MPP electric power tube material and preparation method thereof

By grafting SiC/carbon fiber composites with polypropylene, the problem of uneven dispersion of carbon fiber in MPP power pipes was solved, improving mechanical properties and impact resistance, while also exhibiting good flame retardant properties and extending service life.

CN120944255AActive Publication Date: 2025-11-14SHANDONG DEYUAN PIPES CO LTD

Patent Information

Application Number
CN202511305714.8
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-09-12
Publication Date
2025-11-14
Estimated Expiration
2045-09-12

AI Technical Summary

Technical Problem

Carbon fiber is difficult to disperse evenly in MPP power pipes and tends to agglomerate, affecting mechanical properties and impact resistance. Furthermore, existing technologies have failed to effectively improve its application in MPP power pipes.

Method used

MPP power pipe material was prepared by grafting SiC/carbon fiber composite material with polypropylene, treating carbon fiber with silane coupling agent and compounding it with nano-SiC particles, and combining it with antioxidants, heat stabilizers and lubricants through a twin-screw extruder. This process inhibits carbon fiber agglomeration and improves dispersibility and mechanical strength.

Benefits of technology

This method achieves uniform dispersion of carbon fiber in MPP power pipes, improves mechanical properties and impact resistance, and also provides good flame retardant properties, extending service life.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention belongs to the technical field of power tubes, and particularly relates to an MPP power tube material and a preparation method thereof. The MPP electric power tube material comprises the following raw materials in parts by weight: 80-100 parts of a polypropylene / aluminum diethylphosphinate grafted material, 10-20 parts of a SiC / carbon fiber composite material, 1-5 parts of an antioxidant, 2-5 parts of a heat stabilizer, 0.5-4 parts of a compatilizer and 1-2 parts of a lubricant. The MPP power tube material provided by the invention can effectively inhibit agglomeration of the carbon fiber filler, has good mechanical properties, excellent impact resistance and good flame retardance, and can play a good role in protecting wires and cables.
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Description

Technical Field

[0001] This invention belongs to the field of power pipe technology, specifically relating to an MPP power pipe material and its preparation method. Background Technology

[0002] MPP power pipes, also known as MPP power cable protection pipes, are made primarily of polypropylene. They are characterized by high temperature resistance and external pressure resistance, making them suitable for high-voltage power transmission cable conduits of 10KV and above. Currently, polypropylene-based power pipes still have shortcomings in impact resistance; therefore, improving the impact resistance of MPP power pipes through filler modification is a relatively effective method.

[0003] Carbon fiber possesses properties such as high temperature resistance, friction resistance, electrical conductivity, thermal conductivity, and corrosion resistance, making it a superior mechanical material to glass fiber as a filler in MPP power pipes. Due to its preferred orientation along the fiber axis in its graphite microcrystalline structure, it exhibits high strength and modulus along the fiber axis. Furthermore, carbon fiber has a low density and high specific strength and modulus, thus effectively improving the strength and extending the service life of the pipe without increasing its weight. However, carbon fiber is difficult to disperse uniformly during its use as a reinforcing filler, and it tends to re-agglomerate after dispersion, which to some extent affects its application in the manufacture of MPP power pipes. Summary of the Invention

[0004] To address the problems existing in the prior art, this invention provides an MPP power pipe material and its preparation method. This MPP power pipe material can effectively inhibit the agglomeration of carbon fiber filler, has good mechanical properties, excellent impact resistance, and good flame retardant properties, and can play a good protective role for wires and cables.

[0005] The first aspect of the present invention provides an MPP power pipe material, comprising the following raw materials in parts by weight: 80-100 parts of polypropylene / aluminum diethylphosphinate graft material, 10-20 parts of SiC / carbon fiber composite material, 1-5 parts of antioxidant, 2-5 parts of heat stabilizer, 0.5-4 parts of compatibilizer, and 1-2 parts of lubricant.

[0006] Preparation method of polypropylene / aluminum diethylphosphinate grafted material: Diethylphosphonic aluminum was dispersed in anhydrous ethanol to form a dispersion, and then vinyltrimethoxysilane was added. After thorough stirring, washing and drying were performed to obtain silanized diethylphosphonic aluminum. Silanized aluminum diethylphosphinate, polypropylene, and an initiator are mixed evenly and then added to a twin-screw extruder for melt grafting. Subsequently, the mixture is extruded and granulated to obtain the polypropylene / aluminum diethylphosphinate grafted material.

[0007] Furthermore, the concentration of the aluminum diethylphosphonate dispersion is 15-20 wt%; Furthermore, the amount of vinyltrimethoxysilane added is 3-5% of the mass of aluminum diethylphosphinate; Furthermore, the initiator is benzoyl peroxide and / or dicumyl peroxide.

[0008] Furthermore, the mass ratio of silanized aluminum diethylphosphinic acid, polypropylene, and initiator is 1~2:8:0.5~1.

[0009] Furthermore, the processing temperature of the twin-screw extruder is 220~240℃, and the screw speed is 40~60r / min.

[0010] Preparation method of SiC / carbon fiber composite material: Carbon fibers were dispersed in anhydrous ethanol to form a carbon fiber dispersion, and then γ-aminopropyltriethoxysilane coupling agent was added. The mixture was stirred thoroughly at 70-80°C for 3-5 hours, and then filtered and washed to obtain pretreated carbon fibers. Pretreated carbon fibers and nano-SiC particles were added together to a mixed solvent of deionized water and anhydrous ethanol in a 1:1 volume ratio, and stirred thoroughly at 70-80℃ for 6-8 hours to obtain SiC / carbon fiber composite material.

[0011] Furthermore, the concentration of the carbon fiber dispersion is 10-15 wt%; Furthermore, the mass ratio of γ-aminopropyltriethoxysilane coupling agent, carbon fiber, nano-SiC particles, and mixed solvent is 1~1.5:10:3:100.

[0012] Furthermore, the antioxidant is at least one of antioxidant 1010, antioxidant 168, antioxidant 1076, and antioxidant 626.

[0013] Furthermore, the heat stabilizer is at least one of calcium-zinc composite stabilizers, stearate stabilizers, and organotin stabilizers.

[0014] Furthermore, the compatibilizer is one or more combinations of maleic anhydride-grafted polypropylene, maleic anhydride-grafted ABS, and maleic anhydride-grafted polyethylene.

[0015] Furthermore, the lubricant is at least one of paraffin wax, stearic acid alcohol, and stearamide.

[0016] The second aspect of the present invention provides a method for preparing the above-mentioned MPP power pipe material, wherein polypropylene / aluminum diethylphosphinate graft material, SiC / carbon fiber composite material, antioxidant, heat stabilizer, compatibilizer and lubricant are mixed evenly in a mixer in proportion to obtain a blend, and then extruded and granulated by a twin-screw extruder, and the MPP power pipe material is obtained after being shaped by a die.

[0017] Furthermore, the process parameters of the twin-screw extruder are as follows: zone 1 temperature is 200~220℃, zone 2 temperature is 210~230℃, zone 3 temperature is 220~240℃, zone 4 temperature is 230~250℃, and the extruder screw speed is 80~100r / min.

[0018] The beneficial effects achieved by one or more technical solutions of the present invention are as follows: 1. This invention uses carbon fiber as a reinforcing filler and grows SiC around the carbon fiber, which can not only effectively improve the dispersion of carbon fiber, inhibit the agglomeration of carbon fiber, and improve stability, but also work together with carbon fiber to provide an effective mechanical reinforcement substrate for the entire MPP power pipe material system.

[0019] 2. In this invention, the polypropylene resin substrate is grafted with aluminum diethylphosphinate. This is because aluminum diethylphosphinate has good flame retardant properties, and grafting it around the polypropylene can promote better dispersion throughout the system and better exert the flame retardant effect. On the other hand, some of the aluminum around the polypropylene can form a Si-Al-C phase with silicon carbide, which not only strengthens the polypropylene but also promotes the tight bonding between the polypropylene and carbon fibers, further improving the mechanical strength. Detailed Implementation

[0020] To enable those skilled in the art to better understand the technical solution of the present invention, the technical solution of the present invention will be described in detail below with reference to specific embodiments and comparative examples.

[0021] Example 1 This embodiment provides an MPP power pipe material, comprising the following raw materials in parts by weight: 90 parts polypropylene / aluminum diethylphosphinate grafted material, 15 parts SiC / carbon fiber composite material, 2 parts antioxidant 1010, 3 parts calcium stearate, 1 part maleic anhydride grafted polyethylene, and 1 part paraffin wax.

[0022] Preparation method of polypropylene / aluminum diethylphosphinate grafted material: Diethylphosphonic aluminum was dispersed in anhydrous ethanol to form a dispersion with a concentration of 15 wt%. Then, vinyltrimethoxysilane was added at a concentration of 3% of the mass of diethylphosphonic aluminum. After thorough stirring, the mixture was washed and dried to obtain silanized diethylphosphonic aluminum. Silanized aluminum diethylphosphinate, polypropylene, and benzoyl peroxide were mixed evenly in a mass ratio of 1:8:0.5, and then added to a twin-screw extruder for melt grafting. The processing temperature of the twin-screw extruder was 220℃ and the screw speed was 50 r / min. Subsequently, extrusion granulation was performed to obtain polypropylene / aluminum diethylphosphinate grafted material.

[0023] Preparation method of SiC / carbon fiber composite material: Carbon fibers were dispersed in anhydrous ethanol to form a carbon fiber dispersion with a concentration of 10 wt%. Then, γ-aminopropyltriethoxysilane coupling agent was added, and the mixture was stirred thoroughly at 70°C for 4 hours. After filtration and washing, pretreated carbon fibers were obtained. Pretreated carbon fibers and nano-SiC particles were added together to a mixed solvent consisting of deionized water and anhydrous ethanol in a volume ratio of 1:1. The mass ratio of γ-aminopropyltriethoxysilane coupling agent, carbon fibers, nano-SiC particles, and mixed solvent was 1:10:3:100. The mixture was stirred thoroughly at 70°C for 7 hours to obtain a SiC / carbon fiber composite material.

[0024] The preparation method of this MPP power pipe material is as follows: Polypropylene / aluminum diethylphosphinate grafted material, SiC / carbon fiber composite material, antioxidant 1010, calcium stearate, maleic anhydride grafted polyethylene, and paraffin wax are mixed evenly in a mixer to obtain a blend. Then, the blend is extruded and granulated through a twin-screw extruder. The process parameters of the twin-screw extruder are: zone 1 temperature 200℃, zone 2 temperature 210℃, zone 3 temperature 220℃, zone 4 temperature 230℃, and the extruder screw speed 80r / min. The material is then shaped by a die to obtain MPP power pipe material.

[0025] Example 2 This embodiment provides an MPP power pipe material, comprising the following raw materials in parts by weight: 80 parts polypropylene / aluminum diethylphosphinate grafting material, 10 parts SiC / carbon fiber composite material, 1 part antioxidant 168, 2 parts calcium stearate, 0.5 parts maleic anhydride grafted polyethylene, and 1 part paraffin wax.

[0026] Preparation method of polypropylene / aluminum diethylphosphinate grafted material: Diethylphosphonic aluminum was dispersed in anhydrous ethanol to form a dispersion with a concentration of 15 wt%. Then, vinyltrimethoxysilane was added at a concentration of 3% of the mass of diethylphosphonic aluminum. After thorough stirring, the mixture was washed and dried to obtain silanized diethylphosphonic aluminum. Silanized aluminum diethylphosphinate, polypropylene, and benzoyl peroxide were mixed evenly in a mass ratio of 1:8:1, and then added to a twin-screw extruder for melt grafting. The processing temperature of the twin-screw extruder was 220℃ and the screw speed was 50 r / min. Subsequently, extrusion granulation was performed to obtain polypropylene / aluminum diethylphosphinate grafted material.

[0027] Preparation method of SiC / carbon fiber composite material: Carbon fibers were dispersed in anhydrous ethanol to form a carbon fiber dispersion with a concentration of 10 wt%. Then, γ-aminopropyltriethoxysilane coupling agent was added, and the mixture was stirred thoroughly at 80°C for 3 hours. After filtration and washing, pretreated carbon fibers were obtained. Pretreated carbon fibers and nano-SiC particles were added together to a mixed solvent consisting of deionized water and anhydrous ethanol in a volume ratio of 1:1. The mass ratio of γ-aminopropyltriethoxysilane coupling agent, carbon fibers, nano-SiC particles, and mixed solvent was 1.5:10:3:100. The mixture was stirred thoroughly at 80°C for 6 hours to obtain a SiC / carbon fiber composite material.

[0028] The preparation method of this MPP power pipe material is as follows: Polypropylene / aluminum diethylphosphinate grafted material, SiC / carbon fiber composite material, antioxidant 168, calcium stearate, maleic anhydride grafted polyethylene, and paraffin wax are mixed evenly in a mixer to obtain a blend. Then, the blend is extruded and granulated through a twin-screw extruder. The process parameters of the twin-screw extruder are: zone 1 temperature 220℃, zone 2 temperature 230℃, zone 3 temperature 240℃, zone 4 temperature 250℃, and the extruder screw speed 80r / min. The material is then shaped by a die to obtain MPP power pipe material.

[0029] Example 3 This embodiment provides an MPP power pipe material, comprising the following raw materials in parts by weight: 80 parts polypropylene / aluminum diethylphosphinic acid grafted material, 20 parts SiC / carbon fiber composite material, 5 parts antioxidant 168, 5 parts zinc stearate, 4 parts maleic anhydride grafted polyethylene, and 2 parts paraffin wax.

[0030] Preparation method of polypropylene / aluminum diethylphosphinate grafted material: Diethylphosphonic aluminum was dispersed in anhydrous ethanol to form a dispersion with a concentration of 20 wt%. Then, vinyltrimethoxysilane was added at a concentration of 5% of the mass of diethylphosphonic aluminum. After thorough stirring, the mixture was washed and dried to obtain silanized diethylphosphonic aluminum. Silanized aluminum diethylphosphinate, polypropylene, and dicumyl peroxide were mixed evenly in a mass ratio of 1:8:1, and then added to a twin-screw extruder for melt grafting. The processing temperature of the twin-screw extruder was 240℃ and the screw speed was 60 r / min. Subsequently, extrusion granulation was performed to obtain polypropylene / aluminum diethylphosphinate grafted material.

[0031] Preparation method of SiC / carbon fiber composite material: Carbon fibers were dispersed in anhydrous ethanol to form a carbon fiber dispersion with a concentration of 15 wt%. Then, γ-aminopropyltriethoxysilane coupling agent was added, and the mixture was stirred thoroughly at 80°C for 3 hours. After filtration and washing, pretreated carbon fibers were obtained. Pretreated carbon fibers and nano-SiC particles were added together to a mixed solvent consisting of deionized water and anhydrous ethanol in a volume ratio of 1:1. The mass ratio of γ-aminopropyltriethoxysilane coupling agent, carbon fibers, nano-SiC particles, and mixed solvent was 1:10:3:100. The mixture was stirred thoroughly at 80°C for 6 hours to obtain a SiC / carbon fiber composite material.

[0032] The preparation method of this MPP power pipe material is as follows: Polypropylene / aluminum diethylphosphinate grafted material, SiC / carbon fiber composite material, antioxidant 168, zinc stearate, maleic anhydride grafted polyethylene, and paraffin wax are mixed evenly in a mixer to obtain a blend. Then, the blend is extruded and granulated through a twin-screw extruder. The process parameters of the twin-screw extruder are: zone 1 temperature 210℃, zone 2 temperature 220℃, zone 3 temperature 230℃, zone 4 temperature 240℃, and the extruder screw speed 100r / min. The material is then shaped by a die to obtain MPP power pipe material.

[0033] Example 4 This embodiment provides an MPP power pipe material, comprising the following raw materials in parts by weight: 100 parts polypropylene / aluminum diethylphosphinate grafted material, 15 parts SiC / carbon fiber composite material, 3 parts antioxidant 168, 4 parts calcium-zinc composite stabilizer, 2 parts maleic anhydride grafted polyethylene, and 2 parts paraffin wax.

[0034] Preparation method of polypropylene / aluminum diethylphosphinate grafted material: Diethylphosphonic aluminum was dispersed in anhydrous ethanol to form a dispersion with a concentration of 20 wt%. Then, vinyltrimethoxysilane was added at a concentration of 3% of the mass of diethylphosphonic aluminum. After thorough stirring, the mixture was washed and dried to obtain silanized diethylphosphonic aluminum. Silanized aluminum diethylphosphinate, polypropylene, and benzoyl peroxide were mixed evenly in a mass ratio of 2:8:1, and then added to a twin-screw extruder for melt grafting. The processing temperature of the twin-screw extruder was 230℃ and the screw speed was 40 r / min. Subsequently, extrusion granulation was performed to obtain polypropylene / aluminum diethylphosphinate grafted material.

[0035] Preparation method of SiC / carbon fiber composite material: Carbon fibers were dispersed in anhydrous ethanol to form a carbon fiber dispersion with a concentration of 15 wt%. Then, γ-aminopropyltriethoxysilane coupling agent was added, and the mixture was stirred thoroughly at 80°C for 5 h. After filtration and washing, pretreated carbon fibers were obtained. Pretreated carbon fibers and nano-SiC particles were added together to a mixed solvent consisting of deionized water and anhydrous ethanol in a volume ratio of 1:1. The mass ratio of γ-aminopropyltriethoxysilane coupling agent, carbon fibers, nano-SiC particles, and mixed solvent was 1.5:10:3:100. The mixture was stirred thoroughly at 80°C for 8 hours to obtain a SiC / carbon fiber composite material.

[0036] The preparation method of this MPP power pipe material is as follows: Polypropylene / aluminum diethyl phosphonate grafted material, SiC / carbon fiber composite material, antioxidant 168, calcium-zinc composite stabilizer, maleic anhydride grafted polyethylene, and paraffin wax are mixed evenly in a mixer to obtain a blend. Then, the blend is extruded and granulated through a twin-screw extruder. The process parameters of the twin-screw extruder are: zone 1 temperature 200℃, zone 2 temperature 210℃, zone 3 temperature 220℃, zone 4 temperature 230℃, and the extruder screw speed 100r / min. The material is then shaped by a die to obtain MPP power pipe material.

[0037] Comparative Example 1 This comparative example provides an MPP power pipe material comprising the following raw materials in parts by weight: 90 parts polypropylene, 15 parts SiC / carbon fiber composite material, 2 parts antioxidant 1010, 3 parts calcium stearate, 1 part maleic anhydride grafted polyethylene, and 1 part paraffin wax.

[0038] Preparation method of SiC / carbon fiber composite material: Carbon fibers were dispersed in anhydrous ethanol to form a carbon fiber dispersion with a concentration of 10 wt%. Then, γ-aminopropyltriethoxysilane coupling agent was added, and the mixture was stirred thoroughly at 70°C for 4 hours. After filtration and washing, pretreated carbon fibers were obtained. Pretreated carbon fibers and nano-SiC particles were added together to a mixed solvent consisting of deionized water and anhydrous ethanol in a volume ratio of 1:1. The mass ratio of γ-aminopropyltriethoxysilane coupling agent, carbon fibers, nano-SiC particles, and mixed solvent was 1:10:3:100. The mixture was stirred thoroughly at 70°C for 7 hours to obtain a SiC / carbon fiber composite material.

[0039] The preparation method of this MPP power pipe material is as follows: Polypropylene, SiC / carbon fiber composite material, antioxidant 1010, calcium stearate, maleic anhydride grafted polyethylene, and paraffin are mixed evenly in a mixer to obtain a blend. The blend is then extruded and granulated using a twin-screw extruder. The process parameters of the twin-screw extruder are: zone 1 temperature 200℃, zone 2 temperature 210℃, zone 3 temperature 220℃, zone 4 temperature 230℃, and extruder screw speed 80r / min. The material is then shaped by a die to obtain MPP power pipe material.

[0040] Comparative Example 2 This comparative example provides an MPP power pipe material comprising the following raw materials in parts by weight: 90 parts polypropylene / aluminum diethylphosphinate grafted material, 10 parts carbon fiber, 5 parts nano-SiC particles, 2 parts antioxidant 1010, 3 parts calcium stearate, 1 part maleic anhydride grafted polyethylene, and 1 part paraffin wax.

[0041] Preparation method of polypropylene / aluminum diethylphosphinate grafted material: Diethylphosphonic aluminum was dispersed in anhydrous ethanol to form a dispersion with a concentration of 15 wt%. Then, vinyltrimethoxysilane was added at a concentration of 3% of the mass of diethylphosphonic aluminum. After thorough stirring, the mixture was washed and dried to obtain silanized diethylphosphonic aluminum. Silanized aluminum diethylphosphinate, polypropylene, and benzoyl peroxide were mixed evenly in a mass ratio of 1:8:0.5, and then added to a twin-screw extruder for melt grafting. The processing temperature of the twin-screw extruder was 220℃ and the screw speed was 50 r / min. Subsequently, extrusion granulation was performed to obtain polypropylene / aluminum diethylphosphinate grafted material.

[0042] The preparation method of this MPP power pipe material is as follows: Polypropylene / aluminum diethyl phosphonate grafted material, carbon fiber, nano SiC particles, antioxidant 1010, calcium stearate, maleic anhydride grafted polyethylene, and paraffin wax are mixed evenly in a mixer to obtain a blend. Then, the blend is extruded and granulated through a twin-screw extruder. The process parameters of the twin-screw extruder are: zone 1 temperature 200℃, zone 2 temperature 210℃, zone 3 temperature 220℃, zone 4 temperature 230℃, and the extruder screw speed 80r / min. The material is then shaped by a die to obtain MPP power pipe material.

[0043] Comparative Example 3 This comparative example provides an MPP power pipe material comprising the following raw materials in parts by weight: 90 parts polypropylene, 15 parts SiC / carbon fiber composite material, 2 parts aluminum diethylphosphinate, 2 parts antioxidant 1010, 3 parts calcium stearate, 1 part maleic anhydride grafted polyethylene, and 1 part paraffin wax.

[0044] Preparation method of SiC / carbon fiber composite material: Carbon fibers were dispersed in anhydrous ethanol to form a carbon fiber dispersion with a concentration of 10 wt%. Then, γ-aminopropyltriethoxysilane coupling agent was added, and the mixture was stirred thoroughly at 70°C for 4 hours. After filtration and washing, pretreated carbon fibers were obtained. Pretreated carbon fibers and nano-SiC particles were added together to a mixed solvent consisting of deionized water and anhydrous ethanol in a volume ratio of 1:1. The mass ratio of γ-aminopropyltriethoxysilane coupling agent, carbon fibers, nano-SiC particles, and mixed solvent was 1:10:3:100. The mixture was stirred thoroughly at 70°C for 7 hours to obtain a SiC / carbon fiber composite material.

[0045] The preparation method of this MPP power pipe material is as follows: Polypropylene, SiC / carbon fiber composite material, aluminum diethylphosphinate, antioxidant 1010, calcium stearate, maleic anhydride grafted polyethylene, and paraffin wax are mixed evenly in a mixer to obtain a blend. The blend is then extruded and granulated using a twin-screw extruder. The process parameters of the twin-screw extruder are: zone 1 temperature 200℃, zone 2 temperature 210℃, zone 3 temperature 220℃, zone 4 temperature 230℃, and extruder screw speed 80r / min. The resulting material is then shaped using a die to obtain MPP power pipe material.

[0046] Performance testing: The MPP power pipes prepared in Examples 1-4 and Comparative Examples 1-3 were subjected to tensile strength tests according to standard GB / T1040-2006, bending strength tests according to standard GB / T9341-2008, impact strength tests according to standard GB / T1043.1-2008, and ring stiffness tests (3%) according to DL / T 802.1. A vertical burning test was also conducted with reference to the UL-94 flame retardancy rating standard to determine the flame retardant performance of the MPP power pipes. The results are shown in Table 1.

[0047] Table 1

[0048] According to the test results in Table 1, the MPP power pipe prepared by this invention has good mechanical properties, with high tensile strength, bending strength, impact strength, and ring stiffness. It also has good flame retardant properties and can play a good protective role for wires and cables.

Claims

1. An MPP power pipe material, characterized in that: The raw materials include the following parts by weight: 80-100 parts polypropylene / aluminum diethylphosphinic acid graft material, 10-20 parts SiC / carbon fiber composite material, 1-5 parts antioxidant, 2-5 parts heat stabilizer, 0.5-4 parts compatibilizer, and 1-2 parts lubricant. Preparation method of polypropylene / aluminum diethylphosphinate grafted material: Diethylphosphonic aluminum was dispersed in anhydrous ethanol to form a dispersion, and then vinyltrimethoxysilane was added. After thorough stirring, washing and drying were performed to obtain silanized diethylphosphonic aluminum. Silanized aluminum diethylphosphinate, polypropylene, and initiator are mixed evenly and then added to a twin-screw extruder for melt grafting. After extrusion granulation, polypropylene / aluminum diethylphosphinate grafted material is obtained. Preparation method of SiC / carbon fiber composite material: Carbon fibers were dispersed in anhydrous ethanol to form a carbon fiber dispersion, and then γ-aminopropyltriethoxysilane coupling agent was added. The mixture was stirred thoroughly at 70-80°C for 3-5 hours, and then filtered and washed to obtain pretreated carbon fibers. Pretreated carbon fibers and nano-SiC particles were added together to a mixed solvent of deionized water and anhydrous ethanol in a 1:1 volume ratio, and stirred thoroughly at 70-80℃ for 6-8 hours to obtain SiC / carbon fiber composite material.

2. The MPP power pipe material as described in claim 1, characterized in that: The concentration of the aluminum diethylphosphinate dispersion is 15-20 wt%. The amount of vinyltrimethoxysilane added is 3-5% of the mass of aluminum diethylphosphinate; The mass ratio of silanized diethylphosphinic acid aluminum, polypropylene, and initiator is 1~2:8:0.5~1; The initiator is benzoyl peroxide and / or dicumyl peroxide.

3. The MPP power pipe material as described in claim 1, characterized in that: The processing temperature of the twin-screw extruder is 220~240℃, and the screw speed is 40~60r / min.

4. The MPP power pipe material as described in claim 1, characterized in that: The concentration of the carbon fiber dispersion is 10~15wt%; The mass ratio of γ-aminopropyltriethoxysilane coupling agent, carbon fiber, nano-SiC particles, and mixed solvent is 1~1.5:10:3:

100.

5. The MPP power pipe material as described in claim 1, characterized in that: The antioxidant is at least one of antioxidant 1010, antioxidant 168, antioxidant 1076, and antioxidant 626.

6. The MPP power pipe material as described in claim 1, characterized in that: The heat stabilizer is at least one of calcium-zinc composite stabilizer, stearate stabilizer, and organotin stabilizer.

7. The MPP power pipe material as described in claim 1, characterized in that: The compatibilizer is one or more combinations of maleic anhydride-grafted polypropylene, maleic anhydride-grafted ABS, and maleic anhydride-grafted polyethylene.

8. The MPP power pipe material as described in claim 1, characterized in that: The lubricant is at least one of paraffin wax, stearic acid alcohol, and stearamide.

9. The method for preparing the MPP power pipe material according to any one of claims 1 to 8, characterized in that: Polypropylene / aluminum diethyl phosphonate graft material, SiC / carbon fiber composite material, antioxidant, heat stabilizer, compatibilizer and lubricant are mixed evenly in a mixer to obtain a blend, which is then extruded and granulated by a twin-screw extruder, and then shaped by a die to obtain MPP power pipe material.

10. The method for preparing the MPP power pipe material according to claim 9, characterized in that, The process parameters of the twin-screw extruder are as follows: zone 1 temperature is 200~220℃, zone 2 temperature is 210~230℃, zone 3 temperature is 220~240℃, zone 4 temperature is 230~250℃, and the screw speed of the extruder is 80~100r / min.

Citation Information

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