Beta-cyclodextrin coagulant aid as well as preparation method and application thereof

By introducing olefin groups, amino groups and fluoride ions into β-cyclodextrin, β-cyclodextrin coagulants were prepared and compounded with inorganic coagulants, which solved the problem of low efficiency of traditional coagulants in removing PFAS and achieved efficient and environmentally friendly water treatment effects.

CN120647837APending Publication Date: 2025-09-16RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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Patent Information

Application Number
CN202510736970.6
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-06-04
Publication Date
2025-09-16

AI Technical Summary

Technical Problem

Existing coagulants have low removal efficiency and large dosage when treating PFAS pollution, which makes it difficult to meet water treatment requirements. In addition, long-term use of activated carbon will lead to a decrease in adsorption efficiency.

Method used

By introducing olefin groups, amino groups and fluoride ions into β-cyclodextrin, β-cyclodextrin coagulant aids are prepared to enhance their charge density and hydrophobicity, improve the flocculation effect, and compound with inorganic coagulants to form composite coagulants.

Benefits of technology

It significantly improves the removal efficiency of perfluoroalkyl and polyfluoroalkyl substances, reduces the amount of inorganic coagulants used, is applicable to a wide range of water treatment fields, and has good water treatment effects.

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Abstract

The invention provides a beta-cyclodextrin coagulant aid as well as a preparation method and application thereof, and belongs to the technical field of environment and chemistry. The preparation method of the beta-cyclodextrin coagulant aid comprises the following steps: adding beta-cyclodextrin and acrylic acid into a first solvent for esterification reaction to obtain a first polymer; adding the first polymer and dimethyl diallyl ammonium chloride into a second solvent, and adding an initiator for polymerization reaction to obtain a second polymer; and adding the second polymer, sodium trifluoromethanesulfinate and sodium bromate into a third solvent, and carrying out nucleophilic substitution reaction to obtain the beta-cyclodextrin coagulant aid.
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