System treatment device based on quinone pollutants in industrial production wastewater

By designing a system treatment device that includes a filtration chamber and a photoreactive degradation chamber, and utilizing a combination of multi-layer industrial filter cloth and vibration components, the problem of rubber particles clogging the filtration device in rubber tire production wastewater was solved. This achieved efficient degradation of quinone pollutants, met emission standards, and reduced environmental pollution.

CN120903596AActive Publication Date: 2025-11-07UNIV OF SCI & TECH OF CHINA
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Patent Information

Application Number
CN202511157815.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-08-19
Publication Date
2025-11-07
Estimated Expiration
2045-08-19

AI Technical Summary

Technical Problem

In the current rubber tire production process, rubber particles in the wastewater cause clogging of the filtration device, affecting the photodecomposition reaction of quinone pollutants. Furthermore, the existing filtration device is inefficient and cannot effectively treat quinone pollutants in the wastewater from rubber tire production.

Method used

A system processing device is designed, comprising a filtration chamber and a photoreactive degradation chamber. By utilizing a combination of multi-layer industrial filter cloth and vibration components, high-efficiency filtration of rubber particles is achieved, and quinone pollutants are degraded through the synergistic effect of the photoreactive degradation chamber and the catalyst.

Benefits of technology

It significantly improves the removal efficiency of wastewater treatment, avoids filter cloth clogging, ensures the effective degradation of quinone pollutants, meets emission standards, and reduces the risk of environmental pollution.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention relates to the technical field of quinone pollutant wastewater treatment, and discloses a system treatment device based on quinone pollutants in industrial production wastewater, the system treatment device comprises a filter bin mechanism, a water pump assembly and a photoreaction degradation bin, sewage in the filter bin mechanism is conveyed into the photoreaction degradation bin through the water pump assembly, and the photoreaction degradation bin is connected with the filter bin mechanism through the water pump assembly; a drainage port is formed in the output end of the photoreaction degradation bin, and the filtering bin mechanism and the photoreaction degradation bin are of an integrally-formed structure; according to the system treatment device based on the quinone pollutants in the industrial production wastewater, the filtering mechanism efficiently filters rubber particles in the wastewater through multiple layers of industrial filter cloth, the problem that in a traditional filtering technology, efficiency is reduced due to blockage of the filter cloth is solved, secondly, through the synergistic effect of photodecomposition reaction and a catalyst, the efficiency of the photoreaction degradation bin is improved, and the efficiency is improved. Quinones pollutants can be effectively degraded, and the removal efficiency of wastewater treatment is remarkably improved.
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Description

TECHNICAL FIELD

[0001] The present application relates to the technical field of quinone pollutant wastewater treatment, more specifically, it relates to a system processing device based on quinone pollutants in industrial wastewater. BACKGROUND

[0002] Quinone compounds based on p-phenylenediamine (PPD) are a new type of environmental pollutants that have attracted much attention in recent years. These compounds are formed through oxidation or coupling reactions and have been widely used in industrial production and consumer product manufacturing (such as hair dyes, cosmetics, and rubber products). As a result, they have entered the environment and have gradually revealed potential ecological and health risks.

[0003] Tires are an important consumable in modern transportation, with a global annual production of approximately 3.1 billion. The antioxidant N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine (6PPD) is widely added to the rubber formula of tires and has become an important source of new environmental pollutants. Under the action of ozone oxidation, 6PPD rapidly converts to its quinone derivative, N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine-quinone (6PPD-quinone). This substance has attracted global attention due to its extremely strong toxicity.

[0004] During the high-temperature production and cooling process of rubber tires in industrial production, a large amount of wastewater is generated. The 6PPD-quinone dissolves in the cooling wastewater, making the cooling water a release carrier. 6PPD-quinone is widely present in rainwater, rivers, and sediments, with concentrations ranging from 0.1 to 5.6 μg / L. Based on exposure models, the annual intake of adults through drinking water and food chains has approached the toxicology threshold, and long-term exposure may lead to health risks such as neurotoxicity and reproductive damage, highlighting the severe threat of 6PPD-quinone as a new organic micro-pollutant.

[0005] Existing wastewater from rubber tire production often lacks the necessary quinone pollutant treatment process. Quinone pollutants in cooling water from rubber tire factories have two carriers: rubber particles in wastewater and wastewater. Existing quinone pollutants need to be degraded by a high-level oxidation system of sunlight-activated high iodate. The main active species generated after IO4- photoactivation is IO3•, which attacks two carbon sites on the quinone ring, leading to hydroxylation and ring opening of the quinone group. As a result, small molecule degradation products and final mineralization products are formed, achieving the purpose of degradation.

[0006] But in the existing rubber tire production process, the wastewater contains a large amount of rubber particles, if the rubber particles are mixed in the sewage, the light transmittance of the sewage is poor, the light in the sewage is blocked, and then the photolysis effect is affected, at the same time, the quinone pollutants in the rubber particles need to be treated, and then the wastewater of the rubber production needs to be separated and treated, and the existing filter device is often easily blocked during filtering due to the small structure of the rubber particles, so that the wastewater filtering efficiency is greatly reduced, and then the photolysis reaction of quinone pollutants in the subsequent wastewater is affected, and then the wastewater treatment device for rubber tire production needs to be optimized in structure. SUMMARY

[0007] In order to overcome the above technical problems, the present application provides a system treatment device based on quinone pollutants in industrial wastewater.

[0008] The present application realizes the above-mentioned purpose by the following technical scheme: A system treatment device based on quinone pollutants in industrial wastewater, comprising a filter bin mechanism, a water pump assembly and a photoreaction degradation bin, the wastewater in the filter bin mechanism is conveyed to the inside of the photoreaction degradation bin by the water pump assembly, and the output end of the photoreaction degradation bin is provided with a drainage port; The filter bin mechanism and the photoreaction degradation bin are integrally formed; The middle part of the filter bin mechanism is provided with a filter chamber, and transmission chambers are symmetrically arranged at the positions on both sides of the filter chamber, and the top of the transmission chamber is provided with a water conveying chamber; A plurality of groups of filter mechanisms are uniformly arranged in the filter chamber from top to bottom, the filter mechanism comprises an industrial filter cloth, the industrial filter cloth is used for filtering rubber wastewater, and the filter mechanism further comprises a filter assembly, a vibration assembly and a driving assembly, the driving assembly drives the filter assembly to filter under the action of wastewater flow, and drives the vibration assembly to vibrate and clean the filter assembly; The outer side of the filter bin mechanism is provided with a water inlet pipe which is in intercommunication with the inside of the water conveying chamber, the water inlet pipe conveys the rubber wastewater containing quinone pollutants to the inside of the water conveying chamber, and further conveys to the top of the industrial filter cloth for filtering.

[0009] As a further optimization scheme of the present application, the filter bin mechanism further comprises a sealing top plate and a sealing bottom plate arranged on the top of the inner wall of the water conveying chamber, the sealing top plate and the sealing bottom plate are tightly connected with the inner wall of the water conveying chamber, the sealing bottom plate is provided with a guide plate near the position of the output end of the water inlet pipe, and the guide plate is used for guiding the wastewater.

[0010] As a further optimization scheme of the present application, the filter bin mechanism is provided with a plurality of groups of discharge ports corresponding to the filter mechanism near the middle of the end of the water inlet pipe, and two groups of vertical partitions are symmetrically arranged inside the filter bin mechanism, which separate the inside of the filter bin mechanism into a group of filter bin chambers and two groups of water conveying chambers, and a plurality of groups of limiting guide grooves are symmetrically arranged on the side of the two groups of vertical partitions close to each other.

[0011] As a further optimization scheme of the present application, the drive assembly comprises a transmission impeller arranged inside the water conveying chamber, the transmission impeller is located near the output end of the flow guide plate, a fourth transmission shaft is arranged in the middle of the transmission impeller and extends through the sealing bottom plate to the bottom of the water conveying chamber, and a second bevel gear is uniformly arranged on the outer side of the fourth transmission shaft.

[0012] As a further optimization scheme of the present application, the top of the sealing top plate is communicated with a water outlet mechanism, the water outlet mechanism comprises a water outlet guide pipe, one end of the water outlet guide pipe extends to the top of the filter bin chamber, a plurality of groups of spray heads are arranged on the outer side of the water outlet guide pipe at the top of the filter bin chamber, a support truss is arranged between the outer side of the water outlet guide pipe and the top of the filter bin mechanism, and a light reflecting plate corresponding to the inside of the water conveying chamber is arranged at the top of the support truss.

[0013] As a further optimization scheme of the present application, a plurality of groups of third transmission shafts corresponding to the second bevel gears are uniformly arranged through the two sides of the vertical partition, a first bevel gear meshing with the second bevel gear is arranged at one end of the third transmission shaft close to the second bevel gear, and a cam is arranged at the other end of the third transmission shaft.

[0014] As a further optimization scheme of the present application, a plurality of groups of first transmission shafts are uniformly arranged on the side of the two groups of vertical partitions close to each other, and a synchronous transmission unit is commonly arranged between the outer side of the third transmission shaft close to the cam and the two ends of the first transmission shaft.

[0015] As a further optimization scheme of the present application, the vibration assembly comprises two groups of incomplete gears symmetrically arranged on the outer side of the first transmission shaft, the two groups of incomplete gears are distributed in a structure staggered manner, a support frame matched with the first transmission shaft is arranged on the inner wall of the filter bin chamber, a second transmission shaft is commonly arranged at the other end of the support frame, a knocking hammer is symmetrically arranged on the outer side of the second transmission shaft, a group of teeth meshing with the incomplete gear is arranged on the outer side of the knocking hammer close to the incomplete gear, and the inside of the knocking hammer is supported by the limiting clamping of the limiting second transmission shaft.

[0016] As a further optimization scheme of the present application, the filter assembly comprises a plurality of filter support plates obliquely arranged inside the filter chamber, the output end of the filter support plate extends out of the interior of the filter chamber from the position of the discharge port, the middle part of the filter support plate is provided with an industrial filter cloth, the two sides of the filter support plate are provided with a limiting lug, the limiting lug and the limiting guide groove are matched with each other, the support plate is arranged at the position of the two ends of the bottom of the filter support plate on the inner wall of the filter chamber, and the top of the support plate is provided with a reset spring, and the reset spring elastically supports the filter support plate.

[0017] As a further optimization scheme of the present application, the middle part of the bottom of the filter support plate is provided with a linkage push rod, the linkage push rod is an L-shaped structure, and a cam is located at the top position of the linkage push rod and is attached thereto, and the pore size of the industrial filter cloth is from 100 meshes from top to bottom, and is arranged in turn according to the difference of 200.

[0018] The beneficial effects of the present application are: The filter mechanism in the device realizes efficient filtration of rubber particles in wastewater through multiple layers of industrial filter cloth, avoiding the problem of efficiency reduction caused by filter cloth blockage in traditional filtration technology. Secondly, the photoreaction degradation chamber can effectively degrade quinone pollutants through the synergistic effect of photodecomposition reaction and catalyst, significantly improving the removal efficiency of wastewater treatment. BRIEF DESCRIPTION OF DRAWINGS

[0019] Figure 1 is a perspective view of the present application Figure 1 ; Figure 2 is a perspective view of the present application Figure 2 ; Figure 3 is a perspective view of the present application Figure 4 is an enlarged sectional view of the internal structure of the filter chamber mechanism in the present application Figure 5 is an enlarged sectional view of the internal structure of the filter chamber mechanism in the present application Figure 6 is an enlarged sectional view of the internal structure of the filter chamber mechanism in the present application Figure 7 is an enlarged sectional view of the internal structure of the filter chamber mechanism in the present application Figure 8 is an enlarged sectional view of the internal structure of the filter chamber mechanism in the present application Figure 9 is an enlarged sectional view of the internal structure of the filter chamber mechanism in the present application

[0020] In the drawings: 100, filter warehouse mechanism; 200, water pump assembly; 300, light reaction degradation warehouse; 400, reflective plate; 500, water inlet pipe; 600, drainage port; 700, filter mechanism; 800, water outlet mechanism; 101, filter warehouse; 102, transmission warehouse; 103, water delivery warehouse; 104, discharge port; 105, vertical partition; 106, limiting guide groove; 107, sealing top plate; 108, sealing bottom plate; 109, flow guide plate; 701, filter support plate; 702, linkage push rod; 703, cam; 704, first bevel gear; 705, synchronous transmission unit; 706, first transmission shaft; 707, industrial filter cloth; 708, support plate; 709, limiting protrusion; 710, return spring; 711, second transmission shaft; 712, gear set; 713, incomplete gear; 714, support frame; 715, knocking hammer; 716, third transmission shaft; 717, transmission impeller; 718, fourth transmission shaft; 719, second bevel gear; 801, water outlet conduit; 802, spray head. DETAILED DESCRIPTION

[0021] The subject matter described herein will now be discussed with reference to example implementations. It should be understood that the discussion of these implementations is merely meant to provide a better understanding of the subject matter described herein and can be changed in function and arrangement without departing from the scope of the present disclosure. Various examples can omit, substitute, or add various procedures or components as appropriate. Also, features described with respect to some examples can be combined in other examples. EMBODIMENTS

[0022] As shown in Figure 1 , Figure 2 A system processing device based on quinone pollutants in industrial wastewater, comprising a filter warehouse mechanism 100, a water pump assembly 200 and a light reaction degradation warehouse 300, the sewage inside the filter warehouse mechanism 100 is transported to the inside of the light reaction degradation warehouse 300 by the water pump assembly 200, and the output end of the light reaction degradation warehouse 300 is provided with a drainage port 600; As shown in Figures 1 to 4 The filter warehouse mechanism 100 further comprises a sealing top plate 107 and a sealing bottom plate 108 arranged on the inner wall top of the water delivery warehouse 103, the sealing top plate 107 and the sealing bottom plate 108 are tightly connected with the inner wall of the water delivery warehouse 103, and the sealing bottom plate 108 is provided with a flow guide plate 109 near the output end of the water inlet pipe 500, the flow guide plate 109 is used for guiding the wastewater; The outer side of the filtering bin mechanism 100 is provided with a water inlet pipe 500 in communication with the inside of the water conveying bin chamber 103, and the middle part of the filtering bin mechanism 100 close to one end of the water inlet pipe 500 is provided with a plurality of groups of discharge ports 104 corresponding to the filtering mechanism 700, and the inside of the filtering bin mechanism 100 is symmetrically provided with two groups of vertical partitions 105, which divide the inside of the filtering bin mechanism 100 into a group of filtering bin chambers 101 and two groups of water conveying bin chambers 103, and the side close to each other of the two groups of vertical partitions 105 is symmetrically provided with a plurality of groups of limiting guide grooves 106; The filtering bin mechanism 100 and the photoreaction degradation bin 300 are integrally formed; As shown in Figure 3 , Figure 4 , the middle part of the inside of the filtering bin mechanism 100 is provided with a filtering bin chamber 101, and the transmission bin chambers 102 are symmetrically arranged at positions on both sides of the filtering bin chamber 101, and the top of the transmission bin chamber 102 is provided with a water conveying bin chamber 103; As shown in Figures 4 to 6 , the inside of the filtering bin chamber 101 is uniformly provided with a plurality of groups of filtering mechanisms 700 from top to bottom, and the filtering mechanism 700 comprises an industrial filter cloth 707, which is used for filtering rubber sewage; As shown in Figures 3 to 9 , the filtering mechanism 700 further comprises a filtering assembly, a vibration assembly and a driving assembly, the driving assembly is driven by the flow of wastewater to drive the filtering assembly to filter, and drive the vibration assembly to vibrate and clean the filtering assembly; The driving assembly comprises a transmission impeller 717 arranged in the water conveying bin chamber 103, the transmission impeller 717 is close to the output end of the flow guide plate 109, the middle part of the transmission impeller 717 is provided with a fourth transmission shaft 718 penetrating through the sealing bottom plate 108 and extending to the bottom of the inside of the water conveying bin chamber 103, and the outer side of the fourth transmission shaft 718 is uniformly provided with a second bevel gear 719; The top of the sealing top plate 107 is communicated with a water outlet mechanism 800, the water outlet mechanism 800 comprises a water outlet guide pipe 801, one end of the water outlet guide pipe 801 extends to the top of the filtering bin chamber 101, and the outer side of the water outlet guide pipe 801 at the top of the filtering bin chamber 101 is provided with a plurality of groups of spray heads 802, the outer side of the water outlet guide pipe 801 and the top of the filtering bin mechanism 100 are provided with a supporting truss, and the top of the supporting truss is provided with a light reflecting plate 400 corresponding to the inside of the water conveying bin chamber 103; The vertical partition 105 is uniformly provided with a plurality of groups of third transmission shafts 716 corresponding to the second bevel gears 719 on both sides. The first bevel gears 704 are arranged on one end of the third transmission shaft 716 close to the second bevel gears 719 and mesh with the second bevel gears 719. The other end of the third transmission shaft 716 is provided with a cam 703. The two groups of vertical partitions 105 are uniformly provided with a plurality of groups of first transmission shafts 706 on the side close to each other. The outer side of the third transmission shaft 716 close to the cam 703 is commonly provided with a synchronous transmission unit 705 between the two ends of the first transmission shaft 706. The vibration assembly includes two groups of incomplete gears 713 symmetrically arranged on the outer side of the first transmission shaft 706. The two groups of incomplete gears 713 are distributed in a staggered manner. The inner wall of the filter chamber 101 is provided with a support frame 714 matched with the first transmission shaft 706. The other end of the support frame 714 is commonly provided with a second transmission shaft 711. The outer side of the second transmission shaft 711 is symmetrically provided with a knocking hammer 715. The outer side of the knocking hammer 715 close to the incomplete gear 713 is provided with a gear group 712 meshing with the incomplete gear 713. The inside of the knocking hammer 715 is supported by the limiting clamping of the limiting second transmission shaft 711. The filter assembly includes a plurality of filter support plates 701 obliquely arranged in the filter chamber 101. The output end of the filter support plate 701 extends out of the inside of the filter chamber 101 from the discharge port 104. The middle part of the filter support plate 701 is provided with an industrial filter cloth 707. The two sides of the filter support plate 701 are provided with a limiting lug 709. The limiting lug 709 is matched with the limiting guide groove 106. The inner wall of the filter chamber 101 is provided with a support plate 708 at the position of the two ends of the bottom of the filter support plate 701. The top of the support plate 708 is provided with a return spring 710. The return spring 710 elastically supports the filter support plate 701. The bottom of the filter support plate 701 is provided with a linkage push rod 702. The linkage push rod 702 is L-shaped. The cam 703 is located at the top of the linkage push rod 702 and is attached thereto. The pore size of the industrial filter cloth 707 is 100 mesh from top to bottom, and is arranged in sequence with a difference of 200.

[0023] The water inlet pipe 500 delivers rubber wastewater containing quinone pollutants to the inside of the water delivery chamber 103 and further to the top of the industrial filter cloth 707 for filtration.

[0024] The use process of the system treatment device based on quinone pollutants in industrial wastewater is as follows. When the device is in use, the reflected light of the reflector 400 is adjusted so that the light enters the inside of the photoreaction degradation chamber 300. The wastewater to be treated is delivered to the inside of the water delivery chamber 103 through the water inlet pipe 500, and the guide plate 109 guides the rotation of the transmission impeller 717. At this time, due to the symmetrical position of the two groups of guide plates 109, the rotation directions of the two groups of transmission impellers 717 are opposite, and the two groups of fourth transmission shafts 718 driven by the transmission impellers 717 also rotate in opposite directions. The opposite rotation of the fourth transmission shaft 718 drives the opposite rotation directions of the two groups of second bevel gears 719, and the two groups of first bevel gears 704 meshing with the second bevel gears 719 rotate in opposite directions. The first bevel gear 704 further drives the rotation of the cam 703, and the rotation of the cam 703 causes the convex surface to press the linkage push rod 702, thereby driving the filter support plate 701 at the top of the linkage push rod 702 to displace downward and compress the return spring 710. When the concave surface of the cam 703 is in contact with the outer side of the linkage push rod 702, the filter support plate 701 is displaced upward under the rebounding force of the return spring 710. However, during the downward displacement of the filter support plate 701, the return spring 710 is elastic, so that the downward stroke of the filter support plate 701 has an extension space, and during the upward displacement, the filter support plate 701 is limited by the cam 703, so that the filter support plate 701 as a whole produces an up-down vibration effect. Further, during the up-down displacement of the filter support plate 701, the limiting protrusion 709 is limited by the limiting guide groove 106, thereby maintaining the stability of the overall up-down displacement structure of the filter support plate 701. Further, the water flow input into the inside of the water delivery chamber 103 is delivered to the top of the uppermost filter support plate 701 through the water outlet conduit 801, and is sprayed out through the spray head 802. The sprayed wastewater flows from the top to the bottom of the industrial filter cloth 707 and is filtered, so that the rubber particles in the wastewater are separated and filtered, and the up-down multi-layer filtering of the plurality of groups of industrial filter cloths 707 improves the filtering effect of the wastewater. The wastewater filtered by the industrial filter cloth 707 flows downward through the industrial filter cloth 707, and the filtered rubber particles are discharged from the position of the reflector plate 400 through the inclined structure design of the filter support plate 701. In the process of rotating the third transmission shaft 716, the synchronous transmission unit 705 is synchronously driven to rotate, and in turn drives the first transmission shaft 706 to rotate. Through the rotation of the first transmission shaft 706, the two groups of incomplete gears 713 are driven to rotate. When one group of incomplete gears 713 meshes with the corresponding tooth group 712, the group of knocking hammers 715 is driven to rotate by the incomplete gear 713 at this time, so that one end of the knocking hammer 715 is displaced upward, and in turn the knocking hammer 715 produces a rapid knocking effect on the bottom of the industrial filter cloth 707. At this time, the other group of knocking hammers 715 is not subjected to meshing action and is in the initial state; When the knocking hammer 715 of the knocking group is no longer subjected to the meshing action of the incomplete gear 713, and the other group of knocking hammers 715 is subjected to the meshing action of the corresponding incomplete gear 713, an alternating knocking effect is formed. Through the knocking of the knocking hammer 715, the bottom of the industrial filter cloth 707 is subjected to a transient vibration effect, and in turn the rubber particles filled in the gap of the industrial filter cloth 707 are cleaned away, thereby preventing the rubber particles from blocking the industrial filter cloth 707; In turn, the filtered wastewater flows into the bottom of the filter chamber 101 inside the filter chamber 101, and is pumped into the inside of the photochemical degradation chamber 300 by starting the water pump assembly 200. In turn, by adding a catalyst and combining a photochemical decomposition reaction, a degradation reaction of quinone pollutants is carried out on the wastewater, thereby reducing the quinone pollutant index in the rubber tire production wastewater and reaching the emission standard, thereby reducing the risk of quinone pollutants being discharged into the urban river with the wastewater; It needs to be specially pointed out that the catalyst is any suitable photocatalyst material in the prior art, and the reaction principle used in the photocatalytic reaction is referred to the paper technology with the title of "Solar-light-activated periodate for degradation and detoxification of highly toxic 6PPD-quinone at environmental levels" in Nature Water on April 25, 2024, wherein the degradation reaction uses a solar light activated periodate advanced oxidation system, and the main active species generated after IO4- is photoactivated by the solar light / periodate system is IO3•, which attacks two carbon sites on the quinone ring, resulting in hydroxylation and ring opening of the quinone group, thereby forming small molecule degradation products and final mineralization products. The results of dynamic changes in bond order and bond length characterized by molecular orbital electron transfer show that single electron transfer SET is the most favorable pathway for IO3• to attack 6PPD-quinone, which benefits from the stronger electron delocalization effect of IO3• and the spatial inversion symmetry caused by the dipole moment formed by its special free radical structure. The key intermediate product after IO3• attacks 6PPD-quinone through the SET path is theoretically revealed as a short-lived intermediate 6PPD-quinone cation radical 6PPD-quinone•+, thereby providing a conversion direction and path for the subsequent degradation reaction.

[0025] The specific embodiments of the embodiments of the present application are described above, but the embodiments of the present application are not limited to the specific embodiments described above, and the specific embodiments described above are only illustrative and not limiting. Those skilled in the art can make many forms under the inspiration of the embodiments of the present application, which are all within the protection of the embodiments of the present application.

Claims

1. A system treatment device for quinone pollutants in industrial wastewater, characterized in that, Including filter bin mechanism (100), water pump assembly (200) and light reaction degradation bin (300), the sewage inside the filter bin mechanism (100) is transported to the inside of the light reaction degradation bin (300) by the water pump assembly (200), and the output end of the light reaction degradation bin (300) is provided with a drainage port (600); The filter bin mechanism (100) and the light reaction degradation bin (300) are integrally formed structures; The middle part of the filter bin mechanism (100) is provided with a filter chamber (101), and transmission chambers (102) are symmetrically arranged at positions on both sides of the filter chamber (101); the top of the transmission chamber (102) is provided with a water delivery chamber (103); A plurality of groups of filter mechanisms (700) are uniformly arranged in the filter chamber (101) from top to bottom, the filter mechanism (700) comprises an industrial filter cloth (707), the industrial filter cloth (707) is used for filtering rubber sewage, and the filter mechanism (700) further comprises a filter assembly, a vibration assembly and a driving assembly; the driving assembly drives the filter assembly to filter and drives the vibration assembly to vibrate and clean the filter assembly. The outer side of the filter bin mechanism (100) is provided with a water inlet pipe (500) which is in intercommunication with the inside of the water delivery chamber (103), the water inlet pipe (500) delivers rubber wastewater containing quinone pollutants to the inside of the water delivery chamber (103) and further to the top of the industrial filter cloth (707) for filtering.

2. A system for treating quinone pollutants in industrial wastewater according to claim 1, wherein The filter bin mechanism (100) further comprises a sealing top plate (107) and a sealing bottom plate (108) arranged on the inner wall top of the water delivery chamber (103), the sealing top plate (107) and the sealing bottom plate (108) are tightly connected with the inner wall of the water delivery chamber (103), and the sealing bottom plate (108) is provided with a flow guide plate (109) near the position of the output end of the water inlet pipe (500), the flow guide plate (109) is used for guiding wastewater.

3. A system for treating quinone pollutants in industrial wastewater according to claim 2, wherein The middle part of the filter bin mechanism (100) near one end of the water inlet pipe (500) is provided with a plurality of groups of discharge ports (104) corresponding to the filter mechanisms (700), the inside of the filter bin mechanism (100) is symmetrically provided with two groups of vertical partitions (105), the inside of the filter bin mechanism (100) is divided into a group of filter chambers (101) and two groups of water delivery chambers (103) by the vertical partitions (105), and a plurality of groups of limiting guide grooves (106) are symmetrically arranged on one side of the two groups of vertical partitions (105) close to each other.

4. A system for treating quinone pollutants in industrial wastewater according to claim 3, wherein The driving assembly comprises a transmission impeller (717) arranged in the water delivery chamber (103), the transmission impeller (717) is near the output end of the flow guide plate (109), the middle part of the transmission impeller (717) is provided with a fourth transmission shaft (718) penetrating through the sealing bottom plate (108) and extending to the bottom of the water delivery chamber (103), and the outer side of the fourth transmission shaft (718) is uniformly provided with a second bevel gear (719).

5. A system for treating quinone pollutants in industrial wastewater according to claim 4, wherein The top of the sealing top plate (107) is communicated with a water outlet mechanism (800), which comprises a water outlet conduit (801) extending to the top of the filter chamber (101), and a plurality of groups of spray heads (802) are arranged outside the water outlet conduit (801) at the top of the filter chamber (101), a support truss is arranged between the outside of the water outlet conduit (801) and the top of the filter mechanism (100), and a light reflecting plate (400) corresponding to the inside of the water conveying chamber (103) is arranged at the top of the support truss.

6. A system for treating quinone pollutants in industrial wastewater according to claim 5, wherein A plurality of groups of third transmission shafts (716) corresponding to the second bevel gears (719) are uniformly arranged on both sides of the vertical partition (105), and a first bevel gear (704) meshing with the second bevel gear (719) is arranged at one end of the third transmission shaft (716) close to the second bevel gear (719), and a cam (703) is arranged at the other end of the third transmission shaft (716).

7. A system for treating quinone pollutants in industrial wastewater according to claim 6, wherein A plurality of groups of first transmission shafts (706) are uniformly arranged on one side of the two groups of vertical partitions (105) close to each other, and a synchronous transmission unit (705) is arranged between the outside of the third transmission shaft (716) close to the cam (703) and the two ends of the first transmission shaft (706).

8. A system for treating quinone pollutants in industrial wastewater according to claim 1, wherein The vibration assembly comprises two groups of incomplete gears (713) symmetrically arranged outside the first transmission shaft (706), and the two groups of incomplete gears (713) are distributed in a structure staggered manner, the inner wall of the filter chamber (101) is provided with a support frame (714) matched with the first transmission shaft (706), the other end of the support frame (714) is provided with a second transmission shaft (711), the outside of the second transmission shaft (711) is symmetrically provided with a knocking hammer (715), the outside of the knocking hammer (715) close to the incomplete gear (713) is provided with a gear set (712) meshing with the incomplete gear (713), and the inside of the knocking hammer (715) is supported by the limiting clamping of the limiting second transmission shaft (711).

9. A system for treating quinone pollutants in industrial wastewater according to claim 3, wherein The filter assembly comprises a plurality of groups of filter support plates (701) arranged in an inclined manner inside the filter chamber (101), the output end of the filter support plate (701) extends out of the inside of the filter chamber (101) from the position of the discharge port (104), the middle part of the filter support plate (701) is provided with an industrial filter cloth (707), the two sides of the filter support plate (701) are provided with limiting protrusions (709), the limiting protrusions (709) and the limiting guide grooves (106) are matched with each other, the inner wall of the filter chamber (101) is provided with a support plate (708) at the positions of the two ends of the bottom of the filter support plate (701), and the top of the support plate (708) is provided with a return spring (710) elastically supporting the filter support plate (701).

10. A system for treating quinone pollutants in industrial wastewater according to claim 9, wherein The middle part of the bottom of the filter support plate (701) is provided with a linkage push rod (702), the linkage push rod (702) is L-shaped structure, and a cam (703) is located at the top position of the linkage push rod (702) and is attached thereto, the pore size of the industrial filter cloth (707) is from 100 meshes from top to bottom, and is arranged in turn according to the difference of 200 in turn.

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