl)anthranilic acid and 22 mL of THF. The resulting mixture was stirred at room temperature for 4 hours. Water was added to the resulting mixture, and extraction was performed with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to obtain 3.30 g of Intermediate 7 represented by the following formula.

[0463] [Chemical Formula 19]

[0464]

[0465] Intermediate 7: 1 H-NMR(DMSO-D6)δ:11.98(1H,br s),8.10(1H,d),7.54(1H,d),7.37(1H,s).

[0466] Reference Production Example 4

[0467] Intermediate 8 represented by the following formula was obtained according to Reference Production Example 3 using 2-amino-5-(trifluoromethoxy)benzoic acid instead of 4-(trifluoromethyl)anthranilic acid.

[0468] [Chemical Formula 20]

[0469]

[0470] Intermediate 8: 1 H-NMR(DMSO-D6)δ:9.92(1H,s),5.83(1H,d),5.80-5.77(1H,m),5.26(1H,d).

[0471] Reference Production Example 5

[0472] Under a nitrogen atmosphere, 7.7 mL of potassium bis(trimethylsilyl)amide (1 mol / L THF solution) was added dropwise to a mixture of 1.00 g of 6-iodo-imidazo[1,2-a]pyridin-2-amine (prepared by the method described in Bioorganic & Medicinal Chemistry Letters, 2011, 21, 6586) and 7.7 mL of THF at -78°C, followed by stirring for 30 minutes. 0.95 g of Intermediate 8 and THF were added to the resulting mixture, followed by stirring at 0°C for 30 minutes. Saturated aqueous ammonium chloride was added to the resulting mixture, and extraction was performed with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. Hexane was added to the resulting residue, and the resulting solid was filtered. The filter residue was washed with hexane and then dried under reduced pressure to obtain 1.75 g of Intermediate 9 represented by the following formula.

[0473] [Chemical Formula 21]

[0474]

[0475] Intermediate 9: 1H-NMR(CDCl3)δ:9.66(1H,s),8.19-8.19(1H,m),7.99(1H,s),7.28(1H,d),7.15(1H,dd),6.99-6.96(1H,m),6.85(1H,d),6.56(1H,d),5.54(2H,br s).

[0476] Reference Production Example 6

[0477] Intermediate 10 represented by the following formula was obtained according to Reference Production Example 5 using Intermediate 7 instead of Intermediate 8.

[0478] [Chemical Formula 22]

[0479]

[0480] Intermediate 10: 1 H-NMR(CDCl3)δ:9.79(1H,s),8.36(1H,dd),8.16(1H,s),7.65(1H,d),7.29(1H,dd),6.98(1H,d),6.94(1H,d),6.82(1H,d),5.84(2H,s).

[0481] Reference Preparation Example 7

[0482] A mixture of 1.75 g of Intermediate 9 and 38 mL of triethyl orthoformate was stirred at 120° C. for 40 minutes. The resulting mixture was allowed to cool to room temperature and concentrated under reduced pressure. The resulting solid was washed with hexane to obtain 1.60 g of Intermediate 11 represented by the following formula.

[0483] [Chemical Formula 23]

[0484]

[0485] Intermediate 11: 1 H-NMR(CDCl3)δ:9.44(1H,s),8.49(1H,s),8.47(1H,dd),8.24(1H,d),7.86(1H,d),7.64(1H,dd),7.48(1H,dd),7.42(1H,d).

[0486] Reference Preparation Example 8

[0487] Intermediate 10 was used instead of Intermediate 9, and Intermediate 12 represented by the following formula was obtained according to Reference Production Example 7.

[0488] [Chemical Formula 24]

[0489]

[0490] Intermediate 12: 1 H-NMR(CDCl3)δ:9.53(1H,s),8.56(1H,d),8.53(1H,s),8.50(1H,dd),8.14-8.11(1H,m),7.80(1H,dd),7.52(1H,dd),7.45(1H,d).

[0491] Reference Preparation Example 9

[0492] Under a nitrogen atmosphere, 1.85 g of potassium tert-butoxide was added to a mixture of 2.14 g of 6-iodo-imidazo[1,2-a]pyridin-2-amine (prepared by the method described in Bioorganic & Medicinal Chemistry Letters, 2011, 21, 6586) and 28 mL of THF at 0°C, followed by stirring for 5 minutes. 0.95 g of 5-bromoisatoic anhydride was added to the resulting mixture, and the mixture was stirred at room temperature for 1 hour. Saturated aqueous ammonium chloride was added to the resulting mixture, which was concentrated under reduced pressure, and the resulting solid was filtered. 50 mL of triethyl orthoformate was added to the resulting residue, and the mixture was stirred at 100°C for 2 hours. The resulting mixture was allowed to cool to room temperature and then concentrated under reduced pressure. The resulting solid was washed with MTBE to obtain 2.25 g of Intermediate 13 represented by the following formula.

[0493] [Chemical Formula 25]

[0494]

[0495] Intermediate 13: 1 H-NMR(CDCl3)δ:9.44(1H,s),8.56(1H,s),8.50(1H,s),8.49-8.47(1H,m),7.91(1H,d),7.70(1H,d),7.49(1H,d),7.43(1H,d).

[0496] Reference Preparation Example 10

[0497] A mixture of 1.48 g of 6-bromo-2-chloro-imidazo[1,2-a]pyridine, 2.4 mL of chlorosulfonic acid, and 13 mL of phosphorus oxychloride, produced by the method described in International Publication No. 2019 / 124548, was stirred at 110°C for 5 hours. The obtained mixture was concentrated under reduced pressure, and 2.7 mL of triethylamine, 13 mL of acetonitrile, and 3 mL of dimethylamine (7% tetrahydrofuran solution) were added to the obtained residue, and stirred at room temperature for 1 hour. Water was added to the obtained mixture, and the mixture was extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel column chromatography to obtain 1.9 g of intermediate 14 represented by the following formula.

[0498] [Chemical Formula 26]

[0499]

[0500] Intermediate 14: 1 H-NMR(CDCl3)δ:9.05(1H,s),7.53-7.55(2H,m),2.93(6H,s).

[0501] Reference Preparation Example 11

[0502] A mixture of 0.9 g of intermediate 14, 1.5 g of cesium fluoride, and 5 mL of DMSO was stirred at 120° C. for 4 hours. After the resulting mixture was allowed to reach room temperature, ethyl acetate and water were added sequentially, followed by filtration. The resulting filtrate was separated, and the resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.3 g of intermediate 15 represented by the following formula.

[0503] [Chemical Formula 27]

[0504]

[0505] Intermediate 15: 1 H-NMR(CDCl3)δ:8.95(1H,s),7.50-7.59(2H,m),2.91(6H,s).

[0506] Reference Preparation Example 12

[0507] A mixture of 6.6 g of 2-chloropyridine-3-sulfonyl chloride, 1.5 mL of triethylamine, 8 mL of acetonitrile and 5 mL of dimethylamine (7% tetrahydrofuran solution) was stirred at room temperature for 1 hour. Water was added to the obtained mixture and extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. 9.0 g of cesium fluoride and 30 mL of DMSO were added to the obtained residue and stirred at room temperature for 6 hours. After the obtained mixture was allowed to reach room temperature, ethyl acetate and water were added thereto in sequence and filtered. The obtained filtrate was separated, and the obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel column chromatography to obtain 3.4 g of intermediate 16 represented by the following formula.

[0508] [Chemical Formula 28]

[0509]

[0510] Intermediate 16: 1 H-NMR(CDCl3)δ:8.40-8.43(1H,m),8.29-8.34(1H,m),7.35-7.40(1H,m),2.91(6H,s).

[0511] Reference Preparation Example 13

[0512] According to Reference Preparation Example 9, the intermediate 17 represented by the following formula was obtained.

[0513] [Chemical Formula 29]

[0514]

[0515] Intermediate 17: 1 H-NMR(CDCl3)δ:9.41(1H,s),8.47(1H,s),8.45(1H,d),8.26(1H,d),7.99(1H,d),7.67(1H,dd),7.40-7.49(2H,m).

[0516] Production Example 1

[0517] A mixture of 0.56 g of intermediate 1, 0.5 mL of chlorosulfonic acid and 3 mL of phosphorus oxychloride was stirred at 110 ° C for 5 hours. The obtained mixture was concentrated under reduced pressure, and 0.5 mL of triethylamine, 3 mL of acetonitrile and 0.5 mL of methylamine (7% tetrahydrofuran solution) were added to the obtained residue and stirred at room temperature for 1 hour. Water was added to the obtained mixture and extracted with ethyl acetate. The obtained organic layer was dried using anhydrous sodium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel column chromatography to obtain 0.12 g of compound 1 of the present invention shown in the following formula.

[0518] [Chemical formula 30]

[0519]

[0520] Compound 1 of the present invention: 1 H-NMR(CDCl3)δ:9.41(1H,s),7.88(1H,d),7.77(1H,d),7.55(1H,d),7.40(1H,d),5.79(1H,d),4.54(2H,t),3.59(3H,s),2.85(3H,d).

[0521] Production Example 2

[0522] The compounds produced according to Production Example 1 and their physical properties are shown below.

[0523] [Chemical Formula 31]

[0524]

[0525] Compound 2 of the present invention: 1 H-NMR(CDCl3)δ:9.12(1H,s),7.81(1H,d),7.55(1H,d),7.46-7.42(1H,m),7.37-7 .32(1H,m),5.76(1H,d),4.53(2H,t),3.56(3H,s),3.22-3.15(2H,m),1.22(3H,t).

[0526] [Chemical Formula 32]

[0527]

[0528] Compound 3 of the present invention: 1 H-NMR(CDCl3)δ:8.95(1H,s),7.63(1H,d),7.59(1H,d),7.51-7.47(1H,m),5.64(1H,d),4.53(2H,t),3.54(3H,s),2.75(6H,s).

[0529] [Chemical Formula 33]

[0530]

[0531] Compound 4 of the present invention: 1 H-NMR(CDCl3)δ:9.28(1H,s),7.85(1H,d),7.58(1H,d),7.46-7.43(1H,m ),7.39-7.34(1H,m),5.79(1H,d),4.55(2H,t),3.59(3H,s),2.85(3H,d).

[0532] [Chemical Formula 34]

[0533]

[0534] Compound 5 of the present invention: 1 H-NMR(CDCl3)δ:9.27(1H,s),8.16(1H,s),7.62(1H,d),7.53-7.49(1H,m),7.03(1H,s ),4.95(2H,t),3.55(3H,s),2.50-2.45(1H,m),0.85-0.79(2H,m),0.75-0.70(2H,m).

[0535] [Chemical Formula 35]

[0536]

[0537] Compound 6 of the present invention: 1 H-NMR(CDCl3)δ:9.06(1H,s),8.17(1H,s),7.64(1H,d),7.55-7.51(1H,m),6.03(2H,s),4.96(2H,t),3.56(3H,s).

[0538] [Chemical Formula 36]

[0539]

[0540] Compound 7 of the present invention: 1 H-NMR(CDCl3)δ:9.25(1H,s),8.13(1H,s),7.60(1H,d),7.49(1H,d),6.80-6.76(1H,m),4.93(2H,t),3.54(3H,s),2.85(3H,d).

[0541] [Chemical Formula 37]

[0542]

[0543] Compound 8 of the present invention: 1 H-NMR(CDCl3)δ:8.75(1H,s),8.13-8.11(2H,m),7.23-7.27(1H,m),6.78-6.81(1H,m),4.93(2H,t),3.54(3H,s),2.82(3H,d).

[0544] [Chemical Formula 38]

[0545]

[0546] Compound 9 of the present invention: 1 H-NMR(CDCl3)δ:9.31(1H,s),8.17(1H,s),7.82(1H,d),7.58(1H,d),6.84-6.87(1H,m),4.94(2H,t),3.56(3H,s),2.86(3H,d).

[0547] [Chemical Formula 39]

[0548]

[0549] Compound 10 of the present invention: 1 H-NMR(CDCl3)δ:9.15(1H,d),8.16(1H,s),8.02(1H,s),7.19(1H,d),6.84-6.92(1H,m),4.94(2H,t),3.55(3H,s),2.86(3H,d).

[0550] [Chemical Formula 40]

[0551]

[0552] Compound 11 of the present invention: 1 H-NMR(CDCl3)δ:9.02-9.01(1H,m),8.15(1H,d),8.05(1H,s),7.85(1H,d),7.76(1H,dd),7.66(1H,dd),7.59(1H,dd),2.86(6H,s).

[0553] [Chemical Formula 41]

[0554]

[0555] Compound 12 of the present invention: 1H-NMR(CDCl3)δ:9.22(1H,dd),8.32(1H,s),8.16(1H,d),7.87(1H,d),7.74(1H,dd),7.68(1H,dd),7.57(1H,dd),6.07(1H,q),2.92(3H,d).

[0556] [Chemical Formula 42]

[0557]

[0558] Compound 13 of the present invention: 1 H-NMR(CDCl3)δ:9.24-9.23(1H,m),8.50(1H,d),8.34(1H,s),7.95(1H,dd) ,7.75(1H,dd),7.71(1H,d),7.58(1H,dd),6.12-6.07(1H,m),2.93(3H,d).

[0559] Production Example 3

[0560] Under ice cooling, to a mixture of 0.17 g of sodium hydride (oil, 60%) and 16 mL of NMP was added 0.95 g of 4-(2,2,3,3,3-pentafluoropropoxy)-2(1H)-pyridone, stirred for 10 minutes, and then 0.80 g of intermediate 16 was added, and the mixture was stirred at 60 ° C for 5 hours. After the obtained mixture was cooled to room temperature, water was added to the residue and extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel column chromatography to obtain 0.60 g of compound 14 of the present invention shown in the following formula.

[0561] [Chemical Formula 43]

[0562]

[0563] Compound 14 of the present invention: 1 H-NMR(CDCl3)δ:8.70(1H,s),8.52-8.48(2H,m),7.64(1H,d),7.31(1H,dd),5.78(1H,d),4.55(2H,t),2.86(6H,s).

[0564] Production Example 4

[0565] The compounds produced according to Production Example 3 and their physical properties are shown below.

[0566] [Chemical Formula 44]

[0567]

[0568] Compound 15 of the present invention: 1 H-NMR(CDCl3)δ:8.88(1H,s),7.69-7.63(2H,m),7.56(1H,d),7.40(1H,s),6.86(1H,d),2.87(6H,s).

[0569] Production Example 5

[0570] The compounds produced according to Production Example 1 and their physical properties are shown below.

[0571] [Chemical Formula 45]

[0572]

[0573] Compound 16 of the present invention: 1 H-NMR(CDCl3)δ:9.12(1H,d),8.12(1H,s),7.60(1H,d),7.50(1H,dd),6.80(1H,t),4.93(2H,t),3.55(3H,s),3.19-3.26(2H,m),1.23(3H,t).

[0574] [Chemical Formula 46]

[0575]

[0576] Compound 17 of the present invention: 1 H-NMR(DMSO-D6)δ:8.96(1H,s),8.50(1H,s),8.12(1H,d),8.03(1H,d),7.97(1H,dd),7.79-7.83(2H,m),6.69(1H,d),2.45(3H,d).

[0577] Next, examples of the compounds of the present invention produced according to any of the production examples described in the Examples and the production methods described in this specification are shown below.

[0578] [Chemical Formula 47]

[0579]

[0580] In the compound represented by formula (L-1) (hereinafter referred to as compound (L-1)), R 2a and R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX1).

[0581] [Table 2]

[0582]

[0583] [Table 3]

[0584]

[0585] In compound (L-1), R 2a and R 2b is a hydrogen atom, R 6 The compounds wherein R is an ethyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX2).

[0586] In compound (L-1), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX3).

[0587] In compound (L-1), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is an ethyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX4).

[0588] In compound (L-1), R 2a is ethyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX5).

[0589] In compound (L-1), R 2a is ethyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is an ethyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX6).

[0590] In compound (L-1), R 2a and R 2b is methyl, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX7).

[0591] In compound (L-1), R 2a and R 2b is methyl, R 6The compounds wherein R is an ethyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX8).

[0592] [Chemical Formula 48]

[0593]

[0594] In the compound represented by formula (L-2) (hereinafter referred to as compound (L-2)), R 2a and R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX9).

[0595] In compound (L-2), R 2a and R 2b is a hydrogen atom, R 6 The compounds wherein R is an ethyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX10).

[0596] In compound (L-2), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX11).

[0597] In compound (L-2), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX12).

[0598] In compound (L-2), R 2a is ethyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX13).

[0599] In compound (L-2), R 2a is ethyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is an ethyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX14).

[0600] In compound (L-2), R 2a and R 2b is methyl, R6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX15).

[0601] In compound (L-2), R 2a and R 2b is methyl, R 6 The compounds wherein R is an ethyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX16).

[0602] [Chemical Formula 49]

[0603]

[0604] In the compound represented by formula (L-3) (hereinafter referred to as compound (L-3)), R 2a and R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX17).

[0605] In compound (L-3), R 2a and R 2b is a hydrogen atom, R 6 The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX18).

[0606] In compound (L-3), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX19).

[0607] In compound (L-3), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is an ethyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX20).

[0608] In compound (L-3), R 2a is ethyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX21).

[0609] In compound (L-3), R 2a is ethyl, R2b is a hydrogen atom, R 6 The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX22).

[0610] In compound (L-3), R 2a and R 2b is methyl, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX23).

[0611] In compound (L-3), R 2a and R 2b is methyl, R 6 The compounds wherein R is an ethyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX24).

[0612] [Chemical Formula 50]

[0613]

[0614] In the compound represented by formula (L-4) (hereinafter referred to as compound (L-4)), R 2a and R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX25).

[0615] In compound (L-4), R 2a is methyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX26).

[0616] In compound (L-4), R 2a is ethyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX27).

[0617] In compound (L-4), R 2a and R 2b The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX28).

[0618] [Chemical Formula 51]

[0619]

[0620] In the compound represented by formula (L-5) (hereinafter referred to as compound (L-5)), R 2a and R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX29).

[0621] In compound (L-5), R 2a is methyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX30).

[0622] In compound (L-5), R 2a is ethyl, R 2b A compound wherein α is a hydrogen atom, and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX31).

[0623] In compound (L-5), R 2a and R 2b The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX32).

[0624] [Chemical Formula 52]

[0625]

[0626] In the compound represented by formula (L-6) (hereinafter referred to as compound (L-6)), R 2a and R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX33).

[0627] In compound (L-6), R 2a is methyl, R 2b A compound wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX34).

[0628] In compound (L-6), R 2a is ethyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX35).

[0629] In compound (L-6), R 2a and R 2b The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX36).

[0630] [Chemical Formula 53]

[0631]

[0632] In the compound represented by formula (L-9) (hereinafter referred to as compound (L-9)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX37).

[0633] [Table 4]

[0634]

[0635] [Table 5]

[0636]

[0637] [Table 6]

[0638]

[0639] In compound (L-9), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX38).

[0640] In compound (L-9), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX39).

[0641] In compound (L-9), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX40).

[0642] In compound (L-9), R 2a is methyl, R2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX41).

[0643] In compound (L-9), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX42).

[0644] In compound (L-9), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX43).

[0645] In compound (L-9), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX44).

[0646] In compound (L-9), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX45).

[0647] In compound (L-9), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX46).

[0648] In compound (L-9), R 2a is ethyl, R2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX47).

[0649] In compound (L-9), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX48).

[0650] In compound (L-9), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX49).

[0651] In compound (L-9), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX50).

[0652] In compound (L-9), R 2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX51).

[0653] In compound (L-9), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX52).

[0654] [Chemical Formula 54]

[0655]

[0656] In the compound represented by formula (L-10) (hereinafter referred to as compound (L-10)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX53).

[0657] In compound (L-10), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX54).

[0658] In compound (L-10), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX55).

[0659] In compound (L-10), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX56).

[0660] In compound (L-10), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX57).

[0661] In compound (L-10), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX58).

[0662] In compound (L-10), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX59).

[0663] In compound (L-10), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX60).

[0664] In compound (L-10), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX61).

[0665] In compound (L-10), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX62).

[0666] In compound (L-10), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX63).

[0667] In compound (L-10), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX64).

[0668] In compound (L-10), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX65).

[0669] In compound (L-10), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX66).

[0670] In compound (L-10), R 2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX67).

[0671] In compound (L-10), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX68).

[0672] [Chemical Formula 55]

[0673]

[0674] In the compound represented by formula (L-11) (hereinafter referred to as compound (L-11)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX69).

[0675] In compound (L-11), R 2aand R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX70).

[0676] In compound (L-11), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX71).

[0677] In compound (L-11), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX72).

[0678] In compound (L-11), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX73).

[0679] In compound (L-11), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX74).

[0680] In compound (L-11), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX75).

[0681] In compound (L-11), R 2a is methyl, R2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX76).

[0682] In compound (L-11), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX77).

[0683] In compound (L-11), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX78).

[0684] In compound (L-11), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX79).

[0685] In compound (L-11), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX80).

[0686] In compound (L-11), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX81).

[0687] In compound (L-11), R 2a and R2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX82).

[0688] In compound (L-11), R 2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX83).

[0689] In compound (L-11), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX84).

[0690] [Chemical Formula 56]

[0691]

[0692] In the compound represented by formula (L-12) (hereinafter referred to as compound (L-12)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX85).

[0693] In compound (L-12), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX86).

[0694] In compound (L-12), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX87).

[0695] In compound (L-12), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX88).

[0696] In compound (L-12), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX89).

[0697] In compound (L-12), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX90).

[0698] In compound (L-12), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX91).

[0699] In compound (L-12), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX92).

[0700] In compound (L-12), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX93).

[0701] In compound (L-12), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX94).

[0702] In compound (L-12), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX95).

[0703] In compound (L-12), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX96).

[0704] In compound (L-12), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX97).

[0705] In compound (L-12), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX98).

[0706] In compound (L-12), R 2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX99).

[0707] In compound (L-12), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX100).

[0708] [Chemical Formula 57]

[0709]

[0710] In the compound represented by formula (L-13) (hereinafter referred to as compound (L-13)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX101).

[0711] In compound (L-13), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX102).

[0712] In compound (L-13), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX103).

[0713] In compound (L-13), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX104).

[0714] In compound (L-13), R2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX105).

[0715] In compound (L-13), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX106).

[0716] In compound (L-13), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX107).

[0717] In compound (L-13), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX108).

[0718] In compound (L-13), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX109).

[0719] In compound (L-13), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX110).

[0720] In compound (L-13), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX111).

[0721] In compound (L-13), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX112).

[0722] In compound (L-13), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX113).

[0723] In compound (L-13), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX114).

[0724] In compound (L-13), R 2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX115).

[0725] In compound (L-13), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX116).

[0726] [Chemical Formula 58]

[0727]

[0728] In the compound represented by formula (L-14) (hereinafter referred to as compound (L-14)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX117).

[0729] In compound (L-14), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX118).

[0730] In compound (L-14), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX119).

[0731] In compound (L-14), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX120).

[0732] In compound (L-14), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX121).

[0733] In compound (L-14), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX122).

[0734] In compound (L-14), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX123).

[0735] In compound (L-14), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX124).

[0736] In compound (L-14), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX125).

[0737] In compound (L-14), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX126).

[0738] In compound (L-14), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX127).

[0739] In compound (L-14), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3dis a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX128).

[0740] In compound (L-14), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX129).

[0741] In compound (L-14), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX130).

[0742] In compound (L-14), R 2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX131).

[0743] In compound (L-14), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX132).

[0744] [Chemical Formula 59]

[0745]

[0746] In the compound represented by formula (L-15) (hereinafter referred to as compound (L-15)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX137).

[0747] In compound (L-15), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX138).

[0748] In compound (L-15), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX139).

[0749] In compound (L-15), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX140).

[0750] In compound (L-15), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX141).

[0751] In compound (L-15), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX142).

[0752] In compound (L-15), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX143).

[0753] In compound (L-15), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX144).

[0754] In compound (L-15), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX145).

[0755] In compound (L-15), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX146).

[0756] In compound (L-15), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX147).

[0757] In compound (L-15), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX148).

[0758] In compound (L-15), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX149).

[0759] In compound (L-15), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX150).

[0760] In compound (L-15), R 2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX151).

[0761] In compound (L-15), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX152).

[0762] [Chemical Formula 60]

[0763]

[0764] In the compound represented by formula (L-16) (hereinafter referred to as compound (L-16)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX153).

[0765] In compound (L-16), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX154).

[0766] In compound (L-16), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3dis a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX155).

[0767] In compound (L-16), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX156).

[0768] In compound (L-16), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX157).

[0769] In compound (L-16), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX158).

[0770] In compound (L-16), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX159).

[0771] In compound (L-16), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX160).

[0772] In compound (L-16), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX161).

[0773] In compound (L-16), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX162).

[0774] In compound (L-16), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX163).

[0775] In compound (L-16), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX164).

[0776] In compound (L-16), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX165).

[0777] In compound (L-16), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX166).

[0778] In compound (L-16), R 2a and R 2b is methyl, R 6 is methyl, R3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX167).

[0779] In compound (L-16), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX168).

[0780] [Chemical Formula 61]

[0781]

[0782] In the compound represented by formula (L-17) (hereinafter referred to as compound (L-17)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX169).

[0783] In compound (L-17), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX170).

[0784] In compound (L-17), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX171).

[0785] In compound (L-17), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX172).

[0786] In compound (L-17), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX173).

[0787] In compound (L-17), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX174).

[0788] In compound (L-17), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX175).

[0789] In compound (L-17), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX176).

[0790] In compound (L-17), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX177).

[0791] In compound (L-17), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX178).

[0792] In compound (L-17), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX179).

[0793] In compound (L-17), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX180).

[0794] In compound (L-17), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX181).

[0795] In compound (L-17), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX182).

[0796] In compound (L-17), R 2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX183).

[0797] In compound (L-17), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX184).

[0798] [Chemical Formula 62]

[0799]

[0800] In the compound represented by formula (L-18) (hereinafter referred to as compound (L-18)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX185).

[0801] In compound (L-18), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX186).

[0802] In compound (L-18), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX187).

[0803] In compound (L-18), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX188).

[0804] In compound (L-18), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX189).

[0805] In compound (L-18), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX190).

[0806] In compound (L-18), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX191).

[0807] In compound (L-18), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX192).

[0808] In compound (L-18), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX193).

[0809] In compound (L-18), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX194).

[0810] In compound (L-18), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX195).

[0811] In compound (L-18), R 2a is ethyl, R 2b is a hydrogen atom, R 6is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX196).

[0812] In compound (L-18), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX197).

[0813] In compound (L-18), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX198).

[0814] In compound (L-18), R 2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX199).

[0815] In compound (L-18), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX200).

[0816] [Chemical Formula 63]

[0817]

[0818] In the compound represented by formula (L-19) (hereinafter referred to as compound (L-19)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX201).

[0819] In compound (L-19), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX202).

[0820] In compound (L-19), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX203).

[0821] In compound (L-19), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX204).

[0822] In compound (L-19), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX205).

[0823] In compound (L-19), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX206).

[0824] In compound (L-19), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX207).

[0825] In compound (L-19), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX208).

[0826] In compound (L-19), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX209).

[0827] In compound (L-19), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX210).

[0828] In compound (L-19), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX211).

[0829] In compound (L-19), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX212).

[0830] In compound (L-19), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX213).

[0831] In compound (L-19), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX214).

[0832] In compound (L-19), R 2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX215).

[0833] In compound (L-19), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX216).

[0834] [Chemical Formula 64]

[0835]

[0836] In the compound represented by formula (L-20) (hereinafter referred to as compound (L-20)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX217).

[0837] In compound (L-20), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX218).

[0838] In compound (L-20), R2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX219).

[0839] In compound (L-20), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX220).

[0840] In compound (L-20), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX221).

[0841] In compound (L-20), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX222).

[0842] In compound (L-20), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX223).

[0843] In compound (L-20), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX224).

[0844] In compound (L-20), R2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX225).

[0845] In compound (L-20), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX226).

[0846] In compound (L-20), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX227).

[0847] In compound (L-20), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX228).

[0848] In compound (L-20), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX229).

[0849] In compound (L-20), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX230).

[0850] In compound (L-20), R2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX231).

[0851] In compound (L-20), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX232).

[0852] [Chemical Formula 65]

[0853]

[0854] In the compound represented by formula (L-21) (hereinafter referred to as compound (L-21)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX233).

[0855] In compound (L-21), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX234).

[0856] In compound (L-21), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX235).

[0857] In compound (L-21), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX236).

[0858] In compound (L-21), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX237).

[0859] In compound (L-21), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX238).

[0860] In compound (L-21), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX239).

[0861] In compound (L-21), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX240).

[0862] [Chemical Formula 66]

[0863]

[0864] In the compound represented by formula (L-22) (hereinafter referred to as compound (L-22)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX241).

[0865] In compound (L-22), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX242).

[0866] In compound (L-22), R 2ais methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX243).

[0867] In compound (L-22), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX244).

[0868] In compound (L-22), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX245).

[0869] In compound (L-22), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX246).

[0870] In compound (L-22), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX247).

[0871] In compound (L-22), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX248).

[0872] [Chemical Formula 67]

[0873]

[0874] In the compound represented by formula (L-23) (hereinafter referred to as compound (L-23)), R 2a and R 2bis a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX249).

[0875] In compound (L-23), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX250).

[0876] In compound (L-23), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX251).

[0877] In compound (L-23), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX252).

[0878] In compound (L-23), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX253).

[0879] In compound (L-23), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX254).

[0880] In compound (L-23), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX255).

[0881] In compound (L-23), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX256).

[0882] [Chemical Formula 68]

[0883]

[0884] In the compound represented by formula (L-24) (hereinafter referred to as compound (L-24)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX257).

[0885] In compound (L-24), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX258).

[0886] In compound (L-24), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX259).

[0887] In compound (L-24), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX260).

[0888] In compound (L-24), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX261).

[0889] In compound (L-24), R2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX262).

[0890] In compound (L-24), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX263).

[0891] In compound (L-24), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX264).

[0892] [Chemical Formula 69]

[0893]

[0894] In the compound represented by formula (L-25) (hereinafter referred to as compound (L-25)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX265).

[0895] In compound (L-25), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX266).

[0896] In compound (L-25), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX267).

[0897] In compound (L-25), R 2a is methyl, R2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX268).

[0898] In compound (L-25), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX269).

[0899] In compound (L-25), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX270).

[0900] In compound (L-25), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX271).

[0901] In compound (L-25), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX272).

[0902] [Chemical Formula 70]

[0903]

[0904] In the compound represented by formula (L-26) (hereinafter referred to as compound (L-26)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX273).

[0905] In compound (L-26), R 2a and R 2b is a hydrogen atom, R3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX274).

[0906] In compound (L-26), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX275).

[0907] In compound (L-26), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX276).

[0908] In compound (L-26), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX277).

[0909] In compound (L-26), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX278).

[0910] In compound (L-26), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX279).

[0911] In compound (L-26), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX280).

[0912] [Chemical Formula 71]

[0913]

[0914] In the compound represented by formula (L-27) (hereinafter referred to as compound (L-27)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX281).

[0915] In compound (L-27), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX282).

[0916] In compound (L-27), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX283).

[0917] In compound (L-27), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX284).

[0918] In compound (L-27), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX285).

[0919] In compound (L-27), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX286).

[0920] In compound (L-27), R 2aand R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX287).

[0921] In compound (L-27), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX288).

[0922] [Chemical Formula 72]

[0923]

[0924] In the compound represented by formula (L-28) (hereinafter referred to as compound (L-28)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX289).

[0925] In compound (L-28), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX290).

[0926] In compound (L-28), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX291).

[0927] In compound (L-28), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX292).

[0928] In compound (L-28), R 2a is ethyl, R 2bis a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX293).

[0929] In compound (L-28), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX294).

[0930] In compound (L-28), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX295).

[0931] In compound (L-28), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX296).

[0932] [Chemical Formula 73]

[0933]

[0934] In the compound represented by formula (L-29) (hereinafter referred to as compound (L-29)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX297).

[0935] In compound (L-29), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX298).

[0936] In compound (L-29), R 2a is methyl, R 2b is a hydrogen atom, R 3bis a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX299).

[0937] In compound (L-29), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX300).

[0938] In compound (L-29), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX301).

[0939] In compound (L-29), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX302).

[0940] In compound (L-29), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX303).

[0941] In compound (L-29), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX304).

[0942] [Chemical Formula 74]

[0943]

[0944] In the compound represented by formula (L-30) (hereinafter referred to as compound (L-30)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX305).

[0945] In compound (L-30), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX306).

[0946] In compound (L-30), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX307).

[0947] In compound (L-30), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX308).

[0948] In compound (L-30), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX309).

[0949] In compound (L-30), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX310).

[0950] In compound (L-30), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX311).

[0951] In compound (L-30), R 2a and R 2bis methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX312).

[0952] [Chemical Formula 75]

[0953]

[0954] In the compound represented by formula (L-31) (hereinafter referred to as compound (L-31)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX313).

[0955] In compound (L-31), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX314).

[0956] In compound (L-31), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX315).

[0957] In compound (L-31), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX316).

[0958] In compound (L-31), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX317).

[0959] In compound (L-31), R 2a is ethyl, R 2b is a hydrogen atom, R3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX318).

[0960] In compound (L-31), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX319).

[0961] In compound (L-31), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX320).

[0962] [Chemical Formula 76]

[0963]

[0964] In the compound represented by formula (L-32) (hereinafter referred to as compound (L-32)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX321).

[0965] In compound (L-32), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX322).

[0966] In compound (L-32), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX323).

[0967] In compound (L-32), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX324).

[0968] In compound (L-32), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX325).

[0969] In compound (L-32), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX326).

[0970] In compound (L-32), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX327).

[0971] In compound (L-32), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX328).

[0972] [Chemical Formula 77]

[0973]

[0974] In the compound represented by formula (L-33) (hereinafter referred to as compound (L-33)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX329).

[0975] In compound (L-33), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX330).

[0976] In compound (L-33), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX331).

[0977] In compound (L-33), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX332).

[0978] In compound (L-33), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX333).

[0979] In compound (L-33), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX334).

[0980] In compound (L-33), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX335).

[0981] In compound (L-33), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX336).

[0982] [Chemical Formula 78]

[0983]

[0984] In the compound represented by formula (L-34) (hereinafter referred to as compound (L-34)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX337).

[0985] In compound (L-34), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX338).

[0986] In compound (L-34), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX339).

[0987] In compound (L-34), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX340).

[0988] In compound (L-34), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX341).

[0989] In compound (L-34), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX342).

[0990] In compound (L-34), R 2a and R 2b is methyl, R3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX343).

[0991] In compound (L-34), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX344).

[0992] [Chemical Formula 79]

[0993]

[0994] In the compound represented by formula (L-35) (hereinafter referred to as compound (L-35)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX345).

[0995] In compound (L-35), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX346).

[0996] In compound (L-35), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX347).

[0997] In compound (L-35), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX348).

[0998] In compound (L-35), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX349).

[0999] In compound (L-35), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX350).

[1000] In compound (L-35), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX351).

[1001] In compound (L-35), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX352).

[1002] [Chemical formula 80]

[1003]

[1004] In the compound represented by formula (L-36) (hereinafter referred to as compound (L-36)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX353).

[1005] In compound (L-36), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX354).

[1006] In compound (L-36), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX355).

[1007] In compound (L-36), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX356).

[1008] In compound (L-36), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX357).

[1009] In compound (L-36), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX358).

[1010] In compound (L-36), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX359).

[1011] In compound (L-36), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX360).

[1012] [Chemical Formula 81]

[1013]

[1014] In the compound represented by formula (L-37) (hereinafter referred to as compound (L-37)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX361).

[1015] In compound (L-37), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX362).

[1016] In compound (L-37), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX363).

[1017] In compound (L-37), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX364).

[1018] In compound (L-37), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX365).

[1019] In compound (L-37), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX366).

[1020] In compound (L-37), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX367).

[1021] In compound (L-37), R 2a and R 2bis methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX368).

[1022] [Chemical Formula 82]

[1023]

[1024] In the compound represented by formula (L-38) (hereinafter referred to as compound (L-38)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX369).

[1025] In compound (L-38), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX370).

[1026] In compound (L-38), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX371).

[1027] In compound (L-38), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX372).

[1028] In compound (L-38), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX373).

[1029] In compound (L-38), R 2a is ethyl, R 2b is a hydrogen atom, R3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX374).

[1030] In compound (L-38), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX375).

[1031] In compound (L-38), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX376).

[1032] [Chemical Formula 83]

[1033]

[1034] In the compound represented by formula (L-39) (hereinafter referred to as compound (L-39)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX377).

[1035] In compound (L-39), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX378).

[1036] In compound (L-39), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX379).

[1037] In compound (L-39), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX380).

[1038] In compound (L-39), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX381).

[1039] In compound (L-39), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX382).

[1040] In compound (L-39), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX383).

[1041] In compound (L-39), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX384).

[1042] [Chemical formula 84]

[1043]

[1044] In the compound represented by formula (L-40) (hereinafter referred to as compound (L-40)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX385).

[1045] In compound (L-40), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX386).

[1046] In compound (L-40), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX387).

[1047] In compound (L-40), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX388).

[1048] In compound (L-40), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX389).

[1049] In compound (L-40), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX390).

[1050] In compound (L-40), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX391).

[1051] In compound (L-40), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX392).

[1052] [Chemical Formula 85]

[1053]

[1054] In the compound represented by formula (L-41) (hereinafter referred to as compound (L-41)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX393).

[1055] In compound (L-41), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX394).

[1056] In compound (L-41), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX395).

[1057] In compound (L-41), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX396).

[1058] In compound (L-41), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX397).

[1059] In compound (L-41), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX398).

[1060] In compound (L-41), R 2a and R 2b is methyl, R3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX399).

[1061] In compound (L-41), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX400).

[1062] [Chemical Formula 86]

[1063]

[1064] In the compound represented by formula (L-42) (hereinafter referred to as compound (L-42)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX401).

[1065] In compound (L-42), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX402).

[1066] In compound (L-42), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX403).

[1067] In compound (L-42), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX404).

[1068] In compound (L-42), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX405).

[1069] In compound (L-42), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX406).

[1070] In compound (L-42), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX407).

[1071] In compound (L-42), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX408).

[1072] [Chemical Formula 87]

[1073]

[1074] In the compound represented by formula (L-43) (hereinafter referred to as compound (L-43)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX409).

[1075] In compound (L-43), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX410).

[1076] In compound (L-43), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX411).

[1077] In compound (L-43), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX412).

[1078] In compound (L-43), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX413).

[1079] In compound (L-43), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX414).

[1080] In compound (L-43), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX415).

[1081] In compound (L-43), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX416).

[1082] [Chemical Formula 88]

[1083]

[1084] In the compound represented by formula (L-44) (hereinafter referred to as compound (L-44)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX417).

[1085] In compound (L-44), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX418).

[1086] In compound (L-44), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX419).

[1087] In compound (L-44), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX420).

[1088] In compound (L-44), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX421).

[1089] In compound (L-44), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX422).

[1090] In compound (L-44), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX423).

[1091] In compound (L-44), R 2a and R 2bis methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX424).

[1092] [Chemical Formula 89]

[1093]

[1094] In the compound represented by formula (L-45) (hereinafter referred to as compound (L-45)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX425).

[1095] In compound (L-45), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX426).

[1096] In compound (L-45), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX427).

[1097] In compound (L-45), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX428).

[1098] In compound (L-45), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX429).

[1099] In compound (L-45), R 2a is ethyl, R 2b is a hydrogen atom, R3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX430).

[1100] In compound (L-45), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX431).

[1101] In compound (L-45), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX432).

[1102] [Chemical formula 90]

[1103]

[1104] In the compound represented by formula (L-46) (hereinafter referred to as compound (L-46)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX433).

[1105] In compound (L-46), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX434).

[1106] In compound (L-46), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX435).

[1107] In compound (L-46), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX436).

[1108] In compound (L-46), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX437).

[1109] In compound (L-46), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX438).

[1110] In compound (L-46), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX439).

[1111] In compound (L-46), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX440).

[1112] [Chemical Formula 91]

[1113]

[1114] In the compound represented by formula (L-47) (hereinafter referred to as compound (L-47)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX441).

[1115] In compound (L-47), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX442).

[1116] In compound (L-47), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX443).

[1117] In compound (L-47), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX444).

[1118] In compound (L-47), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX445).

[1119] In compound (L-47), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX446).

[1120] In compound (L-47), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX447).

[1121] In compound (L-47), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX448).

[1122] [Chemical Formula 92]

[1123]

[1124] In the compound represented by formula (L-48) (hereinafter referred to as compound (L-48)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX449).

[1125] In compound (L-48), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX450).

[1126] In compound (L-48), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX451).

[1127] In compound (L-48), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX452).

[1128] In compound (L-48), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX453).

[1129] In compound (L-48), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX454).

[1130] In compound (L-48), R 2a and R 2b is methyl, R3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX455).

[1131] In compound (L-48), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX456).

[1132] [Chemical Formula 93]

[1133]

[1134] In the compound represented by formula (L-49) (hereinafter referred to as compound (L-49)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX457).

[1135] In compound (L-49), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX458).

[1136] In compound (L-49), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX459).

[1137] In compound (L-49), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX460).

[1138] In compound (L-49), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX461).

[1139] In compound (L-49), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX462).

[1140] In compound (L-49), R 2a and R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX463).

[1141] In compound (L-49), R 2a and R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX464).

[1142] [Chemical Formula 94]

[1143]

[1144] In the compound represented by formula (L-50) (hereinafter referred to as compound (L-50)), R 2a and R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX501).

[1145] In compound (L-50), R 2a and R 2b is a hydrogen atom, R 6 The compounds wherein R is an ethyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX502).

[1146] In compound (L-50), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX503).

[1147] In compound (L-50), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX504).

[1148] In compound (L-50), R 2a is ethyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX505).

[1149] In compound (L-50), R 2a is ethyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX506).

[1150] In compound (L-50), R 2a and R 2b is methyl, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX507).

[1151] In compound (L-50), R 2a and R 2b is methyl, R 6 The compounds wherein R is an ethyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX508).

[1152] [Chemical Formula 95]

[1153]

[1154] In the compound represented by formula (L-51) (hereinafter referred to as compound (L-51)), R 2a and R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX509).

[1155] In compound (L-51), R 2a and R 2b is a hydrogen atom, R 6The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX510).

[1156] In compound (L-51), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX511).

[1157] In compound (L-51), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX512).

[1158] In compound (L-51), R 2a is ethyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX513).

[1159] In compound (L-51), R 2a is ethyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX514).

[1160] In compound (L-51), R 2a and R 2b is methyl, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX515).

[1161] In compound (L-51), R 2a and R 2b is methyl, R 6 The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX516).

[1162] [Chemical Formula 96]

[1163]

[1164] In the compound represented by formula (L-52) (hereinafter referred to as compound (L-52)), R 2a and R2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX517).

[1165] In compound (L-52), R 2a and R 2b is a hydrogen atom, R 6 The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX518).

[1166] In compound (L-52), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX519).

[1167] In compound (L-52), R 2a is methyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX520).

[1168] In compound (L-52), R 2a is ethyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX521).

[1169] In compound (L-52), R 2a is ethyl, R 2b is a hydrogen atom, R 6 The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX522).

[1170] In compound (L-52), R 2a and R 2b is methyl, R 6 The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX523).

[1171] In compound (L-52), R 2a and R 2b is methyl, R 6The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX524).

[1172] [Chemical Formula 97]

[1173]

[1174] In the compound represented by formula (L-53) (hereinafter referred to as compound (L-53)), R 2a and R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX525).

[1175] In compound (L-53), R 2a is methyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX526).

[1176] In compound (L-53), R 2a is ethyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX527).

[1177] In compound (L-53), R 2a and R 2b The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX528).

[1178] [Chemical Formula 98]

[1179]

[1180] In the compound represented by formula (L-54) (hereinafter referred to as compound (L-54)), R 2a and R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX529).

[1181] In compound (L-54), R 2a is methyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX530).

[1182] In compound (L-54), R 2a is ethyl, R 2bThe compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX531).

[1183] In compound (L-54), R 2a and R 2b The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX532).

[1184] [Chemical Formula 99]

[1185]

[1186] In the compound represented by formula (L-55) (hereinafter referred to as compound (L-55)), R 2a and R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX533).

[1187] In compound (L-55), R 2a is methyl, R 2b A compound wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX534).

[1188] In compound (L-55), R 2a is ethyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX535).

[1189] In compound (L-55), R 2a and R 2b The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX536).

[1190] [Chemical Formula 100]

[1191]

[1192] In the compound represented by formula (L-56) (hereinafter referred to as compound (L-56)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX537).

[1193] In compound (L-56), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX538).

[1194] In compound (L-56), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX539).

[1195] In compound (L-56), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX540).

[1196] In compound (L-56), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX541).

[1197] In compound (L-56), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX542).

[1198] In compound (L-56), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX543).

[1199] In compound (L-56), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX544).

[1200] In compound (L-56), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX545).

[1201] In compound (L-56), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX546).

[1202] In compound (L-56), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX547).

[1203] In compound (L-56), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX548).

[1204] In compound (L-56), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX549).

[1205] In compound (L-56), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX550).

[1206] In compound (L-56), R 2a and R 2b is methyl, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX551).

[1207] In compound (L-56), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX552).

[1208] [Chemical Formula 101]

[1209]

[1210] In the compound represented by formula (L-57) (hereinafter referred to as compound (L-57)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX553).

[1211] In compound (L-57), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX554).

[1212] In compound (L-57), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3dis a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX555).

[1213] In compound (L-57), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX556).

[1214] In compound (L-57), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX557).

[1215] In compound (L-57), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX558).

[1216] In compound (L-57), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX559).

[1217] In compound (L-57), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX560).

[1218] In compound (L-57), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX561).

[1219] In compound (L-57), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX562).

[1220] In compound (L-57), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX563).

[1221] In compound (L-57), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX564).

[1222] In compound (L-57), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX565).

[1223] In compound (L-57), R 2a and R 2b is methyl, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX566).

[1224] In compound (L-57), R 2a and R 2b is methyl, R 6 is methyl, R3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX567).

[1225] In compound (L-57), R 2a and R 2b is methyl, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX568).

[1226] [Chemical Formula 102]

[1227]

[1228] In the compound represented by formula (L-58) (hereinafter referred to as compound (L-58)), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX569).

[1229] In compound (L-58), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX570).

[1230] In compound (L-58), R 2a and R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX571).

[1231] In compound (L-58), R 2a and R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX572).

[1232] In compound (L-58), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX573).

[1233] In compound (L-58), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX574).

[1234] In compound (L-58), R 2a is methyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX575).

[1235] In compound (L-58), R 2a is methyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX576).

[1236] In compound (L-58), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX577).

[1237] In compound (L-58), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX578).

[1238] In compound (L-58), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX579).

[1239] In compound (L-58), R 2a is ethyl, R 2b is a hydrogen atom, R 6 is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX580).

[1240] In compound (L-58), R 2a and R 2b is methyl, R 6 is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX581).

[1241] In compound (L-58...

Claims

1. A compound represented by formula (I) or an N-oxide thereof, [Chemical formula 1] In formula (I), Q shown in the following formula represents a group shown in formula Q1, a group shown in formula Q2, a group shown in formula Q3, a group shown in formula Q4, a group shown in formula Q5, a group shown in formula Q6, or a group shown in formula Q7 (# represents a bonding site with a sulfur atom, ● represents a bonding site with Het), [Chemical formula 2] [Chemical formula 3] A 1 Indicates NR 5 , oxygen atoms or sulfur atoms, G 1 , G 2 , G 3 and G 4 The combination of: G 1 is a nitrogen atom or CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c combination of; G 1 CR 3a , G 2 is a nitrogen atom, G 3 CR 3d , G 4 CR 3c combination of; G 1 CR 3a , G 2 CR 3b , G 3 is a nitrogen atom, G 4 CR 3c or G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 is the combination of nitrogen atoms, R 2a and R 2b are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom, R 2a and R 2b Together with the nitrogen atom to which they are bound, they may form an aziridinyl, azetidinyl, pyrrolidinyl or piperidinyl group, R 3a , R 3b , R 3c , R 3d , R 3f , R 3g , R 3i and R 3k are the same or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group B, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from group E, a phenyl group which may be substituted by one or more substituents selected from group H, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group H, or an OR 12 NR 11 R 12 NR 11a R 12a NR 24 NR 11 R 12 NR 24 OR 11 NR 11 C(O)R 13 NR 24 NR 11 C(O)R 13 NR 11 C(O)OR 14 NR 24 NR 11 C(O)OR 14 NR 11 C(O)NR 31 R 32 NR 24 NR 11 C(O)NR 31 R 32 、N=CHNR 31 R 32 、N=S(O) p R 15 R 16 、C(O)R 13 、C(O)OR 17 、C(O)NR 31 R 32 、C(O)NR 11 S(O)2R 23 , CR 30 =NOR 17 NR 11 CR 24 =NOR 17 、S(O) q R 23 , cyano group, nitro group, hydrogen atom or halogen atom, R 3e and R 3h are the same or different from each other and represent a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from Group H, When Q is a group represented by the formula Q1, R 3a , R 3b and R 3d The two adjacent substituents in the may form, together with the two carbon atoms to which they are bonded, a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring and the pyrazine ring may be substituted with one or more substituents selected from Group H}, or a triazole ring which may be substituted with one or more substituents selected from Group I, p represents 0 or 1, q represents 0, 1 or 2, R 30 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a halogen atom, or OR 35 NR 36 R 37 , or hydrogen atoms, R 17 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from Group D, or a hydrogen atom, R 12 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from group J, a C3-C7 cycloalkenyl group which may be substituted by one or more substituents selected from group J, a phenyl group which may be substituted by one or more substituents selected from group D, a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group D, a hydrogen atom, or S(O)2R 23 , R 23 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from Group D, R 11a and R 12a Together with the nitrogen atom to which they are bonded, they represent a 3- to 7-membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from Group E, R 13 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, or a hydrogen atom, R 14 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group D}, R 15 and R 16 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, R 31 represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom, R 32 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group J, or a hydrogen atom, Het represents a group represented by formula Het1, a group represented by formula Het2, a group represented by formula Het3, a group represented by formula Het4, a group represented by formula Het5, a group represented by formula Het6, or a group represented by formula Het7, [Chemical formula 4] A 2 Represents nitrogen atom or CR 4a , A 3 Represents nitrogen atom or CR 4b , A 4 Represents nitrogen atom or CR 4c , W 1 represents an oxygen atom or a sulfur atom, When Het is a group represented by the formula Het5 or Het6, A 2 and A 3 The combination of: A 2 CR 4a , A 3 is a nitrogen atom or CR 4b or, A 2 is a nitrogen atom, A 3 CR 4b A combination of B 1 , B 2 and B 3 The combination of: B 1 CR 6e , B 2 is a nitrogen atom or CR 6b , B 3 is a nitrogen atom or CR 6c combination of; B 1 is a nitrogen atom or CR 6a , B 2 CR 6e , B 3 is a nitrogen atom or CR 6c or B 1 is a nitrogen atom or CR 6a , B 2 is a nitrogen atom or CR 6b , B 3 CR 6e A combination of When Het is a group represented by the formula Het7, A 2 and A 3 The combination of: A 2 CR 4a , A 3 is a nitrogen atom or CR 4b or, A 2 is a nitrogen atom, A 3 is a nitrogen atom or CR 4b A combination of B 1 , B 2 , B 3 and B 4 The combination of: B 1 is a nitrogen atom or CR 6a , B 2 CR 6e , B 3 is a nitrogen atom or CR 6c , B 4 is a nitrogen atom or CR 6d combination of; B 1 is a nitrogen atom or CR 6a , B 2 is a nitrogen atom or CR 6b , B 3 CR 6e , B 4 is a nitrogen atom or CR 6d combination of; B 1 is a nitrogen atom or CR 6a , B 2 is a nitrogen atom or CR 6b , B 3 CR 6c , B 4 CR 6e combination of; B 1 is a nitrogen atom or CR 6a , B 2 CR 6b , B 3 is a nitrogen atom, B 4 CR 6e or B 1 CR 6a , B 2 is a nitrogen atom, B 3 is a nitrogen atom, B 4 CR 6e A combination of R 4a , R 4b , R 4c , R 6a , R 6b , R 6c , R 6d The same or different, representing a C1-C6 chain hydrocarbon group, nitro group, OR 18 NR 18 R 19 , cyano group, amino group, halogen atom or hydrogen atom, R 6e represents a C1-C6 chain hydrocarbon group substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C4 cycloalkyl group which may be substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 , OR 7 , halogen atom or OS(O)2R 7 , R 6 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C6 cycloalkyl group which may be substituted by one or more substituents selected from Group J, a phenyl group which may be substituted by one or more substituents selected from Group H, or a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group H, T represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C3-C5 alkenyloxy)C2-C5 alkyl group, a (C3-C5 alkynyloxy)C2-C5 alkyl group, or a (C1-C5 alkyl)-S(O) group. w -(C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) w -(C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) w -(C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O) w -(C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) w -(C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) w -(C2-C5 alkyl) group, and the (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms}, (C3-C7 cycloalkyl)C1-C3 alkyl substituted with one or more substituents selected from group G, C3-C7 cycloalkyl substituted with one or more substituents selected from group G, OR 1 、S(O) v R 1 、OS(O)2R 1 、CH2OR 1 NR 1 R 29 、C(O)R 1 、C(O)NR 1 R 29 NR 29 C(O)R 1 、N=CR 1 R 30 , a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12, [Chemical formula 5] [Chemical formula 6] [Chemical formula 7] X 1 Represents nitrogen atom or CR 1a , X 2 Represents nitrogen atom or CR 1b , X 3 Represents nitrogen atom or CR 1c , X 4 Represents nitrogen atom or CR 1d , X 5 Represents nitrogen atom or CR 1e , R 1x represents a C1-C5 chain hydrocarbon group substituted with one or more halogen atoms, OR 7 、OS(O)2R 7 、S(O) m R 7 NR 8 S(O)2R 7 or halogen atoms, R 1a , R 1b , R 1c , R 1d and R 1e are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom, Y 1 Indicates NR 25 , oxygen atoms or sulfur atoms, Y 2 Represents nitrogen atom or CR 26 , Y 3 Represents nitrogen atom or CR 27 , Y 4 Represents nitrogen atom or CR 28 , R 5 and R 25 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom, R 26 , R 27 and R 28 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom, R 1y represents a C1-C5 chain hydrocarbon group substituted with one or more halogen atoms, OR 7 、OS(O)2R 7 、S(O) m R 7 NR 8 S(O)2R 7 , cyano or halogen atoms, R 1ay and R 7 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group substituted by one or more halogen atoms, m and v are the same or different, representing 0, 1 or 2, w and t are the same or different from each other and represent 0, 1 or 2. R 1 represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C3-C5 alkenyloxy)C2-C5 alkyl group, a (C3-C5 alkynyloxy)C2-C5 alkyl group, a (C1-C5 alkyl)-S(O) t -(C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) t -(C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) t -(C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O) t -(C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) t -(C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) t -(C2-C5 alkyl) group, and the (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms}, (C3-C7 cycloalkyl)C1-C3 alkyl substituted with one or more substituents selected from group G, or C3-C7 cycloalkyl substituted with one or more substituents selected from group G, R 18 and R 35 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, R 8 , R 11 , R 19 , R 24 , R 29 , R 36 and R 37 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, or a hydrogen atom, Group B: the group consisting of C1-C6 alkoxy groups which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfanyl groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfinyl groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfonyl groups which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl groups which may be substituted by one or more halogen atoms, cyano groups, hydroxyl groups and halogen atoms. Group C: a group consisting of a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, and a halogen atom, Group D: C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, hydroxyl group, C1-C6 alkoxy group which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, sulfanyl group, C1-C6 alkylsulfanyl group which may be substituted by one or more halogen atoms, C1-C6 alkylsulfinyl group which may be substituted by one or more halogen atoms, C1-C6 alkylsulfonyl group which may be substituted by one or more halogen atoms, amino group, NHR 21 NR 21 R 22 、C(O)R 21 、OC(O)R 21 、C(O)OR 21 , cyano, nitro and halogen atoms, R 21 and R 22 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, Group E: the group consisting of C1-C6 chain hydrocarbon groups which may be substituted by one or more halogen atoms, C1-C6 alkoxy groups which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted by one or more halogen atoms, halogen atoms, oxo groups, hydroxyl groups, cyano groups and nitro groups, Group F: C1-C6 alkoxy which may be substituted with one or more halogen atoms, phenyl which may be substituted with one or more substituents selected from group D, 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group D, C3-C7 cycloalkyl which may be substituted with one or more halogen atoms, 3-7-membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group C, amino, NHR 21 NR 21 R 22 , a group consisting of a halogen atom and a cyano group, Group G: a group consisting of halogen atoms, C1-C6 haloalkyl groups and cyano groups, Group H: C1-C6 alkyl which may be substituted with one or more halogen atoms, OR 10 NR 9 R 10 、C(O)R 10 、C(O)NR 9 R 10 、OC(O)R 9 、OC(O)OR 9 NR 10 C(O)R 9 NR 10 C(O)OR 9 、C(O)OR 10 , a halogen atom, a nitro group, a cyano group, an amino group and a 5- or 6-membered aromatic heterocyclic group, R 9 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, R 10 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom, Group I: a group consisting of a C2-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group D, a C2-C6 alkylcarbonyl group which may be substituted by one or more halogen atoms, a C2-C6 alkoxycarbonyl group which may be substituted by one or more halogen atoms, an aminocarbonyl group, a (C1-C6 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms, a methyl group, and a di(C1-C4 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms, Group J: A group consisting of a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a halogen atom, and a cyano group.

2. The compound or N-oxide thereof according to claim 1, wherein Q is a group represented by the formula Q1 or a group represented by the formula Q5.

3. The compound or N-oxide thereof according to claim 1, wherein Q is a group represented by the formula Q5.

4. The compound or N-oxide thereof according to claim 3, wherein G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c .

5. The compound or N-oxide thereof according to any one of claims 1 to 4, wherein Het is a group represented by the formula Het1, A 2 CR 4a , A 3 CR 4b or nitrogen atoms.

6. The compound or N-oxide thereof according to any one of claims 1 to 4, wherein Het is a group represented by the formula Het5, A 2 CR 4a , A 3 CR 4b , B 1 CR 6a , B 2 CR 6e , B 3 A nitrogen atom.

7. The compound or N-oxide thereof according to any one of claims 1 to 4, wherein Het is a group represented by the formula Het7, A 2 CR 4a , A 3 is a nitrogen atom, B 1 CR 6a , B 2 CR 6e , B 3 CR 6c , B 4 CR 6d . 8 . A harmful arthropod control composition comprising an inactive carrier and the compound or N-oxide thereof according to claim 1 .

9. A composition comprising one or more components selected from the group consisting of group (a), group (b), group (c) and group (d), and the compound or N-oxide thereof according to any one of claims 1 to 7, Group (a): a group consisting of insecticidal active ingredients, acaricidal active ingredients and nematicidal active ingredients; Group (b): fungicidal active ingredients; Group (c): plant growth regulating ingredients; Group (d): repellent ingredients.

10. A method for controlling harmful arthropods, wherein: An effective amount of the compound or N-oxide thereof according to any one of claims 1 to 7 or an effective amount of the composition according to claim 9 is applied to a harmful arthropod or a habitat of a harmful arthropod.

11. A seed or a vegetative propagation organ, which holds an effective amount of the compound according to any one of claims 1 to 7 or an N-oxide thereof, or an effective amount of the composition according to claim 9.

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