Pesticide composition and application thereof

By combining sulfifflumin with triazole tin or benzyl tin, an efficient compound acaricide with a multi-action mechanism is formed, which solves the problem of difficult to effectively prevent and control agricultural mites in the existing technology, and achieves significant prevention and control effects and delays in drug resistance for citrus spider mites and apple spider mites.

CN120113680AActive Publication Date: 2025-06-10QINGDAO KYX CHEMICAL CO LTD
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Patent Information

Application Number
CN202510480028.8
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-11-29
Publication Date
2025-06-10
Estimated Expiration
2043-11-29

AI Technical Summary

Technical Problem

The existing technology is difficult to effectively prevent and control a class of more difficult-to-control pests in agriculture - mites, especially citrus spider mites and apple spider mites, and the drug resistance of vicious mites is increasing year by year.

Method used

Sulfiflumin is combined with two acaricides, triazole tin or benzyl tin, and acaricides with different mechanisms of action are used to reasonably combine to form a highly efficient compound acaricide with multiple mechanisms of action.

Benefits of technology

It significantly improves the prevention and control effect of citrus spider mites and apple spider mites, enhances the prevention and control effect, reduces the use of pesticides, and delays the resistance of drug mites.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention belongs to the technical field of pesticide mite killing, and discloses a pesticide composition and application thereof.The pesticide composition comprises an active ingredient A and an active ingredient B. The active ingredient A is sulfiflumin, and the active ingredient B is any one of azocyclotin or fenbutatin oxide. The pesticide composition has the advantages that the synergistic effect on mite pests is remarkable, the development of drug resistance is slowed down, and the use amount of pesticide is reduced.
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Description

[0001] This divisional application is a divisional application of the application with the application number 202311612836.2, the application date of November 29, 2023, and the invention name of "A Pesticide Composition and Its Application". Technical Field

[0002] The present invention belongs to the technical field of pesticide acaricides, and discloses a pesticide composition and its application. Background Art

[0003] Azocyclotin, with the CAS registration number 41083-11-8 and the chemical name of tricyclohexyl(1,2,4-triazol-1-yl)stannane, is a broad-spectrum systemic acaricide with a wide acaricidal spectrum, high activity, and safety for crops. It can control various harmful mites such as Panonychus citri, Tetranychus urticae, and Phyllocoptruta oleivora on crops such as citrus, hawthorn, apple, grape, and eggplant, and has good control effects on nymphs, adults, and eggs.

[0004] Fenbutatin oxide, with the CAS registration number 13356-08-6 and the chemical name of bis[tris(2-methyl-2-phenylpropyl)tin]oxide, is an efficient temperature-sensitive acaricide. It is mainly used for controlling mite damage on citrus, apple, grape, tea, solanaceous plants, and ornamental flowers. It can effectively kill citrus red spiders, Tetranychus urticae, Phyllocoptruta oleivora, Brevipalpus obovatus, and Panonychus citri, etc., and has the characteristics of high efficiency, low toxicity, safety, long residual period, and no resistance occurrence.

[0005] Mites are a type of harmful organisms that are relatively difficult to control in agricultural production. Especially due to the improper use of pesticides, Tetranychus urticae has risen from a minor pest to a major pest, showing a trend of increasing year by year in China.

[0006] Mixing or rotating the use of acaricides with different action mechanisms is an important means to delay the resistance of harmful mites and its management, and at the same time has the effects of reducing toxicity and cost. The compound agent with synergistic effect can not only reduce the dosage of pesticides, but also enhance the control effect, and can further delay the resistance of harmful mites. Therefore, the applicant compounded sulfiflumin with either azocyclotin or fenbutatin oxide to develop a highly efficient compound acaricide with multiple action mechanisms, provide a theoretical basis for the management of mite resistance, and further improve the control effect of harmful mites. Summary of the Invention

[0007] Based on the above content, the purpose of the present invention is to provide a pesticide composition. The pesticide composition of the present invention has excellent control effects on harmful mites such as citrus leaf mites and apple leaf mites, and has a significant synergistic effect;

[0008] Another purpose of the present invention is to provide a pesticide composition that is safe for crops;

[0009] To achieve the above object, the present invention adopts the following technical solution. A pesticide composition, wherein the active ingredients of the pesticide composition comprise active ingredient A and active ingredient B. Active ingredient A is sulfiflumin, and active ingredient B is any one of azocyclotin or fenbutatin oxide. The mass ratio of active ingredient A to active ingredient B in the pesticide composition is 1:45 to 35:1.

[0010] Further, active ingredient B in the pesticide composition is azocyclotin, and the mass ratio of active ingredient A to active ingredient B is 1:40 to 30:1;

[0011] Even further, active ingredient B in the pesticide composition is azocyclotin, and the mass ratio of active ingredient A to active ingredient B is 1:30 to 20:1;

[0012] Further, active ingredient B in the pesticide composition is fenbutatin oxide, and the mass ratio of active ingredient A to active ingredient B is 1:45 to 35:1;

[0013] Even further, active ingredient B in the pesticide composition is fenbutatin oxide, and the mass ratio of active ingredient A to active ingredient B is 1:35 to 25:1.

[0014] Further, in addition to the active ingredients, the pesticide composition further comprises agriculturally acceptable auxiliary ingredients, and the auxiliary ingredients are fillers and / or surfactants;

[0015] Further, the surfactants are wetting agents, dispersants, emulsifiers, thickeners, disintegrants, antifreezing agents, defoaming agents, preservatives, stabilizers, synergists;

[0016] Further, the wetting agent is one or more of alkylbenzene sulfonates, alkylnaphthalene sulfonates, lignin sulfonates, sodium dodecyl sulfate, sodium dioctyl sulfosuccinate, α-olefin sulfonates, alkylphenol polyoxyethylene ethers, castor oil polyoxyethylene ethers, alkylphenol ethoxylates, fatty alcohol ethoxylates, sodium fatty alcohol polyoxyethylene ether sulfate, silkworm excrement, soap pod powder, sapindus powder, SOPA, detergent, emulsifier 2000 series, and wetting penetrant F; and / or

[0017] Further, the dispersant is one or more of lignin sulfonates, alkylnaphthalene sulfonate formaldehyde condensates, naphthalene sulfonates, triphenylvinylphenol ethoxylate phosphates, fatty alcohol ethoxylates, alkylphenol polyoxyethylene ethers, alkylphenol polyoxyethylene ether methyl ether condensates sulfates, fatty amine polyoxyethylene ethers, glycerol fatty acid ester polyoxyethylene ethers, polycarboxylates, polyacrylates, phosphates, EO-PO block copolymers, and EO-PO graft copolymers; and / or

[0018] Further, the emulsifier is one or more of calcium dodecylbenzenesulfonate, alkylphenol formaldehyde resin polyoxyethylene ether, phenethylphenol polyoxyethylene polyoxypropylene ether, fatty alcohol ethylene oxide-propylene oxide copolymer, styrylphenol polyoxyethylene ether, castor oil polyoxyethylene ether, and alkylphenol ether phosphate; and / or

[0019] Further, the thickener is one or more of xanthan gum, organobentonite, gum arabic, sodium alginate, magnesium aluminum silicate, carboxymethyl cellulose, and silica white; and / or

[0020] Further, the disintegrant is one or more of sodium sulfate, ammonium sulfate, aluminum chloride, sodium chloride, ammonium chloride, bentonite, glucose, sucrose, starch, cellulose, urea, sodium carbonate, sodium bicarbonate, citric acid, and tartaric acid; and / or

[0021] Further, the antifreeze is one or more of alcohols, alcohol ethers, chlorinated hydrocarbons, and inorganic salts; and / or

[0022] Further, the defoamer is one or more of C 10 -C 20 saturated fatty acid compounds, silicone oils, silicone compounds, C 8 -C 10 fatty alcohols; and / or

[0023] Further, the preservative is one or more of propionic acid, sodium propionate, sorbic acid, sodium sorbate, potassium sorbate, benzoic acid, sodium benzoate, sodium p-hydroxybenzoate, methyl p-hydroxybenzoate, Kathon, and 1,2-benzisothiazolin-3-one; and / or

[0024] Further, the stabilizer is one or more of disodium hydrogen phosphate, oxalic acid, succinic acid, adipic acid, borax, 2,6-di-tert-butyl-p-cresol, triethanolamine oleate, epoxidized vegetable oil, kaolin, bentonite, attapulgite, silica white, talc powder, montmorillonite, and starch; and / or

[0025] Further, the synergist is selected from synergistic phosphorus and synergistic ether; and / or

[0026] Further, the filler is a solvent, a filler, or a carrier;

[0027] Further, the solvent is one or more of benzene, toluene, xylene, durene, methanol, ethanol, isopropanol, n-butanol, dimethyl sulfoxide, dimethylformamide, cyclohexanone, alkylene carbonate, diesel oil, solvent oil, vegetable oil, vegetable oil derivatives, and water; and / or

[0028] Further, the carrier is one or more of ammonium salts, ground natural minerals, ground artificial minerals, silicates, resins, waxes, solid fertilizers, water, organic solvents, mineral oils, vegetable oils, and vegetable oil derivatives.

[0029] Further, the preparation dosage form of the pesticide composition is a soluble solution, a suspension, an emulsifiable concentrate, an emulsion in water, a microcapsule suspension, a microemulsion, a suspension emulsion, a dispersible oil suspension, a granule, a water dispersible granule, or a wettable powder;

[0030] Furthermore, the preparation dosage form is a suspension, an emulsifiable concentrate, a water dispersible granule, or a wettable powder.

[0031] The present invention discloses the use of the pesticide composition as described above for controlling pest mites.

[0032] Further, the pest mites are phytophagous mites;

[0033] Further, the pest mites are Panonychus citri or Panonychus ulmi;

[0034] Furthermore, the Panonychus citri is Panonychus citri McGregor, and the Panonychus ulmi is Panonychus ulmi Koch or Tetranychus viennensis Zacher.

[0035] Further, the pesticide composition is applied to pest mites and the plants on which they grow or the environment in which they grow.

[0036] The beneficial effects of the present invention are as follows:

[0037] 1) The pesticide composition of the present invention reasonably combines acaricides with different action mechanisms, has a significant synergistic effect on the leaf mites of citrus or apple trees, and has a good control effect;

[0038] 2) The pesticide composition of the present invention does not cause phytotoxicity to target plants, is safe for natural enemies, and effectively reduces the amount of pesticide used. Specific Embodiments

[0039] The following will clearly and completely describe the technical solutions in the embodiments of the present invention in conjunction with the preparation examples and specific examples of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

[0040] Preparation Example 1: 18% sulfiflumin·azocyclotin wettable powder (1:8)

[0041] Formulation composition: 2% sulfiflumin, 16% azocyclotin, 2.5% sodium dodecyl sulfate, 4% methylnaphthalenesulfonate formaldehyde condensate, 3% Nekal BX, 5% silica white, and kaolin to make up the balance;

[0042] Preparation method: According to the formula ratio, mix the active ingredient, dispersant, wetting agent and filler, stir evenly in a stirring kettle, and perform multiple pulverizations and mixings uniformly by an air-flow pulverizer to obtain the wettable powder of the composition of the present invention.

[0043] Preparation Example 2: 21% sulfiflumin·azocyclotin water-dispersible granule (6:1)

[0044] Formulation composition: 18% sulfiflumin, 3% azocyclotin, 8% succinate sulfonate, 5% sodium lignosulfonate, 2% sodium dodecyl sulfate, 5% silica white, 25% starch, kaolin to make up the balance;

[0045] Preparation method: According to the formula ratio, add the active ingredient to the carrier, add surfactants and other functional aids thereto, mix, add 10-25% of water after air-flow pulverization, and then obtain the water-dispersible granule product through kneading, granulation, drying and screening; or spray water, granulate and dry the pulverized powder in a fluidized bed granulator, and then screen to obtain the product.

[0046] Preparation Example 3: 20% sulfiflumin·azocyclotin suspension concentrate (3:1)

[0047] Formulation composition: 15% sulfiflumin, 5% azocyclotin, 1% polyoxyethylene ether of gerb alcohol, 5% phosphoric acid ester of polyoxyethylene styrylphenol ether, 1% sodium lignosulfonate, 0.2% xanthan gum, 5% ethylene glycol, 0.1% potassium benzisothiazolinone, 0.5% silicone oil, deionized water to make up the balance;

[0048] Preparation method: According to the formula ratio, place the active ingredient, surfactant and other functional aids in the reaction kettle in sequence, add water and mix evenly, perform high-speed shearing and wet grinding, and finally homogenize and filter to obtain the suspension concentrate product.

[0049] Preparation Example 4: 24% sulfiflumin·azocyclotin emulsifiable concentrate (5:1)

[0050] Formulation composition: 20% sulfiflumin, 4% azocyclotin, 16% DMF, 12% polyoxyethylene ether of isomeric tridecanol, 1% calcium dodecylbenzenesulfonate, 18% propylene carbonate, xylene to make up the balance;

[0051] Preparation method: According to the formula ratio, add the active ingredient, solvent and cosolvent to the mixing kettle and stir to dissolve, then add the emulsifier, make up the balance with the remaining solvent, stir evenly in the mixing kettle, and filter to obtain the emulsifiable concentrate required by the present invention.

[0052] Preparation Example 5: 16% sulfiflumin·fenbutatin wettable powder (3:1)

[0053] Formula composition: 12% sulfiflumin, 4% phenylbutanol, 5% sodium lignin sulfonate, 8% naphthalene sulfonate formaldehyde condensate, 5% pull open powder BX, kaolin makes up the balance;

[0054] Preparation method: Same as Preparation Example 1.

[0055] Preparation Example 6: 25% sulfiflumin·benzenebutin suspension (1:4)

[0056] Formula composition: 5% sulfiflumin, 20% phenylbutanol, 2% Guerbet alcohol polyoxyethylene ether, 2% sodium alkylnaphthalene sulfonate, 4% styrene phenol polyoxyethylene ether phosphate, 2% phenethylphenol polyoxyethylene polyoxypropylene ether, 0.2% xanthan gum, 1% magnesium aluminum silicate, 5% glycerol, 0.2% potassium benzoate, 0.5% silicone oil, and deionized water to make up the balance;

[0057] Preparation method: Same as Preparation Example 3.

[0058] Preparation Example 7: 16% sulfiflumin·phenylbutatin emulsifiable concentrate (15:1)

[0059] Formula composition: 15% sulfiflumin, 1% phenylbutanol, 15% N-methylpyrrolidone, 12% fatty alcohol polyoxyethylene ether, 2% succinate sulfonate, 8% DMF, methyl oleate makes up the balance;

[0060] Preparation method: Same as Preparation Example 4.

[0061] Example 1: Indoor biotoxicity activity assay

[0062] Test basis: The test refers to NY / T1154-12-2008 "Guidelines for Indoor Bioassay Tests of Pesticides - Insecticides Part 12: Spider Mite Slide Dipping Method".

[0063] Biological test material: Apple red spider (Panonychus ulmi (Koch)).

[0064] Test agents: sulfiflumin technical, triazotin technical, fenbutatin technical.

[0065] Experimental preparation: Select female adult mites with the same physiological state raised indoors. Cut the double-sided tape into 2 cm long pieces and stick them on one end of the slide. Then select healthy mites and stick their backs on the double-sided tape. Put 30 mites per slide and place them in a container with a wet sponge pad, cover it with a lid, and place it at (25±1)℃. Perform microscopic examination after 2 hours, remove dead and injured individuals, and make up 30 mites per slide.

[0066] Pharmaceutical preparation: The original drug is formulated into a mother liquor with an organic solvent, and then formulated into 5 series of mass concentrations with a 0.1% Tween-80 aqueous solution.

[0067] Pharmaceutical treatment: Immerse the glass slide in the medicinal liquid, gently shake it for 5 s and then take it out, absorb the excess medicinal liquid with blotting paper, place it in a white disk padded with a moist sponge, and cover it with a plastic film with good light transmittance.

[0068] Each treatment is repeated 4 times, and a treatment without the pharmaceutical (containing all organic solvents and emulsifiers) is set as a blank control.

[0069] Rearing and observation: Place the container containing the treated test insects under the conditions of a temperature of (25 ± 1) °C and a photoperiod of L:D = (16:8) h for rearing and observation.

[0070] Inspection: Check the death situation of the test insects 48 h after treatment, and record the total number of insects and the number of dead insects respectively.

[0071] Calculation method:

[0072] According to the investigation data, calculate the mortality of each treatment. Calculate according to the following formula:

[0073]

[0074] In the formula:

[0075] P —— Mortality, unit: percentage (%);

[0076] K —— Represents the number of dead insects, unit: head;

[0077] N —— Represents the total number of treated insects, unit: head.

[0078]

[0079] In the formula:

[0080] P 1 —— Corrected mortality, unit: percentage (%);

[0081] P t —— Treatment mortality, unit: percentage (%);

[0082] P 0 —— Blank control mortality, unit: percentage (%).

[0083] If the control mortality < 5%, no correction is required; if the control mortality is between 5% and 20%, correction should be carried out according to formula (2); if the control mortality > 20%, the test needs to be redone.

[0084] The co-toxicity coefficient (CTC value) of the mixture is calculated according to Equations (3), (4), and (5):

[0085]

[0086] Wherein:

[0087] ATI—the measured toxicity index of the mixture;

[0088] S—the LC 50 of the standard acaricide, with the unit of milligram per liter (mg / L);

[0089] M—the LC 50 of the mixture, with the unit of milligram per liter (mg / L).

[0090] TTI = TI A × P A + TI B × P B

[0091] Wherein:

[0092] TTI—the theoretical toxicity index of the mixture;

[0093] TI A —the toxicity index of pesticide A;

[0094] P A —the percentage content of pesticide A in the mixture, with the unit of percentage (%);

[0095] TI B —the toxicity index of pesticide B;

[0096] P B —the percentage content of pesticide B in the mixture, with the unit of percentage (%).

[0097]

[0098] Wherein:

[0099] CTC—the co-toxicity coefficient;

[0100] ATI—the measured toxicity index of the mixture;

[0101] TTI—the theoretical toxicity index of the mixture.

[0102] When the co-toxicity coefficient CTC of the compounding ≥ 120, it shows a synergistic effect; when CTC ≤ 80, it shows an antagonistic effect; when 80 < CTC < 120, it shows an additive effect. The results of the indoor toxicity test are shown in the following table:

[0103] Table 1 Test results of the indoor biological activities of sulfiflumin and cyhexatin against Panonychus ulmi

[0104] Test agents <![CDATA[LC 50 (mg / L)]]> ATI TTI Coefficient of co-toxicity (CTC) Sulfiflumin (A) 1.2686 100.000 / / Azocyclotin (B) 10.3170 12.296 / / A:B = 1:40 7.0003 18.122 14.435 125.540 A:B = 1:30 6.3195 20.074 15.125 132.720 A:B = 1:20 5.0313 25.214 16.473 153.067 A:B = 1:10 3.5475 35.760 20.269 176.427 A:B = 1:5 2.5860 49.056 26.914 182.274 A:B = 5:1 0.8911 142.363 85.383 166.736 A:B = 10:1 0.9311 136.247 92.027 148.052 A:B = 20:1 0.9852 128.766 95.824 134.378 A:B = 30:1 1.0323 122.891 97.171 126.469 A:B = 40:1 1.1936 106.284 97.861 108.607 A:B = 50:1 1.2837 98.824 98.280 100.553

[0105] Table 2 Test results of indoor bioactivity determination of sulfiflumin and fenbutatin oxide against Panonychus ulmi

[0106] Test agents <![CDATA[LC 50 (mg / L)]]> ATI TTI Coefficient of co-toxicity (CTC) sulfiflumin (A) 1.2686 100 / / Fenbutatin oxide (B) 40.8097 3.109 / / A:B = 1:55 25.5337 4.968 4.839 102.677 A:B = 1:45 19.5526 6.488 5.215 124.415 A:B = 1:35 15.061 8.423 5.800 145.225 A:B = 1:25 11.4929 11.038 6.835 161.490 A:B = 1:15 8.0949 15.672 9.164 171.007 A:B = 5:1 0.9211 137.727 83.851 164.251 A:B = 15:1 0.8817 143.881 93.944 153.156 A:B = 25:1 0.9861 128.648 96.273 133.628 A:B = 35:1 1.0567 120.053 97.309 123.374 A:B = 45:1 1.2685 100.008 97.894 102.160 A:B = 55:1 1.5093 84.052 98.270 85.532

[0107] From the indoor test results in Table 1 - 2, it can be seen that the pesticide composition of the present invention has good control effect against Panonychus ulmi. When sulfiflumin is compounded with azocyclotin, when the mass ratio of the two is 1:40 to 30:1, it shows a synergistic effect on Panonychus ulmi, and when the mass ratio is 40:1 to 50:1, it shows an additive effect on Panonychus ulmi; when sulfiflumin is compounded with fenbutatin oxide, when the mass ratio of the two is 1:45 to 35:1, the co - toxicity coefficient against Panonychus ulmi is greater than 120, showing a synergistic effect, while when the mass ratio is 1:55, 45:1 to 55:1, the co - toxicity coefficient is less than 120, showing an additive effect.

[0108] Example 2: Field efficacy test against apple leaf mites

[0109] Test site: Apple orchard in Wangjiazhuang Village, Zhaoyuan City, Shandong Province. The soil fertility of the test site is medium to high, and the irrigation condition is good, meeting the local scientific agricultural practice.

[0110] Test crop: Red Fuji.

[0111] Test target: Panonychus ulmi, Tetranychus viennensis.

[0112] Arrangement of test plots: Each test plot consists of 2 fruit trees, and each treatment is repeated 4 times.

[0113] Application time: Apply pesticides for control when the average number of leaf mites per leaf reaches 7 - 11. When applying pesticides, use a knapsack manual sprayer to spray the whole apple plant until the apple leaves are wet with pesticides but do not drip.

[0114] Test investigation: Investigate the mite population base before applying pesticides, and investigate the number of live mites on the 1st, 5th, and 10th days after applying pesticides. Investigate all 2 fruit trees in each plot, and mark 5 leaves at each of the 5 positions of east, south, west, north, and middle on each tree. Use a hand - held magnifying glass to investigate and record the number of all live mites, and at the same time investigate the tree body reaction and the killing situation of natural enemies.

[0115] Method for calculating efficacy:

[0116]

[0117] Results and analysis of field efficacy test:

[0118] Table 3 Results of field efficacy test against apple leaf mites

[0119]

[0120] As can be seen from the results of the above field efficacy tests, the pesticide composition of the present invention has excellent control effects on Panonychus ulmi, and has good fast-acting properties compared with the single-agent control. Moreover, within the test dosage range, no phytotoxicity was found in the apple plants treated with the agent, and it is relatively safe for natural enemies, so it can be applied and promoted in production.

[0121] Example 3: Field control efficacy test against Panonychus citri

[0122] Test site: The test was carried out in a Shatangju citrus orchard in Pingling Village, Yongfu Town, Yongfu County, Guilin City, Guangxi Zhuang Autonomous Region. The soil fertilizer, management conditions, etc. of the test site were basically uniform.

[0123] Test plot setting: A total of 5 pesticide treatments and 1 clear water control treatment were set in the test. Each plot was arranged in a randomized block design. Each treatment plot consisted of 2 citrus trees, and each treatment was replicated 4 times. There were 2 Shatangju trees in each plot, for a total of 48 test plots, and a protection row was set around each plot.

[0124] Pesticide application time and method: Pesticide application was carried out on September 16, 2023. The conventional crown spraying method was used during pesticide application. There was no rainfall on the day of pesticide application and within 2 days after pesticide application, and no adverse weather factors affecting the test results occurred.

[0125] Investigation time and method: The initial population density of pests was investigated before pesticide application, and the number of surviving mites was investigated 3 days, 10 days, and 20 days after pesticide application, for a total of 4 investigations. In each plot, 1 tree tip was marked on the east, south, west, north, and middle of each tree. A total of 50 leaves on each plot were investigated for the number of active mites, and the number of live mites was counted.

[0126] Efficacy calculation method:

[0127]

[0128] Results and analysis of field efficacy tests:

[0129] Table 4: Field control efficacy test against Panonychus citri

[0130]

[0131]

[0132] The investigation results 3 days after application showed that the control effects of 21% sulfiflumin·azocyclotin water dispersible granules (6:1) and 16% sulfiflumin·fenbutatin oxide emulsifiable concentrate (15:1) were 86.77% and 85.61% respectively; 20 days after application, the control effect of the pesticide composition of the present invention against Panonychus citri was significantly higher than that of each single agent control, and the long-lasting period was longer. Within the tested concentration range, no obvious phytotoxicity of the pesticide composition of the present invention to citrus leaves, young shoots and fruits was observed after application.

[0133] From the results of indoor and field efficacy tests, it can be seen that the pesticide composition of the present invention has excellent control effect against Panonychus ulmi or Panonychus citri, effectively reduces the harm of mite pests to crops, and inhibits the outbreak of mite pest populations.

[0134] Although the present invention has been described in detail with general descriptions and specific embodiments above, based on the present invention, some modifications or improvements can be made, which are obvious to those skilled in the art. Therefore, these modifications or improvements made without departing from the spirit of the present invention all fall within the scope of protection required by the present invention.

Claims

1. A pesticide composition, characterized in that the active ingredients of the pesticide composition comprise active ingredient A and active ingredient B, the active ingredient A is sulfiflumin, the active ingredient B is fenbutatin oxide, and the mass ratio of active ingredient A to active ingredient B in the pesticide composition is 1:45 to 35:

1.

2. The pesticide composition according to claim 1, characterized in that the mass ratio of active ingredient A to active ingredient B is 1:45 to 35:

1.

3. The pesticide composition according to claim 1, characterized in that the mass ratio of active ingredient A to active ingredient B is 1:35 to 25:

1.

4. The pesticide composition according to claim 1, characterized in that in addition to the active ingredients, the pesticide composition further comprises agriculturally acceptable auxiliary ingredients, and the auxiliary ingredients are fillers and / or surfactants.

5. The pesticide composition according to claim 1, characterized in that the formulation dosage form of the pesticide composition is a solution, suspension, emulsifiable concentrate, emulsion in water, microcapsule suspension, microemulsion, suspoemulsion, dispersible oil suspension, granule, water dispersible granule or wettable powder.

6. The pesticide composition according to claim 5, characterized in that the formulation dosage form is a suspension, emulsifiable concentrate, water dispersible granule or wettable powder.

7. Use of the pesticide composition according to any one of claims 1-6 for controlling pest mites.

8. The use according to claim 7, characterized in that the pest mites are phytophagous mites.

9. The use according to claim 8, characterized in that the pest mites are Panonychus citri, Panonychus ulmi; the Panonychus citri is Panonychus citri McGregor, and the Panonychus ulmi is Panonychus ulmi Koch or Tetranychus viennensis Zacher.

10. The use according to claim 7, characterized in that the pesticide composition is applied to pest mites and the plants on which they grow or the environment in which they grow.

Citation Information

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