Resin composition

By combining polyester polyols with polylactic acid polymers of a specific structure to form a phase-separated structure, the problem of the glass transition temperature of polylactic acid polymers decreasing after plasticization is solved, and a resin composition with high elongation and impact resistance is achieved.

CN121175375APending Publication Date: 2025-12-19KURARAY CO LTD
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Patent Information

Application Number
CN202480034665.6
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Priority Date
2023-06-02
Filing Date
2024-05-31
Publication Date
2025-12-19

AI Technical Summary

Technical Problem

In the prior art, the glass transition temperature of polylactic acid polymer resin compositions decreases significantly after the addition of plasticizers, which fails to meet the requirements for good elongation and impact resistance.

Method used

A combination of polyester polyols with specific structures and polylactic acid polymers is used. The polyester polyols contain aliphatic diols with alkyl groups as branches and more than 4 carbon atoms. Through compatibility, a phase separation structure is formed, which suppresses the decrease in glass transition temperature and improves elongation and impact resistance.

Benefits of technology

It effectively suppressed the decrease in glass transition temperature, improved the elongation and impact resistance of the resin composition, and achieved good mechanical properties.

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Abstract

A resin composition which contains a polyester polyol (A) and a polylactic acid polymer (B), the polyester polyol (A) comprising units derived from a polyol (a1) and a polycarboxylic acid (a2), and the polyol (a1) comprising an aliphatic diol (a1-1) having 4 or more carbon atoms and having an alkyl group as a branched chain.
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