Plant matrix cleaning polymer as well as preparation method and application thereof

Abstract

The invention discloses a plant matrix cleaning polymer as well as a preparation method and application thereof. The plant matrix cleaning polymer is prepared from plant matrix bundles with 4-5 different diameters of 1 mm, 0.7 mm, 0.5 mm, 0.3 mm, 0.1 mm, 0.07 mm, 0.05 mm, 0.03 mm and 0.01 mm. The plant matrix cleaning polymer is prepared from plant matrix bundles with 4-5 different diameters of 1 mm, 0.7 mm, 0.5 mm, 0.3 mm, 0.1 mm, 0.07 mm, 0.05 mm, 0.03 mm and 0.01 mm. According to the invention, a plant active matrix polymerization action substance is used as a friction substance and is scientifically combined with a toothpaste medicine formula, so that the dual effects of natural active medicines and chemical medicines are exerted, and the convenient functions of self-cleaning and maintaining the oral cavity and teeth of a human body are achieved; the tooth cleaning effect can be achieved by cleaning the oral cavity through the oral muscle and the tongue and in the chewing process, a new method of brushing teeth through a toothbrush is replaced, the troubles of time consumption and inconvenience brought by the tooth brushing process are avoided, and the operation process of cleaning the oral cavity by means of external force in life of people is solved.

Description

Technical Field

[0001] This invention belongs to the field of biotechnology, specifically relating to a plant matrix cleaning polymer, its preparation method, and its application. Background Technology

[0002] Humans have been using oral hygiene methods for thousands of years, employing various techniques since ancient times, such as salt water, tea leaves, tree bark, and herbs. These natural oral cleaning materials could remove bad breath and clean teeth to some extent, but they did not treat oral diseases. By the late 19th century, with the development of the Industrial Revolution, commercial toothpaste began to appear, typically made from soap, soapwort, calcium carbonate, and other ingredients. In the early 20th century, scientists discovered the effectiveness of fluoride in preventing tooth decay, leading to the widespread use of fluoride and other therapeutic ingredients in modern toothpaste. Simultaneously, toothbrushes and toothpaste emerged, co-products of each other. China is one of the earliest countries in the world to invent and use toothbrushes, with rudimentary forms resembling modern toothbrushes appearing as early as the Tang Dynasty. These early toothbrushes were mainly made of bamboo or bone, with holes drilled in the head to insert horsehair, pig bristles, etc., as bristles. By the late 19th and early 20th centuries, plastic toothbrush handles replaced traditional bone and bamboo materials, and the United States began large-scale production and sales of toothbrushes. Toothpaste and toothbrush are two different products that interact with each other and are indispensable.

[0003] In today's rapidly developing society, traditional brushing techniques are limited by time and conditions, failing to meet the needs of busy professionals and the general public, inadvertently reducing work efficiency and causing inconvenience. Developing a solid toothpaste product that cleans the mouth and teeth directly through chewing would significantly improve people's lives and work. For those working in challenging environments, it would greatly alleviate many unnecessary problems, providing convenient, on-the-go oral health protection, especially for those working in aerospace or extreme polar regions, offering immediate and unrestricted oral health maintenance. Therefore, developing a product and method that solves these technical problems is essential. Summary of the Invention

[0004] The first objective of this invention is to provide a plant substrate cleaning polymer; the second objective is to provide applications of the plant substrate cleaning polymer.

[0005] The first objective of this invention is achieved by the fact that the plant substrate cleaning polymer is made of 4 to 5 different diameter bundles of plant substrate selected from 1 mm, 0.7 mm, 0.5 mm, 0.3 mm, 0.1 mm, 0.07 mm, 0.05 mm, 0.03 mm and 0.01 mm.

[0006] According to existing technology, after extracting the palm leaf fiber matrix, it undergoes multi-stage fine separation under dry conditions. To achieve fine grading from 1mm to 0.01mm, three separation technologies are used step-by-step: mechanical vibration sieving, airflow separation, and hydraulic sieving. Mechanical sieving: A mechanical vibration sieving machine is used with three layers of screens with aperture sizes of 1mm, 0.7mm, and 0.5mm. During the vibration process, fiber bundles with diameters smaller than the screen apertures fall into the next layer under the influence of gravity, producing matrix bundles with aperture sizes of 1mm, 0.7mm, and 0.5mm, respectively. Airflow separation: An airflow separator utilizes the different settling velocities of fiber bundles of varying diameters and lengths in the airflow. Lighter, finer fiber bundles are carried away by the airflow, while heavier, coarser fiber bundles settle first and are then collected. By precisely controlling the airflow velocity: at lower velocities, coarser / heavier 0.3mm particles settle first; at medium velocities, 0.1mm particles settle next; and at higher velocities, 0.07mm particles are carried into the collector. This produces matrix bundles of 0.3mm, 0.1mm, and 0.07mm sizes, respectively. Hydraulic sieving: A microporous screen hydrocyclone is used to separate particles of different sizes by utilizing the difference in centrifugal force experienced by the particles in the water vortex. Under centrifugal force, 0.05mm, 0.03mm, and 0.01mm particles are thrown against the wall and collected from the bottom, while particles <0.01mm flow out from the middle outlet, producing matrix bundles of 0.05mm, 0.03mm, and 0.01mm sizes, respectively.

[0007] The softening process utilizes high-pressure steam softening technology. High-pressure steam treatment, as a clean physical modification technique, can break down the gums, hemicellulose, and some lignin within plant fibers through hydrolysis and pyrolysis, thereby reducing fiber rigidity and improving flexibility. The optimal mechanical property control data for high-pressure steam softening are: (1.7 MPa / 25 min, tensile strength 150.8 ± 14.3, strength retention 64.5%, elongation at break 19.3%, elongation change 125.8%). The optimal softness (flexural modulus) data are: (1.7 MPa / 25 min, flexural modulus 842 ± 67 MPa, modulus reduction rate 33.6%). Therefore, the pressure control range is 1 MPa-2 MPa, and the time control range is 10 min-30 min. After air drying, the softening effect is achieved, and a self-cleaning polymer is obtained after formulation.

[0008] The second objective of this invention is achieved through the application of the plant-based cleaning polymer in the preparation of plant-based active self-cleaning toothpaste. Specifically, the plant-based active polymer is used as an abrasive, scientifically combined with the toothpaste's pharmaceutical formulation to leverage the dual effects of natural active pharmaceutical ingredients and chemical pharmaceuticals. This achieves a convenient function of self-cleaning and maintaining the oral cavity and teeth. The cleaning effect is achieved through oral muscles, tongue, and chewing, replacing the need for a toothbrush. This eliminates the time-consuming and inconvenient process of brushing, solving the problem of relying on external force for oral cleaning in daily life.

[0009] The plant matrix is ​​a natural active ingredient extracted from plants that promotes oral hygiene. For example, the matrix extracted from the leaves of the Yunnan palm (Palmaceae family) contains natural flavonoids, which have an auxiliary effect on gum repair. Its medicinal properties include astringency and hemostasis, and it can be used to relieve hematemesis, replenish deficiencies, kill parasites, reduce inflammation, and prevent thrombosis. Similar plant matrices are also common in other families and genera. For instance, mulberry bark matrix has a cooling and swelling-reducing function, pineapple leaf matrix has antibacterial and anti-inflammatory functions, and kudzu matrix has a thirst-quenching, cough-relieving, muscle-relaxing, and fever-reducing function. These are excellent natural active ingredients. Another function of the matrix is ​​that the matrix extracted from palm leaves has an excellent abrasive cleaning effect on teeth. Utilizing the inherent abrasive properties of the plant matrix, bundles of plant matrices of different diameters are mixed in proportion to create a self-cleaning matrix polymer. This polymer is formulated according to the oral conditions of different age groups to achieve a cleaning effect (i.e., friction level) suitable for various age groups. After processing, it possesses the cleaning function of a toothbrush.

[0010] The plant-based active self-cleaning toothpaste is a novel product that combines the abrasive properties of plant matrix with the traditional toothpaste formula to create a self-cleaning toothpaste. It is made by combining the abrasive properties of plant matrix with the traditional toothpaste formula. It can be taken directly into the mouth and cleans and maintains the oral cavity and teeth through the movement of oral muscles, tongue, and chewing.

[0011] The plant-based active self-cleaning toothpaste described above is characterized by its ability to be used regardless of time or conditions, its effectiveness in cleaning the inner surfaces of teeth, the palate, and the base of the tongue, and its ability to compensate for the limitations of toothbrushes in terms of cleaning angle.

[0012] The specific technical principle is as follows: By replacing the toothbrush with a plant-based active matrix and combining it with toothpaste ingredients, a self-cleaning toothpaste with different cleaning strengths and effects can be developed according to the oral needs of different ages. The types are as follows: A high-friction plant-based active matrix polymer is blended with toothpaste ingredients to create a stronger cleaning self-cleaning toothpaste; a neutral-friction plant-based active matrix polymer is blended with toothpaste ingredients to create a neutral cleaning self-cleaning toothpaste; and a low-friction plant-based active matrix polymer is blended with toothpaste ingredients to create... A soft-cleaning self-cleaning toothpaste was obtained; a soft toothpaste (for children) was prepared by blending a plant-based active matrix polymer with low abrasiveness with toothpaste medication; a cavity-preventing self-cleaning toothpaste (fluoride type) was prepared by adding an anti-cavity toothpaste formula; a whitening self-cleaning toothpaste was prepared by adding a whitening toothpaste formula; an anti-sensitivity self-cleaning toothpaste was prepared by adding an anti-sensitivity toothpaste formula; a natural herbal toothpaste formula was prepared by adding a natural herbal self-cleaning toothpaste formula; a probiotic self-cleaning toothpaste formula was prepared by adding a probiotic toothpaste formula; and an activated charcoal self-cleaning toothpaste formula was prepared by adding an activated charcoal toothpaste formula.

[0013] A reinforced oral self-cleaning polymer with a diameter of 1mm, 0.7mm, 0.1mm, and 0.05mm, formulated in a ratio of 15 / 25 / 35 / 25, was prepared, with a thickness of approximately 0.2cm-1cm. The following were added: abrasive (hydrated silica): 45-50g; humectant (glycerin / sorbitol): 25-30g; thickener (xanthan gum / CMC): 1-2g; surfactant (SLS / coco-betaine): 1-2g; fragrance / xylitol: 1-2g; preservative (sodium benzoate): 0.1-0.3g; thus, a reinforced cleaning self-cleaning toothpaste was obtained. A neutral oral self-cleaning polymer with a diameter of 0.7mm, 0.3mm, 0.1mm, 0.07mm, and 0.03mm was prepared according to a ratio of 20 / 30 / 20 / 15 / 15, with a thickness of approximately 0.1-0.6cm. The following were also prepared: an abrasive (hydrated silica): 45-50g; a humectant (glycerin / sorbitol): 25-30g; a thickener (xanthan gum / CMC): 1-2g; a surfactant (SLS / cocobetaine): 1-2g; a fragrance / xylitol: 1-2g; and a preservative (sodium benzoate): 0.1-0.3g. This process yielded a neutral cleaning self-cleaning toothpaste. A soft-textured self-cleaning oral polymer with a diameter of 0.5mm, 0.3mm, 0.1mm, 0.05mm, and 0.01mm, and a formulation ratio of 20 / 20 / 25 / 20 / 15, with a thickness of approximately 0.1-0.4cm, is prepared. The following are also prepared: abrasive (hydrated silica): 45-50g; humectant (glycerin / sorbitol): 25-30g; thickener (xanthan gum / CMC): 1-2g; surfactant (SLS / coco-betaine): 1-2g; fragrance / xylitol: 1-2g; preservative (sodium benzoate): 0.1-0.3g. This process yields a soft-textured self-cleaning toothpaste. A soft oral self-cleaning polymer with diameters of 0.3mm, 0.1mm, 0.05mm, 0.03mm, and 0.01mm was prepared in a ratio of 25 / 20 / 15 / 25 / 15, with a thickness of approximately 0.1-0.3cm. The following were added: flavoring (fruit flavor, such as strawberry flavor); hydrated silica: 35g; glycerin: 30g; xylitol: 3g; cocobetaine: 1g; strawberry flavor: 1g; to obtain a mild, soft children's self-cleaning toothpaste.

[0014] The toothpaste formula is replaced with: fluoride: 0.1-0.15%; abrasive (hydrated silica): 45-50g; humectant (glycerin / sorbitol): 25-30g; thickener (xanthan gum / CMC): 1-2g; surfactant (SLS / cocobetaine): 1-2g; fragrance / xylitol: 1-2g; preservative (sodium benzoate): 0.1-0.3g; thus, enhanced anti-cavity self-cleaning toothpaste, neutral anti-cavity self-cleaning toothpaste, and soft anti-cavity self-cleaning toothpaste are obtained.

[0015] The toothpaste formula was replaced with the following: enzymes: papain: 0.5% (to decompose pigments); hydrated silica: 50g; glycerin: 25g; hydrogen peroxide (3% solution): 5g (added after dilution); xanthan gum: 1.5g; cocobetaine: 2g; peppermint flavor: 1g; preservative: 0.3g; thus, three types of toothpaste were prepared: enhanced whitening self-cleaning toothpaste, neutral whitening self-cleaning toothpaste, and soft self-cleaning toothpaste.

[0016] The toothpaste formula was replaced with: potassium nitrate: 5% (to block the sensitive signal of the dental nerve); strontium chloride: 3-5% (to seal the dentinal tubules); hydrated silica: 40g; glycerin: 30g; potassium nitrate: 5g; xanthan gum: 1g; cocobetaine: 1g; xylitol: 2g; thus, enhanced anti-sensitivity self-cleaning toothpaste, neutral anti-sensitivity self-cleaning toothpaste, and soft anti-sensitivity self-cleaning toothpaste were prepared.

[0017] The toothpaste formula was replaced with: abrasive: baking soda (sodium bicarbonate, 20-30%); moisturizer: coconut oil (10-15%) + glycerin (10%); antibacterial agent: tea tree oil (0.5%); coconut oil: 15g; glycerin: 10g; xanthan gum: 2g; xylitol: 3g; tea tree oil: 0.5g; thus, three types of toothpaste were prepared: enhanced natural herbal self-cleaning toothpaste, neutral natural herbal self-cleaning toothpaste, and soft natural herbal self-cleaning toothpaste.

[0018] Replace the toothpaste formula with: active / inactivated bacteria such as Lactobacillus and Bifidobacterium, at a concentration of 1×10⁻⁶. 6 ~1×10 9 CFU / g, fermentation products or lysate products: such as lactic acid, short-chain fatty acid metabolites, etc., concentration range 1-5%; oily matrix: petrolatum, beeswax, shea butter, etc.: 30-70%; moisturizers: glycerin, hyaluronic acid: 5-15%; emulsifiers: polysorbate-80, lecithin: 1-5%; anti-inflammatory and soothing agents: allantoin, bisabolol 0.1-2%; preservatives: phenoxyethanol, potassium sorbate: 0.5-1%; ceramide (active ingredient): 0.7%; This yields enhanced probiotic self-cleaning toothpaste, neutral probiotic self-cleaning toothpaste, and soft probiotic self-cleaning toothpaste.

[0019] The toothpaste formula is replaced with: natural bamboo charcoal or activated wood charcoal: 10-20%; silicon dioxide, baking soda (sodium bicarbonate): 40-50%; glycerin, sorbitol: 15-20%; foaming agent: 0.5-1%; natural thickeners: xanthan gum, carrageenan: 1-3%; flavoring and sweeteners: 0.5-1%; preservatives: 0.1-0.5%; thus, enhanced activated charcoal self-cleaning toothpaste, neutral activated charcoal self-cleaning toothpaste, and soft activated charcoal self-cleaning toothpaste are obtained.

[0020] After removing the moisturizing agent, the toothpaste medication is dried and powdered in a 1:1 ratio. This powder is then fused with a self-cleaning oral polymer and pressed into a sheet-like solid toothpaste. The resulting products are, in order: Intensive Cleaning Self-Cleaning Solid Toothpaste; Neutral Cleaning Self-Cleaning Solid Toothpaste; Soft Cleaning Self-Cleaning Solid Toothpaste; Gentle Self-Cleaning Solid Toothpaste (Children's); Intensive Anti-Cavity Self-Cleaning Solid Toothpaste (Fluoride); Neutral Anti-Cavity Self-Cleaning Solid Toothpaste (Fluoride); Soft... Anti-cavity self-cleaning solid toothpaste (fluoride); Extra-strength whitening self-cleaning solid toothpaste; Neutral whitening self-cleaning solid toothpaste; Soft whitening self-cleaning solid toothpaste; Extra-strength anti-sensitivity self-cleaning solid toothpaste; Neutral anti-sensitivity self-cleaning solid toothpaste; Soft anti-sensitivity self-cleaning solid toothpaste; Extra-strength natural herbal self-cleaning solid toothpaste; Neutral natural herbal self-cleaning solid toothpaste; Soft natural herbal self-cleaning solid toothpaste; Extra-strength activated charcoal self-cleaning solid toothpaste; Neutral activated charcoal self-cleaning solid toothpaste; Soft activated charcoal self-cleaning solid toothpaste.

[0021] The beneficial live bacteria are replaced with beneficial non-live bacteria in a 1:1 formula ratio. The toothpaste is dried and powdered, then fused with the prepared oral self-cleaning polymer to form a whole. After pressing, it forms a sheet-like probiotic solid toothpaste. The resulting products are, in order: enhanced probiotic self-cleaning solid toothpaste; neutral probiotic self-cleaning solid toothpaste; and soft probiotic self-cleaning solid toothpaste. Detailed Implementation

[0022] The present invention will be further described below with reference to embodiments, but this is not intended to limit the present invention in any way. Any modifications or substitutions made based on the teachings of the present invention shall fall within the protection scope of the present invention.

[0023] The plant substrate cleaning polymer of the present invention is made of 4 to 5 different diameters of plant substrate bundles selected from 1 mm, 0.7 mm, 0.5 mm, 0.3 mm, 0.1 mm, 0.07 mm, 0.05 mm, 0.03 mm and 0.01 mm.

[0024] The plant substrate cleaning polymer is made of plant substrate bundles with diameters of 1 mm, 0.7 mm, 0.1 mm and 0.05 mm.

[0025] The mass ratio of the plant substrates with diameters of 1 mm, 0.7 mm, 0.1 mm and 0.05 mm is (10~20):(20~30):(30~40):(20~30).

[0026] The plant substrate cleaning polymer is made of plant substrate bundles with diameters of 0.7 mm, 0.3 mm, 0.1 mm, 0.07 mm and 0.03 mm.

[0027] The mass ratio of the plant substrates with diameters of 0.7 mm, 0.3 mm, 0.1 mm, 0.07 mm and 0.03 mm is (15~25):(25~35):(15~25):(10~20):(10~20).

[0028] The plant substrate cleaning polymer is made of plant substrate bundles with diameters of 0.5 mm, 0.3 mm, 0.1 mm, 0.05 mm and 0.01 mm.

[0029] The mass ratio of the plant substrates with diameters of 0.5 mm, 0.3 mm, 0.1 mm, 0.05 mm and 0.01 mm is (15~25):(15~25):(20~30):(15~25):(10~20).

[0030] The plant substrate cleaning polymer is made of plant substrate bundles with diameters of 0.3 mm, 0.1 mm, 0.05 mm, 0.03 mm and 0.01 mm.

[0031] The mass ratio of the plant substrates with diameters of 0.3 mm, 0.1 mm, 0.05 mm, 0.03 mm and 0.01 mm is (20~30):(15~25):(10~20):(20~30):(10~20).

[0032] The application described in this invention is the use of the plant-based cleaning polymer in the preparation of plant-based active self-cleaning toothpaste.

[0033] The invention will be further illustrated below with specific implementation examples: Example 1

[0034] Plant matrix polymers include matrices extracted from terrestrial and aquatic plants; such as palm matrix extracted from the Arecaceae family, Alpinia galbana matrix from the Zingiberaceae family, Ziziphus jujuba matrix from the Poaceae family, mulberry bark matrix from the Arboraceae family, pineapple leaf matrix from the Bromeliaceae family, wisteria matrix from the Climbing Vines family, loofah matrix from the Cucurbitaceae family, Rosa laevigata matrix from the Shrub family, Brassicaceae matrix, and kelp matrix from the Algaceae family; among them, the quercetin antibacterial factor contained in palm leaf matrix (Arcaceae family), Alpinia galbana matrix (Zingiberaceae family), mulberry bark matrix (Arboraceae family), and wisteria matrix (Climbing Vines family) are natural examples of plant-based oral care applications. The matrix will be extracted from the above plants, and further extracted to form plant matrix bundles with diameters of 1mm, 0.7mm, 0.5mm, 0.3mm, 0.1mm, 0.07mm, 0.05mm, 0.03mm, and 0.01mm. Furthermore, the plant matrix bundles of different diameters will be mixed in a specific ratio to create a plant matrix cleaning polymer (self-cleaning polymer). Depending on the oral condition of people at different age stages, different friction intensities can be adjusted to achieve different teeth cleaning effects.

[0035] The plant substrate cleaning polymer (self-cleaning polymer) prepared in this embodiment was tested: 1. Clinical trials of plant-based cleaning polymers (self-cleaning polymers) on the oral cleaning process: Experimental objective: To verify the cleaning effect and side effects of different specifications of plant matrix bundles, formulated into self-cleaning matrix polymer bodies according to a certain ratio, and the resulting different friction intensities on teeth cleaning.

[0036] Experimental Results: The self-cleaning polymer formulation in group A achieved a cleaning effect of 86.4%, while groups B, C, and D achieved cleaning effects of 77.5%, 69.6%, and 61.5%, respectively. Under the same time- and conditions as clinical cleaning experiments, clinical data showed no gingival damage and good comfort levels. Comparison with randomized formulations: Groups E and F achieved cleaning effects of 92.3% and 88.4%, respectively. Under the same time- and conditions as clinical cleaning experiments, clinical data showed gingival damage and poor comfort levels, indicating that these formulations are not suitable for self-cleaning polymer formulations. Comparison with randomized formulations: Groups G and H achieved cleaning effects of 52.8% and 47.5%, respectively, indicating relatively good comfort levels but weaker cleaning effects, making them unsuitable for self-cleaning polymer formulations.

[0037] 2. Synergistic testing of self-cleaning polymers and chemical drugs: Experimental objective: To test the cleaning effect of self-cleaning polymers and chemical drugs on oral teeth.

[0038] Experimental Results: The experimental results show that fluoride toothpaste made from self-cleaning polymers, toothpaste ingredients, and fluoride (F-) achieved a 30.1% antibacterial balance rate in clinical testing. Whitening toothpaste made from self-cleaning polymers, toothpaste ingredients, and hydrogen peroxide (HaHCO2) achieved a 91.3% tooth pigment decomposition rate, significantly outperforming other types of toothpaste. Anti-sensitivity toothpaste made from self-cleaning polymers, toothpaste ingredients, and potassium nitrate (KNO3) achieved an 82.7% anti-sensitivity rate, far exceeding other types of toothpaste. Herbal toothpaste made from self-cleaning polymers, toothpaste ingredients, and sodium bicarbonate (NaHCO3) achieved a 39.5% antibacterial balance rate and a 65.8% tooth pigment decomposition rate. Probiotic toothpaste made from self-cleaning polymers, toothpaste ingredients, and Lactobacillus (C3H6O3) achieved an enzyme maintenance rate of 49.4%, significantly exceeding other types of toothpaste. Self-cleaning polymer + toothpaste ingredients + natural bamboo charcoal (C6H) 10 Activated charcoal toothpaste made with O6 can achieve an antibacterial balance rate of up to 42.8%, a pigment decomposition rate of up to 61.4%, an anti-sensitivity efficiency of up to 53%, and an enzyme maintenance rate of up to 36.9%.

[0039] Example 2

[0040] ① Extra-strength self-cleaning toothpaste. Functions: Daily cleaning, cavities prevention, removes tea stains and tobacco residue.

[0041] Formula components: Extracted and prepared plant matrix substrates with diameters of 1mm, 0.7mm, 0.1mm, and 0.05mm are paired in a ratio of 15 / 25 / 35 / 25 to form a polymer with a thickness of 0.2cm-1cm (the thickness can be adjusted according to production needs); abrasive (hydrated silica): 45-50g; humectant (glycerin / sorbitol): 25-30g; thickener (xanthan gum / CMC): 1-2g; surfactant (SLS / coco-betaine): 1-2g; fragrance / xylitol: 1-2g; preservative (sodium benzoate): 0.1-0.3g. The formula conforms to GB / T8372 standard and American Dental Association (ADA) SESS1 standard.

[0042] ② Neutral self-cleaning toothpaste. Function: For daily cleaning and prevention of cavities.

[0043] Formula components: Extracted and prepared plant matrix bundles with diameters of 0.7mm, 0.3mm, 0.1mm, 0.07mm, and 0.03mm are paired in a ratio of 20 / 30 / 20 / 15 / 15 to form a polymer with a thickness of 0.1-0.6cm (the thickness can be adjusted according to production needs); abrasive (hydrated silica): 45-50g; humectant (glycerin / sorbitol): 25-30g; thickener (xanthan gum / CMC): 1-2g; surfactant (SLS / coco-betaine): 1-2g; fragrance / xylitol: 1-2g; preservative (sodium benzoate): 0.1-0.3g. The formula conforms to GB / T8372 standard and American Dental Association (ADA) SESS1 standard.

[0044] ③ Soft-textured self-cleaning toothpaste. Function: For daily cleaning and prevention of cavities.

[0045] Formula components: Extracted and prepared plant matrix bundles with diameters of 0.5mm, 0.3mm, 0.1mm, 0.05mm, and 0.01mm are paired in a ratio of 20 / 20 / 25 / 20 / 15 to form a polymer body with a thickness of 0.1-0.4cm (adjust thickness according to production needs); abrasive (hydrated silica): 45-50g; humectant (glycerin / sorbitol): 25-30g; thickener (xanthan gum / CMC): 1-2g; surfactant (SLS / coco-betaine): 1-2g; fragrance / xylitol: 1-2g; preservative (sodium benzoate): 0.1-0.3g. The formula conforms to GB / T8372 standard and American Dental Association (ADA) SESS1 standard.

[0046] ④ Gentle self-cleaning toothpaste (for children). Functions: Safe cleaning, anti-cavity, low irritation.

[0047] Formula components: Extracted and prepared plant matrix bundles with diameters of 0.3mm, 0.1mm, 0.05mm, 0.03mm, and 0.01mm are paired in a ratio of 25 / 20 / 15 / 25 / 15 to form a polymer with a thickness of 0.1-0.3cm (adjust thickness according to production needs); Fluoride: ≤0.1% (or fluoride-free); Surfactant: SLS is prohibited (cocobetaine is used instead); Flavor: Fruit flavor (e.g., strawberry flavor); Hydrated silica: 35g; Glycerin: 30g; Xylitol: 3g; Cocobetaine: 1g; Strawberry flavor: 1g. The formula conforms to GB / T8372 standard and American Dental Association (ADA) SESS1 standard.

[0048] Example 3

[0049] ① Enhanced anti-cavity self-cleaning toothpaste (fluoride type). Function: Strengthens tooth enamel and prevents cavities.

[0050] Formula ingredients: Extracted and prepared plant matrix bundles with diameters of 1mm, 0.7mm, 0.1mm, and 0.05mm are paired in a ratio of 15 / 25 / 35 / 25 to form a polymer with a thickness of 0.1cm-1cm (adjust thickness according to production needs); Fluoride: 0.1-0.15% for adult toothpaste; Abrasive (hydrated silica): 45-50g; Humectant (glycerin / sorbitol): 25-30g; Thickener (xanthan gum / CMC): 1-2g; Surfactant (SLS / coco-betaine): 1-2g; Fragrance / xylitol: 1-2g; Preservative (sodium benzoate): 0.1-0.3g. The formula conforms to GB / T8372 standard and American Dental Association (ADA) SESS1 standard.

[0051] ② Neutral anti-cavity self-cleaning toothpaste (fluoride type). Function: Strengthens tooth enamel and prevents cavities.

[0052] Formula components: Extracted and prepared plant matrix bundles with diameters of 0.7mm, 0.3mm, 0.1mm, 0.07mm, and 0.03mm are paired in a ratio of 20 / 30 / 20 / 15 / 15 to form a polymer with a thickness of 0.1cm-0.6cm (adjust thickness according to production needs); fluoride (sodium monofluorophosphate): 0.1-0.15%; abrasive (hydrated silica): 45-50g; humectant (glycerin / sorbitol): 25-30g; thickener (xanthan gum / CMC): 1-2g; surfactant (SLS / cocobetaine): 1-2g; fragrance / xylitol: 1-2g; preservative (sodium benzoate): 0.1-0.3g. The formula conforms to GB / T8372 standard and American Dental Association (ADA) SESS1 standard.

[0053] ③ Soft, anti-cavity self-cleaning toothpaste (fluoride type). Function: Strengthens tooth enamel and prevents cavities.

[0054] Formula components: Extracted and prepared plant matrix bundles with diameters of 0.5mm, 0.3mm, 0.1mm, 0.05mm, and 0.01mm are paired in a ratio of 20 / 20 / 25 / 20 / 15 to produce a polymer thickness of 0.1cm-0.4cm (adjust thickness according to production needs); fluoride: 0.1-0.15%; abrasive (hydrated silica): 45-50g; humectant (glycerin / sorbitol): 25-30g; thickener (xanthan gum / CMC): 1-2g; surfactant (SLS / cocobetaine): 1-2g; fragrance / xylitol: 1-2g; preservative (sodium benzoate): 0.1-0.3g. The formula conforms to the national standard GB / T8372 and the American Dental Association (ADA) SESS1 standard.

[0055] Example 4

[0056] ① Extra Whitening Self-Cleaning Toothpaste. Function: Removes stains and whitens teeth.

[0057] Formula components: Extracted and prepared plant matrix bundles with diameters of 1mm, 0.7mm, 0.1mm, and 0.05mm are paired in a ratio of 15 / 25 / 35 / 25 to form a polymer with a thickness of 0.1cm-1cm (adjust thickness according to production needs); Enzymes: Papain: 0.5% (for pigment decomposition); Hydrated silica: 50g; Glycerin: 25g; Hydrogen peroxide (3% solution): 5g (added after dilution); Xanthan gum: 1.5g; Cocamidoside: 2g; Peppermint flavor: 1g; Preservative: 0.3g. The formula conforms to GB / T8372 standard and American Dental Association (ADA SESS1) standard.

[0058] ② Neutral whitening self-cleaning toothpaste. Function: Removes stains and whitens teeth.

[0059] Formula components: Extracted and prepared plant matrix bundles with diameters of 0.7mm, 0.3mm, 0.1mm, 0.07mm, and 0.03mm are paired in a ratio of 20 / 30 / 20 / 15 / 15 to produce a polymer thickness of 0.1cm-0.6cm (adjust thickness according to production needs); Enzymes: Papain: 0.5% (for pigment decomposition); Hydrated silica: 50g; Glycerin: 25g; Hydrogen peroxide (3% solution): 5g (added after dilution); Xanthan gum: 1.5g; Coco-betaine: 2g; Peppermint flavor: 1g; Preservative: 0.3g. The formula conforms to the national standard (GB / T8372).

[0060] ③ Soft-textured whitening self-cleaning toothpaste. Function: Removes stains and whitens teeth.

[0061] Formula components: Extracted and prepared plant matrix bundles with diameters of 0.5mm, 0.3mm, 0.1mm, 0.05mm, and 0.01mm are paired in a ratio of 20 / 20 / 25 / 20 / 15 to produce a polymer thickness of 0.1cm-0.4cm (adjust thickness according to production needs); Enzymes: Papain: 0.5% (for pigment decomposition); Hydrated silica: 50g; Glycerin: 25g; Hydrogen peroxide: 3%; Solution: 5g (added after dilution); Xanthan gum: 1.5g; Coco-betaine: 2g; Peppermint flavor: 1g; Preservative: 0.3g. The formula conforms to GB / T8372 standard and American Dental Association (ADA) SESS1 standard.

[0062] Example 5

[0063] ① Extra-strength desensitizing self-cleaning toothpaste. Function: Relieves tooth sensitivity to hot and cold.

[0064] Formula components: Extracted and prepared plant matrix bundles with diameters of 1mm, 0.7mm, 0.1mm, and 0.05mm are paired in a ratio of 15 / 25 / 35 / 25 to form a polymer with a thickness of 0.1cm-1cm (adjustable according to production needs); Potassium nitrate: 5% (to block sensory signals from dental nerves); Strontium chloride: 3-5% (to seal dentinal tubules); Hydrated silica: 40g; Glycerin: 30g; Potassium nitrate: 5g; Xanthan gum: 1g; Coco-betaine: 1g; Xylitol: 2g. The formula conforms to GB / T8372 standard and American Dental Association (ADA) SESS1 standard.

[0065] ② Neutral, desensitizing, self-cleaning toothpaste. Function: Relieves tooth sensitivity to hot and cold.

[0066] Formula components: Extracted and prepared plant matrix with diameters of 0.7mm, 0.3mm, 0.1mm, 0.07mm, and 0.03mm; paired in a ratio of 20 / 30 / 20 / 15 / 15, resulting in a polymer thickness of 0.1cm-0.6cm (adjustable according to production needs); Potassium nitrate: 5% (to block sensory signals from dental nerves); Strontium chloride: 3-5% (to seal dentinal tubules); Hydrated silica: 40g; Glycerin: 30g; Potassium nitrate: 5g; Xanthan gum: 1g; Coco-betaine: 1g; Xylitol: 2g. The formula conforms to GB / T8372 standard and American Dental Association (ADA) SESS1 standard.

[0067] ③ Soft, desensitizing, self-cleaning toothpaste. Function: Relieves tooth sensitivity to hot and cold.

[0068] Formula components: Extracted and prepared plant matrix substrates with diameters of 0.5mm, 0.3mm, 0.1mm, 0.05mm, and 0.01mm are paired in a ratio of 20 / 20 / 25 / 20 / 15 to produce a polymer thickness of 0.1cm-0.4cm (adjust thickness according to production needs); Potassium nitrate: 5%, to block sensory signals from dental nerves; Strontium chloride: 3-5%, to seal dentinal tubules; Hydrated silica: 40g; Glycerin: 30g; Potassium nitrate: 5g; Xanthan gum: 1g; Coco-betaine: 1g; Xylitol: 2g. The formula conforms to GB / T8372 standard and American Dental Association (ADA) SESS1 standard.

[0069] Example 6 ① Enhanced Natural Herbal Self-Cleaning Toothpaste. Functions: Natural antibacterial, eco-friendly cleaning.

[0070] Formula composition: Extracted and prepared plant matrix bundles with diameters of 1mm, 0.7mm, 0.1mm, and 0.05mm are paired in a ratio of 15 / 25 / 35 / 25 to form a polymer with a thickness of 0.1cm-1cm (adjust thickness according to production needs); abrasive: baking soda (sodium bicarbonate, 20-30%); humectant: coconut oil (10-15%) + glycerin (10%); antibacterial agent: tea tree oil (0.5%); Coconut oil: 15g; Glycerin: 10g; Xanthan gum: 2g; Xylitol: 3g; Tea tree oil: 0.5g. The formula conforms to (GB / T8372) standard.

[0071] ② Neutral natural herbal self-cleaning toothpaste. Functions: Natural antibacterial, eco-friendly cleaning.

[0072] Formula components: Extracted and prepared plant matrix substrates with diameters of 0.7mm, 0.3mm, 0.1mm, 0.07mm, and 0.03mm are mixed in a ratio of 20 / 30 / 20 / 15 / 15 to produce a polymer thickness of 0.1cm-0.6cm (adjust thickness according to production needs); Abrasive: Baking soda (sodium bicarbonate): 20-30%; Humectant: Coconut oil (10-15%) + Glycerin (10%); Antibacterial agent: Tea tree oil: 0.5%; Coconut oil: 15g; Glycerin: 10g; Xanthan gum: 2g; Xylitol: 3g; Tea tree oil: 0.5g. The formula conforms to GB / T8372 standard and American Dental Association (ADA SESS1) standard.

[0073] ③ Soft-type natural herbal self-cleaning toothpaste. Functions: natural antibacterial, eco-friendly cleaning.

[0074] Formula components: Extracted and prepared plant matrix substrates with diameters of 0.5mm, 0.3mm, 0.1mm, 0.05mm, and 0.01mm are paired in a ratio of 20 / 20 / 25 / 20 / 15 to produce a polymer thickness of 0.1cm-0.4cm (adjust thickness according to production needs); abrasive: baking soda (sodium bicarbonate, 20-30%); humectant: coconut oil (10-15%) + glycerin (10%); antibacterial agent: tea tree oil: 0.5%; coconut oil: 15g; glycerin: 10g; xanthan gum: 2g; xylitol: 3g; tea tree oil: 0.5g. The formula conforms to GB / T8372 standard and American Dental Association (ADA SESS1) standard.

[0075] Example 7

[0076] ① Enhanced probiotic self-cleaning toothpaste. Functions: Balances gut flora, regulates immunity, improves bad breath, and reduces tooth decay.

[0077] Formulation components: Extracted and prepared plant matrix bundles with diameters of 1mm, 0.7mm, 0.1mm, and 0.05mm are paired in a ratio of 15 / 25 / 35 / 25 to form a polymer with a thickness of 0.1cm-1cm (adjust thickness according to production needs); Active / inactivated bacterial cells: such as Lactobacillus and Bifidobacterium, at a concentration of 1×10⁻⁶. 6 ~1×10 9 CFU / g (cold chain storage for live bacterial preparations), fermentation products or lysate products: such as lactic acid, short-chain fatty acids and other metabolites, concentration range 1-5% (higher stability without live bacteria); oily matrix: petrolatum, beeswax, shea butter, etc.: 30-70%; moisturizers: glycerin, hyaluronic acid: 5-15%; emulsifiers: polysorbate-80, lecithin: 1-5%; anti-inflammatory and soothing agents (external ingredients): allantoin, bisabolol (0.1-2%); preservatives: phenoxyethanol, potassium sorbate: 0.5-1%; ceramide (active ingredient): 0.7%. The formulation complies with (GB / T8372) standard and American Dental Association (ADA SESS1) standard.

[0078] ② Neutral probiotic self-cleaning toothpaste. Functions: Balances gut flora, regulates immunity, improves bad breath, and reduces tooth decay.

[0079] Formulation components: Extracted and prepared plant matrix bundles with diameters of 0.5mm, 0.3mm, 0.1mm, 0.05mm, and 0.01mm are paired in a ratio of 20 / 20 / 25 / 20 / 15 to form a polymer with a thickness of 0.1cm-0.4cm (adjust thickness according to production needs); active / inactivated bacterial cells, such as Lactobacillus and Bifidobacterium, at a concentration of 1×10⁻⁶. 6 ~1×10 9 CFU / g (cold chain storage for live bacterial preparations), fermentation products or lysate products: such as lactic acid, short-chain fatty acids and other metabolites, concentration range 1-5% (higher stability without live bacteria); oily matrix: petrolatum, beeswax, shea butter, etc.: 30-70%; moisturizers: glycerin, hyaluronic acid: 5-15%. Emulsifiers: polysorbate-80, lecithin: 1-5%; anti-inflammatory and soothing agents (auxiliary ingredients): allantoin, bisabolol: 0.1-2%; preservatives: phenoxyethanol, potassium sorbate: 0.5-1%; ceramide (active ingredient): 0.7%. The formulation complies with (GB / T8372) standards and American Dental Association (ADASesl) standards.

[0080] ③ Soft probiotic self-cleaning toothpaste. Functions: Balances gut flora, regulates immunity, improves bad breath, and reduces tooth decay.

[0081] Formulation components: Extracted and prepared plant matrix bundles with diameters of 0.5mm, 0.3mm, 0.1mm, 0.05mm, and 0.01mm are paired in a ratio of 20 / 20 / 25 / 20 / 15 to form a polymer with a thickness of 0.1cm-0.4cm (adjust thickness according to production needs); active / inactivated bacterial cells, such as Lactobacillus and Bifidobacterium, at a concentration of 1×10⁻⁶. 6 ~1×10 9 CFU / g (cold chain storage for live bacterial preparations), fermentation products or lysate products: such as lactic acid, short-chain fatty acids and other metabolites, concentration range 1-5% (higher stability without live bacteria); oily matrix: petrolatum, beeswax, shea butter, etc.: 30-70%; moisturizers: glycerin, hyaluronic acid: 5-15%. Emulsifiers: polysorbate-80, lecithin: 1-5%; anti-inflammatory and soothing agents (auxiliary ingredients): allantoin, bisabolol: 0.1-2%; preservatives: phenoxyethanol, potassium sorbate: 0.5-1%; ceramide (active ingredient): 0.7%. The formulation complies with (GB / T8372) standards and American Dental Association (ADASesl) standards.

[0082] Example 8

[0083] ① Extra Strong Activated Charcoal Self-Cleaning Toothpaste. Functions: Natural cleaning, odor removal, and natural antibacterial properties.

[0084] Formula composition: Extracted and prepared plant matrix bundles with diameters of 1mm, 0.7mm, 0.1mm, and 0.05mm are paired in a ratio of 15 / 25 / 35 / 25 to form a polymer with a thickness of 0.1cm-1cm (adjust thickness according to production needs); natural bamboo charcoal or activated charcoal: 10-20%; silica, baking soda (sodium bicarbonate): 40-50%; glycerin, sorbitol: 15-20%; foaming agent: 0.5-1%; natural thickeners: xanthan gum, carrageenan: 1-3%; flavoring and sweeteners: 0.5-1%; preservatives: 0.1-0.5%. The formula conforms to GB / T8372 standard and American Dental Association (ADA SESS1) standard.

[0085] ② Neutral activated charcoal self-cleaning toothpaste. Functions: Natural cleaning, odor removal, and natural antibacterial properties.

[0086] Formula components: Extracted and prepared plant matrix bundles with diameters of 0.5mm, 0.3mm, 0.1mm, 0.05mm, and 0.01mm are paired in a ratio of 20 / 20 / 25 / 20 / 15 to produce a polymer thickness of 0.1cm-0.4cm (adjust thickness according to production needs); natural bamboo charcoal or activated wood charcoal: 10-20%; silica, baking soda (sodium bicarbonate): 40-50%; glycerin, sorbitol: 15-20%; foaming agent: 0.5-1%; natural thickeners: xanthan gum, carrageenan: 1-3%; flavoring and sweeteners: 0.5-1%; preservatives: 0.1-0.5%. The formula conforms to GB / T8372 standard and American Dental Association (ADA SESS1) standard.

[0087] ③ Soft-textured activated charcoal self-cleaning toothpaste. Functions: Natural cleaning, odor removal, and natural antibacterial properties.

[0088] Formula components: Extracted and prepared plant matrix bundles with diameters of 0.5mm, 0.3mm, 0.1mm, 0.05mm, and 0.01mm are paired in a ratio of 20 / 20 / 25 / 20 / 15 to produce a polymer thickness of 0.1cm-0.4cm (adjust thickness according to production needs); natural bamboo charcoal or activated wood charcoal: 10-20%; silica, baking soda (sodium bicarbonate): 40-50%; glycerin, sorbitol: 15-20%; foaming agent: 0.5-1%; natural thickeners: xanthan gum, carrageenan: 1-3%; flavoring and sweeteners: 0.5-1%; preservatives: 0.1-0.5%. The formula conforms to GB / T8372 standard and American Dental Association (ADA SESS1) standard.

[0089] Example 9

[0090] Based on the functional formulations in Examples 2, 3, 4, 5, 6, and 8, the moisturizer was removed, and the mixture was prepared in a 1:1 ratio. The mixed toothpaste was dried to a powder state and further fused with the plant-based polymer to form a single unit. After pressing, it was formed into a sheet-like solid toothpaste. The resulting products are, in order: enhanced cleaning self-cleaning solid toothpaste; neutral cleaning self-cleaning solid toothpaste; soft cleaning self-cleaning solid toothpaste; gentle self-cleaning solid toothpaste (for children); and enhanced anti-cavity self-cleaning solid toothpaste. Toothpaste (fluoride type); Neutral anti-cavity self-cleaning solid toothpaste (fluoride type); Soft anti-cavity self-cleaning solid toothpaste (fluoride type); Extra-strength whitening self-cleaning solid toothpaste; Neutral whitening self-cleaning solid toothpaste; Soft whitening self-cleaning solid toothpaste; Extra-strength anti-sensitivity self-cleaning solid toothpaste; Neutral anti-sensitivity self-cleaning solid toothpaste; Soft anti-sensitivity self-cleaning solid toothpaste; Extra-strength natural herbal self-cleaning solid toothpaste; Neutral natural herbal self-cleaning solid toothpaste; Soft natural herbal self-cleaning solid toothpaste; Extra-strength activated charcoal self-cleaning toothpaste; Neutral activated charcoal self-cleaning toothpaste; Soft activated charcoal self-cleaning toothpaste. The formula conforms to (GB / T8372) standards and American Dental Association (ADASesl) standards.

[0091] Example 10

[0092] Based on the formulation in Example 7, ① Enhanced Probiotic Self-Cleaning Toothpaste, ② Neutral Probiotic Self-Cleaning Toothpaste, and ③ Soft Probiotic Self-Cleaning Toothpaste were prepared and mixed in a 1:1 ratio, replacing the beneficial live bacteria in the formulation with non-live bacteria. The mixed toothpaste was then dried to a powder state and further fused with a plant-based polymer to form a single unit. After pressing, it was formed into a sheet-like solid toothpaste. The resulting products are, in order: Enhanced Probiotic Self-Cleaning Solid Toothpaste; Neutral Probiotic Self-Cleaning Solid Toothpaste; and Soft Probiotic Self-Cleaning Solid Toothpaste. The formulation conforms to the (GB / T8372) standard and the American Dental Association (ADA SESS1) standard.

[0093] Example 11

[0094] The toothpaste prepared in Example 3 was subjected to a storage stability test: Test Method: Accelerated test (high temperature and high humidity). Conditions: 40℃±2℃ / 75%RH±5% (high temperature and high humidity). Test duration: 1, 3, 6 months. Data Interpretation: Based on the accelerated test data, the shelf life at room temperature is estimated using empirical formulas (such as the Q10 rule, which states that the reaction rate increases by 2-4 times for every 10℃ increase in temperature). For example, if the product remains within acceptable limits after 3 months at 40℃, it may be equivalent to 18-24 months.

[0095] Example 12

[0096] The toothpastes prepared in Examples 2, 4, 5, 6, 7, 8, 9 and 10 were tested using the same methods as in Example 11. The results showed that the toothpastes prepared in this invention met all the required standards and had a shelf life of 18 to 24 months.

Claims

1. A plant substrate cleaning polymer, characterized in that, The plant substrate cleaning polymer is made of 4 to 5 different diameters of plant substrate bundles selected from 1 mm, 0.7 mm, 0.5 mm, 0.3 mm, 0.1 mm, 0.07 mm, 0.05 mm, 0.03 mm and 0.01 mm.

2. The plant substrate cleaning polymer according to claim 1, characterized in that, The plant substrate cleaning polymer is made of plant substrate bundles with diameters of 1 mm, 0.7 mm, 0.1 mm and 0.05 mm.

3. The plant substrate cleaning polymer according to claim 2, characterized in that, The mass ratio of the plant substrates with diameters of 1 mm, 0.7 mm, 0.1 mm and 0.05 mm is (10~20):(20~30):(30~40):(20~30).

4. The plant substrate cleaning polymer according to claim 1, characterized in that, The plant substrate cleaning polymer is made of plant substrate bundles with diameters of 0.7 mm, 0.3 mm, 0.1 mm, 0.07 mm and 0.03 mm.

5. The plant substrate cleaning polymer according to claim 2, characterized in that, The mass ratio of the plant substrates with diameters of 0.7 mm, 0.3 mm, 0.1 mm, 0.07 mm and 0.03 mm is (15~25):(25~35):(15~25):(10~20):(10~20).

6. The plant substrate cleaning polymer according to claim 1, characterized in that, The plant substrate cleaning polymer is made of plant substrate bundles with diameters of 0.5 mm, 0.3 mm, 0.1 mm, 0.05 mm and 0.01 mm.

7. The plant substrate cleaning polymer according to claim 2, characterized in that, The mass ratio of the plant substrates with diameters of 0.5 mm, 0.3 mm, 0.1 mm, 0.05 mm and 0.01 mm is (15~25):(15~25):(20~30):(15~25):(10~20).

8. The plant substrate cleaning polymer according to claim 1, characterized in that, The plant substrate cleaning polymer is made of plant substrate bundles with diameters of 0.3 mm, 0.1 mm, 0.05 mm, 0.03 mm and 0.01 mm.

9. The plant substrate cleaning polymer according to claim 2, characterized in that, The mass ratio of the plant substrates with diameters of 0.3 mm, 0.1 mm, 0.05 mm, 0.03 mm and 0.01 mm is (20~30):(15~25):(10~20):(20~30):(10~20).

10. The application of the plant substrate cleaning polymer according to claim 1, characterized in that, The application of the plant-based cleaning polymer in the preparation of plant-based active self-cleaning toothpaste.

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