Bubble water and preparation method thereof

Abstract

The invention provides bubble water and a preparation method thereof, and relates to the field of daily chemicals. The bubble water researched and developed by the invention comprises the following components in percentage by mass: 3-6% of a foaming agent, 5-15% of a stabilizer, 25-33% of a surfactant, 1-3% of a humectant, 0.5% of polyquaternium and the balance of water. According to the bubble water, the foaming agent and the surfactant are combined, so that a good film forming effect is achieved, water can be better wrapped by adding glycerin, finally, the stabilizing effect is better by adding polyquaternium and the like, the hang time is finally prolonged, and meanwhile, the bubble water provided by the formula has colorful colors, is free of pungent smells, and has the advantages of being environmentally friendly and free of toxic and side effects. And the air suspension effect is good, the retention time is long, the material is not easy to break, and the density is large.

Description

Technical Field

[0001] The present invention belongs to the field of daily chemicals, and particularly relates to a bubble solution and a preparation method thereof. Background Art

[0002] Bubble solution has always been widely loved by children and teenagers, and is also one of the important tools for creating an atmosphere. As a decorative element for photography, it has a high probability of being used in major occasions such as weddings and festivals. These beautiful bubbles add a happy and cheerful atmosphere to our important life moments and make daily life more colorful.

[0003] Most of the simple homemade bubble solutions use overnight tea, and use the contained tea polyphenols, caffeine, etc. as foam stabilizers to keep the bubbles from bursting, use white sugar, etc. to increase viscosity, and use dishwashing liquid, etc. for proportion compounding, mixing and stirring. The simple homemade bubble solution blows out few bubbles, the bubbles are discontinuous, the color is not obvious, and it is very easy to burst.

[0004] The bubble solutions sold on the market have the following problems: short stay time in the air; high water content, heavy weight, and easy to sink in the air; poor surface tension; restricted by the weather; the number of bubbles blown out by a single hole of the mouth-blown type is small each time; and some bubble solutions are not suitable for electric bubble machines; for the mouth-blown type, often a small amount of bubbles blown out from the first hole have disappeared before the second hole is blown out, making it impossible to play and take pictures happily. Summary of the Invention

[0005] Aiming at the shortcomings and deficiencies in the prior art, the purpose of the present invention is to provide a bubble solution and a preparation method thereof.

[0006] In order to solve the above technical problems, the technical solution proposed by the present invention is: A bubble solution, calculated by mass percentage, the bubble solution includes: 3-6% of a foaming agent, 5-15% of a stabilizer, 25-33% of a surfactant, 1-3% of a humectant, 0.5% of a polyquaternium salt, and the balance is water.

[0007] Further, the foaming agent is 4-5%, the stabilizer is 8-13%, the surfactant is 28-33%, the humectant is 2%, the polyquaternium salt is 0.5%, and the balance is water.

[0008] Further, the foaming agent is one or a mixture of more than one of sodium lauroyl sarcosinate LS-30, bubble solution surfactant FM-030G, and linear alkyl glycoside / alkyl sulfate FM-050G; The stabilizer is one or a mixture of more than one of acrylic polymer MP-50L film-forming agent and modified acrylic polymer MP-3000S; The surfactant is one or a mixture of more than one of sodium lauryl ether sulfate AES, compound alkyl amide propyl betaine FM-20AB, and coconut oil amide propyl betaine CAB-35.

[0009] Furthermore, the foaming agent is a mixture of sodium lauroyl sarcosinate LS-30, bubble water surfactant FM-030G, and linear alkyl polyglycoside / alkyl sulfate FM-050G; The stabilizer is a mixture of acrylic polymer MP-50L film former and modified acrylic polymer MP-3000S; The surfactant includes a mixture of sodium lauryl ether sulfate AES, coconut oil amide propyl betaine CAB-35, and compound alkyl amide propyl betaine FM-20AB.

[0010] Furthermore, the mass ratio of sodium lauroyl sarcosinate LS-30, bubble water surfactant FM-030G, and linear alkyl polyglycoside / alkyl sulfate FM-050G is 1:1:1; For the stabilizer: the mass ratio of acrylic polymer MP-50L film former and modified acrylic polymer MP-3000S is 5:(3 - 5); For the surfactant: the mass ratio of sodium lauryl ether sulfate AES, compound alkyl amide propyl betaine FM-20AB, and coconut oil amide propyl betaine CAB-35 is (0 - 3):5:25.

[0011] Furthermore, for the foaming agent: the mass ratio of sodium lauroyl sarcosinate LS-30, bubble water surfactant FM-030G, and linear alkyl polyglycoside / alkyl sulfate FM-050G is 1:1:1; For the stabilizer: the mass ratio of acrylic polymer MP-50L film former and modified acrylic polymer MP-3000S is 5:3; For the surfactant: the mass ratio of sodium lauryl ether sulfate AES, compound alkyl amide propyl betaine FM-20AB, and coconut oil amide propyl betaine CAB-35 is 3:5:25.

[0012] Furthermore, the humectant is glycerol.

[0013] Furthermore, the polyquaternium is polyquaternium-39.

[0014] For the preparation method of a bubble water according to any one of the above, the method includes: (1) According to mass percentages, configure the following raw materials: 3 - 6% of foaming agent; 5 - 15% of stabilizer; 25 - 33% of surfactant, 1 - 3% of humectant, 0.5% of polyquaternium; the balance is water; (2)Put the raw materials from step (1) into a glass reactor, heat up to 80 - 85 °C, stir and dissolve evenly to obtain a mixed solution; cool to room temperature and let it stand overnight to prepare the bubble solution.

[0015] The advantages of the present invention are as follows: The raw material formula of the present invention: Foaming agents: such as sodium lauroyl sarcosinate LS - 30, bubble solution surfactant FM - 030G, and linear alkyl polyglycoside / alkyl sulfate FM - 050G. These foaming agents can reduce the surface tension of water, making it easier for air to enter the solution to form bubbles.

[0016] Stabilizers: such as acrylic polymer MP - 50L film - forming agent and modified acrylic polymer MP - 3000S. They can form a protective film on the surface of the bubbles, increasing the stability of the bubbles and preventing the bubbles from bursting prematurely.

[0017] Surfactants: such as sodium lauryl polyoxyethylene ether sulfate AES, compound alkyl amide propyl betaine FM - 20AB, and coconut oil amide propyl betaine CAB - 35. These surfactants can further reduce the surface tension of the solution, improving the formation efficiency and stability of the bubbles.

[0018] Humectant: Glycerol can increase the viscosity of the solution, enabling the bubbles to better retain moisture and extending the hovering time of the bubbles.

[0019] Polyquaternium - 39: As a cationic polymer, it can increase the charge density of the solution, causing stronger interactions between bubble molecules, and further improving the stability and hovering time of the bubbles.

[0020] The present invention uses polyquaternium - 39 instead of cationic hydroxyethyl cellulose (alias polyquaternium - 10) for the following reasons: (1) Bubble performance: Polyquaternium - 39 can produce richer and more stable foam, which enables the bubble solution to generate a large number of delicate and long - lasting bubbles during use, enhancing the visual effect and playing experience of the bubbles. Cationic hydroxyethyl cellulose mainly acts as a thickener to adjust the viscosity of the bubble solution, and has a certain auxiliary effect on the richness and stability of the foam, but the effect is not as significant as that of polyquaternium - 39.

[0021] (2) Stability: Polyquaternium - 39 has a wide pH application range (1 - 14) and can maintain good stability under different pH conditions. This enables the bubble solution to remain stable under various environments and usage conditions, and is not prone to phenomena such as stratification and precipitation. Cationic hydroxyethyl cellulose has certain requirements for the pH value and needs to keep the pH value of the formula within the optimal range to obtain ideal effects. Otherwise, its performance may decline, affecting the stability of the bubble solution.

[0022] (3) Safety and compatibility: Polyquaternium-39 has good compatibility with cationic, nonionic, and amphoteric surfactants and can be used in combination with various ingredients, which is convenient for formulators to adjust the formula of the bubble solution according to needs and add other functional ingredients such as fragrances and pigments to meet different requirements. Moreover, polyquaternium-39 has been widely used in personal care products such as cosmetics and toothpaste and is not a prohibited substance in the "Technical Specifications for Cosmetic Safety (2015 Edition)", meeting the requirements of relevant regulations and being relatively safe for the human body under normal use conditions. However, cationic hydroxyethyl cellulose may conflict with other formula ingredients, resulting in instability, and compatibility tests need to be carried out when compounding with other ingredients to ensure the quality and performance of the bubble solution. And a small number of people may be allergic to cationic hydroxyethyl cellulose.

[0023] (4) Moisturizing effect: Due to the differences in their structures, they exhibit different properties and effects in applications. Polyquaternium-39 performs better in terms of foam properties, stability, and moisturizing, while cationic hydroxyethyl cellulose is better in thickening and conditioning.

[0024] The mechanism of the present invention is as follows: The formula of the bubble water of the present invention achieves good foaming effect and stability through the synergistic effect of various raw materials. Among them, the foaming agent reduces the surface tension of water, enabling air to easily enter the solution to form bubbles; the stabilizer forms a protective film on the surface of the bubbles to prevent the bubbles from bursting; the surfactant further reduces the surface tension and improves the formation efficiency of bubbles; the humectant increases the viscosity of the solution, enabling the bubbles to better retain moisture; polyquaternium-39 increases the charge density of the solution, causing stronger interactions between bubble molecules, thereby prolonging the residence time of the bubbles.

[0025] The bubbles of the bubble water of the present invention have many advantages such as colorful colors, no irritating odor, good residence effect, long staying time, not easy to burst, and small density: (1) The foaming agent described in the present invention has a good foaming effect. The number of bubbles blown out of a single hole is significantly better than that of traditional household versions and commercially available bubble water, with bright colors. Moreover, the bubbles produced are also suitable for the commercially purchased electric bubble machines, and the effect is better than that of mouth-blown bubble tubes.

[0026] (2) Moreover, the results of the examples show that the bubble water of the present invention has many advantages such as a large number of bubbles, colorful colors, long stability time (the longest residence time of the bubbles of the bubble water of the present invention is 3-6 times that of the longest residence time of the bubbles of the existing bubble water), and fragrant smell. (3) The raw materials used in the bubble water of the present invention are harmless to human health, with a neutral pH value, safe and non-irritating, and can be used with confidence by children, teenagers, etc.

[0027] (4) The bubble solution of the present invention is also applicable to drones for releasing bubbles to drive away low-altitude flying birds. This is because the components of the bubble solution of the present invention are stable, with a relatively small density, light weight, and large surface tension, making it not easy to break. In contrast, the existing bubble solutions on the market have a high water content, heavy weight, and large density. When operating at low altitudes, affected by environmental factors, their structures are more unstable, so they are not suitable for drone operations. Detailed implementation manners

[0028] The present invention will be further described below in conjunction with embodiments.

[0029] The raw materials in the following embodiments are all existing products obtained through procurement.

[0030] Embodiment 1 In a glass reactor, add 1.5 g of sodium lauroyl sarcosinate LS-30, 1.5 g of bubble solution surfactant FM-050G (purchased from Shandong Yousuo Chemical Technology Co., Ltd.), and 1.5 g of linear alkyl glycoside / alkyl sulfate FM-030G and mix evenly. Then add 5 g of acrylic polymer MP-50L film-forming agent, 3 g of modified acrylic polymer MP-3000S, add 3 g of sodium lauryl polyoxyethylene sulfate AES, 5 g of compound alkyl amide propyl betaine FM-20AB, 25 g of coconut amide propyl betaine CAB-35, add deionized water to 100 g, heat up to 80 - 85 °C and stir to dissolve evenly; cool to room temperature, let stand overnight to obtain the bubble solution.

[0031] Embodiment 2 In a glass reactor, add 1.5 g of sodium lauroyl sarcosinate LS-30, 1.5 g of bubble solution surfactant FM-050G (purchased from Shandong Yousuo Chemical Technology Co., Ltd.), 1.5 g of linear alkyl glycoside / alkyl sulfate FM-030G and mix evenly. Then add 5 g of acrylic polymer MP-50L film-forming agent, 3 g of modified acrylic polymer MP-3000S, add 5 g of compound alkyl amide propyl betaine FM-20AB, 25 g of coconut amide propyl betaine CAB-35, add deionized water to 100 g, heat up to 80 - 85 °C and stir to dissolve evenly to obtain a mixed solution; cool to room temperature, let stand overnight to obtain the bubble solution.

[0032] Embodiment 3 In a glass reactor, add 1.5 g of sodium lauroyl sarcosinate LS-30, 1.5 g of bubble surfactant FM-050G (purchased from Shandong Yousuo Chemical Technology Co., Ltd.), 1.5 g of linear alkyl glycoside / alkyl sulfate FM-030G and mix evenly. Then add 5 g of acrylic polymer MP-50L film former, 5 g of modified acrylic polymer MP-3000S, add 5 g of composite alkyl amide propyl betaine FM-20AB, 25 g of cocamidopropyl betaine CAB-35, add deionized water to 100 g, heat up to 80 - 85 °C and stir to dissolve evenly to obtain a mixed solution; cool to room temperature and let stand overnight to prepare the said bubble liquid.

[0033] Example 4 In a glass reactor, add 1.5 g of sodium lauroyl sarcosinate LS-30, 1.5 g of bubble surfactant FM-050G (purchased from Shandong Yousuo Chemical Technology Co., Ltd.), 1.5 g of linear alkyl glycoside / alkyl sulfate FM-030G and mix evenly. Then add 7.5 g of acrylic polymer MP-50L film former, 7.5 g of modified acrylic polymer MP-3000S, add 25 g of cocamidopropyl betaine CAB-35, 2 g of glycerol, add deionized water to 100 g, heat up to 80 - 85 °C and stir to dissolve evenly to obtain a mixed solution; cool to room temperature and let stand overnight to prepare the said bubble liquid.

[0034] Example 5 In a glass reactor, add 1.5 g of sodium lauroyl sarcosinate LS-30, 1.5 g of bubble surfactant FM-050G (purchased from Shandong Yousuo Chemical Technology Co., Ltd.), 1.5 g of linear alkyl glycoside / alkyl sulfate FM-030G and mix evenly. Then add 5 g of acrylic polymer MP-50L film former, 3 g of modified acrylic polymer MP-3000S, add 3 g of sodium lauryl ether sulfate, 5 g of composite alkyl amide propyl betaine FM-20AB, 25 g of cocamidopropyl betaine CAB-35, add 2 g of glycerol, 0.5 g of polyquaternium-39, add deionized water to 100 g, heat up to 80 - 85 °C and stir to dissolve evenly to obtain a mixed solution; cool to room temperature and let stand overnight to prepare the said bubble liquid.

[0035] Example 6 In a glass reactor, add 1.5 g of sodium lauroyl sarcosinate LS-30, 1.5 g of bubble surfactant FM-050G (purchased from Shandong Yousuo Chemical Technology Co., Ltd.), 1.5 g of linear alkyl glycoside / alkyl sulfate FM-030G and mix them evenly. Then add 5 g of acrylic polymer MP-50L film former, 3 g of modified acrylic polymer MP-3000S, add 5 g of composite alkyl amide propyl betaine FM-20AB, 25 g of cocamidopropyl betaine CAB-35, add 2 g of glycerol, 0.5 g of polyquaternium-39, add deionized water to 100 g, heat up to 80 - 85 °C and stir to dissolve evenly to obtain a mixed solution; cool to room temperature and let it stand overnight to prepare the said bubble liquid.

[0036] Example 7 In a glass reactor, add 1.5 g of sodium lauroyl sarcosinate LS-30, 1.5 g of bubble surfactant FM-050G (purchased from Shandong Yousuo Chemical Technology Co., Ltd.), 1.5 g of linear alkyl glycoside / alkyl sulfate FM-030G and mix them evenly. Then add 5 g of acrylic polymer MP-50L film former, 5 g of modified acrylic polymer MP-3000S, add 5 g of composite alkyl amide propyl betaine FM-20AB, 25 g of cocamidopropyl betaine CAB-35, add 2 g of glycerol, 0.5 g of polyquaternium-39, add deionized water to 100 g, heat up to 80 - 85 °C and stir to dissolve evenly to obtain a mixed solution; cool to room temperature and let it stand overnight to prepare the said bubble liquid.

[0037] Example 8 In a glass reactor, add 1.5 g of sodium lauroyl sarcosinate LS-30, 1.5 g of bubble surfactant FM-050G (purchased from Shandong Yousuo Chemical Technology Co., Ltd.), 1.5 g of linear alkyl glycoside / alkyl sulfate FM-030G and mix them evenly. Then add 7.5 g of acrylic polymer MP-50L film former, 7.5 g of modified acrylic polymer MP-3000S, add 25 g of cocamidopropyl betaine CAB-35, 2 g of glycerol, 0.5 g of polyquaternium-39, add deionized water to 100 g, heat up to 80 - 85 °C and stir to dissolve evenly to obtain a mixed solution; cool to room temperature and let it stand overnight to prepare the said bubble liquid.

[0038] The formulations of Examples 1 - 8 are shown in Table 1:

[0039] Analysis and explanation: (1) Examples 1 - 4 VS Examples 5 - 8: Difference: Glycerol and polyquaternium-39 are added in Examples 5 - 8.

[0040] Analysis: The increase in glycerol improves the viscosity of the solution, enabling the bubbles to better retain moisture, thereby prolonging the air retention time. The increase in polyquaternium-39 increases the charge density of the solution, resulting in stronger interactions between bubble molecules, further enhancing the stability and air retention time of the bubbles.

[0041] (2)Comparison between Examples 5 and 6: Difference: AES is missing in Example 6.

[0042] Analysis: AES is a surfactant that can reduce the surface tension of the solution, improving the formation efficiency and stability of the bubbles. The absence of AES leads to an increase in the surface tension of the solution, a decrease in the formation efficiency of the bubbles, and a deterioration in stability, thus shortening the air retention time.

[0043] (3)Comparison between Examples 6 and 7: Difference: The dosage of the modified acrylic polymer MP-3000S is increased in Example 7.

[0044] Analysis: The modified acrylic polymer MP-3000S is a stabilizer that can form a thicker protective film on the surface of the bubbles, further enhancing the stability of the bubbles. Increasing its dosage can strengthen the stability of the bubbles and prolong the air retention time.

[0045] (4)Comparison between Examples 5, 6, 7 and 8: Difference: The dosage of the acrylic polymer MP-50L film-forming agent is increased in Example 8.

[0046] Analysis: The acrylic polymer MP-50L film-forming agent is also a stabilizer that can form a protective film on the surface of the bubbles. Increasing its dosage can further improve the stability of the bubbles, but excessive use may cause the solution to be too viscous, affecting the formation efficiency of the bubbles.

[0047] Add the bubble solution prepared above to a bubble blowing device, use a mouth-blowing type with a diameter of 2.5 cm to blow bubbles, blow bubbles in a windless room, the tester stands on a 0.6 m stool and blows bubbles into the air in the room, record indicators such as the number of bubbles blown in a single time and the longest stagnation time of the bubbles in the room, repeat each test more than 3 times, and record the average value.

[0048] In addition, set up four control groups: Control Group 1 In a glass reaction kettle, add 25 g of modified acrylic polymer MP-3000S, 3 g of cocamidopropyl betaine CAB-35, 3 g of sodium lauryl ether sulfate AES, 10 g of white sugar, 10 g of dishwashing liquid, add deionized water to 100 g and dissolve evenly to obtain a bubble solution.

[0049] Control Group 2 In a glass reactor, add 25 g of acrylic polymer film-forming MP-3000s, 10 g of white sugar, and 20 g of dishwashing liquid. Add deionized water to make up to 100 g and stir until dissolved evenly to obtain the bubble solution.

[0050] Comparative Example 3 In a glass reactor, add 5 g of white sugar and 30 g of dishwashing liquid. Add deionized water to make up to 100 g to obtain a mixed solution.

[0051] Comparative Example 4 Randomly purchase bubble water from the market.

[0052] Eight groups of examples and four groups of comparative examples, and the obtained test data are shown in Table 2:

[0053] As can be seen from Table 2, the bubble water prepared in Example 5 of the present invention has more single-blow bubble numbers and a longer average maximum staying time compared with Comparative Examples 1-4, proving that the bubble water prepared by the present invention has good bubble-blowing effect, is superior to Comparative Examples 1-4, and has various advantages such as not being easily broken and having rich colors.

[0054] The above are only the preferred example embodiments of the present invention and do not constitute a limitation to the protection scope of the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the claims of the present invention.

Claims

1. A bubble solution, characterized in that, By mass percentage, the bubble solution comprises: 3-6% of a foaming agent, 5-15% of a stabilizer, 25-33% of a surfactant, 1-3% of a humectant, 0.5% of a polyquaternium, and the balance is water.

2. The bubble water according to claim 1, characterized in that, The foaming agent is 4-5%, the stabilizer is 8-13%, the surfactant is 28-33%, the humectant is 2%, the polyquaternium is 0.5%, and the balance is water.

3. A bubble solution according to claim 1 or 2, characterized in that, The foaming agent is one or a mixture of more than one of sodium lauroyl sarcosinate LS-30, bubble solution surfactant FM-030G, and linear alkyl glycoside / alkyl sulfate FM-050G; the stabilizer is one or a mixture of more than one of acrylic polymer MP-50L film-forming agent and modified acrylic polymer MP-3000S; the surfactant is one or a mixture of more than one of sodium lauryl polyoxyethylene ether sulfate AES, compound alkyl amide propyl betaine FM-20AB, and cocoamidopropyl betaine CAB-35.

4. A bubble solution according to claim 1 or 2, characterized in that, The foaming agent is a mixture of sodium lauroyl sarcosinate LS-30, bubble solution surfactant FM-030G, and linear alkyl glycoside / alkyl sulfate FM-050G; the stabilizer is a mixture of acrylic polymer MP-50L film-forming agent and modified acrylic polymer MP-3000S; the surfactant comprises a mixture of sodium lauryl polyoxyethylene ether sulfate AES, cocoamidopropyl betaine CAB-35, and compound alkyl amide propyl betaine FM-20AB.

5. A bubble solution according to claim 1 or 2, characterized in that The mass ratio of the foaming agent: sodium lauroyl sarcosinate LS-30, bubble solution surfactant FM-030G, and linear alkyl glycoside / alkyl sulfate FM-050G is 1:1:1; the mass ratio of the stabilizer: acrylic polymer MP-50L film-forming agent and modified acrylic polymer MP-3000S is 5:(3-5); the mass ratio of the surfactant: sodium lauryl polyoxyethylene ether sulfate AES, compound alkyl amide propyl betaine FM-20AB, and cocoamidopropyl betaine CAB-35 is (0-3):5:

2.

6. A bubble solution according to claim 5, characterized in that, The mass ratio of the foaming agent: sodium lauroyl sarcosinate LS-30, bubble solution surfactant FM-030G, and linear alkyl glycoside / alkyl sulfate FM-050G is 1:1:1; the mass ratio of the stabilizer: acrylic polymer MP-50L film-forming agent and modified acrylic polymer MP-3000S is 5:3; the mass ratio of the surfactant: sodium lauryl polyoxyethylene ether sulfate AES, compound alkyl amide propyl betaine FM-20AB, and cocoamidopropyl betaine CAB-35 is 3:5:

25.

7. A bubble solution according to claim 6, wherein, The humectant is glycerol.

8. A bubble solution according to claim 6, characterized in that, The polyquaternium is polyquaternium-39.

9. A method for preparing a bubble solution according to any one of claims 1-8, characterized in that, The method comprises: (1) configuring the following raw materials by mass percentage: 3-6% of a foaming agent; 5-15% of a stabilizer; 25-33% of a surfactant, 1-3% of a humectant, 0.5% of a polyquaternium; the balance is water; (2) putting the raw materials in step (1) into a glass reaction kettle, heating to 80-85 °C and stirring to dissolve evenly to obtain a mixed solution; cooling to room temperature and standing overnight to prepare the bubble solution.

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