UPS system based on radiation energy conversion module and electrochromic zinc ion battery module

Abstract

The invention discloses a UPS (Uninterrupted Power Supply) system based on a radiation energy conversion module and an electrochromic zinc ion battery module, which comprises a UPS shell, an electrochromic zinc ion battery module, a foldable-unfoldable radiation-proof radiation energy conversion module and an SOC (System On Chip) remote monitoring device, the innermost layer of the electrochromic zinc ion battery module is a battery bin, a plurality of batteries are arranged in the battery bin, and the plurality of batteries are arranged in a battery array and are fixed in the battery bin through a honeycomb-shaped ceramic bracket so as to realize stress dispersion and uniform heat dissipation; macropores of the honeycomb ceramic bracket are filled with a phase change material; and the foldable-unfoldable radiation-proof radiation energy conversion module is made of a flexible material formed by compounding an energy conversion layer and a radiation shielding layer, and is used for converting electromagnetic radiation and ionizing radiation into electric energy and blocking radiation harmful to a life body.

Description

Technical Field

[0001] This invention belongs to the field of electrochemical energy storage technology, specifically relating to a UPS system based on a radiation energy conversion module and an electrochromic zinc-ion battery module, which integrates a foldable-and-unfold radiation-proof radiation energy conversion module and an electrochromic zinc-ion battery module. Background Technology

[0002] An uninterruptible power supply (UPS) is a power protection device containing an energy storage device, used to provide a stable and uninterrupted power supply to critical loads when the power supply is abnormal or interrupted.

[0003] Current UPS systems still have shortcomings in some hazardous environments. For example, lead-acid battery-based UPS systems may release oxygen at the positive electrode when charging to 70%–80% capacity, and hydrogen gas (a Class A hazardous substance) may begin to be released at the negative electrode when charging to about 90% capacity. Lithium-ion battery-based UPS systems are prone to thermal runaway in radiation and explosive environments, leading to the release of toxic gases and explosions. On the other hand, in terms of UPS power visualization signal transmission technology, traditional UPS systems still suffer from problems such as reliance on voltage sensors for power monitoring, the need for additional wiring, and susceptibility to electromagnetic interference. Furthermore, in high-risk scenarios accompanied by strong electromagnetic radiation (such as electromagnetic pulses from nuclear facilities) or ionizing radiation (such as X-rays and gamma rays), traditional UPS systems lack the ability to block, collect, and utilize the energy of ionizing and electromagnetic radiation.

[0004] In summary, there is an urgent need to design an uninterruptible power supply system suitable for use in high-risk environments to address the aforementioned technical deficiencies. Summary of the Invention

[0005] To address the aforementioned technical problems in existing technologies, this invention provides a UPS system based on a radiation energy conversion module and an electrochromic zinc-ion battery module, suitable for use in high-risk environments.

[0006] The technical solution adopted in this invention is:

[0007] A UPS system based on a radiation energy conversion module and an electrochromic zinc-ion battery module is characterized by comprising a UPS housing, an electrochromic zinc-ion battery module housed within the UPS housing, a foldable / unfoldable radiation-proof radiation energy conversion module, and a SOC remote monitoring device. The SOC remote monitoring device achieves non-contact detection of the zinc-ion battery module's state of charge through an electrochromic color-changing mechanism in the infrared band, and integrates a wireless-fiber hybrid transmission architecture and intelligent switching logic to provide real-time alarm responses upon detecting UPS abnormalities.

[0008] The UPS enclosure adopts a multi-layer protective battery compartment structure. The outermost layer of the multi-layer protective battery compartment structure is a stainless steel layer, and a polyurethane coating is applied to the surface of the stainless steel layer.

[0009] The innermost layer of the electrochromic zinc-ion battery module is the battery compartment, which contains multiple batteries arranged in a battery array and fixed in the battery compartment by a honeycomb ceramic support to achieve stress dispersion and uniform heat dissipation; the large pores of the honeycomb ceramic support are filled with phase change material.

[0010] The foldable and unfoldable radiation-proof radiation energy conversion module is installed on the UPS casing. It is made of a flexible material composed of an energy conversion layer and a radiation shielding layer. It is used to convert electromagnetic radiation and ionizing radiation into electrical energy and block radiation that is harmful to living organisms.

[0011] Furthermore, the foldable-unfoldable radiation-proof radiation energy conversion module includes a first part and a second part, which achieve spatial folding function through a hinge linkage structure.

[0012] Furthermore, the energy conversion layer includes a substrate and a pyramid array closely arranged on the flexible substrate, which has the functions of absorbing electromagnetic radiation resonant waves and X / γ ray photovoltaic conversion.

[0013] The pyramid array is composed of closely arranged pyramid-shaped protrusions with a base width of 0.5mm-5mm, and microstrip resonant cavities are embedded inside the pyramid-shaped protrusions; the isosceles triangular sides of the pyramid-shaped protrusions are provided with micro-nano protrusions with a base width of 10-100nm, which are used to suppress the reflection of 2-18 GHz battery waves.

[0014] The pyramid array is made of a carbonyl iron / strontium titanate / epoxy resin / graphene quaternary composite material; the microstrip resonant cavity is used to absorb electromagnetic waves of 0.3-6 GHz and convert them into current, so that the overall electromagnetic wave absorption rate of the energy conversion layer is ≥ 95%.

[0015] Furthermore, the radiation shielding layer uses dimethylsiloxane (PDMS) as a matrix and embeds a charge collection network to provide flexible support, high-energy radiation shielding, and charge management functions; the matrix is ​​embedded with a mixture of tungsten nanoparticles, nano-cerium oxide, and unsaturated lead carboxylate, wherein the mass ratio of the tungsten nanoparticles, nano-cerium oxide, and unsaturated lead carboxylate is 2:3:5.

[0016] The charge harvesting network is a three-dimensional conductive network formed by the self-assembly of copper alloy nanowires with a diameter of 50 nm and an aspect ratio greater than 20 filled inside PDMS. It is used to collect current from the energy harvesting functional layer and absorb and conduct secondary electrons generated by high-energy radiation.

[0017] Furthermore, the stainless steel layer can be 2mm thick 316L stainless steel or other materials that can provide impact and corrosion resistance; the polyurethane coating has a coating thickness of 50μm, and the surface has been verified by salt spray test to have a corrosion resistance of ≥1000h.

[0018] Furthermore, the spacing between adjacent batteries in the battery array is ≤ 50 mm.

[0019] Furthermore, the spacing between adjacent batteries in the battery array is 60~100 mm.

[0020] Furthermore, the ceramic honeycomb scaffold is made of alumina ceramic with a porosity of 40% to 80%. The alumina ceramic has a hierarchical pore structure, namely, macropores with a pore size greater than 50 nm, mesopores with a pore size between 2 nm and 50 nm, and micropores with a pore size less than 2 nm. The phase change material is filled in the macropores. The phase change material is a paraffin / expanded graphite composite material doped with metallic gallium.

[0021] Furthermore, the SOC remote monitoring device extends into the infrared electrochromic positive electrode inside the battery via radiation-resistant optical fiber. Utilizing the battery's own infrared electrochromic color-changing mechanism, a multi-channel infrared detector monitors the changes in the battery's internal infrared-band color-changing electrochromic zinc ion positive electrode.

[0022] Furthermore, the SOC remote monitoring device employs a multi-channel infrared detector to receive infrared light signals from the electrochromic zinc-ion battery and connects them to the wireless transmission module via a signal converter. By integrating the BeiDou satellite radio navigation service supporting the Modbus RTU protocol and the Iridium 9603N module, it ensures bidirectional data transmission in areas without ground base stations, guaranteeing a packet loss rate of ≤0.1%. Simultaneously, it incorporates a DF2B6M4SL TVS diode array to suppress 15kV / μs transient voltage surges and maintain communication stability in a 10V / m strong electromagnetic field environment.

[0023] The technical concept of this invention is to creatively integrate a foldable-and-unfoldable radiation energy conversion module and an electrochromic zinc-ion battery module, supplemented by non-contact SOC monitoring technology based on the infrared electrochromic effect, thus creating a high-risk environment-specific UPS system with "active defense, energy self-sufficiency, and intelligent monitoring" in one integrated system. This system not only passively resists hazards such as radiation and impact, but also actively converts harmful radiation energy in the environment into electrical energy for storage and utilization. Simultaneously, it achieves remote intelligent monitoring through highly reliable communication, fundamentally improving the survivability, continuity, and safety of the UPS under extreme conditions.

[0024] This invention is specifically designed for high-risk and special scenarios involving strong electromagnetic interference, ionizing radiation, flammable and explosive materials, or poor communication conditions. Specific application scenarios include:

[0025] 1. Nuclear industrial sites such as nuclear power plants, nuclear waste treatment facilities, and particle accelerators.

[0026] 2. Medical and research institutions such as radiotherapy rooms and radiological laboratories.

[0027] 3. Industrial environments where explosive gases exist, such as chemical plants and mines.

[0028] 4. Remote and critical facilities such as border posts, islands, and scientific research stations that lack reliable ground communication networks or power grids.

[0029] 5. Emergency command and communication support in response to electromagnetic pulse (EMP) attacks or severe natural disasters.

[0030] This invention has the following application value:

[0031] 1. Safety Value: Provides inherently safe and uninterrupted power protection for critical loads and operators in high-risk environments, greatly reducing the risk of secondary disasters caused by power failure or battery thermal runaway.

[0032] 2. Economic and strategic value: By recovering and utilizing environmental radiation energy, the system's self-sufficient power supply time can be extended, reducing dependence on external energy supply. This has significant economic and strategic implications for remote or enclosed scenarios.

[0033] 3. Technology-driven value: It has promoted the paradigm shift of UPS technology from "passive protection" to "active adaptation and energy recovery", providing new technical paths and integration solutions for the design of energy and electronic systems in future extreme environments.

[0034] Compared with the prior art, the beneficial effects of the present invention are reflected in:

[0035] 1. This invention not only effectively protects critical components of the UPS system and on-site personnel from hazards such as radiation, impact, and corrosion, but also converts some of the harmful radiation energy in the environment into electrical energy and stores it in the UPS battery, achieving a leap from "passive defense" to "active utilization." Specifically:

[0036] ① Achieving integrated radiation protection and energy recovery: The foldable-deployable radiation energy conversion module, with its composite structure (energy conversion layer and radiation shielding layer), can efficiently shield X / γ rays and electromagnetic waves (absorption rate ≥95%), while converting part of the radiation energy into current through photovoltaic and resonant mechanisms to charge the battery, thus enhancing the system's continuous power supply and survivability in the absence of mains power or in extreme environments.

[0037] ② An intrinsically safe and thermally efficient energy storage unit was constructed: Utilizing intrinsically safe electrochromic zinc-ion batteries, the risks of hydrogen evolution, oxygen evolution, and thermal runaway explosions are fundamentally eliminated. A unique honeycomb ceramic support combined with a phase change material filling design achieves mechanical fixation and stress dispersion while significantly optimizing heat dissipation uniformity, effectively suppressing localized overheating, and improving the thermal safety and cycle life of the battery pack under harsh operating conditions.

[0038] ③ It achieves interference-resistant and highly reliable non-contact battery management: It abandons the traditional monitoring method that relies on voltage sensors and wired connections, and innovatively utilizes the electrochromic properties of the battery's positive electrode material in the infrared band to achieve non-contact, in-situ monitoring of the State of Charge (SOC) through a built-in infrared detector. This method fundamentally avoids problems such as electromagnetic interference and insulation failure introduced by leads, resulting in more direct and reliable monitoring signals.

[0039] ④ Provides highly available intelligent communication and monitoring in extreme environments: Employs a redundant transmission architecture that combines wireless (BeiDou / Iridium) and radiation-resistant fiber optics, integrating intelligent switching logic and strong anti-interference circuits (such as TVS arrays). Even under conditions of strong electromagnetic interference and damage to ground base stations, it can still ensure reliable remote bidirectional transmission of system status information (such as SOC and alarm signals) with an extremely low packet loss rate (≤0.1%, fiber optic backup link <0.01%), meeting the stringent requirements for real-time monitoring and reliability in high-risk scenarios.

[0040] ⑤ Robust, durable, and adaptable external protection: The UPS casing features a composite structure of stainless steel outer layer and polyurethane coating, providing excellent impact and corrosion resistance. The foldable radiant energy conversion module facilitates transportation and storage, and can be unfolded during deployment to maximize protection and energy harvesting area, giving the system high environmental adaptability and deployment flexibility.

[0041] 2. The alumina ceramic honeycomb support (60% porosity) in this invention is formed by selective laser sintering, which achieves stress dispersion and uniform heat dissipation, and reduces thermal conductivity while fixing the structure.

[0042] 3. This invention uses a SOC monitoring device to penetrate deep into the infrared electrochromic positive electrode inside the battery. It mainly utilizes the battery's own electrochromic color-changing mechanism in the infrared band. A multi-channel infrared detector monitors the changes in the infrared color-changing electrochromic zinc-ion battery positive electrode inside the battery and feeds the signal back to the signal switching system and communication transmission module.

[0043] 4. This invention incorporates a fiber optic backup link into the communication module. By using radiation-resistant fiber optic links and a dual-channel TLP2768A optical module that supports hot-swappable switching (response time ≤10ms), coupled with a FIFO buffer to compensate for signal jitter, it ultimately achieves ultra-high reliability transmission with a packet loss rate of <0.01%. Attached Figure Description

[0044] Figure 1 This is a side view of the entire device of the present invention.

[0045] Figure 2 This is a cross-sectional side view of the present invention.

[0046] Figure 3 The present invention relates to a ceramic honeycomb support for filling battery gaps and a phase change material for filling the pores of the support.

[0047] Figure 4 This invention relates to the blade-shaped battery pack.

[0048] Figure 5 This is an unfolded view of a single battery removed from the battery pack of the present invention.

[0049] Figure 6 This is a side view of the deployable electromagnetic radiation and ionizing radiation absorption device in the entire device of the present invention after it has been deployed.

[0050] Figure 7 This is a front view of the entire device of the present invention.

[0051] Figure 8 This is a front view of the unfolded electromagnetic radiation and ionizing radiation absorption device of the entire apparatus of the present invention after it has been unfolded.

[0052] Figure 9 This is a top view of the entire device of the present invention.

[0053] Figure 10 This is a top view of the entire device of the present invention after it has been unfolded.

[0054] Figure 11This is a folding schematic diagram of the radiation energy absorption module of the folding-unfolding radiation protection of the present invention.

[0055] Figure 12 This is a schematic diagram of the unfolded energy conversion layer of the foldable-unfoldable radiation-proof radiation energy absorption module of the present invention.

[0056] Figure 13 This is a schematic diagram of the energy conversion layer and its constituent structural units. Detailed Implementation

[0057] The specific embodiments of the present invention will be described in detail below with reference to the accompanying drawings. It should be understood that the specific embodiments described herein are for illustration and explanation only and are not intended to limit the scope of the present invention.

[0058] It should be noted that, unless otherwise specified, the embodiments and features described in the present invention can be combined with each other.

[0059] The present invention will now be described in detail with reference to the accompanying drawings and exemplary embodiments.

[0060] refer to Figures 1 to 13 This invention discloses a UPS system based on a radiation energy conversion module and an electrochromic zinc-ion battery module, comprising a UPS housing 8, an electrochromic zinc-ion battery module housed within the UPS housing 8, a foldable-and-unfold radiation-proof radiation energy conversion module 3, and a SOC remote monitoring device 5. The SOC remote monitoring device 5 achieves non-contact detection of the zinc-ion battery module's state of charge through an electrochromic color-changing mechanism in the infrared light band, and integrates a wireless-fiber hybrid transmission architecture and intelligent switching logic to provide real-time alarm responses upon detecting abnormal UPS conditions.

[0061] The UPS housing 8 adopts a multi-layer protective battery compartment structure. The outermost layer of the multi-layer protective battery compartment structure is a stainless steel layer, and a polyurethane coating is applied to the surface of the stainless steel layer.

[0062] The innermost layer of the electrochromic zinc-ion battery module is the battery compartment, which contains multiple batteries 6. These batteries are arranged in a battery array and fixed in the battery compartment by a honeycomb ceramic support 7 to achieve stress dispersion and uniform heat dissipation. The large pores of the honeycomb ceramic support are filled with phase change material 9.

[0063] The foldable and unfoldable radiation-proof radiation energy conversion module is installed on the UPS casing. It is made of a flexible material composed of an energy conversion layer and a radiation shielding layer. It is used to convert electromagnetic radiation and ionizing radiation into electrical energy and block radiation that is harmful to living organisms.

[0064] In one embodiment, the foldable-unfoldable radiation-proof radiation energy conversion module includes a first part and a second part, the first part and the second part realizing the spatial folding function through a hinge linkage structure.

[0065] Specifically, the first and second parts can employ a four-wing hinge linkage mechanical structure, or other mechanical structures with similar effects. The four-wing hinge linkage mechanical structure uses a double-headed ratchet arm that engages with a square slot on an L-shaped connector to create a stable support structure (such as a "Λ" or "П" shape) when the device is unfolded. When folded, the volume is compressed to 1 / 4 of its unfolded state, meeting the storage requirements of confined spaces. A conductive silicone sealing strip (with radiation resistance ≥) is embedded at the chain connection. (Gy) ensures the continuity of electrical connections between functional layers during folding, while preventing radiation leakage. When folded up, the folding panel can wrap around the battery body; when unfolded, it can serve as a radiation energy conversion screen to block radiation.

[0066] In one embodiment, the energy conversion layer includes a substrate and a pyramid array closely arranged on a flexible substrate, which has the functions of absorbing electromagnetic radiation resonant waves and X / γ-ray photovoltaic conversion.

[0067] The pyramid array is composed of closely arranged pyramid-shaped protrusions with a base width of 0.5mm-5mm, and microstrip resonant cavities are embedded inside the pyramid-shaped protrusions; the isosceles triangular sides of the pyramid-shaped protrusions are provided with micro-nano protrusions with a base width of 10-100nm, which are used to suppress the reflection of 2-18 GHz battery waves.

[0068] The pyramid array is made of a carbonyl iron / strontium titanate / epoxy resin / graphene quaternary composite material; the microstrip resonant cavity is used to absorb electromagnetic waves of 0.3-6 GHz and convert them into current, so that the overall electromagnetic wave absorption rate of the energy conversion layer is ≥ 95%.

[0069] In one embodiment, the radiation shielding layer uses flexible polydimethylsiloxane (PDMS) as a matrix for shielding and charge collection networks to provide flexible support, high-energy radiation shielding, and charge management functions; the matrix is ​​embedded with a mixture of tungsten nanoparticles and lead powder, wherein the mass ratio of tungsten to lead is 7:3.

[0070] The shielding network is composed of stacked beryllium-doped lead nanoparticles filled inside PDMS, and is used to shield against radiation;

[0071] The charge harvesting network is a three-dimensional conductive network formed by the self-assembly of tungsten nanowires with a diameter of 50 nm and an aspect ratio greater than 20 filled inside PDMS. It is used to collect current from the energy harvesting functional layer and absorb and conduct secondary electrons generated by high-energy radiation.

[0072] In one embodiment, the stainless steel layer may be 2mm thick 316L stainless steel or other materials that can provide impact and corrosion resistance; the polyurethane coating has a coating thickness of 50μm, and the surface has been verified by salt spray test to have a corrosion resistance of ≥1000h.

[0073] In one embodiment, the spacing between adjacent cells in the battery array is ≤ 50 mm.

[0074] In one embodiment, the spacing between adjacent batteries in the battery array is 60-100 mm.

[0075] In one embodiment, the ceramic honeycomb scaffold is made of alumina ceramic 10 with a porosity of 40% to 80%. The alumina ceramic has a hierarchical pore structure, namely, macropores with a pore size greater than 50 nm, mesopores with a pore size between 2 nm and 50 nm, and micropores with a pore size less than 2 nm. The phase change material is filled in the macropores. The phase change material is a paraffin / expanded graphite composite material doped with metallic gallium.

[0076] Specifically, the phase change material uses paraffin / expanded graphite (7:3) mixed with a low melting point alloy (Bi 50wt%, Sn 25wt%, Cd 12.5wt%, Cr 12.5wt%), which increases the thermal conductivity to 2.3 W / (m·K) and the thermal propagation delay time is three times that of conventional designs.

[0077] In one embodiment, the SOC remote monitoring device extends into the infrared electrochromic positive electrode inside the battery via a radiation-resistant optical fiber 2. Utilizing the battery's own infrared electrochromic color-changing mechanism, a multi-channel infrared detector monitors the changes in the battery's internal infrared-band color-changing electrochromic zinc ion positive electrode.

[0078] In one embodiment, the SOC remote monitoring device uses a multi-channel infrared detector to receive infrared light signals from the electrochromic zinc-ion battery and connects them to the wireless transmission module through a signal converter. By integrating the BeiDou satellite radio navigation service supporting the Modbus RTU protocol and the Iridium 9603N module, it ensures that bidirectional data transmission can still be maintained in areas without ground base stations, and can guarantee a packet loss rate of ≤0.1%. At the same time, it has a built-in DF2B6M4SL TVS array to suppress 15kV / μs transient voltage surges and maintain communication stability in a strong electromagnetic field environment of 10V / m.

[0079] Specifically, the positive electrode of the electrochromic zinc-ion battery in the infrared band is made of zinc-doped tungsten bronze. Electrochromic material preparation. The SOC remote monitoring device also incorporates a fiber optic backup link. By employing radiation-resistant fiber optic links and using hot-swappable dual-channel TLP2768A optical modules (response time ≤10ms), coupled with a first-in-first-out (FIFO) buffer to compensate for signal jitter, ultra-high reliability transmission with a packet loss rate of <0.01% is achieved. This ensures the transmission of information regarding the SOC status in hazardous production environments.

[0080] More specifically, the UPS of this invention employs a dynamic link assessment and mains power monitoring and assessment system to achieve low-latency power supply switching. It adopts a voltage-frequency (VF) control mode, with a switching time ≤ 0.2 seconds and voltage fluctuation ≤ ±2%, making it suitable for critical loads such as ICUs. It also supports intelligent priority management of mains power, photovoltaic power, and energy storage, optimizing energy allocation through a MILP (Mixed Integer Linear Programming) model. By real-time analysis of the wireless channel bit error rate (BER) and fiber optic signal strength (RSSI), when BER > 10... -4 If RSSI < -90 dBm, the system will automatically switch to the optimal communication link. After the switching event is triggered, the system will push alarm information to the cloud monitoring platform and record the original data fault trace for ten seconds before and after the switch.

[0081] In one embodiment, the battery casing 14 is composed of a stainless steel layer, and a polyurethane coating is applied to the surface of the stainless steel layer. The stainless steel layer can be 2mm thick 316L stainless steel, or other materials that provide impact and corrosion resistance. The polyurethane coating is preferably 50μm thick, and its corrosion resistance has been verified by a salt spray test (ASTM B117 standard) for ≥1000h, resisting corrosion from acid mist, H2S, Cl2, etc.

[0082] Figure 1 The 1 port is the power input / output port. Through the built-in status detection system, it can switch between mains power monitoring mode, radiation absorption mode and energy storage mode in real time to ensure power supply.

[0083] Figure 1 The second fiber is a radiation-resistant fiber, used to support the transmission of information about the battery SOC and the internal status of the power supply in the event of a wireless signal communication interruption.

[0084] Figure 1 3 is a foldable-unfolding radiation energy absorption device.

[0085] The device uses a flexible composite material that integrates an energy conversion layer and a radiation shielding layer as its main material. It achieves spatial folding function through a hinge linkage structure, which can not only convert electromagnetic radiation (such as microwaves and radio frequencies) and ionizing radiation (such as gamma rays and X-rays) into electrical energy, but also completely block radiation that is extremely harmful to living organisms.

[0086] Figure 2 The 1 in Figure 1 The exposed part of the power input / output port,

[0087] Figure 2 The 2 in the figure represents an external radiation-resistant optical fiber.

[0088] Figure 2 The number 3 in the figure represents the folded state of the foldable electromagnetic radiation and ionizing radiation absorption device.

[0089] Figure 2 Component 4 represents the signal switching system and communication transmission module. The wireless communication module integrates a BeiDou RDSS (positioning accuracy <10m) supporting the Modbus RTU protocol and an Iridium 9603N module, ensuring bidirectional data transmission even in areas without ground base stations and guaranteeing a packet loss rate ≤ 0.1% (this module is used for short message communication). It also incorporates a DF2B6M4SL TVS diode array, capable of suppressing 15 kV / μs transient voltage surges and maintaining communication stability in strong electromagnetic fields of 10 V / m, making it suitable for extreme scenarios such as those in the power and chemical industries. A fiber optic backup link is also included in the communication module. By employing radiation-resistant fiber optic links and using dual-channel TLP2768A optical modules supporting hot-swappable switching (response time ≤10ms), coupled with a FIFO buffer to compensate for signal jitter, ultra-high reliability transmission with a packet loss rate <0.01% is ultimately achieved.

[0090] Figure 2 5 in the diagram refers to the SOC monitoring device, which extends deep into the infrared electrochromic positive electrode inside the battery. It mainly utilizes the battery's own electrochromic color-changing mechanism in the infrared band, and monitors the changes in the infrared color-changing electrochromic zinc-ion battery positive electrode inside through a multi-channel infrared detector, and feeds the signal back to the signal switching system and communication transmission module.

[0091] Figure 2 The 6 cells are electrochromic zinc-ion battery packs arranged in a blade shape, with a zinc-ion battery spacing of ≥50mm.

[0092] Figure 2 7 in the figure represents a ceramic honeycomb scaffold filled with phase change material.

[0093] Figure 2The 8 is the outermost shell of the multi-layered protective battery compartment structure.

[0094] Figure 3 9 is a phase change material filled in the macropores of honeycomb alumina ceramic. This phase change material is made by doping low melting point alloy (Bi 50wt%, Sn 25wt%, Cd 12.5wt%, Cr 12.5wt%) with paraffin / expanded graphite (7:3), which increases the thermal conductivity to 2.3 W / (m·K) and the thermal propagation delay time to 3 times that of conventionally designed phase change materials.

[0095] Figure 3 The 10 is an alumina ceramic honeycomb support (60% porosity), which is formed by selective laser sintering to achieve stress dispersion and uniform heat dissipation, and to reduce thermal conductivity while fixing.

[0096] Figure 4 11 is the negative electrode tab of the blade-shaped infrared electrochromic zinc-ion battery.

[0097] Figure 4 l2 is the positive electrode tab of a blade-shaped infrared electrochromic zinc-ion battery.

[0098] Figure 4 Point 13 is the output point of the SOC monitoring device located deep inside the battery at the infrared electrochromic positive electrode, used to output detection information.

[0099] Figure 4 14 is the battery casing, composed of a stainless steel layer, with a polyurethane coating applied to the surface of the stainless steel layer. The stainless steel layer can be 2mm thick 316L stainless steel, or other materials that provide impact and corrosion resistance. The preferred thickness of the polyurethane coating is 50μm, and the surface has been tested for corrosion resistance (≥1000h) using a salt spray test (ASTM B117 standard), demonstrating resistance to acid mist, H2S, Cl2, and other corrosive agents.

[0100] Figure 5 15 is the negative electrode material of the battery, mainly high-purity metallic zinc.

[0101] Figure 5 16 is the battery separator, which contains the battery's electrolyte and is used to separate the positive and negative electrodes to prevent short circuits and to transport ions.

[0102] Figure 5 17 is the electrochromic positive electrode of an electrochromic zinc-ion battery, made of zinc-doped tungsten bronze ( Electrochromic materials have the ability to change color in the mid-infrared light band.

[0103] Figure 5 The 18 is a SOC monitoring device that integrates a multi-channel infrared detector. It goes deep into the battery to collect the color change signal in the mid-infrared band of the positive electrode, and sends the signal to the outside through the connection point of the SOC monitoring device.

[0104] Figure 6 This is the unfolded state of the foldable electromagnetic radiation and ionizing radiation absorption device.

[0105] Figure 7 Point 19 is a fiber optic connection point, directly connected to the signal switching system and the communication transmission module.

[0106] Figure 7 This refers to the folded state of a foldable electromagnetic radiation and ionizing radiation absorption device.

[0107] Figure 8 Point 19 is a fiber optic connection point, directly connected to the signal switching system and the communication transmission module.

[0108] Figure 8 This is the unfolded state of the foldable electromagnetic radiation and ionizing radiation absorption device.

[0109] Figure 9 This refers to the folded state of a foldable electromagnetic radiation and ionizing radiation absorption device.

[0110] Figure 10 This is the unfolded state of the foldable and unfoldable radiation-proof radiation energy conversion module.

[0111] Figure 11 The 20 is the energy conversion layer of a foldable-and-unfoldable radiation-proof radiation energy conversion module.

[0112] Figure 11 21 is the radiation shielding layer of the foldable-unfoldable radiation-proof radiation energy conversion module.

[0113] Figure 11 22 is the hinge for a foldable-unfoldable radiation-proof radiation energy conversion module.

[0114] Figure 12 The 20 is the energy conversion layer of a foldable-and-unfoldable radiation-proof radiation energy conversion module.

[0115] Figure 12 21 is the radiation shielding layer of the foldable-unfoldable radiation-proof radiation energy conversion module.

[0116] Figure 13 23 is a foldable-and-unfoldable radiation-proof radiation energy conversion module with current conductors, mainly used to guide the generated current into the battery pack.

[0117] Figure 13 The 24th layer is a pyramid array that is tightly arranged on a flexible substrate in the energy conversion layer.

[0118] Figure 13 25 represents the micro-nano protrusions on the side surface of the pyramid-shaped protrusion of any unit in the pyramid array.

[0119] Although embodiments of the present invention have been shown and described above, it is understood that the above embodiments are exemplary and should not be construed as limiting the present invention. Those skilled in the art can make changes, modifications, substitutions and variations to the above embodiments within the scope of the present invention.

Claims

1. A UPS system based on a radiation energy conversion module and an electrochromic zinc-ion battery module, characterized in that, The system includes a UPS enclosure, an electrochromic zinc-ion battery module housed within the enclosure, a foldable / unfoldable radiation-proof radiation energy conversion module, and a State of Charge (SOC) remote monitoring device. The SOC remote monitoring device utilizes an infrared electrochromic color-changing mechanism to achieve non-contact detection of the zinc-ion battery module's state of charge, and integrates a wireless-fiber hybrid transmission architecture and intelligent switching logic to provide real-time alarm responses upon detecting UPS anomalies. The UPS enclosure adopts a multi-layer protective battery compartment structure. The outermost layer of the multi-layer protective battery compartment structure is a stainless steel layer, and a polyurethane coating is applied to the surface of the stainless steel layer. The innermost layer of the electrochromic zinc-ion battery module is the battery compartment, which contains multiple batteries arranged in a battery array and fixed in the battery compartment by a honeycomb ceramic support to achieve stress dispersion and uniform heat dissipation; the large pores of the honeycomb ceramic support are filled with phase change material. The foldable and unfoldable radiation-proof radiation energy conversion module is installed on the UPS casing. It is made of a flexible material composed of an energy conversion layer and a radiation shielding layer. It is used to convert electromagnetic radiation and ionizing radiation into electrical energy and block radiation that is harmful to living organisms.

2. The UPS system based on the radiation energy conversion module and the electrochromic zinc-ion battery module as described in claim 1, characterized in that, The foldable-unfoldable radiation-proof radiation energy conversion module includes a first part and a second part, which achieve spatial folding function through a hinge linkage structure.

3. The UPS system based on the radiation energy conversion module and the electrochromic zinc-ion battery module as described in claim 1, characterized in that, The energy conversion layer includes a substrate and a pyramid array closely arranged on the flexible substrate, which has the functions of absorbing electromagnetic radiation resonant waves and X / γ ray photovoltaic conversion. The pyramid array is composed of closely arranged pyramid-shaped protrusions with a base width of 0.5mm-5mm, and microstrip resonant cavities are embedded inside the pyramid-shaped protrusions; the isosceles triangular sides of the pyramid-shaped protrusions are provided with micro-nano protrusions with a base width of 10-100nm, which are used to suppress the reflection of 2-18 GHz battery waves. The pyramid array is made of a carbonyl iron / strontium titanate / epoxy resin / graphene quaternary composite material; the microstrip resonant cavity is used to absorb electromagnetic waves of 0.3-6 GHz and convert them into current, so that the overall electromagnetic wave absorption rate of the energy conversion layer is ≥ 95%.

4. The UPS system based on the radiation energy conversion module and the electrochromic zinc-ion battery module as described in claim 1, characterized in that, The radiation shielding layer uses dimethylsiloxane (PDMS) as a matrix and embeds a charge collection network to provide flexible support, high-energy radiation shielding, and charge management functions. The matrix is ​​embedded with a mixture of tungsten nanoparticles, nano-cerium oxide, and unsaturated lead carboxylate, with the mass ratio of tungsten nanoparticles, nano-cerium oxide, and unsaturated lead carboxylate being 2:3:

5. The charge harvesting network is a three-dimensional conductive network formed by the self-assembly of copper alloy nanowires with a diameter of 50 nm and an aspect ratio greater than 20 filled inside PDMS. It is used to collect current from the energy harvesting functional layer and absorb and conduct secondary electrons generated by high-energy radiation.

5. The UPS system based on the radiation energy conversion module and the electrochromic zinc-ion battery module as described in claim 1, characterized in that, The stainless steel layer can be 2mm thick 316L stainless steel or other materials that can provide impact and corrosion resistance; the polyurethane coating has a coating thickness of 50μm, and the surface has been verified by salt spray test to have a corrosion resistance of ≥1000h.

6. The UPS system based on the radiation energy conversion module and the electrochromic zinc-ion battery module as described in claim 1, characterized in that, The spacing between adjacent cells in the battery array is ≤ 50 mm.

7. The UPS system based on the radiation energy conversion module and the electrochromic zinc-ion battery module as described in claim 3, characterized in that, The spacing between adjacent batteries in the battery array is 60~100 mm.

8. The UPS system based on the radiation energy conversion module and the electrochromic zinc-ion battery module as described in claim 1, characterized in that, The ceramic honeycomb scaffold is made of alumina ceramic with a porosity of 40% to 80%. The alumina ceramic has a hierarchical pore structure, namely, macropores with a pore size greater than 50 nm, mesopores with a pore size between 2 nm and 50 nm, and micropores with a pore size less than 2 nm. The phase change material is filled in the macropores. The phase change material is a paraffin / expanded graphite composite material doped with metallic gallium.

9. The UPS system based on the radiation energy conversion module and the electrochromic zinc-ion battery module as described in claim 1, characterized in that, The SOC remote monitoring device extends deep into the infrared electrochromic positive electrode inside the battery via radiation-resistant optical fiber. It utilizes the battery's own electrochromic color-changing mechanism in the infrared band and monitors the changes in the battery's internal infrared electrochromic zinc ion positive electrode using a multi-channel infrared detector.

10. The UPS system based on the radiation energy conversion module and the electrochromic zinc-ion battery module as described in claim 9, characterized in that, The SOC remote monitoring device uses a multi-channel infrared detector to receive infrared light signals from electrochromic zinc-ion batteries and connects them to a wireless transmission module via a signal converter. By integrating the BeiDou satellite radio navigation service supporting the Modbus RTU protocol and the Iridium 9603N module, it ensures bidirectional data transmission in areas without ground base stations, guaranteeing a packet loss rate of ≤0.1%. At the same time, it has a built-in DF2B6M4SL TVS array to suppress 15kV / μs transient voltage surges and maintain communication stability in a strong electromagnetic field environment of 10V / m.

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